US1059740A - Making auxiliary mordants containing titanium and glycolic acid. - Google Patents
Making auxiliary mordants containing titanium and glycolic acid. Download PDFInfo
- Publication number
- US1059740A US1059740A US65505411A US1911655054A US1059740A US 1059740 A US1059740 A US 1059740A US 65505411 A US65505411 A US 65505411A US 1911655054 A US1911655054 A US 1911655054A US 1059740 A US1059740 A US 1059740A
- Authority
- US
- United States
- Prior art keywords
- glycolic acid
- containing titanium
- acid
- mordants
- making auxiliary
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 title description 24
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 title description 4
- 239000010936 titanium Substances 0.000 title description 4
- 229910052719 titanium Inorganic materials 0.000 title description 4
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 6
- 239000002253 acid Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- UHWHMHPXHWHWPX-UHFFFAOYSA-J dipotassium;oxalate;oxotitanium(2+) Chemical compound [K+].[K+].[Ti+2]=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O UHWHMHPXHWHWPX-UHFFFAOYSA-J 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- BBJSDUUHGVDNKL-UHFFFAOYSA-J oxalate;titanium(4+) Chemical compound [Ti+4].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O BBJSDUUHGVDNKL-UHFFFAOYSA-J 0.000 description 1
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
- GROMGGTZECPEKN-UHFFFAOYSA-N sodium metatitanate Chemical compound [Na+].[Na+].[O-][Ti](=O)O[Ti](=O)O[Ti]([O-])=O GROMGGTZECPEKN-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910000348 titanium sulfate Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
Definitions
- This invention relates to the production of salts of titanium and glycolic acid, to be used as auxiliary mordants.
- titanic acid is added in the presence of alkalies or alkaline earth-metals, or to a solution of freshly precipitated acid glycolates the titanic acid is added, which is readily dissolved when heated. Similar compounds are produced by treating the titanates, for-instance, acid sodium titanate, which are obtained by decomposing heated mineral titanic acid with alkalles, or alkaline carbonates, directly with glycolic acid; Finally also titanic acid salts, such as titanium sulfate, titanium chlorid, titanium oxalate, the double salt of potassium titanium oxalate, etc., may be treated with glycolates, wherecolates are applied, t e bases of which form soluble or insoluble products with the subfiltered, contain principally only titanic acid,
- glycolic acid and an alkali 'or an alkaline earth-metal in every case, however, a mixture of salts is produced whichcontains besides the glycolate of titanic acid also other salts
- dissolving the titanic acid an excess of glycolic acid is'required, it is necessary to fix the quantity of the base bound to the glycolic acid accordingly, for instance, when alkaline solutions of glycolic acid are employed the acid has to be neutralized later on by adding bases.
- the technical production of these salts is obvious from the foregoing without further explanation as thereby alkaline salts or salts of thealkaline earthmetals, or mixtures of both, may be produced according to the purpose desired.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
by,'according to the urpose in question glyinr'r arr OTTO LIEBKNECHT, 0F FRANKFORT-ON-THE-MAIN, AND FERDINAND BLUMENTHAL,
' OF WIESBADEN, GERMANY.
MAKING AUX'ILIARY'MORDANTS CONTAINING TITANIUM AND GLYCOLIC ACID.
110 Drawing.
Specification of Letters Patent.
Application filed October 16, 1911. Serial No. 655,054.
Patented Apr. 22, 1913.
To all whom it may concern:
Be 1t known that we, OTTO LIEBKNEOHT and FERDINAND BLU ENTHAL, cltizens of the German Empire, and residents, respec-' tively, of Frankfort-on the-Main and VViesbaden, Germany have invented certain new and-useful Improvements in Making Auxiliary Mordants Containing Titanium and Glycolic Acid, and of which the following is a specification.
This invention relates to the production of salts of titanium and glycolic acid, to be used as auxiliary mordants.
We succeeded in producing compounds which may be used as'excellent auxiliary mordants, and for similar pur oses by com bining titanic acidwith glycolic acid. Such compounds have not been known heretofore. They are obtained in the following manner:
To an aqueous solution of glycolic acid,
titanic acid is added in the presence of alkalies or alkaline earth-metals, or to a solution of freshly precipitated acid glycolates the titanic acid is added, which is readily dissolved when heated. Similar compounds are produced by treating the titanates, for-instance, acid sodium titanate, which are obtained by decomposing heated mineral titanic acid with alkalles, or alkaline carbonates, directly with glycolic acid; Finally also titanic acid salts, such as titanium sulfate, titanium chlorid, titanium oxalate, the double salt of potassium titanium oxalate, etc., may be treated with glycolates, wherecolates are applied, t e bases of which form soluble or insoluble products with the subfiltered, contain principally only titanic acid,
glycolic acid and an alkali 'or an alkaline earth-metal; in every case, however, a mixture of salts is produced whichcontains besides the glycolate of titanic acid also other salts As for dissolving the titanic acid an excess of glycolic acid is'required, it is necessary to fix the quantity of the base bound to the glycolic acid accordingly, for instance, when alkaline solutions of glycolic acid are employed the acid has to be neutralized later on by adding bases. The technical production of these salts is obvious from the foregoing without further explanation as thereby alkaline salts or salts of thealkaline earthmetals, or mixtures of both, may be produced according to the purpose desired.
We claim:
1. The herein described process of connames to this specification in the presence of two subscribing witnesses.
' OTTG LIEBKNECHT. FERDINAND BLUMENTHAL. Witnesses:
JEAN GRUND, CARL Gnunn.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US65505411A US1059740A (en) | 1911-10-16 | 1911-10-16 | Making auxiliary mordants containing titanium and glycolic acid. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US65505411A US1059740A (en) | 1911-10-16 | 1911-10-16 | Making auxiliary mordants containing titanium and glycolic acid. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1059740A true US1059740A (en) | 1913-04-22 |
Family
ID=3127989
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US65505411A Expired - Lifetime US1059740A (en) | 1911-10-16 | 1911-10-16 | Making auxiliary mordants containing titanium and glycolic acid. |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1059740A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2453520A (en) * | 1946-09-28 | 1948-11-09 | Du Pont | Organic titanium compound and method of making same |
| US2489651A (en) * | 1946-06-25 | 1949-11-29 | Du Pont | Production of organic titanium compounds |
| US2630443A (en) * | 1949-10-21 | 1953-03-03 | Monsanto Chemicals | Process for the preparation of the mixed anhydrides of organic carboxylic acids and ortho titanic acid |
| US2920089A (en) * | 1955-07-14 | 1960-01-05 | Kendall & Co | Organo-metallic titanium compounds and method of making the same |
| US2926183A (en) * | 1957-05-24 | 1960-02-23 | Nat Lead Co | Organotitanium complexes and method of making same |
| US3090728A (en) * | 1957-02-20 | 1963-05-21 | Berger Frank Milan | Titanic acid complexes of hydroxy aliphatic carboxylic acids antiperspirant compostions |
-
1911
- 1911-10-16 US US65505411A patent/US1059740A/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2489651A (en) * | 1946-06-25 | 1949-11-29 | Du Pont | Production of organic titanium compounds |
| US2453520A (en) * | 1946-09-28 | 1948-11-09 | Du Pont | Organic titanium compound and method of making same |
| US2630443A (en) * | 1949-10-21 | 1953-03-03 | Monsanto Chemicals | Process for the preparation of the mixed anhydrides of organic carboxylic acids and ortho titanic acid |
| US2920089A (en) * | 1955-07-14 | 1960-01-05 | Kendall & Co | Organo-metallic titanium compounds and method of making the same |
| US3090728A (en) * | 1957-02-20 | 1963-05-21 | Berger Frank Milan | Titanic acid complexes of hydroxy aliphatic carboxylic acids antiperspirant compostions |
| US2926183A (en) * | 1957-05-24 | 1960-02-23 | Nat Lead Co | Organotitanium complexes and method of making same |
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