US1016758A - Process of producing alkali-metal from oxygen compounds of alkali. - Google Patents
Process of producing alkali-metal from oxygen compounds of alkali. Download PDFInfo
- Publication number
- US1016758A US1016758A US66199311A US1911661993A US1016758A US 1016758 A US1016758 A US 1016758A US 66199311 A US66199311 A US 66199311A US 1911661993 A US1911661993 A US 1911661993A US 1016758 A US1016758 A US 1016758A
- Authority
- US
- United States
- Prior art keywords
- alkali
- metal
- carbon
- oxygen compounds
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003513 alkali Substances 0.000 title description 10
- 238000000034 method Methods 0.000 title description 7
- 229910052783 alkali metal Inorganic materials 0.000 title description 6
- 150000001340 alkali metals Chemical class 0.000 title description 6
- 150000002927 oxygen compounds Chemical class 0.000 title description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 229910052799 carbon Inorganic materials 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 229910001018 Cast iron Inorganic materials 0.000 description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005725 Campbell reaction Methods 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 244000144980 herd Species 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
Definitions
- This invention relates to a process of provducing alkali metal from oxygen compounds of alkali and consists in heating oxygen compounds of alkali in presence of cast iron in liquid condition.
- Suitable oxygen compounds of alkali are carbonate and oxid of alkali.
- the invention may be carried through as I follows.
- a reaction vessel is fed with molten cast iron and soda;
- the two sub stances react with eachlothcr in such a manner that the sodium metal in the form of vapors is set free and that carbon oxid is formed.
- the required carbon being e. ⁇ '-
- the metal vapors may be carried off and condensed so as to form solid metal. or they may be used in the form of vapor for other purposes.
- the cast iron which has become poorer in ⁇ carbon may be made again richer in carbon and at the same time reheated to a temperature suitable for further reaction with the alkali, by adding carbonaceous material to the molten iron in any of the wellknown ways. (See Campbells Metallurgy of Iron aml Steel, 1904,, pp. 300, 301). Of course instead of recharging the cast iron with carbon new portions of cast iron may be used and the used up cast iron poor in carbon may be used for other purposes.
- the oxygen containing compounds of alkali metal are brought to reaction with the required carbon in a very simple and effective manner because at every point where a particle of soda or other alkali compound is in contact with molten cast iron it finds the required carbon for reaction and at the same time the high temperature which is necessary in order to enable reaction of the two substances. Furthermore the process is ad vantageous in so far as every loss in reaction carbon is avoided because the carbon is not used isolated but in the form of an addition to molten metal which by addition of new portionsof carbon can be brought to its initial condition each time when a portion of the carbon has been extracted from the metal by the reaction with the alkali.
- the highly heated mass of cast iron is particularly eflicacious in furnishing not only the carbon as reducing agent but the necessary quantity of heat to cause the reaction to be effected.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
UNITED STATES PATENT FFICE.
HERD/[ANN MEHNER, 0E BERLIN, GERMANY.
PROCESS OF PRODUCING ALKALIMETAL FROM OXYGEN COMPOUN'DS OF ALKALI.
l,tl l6,758.
No Drawing.
To all 'whomit may concern Be it known that l, HERMANN MEI-INER, a citizen of the German Empire, residing at Berlin, Prussia, Germany, have invented certain new and useful Improvements in Processes of Producin Alkali Metal from Oxygen Compounds of Alkali, of which the following is a specification.
This invention relates to a process of provducing alkali metal from oxygen compounds of alkali and consists in heating oxygen compounds of alkali in presence of cast iron in liquid condition. Suitable oxygen compounds of alkali are carbonate and oxid of alkali. i
The invention may be carried through as I follows. A reaction vessel is fed with molten cast iron and soda; The two sub stances react with eachlothcr in such a manner that the sodium metal in the form of vapors is set free and that carbon oxid is formed. The required carbon being e.\'-
tracted from the molten cast iron the metal vapors may be carried off and condensed so as to form solid metal. or they may be used in the form of vapor for other purposes. The cast iron which has become poorer in\ carbon may be made again richer in carbon and at the same time reheated to a temperature suitable for further reaction with the alkali, by adding carbonaceous material to the molten iron in any of the wellknown ways. (See Campbells Metallurgy of Iron aml Steel, 1904,, pp. 300, 301). Of course instead of recharging the cast iron with carbon new portions of cast iron may be used and the used up cast iron poor in carbon may be used for other purposes.
Specification of Letters Patent.
In the process described the oxygen containing compounds of alkali metal are brought to reaction with the required carbon in a very simple and effective manner because at every point where a particle of soda or other alkali compound is in contact with molten cast iron it finds the required carbon for reaction and at the same time the high temperature which is necessary in order to enable reaction of the two substances. Furthermore the process is ad vantageous in so far as every loss in reaction carbon is avoided because the carbon is not used isolated but in the form of an addition to molten metal which by addition of new portionsof carbon can be brought to its initial condition each time when a portion of the carbon has been extracted from the metal by the reaction with the alkali.
As the reaction by which the reduction is effected is highly endothermic, the highly heated mass of cast iron is particularly eflicacious in furnishing not only the carbon as reducing agent but the necessary quantity of heat to cause the reaction to be effected.
What I claim is:
Process of producing alkali metal consisting in bringing oXygen compounds of alkali into reaction with molten cast iron and collecting the vapors forn'led by the reaction.
In testimony whereof I allix II) y signature in presence of two witnesses.
HERMAN-N lVllGllNER.
Witnesses:
HENRY HAsrnn, Womnnvmn HAUr'r.
Patented Feb. 6, 1912. Application filed November 23, 1911. Serial No. 661,993.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66199311A US1016758A (en) | 1911-11-23 | 1911-11-23 | Process of producing alkali-metal from oxygen compounds of alkali. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US66199311A US1016758A (en) | 1911-11-23 | 1911-11-23 | Process of producing alkali-metal from oxygen compounds of alkali. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1016758A true US1016758A (en) | 1912-02-06 |
Family
ID=3085061
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US66199311A Expired - Lifetime US1016758A (en) | 1911-11-23 | 1911-11-23 | Process of producing alkali-metal from oxygen compounds of alkali. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1016758A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2710798A (en) * | 1952-04-04 | 1955-06-14 | Du Pont | Method of producing sodium from sodium ferrite |
| US2852363A (en) * | 1955-10-20 | 1958-09-16 | Callery Chemical Co | Preparation of alkali metals |
| US4401467A (en) * | 1980-12-15 | 1983-08-30 | Jordan Robert K | Continuous titanium process |
-
1911
- 1911-11-23 US US66199311A patent/US1016758A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2710798A (en) * | 1952-04-04 | 1955-06-14 | Du Pont | Method of producing sodium from sodium ferrite |
| US2852363A (en) * | 1955-10-20 | 1958-09-16 | Callery Chemical Co | Preparation of alkali metals |
| US4401467A (en) * | 1980-12-15 | 1983-08-30 | Jordan Robert K | Continuous titanium process |
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