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US1018990A - Method of and apparatus for producing and utilizing disk-like electric arcs for effecting gas reactions. - Google Patents

Method of and apparatus for producing and utilizing disk-like electric arcs for effecting gas reactions. Download PDF

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Publication number
US1018990A
US1018990A US63837111A US1911638371A US1018990A US 1018990 A US1018990 A US 1018990A US 63837111 A US63837111 A US 63837111A US 1911638371 A US1911638371 A US 1911638371A US 1018990 A US1018990 A US 1018990A
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gases
disk
producing
furnace
gas reactions
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US63837111A
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Fritz Rothe
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ELECTROCHEMISCHE WERKE G M B H
ELECTROCHEMISCHE WERKE GmbH
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ELECTROCHEMISCHE WERKE GmbH
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B21/00Nitrogen; Compounds thereof
    • C01B21/20Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
    • C01B21/24Nitric oxide (NO)
    • C01B21/30Preparation by oxidation of nitrogen

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  • the present invention contemplates a process whereinthese fundamental features are included in an operation embodying the further characteristic that the flaming are or a plurality of flaming arcs are spread out into a disk-like flame discharge by the gas movement alone, andpreferably wherein the ases are in contact with both sides of the ame discharge.
  • a fiat cylindrical furnace is employed in whose central plane lie the electrodes, and wherein the arc 1s generated between two or more electrodes; the gases to be treated being forced in tangentially to the periphery of the interior thereof and preferably on both sides of the flame-zone lying in the central plane.
  • the gases pass out of the furnace at or near the middle line of the longitudinal section of the furnace.
  • one outlet passage is provided on each side of the lane of the electrodes, corresponding to the inlet passage at the interior periphery of the furnace.
  • the gases follow spiral paths of comparatively great length between respectiveinlets and outlets, while the flame-zone lies in the central plane between the spiral path in the preferred arrangement.
  • the are formed between the electrodes is so affected that a disk-like flame discharge of large superficial area is produced, along which, preferably on both sides, the injected gases in comparatively thin sheets, rub in spiral paths of great length, whereas, in the plane of the electrodes a zone is formed in which little or but slight renewal of gases takes place.
  • This formation of a disk-shaped flame discharge is surprising, because it would be expected that either the arc would persist directly bet-ween the electrodes or that the arc would be blown out as soon as formed,-
  • FIG. 1 is a cross-section through the furnace; and Fig. 2 is a longitudinal sec tion thereof on the line DD of Fig. 1.
  • the furnace b is of relatively moderate width (or height) with respect to its diameter, in order'that the gases to be treated shall likewise be in the form of comparatively thin sheets.
  • the interior cross-section of the furnace mustlikewise-be so chosen that the movement of the gases shall follow in a spiral path. As illustrated in the draw-- riphery of the furnace linin while the two gas outlet passages f, and 2 are,located on the central line.
  • Fig. 1 the gas-injecting ports or inlet passages g, and g, are shown facing in opposite directions, so that the gases will move in opposite directions to each other on opposite 5 sides of the flame zone;
  • Fig. 2 the gas-injecting ports or inlet passages g, and g, are shown facing in opposite directions, so that the gases will move in opposite directions to each other on opposite 5 sides of the flame zone;
  • the inlet passages 9 and 9 are shown facing in the same direction, in which case the gases on the opposite sides of the flame zone will move in the same direction. If now, gas is 10 injected into the furnace through the inlet passages 9 and 9 the gases move uniformly in spiral paths to the outlet passages f and f while the arcs which have in the meantime been produced, in any well known manner such as by separating the electrodes after they have been brought into contact with. each other, between the electrodes 6 e and e are drawmo'ut and re-formed into a disk-like single flame discharge.
  • the method permits flame discharges of large energy consumption combined into a single flame disk; it further permits the employment to advantage of direct current, or of single-phase alternating current or of '25 polyphase alternating current, the number of electrodes beingfcorrespondingly chosen. Furthermore, a number of circuits can be employed connected upin parallel or in other relationas desired.
  • polyphase current for instance, a sixlayer of gas taking no part in the gas movement.
  • the gases to be treated may be admitted through more than one tangentially-arranged port; for instance, throughtwo, three, four or more symmetrically" distributed ports of the same kind on each side of the flamedisk. It is also feasible to have the gases move in opposite directions to each other on opposite sides of the flame zone.
  • the method of producing a disk-like electric arc and utilizing the same for the production of gas reactions which consists in establishing an electric arc discharge-between electrodes by means of a polyphase current within an inclosed space, forcing in the gases tangentially to the periphery of said space, and in a plane adjacent to but distinct from the electric arc discharge, and conducting the products of the reaction from the said space axially thereof; substantialiy as described.
  • An electric flame discharge apparatus provided with arcing electrodes, a flat furnace of substantially circular form, an
  • An electric flame discharge apparatus comprising a flat furnace of substantially circular form, a .plurality of circumferentially disposed electrodes between which an are or arcs are formed in substantially the centralplane of the furnace, an inlet passage at one side of thecentral plane for-introducing the gases tangentially to the interior periphery of the furnace and an outlet passage near the center ofthe furnace for discharging the gases axially of the furnace; substantially as described.
  • An electric flame discharge apparatus comprising a flat furnace of substantially circular form, a plurality of circumferentially disposed electrodes between which an arc or arcs are formed in substantially the central plane of the furnace, an inlet passage on each side of the central plane for introducing the gases tangentially to the interior periphery of the furnace, and an outlet passage on each side of the centralv FRITZ ROTHE.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Description

F. ROTHIJ.
METHOD OF AND APPARATUS FOR PRODUCING AND UTILIZING DISK LIKE ELECTRIC ARCS FOR EPPECTING GAS REACTIONS.
APPLICATION FILED .TULY13,1911.
1,018,990; Patented Feb. .27, 1912.
Wlfnesses: Jaye/12 0p;
UNIED srn FRITZ ROTHE, OF DESSAU, GERMANY, ASSIGNOB. TO ELECTROCHEMISCHE WERKE, G. M. B. IL, 015 BERLIN, GERMANY.
METHOD OF AND APPARATUS FOR PRODUCING AND UTILIZING DISK-LIKE ELECTRIC ARCS FOR EFFECTING GAS REACTIONS.
Specification of Letters Patent.
Patented Feb. 27, 1912.
Application filed July 13, 1911. Serial No. 638,371.
certain new and useful Improvements in Methods of and Apparatus for Producing and Utilizing Disk-Like Electric Arcs for Efi'ecting Gas Reactions; and I do hereby declare the following tobe a full, clear, and exact description of the invention, such as will enable others skilled in the art to which itappertains to make and use the same. I
Ithas been proposed heretofore to utilize electric arcs for efiectinggas reactionsby drawing out the arcs to a great length by means of whirling air currents, or by means ofv air admitted through openings distributed along the entire length of the are; or, in some instances, by whirling the are by magnetic means into surfaces of various forms. The efliciency of these methods depends upon the expanse of surface of contact between the gases and the arc. Furthermore, the possibility of drawing the are out to an extraordinary great length depends upon the avoidance of renewal of the gases between the electrodes of the arc. The present invention contemplates a process whereinthese fundamental features are included in an operation embodying the further characteristic that the flaming are or a plurality of flaming arcs are spread out into a disk-like flame discharge by the gas movement alone, andpreferably wherein the ases are in contact with both sides of the ame discharge.
In carrying out the invention, a fiat cylindrical furnace is employed in whose central plane lie the electrodes, and wherein the arc 1s generated between two or more electrodes; the gases to be treated being forced in tangentially to the periphery of the interior thereof and preferably on both sides of the flame-zone lying in the central plane.
The gases pass out of the furnace at or near the middle line of the longitudinal section of the furnace. Preferably, one outlet passage is provided on each side of the lane of the electrodes, corresponding to the inlet passage at the interior periphery of the furnace. In this-way, the gases follow spiral paths of comparatively great length between respectiveinlets and outlets, while the flame-zone lies in the central plane between the spiral path in the preferred arrangement. In consequence of this movement of the gases, the are formed between the electrodes is so affected that a disk-like flame discharge of large superficial area is produced, along which, preferably on both sides, the injected gases in comparatively thin sheets, rub in spiral paths of great length, whereas, in the plane of the electrodes a zone is formed in which little or but slight renewal of gases takes place. This formation of a disk-shaped flame discharge is surprising, because it would be expected that either the arc would persist directly bet-ween the electrodes or that the arc would be blown out as soon as formed,-
disk produced by the method herein described is particularly suitable for carrying out endothermic gas reactions; for lnstance,
in the employment of air for the oxidation of the nitrogen thereof, good concentrations as well as good yields have been obtained.
A furnace suitable forcarrying "out the method herein described is shown diagrammatically in the accompanying drawings, wherein Figure 1 is a cross-section through the furnace; and Fig. 2 is a longitudinal sec tion thereof on the line DD of Fig. 1.
The furnace b is of relatively moderate width (or height) with respect to its diameter, in order'that the gases to be treated shall likewise be in the form of comparatively thin sheets. The interior cross-section of the furnace mustlikewise-be so chosen that the movement of the gases shall follow in a spiral path. As illustrated in the draw-- riphery of the furnace linin while the two gas outlet passages f, and 2 are,located on the central line.
In Fig. 1 the gas-injecting ports or inlet passages g, and g, are shown facing in opposite directions, so that the gases will move in opposite directions to each other on opposite 5 sides of the flame zone; Whereas in Fig. 2
the inlet passages 9 and 9 are shown facing in the same direction, in which case the gases on the opposite sides of the flame zone will move in the same direction. If now, gas is 10 injected into the furnace through the inlet passages 9 and 9 the gases move uniformly in spiral paths to the outlet passages f and f while the arcs which have in the meantime been produced, in any well known manner such as by separating the electrodes after they have been brought into contact with. each other, between the electrodes 6 e and e are drawmo'ut and re-formed into a disk-like single flame discharge.
The method permits flame discharges of large energy consumption combined into a single flame disk; it further permits the employment to advantage of direct current, or of single-phase alternating current or of '25 polyphase alternating current, the number of electrodes beingfcorrespondingly chosen. Furthermore, a number of circuits can be employed connected upin parallel or in other relationas desired. When polyphase current is employed (for instance, a sixlayer of gas taking no part in the gas movement. Furthermore, the gases to be treated may be admitted through more than one tangentially-arranged port; for instance, throughtwo, three, four or more symmetrically" distributed ports of the same kind on each side of the flamedisk. It is also feasible to have the gases move in opposite directions to each other on opposite sides of the flame zone.
Having thus described my invention, what I claim is:
1. The method of producing an electric arc and u'tilizin the same for the production. of gas reactlons, which consists in cans ing the gases to-move in substantially parallel planes in roximity to the are on opposite sides thereof? and spreading the are out by the movement of the gases into a sheet discharge intermediate the planes of movement of the gases and distinct therefrom; substantially as described.
2. The method of producing an electric arc and utilizing the same for the production of gas reactions, which consists in causing the gases to move in opposite directions on opposite sides of the arc and in proximity thereto, and spreading the are out into an intermediate sheet discharge by the movement of the gases; substantially as described.
3. The method of producing an electric arc and utilizing the same for the production of gas reactions, which consists in causing the gases to move in p'roximity to the are on opposite sides thereof, and spreading the are out into an intermediate sheet discharge by the movement of the gases and without substantial renewal of such of the gases as collects within the disk zone; substantially as described.
4. The method of producing an electric arc and utilizing the same for the production of gas reactions, which consists in causing the gases to move in opposite directions on opposite sides of the arc and in proximity thereto, and spreading the are out into an intermediate sheet discharge by the movement of the gases and without substantial renewal of such of the gases as collects within the disk zone; substantially as described.
5. The method of producing a disk-like electric arc and utilizing the same for the production of gas reactions, which consists in causing the gases to move in a spiral path in a plane substantially parallel with and adjacent to but distinct from the plane of the are, and drawing the are out into disk form by the movement of the gases; substantially as described.
6. The method of producing a disk-like electric arc and utilizing the same for the production of gas reactions, which consists in causing the gases to move in spiral paths on opposite sides of the arc, and drawing the are out into disk-form by the mov'ement of the gases; substantially as described.
7. The method of producing a disk-like electric arc and utilizing the same for the production of gas reactions,which consists in causing the gases to move in spiral paths in opposite directions, on opposite sides of the arc, and drawing the are out into diskform by the movement of the gases; sub: stantially as described.
8. The method of producing a disk-like electric arc and utilizing the same for the production of gas reactions, which consists in causing the gases to move in a spiral path in a plane substantially parallel with and adjacent to but distinct from the path of the arc, and drawing the are out into disk form by the movement of the gases and without substantial renewal of such gas ascollects within the disk zone; substantially as described.
9. The method of producing a disk-like electric arc and utilizing the same for the production of gas reactions, which consists in causing the gases to move in spiral paths on opposite sides of the are and drawing the arc out into disk-form by the movement of the gases and without substantial renewal of such of the gas as collects within the disk zone; substantially as described.
10. The method of producing a disk-like electric arc and utilizing the'same for the production of gas reactions, which consists in establishing an electric are within an inclosed space, forcing the gases tangentially to the periphery of said space, and in a plane adjacent to but distinct from the arc, and conducting the products of the reaction from the said space axially thereof; substantially as described.
11. The method of producing a disk-like electric arc and utilizing the same for the production of gas reactions, which consists in establishing an electric are within an 'inclosed space, forcing in the gases tangentially to the periphery of said space, and in planes adjacent to the are but on opposite sides thereof, and conductingthe products of the reaction fromthe said space axially thereof; substantially as described.
12. The method of producing a disk-like electric arc and utilizing the same for the production of gas reactions, which consists in establishing an electric arc discharge-between electrodes by means of a polyphase current within an inclosed space, forcing in the gases tangentially to the periphery of said space, and in a plane adjacent to but distinct from the electric arc discharge, and conducting the products of the reaction from the said space axially thereof; substantialiy as described.
13. An electric flame discharge apparatus, provided with arcing electrodes, a flat furnace of substantially circular form, an
inletpassage on each side of a central plane of the furnace and tangentially disposed to the interior periphery of the furnace, and an outlet passage on each side of the central plane and axially disposed near-the center of the furnace; substantially. as described.
14. An electric flame discharge apparatus comprising a flat furnace of substantially circular form,a .plurality of circumferentially disposed electrodes between which an are or arcs are formed in substantially the centralplane of the furnace, an inlet passage at one side of thecentral plane for-introducing the gases tangentially to the interior periphery of the furnace and an outlet passage near the center ofthe furnace for discharging the gases axially of the furnace; substantially as described.
15. An electric flame discharge apparatus comprising a flat furnace of substantially circular form, a plurality of circumferentially disposed electrodes between which an arc or arcs are formed in substantially the central plane of the furnace, an inlet passage on each side of the central plane for introducing the gases tangentially to the interior periphery of the furnace, and an outlet passage on each side of the centralv FRITZ ROTHE. Witnesses:
MAX HAMBURGER, GsKAn SINGER.
US63837111A 1911-07-13 1911-07-13 Method of and apparatus for producing and utilizing disk-like electric arcs for effecting gas reactions. Expired - Lifetime US1018990A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2731410A (en) * 1951-02-28 1956-01-17 Horace M Weir Production of compounds by means of the electric arc
US2768947A (en) * 1952-03-13 1956-10-30 Horace M Weir Gas phase arc conversion

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2731410A (en) * 1951-02-28 1956-01-17 Horace M Weir Production of compounds by means of the electric arc
US2768947A (en) * 1952-03-13 1956-10-30 Horace M Weir Gas phase arc conversion

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