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UA98661C2 - Способ активации катализатора процесса фишера-тропша - Google Patents

Способ активации катализатора процесса фишера-тропша

Info

Publication number
UA98661C2
UA98661C2 UAA201002004A UAA201002004A UA98661C2 UA 98661 C2 UA98661 C2 UA 98661C2 UA A201002004 A UAA201002004 A UA A201002004A UA A201002004 A UAA201002004 A UA A201002004A UA 98661 C2 UA98661 C2 UA 98661C2
Authority
UA
Ukraine
Prior art keywords
fischer
catalyst
activation
tropsch catalyst
iron
Prior art date
Application number
UAA201002004A
Other languages
English (en)
Ukrainian (uk)
Inventor
Йоганнес Якобус Хайзер
ван Вюрен Маттис Джозефус Янсе
Рино Котзе
Original Assignee
Сейсол Текнолоджи (Пти) Лимитед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Сейсол Текнолоджи (Пти) Лимитед filed Critical Сейсол Текнолоджи (Пти) Лимитед
Publication of UA98661C2 publication Critical patent/UA98661C2/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Изобретение относится к отрасли катализа процесса Фишера-Тропша, в частности активации катализатора Фишера-Тропша. Способ активации катализатора процесса Фишера-Тропша на основе железа, который содержит железо в состоянии позитивного окисления, контактирование в реакторе указанного катализатора на основе железа с восстановительным газом, выбранным из группы, которая состоит из СО и комбинации Ни CO, при молярном соотношении Ни CO от 100:1 до 1:100, при температуре как минимум 245 °C и ниже 280 °C, при давлении восстановительного газа более 0,5 МПа и не более чем 2,2 МПа и при среднечасовой скорости (GHSV) подачи всего газа, который подают в реактор, как минимум 6000 мл(норм.)/г кат./час, с восстановлением железа, которое находится в состоянии окисления в катализаторе.
UAA201002004A 2007-08-10 2008-08-05 Способ активации катализатора процесса фишера-тропша UA98661C2 (ru)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ZA200706647 2007-08-10

Publications (1)

Publication Number Publication Date
UA98661C2 true UA98661C2 (ru) 2012-06-11

Family

ID=40351239

Family Applications (2)

Application Number Title Priority Date Filing Date
UAA201001352A UA96820C2 (ru) 2007-08-10 2008-08-05 Трехфазный низкотемпературный процесс фишера-тропша
UAA201002004A UA98661C2 (ru) 2007-08-10 2008-08-05 Способ активации катализатора процесса фишера-тропша

Family Applications Before (1)

Application Number Title Priority Date Filing Date
UAA201001352A UA96820C2 (ru) 2007-08-10 2008-08-05 Трехфазный низкотемпературный процесс фишера-тропша

Country Status (7)

Country Link
US (2) US8513312B2 (ru)
CN (2) CN101796166B (ru)
AU (2) AU2008288198B2 (ru)
RU (2) RU2450044C2 (ru)
UA (2) UA96820C2 (ru)
WO (2) WO2009022261A2 (ru)
ZA (2) ZA201000617B (ru)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10086365B2 (en) 2007-08-30 2018-10-02 Res Usa, Llc Strengthened iron catalyst for slurry reactors
US7915193B2 (en) * 2007-08-30 2011-03-29 Rentech, Inc. Method for activating strengthened iron catalyst for slurry reactors
AU2009329087B2 (en) * 2008-12-18 2013-07-18 Sasol Technology (Pty) Limited Method for the preparation of a hydrocarbon synthesis catalyst material and the use thereof in a hydrocarbon synthesis process
FR2984346B1 (fr) * 2011-12-14 2013-12-27 IFP Energies Nouvelles Procede de fabrication d'hydrocarbures avec chargement en continu du catalyseur
CN102553657B (zh) * 2012-01-06 2013-11-20 神华集团有限责任公司 费托催化剂的还原方法
CN103418393B (zh) * 2012-05-16 2016-02-10 中国石油化工股份有限公司 费托合成重质烃的催化剂及其制备方法
CN102863983B (zh) * 2012-09-20 2014-12-10 神华集团有限责任公司 一种费托合成催化剂活化及开工方法
CN105324173B (zh) 2013-06-28 2019-04-05 陶氏环球技术有限责任公司 适用于费托反应的基于铁的新颖催化剂和其处理方法
CN104549559B (zh) * 2013-10-28 2017-03-15 中国石油化工股份有限公司 流化床合成气直接制备低碳烯烃铁基催化剂的活化方法
AP2016009413A0 (en) * 2014-03-24 2016-08-31 Sasol Tech Pty Ltd Fischer-tropsch synthesis
CN105080570B (zh) * 2014-05-14 2017-10-27 中国石油化工股份有限公司 流化床合成气直接制备低碳烯烃铁基催化剂的再生方法
WO2016019403A2 (en) 2014-07-28 2016-02-04 Sasol Technology Proprietary Limited Production of oilfield hydrocarbons
GB201614363D0 (en) * 2016-08-23 2016-10-05 Bp Plc Fischer-tropsch catalyst performance enhancement process
GB201702248D0 (en) * 2017-02-10 2017-03-29 Bp Plc Start-up procedure for a fischer-tropsch process
CN110201673B (zh) * 2018-02-28 2022-02-18 国家能源投资集团有限责任公司 还原铁基费托合成催化剂的方法和还原态铁基费托合成催化剂
CN110361499A (zh) * 2018-04-09 2019-10-22 国家能源投资集团有限责任公司 铁基费托合成催化剂活性评价的方法
CN115430434B (zh) * 2021-06-03 2024-07-05 国家能源投资集团有限责任公司 费托合成催化剂的还原方法和还原态费托合成催化剂以及费托合成方法
GB202500377D0 (en) * 2024-02-20 2025-02-26 Johnson Matthey Davy Technologies Ltd Method of starting up a fischer-tropsch plant

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7452844B2 (en) * 2001-05-08 2008-11-18 Süd-Chemie Inc High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis
US7361619B2 (en) * 2003-04-11 2008-04-22 Exxonmobil Research And Engineering Company Fischer-Tropsch catalyst production
CN1803281A (zh) * 2006-01-24 2006-07-19 吕毅军 用于费托合成反应工艺的含助剂瑞尼铁催化剂及其制法
US7544719B2 (en) * 2006-07-12 2009-06-09 Rentech, Inc. Method for activating an iron-based fischer-tropsch catalyst

Also Published As

Publication number Publication date
CN101796166A (zh) 2010-08-04
RU2450044C2 (ru) 2012-05-10
US8716160B2 (en) 2014-05-06
WO2009022262A3 (en) 2009-06-25
AU2008288199B2 (en) 2011-08-18
UA96820C2 (ru) 2011-12-12
RU2010107699A (ru) 2011-09-10
RU2450043C2 (ru) 2012-05-10
ZA201000928B (en) 2010-10-27
US20110178189A1 (en) 2011-07-21
RU2010107701A (ru) 2011-09-20
ZA201000617B (en) 2010-10-27
US20110275512A1 (en) 2011-11-10
AU2008288199A1 (en) 2009-02-19
AU2008288198B2 (en) 2011-08-18
WO2009022262A2 (en) 2009-02-19
CN101868518A (zh) 2010-10-20
WO2009022261A3 (en) 2009-06-25
US8513312B2 (en) 2013-08-20
WO2009022261A2 (en) 2009-02-19
CN101796166B (zh) 2015-01-28
AU2008288198A1 (en) 2009-02-19

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