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US1022598A - Process for producing the alloy of titanium with tin. - Google Patents

Process for producing the alloy of titanium with tin. Download PDF

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Publication number
US1022598A
US1022598A US60645411A US1911606454A US1022598A US 1022598 A US1022598 A US 1022598A US 60645411 A US60645411 A US 60645411A US 1911606454 A US1911606454 A US 1911606454A US 1022598 A US1022598 A US 1022598A
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US
United States
Prior art keywords
titanium
tin
alloy
producing
oxid
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US60645411A
Inventor
Auguste J Rossi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tam Ceramics LLC
Original Assignee
Titanium Alloy Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Titanium Alloy Manufacturing Co filed Critical Titanium Alloy Manufacturing Co
Priority to US60645411A priority Critical patent/US1022598A/en
Application granted granted Critical
Publication of US1022598A publication Critical patent/US1022598A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/24Selection of soldering or welding materials proper
    • B23K35/26Selection of soldering or welding materials proper with the principal constituent melting at less than 400 degrees C
    • B23K35/262Sn as the principal constituent

Definitions

  • PROCESS FOR PRODUCING THE ALLOY OF TITANIUM WITH TIN PROCESS FOR PRODUCING THE ALLOY OF TITANIUM WITH TIN.
  • My present invention relates to the production of said alloy by a novel method which, under special conditions and for special purposes, possesses advantages both in practice thereof and in resulting products.
  • Letters Patent No. 979,394 were granted to me December 20, 1910 for a method of producing said alloy by aid of aluminium reduction of titanium oxid as therein described.
  • My researches have now satisfied me that the said alloy may also for some purposes, notwithstanding the peculiar characteristics of tin, be also satisfactorily pro; prised by aid of carbon reduction of titanium oxid, though usually this method and its resulting product will prove, in my opinion, less desirable than that covered by my aforesaid patent.
  • My said alloy of titanium and tin I produce by the method of my present invention as follows.
  • I charge a mixture, preferably intimate, of oxid of tin, oxid of titanium and carbon, as for instance per the formulae
  • I also preferably add some tin.
  • the current is then turned on. This, the temperature being sufficiently raised, will result in production of a bath of molten tin, and reduction also of the titanium oxid, the titanium resulting from which mingles or dissolves in said bath of tin to constitute the said alloy.
  • the addition of tin'in metallic state though not absolutely necessary, facilitates the reduction of the titanium oxid by the carbon.
  • the procedure is such that the resulting alloy usually contains some carbon, often in excess of 1% derivedfrom the electrodes of the electric furnace by the well known carburizing action of the are, or also due, under the conditions of industrial practice, to the difficulty of exactly proportioning the reducing agent so as to merely satisfy chemical aflinit-y therefor of the oxygen present without leaving some uncombined carbon.
  • This circumstance is of no detriment to the product for many purposes, but will prove of advantage in certain special uses thereof.
  • the method of producing the binary alloy of titanium with tin which comprises charging together oxid of tin, oxid of titanium and carbon, and raising the temperature sufliciently to produce a bath of molten tin, and reduction also of the titanium oxid, substantially as described.
  • the method of producing the binary alloy of titanium with tin which comprises reducing titanium oxid by carbon in a bath of molten tin, substantially as described.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Electroplating And Plating Baths Therefor (AREA)
  • Coating With Molten Metal (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)

Description

IINITED STATE PATENT @FFIQE.
AUGUSTE J. BOSSI, 0F NIAG ARA FALLS, NEW YORK, ASSIGNOB TO THE TITANIUM ALLOY MANUFACTURING COMPANY, OF NEW YORK, N. Y., A CORPORATION OF MAINE.
PROCESS FOR PRODUCING THE ALLOY OF TITANIUM WITH TIN.
No Drawing.
To all whom z'tmay concern:
Be itknown that I, AUGUSTE J. Rossr, a citizen of the United States, and a resident of Niagara Falls, in the county of Niagara and State of New York, have invented certain new and useful Improvements inProcesses for Producing the Alloy of Titanium with Tin, of which the following is a specification.
My present invention relates to the production of said alloy by a novel method which, under special conditions and for special purposes, possesses advantages both in practice thereof and in resulting products. Letters Patent No. 979,394 were granted to me December 20, 1910 for a method of producing said alloy by aid of aluminium reduction of titanium oxid as therein described. My researches have now satisfied me that the said alloy may also for some purposes, notwithstanding the peculiar characteristics of tin, be also satisfactorily pro; duced by aid of carbon reduction of titanium oxid, though usually this method and its resulting product will prove, in my opinion, less desirable than that covered by my aforesaid patent.
My said alloy of titanium and tin I produce by the method of my present invention as follows. Into an electric furnace of any of the now well known forms, as for example such as illustrated and described in Letters Patent No. 802,941, granted to me October 24, 1905, I charge a mixture, preferably intimate, of oxid of tin, oxid of titanium and carbon, as for instance per the formulae To this mixture I also preferably add some tin. The current is then turned on. This, the temperature being sufficiently raised, will result in production of a bath of molten tin, and reduction also of the titanium oxid, the titanium resulting from which mingles or dissolves in said bath of tin to constitute the said alloy. The addition of tin'in metallic state, though not absolutely necessary, facilitates the reduction of the titanium oxid by the carbon.
Specification of Letters Patent.
Patented Apr. 9, 1912.
Application filed February 4, 1911. Serial No. 606,454.
In producing said alloy by my said process, in operations conducted on an industrial scale, it is preferable, if not indispensable, owing to the characteristic properties of tin under the conditions mentioned, to interpose between the atmosphere and the charge a liquid coating comprising molten neutral substances such as slag by superimposing and maintaining such coating as. for example, described in my Letters Patent X0. 877,518, granted January 28,. 1908. The procedure is such that the resulting alloy usually contains some carbon, often in excess of 1% derivedfrom the electrodes of the electric furnace by the well known carburizing action of the are, or also due, under the conditions of industrial practice, to the difficulty of exactly proportioning the reducing agent so as to merely satisfy chemical aflinit-y therefor of the oxygen present without leaving some uncombined carbon. This circumstance is of no detriment to the product for many purposes, but will prove of advantage in certain special uses thereof.
IVhat I claim as new and desire to secure by Letters Patent is the following, viz
1. The method of producing the binary alloy of titanium with tin, which comprises charging together oxid of tin, oxid of titanium and carbon, and raising the temperature sufliciently to produce a bath of molten tin, and reduction also of the titanium oxid, substantially as described.
2. The method of producing the binary alloy of titanium with tin, which comprises reducing titanium oxid by carbon in a bath of molten tin, substantially as described.
3. As a new article an alloy, or compound, consisting predominantly of titanium and tin alloyed together and containing also some carbon.
4. As a new article an alloy, or compound, consisting predominantly of titanium and tin alloyed together and containing also carbon in excess of 1%.
WALTER D. EDMONDS, PHILIP O. PECK.
US60645411A 1911-02-04 1911-02-04 Process for producing the alloy of titanium with tin. Expired - Lifetime US1022598A (en)

Priority Applications (1)

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US60645411A US1022598A (en) 1911-02-04 1911-02-04 Process for producing the alloy of titanium with tin.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US60645411A US1022598A (en) 1911-02-04 1911-02-04 Process for producing the alloy of titanium with tin.

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2669514A (en) * 1953-03-11 1954-02-16 Rem Cru Titanium Inc Titanium base alloys containing tin

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2669514A (en) * 1953-03-11 1954-02-16 Rem Cru Titanium Inc Titanium base alloys containing tin

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