UA73334C2 - Herbicidal agent on the basis of 2,6-disubstituted pyridine derivatives - Google Patents

Abstract

The invention relates to novel, synergistic, herbicidal agent combinations, which comprise 2,6 di-substituted pyridine derivatives and known herbicidally effective compounds and/or safeners. Said combinations are particularly successful when used for selective weed control with various crop seedlings, in particular, cereals.

Description

Description of the invention

The invention relates to new synergistic herbicidal mixtures, which include known 2,6-disubstituted pyridine derivatives, on the one hand, and known compounds and/or antidotes having herbicidal activity, on the other hand, and can be used with particularly good success for selective control of weedy vegetation in various crops of useful plants.

As herbicides with a wide range of action, 2,6-disubstituted pyridine derivatives are the subject of a number of patent applications (see application MOER447004, international application MOUUO94/22833). However, the action of known pyridine derivatives 70 is often insufficient. In addition, the tolerance of these compounds by cultivated plants is not sufficient in all conditions.

Now it has been unexpectedly found that a number of known active substances from the group of 2,6-disubstituted pyridine derivatives, when used together with known compounds of various classes of substances having herbicidal activity, show a clear synergistic effect in relation to activity in the control of weedy vegetation and as 12 combined preparations can be particularly advantageously used for selective control of weed vegetation in crops of useful plants, such as, for example, crops of wheat.

Unexpectedly, it has also been found that 2,6-disubstituted pyridine derivatives alone or together with known compounds having herbicidal activity, when used together with the compounds (antidotes) described below, which improve the tolerance of cultivated plants, very well prevent damage to cultivated plants. plants and can be especially advantageously used for selective control of weed vegetation in crops of useful plants, such as, for example, grain crops.

The object of the invention are selective herbicides, which differ in the effective content of the herbicide mixture, which includes a) at least one 2,6-disubstituted derivative of the general formula (I) c o A, i) and - zd!

What) "where so

B" unsubstituted or singly or multiply substituted by haloalkyl and/or haloalkyl with 1-3 carbon atoms 5-6-ene heterocycle containing 1-3 carbon atoms, or unsubstituted or singly or multiply substituted by haloalkyl and/or haloalkyl with 1-3 carbon atoms, phenyl radical, so

IN? unsubstituted or substituted by haloalkyl and/or haloalkyl with 1-3 carbon atoms phenoxy radical, -

VZ hydrogen atom or methyl,

MU of oxygen or the group -"СО-МН-

(b) one or more compounds from the second group of herbicides, which contains the following active beginnings: c M-isopropyl-M-(4-fluorophenyl)-amide ( 5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy)-acetic acid (flufenacet, ; » application MorEZ821600), 2-(2-methoxycarbonyl-phenylsulfonylaminocarbonyl)-methyl-5-n.-propoxy-2 ,4-dihydro-ZH-1,2,4-triazol-3-one or the sodium salt of this compound (propoxycarbozone-sodium, application MoERBO7171), -1 395 2-(2-trifluoromethoxy-phenylsulfonylaminocarbonyl)-4-methyl-5 -methoxy-2,4-dihydro-ZH-1,2,4-triazol-3-one or the sodium salt of this compound (flucarbazone sodium, application MOERBO7171), M-(3,4-dichlorophent)propanamide (propanil,

Ge) application MoOE1039779), M-2-benzothiazolyl-M,M'-dimethylurea (metabenzthiazuron, application MoB1085430), o 4-amino-6-(1,1-dimethylethyl)-3-(methylthio)-1,2, 4-triazin-5-(4H)-one (metribuzin, application MoOE1795784), 4-(2-chlorophent)-M-cyclohexyl-M-ethyl-4,5-dipdro-5-oxo-1H-tetrazole-1- carboxamide (fentrazamide, application (95) 50 MoERbB12735), 4-amino-3-methyl-b-phenyl-1,2,4-triazin-5(4H)-one (metamitron, application MoOE2138031),

I» 2-(2-benzothiazolyl-oxy)-M-methyl-M-phenylacetamide (mefenacet, application MoOE2822155), 4-amino-6-(1,1-dimethylethyl)-3-(ethylthio)-1,2, 4-triazin-5(4H)-one (ethiosin, application MOOE1542873) or 1-methylethyl 5-I4-bromo-1-methyl-5-trifluoromethyl)-1H-pyrazol-3-yl|-2-chloro-4- fluorobenzoate (fluazolate, international application mmouuu09206962) 59 C. active beginnings of group 2")

GF) and, if necessary, c) additionally at least one compound that improves tolerance by cultivated plants from the following group of compounds: o-(1,3-dioxolan-2-yl-methoxyimino)-phenylacetonitrile (oxabethrinil), o-(cyanomethoxyimino)- phenylacetonitrile bo (cyometrinil), 4-chloro-M-(1,3-dioxolan-2-yl-methoxy)-y-trifluoro-acetophenonexime (fluxofenim), 4,6-dichloro-2-phenylpyrimidine (fenclorim), 4- dichloroacetyl-3,4-dihydro-3-methyl-2H-1,4-benzoxadine (benoxacor), (1-methyl-hexyl ester) of 5-chloro-quinoxaline-8-oxy-acetic acid (cloquintocet), 2, 2-dichloro-M-(2-oxo-2(2-propenylamino)-ethyl)-M-(2-propenyl)-acetamide (OKA-24), anhydride of 1,5-naphthalic acid, complex ethyl ester of 1- (2,4-dichloro-phenyl)-5-trichloromethyl-1H-1,2,4-triazole-3-carboxylic acid (phenchlorazole-ethyl), complex phenyl-methyl ether 2-chloro-4-trifluoromethyl-thiazole-5 -carboxylic acid

(flurazole), 3-dichloroacetyl-5-(2-furanyl)-2,2-dimethyl-oxazolidine (furylazole, MOM-13900), 4-dichloroacetyl-1-oxa-4-aza-spiro(4,5|- decane (A 076), 2-dichloromethyl-2-methyl-1,3-dioxolane / (MO-191), 2,2-dichloro-M-(1,3-dioxolan-2-yl-methyl)-M- (2-propenyl)-acetamide (PPO 1292), 2,2-dichloro-M,M-di-2-propenyl-acetamide (dichloramide), M-(4-methyl-phenyl)-M'-(1-methyl -1-phenyl-ethyl)-urea (dimron), 1-dichloroacetyl-hexahydro-3,3,va-trimethylpyrrole|1,2-a|-pyrimidin-6(2H)-one (VAZ3-145138),

M-(2-methoxy-benzoyl)-4-(methylaminocarbonylamino)-benzenesulfonamide, ethyl-4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadiphen-ethyl), diethyl-1-(2,4- dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl), 7/0. (4-chloro-2-methyl-phenoxy)-acetic acid (MSORA), (1-)-2-(4-chloro-2-methylphenoxy)-propanoic acid (mecoprop), 3-dichloroacetyl-2,2,5 -trimethyl-oxazolidine (K-29148) and 2,4-dichlorophenoxyacetic acid (2,4-O) and their derivatives

C. active beginnings of group 3") and, if necessary, d) additionally one or more compounds from the third group of herbicides, which includes the active beginnings listed below: 2-chloro-M-(ethoxymethyl)-M-(2-ethyl-b6 -methyl-phenyl)acetamide (acetochlor), sodium salt of 5-(2-chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoic acid (acifluorphene-sodium), 2-chloro-6-nitro-3-phenoxy- benzenamine (aclonifen), 2-chloro-M-(methoxymethyl)-IM-(2,6-diethyl-phenyl)-acetamide 2o (alachlor), M-ethyl-M'-isopropyl-b6-methylthio-1,3, 5-triazine-2,4-diamine (ametrine), 4-amino-M-(1,1-dimethyl-ethyl)-4,5-dihydro-3-(1-methyl-ethyl)-5-oxo-1H -1,2,4-triazole-1-carboxamide (amicarbazone), M-(4,6-dimethoxy-pyrimidin-2-yl)-ME(M-methyl-M-methylsulfonate-sulfamot)-urea (amidosulfuron ), 1H-1,2,4-triazol-3-amine (amitrol), b-chloro-4-ethylamino-2-isopropylamino-1,3,5-triazine (atrazine), 2-(2,4-dichloro -5-(2-propynyloxy)-phenyl)-5,6,7,8-tetrahydro-1,2,4-triazolo-|4,3-a|-pyridin-3(2H)-one (azaphenidine),

N-(4,6-dimethoxy-pyrimidin-2-yl)-N'-1-methyl-4-(2-methyl-2H-tetrazol-5-yl)-1H-pyrazol-5-ylsulfonyl urea and ) (azimsulfuron), M-benzyl-2-(4-fluoro-3-trifluoromethyl-phenoxy)-butanamide (buflubutamide), 4-chloro-2-oxo-3(2H)-benzthiazolacetic acid (benazolin),

M-butyl-M-ethyl-2,6-dinitro-4-trifluoromethyl-benzenamine (benfluralin), "g zo M-(4,6-dimethoxy-pyrimidin-2-yl)-M'-(2-methoxycarbonyl- phenylmethylsulfonyl)-urea (bensulfuron), complex methyl ether o 2-(2-IA4-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1-(2H)-pyrimidinyl-phenoxy| methyl|-5-ethyl-phenoxy-propa c new acid (benzphendizone), 3-(2-chloro-4-methylsulfonyl-benzoyl)-4-phenylthio-bicyclo-I3.2.1|-oct-3-en-2- one (benzobicyclone), ethyl M-benzoyl-M-(3,4-dichloro-phenyl)-OiI -alanilate (benzoylprop-ethyl), me)

3-isopropyl-1H-2,1,3-benzothiadiazin-4(ZH)-one (benzathone), methyl-5-(2,4-dichloro-phenoxy)-2-nitro-benzoate- (bifenox), sodium 2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoic acid (bispyribac sodium) salt, 2-bromo-3,3-dimethyl-M-(1-methyl-1- phenyl-ethyl)-butanamide (bromobutide), 3,5-dibromo-4-hydroxy-benzaldehyde-O-(2,4-dinitro-phenyl)-oxime (bromophenoxime), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), M-butoxymethyl-2-chloro-M-(2,6-diethyl-phenyl)-acetamide " (butachlor), complex P1,1-dimethyl-2-oxo-2-(2-propenyloxy)|- 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinyl)-benzoic acid ethyl ester

And (butaphenacylalyl), and? 2-(1-ethoxyimino-propyl)-3-hydroxy-5-(2,4,6-trimethyl-3-(1-oxo-butyl)-phenyl|-2-cyclohexan-1-one (butroxidim), C -ethyl-bis-(2-methyl-propyl)-thiocarbamate (butylate),

M,M-diethyl-3-(2,4,6-trimethyl-phensulfonate)-1H-1,2,4-triazole-1-carboxamide (cafenstrol), -I 2-(I1-К-3-chloro- 2-propenyl)-oxyimino|-propyl|-3-hydroxy-5-(tetrahydro-2H-pyran-4-yl)-2-cyclohexen-1-one (caloxidim, tepraloxidim), about 2-(4-chloro- 2-fluoro-5-(2-chloro-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-ZH-1,2,4-triazol-2) Z-one (carfentrazoneethyl), 2,4-dichloro-1-(3-methoxy-4-nitro-phenoxy)-benzene (clomethoxyphen), 3-amino-2,5-dichloro-benzoic acid (chloramben), o M-(4 -chloro-β6-methoxy-pyrimidin-2-yl)-N'-(2-ethoxycarbonyl-phenylsulfonyl)-urea (chloromuron-ethyl), 1,3,5-trichloro-2-(4-nitro-phenoxy )-benzene (chloronitrophen),

M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'-(2-chloro-phenylsulfonyl)-urea (chlorosulfuron),

M'-(3-chloro-4-methyl-phenyl)-M,M-dimethyl-urea (chlorotoluron), complex ethyl ether 2-chloro-3-(2-chloro-5-(1,3,4,5 ,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenyl|-2-propanoic acid (cinidone-ethyl), M-(4,6-dimethoxy-1,3,5- triazin-2-yl)-M'-(2-(2-methoxy-ethoxy)-phenylsulfonyl)-urea i) (cynosulfuron), ka 2-(1--2-(4-chlorophenoxy)-propoxyamino)|- butyl|/|-5-(tetrahydro-2H-thiopyran-3-yl)-1,3-cyclohexanedione (klefoxidim), (E,E)-(c)-2-1-((3-chloro-2- propenyl)-oxy|-imino|-propyl|-3-hydroxy-2-cyclohexen-1-one bo (clethodim), (K)-(2-propynyl)-2-I4-(5-chloro-3-fluoro -pyridin-2-yl-oxy)-phenoxy-propanoate (clodinafop-propargyl), 3,6-dichloro-pyridine-2-carboxylic acid (clopyralid), methyl-3-chloro-2-Y(5-ethoxy-7 -fluoro(1,2,triazol!|1,5-c|Ipyrimidin-2-yl-sulfonyl)-amino)|-benzoate (cloransulam-methyl), 2-chloro-4-ethylamino-6-(1-cyano -1-methyl-ethylamino)-1,3,5-triazine (cyanazine),

M-(4,6-dimethoxy-pyrimidin-2-yl)-M'-(2-cyclopropylcarbonyl-phenylsulfonyl)-urea (cyclosulfamuron), 65 2-(1-ethoxyminobutyl)-3-hydroxy-5-(tetrahydro- 2H-thiopyran-3-yl)-2-cyclohexen-1-one (cyclooxydime), complex butyl ether (K)-2-I4-(4-cyano-2-fluoro-phenoxy)-phenoxy|-propanoic acid (cyhalofop -butyl),

2,4-dichloro-phenoxy-acetic acid (2,4-05), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), (k)-2-(2,4-dichloro-phenoxy)- propanoic acid (dichloroprop-P), methyl 2-I4-(2,4-diphor-phenoxy)-phenoxy|-propanoate (diclofop-methyl),

IM-(2,6-dichloro-phent)-5-ethoxy-7-fluoro(|1,2,4|-triazolo-(1,5-c|-pyrimidine-2-sulfonamide (diclosulam), 1,2 -dimethyl-3,5-diphenyl-1H-pyrazolium-methylsulfate (difenzoquat),

IM-(2,4-difluorophenyl)-2-(3-trifluoromethyl-phenoxy)-pyridine-3-carboxamide (diflufenican), 2-(1-KZ,5-difluoro-phenyl)-amino-carbonyl-hydrazono|- ethyl|-pyridine-3-carboxylic acid (diflufenzopyr), 5-(1-methyl-1-phenyl-ethyl)-1-piperidine-carbothiate (dimepiperate), 70. (8-)2-chloro-M-(2 ,4-dimethyl-3-thienyl)-M-(2-methoxy-1-methyl-ethyl)-acetamide (5-dimethenamid), 2-amino-4-(1-fluoro-1-methyl-ethyl)-6 -(1-methyl-2-(3,5-dimethyl-phenoxy)-ethylamino)-1,3,5-triazine (dimexiflam),

М3,МЗ-diethyl-2,4-dinitro-б6-trifluoromethyl-1,3-diamino-benzene (dinitramine), 6,7-dihydro-dipyridoi|1,2-а:2",1,-с|- pyrazinediium (diquat), 8,3-dimethyl-2-difluoromethyl-4-isobutyl-6-trifluoromethyl-pyridine-3,5-dicarbothioate (dithiopyr), 75. M'(3,4-dichlorophent)- M,M-dimethyl-urea (diuron), 2-(2-(3-chloro-phenyl)-oxiranylmethyl|-2-ethyl-1H-inden-1,3(2H)-dione (epropodan), 3-ethyl -dipropylthiocarbamate (ERTO), 3-(phentmethyl)-M-(1,2-dimethyl-propyl)-thiocarbamate (esprocarb),

M-ethyl-M-(2-methyl-2-propenyl)-2,6-dinitro-4-trifluoromethyl-benzenamine (ethalfluralin), (5)-(2-ethoxy-1-methyl-2-oxoethyl)-2 -chloro-5-(2-chloro-4-trifluoromethyl-phenoxy)-benzoate (ethoxyphene),

M-(4,6-dimethoxy-pyrimidin-2-yl)-M''(2-ethoxy-phenoxysulfonyl)-urea (ethoxysulfuron), (K)-ethyl-2-I4-(6-chloro-benzoxazole-2 -yl-oxy)-phenoxy|-propanoate (phenoxaprop-(P)-ethyl), 4-(2-chloro-phenyl)-M-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1- carboxamide (fentrazamide), isopropyl-M-benzoyl-M-(3-chloro-4-fluoro-phenyl)-OI-alaninate (flampropisopropyl), isopropyl-M-benzoyl-M-(3-chloro-4-fluoro-phenyl) )-I-alaninate (flamprop-isopropyl-i), sc methyl-M-benzoyl-M-(3-chloro-4-fluoro-phenoxy)-OiI-alanine (flamprop-methyl),

IM-(2,6-difluoro-phenyl)-8-fluoro-5-methoxy-|1,2,4|-triazolo-|1,5-si-pyrimidine-2-sulfonamide (florasulam), and) complex butyl (K)-2-I4-(5-trifluoromethyl-pyridin-2-yl-oxy)-phenoxy|-propanoic acid ester (fluazifop, -butyl, -P-butyl), isopropyl ether 5-(4-bromo- 1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl)-2-chloro-4-fluoro-benzoic acid (fluazolate), 4,5-dihydro-3-methoxy-4-methyl-5- oxo-M-(2-trifluoro-methoxy-phenyl)-sulfonyl|-1-H-1,2,4-triazole-1-carboxamide sodium salt (flucarbazone sodium), o

IM-(4-fluoro-phenyl)-M-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy)-acetamide (flufenacet), c

IM-(2,6-difluorophenyl)-5-methyl-1,2,4-triazolo|1,5-a|-pyrimidine-2-sulfonamide (flumetsulam), pentyl-|2-chloro-4-fluoro-5 -(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenoxy|-acetate me) (flumiclorac-pentyl), y- 2-(7- fluoro-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazin-b6-yl1I-4,5,6,7-tetrahydro-1H-isoindole-1,3- dione (flumioxazin), 2-I(4-chloro-2-fluoro-5-(1-methyl-2-propynyl)-oxy|-phenyl)-4,5,6,7-tetrahydro-1H-isoindole- 1,3-dione (flumipropine), 3-chloro-4-chloromethyl-1-(3-trifluoromethyl-phenyl)-2-pyrrolidinone (fluorochloridone), complex ethoxycarbonylmethyl ether 5-(2-chloro-4-trifluoromethyl-phenoxy) -2-nitro-benzoic acid « (fluoroglycophen-ethyl), with c 1-(4-chloro-3-(2,2,3,3,3-pentafluoro-propoxymethyl)-phenyl)-5-phenyl-1H- 1,2,4-triazole-3-carboxamide (flupoxam), . 1-isopropyl-2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1-(2H)-pyrimidyl)-benzoate (flupropacil), and? sodium salt

M-(4,6-dimethoxy-pyrimidin-2-yl)-M'-(33-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl)-urea (flupyrsulfuron-methyl-sodium), 9-hydroxy- UN-fluorene-9-carboxylic acid (flurenol), (complex -I -2-butoxy-1-methyl-ethyl ether, complex -1-methyl-heptyl ether) (4-amino-3,5-dipor-6- fluoro-pyridin-2-yl-oxy)-acetic acid (fluroxypyr, -butoxypropyl, -meptyl), o 5-methylamino-2-phenyl-4-(3-fluoromethyl-phenyl)-3(2H)-furanone (flurtamone ), 2) methyl-|((2-chloro-4-fluoro-5-(tetrahydro-3-oxo-1H,ZH-(1,3,4|-thiadiazolo-|Z3,4-a|-pyridazine- 1-ylidene)-amino-phenyl/|-boron u-acetate (fluthiacet-methyl), 5-(2-chloro-4-trifluoromethyl-phenoxy)-M-methylsulfonyl-2-nitro-benzamide o (fomesafen), 2-ShCC4,b-dimethoxy-2-pyrimidinyl)-amino|-carbonyl|-sulfonyl|-4-formylamino-M,M-dimethyl-benzamide (foramsulfuron), (-ammonium salt) 2-amino-4- (hydroxymethylphosphinyl)-butanoic acid (glufosinate(-ammonium)),

M-phosphonomethyl-glycine (-isopropylammonium salt), (glyphosate, -isopropyl-ammonium), (methyl ester,

B complex -2-ethoxy-ethyl ether, complex -butyl ether) (k)-2-I4-(3-chloro-5-trifluoromethyl-pyridin-2-yl-oxy)-phenoxy|-propanoic acid (haloxyfop, - methyl, -P-methyl, (F) -ethoxyethyl, -butyl), 3-cyclohexyl-b6-dimethylamino-1-methyl-1,3,5-triazine-2,A(1H,3H)-dione (hexazinone) , ka methyl-2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4-methyl-benzoate (imazametabenz-methyl), 2-(4, 5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methyl-pyridine-3-carboxylic acid bo (imazametapyr), 2-(4,5-dihydro- 4-methyl-4-iso-propyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethyl-pyridine-33-carboxylic acid (imazamox), 2-(4,5-dihydro-4-methyl -4-isopropyl-5-oxo-1H-imidazol-2-yl)-quinoline-3-carbonic acid (imazaquin), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H -imidazol-2-yl)-5-ethyl-pyridine-3-carboxylic acid (imazethapyr), M-(4,6-dimethoxy-pyrimidin-2-yl)-M'-(2-chloro-imidazoli1,2- α|-pyridin-3-yl-sulfonyl)-urea 65 (imazosulfuron), sodium salt

M-(4-methoxy-b-methyl-1,3,5-triazin-2-yl)-M'(5-iodo-2-methoxycarbonyl-phenylsulfonyl)-urea

(iodosulfuron-methyl-sodium), 4-hydroxy-3,5-diiodo-benzonitrile (ioxynil),

M,M-dimethyl-M'-(4-isopropyl-phenyl)-urea (isoproturon),

IM-(3-(1-ethyl-1-methyl-propyl)-isoxazol-5-yl)-2,6-dimethoxy-benzamide (isoxaben), (4-chloro-2-methylsulfonyl-phenyl)-(5- cyclopropyl-isoxazol-4-yl)-methanone (isoxaportol), (5-cyclopropyl-isoxazol-4-yl)-(2-methylsulfonyl-4-trifluoromethyl-phenyl)-methanone (isoxaflutol), 2-(2-I( 4-3,5-dichloro-2-pyridinyl)-oxy|-phenoxy|-1-oxo-propyl|-isoxazolidine (isoxapyrifop), (2-ethoxy-1-methyl-2-oxo-ethyl)-5-( 2-chloro-4-trifluoromethyl-phenoxy)-2-nitrobenzoate (lactophen),

M'-(3,4-dichloro-phenyl)-M-methoxy-M-methyl-urea (linuron), (4-chloro-2-methyl-phenoxy)-acetic acid (MOSPA), 70. 2-(4 -chloro-2-methyl-phenoxy)-propionic acid (mecoprop), 2-(2-benzthiazolyloxy)-M-methyl-M-phenyl-acetamide (mefenacet), 2-(4-methylsulfonyl-2-nitrobenzoyl)-1 ,3-cyclohexanedione (mesotrione), 4-amino-3-methyl-b-phenyl-1,2,4-triazin-5(4H)-one (methamitron), 2-chloro-M-(2,6-dimethyl -phent)-M-(1H-pyrazol-1-yl-methyl)-acetamide (metazachlor),

M'-(4-(3,4-dihydro-2-methoxy-2 54,4-trimethyl-2H-1-benzopyran-7-yl-oxy)-phenyl)-M-methoxy-M-methylurea (methobenzuron) , M'««4-bromo-phenyl)-M-methoxy-M-methylurea (metobromuron), (5)-2-chloro-M-(2-ethyl-b6-methyl-phenyl)-M-(2- methoxy-1-methyl-ethyl)-acetamide (metolachlor, Z-metolachlor),

IM-(2,6-dichloro-33-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo|1,5-a|-pyrimidine-2-sulfonamide (methosulam),

M'-(3-chloro-4-methoxy-phenyl)-M,M-dimethyl-urea (methoxuron), 4-amino-6-tert.butyl-3-methylthio-1,2,4-triazine-5( 4H)-one (metribuzin),

M-(4-methoxy-b-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonyl-phenylsulfonyl)-urea (metsulfuron-methyl), 3-ethyl-hexahydro-1H-azepine -1-carbothioate (molinate), 2-(2-naphthyloxy)-M-phenyl-propanylide (naproanilide), M-butyl-M'-(3,4-dichloro-phenyl)-M-methyl-urea (neburon) ,

M-(4,6-dimethoxy-pyrimidin-2-yl)-M'-(3-dimethylcarbamoyl-pyridin-2-yl-sulfonyl)-urea (nicosulfuron), 5-(2-chloro-benzyl)-M, M-diethyl-thiocarbamate (orbencarb), 4-dipropylamino-3,5-dinitro-benzenesulfonamide s ov (oryzalin), 3-(2,4-dichloro-5-(2-propynyloxy)-phenyl|-5-(tert .butyl)-1,3,4-oxadiazol-2(ZH)-one (oxadiargyl), 3-(2,4-dichloro-5-(1-methyl-ethoxy)-phenyl|-5-(tert.butyl )-1,3,4-oxadiazol-2(Z3H)-one (oxadiazone), and)

M-(4,6-dimethyl-pyrimidin-2-yl)-M'-(2-oxetan-3-yl-oxycarbonyl-phenylsulfonyl)-urea (oxasulfuron), 3-(1-(3,5-dipor- phenyl)-1-isopropyl|-2,3-dihydro-b6-methyl-5-phenyl-4H-1,3-oxazin-4-one (oxacyclomefon), 2-chloro-1-(3-ethoxy-4- nitro-phenoxy)-4-trifluoromethyl-benzene (oxyfluorfen), 1,1-dimethyl-4-bipyridinium zo (paraquat), 1-amino-M-(1-ethyl-propyl)-3,4-dimethyl -2,6-dinitro-benzene (pendimethalin), 4-(tert.butyl)-M-(1-ethyl-propyl)-2,6-dinitro-benzenamine (pendraline), o 4-amino-3,5, 6-trichloro-pyridine-2-carboxylic acid (picloram), «9 2-chloro-M-(2,6-diethyl-phenyl)-M-(2-propoxy-ethyl)-acetamide (pretylchlor),

M-(4,6-bis-difluoromethoxy-pyrimidin-2-yl)-M'-(2-methoxycarbonyl-phenylsulfonyl)-urea me) (primisulfuron-methyl), y-1-chloro-M-(2-chloro -4-fluoro-5-(65,7ac)-6b-fluoro-tetrahydro-1,3-dioxo-1H-pyrrolo|1,2-c|imidazol-2-(ZH)-yl|-phenyl|-me tan-sulfonamide (profluazol), 2-chloro-M-isopropyl-M-phenyl-acetamide (propachlor),

IM-(3,4-dichloro-phenyl)-propanamide (propanyl), (KO-I2-(1-methyl-ethylidene)-amino|-oxy|-ethyl|-2-(4-(6-khpor-2 -quinoxalinyloxy)-phenoxy|-propanoate (propaquizafop), 2-chloro-M-(2-ethyl-b-methyl-phenyl)-M-|(1-methyl-ethoxy)-methyl)-acetamide (propisochlor), sodium She) with complex methyl ether salt. 2-I(K4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl)-carbonyl|-amino|-sulfonyl|-benzoic acid acids (propoxycarbazone-sodium), 8-phenylmethyl-M,M-dipropyl-thiocarbamate (prosulfocarb),

M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'-(2-(3,3,3-trifluoro-propyl)-phenyl-sulfonyl)-urea (prosulfuron ), ethyl-(2-chloro-5-(4-chloro-5-difluorometh-oxy-1-methyl-1H-pyrazol-3-yl)-4-fluoro-phenoxy)|-acetate -I (pyraflufen-ethyl ), 1-(3-chloro-4,5,6,7-tetrahydro-pyrazolo|1,5-a|Ipyridin-2-yl)-5-(methyl-2-propynylamino)-1H-pyrazole-4- carbonitrile o (pyrazolyl), 4-(2,4-dichloro-benzoyl)-1,3-dimethyl-5-(4-methyl-phenylsulfonyloxy)-pyrazole (pyrazolate), 2) 4-(2,4-dichlorobenzoyl) -1,3-dimethyl-5-(phenylcarbonylmethoxy)-pyrazole (pyrazoxifene),

M-(4,6-dimethoxy-pyrimidin-2-yl)-M'-(4-ethoxycarbon-1-methyl-pyrazol-5-yl-sulfonyl)-urea o (pyrazosulfuron-ethyl), diphenyl-methanone-O -(2,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoyl|-oKxime) (pyribenzoxime), b-chloro-3-phenyl-4-pyridazinol (pyridafol),

O-(6-chloro-3-phenyl-pyridazin-4-yl)-8-octyl-thiocarbonate (pyridate), b-chloro-3Z-phenyl-4-pyridazin-4-ol (pyridatol), 7-(4 ,6-dimethoxy-2-pyrimidinyl)-thio|-3-methyl-1(ZH)-isobenzofuranone (pyrifthalide), complex methyl ester of 2-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoic acid (pyriminobac-methyl), sodium salt of 2-chloro-6-(4,6-dimethoxy-pyrimidin-2-ylthio)-benzoic acid (pyrithiobac-sodium),

F) 3,7-dichloro-quinoline-3-carboxylic acid (quinchlorac), 7-chloro-3-methyl-quinoline-3-carboxylic acid (quin-merac), ka (complex ethyl ether, complex tetrahydro-2-furanyl -methyl ether) 2-I4-(b-chloro-2-quinoxaliniloxy)-phenoxy|-propanoic acid (quizalofop, -ethyl, -P-ethyl, -P-tefuryl), because M-(4,6-dimethoxy- Pyrimidin-2-yl)-M''(3-ethylsulfonylpyridin-2-yl-sulfonyl)-urea (rimsulfuron), 2-(1-ethoxyimino-butyl)-5-(2-ethylthiopropyl)-3-hydroxy-2 -cyclohexen-1-one (sethoxydim), b-chloro-2,4-bis-ethylamino-1,3,5-triazine (simazine), /2-(2-chloro-4-methylsulfonyl-benzoyl)-cyclohexane- 1,3-dione (sulcotrione), 2-(2,4-dichloro-5-methylsulfonylamino-phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-ZH-1,2,4-triazole-3 -one 65 (sulfentrazone), M-phosphonomethyl-glycine-trimethylsulfonium (sulfosate),

M-(4,6-dimethoxy-pyrimidin-2-yl)-M'(2-ethylsulfonyl)-imidazo|1,2-a|pyridine-3-sulfonamide (sulfosulfuron),

b-chloro-4-ethylamino-2-tert.butylamino-1,3,5-triazine (terbuthylazine), 2-tert.butylamino-4-ethylamino-b-methylthio-1,3,5-triazine (terbutrin), 2-chloro-M-(2,6-dimethyl-phenyl)-M-(3-methoxy-2-thienyl-methyl)-acetamide (thenylchlor), 2-difluoromethyl-5-(4,5-dihydro -thiazol-2-yl)-4--2-methyl-propyl)-6-trifluoromethyl-pyridine-3-carboxylic acid (thiazopyr), 6-(6,7-dihydro-6,6-dimethyl-ZH,5H -pyrrole|2,1-c1-1,2,4-thiadiazol-3-ylideneamino)-7-fluoro-4-(2-propynyl)-2H-1,4-ben zoxazin-3-(4H)-one (thidiazimin),

M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'-(2-methoxycarbonyl-thien-3-yl-sulfonyl)-urea 7/0 (thifensulfuron-methyl) , 2-(ethoxyimino-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2-cyclohexen-1-one (thralcoxidim), 5-(2,3,3-trichloro-2 -propenyl)-disopropyl carbamotisoate (trialate),

M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'-(2-(2-chloro-ethoxy)-phenylsulfonyl|-urea (triasulfuron),

M-methyl-M-(4-methoxy-β6-methyl-1,3,5-triazin-2-yl)-M'(2-methoxy-carbonyl-phenylsulfonyl)-urea (tribenuron-methyl), (3, 5,6-trichloro)-pyridin-2-yl-oxy-acetic acid (triclopyr), 75 2-(3,5-dichloro-phenyl)-2-(2,2,2-trichloro-ethyl) oxirane (tridiphan ), sodium salt

IM-I (IK4,b6-dimethoxy-2-pyrimidinyl)-amino)-carbonyl/)-3-(2,2,2-trifluoro-ethoxy)-2-pyridinesulfonamide (trifloxysulfuron), 1-amino-2,6 -dinitro-M,M'-dipropyl-4-trifluoromethyl-benzene (trifluralin),

I-(4-dimethylamino-6-(2,2,2-trifluoroethoxy)-1,3,5-triazin-2-yl|-M'(2-methoxy-carbonyl-phenylsulfonyl)-urea (triflusulfuron-methyl) ,

M-(4-methoxy-b-trifluoromethoxy-1,3,5-triazin-2-yl)-M''(2-trifluoromethyl-phenylsulfonyl)-urea (tritosulfuron),

I-I(IK4,b6-dimethoxy-2-pyrimidinyl)-amino)-carbonyl)|-3-(M-methyl-M-methylsulfonyl-amino)-2-pyridine-sulfonamide (see international application mmouu092/10660) , complex methyl ester of 2-ISHCC4,b-dimethoxy-2-pyrimidinyl)-amino|-carbonyl|-amino|-sulfonylI-4-I(methylsulfonyl)-amino|-methyl|-benzoic acid (see application MoOE4335297 ), 4-I4,5-dihydro-4-methyl-5-oxo-(3-trifluoromethyl)-1H-1,2,4-triazol-1-ylI|-2-Ketylsulfonyl)-amino|-5-fluoro -benzenc i) arbothio-amide (see international application IOM/UO95/30661)

C. active beginnings of group 4"), in the event that the compound under (a) represents "E zo 2-(3,4-difluorophenoxy)-4-methyl-6-(1-methyl-3-trifluoromethylpyrazol-o- yl)-pyridine, then the compound under (6) does not mean flufenacet

The preferred substituents of the radicals listed in formula (I) above are explained in c below.

B means preferably a pyrazolyl radical, unsubstituted or mono- or poly-substituted by trifluoromethyl or methyl, or unsubstituted or mono- or poly-substituted by fluorine phenyl radical.

IN? means preferably a phenoxy radical, unsubstituted or substituted by halogen and/or haloalkyl with 1-3 carbon atoms. "

VZ means mainly a hydrogen atom or methyl.

M/ means mainly oxygen or the group -"СО-МН-". t c As ingredients from the active beginnings of group C, the following compounds are especially preferred: h (complex 1-methylhexyl ether) 5-chloro-quinoxaline-8-oxy-acetic acid (cloquintocet), complex » ethyl ether 1-(2,4- dichloro-phenyl)-5-trichloromethyl-1H-1,2,4-triazole-3-carboxylic acid (phenchlorazole-ethyl), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadiphen-ethyl ), diethyl-1-(2,4-dichloro-phenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl) and - 2,4-dichlorophenoxyacetic acid (2 ,4-O) and their derivatives. c As described above, the activity of the above-described mixtures can be further improved in terms of their properties by adding a compound from the third group of herbicides (active beginnings of group 4"). As ingredients from "active o beginnings of group 4", the following compounds are especially preferred: o 20 4-amino -M-(1,1-dimethyl-ethyl)-4,5-dihydro-3-(1-methyl-ethyl)-5-oxo-1H-1,2,4-triazole-1-carboxamide (amicarbazone), M-(4,6-dimethoxy-pyrimidin-2-yl)-M'EM-methyl-M-methylsulfonyl-sulfamoyl)-urea (amidosulfuron), M-benzyl-2-(4-fluoro-3-trifluoromethyl) -phenoxy)-butanamide (beflubutamide),

C-isopropyl-1H-2,1,3-benzothiadiazin-4(ZH)-one (bentazone), methyl-5-(2,4-dichloro-phenoxy)-2-nitro-benzoate (bifenox), sodium salt 2 ,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoic acid (bispyribac-sodium), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), complex |1,1- dimethyl-2-oxo-2-(propenyloxy)|-ethyl ether

Gee! 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1-(2H)-pyrimidinyl)-benzoic acid (butaphenacil-allyl), where 2-(4- chloro-2-fluoro-5-(2-chloro-2-ethoxy-carbonyl-ethyl)-phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-ZH-1,2,4-triazole-

Z-one (carfentrazone-ethyl), M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'-(2-chloro-phenylsulfonyl)-urea 60 (chlorosulfuron), M'-(3-chloro-4-methyl-phenyl)-M,M-dimethyl-urea (chlorotoluron), complex ethyl ether 2-chloro-3-(2-chloro-5-(1,3,4,5 ,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-phenyl|-2-propanoic acid (cinidone-ethyl), (K)-(2-propynyl)-2-(4- (5-chloro-3-fluoro-pyridin-2-yl-oxy)-phenoxy-propanoate (clodinafop-propargyl), 3,6-dichloro-pyridine-2-carboxylic acid (clopyralide), 2-chloro-4-ethylamino -6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazine (cyanazine), 65 M-(4,6-dimethoxy-pyrimidin-2-yl)-ME(2-cyclopropylcarbonyl -phenylsulfonyl)-urea (cyclosulfamuron), 2,4-dichloro-phenoxyacetic acid (2,4-05), 3,6-dichloro-2-methoxy-benzoic acid (dicamba),

(k)-2-(2,4-dichloro-phenoxy)-propanoic acid (dichloroprop-P), methyl 2-I4-(2,4-dichloro-phenoxy)-phenoxy|-propanoate (diclofop-methyl), 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium-methylsulfate (difenzoquat), (5)-(2-ethoxy-1-methyl-2-oxoethyl)-2-chloro-5-(2-chloro- 4-trifluoromethyl-phenoxy)-benzoate (ethoxyphene),

M-(4,6-dimethoxy-pyrimidin-2-yl)-M'(2-ethoxy-phenoxysulfonyl)-urea (ethoxysulfuron), (K)-ethyl-2-I4-(6-chloro-benzoxazol-2- yl-oxy)-phenoxy|-propanoate (phenoxaprop-(P)-ethyl), 4-(2-chloro-phent)-M-cyclohexyl-M-ethyl-4,5-dipdro-5-oxo-1H-tetrazole -1-carboxamide (fentrazamide), isopropyl-M-benzoyl-M-(3-chloro-4-fluoro-phenyl)-OI -alanine (flamprop-isopropyl), 70 isopropyl-M-benzoyl-M-(3-chloro -4-fluoro-phenyl)-I-alaninate (flamprop-isopropyl-i), methyl-M-benzoyl-M-(3-chloro-4-fluoro-phenoxy)-Oil-alanine (flamprop-methyl),

IM-(2,6-difluoro-phenyl)-8-fluoro-5-methoxy-|1,2,4|-triazolo-|1,5-si-pyrimidine-2-sulfonamide (florasulam), complex isopropyl ether / 5-(4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl)-2-chloro-4-fluoro-benzoic acid (fluazolate), 4,5-dihydro-3-methoxy-4- methyl-5-oxo-M-(2-trifluoro-methoxy-phenyl)-sulfonyl|-1-H-1,2,4-triazole-1-carboxamide sodium salt (flucarbazone sodium),

IM-(4-fluoro-phenyl)-M-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy)-acetamide (flufenacet),

IM-(2,6-difluoro-phenyl)-5-methyl-1,2,4-triazolo|1,5-a|-pyrimidine-2-sulfonamide (flumetsulam), complex ethoxy-carbonylethyl ether 5-(2- chloro-4-trifluoromethyl-phenoxy)-2-nitro-benzoic acid (fluoroglycophen-ethyl), 1-(4-chloro-3-(2,2,3,3,3-pentafluoro-propoxymethyl)-phenyl)-5 -phenyl-1H-1,2,4-triazole-3-carboxamide (flupoxam), sodium salt

M-(4,6-dimethoxy-pyrimidin-2-yl)-M'-(33-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl)-urea (flupyrsulfuron-methyl-sodium), 9-hydroxy- UN-fluorene-9-carboxylic acid (flurenol), complex chain (C2-butoxy-1-methyl-ethyl ether, -1-methyl-heptyl ether) (4-amino-3,5-dichloro-b6-fluoro- pyridin-2-yl-oxy)-acetic acid (fluroxypyr, -butoxypropyl, -meptyl), and) 5-methylamino-2-phenyl-4-(3-trifluoromethyl-phenyl)-3(2H)-furanone (flurtamone) , (-ammonium salt) 2-amino-4-(hydroxymethylphosphinyl)-butanoic acid (glufosinate (-ammonium)), M-phosphonomethyl-glycine (-isopropylammonium salt), (glyphosate, -isopropylammonium), "g zo methyl-2 -(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-4-methyl-benzoate (imazametabenz-methyl), 2-(4,5-dihydro-4 -methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethyl-pyridine-3-carboxylic acid o (imazamox), 2-(4,5-dihydro-4-methyl-4 -isopropyl-5-oxo-1H-imidazol-2-yl)-5-ethyl-pyridine-3-carboxylic acid (imazethapyr), sodium salt

M-(4-methoxy-b-methyl-1,3,5-triazin-2-yl)-M'(5-iodo-2-methoxycarbonyl-phenylsulfonyl)-urea me) (iodo-sulfuron-methyl-sodium) , 4-hydroxy-3,5-diiodo-benzonitrile (oxynil), p.

M,M-dimethyl-M'-(4-isopropyl-phenyl)-urea (isoproturon),

IM-(3-(1-ethyl-1-methyl-propyl)-isoxazol-5-yl)-2,6-dimethoxy-benzamide (isoxaben), (4-chloro-2-methyl-phenoxy)-acetic acid ( MOSRA), 2-(4-chloro-2-methyl-phenoxy)-propionic acid (mecoprop), 2-(2-benzthiazolyloxy)-M-methyl-M-phenyl-acetamide (mefenacet), 4-amino-3- methyl-b-phenyl-1,2,4-triazin-5(4H)-one (methamitron), M-(2,6-dichloro-3-methyl-phenyl)-5,7-dimethoxy-1,2 ,4-triazolo|1,5-a|-pyrimidine-2-sulfonamide with c (methosulam), 4-amino-b6-tert.butyl-3-methylthio-1,2,4-triazine-5(4H)- he (metribuzin), . M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M-(2-methoxy-carbonyl-phenylsulfonyl)-urea and? (metsulfuron-methyl), 1-amino-M-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzene (pendimethalin),

IM-(3,4-dichloro-phenyl)-propanamide (propanil), sodium salt of complex methyl ether 2-IK4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4- triazol-1-yl)u-carbonyl)|-amino|-sulfonyl|-benzoic acid (propoxycarbazone-sodium), 3-phenylmethyl-M,M-dipropyl-thiocarbamate (prosulfocarb), ethyl-(2-chloro- 5-(4-chloro-difluoromethoxy-1-methyl-1H-pyrazol-3-yl)-4-fluoro-phenoxy|-acetate (pyraflufen-ethyl), o 7-chloro-3-methyl-quinoline-8-carbon acid (quinmerac), M-phosphonomethyl-glycine-trimethylsulfonium 2) (sulfosate), M-(4,6-dimethoxy-pyrimidin-2-yl)-M'(2-ethylsulfonate)-imidazo 11,2-a|pyridine -3-sulfonamide 5p (sulfosulfuron), 2-tert.butylamino-4-ethylamino-b-methylthio-1,3,5-triazine (terbutrin), o M-(4-methoxy-b6-methyl-1,3, 4-triazin-2-yl)-N'-(2-methoxycarbonyl-thien-3-yl-sulfonyl)-urea i" (thifensulfuron-methyl), 2-(ethoxyimino-propyl-)-3-hydroxy-5- (2,4,6-trimethyl-phenyl)-2-cyclohexen-1-one (thralkoxide), 5-(2,3,3-trichloro-2-propenyl)-diisopropyl carbamotisoate (triallate),

M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'-(2-(2-chloro-ethoxy)-phenyl-sulfonyl|-urea (triasulfuron),

M-methyl-M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonyl-phenylsulfonyl)-urea (tribenuron-methyl),

F) IM-I(IK4,b-dimethoxy-2-pyrimidinyl)-amino)|-carbonyl/)-3-(2,2,2-trifluoro-ethoxy)-2-pyridinesulfonamide sodium salt (trifloxysulfuron), 1-amino-2,6-dinitro-M,M-dipropyl-4-trifluoromethyl-benzene (trifluralin),

M-(4-methoxy-b6-trifluoromethoxy-1,3,5-triazin-2-yl)-M'2-trifluoromethyl-phenylsulfonyl)-urea bo (tritosulfuron).

In particular, the best means according to the invention are selective herbicidal means, which differ in the content of a mixture of active substances, which contains a) M-(4-fluorophent)-6-III-trifluoromethyl)phenoxy|-2-pyridinecarboxamide (picolinafen) or 2- (3,4-difluorophenoxy)-4-methyl-6-(1-methyl-3-trifluoromethylpyrazol-5-yl)-pyridine and that b) one or more compounds from the second group of herbicides, which includes those mentioned above under (b) active beginnings (active beginnings of group 2"), while in the case that compound (a) represents 2-(3,4-difluorophenoxy)-4-methyl-6-(1-methyl-3-trifluoromethylpyrazol-b-yl) -pyridine, then the compound from group (6) does not mean flufenacet, and also, if necessary, d) at least one of the above-mentioned compounds of active beginnings of group C that improve the tolerance of cultivated plants, while preference is given to the compounds that were named above as the best.

In addition, it is worth mentioning selective herbicides, which differ in the content of a mixture of active 7/o beginnings, which includes (a) picolinafen, and (6) M-isopropyl-M-(4-fluorophenyl)-amide (bB-trifluoromethyl-1 ,3,4-thiadiazol-2-yl-oxy)-acetic acid (flufenacet), and (c) optionally, one or more compounds from the group consisting of 2-6-bis-(4,6-dimethoxy) sodium salt -pyrimidin-2-yl-oxy)-benzoic acid (bispyribac sodium),

IM-(2,6-difluoro-phenyl)-8-fluoro-5-methoxy-|1,2,4|-triazolo-|1,5-s|I-pyrimidine-2-sulfonamide (florasulam), sodium salt . M-(4,6-dimethoxy-pyrimidin-2-yl)-M'-(3-methoxycarbonyl-6-tri-fluoromethyl-pyridin-2-yl-sulfonyl)-urea (flupyrsulfuron-methyl-sodium), M, M-dimethyl-M'-(4-isopropyl-phenyl)-urea (isoproturon),

IM-(2,6-dichloro-3-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo|1,5-a|-pyrimidine-2-sulfonamide (methosulam), 1-amino- M-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzene (pendimethalin) and ethyl-(2-chloro-5-(4-chloro-5-difluorometh-oxy-1-methyl) -1H-pyrazol-3-yl)-4-fluoro-phenoxy|-acetate (pyrafluphenethyl).

It is also worth mentioning selective herbicides, which differ in the content of a mixture of active ingredients, which includes (a) picolinafen, and (6) 2-(2-methoxycarbonyl-phenylsulfonylaminocarbonyl)-4-methyl-5-n.-propoxy-2, 4-dihydro-ZH-1,2,4-triazol-3-one i) or the sodium salt of this compound (propoxycarbazone sodium), and (c) optionally, one or more compounds from the group consisting of

IM-(4,6-dimethoxy-pyrimidin-2-yl)-ME(M'-methyl-M-methylsulfonyl-sulfamoyl)-urea (amidosulfuron), sodium salt of 2,6-bis-(4 ,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoic acid (bispyribac-sodium), 2-(4-chloro-2-fluoro-5-(2-chloro-2-ethoxycarbonyl-ethyl)-phenyl)- 4-difluoromethyl-5-methyl-2,4-dihydro-ZH-1,2,4-triazol-o

Z-one (carfentrazone-ethyl), complex ethyl ester with 2-chloro-3-(2-chloro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindole) -2-yl)-phenyl|-2-propanoic acid (cinidone-ethyl), 2-chloro-4-ethylamino-6-(1-cyano-1-methyl-ethylamino)-1,3,5-triazine (cyanazine ), me) 2,4-dichloro-phenoxyacetic acid (24-03), (K)-2-(2,4-dichloro-phenoxy)-propanoic acid (dichloroprop-P), i-

IM-(2,6-difluoro-phenyl)-8-fluoro-5-methoxy-|1,2,4|-triazolo-|1,5-si-pyrimidine-2-sulfonamide (florasulam),

IM-(4-fluoro-phenyl)-M-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yl-oxy)-acetamide (flufenacet), sodium salt. M-(4,6-dimethoxy-pyrimidin-2-yl)-M'-(3-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl)-urea (flupyrsulf-uron-methyl-sodium), (complex -2-butoxy-1-methyl-ethyl ether, complex -1-methyl-heptyl « 420 ether). (4-amino-3,5-dichloro-6-fluoro-pyridin-2-yl-oxy)-acetic acid (fluroxypyr, -butoxypropyl, -meptyl), pa) c sodium salt M-(4-methoxy-b- methyl-1,3,5-triazin-2-yl)-M'(5-iodo-2-methoxycarbonyl-phenylsulfonyl)-urea. (iodosulfuron-methyl-sodium), M,M-dimethyl-M'-(4-isopropyl-phenyl)-urea (isoproturon), and? 2-(4-chloro-2-methyl-phenoxy)-propionic acid (mecoprop),

IM-(2,6-dichloro-3Z-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo|1,5-a|-pyrimidine-2-sulfonamide (methosulam), 4-amino- 6-tert.butyl-3-methylthio-1,2,4-triazin-5-(4H)-one (metribuzin), -I M-(4-methoxy-b-methyl-1,3,5-triazin- 2-yl)-M'(2-methoxycarbonyl-phenylsulfonyl)-urea (metsulfuron-methyl), 1-amino-M-(1-ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzene ( pendimethalin), o M-(4-methoxy-b-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonyl-thien-3-yl-sulfonyl)-urea 2) (thiphen- sulfuronone-methyl),

M-methyl-M-(4-methoxy-b6-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonyl-phenylsulfonyl)-urea o (tribenuron-methyl), i» I- I(IK4,b-dimethoxy-2-pyrimidinyl)-amino)|-carbonyl/)-3-(2,2,2-trifluoro-ethoxy)-2-pyridinesulfonamide sodium salt (trifloxysulfuron),

M-(4-methoxy-b6-trifluoromethoxy-1,3,5-triazin-2-yl)-M'2-trifluoromethyl-phenyl-sulfonyl)-urea dv (tritosulfuron).

It is also worth mentioning selective herbicides that differ in the content of a mixture of active ingredients, (F, which includes ka (a) picolinafen, and (6). 2-(2--riftomethoxy-phenylsulfonylaminocarbonyl)-4-methyl-5-methoxy- 2,4-dihydro-ZH-1,2,4-triazol-3-one boron or the sodium salt of this compound (flucarbazone sodium), and (c) if necessary, one or more compounds from the group that includes sodium salt 2 ,6-bis-(4,6-dimethoxy-pyrimidin-2-yl-oxy)-benzoic acid (bispyribac-sodium), 3,5-dibromo-4-hydroxy-benzonitrile (bromoxynil), 2-(4-chloro -2-fluoro-5-(2-chloro-2-ethoxycarbonyl-ethyl)-phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-ZH-1,2,4-triazol-65 Z-one (carfentrazone-ethyl), complex ethyl ester 2-chloro-3-(2-chloro-5-(1.3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)- phenyl|-2-propanoic acid

(cinidone-ethyl), (K)-(2-propynyl)-2-(4-(5-chloro-3-fluoro-pyridin-2-yl-oxy)-phenoxy-propanoate (clodinafop-propargyl), C3, b-dichloro-pyridine-2-carboxylic acid (clopyralid), 2,4-dichloro-phenoxyacetic acid (2,4-05), 3,6-dichloro-2-methoxy-benzoic acid (dicamba), (K)- ethyl 2-I4-(6-chloro-benzoxazol-2-yl-oxy)-phenoxy|-propanoate (fenoxaprop-(P)-ethyl),

IM-(2,6-difluorophenyl)-8-fluoro-5-methoxy-|1,2,41-triazolo-|1,5-c|-pyrimidine-2-sulfonamide (florasulam),

M-(fluoro-phenyl)-M-isopropyl-2-(5-trifluoromethyl-1,3,4-thia-diazol-2-yl-oxy)-acetamide (flufenacet), sodium salt

M-(4,6-dimethoxy-pyrimidin-2-yl)-M'-(33-methoxycarbonyl-6-trifluoromethyl-pyridin-2-yl-sulfonyl)-urea (flupyrsulfuron-methyl-sodium), (complex-2 -butoxy-1-methyl ether, complex -1-methyl-heptyl ether) 7/0. "4-amino-3,5-dichloro-6b-fluoro-pyridin-2-yl-oxy)-acetic acid (fluroxypyr, -butoxypropyl, -meptyl), methyl-2-(4,5-dihydro-4-methyl -4-isopropyl-5-oxo-1H-imidazol-2-yl)-4-methyl-benzoate (imazametabenz-methyl), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo- 1H-imidazol-2-yl)-5-methoxymethyl-pyridine-3-carboxylic acid (imazamox), sodium salt

M-(4-methoxy-b-methyl-1,3,5-triazin-2-yl)-M'(5-iodo-2-methoxycarbonyl-phenylsulfonyl)-urea (iodosulfuron-methyl-sodium), M,M -dimethyl-M'-(4-isopropyl-phenyl)-urea (isoproturon), (4-chloro-2-methyl-phenoxy)-acetic acid (MCPA), 2-(4-chloro-2-methyl-phenoxy) - propionic acid (mecoprop),

IM-(2,6-dichloro-3Z-methyl-phenyl)-5,7-dimethoxy-1,2,4-triazolo|1,5-a|-pyrimidine-2-sulfonamide (methosulam), 4-amino- 6-tert.butyl-3-methylthio-1,2,4-triazin-5(4H)-one (metribuzin),

M-(4-methoxy-b6-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonyl-phenylsulfonyl)-urea (methsulfuron-methyl), 1-amino-M-( 1-ethyl-propyl)-3,4-dimethyl-2,6-dinitro-benzene (pendimethalin), sodium salt of complex methyl ether 2-I ((4,5-dihydro-4-methyl-5-oxo-3- propoxy-1H-1,2,4-triazol-1-yl)-carbonyl|-amino|sulfonyl)|-benzoic acid (propoxycarbozone-sodium), ethyl-2-chloro-5-(4-chloro-5-difluoromethoxy -1-methyl-1H-pyrazol-3-yl)-4-fluoro-phenoxy|-acetate (pyraflufen-ethyl), sc two M-(4,6-dimethoxy-pyrimidin-2-yl)-M'"( 2-ethylsulfonyl)-imidazo|1,2-a|pyridine-3-sulfonamide (sulfosulfuron),

M-(4-methoxy-b-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonyl-thien-3-yl-sulfonyl)-urea i) (thifensulfuron-methyl), 2 -(ethoxyimino-propyl)-3-hydroxy-5-(2,4,6-trimethyl-phenyl)-2-cyclohexen-1-one (thralkoxide), 3-(2,3,3-trichloro-2-propenyl) )-disopropyl carbamothioate (triaplat),

M-methyl-M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbon-phensulfonate)-urea "gzo (tribenuron-methyl),

I-I(IK4,b-dimethoxy-2-pyrimidinyl)-amino)|-carbonyl/)-3-(2,2,2-trifluoro-ethoxy)-2-pyridinesulfonamide sodium o salt (trifloxysulfuron), c

M-(4-methoxy-b6-trifluoromethoxy-1,3,5-triazin-2-yl)-ME2-trifluoromethyl-phenylsulfonyl)-urea (tritosulfuron). me)

It was unexpectedly found that the above herbicidal mixtures of 2,6-disubstituted pyridine derivatives of the general formula (I) and the above active groups 2, if necessary in combination with active groups C and 4, with very good tolerance by useful plants have particularly high herbicidal activity and can be used for selective control of weedy vegetation in various crops, in particular wheat crops, but, in addition, in corn crops, barley and rice crops. "

Unexpectedly, the herbicidal activity of the proposed herbicidal mixtures of compounds of the above groups 1 and 2 pt") c significantly exceeds the sum of the actions of each individual active substance.

And thanks to this, not just additional activity is obtained, but an unforeseen synergistic activity. New and? herbicide mixtures are well tolerated by many: different crops. At the same time, the new herbicide mixtures are also suitable for combating such weedy vegetation, which is usually difficult to combat. Therefore, new herbicide mixtures represent a valuable extension of the spectrum of available selective herbicides. -I It was unexpectedly found, in addition, that the above herbicidal mixtures of 2,6-disubstituted pyridine derivatives of the general formula (I) and an antidote (active principles of group 3") in combination with one or more of the above active principles of group 2 with very good tolerance by useful plants, they have particularly 2) high herbicidal activity and can be used for selective control of weedy vegetation in various crops, in particular grain and corn crops, primarily in wheat crops, as well as in soybean crops and potato crops and In addition, it was unexpectedly found that both 2,4-dichlorophenoxy-acetic acid as a substance with herbicidal action and its derivatives can be used as the above-described antidotes.

Compounds diethyl-1-(2,4-dichlorophenyl)-4,5-dihydro-5--methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl), two (1-methylhexyl)-|(5- chloro-8-quinolinyl)-oxy|-acetate (chloroquintocet-methyl) and ethyl 1-(2,4-dichlorophenyl)-5-(trichloromethyl)-1H-1,2,4-triazole-3-carboxylate ( fenchlorazol-ethyl) are described in the following (F) patent applications: MoOMorE3939503, EP191736 or OE3525295 applications. 2,4-O is a well-known herbicide. It should be considered unexpected, in addition to the fact that of the numerous known antidotes capable of preventing the harmful effect of the herbicide on cultivated plants, it is the above-mentioned active principles of group C that are able to almost completely stop the harmful effect of the compounds of formula (I) in combination with one or more of of the active beginnings of group 2 given above on cultivated plants, without at the same time reducing the herbicide effect on weedy vegetation.

At the same time, it is worth emphasizing the particularly predominant effect of especially the best active beginnings added to the mixture, from the active beginnings of group C, in particular due to the careful attitude to grain plants as cultural plants, such as, for example, rice, wheat, barley and rye.

The following plants can be treated with the proposed herbicide mixtures, for example:

Dicotyledonous weeds of the genera: Zipariz, Ieridiyt, Szayt, Z(ePagia, Maiygisagia, Ap-I(yetiv, Saiyipzoda,

Speporodisht, Opisa, Bepesio, Atagapiyiv, Rogishasa, Hapipyisht, Sopmoimshiiv5, Irotoea, Roiudopyt, Zezbapia,

Atrgosia, Siegvits, Sagatsivus, Zopspiv, Zoiagistus, Cogirra, Koiiaia, I ipdegpia, atisht, Megopisa, Archiope, Etech,

Bashga, Mioia, Saieorziv, Rarameg, Sepiatsgea, TgyoYiisht, Kapipstzshv, Tagahasit.

Dicot cultures of rocks: bozzurisht, Siusipe, Ve(a, Yuaisiv, Rpazeoiiv, Ri-site, ZoYapit, Hipit, Irotoea,

Misia, Misoiapa, I usoregvisop, Agaspiv, Vgazvisa, I asiisa, Sisytiv, Sirigria.:

Monocotyledonous weeds of the genera: Espipospioa, Zeiagia, Rapisit, Oidnaga, Rpeit, Roa, Reviisa, EIIeisipe,

Vgaspiagia, I oiisht, Vgotiv, Amepa, Suregiv, Zogupyt, Adgo-rugop, Supodop, Mopospogia, Ritrgiv(uiiv, 70 zaditsagi, Eieospagiv, Zsigryz, Razraisht, Izspaetit, Zrpeposiega, Juasiuiosiepisht, Adgoviiv, AIoresitv, Arega,

Raiagiv

Monocot cultures of rocks: Ogula, 7ea, Tiysit, Nogdets, Amepa, Besaiee, Zogopyt, Rapisit, Zasspagyt,

Apapavz, Azragadiz, AyPyt.

However, the use of the proposed herbicide mixtures is not limited to these species, but 7/5 also applies to other plants.

According to the invention, all plants and plant parts can be processed. At the same time, plants should be understood as all plants and plant populations, such as desirable and undesirable wild plants or cultivated plants (including wild cultivated plants). Cultivated plants can be plants that are grown by traditional methods of cultivation or optimization or by biotechnological methods and genetic engineering methods or a combination of these methods, including transgenic plants and including such plants that are protected under the legislation for the preservation of varieties or those that are not protected.

The parts of plants should be understood as all above-ground and underground parts and organs of plants, such as a shoot, leaf, flower, root, while you can name, for example, leaves, needles, stems, flowers, fruiting bodies, fruits and seeds, as well as roots , vegetative and generative seed material, for example, petioles, tubers, p

Rhizomes, layers and seeds.

Treatment of plants and parts of plants with active beginnings according to the invention is carried out by applying i) active beginning directly to plants or plant parts or to their environment, to their living environment or in storage, i.e. in the room for their preservation, while the treatment is carried out according to usual methods, such as, for example, immersion, spraying, evaporation, dusting, scattering, "E zo smearing, and, in addition, with propagating material, in particular, seed material, by applying a single or multilayer coating in the form of a shell. at

The synergistic effect of the proposed herbicide mixtures is particularly pronounced at certain concentration ratios. However, the weight ratios of individual active substances in herbicide mixtures can vary within relatively wide limits. 0.01-1000 wt. parts, preferably 0.05-500 wt. parts and in particular 0.1-100 wt. parts of the active part - the beginning of group 2.

The predominant effect of tolerance by cultivated plants of the proposed herbicide mixtures at certain concentration ratios is also particularly pronounced. However, the weight ratios of individual active substances in herbicide mixtures can vary within relatively wide limits. 0.001-100Owag is usually applied to the weight part of the active beginning of formula (I), its salts or its mixtures with active beginnings of group 2 /7-Z. parts, preferably 0.01-100 wt. parts and in particular 0.1-1Owag. parts of one of the compounds (antidotes) named above or under (c) that improve the tolerance of cultivated plants. ;" Herbicide mixtures can be converted into conventional preparation forms, for example, solutions, emulsions, spraying powders, suspensions, powders, dusting agents, pastes, soluble powders, granules,

Concentrates in the form of suspensions and emulsions, natural and synthetic substances impregnated with an active principle, as well as thinly encapsulated in polymeric substances of the form.

These compounds are obtained in a known way, for example, by mixing the active ingredient with fillers, i.e. liquid solvents and/or solid carriers, if necessary with the use of surface-active agents, i.e. emulsifiers and/or dispersants and/or foaming agents.

These compounds are obtained in a known way, for example, by mixing the active substance with fillers, i.e. liquid solvents and/or solid carriers, if necessary with the use of surfactants, i.e. emulsifiers and/or dispersants and/or foaming agents.

In the case of using water as a filler, organic solvents can also be used as auxiliaries. As liquid solvents, aromatic hydrocarbons are mainly used, for example, dixylene, toluene, or alkylnaphthalenes, chlorinated aromatic and chlorinated aliphatic hydrocarbons, for example, chlorobenzene, ethylene chloride or methylene chloride, aliphatic hydrocarbons, for example, cyclohexane, or

F) paraffins, for example, petroleum fractions, mineral and vegetable oils, alcohols, for example, butanol or glycol, as well as their simple and complex esters, ketones, for example, acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, highly polar solvents, for example, dimethylformamide and dimethyl sulfoxide, as well as water. As solid carriers are used: for example, ammonium-based salts and ground natural rocks, such as, for example, kaolin, alumina, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth and ground synthetic rocks, for example, highly dispersed silicic acid , aluminum oxide and silicates. For example, crushed and fractionated natural rocks, such as calcite, marble, pumice, sepiolite, dolomite, as well as synthetic granules from inorganic and organic grinding, as well as granules from organic materials, are used as solid carriers for granules. , for example, bran, coconut husk,

corn cobs and tobacco stalks. As emulsifying and/or foaming agents, nonionic and anionic emulsifiers are used, for example, polyoxyethylene and fatty acid esters, polyoxyethylene and fatty alcohol ethers, for example, alkylaryl polyglycol ether, alkyl sulfonates, alkyl sulfates, aryl sulfonates, as well as protein hydrolysates. As a dispersant, for example, lignin sulfite alkali and methyl cellulose are used.

Binders, for example, carboxymethyl cellulose, natural and synthetic powdery, granular or latex polymers, for example, gum arabic, polyvinyl alcohol, polyvinyl acetate, as well as natural phospholipids, for example, cephalins and lecithins, and synthetic phospholipids can also be used in the compositions. /0 Other additives can be mineral and vegetable oils.

Dyes can also be used, such as, for example, inorganic pigments, for example, iron oxide, titanium oxide, ferrocyanine blue, and organic dyes, for example, alizarin, azo- and metal phthalocyanine dyes, and trace elements in the form of salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.

In the compositions, the concentration of active substances, including active principles acting as antidotes, usually ranges from 0.1 to 95 wt. 95, preferably from 0.5 to UOvag. 90.

The proposed herbicide mixtures are usually used in the form of forms prepared from them for use. However, it is also possible to mix the individual active substances in the tank during application.

The new herbicide mixtures can be used as such or in the form of compositions in a mixture with known herbicides. At the same time, forms prepared from compositions can be used for or individual compositions mixed when used in a tank. It is also possible to use in the form of compositions in a mixture with known active substances, for example, fungicides, insecticides, acaricides, nematicides, means for protection against birds, substances for accelerating growth, nutrients for plants and means for improving the structure of the soil. In addition, for certain purposes of application, in particular, during post-emergence treatment, it may be beneficial to add plant-borne mineral or vegetable oils to the compositions as additional additives (for example, the commercial product "Oieo Yuropi 11 E") or salts of an ammonium base, and) for example, ammonium sulfate or ammonium rhodanide.

New herbicide mixtures can be used as such or in the form of their compositions or prepared from them by further dilution of forms for use, such as, for example, ready-to-use solutions, gas suspensions, emulsions, powders, pastes and granules. Application is by conventional methods, such as watering, spraying, spreading, spraying or scattering. and,

Herbicidal mixtures according to the invention can be applied before or after the emergence of plants, that is, by means of pre-emergence treatment or post-emergence treatment. they can also be applied to the soil before sowing.

With herbicides, a synergistic effect is always present if the herbicidal activity of the herbicide me)

The activity of the mixture exceeds the activity of the individual active substances used. uh-

The expected activity of this mixture of two herbicides can be calculated in the following way (see COLBY SR.: »"SaIscaipod zupegadivziis apa apiadopiviis gezropzez oi Ppegriside sotbipayopvg", U/eedz 15, pp. 20-22, 1967):

In the event that X-95 is affected by herbicide A (the active ingredient of formula I) at r kg/ha of the applied amount and Y-95 is affected by herbicide B (the active ingredient of formula II) at 4 kg/ha of the applied amount with c and E - expected damage by herbicides A and B at p and 4 kg/ha of the applied quantity, then E-ХУ-(Х"/100). ;" If the actual damage is greater than the calculated one, the mixture is superadditive in relation to the activity, that is, it shows a synergistic effect.

Examples of use: - I Use the usual compounds of the applied active principles. Propoxycarbazone sodium is used in the form of 7090-th aqueous granules, rlufenacet - in the form of b090-th aqueous granules and picolinafen - in the form of o 7590-th aqueous granules. A liquid for spraying containing 0.1 96 additives 2) Renex-36 is prepared from active buds.

Example A o Post-emergence treatment/greenhouse i» Control plants are grown in a greenhouse under constant control of conditions (temperature and light).

Control plants with a height of 5 to 15 cm are sprayed with a control solution. At the same time, the concentration of the liquid for spraying is chosen so that each desired amount of active substance is used in 500 liters of water/ha.

After spraying, the plant is allowed to stand in a greenhouse under unchanged conditions in relation to light and temperature.

Ф) Approximately three weeks after treatment, the degree of damage to cultured plants is determined in 95 in comparison with the development of untreated control plants.

This means: in 095 there is no damage (corresponds to the untreated control plant): 100965 complete destruction/damage

Active starters, applied amounts, control plants and results can be seen from the tables below: 65 Concentration of active starter in g/ha Ameptsia observed Ameptsia calculated"

Flufenaceh nn ny ny Po nin ny ny pe po -e 0020-85 LA . . 5. | ( nn zhyshyshn nin fluphenacet picolinafen bozo zochzo 70 " Values are calculated according to Colby

Table A-2 0 |Concentration of the active principle in g/ha (Oidiagia observed |Oidiiagia calculated" flufenacet pish pish nin y 116 piuafeno 611111 fluphenacet picolinafen taBezo yuyu boho yuyu " Values are calculated according to Colby

Table A-3

The concentration of the active principle in g/ha of Espipospis was observed |Espipospis was calculated" se flufenacet viyu 11 o lyud 1111171111111181111111110ю601 " The values were calculated according to Colby chI so

Table A-A with flufenacet v1116 1 o people 111171111111ю1111101ю011

F and - "The values are calculated according to Colby

Table A-5 - c 0 | Concentration of the active principle in g/ha Protoea observed oral calculated" ; flufenacet 1 and?

Photo 80117078 s vv i" " The values are calculated according to Colby

Table A-6

Concentration of the active principle in g/ha Language. observed Misia calculated" about Flufenaceh pni i Po t piulafeno 18111 60 " Values calculated according to Colby

Table A-7

Concentration of the active principle in g/ha of Amepts observed Amepts calculated" b5 tyu 71180110 -000000М---2--5 5 0---- nn nyshshsh ni shshshny yuyu 17111111 vv o nin i ily o yuyu in 00010091 22000000 Motenratsa apuvnoy fire observed|soyutt calculated -k 0 -- НЦТ.О-О2ШЗШЗТННН-- in vyv o - zo 22202000 Metenratsya akuvuno pozhu vtia|rovdotiya observed|rovdotiya calculated as yuyu o vv so picolinafen yuyu 1 in 12-- 5 « 5 :I lEKN«-- i- yuyu 17111111 vv " pn: ni ni zn No NN z shi inshshshsh shshshsh shsh N Z ch - nn shi ni i poh NN g" " The values are calculated according to Colby

Example B - Experiments on an open pound / grain crop. Post-emergence processing in the spring

To study possible synergism, determine the effect of compounds picolinafen and propoxycarbazone-sodium on (95) weedy grasses of agricultural importance in grain culture under conditions of open ground. Experiments of this 50 are carried out on small plots of land located on agricultural arable land. At the same time, choose areas with a fairly good development of weedy vegetation. The application of active buds is carried out in the spring in a post-emergence manner on the area with control plants by spraying with a drug with medium-sized drops. To obtain a suitable preparation, the active principles are prepared in the form of 7090th aqueous granulate (70905th by weight of powder dispersed in water) or 7595th aqueous granulate (7590th of powder dispersed in water) and suspended in water. Then the spraying solution is used in the amount of water usually used in practice.

Approximately 8-10 weeks after applying the spraying solution, the herbicidal effect is visually determined. This means:

Ob - no herbicidal effect, 60 10095 - complete destruction of culture or weedy vegetation.

In this experiment, the mixture of active roots shows a pronounced synergistic effect in the fight against various weeds. The action significantly exceeds the value expected for the mixture according to the Colby equation (COLBY 1967) (see tables below). 65 Table B-1:

Concentration: of the active principle in g/ha p inn es vyt esy rozhsyzharonyunsyai 11171111 17777117 yuyu 7/1 voy 00000111501161 911 propoxyzharbazon-sodiipyulnafen | 02000002 war 72220202 Tenintration of the poet's acton in the pa|syasikya observed observed and calculated and protzhsyzharonyunsyad 1111161 chan nyshshzhnishishshn and 72202020 Mokentration of the acton of the current in the tta|vnynnya observed can. calculated proyuzhynaryayutyady 111141 1yu lyuli 07777115 yu1 20 77222022 Tenintration of the acton poet in pia | Mainsyanya t observed Maiitsyanya t calculated tt they shin ny and PIN sch dk yuyu 110011111111111185111111v1101 o11000011111185111111v1101 o11001001111185111111 02000004 01ев1в6 « зо 72020202 Tenintratsia akuvnya to the poet in pa uezhnia observedenorlovnia calculated puti you write and g Fo lyud 77171711 17777750 ne propoxyzharbazon-sodiipiyulnafen | 02000021 510 so 35 and - 22222222 Toschenratsa akuvnou poet in and | it was observed bath is calculated tet rdvy shin ny Pi PNYA nn nin shi shin "20 no s iz" 72220202 Tenintratsia actonoyyu poet in pa|syasikya observedor avshsya calculated protzhsyzharonyunsyady 1111161 chan nyshshshzhnyshishsh

Claims (1)

The formula of the invention T" 1. Herbicide, which is distinguished by the effective content of the herbicidal mixture, which includes a) at least one 2,6-disubstituted derivative of the general formula (I) t B / and what () (F) where there is) EZ 60 where B! - unsubstituted or mono- or polysubstituted by haloalkyl and/or haloalkyl with 1-3 carbon atoms 5-6-ene heterocycle containing 1-3 carbon atoms, or unsubstituted or mono- or polysubstituted by haloalkyl and/or haloalkyl with 1 -3 carbon atoms is a phenyl radical, B?- unsubstituted or substituted by haloalkyl and/or haloalkyl with 1-3 carbon atoms phenoxy radical, BZ - hydrogen atom or methyl, MU - oxygen or group -СО-МН-, (active principle of group 1) and (b) one or several compounds from the second group of herbicides, which contains the following active principles: M-isopropyl-M-(4-fluorophenyl)amide (5-trifluoromethyl-1,3,4-thiadiazol-2-yloxy)acetic acid (flufenacet), 70. 2-(2-Methoxycarbonylphenylsulfonylaminocarbonyl)-4-methyl-5-n.-propoxy-2,4-dihydro-ZH-1,2,4-triazol-3-one or the sodium salt of this compound (propoxycarbozone-sodium) , 2-(2-trifluoromethoxyphenylsulfonylaminocarbonyl)-4-methyl-5-methoxy-2,4-dihydro-ZH-1,2,4-triazol-3-one. or the sodium salt of this compound (flucarbazone-sodium), IM-(3,4-dichlorophenyl)propanamide (propanil), M-2-benzothiazolyl-M,M'-dimethylurea (metabenzthiazuron), 75 4-amino-6-(1 ,1-dimethylethyl)-3-(methylthio)-1,2,4-triazin-5-(4H)-one (metribuzin), 4-(2-chlorophenyl)-M-cyclohexyl-M-ethyl-4,5 -dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamide), 4-amino-3-methyl-b-phenyl-1,2,4-triazin-5(4H)-one (methamitron), 2- (2-Benzothiazolyloxy)-M-methyl-M-phenylacetamide (mefenacet), 4-amino-6-(1,1-dimethylethyl)-3-(ethylthio)-1,2,4-triazine-5(4H)- one (ethiosin) or 1-methylethyl 5-14-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl|-2-chloro-4-fluorobenzoate (fluazolate) (active principle of group 2). 2. The herbicide according to claim 1, which is characterized by the fact that it additionally contains at least one compound that improves the tolerance of cultivated plants from the following group of compounds: А-(1,3-dioxolan-2-ylmethoxyimino)phenylacetonitrile (oxabetrinil), А-( cyanomethoxyimino)phenylacetonitrile (cyometrinil), 4-chloro-M-(1,3-dioxolan-2-ylmethoxy)-A-trifluoroacetophenonexime (fluxofenim), SM 4,6-dichloro-2-phenylpyrimidine (fenclorim), 4-dichloroacetyl- 3,4-dihydro-3-methyl-2H-1,4-benzoxadine o (benoxacor), (1-methylhexyl ester) of 5-chloroquinoxaline-8-oxyacetic acid (cloquintocet), 2,2-dichloro-M-(2 -oxo-2-(2-propenylamino)ethyl)-M-(2-propenyl)uacetamide (OKA-24), anhydride of 1,8-naphthalic acid, ethyl ester of 1-22,4-dichlorophenyl)-5-trichloromethyl- 1TH-1,2,4-triazole-3-carboxylic acid (fenchlorazole-ethyl), phenylmethyl ester of 2-chloro-4-trifluoromethylthiazole-5-carboxylic acid (flurazole), 3-dichloroacetyl-5-(2- furanyl)-2,2-dimethyloxazolidine (furylazole, MOM-13900), 4-dichloroacetyl-1-oxa-4-azaspiro|4,5)dec an (AO 67), 2-dichloromethyl-2-methyl-1,3-dioxolane (MO-191), o 2,2-dichloro-M-(1,3-dioxolan-2-ylmethyl)-M-(2 -propenyl)acetamide (PPO 1292), "o 2,2-dichloro-M,M-di-2-propenylacetamide (dichloroamide), M-(4-methylphenyl)-M'-(1-methyl-1-phenylethyl) urea (dimron), 1-dichloroacetylhexahydro-3,3, va-trimethylpyrrole|1,2-a|Ipyrimidin-6(2H)-one (VAB-145138), o M-(2-methoxybenzoyl)-4-(methylaminocarbonylamino )benzenesulfonamide, i-ethyl-4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadiphen-ethyl), diethyl-1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl- 1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl), (4-chloro-2-methylphenoxy)acetic acid (MCPA), (-)-2-(4-chloro-2-methylphenoxy)propanoic acid (mecoprop) , " 3-dichloroacetyl-2,2,5-trimethyloxazolidine (K-29148) and 2,4-dichlorophenoxyacetic acid (2,4-03 and their derivatives (active principle of group 3). - c 3. The herbicide according to claims 1 or 2, which is characterized by the fact that it additionally contains one or more compounds a from the third group of herbicides, which includes the active principles listed below: "» 2-chloro-M-(ethoxymethyl)-M-( 2-ethyl-b6-methylphenyl)acetamide (acetochlor), sodium salt of 5-(2-chloro-4-trifluoromethylphenoxy)-2-nitrobenzoic acid (acifluorfen sodium), 2-chloro-b-nitro-3-phenoxybenzenamine (aclonifen ), 2-chloro-M-(methoxymethyl)-M-(2,6-diethylphenyl)acetamide -i (alachlor), M-ethyl-M'-isopropyl-b-methylthio-1,3,5-triazine-2 ,4-diamine (ametrine), 4-amino-M-(1,1-dimethylethyl)-4,5-dihydro-3-(1-methylethyl)-5-oxo-1H-1,2,4-triazole- 1-carboxamide (amicarbazone), M-(4,6-dimethoxypyrimidin-2-yl)-ME(M-methyl-M-methylsulfonylsulfamoyl)urea (amidosulfuron), (95) 1n-1,2,4-triazole -3-amine (amitrol), b-chloro-4-ethylamino-2-isopropylamino-1,3,5-triazine (atrazine), c 50 2-(2,4-dichloro-5-(2-propynyloxy)- phenyl/|-5,6,7,8-tetrahydro-1,2,4-triazolo|4,3-a|Ipyridine-Z3(2H)-one (azaphenidine), chz» M-(4,6-dimethoxypyrimidine -2-yl) -M'-(/1-methyl-4--2-methyl-2H-tetrazol-5-yl)-1H-pyrazol-5-ylsulfonyl|urea (azimsulfuron), M-benzyl-2-(4-fluoro- 3-trifluoromethylphenoxy)butanamide (beflubutamide), 4-chloro-2-oxo-3(2H)-benzthiazoloacetic acid (benazolin), M-butyl-M-ethyl-2,6-dinitro-4-trifluoromethylbenzenamine (benfluralin), M -(4,6-dimethoxypyrimidin-2-yl)-M'(2-methoxycarbonylphenylmethylsulfonyl)urea (bensulfuron), o methyl ester ime) 2-(2-I(4-(3,6-dihydro-3-methyl- 2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidinylphenoxy|methyl|-5-ethylphenoxypropanoic acid (benzphendizone), 3-(2-chloro-4-methylsulfonylbenzoyl)-4-phenylthiobicyclo-I|3.2.1 |oct-3-en-2-one 60 "benzobicyclone), ethyl M-benzoyl-M-(3,4-dichlorophenyl)-OH-alanilate (benzoylprop-ethyl), 3-isopropyl-1H-2,1,3 -benzothiadiazin-4(ZH)-one (benzathone), methyl-5-(2,4-dichlorophenoxy)-2-nitrobenzoate (bifenox), sodium salt 2,6-bis-(4,6-dimethoxy-pyrimidine-2 -yloxy)benzoic acid (bispyribac sodium), 2-bromo-3,3-dimethyl-M-(1-methyl-1-phenylethyl)butanamide (bromobutide), 3,5-dibromo-4-hydroxy Ibenzaldehyde-O-(2,4-dinitrophenyl)oxime (bromophenoxime), 65 3,5-dibromo-4-hydroxybenzonitrile (bromoxynil), M-butoxymethyl-2-chloro-M-(2,6-diethylphenyl)acetamide (butachlor ), complex P1,1-dimethyl-2-oxo-2-(2-propenyloxy))ethyl ester 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-fluoromethyl-1-(2H)-pyrimidinyl)benzoic acid (butaphenacil-allyl), 2-(1-ethoxyiminopropyl )-3-hydroxy-5-I(2,4,6-trimethyl-3-(1-oxobutyl)phenyl|-2-cyclohexan-1-one. (butroxydim), 3-ethylbis-(2-methylpropyl)thiocarbamate (butylate), M,M-diethyl-3-(2,4,6-trimethylphenylsulfonyl)-1H-1,2,4-triazole-1-carboxamide (cafenstrol), 2-(11-K-3-chloro- 2-propenyl)oxyimino|propyl|-3-hydroxy-5-(tetrahydro-2H-pyran-4-yl)-2-cyclohexen-1-one (caloxidim, tepraloxidim), 2-(4-chloro-2-fluoro -5-(2-chloro-2-ethoxycarbonylethyl)phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-ZH-1,2,4-triazol-3-7/0one (carfentrazone-ethyl) , 2,4-dichloro-1-(3-methoxy-4-nitrophenoxy)benzene (clomethoxifene), 3-amino-2,5-dichlorobenzoic acid (chloramben), M-(4-chloro-b-methoxypyrimidine-2- yl)-M'-(2-ethoxycarbonylphenylsulfonyl)-urea (chloromuron-ethyl), 1,3,5-trichloro-2-(4-nitrophenoxy)benzene (chloronitrophen), M-(4-methoxy-6-methyl- 1,3,5-triazin-2-yl)-M'-(2-chlorophenylsulfonyl)urea (chlorosulfuron), 75. M'(3-chloro-4-methylphenyl)-M,M-dimethylurea (chlorotoluron), ethyl ester 2-chloro-3-(2-chloro-5-(1,3,4,5,6, 7-hexahydro-1,3-dioxo-2H-isoindol-2-iluphenyl|-2-propanoic acid (cinidone-ethyl), M-(4,6-dimethoxy-1,3,5-triazin-2-yl) -M'-(2-(2-methoxyethoxy)-phenylsulfonyl)urea (cynosulfuron), 2-(1--2-(4-chlorophenoxy)propoxyamino|butyl|-5-(tetrahydro-2H-thiopyran-3-yl) )-1,3-cyclohexanedione 2o (clefoxidim), (E,E)-(k)-2-11-((3-chloro-2-propenyl)oxy|imino|propyl)-3-hydroxy-2-cyclohexene -1-one (clethodim), /(K)-(2-propynyl)-2-I4-(5-chloro-3-fluoropyridin-2-yl-oxy)phenoxypropanoate (clodinafop-propargyl), 3,6-dichloropyridine -2-carboxylic acid (clopyralide), methyl-3-chloro-2-Y(5-ethoxy-7-fluoro(1,2,4-triazolo|1,5-c|Ipyrimidin-2-yl-sulfonyl)amino|benzoate (cloransulam-methyl), 2-chloro-4-ethylamino-6-(1-cyano-1-methylethylamino)-1,3,5-triazine (cyanazine), SC M-(4,6-dimethoxypyrimidin-2-yl )-M'(2-cyclopropylcarbonylphenylsulfonyl)urea (cyclosulfamuron), 2-(1-ethoxyiminobutyl)-3-hydroxy-5-(tetrahydro-2H-thi opyran-3-yl)-2-cyclohexen-1-one (cyclooxydime), butyl i) ester (K)-2-I(4-(4-cyano-2-fluorophenoxy)phenoxy)propanoic acid (cyhalofop-butyl) , 2,4-dichlorophenoxyacetic acid (2,4-05), 3,6-dichloro-2-methoxybenzoic acid (dicamba), (k)-2-(2,4-dichlorophenoxy)propanoic acid (dichloroprop-P), «g z/methyl-2-I4-(2,4-dichlorophenoxy)phenoxy|propanoate (diclofop-methyl), IM-(2,6-dichlorophenyl)-5-ethoxy-7-fluoro|/1,2,) griazolo-|1,5-c|Ipyrimidine-2-sulfonamide (diclosulam), o 1,2-dimethyl-3,5-diphenyl-1H-pyrazolium methylsulfate (difenzoquat), c IM-(2,4-difluorophenyl)-2 -(3-trifluoromethylphenoxy)-pyridine-3-carboxamide. (diflufenizan), 2-(1-KZ,5-difluorophenyl)aminocarbonylhydrazono|ethyl|pyridine-3-carboxylic acid (diflufenzopyr), me) 5-(1-methyl-1-phenylethyl)-1-piperidine carbothioate (dimepiperate), y- (5-)2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide (5-) (dimethenamid), 2-amino-4- (1-fluoro-1-methylethyl)-6-(1-methyl-2-(3,5-dimethylphenoxy)ethylamino)-1,3,5-triazine (dimexiflam), M3,M3-diethyl-2,4- dinitro-b-trifluoromethyl-1,3-diaminobenzene (dinitramine), 6,7-dihydrodipyridoi|1,2-a:2",1-c|pyrazinium (diquat), « 5,8Z-dimethyl-2-difluoromethyl- 4-isobutyl-6-trifluoromethyl-pyridine-3,5-dicarbothioate (dithiopyr), with M'-(3,4-dichlorophenyl)-M,M-dimethylurea (diuron), . 2-(2-(3-chlorophenyl)oxiranylmethyl/|-2-ethyl-1H-inden-1,3-(2H)-dione (epropodan), 3-ethyldipropylthiocarbamate (ERTO), 3-(phenylmethyl) -M-(1,2-dimethyl-propyl)thiocarbamate (esprocarb), M-ethyl-M-(2-methyl-2-propenyl)-2,6-dinitro-4-trifluoromethylbenzenamine (ethalfluralin), (5)- (2-ethoxy-1-methyl-2-oxoethyl)-2-chloro-5-(2-chloro-4-trifluoromethylphenoxy)benzoate (ethoxyphene), -I M-(4,6-dimethoxypyrimidin-2-yl)- M'-(2-ethoxyphenoxysulfonyl)urea (ethoxysulfuron), (K)-ethyl-2-I4-(6-chlorobenzoxazol-2-yloxy)phenoxy|propanoate (phenoxaprop-(P)-ethyl), o 4-(2 -chlorophenyl)-M-cyclohexyl-M-ethyl-4,5-dihydro-5-oxo-1H-tetrazole-1-carboxamide (fentrazamide), 2) isopropyl-M-benzoyl-M-(3-chloro-4- fluorophenyl)-OI -alaninate (flamprop-isopropyl), isopropyl-M-benzoyl-M-(3-chloro-4-fluorophenyl)-I -alaninate (flamprop-isopropyl-y), o methyl-M-benzoyl-M- (3-chloro-4-fluorophenoxy)-OiI-alanine (flamprop-methyl), i» IM-(2,6-difluorophenyl)-8-fluoro-5-methoxy c|Ipyrimidine-2-sulfonamide (florasulam), butyl ester (K)-2-I4-(5-triph tormethyl-pyridin-2-yloxy)phenoxy|propanoic acid (fluazifop, -butyl, -P-butyl), isopropyl ester 5-(4-bromo-1-methyl-5-trifluoromethyl-1H-pyrazol-3-yl)- 2-chloro-4-fluoro-benzoic acid dv (fluazolate), 4,5-dihydro-3-methoxy-4-methyl-5-oxo-M-(2-trifluoromethoxy-phenyl)sulfonyl/)-1-H- 1,2,4-triazole-1-carboxamide F) triium salt (flucarbazone-sodium), ka M-(4-fluorophenyl)-M-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadiazole-2 -yloxy)dacetamide (flufenacet), IM-(2,6-difluorophenyl)-5B-methyl-1,2,4-triazolo|1,5-a|Ipyrimidine-2-sulfonamide (flumetsulam), because pentyl-(2 -chloro-4-fluoro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yluphenoxy)acetate (flumiclorac-pentyl), 2-(7- fluoro-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazin-b6-yl1I-4,5,6,7-tetrahydro-1H-isoindole-1,3- dione (flumioxazin), 2-I(D-chloro-2-fluoro-5-(1-methyl-2-propynyl)oxy|phenyl)-4,5,6,7-tetrahydro-1H-isoindole-1, 93(2H)-dione. (flumipropine), 65 3-chloro-4-chloromethyl-1-(3-trifluoromethylphenyl)-2-pyrrolidinone (fluorochloridone), ethoxycarbonylmethyl ester of 5-(2-chloro-4-trifluoromethylphenoxy)-2-nitrobenzoic acid (fluoroglycophen-ethyl ), 1-(4-chloro-3-(2,2,3,3,3-pentafluoropropoxymethyl)phenyl)-5-phenyl-1H-1,2,4-triazole-3-carboxamide (flupoxam), 1-isopropyl- 2-chloro-5-(3,6-dihydro-3-methyl-2,6-dioxo-4-trifluoromethyl-1(2H)-pyrimidyl)benzoate (flupropacil), sodium salt M-(4,6-dimethoxypyrimidine- 2-yl)-M'-(3-methoxycarbonyl-b-trifluoromethylpyridin-2-ylsulfonyl)urea (flupyr-sulfuron-methyl-sodium), 9-hydroxy-UN-fluorene-9-carboxylic acid (flurenol), (- 2-butoxy-1-methylethyl ester, -1-methylheptyl ester) (4-amino-3,5-dichloro-6-fluoropyridin-2-yloxy)acetic acid (fluroxypyr, -butoxypropyl, -meptyl), 5-methylamino- 2-phenyl-4-(3-trifluoromethylphenyl)-3(2H)-furanone (flurtamone), 7/0 methyl-|(2-chloro-4-fluoro-5-(tetrahydro-3-oxo-1H,ZH- (1,3,4)-thiadiazolo-|3,4-a|-pyridazin-1-ylidene)aminophenylthioacetate (fluthiacet-methyl), 5-(2-chloro-4-trifluoromethyl-phenoxy)-M-methylsulfonyl- 2-nitrobenzamide (fomesafen), 2-ICC(4,b-dimethoxy-2-pyrimidinyl)amino)carbonylamino|)sulfonyl|-4-formylamino-M,M-dimethylbenzamide (foramsulfuron), (-ammonium salt ) 2-amino-4-(hydroxymethylphosphinyl)butanoic acid (glufosinate (-ammonium)), M-phosphonomethylglycine (-isopropylammonium salt), (glyphosate, -isopropylammonium), (methyl ester, u75 7 2-ethoxyethyl ester, -butyl ester ) (kK)-2-I4-(3-chloro-5-trifluoromethyl-pyridin-2-yloxy)phenoxy|propanoic acid (haloxyfop, -methyl, -P-methyl, -ethoxyethyl, -butyl), 3-cyclohexyl- b6-dimethylamino-1-methyl-1,3,5-triazine-2,A(1H,ZH)dione (hexazinone), methyl-2-(4,5-dihydro-4-methyl-4-isopropyl-5- oxo-1H-imidazol-2-yl)-4-methylbenzoate (imazametabenz-methyl), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)- b--methylpyridine-3Z-carboxylic acid (mazametapyr), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)y-5-methoxymethylpyridin-3- carboxylic acid (imazamox), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)quinoline-3-carboxylic acid (imazaquin), 2-(4, 5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-ethylpyridine-3-carboxylic acid (imazethapyr), M-(4,6-dimethoxypyrimidine-2 -yl)-M'-(2-chloroimidazol1,2-a|Ipyridin-3-yl-sulfonyl)urea (imazosulfuron), sodium salt of M-(4-methoxy-b6-methyl-1,3,5-triazine -2-yl)-M'(5-iodo-2-methoxycarbonylphenylsulfonyl)urea (iodosulfuron-methyl-sodium), 4-hydroxy-3,5-diiodobenzonitrile (ioxynil), and) M,M-dimethyl-M'- (4-isopropylphenyl)urea (isoproturon), IM-(3-(1-ethyl-1-methylpropyl)isoxazol-5-yl)-2,6-dimethoxybenzamide (isoxaben), (4-chloro-2-methylsulfonylphenyl)- (5-cyclopropylisoxazol-4-yl)umethanone (isoxachlorotol), "g Zo (b-cyclopropylisoxazol-4-yl)-(2-methylsulfonyl-4-trifluoromethylphenyl)methanone (isoxaflutol), 2-(2-(4-IZ) ,5-dichloro-2-pyridinyl)oxy|phenoxy |-1-oxo-propylisoxazolidine (isoxapyrifop), o (2-ethoxy-1-methyl-2-oxoethyl)-5-(2-chloro-4-trifluoromethylphenoxy)- 2-nitrobenzoate (lactophen), with M'-(3,4-dichlorophenyl)-M-methoxy-M-methylurea (linuron), (4-chloro-2-methylphenoxy)acetic acid (MSORA), 2-(4- chloro-2-methylphenoxy)propionic acid (mecoprop), 2-(2-benzthiazolyloxy)-M-methyl-M-phenyl-acetamide me) (mefenacet), 2 -(4-methylsulfonyl-2-nitrobenzoyl)-1,3-cyclohexanedione (mesotrione), y- 4-amino-3-methyl-b-phenyl-1,2,4-triazin-5(4H)-one (methamitron ), 2-chloro-M-(2,6-dimethyl-phenyl)-M-(1H-pyrazol-1-ylmethyl)acetamide (metazachlor), M'-(4-(3,4-dihydro-2-methoxy -2,4,4-trimethyl-2H-1-benzopyran-7-yloxy)phenyl)-M-methoxy-M-methylurea (methobenzuron), M'-(4-bromophenyl)-M-methoxy-M-methylurea ( metobromuron), " 40. (3)-2-chloro-M-(2-ethyl-6-methyl-phenyl)-Mm-(2-methoxy-1-methylethyl)acetamide (metolachlor, 3-metolachlor), st») with IM- (2,6-dichloro-3-methylphenyl)-5,7-dimethoxy-1,2,4-triazolo|1,5-a|Ipyrimidine-2-sulfonamide (methosulam), . M'-(3-chloro-4-methoxyphenyl)-M,M-dimethylurea (methoxuron), and? 4-amino-6-tert.-butyl-3-methylthio-1,2,4-triazin-5(4H)-one (metribuzin), M-(4-methoxy-b6-methyl-1,3,5- triazin-2-yl)-M'(2-methoxycarbonylphenylsulfonyl)urea (metsulfuron-methyl), 3-ethylhexahydro-1H-azepine-1-carbothioate (moline), 2-(2-naphthyloxy)-M-phenylpropanamide (naproanilide) , -I M-butyl-M'-(3,4-dichlorophenyl)-M-methylurea (neburon), M-(4,6-dimethoxypyrimidin-2-yl)-M'(3-dimethylcarbamoylpyridin-2-ylsulfonyl) urea (nicosulfuron), o -(2-chlorobenzyl)-M,M-diethylthiocarbamate (orbencarb), 4-dipropylamino-3,5-dinitrobenzenesulfonamide (oryzalin), 2) 3-(2,4-dichloro-5-(2 -propynyloxy)phenyl/|-5-(tert.butyl)-1,3,4-oxadiazol-2(ZH)-one (oxadiargyl), 3-(2,4-dichloro-5-(1-methylethoxy)phenyl |-5-(tert.butyl)-1,3,4-oxadiazol-2(ZH)-one (oxadiazone), o M-(4,6-dimethylpyrimidin-2-yl)-M'-(2-oxetane -3-yloxycarbonylphenylsulfonyl)urea (oxasulfuron), 3-(1-(3,5-dichlorophenyl)-1-isopropyl|-2,3-dihydro-6-methyl-5-phenyl-4H-1-1, 3-oxazin-4-one (oxacyclomefon), 2-chloro-1-(3-ethoxy-4-nitrophenoxy)-4-trifluoromethyl lbenzene (oxyfluorfen), 1,1-dimethyl-4-bipyridinium (paraquat), 1-amino-M-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzene (pendimethalin), 4-(tert .butyl)-M-(1-ethylpropyl)-2,6-dinitrobenzenamine (pendraline), 4-amino-3,5,6-trichloropyridine-2-carboxylic acid (picloram), 2-chloro-M-(2, 6-diethylphenyl)-M-(2-propoxyethyl)acetamide (pretylchlor), F) M-(4,6-bisdifluoromethoxypyrimidin-2-yl)-M'-(2-methoxycarbonylphenylsulfonyl)urea ka (primisulfuron-methyl), 1 -chloro-M-(2-chloro-4-fluoro-5-(65,7ac)-6-fluorotetrahydro-1,3-dioxo-1H-pyrrolo|1,2-cimidazol-2(ZH)-yl|phenyl )|methanesulfonamide (profluazol), 2-chloro-M-isopropyl-M-phenylacetamide (propachlor), M-(3,4-dichlorophenyl)propanamide (propanil), (K)-(2-C((1- methylethylidene)amino|oxethyl|-2-(4-(b-chloro-2-quinoxalinyloxy)phenoxy|propanoate (propaquizafop), 2-chloro-M-(2-ethyl-b6-methylphenyl)-M-(1-methylethoxy )methylacetamide (propisochlor), sodium salt of methyl ester 2-I((4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl)/ucarbonylamino| sulfonyl|benzoic acid ti 65 (propoxycarbazone-sodium), 3-phenylmethyl-M,M-dipropylthiocarbamate (prosulfocarb), M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'-(2 -(3,3,3-trifluoropropyl)phenylsulfonyl)urea (prosulfuron), ethyl-(2-chloro-5-(4-chloro-5-difluoromethoxy-1-methyl-1H-pyrazol-3-yl)-4-fluorophenoxy|acetate (pyraflufen-ethyl), 1-(3-chloro-4 ,5,6,7-tetrahydropyrazolo |1,5-a|pyridin-2-yl)-5-(methyl-2-propynylamino)-1H-pyrazole-4-carbonitrile (pyrazolyl), 4-(2,4- dichlorobenzoyl)-1,3-dimethyl-5-(4-methylphenylsulfonyloxy)pyrazole (pyrazolate), 4-(2,4-dichlorobenzoyl)-1,3-dimethyl-5-(phenylcarbonylmethoxy)pyrazole (pyrazoxifen), M-( 4,6-dimethoxypyrimidin-2-yl)-M'-(4-ethoxycarbonyl-1-methylpyrazol-5-ylsulfonyl)urea (pyrazosulfuron-ethyl), diphenylmethanone-O-|2,6-bis-(4,6- dimethoxypyrimidin-2-yloxy)benzoyl|oxime (pyribenzoxime), b-chloro-3-phenyl-4-pyridazinol (pyridafol), O-(6-chloro-3-phenylpyridazin-4-yl)-5-octylthiocarbonate (pyridate) , b-chloro-3-phenyl-4-pyridazin-4-ol (pyridatol), 70 7-(4,6-dimethoxy-2-pyrimidinyl)thio|-3-methyl-1(ZH)-isobenzofuranone (pyrifthalide) , complex methyl ester of 2-(4,6-dimethoxypyrimidin-2-yloxy)benzoic acid (pyriminobac-methyl), sodium salt of 2-chloro-6-(4,6-dimethoxypyrimidin-2-ylthio)benzoic acid and (pyrithiobac sodium), 3,7-dichloro-quinoline-1-carboxylic acid (quinchlorac), 7-chloro-3-methylquinoline-3-carboxylic acid (quinmerac), (ethyl ester, tetrahydro-2-furanyl methyl ester) 2-I4-(6-chloro-2-quinoxalinyloxy)phenoxy|propanoic /5 ACID (quizalofop, -ethyl, -P-ethyl, -P-tefuryl), IM-(4,6-dimethoxypyrimidin-2-yl)- M'"(3-ethylsulfonylpyridin-2-yl-sulfonyl)urea (rimsulfuron), 2-(1-ethoxyiminobutyl)-5-(2-ethylthiopropyl)-3-hydroxy-2-cyclohexen-1-one (sethoxydime), b-chloro-2,4-bisethylamino-1,3,5-triazine (simazine), 2-(2-chloro-4-methylsulfonylbenzoyl)cyclohexane-1,3-dione (sulcotrione), 2(2,4-dichloro -5-methylsulfonylaminophenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-ZH-1,2,4-triazol-3-one (sulfentrazone), M-phosphonomethyl-glycinetrimethylsulfonium (sulfosate), IM-(4 ,6-dimethoxypyrimidin-2-yl)-M'-(2-ethylsulfonyl)imidazoli|(1,2-a|pyridine-3-sulfonamide (sulfosulfuron), b-chloro-4-ethylamino-2-tert.-butylamino -1,3,5-triazine (terbuthylazine), 2-tert.-butylamino-4-ethylamino-b-methylthio-1,3,5-triazine (ter butrin), ch dvo 27 chloro-M-(2,6-dimethylphenyl)-IM-(3-methoxy-2-thienylmethyl)acetamide (thenylchlor), methyl ester 2-difluoromethyl-5-(4,5-dihydrothiazole-2 -yl)-4-(2-methylpropyl)-b-trifluoromethylpyridine-3-carboxylic acid i) (thiazopyr), 6-(6,7-dihydro-6,6-dimethyl-3H,5H-pyrrole|2,1 -c1-1,2,4-thiadiazol-3-ylideneamino)-7-fluoro-4-(2-propynyl)-2H-1,4-benzoxazin-3(4H)-one (thidiazimine), M-(4-methoxy-b6-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonylthien-3-ylsulfonyl)urea (thifensulfuron-methyl), 2-(ethoxyiminopropyl)-3- hydroxy-5-(2,4,6-trimethylphenyl)-2-cyclohexen-1-one o (thralkoxide), 5-(2,3,3-trichloro-2-propenyl)-diisopropyl carbamotisoate (trialate), "9 M -(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'-(2-(2-chloro-ethoxy)phenylsulfonyl|urea (triasulfuron), M-methyl-M-( 4-methoxy-β6-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonylphenylsulfonyl)urea me) (tribenuron-methyl), (3,5,6-trichloro)pyridine-2- yl-oxyacetic acid (triclopyr), y-2-(3,5-dichlorophenyl)-2-(2,2,2-trichloroethyl)oxirane (tridiphan) , sodium salt IM-I(IK4,b-dimethoxy-2-pyrimidinyl)amino|carbonyl/|-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide (trifloxysulfuron), 1-amino-2,6- dinitro-M,M-dipropyl-4-trifluoromethylbenzene (trifluralin), -(4-dimethylamino-6-(2,2,2-trifluoroethoxy)-1,3,5-triazin-2-yl|-ME( 2-Methoxycarbonylphenylsulfonyl)urea (triflusulfuron-methyl), with M-(4-methoxy-b6-trifluoromethoxy-1,3,5-triazin-2-yl)-M'2-trifluoromethylphenylsulfonyl)urea . (tritosulfuron), and? I-I(K4,b6-dimethoxy-2-pyrimidinyl)amino|carbonyl|-3-(M-methyl-M-methylsulfonylamino)-2-pyridinesulfonamide, methyl ester 2-ISHTC(K4,b-dimethoxy-2-pyrimidinyl) )amino|carbonylamino|sulfonyl|-4-((methylsulfonyl)amino|methyl|benzoic-I acid, 4-I4,5-dihydro-4-methyl-5-oxo-(3-trifluoromethyl)-1H-1,2 ,4-triazol-1-yl|-2-Ketylsulfonyl)amino|-5-fluorobenzene and rbothioamide 2) (active principles of group 4) in the event that the compound under (a) is about 2-(3,4 -difluorophenoxy)-4-methyl-6-(1-methyl-3-trifluoromethylpyrazol-5-yl)-pyridine, then the compound under (b) does not mean flufenacet. 4. The herbicide according to claim 1, which is characterized by the fact that it contains, as the active principle of group 1, a 2,6-disubstituted pyridine derivative of the general formula (I), where B" means a pyrazolyl radical, unsubstituted or mono- or polysubstituted by trifluoromethyl or methyl , or an unsubstituted or mono- or polysubstituted by fluorine phenyl radical. o B? means a phenoxy radical, unsubstituted or substituted by halogen and/or haloalkyl with 1-3 carbon atoms. BZ means a hydrogen atom or methyl. 60 M means oxygen or a group - "SO-MN-. 5. Herbicide according to claim 1, which differs in that it contains M-(4-fluorophenyl)-6-3-3-trifluoromethyl)phenoxy|-2-pyridinecarboxamide (picolinafen) or 2-(3 ,4-difluorophenoxy)-4-methyl-6-(1-methyl-3-trifluoromethylpyrazol-5-yl)-pyridine. 6. The herbicide according to any of claims 2-5, which is characterized by the fact that it contains at least one compound that improves the tolerance of cultivated plants from the following group of compounds: (1-methylhexyl complex ester) 5-chloroquinoxalin- 8-oxyacetic acid (cloquintocet), ethyl ester 1-22,4-dichlorophenyl)-5-trichloromethyl-1TH-1,2,4-triazole-3-carboxylic acid (fenchlorazole-ethyl), ethyl 4,5-dihydro-5,5-diphenyl-3-isoxazolecarboxylate (isoxadifen-ethyl), diethyl-1-(2,4-dichlorophenyl)-4,5-dihydro-5-methyl-1H-pyrazole-3,5-dicarboxylate (mefenpyr-diethyl) and 2,4-dichlorophenoxyacetic acid ( 2,4-O) and their derivatives. 7. The herbicide according to claim 1, which differs in that it contains as an active principle of group 1 picolinafen and as an active principle of group 2 - M-isopropyl-M-(4-fluorophenyl)amide (5-trifluoromethyl-1,3,4 -thiadiazol-2-yloxy)acetic acid (flufenacet). 8. The herbicide according to claim 7, which is characterized by the fact that it additionally contains as another active principle or 7/0 Other active principles one or more compounds from the group including the sodium salt of 2,6-bis-(4,6-dimethoxy -pyrimidin-2-yloxy)benzoic acid (bispyribac sodium), IM-(2,6-difluorophenyl)-8-fluoro-5-methoxy-|1,2,4|-triazolo-|1,5-s| -pyrimidine-2-sulfonamide (florasulam), sodium salt. M-(4,6-dimethoxypyrimidin-2-yl)-ME(3-methoxycarbonyl-6-trifluoromethylpyridin-2-yl-sulfonyl)urea (flupyrsulfuron-methyl-sodium), M,M-dimethyl-M'- (4-isopropylphenyl)urea (isoproturon), 75. M-(2,6-dichloro-3-methylphenyl)-5,7-dimethoxy-1,2,4-triazolo|1,5-a|-pyrimidine-2-sulfonamide (methosulam), 1-amino- M-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzene (pendimethalin) and ethyl-(2-chloro-5-(4-chloro-5-difluoromethoxy-1-methyl-1H-pyrazole-3 -yl)-4-fluorophenoxy|acetate (pyraflufen-ethyl). 9. The herbicide according to claim 1, which differs in that it contains picolinafen as an active principle of group 1 and 2-(2-methoxycarbonyl-phenylsulfonylaminocarbonyl)-4-methyl-5-n.-propoxy-2 as an active principle of group 2 ,4-dihydro-ZH-1,2,4-triazol-3-one or the sodium salt of this compound (propoxycarbozone-sodium). 10. The herbicide according to claim 9, which is characterized by the fact that it additionally contains as another active principle or other active principles one or more compounds from the group including M-(4,6-dimethoxypyrimidin-2-yl)-ME (M-methyl-M-methylsulfonylsulfamoyl)urea (amidosulfuron), sch g Sodium salt of 2,6-bis-(4,6-dimethoxypyrimidin-2-yloxy)benzoic acid (bispyribac sodium), 2-(4-chloro-2 -fluoro-5-(2-chloro-2-ethoxycarbonylethyl)phenyl)-4-difluoromethyl-5-methyl-2,4-dihydro-ZH-1,2,4-triazol-3-i)one (carfentrazone-ethyl ), 2-chloro-3-(2-chloro-5-(1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-iluphenyl|-2-propane) ethyl ester acid (cinidone-ethyl), 2-chloro-4-ethylamino-6-(1-cyano-1-methylethylamino)-1,3,5-triazine (cyanazine), 2,4-dichlorophenoxyacetic acid (2,4- 0), (K)-2-(2,4-dichlorophenoxy)-propanoic acid (dichloroprop-P), IM-(2,6-difluorophenyl)-8-fluoro-5-methoxy|1,2,triazolo-| 1,5-s|Ipyrimidine-2-sulfonamide (florasulam), o M-(4-fluorophenyl)-M-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yloxy)acetamide ( flufenacet), sodium salt "93 M-(4,6-dimethoxypyrimidin-2-yl)-M'-(3-methoxycarbonyl-b-trifluoromethylpyridin-2-ylsulfonyl)urea (flupyrsulfuron-methyl-sodium), (-2- butoxy-1-methylethyl ester, -1-methylheptyl ester) me) (4-amino-3,5-dichloro-b6-fluoropyridin-2-yloxy)acetic acid (fluroxypyr, -butoxypropyl, -meptyl), sodium salt . M-4-methoxy-b-methyl-1,3,5-triazin-2-yl)-ME(5-iodo-2-methoxycarbonylphenylsulfonyl)urea (iodosulfuron-methyl-sodium), M,M-dimethyl- M'-(4-isopropylphenyl)urea (isoproturon), 2-(4-chloro-2-methylphenoxy)propionic acid (mecoprop), IM-(2,6-dichloro-3-methylphenyl)-5,7-dimethoxy- 1,2,4-triazolo P1,5-a|Ipyrimidine-2-sulfonamide (methosulam), " 4-amino-tert.butyl-3-methylthio-1,2,4-triazin-5(4H)-one ( metribuzin), with M-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonylphenylsulfonyl)urea (metsulfuron-methyl), . 1-amino-M-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzene (pendimethalin), and? M-(4-methoxy-b6-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonylthien-3-ylsulfonyl)urea (thiphen-sulfuronone-methyl), M-methyl-M- (4-methoxy-b6-methyl-1,3,5-triazin-2-yl)-M'(2-methoxycarbonylphenylsulfonyl)urea -I (tribenuron-methyl), I-I (IK4,b-dimethoxy-2- pyrimidinyl)-amino|-carbonyl)-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide sodium salt o (trifloxysulfuron), 2) M-(4-methoxy-b6-trifluoromethoxy-1,3,5- triazin-2-yl)-M'2-trifluoromethylphenylsulfonyl)urea 5p (tritosulfuron). o 11. The herbicide according to claim 1, which differs in that it contains as an active principle of group 1 picolinafen and as an active principle of group 2 - 2-(2-trifluoromethoxyphenylsulfonylaminocarbonyl)-4-methyl-5-methoxy-2,4 -dihydro-ZN-1,2,4-triazol-3-one. or the sodium salt of this compound (flucarbazone sodium). 12. The herbicide according to claim 11, which is characterized by the fact that it additionally contains another active principle or other active principles, one or more compounds from the group that includes Ф) sodium salt of 2,6-bis-(4,6-dimethoxypyrimidine-2 -yloxy)benzoic acid (bispyribac sodium), ka 3,5-dibromo-4-hydroxybenzonitrile (bromoxynil), 2-(4-chloro-2-fluoro-5-(2-chloro-2-ethoxycarbonylethyl)phenyl)- 4-difluoromethyl-5-methyl-2,4-dihydro-ZH-1,2,4-triazol-3-boone (carfentrazone-ethyl), ethyl ester 2-chloro-3-(2-chloro-5-( 1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindole-2-iluphenyl|-2-propanoic acid (cinidone-ethyl), (K)-(2-propynyl)-2 -(4-(5-chloro-3-fluoropyridin-2-yloxy)-phenoxypropanoate (clodinafop-propargyl), 3,6-dichloropyridine-2-carboxylic acid (clopyralid), 2,4-dichlorophenoxyacetic acid (24-05) , 3,6-dichloro-2-methoxybenzoic acid (dicamba), 65 (K)-ethyl-2-I4-(6-chlorobenzoxazol-2-yloxy)phenoxy|propanoate (fenoxaprop-(P)-ethyl), IM- (2,6-difluorophenyl)-8-fluoro-5-methoxy|1,2,griazolo|1,5-c|Ipyrimidine-2-sulfonamide (flora sulam), M-(4-fluorophenyl)-M-isopropyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yloxy)dacetamide (flufenacet), M-(4,6-dimethoxypyrimidin-2-yl) sodium salt )-M'-(3-methoxycarbonyl-b-trifluoromethylpyridin-2-ylsulfonyl)urea (flupyrsulfuron-methyl-sodium), (-2-butoxy-1-methyl ester, -1-methylheptyl ester) (4-amino-3 ,5-dichloro-6-fluoropyridin-2-yloxy)acetic acid (fluroxypyr, -butoxypropyl, -meptyl), methyl-2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H- imidazol-2-yl)-4-methylbenzoate (imazametabenzmethyl), 2-(4,5-dihydro-4-methyl-4-isopropyl-5-oxo-1H-imidazol-2-yl)-5-methoxymethylpyridin-Z -carboxylic acid (imazamox), sodium salt M-(4-methoxy-b6-methyl-1,3,5-triazin-2-yl)-M'(5-iodo-2-methoxycarbonylphenylsulfonyl)urea 70 (iodosulfuron-methyl -sodium), M,M-dimethyl-M'-(4-isopropylphenyl)urea (isoproturon), (4-chloro-2-methylphenoxyacetic acid (MCPA), 2-(4-chloro-2-methylphenoxy)propionic acid ( mecoprop), IM-(2,6-dichloro-3-methylphenyl)-5,7-dimethoxy-1,2,4-triazolo|1,5-a|Ipyrimidine-2-sulfonamide (methosulam), 4-amino-6-tert.butyl-3-methylthio-1,2,4-triazin-5(4H)-one (metribuzin), M-(4-methoxy-b6-methyl-1,3 ,5-triazin-2-yl)-M'(2-methoxycarbonylphenylsulfonyl)urea (metsulfuron-methyl), 1-amino-M-(1-ethylpropyl)-3,4-dimethyl-2,6-dinitrobenzene (pendimethalin) , sodium salt of methyl ester 2-I(K4,5-dihydro-4-methyl-5-oxo-3-propoxy-1H-1,2,4-triazol-1-yl)-carbonyl|-amino|-sulfonyl| -benzoic acid (propoxycarbozone-sodium), ethyl-(2-chloro-5-(4-chloro-5-difluoromethoxy-1-methyl-1H-pyrazol-3-yl)-4-fluorophenoxy|acetate (pyraflufen-ethyl) . -1,3,5-triazin-2-yl)-M'(2-methoxycarbonylthien-3-ylsulfonyl)urea (thifensulfuron-methyl), 2-(ethoxyiminopropyl)-3-hydroxy-5-(2,4,6 -trimethylphenyl)-2-cyclohexen-1-one (thralkoxide), 5-(2,3,3-trichloro-2-propenyl)diisopropylcarbamothioate (trialate), M-methyl-M-(4-methoxy-b6-methyl- 1,3,5-triazin-2-yl)-M'(2-methoxycarbonylphenylsulfone il)urea (tribenuron-methyl), ch I-I(IK4,b-dimethoxy-2-pyrimidinyl)amino|carbonyl/|-3-(2,2,2-trifluoroethoxy)-2-pyridinesulfonamide sodium salt (trifloxysulfuron), i) M-(4-methoxy-b6-trifluoromethoxy-1,3,5-triazin-2-yl)-M'2-trifluoromethylphenylsulfonyl)urea (tritosulfuro n). triigya i " : " " : : pov Z zo Official Bulletin "Industrial Property". Book 1 "Inventions, useful models, topographies of integrated microcircuits", 2005, M 7, 15.07.2005. State Department of Intellectual Property of the Ministry of Education and Science of Ukraine s so i - shi s ;" -I (95) (95) o 50 s» F) ime) 60 b5