TWI788490B - 聚碳酸酯一聚二有機矽氧烷共聚物、其樹脂組成物、及其製造方法 - Google Patents

聚碳酸酯一聚二有機矽氧烷共聚物、其樹脂組成物、及其製造方法 Download PDF

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Publication number: TWI788490B
Authority: TW; Taiwan
Prior art keywords: group; carbon atoms; polydiorganosiloxane; copolymer; polycarbonate
Prior art date: 2017-12-21

Application number

TW107146507A

Other languages

English (en)

Chinese (zh)

Other versions

TW201930408A (zh

Inventor

木村太一

丹藤和志

小田晃司

Original Assignee

日商帝人股份有限公司

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2017-12-21

Filing date

2018-12-21

Publication date

2023-01-01

2018-12-21 Application filed by 日商帝人股份有限公司 filed Critical 日商帝人股份有限公司

2019-08-01 Publication of TW201930408A publication Critical patent/TW201930408A/zh

2023-01-01 Application granted granted Critical

2023-01-01 Publication of TWI788490B publication Critical patent/TWI788490B/zh

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229920001577 copolymer Polymers 0.000 title claims abstract description 137
239000011342 resin composition Substances 0.000 title claims abstract description 102
238000004519 manufacturing process Methods 0.000 title claims abstract description 54
229920000515 polycarbonate Polymers 0.000 claims abstract description 42
239000004417 polycarbonate Substances 0.000 claims abstract description 42
229920005668 polycarbonate resin Polymers 0.000 claims abstract description 24
239000004431 polycarbonate resin Substances 0.000 claims abstract description 24
238000010894 electron beam technology Methods 0.000 claims abstract description 8
125000004432 carbon atom Chemical group C* 0.000 claims description 157
ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 74
125000003118 aryl group Chemical group 0.000 claims description 52
239000003063 flame retardant Substances 0.000 claims description 48
229910052751 metal Inorganic materials 0.000 claims description 45
239000002184 metal Substances 0.000 claims description 45
239000000243 solution Substances 0.000 claims description 40
125000000217 alkyl group Chemical group 0.000 claims description 39
238000006243 chemical reaction Methods 0.000 claims description 39
IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 37
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 35
150000003839 salts Chemical class 0.000 claims description 32
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125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 26
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125000003545 alkoxy group Chemical group 0.000 claims description 22
150000002989 phenols Chemical class 0.000 claims description 21
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 20
125000003710 aryl alkyl group Chemical group 0.000 claims description 18
229910052799 carbon Inorganic materials 0.000 claims description 18
125000005843 halogen group Chemical group 0.000 claims description 18
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238000003756 stirring Methods 0.000 claims description 17
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RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims description 14
239000003960 organic solvent Substances 0.000 claims description 14
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
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125000002102 aryl alkyloxo group Chemical group 0.000 claims description 12
125000004104 aryloxy group Chemical group 0.000 claims description 12
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125000004093 cyano group Chemical group *C#N 0.000 claims description 10
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238000012696 Interfacial polycondensation Methods 0.000 claims description 9
125000003172 aldehyde group Chemical group 0.000 claims description 9
238000002834 transmittance Methods 0.000 claims description 9
239000011737 fluorine Substances 0.000 claims description 8
239000011259 mixed solution Substances 0.000 claims description 8
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AOGYCOYQMAVAFD-UHFFFAOYSA-N chlorocarbonic acid Chemical group OC(Cl)=O AOGYCOYQMAVAFD-UHFFFAOYSA-N 0.000 claims description 6
239000006097 ultraviolet radiation absorber Substances 0.000 claims description 6
125000001931 aliphatic group Chemical group 0.000 claims description 5
229910052721 tungsten Inorganic materials 0.000 claims description 4
238000012695 Interfacial polymerization Methods 0.000 claims description 2
239000000126 substance Substances 0.000 abstract description 32
-1 polytetrafluoroethylene Polymers 0.000 description 207
YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 108
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239000002253 acid Substances 0.000 description 22
230000000052 comparative effect Effects 0.000 description 22
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239000000178 monomer Substances 0.000 description 19
239000003381 stabilizer Substances 0.000 description 19
238000012360 testing method Methods 0.000 description 19
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ZJIPHXXDPROMEF-UHFFFAOYSA-N dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O ZJIPHXXDPROMEF-UHFFFAOYSA-N 0.000 description 16
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235000014113 dietary fatty acids Nutrition 0.000 description 10
238000009826 distribution Methods 0.000 description 10
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 10
239000000194 fatty acid Substances 0.000 description 10
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235000008434 ginseng Nutrition 0.000 description 10
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 10
239000002243 precursor Substances 0.000 description 10
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 10
GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 10
229910019142 PO4 Inorganic materials 0.000 description 9
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 9
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230000007423 decrease Effects 0.000 description 9
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239000002904 solvent Substances 0.000 description 9
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125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 8
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NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 description 7
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125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 7
150000002430 hydrocarbons Chemical class 0.000 description 7
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VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 6
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238000002485 combustion reaction Methods 0.000 description 6
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SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 4
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SMIZARYCGYRDGF-UHFFFAOYSA-N phenyl dipropan-2-yl phosphite Chemical compound CC(C)OP(OC(C)C)OC1=CC=CC=C1 SMIZARYCGYRDGF-UHFFFAOYSA-N 0.000 description 1
ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
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UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
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ABHHITAVUODQNA-UHFFFAOYSA-M potassium;benzenesulfonate Chemical compound [K+].[O-]S(=O)(=O)C1=CC=CC=C1 ABHHITAVUODQNA-UHFFFAOYSA-M 0.000 description 1
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- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/18—Block or graft polymers
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- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
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- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
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TW107146507A 2017-12-21 2018-12-21 聚碳酸酯一聚二有機矽氧烷共聚物、其樹脂組成物、及其製造方法 TWI788490B (zh)

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US11414523B2 (en)	2022-08-16
EP3730534A4 (fr)	2021-02-24
JP7254126B2 (ja)	2023-04-07
KR20200068737A (ko)	2020-06-15
EP3730534A1 (fr)	2020-10-28
JP7055152B2 (ja)	2022-04-15
WO2019124556A1 (fr)	2019-06-27
TW201930408A (zh)	2019-08-01
EP3730534B1 (fr)	2021-11-10
CN111386298B (zh)	2023-01-13
CN111386298A (zh)	2020-07-07
JPWO2019124556A1 (ja)	2020-10-22
KR102321244B1 (ko)	2021-11-02
JP2021169630A (ja)	2021-10-28
US20210108033A1 (en)	2021-04-15

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