UA77008C2 - Herbicidal mixtures based on the 3-phenyluracis and use thereof - Google Patents

Abstract

Herbidically active compositions, comprising: A) at least one phenyluracil compound of the formula (I); in which the variables R' - R7 are as defined in the claims, and/or at least one of its agriculturally acceptable salts; and at least one further active compound, selected from B) herbicides of classes b1) to b15): b1) lipid biosynthesis inhibitors; b2) acetolactate synthase inhibitors (ALS inhibitors); b3) photosynthesis inhibitors; b4) protoporphyrinogen-IX oxidase inhibitors; b5) bleacher herbicides; b6) enolpyruvyi shikimate 3-phosphate synthase inhibitors (EPSP inhibitors); b7) glutamine synthetase inhibitors; b8) 7,8-dihydropteroate synthase inhibitors (DHP inhibitors); b9) mitose inhibitors; b10) inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors); b11) cellulose biosynthesis inhibitors; b12) decoupler herbicides; b13) auxin herbicides; b14) auxin transport inhibitors; b15) other herbicides selected from the group consisting of benzoylprop, flamprop, flamprop-M, bromobutide, chlorflurenol, cinmethylin, methyldymron, etobenzanid, fosamine, metam, pyributicarb, oxaziclomefone, dazomet, triaziflam and methyl bromide; and safeners selected from: benoxacor, cloquintocet, cyometrinil, dichlormid, dicyclonon, dietholate, fenchlorazole, fenclorim, flurazole, fluxolenim, furilazole, isoxadifen, mefenpyr, mephenate, naphthalic anhydride, 2,2,5-trimethyl-3-(dichloroacetyl)-l,3-oxazolidine, 4-(dichloroacetyl)-l-oxa-4-azaspiro[4.5]decane and oxabetrinil, the agriculturally acceptable salts of the active compounds B and C and the agriculturally acceptable derivatives of the active compounds B and C, provided they have a carboxyl group.

Description

VU B" independently of each other represent B is trifluoromethyl; hydrogen, a C1i-Cv-alkyl group, a C1i-Cv-alkyl group, VAZ is hydrogen, fluorine or chlorine;

C3-Cv-alkenyl group, C3-Cv-alkynyl group, C3-B" represents halogen or cyano;

C-cycloalkyl group, C3-C-cycloalkenyl B: represents hydrogen; group, phenyl or benzyl, where each of the 8 above - Вб, В" independently of each other represent the following substituents, unsubstituted or can be hydrogen, C1i-Cv-alkyl, C3-Cv- substituted from 1 to 6 times by halogen atoms and/or alkenyl, C3-C6-alkynyl, C3-C-cycloalkyl, C3-C7- with one, two or three groups selected from: cycloalkenyl, phenyl

ОН, МН», СМ, СОМН», C1-C4- or benzyl, or P», B" together with the nitrogen atom of a halogeno-alkoxy group, C1-C4- alkylthio group, C1-C4- are pyrrolidine, piperidine, haloalkylthio group, C1i-C alkylsulfonyl morpholine, M-methylpiperazine or perhydro group, C1i1-C4 haloalkylsulfonyl group, C1 azepine ring.

C4-alkylamino groups, di(C1i-C4-alkylamino groups, fo- 3. The composition according to item 2, in which the variables B!-B" in the formula I of the rmyl group, C1-Ca-alkylcarbonyl group, C1- have the following values:

C4-Alkoxycarbonyl group, C1-C4-B' is methyl; alkylaminocarbonyl group, di(C1-C4-B?) represents trifluoromethyl; alkyl)iaminocarbonyl group, C3-C7-BZ represents fluorine; cycloalkyl group, phenyl and benzyl; or Re, B" B" represents chlorine; together with a nitrogen atom form 3-, 4-, 5-, 6- or ВZ is hydrogen; 7--linen saturated or unsaturated nitrogen-containing VU. B" independently of each other represent a heterocycle that can be substituted from 1 to C-Cv-alkyl. 6 times by methyl groups and which can contain 1 4. The composition according to item 2, in which the variables B!-B" in formula I or 2 additional heteroatoms selected from the group have the following meanings: which includes nitrogen, oxygen and sulfur as ring members, B' is MH"; and/or at least one of its acceptable in rural B is trifluoromethyl; salt management; and at least one additional BZ is fluorine; the active compound selected from B" is chlorine;

B) herbicides of classes from B1) to B15): B? is hydrogen;

BI) lipid biosynthesis inhibitors; Вб, В" independently of each other represent рg) inhibitors of acelactate synthase (AG 5 inhibitors); C-Cv-alkyl.

B3) photosynthesis inhibitors; 5. The composition according to any of the previous items, ri) protoporphyrinogen-X oxidase inhibitors; which includes at least one

B5) bleaching herbicides; herbicide B selected from the compounds indicated below: рб) inhibitors of enolpyruvyl shikimate 3-BI) from the group of lipid biosynthesis inhibitors: chlorazi-phosphate synthase (ERBR inhibitors); fop, clodinafop, klofop, cigalofop, diclofop, p) glutamine synthetase inhibitors; fenoxaprop, fenoxaprop-P, fentiaprop, flua-p8) inhibitors of 7,8-dihydropteroate synthase (ONR zifop, fluazifop-P, haloxifop, haloxifop-P, inhibitors); isoxapyrifop, metamifop, propaquizafop, quiza-

BO) mitosis inhibitors; Lofop, Quizalofop-P, Trifop, Aloxidim, Butro-010) fatty acid synthesis inhibitors with a very long doxydim, clethodim, cloproxidim, cycloxidim, hyme chain (MI SERA inhibitors); profoxidim, sethoxidim, tepraloxidim, tral-011) cellulose biosynthesis inhibitors; coxidim, butylate, cycloate, diallate, dimepiperate, p12) decomposing herbicides; ERTS, esprocarb, etiolate, isopolinate, methioben-p13) auxin herbicides; carb, molinate, orbencarb, pebulate, prosulfur- p14) auxin transport inhibitors; carb, sulfalate, thiobencarb, thiocarbazil, tria-015) other herbicides selected from the group that includes benfurezate, vernolate, benfurezate, etofumesate: benzoylprop, flamprop, flamprop-M, bromobensulide; butide, chlorflurenol, cinmethylin, methyldimuron, rg) from the AG group of 5 inhibitors: amidosulfuron, azymetobenzanide, fosamine, metham, pyributycarb, oxasulfuron, bensulfuron, chlorimuron, chlorsucyclomefon, dazomet, triaziflam and methyl bromide; lfuron, cynosulfuron, cyclosulfamuron, and ethametsulfuron, ethoxysulfuron, flazasul-

C) antidotes selected from the group that includes: benofuron, flupirsulfuron, foramsulfuron, haloxacor, cloquintocet, tsiometrinil, dichlormid, disulfuron, imazosulfuron, iodosulfuron, mecyclonon, dietolate, fenchlorazole, fenchlorim, zosulfuron, metsulfuron , nicosulfuron, flurazole, fluxofenim, furilazole, isoxadifen, oxasulfuron, primesulfuron, prosulfuron, mefenpyr, mefenate, naphthoic anhydride, 2,2,5-pyrazosulfuron, rimsulfuron, sulfometuron, trimethyl-3-(dichloroacetyl)-1,3-oxazolidine, 4-sulfosulfuron, thifensulfuron, triazul- (dichloroacetyl)-1-oxa-4-azaspiro(4.5|decane and oxafuron, tribenuron, trifloxysulfuron, tribetrinil, acceptable in agriculture flusulfuron, tritosulfuron, imazametabenz, salts of active compounds B and C and acceptable in agriculture - imazamox, imazapic, imazapyr, imazaquin, imazetapyr, derivatives of active compounds B and C, cloransulam, diclosulam, florasulam, flu-provided that they have a carboxyl group. metsulam, methosulam .

They, independently of each other, have the following properties: benzoxime, pyriphthalide and pyrithiobac; composition: pZ3) from the group of photosynthesis inhibitors: atraton, atra-

B' represents methyl or MH"; zine, ametrine, aziprothrine, cyanazine, cyanathrine,

chlorazine, cyprazine, desmethrin, dimetamethrin, or polysubstituted by halogen, C1-C4-alkyl dipropethrin, eglinazine, ipazine, mesoprazine, me group, C1i-Ca-alkoxy group, C-C4 tometone, methoprothrin, procyazine, proglynazine, haloalkyl group , C1-64- promethone, promethrin, propazine, sebuthylazine, haloalkoxy group or C-C4 alkylthio group; secbumetone, simazine, simetone, symetryn, terbu- B' represents hydrogen, halogen or Si-Sv- metone, terbuthylazine, terbutrin, triethazine, ameth-alkyl group; ridion, amibuzin, hexazinone, isomethiosin, metamit- B!? is a Ci-Cv-alkyl group; ron, metribuzin, bromacil, isocyl, lenacil, B": represents hydrogen or a C-Cv-alkyl group; terbacil, brompyrazone, chloridazone, dimidazone, Ob) from the group of EROR synthase inhibitors: glyphosate; desmedifam, phenizofam, phenmedifam, phenme- p7) from the group of glutamine synthase inhibitors: glufosinate dipham-ethyl, benzthiazuron, butiuron, etidimuron, and bilanafos; isouron, metabenzthiazuron, monoisouron, tebutiure) from the group of ONR synthase inhibitors: azulam; ron, thiazafluron, anizuron, buguron, chlorbromuron - p9 ) from the group of mitosis inhibitors: benfluralin, butraron, chloreturon, chlorotoluron, chloroxuron, dilin, dinitramine, fenoxuron, dimefuron, diuron, fenuron, etalfluralin, fluchloralin, isopropalin, metal fluometuron, fluotiuron, isoproturon, linuron, propalin, nitralin, metiuron, metobenzuron, metobromuron, methoxy- oryzalin, pendimethalin, prodiamine, profluralin, ron, monolinuron, monuron, neburon, parafluron, trifluralin, amiprophos-methyl, butamiphos, ditiphenobenzuron, siduron, tetrafluron, thidiazuron, opir, t iazopyr, propizamide, tebutam, chlorthal, carbecyperquat, dietamquat, difenzoquat, diquat, mortamide, chlorbupham, chlorpropham and propham; famquat, paraquat, bromobonil, bromoxynil, 010) from the group of MISEA inhibitors: acetochlor, ala-chloroxynil, iodoboryl, ioxynil, amicarbazone, chlorine, butachlor, butenachlor, delachlor, dietatyl, bromophenoxime, flumezin, metazol, bentazon, dimetachlor, dimethenamid, dimethenamid -P, meta-propanil, pentanochlor, pyridate and pyridafol; zachlor, metolachlor, 5-metolachlor, pretilachlor, p4) from the group of inhibitors of protoporphyrinogen-YH oxypropachlor, propisochlor, prinachlor, terbuchlor, doses: acifluorfen, bifenox, chlomethoxifen, tenylchlor, xylachlor, alidochlor, COEA, epronaz, chlornitrophen, ethoxyfen, fluorodifen, fluorodiphenamide, napropamide, naproanilide, pentaxamide, glycophen, fluoronitrophen, fomezafen, furylokflufenacet, mefenacet, fentrazamide, anilophos, sifen, halozafen, lactofen, nitrofen, nitroflupiperophos, cafenestrol, indanophan, and tridiphan; orfen, oxyfluorfen, fluazolate, pyraflufen, 011) from the group of cellulose biosynthesis inhibitors: dichcinidone-ethyl, flumiclorac, flumioxazin, flumilobenil, chlorthiamide, isoxaben, and flupoxam; propine, fluthiacet, thidiazimin, oxadiazon, oxadi-p12) from the group of splitting herbicides: dinofenate, argil, azafenidin, carfentrazone, sulfentrazone, dinoprop, dinosam, dinoseb, dinoterb, OMOS, etipentoxazone, benzphendizone, butafenacil, pyracnofen and medinoterb ; lonil, profluazol, flufenpyr, flupropacil, 013) from the group of auxin herbicides: clomeprop, 2,4-0, nipiraklofen and etnipromid; 2,4,5-T, MCPA, MCORA thioethyl, dichloroprop, dich-

B5) from the group of bleaching herbicides: metflurazon, lorprop-R, mecoprop, mekoprop-R, 2,4-08, MSRV, norflurazon, flufenican, diflufenican, picoli-chloramben, dicamba, 2,3,6-TVA, tricamba, quinine - nafen, beflubutamide, fluridone, flurochloridone, clorac, quinmerac, clopyralid, fluroxypyr, picloflurtamone, mesotrione, sulcotrione, isoxachloram, triclopyr and benazolin; tol, isoxaflutol, benzofenap, pyrazolinate, pyr-p14) from the group of auxin transport inhibitors: zoxifen, benzobicyclone, amitrol, clomazone, naptalam, diflufenzopyr; aclonifen, 4-(3-fluoromethylphenoxy)-2-(4-015)benzoylprop, flamprop, flamprop-M, bro-trifluoromethylphenyl)pyrimidine, as well as /3-mobutide, chloroflurenol, cinmethylin, methyl-heterocyclyl-substituted benzoyl derivatives of formula II dimron, ethobenzanid, fosamine, metham, pyribut-

VZ is) 8 carb, oxacyclomefon, dazomet, triaziflam and ve methyl bromide; | | What are acceptable salts and additives in agriculture

M and | distinct in rural areas

In the management of derivatives of herbicides B, provided that they have a carboxyl group. | Щ in" (1) 6. The composition according to item 5, in which herbicides B are selected in which variables B8-B"Z, such as those specified below: from the group including:

AB, ВЕ represent hydrogen, halogen, С1-Св-01) clodinafop, cigalofop, diclofop, phenoxa- alkyl group C-Se-halogenoalkyl group prop, fenoxaprop-P, fluazifop, fluazifopP,

C-Cv-Alkoxy Group C-Ce-Halogeno-Alkoxy Group Haloxyfop, Haloxyfop-P, Metamifop, Quizalo-

C-Cv-alkylthio group, C-Cv-alkylsulfinyl group fop, quizalofop-P, alkoxide, butroxide, cle- or C-Ce-alkylsulfonyl group; todim, cloproxidim, cycloxidim, profoxidim,

IN? is a heterocylic radical selected from sethoxydime, tepraloxide, tralkoxide,

My shi Ty p2) amidosulfuron, azimsulfuron, benzul- from the group, which includes: thiazol-2-yl, thiazol-4-yl, thiazolin t, write and furon, chlorimuron, chlorsulfuron, cinosul-

B-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-5-yl, nd : : - and furon, cyclosulfamuron, ethametsulfuron, 4,5-dihydroisoxazol-3-yl, 4,5-dihydroisoxazol-4 -yl Я and 4,5-dihydroisoxazol-5-yl, where the nine ethoxysulfuron, flazasulfuron, flupirsul radicals can be unsubstituted or mono-furon, foramsulfuron, halosulfuron, imazo-sulfuron, iodosulfuron, mesosulfuron,

metsulfuron, nicosulfuron, oxasulfuron, 7. The composition according to item 5, which includes at least one primisulfuron, prosulfuron, pyrazosul-3-heterocyclyl-substituted benzoyl derivative of the formula furon, rimsulfuron, sulfometuron, sul-III, in which the variables E8-B'Z are as indicated below: fosulfuron, thifensulfuron, triasulfuron, BZ is a halogen or a C-C alkyl group; tribenuron, trifloxysulfuron, triflusul- B? is a heterocyclic radical, vibrafuron, tritosulfuron, propoxycarbazone, flunium from the group including: carbazone, imazametabenz, imazamox, imazapic, imaisoxazol-3-yl, isoxazol-5-yl, 4,5-dihydroisoxazol- zapir, imazaquin, imazetapir, cloransulam, Z-il, where the three indicated radicals can be nediclosulam, florasulam, flumetsulam, methose-substituted or mono- or disubstituted halogels, penoxsulam, bispiribac, pyribenzoxim, foam, Si- Ca-alkyl or C1i-C4-halogenoalkyl; rifthalide, pyrithiobac, piriminobac; IN!? is C1-Ca-alkylsulfonyl;

YurZ3) atrazine, cyanazine, simazine, terbuthylazine, hec- B"! represents hydrogen; sazinone, metamitron, metribuzin, amicarbazone, B"? is C1-C1-alkyl; chloridazon, chlorbromuron, chlorotoluron, diuron, B": is hydrogen. isoproturon, linuron, metabenzthiazuron, propanil, 8. The composition according to any of the preceding items, bromoxynil, ioxynil, bentazone, pyridate, diphenzo- which includes at least one antidote C , selected from quat, diquat, paraquat; the group that includes: benoxacor, cloquintocet, di-p4) acifluorfen, fluoroglycofen, halozafen, lormid, fenchlorazole, fenclorim, fluxofenim, lactofen, oxyfluorfen, fluazolate, pyraflufurilazole, isoxadifen, mefenpyr, 2,2,5-phen, cinidone-ethyl, flumiclorac, flumioxazin, trimethyl-3-(dichloroacetyl)-1,3-oxazolidine, 4-fluthiacet, oxadiazone, oxadiargyl, azafenidine, (dichloroacetyl)-1-oxa-4- azaspiro(4.5|decane and oxacarfentrazone, sulfentrazone, pentoxazone, benbetrinil, their acceptable in agriculture zfendisone, butafenacil, pyraclonil, profluazole, salts and, in the case of carboxylic acids, their acceptable in flufenpyr, nipyraclofen; agricultural derivatives. 05) norflurazon, diflufenican, picol inafen, 9. The composition according to any of the previous clauses, in beflubutamide, fluridone, flurochloridone, fluro- in which the mass ratio of component A to com- tamone, mesotrione, sulcotrione, isoxachlortol, component B is in the range from 10:11 to isoxaflutol, benzofenap, pyrazolinate, pyrazol- 1:500. xyfen, benzobicyclone, clomazone, 4-(3- 10. The composition according to any of the preceding items, trifluoromethylphenoxy)-2-(4-trifluoromethylphenyl)- in which the mass ratio of component A to pyrimidines, as well as (2-chloro-3 -(4,5-dihydro-3- component C is in the range from 10:1 to isoxazolyl)-4-(methylsulfonyl)phenyl|(5-hydroxy- 170. 1-methyl-1H-pyrazol-4-yl)umethanone , I3-(4,5-dihydro-3- 11. The composition according to any of the previous items, isoxazolyl)-2-methyl-4-(methylsulfonyl)phenyl)(5- in which the mass ratio of component B to hydroxy-1 -methyl-1H-pyrazol-4-ylumethanone, (2-chloro-component C is in the range from 50:1 to 3-(3-methyl-5-isoxazolyl)-4--methylsulfonyl)- 170. phenyl|(5 -hydroxy-1-methyl-1H-pyrazol-4- 12. The composition according to any of the previous items, ilumethanone, (5-hydroxy-1-methyl-1H-pyrazol-4-yl)(2- in the form of a composition crop protection, which additionally includes methyl-3-(3-methyl-5-isoxazolyl)-4- at least one inert liquid and/or (methylsulfonyl)phenyl|methanone; a solid carrier, according to by request, at least one time) glyphosate; rheologically active substance and, if acceptable, zvir-p7) glufosinate; tea excipients. 609) benfluralin, butralin, dinitramine, etalflu- 13. Composition according to any of the previous points, ralin, oryzalin, in the form of a crop protection composition represented by pendimethalin, trifluralin, propizamide; in the form of a 2-component composition containing p10) acetochlor, alachlor, butachlor, dimethenamid, the first component, which includes the active compound A, dimethenamid-P, a solid or liquid carrier and, if acceptable, one metazachlor, metolachlor, 5-metolachlor, petxa- or more surfactants, and a second copper, pretilachlor, a component including at least one additional propachlor, propisochlor, tenylchlor, flufenacet, an active compound selected from herbicides B and antidotes mefenacet, C, a solid or liquid carrier and, if acceptable, fentrazamide, cafenstrol, indanophan; one or more surfactants. 011) dichlobenil, chlorothiamide, isoxaben, flupok- 14. A method of combating unwanted vegetation, which itself; includes the application of herbicide-effective kil- p13) 2,4-0, 24-08, dichlorprop, dichlorprop-P, bones of the composition according to any of items 1-13 to plants,

MSOSRA, MOSRV, mekoprop, their growing medium or grains. mecoprop-P, dicamba, quinclorac, quinmerac, clopi- 15. The method according to p. 14, in which the composition according to p. 14 is bibralid, fluroxypyr, which is used from p. 1-13 before, during and/or picloram, triclopyr, benazolin; after germination of unwanted plants, and p14) diflufenzopyr; Herbicidally active components A), B) and C) are used - 015) bromobutide, cinmethylin, methyldimron, are oxidized simultaneously or sequentially. ziclomefon, triaziflam; 16. The method according to item 15, in which the leaves of agriculturally acceptable and unwanted plants are treated with salts. of the above-mentioned active compounds B and acceptable in agriculture 17. Use of compositions according to any of clauses 1- derivatives of active compounds B, 13 for combating unwanted vegetation. provided they have a carboxyl group.

18. Use of compositions according to any of items 1-22. Use of compositions according to any of items 1-13 for combating unwanted vegetation in crops 13 for combating unwanted vegetation in cereal forests. your household. 19. Use of compositions according to any of items 1-23. Use of compositions according to any of items 1-13 to control unwanted vegetation in crops 13, to control unwanted vegetation in corn crops and in crops sorghum. plants, where cultivated plants are resistant to 20. Application of the compositions according to any of items 1- one or more herbicides due to genetic engineering 13 for combating unwanted vegetation in posineria and/or selection. wah rice 24. The use of compositions according to any of items 1-21. The use of compositions according to any of items 1-13 for the control of unwanted vegetation in crops 13 for the control of unwanted vegetation in crops of plants where cultivated plants are resistant to weevils in cotton, in rapeseed crops, in soybean crops, in insect pests, thanks to genetic engineering and/or potato breeders, in bean crops, in peanut crops and in tion. crops of perennial plants. 25. Use of herbicide mixtures according to any of items 1-13 for drying and/or defoliation of plants.

This invention relates to the herbicide Z-Phenyluracil formula I: active compositions containing Z-Phenyluracil and, p! at least one additional compound selected from herbicide-active compounds and antidotes.

In means of protection of agricultural crops, it is desirable, in principle, to improve the specificity (I) and reliability of action of active compounds. In particular, it is desirable that the means of protection of agricultural crops more effectively combats harmful plants and, at the same time, is tolerant to the mentioned beneficial crops. in which the variables B!-B" are as indicated below:

In various publications were described 3- V! is a metal group or МН»2; phenyluracils as highly effective herbicides. Od-V? is a C-C0-halogenoalkyl group; nak, their compatibility with cultures of dicotyledonous plants, VZ is hydrogen or halogen; such as cotton, rape and some cereals, also - B: represents a halogen or a cyano group; we like, barley, millet, corn, rice, wheat and A? is hydrogen, cyano group, C1-Cv- is not always satisfactory with sugar cane, i.e. alkyl group, C-Cv-alkoxy group, C-C4--alkoxy- in addition to harmful plants are also damaged by co-Ci-C4-alkyl group, Cz-C7 -cycloalkyl group, rice crops to an unacceptable degree. There is a Cz-Cv-alkenyl group, a Cz-Cv-alkynyl group, or the possibility of preventing damage to useful benzyl, which is unsubstituted or substituted haloge-cultures by reducing the applied doses, nom or alkyl group; however, in this case, naturally, it also reduces - Vo, B" independently of each other represent the degree of control of harmful plants. hydrogen, C-Cv-alkyl group, /C-Cv-

It is known that certain combinations of different herbicides with an alkoxy group, a C3-C8-alkenyl group, a C3-C8-alkenyl group, C3-C7-cycloalkyl group, a C3-C7-cycloalkyl group, a C3-C7-cycloalkyl group, a specific effect lead to an improved activity of herbicide components due to a synergistic cycloalkenyl group , phenyl or benzyl, where each effect. As a result, it is possible to reduce the unsubstituted or used doses of herbicide-active compounds from the 8 above-mentioned substituents, which can be substituted from 1 to 6 times by atoms that are necessary for suppressing harmful plants. halogen and/or one, two or three group-

In addition, it is known that in some cases we are better, selected from: ОН, МН», СМ, СОМН», С-Са- compatibility with cultivated plants can be alkoxy groups, С-С--haloalkyl groups, С1-С4- achieved by joint use of herbi-alkylthio group, С1-Саг-halogenoalkylthio group, С1-Са-acids of specific action with organic active alkylsulfonyl group, С-Са compounds, some of which themselves have herbicidal haloalkylsulfonyl group, С1-б4- activity. In these cases, the active compounds act as an antidote or antagonist, and due to the fact that they can reduce or even to prevent the damage caused by the alkylaminocarbonyl group, di(C1-Са-), they are also called antidotes. alkyl)aminocarbonyl group, C3-C»-

GU OE 195 06 202) herbicide compounds of the cycloalkyl group, phenyl and benzyl are described; or cations containing a herbicide-effective amount of 3-Bé, B" together with a nitrogen atom form a 3-, 4-, phenyluracil and antagonistically effective ring- 5-, vb- or 7-membered saturated or unsaturated bone Ш-(2- chlorophenylmethyl)-1-(1-methyl-1- nitrogen-containing heterocycle, which can be substituted by phenylethyl)urea and/or 1-41-methyl-1-one from 1 to 6 times with methyl groups and which phenylethyl)-3-( 4-tolyl) urea may contain 1 or 2 additional heteroatoms,

selected from the group consisting of nitrogen, oxygen and sulfur, which contains a first component that includes ku as ring members, active compound A, a solid or liquid carrier and, as and their agriculturally acceptable salts, preferably, one or more surfactants are described in an earlier (patent application) substances, and the second component, which includes at least

PCT/ERO1/048501. me one additional active compound selected from

The purpose of this invention is to increase herbicides B and antidotes C, solid or liquid norbicidal activity of Z-phenyluracils of formula I and, if applicable, one or more surface- in relation to unwanted harmful plants and 5 active substances, and both components simultaneously improving their compatibility with useful can, in addition, include additional auxiliary cultures. substances that are usually used in the composition

Unexpectedly, we found that the goal of protecting agricultural crops. of this invention is achieved by compositions which The invention, in addition, relates to a method of containing at least one 3-phenyluracil of the formula | crops with undesirable vegetation, in particular, in the cult- and/or at least one acceptable in rural crops of cereals, corn, soybeans, rice, rapeseed, salt compounds of the formula | and, at least, cotton, potatoes, peanuts, in perennial crops - one additional active compound selected from these plants, as well as in crops that, thanks to genetic

C) herbicides of classes from B1) to 015): engineering or breeding, are resistant to one or

BI) lipid biosynthesis inhibitors; more herbicides or before insect attack. The invention rg) inhibitors of acelactate synthase (A! 5 inhibitor also refers to the method of drying or tory); defoliation of plants. In the last methods it does not have

B3) photosynthesis inhibitors; the importance of whether the herbicide-active compounds are ri) inhibitors of protoporphyrinogen-X oxidase; components A) and B) and/or C) are presented in com- 55) bleaching herbicides; positions and be applied together or separately, and, in

Jub) enolpyruvyl shikimate inhibitors 3- case of individual use, in which order of phosphate synthase (ERBR inhibitors); they will apply. p) glutamine synthetase inhibitors; Organic residues mentioned in the definition of zara8) inhibitors of 7,β-dihydropteroate synthase (ONR of substituents 2, В», Ве, В" in formula I and В8-В'"Z in for-inhibitors); Muli II or as radicals on cycloalkyl, feniro) mitosis inhibitors; ring or heterocyclic rings, are 010) fatty acid synthesis inhibitors with a very long chain (MI SREA inhibitors); for individual enumerations of individual group members. 011) cellulose biosynthesis inhibitors; All hydrocarbon chains, i.e. all alkyl, halo-p12) splitting herbicides; genoalkyl, cycloalkyl, alkoxy, haloal-p13) auxin herbicides; coxy, alkylamino, alkylthio, haloalkylthio, alkyl- p14) auxin transport inhibitors; sulfinyl, haloalkylsulfinyl, 015) other herbicides selected from the group including alkylsulfonyl, haloalkylsulfonyl, benzoylprop, flamprop, flamprop-M, bromo-alkenyl and alkynyl groups and corresponding residues in butide, chloroflurenol, cinmethylin, methyldimuron, large groups , such as alkylcarbonyl groups, ethobenzanide, fosamine, metham, pyributycarb, oxa-alkylaminocarbonyl groups, dialkylaminocarzylmefon, dazomet, triaziflam and methylbro- carbonyl groups, alkoxycarbonyl groups, and copper; and so on, can be unbranched or branched

C) antidotes selected from the group that includes: tinned, the prefix Сп-Ст indicates in each case - benoxacor, cloquintocet, cyometrinil, dichlormid, to the possible number of carbon atoms in the group. Halo- dicyclonone, dietholate, fenchlorazole, fenclorim, genated substitutes mainly have one, two, flurazole, fluxofenim, furilazole, isoxadifen, three, four or five identical or different atoms mefenpyr, mefenate, naphthoic anhydride, 2,2,5- halogen The term halogen denotes in each vitrimethyl-3-(dichloroacetyl)-1,3-oxazolidine (K- fall of fluorine, chlorine, bromine or iodine. 29148), 4-(dichloroacetyl)-1-oxa-4- Examples of other meanings are: azaspiro(4.5|decane (40-67; IOM 4660) and oxabetri- -C1-C4-alkyl: СН3, СеН5, n-propyl, СН(СН3)», n-nil, acceptable in agriculture salts of actin- butyl, CH(CH3)-C»H5, CH»-CH(CH3)» and C(CH33)3; other compounds B and C and acceptable in the agricultural economy - -b1-C4-halogenoalkyl: radical Ci-Ca-alkyl , as derivatives of active compounds B and C, provided that it is specified above, which partially or completely they have a carboxyl group substituted by fluorine, chlorine, bromine and/or iodine,

In particular, the invention relates to compositions, i.e., for example, СНР, СНЕ», СЕз, СНеСИ, dichloroform herbicide-active protection compositions rmethyl, trichloromethyl, chlorofluoromethyl, dichloro- agricultural crops containing gerbilorfluoromethyl, chlorodifluoromethyl, 2- fluoroethyl, 2- an effective amount of at least one mixture of chloroethyl, 2-bromoethyl, 2-iodoethyl, 2,2-difluoroethyl,

A and B and/or C as defined above and at least 2,2,2-trifluoroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2- one liquid and/or solid carrier and, if preferably, difluoroethyl, 2,2-dichloro-2-fluoroethyl, 2,2,2- one or more surfactants and, trichloroethyl, Sov, 2-fluoropropyl, 3-fluoropropyl, if desired, one or more additional additives 2,2-difluoropropyl, 2,3-difluoropropyl, 2- intermediate substances that are usually used in com- chloropropyl, 3-chloropropyl, 2,3-dichloropropyl, 2- positions of crop protection. bromopropyl, C3-bromopropyl, 3,3,3-trifluoropropyl,

The invention also relates to compositions in the form of 3,3,3-trichloropropyl, 2,2,3,3,3-pentafluoropropyl, crop protection compositions, heptafluoropropyl, 1-(fluoromethyl)-2-fluoroethyl, 1-presented in the form 2-component compound- (chloromethyl)-2-chloroethyl, 1-"(bromomethyl)-2-

bromethyl, 4-fluorobutyl, 4-chlorobutyl, 4-bromobutyl fluoropropylthio, 2,2-difluoropropylthio, 2,3- or nonafluorobutyl; difluoropropylthio, 2-chloropropylthio, 3-chloropropylthio, -Ci-Cv-alkyl: Ci-Ca-alkyl as specified 2,3-dichloropropylthio, 2-bromopropylthio, 3- above, and also, for example, n-pentyl, 1 - bromopropylthio, 3,3,3-trifluoropropylthio, 3,3,3- methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2- trichloropropylthio, ЗСН2-СоЕ5, ЗСЕ2-С2Ев, 1-(СНеавг)- dimethylpropyl, 1 -ethylpropyl, n-hexyl, 1,1-2-fluoroethylthio, 1-(СНеСИ)-2-chloroethylthio, 1-(СНеГГ)- dimethylpropyl, 1,2-dimethylpropyl, 1- 2-bromomethylthio, 4-fluorobutylthio, 4 -chlorobutylthio, 4-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-bromobutylthio or ЗСЕ»-СЕ2-СОЕ5, preferably methylpentyl, 1,1-dimethylbutyl, 1,2- ЗСНЕ», ЗСЕ3, dichlorofluoromethylthio, chlorodifluorodimethylbutyl, 1,3-dimethylbutyl, 2,2-methylthio or 2,2,2-trifluoroethylthio; dimethylbutyl, 2,3-dimethylbutyl, 3,3- -C1-C--alkoxy-C1-Ca-alkyl: C1-C1-alkyl, which dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2- substituted by C1i-C-- alkoxy group, such as trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1- above, i.e., for example, CH»-ОСН»3, СНо-ОС»нНв5, methylpropyl or 1 -ethyl-2-methylpropyl, preferably n-propoxymethyl, CH»--ОСН(CHвЗ3)», n-butoxymethyl, methyl, ethyl, n-propyl, 1-methylethyl, n-butyl, 1,1-(1-methylpropoxy )methyl, (2-methylpropoxy)methyl, dimethylethyl, n-pentyl or n-hexyl; SnNo-OoC(SnNZz)z, 2-(methoxy)ethyl, 2-(ethoxy)ethyl, 2- -C1-Cv-halogenoalkyl: a radical of Ci-Cv-alkyl, as (n-propoxy)ethyl, 2-(1 -methylethoxy)ethyl, /-2-(n- it is specified above which is partially or fully butoxy)ethyl, 2-(1-methylpropoxy)ethyl, 2-(2- substituted with fluorine, chlorine, bromine and/or iodine, methylpropoxy )ethyl, 2-(1,1-dimethylethoxy)ethyl, i.e., for example, one of the radicals mentioned for 2-(methoxy)propyl, 2-(ethoxy)propyl, 2-(n-

C1-C.-haloalkyl, as well as 5-fluoro-1-pentyl, 5-propoxy)propyl, 2-(1-methylethoxy)propyl, 2-(n-chloro-1-pentyl, 5-bromo-1-pentyl) , 5-iodo-1-pentyl, butoxy)propyl, 2-(1-methylpropoxy)propyl, 2-(2-5,5,5-trichloro-1-pentyl, undecafluoropentyl, 6-methylpropoxy)propyl, 2-( 1,1-fluoro-1-hexyl, b-chloro-1-hexyl, 6-bromo-1-hexyl, dimethylethoxy)propyl, 3-(methoxy)propyl, 3-b-iodo-1-hexyl, 6,6 ,6-trichloro-1-hexyl or dode-(ethoxy)propyl, 3-(n-propoxy)propyl, 3-(1-caftorhexyl; methylethoxy)propyl, 3-(n-butoxy)propyl, 3-(1- -C.-C--Alkoxy: ОСН3, ОСеН5в, n-propoxy, methylpropoxy)propyl, 3-(2-methylpropoxy)propyl,

OSH(CH3)", o n-butoxy, OSH(CH3)-CoH5, OSsH»- 3-(1,1-dimethylethoxy)propyl, 2-(methoxy)butyl, 2-

CH(CH3)g or OS(CnH3)z, preferably OSH»z, OS»H5 (ethoxy)butyl, 2-(n-propoxy)butyl, 2-(1- or OSH(CH33)»; Si-Ca- haloalkoxy: radical methylethoxy)butyl, 2-(n-butoxy)butyl, 2-(1-

C-C-Alkoxy, as defined above, which is partially methylpropoxy)butyl, 2-(2-methylpropoxy)butyl, partially or fully substituted with fluorine, chlorine, 2-(1,1-dimethylethoxy)butyl, 3-( methoxy)butyl, 3- bromine and/or iodine, i.e., for example, OSNoE, (ethoxy)butyl, 3-(n-propoxy)butyl, 3-(1-

ОСНЕ», ОСЕ3, ОСНоСИ, OSН(СИ)2, OS(СИ)3, chloromethylethoxy)butyl, 3-(n-butoxy)butyl, 3-(1-rfluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethylpropoxy)butyl, 3 -(2-methylpropoxy)butyl, methoxy, 2-fluoroethoxy, 2-chloroethoxy, 2- 3-(1,1-dimethylethoxy)butyl, 4-(methoxy)butyl, 4-bromomethoxy, 2-iodoethoxy, 2,2- difluoroethoxy, 2,2,2- (ethoxy)butyl, 4-(n-propoxy)butyl, 4-(1-trifluoroethoxy, 2-chloro-2-fluoroethoxy, 2-chloro-2,2-methylethoxy)butyl, 4 -(n-butoxy)butyl, 4-(1- difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2- methylpropoxy)butyl, 4-(2-methylpropoxy)butyl trichloroethoxy, OSoB5, 2-fluoropropoxy , /3- or 4-(1,1-dimethylethoxy)butyl, preferably CNe-fluoropropoxy, 2,2-difluoropropoxy, 2,3-Osn", СНо-ОС»оН5, 2-methoxyethyl or 2-ethoxyethyl; difluoropropoxy, 2-chloropropoxy, 3-chloropropoxy, -(С1-С4-alkylcarbonyl: СО-СН3, СО-С2Н5, СО- 2,3-dichloropropoxy, 2-bromopropoxy, 3-СНо-С2Но, СО-СН(СН3) », n-butylcarbonyl, CO-bromopropoxy, 3,3,3Z-trifluoropropoxy, /-3,3,3- СН(СН33)-С»Н5, СО-СНо-СН(СН3)» or СО-С(СН33 )z, trichloropropoxy, 2,2,3,3,3-pentafluoropropoxy, preferably СО-СН3 or СО-С2Н5;

ОСи2-Сов5, /1-(СНоБ)-2-fluoroethoxy, 1-(СНеССИ)-2- -(С1-С4-аlkoxy)carbonyl: СО-ОСсН», со-chloroethoxy, 1-«СН2гВг)-2- bromethoxy, 4- ОСоН, n-propoxycarbonyl, СО-ОСН(СНЗ3)2, n- fluorobutoxy, 4-chlorobutoxy, 4-bromobutoxy or butoxycarbonyl, СО-ОСН(СН»з)-С»Н5, СО-ОСН»- nonafluorobutoxy, preferably ОСНЕ», ОСЕ3, dich-СН(СН3)»2 or СО-ОС(СН3)з, preferably СО-ОСН3 lorfluoromethoxy, chlorodifluoromethoxy or 2,2,2- or СО-ОС»Нв5; trifluoroethoxy; -С1-Са-alkylsulfinyl: 5О-СН3, 50-С2Н5, 50- -С1и1-С4-alkylthio: 5ССН3, СС2Н5, n-propylthio, СНе-С2Н5, 5О-СН(СН3)», n-butylsulfinyl, 50-

ЗСН(СН3)», n-butylthio, ЗСН(СН33)-С2иН5, 5СНе-СНn(СН3)-С2Н5, 50-СНа-СН(СН3)г or 50О-С(СНвз)з,

CH(CH3)»26 or ZC(CH3)3, preferably 5CH3 or preferably 50-CH3 or 5О-С2НБ;

ZCo Nv; -C1-C4-haloalkylsulfinyl: C1-C4 radical -C1-C4-halogenoalkylthio: C1-b4- alkylsulfinyl radical - as specified above - alkylthio as specified above, which is partially or completely substituted by fluorine, chlorine, or completely substituted by fluorine, chlorine, bromine, bromine and/or iodine, i.e., for example, ЗО-СНоЕ, and/or iodine, that is, for example, ЗСНоЕ, 5СНЕ», 5О-СНЕ», 50-СЕз, 50-СНоСИ , 50О-СН(СИ)», 50-

ЗСНегСИ, 5СН(СИ)», ЗО(СИ)з, ZSEz, chlorofluoromethyl-С(СИ)з, chlorofluoromethylsulfinyl, dichlorofluoromethio, dichlorofluoromethylthio, chlorodifluoromethylthio, 2-thylsulfinyl, chlorodifluoromethylsulfinyl, -.2- fluoroethylthio, 2-chloroethylthio, 2-bromomethylthio, 2-fluoroethylsulfinyl, 2-xporeethylsulfinyl, 2-iodoethylthio, 2,2-difluoroethylthio, 2,2,2- bromomethylsulfinyl, 2-iodoethylsulfinyl, 2,2- trifluoroethylthio, 2-chloro-2-fluoroethylthio, 2- chloro-2,2- difluoroethylsulfinyl, 2,2,2- difluoroethylthio, 2,2-dichloro-2-fluoroethylthio, 2,2,2- trifluoroethylsulfinyl, 2-chloro-2-trichloroethylthio, ZSobv, 2-fluoropropylthio, /З - fluoroethylsulfinyl, 2-chloro-2,2-

difluoroethylsulfinyl, 2,2-dichloro-2-M-butyl-M-ethylamino, M-ethyl-m-(1-fluoroethylsulfinyl, 2,2,2-trichloroethylsulfinyl, methylpropyl)amino,

ZO-CoEv, 2-fluoropropylsulfinyl, 3-M-ethyl-M-(2-methylpropyl)amino, M-ethyl-M-(1,1-fluoropropylsulfinyl, 2,2-difluoropropylsulfinyl, dimethylethyl)amino, 2,3- difluoropropylsulfinyl, 2- M-(1-methylethyl)-M-propylamino, M-butyl-M- chloropropylsulfinyl, C-chloropropylsulfinyl, 2,3- propylamino, dichloropropylsulfinyl, 2-bromopropylsulfinyl, 3- M-(1-methylpropyl)- M-propylamino, M-(2- bromopropylsulfinyl, 3,3,3- methylpropyl)-M-propylamino, trifluoropropylsulfinyl, 3,3,3- M-(1,1-dimethylethyl)-M-propylamino, M-butyl- M-(1-trichloropropylsulfinyl, 5O-CHIN2-CoE5, 5O-CE»- methylethyl)amino,

Owl, 1-(fluoromethyl)-2-fluoroethylsulfinyl, 1- M-(1-methylethyl)-M-(1-methylpropyl)amino, (chloromethyl)-2-chloroethylsulfinyl, 1-(bromomethyl)- M-(1- methylethyl)-M-(2-methylpropyl)amino, 2-bromomethylsulfinyl, 4-fluorobutylsulfinyl, 4-M-(1,1-dimethylethyl)-M-(1-methylethyl)amino, chlorobutylsulfinyl, 4-bromobutylsulfinyl or M-butyl -M-(1-methylpropyl)amino, nonafluorobutylsulfinyl, preferably 50-SEz, 50-M-butyl-M-(2-methylpropyl)amino,

СНеСИ or 2,2,2-trifluoroethylsulfinyl; M-butyl-M-(1,1-dimethylethyl)amino, -C1-C"-alkylsulfonyl: 502-CH3, 502-С2НвБ, M-(1-methylpropyl)-M-(2-methylpropyl)amino, 502- СН2-С2Н, 502-СН(СН3)г», n-butylsulfonyl, M-(1,1-dimethylethyl)-IM-(1-methylpropyl)amino or 502-СН(СН3)-СеН5, 502-СН»- CH(CH3)" or 505-M-(1,1-dimethylethyl)-M-(2-

С(СнНз)з, preferably 502-СН3 or 502-С2Нв5; methylpropyl)amino preferably Mm(CHbz)"2 or -Ci-C4-halogenoalkylsulfonyl: radical C1-C4- M(Ce2 Hv)"; alkylsulfonyl-as defined above-which -C1-C4-alkylaminocarbonyl: for example, methyl- partially or fully substituted with fluorine, chlorine, laminocarbonyl, ethylaminocarbonyl, 1- bromine and/or iodine, i.e., for example, 502- methylethylaminocarbonyl, propylaminocarbonyl,

СНев, 502-СНЕ», 502-СЕз, 502-СНеСИ, 502-СН(СИ)», butyl aminocarbonyl, 1-methylpropylaminocarbonyl,

ЗО2-С(СИ)з, chlorofluoromethylsulfonyl, dich-2-methylpropylaminocarbonyl, 1,1-chlorofluoromethylsulfonyl, chlorodifluoromethylsul-dimethylethylaminocarbonyl; fonyl, 2-fluoroethylsulfonyl, 2- -di(C1i-Ca-alkyl)aminocarbonyl: for example, chloroethylsulfonyl, 2-bromomethylsulfonyl, 2-M,M-dimethylaminocarbonyl, M,M- iodoethylsulfonyl, 2,2-difluoroethylsulfonyl, diethylaminocarbonyl, 2 . - M,M-dibutylaminocarbonyl, M,M-di(1-fluoroethylsulfonyl, 2,2,2-trichloroethylsulfonyl, methylpropyl)aminocarbonyl,

ZO2-CoEv, 2-fluoropropylsulfonyl, 3-M,M-di(2-methylpropyl)aminocarbonyl, fluoropropylsulfonyl, 2,2-M,M-di(1,1-dimethylethyl)aminocarbonyl, difluoropropylsulfonyl, 2,3-M- ethyl-M-methylaminocarbonyl, difluoropropylsulfonyl, 2-chloropropylsulfonyl, M-methyl-M-propylaminocarbonyl,

C-chloropropylsulfonyl, 2,3-M-methyl-M-(1-methylethyl)aminocarbonyl, dichloropropylsulfonyl, 2-bromopropylsulfonyl, M-butyl-M-methylaminocarbonyl,

C-bromopropylsulfonyl, 3,3,3-M-methyl-M-(1-methylpropyl)aminocarbonyl, trifluoropropylsulfonyl, 3,3,3-M-methyl-M-(2-methylpropyl)aminocarbonyl, trichloropropylsulfonyl, 5О2-СН2- СоЕ5, 502-СЕ2- M-(1,1-dimethylethyl)-M-methylaminocarbonyl,

Со5, 1-(fluoromethyl)-2-fluoroethylsulfonyl, -/ 1- M-ethyl-M-propylaminocarbonyl, (chloromethyl)-2-chloroethylsulfonyl, 1-(bromomethyl)- M-ethyl-M-(1-methylethyl)aminocarbonyl . -(2-methylpropyl)aminocarbonyl, 502-SNeSi or 2,2,2-trifluoroethylsulfonyl; M-ethyl-M-(1,1-dimethylethyl)aminocarbonyl, -Ci-C4-alkylamino: МН(CH3), МН(СеНв5), propi- M-(1-methylethyl)-M-propylaminocarbonyl, lamino, МНИСН( CH33)2i, butylamino, 1-M-butyl-M-propylaminocarbonyl, methylpropylamino, 2-methylpropylamino, M-(1-methylpropyl)-M-propylaminocarbonyl,

MNIS (SZ) with; M-(2-methylpropyl)-M-protlaminocarbonyl, -di(Si-Ca-alkylamino: M(CH3)", M(Cg2Hv)2, M,M- M-(1,1-dimethylethyl)-M-propylaminocarbonyl , dipropylamino, MISN(CHZ3)hy|2, M-butyl-M-(1-methylethyl)aminocarbonyl,

M,M-dibutylamino, M,M-di(1-methylpropyl)amino, M-(1-methylethyl)-M-(1-methylpropyl)aminocarbonyl,

M,M-di(2-methylpropyl)amino, MIS(CH3)z|», M-ethyl- M-(1-methylethyl)-M-(2-methylpropyl)aminocarbonyl,

M-methylamino, M-(1,1-dimethylethyl)-M-(1-

M-methyl-M-propylamino, M-methyl-M-(1-methylethyl)aminocarbonyl, methylethyl)amino, M-butyl-IM-(1-methylpropyl)aminocarbonyl,

M-butyl-M-methylamino, M-methyl-Im-(1-M-butyl-M-(2-methylpropyl)aminocarbonyl, methylpropyl)amino, M-butyl-M-(1,1-dimethylethyl)aminocarbonyl,

M-methyl-IM-(2-methylpropyl)amino, M-(1,1- M-(1-methylpropyl)-M-(2-dimethylethyl)-M-methylamino, methylpropyl)aminocarbonyl,

M-ethyl-M-propylamino, M-ethyl-M-(1-M-(1,1-dimethylethyl)-M-(1-methylethyl)amino, methylpropyl)aminocarbonyl or

M-(1,1-dimethylethyl)-M-(2-n-hex-2-yn-4-yl, n-hex-2-yn-5-yl, n-hex-2-yn-6-yl , n-methylpropyl)aminocarbonyl; hex-3-yn-1-yl, -C3-C6-alkenyl: prop-1-en-1-yl, allyl, 1-n-hex-33-yn-2-yl, 3-methylpent-1-yn -yl, 3-methylethenyl, 1-buten-1-yl, methylpent-1-yn-3-yl, 1-buten-2-yl, 1-buten-3-yl, 2-buten-1-yl , 1-Z-methylpent-1-yn-4-yl, Z-methylpent-1-yn-5-yl, 4-methylprop-1-en-1-yl, methylpent-1-yn-1-yl, 2 -methylprop-1-en-1-yl, 1-methylprop-2-en-1-yl, 2-4-methylpent-2-yn-4-yl or 4-methylpent-2-yn-5-yl, methylprop -2-en-1-yl, preferably prop-2-yn-1-yl; n-penten-1-yl, n-penten-2-yl, n-penten-3-yl, n- -C33-C-cycloalkyl: cyclopropyl, cyclobutyl, penten-4-yl, cyclopentyl, cyclohexyl or cycloheptyl; 1-methylbut-1-en-y-yl, 2-methylbut-1-en-1-yl, / 3- -C3-C7-cycloalkyl having a carbonyl or methylbut-1-en-1-yl, thiocarbonyl ring member: 1-methylbut-2-en-y-yl, 2-methylbut-2-en-1-yl, / 3- for example, cyclobutanon-2-yl, cyclobutanon-methylbut-2-en-1-yl, C -yl, cyclopentanon-2-yl, cyclopentanon-3-yl, cycl-1-methylbut-3-en-1-yl, 2-methylbut-3-en-1-yl, 3- loghexanon-2-yl, cyclohexanone -4-yl, cyclohepta-methylbut-3-en-1-yl, non-2-yl, cyclooctanon-2-yl, cyclobutanthion-2-yl, 1,1-dimethylprop-2-en-1-yl, 1 ,2-dimethylprop-1-en-cyclobutanthion-3-yl, cyclopentanthion-2-yl, cyclo-1-yl, pentanthion-3-yl, cyclohexanethion-2-yl, cyclohexane-1,2-dimethylprop-2-ene -1-yl, 1-ethylprop-1-en-2-yl, 1-thion-4-yl, cycloheptanthion-2-yl or cyclooctanthion-ethylprop-2-en-1-yl, 2-yl, preferably cyclopentanone- 2-yl or cyclohex-n-hex-1-en-1-yl, n-hexo-2-en-1-yl, n-hex-3-en-1-yl, n-sanon-2-yl. hex-4-en-1-yl, The best herbicides B, which can be n-hexo-5-en-1-yl, 1-methylpent-1-en-y-yl, 2- used according to this invention in combi-methylpent-1-en-1-yl, nations with 3-phenyluracils of the formula and, are:

3-methylpent-1-en-1-yl, 4-methylpent-1-en-1-yl, 1-BI) from the group of lipid biosynthesis inhibitors: chlora-methylpent-2-en-1-yl, zifop, clodinafop, clofop, cigalofop, diclo-2-methylpent-2-en-1-yl, 3-methylpent-2-en-1-yl, 4-fop, fenoxaprop, fenoxaprop-P, fenthiaprop, methylpent-2-en-1- yl, fluazifop, fluazifop-P, haloxyfop, haloxy-1-methylpent-3-en-1-yl, 2-methylpent-3-en-y-yl, 3-fop-P, isoxapyrifop, metamifop, propaquizafop, methylpent- 3-en-1-yl, quizalofop, quizalofop-P, tryfop, aloxidim, 4-methylpent-3-en-1-yl, 1-methylpent-4-en-1-yl, 2- butroxidim, clethodim, cloproxidim, cycloxymethylpent-4-en-1-yl, dim, profoxidim, sethoxidim, tepraloxidim,

3-methylpent-4-en-1-yl, 4-methylpent-4-en-1-yl, 1,1-thralkoxide, butylate, cycloate, diallate, dimepi-dimethylbut-2-en-1-yl, perate, ERTS, esprocarb, etiolate, isopolinate, methyl-1,1-dimethylbut-3-en-1-yl, 1,2-dimethylbut-1-en-1-obencarb, molinate, orbencarb, pebulate, prosulyl, focarb, sulfallate, thiobencarb, thiocarbazyl, 1,2-dimethylbut-2-en-1-yl, 1,2-dimethylbut-3-en-1-triallate, vernolate, benfurezate, etofumesate and yl, bensulide; 1,3-dimethylbut-1-en-1-yl, 1,3-dimethylbut-2-en-1-p2) from the AG group of 5 inhibitors: amidosulfuron, il, azimsulfuron, bensulfuron, chlorimuron, 1,3-dimethylbut- 3-en-1-yl, 2,2-dimethylbut-3-en-1-chlorosulfuron, cynosulfuron, cyclosulfamuyl, ron, ethametsulfuron, ethoxysulfuron, flaz-2,3-dimethylbut-1-en-1-yl, 2,3-dimethylbut-2-en-1-sulfuron, flupyrsulfuron, foramsulfuron, il, halosulfuron, imazosulfuron, iodosulfuron, 2,3-dimethylbut-3-en-1-yl, 3,3-dimethylbut-1-en- 1- mesosulfuron, metsulfuron, nicosulfuron, il, oxasulfuron, primemisulfuron, prosulfuron,

3,3-dimethylbut-2-en-1-yl, 1-ethylbut-1-en-1-yl, 1-pyrazosulfuron, rimsulfuron, sulfometuron, ethylbut-2-en-1-yl, sulfosulfuron, thifensulfuron, triasul- 1-ethylbut-3-en-1-yl, 2-ethylbut-1-en-1-yl, 2-ethylbutfuron, tribenuron, trifloxysulfuron, tri-2-en-1-yl, flusulfuron, tritosulfuron, imazametabenz, 2-ethylbut-3-en-1-yl, 1,1,2-trimethylprop-2-en-1-yl, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, 1-ethyl-1-methylprop-2-en- 1-yl, 1-ethyl-2-methylprop-cloransulam, diclosulam, florasulam, flu-1-en-1-yl or metsulam, methosulam, penoxsulam, bispiribac, 1-ethyl-2-methylprop-2-en-1- silt; pyriminobac, propoxycarbazone, flucarbazone, pi--C3-Cv-alkynyl: prop-1-yn-1-yl, prop-2-yn-1-yl, n-ribenzoxime, pyriphthalide and pyrithiobac; but-1-yn-1-yl, B3) from the group of photosynthesis inhibitors: atraton, n-but-1-yn-3-yl, n-but-1-yn-4-yl, n-but-2-yn -1-yl, n- atrazine, ametryn, aziprothrin, cyanazine, cya-pent-1-yn-1-yl, natrin, chlorazine, cyprazine, desmethrin, dimeta-n-pent-1-yn-3-yl, n -pent-1-yn-4-yl, n-pent-1-yn-5-yl, methrin, dipropethrin, eglinazine, ipazine, mesopra-n-pent-2-yn-1-yl, zine, methometon, methoprothrin )

Z-il, butylazine, secbumeton, simazine, simeton, simet-

Z-methylbut-1-yn-4-yl, n-hex-1-yn-1-yl, n-hex-1-yn-rin, terbumetone, terbuthylazine, terbutrin,

Z-yl, triethazine, ametridione, amibuzin, hexazinone, iso-n-hex-1-yn-4-yl, n-hex-1-yn-5-yl, n-hexo-1-yn-6-yl, n-methiosin, metamitron, metribuzin, bromacil, iso-hexo-2-yn-1-yl, cil, lenacil, terbacil, brompyrazone, chloridazone,

dimidazone, desmedifam, phenizofam, phenmedi- V!? is a Ci-Cv-alkyl group; fam, phenmedipham-ethyl, benzthiazuron, butiuron, BZ represents hydrogen or a C-Cv-alkyl ethidimuron, isouron, metabenzthiazuron, monoiso group. ron, tebutiuron, thiazafluron, anizuron, buturon, Bb) from the group of ERBR synthase inhibitors: glyphosate; chlorbromuron, chloreturon, chlorotoluron, 07) from the group of glutamine synthetase inhibitors: chloroxuron, difenoxuron, dimefuron, diuron, glufosinate and bilanafos; fenuron, fluometuron, fluotiuron, isoproturon, re) from the group of ONR synthase inhibitors: azulam; linuron, metiuron, metobenzuron, metobromuron, pO) from the group of mitosis inhibitors: benfluralin, bumethoxuron, monolinuron, monuron, neburon, patralin, dinitramine, etalfluralin, fluchloralin, rafluron, phenobenzuron, siduron, tetrafluron, isopropalin, metalpropalin, nitralin ) - pyr, propizamide, tebutam, chlorthal, carbetamide, rbazone, bromofenoxime, flumezin, metazol, ben-chlorbufam, chlorpropham and profam; tazon, propanil, pentanochlor, pyridate and pyridafol; 010) from the group of inhibitors of MI SEA: acetochlor, ala- 04) from the group of inhibitors of protoporphyrinogen-Ich chlorine, butachlor, butenachlor, delachlor, diethyl, oxidases: acifluorfen, bifenox, chlomethoxydimetachlor, dimethenamid, dimethenamid-P, metafen, chlornitrophen, ethoxyfen, fluorodifen, zachlor, metolachlor, 5-metolachlor, pretilachlor, fluoroglycofen, fluoronitrophen, fomezafen, propachlor, propisochlor, prinachlor, terbuchlor, furyloxifene, halozafen, lactofen, nitrofen, tenylchlor, xylachlor, alidochlor, COEA, epronaz, nitrofluorfen, oxyfluorfen, fluazolate, pyridifenamide, napropamide, naproanilide, pentaxamide, flufen, cinidon-ethyl, flumiclorac, flumioxa-flufenacet, mefenacet, fentrazamide, anilophos, zine, flumipropine, fluthiacet, thidiazimin, oxadia-piperophos, cafenstrol, indanophan and tridiphan; zon, oxadiargil, azafenidine, carfentrazone, 011) from the group of cellulose biosynthesis inhibitors: sulfentrazone, pentoxazone, benzphendizone, budichlobenil, chlorthiamide, isoxaben and flupoxam; tafenacyl, pyraclonil, profluazole, flufenpyr, 012) from the group of splitting herbicides: dino-flupropacil, nipyraclofen and etnipromid; phenate, dinoprop, dinosam, dinoseb, dinoterb,

B5) from the group of bleaching herbicides: metflura-OMOS, etinofen and medinorb; zon, norflurazon, flufenican, diflufenican, 013) from the group of auxin herbicides: clomeprop, 2,4-picolinafen, beflubutamide, fluridone, flurochloro, 2,4,5-T, MSPA, MSORA thioethyl, dichlorprop, dihydron, flurtamone, mesotrione, sulcotrione, isolorprop-P, mecoprop, mecoprop-P, 2,4-08, MSRV, xachlortol, isoxaflutol, benzofenap, pyrazolichloramben, dicamba, 2,3,6-TVA, tricamba, quin- nat, pyrazoxifene, benzobicyclone, amitrole, clorac, quinmerac, clopyralid, fluroxypyr, picloclomazone, aclonifen, 4-(3-trifluoromethylphenoxy)ram, triclopyr and benazolin; 2-(4-trifluoromethylphenyl)pyrimidine, as well as 3-p14) from the group of oxy-heterocyclyl-substituted benzoyl derivatives of the formula II: naptalam, diflufenzopyr;

015) benzoylprop, flamprop, flamprop-M, bromobutide, chlorflurenol, cinmethylin, methyl-

M dimron, ethobenzanid, fosamine, metham, pyributych and (I) carb, oxacyclomefon, dazomet, triaziflam and

What about methyl bromide. in it Active compounds of groups B from B1) to p15) and active

B compounds C are known herbicides and antidotes, in which the variables E8-B"U, such as those indicated below: (see, for example, Tpe Sotrepaicht oi Reviiside

VU, V? represent hydrogen, halogen, С1-Св- Sottop Matev alkyl group, (peru/Llymly. psig55.aetop.so.yK/paeh. piti); Ragt

C1-Cv-halogenoalkyl group, C1-Cv- SPpetisaie Naparook 2000 Moi. 86, Meyvieg Alkoxygrupu, Rybiizpipd Sotrapu, 2000; V. Nosk, S. Redike, V.V.

C1i-Cv-halogenoalkyl group, C1-Cv- Zeptiai, Negrigide, Sbeogd Tpiyete Mepad, Zshchidai alkylthio group, 1995; M. N. Angepv, Negriside Napabook, 7!" Eaiiop,

C1i-Cv-alkylsulfinyl group or Uueei BZsiepse Boseiiu oi Ategisa, 1994; and K.K.

C1i-Cv-alkylsulfonyl group; Naigiov5, Negbiside Naparook, Zirrietepi and 7

VZ is a heterocylic radical, chosen by Eayop, UUeed Zsiepse Bbosieiu oi Ateigisa, 1998). early from the group including: thiazol-2-yl, thiazol-4-yl, 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidin thiazol-5-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-ISA5 Mo.52836-31-4| also known as

B-yl, 4,5-dihydroisoxazol-Z-yl, 4,5-nyam k-29148. 4-(Dichloroacetyl)-1-oxa-4-dihydroisoxazol-4-yl and 4,5-dihydroisoxazol-5-yl, azaspiro(4.5|decane ISAB Mo.71526-07-03| also where the specified nine radicals can be unknown under the designation AO-67 and IOM 4660. Substituted or mono- or polysubstituted, adhering herbicides of formula II, which are described below, clade, mono-, di-, tri- or tetra-substituted, halo-disclosed in UMO 96/26202, UMO 97/41116, UMO genome, Si1-C.-alkyl group, Si1-Ca- 97/41117 Her UMO 97/41118). an alkoxy group, a C1-C4-haloalkyl group, Classification of active compounds according to their

C1-C4-haloalkyl or C-b4- method of action is based on modern understanding. alkylthio group; If the active compound acts in more than one way

B" represents hydrogen, halogen, or Si-Sb- by action, this substance is attributed to only one alkyl group; mode of action.

If phenyluracils I, herbicides B and/or ansat, glufosinate, bilanafos, clomeprop, 2,4-0, 2,4- tidoth C are capable of forming geometric isomers, OB, dichlorprop, dichlorprop-P, MCRA, MCRV, for example, E/2 isomers, it is possible to use both mecoprop, mecoprop-P, 2,4,5-T, chloramben, dicam-pure isomers, and their mixtures in the compositions of otba, 2,3,6-TVA, tricamba, quinclorac , quinmerac, according to the present invention. If phenyluracils I, clopyralid, fluroxypyr, picloram, triclopyr, nap- herbicides B and/or antidotes C have one or talam, diflufenzopyr, cloquintocet, fenchlora- more centers of chirality and, as a result, zol, isoxadifen and mefenpyr are present, as desired in the form of enantiomers or diastereoisomers, such as salts, acceptable in agriculture, the profitable use of both pure enantiomers and diacetions mentioned above in the compositions of the opposite stereoisomers, and their mixtures in the compositions of the present invention. according to the present invention.Anions of acceptable acid addition salts

If phenyluracils I, herbicides B and/or ani- are primary chloride, bromide, fluoridates C have functional groups that can be ionized, then they can also be vycoryphate, dihydrophosphate, hydrophosphate, nitrate, dicarstane in the form of their acceptable in the rural government, phosphate, carbonate, hexafluorosilicate, gift of salts. In general, salts of these hexafluorophosphate, benzoate and anions /Ci-C4- cations or salts of addition acids of these acids are acceptable, where alkanoic acids, mainly formate, acetate, cations and anions, respectively, do not have a disadvantage - propionate and butyrate. left influence on the effect of active compounds. In the compositions according to this invention,

The best cations are ions of alkali metals, active compounds of cyperquat, dietamquat, especially lithium, sodium and potassium, alkaline earth quats, diquats, morphamquats and paraquats, usually of metals, mainly calcium and magnesium, and transients are used in the form of acceptable salts in salts of metals, mainly manganese, copper, zinc, and iron, in the management of cations mentioned above. in addition, ammonium and substituted ammonium, in which from In the compositions according to this invention, one to four hydrogen atoms are replaced by groups of active compounds that have a carboxyl group, on

C1-C4-alkyl, hydroxy-C1-Ca-alkyl, C1-C4-alkyl-C1- unlike the active compounds mentioned above, mo-

C.4-alkyl, hydroxy-C1-C4-alkoxy-C1-C4-alkyl, phenyl can also be used in the form of agronomic or benzyl, preferably ammonium, methylammonium, an isopically acceptable derivative, for example, as amides such as propylammonium, dimethylammonium , diisopropylammonium, such as mono- or di-C1-C8-alkylamides or arylamides, such as trimethylammonium, tetramethylammonium, tetraethyl-esters, for example, such as allyl esters, propargylammonium, tetrabutylammonium, 2-hydroxyethylammonium, 2-esters, Ci-Cio-alkyl esters or alkoxyalkyl (2-hydroxyethoxy)eth-1-ylammonium, di(2-hydroxyethoxy)eth-1-ylammonium, di(2-hydroxyethoxy)ethyl-1-esters, and also as thioesters, for example as C1-C10-yl)ammonium, benzyltrimethylammonium, benzyltriethylalkylthioesters. Examples of active compounds that lamonium, in addition, phosphonium ions, sulfonium ions have a СООН group, which can also be vycori-ions, preferably tri(C1-C4-alkyl)usulfonium in this state in the form of derivatives, are: chlorazifop, clod- like trimethylsulfonium , and sulfoxonium ions, penafop, clofop, cigalofop, diclofop, fenoxa - mainly tri(C1-C4-alkyl) usulfoxonium. rop, fenoxaprop-P, fentiaprop, fluazifop,

It is possible to use, for example, active fluazifop-P, haloxyfop, haloxyfop-P, isoxa - compounds of formulas I and II and compounds selected from the group that pyrifop, propaquizafop, quizalofop, quizalofop - includes: chlorazifop, clodinafop, klofop, tsiga-P, trifop, bensulfuron, chlorimuron, etametsulofop, diclofop, fenoxaprop, fenoxaprop-R, lfuron, flupyrsulfuron, halosulfuron, iofentiaprop, fluazifop, fluazifop-R, haloxydosulfuron, mesosulfuron, metsulfuron, fop, haloxyfop-R, isoxapyrifop, propaquizafop, primesulfuron, pyrazosulfuron, sulquizalofop, quizalofop-R, tripofop, aloxidim, fometuron, tifensulfuron, tribenuron, tributroxidim, clethodim, cloproxidim, cycloxyflusulfuron, imazametabnz, imazamox, imazadim, profoxidim, sethoxidim, tepraloxidim, peak, imazapyr, imazaquin, imazetapyr, cloransulam, tralkoxide, amidosulfuron, azimsulfuron, bispiribac, pyrithiobac, piriminobac, adifluorfen, bensulfuron, chlorimuron, chlorsulfuron, cyethoxifen, fluoroglycofen, lactof en, pyraflunosulfuron, cyclosulfamuron, etametsulfen, flumiclorac, fluthiacet, carfentrazone, furon, ethoxysulfuron, flasasulfuron, fluflufenpyr, clomeprop, 2,4-0, 2,4-O8, dichlorprop, pyrsulfuron, foramsulfuron, halosulfuron, dichlorprop-P, MSRA, MSRV, mecoprop, mecoprop-imazosulfuron, iodosulfuron, mesosulfuron, P, 2,4,5-T6, chloramben, dicamba, 2,3,6-TVA, trikametsulfuron, nicosulfuron, oxasulfuron, mba, quinclorac, quinmerac, clopyralid, fluroxyprimisulfuron, prosulfuron, pyrazosulpyr, picloram, triclopyr, naptalam, diflufenzofuron, rimsulfuron, sulfometuron, sulpir, cloquintocet, fenchlorazole, isoxadifen and fosulfuron, thifensulfuron, triasulfuron, mefengpir. tribenuron, trifloxysulfuron, triflusul. The best mono-di-Ci-Cv-alkylamides are mefuron, tritosulfuron, propoxycarbazone, flutyl-dimethylamides. The best aryl amides are na-carbazone, imazametabenz, imazamox, imazapic, ima-plast, anilidines and 2-chloroanilides. The best alkizapyr, imazaquin, imazethapyr, cloransulam, linoleic esters are, for example, methyl, diclosulam, florasulam, flumetsulam, methoseethyl, propyl, isopropyl, butyl, lam, penoxsulam, bispiribac, pyrithiobac, pyrimino-isobutyl, pentyl, mexyl (1-bac, bentazone, adifluorfen, ethoxyphen, fluoromethylhexyl) or isooctyl (2-glycophen, fomezafen, halozaphen, lactophen, ethylhexyl) esters. The best Ci1-C--Alkoxypyraflufen, flumiclorac, fluthiacei, carfentra-Ci-C.-- alkyl esters are unbranched or zone, flufenpyr, mesotrione, sulcotrione, glyphosate-branched Ci-C.--Alkoxyethyl esters, for example, methoxyethyl, ethoxyethyl or butoxyeti - 011.4. amino|methyl.|ethyl.. linoleic esters. An example of unbranched or | 15 methyl |methyl |propl../-y branched Si1-Sthio-alkyl thiocompound eth- 11116 amino |methyl,. |propl./-- ru is an ethyl thioester.

Among the 3-phenyluracils of formula I!, the advantage | 1.8 famino|methyl (isopropyl./ is given to those in which the variables B'-B" independently of each other, but better in combination, accept findings; predeteti NiyaMe 77777211 amino |methylo |torbutyl.

IN! is methyl or MH"; TK:

A, It is trifluoromethia; At the 11th amino, Zmetilo isobutlo

But represents hydrogen, fluorine or chlorine, zoc; rhema fluorine; 116 amino |methyl o |tert-butyl//

IN? represents halogen or cyano, in particular chlorine or cyano; 11178 amino |methyl / |nlpentyl//

AND? is hydrogen;

VAE, B" independently of each other represent co- (011.20. amino |methyl o |Intexyl of hydrogen, Ci-Cv-alkyl, Cz-Cv-alkenyl, Cz-Cv- 121 Y|methyl o |methyldo// |all / alkynyl, C3-SU-cycloalkyl, C3-C7-cycloalkenyl, phe-|122 |amino|methyl,.|all../-:-:-:U nil or benzyl, or

A, B" together with the nitrogen atom form a pyro- 111124 famino | methyl | propargyl lidin, piperidine, morpholine, M- 01010125 methyl methyl (phenyl/ methylpiperazine or perhydroazepine ring. 00101126 | amino methyl Ifenyl

Ве, В" represent, in particular, the same or different C-Cv-alkyl radicals. pd

In a particularly preferred embodiment of the invention, GG 130 amino |elyl. floor compositions include at least one /3- 733531. |methyl |ethyl. | Propyl phenyluracil i, in which the variables BA" in the formula!

IN! is methyl;

IN? is trifluoromethyl; 136 |amino |ethyl,. |butyl./-ZUu

VZ is fluorine;

Ve is chlorine; 138 amino|ethyl. |nlpentyl./

A: represents hydrogen;

B. B" independently of each other represent co-

In another particularly preferred embodiment, 101142 amino Shpropyl. |proplo of the invention, the compositions include at least one 3-143 methyl |propyl |isopropyl. Phenyluracil I, in which the CA variables in the formula! ГОт45 00 methyl|propyl |butyl take the following values (below also posi- (1.46 |amino |propyl. |butyl. (supplied as for phenyluracils IV): 47 11omethyl|propyl |nlentyl is MH2; 48 amino Shpropyl o |nlentyl

B: is trifluoromethyl; 11149 methyl |propyl. |ntexil//

AND? is fluorine; 11150 amino |propyl, |nchtexyl./

A" is chlorine;

A: represents hydrogen; 111852 amino Isopropyl (isopropyl./-

ВАЭ, В" independently of each other are Ci-Cv-alkyl. 117.54 amino Oisopropyl butyl../-/:UK(O

Examples of especially best herbicides a or Ir are the compounds of the formula !, listed below, in 156 amino |isopropyl |npentyl./ in which EB", Ve and B" together take the values given in one row of Table A (compounds 1.1-1.74) . tables (531600 amino |bull was in 1162 |amino |butyl o |npentyl./ x-4 "5: 11.64 amino |butyl, |ntexyl./

N o DL 11166 amino Znlpentyl |nlpentyl//

To them, m o; 168 f|amino |n-lentyl |nchtexyl./

Phenyluracil In | 'R' | In /| (170 f|amino |n-hexyl |ntexyl// 1112 amino |methyl. |methyl./ /-U| 1172 |amino |-iSnayu

Ob) glyphosate; p7) glufosinate;

Among the compositions according to the invention, 609) benfluralin, butralin, dinitramine, etal - particular preference is given to those that include, fluralin, oryzalin, pendimethalin, trifluralin, at least one herbicide B selected from groups B1) - propizamide; 57), 69)-011), 013) or p14), better in combination with 3-010) acetochlor, alachlor, butachlor, dimethe-phenyluracil of formula Ia or IB. namid, dimethenamid-P, metazachlor, metolachlor, 5-

Among the compositions according to the invention, pemetolachlor, petaxamide, pretilachlor, propachlor, preference is given to those that include at least propisochlor, tenilchlor, flufenacet, mefenacet, one herbicide B selected from groups 01), 52), 55), 056 ), fentrazamide, cafenestrol, indanophan; 07), 69), 610), 613) and 014), especially selected from B11) dichlobenil, chlorothiamide, isoxaben, flupo- groups 52), 55), 06), 57), 69) and 010), better in combination xam with C3-phenyluracil of formula Ia or IB. p13) 2,4-0, 2,4-OB, dichlorprop, dichlorprop-P,

The best herbicides in groups B1)-615) are spol-MOSRA, MOSRV, mecoprop, mecoprop-P, dicamba, which are listed below: p1) clodinafop, cigalo-quinclorac, quinmerac, clopyralid, fluroxypyr, fop, diclofop, fenoxaprop, fenoxaprop -P, picloram, triclopyr, benazolin; fluazifop, fluazifop-P, haloxyfop, haloxy-p14) diflufenzopyr; fop-P, metamifop, quizalofop, quizalofop-P, allo-015) bromobutide, cinmethylin, methyldimron, xidim, butroxidim, clethodim, cloproxidim, oxacyclomefon, triaziflam; and their acceptable in cycloxidim, profoxidim, sethoxidim, tepralo- agriculture salts and, in the case of compounds, xidim, tralkoxidim; 52) amidosulfuron, azyme, which have a carboxyl group, and their derivatives are also acceptable in sulfuron, bensulfuron, chlorimuron, chlorsu- in agriculture. lfuron, cynosulfuron, cyclosulfamuron. Among the compositions that include, at least, ethametsulfuron, ethoxysulfuron, flazasul - one bleaching herbicide B5) and those that are especially furon, flupirsulfuron, foramsulfuron, the most preferable according to the invention, one in particular - sulfuron , imazosulfuron, iodosulfuron, grinding of the invention refers to those compositions, zosulfuron, metsulfuron, nicosulfuron, which, as a bleaching herbicide 55), include spol-oxasulfuron, primemisulfuron, prosulfuron, according to formula II, preferably in combination with 3-pyrazosulfuron, rimsulfuron , sulfometuron, phenyluracil of formula Ia or Ir. In this regard, sulfosulfuron, thifensulfuron, triazulleni, preference is given to those compositions that furon, tribenuron, trifloxysulfuron, tri- include a compound of formula II, in which the variables 28-83 are flusulfuron, tritosulfuron, propoxycar- independently of each other and especially better together, bason, flucarbazone, imazametabenz, imazamox, take the following meanings: imazapic, imazapyr, imazaquin, imazetapyr, cloransu - BZ is a halogen, C-Ca-alkyl, C1-C4-lam, diclosulam, florasulam, flumetsulam, me-alkylthio, C1-C.-alkylsulfinyl or C1-C4- tosulam, penoxsulam, bispyribac, pyribenzoxime, alkylsulfonyl, preferably halogen or C-Ca-alkyl and pyriphthalide, pyrithiobac, pyriminobac; methyl or chlorine is best;

VZ) atrazine, cyanazine, simazine, terbuthylazine, B? is a heterocyclic radical, vihexazinone, metamitron, metribuzin, amicarbazone, selected from the group including: isoxazol-3-yl, isoxachloridazone, chlorbromuron, chlorotoluron, diuron, zol-b-yl and 4,5-dihydroisoxazol- Z-yl, where the three known isoproturon, linuron, metabenzthiazuron, propanil, chenich radicals can be unsubstituted or mono-bromoxynil, ioxynil, bentazone, pyridate, diphenso- or disubstituted by halogen, C-C-alkyl, C1-C4- quat, diquat, paraquat; alkyl or C1-C4-haloalkyl, in particular p4) acifluorfen, fluoroglycophen, haloisoxazol-b5-yl or 4,5-dihydroisoxazol-3-yl, which phen, lactophen, oxyfluorfen, fluazolate, pyra- can be substituted as indicated above, it is better flufen, cinidon-ethyl, flumiclorac, flumioxa - with one or two C-Ca-alkyl, in particular mezine, fluthiacet, oxadiazone, oxadiargyl, rear groups, for example, 4,5-azafenidine, carfentrazone, sulfentrazone, pen- dihydroisoxazol-3-yl or 3-methylisoxazol-5-yl; toxazone, benzphendisone, butafenacil, pyraclonil, B? represents a halogen, C1i-Ca-alkyl, C1-Ca4- profluazole, flufenpyr, nipyraclofen; alkylthio, C1-C.-alkylsulfinyl or C1-C4-p5) norflurazon, diflufenican, picolinafen, alkylsulfonyl, preferably C-C--alkylsulfonyl. | and beflubutamide, fluridone, flurochloridone, flur - preferably methylsulfonyl; tamone, mesotrione, sulcotrione, isoxachlortol, B! is hydrogen; isoxaflutol, benzofenap, pyrazolinate, pyrazol-B": represents Ci1-Ca-alkyl; xyphene, benzobicyclone, clomazone, 4-(3- VAZ represents hydrogen or Ci-C.--alkyl, especially trifluoromethylphenoxy)-2- (4-trifluoromethylphenyl)- hydrogen pyrimidine, (2-chloro-3-(4,5-dihydro-3-isoxazolyl)-4- Among them, preference is given to those composi- (methylsulfonyl)phenyl 1-methyl-1H-thium, including compounds II in combination with 3-pyrazol-4-yl)umethanone, III-(4,5-dihydro-3-phenyluracil of the formula Ia or II. isoxazolyl)-2-methyl- 4-(methylsulfonyl)phenyl)(5- As active compounds C, compositions according to hydroxy-1-methyl-1H-pyrazol-4-ylumethanone, (2-chloro) of the invention especially preferably include, with- 3-(3З- methyl-5-isoxazolyl)-4-namely, one of the compounds listed below: be-(methylsulfonyl)phenyl|(5-hydroxy-1-methyl-1 H- noxacor, cloquintocet, dichlormid, fenchlorazole, pyrazole-4-ylumethanone and (5-hydroxy-1-methyl-1H-fenclorim, fluxofenim, furilazole, isoxadi-pyrazol-4-yl)|2-methyl-3-(3-methyl-5-isoxazolyl)-4-phen , mefenpyr, 2,2,5-trimethyl-3-(dichloroacetyl)-(methylsulfonyl)phenyl)methanone; 1,3-oxazolidine, 4-(dichloroacetyl)-1-oxa-4-

azaspiro(4.5|decane and oxabetrinil and/or their derivatives - propoxycarbazone, flucarbazone, imazametabenz, tnu in agriculture salt and/or, in the case of - imazamox, imazapic, imazapyr, imazaquin, imazethapyr, to compounds having the COOH group, agronomically methosulam, diclosulam, florasulam, penoxsu- an acceptable derivative, lam, pyriphthalide and pyriminobac and, if desired, an-

Particular preference is given to those binary and tidot C), in particular selected from the group that include trinary compositions, which include furilazole, fenclorazole, cloquintocet, no, one 3-phenyluracil of formula I as an active agent, isoxadifen and mefenpyr. onion A and at least one herbicide selected from In another particularly preferred embodiment of classes B1)-015), and, if acceptable, one or more contain Z-phenyluracil form-

Here and below, the term "binary compositions" includes I, especially formulas Ia or Ir, in combination with tea compositions containing one or more, at least one and especially exactly one herbicide - example 2 or 3, active compounds A and one or a weakly active compound from group 53), in particular more, for example 2 or 3, herbicides B or one wound from the group including atrazine, cyanazine, or more, for example 2 or 3, antidotes C. terbuthylazine, amicarbazone, chlorotoluron, diuron, accordingly, the term "ternary compositions" includes isoproturon, metabenzthiazuron, propanil, bromo- compositions containing one or more, for example, cyanyl, ioxynil and paraquat and, if desired, antido- 2 or 3, active compounds A, one or more, especially C), in particular selected from the group including example 2 or 3, herbicides B and one or more, furilazole, fenclorazole, cloquintocet, isoxades - for example 2 or 3, antidotes C. fen and mefenpyr

In binary compositions containing at least one Z-phenyluracil of formula I! as component A of the invention, preference is given to those compositions and at least one herbicide B of the related invention, containing Z-phenyluracil formation of active compounds A.B is usually found in I, especially formulas Ia or II, in combination with in the range from 1:500 to 101, preferably in the range from at least one and especially precisely one herbicide - 1:100 to 10:1, in particular in the range from 1:50 to 1071 and a bottom-active compound from group 55), in particular select - the best in the interval from 1:25 to 5:1. wound from the group including diflufenican, picoli-

In binary compositions containing prynaimnafen, mesotrione, sulcotrione, isoxaflutol, 4-no, one Z-phenyluracil of the formula | and, at least, (3-trifluoromethylphenoxy)-2-(4- one antidote C, the mass ratio of active trifluoromethylphenyl)pyrimidine, (2-chloro-3-(4,5- compounds A:C is usually in the range of dihydro-3 -isoxazolyl)-4--"methylsulfonyl)phenyl)(5- 1:100 to 10:11, better from 1:50 to 1071 and in particular in hydroxy-1-methyl-1H-pyrazol-4-ylumethanone and I3-( 4,5- intervals from 1:25 to 5:1. dihydro-3-isoxazolyl)-2-methyl-4-

In ternary compositions containing 3-(methylsulfonyl)phenyl)(5-hydroxy-1-methyl-1H-phenyluracil of formula I as component A, at least pyrazol-4-yl)umethanone and, if desired, antidote C) , no, one herbicide B and at least one antidote C, in particular selected from the group including furilazole, corresponding mass ratios of the components fenclorazole, cloquintocet, ioxadifen and mefen-

A:B:C are usually in the interval from 10:11 pir. to 1:500:10, preferably from 10:1:1 to 1:100:10, in particular In another particularly preferred embodiment, from 10:1:1 to 1:50:1 and best from 5:11 to 1: 25:5. finding, preference is given to those compositions that

In these ternary compositions, mass ratio of the invention, containing 3-phenyluracil formulation of herbicide B to antidote C, I, especially of formulas Ia or Ir, in combination with is used in the interval from 50:1 to 1:10. at least one and especially exactly one herbicide-

In a particularly preferred embodiment of the invention, a bottom-active compound from the group rb), in particular, preference is given to those compositions of this wine with glyphosate and, if desired, antidote C), in particular, the course containing 3-phenyluracil of the formula I, specially selected from group including furilazole, fennel of formulas Ia or II, in combination with at least clorazole, cloquintocet, isoxadifen and mefenpyr. one and especially precisely one herbicidal- In another, especially better embodiment, an active compound from the group Br1), in particular selected du, preference is given to those compositions of this invention from the group that includes clodinafop, diclofop, fe- of the invention, which contain 3-phenyluracil of the formula |, noxaprop, fenoxaprop-P, profoxidim, se- especially formulas Ia or IB, in combination with prinitoxidim, tepraloxidim and tralkoxidim and, if I have one and especially precisely one herbicide - preferably, antidote C), in particular selected from the group, an active compound from group Bb7), in particular glufo, which includes fenclorazol, cloquintocet, isoxadizinate and, if desired, antidote C), in particular fen and mefenpyr. selected from the group including furilazole, phen-

In another particularly preferred embodiment, viclorazole, cloquintocet, isoxadifen and mefenpyr. invention, preference is given to those compositions of this In another, especially better embodiment of the invention, containing Z-phenyluracil formula, preference is given to those compositions of this I, especially formulas Ia or II, in the combination according to the invention, containing C -phenyluracil of formula I, with at least one and especially precisely one herbicide, especially of formulas Ia or IB, in combination with a highly active compound from group p2), in particular selectable by one and especially precisely one herbicide from the group that includes amidosulfuron, an active compound from group p9), in particular pendimechlorsulfuron, foramsulfuron, iodosultaline and, if desired, antidote C), in particular furon, mesosulfuron, metsulfuron, nicosulfuron, selected from the group including furilazole, fenfuron, primesulfuron , prosulfuron, rim-clorazol, cloquintocet, isoxadifen and mefenpyr. sulfuron, sulfosulfuron, tritosulfuron,

In another especially preferred embodiment, among the compositions according to the invention, preference is given to those compositions of the invention, especially those compositions of the invention containing the 3-phenyluracil formula, the compositions of the invention, which include "3- or I, especially the formulas Ia or Ir, in combination with phenyluracil of formula I, especially formulas Ia or at least one and especially precisely one herbicide-Io, in combination with at least one and especially precisely active compound from group 010), in particular preferably one herbicide- an active compound selected from the group including acetochlor, butachlor, one from the group including tralkoxide, profok-dimethenamid, dimethenamid-P, metolachlor, 5-sidim, fenoxaprop, fenoxaprop-P, imazamox, metolachlor, pectaxamide, pretilachlor , flufena- imazethapyr, nicosulfuron, atrazine, diuron, isoprocet, mefenacet and fentrazamide and, if desired, turon, paraquat, cinidone-ethyl, picolinafen, sul- antidote C), in particular selected from the group that cotrione, glyphosate, glufosi nat, pendimethalin, di- includes 2,2,5-trimethyl-3-(dichloroacetyl)-1,3- methenamide, dimethenamid-P, acetochlor, oxazolidine, dichlormid, furilazole, oxabetrinil, metolachlor, 5-metolachlor, isoxaben, dichlor - fluxofenim, benoxacor, fenclorim and nu4-prop, dichlorprop-P, dicamba, 2,4-0, diflufenzo- (dichloroacetyl)-1-oxa-4-azaspiro(4.5|decane. pir and/or one antidote C) selected from the group,

In another particularly preferred embodiment, the above comprises mefenpyr and benoxacor. invention, preference is given to those compositions given in the preferred or particularly preferred compositions of the invention containing 3-phenyluracil formulations, which are described above, herbicides B), as well as I, especially formulas Ia or II, in combination with as well as antidotes C) can be used in the form of at least one, and especially exactly one, herbicide-acceptable in agriculture salts or a bottom-active compound from the group p13), in particular a choice- in the form of their acceptable in agriculture wound from the group that includes 2,4-O0, dichloroprop, derivatives as described above. The mass ratios of dichlorprop-P, mecoprop, MCPA, mecoprop-P, di- of individual components in the compositions are within the limits defined above. Among especially pertidot C), in particular those selected from the group including important compositions, special preference is given to furilazole, fenclorazole, cloquintocet, those compositions of this invention in which the variables K!-isoxadifen and mefenpyr are given. In" take predominant values, mainly

In another particularly preferred embodiment, the values are particularly predominant. In particular, preference is given to those compositions of 3Z-phenyluracil of formula Ia or of the invention containing 3Z-phenyluracil of formula IB as defined above. or I, especially formulas Ia or II, in combination with Preference is given, for example, to those compositions - at least one and especially exactly one herbicides, which, as an active compound A), include a phenidin-active compound from group p14), in particular diluracil 1.1 and, as an additional active compound, recho-flufenzopyr, and if desired, antidote C), wines listed in one row of Table 2, in particular selected from the group including furyl- (compositions 1.1-1.346). Mass ratios of oxol, fenclorazole, cloquintocet, isoxadifen and other components in compositions 1.1-1.346 znacho-mefenpyr. occur within certain limits, in the case of binaries

In another particularly preferred embodiment of mixtures of phenyluracil 1.1 and herbicide B) for example, preference is given to those compositions of the ratio 1:1, in the case of binary mixtures of the phenyluracil invention, containing 3-phenyluracil of formula 1.1 and antidote C for example 11, and in the case of trila I, especially formulas Ia or Ir, in a combination of natural mixtures of phenyluracil 1.1, herbicide B and at least one and especially precisely one herbicide - antidote C, for example, 1:1:1,2:1 :1, 1:21, 1:51 or a bottom-active compound from the p15 group), in particular, select 1:5:2. wound from the group including cinmethylin, oxacyclomefon and otriaziflam and if desired, Table 2 antidote C), in particular selected from the group that Como includes furilazole, fenclorazole, cloquintocet, isoxadifen and mefenpyr. | ЛЯ ф|клодилафоп./://///:/2О/Й 777771

In another particularly preferred embodiment of the invention, preference is given to those compositions of this invention containing 3-phenyluracil of formula I, especially of formula Ia or II, in combination with at least one antidote C) , in particular selected from the group including furilazole, fenclorazole, cloquintocet, isoxadifen and mefenpyr. | ЛЯ фидиклордоп.///777/Ї777777771111111с1сС

In another especially preferred embodiment of the (12 |diclofop. 00101011... |cloquintocet invention, preference is given to those compositions and of the invention, containing 3-phenyluracil formula I, especially formulas Ia or II, in combination with at least one and especially precisely by one antidote C), in particular selected from the group including 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine, dichlormid, furilazole, oxabetrinil, fluxofe-C 18o |fenoxaprop 20202020 ( " Mefenlo : : | 21 | fenoxaprop?.///////Ї-.-//:/SS. nim, benoxacor, fenclorim and 4-(dichloroacetyl)-1-oxa-4-azaspiro|y. 5 Dean.

ee Be

Continuation of table 2 about Ifluazhfa. 7-1--------4 (1706 | meyusulfuron. 1-7 77107 niosulfuron 7771- lov oxasulfuron 1-3 71709 primesulfuron 1-7 31 | fpuazifov. 1-20 171 | prazosulfuron 3731-13 l12 rimsulfuron 7772 25222252. /71-- halokyfopi 1-22 71221 | propoxycarbazone 1-3 le | Fluarban 777731 l23 mazametabeni 75555531 l2ya Imazamas 1-3 tab o quizalofop Z 5 5 5 2 2 2 2 2 2 2 2 51 5 20202020 | 426 | mazar 331 -- lei mazavn o Z 12 2 OZ lov o mazialr Z 5 55 1-- 129 kloransulam 77777771

BIKVIVALOFOPV 77777100 (231 | Floragules 77771-73 182 O Flumetsum 7777.1 LAZ Metsulas 7775 5 5 5 52525251 «5 184 Parisums 7777777771 R 3

BV kedy 25555221 238 Uses 771-------- ve cloprokidim 77777717 (1239 smamn /31---- and Iepraloidim 7771-1743 |terbumlamn 1-7 va ralyuydim 77777771 (1244 |ekamnyuni 7771-73 165 amidosulbruron 3331-1245 |methamitron 1-------07 lav o metribumno 9.955251 147 amiarbazon7 7777 lava ochloridazn at 77777770

Because Ochlorotoluron 77777777 331-- Facino sulfuron 55551-1255 Propane 301071 6 cyslososulfamuron 353555531 256 Bromobinil 1-7 777 Tetametmethuron 17777771 in fluprsulfuron 7771-77 1760 |difenyuat 1-7 stvi foramsulfuron 33357711 00461 diva 07771 le?paravat 75 551---- le |Fluorothiofen /1----- lev |lacofen 775551-----4- 13 vu Halosulfuron 55 5 52555531 01010107 | 1767 | oxyflurfeni 1-7 lev o fluazolate 7777771 70 puinidonetia 77555551.

Sl? |flumoxacin 77727771 78 mazosulfuron 7771-3301. 1773 |fluivcet 1-7 tva iodosulfuron 7771-1274 |okadan 1--------- luv okadivril 771-- 776 azafendiyan 5 5 525551------- 177 carfentrano 77777771

Glta Ipentokavn 777771 i180 |benzfendizone.//:// OЇ. 111 | 1242 |dimethenamid-P | fluxofenim./ 1181 |butafenacil.:.:-//// SG. | 1.243

Continuation of table 2 of yiva

Compounds i246 |metolachlor.://:/ | -..7777777771111

Herbicide B) 1247

T182 |pyraklonl./////777771717111111111111111111111с1С | 1.248 1183 |profluazol./-/:/ /.://...///// (|| 1.249 t2184 |Fflufenpyri 3331 i250 |metolachlor,.i | fluxofenim. ZO i185 |nipiraklofen.i 7711111 11111111 | 1251 tl86 | norflurazon 3333311 T2v2 | metolachlor. 0 | fenclorim.

T187. 1254

T189 |beflubutamd. 333331 1255 и190 |fluridon.y.//./:/ЖУЦССССССШ1.117171717171111111с | 1256 il91 |flurochloridone././-://-:/ОЙ|-..///111 | 1257 |b-metolachlor, | fluxofenim./ t3192 | flurtamonium 33331 1258 i193 | mezotrisn.////:./СЩ1..11111111111111с | 1259 |B-metolachlor, |fenchlorim./ и2194 |sulcotrisn 33333331 и260 |petoxamid.и 77771111 и195 |isoxachlorotol.0////: C 1.111111 | 1261 | pretilachlor.//://O/ 1-11 196 | isoxaflutol..7/:/ FG 1262 1197 | benzofenap. 33333331 1263 1198 |pyrazolnate////::сс111СЩ111111111111111с | 1264 1199 |pyrazoxifen.//-://-: || 1265 |pretilachlor,i | fluxofenim.7 1200 | benzobicyclone 33333331) 1266 201 | clomazone./////7777777111111111111111111111s | 1267 |pretilachlor,. 0 |Ffenchlorim//

Гг-хпор-3-(4,5-dihydro-3-і268 | flupoxam. 71111111 isoxazolyl)-4- 1269 | propachlor././.:/ // 1-11 1202. | (methylsulfonyl)phenyl)(5-1270 |propiochlor.//:/://O/ 1-11 hydroxy-1-methyl-1H-pyrazole-4- T271 |tenlchlor.:«//its11 1-11 ipumethanone і272 |flufenacet//-:// |/!-

IZ-(4,5-dihydro-3-isoxazolyl)-2-1273 |mefenacet//-://:/ / |-...77777111 methyl-4- 274 |fentrazamd.y//-/:// ..GSІ1-.77777711111111С 1203 | (methylsulfonyl)phenylI(5-і275 |kafenstrol./:/ /://./.../ДГ/(|-71 in hydroxy-1-methyl-TNpyrazol-4-і276 |indanophan.././. ///ОЇ1-..111717171711111111C ipumethanon T277 |dihlobenl././-.-://.:/.../ Ї-..777777777111111 osa ї278 |chlortamide.ї//-/-:// Her. methysulffo | 7279 | isoxaben.////11111111 12111111 1204. | (methylsulfonyl)phenipu in; tota. 22222221 hydroxy-1-methyl-1H-pyrazol-4- TVi 5 V Y---ASHISHSHSH yl)umethanone : with 4-yl) (2-methyl-3-(3-methyl-5-.dichloroprop-1205 isoxazolyl)-4- 1284 | MSRA I 77777111 methylsulfonyl)phenyl|methanone 1285 | MSRV I 1206 | glyphosate 30303000 T286 | mekoprop./////777777777С1Й-111111111111с1С 1207 | glufosinate 333331. and smeylrotye 2 ОЗОС0СЦНС L I «О I I - - 5

T208 |benfluraln. 333331, | 1288 dicamba 1291 |cloprald. 77777771 Sh|1111111111111 t212 |oryzaln 30303031, y292 |fluroxypr.////-:(;!;86/Г/Г/ЗГ/ ||. t213 |pendimetal 1-7 Tv |pishlvram. 11111101 1214 |trifluralin 33333313 1294 |triclopr.///////7777777717111111 11111111

T215 Ipropizamd. 331-1 и295 |benazoln././.:(/1.Ї1-..11111111111 и216 |acetochlor. 3303131. 1296 |diflufenzopr.//-/-/:////// 1217 1297 |bromobutid./ /////////777111С 1218 1298 |zinmethyln 77777771 Ш|111111111111с1 1219 1299 |methyldimron.///-/-://///Ш|-.1117171717111111 1220 |acetochlor. 3333... |fpuxofenim 1 i.300 | oxacyclomefon. 1-11 1221 301 | tridazirlam. apachlor

T224 | bugachlor. 30303031 1304 Х- 77171711 |cymethrinil/ 1225 Х305Х1- ХХ7Х790Ь6Х.7Х7ХХХХ7р1р11 |dichlormd!/ 1226 1306 Х- 77777771 |Ydicyclonone// 1227 1307 Х- 77171711 | 3333... | fpuxofenim 1 1308 Y- 77171711 |fenchlorazol/Х7/ 1229 ТЗОВ И 77777777 |Ffenchlorim/// y230 |butachlor. (3011111... | Ffenclorim. (I | 1310 ЙТ- 77777717 | Fflurazol//

T231 Idymetenamd 33333310 1311 Y- 77777717 | fluxofenim.7/ 1232 18312 Y- 77771711 | furilazole/7/ 1233 1313 1-71 | isoxadifen.// H 1234 1314 Y- 77717171 | mefenpr// 1235 | dimethenamd. 5555 |fpuxophenim. 1 13151-.7777717Х7юЮюЮююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююююЮюююююю. naphthoic anhydride) 1237 |dimethenamd 5... |fenchlorim. (| 1317 Y- 77171711 Ooxabetrinil//

T238 |dimethenamd.? -:/ (1-11 | 2,2,5-trimethyl-3- 1239 1318 (dichlor- . 1.240 tat dur ethyluxazopidin

Pr | 7319 |(3-trifluoromethylphenoxy)2- | (

trifluoromethylphenyl)pyrimidine - the main active compounds, i.e. active compounds,

Continuation of Table 2 that can be protonated are, in particular, chlorides,

Compound 7 bromides, sulfates, hydrosulfates, methyl sulfation of Me Herbicide B) Antidote C) you, dihydrophosphates or hydrophosphates of active 2,2,5-trimethyl-3-compounds, mentioned above. If active compounds, 1.320 | acetophores of wormwood are listed in Table 2, have a carboxyl group, 22 B-trimethyp-3- they, of course, can also be present in the 1.321 (diphor-acetyl)- form of their agriculturally acceptable 1,3-oxazolidine derivatives, in particular in the form their methyl-and dimethylami-2,2,5-trimethyl-3- and p-di-ipyls and 1822 | dimethenamid (dipor-acetyl)-dives, In the form of their anilides or 2 xporanilides, and also in the 1,3-oxazolidine form of their methyl, ethyl, propyl, isopropyl, 2,2,5-trimethyl-3-propyl, butyl, isobutyl , pentyl- 1.323 | dimethenamid-P (diporgacetimthyl, hexyl, isooctyl, methoxyethyl, z-trimethyl ethoxyethyl, butoxyethyl or thioethyl- and tri-oxazolidine- and 1,3-oxazolidine. Preference is also given to compositions 2.1-18 2,2,5-trimethyl- 3- 2.346, which differ from the corresponding compositions | Z-metolachlor poyucoracetnm 1.1-1.346 only in that phenyluracil 1.1 is replaced by 2,2,5-trimethyl-3- phenyluracil 1.2. 1.326 | pretilachlor (diphor-acetyl)- Advantage is also given to the compositions 3.1-1,9-oxazolidine 3.346, which differ from the corresponding compositions 2,ah-trimethyl-3-1.1-1.346 only in that phenyluracil 1.1 is replaced by 1.327 And 1,3-oxazolidinium on phenyluracil 1.3. 1.328 Preference is also given to compositions 4.1- 1.329 4.346, which differ from the corresponding compositions 332 on phenyluradil 1. 1.333 |petoxamd | fenclorim//|

And 4-(dipore-acetyl)- 5.346, which differ from the corresponding compositions 1.334 | pentaxamide azathioate BI decane 1.1-1.346 only because phenyluracil 1.1 is replaced by 4-(dichloro-acetypl)- phenyluracil 1.5. 1.335 | acetochlor 1-oxa-4- Preference is also given to compositions 6.1- azaspiro|4.5|-decane 6.346, which differ from the corresponding compositions 1836 | butachlor 1 dichloroacetyl. 1.1-1.346 only by the fact that phenyluracil 1.1 replaces

And azaspiro|4.5| decane on phenyluracil 1.6. and 4-(dichloro-acetyl)- Preference is also given to compositions t4- 1.337 | dimethenamid 1-oxa-4- 7.346, which differ from the corresponding compositions of breath 1.1-1.346 only in that phenyluracil 1.1 is replaced by 1.338 | dimethenamid-P 1-oxa-4-ny on phenyluracil 1.7. azaspiro|4.5|-decane Preference is also given to compositions 8.1- 4-(dipore-acetyl)- 8.346, which differ from the corresponding compositions 1.339 | metolachlor 1-oxa-4- 1.1-1.346 ti o phen and 1.1 will replace azaspirog4.5I-decane 41-11. only because phenyluracil 1. is converted to 4-(dichloroacetyl)- phenyluracil 1.8. 1.340 | b-metol achlor 1-oxa-4- Preference is also given to compositions 9.1- azaspira 4.5| dean 9.346, which differ from the corresponding compositions 1841. | pretilachlor 1 (dipor'acetyl 1.1-1.346 only because phenyluracil 1.1 is replaced by azaspiro(4.5|-decane for phenyluracil 1.9. 1342 |metamphop.////////1С1СЩ111111111111111с | Preference is also given to compositions 10.1- 1.343 10.346 , which differ from the corresponding compositions 1.1-1.346 only in that phenyluracil 1.1 is replaced by

Tzaye |metamifop 7... |mefenpr | /neny on phenyluracil 1-10.

Preference is also given to compositions 11.1-

If the active compounds listed in Table 2, 11.346, which differ from the corresponding composi- have functional groups that can be ionized 1.1-1.346 only where phenyluracil 1.1 is fused, they can, of course, also be present on phenyluracil 1.11. , by them in the form of their acceptable in agriculture - 12 attention is also given to the compositions of 12.1 salts. In the case of acidic active compounds, depending on the corresponding properties, i.e., active compounds that can be deprotonated 1.171945, only mt phenyluracil 1.1 is substituted, in particular lithium, sodium, potassium salts, calcined to phenyluracil 1.12. . 2-hydroxyethylammonium, 2-phenyluracil 1.13. (2-hydroxyethoxy)eth-1-ylammonium, di-(2-hydroxyeth-1-yl)ammonium, benzyltrimethylammonium, benzyl-14.346, which differ from the corresponding compositions

composition 1.1-1.346 only in that phenyluracil 1.1 is replaced by phenyluracil 1.14. Preference is also given to compositions 31.1-. 31.346, which differ from the corresponding compositions

Preference is also given to the compositions 15.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 15.346, which differ from the corresponding compounds composed of phenyluracil 1.31. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.15. Compositions 32.1 are also preferred. 32.346, which differ from the corresponding compositions

Preference is also given to compositions 16.1- tions 1.1-1.346 only in that phenyluracil 1.1 replaces 16.346, which differ from the corresponding compounds composed of phenyluracil 1.32. composition 1.1-1.346 only in that phenyluracil 1.1 is replaced by phenyluracil 1.16. Preference is also given to compositions 33.1-. 33.346, which differ from the corresponding compositions

Preference is also given to compositions 17.1- tions 1.1-1.346 only in that phenyluracil 1.1 replaces 17.346, which differ from the corresponding compounds composed of phenyluracil 1.33. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.17. Compositions 34.1 are also preferred. 34.346, which differ from the corresponding compositions

Preference is also given to compositions 18.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 18.346, which differ from the corresponding compounds composed of phenyluracil 1.34. composition 1.1-1.346 only because phenyluracil 1.1 is replaced by phenyluracil 1.18. Preference is also given to compositions 35.1-. 35.346, which differ from the corresponding compositions

Preference is also given to compositions 19.1- tions 1.1-1.346 only in that phenyluracil 1.1 replaces 19.346, which differ from the corresponding compounds composed of phenyluracil 1.35. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.19. Compositions 36.1- are also preferred. 36.346, which differ from the corresponding compositions

Preference is also given to the compositions 20.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 20.346, which differ from the corresponding compounds composed of phenyluracil 1.36. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.20. Compositions 37.1 are also preferred. 37.346, which differ from the corresponding compositions

Preference is also given to the compositions 21.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 21.346, which differ from the corresponding compounds composed of phenyluracil 1.37. composition 1.1-1.346 only because phenyluracil 1.1 is replaced by phenyluracil 1.21. Preference is also given to compositions 38.1-. 38.346, which differ from the corresponding compositions

Preference is also given to compositions 22.1- tions 1.1-1.346 only in that phenyluracil 1.1 replaces 22.346, which differ from the corresponding compounds composed of phenyluracil 1.38. composition 1.1-1.346 only in that phenyluracil 1.1 is replaced by phenyluracil 1.22. Preference is also given to compositions 39.1-. 39.346, which differ from the corresponding compositions

Preference is also given to compositions 23.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 23.346, which differ from the corresponding compounds composed of phenyluracil 1.39. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.23. Compositions 40.1 are also preferred. 40.346, which differ from the corresponding compositions

Preference is also given to compositions 24.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 24.346, which differ from the corresponding compounds composed of phenyluracil 1.40. composition 1.1-1.346 only because phenyluracil 1.1 is replaced by phenyluracil 1.24. Preference is also given to compositions 41.1-. 41.346, which differ from the corresponding compositions

Preference is also given to the compositions 25.1-tions 1.1-1.346 only in that phenyluracil 1.1 is replaced by 25.346, which differ from the corresponding compounds composed of phenyluracil 1.41. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.25. Compositions 42.1 are also preferred. 42.346, which differ from the corresponding compositions

Preference is also given to the compositions 26.1-tions 1.1-1.346 only in that phenyluracil 1.1 is replaced by 26.346, which differ from the corresponding compounds composed of phenyluracil 1.42. composition 1.1-1.346 only in that phenyluracil 1.1 is replaced by phenyluracil 1.26. Preference is also given to compositions 43.1-. 43.346, which differ from the corresponding compositions

Preference is also given to compositions 27.1- tions 1.1-1.346 only in that phenyluracil 1.1 replaces 27.346, which differ from the corresponding compounds composed of phenyluracil 1.43. composition 1.1-1.346 only in that phenyluracil 1.1 is replaced by phenyluracil 1.27. Preference is also given to compositions 44.1-. 44.346, which differ from the corresponding compositions

Preference is also given to compositions 28.1- tions 1.1-1.346 only in that phenyluracil 1.1 replaces 28.346, which differ from the corresponding compounds composed of phenyluracil 1.44. composition 1.1-1.346 only because phenyluracil 1.1 is replaced by phenyluracil 1.28. Preference is also given to compositions 45.1-. 45.346, which differ from the corresponding compositions

Preference is also given to compositions 29.1- tions 1.1-1.346 only in that phenyluracil 1.1 replaces 29.346, which differ from the corresponding compounds composed of phenyluracil 1.45. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.29. Compositions 46.1 are also preferred. 46.346, which differ from the corresponding compositions

Preference is also given to compositions 30.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 30.346, which differ from the corresponding compounds composed of phenyluracil 1.46. composition 1.1-1.346 only because phenyluracil 1.1 is replaced by phenyluracil 1.30. Preference is also given to compositions 47.1-. 47.346, which differ from the corresponding compositions

composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.47. Compositions 64.1 are also preferred. 64.346, which differ from the corresponding compositions

Preference is also given to compositions 48.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 48.346, which differ from the corresponding compounds composed of phenyluracil 1.64. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.48. Compositions 65.1 are also preferred. 65.346, which differ from the corresponding compositions

Preference is also given to compositions 49.1- tions 1.1-1.346 only in that phenyluracil 1.1 replaces 49.346, which differ from the corresponding compounds composed of phenyluracil 1.65. composition 1.1-1.346 only in that phenyluracil 1.1 is replaced by phenyluracil 1.49. Preference is also given to compositions 66.1-. 66.346, which differ from the corresponding compositions

Preference is also given to compositions 50.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 50.346, which differ from the corresponding compounds composed of phenyluracil 1.66. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.50. Compositions 67.1 are also preferred. 67.346, which differ from the corresponding compositions

Preference is also given to compositions 51.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 51.346, which differ from the corresponding compounds composed of phenyluracil 1.67. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.51. Compositions 68.1 are also preferred. 68.346, which differ from the corresponding compositions

Preference is also given to the compositions 52.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 52.346, which differ from the corresponding compounds composed of phenyluracil 1.68. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.52. Compositions 69.1 are also preferred. 69.346, which differ from the corresponding compositions

Preference is also given to compositions 53.1- tions 1.1-1.346 only in that phenyluracil 1.1 replaces 53.346, which differ from the corresponding compounds composed of phenyluracil 1.69. composition 1.1-1.346 only because phenyluracil 1.1 is replaced by phenyluracil 1.53. Preference is also given to compositions 70.1-. 70.346, which differ from the corresponding compositions

Preference is also given to compositions 54.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 54.346, which differ from the corresponding compounds composed of phenyluracil 1.70. composition 1.1-1.346 only because phenyluracil 1.1 is replaced by phenyluracil 1.54. Preference is also given to compositions 71.1-. 71.346, which differ from the corresponding compositions

Preference is also given to the compositions 55.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 55.346, which differ from the corresponding compounds composed of phenyluracil 1.71. composition 1.1-1.346 only because phenyluracil 1.1 is replaced by phenyluracil 1.55. Preference is also given to compositions 72.1-. 72.346, which differ from the corresponding compositions

Preference is also given to compositions 56.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 56.346, which differ from the corresponding compounds composed of phenyluracil 1.72. composition 1.1-1.346 only because phenyluracil 1.1 is replaced by phenyluracil 1.56. Preference is also given to compositions 73.1-. 73.346, which differ from the corresponding compositions

Preference is also given to compositions 57.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 57.346, which differ from the corresponding compounds composed of phenyluracil 1.73. composition 1.1-1.346 only by the fact that phenyluracil 1.1 is replaced by phenyluracil 1.57. Compositions 74.1 are also preferred. 74.346, which differ from the corresponding compositions

Preference is also given to compositions 58.1-tions 1.1-1.346 only in that phenyluracil 1.1 replaces 58.346, which differ from the corresponding compounds composed of phenyluracil 1.74. 1.1-1.346 only because phenyluracil 1.1 is replaced by phenyluracil 1.58. compositions 2.1-74.346 are within the limits of

Preference is also given to compositions 59.1- defined above, in the case of binary mixtures of phenyl- 59.346, which differ from the corresponding compositions of uracil 1.1 and herbicide B), for example, 1:1, 1:2 tion 1.1-1.346 only in that phenyluracil 1.1 is replaced - or 1:5, in the case of binary mixtures of phenyluracil, the ratio of phenyluracil to phenyluracil is 1.59. 1.1 antidote C, for example, 1:1, 1:22 or 1:51 U

Preference is also given to the compositions of 60.1 case of ternary mixtures of phenyluracil 1.1, 60.346, which differ from the corresponding compositions of herbicide B and antidote C, for example, 1:1:1, 2:11, this 1.1-1.346 only in that phenyluracil 1.1 replaces 1:2:1, 1:51 or 1:5:2. phenyluracil 1.60. In ready-to-use preparations, i.e. in

Preference is also given to compositions 61.1- compositions according to the present invention in fo- 61.346, which differ from the corresponding compositions of means of protection of agricultural crops, this 1.1-1.346 only in that phenyluracil 1.1 replaces components A and B and/or C, in suspended, immune to phenyluracil 1.61. solution or dissolved form, can be pre-

Preference is also given to compositions 62.1- placed in a composition together or separately. The forms of 62.346, which differ from the corresponding composi- the use depends entirely on the intended 1.1-1.346 only by the fact that phenyluracil 1.1 replaces the use. phenyluracil 1.62. Compositions according to this invention,

Preference is also given to the compositions 63.1- can be used, for example, in the form of 63.346, which differ from the corresponding compositions- indirectly sprayed aqueous solutions, por- 1.1-1.346 only in that phenyluracil 1.1 slurry, suspensions, as well as highly concentrated neny on phenyluracil 1.63. water, oil or other suspensions or dispersions

seeds, emulsions, dispersions in oil, pastes, duets, glycol ethers, alkylaryl polyether alcohols, isotomes for dispersing or granulates, with the help of decyl alcohol, fatty alcohol condensates / by spraying, spraying, dusting, ethylene oxide, ethoxylated castor oil, throwing or watering. The forms of using polyethylene oxide alkyl ether or polypropylene depend on the intended application; in any case, they must guarantee maximum lauryl alcohol, sorbitol esters, practically possible distribution of active compounds. solutions of lignosulfite or methylcellulose.

Depending on the form in which they are ready for use. solid medium. only liquid or solid carriers, if appropriate. Granules, for example, coated granules, surfactants and, if appropriate, granules and homogeneous granules, may be additional excipients that are generally accepted, by binding active ingredients for the development of means of protection for rural guests with solid carriers. Solid mineral carriers of gift cultures. A person skilled in the art, such as silicas, silica gels, silicates, is sufficiently familiar with the recipe talc, kaolin, limestone, lime, chalk, bolus, loess, rounds of such compositions. clay, dolomite, kieselguhr, calcium sulfate, sulfur

Ready-to-use preparations include magnesium phate, magnesium oxide, ground synthetic components A and B and/or C and auxiliary substances, which substances, fertilizers such as ammonium sulfate, phos- are generally accepted for the development of means of protection, ammonium nitrate, ammonium nitrate, urea , and simple agricultural crops, where auxiliary ducts of plant origin, such as flour substances may also include a liquid carrier. coarse grinding of bread grain, coarse flour

Acceptable inert fillers with the function of grounding tree bark, wood flour and sawdust are, strictly speaking: oil fractions of coarse grinding of nut shells, cellulose products from medium-boiling to high-boiling powders, or other solid carriers. such as kerosene and diesel oil, in addition. Concentrations of active compounds in ready-to- coal tar and vegetable oil or application preparations can vary in me- of animal origin, aliphatic, cyclic and horror of wide ranges. Basically, compositions of aromatic hydrocarbons, for example, paraffins, tet- include from 0.001 to 9895 by weight, preferably from rahydronaphthalene, alkylated naphthalene and their derivatives, 0.01 to 9595 by weight, of active ingredients. Acty-alkylated benzenes and their derivatives, alcohols, such as the mentioned ingredients are used with a purity of 9095 ethanol, ethanol, propanol, butanol and cyclohexanol, up to 10095, better from 9595 to 10095 (according to NMR spectra, ketones such as cyclohexanone, strongly polar disparity). factors, for example, amines, such as M- Compounds according to the invention can, na- methylpyrrolidone, and water. example, formulated in the composition in such a way

Aqueous forms of application can be obtained by: mani from emulsion concentrates, suspensions, pastes, | 20 parts by weight of the active compound or wettable powders or granules, which are dissolved in the dissolved mixture of active compounds in water, by adding water. For a mixture consisting of 80 parts by weight of alky- production of emulsions, pastes or dispersions in oil, benzene, 10 parts by weight of adduct 8-10 active compounds from A) to C) by themselves or grinding ethylene oxide up to 1 mol -M- made in oil or a solvent, can be homo- monoethanolamide of oleic acid, 5 parts by genized in water with the help of a wetting agent, calcium dodecylbenzenesulfonate and 5 parts, substances to increase stickiness, tin by weight of the adduct 40 moles of ethylene oxide to 1 dispersing agent or emulsifier. Alternamol of castor oil. By pouring the solution into a container, you can prepare concentrates that are 100,000 parts by weight of water and are well distributed from the active substance, the wetting agent, or obtain an aqueous dispersion containing 0.029 of a substance to increase stickiness, the dispersing agent by weight of the active ingredient. th agent or emulsifier and, if desired, a solution of 20 parts by weight of the active compound or oil or oil, so that these concentrates of the concentrated mixture of active compounds dissolve in were suitable for dilution with water. mixture consisting of 40 parts by mass of cyclic

Acceptable surface-active substances are loghexanone, 30 parts by weight of isobutanol, 20 parts by weight of alkali metal salts, alkaline earth salts - parts by weight of an adduct of 7 moles of ethylene oxide of metals and ammonium salts of aromatic sulfo- up to 1 mole of isooctylphenol and 10 parts by weight acids, for example, ligno-, phenol-, naphthalene-and adduct of 40 moles of ethylene oxide to 1 mole of casto-dibutylnaphthalenesulfonic acid, and fatty oil. Pouring a solution into 100,000 parts of acids, alkyl- and alkylarylsulfonates, alkylsul- by weight of water and distributing well, an aqueous dispersion containing 0.0295 by weight of fatty alcohols and salts of sulfated hexa-, heptative ingredient. and octadecanols and glycol ethers of fatty alcohols, PI 20 parts by weight of the active compound or condensates of sulfonated naphthalene and its similar mixture of active compounds are dissolved in days with formaldehyde, condensates of naphthalene or a mixture consisting of 25 parts by weight of cyclo-naphthalene sulfonic acids with phenol and formologexanone, 65 parts by weight of the naphtholdehyde fraction, polyethylene oxide octylphenol ether, products with a boiling point of 210-280"C and 10 parts of ethoxylated isooctyl-, octyl- or nonylphenol, by weight of the adduct of 40 moles of ethylene oxide to 1 alkylphenyl polyglycol ethers , tributylphenylpolymol of castor oil. Pouring the solution into

100,000 parts by weight of water and distributes well. The required rate of application of phenyluracil means that an aqueous dispersion containing 0.029 goes mainly in the range from O0.1g/ha to by weight of the active ingredient. 1kg/ha and better in the range from 1g/ha to 500g/ha or

IM 20 parts by weight of the active compound or from 5g/ha to 500g/ha a.y. of the considered mixture of active compounds is completely mixed. The application of sodium sulfonate, 17 parts by mass, can be performed with the generally accepted solution of the sodium salt of lignosulfonic acid (with spraying, using, for example, water from a spent sulfite solution and 60 parts as a carrier, and the dosage of the liquid sprayer is by mass of powdered silica gel, and from about 100 to 1 Obol/ha (for example, the mixture is ground in a hammer crusher. It is good from 300 to 400 l/ha). It is possible to use herbi- by dividing the mixture into 20,000 parts by mass of vocicidal compositions by the method of small amounts and spods, obtain a spray mixture containing an "ultra small amount" is, for example, their 0.195 by weight of the active ingredient. application in the form of microgranules.

M 3 parts by weight of the active compound or Composition according to this invention of the mixture of active compounds in question is mixed with 97 parts by weight of finely ground kaolin suitable for combating common harmful substances. plants in useful crops, especially cereals

A powder containing 390 by mass of wheat, barley, oat, corn, tive ingredient is obtained. soybeans, sorghum, rice, rapeseed, cotton, potatoes, dry

MI 20 parts by weight of the active compound or beans, ground nuts or in crops of perennials of the considered mixture of active compounds completely mixed crops. In another embodiment of the invention, they are useful when mixed with 2 parts by weight of dodecylbenzenes to combat all vegetation, i.e. they use calcium dilphonate, 8 parts by weight of polyglycoide as a total herbicide. Moreover, in another fatty alcohol kol ether, 2 parts embodiment of this invention, compositions are useful for controlling unwanted vegetation in forestry. of urea-formaldehyde condensate and 68 parts- In addition, it may be useful to use by weight of paraffin mineral oil. compositions according to the invention together as a mixture

A stable oil dispersion is obtained. with other products for the protection of agriculture

MI 1 part by weight of the active compound or donor cultures, for example, with pesticides or the considered mixture of active compounds is dissolved in agents for combating phytopathogenic fungi - a mixture consisting of 70 parts by weight of cicama or bacteria. It is also important to displace loghexanone, 20 parts by weight of ethoxylated with solutions of mineral salts used isooctylphenol and 10 parts by weight of ethoxylated for the treatment of food and castor oil. Get stable trace element deficiencies. You can also add emulsion concentrate. non-phytotoxic oils and oil concentrates.

MI 1 part by weight of the active compound or the composition according to the invention can be dissolved in the skin of the mixture of active compounds in question and used on cultivated plants, which mixtures consisting of 80 parts by weight are resistant to one or more herbicides thanks to logexanone and 20 parts by the mass of Umeyo!? EM 31 genetic engineering or breeding or which are resistant to (nonionic emulsifier, based on ethoxylated insect attack due to genetic engineering or breeding. castor oil). They receive a stable concen- Suitable are, for example, cultivated plants that are rat emulsion. resistant to herbicide EP5P synthase inhibitors,

Components A and B and/or C can be precursors, such as, for example, glyphosate, to herbicides added to the composition together or separately. glutamine synthase inhibitors, such as e.g.

Components A and B and/or C can be applied to glufosinate, protoporphyte herbicide inhibitors together or separately, at the same time or after rinogen-YX oxidase, such as, for example, butafevno, before, during or after the emergence of plants. nacil, or to herbicide AG 5 inhibitors, such as

If the active compounds A and B and/or C are less well-for example, imazametabenz, imazamox, imazapic, bre are transferred by some cultivated plants- imazapyr, imazaquin, imazetapyr, or cultivated yeasts, it is possible to use methods of application, lines that, as a result of the introduction genes for Vi toxin, in which herbicide compositions are sprayed by genetic modification, are resistant to attack by sprayers in such a way that some insects. the leaves of sensitive cultivated plants to the maximum Unexpectedly, the compositions according to the invention are not affected to the extent possible, while the active du including at least one phenyluracil compound reaches the leaves of undesirable plants that formula I and at least one herbicide B, have growing from below, or open surface soil better herbicidal activity against pests

The required rate of introduction of the composition of the active plant than the expected herbicidal activity of the compound, i.e. A and B and/or C without auxiliary com- individual compounds. In other words, the joint application depends on the combination of the location of phenyluracil I and herbicide B leads to plants, on the stage of plant development, on the climate - increased activity against harmful plants in the conditions of the location, where the understanding of the synergistic effect is applied ( synergism). From this composition, and from the method of application. Basically, mixtures, on the basis of individual products, for example, the application rate of A and B and/or C is to be used with a lower dosage - 0.001 to 3 kg/ha, better from 0.005 to 2 kg/ha and in particular to achieve a herbicidal effect, compare - from 0.01 to 1 kg/ha of active substance (automatic but with separate products. sprayer (a. r.)).

Unexpectedly, the compositions according to the invention with the method of obtaining free acids PI-evidone, which in addition to phenyluracil I and, if accepted from the prior art or can be clearly, herbicide B, include an active compound that can be obtained in a similar way . group C, are better tolerated by useful plants than the corresponding phenyluracil I! or corresponding to the corresponding acids, also the previously known mixture of phenyluracil "with herbicide B without an active combination of techniques or standards from group C can be performed by these methods for the hydrolysis of complex esters

Z-phenyluracils of formula I can be obtained - see also: Kosiep5ki, "Rgoiesiipd sgocrv", Tpiete ni methods A-O, described below, which are subject- Mepad 1994; Spteepe, MUUtsiv, Rgoiesiipd dgotsre ip tom earlier (applications PCT/ER 01/04850). What is ogdapis 5upipevii, UMPeu 1999; Noibrep-M/eui, before obtaining certain compounds, Meipodep deg ogdapizspep Spetie (Methods Organi- reference to examples (applications PCT/ER 01/048501. chnoy Khimiya), vol. E5, part I! (1985), p. 223 and on -

Compounds that are not sufficiently disclosed in this pre-purchase. acid, such as 2-chloro-5-I3,6- bom. dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl)-

In the schemes below, O takes the following value: 1(2H)-pyrimidinyl|-4-fluorobenzoic acid (СА5

IN! Go! Me120890-57-5), and their esters are described (for example, in x - EP-A 195346, UMO 89/02891, UMO 98/081511 and letter-

M tour given here or they can be obtained

E X M- 2-0 by the method described in this description.

B) Reaction of aniline of the formula M with oxazinone o MI, with the production of 3-phenyluracil of the formula MI,

A) Reaction of a derivative of benzoic acid, which is then alkylated with an alkyl halide: mule I, in which VU, B" and O take the values indicated above, with sulfonamide IM, if the acceptance in bo2-MAEVT Kz ber)no, in the presence of a binding agent such as carbonyldiimidazole (SOI), or the conversion of the PSH compound into its chloride anhydride and the subsequent reaction of the chloroanhydride of the PI compound with the IM compound: U | nis-soon x POryaki t buri ono 0lzhtyyuyuv 0 bob tuornkh ren p ne p TO VD n

Ot ko aty EZSh o o y V "Uh p | you

Basically, the reaction with the IM compound is preceded by the activation of the carboxylic acid I. For the activation of I (I), it is possible, for example, to convert the PP compound into its B and I chloride anhydride by treating the acid Ii with chlorinating agents 5OXI, ROSIz, RSib5, SOS" or (SOSI)". Alternatively, it is possible to obtain imidazole vi-Nai / Bave by reacting compound III with M,M-carbonyldiimidazole. These methods are mostly well-known (for example, from

Notsrep UUeu!Yi, Meiyodep deg Ogdapizsnep Spetiye | a o (Methods of Organic Chemistry), volume E5 (1985), part M I BOz-MVbyU! 1. p. 587 et seq. and volume E5 (1985), part IY, T p. 934 et seq. about in va U

As an alternative to the activation of compound PI through its imidazolides or chloride anhydrides, it is also possible to use other conventional methods of activation of new acids to activate compound I. Oxazinon MI compounds are known (for example, from

In a typical embodiment, for example, /M,M- UMO 99/14216|Y. Here, KE" mainly represents carbonyldiimidazole (SOI) carmethyl is added to the solution. What bonic acid PI in an inert solvent such as tetrahydrofuran. at the temperature of phlegm, until there is no deposit, acetic acid, at temperatures in the interval, complete conversion is achieved, and then cooled from 0 to 100"C, for example, at room temperature. Unsubstituted or substituted sulfonamide raturi, and the components are usually taken from

IM is added to this mixture, followed by the addition of equimolar amounts, or one of the components, if acceptable, of a nitrogen base, for example, an excess is taken. tertiary amine, or amidine base, such as Alkylation of aniline MI! on the free nitrogen of uradiazabicycloundecane (08), and the mixture is stirred until the reaction is complete. Usual obro- uracil by introducing the MI compound into the reaction! from bka and separation in the usual way leads to the preparation of the target compound 1 with an alkylating agent, preferably a methylating agent, for example, methyl halide, preferably methyl iodide

Derivatives of benzoic acid PPI and their corresponding esdom, or dimethyl sulfate. The reaction is mainly carried out in the presence of a base, for example, alkali metal hydroxide or alkaline earth hydroxide, which can be hydrolyzed by conventional

alkali metal, alkali metal bicarbonate or, isopropanol, and also ethers, for example, diethyl in particular, in the presence of alkali metal carbonate. ether, methyl tert-butyl ether, dioxane, tetrahydro

The alkylating agent is preferably taken in excess, with dropfuran and ethylene glycol dimethyl ether, calculated on the MIA. Suitable solvents are, in which the solvent is chosen in accordance with the principle of the method, all inert organic solvents, for example, for the reducing agent used, C-Ca-alcohols, halogeno-alkyl compounds, such as caustic agents. such as dichloromethane, ethers such as tetrahydrofuran. If either dioxane or, preferably, polar aprotic solvents metal are used as a reducing agent, the reduction is preferably carried out in such as dimethylformamide or dimethylsulfonic-inorganic acid, in particular in diluted or acid. concentrated hydrochloric acid, or in liquid organic

Aniline compounds of formula M can be prepared by a tricyclic acid, such as acetic acid, or by conventional methods, such as peroxyacid. However, the acid can be mixed with benzoic acid MI! analogously to the process of one of the above-mentioned solvents or the procedure described in A, in the corresponding /-M- solvents. Reduction of compound X to dosulfonylcarboxamide IX, which is first nitrated and with the help of a complex hydride is usually carried out, then reduced to obtain aniline M: in an organic solvent, preferably in ether or CO or alcohol. This halogenation grade of Nitrocompound X and the reducing agent is often

K in N. d78O;--MVeV? in ts B they are used in approximately equimolar amounts of Pho; as far as reaction optimization is concerned, it may also be better to use relatively large

But what about an excess of the reducing agent, for example, up to a 10-fold excess, based on stoichiometry? metric quantity. yr ve/ era Mk The amount of acid is not of great importance. is in the NSS in To achieve a complete transformation of the original material, it is recommended to use,

Suitable riveting agents, for example, are used in excess of sor. class, nitric acid in various concentrations, reaction to the nitro compound X, including concentrated fuming nitric acid. Reduction is usually performed at temperature, and also mixtures of nitric acid and sulfuric acid in the range from (-30)-С to 2002С, better in lots, wines and alkypnitrates. the temperature ranges from 02C to 802C. ! iteration can be performed in the presence of - the presence of a solvent in an excess of a nitrating agent, i.e., water, a tanpnov spon M is isolated by FI: either in an inert solvent or by diluting by filtration or extraction with a solution, for example, in water, in an inorganic acid, in an immiscible factor with water, for example, organic acids or their anhydrides, such as ethyl acetate of diethyl ether or methylchloroacetic acid and acetic anhydride, in the halide. If necessary, the aniline compound M can be in them hydrocarbons, such as methylene chloride, or in the usual way. , for example, mixtures of the above-mentioned solvents.

M-sulfonylbenzamide IX and the nitrating agent of mo-crystal A of the tgrogroup in the compound X can also be used, for example, in equimolar- to perform catalytic hydrogenation. Examples of their quantities. To improve the yield of their compound, suitable catalysts are nickel Raney palladium on it may be better to use a nitrating agent on activated carbon with up to a 10-fold molar excess, with U UuGLLI, palladium oxide, platinum and calculation on U. If the reaction is carried out at oriyano o nteral from SV to the absence of a solvent, using a nitrating agent for the nitro compound X as necessary as a diluting agent, a nitrating agent for the ruku l, which is often used even in a larger excess. The partial pressure of hydrogen required for the liquid. Nitriding is usually carried out at tempering, it is usually in the range from (100)'C to 200'C, it is better to etatitic nitration is often carried out in the range from (-30)'C to 5070. her

The obtained nitrosoluyu X is then reduced with sodium hydroxide, stilacet by the usual methods to obtain aniline U. top oil after removal of catapizato a, eaktion

The reduction of compound X to compound M can be carried out in a conventional way. As a rule, the mixture is prepared in the usual way. The reduction of compound X is carried out using a transition metal such as iron. , zinc or tin in Other suitable methods can be found in under acidic reaction conditions, or by treating the mixture with a complex hydride, such as lithialyuves osep and og gdapizspep etiv, Nitrogen compounds) I, part 1 mohydride or sodium borohydride (1971), volume X/, p. 463 et seq.)

The recovery of compound X can be carried out in Other methods that can be used in the absence of a solvent or in a solvent or in the presence of an additive. Examples of factors suitable for the production of phenyluracils by this method are water, alcohols such as methanol, ethanol and

Y, described in Vodeg, UMakarauazhpi: Regohydigipd XII esters can be obtained from the corresponding

Negrisides, Zrgipdeg Mepad 1999). C-aminobenzoic acids or esters of 3-

Analogous to the synthesis described here in the aminobenzoic acid section using methods

B), it is possible to obtain carboxylic acid III from the derivatives described in point B). Hydrolysis of compounds ХІІ! in acid or from carboxylic acid MI. that chemical engineering is performed by conventional methods, for example

C) Substitution of the halogen radical by the uracil radical, in the presence of catalytic amounts of nonorcal 0: ganic acid, such as hydrochloric acid or bisulfuric acid, or in the presence of an organic su- I alphonic acid, preferably in aqueous or aqueous alcohol solution. Alternatively, "hydrolysis" and- a | Is it possible to do this under waterless conditions? day of the reaction, for example, by means of a multistage 7th and 1st cleavage with the help of a transfer reagent ? then a halogen such as boron tribromide or trimethyl- in bo) in (on) silyl iodide and followed by aqueous treatment. o When obtaining, 3-phenyluracils I, which use

On! - halogen, preferably bromine or iodine. | | are produced in accordance with this invention, can

Here, aniline M is first converted into a mixture of isomers, which can be obtained as a diazonium salt, which can then be separated into pure isomers according to the Zand reaction using Zwimeyer (Zapateuegh Geasip), a well-known tea method, for example, crystallization, Chromatography, convert into a halogen compound ХИ, naraphia and the like. example, by treatment with halogen- For additional information on the preparation of copper(I) 3- or copper(II) halide or, in the case of io-phenyluracils I, (see PCT EP/01/048501, zocredide XI (Na !-I), also by treating the diazonium salt of compound M with iodine/potassium iodide. These examples of application methods are widely known to a specialist skilled in the effect of herbicide mixtures according to the given state of the art, (for example, from Nochrep -Mu/eui, leg of the invention, components A and B and, if accepted-

Meijpodep deg Ogo. Spetiye, volume 5/4, 4th supplement. but, C on the growth of unwanted vegetation, in comparison with 1960, p. 438) et seq. herbicide-active compounds separately, was pro-

The reaction of XI with the uracil OH compound is better demonstrated by the following greenhouse experiments in the presence of the copper(I) compound as a catalyst, examples (Examples 1 to 11): add to the corresponding 3-phenyluracil I. For post-emergence treatment, the experimental plants

In this way, it is also possible to obtain phenyluracils I, in which NaiI-iodine, similar to methonity from the nature of plant growth, and only dams (described by T. Magchuata, K. Ry/ Maga and M. were then subjected to processing.

Rikypaga in U. Spet. Zos, regkip Tgap5. 1995 (7), that, herbicidal compositions were suspended or emu- p. 733-734|, using compounds Сщ). lied in water as a medium for distribution and

О) Reaction of benzoic acid ester ХИЙ, sprayed, using a finely atomized example, of methyl ester with an electrophilic nozzle. with an aminating agent, leads to the corresponding components A and B and/or C were 3-(1-aminouracil-Z-ilubenzoic ester presented as 1095 by mass concentrate of emul-acid XII, hydrolysis of XIII leads to the production of sion and introduced into a solution for spraying together with 3-(11-aminouracil-Z-ilubenzoic acid KHIM (in the bone of a mixture of solvents used for which K'-MHg) and transformation of KHM by the method described- the use of the active compound. In the examples, including in point A), leads to the compound |, the solvent used was water.

In which VYAMNe: The trial period lasted more than 21 days. In this one

MAM o A time, the plants were observed and their slectrophilic reaction to treatment with the active compound was evaluated. and: О-КО00СЖ o aminating agent Assessment of damage caused by chemical

Oh wonder oblique compositions, was performed using a scale from 0 to 10095, in comparison with unprocessed- (HIBA from Sebrazki) | t tldroli them control plants. In this case, O means no damage and 100 means . t; complete destruction of plants.

What is the In the examples below, the value E, which represents the so-

Five hundred and one individual compounds are only additive, was

This is calculated using the method of S. K. Soir

Examples of electrophilic aminating agents are 2,4-dinitro-phenylhydroxylamine. and O-hezropzevz oi Neiiside sotrBripaiopv", UMUeeaiv 15, mesitylenesulfonylhydroxylamine. Corresponding p. 22| et seq. conditions for carrying out the reaction of electrophilic amine-EXH ZHU-(HULOO), in which the ), description X - the effect in percentages, the use of which is active, which concerns the electrophilic amination of compound A at the application rate a; Y is specifically included in this description as a reference. y - the effect in percent, the use of the active compound B at the application rate b;

E - the expected effect (do) of AB at the norms demonstrate the synergistic effect of mixtures, which mis- introduction of ajr. that is, at least one phenyluracil I and at least

If the value determined in this way is greater than the value of E, calculated according to the method of Example 1: Herbicidal effect of mixture 8.124, which

Colby, there is a synergistic effect. applied by the post-emergence method, 5 times

The following active compounds were studied: phenyluracil 1.1 from Table 1 (Example 54 from the application PCT/ЕРО1/04850); Herbicidal action in relation to phenyluracil 1.7 from Table 1 (Example 101 from the PCT/ERO1/04850 application); phenyluracil 1.8 from Table 1 (Example 76 from application PCT/ER 01/04850; 7-0 G17781 4 | - phenyluracil 1.14 from Table 1 (Example 127 with trapcoxidim (group 61): herbicide 01.1 ; profoxidim (group 51): herbicide 51.2; " " pmavamoko (corpse bo). Fields 51.3; Example 2: Herbicidal effect of the mixture 8.128, which is applied by the post-emergence method, respectively, imazethapyr (group B2): herbicide 62.2 ; to VIORI nicosulfuron (group p2): herbicide 2.3; atrazine (group 53): herbicide 63.1; - - -

Duo (ruta oo) tera isoproturon (group 03): herbicide 63.3; 7800122 | defined | calculated paraquat (group 03): herbicide b3.4; oh | - 1 0 1 shShsh- With cinidon-ethyl (group B4): herbicide b4.1; 7-2 r 11729011 picolinafen (group 55): herbicide 55.1; sulcotrione (group p5): herbicide 55.2; 098 | - І 20 | - glyphosate isopropylammonium salt (group bB6): | - | 1563 | 20 | - herbicide 06.1; glufosinate ammonium salt (group p7): herbicide 07.1; Example 3: Herbicidal effect of mixture 7.140, which pendimethalin (group 59): herbicide 59.1; applied by the post-emergence method, according to one-dimethenamid-P (group 510): herbicide 510.1; in relation to AMERA and in relation to ROI PE acetochlor (group 010): herbicide 010.2; isoxaben (group 011): herbicide 011.1; today in g/ha INTRODUCTION TO INTRODUCTION TO

No: AMOEBA ROGRE dichlorprop-P dimethylammonium salt (dicamba group (group 513): herbicide 13.2; in 2172296 17: 1791 2,4-O dimethylammonium salt (group p13): herpes SU:H SHYTI BELT PON bicide 513.3; diflufenzopyr sodium salt (group p14): her- 3911-1150 | sh- | 250|. Yuzhd-. bicide 014.1; 7 17125101 1801 1 oxacyclomefon (group 515): herbicide 015.1; 391 | 125| 50 | 15 | 98 | 7 | / mefenpyr-diethyl: antidote si; benoxacor: antidote p. 2. Example 4: Herbicidal action of mixture 7.151. which

The following experimental plants were used by the post-emergence method, according to the method used for greenhouse research: in relation to VEARI and in relation to ESNSO

Normal- | /herbicidal effect on | Herbicidal effect on sennyav/a | relation to relation to

BOIL. ESNOO (AMAVE 0 | Atagapishyiztgentoyehiiid 0000 and 7 | cheno | vano / cheno | vano 195| - | 40 | - | 0 | - - 16251 25 | - | 15 | - 3911 - | 60 | - | 30 | - and - | 7125 | 60 | - | 20 | - (391 | 125 | 98 | 84 | 70 | 44

Example 5: Herbicidal effect of mixture 7.152, which is applied by the post-emergence method, in relation to AVOTN

The results of the experiments are presented below in the tables of Examples 1 to 26, they are

N / Herbicidal effect in relation to Example 10: Herbicidal effect of mixture 7.207, which is applied at the rate of application in g/ha to AVIOTN by the post-emergence method, according to

И7 з З is defined by | Calculated (in relation to AMER and in relation to ROGRE ! ! by the Kolobi method)

And 098 | - 0 1 - | Herbicidal effect on | Herbicidal effect on

And - | 3125 | 0 | - | Norm vne: relative to relative to 3125 | 60 | 0 5 in| AMERA ROGRE 795 | - | 3 Y - | 7 st | recognize- | calculated | recognize- | calculated

And - 1,625 | 40 | - | and | cheno vano cheno vano 95 | 625 | 98 | 58 | 195, - | 10 | - | 0 1 -

And - 2501 0 | - | 0 her -

Example 6: Herbicidal effect of mixture 7.162, which | 1.95| 250| 25 | l0 | 40 | 0 and and and 391| - | 15 | - | 25 | - applied by the post-emergence method, in relation to AVITN 7-51 201-131

H / Herbicidal effect in relation to the application rate in g/ha to AVIOTN Example 11: Herbicidal effect of mixture 7.283, which

И7 зА is defined | Calculated (applied by the post-emergence method, in relation to the "" Colby method) to SOMVE and in relation to ROGRE

And 098 | - HER 0 HER - - | 925 | 0 / - | Herbicidal effect on | Herbicidal effect on 3125 | 50 | 0 | The norm of implementation in relation to | in relation to 195 | - | 30 HER - | SOMWE ROGRE

And - | 625 | 4 | - | 7 | cut | recognize- |calculate-| recognize- | estimated at 795 | 625 | 80 | 58 2 | and | cheno | vano | cheno | vano 195| - ,Y 0 | - | 0 1 -

Example 7: The herbicidal effect of mixture 8.188, which is applied by the post-emergence method, according to 195 1 5Ю | 85 | 40 | 70 | from the train to VEARI. and in relation to ROGRE 391 | - HER 0 Her - | 25 | - - 7000! 75 | - | from 30 | - : : : : 1000

The norm is introduced- Herbicidal effect on Herbicidal effect on / in relation to relation to y and s. nya in the city of VVARA. ROIRE Example 12: Herbicidal effect of mixture 1.64, which

B admit- | calculated | recognize- | the calculation is applied by the post-emergence method, in relation to SAGAR 098 | - | 30 | - | t | -

And - | 781| 20 | - | from | - | Herbicidal effect on the relationship

The rate of contribution to PA to SAIAR is 195| - | 40 | - | 20 | -

And - |1563| 20 | - | yu | - | 795 | - G 20 | - 1563| 75 | 52 | 60 | 52 | | - | 625 | 0 | -

Example 8: Herbicidal effect of mixture 8.194, which 391 | - | 20 | - applied by the post-emergence method, respectively - | 7125 | 0 1 - to the ESNSO

N / Herbicidal effect in relation to Example 13: Herbicidal effect of mixture 1.61. what rate of application in g/ha to the ESNSS is applied by the post-emergence method, according to

And 18 | 52 | defined | calculated | to AVOTN 195 | sh- HER 2 | - 31.25 | 60 | - | Herbicidal action in relation to z | 106-168 0 |Chormavnessnnyavtta 07 dovotn.

And Z91 | 7-40 | -

And - 11625 | 75 | - | 195 | - Eat! 20 HER - - | 3125 | 3 | - 31.25

Example 9: Herbicidal effect of mixture 7.206, which | 391 | - ! 30 | - applied by the post-emergence method, respectively - I - | 625 | 4 | - shenyu to AMER

Application rate in g/ha Herbicidal effect in relation to Example 14: Herbicidal effect of mixture 1.25, which is applied to AMEEA by the post-emergence method, in relation to SAGAR 95 | sh-- | 10 HER - you -8-- 75 ny Application rate in g/ha Heroicidal in the field 5391 | sh- HER 15 | - | B1.Zzhs.1

I - H 250 | 0 1 - | | 195 | - | 50 | - 391 | 250 | 60 | 15 | | - | bath | 0 | -

Herbicidal action in relation to senna to VIORI

Holiday 861-25-22 - | la51359|. YDTSD0 1 - same 8.91 | i25-1359 | 80 | 60 | | 195 | - |; 45 | -

And - 250 | 3 | -

Example 15: Herbicidal effect of mixture 14.107, which | 7195 | 250 | 98 | 58 is applied by the post-emergence method, according to I 391 | - She is 85 | - in relation to AGOMU and in relation to VKARA. | - 500 2 HER 5 sh7 | - 8391 | 500 | 98 | 955

Herbicidal effect on | Herbicidal effect on

Example 20: The herbicidal effect of the mixture 14.288, which is applied in the AHOMU VAAR field by the post-emergence method, according to the ESNOO, the soma bath tubs! 0e8 | 80 | 50 | 80 | t soy! - | 0 - | 0. the same as | | 195 | - | 4 | - 5224185, 60, | 70 | 7777175 1 60 6 ш6ж51.Ю.Б 6 BI (ов | тя | 80 | 60 | 80 | 70 | | 195 | 125 | 60 | 4 391 | - 7 | -

Example 16: Herbicidal effect of mixture 1170, which. (77-01 25071301 is used by the post-emergence method, in relation to ROGRE

Example 21: Herbicidal effect of mixture 1.296, which is applied by the post-emergence method, in relation to AMARE and in relation to VIORI

And 049 | sh- Y 10 /! - | Herbicidal effect on | Herbicidal action according to 21 July 86 71777407...) | in relation to

And 049 | 098 | 60 | 46 | in the village of AMAVE VIORI

And 098 | - | 25 | - | recognize- Irorazho-| recognize- | calculated

And - 795 | 5 sh6v60 Y - 0491 - | 600 15ж6.-6ЖБ15200156-

And - | 781 0 | - | 201 -

Example 17: Herbicidal action of mixture 1.213, which I 049| 781 | 80 | 50 | 50 | c6 is applied by the post-emergence method, according to I098| - | 60 | - | z0 | - sent to AMEEA | - 11563| 0 | - | 30 | - (0.98 | 15.63 | 80 | 60 | 60 | 51 to AMEEA Example 22: Herbicidal effect of mixture 14.253, which is applied by the post-emergence method, according to

And 098 | - | 5 /! - | in the direction of 5ETRA and in relation to SAGAR 1-11 7125 | 0 | -

Herbicidal effect on | Herbicidal action according to 175-019. 1--- | |Normavnyesov) in relation to | in relation to - 1,250 | sh2 | - | g/ha ZETEA SAGAR

Y Y cheno vano cheno vano

Example 18: Herbicidal effect of mixture 1.238, which 049 | - | 20 | - | 0 | - applied by the post-emergence method, according to the renewal of the 1st year, the yield to AMER and in relation to VIORI is higher in g/ha than in relation to z z

AMOEBA VIORI

Example 23: The herbicidal effect of the mixture 14258, which is applied by the post-emergence method, according to

And 195 | - | 10 Her - | 40 | - | in relation to 5ETEA and in relation to SAGAR - |7125| 30 | - | 25 | - 1.95 | 125 | 60 | 37 | 85 | 55 | Herbicidal effect on | Herbicidal effect on

And 391, - | 10 | - | 50 | - | Contribution rate) in relation to | in relation to - |250| from 30 | - | 25 | - | in the village of ZETEA SAGAR now. -Zvs.2 cheno vano no vano

Example 19: Herbicidal action of mixture 14.216, which 049| .- | 20 | - | 0 | - applied by the post-emergence method, respectively - I6b25-3iz| 0 | - | 0 HER -

Rate of introduction Herbicidal effect on Herbicidal effect on in g/ha relative to Relative to Effect of antidote

ZETRA adgAR In the examples below, mixtures were used dos-b2,5-3y3| 60 | 20 | 30 | 0 | running method. For this, experimental plants with 0 |72516,25| 30 | - | 0 1: | After that (that is, before the germination of their pods and 0.98|125-625| 75 | 47.5 | 50 | 25 | K igooto, before the growth of the plants), the mixture according to the invention is dispersed. applied to the soil in the form of a water-sprayed liquid - apply post-shooting, accordingly, at a constant application rate. As in the post-emergence and second method, described above, the period of training is carried out before VKARA. and in relation to AVOTN the study was 21 days. Then they assessed

Herbicidal action on Y Herbicidal action on damage as described above, using

The norm is introduced in relation to the scale of damages from 0 to 100905 in comparison with nya in g/ha VVARI. AVITN untreated control plants (095 (14 | cuts, 3 | recognized | calculated | recognized | calculated damage).

I I cheno vano cheno vano The antidote works if damage by cultural

And 049| - | 10 | - | 0 | - | saliva caused by the use of the mixture, respectively

And - 1625| 20 | - | 25 | - | to this invention containing antidote C) are smaller than the damage caused when using 0981 - | 15 | - | 20 | - | active compound A) or active compounds A) and B) without and - | 71251 50 | - | 65 | - | antidote (098 | 125 | 60 | 575 | 95 | 72 | Example 27: Herbicidal effect of mixture 7.314 in relation to ROARC and in relation to TERRE, and

Example 25: The herbicidal effect of the mixture 14.279, which is the effect of the antidote in the case of TE2AM/ applied by the post-emergence method, in relation to ZETRA and in relation to SAGAR Norm vne- |Damage| Herbicidal | Herbicide application in g/ha cultural | action on one | action on

The rate is introduced - Herbicidal effect on | Herbicidal effect on I? from the shenido plant | increase in g/ha in relation to TAV2AM ROARC TVERV

ZETEA SAGAR 200 | - | 10 1 98 | (14 | bath 049| - | 20 - | 0 | - | 4001 - | 35 | 98 ЮЩ | 100. and 185, 00117913 1 12461005 029 | 625 | 401 2001 20101 202001 1551 81 100 098| - | 25 | - | 25 | - and - | 7125 | 10 | - | 01 - | Example 28: Herbicidal effect of mixture 8.314 in relation to ROARR and in relation to TRERR, and and and c, antidote action in the case of TK2AMUU

Example 26: The herbicidal action of the mixture 14.300, which is applied by the post-emergence method, according to the external standard | Damage | Herbicidal | Herbicide for application to SOMVE today in g/ha | cultural | action on one | action on

ХА с шенью шеню шенью до

Application rate per hectare | The strategic action in relation to TA2AM/ROARV TVER will be included in the COMME 2-1 30 | 985 Yuyu 100 /

BIB 7-20 01015 195 | - /! 0 HER - | 2002001 yush 0 | 98 | 00 1-1 1117125 | 0 HER - | 400 | - | 65 | forehead | lo le5 | 2125 1.yuYu2.201.6..6..0..1. | 1201 0 1 6 шжЩ at 1 55 I

For | - | 40 | - 7-1 250 | 0 1 -

And ze | 250 | 60 | 4

Ministry of Education and Science of Ukraine

State Department of Intellectual Property, str. Urytskogo, 45, Kyiv, MSP, 03680, Ukraine

SE "Ukrainian Institute of Industrial Property", str. Glazunova, 1, Kyiv - 42, 01601