US1378052A - Process of coating steel sheets with aluminum - Google Patents
Process of coating steel sheets with aluminum Download PDFInfo
- Publication number
- US1378052A US1378052A US422812A US42281220A US1378052A US 1378052 A US1378052 A US 1378052A US 422812 A US422812 A US 422812A US 42281220 A US42281220 A US 42281220A US 1378052 A US1378052 A US 1378052A
- Authority
- US
- United States
- Prior art keywords
- aluminum
- sheets
- coating
- bath
- steel sheets
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052782 aluminium Inorganic materials 0.000 title description 28
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title description 28
- 238000000576 coating method Methods 0.000 title description 18
- 239000011248 coating agent Substances 0.000 title description 17
- 229910000831 Steel Inorganic materials 0.000 title description 15
- 239000010959 steel Substances 0.000 title description 15
- 238000000034 method Methods 0.000 title description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 7
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- -1 AlNaCh Chemical compound 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/12—Aluminium or alloys based thereon
Definitions
- This invention relates to a process of coating thin steel sheets with aluminum and has for its object to provide a procedure which will be more efiicient in action and less costly to carry out than those which have been heretofore proposed.
- chlorid such as AlNaCh, which has a melting point of about 200 C.
- I further employ the usual apparatus for coating with tin, consisting of a series of submerged guide and traction rolls to carry the steel sheets into and out of the aluminum bath.
- the double aluminum sodium chlorid layer or bath is preferably maintained at about 300 C. on top of the aluminum by means of cooling coils.
- the steel sheets being freed from their oxids, or cleaned, are now heated up in a non-oxidizing atmosphere, or out of contact with the air, to a temperature of say 250 C. or 300 C. or higher, whereupon they are carried through the said double chlorid layer into the aluminum bath.
- Said double aluminum alkali chlorid is found to readily deposit a firmly adhering film on the.
- Tlidprocessof coating steel sheets with aluminum which consists in first depriving said sheets of any oxid coating they may have, then passing said sheets through a substantially as described.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating With Molten Metal (AREA)
Description
V adhere to" the I oial precautions are taken. If to remedy UNITED srarrs PATENT": orrice.
MENTS, TO WHEELING STEEL & IRON COMPANY, OF
A. CORPORATION OF WEST VIRGINIA.
WHEELING, WEST VIRGINIA,
PROCESS OF COATING STEEL SHEETS WITH AL'UMINUM,
No Drawing.
To all whom it may concern:
Be it known that I, SAMUEL PEAGOCK. a citizen of the United States. residing at Wheeling, in the county of Ohio and State of West Virginia, have invented certain new and useful Improvements in Processes of Coating Steel Sheets with Aluminum; and I do hereby declare the following to be a full, clear, and exact description of the invention, such as will enable others skilled 1n the art to which it appertains to make and use the same.
This invention relates to a process of coating thin steel sheets with aluminum and has for its object to provide a procedure which will be more efiicient in action and less costly to carry out than those which have been heretofore proposed.
With these'and other objects in view the invention consists in the novel steps and combinations of steps constituting the process, all as will be more fully hereinafter disclosed and particularly pointed out in the claims.
In order that the precise invention may be the more clearly understood, it is said: It is well known that thin sheets of steel after being descaled or cleaned according to well known procedures are now commonly immersed in a bath of molten tin, inorder to convert them into the tin plate of commerce. The tin of the coating, however, is a largeitem of cost when it is considered that these sheets are treated by the million, and in addition, said coating entails other well known objections not necessary to mention. A
It is therefore the object of this invention more specifically stated, to coat said sheets with aluminum and thus obviate many of the objections that are now met with in the tin coating processes.
But in coating said sheets by dipping them into a molten bath of aluminum, the
relatively high temperature of about 700? C. of the latter causes many practical d fliculties in obtaining a good coating, which greatly increase the cost of the procedure. 1
That is to say, the differences in temperature between the steel and aluminum are considerable and the coating is not apt to steel throughout,-:unless spe- Specification of Letters Patent.
Application filed November 9, 1920. Serial No. 422,812.,
Patented May 17, 1921.
this objection, we pass the steelsheets through the molten aluminum slowly enoughfor the steel sheets to reach the temperature of the bath, and to form an alloy film to hold the coating, the process will be found to be too slow to be commercial.
On the other hand, a rapid passage of the steel sheets through the molten bath will result in a coating consisting of a solidified, or frozen la er, almost devoid, of a film of alloy to hold it to the sheet, and possessing a considerable structure.
In carrying out this invention, I avoid the foregoing objections by employing 011 top of the molten aluminum a molten layer of an anhydrous double alkali aluminum porosity .due to a crystalline,
chlorid such as AlNaCh, which has a melting point of about 200 C. I further employ the usual apparatus for coating with tin, consisting of a series of submerged guide and traction rolls to carry the steel sheets into and out of the aluminum bath. The double aluminum sodium chlorid layer or bath is preferably maintained at about 300 C. on top of the aluminum by means of cooling coils. The steel sheets being freed from their oxids, or cleaned, are now heated up in a non-oxidizing atmosphere, or out of contact with the air, to a temperature of say 250 C. or 300 C. or higher, whereupon they are carried through the said double chlorid layer into the aluminum bath. Said double aluminum alkali chlorid is found to readily deposit a firmly adhering film on the. steel sheets as they pass into the aluminum, and the molten aluminum readily coats said filmwith a firmly adhering film of aluminum, as said sheets pass therethrough, with the result that the finonv the molten aluminum, however, -all contact with the air is avoided and thewcoating is thereforegreatly improved. Again, as is well known in coating procedures of this kind it-is very desirable to pass the coated,
sheets throu h palm oil as they leave the apparatus. t is found that instead of having a single double chlorid bath, two may be provided. The one is positioned on that side of the machine at which the steel plates enter the bath of aluminum, and the other Y is positioned on the exit side of the maplates therewith, as they leave the apparatus. 1
It is obvious that those skilled in the art may vary the details of the procedure without departing from .the spirit of the invention, and therefore it is not desired to be limited to the above disclosure except as may be required by the claims.
What is .claimed is:
1. The process ofcoating steel sheets with aluminum which consists in first passing said sheets through a molten bath of a double aluminum alkali metal chlorid, and then through a molten bath of aluminum} substantially as described.
2. Tlidprocessof coating steel sheets with aluminum which consists in first depriving said sheets of any oxid coating they may have, then passing said sheets through a substantially as described.
i said baths in the order named, substantially as described.
4. The process of coating steel sheets with aluminum which consists in floating a molf ten bath of a double aluminum alkali metal chlorid upon a molten bath of aluminum; maintaining the temperature of said first named bath below that of saidsecond named bath; heating said sheets to the approximate temperature of said first named bath; and passing said sheets through said baths in the order named, substantially a described.
5. The process of coating steel s eets with aluminum which consists in floating a molten bath of a double aluminum alkali metal chlorid upon a molten bath of aluminum; maintaining'the temperature of said first named bath below that of said second named bath; passing said sheets through said baths in the order named; and thin passing the coated sheets through a bat In testimony whereof I afiix my signature.
SAMUEL PEACOCK.
of palm oil,
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US422812A US1378052A (en) | 1920-11-09 | 1920-11-09 | Process of coating steel sheets with aluminum |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US422812A US1378052A (en) | 1920-11-09 | 1920-11-09 | Process of coating steel sheets with aluminum |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1378052A true US1378052A (en) | 1921-05-17 |
Family
ID=23676494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US422812A Expired - Lifetime US1378052A (en) | 1920-11-09 | 1920-11-09 | Process of coating steel sheets with aluminum |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1378052A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2437919A (en) * | 1945-07-19 | 1948-03-16 | American Rolling Mill Co | Process and means for improving the adherence of aluminum coatings |
| US2441776A (en) * | 1938-10-21 | 1948-05-18 | Freeport Sulphur Co | Process of metal coating metal articles |
| US2848797A (en) * | 1945-04-16 | 1958-08-26 | Lowell D Eubank | Metal-coated articles and method of making |
| US2848796A (en) * | 1945-04-12 | 1958-08-26 | Lowell D Eubank | Alloy coatings and method of applying |
| US2866262A (en) * | 1955-04-15 | 1958-12-30 | Horizons Inc | Process of metal coating metal objects to facilitate shaping the same |
-
1920
- 1920-11-09 US US422812A patent/US1378052A/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2441776A (en) * | 1938-10-21 | 1948-05-18 | Freeport Sulphur Co | Process of metal coating metal articles |
| US2848796A (en) * | 1945-04-12 | 1958-08-26 | Lowell D Eubank | Alloy coatings and method of applying |
| US2848797A (en) * | 1945-04-16 | 1958-08-26 | Lowell D Eubank | Metal-coated articles and method of making |
| US2437919A (en) * | 1945-07-19 | 1948-03-16 | American Rolling Mill Co | Process and means for improving the adherence of aluminum coatings |
| US2866262A (en) * | 1955-04-15 | 1958-12-30 | Horizons Inc | Process of metal coating metal objects to facilitate shaping the same |
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