US1337718A - Cleansing of ferrous and non-ferrous metals - Google Patents
Cleansing of ferrous and non-ferrous metals Download PDFInfo
- Publication number
- US1337718A US1337718A US252474A US25247418A US1337718A US 1337718 A US1337718 A US 1337718A US 252474 A US252474 A US 252474A US 25247418 A US25247418 A US 25247418A US 1337718 A US1337718 A US 1337718A
- Authority
- US
- United States
- Prior art keywords
- ferrous
- cleansing
- electrolyte
- metals
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title description 9
- 239000002184 metal Substances 0.000 title description 9
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 title description 4
- -1 ferrous metals Chemical class 0.000 title description 3
- 239000003792 electrolyte Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 150000002739 metals Chemical class 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- RYKKQQUKJJGFMN-HVDRVSQOSA-N 4,5-bis(hydroxymethyl)-2-methylpyridin-3-ol;(2s)-5-oxopyrrolidine-2-carboxylic acid Chemical compound OC(=O)[C@@H]1CCC(=O)N1.CC1=NC=C(CO)C(CO)=C1O RYKKQQUKJJGFMN-HVDRVSQOSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Chemical group 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical compound [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- WKPSFPXMYGFAQW-UHFFFAOYSA-N iron;hydrate Chemical compound O.[Fe] WKPSFPXMYGFAQW-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- NNFCIKHAZHQZJG-UHFFFAOYSA-N potassium cyanide Chemical compound [K+].N#[C-] NNFCIKHAZHQZJG-UHFFFAOYSA-N 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000010959 steel Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25F—PROCESSES FOR THE ELECTROLYTIC REMOVAL OF MATERIALS FROM OBJECTS; APPARATUS THEREFOR
- C25F1/00—Electrolytic cleaning, degreasing, pickling or descaling
Definitions
- This invention relates to the cleansing of ferrous and non-ferrous metals, and more particularly to the electrolytic cleansing of such metals-
- the invention has for itsobject in eneral the rapid and thorou h cleansing of errous and non-ferrous meta sin an economical an efficient manner.
- the metals are cleansed by an elec trolytic process without the use of fixed electrodes.
- the parts to be cleansed are submerged in the electrolyte and are made the terminals for a source of alternating current.
- an electrolyte which is free from acids, eflicient in action, and inexpensive to roduce.
- the electrolyte has as its princi al in edient socom ined with a small quantity of hydrate or carbonate, either sodium, carbonate, or potassium.
- the electrolyte may be varied considerably as to the quantities of the several ingredients, but a typical electrolyte of this invention would be made by dissolving 32 grams of sodium or potassium cyanid in one liter of water and then adding four grams of sodium or potassium hydrate or by adding sodium or potassium carbonate and eight grams of grape sugar in case the electrolyte is to be used in the cleansing of ferrous metals.
- the organic matter such as grape sugar is added in order to keep the surfaces being cleaned free from coatin s and slime of iron oxid or iron hydrate. artrates and citrates may also be used for this purpose, but are not so satisfactory and are more expensive.
- terminalpf an alternating current source, the remaining ones to theother terminal of said source.
- the bright sur ace produced by this process also avoids the use of the bright dip which is composed of expensive nitric acid usedalone or in conjunction with sulfuric acid in the well-known bright dip process.
- a further advantage of this process resides 1n the fact that in the treatment with a nonac1d electrolyte the danger of rusting, due to acid remaming on the parts or the tedious process of thoroughly cleansin the acid rom the parts in water dips, is avoided. Parts cleansed in the cyanid electrolyte and by the use of alternating current may be removed directly from the electrolyte and left indefinitely without danger of rustin while the solution of which the electrolyte is composed remains upon them. 7
- the parts treated by the electrolyte and process of this invention are ready, when withdrawn from the solution and rinsed in water, to be plated, painted, lacquered, or welded, without further treatment.
- the process which utilizes the parts to be cleaned as the electrodes has the advantage that it avoids the use of the expensive fixed electrodes.
- An electrolyte for the cleansing ofv metals comprising cyanid, hydrate, and an organic agent.
- An electrolyte for the cleansing of metals comprising cyanid, hydrate, and grape sugar.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Cosmetics (AREA)
Description
.dium or potassium cyani STATES PATENT oF'FIoE.
SUMNER B. MASON, OF WILMETTE, ILLINOIS, ASBIGNOB TO WESTERN ELECTRIC COMPANY, INCORPORATED, OF NEW YORK, N. Y., A CORPORATION OF NEW YORK.
CLEANSING OF FEBBOUS AND NON-FERROUS METALS.
He Drawing.
To all whom it may concern:
Be it known that I, UMNER R. Mason, a citizen of the United States, residing at Wilmette, in the county of Cook and btate of Illinois, have invented certain new and useful Improvements in the Cleansm of Ferrous and Non-Ferrous Metals, of w ich the following is a full, clear, concise, and exact description.
This invention relates to the cleansing of ferrous and non-ferrous metals, and more particularly to the electrolytic cleansing of such metals- The invention has for itsobject in eneral the rapid and thorou h cleansing of errous and non-ferrous meta sin an economical an efficient manner.
In accordance with one feature of this invention, the metals are cleansed by an elec trolytic process without the use of fixed electrodes. In accordance with this feature, the parts to be cleansed are submerged in the electrolyte and are made the terminals for a source of alternating current.
In accordance with another feature of this invention, there is provided an electrolyte which is free from acids, eflicient in action, and inexpensive to roduce. According to this feature of t e invention, the electrolyte has as its princi al in edient socom ined with a small quantity of hydrate or carbonate, either sodium, carbonate, or potassium.
I The electrolyte may be varied considerably as to the quantities of the several ingredients, but a typical electrolyte of this invention would be made by dissolving 32 grams of sodium or potassium cyanid in one liter of water and then adding four grams of sodium or potassium hydrate or by adding sodium or potassium carbonate and eight grams of grape sugar in case the electrolyte is to be used in the cleansing of ferrous metals. The organic matter such as grape sugar is added in order to keep the surfaces being cleaned free from coatin s and slime of iron oxid or iron hydrate. artrates and citrates may also be used for this purpose, but are not so satisfactory and are more expensive. I
In practising the process of this invention a plurality of the parts to be cleansed would be submerged in the electrolyte and a portion of them would be connected to one Specification of Letters Patent.
terminalpf an alternating current source, the remaining ones to theother terminal of said source.
The greatest advantages of this process are realized when applied to the cleansin of iron or steel parts, due to the unusual brightness of the surface which is produced by this process. In its commercial a plication the unusual brightness of the surIace produced will in most cases make unnecessary the pol- 1sh1ng and burnishing of the parts which have been necessary eretofore to produce the necessary bri htness.
The bright sur ace produced by this process also avoids the use of the bright dip which is composed of expensive nitric acid usedalone or in conjunction with sulfuric acid in the well-known bright dip process.
A further advantage of this process resides 1n the fact that in the treatment with a nonac1d electrolyte the danger of rusting, due to acid remaming on the parts or the tedious process of thoroughly cleansin the acid rom the parts in water dips, is avoided. Parts cleansed in the cyanid electrolyte and by the use of alternating current may be removed directly from the electrolyte and left indefinitely without danger of rustin while the solution of which the electrolyte is composed remains upon them. 7
The parts treated by the electrolyte and process of this invention are ready, when withdrawn from the solution and rinsed in water, to be plated, painted, lacquered, or welded, without further treatment.
The process which utilizes the parts to be cleaned as the electrodes has the advantage that it avoids the use of the expensive fixed electrodes.
What is claimed is:
l. The process of cleansing metals which consists in making the parts to be cleansed the electrodes of an electrolytic cell, and subjecting them to the action of alternating cur rent.
2. An electrolyte for the cleansing ofv metals comprising cyanid, hydrate, and an organic agent.
Patented Apr. 20, 1920. Application filed September 8, 1818. Serial No. 252,474.
meta-ls flirmed in the proportions of 32 grams of cyanid, one liter of water, 4 grams of hydrate, and 8 grams of grape sugar.
5. An electrolyte for the cleansing of metals, comprising cyanid, hydrate, and grape sugar.
6. The process of cleansing metals, which consists 1n submerging the parts to be cleansed in a solution of cyanid, water, bydmte, and an organic agent, and submitting 10 them as electrodes to the action of alternatin current.
11 witness whereof, I hereunto subscribe my name this 24th day of August A. D.,
SUMNER MASON.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US252474A US1337718A (en) | 1918-09-03 | 1918-09-03 | Cleansing of ferrous and non-ferrous metals |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US252474A US1337718A (en) | 1918-09-03 | 1918-09-03 | Cleansing of ferrous and non-ferrous metals |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1337718A true US1337718A (en) | 1920-04-20 |
Family
ID=22956152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US252474A Expired - Lifetime US1337718A (en) | 1918-09-03 | 1918-09-03 | Cleansing of ferrous and non-ferrous metals |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1337718A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2685564A (en) * | 1949-06-25 | 1954-08-03 | Detrex Corp | Electrolytic cleaning process |
| DE1116013B (en) * | 1955-12-09 | 1961-10-26 | Enthone | Electrolyte for the cathodic removal of foreign matter from ferrous metals |
| US3357905A (en) * | 1960-03-28 | 1967-12-12 | Cleveland Twist Drill Co | Electrolyte composition and method of electrolytically removing stock from workpiece |
| US3429792A (en) * | 1965-07-30 | 1969-02-25 | Mitsubishi Heavy Ind Ltd | Method of electrolytically descaling and pickling steel |
| US6203691B1 (en) | 1998-09-18 | 2001-03-20 | Hoffman Industries International, Ltd. | Electrolytic cleaning of conductive bodies |
-
1918
- 1918-09-03 US US252474A patent/US1337718A/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2685564A (en) * | 1949-06-25 | 1954-08-03 | Detrex Corp | Electrolytic cleaning process |
| DE1116013B (en) * | 1955-12-09 | 1961-10-26 | Enthone | Electrolyte for the cathodic removal of foreign matter from ferrous metals |
| US3357905A (en) * | 1960-03-28 | 1967-12-12 | Cleveland Twist Drill Co | Electrolyte composition and method of electrolytically removing stock from workpiece |
| US3429792A (en) * | 1965-07-30 | 1969-02-25 | Mitsubishi Heavy Ind Ltd | Method of electrolytically descaling and pickling steel |
| US6203691B1 (en) | 1998-09-18 | 2001-03-20 | Hoffman Industries International, Ltd. | Electrolytic cleaning of conductive bodies |
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