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UA95663C2 - Process for the preparation of c1-c3 aliphatic carboxylic acid and/or corresponding ester by carbonylation - Google Patents

Process for the preparation of c1-c3 aliphatic carboxylic acid and/or corresponding ester by carbonylation

Info

Publication number
UA95663C2
UA95663C2 UAA200907279A UAA200907279A UA95663C2 UA 95663 C2 UA95663 C2 UA 95663C2 UA A200907279 A UAA200907279 A UA A200907279A UA A200907279 A UAA200907279 A UA A200907279A UA 95663 C2 UA95663 C2 UA 95663C2
Authority
UA
Ukraine
Prior art keywords
carboxylic acid
aliphatic carboxylic
corresponding ester
carbonylation
preparation
Prior art date
Application number
UAA200907279A
Other languages
Russian (ru)
Ukrainian (uk)
Inventor
Енріке Іглесія
Джон Гленн Санлі
Девід Джон Лоу
Адіт'я Бхан
Original Assignee
Зе Регентс Оф Зе Юніверситі Оф Каліфорнія
Бп Кемікалз Лімітед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Зе Регентс Оф Зе Юніверситі Оф Каліфорнія, Бп Кемікалз Лімітед filed Critical Зе Регентс Оф Зе Юніверситі Оф Каліфорнія
Publication of UA95663C2 publication Critical patent/UA95663C2/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/09—Preparation of carboxylic acids or their salts, halides or anhydrides from carboxylic acid esters or lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A product comprising a C1-C3 aliphatic carboxylic acid or corresponding ester is produced by a process comprising reacting a C1-C3 aliphatic alcohol or a reactive derivative thereof with carbon monoxide in the presence of a zeolite catalyst having an 8-member ring channel which is interconnected with a channel defined by a ring with greater than or equal to 8 members, the 8-membcr ring having a window size of at least 2.5 Angstroms x at least 3.6 Angstroms and at least one Broensted acidic site and the zeolite having a silica: X2O3, ratio of at least 5, wherein X is selected from aluminum, boron, iron, gallium and mixtures thereof with the proviso that the zeolite is not mordenite or ferrierite.
UAA200907279A 2006-12-15 2006-12-15 Process for the preparation of c1-c3 aliphatic carboxylic acid and/or corresponding ester by carbonylation UA95663C2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2006/047718 WO2008073096A1 (en) 2006-12-15 2006-12-15 Process for carbonylation of aliphatic alcohols and/or reactive derivatives thereof

Publications (1)

Publication Number Publication Date
UA95663C2 true UA95663C2 (en) 2011-08-25

Family

ID=39512001

Family Applications (1)

Application Number Title Priority Date Filing Date
UAA200907279A UA95663C2 (en) 2006-12-15 2006-12-15 Process for the preparation of c1-c3 aliphatic carboxylic acid and/or corresponding ester by carbonylation

Country Status (8)

Country Link
EP (1) EP2114850A4 (en)
JP (1) JP2010513270A (en)
KR (2) KR20140054448A (en)
CN (1) CN101600678B (en)
BR (1) BRPI0622186A2 (en)
CA (1) CA2671361C (en)
UA (1) UA95663C2 (en)
WO (1) WO2008073096A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2292578A1 (en) * 2009-09-03 2011-03-09 BP Chemicals Limited Process for producing acetic acid and dimethyl ether using a zeolite catalyst
CN103012062B (en) * 2012-12-20 2015-04-22 上海戊正工程技术有限公司 Process for indirectly producing alcohol with synthetic gas and application of process
TW201443015A (en) * 2013-03-08 2014-11-16 Bp Chem Int Ltd Carbonylation process
CN106365994B (en) * 2015-07-20 2019-01-01 中国科学院大连化学物理研究所 A kind of production method of lower aliphatic carboxylic acid's Arrcostab
CN106365995B (en) * 2015-07-20 2018-06-05 中国科学院大连化学物理研究所 A kind of production method of methyl acetate
CN106365992B (en) * 2015-07-20 2019-01-01 中国科学院大连化学物理研究所 A method of preparing acetal carbonyl compound
WO2019037768A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. Process
WO2019037766A1 (en) 2017-08-24 2019-02-28 Bp P.L.C. Process
KR102762146B1 (en) * 2019-07-12 2025-02-03 주식회사 엘지화학 Method for preparing acetate-based compound using heterogeneous catalyst
CN114539057B (en) * 2020-11-18 2024-03-19 中国科学院大连化学物理研究所 Preparation method of methyl acetate

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3130007A (en) 1961-05-12 1964-04-21 Union Carbide Corp Crystalline zeolite y
GB1185453A (en) 1967-02-20 1970-03-25 Monsanto Co Multiphase Catalysis.
US3717670A (en) 1968-08-02 1973-02-20 Monsanto Co Production of carboxylic acids and esters
US3689533A (en) 1971-03-15 1972-09-05 Monsanto Co Production of carboxylic acids and esters
CA1064890A (en) 1975-06-10 1979-10-23 Mae K. Rubin Crystalline zeolite, synthesis and use thereof
US4612387A (en) 1982-01-04 1986-09-16 Air Products And Chemicals, Inc. Production of carboxylic acids and esters
GB9223170D0 (en) * 1992-11-05 1992-12-16 British Petroleum Co Plc Process for preparing carboxylic acids
CA2159410A1 (en) 1994-11-14 1996-05-15 Pei-Shing Eugene Dai Catalyst for multistage etherification with high conversion of t-butanol
US6127432A (en) 1998-01-29 2000-10-03 Union Carbide Chemicals & Plastics Technology Corporation Processes for preparing oxygenates and catalysts therefor
GB0409490D0 (en) 2004-04-28 2004-06-02 Bp Chem Int Ltd Process
US20060252959A1 (en) * 2005-05-05 2006-11-09 The Regents Of The University Of California Process for carbonylation of alkyl ethers

Also Published As

Publication number Publication date
KR20090092280A (en) 2009-08-31
KR20140054448A (en) 2014-05-08
BRPI0622186A2 (en) 2011-12-27
CN101600678B (en) 2012-08-15
EP2114850A1 (en) 2009-11-11
CA2671361C (en) 2014-10-21
CN101600678A (en) 2009-12-09
JP2010513270A (en) 2010-04-30
CA2671361A1 (en) 2008-06-19
EP2114850A4 (en) 2013-03-27
WO2008073096A1 (en) 2008-06-19

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