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US1363754A - Storage-battery separator - Google Patents

Storage-battery separator Download PDF

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Publication number
US1363754A
US1363754A US225660A US22566018A US1363754A US 1363754 A US1363754 A US 1363754A US 225660 A US225660 A US 225660A US 22566018 A US22566018 A US 22566018A US 1363754 A US1363754 A US 1363754A
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US
United States
Prior art keywords
same
constituents
wood
battery
separators
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US225660A
Inventor
Gustav H Rabenalt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GOULD STORAGE BATTERY Co
Original Assignee
GOULD STORAGE BATTERY CO
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GOULD STORAGE BATTERY CO filed Critical GOULD STORAGE BATTERY CO
Priority to US225660A priority Critical patent/US1363754A/en
Application granted granted Critical
Publication of US1363754A publication Critical patent/US1363754A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • H01M50/429Natural polymers
    • H01M50/4295Natural cotton, cellulose or wood
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • My invention pertains to that classof devices known as battery separators which are ordinarily used to separate the plates of an electric battery, and are, therefore, partly or wholly immersed in the solution or electrolyte thereof.
  • separators should be impervious to even very minute particles of the material comprising battery elements, and at the same time pervious to the solution or electrolyte, they are often made of wood, as these characteristics are possessed in different degrees by various Untreated wood is affected, and more or less decomposed, by the battery solution and electrolytic action taking place in the battery, and in many types of battery is caused to liberate constituents or products, causing detrimental action to the cells. It is, therefore, usual to treat the wooden separators before use in a battery in some manner to deprive the same of such constituents as might inju-riously afiect the battery. Such treatment as ordinarily employed characterizes the separator by the properties of warping, curling and splitting, when dry. Therefore, it is usually necessary to keep such separators in water until they are to be used, and they are ordinarily transported and handled in water or in a soaked condition, in order that they may be kept from warping or splitting or otherwise becoming unfit for use.
  • My invention provides a satisfactorily treated separator which, in a dry condition, is not characterized by such detrimental qualities as warping, splitting, curling or disintegration, but may be kept in stock, shipped and handled in a dry condition ready for immediate use.
  • My method of producing such a separator is substantially as follows:
  • I first form the desired shape and size of separator from suitable wood. I then chemic'ally treat the wood in such manner as to remove the constituents which might have a deleterious effect upon the operation of the battery, and then wash the same thor- Specification of Letters Patent.
  • cedar One wood which I find very suitable for the employment of my invention is cedar; and one method of treating the same to remove deleterious constituents or products is to soak the separators in a mild solution of caustic potash or caustic soda and then wash Patented Dec. 28, 1920.
  • the separators may then be held in any suitable manner,asbetween ordinaryhand clamps, so that they cannot warp during drying, and then dried in anordinary commercial vacuum drier at a temperature in the neighborhood of 50 to 70 degrees Fahrenheit, at a pressure of about one inch of mercury, until the moisture content is approximately say 12 or 15%, or substantially the usual content of such wood when seasoned in ordinary atmospheric air.
  • a battery separator composed of wood from which some of the natural constituents have been extracted and containing its natural moisture content.
  • a battery separator composed of wood deprived of certain of its constituents and having substantially its natural moisture content for preventing warping and splitting when exposed to the atmosphere.
  • a battery separator composed of wood deprived of some of its natural constituents and containing those rendering it capable of withstanding ordinary climatic changes in and splitting.
  • a battery separator composed of wood deprived of certain of its constituents and containing substantially its natural moisture content whereby it is protected against warping and splitting when exposed to the action of atmospheric air.
  • a battery separator composed of wood deprived of certain of its constituents and retaining those rendering it capable of withstanding exposure to atmospheric air and retaining its physical properties substantially unaltered thereby.
  • a battery separator composed of wood deprived of some of its natural constituents while retaining others thereof, said retained constituents having associated therewith a moisture content substantially equal to the normal moisture content of the Wood when dried in air for the purpose of preventing warping and splitting of the separator when exposed to atmospheric air.
  • the method of making wooden sepa rators for batteries comprehending soaking the same in a chemical bath to affect certain constituents thereof, washing the same to extract the chemicals and said constituents, and subsequently drying the same in 'vacuo.
  • the method of making wooden separators for batteries comprehending soaking the same in'a chemical bath to affect certain constituents thereof, washing the same to extract the chemicals and said constituents, and subsequently drying the same in vacuo until the moisture content is substantially the same as that of the natural wood air dried.
  • the method of preparing wooden separators for use in batteries which consists in subjecting the same to achemical bath to affect certain constituents, subsequently washing the same to remove the chemicals and affected constituents, restraining the same from warping, and then while so restrained drying the same in vacuo until the moisture content is substantially the same as that of the natural wood air dried.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Description

. kinds of that material.
UNITED STATES PATENT OFFICE.-
G'USTAV H. RAIBENALT, OF LANCASTER, NEW YORK, ASSIGNOR TO GOULD STORAGE BATTERY COMPANY, A CORPORATION OF NEW YORK.
STORAGE-BATTERY SEPABATOR.
No Drawing.
To all whom it may concern:
Be it known that I, GUSTAV H. RABE'NALT, a citizen of the United States, residing in Lancaster, county of Erie, and State of New York, have invented new and useful Improvements in Storage-Battery Separators, of which the following is a description.
My invention pertains to that classof devices known as battery separators which are ordinarily used to separate the plates of an electric battery, and are, therefore, partly or wholly immersed in the solution or electrolyte thereof.
As it is highly important that such separators should be impervious to even very minute particles of the material comprising battery elements, and at the same time pervious to the solution or electrolyte, they are often made of wood, as these characteristics are possessed in different degrees by various Untreated wood is affected, and more or less decomposed, by the battery solution and electrolytic action taking place in the battery, and in many types of battery is caused to liberate constituents or products, causing detrimental action to the cells. It is, therefore, usual to treat the wooden separators before use in a battery in some manner to deprive the same of such constituents as might inju-riously afiect the battery. Such treatment as ordinarily employed characterizes the separator by the properties of warping, curling and splitting, when dry. Therefore, it is usually necessary to keep such separators in water until they are to be used, and they are ordinarily transported and handled in water or in a soaked condition, in order that they may be kept from warping or splitting or otherwise becoming unfit for use.
My invention provides a satisfactorily treated separator which, in a dry condition, is not characterized by such detrimental qualities as warping, splitting, curling or disintegration, but may be kept in stock, shipped and handled in a dry condition ready for immediate use.
My method of producing such a separator is substantially as follows:
I first form the desired shape and size of separator from suitable wood. I then chemic'ally treat the wood in such manner as to remove the constituents which might have a deleterious effect upon the operation of the battery, and then wash the same thor- Specification of Letters Patent.
oughly in pure water in order to remove any chemicals which may have been used in the process, and to carry off such constituents as have been taken out of the wood. I then drain the separators and hold them in any suitable manner which will restrain them from warping; and, while so held, I dry them in vacuo or at a pressure quite below ordinary atmospheric pressure until I have extracted suflicient of the moisture that the wood has substantially the same degree of moisture as it naturally would have under ordinary atmospheric conditions if well seasoned in the open air.
One wood which I find very suitable for the employment of my invention is cedar; and one method of treating the same to remove deleterious constituents or products is to soak the separators in a mild solution of caustic potash or caustic soda and then wash Patented Dec. 28, 1920.
Application filed March 30, 1918. Serial No. 225,660.
them in several changes of Water. The separators may then be held in any suitable manner,asbetween ordinaryhand clamps, so that they cannot warp during drying, and then dried in anordinary commercial vacuum drier at a temperature in the neighborhood of 50 to 70 degrees Fahrenheit, at a pressure of about one inch of mercury, until the moisture content is approximately say 12 or 15%, or substantially the usual content of such wood when seasoned in ordinary atmospheric air.
I do not wish to limit myself in any way to the exact method or product described herein to illustrate one embodiment of my invention, as considerable departure both in the nature of my improved separator and in the method of producing it may be made without departing from the spirit and scope of my invention, which is as set forth in the following claims: I
1. A battery separator composed of wood from which some of the natural constituents have been extracted and containing its natural moisture content.
2. A battery separator composed of wood deprived of certain of its constituents and having substantially its natural moisture content for preventing warping and splitting when exposed to the atmosphere.
3. A battery separator composed of wood deprived of some of its natural constituents and containing those rendering it capable of withstanding ordinary climatic changes in and splitting.
4. A battery separator composed of wood deprived of certain of its constituents and containing substantially its natural moisture content whereby it is protected against warping and splitting when exposed to the action of atmospheric air.
5. A battery separator composed of wood deprived of certain of its constituents and retaining those rendering it capable of withstanding exposure to atmospheric air and retaining its physical properties substantially unaltered thereby.
6. A battery separator composed of wood deprived of some of its natural constituents while retaining others thereof, said retained constituents having associated therewith a moisture content substantially equal to the normal moisture content of the Wood when dried in air for the purpose of preventing warping and splitting of the separator when exposed to atmospheric air.
7. The method of making wooden battery separators which consists in subjecting the wood to a liquid bath and subsequently drying the same under the influence of heat at a pressure below that of the atmosphere.
8. The method of making wooden separators for use in storage batteries comprehending soaking the same and then drying in cacao.
9. The method of making wooden separators for use in storage batteries which comprehends soaking the same to remove certain constituents and afterward drying in cacao.
10. The method of making wooden separators for use in storage batteries which comprehends soaking the same to remove certain constituents and afterward drying in vacuo until the moisture content is substantially equal to that of the natural wood dried in air. v
11. The method of making wooden sepa rators for batteries comprehending soaking the same in a chemical bath to affect certain constituents thereof, washing the same to extract the chemicals and said constituents, and subsequently drying the same in 'vacuo.
12. The method of making wooden separators for batteries comprehending soaking the same in'a chemical bath to affect certain constituents thereof, washing the same to extract the chemicals and said constituents, and subsequently drying the same in vacuo until the moisture content is substantially the same as that of the natural wood air dried.
13. The method of making wooden separators for batteries which comprehends chemically treating the wood to remove constituents which might deleteriously affect the operation of the battery, removing the chemicals therefrom and then drying the same in oaouo.
'14. The method of making wooden separators for batteries which comprehends chemically treating the wood'to remove constituents which might deleteriously affect.
the operation of the battery, removing the chemicals therefrom, and then drying the same in vacuo until the moisture content is substantially the same as that of the natural wood air dried. j v
15. The method of preparing wooden separators for batteries which consists in impregnating the same with chemicals acting upon certain constituents thereof, washing out the chemicals and certain affected constituents, and then drying in vacuo.
16. The method of preparing wooden separators for batteries which consists in impregnating the same with chemicals acting upon certain constituents thereof, washing out the chemicals and certain affected constituents, and then drying in oacuo until the moisture content is substantially the same as that of the natural wood air dried.
17. The method of preparing wooden separators for batteries which consists in impregnating the same with chemicals acting upon certain constituents thereof, washing out the chemicals and certain affected constituents, and then drying in vacuo while restrained from warping until the moisture content is substantially the same as that of the natural wood air dried.
18. The method of preparing wooden separators for batteries which comprehends impregnating the wood with chemicals affecting certain constituents, washing out the chemicals and affected constituents, confining the Wood while still wet to prevent Warping, and thendrying in an air bath having a temperature above that of the atmosphere and a pressure below that of the atmosphere until the moisture content of the Wood is substantially equal to that of the same Wood when dried by exposure to the atmosphere.
19. The method of preparing wooden separators for use in batteries which consists in subjecting the same to a chemical bath to afl'ect certain constituents, subsequently washing the same to remove the chemicals and affected constituents, restraining the same from Warping, and then while so restrained drying the same in vac 1w.
20. The method of preparing wooden separators for use in batteries which consists in subjecting the same to achemical bath to affect certain constituents, subsequently washing the same to remove the chemicals and affected constituents, restraining the same from warping, and then while so restrained drying the same in vacuo until the moisture content is substantially the same as that of the natural wood air dried.
GUSTAV H. RABENALT.
US225660A 1918-03-30 1918-03-30 Storage-battery separator Expired - Lifetime US1363754A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US225660A US1363754A (en) 1918-03-30 1918-03-30 Storage-battery separator

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US225660A US1363754A (en) 1918-03-30 1918-03-30 Storage-battery separator

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