TWI818628B - Method for removing slag on surfaces of steel slab, carbon steel and alloy steel - Google Patents
Method for removing slag on surfaces of steel slab, carbon steel and alloy steel Download PDFInfo
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本發明係有關於一種鋼胚表面熔渣之去除方法及其所製得之碳鋼材與合金鋼材,且特別是有關於一種維持鋼胚表面於特定溫度下所進行之熔渣去除方法及其所製得之碳鋼材與合金鋼材。The present invention relates to a method for removing molten slag from the surface of steel blanks and the carbon steel and alloy steel materials produced therefrom, and in particular to a method for removing molten slag from the surface of steel blanks by maintaining it at a specific temperature and the method thereof. Carbon steel and alloy steel produced.
大鋼胚經鍊鋼製程後,大鋼胚表面會有許多線縫缺陷。早期,雖可藉由燒除處理改善線縫缺陷及脫碳層,但是於燒除處理時,燒除所產生之熔渣會四處噴濺,而沾附於大鋼胚表面,因此產生新的表面缺陷。近來,發展出二次除鏽處理,其係利用砂輪片研磨大鋼胚表面的熔渣,以將其去除。After the large steel embryo undergoes the chain steel process, there will be many seam defects on the surface of the large steel embryo. In the early days, seam defects and decarburized layers could be improved by burning. However, during the burning process, the slag produced by the burning would splash around and adhere to the surface of the large steel blank, thus producing new slag. Surface defects. Recently, a secondary rust removal treatment has been developed, which uses a grinding wheel to grind the slag on the surface of the large steel blank to remove it.
然而,此二次除鏽處理浪費人力及電力,且需要大量的砂輪片,故增加成本。有鑑於此,亟需發展一種新的鋼胚表面熔渣之去除方法,以改善上述缺點。However, this secondary rust removal process wastes manpower and electricity, and requires a large number of grinding wheels, thus increasing the cost. In view of this, there is an urgent need to develop a new method for removing slag from the surface of steel blanks to improve the above shortcomings.
有鑑於上述之問題,本發明之一態樣是在提供一種鋼胚表面熔渣之去除方法。此去除方法維持經特定溫度的燒除處理後之鋼胚在特定溫度下且以特定壓力的水沖洗,以快速去除鋼胚表面之熔渣。In view of the above problems, one aspect of the present invention is to provide a method for removing slag on the surface of a steel blank. This removal method maintains the steel blank that has been burned at a specific temperature and flushes it with water at a specific pressure to quickly remove the slag on the surface of the steel blank.
本發明之另一態樣是在提供一種碳鋼材。此碳鋼材利用前述之鋼胚表面熔渣之去除方法所製得。Another aspect of the present invention provides a carbon steel material. This carbon steel is produced using the aforementioned method of removing slag from the surface of the steel blank.
本發明之又一態樣是在提供一種合金鋼材。此合金鋼材利用前述之鋼胚表面熔渣之去除方法所製得。Another aspect of the present invention provides an alloy steel material. This alloy steel is produced by using the aforementioned method of removing slag from the surface of the steel blank.
根據本發明之一態樣,提出一種鋼胚表面熔渣之去除方法。此去除方法包含對煉鋼所得之鋼胚進行燒除處理,以獲得燒除後鋼胚;以及對燒除後鋼胚進行去除處理,以去除熔渣。於燒除處理中,燒除處理之燒除溫度為大於950℃且不大於1300℃,且熔渣形成於燒除後鋼胚之表面。於進行去除處理時,燒除後鋼胚持溫於950℃至1100℃,並以具有不小於170巴之壓力的水沖洗表面。According to one aspect of the present invention, a method for removing molten slag on the surface of a steel blank is proposed. This removal method includes burning the steel blank obtained from steelmaking to obtain the burned steel blank; and removing the burned steel blank to remove slag. In the burning treatment, the burning temperature of the burning treatment is greater than 950°C and not greater than 1300°C, and molten slag is formed on the surface of the steel blank after burning. During the removal process, the temperature of the steel blank after burning is maintained at 950°C to 1100°C, and the surface is rinsed with water with a pressure of not less than 170 bar.
依據本發明之一實施例,在進行去除處理之前,去除方法排除降溫處理,降溫處理係將燒除後鋼胚降溫至小於950℃。According to one embodiment of the present invention, before the removal treatment is performed, the removal method excludes a cooling treatment. The cooling treatment is to cool the burned steel blank to less than 950°C.
依據本發明之另一實施例,於去除處理期間,鋼胚之移動速度為0.5m/sec至1.5m/sec。According to another embodiment of the present invention, during the removal process, the moving speed of the steel blank is 0.5m/sec to 1.5m/sec.
依據本發明之又一實施例,壓力為170巴至220巴。According to a further embodiment of the invention, the pressure is 170 bar to 220 bar.
根據本發明之另一態樣,提出一種碳鋼材。此碳鋼材利用前述之鋼胚表面熔渣之去除方法所製得,其中碳鋼材包含低碳鋼及/或高碳鋼。According to another aspect of the present invention, a carbon steel material is provided. The carbon steel is produced by using the aforementioned method of removing slag from the surface of the steel blank, and the carbon steel includes low carbon steel and/or high carbon steel.
依據本發明之一實施例,低碳鋼之平均火花時間為不大於3分鐘。According to an embodiment of the present invention, the average spark time of low carbon steel is no more than 3 minutes.
依據本發明之另一實施例,高碳鋼之平均火花時間為不大於4.5分鐘。According to another embodiment of the invention, the average spark time of the high carbon steel is no more than 4.5 minutes.
根據本發明之又一態樣,提出一種合金鋼材。此合金鋼材利用前述之鋼胚表面熔渣之去除方法所製得,其中合金鋼材包含多元合金鋼及/或單元金鋼。According to another aspect of the present invention, an alloy steel is provided. This alloy steel is produced by using the aforementioned method of removing slag from the surface of a steel blank. The alloy steel includes multi-component alloy steel and/or unit gold steel.
依據本發明之一實施例,多元合金鋼之平均火花時間為不大於4.5分鐘。According to an embodiment of the present invention, the average spark time of the multi-component alloy steel is no more than 4.5 minutes.
依據本發明之另一實施例,單元合金鋼之平均火花時間為不大於7.5分鐘。According to another embodiment of the present invention, the average spark time of the unit alloy steel is no more than 7.5 minutes.
應用本發明之鋼胚表面熔渣之去除方法,其中將經特定溫度的燒除處理後之鋼胚維持於特定溫度下,並利用特定壓力的水沖洗鋼胚表面,以在表面生成之熔渣未固化前,將其快速去除,從而縮短去除熔渣的時間。The method for removing molten slag on the surface of a steel blank is applied according to the present invention, in which the steel blank after being burned at a specific temperature is maintained at a specific temperature, and water at a specific pressure is used to flush the surface of the steel blank to remove the molten slag generated on the surface. Quickly remove the slag before it solidifies, thus shortening the slag removal time.
以下仔細討論本發明實施例之製造和使用。然而,可以理解的是,實施例提供許多可應用的發明概念,其可實施於各式各樣的特定內容中。所討論之特定實施例僅供說明,並非用以限定本發明之範圍。The making and using of embodiments of the invention are discussed in detail below. It is to be appreciated, however, that the embodiments provide many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed are illustrative only and are not intended to limit the scope of the invention.
本發明之鋼胚表面熔渣之去除方法係將經大於950℃且不大於1300℃的燒除處理後之鋼胚維持於950℃至1100℃下,並利用不小於170巴之壓力的水沖洗鋼胚表面,以在鋼胚表面生成之熔渣未固化前,將其快速去除。因此相較於習知的使用砂輪片除去熔渣之方法,本發明之去除方法可免除使用砂輪片,並避免使用砂輪片而增長的時間,從而縮短去除熔渣的時間,並降低砂輪片的成本。The method for removing slag on the surface of steel blanks of the present invention is to maintain the steel blanks at 950°C to 1100°C after burning treatment at a temperature of greater than 950°C and not greater than 1300°C, and flush it with water at a pressure of not less than 170 bar. The surface of the steel blank is used to quickly remove the slag generated on the surface of the steel blank before it solidifies. Therefore, compared with the conventional method of using a grinding wheel to remove slag, the removal method of the present invention can eliminate the use of a grinding wheel and avoid the increased time required by using a grinding wheel, thereby shortening the time for removing slag and reducing the wear and tear of the grinding wheel. cost.
請參閱圖1,在鋼胚表面熔渣之去除方法100中,對煉鋼所得之鋼胚進行燒除處理,以獲得燒除後鋼胚,如操作110所示。在一些實施例中,鋼胚可包含製造碳鋼材及/或合金鋼材之鋼胚。Please refer to FIG. 1 . In the
煉鋼製程之條件為本發明所屬技術領域中具有通常知識者所慣用之條件,例如:1100℃至1200℃之煉鋼溫度。再者,燒除處理係用以改善煉鋼後鋼胚的線縫缺陷及脫碳層。以大於950℃且不大於1300℃之燒除溫度對煉鋼後鋼胚進行燒除處理,且於燒除處理期間,熔渣會形成於燒除後鋼胚之表面。詳述之,燒除處理之高溫會局部熔化鋼胚,故形成熔渣於燒除後鋼胚之表面上。此熔渣會降低所製得之鋼材的品質,所以必需去除。倘若燒除溫度不大於950℃,過低溫度不能改善煉鋼後鋼胚的線縫缺陷及脫碳層。反之,倘若燒除溫度大於1300℃,過高溫度會產生過多的熔渣。The conditions of the steel-making process are those commonly used by those with ordinary knowledge in the technical field to which the present invention belongs, for example: a steel-making temperature of 1100°C to 1200°C. Furthermore, the burning treatment is used to improve the seam defects and decarburization layer of the steel blank after steelmaking. The steel blank after steelmaking is burned at a burning temperature of greater than 950°C and not greater than 1300°C, and during the burning treatment, molten slag will be formed on the surface of the burned steel blank. To elaborate, the high temperature of the burning treatment will partially melt the steel blank, thus forming slag on the surface of the burned steel blank. This slag degrades the quality of the steel produced and must be removed. If the burning temperature is not greater than 950°C, too low a temperature cannot improve the seam defects and decarburization layer of the steel blank after steelmaking. On the contrary, if the burning temperature is greater than 1300℃, too high temperature will produce too much slag.
在進行操作110後,對燒除後鋼胚進行去除處理,以去除熔渣,如操作120所示。前述去除處理係將燒除後鋼胚持溫於950℃至1100℃,並以具有不小於170巴之壓力的水沖洗燒除後鋼胚之表面,以去除熔渣。前述之持溫之目的係確保在生成之熔渣未固化前,將其快速去除。After
倘若燒除後鋼胚之燒除溫度小於950℃,熔渣已經固化於鋼胚表面,故無法以水除去。反之,倘若燒除後鋼胚之溫度大於1100℃,鋼胚的表面處於過熱的狀態,水不能發揮沖洗的效果,亦無法除去熔渣。If the burning temperature of the steel blank after burning is less than 950°C, the slag has solidified on the surface of the steel blank and cannot be removed with water. On the contrary, if the temperature of the steel blank after burning is greater than 1100°C, the surface of the steel blank will be in a superheated state, and the water will not be able to exert its flushing effect and the slag will not be removed.
此外,倘若水壓力小於170巴,過小壓力之水無法除去熔渣。較佳地,水壓力可為170巴至220巴。當水壓力為170巴至220巴時,水可除去熔渣,且不浪費水。In addition, if the water pressure is less than 170 bar, the water with too small pressure cannot remove the slag. Preferably, the water pressure may be from 170 bar to 220 bar. When the water pressure is 170 bar to 220 bar, the water can remove the slag without wasting water.
在一些實施例中,於去除處理期間,鋼胚之移動速度可為0.5m/sec至1.5m/sec。當移動速度為前述之範圍時,水與熔渣有足夠的接觸時間,以利於除去熔渣。In some embodiments, the moving speed of the steel blank during the removal process may be 0.5 m/sec to 1.5 m/sec. When the moving speed is within the aforementioned range, there is sufficient contact time between the water and the slag to facilitate removal of the slag.
在較佳的實施例中,進行去除處理之前,去除方法100排除降溫處理。當燒除後鋼胚之溫度一直維持在不小於950℃時,生成之熔渣不會固化,所以容易被去除。In a preferred embodiment, the
在一些應用例中,鋼胚表面熔渣之去除方法100可藉由高壓型噴嘴進行,其中高壓型噴嘴之數量可依據鋼胚表面的面積而定,例如,愈大面積使用愈多噴嘴,以同時對整個鋼胚表面進行熔渣之去除。在此些應用例中,噴嘴的噴射方向可與鋼胚表面的法線沒有特別限制,較佳地,二者可呈現70度至20度之角度。In some application examples, the
本發明之另一態樣是提出一種碳鋼材。此碳鋼材利用前述之鋼胚表面熔渣之去除方法所製得。碳鋼材可包含低碳鋼及/或高碳鋼。Another aspect of the invention provides a carbon steel material. This carbon steel is produced using the aforementioned method of removing slag from the surface of the steel blank. Carbon steel may include low carbon steel and/or high carbon steel.
舉例而言,低碳鋼可包含鋼種編號為AISI 1006之鋼材,其含有不大於0.08重量百分比之碳、0.25重量百分比至0.40重量百分比之錳、不大於0.040重量百分比之磷及不大於0.050重量百分比之硫。其次,高碳鋼可包含鋼種編號為AISI 1050之鋼材,其含有0.5重量百分比之碳,且其餘組成元素及含量如本發明所屬技術領域中具有通常知識者所習知者。For example, low carbon steel may include steel with steel grade number AISI 1006, which contains no more than 0.08 weight percent carbon, 0.25 to 0.40 weight percent manganese, no more than 0.040 weight percent phosphorus, and no more than 0.050 weight percent. of sulfur. Secondly, the high carbon steel may include steel with the steel grade number AISI 1050, which contains 0.5 weight percent carbon, and the remaining constituent elements and contents are as known to those with ordinary knowledge in the technical field to which the present invention belongs.
進一步,對於所製得之鋼材利用後述之火花時間試驗來評價去除熔渣之效果。舉例而言,在低碳鋼之實施中,低碳鋼之平均火花時間為不大於3分鐘。在高碳鋼之實施中,高碳鋼之平均火花時間為不大於4.5分鐘。Furthermore, the slag removal effect of the steel material produced was evaluated using the spark time test described below. For example, in low carbon steel implementations, the average spark time of low carbon steel is no greater than 3 minutes. In the implementation of high carbon steel, the average spark time of high carbon steel is no more than 4.5 minutes.
根據本發明之又一態樣,提出一種合金鋼材。此合金鋼材利用前述之鋼胚表面熔渣之去除方法所製得。合金鋼材可包含多元合金鋼及/或單元金鋼。According to another aspect of the present invention, an alloy steel is provided. This alloy steel is produced by using the aforementioned method of removing slag from the surface of the steel blank. Alloy steel may include multi-element alloy steel and/or unit gold steel.
本發明之單元金鋼係指僅包含一種金屬元素之鋼胚,但不排除製程中無法除去或必然殘留之餘量(如小於0.001重量百分比)的金屬元素。The unit gold steel of the present invention refers to a steel blank containing only one metal element, but it does not exclude metal elements that cannot be removed during the manufacturing process or must remain in a residual amount (such as less than 0.001 weight percent).
此外,多元合金鋼可包含鋼種編號為AISI 8620之鋼材,其含有0.5重量百分比之鉻、0.2重量百分比之鉬及0.5重量百分比之鎳。再者,單元合金鋼可包含鋼種編號為AISI 5120之鋼材,其含有0.17重量百分比至0.22重量百分比之碳、0.15重量百分比至0.3重量百分比之矽、0.7重量百分比至0.9重量百分比之錳、不大於0.035重量百分比之碘及不大於0.04重量百分比之硫。In addition, the multi-component alloy steel may include steel with steel grade number AISI 8620, which contains 0.5 weight percent chromium, 0.2 weight percent molybdenum and 0.5 weight percent nickel. Furthermore, the unit alloy steel may include steel with steel grade number AISI 5120, which contains 0.17 to 0.22 weight percent of carbon, 0.15 to 0.3 weight percent of silicon, 0.7 to 0.9 weight percent of manganese, not more than 0.035 weight percent iodine and no more than 0.04 weight percent sulfur.
在一些實施例中,多元合金鋼之平均火花時間可為不大於4.5分鐘。在另一些實施例中,單元合金鋼之平均火花時間可為不大於7.5分鐘。In some embodiments, the average spark time of the multicomponent alloy steel may be no greater than 4.5 minutes. In other embodiments, the average spark time of the unit alloy steel may be no greater than 7.5 minutes.
根據前述碳鋼材及合金鋼材之平均火花時間之結果,本發明之鋼胚表面熔渣之去除方法可適用於多種類型之鋼材。較佳地,去除方法可適用於碳鋼材(如低碳鋼與高碳鋼)及多元合金鋼。更佳地,去除方法更適用於多元合金鋼。According to the aforementioned average spark time results of carbon steel and alloy steel, the method for removing slag on the surface of steel blanks of the present invention can be applied to various types of steel. Preferably, the removal method can be applied to carbon steel (such as low carbon steel and high carbon steel) and multi-component alloy steel. Preferably, the removal method is more suitable for multi-component alloy steel.
鋼材之製造Manufacturing of steel
實施例1Example 1
實施例1之鋼材的製造係於鋼胚進行煉鋼處理後,再以大於950℃且不大於1300℃之溫度對鋼胚進行燒除處理,且在燒除處理後,立即於鋼胚尚處於950℃至1100℃下,以170巴至220巴之高壓水沖洗鋼胚之表面,鋼胚之移動速度為0.5m/sec至1.5m/sec,以去除燒除處理所產生之熔渣,再依序經過粗軋、精軋、剪切及冷卻之製程,以製得實施例1之鋼材。然後以後述之評價方式進行評價。The steel material of Example 1 is manufactured by performing steelmaking treatment on the steel blank, and then burning the steel blank at a temperature of greater than 950°C and not greater than 1300°C, and immediately after the burning treatment, the steel blank is still in the Wash the surface of the steel blank with high-pressure water of 170 bar to 220 bar at 950°C to 1100°C. The moving speed of the steel blank is 0.5m/sec to 1.5m/sec to remove the slag generated by the burning process. The steel material of Example 1 is obtained by sequentially undergoing the processes of rough rolling, finish rolling, shearing and cooling. Then evaluate using the evaluation method described below.
實施例2至4及比較例1至4Examples 2 to 4 and Comparative Examples 1 to 4
實施例2至4及比較例1至4之鋼材係以實施1相似的方法進行。不同的是,實施例2至4及比較例1至4使用不同的鋼胚種類,且比較例1至4未經去除處理。前述實施例1至4及比較例1至4之具體條件及評價結果如下表1所示。The steel materials of Examples 2 to 4 and Comparative Examples 1 to 4 were processed in a similar manner to Example 1. The difference is that Examples 2 to 4 and Comparative Examples 1 to 4 use different types of steel blanks, and Comparative Examples 1 to 4 are not removed. The specific conditions and evaluation results of the aforementioned Examples 1 to 4 and Comparative Examples 1 to 4 are shown in Table 1 below.
評價方式Evaluation method
火花之試驗Spark Test
火花之試驗係分別以矽滾輪貼近各實施例及各比較例所製得之鋼材表面,其中當鋼材表面存在熔渣時,滾動的矽滾輪會磨擦熔渣,而產生火花,且在矽滾輪磨掉熔渣後,火花便消失,故以火花產生的時間做為評價去除熔渣的效果。火花產生的時間愈短,去除熔渣的效果愈佳。The spark test was carried out by placing a silicon roller close to the surface of the steel produced in each of the examples and comparative examples. When there is molten slag on the surface of the steel, the rolling silicon roller will rub the slag and generate sparks. After the slag is removed, the spark disappears, so the time when the spark is generated is used to evaluate the effect of removing the slag. The shorter the spark generation time, the better the slag removal effect.
表1
請參閱表1,相較於未使用除處理之比較例1,屬於相同鋼材種類(即低碳鋼)之實施例1所測得之平均火花時間較短,即熔渣去除的效果較佳。相同地,對應於相同種類的鋼材之各實施例及比較例也存在相同的結果,故去除處理可有效去除鋼胚表面之熔渣。Please refer to Table 1. Compared with Comparative Example 1 that does not use removal treatment, the average spark time measured in Example 1 belonging to the same steel type (ie, low carbon steel) is shorter, that is, the slag removal effect is better. Similarly, the same results exist in the various examples and comparative examples corresponding to the same type of steel material, so the removal treatment can effectively remove the slag on the surface of the steel blank.
此外,此些實施例去除熔渣所花費的時間比習知使用砂輪片除去熔渣之方法所需花費的時間更短,故此些實施例可縮短去除熔渣的時間,並降低使用砂輪片的成本。In addition, the time it takes to remove slag in these embodiments is shorter than the time required by the conventional method of using grinding wheels to remove slag. Therefore, these embodiments can shorten the time to remove slag and reduce the cost of using grinding wheels. cost.
綜上所述,本發明之鋼胚表面熔渣之去除方法係將經特定溫度的燒除處理後之鋼胚維持於特定溫度下,並利用特定壓力的水沖洗鋼胚表面,以在表面生成之熔渣未固化前,將其快速去除,從而縮短去除熔渣的時間。To sum up, the method for removing slag on the surface of a steel embryo according to the present invention is to maintain the steel embryo at a specific temperature after being burned at a specific temperature, and use water at a specific pressure to rinse the surface of the steel embryo to generate slag on the surface. The slag is quickly removed before it solidifies, thereby shortening the slag removal time.
雖然本發明已以實施方式揭露如上,然其並非用以限定本發明,在本發明所屬技術領域中任何具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention. Anyone with ordinary knowledge in the technical field to which the present invention belongs can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the scope of protection of the present invention shall be determined by the appended patent application scope.
100:方法 110,120:操作 100:Method 110,120: Operation
為了對本發明之實施例及其優點有更完整之理解,現請參照以下之說明並配合相應之圖式。必須強調的是,各種特徵並非依比例描繪且僅係為了圖解目的。相關圖式內容說明如下: 圖1係繪示根據本發明之一實施例的鋼胚表面熔渣之去除方法的流程圖。 In order to have a more complete understanding of the embodiments of the present invention and its advantages, please refer to the following description together with the corresponding drawings. It must be emphasized that various features are not drawn to scale and are for illustration purposes only. The relevant diagram content is explained as follows: FIG. 1 is a flow chart illustrating a method for removing slag from the surface of a steel blank according to an embodiment of the present invention.
100:方法 100:Method
110,120:操作 110,120: Operation
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| US20080115624A1 (en) * | 2006-07-27 | 2008-05-22 | Jean Brodeur | Method of handling, conditioning and processing steel slags |
| CN104789718A (en) * | 2015-03-13 | 2015-07-22 | 中冶宝钢技术服务有限公司 | Steel slag recycling method |
| CN111235355A (en) * | 2020-03-05 | 2020-06-05 | 日照泰东环保科技有限公司 | Low-cost pre-melting slag equipment and control method thereof |
| WO2021095595A1 (en) * | 2019-11-13 | 2021-05-20 | Jfeスチール株式会社 | Method and system for operating production facility |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080115624A1 (en) * | 2006-07-27 | 2008-05-22 | Jean Brodeur | Method of handling, conditioning and processing steel slags |
| CN104789718A (en) * | 2015-03-13 | 2015-07-22 | 中冶宝钢技术服务有限公司 | Steel slag recycling method |
| WO2021095595A1 (en) * | 2019-11-13 | 2021-05-20 | Jfeスチール株式会社 | Method and system for operating production facility |
| CN111235355A (en) * | 2020-03-05 | 2020-06-05 | 日照泰东环保科技有限公司 | Low-cost pre-melting slag equipment and control method thereof |
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