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TWM643298U - Two-coat two-bake powder coating structure - Google Patents

Two-coat two-bake powder coating structure Download PDF

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Publication number
TWM643298U
TWM643298U TW112201052U TW112201052U TWM643298U TW M643298 U TWM643298 U TW M643298U TW 112201052 U TW112201052 U TW 112201052U TW 112201052 U TW112201052 U TW 112201052U TW M643298 U TWM643298 U TW M643298U
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Taiwan
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layer
toner
powder coating
primer
topcoat layer
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TW112201052U
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Chinese (zh)
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陳政杰
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國竑實業股份有限公司
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Publication of TWM643298U publication Critical patent/TWM643298U/en

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Abstract

本新型係關於一種二塗二烤的粉末塗裝結構,係最主要係利用面漆層經靜電噴塗後的烘烤時,其底漆層內的高濃度的移行性色粉會滲透擴散到無色粉的該面漆層中,其原理係透過該移行性色粉的分子於第二次的烘烤過程中,讓該底漆層分子鏈鬆散,使小分子移行性色粉可經由該底漆層經其與面漆層的界面而均勻地滲透並擴散到該面漆層內,當該面漆層降溫後,則該移行性色粉則會固化於該面漆層內,進而改善表面塗層的色差。 The present invention relates to a two-coat and two-baking powder coating structure. The most important thing is that when the topcoat layer is baked after electrostatic spraying, the high-concentration migratory toner in the primer layer will permeate and diffuse into the toner-free topcoat layer. The principle is to loosen the molecular chains of the primer layer through the molecules of the migratory toner during the second baking process, so that the small molecular migratory toner can penetrate and diffuse evenly into the primer layer through the interface between the primer layer and the topcoat layer. In the topcoat layer, when the topcoat layer cools down, the migratory toner will solidify in the topcoat layer, thereby improving the color difference of the topcoat layer.

Description

二塗二烤的粉末塗裝結構 Two-coat and two-baked powder coating structure

本新型涉及一種粉末塗裝之技術領域,尤指一種二塗二烤的粉末塗裝結構之技術範疇。 The present invention relates to the technical field of powder coating, in particular to the technical category of a two-coat and two-baking powder coating structure.

隨着人們審美要求的提高,追求塗料的高度美感已成為一種趨勢。金屬感、珠光或顏色效果的粉末塗料能展現一種從水晶般金屬光澤到絲緞般珍珠明亮的豪華裝飾效果,因而廣泛於家具飾品,運動器材和汽車等的噴塗。 With the improvement of people's aesthetic requirements, it has become a trend to pursue the high aesthetic feeling of coatings. Metallic, pearlescent or color-effect powder coatings can show a luxurious decorative effect from crystal-like metallic luster to satin-like pearl brightness, so they are widely used in the spraying of furniture accessories, sports equipment and automobiles.

過去金屬基材之塗佈方法,大多需要經過二塗二烤等工序,其係先施作一底漆層以封固基底,再添加色粉於面漆塗料中,經過施作於該底漆層後烘烤之,讓該面漆層附著於該底漆層,來達到二塗二烤的顏色效果。 In the past, coating methods for metal substrates mostly required two-coating and two-baking processes. Firstly, a primer layer was applied to seal the substrate, and then toner was added to the topcoat coating, which was applied to the primer layer and then baked to allow the topcoat layer to adhere to the primer layer to achieve the color effect of two-coating and two-baking.

然而,上述該面漆層容易因膜厚的不均勻會有色差的現象,乃至於金屬基材邊緣的流垂處因積累面漆層色料而產生色差,故習用二塗二烤的粉末塗裝結構製程,實有需要加以改善。 However, the above-mentioned topcoat layer is prone to color difference due to uneven film thickness, and even the sag on the edge of the metal substrate is caused by accumulation of topcoat colorant. Therefore, the conventional two-coating and two-baking powder coating structure process needs to be improved.

緣此,鑑於上述習式二塗二烤等粉末塗裝存在的問題點,故本新型創作人乃窮極心思開發出一種二塗二烤的粉末塗裝結構,故本新型之主要目的:在於提供不因面漆層的膜厚不均勻而形成色差現象的二塗二烤的粉末塗裝結構;本新型之次要目的:在於提供不因金屬基材邊緣的流垂處因積累面漆層色料而產生色差現象的二塗二烤的粉末塗裝結構。 Therefore, in view of the above-mentioned problems in conventional two-coating and two-baking powder coating, the creators of the present invention have devised a two-coating and two-baking powder coating structure with great thought. Therefore, the main purpose of the present invention is to provide a two-coating and two-baking powder coating structure that does not cause chromatic aberration due to the uneven film thickness of the top coat layer.

本新型為達上述目的,運用如下技術手段:一種二塗二烤的粉末塗裝結構,係包含有:一底漆層,係添加移行性色粉的一底漆粉,然後靜電塗佈於金屬基材的表面,經第一次烘烤後形成該底漆層;及一面漆層,係將一面漆粉靜電塗佈於該底漆層表面,經第二次烘烤時該底漆層內的移行性色粉會因該第二次烘烤時面漆層的溫度大於該第一次烘烤後底漆層的溫度,且該底漆層的密度大於該面漆層的密度,以致讓色粉能夠均勻地滲透並擴散到該面漆層內,經降溫冷卻後則固化成該面漆層及底漆層。 In order to achieve the above purpose, the present invention adopts the following technical means: a two-coating and two-baking powder coating structure, which includes: a primer layer, which is a primer powder added with migratory toner, and then electrostatically coated on the surface of the metal substrate, and the primer layer is formed after the first baking; The temperature of the layer, and the density of the primer layer is greater than the density of the topcoat layer, so that the toner can penetrate and diffuse into the topcoat layer evenly, and then solidify into the topcoat layer and the primer layer after cooling down.

所述該底漆層係由包含有45%~99%的粉末塗料樹脂、流平劑0.5%~2%、硬化劑3%~10%、移行性色粉0.1%~15%、消泡劑0.2%~1.5%、填充物0.1%~40%所構成100%的底漆塗料所施作而成。 The primer layer is made of a 100% primer coating consisting of 45%-99% powder coating resin, 0.5%-2% leveling agent, 3%-10% hardener, 0.1%-15% migrating toner, 0.2%-1.5% defoamer, and 0.1%-40% filler.

所述該面漆層係由包含有90%~99%的粉末塗料樹脂、流平劑0.5%~2%、硬化劑3%~10%、光澤調整助劑0%~10%、消泡劑0.2%~1.5%所構成100%的底漆塗料所施作而成。 The topcoat layer is composed of 90%-99% of powder coating resin, 0.5%-2% of leveling agent, 3%-10% of hardener, 0%-10% of gloss adjustment additive, and 0.2%-1.5% of defoamer, which constitutes 100% primer coating.

所述該移行性色粉設為小分子有機色粉,其粒徑設為0.01um~10um之間,其分子量介於180~1000之間。 The migratory toner is a small molecule organic toner, its particle size is set between 0.01um~10um, and its molecular weight is between 180~1000.

所述該底漆層設為平面、皺紋、垂紋或砂紋之結構表面。 Said primer layer is set as a plane, wrinkled, vertical or sandy textured surface.

所述該面漆層設為亮光、平光、消光、透明或半透明等之面漆層。 The topcoat layer is set as a glossy, flat, matte, transparent or translucent topcoat layer.

本新型運用上述技術手段,可以達成如下功效: The present invention uses the above-mentioned technical means to achieve the following effects:

1.本新型係在面漆層的施作的烘烤過程中,由該底漆層中移行並均勻地滲出移行性色粉分子而擴散於該面漆層內,待該面漆層冷卻固化後形成無色差的表面塗層。 1. During the baking process of the topcoat layer, the new type migrates from the primer layer and evenly oozes migratory toner molecules and diffuses in the topcoat layer. After the topcoat layer is cooled and solidified, a surface coating without color difference is formed.

2.本新型係在面漆層的施作烘烤過程中,即使在金屬基材邊緣的流垂處因積累面漆層,亦不會產生色差現象。 2. This new type is in the process of applying and baking the topcoat layer, even if the topcoat layer is accumulated on the drooping part of the edge of the metal substrate, there will be no color difference.

A:粉末塗裝結構 A: Powder coated structure

1:金屬基材 1: Metal substrate

2:底漆層 2: primer layer

3:面漆層 3: Topcoat layer

4:色粉 4: Toner

B:粉末塗裝結構的施作方法 B: Application method of powder coating structure

a:步驟 a: steps

b:步驟 b: step

c:步驟 c: step

d:步驟 d: steps

e:步驟 e: step

〔圖1〕係為本新型「二塗二烤的粉末塗裝結構」之示意圖。 [Fig. 1] is a schematic diagram of the new "two-coated-two-baked powder coating structure".

〔圖2〕係為本新型移行性色粉分子均勻地由具有高濃度色粉的底漆層滲透並擴散於無色粉的面漆層之示意圖。 [Fig. 2] is a schematic diagram of the new migratory toner molecules uniformly permeating through the primer layer with high concentration of toner and diffusing into the topcoat layer without toner.

〔圖3〕係為本新型「二塗二烤的粉末塗裝結構的施作方法」之步驟流程圖。 [Fig. 3] is a flow chart of the steps of the new "two-coating and two-baking powder coating structure application method".

首先,請參閱圖1所示,本新型係關於一種二塗二烤的粉末塗裝結構A,係提供塗佈於一金屬基材1,其包含有:一底漆層2及一面漆層3。 First, please refer to FIG. 1 , the present invention relates to a powder coating structure A with two coats and two bakes.

所述該底漆層2,係添加移行性色粉4的一底漆粉,然後靜電塗佈於金屬基材1的表面,依序經過高溫第一次烘烤、冷卻而形成該底漆層2;進一步,該底漆層2係由包含有45%~99%的粉末塗料樹脂、流平劑0.5%~2%、硬化劑3%~10%、移行性色粉0.1%~15%、消泡劑0.2%~1.5%、填充物0.1%~40%所構成100%的底漆塗料所施作而成;進一步,該粉末塗料樹脂可為環氧型、環氧聚酯混合型、純聚酯型、PU型、壓克力型、PE型或Nylon型;其中該流平劑可用壓克力型、矽型或氟素型;其中針對環氧聚酯混合型、PE型、Nylon型等粉末塗料樹脂則不須使用硬化劑,而其它粉末塗料樹脂則可使用相關氨基、TGIC、HAA、PU異氰酸鹽、DDDA雙酸基等粉末塗料硬化劑;其中該移行性色粉可包含染料、顏料、螢光色粉等種類的小分子有機色粉,其粒徑設為0.01um~10um之間,其分子量介於180~1000之間;其中該消泡劑種類包含有安息香、臘類、 矽類、氟素類等;其中該填充物泛指各類無機金屬及礦石等,如鋁粉、銅粉、珍珠粉、硫酸鋇、碳酸鈣、鈦白粉、黏土等。 The primer layer 2 is a primer powder added with migratory toner 4, then electrostatically coated on the surface of the metal substrate 1, and then baked at high temperature for the first time and cooled to form the primer layer 2; further, the primer layer 2 is composed of 45%~99% of powder coating resin, 0.5%~2% of leveling agent, 3%~10% of hardener, 0.1%~15% of migratory toner, 0.2%~1.5% of defoamer, filler 0 .1%~40% constitutes 100% primer coating; further, the powder coating resin can be epoxy type, epoxy polyester mixed type, pure polyester type, PU type, acrylic type, PE type or Nylon type; the leveling agent can be acrylic type, silicon type or fluorine type; among them, no hardener is required for epoxy polyester mixed type, PE type, Nylon type powder coating resins, while other powder coating resins can use related amino, TGIC, HAA, PU isocyanate, DDDA bis-acid base and other powder coating hardeners; the migrating toner can include dyes, pigments, fluorescent toners and other small molecular organic toners, the particle size is set between 0.01um~10um, and its molecular weight is between 180~1000; the type of defoamer includes benzoin, waxes, Silicon, fluorine, etc.; the filler generally refers to various inorganic metals and ores, such as aluminum powder, copper powder, pearl powder, barium sulfate, calcium carbonate, titanium dioxide, clay, etc.

所述該面漆層3,係將一面漆粉靜電塗佈於該底漆層2表面,依序經過第二次烘烤時,該底漆層2內的移行性色粉4會移行並擴散到該面漆粉內,如圖2所示,經降溫冷卻後則固化成該面漆層3及底漆層2;進一步,該面漆層3係由包含有90%~99%的粉末塗料樹脂、流平劑0.5%~2%、硬化劑3%~10%、光澤調整助劑0%~10%、消泡劑0.2%~1.5%所構成100%的底漆塗料所施作而成;進一步,該粉末塗料樹脂可為環氧型、環氧聚酯混合型、純聚酯型、PU型、壓克力型、PE型或Nylon型;其中該流平劑可用壓克力型、矽型或氟素型;其中針對環氧聚酯混合型、PE型、Nylon型等粉末塗料樹脂則不須使用硬化劑,而其它粉末塗料樹脂則可使用相關氨基、TGIC、HAA、PU異氰酸鹽、DDDA雙酸基等粉末塗料硬化劑;其中該光澤調整助劑可以使用或不使用,並運用不同比例的光澤調整助劑,以獲得亮光、平光、消光、透明或半透明等之面漆層3。 The topcoat layer 3 is electrostatically coated with a topcoat powder on the surface of the primer layer 2, and after the second baking in sequence, the migratory toner 4 in the primer layer 2 will migrate and diffuse into the topcoat powder, as shown in Figure 2, after cooling down, the topcoat layer 3 and the primer layer 2 are solidified; further, the topcoat layer 3 is composed of powder coating resin containing 90% to 99%, 0.5% to 2% of a leveling agent, and 3% to 10% of a hardener. 0%~10% gloss adjustment additive and 0.2%~1.5% defoamer constitute 100% primer coating; further, the powder coating resin can be epoxy type, epoxy polyester mixed type, pure polyester type, PU type, acrylic type, PE type or Nylon type; the leveling agent can be acrylic type, silicon type or fluorine type; among them, epoxy polyester mixed type, PE type, Nylon type powder coating resin does not need to use hardener, while other powder coating resins Related powder coating hardeners such as amino, TGIC, HAA, PU isocyanate, DDDA bis-acid group can be used; the gloss adjustment additive can be used or not, and the gloss adjustment additive can be used in different proportions to obtain a glossy, flat, matte, transparent or translucent topcoat layer 3.

藉由上述底漆層2及面漆層3以構成本新型二塗二烤的粉末塗裝結構A,如圖2所示者,係在該面漆層3的施作的烘烤過程中,高溫會傳導至該面漆層3,因該第二次烘烤時面漆層3的溫度大於第一次烘烤後底漆層2的溫度,且該底漆層2的密度大於該面漆層3的密度,配合底漆層2的色粉4濃度較高,故該色粉4會由該底漆層2中移行並均勻地滲出移行性色粉4分子擴散於無色粉的該面漆層3內,待冷卻固化後形成無色差的表面塗層,其原理是透過高分子於加溫的過程中,讓該底漆層2的分子鏈鬆散,使小分子移行性色粉4可由位於下方的底漆層2經由與面漆層3的界面而均勻地滲透並擴散至上方的面漆層3;同理,本新 型藉由此原理讓在該面漆層3的施作的烘烤過程中,即使在金屬基材1邊緣的流垂處因積累面漆層3,亦不會產生色差現象。 The above-mentioned primer layer 2 and topcoat layer 3 constitute the novel two-coating-two-baking powder coating structure A of the present invention. As shown in FIG. The migratory toner 4 migrates in the paint layer 2 and oozes uniformly into the toner-free topcoat layer 3, and forms a surface coating without color difference after being cooled and solidified. The principle is to loosen the molecular chains of the primer layer 2 through polymers during the heating process, so that the small-molecule migratory toner 4 can penetrate and diffuse evenly from the lower primer layer 2 to the upper topcoat layer 3 through the interface with the topcoat layer 3; By virtue of this principle, during the baking process of the application of the topcoat layer 3, even if the topcoat layer 3 accumulates at the edge of the metal substrate 1 due to the accumulation of the topcoat layer 3, there will be no color difference.

關於實施於本新型粉末塗裝結構A之二塗二烤的粉末塗裝結構的施作方法B,如圖1、圖2及圖3所示,係包含有:一添加色粉步驟a,係添加移行性色粉4於基粉中而形成一底漆粉;一底漆粉塗佈步驟b,係將該底漆粉靜電塗佈於金屬基材1表面;一第一次烘烤步驟c,係對該底漆粉進行初次烘烤而成一底漆層2,烘烤的溫度設為120~200℃之間,烘烤為5~20分鐘;一面漆粉塗佈步驟d,係將一面漆粉靜電塗佈於該底漆層2表面;及一第二次烘烤步驟e,係對該面漆粉進行烘烤,其烘烤溫度設為130℃~240℃以上,烘烤5~20分鐘,讓該底漆層2內的移行性色粉4會均勻地滲透並擴散至該面漆粉內,而經冷卻固化成一面漆層3及該底漆層2,進而讓該金屬基材1的表面獲得具顏色的塗層。 Regarding the application method B of the two-coating and two-baking powder coating structure implemented in the new powder coating structure A of the present invention, as shown in Figures 1, 2 and 3, it includes: a step of adding toner a, adding migrating toner 4 to the base powder to form a primer powder; a primer powder coating step b, electrostatically coating the primer powder on the surface of the metal substrate 1; 0°C, baking for 5-20 minutes; top coat powder coating step d, is to electrostatically coat the top coat powder on the surface of the primer layer 2; and a second baking step e, is to bake the top coat powder, the baking temperature is set at 130°C-240°C, and bake for 5-20 minutes, so that the migratory toner 4 in the primer layer 2 can penetrate and diffuse into the top coat powder evenly, and after cooling and solidification, the top coat layer 3 and the primer layer 2 are formed. The surface of the metal substrate 1 receives a colored coating.

進一步,在該底漆粉塗佈步驟b中,將該底漆粉靜電塗佈於金屬基材1的表面結構設為平面、皺紋、垂紋或砂紋等底漆層2之結構表面;進一步,在該第二次烘烤步驟e中,經由運用不同比例光澤調整助劑的調整,而獲得亮光、平光、消光、透明或半透明等之面漆層3,進而讓該金屬基材1的表面獲得具不同變化的顏色塗層。 Further, in the primer powder coating step b, the primer powder is electrostatically coated on the surface structure of the metal substrate 1 to make the surface structure of the primer layer 2 such as plane, wrinkle, vertical grain or sand pattern; further, in the second baking step e, through the adjustment of gloss adjustment additives in different proportions, a topcoat layer 3 with bright light, flat light, matte, transparent or translucent, etc. is obtained, and then the surface of the metal substrate 1 is obtained with different color coatings.

綜上所述,本新型係關於一種二塗二烤的粉末塗裝結構,且其構成結構均未曾見諸書刊或公開使用,誠符合新型專利申請要件,懇請鈞局明鑑,早日准予專利,至為感禱。 To sum up, this new model is related to a two-coated and two-baked powder coating structure, and its structure has never been published in books or public use. It really meets the requirements for a new patent application. I sincerely hope that the bureau will grant the patent as soon as possible, and I will pray for it.

需陳明者,以上所述乃是本案之具體實施例所運用之技術原理,若依照本案之構想所作之改變,其所產生之功能作用未能超出說明書及圖式所涵蓋之精神時,均應在本案之範圍內,合予陳明。 It needs to be stated that the above is the technical principle used in the specific embodiment of this case. If the changes made according to the concept of this case do not exceed the spirit covered by the instructions and drawings, they should be stated within the scope of this case.

A:粉末塗裝結構 A: Powder coated structure

1:金屬基材 1: Metal substrate

2:底漆層 2: primer layer

3:面漆層 3: Topcoat layer

4:色粉 4: Toner

Claims (6)

一種二塗二烤的粉末塗裝結構,係包含有:一底漆層,係添加移行性色粉的一底漆粉,然後靜電塗佈於金屬基材的表面,經第一次烘烤後形成該底漆層;及一面漆層,係將一面漆粉靜電塗佈於該底漆層表面,經第二次烘烤時該底漆層內的移行性色粉會因該第二次烘烤時面漆層的溫度大於第一次烘烤後底漆層的溫度,且該底漆層的密度大於該面漆層的密度,致該移行性色粉能夠均勻地滲透並擴散到該面漆層內,經降溫冷卻後則固化成該面漆層及底漆層。 A two-coat and two-baking powder coating structure, comprising: a primer layer, which is a primer powder added with migratory toner, and then electrostatically coated on the surface of a metal substrate, and the primer layer is formed after the first baking; The density of the topcoat layer is such that the migratory toner can evenly penetrate and diffuse into the topcoat layer, and solidify into the topcoat layer and primer layer after cooling down. 如請求項1所述二塗二烤的粉末塗裝結構,其中該底漆層係由包含有45%~99%的粉末塗料樹脂、流平劑0.5%~2%、硬化劑3%~10%、移行性色粉0.1%~15%、消泡劑0.2%~1.5%、填充物0.1%~40%所構成100%的底漆塗料所施作而成。 The two-coating and two-baking powder coating structure as described in Claim 1, wherein the primer layer is made of 100% primer coating composed of 45%~99% powder coating resin, 0.5%~2% leveling agent, 3%~10% hardener, 0.1%~15% migrating toner, 0.2%~1.5% defoamer, and 0.1%~40% filler. 如請求項1所述二塗二烤的粉末塗裝結構,其中該面漆層係由包含有90%~99%的粉末塗料樹脂、流平劑0.5%~2%、硬化劑3%~10%、光澤調整助劑0%~10%、消泡劑0.2%~1.5%所構成100%的底漆塗料所施作而成。 The powder coating structure of two-coating and two-baking as described in Claim 1, wherein the topcoat layer is made of 100% primer coating comprising 90%-99% of powder coating resin, 0.5%-2% of leveling agent, 3%-10% of hardener, 0%-10% of gloss adjustment additive, and 0.2%-1.5% of defoamer. 如請求項1所述二塗二烤的粉末塗裝結構,其中該移行性色粉設為小分子有機色粉,其粒徑設為0.01um~10um之間,其分子量介於180~1000之間。 The two-coating and two-baking powder coating structure as described in Claim 1, wherein the migration toner is a small molecular organic toner, its particle size is set between 0.01um~10um, and its molecular weight is between 180~1000. 如請求項1所述二塗二烤的粉末塗裝結構,其中該底漆層設為平面、皺紋、垂紋或砂紋之結構表面。 The two-coated-two-baked powder coating structure as described in Claim 1, wherein the primer layer is set as a flat, wrinkled, vertical or sandy structured surface. 如請求項1所述二塗二烤的粉末塗裝結構,其中該面漆層設為亮光、平光、消光、透明或半透明等之面漆層。 The two-coated-two-baked powder coating structure as described in Claim 1, wherein the topcoat layer is set as a glossy, flat, matte, transparent or translucent topcoat layer.
TW112201052U 2020-03-18 2020-03-18 Two-coat two-bake powder coating structure TWM643298U (en)

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