US1206456A - Process of making a detonating explosive. - Google Patents
Process of making a detonating explosive. Download PDFInfo
- Publication number
- US1206456A US1206456A US82905814A US1914829058A US1206456A US 1206456 A US1206456 A US 1206456A US 82905814 A US82905814 A US 82905814A US 1914829058 A US1914829058 A US 1914829058A US 1206456 A US1206456 A US 1206456A
- Authority
- US
- United States
- Prior art keywords
- lead
- chlorate
- detonating
- making
- glycerin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title description 9
- 238000000034 method Methods 0.000 title description 3
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical compound [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 18
- 235000011187 glycerol Nutrition 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 3
- 235000010355 mannitol Nutrition 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- JNYAEWCLZODPBN-KVTDHHQDSA-N (2r,3r,4r)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@@H](O)[C@H]1O JNYAEWCLZODPBN-KVTDHHQDSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 229910001864 baryta Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 230000037452 priming Effects 0.000 description 2
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 description 1
- CQXXYOLFJXSRMT-UHFFFAOYSA-N 5-diazocyclohexa-1,3-diene Chemical class [N-]=[N+]=C1CC=CC=C1 CQXXYOLFJXSRMT-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 235000015842 Hesperis Nutrition 0.000 description 1
- 235000012633 Iberis amara Nutrition 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- MHWLNQBTOIYJJP-UHFFFAOYSA-N mercury difulminate Chemical compound [O-][N+]#C[Hg]C#[N+][O-] MHWLNQBTOIYJJP-UHFFFAOYSA-N 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- -1 paraifin Substances 0.000 description 1
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 239000000015 trinitrotoluene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B29/00—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate
- C06B29/02—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal
- C06B29/08—Compositions containing an inorganic oxygen-halogen salt, e.g. chlorate, perchlorate of an alkali metal with an organic non-explosive or an organic non-thermic component
Definitions
- the body behaves well within moist atmosphere, it is not readily soluble in water and its solutions evaporating spontaneously when exposed to air, leave as a residuum the detonating body.
- This substance may, without danger and after moistening with alcohol, be mixed with various combustible bodies, explosives, burning or even inert substances, paraifin, trinitrotoluene, tri-, and tetranitronaphthalene, nitrocellulose, chlorate of potassium or of baryta, perchlorate of ammonia, nitrate of baryta, chromates, etc., and when being mixed simultaneously with burning and combustible substances or reduction bodies, such as cyanids and-sulfocyanids of copper, of lead, etc., and with nitrocellulose and the new fulminating body, there will easily be obtained a viscous and thick paste. the said paste allows of the manufacture of primings for guns.
- the mixtures in which is moorporated the detonating body, resulting from the glycerin acting upon the basic chlorate of lead, as well as the said body in pure state, may be adapted for the manufacture of for detonating fuses for rockets, composition for fireworks and even inflammable compositions for matches.
- the said body may further enter into the composition of spccial explosives and may be used, in a small quantity, for the purpose of 1ncreasing the aptitude as to the detonation of certain mine explosives.
- One of these compounds is for instance obtained by causing one molecule of basic chlorate of lead, one molecule of plumbic hydrate to act upon one molecule of mannite or of mannitan. Likewise, a solu 'tion of bibasic or tribasic acetate of lead completion of the preparation and in the proportion of from one fifth to one twentieth of the weight of the explosive, amylic Patented Nov. 28, 1916.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Air Bags (AREA)
Description
' primings eer, isc.
Unrnn STATES PATEN OFFICE.
ALEXANDBE JOSEPH MARIN,
0F LAEKEN, NEAR BRUSSELS, BELGIUM.
PROCESS OF MAKING A IDE'I'QNATING EXPLOSIVE.
No Drawing.
To all whom it may concern Be it known that I, ALnxANnnn Josnrn MARIN, a subject of the King of Belgium, residing at Laeken, near Brussels, Belgium, have invented new and useful Improvements in Processes of Making Detonating Explosives; and I do hereby declare the following to be a full, clear, and exact description of the same.
When dissolving, of lead in glycerin,
in the hot state, chlorate it will be observed in course of time and during cooling, that an abundant deposit is formed, composed of fine, white crystals having silken brightness. The said crystalline powder, separated from the excess of glycerin and washed with alcohol, constitutes a very powerful detonating substance showing great analogy with fulminate of mercury and the diazobenzol salts.
The body behaves well within moist atmosphere, it is not readily soluble in water and its solutions evaporating spontaneously when exposed to air, leave as a residuum the detonating body. This substance may, without danger and after moistening with alcohol, be mixed with various combustible bodies, explosives, burning or even inert substances, paraifin, trinitrotoluene, tri-, and tetranitronaphthalene, nitrocellulose, chlorate of potassium or of baryta, perchlorate of ammonia, nitrate of baryta, chromates, etc., and when being mixed simultaneously with burning and combustible substances or reduction bodies, such as cyanids and-sulfocyanids of copper, of lead, etc., and with nitrocellulose and the new fulminating body, there will easily be obtained a viscous and thick paste. the said paste allows of the manufacture of primings for guns.
Generally, the mixtures, in which is moorporated the detonating body, resulting from the glycerin acting upon the basic chlorate of lead, as well as the said body in pure state, may be adapted for the manufacture of for detonating fuses for rockets, composition for fireworks and even inflammable compositions for matches. The said body may further enter into the composition of spccial explosives and may be used, in a small quantity, for the purpose of 1ncreasing the aptitude as to the detonation of certain mine explosives.
Basic chlorate of lead in a concentrated a ueous solution forms with mannite, sugar,
g u 359, dextrin and even with tannin, more Specification of Letters Patent.
By adding thereto ether,
or less crystallized or amorphous compounds. All these products explode violently means of heat or shocks. However, the violence of explosion is less than with the glycerin composition.
If basic perchlorate of lead (or neutral perchlorate of lead simultaneously .with oxid of lead) is caused to act'upon glycerin, there will be obtained a detonating combination, similar to that obtained with basic chlorate of lead, but crystallizing with difiiculty and being very soluble, even in alcohol. All these detonating products may, in the same manner as the glycerin composition, constituted with basic chlorate of lead, be mixed with the oxidizing salts of combustibles and of various explosive substances, and they may be adapted for the same uses as the explosive mixtures prepared with the glycerin combination of basic chlorate of lead. Besides these reactions, I'have found that similar reaction will be produced also between basic chlorate of' lead, mannitan and the glucosones, or (which is quite the same) by causing neutral chlorate of lead, simultaneously with oxid or hydrate of lead, to act upon the said substances. Usually, one molecule of neutral chlorate of lead, one molecule of glycerin, of mannite or of any other polyatomic alcohol, and one molecule of plumbic oxid or hydrate respectively are caused to react. By causing two molecules of plumbic oxid or hydrate to react, there will be obtained products being very little soluble in water, but being always highly detonating. One of these compounds is for instance obtained by causing one molecule of basic chlorate of lead, one molecule of plumbic hydrate to act upon one molecule of mannite or of mannitan. Likewise, a solu 'tion of bibasic or tribasic acetate of lead completion of the preparation and in the proportion of from one fifth to one twentieth of the weight of the explosive, amylic Patented Nov. 28, 1916.
Application filed April 2, 1914. Serial No. 829,058.
messes lead or its described equivalents with glycerin or its described equivalents, and treating the resulting substance with a substance insoluble in Water, Volatile, and having its boiling point above 100 C. at atmospheric pressure.
In testimony whereof, I have signed my name to this specification in the presence of two subscribing Witnesses.
ALEXANDRE JOSEPH MARIN Witnesses:
RUDOLPHE SAMHOF, CHAS. ROY VASMIT.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US82905814A US1206456A (en) | 1914-04-02 | 1914-04-02 | Process of making a detonating explosive. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US82905814A US1206456A (en) | 1914-04-02 | 1914-04-02 | Process of making a detonating explosive. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1206456A true US1206456A (en) | 1916-11-28 |
Family
ID=3274377
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US82905814A Expired - Lifetime US1206456A (en) | 1914-04-02 | 1914-04-02 | Process of making a detonating explosive. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1206456A (en) |
-
1914
- 1914-04-02 US US82905814A patent/US1206456A/en not_active Expired - Lifetime
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