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TWI713155B - Memory device - Google Patents

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Publication number
TWI713155B
TWI713155B TW108138306A TW108138306A TWI713155B TW I713155 B TWI713155 B TW I713155B TW 108138306 A TW108138306 A TW 108138306A TW 108138306 A TW108138306 A TW 108138306A TW I713155 B TWI713155 B TW I713155B
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memory
channel
sidewall
drain
source
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TW108138306A
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TW202117935A (en
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江昱維
邱家榮
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旺宏電子股份有限公司
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Abstract

A memory device includes a channel element, a memory element, and an electrode element. The channel element has an open ring shape. A memory cell is defined in the memory element between the channel element and the electrode element.

Description

記憶體裝置 Memory device

本發明是有關於一種記憶體裝置。 The present invention relates to a memory device.

隨著積體電路中元件的關鍵尺寸逐漸縮小至製程技術所能感知的極限,設計者已經開始尋找可達到更大記憶體密度的技術,藉以達到較低的位元成本(costs per bit)。 As the critical size of components in integrated circuits gradually shrinks to the perceptible limit of the process technology, designers have begun to look for technologies that can achieve greater memory density, thereby achieving lower costs per bit.

本發明係有關於一種記憶體裝置。 The invention relates to a memory device.

根據本發明之一方面,提出一種記憶體裝置。記憶體裝置包括通道元件、記憶元件、電極元件。通道元件具有開環形狀。記憶胞定義在通道元件與電極元件之間的記憶元件中。 According to one aspect of the present invention, a memory device is provided. The memory device includes channel elements, memory elements, and electrode elements. The channel element has an open loop shape. The memory cell is defined in the memory element between the channel element and the electrode element.

根據本發明之另一方面,提出一種記憶體裝置。記憶體裝置包括通道元件、記憶元件、電極元件。記憶元件具有開環形狀。記憶胞定義在通道元件與電極元件之間的記憶元件中。 According to another aspect of the present invention, a memory device is provided. The memory device includes channel elements, memory elements, and electrode elements. The memory element has an open loop shape. The memory cell is defined in the memory element between the channel element and the electrode element.

根據本發明之又另一方面,提出一種記憶體裝置。記憶體裝置包括記憶元件、源極側元件、汲極側元件、通道元件、絕緣元件與電極元件。通道元件電性連接在源極側元件與汲極側元件之間。通道元件與源極側元件及汲極側元件是分別在絕緣元 件的相反側。記憶胞定義在通道元件與電極元件之間的記憶元件中。 According to yet another aspect of the present invention, a memory device is provided. The memory device includes a memory element, a source-side element, a drain-side element, a channel element, an insulating element, and an electrode element. The channel element is electrically connected between the source-side element and the drain-side element. The channel element, the source-side element and the drain-side element are respectively in the insulating element The opposite side of the piece. The memory cell is defined in the memory element between the channel element and the electrode element.

為了對本發明之上述及其他方面有更佳的瞭解,下文特舉實施例,並配合所附圖式詳細說明如下: In order to have a better understanding of the above and other aspects of the present invention, the following specific examples are given in conjunction with the accompanying drawings to describe in detail as follows:

100:記憶元件 100: memory element

110:凹曲側壁記憶表面 110: Concave side wall memory surface

120:凸曲側壁記憶表面 120: Convex side wall memory surface

130:側壁記憶平面 130: Sidewall memory plane

200:通道元件 200: channel element

210:凹曲側壁通道表面 210: Concave curved side wall channel surface

217:側壁通道表面 217: sidewall channel surface

220:凸曲側壁通道表面 220: Convex side wall channel surface

242:源極側元件 242: Source-side components

244:汲極側元件 244: Drain side component

245:凸曲側壁表面 245: Convex side wall surface

300:電極元件 300: Electrode element

310:側壁電極表面 310: sidewall electrode surface

400:絕緣元件 400: insulating element

410:平面狀側壁絕緣表面 410: Flat sidewall insulation surface

420:凸曲狀側壁絕緣表面 420: convex curved sidewall insulation surface

500:絕緣層 500: insulating layer

650:基底 650: Base

651:堆疊結構 651: Stacked Structure

652:材料膜 652: material film

654、674:絕緣膜 654, 674: insulating film

656:孔洞 656: hole

657:側壁表面 657: sidewall surface

658:絕緣材料膜 658: Insulating material film

660:絕緣材料層 660: insulating material layer

662、671:溝槽 662, 671: groove

664:凹口 664: Notch

666:金屬矽化物層 666: metal silicide layer

673:狹縫 673: Slit

676:材料元件 676: Material Components

678:第一導電通孔 678: first conductive via

680:第二導電通孔 680: second conductive via

D1:第一方向 D1: First direction

D2:第二方向 D2: second direction

D3:第三方向 D3: Third party

K1、K2:尺寸 K1, K2: size

M1:第一金屬層 M1: The first metal layer

M2:第二金屬層 M2: second metal layer

P-P、Q-Q:剖面線 P-P, Q-Q: Section line

第1圖為一實施例之記憶體裝置的剖面圖。 Figure 1 is a cross-sectional view of a memory device according to an embodiment.

第2圖為另一實施例之記憶體裝置的剖面圖。 Figure 2 is a cross-sectional view of a memory device of another embodiment.

第3A圖至第14圖繪示根據實施例之記憶體裝置的製造方法。 3A to 14 illustrate a method of manufacturing a memory device according to an embodiment.

第15圖為根據實施例之記憶體裝置的剖面圖。 Figure 15 is a cross-sectional view of a memory device according to an embodiment.

第16圖為根據實施例之記憶體裝置的剖面圖。 Figure 16 is a cross-sectional view of a memory device according to an embodiment.

第17圖為根據實施例之記憶體裝置的剖面圖。 Fig. 17 is a cross-sectional view of a memory device according to an embodiment.

以下係以一些實施例做說明。須注意的是,本揭露並非顯示出所有可能的實施例,未於本揭露提出的其他實施態樣也可能可以應用。再者,圖式上的尺寸比例並非按照實際產品等比例繪製。因此,說明書和圖示內容僅作敘述實施例之用,而非作為限縮本揭露保護範圍之用。另外,實施例中之敘述,例如細部結構、製程步驟和材料應用等等,僅為舉例說明之用,並非對本揭露欲保護之範圍做限縮。實施例之步驟和結構各自細節可在不脫離本揭露之精神和範圍內根據實際應用製程之需要而加以 變化與修飾。以下是以相同/類似的符號表示相同/類似的元件做說明。 Some examples are described below. It should be noted that this disclosure does not show all possible embodiments, and other implementation aspects not mentioned in this disclosure may also be applicable. Furthermore, the size ratios in the drawings are not drawn in proportion to the actual products. Therefore, the contents of the description and illustrations are only used to describe the embodiments, rather than to limit the protection scope of this disclosure. In addition, the descriptions in the embodiments, such as detailed structure, process steps, material applications, etc., are for illustrative purposes only, and are not intended to limit the scope of the disclosure. The respective details of the steps and structures of the embodiments can be added according to the needs of the actual application process without departing from the spirit and scope of this disclosure Change and modification. In the following description, the same/similar symbols represent the same/similar elements.

請參照第1圖,其繪示一實施例之記憶體裝置的剖面圖。記憶體裝置包括記憶元件100、通道元件200與電極元件300。 Please refer to FIG. 1, which shows a cross-sectional view of a memory device according to an embodiment. The memory device includes a memory element 100, a channel element 200, and an electrode element 300.

記憶元件100具有開環形狀。記憶元件100包括凹曲側壁記憶表面110、凸曲側壁記憶表面120、與側壁記憶平面130。側壁記憶平面130在凹曲側壁記憶表面110與凸曲側壁記憶表面120之間。 The memory element 100 has an open loop shape. The memory element 100 includes a concave curved sidewall memory surface 110, a convex curved sidewall memory surface 120, and a sidewall memory plane 130. The sidewall memory plane 130 is between the concave curved sidewall memory surface 110 and the convex curved sidewall memory surface 120.

通道元件200具有開環形狀。通道元件200具有相對的凹曲側壁通道表面210及凸曲側壁通道表面220。通道元件200電性連接在源極側元件242與汲極側元件244之間。通道元件200可包括源極側元件242與汲極側元件244。源極側元件242與汲極側元件244具有凸曲側壁表面245,相對於通道元件200的凸曲側壁通道表面220。通道元件200可位於源極側元件242、汲極側元件244與記憶元件100之間。一實施例中,通道元件200在記憶元件100的凹曲側壁記憶表面110上,且源極側元件242與汲極側元件244分別從通道元件200的相對末端延伸超過記憶元件100的側壁記憶平面130。 The channel element 200 has an open loop shape. The channel element 200 has a concave curved sidewall channel surface 210 and a convex curved sidewall channel surface 220 opposite to each other. The channel element 200 is electrically connected between the source-side element 242 and the drain-side element 244. The channel element 200 may include a source-side element 242 and a drain-side element 244. The source-side element 242 and the drain-side element 244 have a convex curved sidewall surface 245 opposite to the convex curved sidewall channel surface 220 of the channel element 200. The channel element 200 may be located between the source-side element 242, the drain-side element 244 and the memory element 100. In one embodiment, the channel element 200 is on the concave curved sidewall memory surface 110 of the memory element 100, and the source side element 242 and the drain side element 244 respectively extend from opposite ends of the channel element 200 beyond the sidewall memory plane of the memory element 100 130.

實施例中,通道元件200的尺寸K1是小於源極側元件242與汲極側元件244的尺寸K2。通道元件200的尺寸K1可為定義在凹曲側壁通道表面210及凸曲側壁通道表面220之間 的尺寸例如厚度。源極側元件242與汲極側元件244的尺寸K2可為凸曲側壁表面245的最大間距。 In the embodiment, the size K1 of the channel element 200 is smaller than the size K2 of the source-side element 242 and the drain-side element 244. The dimension K1 of the channel element 200 can be defined between the concave curved sidewall channel surface 210 and the convex curved sidewall channel surface 220 The dimensions such as thickness. The dimension K2 of the source-side element 242 and the drain-side element 244 may be the maximum distance between the convex curved sidewall surface 245.

通道元件200、源極側元件242與汲極側元件244可包括半導體材質,例如多晶矽、單晶矽等等。源極側元件242與汲極側元件244的摻雜質濃度可不同於通道元件200的摻雜質濃度。源極側元件242與汲極側元件244的導電性可大於通道元件200的導電性。源極側元件242與汲極側元件244的摻雜質濃度可大於通道元件200的摻雜質濃度。舉例來說,源極側元件242與汲極側元件244可包括N型重摻雜半導體材質(例如單晶矽或多晶矽等),通道元件200可包括未摻雜或N型輕摻雜的半導體材質(例如單晶矽或多晶矽等)。但本揭露不限於此。 The channel element 200, the source-side element 242, and the drain-side element 244 may include semiconductor materials, such as polysilicon, single crystal silicon, and so on. The dopant concentration of the source-side element 242 and the drain-side element 244 may be different from the dopant concentration of the channel element 200. The conductivity of the source-side element 242 and the drain-side element 244 may be greater than the conductivity of the channel element 200. The dopant concentration of the source-side element 242 and the drain-side element 244 may be greater than the dopant concentration of the channel element 200. For example, the source-side element 242 and the drain-side element 244 may include N-type heavily doped semiconductor materials (such as monocrystalline silicon or polysilicon, etc.), and the channel element 200 may include undoped or N-type lightly doped semiconductors. Material (such as monocrystalline silicon or polycrystalline silicon, etc.). But this disclosure is not limited to this.

電極元件300具有側壁電極表面310。電極元件300的側壁電極表面310與記憶元件100的側壁記憶平面130可為共平面。電極元件300在記憶元件100的凸曲側壁記憶表面120上。 The electrode element 300 has a sidewall electrode surface 310. The sidewall electrode surface 310 of the electrode element 300 and the sidewall memory plane 130 of the memory element 100 may be coplanar. The electrode element 300 is on the memory surface 120 of the convex curved sidewall of the memory element 100.

通道元件200與源極側元件242及汲極側元件244是分別在絕緣元件400的相反側。絕緣元件400具有相鄰的平面狀側壁絕緣表面410與凸曲狀側壁絕緣表面420。凸曲狀側壁絕緣表面420可相對於平面狀側壁絕緣表面410。通道元件200可鄰接凸曲狀側壁絕緣表面420。源極側元件242與汲極側元件244從通道元件200延伸超出平面狀側壁絕緣表面410。源極側元件242與汲極側元件244可在平面狀側壁絕緣表面410上。 The channel element 200 and the source-side element 242 and the drain-side element 244 are respectively on opposite sides of the insulating element 400. The insulating element 400 has an adjacent planar side wall insulating surface 410 and a convex curved side wall insulating surface 420. The convex curved sidewall insulation surface 420 may be opposite to the planar sidewall insulation surface 410. The channel element 200 may abut the convex curved sidewall insulating surface 420. The source side element 242 and the drain side element 244 extend from the channel element 200 beyond the planar sidewall insulation surface 410. The source side element 242 and the drain side element 244 may be on the planar sidewall insulating surface 410.

絕緣層500鄰近源極側元件242與汲極側元件244。 絕緣元件400在絕緣層500與通道元件200之間。具體而言,絕緣層500可位在電極元件300的側壁電極表面310、記憶元件100的側壁記憶平面130、源極側元件242與汲極側元件244的凸曲側壁表面245與絕緣元件400的平面狀側壁絕緣表面410上。 The insulating layer 500 is adjacent to the source-side element 242 and the drain-side element 244. The insulating element 400 is between the insulating layer 500 and the channel element 200. Specifically, the insulating layer 500 may be located on the sidewall electrode surface 310 of the electrode element 300, the sidewall memory plane 130 of the memory element 100, the convex curved sidewall surface 245 of the source side element 242 and the drain side element 244, and the insulating element 400 On the insulating surface 410 of the planar sidewall.

此實施例中,絕緣元件400的平面狀側壁絕緣表面410並未對齊記憶元件100的側壁記憶平面130,也未對齊電極元件300的側壁電極表面310。 In this embodiment, the planar sidewall insulating surface 410 of the insulating element 400 is not aligned with the sidewall memory plane 130 of the memory element 100, nor is it aligned with the sidewall electrode surface 310 of the electrode element 300.

實施例中,金屬矽化物層(未顯示)可配置在源極側元件242與汲極側元件244相對於通道元件200的側壁表面上。具體而言,金屬矽化物層可配置在源極側元件242與汲極側元件244之未與絕緣元件400與通道元件200接觸的凸曲側壁表面245上。 In an embodiment, a metal silicide layer (not shown) may be disposed on the sidewall surfaces of the source side element 242 and the drain side element 244 opposite to the channel element 200. Specifically, the metal silicide layer may be disposed on the convex curved sidewall surface 245 of the source side element 242 and the drain side element 244 that is not in contact with the insulating element 400 and the channel element 200.

一實施例中,源極側元件242與汲極側元件244分別作用為源極電極與汲極電極。電極元件300作用為閘電極,例如作用為字元線。記憶胞定義在通道元件200與電極元件300之間的記憶元件100中。 In one embodiment, the source-side element 242 and the drain-side element 244 function as a source electrode and a drain electrode, respectively. The electrode element 300 functions as a gate electrode, for example, functions as a word line. The memory cell is defined in the memory element 100 between the channel element 200 and the electrode element 300.

根據如第1圖所示的通道元件200(可包括源極側元件242與汲極側元件244)與記憶元件100的配置輪廓,能使記憶體構件具有較小的單元尺寸,提升記憶體裝置的記憶胞陣列密度。源極側元件242與汲極側元件244具有比通道元件200更大的尺寸,因此能增進上方導電元件(例如第14圖所示的第一導電通孔678)的製程對準並具有良好電性連接關係,製程操作窗(process window)大,並提高產品良率。 According to the configuration profile of the channel element 200 (which may include the source-side element 242 and the drain-side element 244) and the memory element 100 as shown in FIG. 1, the memory element can have a smaller cell size, and the memory device can be improved The density of the memory cell array. The source-side element 242 and the drain-side element 244 have a larger size than the channel element 200, so the process alignment of the upper conductive element (such as the first conductive via 678 shown in FIG. 14) can be improved and have good electrical properties. Sexual connection, the process operation window (process window) is large and improves product yield.

一實施例中,第1圖可為記憶體裝置在第一方向D1與第二方向D2構成平面上的剖面圖。第一方向D1不同於第二方向D2。一實施例中,第一方向D1實質上垂直第二方向D2。舉例來說,第一方向D1為X方向,且第二方向D2為Y方向。 In an embodiment, FIG. 1 may be a cross-sectional view of the memory device on a plane formed by the first direction D1 and the second direction D2. The first direction D1 is different from the second direction D2. In an embodiment, the first direction D1 is substantially perpendicular to the second direction D2. For example, the first direction D1 is the X direction, and the second direction D2 is the Y direction.

請參照第2圖,其繪示另一實施例之記憶體裝置的剖面圖。此實施例中,絕緣元件400的平面狀側壁絕緣表面410可對實質上對齊記憶元件100的側壁記憶平面130,並可對齊電極元件300的側壁電極表面310。根據如第2圖所示的通道元件200、源極側元件242、汲極側元件244、與記憶元件100的配置輪廓,能使記憶體構件具有較小的單元尺寸,提升記憶體裝置的記憶胞陣列密度。源極側元件242與汲極側元件244具有比通道元件200更大的尺寸,因此能增進上方導電元件(例如第14圖所示的第一導電通孔678)的製程對準並具有良好電性連接關係,製程操作窗大,並提高產品良率。 Please refer to FIG. 2, which shows a cross-sectional view of a memory device according to another embodiment. In this embodiment, the planar sidewall insulating surface 410 of the insulating element 400 can be substantially aligned with the sidewall memory plane 130 of the memory element 100 and can be aligned with the sidewall electrode surface 310 of the electrode element 300. According to the configuration outlines of the channel element 200, the source-side element 242, the drain-side element 244, and the memory element 100 as shown in FIG. 2, the memory component can have a smaller cell size and improve the memory of the memory device Cell array density. The source-side element 242 and the drain-side element 244 have a larger size than the channel element 200, so the process alignment of the upper conductive element (such as the first conductive via 678 shown in FIG. 14) can be improved and have good electrical properties. Sexual connection relationship, large process operation window, and improve product yield.

第3A圖至第14圖繪示根據實施例之記憶體裝置的製造方法。 3A to 14 illustrate a method of manufacturing a memory device according to an embodiment.

請參照第3A圖與第3B圖。第3A圖為記憶體裝置的縱向剖面圖,其可為沿第3B圖所示之PP剖面線繪製。第3B圖為記憶體裝置的橫向剖面圖,其可為沿第3A圖所示之QQ剖面線繪製。在基底650上形成堆疊結構651。堆疊結構651包括交錯堆疊的材料膜652與絕緣膜654。材料膜652的材料不同於 絕緣膜654的材料。一實施例中,材料膜652包括氮化物例如氮化矽。絕緣膜654包括氧化物例如氧化矽。但本揭露不限於此,絕緣膜654可使用其它合適的絕緣材料,材料膜652可使用其它合適的材料例如介電材料或導電材料。可利用黃光微影蝕刻技術在堆疊結構651中形成孔洞656。 Please refer to Figure 3A and Figure 3B. Figure 3A is a longitudinal cross-sectional view of the memory device, which can be drawn along the PP section line shown in Figure 3B. Figure 3B is a transverse cross-sectional view of the memory device, which can be drawn along the QQ section line shown in Figure 3A. A stacked structure 651 is formed on the substrate 650. The stacked structure 651 includes a material film 652 and an insulating film 654 stacked alternately. The material of the material film 652 is different from The material of the insulating film 654. In one embodiment, the material film 652 includes nitride such as silicon nitride. The insulating film 654 includes oxide such as silicon oxide. However, the present disclosure is not limited to this. The insulating film 654 can use other suitable insulating materials, and the material film 652 can use other suitable materials such as dielectric materials or conductive materials. The hole 656 can be formed in the stacked structure 651 using the yellow light lithography etching technique.

記憶元件100可形成在孔洞656中與堆疊結構651的上表面上。記憶元件100可包括任意的電荷捕捉結構,例如一氧化物-氮化物-氧化物(ONO)結構或一氧化物-氮化物-氧化物-氮化物-氧化物(BE-SONOS)結構等。舉例來說,電荷捕捉層可使用氮化物例如氮化矽,或是其他類似的高介電常數物質包括金屬氧化物,例如三氧化二鋁(Al2O3)、氧化鋯(HfO2)等。通道元件200可形成在記憶元件100上。通道元件200可包括未摻雜或經摻雜的半導體材料例如多晶矽、單晶矽等等)。絕緣材料膜658可形成在通道元件200上。一實施例中,絕緣材料膜658可包括氧化物例如氧化矽,但不限於此,其也可包括氮化物例如氮化矽,或其它合適的絕緣材質。 The memory element 100 may be formed in the hole 656 and on the upper surface of the stacked structure 651. The memory device 100 may include any charge trapping structure, such as an oxide-nitride-oxide (ONO) structure or an oxide-nitride-oxide-nitride-oxide (BE-SONOS) structure. For example, the charge trapping layer can use nitrides such as silicon nitride, or other similar high dielectric constant materials including metal oxides, such as aluminum oxide (Al 2 O 3 ), zirconium oxide (HfO 2 ), etc. . The channel element 200 may be formed on the memory element 100. The channel element 200 may include undoped or doped semiconductor materials such as polysilicon, single crystal silicon, etc.). The insulating material film 658 may be formed on the channel member 200. In an embodiment, the insulating material film 658 may include oxide such as silicon oxide, but is not limited to this, and it may also include nitride such as silicon nitride, or other suitable insulating materials.

請參照第4A圖與第4B圖。第4A圖為記憶體裝置的縱向剖面圖,其可為沿第4B圖所示之PP剖面線繪製。第4B圖為記憶體裝置的橫向剖面圖,其可為沿第4A圖所示之QQ剖面線繪製。可進行回蝕刻步驟,以移除記憶元件100、通道元件200與絕緣材料膜658在堆疊結構651的上表面上的部分與在孔洞656底部的部分。一實施例中,可利用一非等向蝕刻步驟移除 絕緣材料膜658在堆疊結構651的上表面上的部分與在孔洞656底部的部分,並留下在通道元件200的側壁表面上的部分,然後,利用另一蝕刻步驟移除通道元件200與記憶元件100未被絕緣材料膜658遮蔽的部分。可形成絕緣材料層660填充孔洞656並在堆疊結構651的上表面上。一實施例中,絕緣材料層660可包括氧化物例如氧化矽,但不限於此,其也可包括氮化物例如氮化矽,或其它合適的絕緣材質。絕緣元件400可包括絕緣材料膜658與絕緣材料層660。 Please refer to Figure 4A and Figure 4B. FIG. 4A is a longitudinal sectional view of the memory device, which can be drawn along the PP section line shown in FIG. 4B. Figure 4B is a transverse cross-sectional view of the memory device, which can be drawn along the QQ section line shown in Figure 4A. An etch-back step may be performed to remove the memory element 100, the channel element 200, and the insulating material film 658 on the upper surface of the stacked structure 651 and the portion at the bottom of the hole 656. In one embodiment, an anisotropic etching step can be used to remove The portion of the insulating material film 658 on the upper surface of the stacked structure 651 and the portion at the bottom of the hole 656 and the portion on the sidewall surface of the channel element 200 are left. Then, another etching step is used to remove the channel element 200 and the memory. The part of the element 100 that is not shielded by the insulating material film 658. An insulating material layer 660 may be formed to fill the hole 656 and on the upper surface of the stacked structure 651. In one embodiment, the insulating material layer 660 may include oxide such as silicon oxide, but is not limited to this, and it may also include nitride such as silicon nitride, or other suitable insulating materials. The insulating element 400 may include an insulating material film 658 and an insulating material layer 660.

如第4B圖所示,絕緣元件400可具有實心圓形狀。通道元件200可具有封閉環形狀或中空圓形狀,環繞絕緣元件400。記憶元件100可具有封閉環形狀或中空圓形狀,環繞通道元件200。一實施例中,可在第4A圖與第4B圖所示的結構中形成溝槽662以形成如第5A圖、第5B圖與第5C圖所示的結構。第5A圖與第5B圖為記憶體裝置的縱向剖面圖,其中第5A圖可為沿第5C圖所示之PP剖面線繪製,第5B圖可為沿第5C圖所示之EE剖面線繪製。第5C圖為記憶體裝置的橫向剖面圖,其可為沿第5A圖與第5B圖所示之QQ剖面線繪製。 As shown in FIG. 4B, the insulating element 400 may have a solid circular shape. The channel element 200 may have a closed ring shape or a hollow circular shape, surrounding the insulating element 400. The memory element 100 may have a closed ring shape or a hollow circular shape surrounding the channel element 200. In one embodiment, trenches 662 may be formed in the structures shown in FIGS. 4A and 4B to form the structures shown in FIGS. 5A, 5B, and 5C. Figures 5A and 5B are longitudinal cross-sectional views of the memory device. Figure 5A can be drawn along the PP profile line shown in Figure 5C, and Figure 5B can be drawn along the EE profile line shown in Figure 5C. . FIG. 5C is a transverse cross-sectional view of the memory device, which can be drawn along the QQ section line shown in FIG. 5A and FIG. 5B.

如第5C圖所示,絕緣元件400藉由溝槽662被圖案化為實心半圓形狀。通道元件200藉由溝槽662被圖案化為開環形狀。記憶元件100藉由溝槽662被圖案化為開環形狀。絕緣元件400的平面狀側壁絕緣表面410、通道元件200的側壁通道表面217、記憶元件100的側壁記憶平面130、與材料膜652的 側壁表面657可為共平面。 As shown in FIG. 5C, the insulating element 400 is patterned into a solid semicircular shape by the trench 662. The channel element 200 is patterned into an open loop shape by the groove 662. The memory device 100 is patterned into an open loop shape by the groove 662. The planar sidewall insulation surface 410 of the insulating element 400, the sidewall channel surface 217 of the channel element 200, the sidewall memory plane 130 of the memory element 100, and the material film 652 The sidewall surface 657 may be coplanar.

請參照第6A圖、第6B圖與第6C圖。第6A圖與第6B圖為記憶體裝置的縱向剖面圖,其中第6A圖可為沿第6C圖所示之PP剖面線繪製,第6B圖可為沿第6C圖所示之EE剖面線繪製。第6C圖為記憶體裝置的橫向剖面圖,其可為沿第6A圖與第6B圖所示之QQ剖面線繪製。可從溝槽662露出之絕緣元件400的平面狀側壁絕緣表面410進行回蝕刻步驟,使得平面狀側壁絕緣表面410向絕緣元件400的內部方向移進,並形成凹口664。凹口664露出通道元件200的凹曲側壁通道表面210。然後,可利用沉積方式在通道元件200露出凹口664與溝槽662的表面(包括凹曲側壁通道表面210與側壁通道表面217)上形成如第7A圖與第7B圖所示的源極側元件242與汲極側元件244。第7A圖為記憶體裝置的縱向剖面圖,其可為沿第7B圖所示之PP剖面線繪製。第7B圖為記憶體裝置的橫向剖面圖,其可為沿第7A圖所示之QQ剖面線繪製。一實施例中,磊晶成長形成的源極側元件242與汲極側元件244具有凸曲側壁表面245。 Please refer to Figure 6A, Figure 6B and Figure 6C. Figures 6A and 6B are longitudinal cross-sectional views of the memory device. Figure 6A can be drawn along the PP profile line shown in Figure 6C, and Figure 6B can be drawn along the EE profile line shown in Figure 6C. . Figure 6C is a transverse cross-sectional view of the memory device, which can be drawn along the QQ section line shown in Figure 6A and Figure 6B. The planar sidewall insulating surface 410 of the insulating element 400 exposed from the trench 662 undergoes an etch-back step, so that the planar sidewall insulating surface 410 moves inwardly of the insulating element 400 and forms a recess 664. The notch 664 exposes the concave curved sidewall channel surface 210 of the channel element 200. Then, a deposition method can be used to form the source side as shown in FIGS. 7A and 7B on the surface of the channel element 200 where the recess 664 and the trench 662 are exposed (including the concave curved sidewall channel surface 210 and the sidewall channel surface 217). Element 242 and drain-side element 244. FIG. 7A is a longitudinal cross-sectional view of the memory device, which can be drawn along the PP cross-section line shown in FIG. 7B. FIG. 7B is a transverse cross-sectional view of the memory device, which can be drawn along the QQ section line shown in FIG. 7A. In one embodiment, the source-side element 242 and the drain-side element 244 formed by epitaxial growth have convex curved sidewall surfaces 245.

請參照第8A圖與第8B圖。第8A圖為記憶體裝置的縱向剖面圖,其可為沿第8B圖所示之PP剖面線繪製。第8B圖為記憶體裝置的橫向剖面圖,其可為沿第8A圖所示之QQ剖面線繪製。金屬矽化物層666可形成在源極側元件242與汲極側元件244的暴露表面(包括凸曲側壁表面245)上。金屬矽化物層666可包括矽化鎳(NiSi)、矽化鉑(PtSi)、矽化鈦(TiSi2)、矽化鎢 (WSi2)、矽化鈷(CoSi2)等等。 Please refer to Figure 8A and Figure 8B. FIG. 8A is a longitudinal sectional view of the memory device, which can be drawn along the PP section line shown in FIG. 8B. FIG. 8B is a transverse cross-sectional view of the memory device, which can be drawn along the QQ section line shown in FIG. 8A. The metal silicide layer 666 may be formed on the exposed surfaces (including the convex curved sidewall surface 245) of the source side element 242 and the drain side element 244. The metal silicide layer 666 may include nickel silicide (NiSi), platinum silicide (PtSi), titanium silicide (TiSi2), tungsten silicide (WSi2), cobalt silicide (CoSi2) and so on.

請參照第9A圖、第9B圖與第9C圖。第9A圖與第9B圖為記憶體裝置的縱向剖面圖,其中第9A圖可為沿第9C圖所示之PP剖面線繪製,第9B圖可為沿第9C圖所示之EE剖面線繪製。第9C圖為記憶體裝置的橫向剖面圖,其可為沿第9A圖與第9B圖所示之QQ剖面線繪製。可形成絕緣層500填充凹口664與溝槽662,並在堆疊結構651的上表面上。絕緣層500可包括氧化物例如氧化矽、氮化物例如氮化矽、或其它合適的絕緣材質。 Please refer to Figure 9A, Figure 9B and Figure 9C. Figures 9A and 9B are longitudinal cross-sectional views of the memory device. Figure 9A can be drawn along the PP profile line shown in Figure 9C, and Figure 9B can be drawn along the EE profile line shown in Figure 9C. . FIG. 9C is a transverse cross-sectional view of the memory device, which can be drawn along the QQ section line shown in FIGS. 9A and 9B. The insulating layer 500 may be formed to fill the recess 664 and the trench 662 and on the upper surface of the stacked structure 651. The insulating layer 500 may include oxide such as silicon oxide, nitride such as silicon nitride, or other suitable insulating materials.

請參照第10A圖與第10B圖。第10A圖為記憶體裝置的縱向剖面圖,其可為沿第10B圖所示之EE剖面線繪製。第10B圖為記憶體裝置的橫向剖面圖,其可為沿第10A圖所示之QQ剖面線繪製。可利用黃光微影蝕刻製程在堆疊結構651中形成溝槽671。溝槽671可露出堆疊結構651的絕緣膜654與材料膜652。可利用蝕刻步驟將溝槽671露出的材料膜652(即可作為犧牲層)移除,以形成如第11A圖、第11B圖與第11C圖所示的狹縫673。第11A圖與第11B圖為記憶體裝置的縱向剖面圖,其中第11A圖可為沿第11C圖所示之PP剖面線繪製,第11B圖可為沿第11C圖所示之EE剖面線繪製。第11C圖為記憶體裝置的橫向剖面圖,其可為沿第11A圖與第11B圖所示之QQ剖面線繪製。狹縫673可露出記憶元件100的凸曲側壁記憶表面120、絕緣膜654的上表面/下表面。 Please refer to Figure 10A and Figure 10B. FIG. 10A is a longitudinal sectional view of the memory device, which can be drawn along the EE section line shown in FIG. 10B. FIG. 10B is a transverse cross-sectional view of the memory device, which can be drawn along the QQ section line shown in FIG. 10A. The trench 671 can be formed in the stacked structure 651 using a yellow light photolithography etching process. The trench 671 can expose the insulating film 654 and the material film 652 of the stacked structure 651. An etching step can be used to remove the material film 652 (that is, as a sacrificial layer) exposed by the trench 671 to form the slit 673 as shown in FIGS. 11A, 11B, and 11C. Figures 11A and 11B are longitudinal cross-sectional views of the memory device. Figure 11A can be drawn along the PP profile line shown in Figure 11C, and Figure 11B can be drawn along the EE profile line shown in Figure 11C. . FIG. 11C is a transverse cross-sectional view of the memory device, which can be drawn along the QQ section line shown in FIGS. 11A and 11B. The slit 673 can expose the convex curved sidewall memory surface 120 of the memory device 100 and the upper surface/lower surface of the insulating film 654.

請參照第12A圖、第12B圖與第12C圖。第12A圖與第12B圖為記憶體裝置的縱向剖面圖,其中第12A圖可為沿第12C圖所示之PP剖面線繪製,第12B圖可為沿第12C圖所示之EE剖面線繪製。第12C圖為記憶體裝置的橫向剖面圖,其可為沿第12A圖與第12B圖所示之QQ剖面線繪製。可形成電極元件300在狹縫673中。電極元件300可包括金屬層例如鎢(W)等等。電極元件300亦可包括具有導電性質的阻障層(barrier layer),且金屬層形成在阻障層上。阻障層可例如包括氮化鉭(TaN)、氮化鈦(TiN)等等。一實施例中,可在形成介電薄膜之後形成電極元件300在介電薄膜上。介電薄膜可包括高介電係數(high K)材料例如三氧化二鋁(Al2O3)、二氧化鉿(HfO2)等合適的介電材料。電極元件300在第三方向D3上藉由絕緣膜654互相分開配置在記憶元件100的側壁記憶表面(即凸曲側壁記憶表面120)上。第三方向D3不同於第一方向D1與第二方向D2。一實施例中,第三方向D3可實質上垂直第一方向D1與第二方向D2。第三方向D3可為Z方向,例如垂直於基底650的上表面的方向。 Please refer to Figure 12A, Figure 12B and Figure 12C. Figures 12A and 12B are longitudinal cross-sectional views of the memory device. Figure 12A can be drawn along the PP profile line shown in Figure 12C, and Figure 12B can be drawn along the EE profile line shown in Figure 12C. . Figure 12C is a transverse cross-sectional view of the memory device, which can be drawn along the QQ cross-sectional line shown in Figures 12A and 12B. The electrode element 300 may be formed in the slit 673. The electrode element 300 may include a metal layer such as tungsten (W) or the like. The electrode element 300 may also include a barrier layer with conductive properties, and the metal layer is formed on the barrier layer. The barrier layer may include, for example, tantalum nitride (TaN), titanium nitride (TiN), or the like. In an embodiment, the electrode element 300 may be formed on the dielectric film after the dielectric film is formed. The dielectric film may include high K materials, such as aluminum oxide (Al 2 O 3 ), hafnium oxide (HfO 2 ), and other suitable dielectric materials. The electrode elements 300 are separated from each other by the insulating film 654 in the third direction D3 and are arranged on the sidewall memory surface of the memory element 100 (ie, the convex curved sidewall memory surface 120). The third direction D3 is different from the first direction D1 and the second direction D2. In an embodiment, the third direction D3 may be substantially perpendicular to the first direction D1 and the second direction D2. The third direction D3 may be the Z direction, for example, a direction perpendicular to the upper surface of the substrate 650.

一實施例中,構成記憶胞的結構可類似第1圖所示的結構。電極元件300為閘電極元件,用作字元線。記憶胞定義在通道元件200與電極元件300之間的記憶元件100中。在第三方向D3上不同階層的記憶胞電性並聯在源極側元件242與汲極側元件244之間。記憶體裝置可包括AND型記憶體裝置。根據實施例的製造方法能以自對準的方式形成記憶體裝置,方法簡單 且可降低成本。 In one embodiment, the structure constituting the memory cell may be similar to the structure shown in Figure 1. The electrode element 300 is a gate electrode element and serves as a word line. The memory cell is defined in the memory element 100 between the channel element 200 and the electrode element 300. In the third direction D3, memory cells of different levels are electrically connected in parallel between the source-side element 242 and the drain-side element 244. The memory device may include an AND type memory device. The manufacturing method according to the embodiment can form the memory device in a self-aligned manner, and the method is simple And can reduce costs.

請參照第13A圖與第13B圖。第13A圖為記憶體裝置的縱向剖面圖,其可為沿第13B圖所示之EE剖面線繪製。第13B圖為記憶體裝置的橫向剖面圖,其可為沿第13A圖所示之QQ剖面線繪製。可形成絕緣膜674在溝槽671中。絕緣膜674可包括氧化物例如氧化矽,或氮化物例如氮化矽,或其它合適的絕緣材料。絕緣膜674可利用例如物理氣相沉積或化學氣相沉積等合適的方式形成。可形成材料元件676在絕緣膜674上,並填充溝槽671。一實施例中,材料元件676為導電元件,其可藉由絕緣膜674電性絕緣於堆疊結構中的電極元件300。此例中,可在材料元件676施加偏壓以注入電流對記憶胞進行焦耳加熱(joule heat),可藉此提升記憶胞的效能例如耐久性(endurance)及資料保存性(retention)。另一實施例中,材料元件676為絕緣材料,例如包括氧化物如氧化矽等等,可與絕緣膜674一起作為分流元件(bypass)。 Please refer to Figure 13A and Figure 13B. FIG. 13A is a longitudinal sectional view of the memory device, which can be drawn along the EE section line shown in FIG. 13B. FIG. 13B is a transverse cross-sectional view of the memory device, which can be drawn along the QQ section line shown in FIG. 13A. An insulating film 674 may be formed in the trench 671. The insulating film 674 may include oxide such as silicon oxide, or nitride such as silicon nitride, or other suitable insulating materials. The insulating film 674 can be formed by a suitable method such as physical vapor deposition or chemical vapor deposition. A material element 676 can be formed on the insulating film 674 and fill the trench 671. In one embodiment, the material element 676 is a conductive element, which can be electrically insulated from the electrode element 300 in the stacked structure by the insulating film 674. In this example, a bias voltage can be applied to the material element 676 to inject current to perform joule heat on the memory cell, thereby improving the performance of the memory cell such as endurance and data retention. In another embodiment, the material element 676 is an insulating material, such as an oxide such as silicon oxide, etc., which can be used as a bypass element together with the insulating film 674.

請參照第14圖所示之記憶體裝置的縱向剖面圖。第一導電通孔(conductive via)678可形成在源極側元件242及汲極側元件244上。第一金屬層M1可形成在第一導電通孔678上。第二導電通孔680可形成在第一金屬層M1上。第二金屬層M2可形成在第二導電通孔680上。 Please refer to the longitudinal sectional view of the memory device shown in Figure 14. The first conductive via 678 may be formed on the source side element 242 and the drain side element 244. The first metal layer M1 may be formed on the first conductive via 678. The second conductive via 680 may be formed on the first metal layer M1. The second metal layer M2 may be formed on the second conductive via 680.

另一實施例中,參照第3A圖與第3B圖所述的製程是省略形成記憶元件100的步驟,並在參照類似第11A圖、第11B 圖與第11C圖所述的形成狹縫673的步驟之後,形成記憶元件100在狹縫673露出的通道元件200的凸曲側壁通道表面220與絕緣膜654的表面上。然後,進行類似參照第12A圖、第12B圖與第12C圖所述的形成電極元件300在狹縫673中的步驟。透過此變更能形成如第15圖所示的記憶體裝置,其中,記憶元件100位在電極元件300的上電極表面、下電極表面、與側壁電極表面上。 In another embodiment, the manufacturing process described with reference to FIGS. 3A and 3B is to omit the step of forming the memory element 100, and referring to FIGS. 11A and 11B. After the step of forming the slit 673 described in FIG. and FIG. 11C, the memory element 100 is formed on the surface of the channel surface 220 and the insulating film 654 of the convex sidewall of the channel element 200 exposed by the slit 673. Then, steps similar to those described with reference to FIGS. 12A, 12B, and 12C to form the electrode element 300 in the slit 673 are performed. Through this modification, a memory device as shown in FIG. 15 can be formed, in which the memory element 100 is located on the upper electrode surface, the lower electrode surface, and the sidewall electrode surface of the electrode element 300.

一實施例中,可省略參照第6A圖、第6B圖與第6C圖所述的絕緣元件400的回蝕刻步驟/形成凹口664的步驟。透過此變更可形成如第2圖所示的記憶體裝置。 In an embodiment, the step of etching back/forming the notch 664 of the insulating element 400 described with reference to FIGS. 6A, 6B, and 6C may be omitted. Through this change, a memory device as shown in Figure 2 can be formed.

參照第7A圖與第7B圖說明的利用磊晶方式形成的源極側元件242與汲極側元件244並不限於第7B圖所示的輪廓。源極側元件242與汲極側元件244可能因選用的磊晶製程參數而具有其它的輪廓,例如第16圖與第17圖所示。利用磊晶方式從通道元件200的表面成長出的任意輪廓的源極側元件242與汲極側元件244皆在本揭露的概念內。 The source-side element 242 and the drain-side element 244 formed by the epitaxial method described with reference to FIGS. 7A and 7B are not limited to the outline shown in FIG. 7B. The source-side element 242 and the drain-side element 244 may have other profiles due to the selected epitaxial process parameters, for example, as shown in FIGS. 16 and 17. The source-side element 242 and the drain-side element 244 of any contour grown from the surface of the channel element 200 by epitaxial method are all within the concept of the present disclosure.

根據以上揭露內容,實施例之記憶體裝置可具有提升的記憶胞陣列密度。 According to the above disclosure, the memory device of the embodiment can have an improved memory cell array density.

綜上所述,雖然本發明已以實施例揭露如上,然其並非用以限定本發明。本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。 In summary, although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention. Those who have ordinary knowledge in the technical field to which the present invention belongs can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention shall be subject to those defined by the attached patent application scope.

100:記憶元件 100: memory element

110:凹曲側壁記憶表面 110: Concave side wall memory surface

120:凸曲側壁記憶表面 120: Convex side wall memory surface

130:側壁記憶平面 130: Sidewall memory plane

200:通道元件 200: channel element

210:凹曲側壁通道表面 210: Concave curved side wall channel surface

220:凸曲側壁通道表面 220: Convex side wall channel surface

242:源極側元件 242: Source-side components

244:汲極側元件 244: Drain side component

245:凸曲側壁表面 245: Convex side wall surface

300:電極元件 300: Electrode element

310:側壁電極表面 310: sidewall electrode surface

400:絕緣元件 400: insulating element

410:平面狀側壁絕緣表面 410: Flat sidewall insulation surface

420:凸曲狀側壁絕緣表面 420: convex curved sidewall insulation surface

500:絕緣層 500: insulating layer

D1:第一方向 D1: First direction

D2:第二方向 D2: second direction

D3:第三方向 D3: Third party

K1、K2:尺寸 K1, K2: size

Claims (9)

一種記憶體裝置,包括:一通道元件,具有開環形狀;一記憶元件;一電極元件,其中一記憶胞定義在該通道元件與該電極元件之間的該記憶元件中;一絕緣元件,具有相鄰的一凸曲狀側壁絕緣表面與一平面狀側壁絕緣表面;一源極側元件;及一汲極側元件,其中該通道元件電性連接在該源極側元件與該汲極側元件之間,該通道元件鄰近該凸曲狀側壁絕緣表面,該源極側元件與該汲極側元件從該通道元件延伸超出該平面狀側壁絕緣表面。 A memory device includes: a channel element having an open-loop shape; a memory element; an electrode element, wherein a memory cell is defined in the memory element between the channel element and the electrode element; an insulating element having An adjacent convex curved sidewall insulation surface and a planar sidewall insulation surface; a source side element; and a drain side element, wherein the channel element is electrically connected to the source side element and the drain side element In between, the channel element is adjacent to the convex curved sidewall insulation surface, and the source side element and the drain side element extend from the channel element beyond the planar sidewall insulation surface. 如申請專利範圍第1項所述之記憶體裝置,其中該通道元件具有相對的一凹曲側壁通道表面及一凸曲側壁通道表面。 The memory device described in claim 1, wherein the channel element has a concave curved side wall channel surface and a convex curved side wall channel surface opposite to each other. 如申請專利範圍第1項所述之記憶體裝置,其中該通道元件的尺寸是小於該源極側元件的尺寸,該通道元件的該尺寸是小於該汲極側元件的尺寸。 In the memory device described in claim 1, wherein the size of the channel element is smaller than the size of the source-side element, and the size of the channel element is smaller than the size of the drain-side element. 一種記憶體裝置,包括:一通道元件;一記憶元件,具有開環形狀; 一電極元件,其中一記憶胞定義在該通道元件與該電極元件之間的該記憶元件中;一絕緣元件,具有相鄰的一凸曲狀側壁絕緣表面與一平面狀側壁絕緣表面;一源極側元件;及一汲極側元件,其中該通道元件電性連接在該源極側元件與該汲極側元件之間,該通道元件鄰近該凸曲狀側壁絕緣表面,該源極側元件與該汲極側元件從該通道元件延伸超出該平面狀側壁絕緣表面。 A memory device includes: a channel element; a memory element having an open loop shape; An electrode element, in which a memory cell is defined in the memory element between the channel element and the electrode element; an insulating element having an adjacent convex curved sidewall insulating surface and a planar sidewall insulating surface; a source A pole-side element; and a drain-side element, wherein the channel element is electrically connected between the source-side element and the drain-side element, the channel element is adjacent to the insulating surface of the convex curved sidewall, the source-side element The drain side element extends from the channel element beyond the insulating surface of the planar sidewall. 如申請專利範圍第4項所述之記憶體裝置,其中該記憶元件包括相對的一凹曲側壁記憶表面及一凸曲側壁記憶表面,與一側壁記憶平面在該凹曲側壁記憶表面與該凸曲側壁記憶表面之間。 The memory device according to claim 4, wherein the memory element includes a concave curved sidewall memory surface and a convex curved sidewall memory surface opposite to each other, and a sidewall memory plane is formed between the concave curved sidewall memory surface and the convex Between the curved sidewall memory surfaces. 如申請專利範圍第5項所述之記憶體裝置,其中該通道元件在該凹曲側壁記憶表面上,該電極元件在該凸曲側壁記憶表面上。 The memory device described in claim 5, wherein the channel element is on the memory surface of the concave curved side wall, and the electrode element is on the memory surface of the convex curved side wall. 如申請專利範圍第4項所述之記憶體裝置,其中該通道元件設置在該源極側元件、該汲極側元件與該記憶元件之間。 The memory device according to claim 4, wherein the channel element is disposed between the source-side element, the drain-side element, and the memory element. 一種記憶體裝置,包括:一記憶元件;一源極側元件;一汲極側元件; 一通道元件,電性連接在該源極側元件與該汲極側元件之間;一絕緣元件,具有相鄰的一凸曲狀側壁絕緣表面與一平面狀側壁絕緣表面,其中該通道元件與該源極側元件及該汲極側元件是分別在該絕緣元件的相反側,該通道元件鄰近該凸曲狀側壁絕緣表面,該源極側元件與該汲極側元件從該通道元件延伸超出該平面狀側壁絕緣表面;及一電極元件,其中一記憶胞定義在該通道元件與該電極元件之間的該記憶元件中。 A memory device includes: a memory element; a source side element; a drain side element; A channel element is electrically connected between the source side element and the drain side element; an insulating element has an adjacent convex curved sidewall insulating surface and a flat sidewall insulating surface, wherein the channel element and The source-side element and the drain-side element are respectively on opposite sides of the insulating element, the channel element is adjacent to the convexly curved sidewall insulating surface, and the source-side element and the drain-side element extend beyond the channel element The planar sidewall insulating surface; and an electrode element, in which a memory cell is defined in the memory element between the channel element and the electrode element. 如申請專利範圍第1項至第8項其中之一所述之記憶體裝置,包括多個該電極元件,在一垂直方向上分開配置在該記憶元件的一凸曲側壁記憶表面上,其中多個該記憶胞定義在該些電極元件與該通道元件之間的該記憶元件中。 The memory device described in one of items 1 to 8 of the scope of the patent application includes a plurality of the electrode elements separately arranged in a vertical direction on a memory surface of a convex sidewall of the memory element, wherein most One of the memory cells is defined in the memory element between the electrode elements and the channel element.
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