TWI818684B - System to provide texture to surface of component for use in semiconductor processing chamber and method thereof - Google Patents
System to provide texture to surface of component for use in semiconductor processing chamber and method thereof Download PDFInfo
- Publication number
- TWI818684B TWI818684B TW111131114A TW111131114A TWI818684B TW I818684 B TWI818684 B TW I818684B TW 111131114 A TW111131114 A TW 111131114A TW 111131114 A TW111131114 A TW 111131114A TW I818684 B TWI818684 B TW I818684B
- Authority
- TW
- Taiwan
- Prior art keywords
- component
- photon beam
- laser
- photon
- photons
- Prior art date
Links
- 239000004065 semiconductor Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims description 39
- 239000007789 gas Substances 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 13
- 239000012080 ambient air Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 238000007493 shaping process Methods 0.000 claims description 3
- 230000003287 optical effect Effects 0.000 abstract description 19
- 239000011324 bead Substances 0.000 description 33
- 238000005422 blasting Methods 0.000 description 23
- 230000008569 process Effects 0.000 description 17
- 238000004140 cleaning Methods 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 238000009826 distribution Methods 0.000 description 11
- 235000012431 wafers Nutrition 0.000 description 11
- 238000010894 electron beam technology Methods 0.000 description 9
- 239000000758 substrate Substances 0.000 description 7
- 230000008859 change Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 238000011109 contamination Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000000737 periodic effect Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000012768 molten material Substances 0.000 description 4
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 241000287127 Passeridae Species 0.000 description 2
- 239000004696 Poly ether ether ketone Substances 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000005530 etching Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000013532 laser treatment Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 229920002530 polyetherether ketone Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000005488 sandblasting Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000012876 topography Methods 0.000 description 2
- 229910021654 trace metal Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910000767 Tm alloy Inorganic materials 0.000 description 1
- 229910001080 W alloy Inorganic materials 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- XJNCHICLWKVTQA-UHFFFAOYSA-N [Mo].[W].[Cr].[Ni] Chemical compound [Mo].[W].[Cr].[Ni] XJNCHICLWKVTQA-UHFFFAOYSA-N 0.000 description 1
- UMVBXBACMIOFDO-UHFFFAOYSA-N [N].[Si] Chemical compound [N].[Si] UMVBXBACMIOFDO-UHFFFAOYSA-N 0.000 description 1
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910000963 austenitic stainless steel Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- ZTXONRUJVYXVTJ-UHFFFAOYSA-N chromium copper Chemical compound [Cr][Cu][Cr] ZTXONRUJVYXVTJ-UHFFFAOYSA-N 0.000 description 1
- BIJOYKCOMBZXAE-UHFFFAOYSA-N chromium iron nickel Chemical compound [Cr].[Fe].[Ni] BIJOYKCOMBZXAE-UHFFFAOYSA-N 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910000856 hastalloy Inorganic materials 0.000 description 1
- 229910001026 inconel Inorganic materials 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000001020 plasma etching Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/352—Working by laser beam, e.g. welding, cutting or boring for surface treatment
- B23K26/355—Texturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/0006—Working by laser beam, e.g. welding, cutting or boring taking account of the properties of the material involved
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
- B23K26/062—Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam
- B23K26/0622—Shaping the laser beam, e.g. by masks or multi-focusing by direct control of the laser beam by shaping pulses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/02—Positioning or observing the workpiece, e.g. with respect to the point of impact; Aligning, aiming or focusing the laser beam
- B23K26/06—Shaping the laser beam, e.g. by masks or multi-focusing
- B23K26/064—Shaping the laser beam, e.g. by masks or multi-focusing by means of optical elements, e.g. lenses, mirrors or prisms
- B23K26/0648—Shaping the laser beam, e.g. by masks or multi-focusing by means of optical elements, e.g. lenses, mirrors or prisms comprising lenses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
- B23K26/0823—Devices involving rotation of the workpiece
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
- B23K26/083—Devices involving movement of the workpiece in at least one axial direction
- B23K26/0853—Devices involving movement of the workpiece in at least in two axial directions, e.g. in a plane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/08—Devices involving relative movement between laser beam and workpiece
- B23K26/0869—Devices involving movement of the laser head in at least one axial direction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/12—Working by laser beam, e.g. welding, cutting or boring in a special atmosphere, e.g. in an enclosure
- B23K26/123—Working by laser beam, e.g. welding, cutting or boring in a special atmosphere, e.g. in an enclosure in an atmosphere of particular gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/12—Working by laser beam, e.g. welding, cutting or boring in a special atmosphere, e.g. in an enclosure
- B23K26/127—Working by laser beam, e.g. welding, cutting or boring in a special atmosphere, e.g. in an enclosure in an enclosure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/36—Removing material
- B23K26/362—Laser etching
- B23K26/364—Laser etching for making a groove or trench, e.g. for scribing a break initiation groove
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/36—Removing material
- B23K26/38—Removing material by boring or cutting
- B23K26/382—Removing material by boring or cutting by boring
- B23K26/384—Removing material by boring or cutting by boring of specially shaped holes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K26/00—Working by laser beam, e.g. welding, cutting or boring
- B23K26/36—Removing material
- B23K26/40—Removing material taking account of the properties of the material involved
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2101/00—Articles made by soldering, welding or cutting
- B23K2101/36—Electric or electronic devices
- B23K2101/40—Semiconductor devices
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2101/00—Articles made by soldering, welding or cutting
- B23K2101/36—Electric or electronic devices
- B23K2101/42—Printed circuits
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K2103/00—Materials to be soldered, welded or cut
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Plasma & Fusion (AREA)
- Mechanical Engineering (AREA)
- Laser Beam Processing (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Chemical Vapour Deposition (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Recrystallisation Techniques (AREA)
- Cleaning In General (AREA)
- Automation & Control Theory (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
Abstract
Description
本揭示內容的具體實施例大抵涉及用於對部件表面進行紋理化的方法、系統與設備,此部件係使用在半導體處理腔室中。Embodiments of the present disclosure generally relate to methods, systems, and apparatus for texturing surfaces of components for use in semiconductor processing chambers.
隨著積體電路裝置繼續以減小的尺寸製造,這些裝置的製造變得更容易因污染而降低良率。因此,製造積體電路裝置(特別是具有較小實體尺寸的積體電路裝置),需要比以前認為必要的程度更大程度地控制污染。As integrated circuit devices continue to be manufactured at reduced sizes, the fabrication of these devices becomes more susceptible to yield degradation due to contamination. Therefore, the manufacture of integrated circuit devices, particularly those with smaller physical dimensions, requires a greater degree of contamination control than previously thought necessary.
積體電路裝置的污染,可能源於諸如在薄膜沉積、蝕刻或其他半導體製造處理期間,撞擊在基板上的不期望的雜散粒子之類的來源。一般而言,積體電路裝置的製造包括使用腔室,包括但不限於物理氣相沉積(PVD)濺射腔室、化學氣相沉積(CVD)腔室和電漿蝕刻腔室。在沉積和蝕刻處理中,材料通常從氣相冷凝到腔室的各個內表面上,以及設置在腔室內的腔室部件的表面上。當材料從氣相冷凝時,材料形成駐留在腔室和部件表面上的固體塊。此冷凝的異物積聚在表面上,並且在晶圓處理序列期間或之間易於從表面脫離或剝落。這種分離的異物可能撞擊並污染晶圓和在晶圓上形成的裝置。受污染的裝置經常必須被丟棄,從而降低了處理的製造良率。Contamination of integrated circuit devices can result from sources such as undesirable stray particles striking the substrate during film deposition, etching, or other semiconductor manufacturing processes. Generally speaking, the fabrication of integrated circuit devices includes the use of chambers, including, but not limited to, physical vapor deposition (PVD) sputtering chambers, chemical vapor deposition (CVD) chambers, and plasma etching chambers. During deposition and etching processes, material typically condenses from the gas phase onto various interior surfaces of the chamber, as well as on the surfaces of chamber components disposed within the chamber. As the material condenses from the gas phase, the material forms solid masses that reside on the surfaces of the chamber and components. This condensed foreign material accumulates on the surface and tends to detach or peel from the surface during or between wafer processing sequences. Such detached foreign matter may impact and contaminate the wafer and devices formed on the wafer. Contaminated devices often must be discarded, reducing the manufacturing yield of the process.
為了防止已經形成的異物的分離,腔室的內表面和設置在腔室內的腔室部件的表面,可以具有特定的表面紋理。表面紋理被配置成使得在這些表面上形成的異物具有增強的對表面的黏附性,並且不太可能分離且污染晶圓。表面紋理的關鍵參數是表面粗糙度。In order to prevent the separation of foreign matter that has formed, the inner surface of the chamber and the surface of the chamber components disposed within the chamber may have a specific surface texture. The surface texture is configured such that foreign matter that forms on these surfaces has enhanced adhesion to the surface and is less likely to detach and contaminate the wafer. The key parameter for surface texture is surface roughness.
一種常見的紋理化方法是珠粒噴砂(bead blasting)。在珠粒噴砂處理中,將固體噴砂珠推向要進行紋理化的表面。一種方式可為通過加壓氣體將固體噴砂珠推向待紋理化的表面。固體噴砂珠由合適的材料製成,例如氧化鋁、玻璃、二氧化矽或硬塑膠。根據所需的表面粗糙度,噴砂珠粒可具有不同的尺寸和形狀。One common texturing method is bead blasting. In bead blasting, solid blasting beads are pushed against the surface to be textured. One approach may be to push solid blast beads through pressurized gas against the surface to be textured. Solid blasting beads are made from suitable materials such as alumina, glass, silica or hard plastic. Sandblasting beads can be of different sizes and shapes depending on the desired surface roughness.
然而,可能難以控制珠粒噴砂處理的均勻性和可重複性。此外,在珠粒噴砂處理過程中,待紋理化的表面可能變得尖銳並為鋸齒狀,使得表面的尖端由於固體噴砂珠的衝擊而脫落,從而引入污染源。另外,在珠粒噴砂處理期間,噴砂珠粒可能被捕獲或嵌入表面內。例如,如果被紋理化的表面包括具有變化寬度的小通孔(例如氣體分配噴淋頭),則噴砂珠粒可能陷入通孔內。在這種情況下,噴砂珠不僅例如防止通孔起到氣體通道的作用,而且還引入了晶圓的潛在污染源。However, it can be difficult to control the uniformity and repeatability of bead blasting. Additionally, during bead blasting, the surface to be textured may become sharp and jagged, causing the tips of the surface to break off due to the impact of the solid blast beads, thereby introducing a source of contamination. Additionally, during bead blasting, blast beads may become trapped or embedded within the surface. For example, if the surface being textured includes small through-holes with varying widths (such as a gas distribution sprinkler head), sandblasting beads may become trapped within the through-holes. In this case, the sandblast beads not only prevent the vias from functioning as gas channels, for example, but also introduce a potential source of contamination to the wafer.
電磁束也可用於使腔室表面紋理化。使用電磁束使腔室表面紋理化,可以克服與珠粒噴砂相關的一些上述問題。但是,電磁束必須在真空下操作以防止散射。當電磁束內的電子與空氣或其他氣體分子相互作用時,可能發生散射。因此,電磁束必須在真空腔室內操作。對真空腔室的需求限制了可以紋理化的部件的尺寸,因為部件必須能夠裝配在真空腔室內。此外,與操作電磁束相關的資本成本,顯著高於與珠粒噴砂處理相關的資本成本。例如,對真空腔室的需求增加了與用電磁束紋理化表面相關的成本。Electromagnetic beams can also be used to texture chamber surfaces. Texturing the chamber surface using an electromagnetic beam can overcome some of the above-mentioned problems associated with bead blasting. However, electromagnetic beams must be operated under vacuum to prevent scattering. Scattering can occur when electrons within an electromagnetic beam interact with air or other gas molecules. Therefore, the electromagnetic beam must be operated within a vacuum chamber. The need for a vacuum chamber limits the size of the parts that can be textured because the parts must be able to fit within the vacuum chamber. Furthermore, the capital costs associated with operating the electromagnetic beam are significantly higher than those associated with bead blasting. For example, the need for a vacuum chamber increases the costs associated with texturing surfaces with electromagnetic beams.
因此,需要一種改進的紋理化方法,此方法克服了與珠粒噴砂相關的問題,同時避免了與使用電磁束相關的資本成本和尺寸限制。Therefore, there is a need for an improved texturing method that overcomes the problems associated with bead blasting while avoiding the capital costs and size limitations associated with the use of electromagnetic beams.
本揭示內容的一個實施例涉及用於對部件表面進行紋理化的方法,此部件係使用在半導體處理腔室中。方法包括:將光子束引導通過環境空氣或氮氣至部件表面處;以及跨部件表面第一區域掃描光子束,以在第一區域內的表面上形成複數個特徵,其中形成的特徵是凹陷、突起或其組合。One embodiment of the present disclosure relates to a method for texturing the surface of a component for use in a semiconductor processing chamber. The method includes: directing a photon beam through ambient air or nitrogen to a component surface; and scanning the photon beam across a first region of the component surface to form a plurality of features on the surface in the first region, wherein the formed features are depressions, protrusions or combination thereof.
本揭示內容的另一個實施例涉及用於對部件表面進行紋理化的方法,此部件係使用在半導體處理腔室中。方法包括:將光子束引導至在大氣中部件表面處,大氣的壓力大抵均等於大氣壓力;以及跨部件表面第一區域掃描光子束,以在第一區域內的表面上形成複數個特徵,其中形成的特徵是凹陷、突起或其組合。Another embodiment of the present disclosure relates to a method for texturing the surface of a component for use in a semiconductor processing chamber. The method includes directing a photon beam to a surface of the component in an atmosphere at a pressure approximately equal to atmospheric pressure; and scanning the photon beam across a first region of the component surface to form a plurality of features on the surface within the first region, wherein The features formed are depressions, protrusions, or a combination thereof.
本揭示內容的另一個具體實施例是用於半導體處理腔室的部件。部件包括在第一區域內的表面上的複數個特徵,其中形成的特徵是凹陷、突起或其組合。藉由跨部件表面掃描光子束來形成這些特徵。Another specific embodiment of the present disclosure is a component for a semiconductor processing chamber. The component includes a plurality of features on the surface within the first region, wherein the formed features are depressions, protrusions, or a combination thereof. These features are created by scanning a photon beam across the part's surface.
本揭示內容的另一個具體實施例為一種為部件表面提供紋理的系統,部件使用在半導體處理腔室中。系統包含:外殼,外殼包含處理區域;設置在處理區域中的包含支撐表面的支座;用於產生光子流的光子光源;可操作地耦合至光子光源以接收來自光子光源的光子流的光學模組;以及透鏡。光學模組包含光束調變器與光束掃描器,光束調變器用於從光子光源產生的光子流產生光子束,光束掃描器用於跨部件表面掃描光子束。透鏡用於接收來自光束掃描器的光子束,並在約345nm至約1100nm之間的範圍的波長下,跨部件的表面分佈光子束,以在部件上形成複數個特徵。Another embodiment of the present disclosure is a system for providing texture to the surface of a component for use in a semiconductor processing chamber. The system includes: a housing including a processing area; a support including a support surface disposed in the processing area; a photon light source for generating a photon light source; and an optical module operably coupled to the photon light source to receive the photon flow from the photon light source. groups; and lenses. The optical module includes a beam modulator for generating a photon beam from a stream of photons generated by a photon light source, and a beam scanner for scanning the photon beam across the component surface. The lens is used to receive the photon beam from the beam scanner and distribute the photon beam across the surface of the component at wavelengths ranging from about 345 nm to about 1100 nm to form a plurality of features on the component.
本揭示內容的另一個具體實施例是一種為部件的表面提供紋理的方法,部件使用在半導體處理腔室中。方法包含:產生光子流;將光子流整形為光束;掃描光子束透過處理區域朝向部件的表面,處理區域包含環境空氣或氮氣的氣體濃度,且環境空氣或氮氣的壓力大抵均等於大氣壓力;以及跨部件的表面分佈光子束,以在表面上形成複數個特徵。Another embodiment of the present disclosure is a method of providing texture to a surface of a component for use in a semiconductor processing chamber. The method includes: generating a stream of photons; shaping the stream of photons into a beam; scanning the beam of photons through a processing region toward a surface of the component, the processing region containing a gas concentration of ambient air or nitrogen, and the pressure of the ambient air or nitrogen being approximately equal to atmospheric pressure; and The photon beam is distributed across the surface of the component to create features on the surface.
再者,本揭示內容的又另一個具體實施例為一種為部件表面提供紋理的系統,部件使用在半導體處理腔室中。系統包含:外殼,外殼包含被維持為1級(Class 1)環境的處理區域,具有大抵均等於大氣壓力的壓力;設置在處理區域中的包含支撐表面的支座;用於產生光子流的光子光源;可操作地耦合至光子光源以接收來自光子光源的光子流的光學模組;以及透鏡。光學模組包含光束調變器與光束掃描器,光束調變器用於從光子光源產生的光子流產生光子束,光束掃描器用於跨部件表面掃描光子束。透鏡設置在處理區域中,用於接收來自光束掃描器的光子束,並在約345nm至約1100nm之間的範圍的波長下,跨部件的表面分佈光子束,以在部件上形成複數個特徵。Yet another embodiment of the present disclosure is a system for providing texture to the surface of a component for use in a semiconductor processing chamber. The system includes: a housing containing a processing area maintained as a Class 1 environment with a pressure approximately equal to atmospheric pressure; a support containing a support surface disposed in the processing area; photons for generating a stream of photons a light source; an optical module operably coupled to the photon light source to receive a stream of photons from the photon light source; and a lens. The optical module includes a beam modulator for generating a photon beam from a stream of photons generated by a photon light source, and a beam scanner for scanning the photon beam across the component surface. A lens is disposed in the processing area for receiving the photon beam from the beam scanner and distributing the photon beam across the surface of the component at wavelengths ranging from about 345 nm to about 1100 nm to form a plurality of features on the component.
本文描述的實施例,利用由雷射產生的光子束,以在部件的表面上進行紋理化處理,此部件用於半導體處理腔室中。光子束指向部件的表面,並掃過表面區域以形成複數個特徵。在表面上形成的特徵,包括凹陷、突起及(或)其組合。光子束可被減少強度、散焦及(或)以特定的行進速度掃描,以形成所需的表面形態。Embodiments described herein utilize a photon beam generated by a laser to texture the surface of a component used in a semiconductor processing chamber. The photon beam is directed at the surface of the part and sweeps across the surface area to create features. Features formed on a surface, including depressions, protrusions, and/or combinations thereof. The photon beam can be reduced in intensity, defocused and/or scanned at a specific travel speed to create the desired surface morphology.
圖1描繪了雷射機100的示意圖,雷射機100可用於將部件104的表面103與支撐系統102紋理化。部件104可以是例如氣體分配噴淋頭、腔室壁或靜電吸盤。雷射機100包括電源供應器106、控制器108和雷射裝置116。雷射裝置116輸出光子束112。控制器108可以包括調變器及(或)掃描器,以調變和掃描光子束112。雷射機還可以包括脈衝供應單元,以脈衝化光子束112。脈衝化光子束112可有助於最小化施加到部件104的表面103的熱量。另外,脈衝化光子束112可以幫助減少由於部件104的表面103的反射而引起的問題。本文揭示的具體實施例可用於使部件104的表面103紋理化,以具有約60μin至約360μin的粗糙度輪廓的算術平均值(Ra)。FIG. 1 depicts a schematic diagram of a laser machine 100 that may be used to texture a surface 103 of a component 104 with a support system 102 . Component 104 may be, for example, a gas distribution showerhead, a chamber wall, or an electrostatic chuck. The laser machine 100 includes a power supply 106, a controller 108 and a laser device 116. Laser device 116 outputs photon beam 112 . Controller 108 may include modulators and/or scanners to modulate and scan photon beam 112 . The laser may also include a pulse supply unit to pulse the photon beam 112 . Pulsed photon beam 112 may help minimize heat applied to surface 103 of component 104 . Additionally, the pulsed photon beam 112 can help reduce problems caused by reflections from the surface 103 of the component 104 . Specific embodiments disclosed herein may be used to texture surface 103 of component 104 to have an arithmetic mean (Ra) roughness profile of about 60 μin to about 360 μin.
部件104可包括的材料諸如金屬或金屬合金、陶瓷材料、聚合物材料、複合材料或其組合。在一個實施例中,部件104包括選自包含以下材料之群組的材料:鋼、不銹鋼、鉭、鎢、鈦、銅、鋁、鎳、金、銀、氧化鋁、氮化鋁、矽、氮化矽、氧化矽、碳化矽、藍寶石(Al 2O 3)、氮化矽、氧化釔(yttria)、氧化釔(yttrium oxide)及其組合。在一個實施例中,部件104包括金屬合金,諸如奧氏體不銹鋼、鐵-鎳-鉻合金(例如Inconel TM合金)、鎳-鉻-鉬-鎢合金(例如Hastelloy TM)、銅鋅合金、鉻銅合金(例如5%或10%Cr,餘量為Cu)等。在另一個實施方案中,部件包含石英。部件104還可以包括聚合物,諸如聚酰亞胺(Vespel TM)、聚醚醚酮(PEEK)、聚芳酯(Ardel TM)等。在又一實施例中,部件104可以包括諸如金、銀、鋁矽、鍺、鍺矽、氮化硼、氧化鋁、氮化鋁、矽、氮化矽、氧化矽、碳化矽、氧化釔、氧化釔、非聚合物及其組合。 Component 104 may include materials such as metals or metal alloys, ceramic materials, polymeric materials, composite materials, or combinations thereof. In one embodiment, component 104 includes a material selected from the group consisting of: steel, stainless steel, tantalum, tungsten, titanium, copper, aluminum, nickel, gold, silver, aluminum oxide, aluminum nitride, silicon, nitrogen Silicon, silicon oxide, silicon carbide, sapphire (Al 2 O 3 ), silicon nitride, yttria (yttria), yttrium oxide (yttrium oxide) and combinations thereof. In one embodiment, component 104 includes a metal alloy such as austenitic stainless steel, iron-nickel-chromium alloy (eg, Inconel ™ alloy), nickel-chromium-molybdenum-tungsten alloy (eg, Hastelloy ™ ), copper-zinc alloy, chromium Copper alloys (e.g. 5% or 10% Cr, balance Cu) etc. In another embodiment, the component includes quartz. Component 104 may also include polymers such as polyimide (Vespel ™ ), polyetheretherketone (PEEK), polyarylate (Ardel ™ ), and the like. In yet another embodiment, component 104 may include components such as gold, silver, aluminum silicon, germanium, silicon germanium, boron nitride, aluminum oxide, aluminum nitride, silicon, silicon nitride, silicon oxide, silicon carbide, yttrium oxide, Yttrium oxide, non-polymers and combinations thereof.
支撐系統102可以位於雷射機100的下游。支撐系統102包括支撐件122,諸如類似於一個或多個具體實施例中的基板支座,用於支撐部件104。支撐系統102和雷射機100相對於彼此定位,使得由雷射裝置116輸出的光子束112指向部件104的表面103。在圖1所示的本揭示內容的一個實施例中,雷射機100還可以包括用於調節雷射裝置116的輸出的位置的致動構件124。在這樣的實施例中,支座122可以保持靜止,並且致動構件124可以調整雷射裝置116的輸出位置,從而使得由雷射裝置116輸出的光子束112被在表面103上掃描。在圖2所示的本揭示內容的替代實施例中,支撐系統102可包括用於移動支座122的致動構件124。在這樣的實施例中,雷射裝置116的輸出可以保持靜止,並且致動構件124可以調節支座122的位置,從而使得由雷射裝置116輸出的光子束112在表面103上掃描。用於調節雷射裝置116或支座122的位置的致動構件124,可包括例如X-Y平台、延伸臂及(或)能夠進行平移運動及(或)旋轉運動的旋轉軸。Support system 102 may be located downstream of laser 100 . Support system 102 includes supports 122 , such as substrate supports similar to one or more embodiments, for supporting components 104 . The support system 102 and the laser 100 are positioned relative to each other such that the photon beam 112 output by the laser device 116 is directed toward the surface 103 of the component 104 . In one embodiment of the present disclosure shown in FIG. 1 , laser 100 may also include an actuation member 124 for adjusting the position of the output of laser device 116 . In such embodiments, the support 122 may remain stationary and the actuating member 124 may adjust the output position of the laser device 116 such that the photon beam 112 output by the laser device 116 is scanned across the surface 103 . In an alternative embodiment of the present disclosure shown in FIG. 2 , the support system 102 may include an actuation member 124 for moving the stand 122 . In such embodiments, the output of laser device 116 may remain stationary and actuating member 124 may adjust the position of support 122 such that photon beam 112 output by laser device 116 scans across surface 103 . The actuation member 124 for adjusting the position of the laser device 116 or the support 122 may include, for example, an X-Y stage, an extension arm, and/or a rotation axis capable of translational and/or rotational motion.
控制器108可以連接到雷射裝置116,並使得控制器能夠控制與雷射裝置116輸出的光子束112相關聯的各種參數。具體而言,控制器108可以連接到雷射裝置116,以至少控制與光子束112相關的以下參數:波長、脈衝寬度、重複率、行進速度、功率位準、和光束尺寸。由於能夠控制與光子束112相關聯的這些各種參數,控制器108能夠控制在部件104的表面103上形成的表面形態。應當理解,「行進速度」包括其中光子束112正在移動並且部件104靜止的實施例,以及光子束112靜止並且部件正在移動的實施例。如圖2所示,控制器108還可以連接到支撐系統102,而使得控制器能夠控制連接到支座122的致動構件124。或者,輔助控制器可以連接到支撐系統102,以控制連接到支座122的致動構件124。The controller 108 may be coupled to the laser device 116 and enable the controller to control various parameters associated with the photon beam 112 output by the laser device 116 . Specifically, the controller 108 may be coupled to the laser device 116 to control at least the following parameters associated with the photon beam 112: wavelength, pulse width, repetition rate, travel speed, power level, and beam size. By being able to control these various parameters associated with the photon beam 112, the controller 108 is able to control the surface morphology formed on the surface 103 of the component 104. It should be understood that "speed of travel" includes embodiments in which the photon beam 112 is moving and the component 104 is stationary, as well as embodiments in which the photon beam 112 is stationary and the component is moving. As shown in FIG. 2 , the controller 108 may also be connected to the support system 102 such that the controller can control the actuation member 124 connected to the support 122 . Alternatively, an auxiliary controller may be connected to the support system 102 to control the actuation member 124 connected to the mount 122 .
控制器108可以是可以在工業環境中使用的任何形式的一般用途電腦處理器(CPU)之一。電腦可以使用任何合適的記憶體,諸如隨機存取記憶體、唯讀記憶體、軟碟機、硬碟、或任何其他形式的本端或遠端的數位儲存器。各種支援電路可以耦合到CPU,以便以習知方式支援處理器。所需的軟體程序可以存儲在記憶體中,或由位於遠端的第二CPU執行。軟體程序在執行時,將一般用途電腦轉換為控制作業的特定程序電腦,以便執行腔室處理。或者,本文描述的實施例可以在硬體中執行,作為特定應用積體電路或其他類型的硬體實施例,或者軟體或硬體的組合。Controller 108 may be one of any form of general purpose computer processor (CPU) that may be used in an industrial environment. The computer may use any suitable memory, such as random access memory, read-only memory, floppy disk, hard disk, or any other form of local or remote digital storage. Various support circuits may be coupled to the CPU to support the processor in a conventional manner. The required software programs can be stored in memory or executed by a second CPU located remotely. The software program, when executed, converts the general-purpose computer into a program-specific computer that controls the operations required to perform chamber processing. Alternatively, embodiments described herein may be implemented in hardware, as application specific integrated circuits or other types of hardware embodiments, or a combination of software or hardware.
雷射機100的雷射裝置116可具有約3W至約30W的功率輸出。或者,雷射機可具有約1W至約150W的功率輸出。雷射裝置116還能夠脈衝化和改變與光子束112相關的參數(例如波長、脈衝寬度、脈衝頻率、重複率、行進速度、功率位準和光束尺寸),這將在下面進行更詳細討論。雷射機100的雷射裝置116可以是市售的雷射。可符合本揭示內容的市售雷射機的範例是Spectral Physics Quanta-Ray Laser的IPG YLPP雷射。The laser device 116 of the laser machine 100 may have a power output of about 3W to about 30W. Alternatively, the laser may have a power output of about 1W to about 150W. Laser device 116 is also capable of pulsing and changing parameters associated with photon beam 112 (such as wavelength, pulse width, pulse frequency, repetition rate, travel speed, power level, and beam size), which are discussed in more detail below. The laser device 116 of the laser machine 100 may be a commercially available laser. An example of a commercially available laser that would fit within the scope of this disclosure is Spectral Physics Quanta-Ray Laser's IPG YLPP laser.
雷射機100和支撐系統102不需要真空環境來執行紋理化處理,因為雷射裝置116的輸出是光子束112。因此,雷射裝置116的輸出不同於習知的電磁束產生系統,其中使用電子束以執行紋理化處理。由於電子與環境氣體原子的相互作用和散射,電磁束系統通常需要真空環境(例如真空腔室),因此真空環境對於保持電子束的精確控制是必要的。如上所述,真空環境的要求對可以使用電磁束系統進行紋理化的部件的尺寸施加了實體限制,因為部件必須能夠被裝配在真空腔室內。此外,真空環境的要求增加了電磁系統的複雜性,因為真空腔室必須包括特殊設備(例如泵、感測器、密封件)。因此,電磁束系統的資本成本,比使用本揭示內容中討論的雷射機100和支撐系統102進行紋理化處理時所產生的資本成本顯著更高。Laser 100 and support system 102 do not require a vacuum environment to perform the texturing process because the output of laser device 116 is photon beam 112. Therefore, the output of the laser device 116 differs from conventional electromagnetic beam generation systems in which electron beams are used to perform the texturing process. Electromagnetic beam systems often require a vacuum environment (such as a vacuum chamber) due to the interaction and scattering of electrons with ambient gas atoms, so a vacuum environment is necessary to maintain precise control of the electron beam. As mentioned above, the requirements of a vacuum environment impose physical limitations on the size of parts that can be textured using electromagnetic beam systems, since the parts must be able to be assembled within the vacuum chamber. Furthermore, the requirements of a vacuum environment increase the complexity of the electromagnetic system because the vacuum chamber must include special equipment (e.g., pumps, sensors, seals). Therefore, the capital cost of the electromagnetic beam system is significantly higher than that incurred when texturing using the laser 100 and support system 102 discussed in this disclosure.
因此,雷射機100和支撐系統102可以用在環境空氣環境中,其中光子束112通過的空氣是大約78%的氮和大約21%的氧。然而,在某些情況下,可能期望將雷射機100和支撐系統102定位在貧氧環境中。在這種情況下,雷射機100和支撐系統102可以定位在使用氮氣代替環境空氣的腔室內。因為不需要真空,所以腔室內的壓力可以保持在大氣壓。應該理解到,在不同位置處的「大氣壓」可以不同。在一些實施例中,在處理期間部件104所在區域中的壓力可以是不受管制的。Accordingly, laser 100 and support system 102 may be used in ambient air environments where the air through which photon beam 112 passes is approximately 78% nitrogen and approximately 21% oxygen. However, in some cases, it may be desirable to position the laser 100 and support system 102 in an oxygen-depleted environment. In this case, the laser 100 and support system 102 may be positioned within a chamber using nitrogen gas instead of ambient air. Because a vacuum is not required, the pressure within the chamber can be maintained at atmospheric pressure. It should be understood that the "atmospheric pressure" can be different at different locations. In some embodiments, the pressure in the area where component 104 is located may be unregulated during processing.
圖4描繪了用於操作雷射機100和支撐系統102的方法的處理序列200,處理序列200開始於201並結束於209。在框202處,部件104定位在支座122上。在框204處,在部件104的表面103上限定第一區域126。如圖3所示,其中部件104是具有複數個通孔135的氣體分配噴淋頭133,第一區域126具有限定第一區域的外邊界的第一外邊界127。第一外邊界127限定第一表面區域。部件104的第一表面積與第二表面積的比率可以是至少0.6。部件104的第二表面區域由被紋理化的表面103的第二外邊界132限定。因此,位於第二表面區域內的第一表面區域可以是第二表面區域的至少60%。應該理解,第一和第二表面區域的尺寸將根據正在紋理化的部件104的形狀和尺寸而變化。或者,第一表面積與第二表面積的比率可以大於0.7、0.8及(或)0.9。FIG. 4 depicts a process sequence 200 for a method of operating laser machine 100 and support system 102 , beginning at 201 and ending at 209 . At block 202 , component 104 is positioned on support 122 . At block 204, a first region 126 is defined on the surface 103 of the component 104. As shown in Figure 3, in which component 104 is a gas distribution showerhead 133 having a plurality of through holes 135, first region 126 has a first outer boundary 127 defining an outer boundary of the first region. The first outer boundary 127 defines a first surface area. The ratio of the first surface area to the second surface area of component 104 may be at least 0.6. The second surface area of component 104 is defined by the second outer boundary 132 of textured surface 103 . Therefore, the first surface area located within the second surface area may be at least 60% of the second surface area. It should be understood that the size of the first and second surface areas will vary depending on the shape and size of the component 104 being textured. Alternatively, the ratio of the first surface area to the second surface area may be greater than 0.7, 0.8, and/or 0.9.
在框206處,雷射機100經由電源供應器106供電,使得雷射裝置116輸出光子束112。如上所述,雷射機100的控制器108可以根據表面103上的所需紋理,改變與光子束112相關的參數。在一個實施例中,光子束112可具有介於約345nm與約1100nm之間的波長。在另一個實施例中,光子束可具有紫外光範圍(約170nm至約400nm)的波長。在又一實施例中,光子束可具有紅外光範圍內(約700nm至約1.1mm)的波長。由雷射裝置116輸出的光子束112,被引導朝向部件104的表面103於第一區域126內的位置處。光子束112可以在部件104的表面103處具有在約7μm至約75μm的範圍內的光束直徑。或者,光子束112可以在部件104的表面103處具有在約2.5μm至約100μm的範圍內的光束直徑。在一種實施例中,光子束112行進的工作距離為約50毫米至約1,000毫米。在另一實施例中,光子束112行進的工作距離在約200毫米至約350毫米之間。由於雷射機100的雷射裝置116可具有在約1W至約150W範圍內的功率輸出,因此光子束112可具有在約10×10 -6J至約400×10 -6J範圍內的脈衝功率。光子束112可以具有在大約10ps到大約30ns之間的範圍內的脈衝寬度。此外,在一個具體實施例中,光子束112可以具有在大約10KHz到大約200KHz之間的範圍內的脈衝重複率,並且更具體而言,在另一個具體實施例中,在大約10KHz到大約3MHz之間的範圍內。控制器108可用於控制雷射裝置116的脈衝寬度及(或)脈衝重複率。 At block 206 , laser 100 is powered via power supply 106 such that laser device 116 outputs photon beam 112 . As discussed above, the controller 108 of the laser 100 can change the parameters associated with the photon beam 112 based on the desired texture on the surface 103 . In one embodiment, photon beam 112 may have a wavelength between approximately 345 nm and approximately 1100 nm. In another embodiment, the photon beam may have a wavelength in the ultraviolet range (about 170 nm to about 400 nm). In yet another embodiment, the photon beam may have a wavelength in the infrared range (about 700 nm to about 1.1 mm). The photon beam 112 output by the laser device 116 is directed toward the surface 103 of the component 104 at a location within the first region 126 . Photon beam 112 may have a beam diameter in the range of about 7 μm to about 75 μm at surface 103 of component 104 . Alternatively, the photon beam 112 may have a beam diameter in the range of about 2.5 μm to about 100 μm at the surface 103 of the component 104 . In one embodiment, the photon beam 112 travels a working distance of about 50 millimeters to about 1,000 millimeters. In another embodiment, the photon beam 112 travels a working distance of between about 200 millimeters and about 350 millimeters. Since laser device 116 of laser machine 100 may have a power output in the range of about 1 W to about 150 W, photon beam 112 may have pulses in the range of about 10×10 −6 J to about 400×10 −6 J power. Photon beam 112 may have a pulse width in the range between approximately 10 ps and approximately 30 ns. Additionally, in one embodiment, the photon beam 112 may have a pulse repetition rate in the range between about 10 KHz to about 200 KHz, and more specifically, in another embodiment, between about 10 KHz to about 3 MHz. within the range between. The controller 108 may be used to control the pulse width and/or pulse repetition rate of the laser device 116 .
在框208處,橫跨表面103的第一區域126掃描光子束112,從而在表面上形成複數個特徵。光子束112可以由約0.1 m/s至約30 m/s的行進速度掃過表面103的第一區域126,例如當從雷射裝置116脈衝輸出光子束112時。如在圖5至10中可以看到的,由於光子束112被掃過表面103的第一區域126而形成的特徵,包括凹陷、突起或其組合。控制器108可以被編程為在橫跨第一區域126掃描光束時改變與光子束112相關聯的某些參數。例如,控制器108可以在橫跨第一區域126掃描光束的同時脈衝化光子束112。在一個實施例中,控制器108可以控制雷射設備116具有在約0.2ns至約100ns範圍內的脈衝寬度。在一個具體實施例中,控制器108可以控制雷射裝置116具有在約400fs至約200ns範圍內的脈衝寬度。At block 208, photon beam 112 is scanned across first region 126 of surface 103, forming a plurality of features on the surface. The photon beam 112 may sweep across the first region 126 of the surface 103 at a traveling speed of about 0.1 m/s to about 30 m/s, such as when the photon beam 112 is pulsed from the laser device 116 . As can be seen in Figures 5-10, features formed as a result of the photon beam 112 being swept across the first region 126 of the surface 103 include depressions, protrusions, or combinations thereof. Controller 108 may be programmed to change certain parameters associated with photon beam 112 as the beam is scanned across first region 126 . For example, controller 108 may pulse photon beam 112 while scanning the beam across first region 126 . In one embodiment, the controller 108 may control the laser device 116 to have a pulse width in the range of about 0.2 ns to about 100 ns. In one specific embodiment, the controller 108 may control the laser device 116 to have a pulse width in the range of about 400 fs to about 200 ns.
以這種方式,雷射機100可用於形成第一區域的整體表面形態。In this manner, the laser 100 can be used to form the overall surface topography of the first area.
根據情況,雷射機100可用於形成第一區域126的三種不同類型的表面形態。第一表面形態是重複隨機形式,如圖5和6所示,其中重複隨機形式產生突起和凹陷的組合。應該瞭解到,複數個突起可以具有例如平坦表面和突起表面。在圖5和6中,從最低凹陷到最高突起的高度變化最大值,在約4,000nm至約4,500nm的範圍內。因為表面形態是重複的隨機形式,所以突起和凹陷不形成週期波。Depending on the situation, the laser 100 may be used to form three different types of surface morphologies of the first region 126 . The first surface morphology is a repeating random pattern, as shown in Figures 5 and 6, where the repeating random pattern creates a combination of protrusions and depressions. It will be appreciated that the plurality of protrusions may have, for example, flat surfaces and raised surfaces. In Figures 5 and 6, the maximum change in height from the lowest depression to the highest protrusion is in the range of about 4,000 nm to about 4,500 nm. Because the surface morphology is a repeating, random pattern, the bumps and depressions do not form periodic waves.
可以藉由同步脈衝頻率和掃描速率,來實現重複形式。當脈衝雷射和基板相對於彼此移動時,雷射以重複間隔發射衝擊基板表面的輻射,從而產生重複形式。可以藉由將雷射脈衝的時間分佈調整為掃描速率,來調整重複形式的確切形狀。如果使用與掃描速率相比具有非常快的功率斜坡時間的雷射脈衝,則重複形式將傾向於實質上矩形的輪廓,因為在斜升或斜降期間基板不會平移很遠。如果斜坡時間與脈衝持續時間相比非常小,則重複形式也將傾向於實質上矩形的輪廓,因為雷射脈衝的時間分佈實質上是平坦的。如果掃描速率與脈衝持續時間或斜坡時間相比較低,則重複形式也將傾向於實質上矩形的輪廓,因為由每個雷射脈衝傳遞的光子集中在基板的較小區域中。相對於脈衝持續時間增加斜坡時間及(或)掃描速率,將導致所形成的特徵的角更圓滑或更呈錐形。雷射脈衝本身也可以藉由將波形產生器耦合到雷射電源供應器來調變。藉由這種方式,可以產生具有更多錐形斜率的脈衝,甚至是正弦時間曲線。這些措施將產生傾向於波浪形狀的特徵。特徵間距由脈衝頻率與掃描速率的關係決定。因此,可以藉由調節脈衝頻率來獨立地調節特徵間距,脈衝頻率將被脈衝持續時間在高端受限。Repeating patterns can be achieved by synchronizing the pulse frequency and scan rate. As the pulsed laser and substrate move relative to each other, the laser emits radiation that strikes the substrate surface at repeating intervals, creating a repeating pattern. The exact shape of the repeating pattern can be tuned by adjusting the temporal distribution of the laser pulses to the scan rate. If a laser pulse with a very fast power ramp time compared to the scan rate is used, the repetitive pattern will tend to have a substantially rectangular profile because the substrate will not translate very far during the ramp up or down. If the ramp time is very small compared to the pulse duration, the repeating pattern will also tend to have a substantially rectangular profile, since the time distribution of the laser pulse is substantially flat. If the scan rate is low compared to the pulse duration or ramp time, the repeating pattern will also tend to have a substantially rectangular profile because the photons delivered by each laser pulse are concentrated in a smaller area of the substrate. Increasing the ramp time and/or scan rate relative to the pulse duration will result in the resulting features having rounder or more tapered corners. The laser pulse itself can also be modulated by coupling the waveform generator to the laser power supply. In this way, pulses with more tapered slopes or even sinusoidal time profiles can be generated. These measures will produce features that tend to have a wavy shape. Feature spacing is determined by the relationship between pulse frequency and scan rate. Therefore, the feature spacing can be adjusted independently by adjusting the pulse frequency, which will be limited at the high end by the pulse duration.
當雷射機100的功率輸出為30W、部件104為鋁、並且光束直徑為約7μm時,圖5和圖6中所示的重複隨機形式的Ra的範例為約60μin。應當理解,Ra值將根據雷射機100的功率輸出和與光子束112相關的各種變量而變化。使用雷射機100實現的重複隨機形式的表面形態和Ra值,可類似於使用珠粒噴砂處理所可實現的表面形態和Ra值,不同之處在於使用雷射機100將避免一些珠粒噴砂處理固有的問題。例如,如果部件104是氣體分配噴淋頭133(在圖3中示意性地示出),則將存在複數個錐形的通孔135。如上所述,珠粒噴砂處理涉及以高速對要紋理化的表面噴射複數個珠粒。因此,存在與珠粒噴砂處理相關的固有的缺乏控制和精確性。When the power output of the laser 100 is 30 W, the component 104 is aluminum, and the beam diameter is about 7 μm, the example of a repeating random pattern of Ra shown in Figures 5 and 6 is about 60 μin. It should be understood that the Ra value will vary depending on the power output of the laser 100 and various variables associated with the photon beam 112 . Repeated random patterns of surface morphology and Ra values achieved using laser machine 100 may be similar to those achievable using bead blasting, except that some bead blasting will be avoided using laser machine 100 Deal with inherent problems. For example, if component 104 was a gas distribution showerhead 133 (shown schematically in FIG. 3 ), there would be a plurality of tapered through holes 135 . As mentioned above, bead blasting involves spraying a plurality of beads at high speed onto the surface to be textured. Therefore, there is an inherent lack of control and precision associated with bead blasting.
在珠粒噴砂處理中使用的珠粒,也可以被捕獲或嵌入通孔135內。另外,珠粒可能撞擊通孔135的拐角或邊緣,不期望地改變通孔的輪廓而不是紋理化表面103。使用雷射機100以重複隨機形狀表面形態紋理化氣體分佈噴淋頭133,將不會顯著改變噴淋頭133中的通孔135的邊界輪廓,因為透過此紋理化處理可以實現更高的精度。雷射機100可以使第一區域126內的表面103紋理化,使得重複隨機形式在第一外邊界127內連續地重複。Beads used in bead blasting may also be trapped or embedded within vias 135 . Additionally, beads may strike corners or edges of vias 135 , undesirably altering the profile of the vias rather than texturing surface 103 . Using laser machine 100 to texture gas distribution sprinkler head 133 with a repeating random-shaped surface topography will not significantly change the boundary profile of through holes 135 in sprinkler head 133 because greater accuracy can be achieved through this texturing process. . The laser 100 can texture the surface 103 within the first region 126 such that a repeating random pattern repeats continuously within the first outer boundary 127 .
第二表面形態是重複波形,如圖7和8所示,其中重複波形產生突起和凹陷的組合。應該瞭解到,複數個突起可以具有例如大抵凸起表面。在圖7和8中,從最低凹陷到最高突起的高度變化最大值,在約4,000nm至約4,500nm的範圍內。因為表面形態是重複波形,所以突起和凹陷形成週期性輪廓,其中複數個突起中的每一個到達大抵凸起的尖頭部分。與重複波形相關聯的週期性輪廓沿著表面的x軸和表面的y軸,在整個表面103的第一區域126中重複。The second surface morphology is a repeating waveform, as shown in Figures 7 and 8, where the repeating waveform creates a combination of protrusions and depressions. It will be appreciated that the plurality of protrusions may have, for example, generally convex surfaces. In Figures 7 and 8, the maximum change in height from the lowest depression to the highest protrusion is in the range of about 4,000 nm to about 4,500 nm. Because the surface morphology is a repeating wave, the protrusions and depressions form a periodic profile, with each of the plurality of protrusions arriving at a generally convex tip portion. The periodic profile associated with the repeating waveform repeats throughout the first region 126 of the surface 103 along the x-axis of the surface and the y-axis of the surface.
當雷射機100的功率輸出為30W、部件104為鋁並且光束直徑約為7微米時,圖7和8中所示的重複波形的粗糙度輪廓的算術平均值(Ra)的範例為約108μin。應當理解,Ra值將根據雷射機100的功率輸出和與光子束112相關的各種變量而變化。與重複隨機形式不同,重複波形不同於使用珠粒噴砂處理通常會實現的表面形態。雷射機100可以使第一區域126內的表面103紋理化,使得重複波形在第一外邊界127內連續地重複。When the power output of the laser 100 is 30 W, the component 104 is aluminum, and the beam diameter is about 7 microns, an example of the arithmetic mean (Ra) of the roughness profile of the repeating waveform shown in Figures 7 and 8 is about 108 μin. . It should be understood that the Ra value will vary depending on the power output of the laser 100 and various variables associated with the photon beam 112 . Rather than repeating a random pattern, the repeating waveform differs from the surface morphology typically achieved using bead blasting. The laser 100 may texture the surface 103 within the first region 126 such that the repeating waveform continuously repeats within the first outer boundary 127 .
第三表面形態是重複方形,如圖9和10所示,其中重複方形產生突起和凹陷的組合。應該瞭解到,複數個突起可以具有例如大抵平坦表面。在圖9和10中,從最低凹陷到最高突起的高度變化最大值,在約4,000nm至約4,500nm的範圍內。因為表面形態是重複方形,所以突起和凹陷形成週期性輪廓,其中複數個突起中的每一個到達大抵平坦部分。與重複方形相關聯的週期性輪廓沿著表面的x軸和表面的y軸,在整個表面103的第一區域126中重複。A third surface morphology is a repeating square shape, as shown in Figures 9 and 10, where the repeating square shape creates a combination of protrusions and depressions. It will be appreciated that the plurality of protrusions may have, for example, generally flat surfaces. In Figures 9 and 10, the maximum change in height from the lowest depression to the highest protrusion is in the range of about 4,000 nm to about 4,500 nm. Because the surface morphology is a repeating square, the protrusions and depressions form a periodic profile, with each of the plurality of protrusions reaching a generally flat portion. The periodic profile associated with the repeating square repeats throughout the first region 126 of the surface 103 along the x-axis of the surface and the y-axis of the surface.
當雷射機100的功率輸出為30W、部件104為鋁並且光束直徑約為25微米時,圖9和10中所示的重複方形的粗糙度輪廓的算術平均值(Ra)的範例為約357μin。應當理解,Ra值將根據雷射機100的功率輸出和與光子束112相關的各種變量而變化。當部件104是靜電吸盤時,重複方形可能特別適用。如圖9中最佳所示,重複方形內的突起和凹陷產生複數個通道。複數個通道使得氣體能夠通過矽晶圓下方的通道,例如,矽晶圓在晶圓處理期間位於靜電吸盤的頂部。When the power output of laser 100 is 30 W, component 104 is aluminum, and the beam diameter is approximately 25 microns, the example arithmetic mean (Ra) of the repeating square roughness profile shown in Figures 9 and 10 is approximately 357 μin. . It should be understood that the Ra value will vary depending on the power output of the laser 100 and various variables associated with the photon beam 112 . Repeating squares may be particularly useful when component 104 is an electrostatic chuck. As best shown in Figure 9, repeating the protrusions and depressions within the square creates a plurality of channels. The plurality of channels allows gases to pass through channels beneath the silicon wafer, which sits on top of an electrostatic chuck during wafer processing, for example.
可以在紋理化處理之後執行隨後的拋光處理,以幫助平坦化突起的頂表面,從而有助於在晶圓處理期間使矽晶圓黏附到靜電吸盤。在拋光過程中未平坦化的部件104的部分將保持表面粗糙度,從而有助於防止在晶圓處理期間在複數個通道內冷凝的異物的分離。雷射機100可以使第一區域126內的表面103紋理化,使得重複方形在第一外邊界127內連續地重複。A subsequent polishing process can be performed after the texturing process to help planarize the top surface of the bumps, thereby aiding in adhesion of the silicon wafer to the electrostatic chuck during wafer processing. Portions of component 104 that are not planarized during polishing will maintain surface roughness, thereby helping to prevent the separation of foreign matter that condenses within the plurality of channels during wafer processing. The laser 100 can texture the surface 103 within the first area 126 such that the repeating square repeats continuously within the first outer boundary 127 .
與使用雷射機100相關的另一個好處是,正在紋理化的部件104的表面103不必在此過程的框202之前經歷精確的預清潔過程。相反的,所需要的只是粗略的預清潔過程以對部件104的表面103進行脫脂。這與電磁束系統不同,在電磁束系統中,由於電子束的高反應性本質,通常需要精確的預清潔處理。Another benefit associated with using the laser machine 100 is that the surface 103 of the part 104 being textured does not have to undergo a precise pre-cleaning process prior to block 202 of the process. Instead, all that is required is a rough pre-cleaning process to degrease the surface 103 of the component 104 . This differs from electromagnetic beam systems, where precise pre-cleaning is often required due to the highly reactive nature of the electron beam.
與使用雷射機100對部件104的表面103進行紋理化相關聯的另一個好處是,在框202之後,沒有額外的步驟來降低真空腔室內的壓力,相較於使用電磁束系統的情況。如上所述,電磁束系統在真空環境中操作,從而需要抽空環境壓力。雖然雷射機100和支撐系統102可以定位在腔室內以便產生貧氧環境,但環境壓力不必被抽空。因為消除了此抽空步驟,所以用雷射機100使部件104的表面103紋理化所需的時間小於用電子束使部件表面紋理化所需的時間。與使用電磁束系統對部件表面紋理化相比,這有助於增加相關聯於利用雷射機100對部件表面紋理化的產量。與雷射機100相關的產量,也大於與使用電磁束系統相關的產量,因為在表面上掃描電子束以形成複數個特徵的行進速度,顯著小於在表面上掃描光子束112的行進速度。例如,當使表面紋理化時,電子束的行進速度在約0.02M/s至約0.03M/s的範圍內。如上所述,當使表面紋理化時,光子束112的行進速度在約0.1M/s至約300M/s的範圍內。Another benefit associated with using the laser 100 to texture the surface 103 of the part 104 is that after block 202 there are no additional steps to reduce the pressure within the vacuum chamber as compared to using an electromagnetic beam system. As mentioned above, electromagnetic beam systems operate in a vacuum environment, requiring evacuation of ambient pressure. Although the laser 100 and support system 102 may be positioned within the chamber to create an oxygen-depleted environment, the ambient pressure need not be evacuated. Because this evacuation step is eliminated, the time required to texture the surface 103 of the part 104 with the laser 100 is less than the time required to texture the surface of the part using an electron beam. This helps increase throughput associated with texturing part surfaces using laser 100 compared to using electromagnetic beam systems to texturize part surfaces. The throughput associated with laser machine 100 is also greater than that associated with systems using electromagnetic beams because the speed of travel of the electron beam scanning the surface to form a plurality of features is significantly less than the speed of travel of the photon beam 112 scanning the surface. For example, when texturing a surface, the electron beam travels at a speed in the range of about 0.02 M/s to about 0.03 M/s. As mentioned above, when texturing a surface, the photon beam 112 travels at a speed in the range of about 0.1 M/s to about 300 M/s.
利用雷射裝置116輸出的光子束112對部件104的表面103進行紋理化的另一個好處是,它可以產生比使用例如珠粒噴砂或電子束更清潔的處理。取決於光子束112的波長,光子束所指向的表面103的材料可主要接收光學輻射或熱能以修改表面。光輻射在光子束被引導的位置處熔化部件104的表面103,從而產生熔融材料或熔渣,當再固化時,熔融材料或熔渣產生凹陷或突起。因為與熔融材料相關的動能可以最小化,所以熔融材料不太可能從剩餘表面103撞擊下並且再沉積到一些其他位置。這減少了在其他情況下可能發生的再沉積量。相反的,當使用電磁束系統時,被紋理化的部件通常嵌入與電子束相互作用的電子,產生顯著的能量,導致至少一些熔融材料從剩餘表面被撞擊下,從而增加了再沉積的可能。因此,用光子束112對表面進行紋理化,可以產生比用電子束對表面紋理化更清潔的處理。Another benefit of texturing the surface 103 of the component 104 using the photon beam 112 output from the laser device 116 is that it can produce a cleaner process than using, for example, bead blasting or electron beam. Depending on the wavelength of the photon beam 112, the material of the surface 103 towards which the photon beam is directed may receive primarily optical radiation or thermal energy to modify the surface. The optical radiation melts the surface 103 of the component 104 at the location where the photon beam is directed, thereby producing molten material or slag that, when resolidified, creates depressions or protrusions. Because the kinetic energy associated with the molten material can be minimized, the molten material is less likely to impact off the remaining surface 103 and redeposit to some other location. This reduces the amount of redeposition that might otherwise occur. In contrast, when electromagnetic beam systems are used, the textured part typically embeds electrons that interact with the electron beam, creating significant energy that causes at least some molten material to be knocked off the remaining surface, thereby increasing the potential for redeposition. Therefore, texturing a surface with a photon beam 112 can produce a cleaner process than texturing a surface with an electron beam.
應注意到,由雷射裝置116傳遞到部件104的表面103的光子束112,不會引起部件104的顯著或嚴重的變形(例如熔化、翹曲、斷裂等)。部件104的顯著或嚴重變形,通常可以定義為由於紋理化處理的應用,部件104不能用於其預期目的的狀態。It should be noted that the photon beam 112 delivered by the laser device 116 to the surface 103 of the component 104 will not cause significant or severe deformation (eg, melting, warping, breaking, etc.) of the component 104 . Significant or severe deformation of a part 104 may generally be defined as a state in which the part 104 cannot be used for its intended purpose due to the application of texturing.
圖11和12描繪了可用於使部件104的表面103紋理化的雷射機100的示意圖。特定而言,圖11和12示出了雷射機100及(或)雷射裝置116的不同的設置、零件和元件。如圖11所示,雷射機100可以具有相對於部件104的垂直取向,或者雷射裝置116可以具有相對於部件104的水平取向,如圖12所示。如上所述,部件104用在半導體處理腔室中。部件104可例如為氣體分配噴淋頭、遮罩、腔室襯墊、蓋環、夾環、基板支撐基座、及(或)靜電吸盤。因此,在用雷射機100進行紋理化之後,部件104用作半導體處理腔室的部件,其中在半導體處理腔室內處理諸如晶圓的半導體。Figures 11 and 12 depict schematic diagrams of a laser 100 that may be used to texture the surface 103 of a component 104. In particular, FIGS. 11 and 12 illustrate various arrangements, parts and components of laser 100 and/or laser device 116 . Laser 100 may have a vertical orientation relative to component 104, as shown in FIG. 11, or laser device 116 may have a horizontal orientation relative to component 104, as shown in FIG. 12. As mentioned above, component 104 is used in a semiconductor processing chamber. Component 104 may be, for example, a gas distribution showerhead, a mask, a chamber liner, a cover ring, a clamp ring, a substrate support base, and/or an electrostatic chuck. Thus, after texturing with laser 100, component 104 serves as a component of a semiconductor processing chamber in which semiconductors, such as wafers, are processed.
如上所述,雷射裝置116用於輸出光子束。圖11和12中的雷射裝置116被示出為包括光源142,諸如光子光源、光學模組144和透鏡146,每個光源可操作地彼此耦合。然而,在其他具體實施例中,儘管雷射裝置116被示出為包括光源142、光學模塊144和透鏡146,但是本揭示內容不限於此。例如,在一個或多個其他具體實施例中,圖1和2中所示的電源供應器106及(或)控制器108可以附加地或替代地包括光源142、光學模塊144及(或)透鏡146,而不背離本揭示內容的範圍。As mentioned above, laser device 116 is used to output a photon beam. Laser device 116 in Figures 11 and 12 is shown as including a light source 142, such as a photonic light source, an optical module 144, and a lens 146, each light source operably coupled to one another. However, in other embodiments, although laser device 116 is shown as including light source 142, optical module 144, and lens 146, the present disclosure is not limited thereto. For example, in one or more other embodiments, the power supply 106 and/or the controller 108 shown in FIGS. 1 and 2 may additionally or alternatively include a light source 142, an optical module 144, and/or a lens. 146 without departing from the scope of this disclosure.
在此具體實施例中,光源142用於產生光源,特定而言為光子流。可操作地耦合到光源142的光學模組144接收來自光源142的光子流,以對來自光源142的光子流進行整形、引導或以其他方式調變。光學模組144包括光束調變器和光束掃描器,光束掃描器位於光束調變器的下游(相對於光源142)。光束調變器接收來自光源142的光子流,以從光子流產生光子束。例如,藉由整形來自光源142的光子流,光束調變器可用於產生具有單個焦點的光子束。光束掃描器用於接收來自光束調變器的光子束,以掃描跨越部件104的表面103的光子束。因此,光束掃描器用於移動、偏轉和以其他方式控制光子束的方向,諸如透過使用機電致動器。In this particular embodiment, light source 142 is used to generate a light source, specifically a stream of photons. Optical module 144 operatively coupled to light source 142 receives the photon flow from light source 142 to shape, direct, or otherwise modulate the photon flow from light source 142 . The optical module 144 includes a beam modulator and a beam scanner located downstream of the beam modulator (relative to the light source 142 ). The beam modulator receives the photon stream from the light source 142 to generate a photon beam from the photon stream. For example, a beam modulator can be used to generate a photon beam with a single focus by shaping the flow of photons from light source 142. The beam scanner is used to receive the photon beam from the beam modulator to scan the photon beam across the surface 103 of the component 104 . Thus, beam scanners are used to move, deflect, and otherwise control the direction of the photon beam, such as through the use of electromechanical actuators.
透鏡146用於接收來自光學模組144的光子束,更特定而言來自光束掃描器,以將光子束分佈在部件104的表面103上。當光學模組144的光束調變器用於將光子流聚焦成光子束(諸如單個焦點光子束)時,透鏡146用於使光子束散焦並均勻地分佈在預定地區或區域。例如,透鏡146可用於將光子束分佈在約355mm 2的區域上。分佈在部件104的表面103上的光子束用於在部件104的表面103上形成一個或多個紋理化特徵,諸如部件104的表面103上的凹陷及(或)突起。 Lens 146 is used to receive the photon beam from the optical module 144 , and more specifically from the beam scanner, to distribute the photon beam over the surface 103 of the component 104 . While the beam modulator of optical module 144 is used to focus a stream of photons into a beam of photons (such as a single focal photon beam), lens 146 is used to defocus and evenly distribute the photon beam over a predetermined region or area. For example, lens 146 may be used to distribute the photon beam over an area of approximately 355 mm. The photon beam distributed over the surface 103 of the component 104 is used to form one or more textured features on the surface 103 of the component 104 , such as depressions and/or protrusions on the surface 103 of the component 104 .
雷射裝置116用於控制從雷射裝置116發射並掃過部件104的表面103的光子束的功率、速度、頻率、方向、分佈、及(或)脈衝。例如,光源142及(或)光學模組144可用於脈衝化光子束,同時光子束被掃描過部件104的表面103。此外,光學模組144的光束掃描器可用於以一個或多個預定圖案,將光子束引導或掃描過部件104的表面103。在一個具體實施例中,光束掃描器可用於使用逐行圖案、麻雀(sparrow)圖案及(或)隨機圖案來掃描光子束。麻雀圖案包括相對於部件104的表面103的中間或中心區域,以外向內圖案或內向外圖案掃描光子束,因此以徑向圖案工作,而不是逐行圖案。The laser device 116 is used to control the power, speed, frequency, direction, distribution, and/or pulse of the photon beam emitted from the laser device 116 and swept across the surface 103 of the component 104 . For example, the light source 142 and/or the optical module 144 may be used to pulse a photon beam while the photon beam is scanned across the surface 103 of the component 104 . Additionally, the beam scanner of the optical module 144 may be used to direct or scan the photon beam across the surface 103 of the component 104 in one or more predetermined patterns. In one embodiment, a beam scanner may be used to scan the photon beam using a progressive pattern, a sparrow pattern, and/or a random pattern. The sparrow pattern involves scanning the photon beam in an outside-in pattern or an inside-out pattern relative to a middle or central area of the surface 103 of the component 104, thus operating in a radial pattern rather than a row-by-row pattern.
雷射裝置116還用於從透鏡146垂直或水平地分佈和掃描光子束並朝向部件104的表面103。示出了包括支撐表面190的支座122,支座與雷射機100一起使用,其中部件104定位在透鏡146和支座122之間。支撐表面190用於將部件104支撐在支座122上,因此部件104以圖11所示的設置定位在支座122的支撐表面190上,其中光子束垂直地朝向部件104的表面103分佈。在圖12所示的佈置中,支座122的支撐表面190作為部件104後方的屏障,其中光子束水平地朝向部件104的表面103分佈。圖12中所示的水平佈置的一個優點,是可以使用重力將材料從部件104的表面103拉出,例如當材料熔化時。與材料能夠在表面上再沉積或形成時相比,這可以產生更清潔的過程。The laser device 116 is also used to distribute and scan the photon beam vertically or horizontally from the lens 146 and towards the surface 103 of the component 104 . Mount 122 is shown including support surface 190 for use with laser 100 with component 104 positioned between lens 146 and mount 122 . The support surface 190 is used to support the component 104 on the support 122 such that the component 104 is positioned on the support surface 190 of the support 122 in the arrangement shown in Figure 11, with the photon beam distributed vertically towards the surface 103 of the component 104. In the arrangement shown in Figure 12, the support surface 190 of the standoff 122 acts as a barrier behind the component 104, with the photon beam distributed horizontally towards the surface 103 of the component 104. One advantage of the horizontal arrangement shown in Figure 12 is that gravity can be used to pull material away from surface 103 of component 104, such as when the material melts. This results in a cleaner process than when the material is able to be redeposited or formed on the surface.
仍參照圖11和12,包括清潔外殼150或清潔隔室以與雷射機100一起使用。清潔外殼150通常包括處理區域151,支座122設置在處理區域151中。例如,在紋理化處理期間,部件104定位在清潔外殼150內,其中清潔外殼150的處理區域151包括過濾系統,此過濾系統能夠將處理區域保持為根據ISO 14644-1的分類參數的1級環境。此外,支座122和雷射裝置116的至少一部分(諸如透鏡146)定位在清潔外殼150內。由於雷射機100在非加壓(例如大氣)環境中使用,清潔外殼150內的壓力通常可以等於或接近大氣壓,或者壓力可以是不受控制的。可以替代地及(或)另外地用惰性氣體(例如,N 2)吹掃清潔外殼150,以去除氧氣、水及(或)其他處理污染物。另外,輸送器可用於將部件104引入清潔外殼150中並且引入支座122上,及(或)輸送器可用於將部件104從支座122移除並移出清潔外殼150。例如,在這樣的具體實施例中,支座122可包括輸送器。或者,可以使用單獨的機器人臂或類似機構,來便於從輸送器移除部件104及(或)將部件104放置在輸送器上。 Still referring to FIGS. 11 and 12 , a cleaning housing 150 or cleaning compartment is included for use with the laser 100 . Cleaning housing 150 generally includes a processing area 151 in which stand 122 is disposed. For example, during the texturing process, the component 104 is positioned within the cleaning housing 150, wherein the processing area 151 of the cleaning housing 150 includes a filtration system capable of maintaining the processing area as a Level 1 environment according to the classification parameters of ISO 14644-1 . Additionally, the support 122 and at least a portion of the laser device 116 , such as the lens 146 , are positioned within the cleaning housing 150 . Since the laser machine 100 is used in a non-pressurized (eg, atmospheric) environment, the pressure within the cleaning housing 150 may generally be equal to or close to atmospheric pressure, or the pressure may be uncontrolled. Housing 150 may alternatively and/or additionally be purged with an inert gas (eg, N 2 ) to remove oxygen, water, and/or other process contaminants. Additionally, a conveyor may be used to introduce the component 104 into the cleaning housing 150 and onto the holder 122 , and/or the conveyor may be used to remove the component 104 from the holder 122 and out of the cleaning housing 150 . For example, in such embodiments, the support 122 may include a conveyor. Alternatively, a separate robotic arm or similar mechanism may be used to facilitate removal of the part 104 from the conveyor and/or placement of the part 104 on the conveyor.
圖13示出了比較使用珠粒噴砂處理302所紋理化的部件、根據本文所述具體實施例使用雷射處理304所紋理化的部件、以及使用在半導體處理腔室中的部件通常所需的規格306的平均元素性結果的視圖。x軸提供在每個部件中測試的不同元素(例如痕量金屬),並且y軸以原子/cm 2為單位提供在部件表面上發現的元素的量。如圖所示,使用雷射處理304紋理化的部件,通常具有比規格306所需的元素或痕量金屬更少的元素或痕量金屬,並且通常還具有比使用珠粒噴砂處理302紋理化的元素或痕量金屬更少的元素或痕量金屬。例如,由於在珠粒噴砂處理302中使用的珠粒通常包括鈉(Na),因此與珠粒噴砂處理302相比,使用雷射處理304紋理化的部件的鈉的量顯著減少。使用雷射處理304紋理化的部件,通常可以導致具有更高量的鎂(Mg),但是隨後可以使用稀酸和高純度水(例如熱去離子水)清潔這些部件以去除過量的鎂。因此,與使用珠粒噴砂處理302紋理化的部件相比(可以預期其為約50%),使用雷射處理304紋理化的部件在隨後的半導體處理期間產生更高的良率(例如約95%)。 13 illustrates a comparison of what is typically required for parts textured using bead blasting 302 , parts textured using laser processing 304 in accordance with specific embodiments described herein, and parts used in semiconductor processing chambers. View of the average elementality results for Spec 306. The x-axis provides the different elements (such as trace metals) tested in each part, and the y-axis provides the amount of the element found on the surface of the part in atoms/ cm . As shown, parts textured using Laser Process 304 will typically have less elemental or trace metal than required by specification 306, and will also typically have less elemental or trace metal than required using Bead Blasting 302 Texture of elements or trace metals fewer elements or trace metals. For example, because the beads used in bead blasting 302 typically include sodium (Na), the amount of sodium in a part textured using laser treatment 304 is significantly reduced compared to bead blasting 302 . Parts textured using laser processing 304 can often result in having higher amounts of magnesium (Mg), but these parts can then be cleaned using dilute acids and high-purity water (such as hot deionized water) to remove excess magnesium. Accordingly, components textured using laser processing 304 yield higher yields during subsequent semiconductor processing (e.g., approximately 95 %).
雖然前述內容係關於特定實施例,但可發想其他與進一步的實施例而不脫離前述內容的基板範圍,且前述內容的範圍係由下列申請專利範圍判定。While the foregoing relates to specific embodiments, other and further embodiments may be contemplated without departing from the scope of the foregoing, and the scope of the foregoing is determined by the scope of the following claims.
100:雷射機 102:支撐系統 103:表面 104:部件 106:電源供應器 108:控制器 112:光子 116:雷射裝置 122:支座 126:第一區域 127:第一外邊界 132:第二外邊界 133:氣體分配噴淋頭 135:通孔 142:光源 144:光學模塊 146:透鏡 150:清潔外殼 151:處理區域 190:支撐表面 200:處理序列 202-208:框 302:珠粒噴砂處理 304:雷射處理 306:規格 100:Laser machine 102:Support system 103:Surface 104:Components 106:Power supply 108:Controller 112:Photon 116:Laser device 122:Bearing 126:First area 127: First outer boundary 132: Second outer boundary 133:Gas distribution sprinkler head 135:Through hole 142:Light source 144:Optical module 146:Lens 150: Clean the shell 151: Processing area 190:Support surface 200: Processing sequence 202-208:Box 302:Bead blasting 304:Laser treatment 306:Specifications
可參考多個實施例以更特定地說明以上簡要總結的本公開內容,以更詳細瞭解本揭示內容的上述特徵,附加圖式圖示說明了其中一些具體實施例。然而應注意到,附加圖式僅說明一些示例性實施例,且因此不應被視為限制範圍。The above-described features of the disclosure may be understood in more detail by reference to a number of embodiments, some of which are illustrated in the accompanying drawings, to which the disclosure briefly summarized above may be described more particularly. It should be noted, however, that the appended drawings illustrate only some exemplary embodiments and therefore should not be considered limiting of scope.
圖1示出了根據本揭示內容的雷射機和支撐系統的示意圖。Figure 1 shows a schematic diagram of a laser machine and support system in accordance with the present disclosure.
圖2示出了根據本揭示內容的雷射機和支撐系統的替代示意圖。Figure 2 shows an alternative schematic diagram of a laser and support system in accordance with the present disclosure.
圖3示出了根據本揭示內容的氣體分配噴淋頭的俯視圖,其中待紋理化的區域由邊界線標記。Figure 3 shows a top view of a gas distribution showerhead in accordance with the present disclosure, with areas to be textured marked by boundary lines.
圖4示出了根據本揭示內容的操作雷射機和支撐系統的方法的處理序列。Figure 4 illustrates a process sequence for a method of operating a laser and support system in accordance with the present disclosure.
圖5和6示出了重複隨機形式的表面形態,表面形態由根據本揭示內容的雷射機產生。圖5示出了顯示表面形態的透視圖,圖6示出了顯示表面形態的俯視圖。Figures 5 and 6 illustrate repeating random patterns of surface morphology produced by a laser machine in accordance with the present disclosure. FIG. 5 shows a perspective view showing the surface morphology, and FIG. 6 shows a top view showing the surface morphology.
圖7和8示出了重複波形的表面形態,表面形態由根據本揭示內容的雷射機產生。圖7示出了顯示表面形態的透視圖,圖8示出了顯示表面形態的俯視圖與側視圖。Figures 7 and 8 illustrate the surface morphology of a repeating waveform produced by a laser in accordance with the present disclosure. FIG. 7 shows a perspective view showing the surface morphology, and FIG. 8 shows a top view and a side view showing the surface morphology.
圖9和10示出了重複方形的表面形態,表面形態由根據本揭示內容的雷射機產生。圖9示出了顯示表面形態的透視圖,圖10示出了顯示表面形態的俯視圖與側視圖。Figures 9 and 10 illustrate repeating square surface morphologies produced by a laser in accordance with the present disclosure. FIG. 9 shows a perspective view showing the surface morphology, and FIG. 10 shows a top view and a side view showing the surface morphology.
圖11示出了根據本揭示內容的雷射機和雷射裝置的示意圖。Figure 11 shows a schematic diagram of a laser machine and laser device according to the present disclosure.
圖12示出了根據本揭示內容的雷射機和雷射裝置的替代性示意圖。Figure 12 shows an alternative schematic diagram of a laser machine and laser device in accordance with the present disclosure.
圖13顯示比較使用珠粒噴砂處理和根據本揭示內容的方法紋理化的部件的結果的圖形。Figure 13 shows a graph comparing the results of parts textured using bead blasting and methods in accordance with the present disclosure.
為了協助瞭解,已儘可能使用相同的元件符號標定圖式中共有的相同元件。已思及到,一個實施例的元件與特徵,可無需進一步的敘述即可被有益地併入其他實施例中。To aid understanding, the same component symbols have been used wherever possible to refer to the same components common in the drawings. It is contemplated that elements and features of one embodiment may be beneficially incorporated into other embodiments without further recitation.
此專利或申請文件包含至少一幅彩色附圖。具有彩色附圖的本專利或專利申請公開的副本將在請求和支付必要費用後由主管局提供。This patent or application file contains at least one drawing executed in color. Copies of this patent or patent application publication with color drawing(s) will be provided by the Office upon request and payment of the necessary fee.
國內寄存資訊 (請依寄存機構、日期、號碼順序註記) 無 Domestic storage information (please note in order of storage institution, date and number) without
國外寄存資訊 (請依寄存國家、機構、日期、號碼順序註記) 無 Overseas storage information (please note in order of storage country, institution, date, and number) without
100:雷射機 100:Laser machine
103:表面 103:Surface
104:部件 104:Components
116:雷射裝置 116:Laser device
122:支座 122:Bearing
142:光源 142:Light source
144:光學模塊 144:Optical module
146:透鏡 146:Lens
150:清潔外殼 150: Clean the shell
151:處理區域 151: Processing area
190:支撐表面 190:Support surface
Claims (9)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/955,503 | 2018-04-17 | ||
| US15/955,503 US10434604B2 (en) | 2016-10-14 | 2018-04-17 | Texturizing a surface without bead blasting |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW202247256A TW202247256A (en) | 2022-12-01 |
| TWI818684B true TWI818684B (en) | 2023-10-11 |
Family
ID=68239815
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW108113049A TWI741280B (en) | 2018-04-17 | 2019-04-15 | System to provide texture to surface of component for use in semiconductor processing chamber and method thereof |
| TW109139102A TWI797497B (en) | 2018-04-17 | 2019-04-15 | System to provide texture to surface of component for use in semiconductor processing chamber and method thereof |
| TW111131114A TWI818684B (en) | 2018-04-17 | 2019-04-15 | System to provide texture to surface of component for use in semiconductor processing chamber and method thereof |
| TW112124229A TWI841432B (en) | 2018-04-17 | 2019-04-15 | System to provide texture to surface of component for use in semiconductor processing chamber and method thereof |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW108113049A TWI741280B (en) | 2018-04-17 | 2019-04-15 | System to provide texture to surface of component for use in semiconductor processing chamber and method thereof |
| TW109139102A TWI797497B (en) | 2018-04-17 | 2019-04-15 | System to provide texture to surface of component for use in semiconductor processing chamber and method thereof |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW112124229A TWI841432B (en) | 2018-04-17 | 2019-04-15 | System to provide texture to surface of component for use in semiconductor processing chamber and method thereof |
Country Status (5)
| Country | Link |
|---|---|
| JP (4) | JP7239607B2 (en) |
| KR (3) | KR20250007702A (en) |
| CN (1) | CN111801624A (en) |
| TW (4) | TWI741280B (en) |
| WO (1) | WO2019203978A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102616691B1 (en) | 2019-02-12 | 2023-12-20 | 어플라이드 머티어리얼스, 인코포레이티드 | Method for manufacturing chamber components |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030188685A1 (en) * | 2002-04-08 | 2003-10-09 | Applied Materials, Inc. | Laser drilled surfaces for substrate processing chambers |
| US20100059366A1 (en) * | 2004-06-07 | 2010-03-11 | Applied Materials, Inc. | Textured chamber surface |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001509214A (en) * | 1997-01-16 | 2001-07-10 | ボトムフィールド,ロジャー,エル. | Vapor deposition components and corresponding methods |
| US7070106B2 (en) * | 1998-03-24 | 2006-07-04 | Metrologic Instruments, Inc. | Internet-based remote monitoring, configuration and service (RMCS) system capable of monitoring, configuring and servicing a planar laser illumination and imaging (PLIIM) based network |
| US6899798B2 (en) * | 2001-12-21 | 2005-05-31 | Applied Materials, Inc. | Reusable ceramic-comprising component which includes a scrificial surface layer |
| US6933508B2 (en) * | 2002-03-13 | 2005-08-23 | Applied Materials, Inc. | Method of surface texturizing |
| TWI342582B (en) * | 2003-07-17 | 2011-05-21 | Applied Materials Inc | Method of surface texturizing |
| JP3116197U (en) * | 2004-06-28 | 2005-12-02 | アプライド マテリアルズ インコーポレイテッド | Substrate processing chamber component having a surface for depositing process residues |
| US7762114B2 (en) * | 2005-09-09 | 2010-07-27 | Applied Materials, Inc. | Flow-formed chamber component having a textured surface |
| US7432513B2 (en) * | 2005-10-21 | 2008-10-07 | Asml Netherlands B.V. | Gas shower, lithographic apparatus and use of a gas shower |
| WO2008127807A1 (en) * | 2007-03-09 | 2008-10-23 | University Of Virginia Patent Foundation | Systems and methods of laser texturing of material surfaces and their applications |
| US20150136226A1 (en) * | 2006-09-29 | 2015-05-21 | University Of Rochester | Super-hydrophobic surfaces and methods for producing super-hydrophobic surfaces |
| US20080299408A1 (en) * | 2006-09-29 | 2008-12-04 | University Of Rochester | Femtosecond Laser Pulse Surface Structuring Methods and Materials Resulting Therefrom |
| US20080131622A1 (en) * | 2006-12-01 | 2008-06-05 | White John M | Plasma reactor substrate mounting surface texturing |
| WO2008091898A1 (en) * | 2007-01-23 | 2008-07-31 | Imra America, Inc. | Ultrashort laser micro-texture printing |
| US20150140297A1 (en) * | 2013-11-19 | 2015-05-21 | Steven E. Johnson | Surface preparation using optical energy |
| JP6544902B2 (en) * | 2014-09-18 | 2019-07-17 | 東京エレクトロン株式会社 | Plasma processing system |
| KR102467442B1 (en) * | 2015-02-06 | 2022-11-14 | 어플라이드 머티어리얼스, 인코포레이티드 | 3D printed chamber components configured for lower film stress and lower operating temperature |
| US10590559B2 (en) * | 2015-03-13 | 2020-03-17 | Apple Inc. | Anodizing and pre-anodizing processes based on incoming laser textured part |
| JP6385915B2 (en) * | 2015-12-22 | 2018-09-05 | 東京エレクトロン株式会社 | Etching method |
| JP2018041217A (en) * | 2016-09-06 | 2018-03-15 | 東京エレクトロン株式会社 | Abnormality detection method and semiconductor manufacturing apparatus |
-
2019
- 2019-03-20 KR KR1020247043379A patent/KR20250007702A/en active Pending
- 2019-03-20 CN CN201980016675.6A patent/CN111801624A/en active Pending
- 2019-03-20 WO PCT/US2019/023109 patent/WO2019203978A1/en not_active Ceased
- 2019-03-20 KR KR1020237010018A patent/KR102750251B1/en active Active
- 2019-03-20 KR KR1020207032887A patent/KR102515494B1/en active Active
- 2019-03-20 JP JP2020555829A patent/JP7239607B2/en active Active
- 2019-04-15 TW TW108113049A patent/TWI741280B/en active
- 2019-04-15 TW TW109139102A patent/TWI797497B/en active
- 2019-04-15 TW TW111131114A patent/TWI818684B/en active
- 2019-04-15 TW TW112124229A patent/TWI841432B/en active
-
2022
- 2022-09-27 JP JP2022154120A patent/JP7474818B2/en active Active
-
2023
- 2023-03-02 JP JP2023031545A patent/JP7612734B2/en active Active
-
2024
- 2024-11-05 JP JP2024193450A patent/JP2025032082A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030188685A1 (en) * | 2002-04-08 | 2003-10-09 | Applied Materials, Inc. | Laser drilled surfaces for substrate processing chambers |
| US20100059366A1 (en) * | 2004-06-07 | 2010-03-11 | Applied Materials, Inc. | Textured chamber surface |
| US8142989B2 (en) * | 2004-06-07 | 2012-03-27 | Quantum Global Technologies LLC | Textured chamber surface |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2025032082A (en) | 2025-03-11 |
| KR102750251B1 (en) | 2025-01-06 |
| TW202247256A (en) | 2022-12-01 |
| KR20200133276A (en) | 2020-11-26 |
| TW202343540A (en) | 2023-11-01 |
| JP7474818B2 (en) | 2024-04-25 |
| TWI741280B (en) | 2021-10-01 |
| KR20230046324A (en) | 2023-04-05 |
| TWI841432B (en) | 2024-05-01 |
| WO2019203978A1 (en) | 2019-10-24 |
| KR20250007702A (en) | 2025-01-14 |
| JP7612734B2 (en) | 2025-01-14 |
| JP2023002551A (en) | 2023-01-10 |
| TW201945108A (en) | 2019-12-01 |
| CN111801624A (en) | 2020-10-20 |
| JP7239607B2 (en) | 2023-03-14 |
| KR102515494B1 (en) | 2023-03-29 |
| JP2021521479A (en) | 2021-08-26 |
| TWI797497B (en) | 2023-04-01 |
| TW202127513A (en) | 2021-07-16 |
| JP2023088915A (en) | 2023-06-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5703262B2 (en) | Articles for use in a semiconductor process chamber | |
| KR102139391B1 (en) | Contamination removal apparatus and method | |
| EP0599276A2 (en) | Method of removing particles from the surface of a substrate | |
| US12318868B2 (en) | Texturizing a surface without bead blasting | |
| JP2025032082A (en) | Surface texturing without bead blasting | |
| US20180104767A1 (en) | Texturizing a surface without bead blast | |
| US6265138B1 (en) | Process and apparatus for oblique beam revolution, for the effective laser stripping of sidewalls | |
| TWI566284B (en) | Lavacoat pre-clean and pre-heat | |
| EP0574859B1 (en) | Method of removing particles in a plasma processing chamber | |
| US11474440B2 (en) | Method of and apparatus for in-situ repair of reflective optic |