TWI680771B - Cleaning products - Google Patents
Cleaning products Download PDFInfo
- Publication number
- TWI680771B TWI680771B TW104141972A TW104141972A TWI680771B TW I680771 B TWI680771 B TW I680771B TW 104141972 A TW104141972 A TW 104141972A TW 104141972 A TW104141972 A TW 104141972A TW I680771 B TWI680771 B TW I680771B
- Authority
- TW
- Taiwan
- Prior art keywords
- foam
- cleaning composition
- weight
- cleaning
- surfactants
- Prior art date
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- 238000004140 cleaning Methods 0.000 title claims abstract description 122
- 239000006260 foam Substances 0.000 claims abstract description 119
- 239000000203 mixture Substances 0.000 claims abstract description 102
- 239000000344 soap Substances 0.000 claims abstract description 70
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 60
- 229920000084 Gum arabic Polymers 0.000 claims abstract description 50
- 239000000205 acacia gum Substances 0.000 claims abstract description 50
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 50
- -1 lauryl aspartate Chemical compound 0.000 claims description 65
- 239000004094 surface-active agent Substances 0.000 claims description 63
- 244000215068 Acacia senegal Species 0.000 claims description 47
- 239000003240 coconut oil Substances 0.000 claims description 40
- 235000019864 coconut oil Nutrition 0.000 claims description 40
- XOAAWQZATWQOTB-UHFFFAOYSA-N Taurine Natural products NCCS(O)(=O)=O XOAAWQZATWQOTB-UHFFFAOYSA-N 0.000 claims description 31
- 229960003080 taurine Drugs 0.000 claims description 22
- 229940009098 aspartate Drugs 0.000 claims description 16
- 229940024606 amino acid Drugs 0.000 claims description 15
- 150000001413 amino acids Chemical class 0.000 claims description 14
- 239000012528 membrane Substances 0.000 claims description 12
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 7
- TXNJAVCZNMSELK-UHFFFAOYSA-N CCCCCCCCCCCCOC(=O)CNC Chemical compound CCCCCCCCCCCCOC(=O)CNC TXNJAVCZNMSELK-UHFFFAOYSA-N 0.000 claims description 6
- 229940071204 lauryl sarcosinate Drugs 0.000 claims description 6
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 claims description 5
- 150000001450 anions Chemical class 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 2
- ZDXPYRJPNDTMRX-UHFFFAOYSA-N glutamine Natural products OC(=O)C(N)CCC(N)=O ZDXPYRJPNDTMRX-UHFFFAOYSA-N 0.000 claims 1
- 241000978776 Senegalia senegal Species 0.000 abstract 2
- 230000000694 effects Effects 0.000 description 38
- 230000000052 comparative effect Effects 0.000 description 29
- 244000060011 Cocos nucifera Species 0.000 description 22
- 235000013162 Cocos nucifera Nutrition 0.000 description 22
- 239000011734 sodium Substances 0.000 description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 19
- 229910052708 sodium Inorganic materials 0.000 description 19
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 15
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 14
- 229930195712 glutamate Natural products 0.000 description 14
- 235000001014 amino acid Nutrition 0.000 description 13
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 8
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 8
- 229910052700 potassium Inorganic materials 0.000 description 8
- 239000011591 potassium Substances 0.000 description 8
- 229940071089 sarcosinate Drugs 0.000 description 8
- 235000004279 alanine Nutrition 0.000 description 7
- 235000014113 dietary fatty acids Nutrition 0.000 description 7
- 239000000194 fatty acid Substances 0.000 description 7
- 229930195729 fatty acid Natural products 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 6
- 238000011156 evaluation Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000010452 phosphate Substances 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 244000147568 Laurus nobilis Species 0.000 description 5
- 235000017858 Laurus nobilis Nutrition 0.000 description 5
- 235000005212 Terminalia tomentosa Nutrition 0.000 description 5
- 239000012459 cleaning agent Substances 0.000 description 5
- 150000004665 fatty acids Chemical class 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- 230000001953 sensory effect Effects 0.000 description 5
- 229940104261 taurate Drugs 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 4
- LPQVLIUFLWUMHG-UHFFFAOYSA-N acetyl 2-aminoacetate Chemical compound CC(=O)OC(=O)CN LPQVLIUFLWUMHG-UHFFFAOYSA-N 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 4
- 239000002280 amphoteric surfactant Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical class C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 4
- 238000005507 spraying Methods 0.000 description 4
- UTIMBUCRNZURQB-UHFFFAOYSA-N 2-(propylamino)propanoic acid Chemical compound CCCNC(C)C(O)=O UTIMBUCRNZURQB-UHFFFAOYSA-N 0.000 description 3
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 3
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 108010077895 Sarcosine Proteins 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 3
- 229960003237 betaine Drugs 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 235000013922 glutamic acid Nutrition 0.000 description 3
- 239000004220 glutamic acid Substances 0.000 description 3
- YMAWOPBAYDPSLA-UHFFFAOYSA-N glycylglycine Chemical class [NH3+]CC(=O)NCC([O-])=O YMAWOPBAYDPSLA-UHFFFAOYSA-N 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 3
- 230000007794 irritation Effects 0.000 description 3
- 229940105132 myristate Drugs 0.000 description 3
- GZWNUORNEQHOAW-UHFFFAOYSA-M potassium;2-aminoacetate Chemical compound [K+].NCC([O-])=O GZWNUORNEQHOAW-UHFFFAOYSA-M 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 229940079862 sodium lauryl sarcosinate Drugs 0.000 description 3
- ADWNFGORSPBALY-UHFFFAOYSA-M sodium;2-[dodecyl(methyl)amino]acetate Chemical compound [Na+].CCCCCCCCCCCCN(C)CC([O-])=O ADWNFGORSPBALY-UHFFFAOYSA-M 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 3
- 239000000230 xanthan gum Substances 0.000 description 3
- 229920001285 xanthan gum Polymers 0.000 description 3
- 235000010493 xanthan gum Nutrition 0.000 description 3
- 229940082509 xanthan gum Drugs 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- BLXDDKAWAKERQV-HNNXBMFYSA-N (4s)-4-amino-5-dodecoxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCCOC(=O)[C@@H](N)CCC(O)=O BLXDDKAWAKERQV-HNNXBMFYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- QNAYBMKLOCPYGJ-REOHCLBHSA-N L-alanine Chemical compound C[C@H](N)C(O)=O QNAYBMKLOCPYGJ-REOHCLBHSA-N 0.000 description 2
- OTCCIMWXFLJLIA-BYPYZUCNSA-N N-acetyl-L-aspartic acid Chemical compound CC(=O)N[C@H](C(O)=O)CC(O)=O OTCCIMWXFLJLIA-BYPYZUCNSA-N 0.000 description 2
- KCFRUUYAXCDZNZ-UHFFFAOYSA-N N-dodecanoyltaurine Chemical compound CCCCCCCCCCCC(=O)NCCS(O)(=O)=O KCFRUUYAXCDZNZ-UHFFFAOYSA-N 0.000 description 2
- 244000299461 Theobroma cacao Species 0.000 description 2
- 235000009470 Theobroma cacao Nutrition 0.000 description 2
- CXJAAWRLVGAKDV-UHFFFAOYSA-N acetyltaurine Chemical compound CC(=O)NCCS(O)(=O)=O CXJAAWRLVGAKDV-UHFFFAOYSA-N 0.000 description 2
- 239000013543 active substance Substances 0.000 description 2
- 125000003295 alanine group Chemical group N[C@@H](C)C(=O)* 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- UCMIRNVEIXFBKS-UHFFFAOYSA-N beta-alanine Chemical compound NCCC(O)=O UCMIRNVEIXFBKS-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 2
- 229940070765 laurate Drugs 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
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- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
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- 239000002562 thickening agent Substances 0.000 description 2
- UTIMBUCRNZURQB-YFKPBYRVSA-N (2s)-2-(propylamino)propanoic acid Chemical class CCCN[C@@H](C)C(O)=O UTIMBUCRNZURQB-YFKPBYRVSA-N 0.000 description 1
- QEYATHUQKXAPIM-NRFANRHFSA-N (4s)-4-amino-5-octadecoxy-5-oxopentanoic acid Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)[C@@H](N)CCC(O)=O QEYATHUQKXAPIM-NRFANRHFSA-N 0.000 description 1
- SIDHIEPQHMKDSR-NSHDSACASA-N (4s)-4-amino-5-octoxy-5-oxopentanoic acid Chemical compound CCCCCCCCOC(=O)[C@@H](N)CCC(O)=O SIDHIEPQHMKDSR-NSHDSACASA-N 0.000 description 1
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 1
- WLXGQMVCYPUOLM-UHFFFAOYSA-N 1-hydroxyethanesulfonic acid Chemical compound CC(O)S(O)(=O)=O WLXGQMVCYPUOLM-UHFFFAOYSA-N 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- RRBZUCWNYQUCTR-UHFFFAOYSA-N 2-(aminoazaniumyl)acetate Chemical compound NNCC(O)=O RRBZUCWNYQUCTR-UHFFFAOYSA-N 0.000 description 1
- OTTPFCJTQXRWHO-UHFFFAOYSA-N 3-(2,3-dichloroanilino)cyclohex-2-en-1-one Chemical compound ClC1=CC=CC(NC=2CCCC(=O)C=2)=C1Cl OTTPFCJTQXRWHO-UHFFFAOYSA-N 0.000 description 1
- WVLFZLFLLJQWOR-UHFFFAOYSA-N 7,9-dihydro-3h-purine-2,6,8-trione;potassium Chemical compound [K].N1C(=O)NC(=O)C2=C1NC(=O)N2 WVLFZLFLLJQWOR-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
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- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
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- SHBUUTHKGIVMJT-UHFFFAOYSA-N Hydroxystearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OO SHBUUTHKGIVMJT-UHFFFAOYSA-N 0.000 description 1
- DEFJQIDDEAULHB-IMJSIDKUSA-N L-alanyl-L-alanine Chemical compound C[C@H](N)C(=O)N[C@@H](C)C(O)=O DEFJQIDDEAULHB-IMJSIDKUSA-N 0.000 description 1
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- KVTFEOAKFFQCCX-UHFFFAOYSA-N N-hexadecanoylglycine Chemical compound CCCCCCCCCCCCCCCC(=O)NCC(O)=O KVTFEOAKFFQCCX-UHFFFAOYSA-N 0.000 description 1
- FKZMHRYDDKVZIN-RSAXXLAASA-M N[C@@H](CCC(=O)[O-])C(=O)OCCCCCCCCCCCC.[K+] Chemical compound N[C@@H](CCC(=O)[O-])C(=O)OCCCCCCCCCCCC.[K+] FKZMHRYDDKVZIN-RSAXXLAASA-M 0.000 description 1
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- YVIGPQSYEAOLAD-UHFFFAOYSA-L disodium;dodecyl phosphate Chemical compound [Na+].[Na+].CCCCCCCCCCCCOP([O-])([O-])=O YVIGPQSYEAOLAD-UHFFFAOYSA-L 0.000 description 1
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- 239000011777 magnesium Substances 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N mono-n-propyl amine Natural products CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
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- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
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- SDZQBOPNAYVSFF-UHFFFAOYSA-M potassium 2-[dodecyl(methyl)amino]acetate Chemical compound [K+].CCCCCCCCCCCCN(C)CC([O-])=O SDZQBOPNAYVSFF-UHFFFAOYSA-M 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229940080279 sodium cocoate Drugs 0.000 description 1
- 229940065859 sodium cocoyl glycinate Drugs 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- IEXXLSKKBWIDAC-ZOWNYOTGSA-M sodium;(3s)-3-(dodecanoylamino)-4-hydroxy-4-oxobutanoate Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CC(O)=O IEXXLSKKBWIDAC-ZOWNYOTGSA-M 0.000 description 1
- JWZSXZWCWMCYPE-RSAXXLAASA-M sodium;(4s)-4-amino-5-dodecoxy-5-oxopentanoate Chemical compound [Na+].CCCCCCCCCCCCOC(=O)[C@@H](N)CCC([O-])=O JWZSXZWCWMCYPE-RSAXXLAASA-M 0.000 description 1
- IKGKWKGYFJBGQJ-UHFFFAOYSA-M sodium;2-(dodecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCC([O-])=O IKGKWKGYFJBGQJ-UHFFFAOYSA-M 0.000 description 1
- HSFQBFMEWSTNOW-UHFFFAOYSA-N sodium;carbanide Chemical group [CH3-].[Na+] HSFQBFMEWSTNOW-UHFFFAOYSA-N 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 229940124549 vasodilator Drugs 0.000 description 1
- 239000003071 vasodilator agent Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/046—Aerosols; Foams
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/18—Sulfonic acids or sulfuric acid esters; Salts thereof derived from amino alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/87—Application Devices; Containers; Packaging
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
- Birds (AREA)
- Organic Chemistry (AREA)
- Dermatology (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
本發明之目的在於提供雖然使用非皂類陰離子性表面活性劑，仍能形成優質泡沫的清洗製品、填充到泡沫噴出器中而使用的清洗用組成物等。在含有泡沫噴出器及清洗用組成物的清洗製品以及填充到泡沫噴出器中而使用的清洗用組成物中，清洗用組成物含有非皂類陰離子性表面活性劑及阿拉伯膠，在清洗用組成物中，非皂類陰離子性表面活性劑的含量為1~20重量%，阿拉伯膠的含量為0.1~10重量%。 An object of the present invention is to provide a cleaning product that can form a high-quality foam even if a non-soap anionic surfactant is used, a cleaning composition used in a foam ejector, and the like. In the cleaning products containing the foam sprayer and the cleaning composition, and the cleaning composition used for filling the foam sprayer, the cleaning composition contains a non-soap anionic surfactant and gum arabic. Among them, the content of non-soap anionic surfactant is 1-20% by weight, and the content of gum arabic is 0.1-10% by weight.
Description
本發明涉及含有泡沫噴出器及清洗用組成物的清洗製品、以及填充到泡沫噴出器中而使用的清洗用組成物。 The present invention relates to a cleaning product containing a foam ejector and a cleaning composition, and a cleaning composition used for filling the foam ejector.
先前已知有各種清洗料，使用各種表面活性劑作為清洗劑(專利文獻1)。作為這種表面活性劑的一種，可列舉非皂類陰離子性表面活性劑。然而，例如非皂類陰離子性表面活性劑與脂肪酸皂相比，有起泡性差的傾向。 Various cleaning materials have been known in the past, and various surfactants are used as cleaning agents (Patent Document 1). As one of such surfactants, non-soap anionic surfactants may be mentioned. However, for example, non-soap anionic surfactants tend to be less foamable than fatty acid soaps.
另一方面，泡沫有使污垢從對象物浮起、包裹污垢、因其表面積而以較少液量便可清洗較廣面積的優點，特別是應用於皮膚時，可對皮膚賦予柔軟的觸感，另外，給皮膚帶來低摩擦性等。而且，為了簡便地獲得這種優點，較佳的是能夠省去自己起泡的操作、使清洗劑成為泡沫並從容器中噴出的所謂泡沫型的商品。 On the other hand, foam has the advantages of lifting dirt from the object, covering the dirt, and cleaning a wider area with a small amount of liquid due to its surface area, especially when applied to the skin, it can give the skin a soft touch , In addition, it brings low friction to the skin. Furthermore, in order to obtain this advantage easily, it is preferable to be able to eliminate the foaming operation by itself, so that the cleaning agent is foamed and sprayed from the container.
然而，所述非皂類陰離子性表面活性劑由於起泡性差，所以主要使用非皂類陰離子性表面活性劑的，難以藉 由噴出來獲得進一步優質的泡沫。 However, since the non-soap anionic surfactants have poor foaming properties, it is difficult to borrow those that mainly use non-soap anionic surfactants. By spraying out to obtain further high-quality foam.
[專利文獻1]日本專利特開平3-227914號公報 [Patent Document 1] Japanese Patent Laid-Open No. 3-227914
本發明之目的在於提供雖然使用非皂類陰離子性表面活性劑仍能形成優質的泡沫的清洗製品。另外，本發明之目的在於提供填充到泡沫噴出器中而使用的清洗用組成物。 The object of the present invention is to provide a cleaning product capable of forming high-quality foam even though non-soap anionic surfactant is used. In addition, an object of the present invention is to provide a cleaning composition used for filling a foam dispenser.
本發明者等人鑒於所述問題而進行了努力研究，結果發現，使如下組成物從泡沫噴出器中噴出而形成泡沫時，會獲得優質的泡沫，該組成物係將非皂類陰離子性表面活性劑與阿拉伯膠並用，並且在組成物中，將非皂類陰離子性表面活性劑的含量設為1~20重量%，將阿拉伯膠的含量設為0.1~10重量%。本發明係基於該知識見解進一步反復研究而完成的，其內容如下。 The inventors of the present invention conducted intensive studies in view of the above-mentioned problems, and found that when the following composition is ejected from the foam ejector to form a foam, a high-quality foam is obtained, and the composition is a non-soap anionic surface The active agent is used in combination with gum arabic, and in the composition, the content of the non-soap anionic surfactant is 1 to 20% by weight, and the content of acacia is 0.1 to 10% by weight. The present invention was completed based on this knowledge and further repeated research, and its contents are as follows.
項1.一種清洗製品，其含有泡沫噴出器及下述清洗用組成物，該清洗用組成物含有非皂類陰離子性表面活性劑及阿拉伯膠，在該清洗用組成物中，非皂類陰離子性表面活 性劑的含量為1~20重量%，阿拉伯膠的含量為0.1~10重量%。 Item 1. A cleaning product comprising a foam ejector and a cleaning composition containing a non-soap anionic surfactant and gum arabic. In the cleaning composition, a non-soap anion Sexual surface activity The content of the sex agent is 1-20% by weight, and the content of the gum arabic is 0.1-10% by weight.
項2.根據項1所述之清洗製品，在所述清洗用組成物中，相對於表面活性劑100重量份，所述非皂類陰離子性表面活性劑的含量為40重量份以上。 Item 2. The cleaning product according to Item 1, in the cleaning composition, the content of the non-soap anionic surfactant is 40 parts by weight or more relative to 100 parts by weight of the surfactant.
項3.根據項1或2所述之清洗製品，所述非皂類陰離子性表面活性劑係選自由胺基酸類表面活性劑、羥基乙磺酸鹽型表面活性劑、磷酸鹽型表面活性劑及磺基琥珀酸鹽型表面活性劑所組成之群組中的至少1種。 Item 3. The cleaning product according to Item 1 or 2, wherein the non-soap anionic surfactant is selected from the group consisting of amino acid surfactants, isethionate surfactants, and phosphate surfactants At least one of the group consisting of sulfosuccinate surfactants.
項4.根據項1至3中任一項所述之清洗製品，所述非皂類陰離子性表面活性劑係選自由椰油醯基甘胺酸鹽、椰油醯基穀胺酸鹽、月桂醯基天冬胺酸鹽、椰油醯基甲基牛磺酸鹽、月桂醯基肌胺酸鹽及椰油醯基羥基乙磺酸鹽所組成之群組中的至少1種表面活性劑。 Item 4. The cleaning product according to any one of Items 1 to 3, wherein the non-soap anionic surfactant is selected from the group consisting of coconut oil glycinate, coconut oil glutamine salt, and laurel At least one surfactant in the group consisting of acetyl aspartate, coconut oil acetyl methyl taurine, lauryl sarcosinate, and coconut oil hydroxy isethionate.
項5.根據項1至4中任一項所述之清洗製品，所述泡沫噴出器係通過多孔質膜而噴出泡沫的泵型。 Item 5. The cleaning product according to any one of Items 1 to 4, wherein the foam ejector is a pump type that ejects foam through a porous membrane.
項6.一種清洗用組成物，其係填充到泡沫噴出器中而使用，該清洗用組成物含有非皂類陰離子性表面活性劑及阿拉伯膠，在該清洗用組成物中，非皂類陰離子性表面活性劑的含量為1~20重量%，阿拉伯膠的含量為0.1~10重量%。 Item 6. A cleaning composition which is filled into a foam ejector and used. The cleaning composition contains a non-soap anionic surfactant and gum arabic. In the cleaning composition, a non-soap anion The content of the surfactant is 1-20% by weight, and the content of gum arabic is 0.1-10% by weight.
項7.根據項6所述之清洗用組成物，在所述清洗用組成物中，相對於表面活性劑100重量份，所述非皂類陰離子性表面活性劑的含量為40重量份以上。 Item 7. The cleaning composition according to Item 6, wherein the content of the non-soap anionic surfactant is 40 parts by weight or more relative to 100 parts by weight of the surfactant.
項8.一種使下述清洗用組成物從泡沫噴出器中噴出，並使所噴出的泡沫接觸物件物之方法，此處清洗用組成物含有非皂類陰離子性表面活性劑及阿拉伯膠，在該清洗用組成物中，非皂類陰離子性表面活性劑的含量為1~20重量%，阿拉伯膠的含量為0.1~10重量%。 Item 8. A method of ejecting the following cleaning composition from a foam ejector and bringing the ejected foam into contact with an object, where the cleaning composition contains a non-soap anionic surfactant and gum arabic, in In the cleaning composition, the content of the non-soap anionic surfactant is 1 to 20% by weight, and the content of gum arabic is 0.1 to 10% by weight.
項9.一種非皂類陰離子性表面活性劑及阿拉伯膠之用途，其係用以製造清洗用組成物，此處非皂類陰離子性表面活性劑在該清洗用組成物中為1~20重量%，阿拉伯膠在該清洗用組成物中為0.1~10重量%。 Item 9. Use of a non-soap anionic surfactant and gum arabic, which is used to manufacture a cleaning composition, where the non-soap anionic surfactant is 1 to 20 weights in the cleaning composition %, gum arabic is 0.1 to 10% by weight in the cleaning composition.
根據本發明的清洗製品，雖然使用非皂類陰離子性表面活性劑仍能形成優質的泡沫。另外，根據本發明的清洗用組成物，雖然使用非皂類陰離子性表面活性劑仍能形成優質的泡沫。特別是根據本發明的清洗製品或清洗用組成物，雖然使用非皂類陰離子性表面活性劑，仍能抑制從泡沫噴出器中噴出清洗用組成物時的孔堵塞，並且獲得在所噴出的泡沫的彈性、所噴出的泡沫的穩定性及清洗後的黏膩感的至少一個方面良好的效果，由此形成優質的泡沫。 According to the cleaning product of the present invention, although non-soap anionic surfactants are used, high-quality foam can be formed. In addition, according to the cleaning composition of the present invention, high-quality foam can be formed even though non-soap anionic surfactant is used. In particular, although the non-soap anionic surfactant is used for the cleaning product or the cleaning composition according to the present invention, it is possible to suppress clogging of the pores when the cleaning composition is sprayed from the foam sprayer, and obtain the sprayed foam At least one of the elasticity of the foam, the stability of the sprayed foam and the sticky feeling after cleaning has a good effect, thereby forming a high-quality foam.
以下，更詳細地說明本發明。 Hereinafter, the present invention will be described in more detail.
1.清洗製品 1. Cleaning products
本發明的清洗製品含有泡沫噴出器及下述清洗用組成物。該清洗用組成物含有非皂類陰離子性表面活性劑及阿拉伯膠，所述清洗用組成物中的非皂類陰離子性表面活性劑的含量為1~20重量%，阿拉伯膠的含量為0.1~10重量%。以下，對清洗用組成物及泡沫噴出器進行說明。 The cleaning product of the present invention contains a foam dispenser and the following cleaning composition. The cleaning composition contains non-soap anionic surfactant and gum arabic. The content of the non-soap anionic surfactant in the cleaning composition is 1-20% by weight, and the content of gum arabic is 0.1- 10% by weight. Hereinafter, the cleaning composition and the foam ejector will be described.
2.清洗用組成物 2. Cleaning composition
清洗用組成物含有非皂類陰離子性表面活性劑及阿拉伯膠，該清洗用組成物中的非皂類陰離子性表面活性劑的含量為1~20重量%，阿拉伯膠的含量為0.1~10重量%。 The cleaning composition contains non-soap anionic surfactant and gum arabic. The content of the non-soap anionic surfactant in the cleaning composition is 1-20% by weight, and the content of gum arabic is 0.1-10% by weight %.
該非皂類陰離子性表面活性劑只要能夠獲得本發明的效果則沒有限制，非皂類的陰離子性表面活性劑係熟習該項技術者公知的。作為該非皂類的陰離子性表面活性劑，可例示胺基酸類表面活性劑、羥基乙磺酸鹽型表面活性劑、磷酸鹽型表面活性劑、磺基琥珀酸鹽型表面活性劑、烷基硫酸鹽型表面活性劑、聚氧乙烯烷基醚硫酸鹽型表面活性劑、醯胺醚硫酸鹽型表面活性劑等，較佳的是例示胺基酸類表面活性劑、羥基乙磺酸鹽型表面活性劑、磷酸鹽型表面活性劑、磺基琥珀酸鹽型表面活性劑，更較佳的是例示胺基酸類表面活性劑、羥基乙磺酸鹽型表面活性劑、磷酸鹽型表面活性劑，進一步較佳的是例示胺基酸類表面活性劑、羥基乙磺酸鹽型表面活性劑。 The non-soap anionic surfactant is not limited as long as the effect of the present invention can be obtained, and the non-soap anionic surfactant is well known to those skilled in the art. Examples of the non-soap anionic surfactants include amino acid surfactants, isethionate surfactants, phosphate surfactants, sulfosuccinate surfactants, and alkyl sulfates. Salt type surfactants, polyoxyethylene alkyl ether sulfate type surfactants, amide ether sulfate type surfactants, etc., preferably exemplified amino acid surfactants, isethionate type surfactants Agents, phosphate type surfactants, sulfosuccinate type surfactants, more preferably exemplified amino acid surfactants, isethionate type surfactants, phosphate type surfactants, further Preferably, amino acid surfactants and isethionate surfactants are exemplified.
此處，作為胺基酸類表面活性劑，只要能夠獲得本發明的效果則沒有限制，較佳的是例示醯基甘胺酸鹽、醯基丙胺酸鹽、醯基穀胺酸鹽、醯基天冬胺酸鹽、肌胺酸衍生物型、牛磺酸衍生物型等胺基酸類表面活性劑。關於該等表面活性劑，其鹽也是只要能夠獲得本發明的效果則沒有限制，作為鹽，可例示鈉鹽(Na)、鉀鹽(K)等鹼金屬鹽，鈣鹽(Ca)、鎂鹽(Mg)等鹼土金屬鹽，三乙醇胺鹽(TEA)、銨鹽等，更較佳的是例示鉀鹽、鈉鹽、三乙醇胺鹽、銨鹽。 Here, the amino acid-based surfactant is not limited as long as the effect of the present invention can be obtained, and preferably exemplified by glycylglycine salt, propylalanine salt, gluglutamic acid salt, acetylglutamine Amino acid surfactants such as aspartate, sarcosinate derivatives, and taurine derivatives. The salts of these surfactants are not limited as long as the effects of the present invention can be obtained. Examples of the salts include alkali metal salts such as sodium salt (Na) and potassium salt (K), calcium salt (Ca), and magnesium salt (Mg) and other alkaline earth metal salts, triethanolamine salt (TEA), ammonium salt, etc., more preferably exemplified potassium salt, sodium salt, triethanolamine salt, ammonium salt.
關於該等表面活性劑，作為醯基甘胺酸鹽的胺基酸類表面活性劑，只要能夠獲得本發明的效果則沒有限制，更較佳的是例示椰油醯基甘胺酸鹽、棕櫚醯基甘胺酸鹽、辛醯基甘胺酸鹽、十一碳烯醯基甘胺酸鹽等，進一步較佳的是例示椰油醯基甘胺酸鹽，特別較佳的是例示椰油醯基甘胺酸鉀、椰油醯基甘胺酸鈉、椰油醯基甘胺酸TEA。 Regarding these surfactants, as the amino acid surfactants of acetylglycinate, there is no limitation as long as the effect of the present invention can be obtained, and more preferably exemplified coconut oil glycinate and palmitate Glycinate, octyl glycinate, undecylenyl glycinate, etc., further preferred is exemplified coconut oil acetyl glycinate, and particularly preferred is exemplified coconut oil acetyl glycinate Potassium urate, sodium cocoyl glycinate, TEA cocoyl glycinate.
另外，關於該等表面活性劑，醯基丙胺酸鹽的胺基酸類表面活性劑也是只要能夠獲得本發明的效果則沒有限制，更較佳的是例示椰油醯基丙胺酸鹽、椰油醯基甲基丙胺酸鹽、月桂醯基丙胺酸鹽、月桂醯基甲基丙胺酸鹽、肉豆蔻醯基甲基丙胺酸鹽等，進一步較佳的是例示椰油醯基丙胺酸鹽、椰油醯基甲基丙胺酸鹽、月桂醯基甲基丙胺酸鹽，特別較佳的是例示椰油醯基丙胺酸鈉、椰油醯基丙胺酸TEA、椰油醯基甲基丙胺酸鈉、月桂醯基甲基丙胺酸鈉、 月桂醯基甲基丙胺酸TEA。 In addition, regarding these surfactants, the amino acid surfactants of alanyl alanate are also not limited as long as the effect of the present invention can be obtained, and more preferably exemplified coconut oil alanyl alanate, coconut oil amid Methyl alanine, lauryl alanine, lauryl methyl alanine, myristyl methyl alanine, etc., further preferably exemplified coconut oil alanyl alanine, coconut oil Acyl methyl alanine, lauryl methyl alanine, particularly preferably exemplified sodium coconut propyl alanine, coconut propyl alanine TEA, sodium coconut propyl alanine, laurel Sodium acetylmethylalanine, Lauryl methyl alanine TEA.
另外，關於該等表面活性劑，醯基穀胺酸鹽的胺基酸類表面活性劑也是只要能夠獲得本發明的效果則沒有限制，更較佳的是例示椰油醯基穀胺酸鹽、月桂醯基穀胺酸鹽、肉豆蔻醯基穀胺酸鹽、棕櫚油脂肪酸穀胺酸鹽、硬脂醯基穀胺酸鹽、氫化牛脂穀胺酸鹽、橄欖油脂肪酸穀胺酸鹽、辛醯基穀胺酸鹽等，進一步較佳的是例示椰油醯基穀胺酸鹽、月桂醯基穀胺酸鹽，特別較佳的是例示椰油醯基穀胺酸鉀、椰油醯基穀胺酸鈉、椰油醯基穀胺酸二鈉、椰油醯基穀胺酸TEA、月桂醯基穀胺酸鉀、月桂醯基穀胺酸鈉、月桂醯基穀胺酸二鈉、月桂醯基穀胺酸TEA。 In addition, regarding these surfactants, the amino acid surfactants of the glutamic acid glutamate are not limited as long as the effect of the present invention can be obtained, and more preferably exemplified coconut oil glutamate and laurel Acetyl glutamate, myristic glutamate, palm oil fatty acid glutamate, stearyl glutamate, hydrogenated tallow glutamate, olive oil fatty acid glutamate, octyl glutamate Aminates and the like, further preferred are exemplified coconut oil glutamate and lauryl glutamate, particularly preferred are exemplified potassium coconut oil glutamate and coconut oil glutamate Sodium, disodium coconut glutamate, TEA coconut glutamate, potassium lauryl glutamate, sodium lauryl glutamate, disodium lauryl glutamate, lauryl glutamate Amine TEA.
另外，關於該等表面活性劑，醯基天冬胺酸鹽的胺基酸類表面活性劑也是只要能夠獲得本發明的效果則沒有限制，更較佳的是例示棕櫚醯基天冬胺酸鹽、肉豆蔻基天冬胺酸鹽、月桂基天冬胺酸鹽、月桂醯基天冬胺酸鹽等，進一步較佳的是例示月桂基天冬胺酸鹽、月桂醯基天冬胺酸鹽，特別較佳的是例示月桂基天冬胺酸鉀、月桂基天冬胺酸鈉、月桂基天冬胺酸TEA、月桂醯基天冬胺酸鈉。 In addition, regarding these surfactants, the amino acid surfactants of acetyl aspartate are not limited as long as the effect of the present invention can be obtained, and more preferably exemplified palm amide aspartate, Myristyl aspartate, lauryl aspartate, lauryl aspartate, etc., further preferably exemplified lauryl aspartate, lauryl aspartate, Particularly preferred are exemplified potassium lauryl aspartate, sodium lauryl aspartate, TEA lauryl aspartate, and sodium lauryl aspartate.
另外，關於該等表面活性劑，肌胺酸衍生物型的胺基酸類表面活性劑也是只要能夠獲得本發明的效果則沒有限制，更較佳的是例示醯基肌胺酸鹽的表面活性劑等，進一 步較佳的是例示椰油醯基肌胺酸鹽、月桂醯基肌胺酸鹽、肉豆蔻醯基肌胺酸鹽、棕櫚醯基肌胺酸鹽、油醯基肌胺酸鹽等，特別較佳的是例示椰油醯基肌胺酸鹽、月桂醯基肌胺酸鹽，進一步特別較佳的是例示椰油醯基肌胺酸鉀、椰油醯基肌胺酸鈉、椰油醯基肌胺酸TEA、月桂醯基肌胺酸鉀、月桂醯基肌胺酸鈉、月桂醯基肌胺酸TEA。 In addition, regarding these surfactants, amino acid surfactants of sarcosine derivative type are also not limited as long as the effect of the present invention can be obtained, and more preferably surfactants exemplified by acetyl sarcosinate Wait a minute More preferred are exemplified coconut amide sarcosinate, lauryl sarcosinate, myristate sarcosinate, palm acetyl sarcosinate, palm acetyl sarcosinate, etc., in particular Preferred are exemplified coconut amide sarcosinate, lauryl sarcosinate, and even more particularly preferred are exemplified potassium coconut amide sarcosinate, sodium coconut amide sarcosinate, coconut amide TEA, lauryl sarcosinate, potassium lauryl sarcosinate, sodium lauryl sarcosinate, TEA lauryl sarcosinate.
另外，關於該等表面活性劑，牛磺酸衍生物型的胺基酸類表面活性劑也是只要能夠獲得本發明的效果則沒有限制，更較佳的是例示醯基牛磺酸鹽的表面活性劑等，進一步較佳的是例示椰油醯基牛磺酸鹽、椰油醯基甲基牛磺酸鹽、椰油醯基甲基牛磺酸牛磺酸鹽、月桂酸牛磺酸鹽、月桂醯基牛磺酸鹽、月桂醯基甲基牛磺酸鹽、硬脂醯基甲基牛磺酸鹽、肉豆蔻醯基甲基牛磺酸鹽、棕櫚醯基甲基牛磺酸鹽、油醯基甲基牛磺酸鹽、己醯基甲基牛磺酸鹽、棕櫚醯基甲基牛磺酸鹽、月桂醯基甲基β-丙胺酸牛磺酸鹽等，特別較佳的是例示椰油醯基牛磺酸鹽、椰油醯基甲基牛磺酸鹽、椰油醯基甲基牛磺酸牛磺酸鹽、月桂酸牛磺酸鹽、月桂醯基牛磺酸鹽、月桂醯基甲基牛磺酸鹽，進一步特別較佳的是例示椰油醯基牛磺酸鈉、椰油醯基甲基牛磺酸鉀、椰油醯基甲基牛磺酸鈉、椰油醯基甲基牛磺酸鎂、椰油醯基甲基牛磺酸牛磺酸鈉、月桂酸牛磺酸鉀、月桂酸牛磺酸鈉、月桂醯基牛磺酸鈉、月桂醯基甲基牛磺酸鈉。 In addition, regarding these surfactants, taurine derivative-type amino acid surfactants are also not limited as long as the effect of the present invention can be obtained, and more preferably surfactants exemplifying acetyl taurates. Etc., further preferred are exemplified coconut oil acetyl taurate, coconut oil acetyl methyl taurine, coconut oil acetyl methyl taurine taurate, lauric acid taurine, laurel Acetyl Taurine, Lauryl Methyl Taurine, Stearyl Acetyl Methyl Taurine, Myristyl Acetyl Methyl Taurine, Palm Acetyl Methyl Taurine, Oil Acetylmethyl taurine, hexylmethyl taurine, palmetyl methyl taurine, lauryl methyl β-alanine taurate, etc., particularly preferably exemplified Coconut Oil Taurine, Coconut Oil Acetyl Methyl Taurine, Coconut Oil Acetyl Methyl Taurine, Lauryl Taurate, Lauryl Taurine, Laurel Acetylmethyl taurine salt, further particularly preferred are exemplified sodium coconut acetyl taurine, potassium coconut acetyl methyl taurine, sodium coconut acetyl methyl taurine, coconut oil acetyl Magnesium methyl taurine, sodium cocoyl methyl taurine taurine, potassium laurate taurine, sodium laurate taurine, sodium lauryl taurine, lauryl methyl taurine Sodium sulfonate.
另外，關於該等表面活性劑，羥基乙磺酸鹽的表面活性劑也是只要能夠獲得本發明的效果則沒有限制，更較佳的是例示醯基羥基乙磺酸鹽的表面活性劑等，關於其鹽，和所述說明同樣地，進一步較佳的是例示椰油醯基羥基乙磺酸鈉、椰油醯基羥基乙磺酸銨、月桂醯基甲基羥基乙磺酸鈉。 In addition, regarding these surfactants, the isethionate surfactants are also not limited as long as the effect of the present invention can be obtained, and more preferably are exemplified surfactants such as acetyl isethionates. As for the salt, as described above, it is further preferred to exemplify sodium coconut oil hydroxyethyl sulfonate, ammonium coconut oil hydroxyethyl sulfonate, and sodium lauryl methyl hydroxyethanesulfonate.
另外，關於該等表面活性劑，磷酸鹽型的表面活性劑也是只要能夠獲得本發明的效果則沒有限制，較佳的是例示單烷基磷酸鹽的表面活性劑等，關於其鹽，和所述說明同樣地，進一步較佳的是例示單烷基磷酸鹽、月桂基磷酸鈉等。 In addition, regarding these surfactants, phosphate-type surfactants are also not limited as long as the effects of the present invention can be obtained, and it is preferable to exemplify surfactants such as monoalkyl phosphate. Similarly to the above description, it is further preferred to exemplify monoalkyl phosphate, sodium lauryl phosphate and the like.
該等也可以使用市售品，另外，可以單獨使用1種，也可以將2種以上組合使用。 Commercial products may be used for these, and one type may be used alone, or two or more types may be used in combination.
阿拉伯膠只要能夠獲得本發明的效果，並且只要為藥學或香料化妝品學上所容許的阿拉伯膠，則沒有限制。作為阿拉伯膠，較佳的是例示分子量20萬~25萬左右的阿拉伯膠。阿拉伯膠的形狀也是只要能夠獲得本發明的效果則沒有限制，可例示粉末狀、粒狀、顆粒狀、粗粉碎物、球狀物、塊狀物等任意形狀。 Gum arabic is not limited as long as the effect of the present invention can be obtained, and as long as it is a gum arabic that is pharmacologically or cosmetically acceptable. As gum arabic, gum arabic with a molecular weight of about 200,000 to 250,000 is preferably exemplified. The shape of gum arabic is not limited as long as the effect of the present invention can be obtained, and any shape such as powder, granules, granules, coarsely pulverized materials, spheres, and lumps can be exemplified.
阿拉伯膠也可以使用市售品，另外，可以單獨使用1 種，也可以將2種以上組合使用。 Acacia gum can also use commercially available products, in addition, can be used alone 1 You may use 2 or more types together.
非皂類陰離子性表面活性劑的含量在該清洗用組成物中為1~20重量%，較佳的是例示2~15重量%，更較佳的是例示3~10重量%。 The content of the non-soap anionic surfactant is 1 to 20% by weight in the cleaning composition, preferably 2 to 15% by weight, more preferably 3 to 10% by weight.
阿拉伯膠的含量在該清洗用組成物中為0.1~10重量%，較佳的是例示0.1~7重量%，更較佳的是例示0.2~5重量%。 The content of gum arabic is 0.1 to 10% by weight in the cleaning composition, preferably 0.1 to 7% by weight, more preferably 0.2 to 5% by weight.
另外，該清洗用組成物就其而言沒有限制，較佳的是例示相對於該清洗用組成物中的表面活性劑(合計)100重量份，該非皂類陰離子性表面活性劑的含量為40重量份以上，更較佳的是例示相對於該清洗用組成物中的表面活性劑100重量份，該非皂類陰離子性表面活性劑的含量為40~90重量份，進一步較佳的是例示45~85重量份，特別較佳的是例示50~80重量份。 In addition, the cleaning composition is not limited, and it is preferable to exemplify 100 parts by weight of the surfactant (total) in the cleaning composition, and the content of the non-soap anionic surfactant is 40 More than parts by weight, more preferably exemplified with respect to 100 parts by weight of the surfactant in the cleaning composition, the content of the non-soap anionic surfactant is 40 to 90 parts by weight, more preferably exemplified 45 ~85 parts by weight, particularly preferably 50 to 80 parts by weight.
本發明的清洗用組成物中，只要不妨礙本發明的效果，則根據需要也可以含有藥學或香料化妝品學上所容許的任意成分。例如可例示：非皂類陰離子性表面活性劑以外的表面活性劑、溶劑、金屬螯合劑、增黏劑、pH值調節劑、殺菌劑、保濕劑、抗炎症劑、美白劑、香料、著色劑、抗氧化劑、防腐劑、維生素類、植物萃取物、細胞活化劑、 血管擴張劑、血流促進劑、清涼化劑等。該等可以單獨使用1種，也可以將2種以上組合使用。 The cleaning composition of the present invention may contain optional components that are pharmaceutically or perfumery cosmetically acceptable, as long as the effects of the present invention are not hindered. For example, surfactants other than non-soap anionic surfactants, solvents, metal chelating agents, thickeners, pH adjusters, bactericides, humectants, anti-inflammatory agents, whitening agents, fragrances, colorants , Antioxidants, preservatives, vitamins, plant extracts, cell activators, Vasodilators, blood flow promoters, cooling agents, etc. One of these may be used alone, or two or more may be used in combination.
如果對任意成分加以例示，則作為非皂類陰離子性表面活性劑以外的表面活性劑，可例示兩性表面活性劑、非離子表面活性劑、脂肪酸皂。 If any components are exemplified, as surfactants other than non-soap anionic surfactants, amphoteric surfactants, nonionic surfactants, and fatty acid soaps may be exemplified.
作為兩性表面活性劑，只要不妨礙本發明的效果則沒有限制，可例示椰油醯兩性基乙酸鹽、椰油醯兩性基丙酸鹽、椰油醯胺丙基甜菜鹼、月桂醯胺丙基甜菜鹼、月桂醯胺丙基羥基磺基甜菜鹼、月桂醯胺丙基氧化胺，較佳的是例示椰油醯兩性基乙酸鈉、月桂醯胺丙基甜菜鹼。 As the amphoteric surfactant, there is no limitation as long as it does not hinder the effect of the present invention, and examples include coconut amphoteric acetate, coconut amphoteric propionate, coconut amidylpropyl betaine, and laurylaminopropyl Betaine, lauryl propyl hydroxysulfobetaine, lauryl propyl amine oxide, preferably exemplified sodium amphoteric sodium cocoate, lauryl propyl betaine.
作為非離子性表面活性劑，只要不妨礙本發明的效果則沒有限制，可例示椰油醯胺DEA(二乙醇胺)、椰油醯胺MEA(單乙醇胺)、月桂醯胺DEA、PEG(聚乙二醇)-2辛醯胺，較佳的是例示椰油醯胺DEA、PEG-2辛醯胺。 The nonionic surfactant is not limited as long as it does not hinder the effect of the present invention, and examples include coconut oil amide DEA (diethanolamine), coconut oil amide MEA (monoethanolamine), lauramide amide DEA, and PEG (polyethylene Diol)-2 octyl amide, preferably exemplified DEA and PEG-2 octyl amide.
作為脂肪酸皂，只要不妨礙本發明的效果則沒有限制，可例示月桂酸鹽、肉豆蔻酸鹽、棕櫚酸鹽、硬脂酸鹽、油酸鹽、異硬脂酸鹽、羥基硬脂酸鹽，較佳的是例示月桂酸鹽、肉豆蔻酸鹽、棕櫚酸鹽。 The fatty acid soap is not limited as long as it does not hinder the effect of the present invention, and examples thereof include laurate, myristate, palmitate, stearate, oleate, isostearate, and hydroxystearate. Preferably, laurate, myristate and palmitate are exemplified.
關於該等，其鹽和所述說明相同，另外，可以單獨使 用1種，也可以將2種以上組合使用。 Regarding these, the salt is the same as the description, in addition, you can use One type may be used in combination of two or more types.
如此，只要不妨礙本發明的效果，則也可以使用非皂類陰離子性表面活性劑以外的任意表面活性劑。在不僅含有非皂類陰離子性表面活性劑，還含有選自由兩性表面活性劑、非離子性表面活性劑及脂肪酸皂所組成之群組中的至少1種表面活性劑的情況下，作為本發明的清洗用組成物，更較佳的是例示該組成物中非皂類陰離子性表面活性劑的含量分別和兩性表面活性劑的含量、非離子性表面活性劑的含量、脂肪酸皂的含量相比最高。 In this way, any surfactant other than the non-soap anionic surfactant may be used as long as the effect of the present invention is not hindered. In the case of containing not only non-soap anionic surfactant, but also at least one surfactant selected from the group consisting of amphoteric surfactants, nonionic surfactants and fatty acid soaps, it is the present invention It is more preferable to exemplify the content of the non-soap anionic surfactant in the composition compared with the amphoteric surfactant content, the nonionic surfactant content, and the fatty acid soap content, respectively. highest.
作為溶劑的例子，只要不妨礙本發明的效果則沒有限制，可例示：水、甘油、丙二醇、二丙二醇、1,3-丁二醇等多元醇等。 Examples of the solvent are not limited as long as they do not hinder the effects of the present invention, and examples thereof include polyhydric alcohols such as water, glycerin, propylene glycol, dipropylene glycol, and 1,3-butanediol.
該等任意成分的含量也是可以在不妨礙本發明的效果的範圍內根據目的而適當設定。例如在本發明的清洗用組成物含有水的情況下，只要不妨礙本發明的效果，則水的含量沒有限制，較佳的是例示30~95重量%，更較佳的是例示50~90重量%。 The content of these arbitrary components can also be appropriately set according to the purpose within a range that does not hinder the effects of the present invention. For example, when the cleaning composition of the present invention contains water, as long as the effect of the present invention is not hindered, the water content is not limited, preferably 30 to 95% by weight, more preferably 50 to 90 weight%.
本發明的清洗用組成物的製造方法也是只要能夠獲得本發明的清洗用組成物則沒有限制，可以將非皂類陰離子性表面活性劑及阿拉伯膠、以及根據需要的所述任意成分 適當混合而製造。作為更具體的一例，可例示下述實施例中所記載的順序。 The manufacturing method of the cleaning composition of the present invention is also not limited as long as the cleaning composition of the present invention can be obtained, and a non-soap anionic surfactant, gum arabic, and any of the above-mentioned optional components may be used Properly mixed and manufactured. As a more specific example, the sequence described in the following examples can be exemplified.
本發明的清洗用組成物的形狀只要能夠獲得本發明的效果則沒有限制，較佳的是常溫(25℃)下為液體狀，水溶系、乳化系、可溶化系、分散系等均可。 The shape of the cleaning composition of the present invention is not limited as long as the effect of the present invention can be obtained, and it is preferably liquid at ordinary temperature (25° C.), and may be a water-soluble system, an emulsification system, a soluble system, a dispersion system, or the like.
另外，本發明的清洗用組成物的黏度也是只要能夠獲得本發明的效果則沒有限制，較佳的是例示25℃下為0.1~100mPa‧s，更較佳的是例示1~50mPa‧s，進一步較佳的是例示1~30mPa‧s。黏度係使用BL型黏度計(東京計器公司製造)對使用轉子No.1在25℃下以轉速60rpm旋轉1分鐘後的值進行測定。在所述清洗用組成物的黏度小於10mPa‧s的情況下，進一步安裝BL適配器進行測定。 In addition, the viscosity of the cleaning composition of the present invention is not limited as long as the effect of the present invention can be obtained, preferably 0.1 to 100 mPa‧s at 25°C, more preferably 1 to 50 mPa‧s, It is further preferable to exemplify 1~30mPa‧s. The viscosity was measured using a BL-type viscometer (manufactured by Tokyo Keiki Co., Ltd.) using a rotor No. 1 at 25° C. at a rotation speed of 60 rpm for 1 minute. When the viscosity of the cleaning composition is less than 10 mPa‧s, a BL adapter is further installed and measured.
本發明的清洗用組成物可以藉由使清洗用組成物從泡沫噴出器中噴出，接著使所獲得的泡沫和物件物接觸而使用。物件物可以根據使用目的而選擇，沒有限制，就優質的泡沫能夠對皮膚賦予柔軟的觸感，另外，帶來對皮膚的低摩擦性等觀點而言，作為較佳的對象物，可例示皮膚(包括頭皮及指甲)。就該觀點而言，作為本發明的清洗用組成物的使用例，較佳的是例示皮膚清洗用組成物，較佳的是例示使所形成的泡沫接觸皮膚，使之與皮膚融合後，藉由水洗或擦拭等將清洗用組成物從皮膚除去。作為這種皮膚 清洗用組成物，可例示：洗面劑、卸妝劑、沐浴液、洗手液、洗髮精、護髮素等。另外，如此本發明的清洗用組成物較佳的是例示應用於皮膚，所以就減輕對皮膚的刺激的觀點而言，作為清洗用組成物的pH值，較佳的是例示5~8.5，更較佳的是例示5.5~8。pH值係在25℃下進行測定。 The cleaning composition of the present invention can be used by spraying the cleaning composition from the foam sprayer, and then contacting the obtained foam with the object. Objects can be selected according to the purpose of use, without limitation, as high-quality foam can give a soft touch to the skin, and from the viewpoint of bringing low friction to the skin, etc., as a preferred object, skin can be exemplified (Including scalp and nails). From this point of view, as an example of use of the cleaning composition of the present invention, it is preferable to exemplify the composition for skin cleansing, and it is preferable to exemplify that the formed foam is brought into contact with the skin to fuse it with the skin. The cleaning composition is removed from the skin by washing with water or wiping. As this skin Examples of cleaning compositions include facial cleansers, makeup removers, body washes, hand sanitizers, shampoos, and conditioners. In addition, the cleaning composition of the present invention is preferably applied to the skin by way of example, so from the viewpoint of reducing irritation to the skin, the pH value of the cleaning composition is preferably exemplified by 5 to 8.5. It is better to exemplify 5.5~8. The pH value is measured at 25°C.
本發明的清洗用組成物的使用量及每天的使用次數也是只要能夠獲得本發明的效果則沒有限制，根據清洗物件的污垢的程度或皮膚的狀態等、以及使用者的需要而適當設定。 The amount of the cleaning composition of the present invention and the number of times of use per day are not limited as long as the effect of the present invention can be obtained, and are appropriately set according to the degree of dirt of the cleaning object, the condition of the skin, etc., and the needs of users.
這種本發明的清洗用組成物可以藉由從泡沫噴出器中噴出而形成優質的泡沫。特別是，本發明的清洗製品或清洗用組成物雖然使用非皂類陰離子性表面活性劑作為清洗劑，仍能抑制從泡沫噴出器噴出清洗用組成物時的孔堵塞，並且在提高所噴出的泡沫的彈力、提高所噴出的泡沫的穩定性及抑制清洗後的黏膩感的至少一個方面獲得良好效果。據此，本發明能夠在去除物件物的污垢、特別是去除皮膚的污垢方面發揮出進一步優異的效果。特別是由於使孔堵塞降低，所以根據本發明，能夠容易地持續藉由噴出而形成良好的泡沫。另外，由於特別是泡沫的彈性提高，所以根據本發明，能夠降低對於物件物的摩擦之類的刺激。另外，由於特別是改善泡沫的穩定性，所以根據本發明，在應用於物件物時也能使泡沫持續長時間，而能夠實 現更有效果的清洗。另外，由於特別是清洗後的黏膩感降低，所以根據本發明，在清洗後也能夠獲得不會發黏的良好使用感。 The cleaning composition of the present invention can form high-quality foam by being ejected from the foam ejector. In particular, although the non-soap anionic surfactant is used as the cleaning agent in the cleaning product or cleaning composition of the present invention, it is possible to suppress clogging of pores when the cleaning composition is ejected from the foam ejector, and to improve the Good effects are obtained in at least one of the elasticity of the foam, improving the stability of the sprayed foam, and suppressing the stickiness after cleaning. According to this, the present invention can exert a further excellent effect in removing the dirt of the article, especially the dirt of the skin. In particular, since the clogging of the holes is reduced, according to the present invention, it is possible to easily continue to form good foam by ejection. In addition, since the elasticity of the foam in particular is improved, according to the present invention, it is possible to reduce irritation such as friction on objects. In addition, since the stability of the foam is particularly improved, according to the present invention, the foam can be sustained for a long time even when applied to objects and objects. Now more effective cleaning. In addition, since the sticky feeling after washing is reduced in particular, according to the present invention, a good feeling of use without stickiness can be obtained even after washing.
據此，本發明的清洗用組成物較佳的是填充到泡沫噴出器中而使用，另外，非常便於使用，使用感得到極大提高。如此，毋庸置疑這裡說明的是本發明的填充到泡沫噴出器中而使用的清洗用組成物。 Accordingly, the cleaning composition of the present invention is preferably filled into a foam ejector and used. In addition, it is very convenient to use and the feeling of use is greatly improved. In this way, it is needless to say that the composition for cleaning used in the foam dispenser of the present invention is described here.
另外，據此本發明也提供將該清洗用組成物從泡沫噴出器中噴出，使所噴出的泡沫接觸物件物、特別是皮膚的方法。另外，據此本發明提供非皂類陰離子性表面活性劑及阿拉伯膠之用途，其用以製造所述清洗用組成物，在該使用中，該清洗用組成物中的非皂類陰離子性表面活性劑的含量為1~20重量%，所述清洗用組成物中的阿拉伯膠的含量為0.1~10重量%。對於該等的說明也和上文相同。 In addition, according to the present invention, there is also provided a method of ejecting the cleaning composition from a foam ejector so that the ejected foam contacts an object, particularly skin. In addition, according to the present invention, the present invention provides the use of non-soap anionic surfactants and gum arabic, which is used to manufacture the cleaning composition. In this use, the non-soap anionic surface in the cleaning composition The content of the active agent is 1-20% by weight, and the content of the gum arabic in the cleaning composition is 0.1-10% by weight. The explanation for these is also the same as above.
3.泡沫噴出器 3. Foam ejector
在本發明中，泡沫噴出器可以填充所述清洗用組成物而使用，只要能夠噴出來自所填充的清洗用組成物的泡沫，則沒有限制，也可以使用以前公知的泡沫噴出器。 In the present invention, the foam ejector can be filled with the cleaning composition and used, as long as the foam from the filled cleaning composition can be ejected, there is no limitation, and a previously known foam ejector can also be used.
作為這種泡沫噴出器，可例示非氣溶膠型、氣溶膠型，較佳的是例示非氣溶膠型，更較佳的是例示藉由在泡沫噴出器中使所填充的清洗用組成物和空氣混合並將泡沫噴出 的類型的泡沫噴出器。另外，作為這種泡沫噴出器，可例示泵型、擠壓型等，較佳的是泵型，更較佳的是包含通過多孔質膜(也稱為網)而噴出泡沫的泵的泡沫噴出器。 As such a foam ejector, a non-aerosol type and an aerosol type can be exemplified, preferably a non-aerosol type, and more preferably a cleaning composition filled with the foam ejector and Air mixes and sprays foam Type of foam ejector. In addition, as such a foam ejector, a pump type, a squeeze type, etc. may be exemplified, a pump type is preferred, and a foam ejection including a pump that ejects foam through a porous membrane (also referred to as a net) is more preferred. Device.
泡沫噴出器較佳的是具有這樣用以使泡沫噴出的多孔質膜，該多孔質膜的孔的大小只要能夠形成泡沫，則沒有限制，以平均孔徑計較佳的是例示50~500目，更較佳的是例示80~400目。另外，多孔質膜的材質也是只要能夠形成泡沫則沒有限制，可例示：尼龍、聚酯、聚烯烴等。在泡沫噴出器中，為了形成泡沫而使用的多孔質膜可以是1片，也可以是多片，較佳的是多片，就形成泡沫及經濟性的觀點而言，較佳的是2片。在具備多片多孔質膜的情況下，可以使用1種多孔質膜，也可以將2種以上多孔質膜組合使用。關於該多孔質膜，對於熟習該項技術者而言可容易地理解，可以根據目的而適當選擇。 The foam ejector preferably has a porous membrane for ejecting the foam. The pore size of the porous membrane is not limited as long as the foam can be formed. Preferably, the average pore size is exemplified by 50 to 500 meshes. It is preferable to exemplify 80 to 400 meshes. In addition, the material of the porous membrane is not limited as long as it can form foam, and examples include nylon, polyester, and polyolefin. In the foam ejector, the porous membrane used to form the foam may be one piece or multiple pieces, preferably multiple pieces, and from the viewpoint of foam formation and economy, two pieces are preferred . When a plurality of porous membranes are provided, one kind of porous membrane may be used, or two or more kinds of porous membranes may be used in combination. The porous membrane can be easily understood by those skilled in the art, and can be appropriately selected according to the purpose.
並不是對本發明進行限制，這種泡沫噴出器只要不妨礙本發明的效果，則可以使用任意的泡沫噴出器，可例示日本吉野工業所公司製造、大和制罐公司製造等的市售品，另外，熟習該項技術者可以根據目的從日本專利特開平07-315463、日本專利特開平08-230924、日本專利特開平08-230961、日本專利特開平09-118351、日本專利特開平10-324357等中所記載的容器等中適當決定。 The present invention is not limited, and such a foam ejector can use any foam ejector as long as it does not hinder the effect of the present invention, and can exemplify commercial products manufactured by Yoshino Industries, Japan, and Yamato Can Co., Ltd. According to the purpose, those skilled in the art can choose from Japanese Patent Publication No. 07-315463, Japanese Patent Publication No. 08-230924, Japanese Patent Publication No. 08-230961, Japanese Patent Publication No. 09-118351, Japanese Patent Publication No. 10-324357, etc. Appropriately determined in the container described in the.
泡沫噴出器的容量也沒有限制，熟習該項技術者可以根據使用目的等而適當決定。並不是對本發明加以限制，作為泡沫噴出器的容量，可例示10~1000mL，較佳的是例示30~700mL。 There is no limit to the capacity of the foam ejector. Those skilled in the art can make appropriate decisions according to the purpose of use. The present invention is not limited, and as the capacity of the foam ejector, 10 to 1000 mL can be exemplified, preferably 30 to 700 mL.
藉由將該泡沫噴出器和所述清洗用組成物組合使用，可以從泡沫噴出器形成源於所述清洗用組成物的優質泡沫。特別是，本發明的清洗製品雖然使用非皂類陰離子性表面活性劑作為清洗劑，仍能抑制使所填充的清洗用組成物從泡沫噴出器中噴出時的孔堵塞，並且在提高所噴出的泡沫的彈力、提高所噴出的泡沫的穩定性及抑制清洗後的黏膩感的至少一個方面獲得良好效果。據此，根據本發明的清洗製品，可以在除去物件物的污垢、特別是皮膚的污垢方面發揮出進一步優異的效果。特別是由於孔堵塞降低，所以根據本發明，可以容易地持續藉由噴出而形成良好的泡沫。另外，特別是由於泡沫的彈性提高，所以根據本發明，可以降低對於物件物的摩擦之類的刺激。另外，特別是由於改善泡沫的穩定性，所以根據本發明，在應用於物件物時也能使泡沫持續長時間，而能夠實現更有效果的清洗。另外，特別是由於清洗後的黏膩感降低，所以根據本發明，在清洗後也能獲得良好的使用感。如此，本發明的清洗製品非常便於使用，使用感得到極大提高。 By using the foam ejector in combination with the cleaning composition, high-quality foam derived from the cleaning composition can be formed from the foam ejector. In particular, although the cleaning product of the present invention uses a non-soap anionic surfactant as the cleaning agent, it can still suppress clogging of the hole when the filled cleaning composition is ejected from the foam ejector, and improve the ejected Good effects are obtained in at least one of the elasticity of the foam, improving the stability of the sprayed foam, and suppressing the stickiness after cleaning. According to this, according to the cleaning product of the present invention, it is possible to exert a further excellent effect in removing the dirt of the article, especially the dirt of the skin. In particular, since the clogging of the holes is reduced, according to the present invention, it is possible to easily continue to form good foam by spraying. In addition, since the elasticity of the foam is improved, according to the present invention, it is possible to reduce irritation such as friction on objects. In addition, in particular, since the stability of the foam is improved, according to the present invention, the foam can be continued for a long time even when it is applied to objects, and more effective cleaning can be achieved. In addition, since the stickiness after washing is reduced, according to the present invention, a good feeling of use can also be obtained after washing. In this way, the cleaning product of the present invention is very convenient to use, and the sense of use is greatly improved.
以下，列舉實施例說明本發明，但本發明並不限定於該等實施例。 Hereinafter, the present invention will be described with examples, but the present invention is not limited to these examples.
1-1.清洗用組成物及清洗製品的製造 1-1. Manufacture of cleaning compositions and cleaning products
將下述表1所示的成分以總量達到100重量%的方式進行混合，而製造清洗用組成物(實施例1-1a)及比較組成物(比較例1-1a~1-6a)。表中，單位為重量%。具體而言，在室溫(25℃)下將表1所示的成分全部混合，使用攪拌器攪拌至均勻，由此製造各組成物。此外，檸檬酸係以所獲得的組成物的pH值達到表中所示的pH值的方式進行混合。 The components shown in Table 1 below were mixed so that the total amount reached 100% by weight to produce a cleaning composition (Example 1-1a) and a comparative composition (Comparative Examples 1-1a to 1-6a). In the table, the unit is% by weight. Specifically, all the components shown in Table 1 were mixed at room temperature (25°C) and stirred until uniform using a stirrer, thereby producing each composition. In addition, citric acid was mixed so that the pH of the obtained composition reached the pH shown in the table.
此外，表中的各成分如下。 In addition, each component in the table is as follows.
椰油醯基甘胺酸鉀：商品名AMILITE GCK-12K(AJINOMOTO HEALTHY SUPPLY公司製造(此外，該商品為椰油醯基甘胺酸鉀的30%水溶液，表中的“6”表示換算為僅有椰油醯基甘胺酸鉀的含量的值；即，表中所示的組成物係指含有20重量%的AMILITE GCK-12K；以下相同。)) Potassium Coconut Oil Glycinate: Trade name AMILITE GCK-12K (AJINOMOTO HEALTHY SUPPLY Co., Ltd. (In addition, this product is a 30% aqueous solution of Coconut Oil Potassium Glycinate, "6" in the table means that it is converted to only There are values for the content of coconut oil acetylglycinate; that is, the composition shown in the table refers to AMILITE GCK-12K containing 20% by weight; the same below.))
椰油醯兩性基乙酸鈉：商品名SOFTAZOLINE CH-R(Kawaken Fine Chemicals公司製造(和所述椰油醯基甘胺酸鉀同樣地，表中的“4.2”表示換算為僅有椰油醯兩性基乙酸鈉的含量的值；以下相同。)) Sodium Cocoamphoteric Acetate: Trade name SOFTAZOLINE CH-R (manufactured by Kawaken Fine Chemicals Co., Ltd. (Similar to the Cocoacoyl Acetyl Potassium Glycolate, "4.2" in the table means that it is converted to Cocoa Amphoteric only The value of the content of sodium sodium acetate; the same below.))
阿拉伯膠：商品名精製阿拉伯膠噴霧粉(DSP Gokyo Food & Chemical公司製造) Gum Arabic: trade name refined gum arabic spray powder (manufactured by DSP Gokyo Food & Chemical)
聚季銨鹽-7(重均分子量160萬)：商品名Merquat 550(日本路博潤公司製造) Polyquaternium-7 (weight average molecular weight 1.6 million): Merquat 550 (manufactured by Lubrizol Corporation)
PEG-65M：商品名ALKOX E-100(明成化學工業公司製造) PEG-65M: Trade name ALKOX E-100 (made by Mingcheng Chemical Industry Co., Ltd.)
羥丙基甲基纖維素(重均分子量30萬)：商品名Metolose 60SH-4000(信越化學工業公司製造) Hydroxypropyl methylcellulose (weight average molecular weight 300,000): trade name Metolose 60SH-4000 (manufactured by Shin-Etsu Chemical Co., Ltd.)
黃原膠：商品名Echo Gum(DSP Gokyo Food & Chemical公司製造) Xanthan gum: trade name Echo Gum (manufactured by DSP Gokyo Food & Chemical)
銀耳多糖體：商品名Tremoist-TP(日本精化公司製造) Tremella polysaccharide: trade name Tremoist-TP (manufactured by Nippon Seiki Chemical Co., Ltd.)
使用BL型黏度計(東京計器公司製造)、轉子No.1在25℃、60rpm的條件下測定所獲得的各組成物的黏度1分鐘。 The viscosity of each obtained composition was measured using a BL-type viscometer (manufactured by Tokyo Keiki Co., Ltd.) and rotor No. 1 at 25°C and 60 rpm for 1 minute.
將所獲得的組成物100mL分別填充到容量150mL的泡沫噴出器(吉野工業所公司製造、非氣溶膠型的包含泵的類型、具備多孔質膜、藉由按壓泡沫噴出器的上部而使泡沫噴出)中，而製造清洗製品(實施例1-1b)及比較製品(比較例1-1b~1-6b)。 Each of the obtained compositions was filled with 100 mL of a foam ejector of 150 mL capacity (manufactured by Yoshino Industries, non-aerosol type including pump type, equipped with a porous membrane, and foam was ejected by pressing the upper part of the foam ejector ), cleaning products (Example 1-1b) and comparative products (Comparative Examples 1-1b to 1-6b) were manufactured.
1-2.噴出評價 1-2. Ejection evaluation
使用所獲得的清洗製品(實施例1-1b)及比較製品(比較例1-1b~1-6b)而評價噴出時的孔堵塞。具體而言，對藉由按壓泡沫噴出器的上部而從泡沫噴出器噴出泡沫時的孔堵塞進行評價。 Using the obtained cleaning product (Example 1-1b) and comparative products (Comparative Examples 1-1b to 1-6b), the hole clogging at the time of discharge was evaluated. Specifically, the hole clogging when foam was ejected from the foam ejector by pressing the upper part of the foam ejector was evaluated.
更具體而言，以使用比較例1-6b而使泡沫噴出的情況作為標準，將和比較例1-6b同樣地能夠順暢地噴出泡沫的情況設為“○”，將和比較例1-6b相比使泡沫噴出需要更大力(按壓上部的力)的情況設為“△”，將沒能噴出泡沫的情況設為“×”。將結果示於表1。 More specifically, the case where foam is ejected using Comparative Example 1-6b as a standard, and the case where foam can be smoothly ejected as in Comparative Example 1-6b is set to "○", which is the same as that of Comparative Example 1-6b Compared to the case where a larger force (force pressing the upper part) is required to eject the foam, it is set to “△”, and the case where the foam cannot be ejected is set to “×”. The results are shown in Table 1.
由表1明確，關於實施例1-1a所示的椰油醯基甘胺酸鉀(非皂類陰離子性表面活性劑)和阿拉伯膠的組合，和比 較例1-6b同樣地能夠從泡沫噴出器中順暢地噴出泡沫。 It is clear from Table 1 that the combination of potassium coconut palmitoylglycine (non-soap anionic surfactant) and gum arabic shown in Example 1-1a, and the ratio In Comparative Example 1-6b, the foam can be smoothly ejected from the foam ejector.
相對於此，使用以前為了提高起泡而使用的聚季銨鹽-7(由丙烯醯胺和二甲基二烯丙基氯化銨所獲得的季銨鹽的聚合物、重均分子量160萬)代替阿拉伯膠而和非皂類陰離子性表面活性劑組合，無法實現良好的噴出，泡沫噴出器中發生了孔堵塞。另外，在使用其他的聚乙二醇、羥丙基甲基纖維素、黃原膠、銀耳多糖類代替阿拉伯膠的情況下，和非皂類陰離子性表面活性劑的組合都無法良好地噴出，即泡沫噴出器中發生了孔堵塞。 In contrast to this, the polymer of quaternary ammonium salt-7 (a polymer of quaternary ammonium salt obtained from acrylamide and dimethyldiallyl ammonium chloride, weight average molecular weight 1.6 million ) Instead of gum arabic, in combination with non-soap anionic surfactants, good ejection cannot be achieved, and pore blockage has occurred in the foam ejector. In addition, when other polyethylene glycols, hydroxypropyl methyl cellulose, xanthan gum, and white fungus polysaccharides are used instead of gum arabic, the combination with non-soap anionic surfactants cannot be ejected well. That is, a hole blockage occurred in the foam ejector.
由此確認，在採用以前為了提高清洗劑的起泡而一直使用的聚季銨鹽-7、或以前已知和阿拉伯膠同樣地用作增黏劑的黃原膠等成分時，會發生孔堵塞，而無法實現良好的泡沫噴出，相對於此，令人意想不到的是將非皂類陰離子性表面活性劑和阿拉伯膠組合時，不會發生泡沫噴出器中的孔堵塞。由此可知，藉由將非皂類陰離子性表面活性劑和阿拉伯膠組合，能夠容易地持續藉由噴出而形成良好的泡沫。 From this, it was confirmed that when using components such as polyquaternium-7, which has been used to increase the foaming of the cleaning agent, or xanthan gum, which was previously known to be used as a thickener in the same way as gum arabic, pores may occur Clogging does not allow good foam ejection. On the other hand, it is unexpected that when a non-soap anionic surfactant and gum arabic are combined, there is no clogging in the foam ejector. From this, it can be seen that by combining the non-soap anionic surfactant and gum arabic, it is possible to easily continue to form good foam by spraying.
2-1.清洗用組成物及清洗製品的製造 2-1. Manufacture of cleaning compositions and cleaning products
將下述表2所示的成分以總量達到100重量%的方式和所述試驗例同樣地進行混合，而製造清洗用組成物(實施例2-1a~2-6a)及比較組成物(比較例2-1a~2-6a)。將所獲 得的組成物100mL和所述同樣地分別填充到泡沫噴出器中，而製造清洗製品(實施例2-1b~2-6b)及比較製品(比較例2-1b~2-6b)。泡沫噴出器係使用和所述相同者。 The components shown in Table 2 below were mixed in the same manner as in the test example so that the total amount reached 100% by weight, to produce cleaning compositions (Examples 2-1a to 2-6a) and comparative compositions ( Comparative Examples 2-1a~2-6a). Will get 100 mL of the obtained composition was filled into a foam ejector in the same manner as described above, to produce a cleaning product (Examples 2-1b to 2-6b) and a comparative product (Comparative Examples 2-1b to 2-6b). The foam ejector is the same as described above.
此外，表中的各成分如下。 In addition, each component in the table is as follows.
椰油醯基甘胺酸鉀：和試驗例1相同。 Coconut oil potassium glycinate: Same as Test Example 1.
椰油醯基穀胺酸TEA：商品名AminoSurfact ACMT-L(旭化成化學公司製造(此外，該商品為椰油醯基穀胺酸TEA的30%水溶液，表中的“6”表示換算為僅有椰油醯基穀胺酸TEA的含量的值；以下相同。)) Coconut oil glutamic acid TEA: Trade name AminoSurfact ACMT-L (manufactured by Asahi Kasei Chemicals Co., Ltd. (In addition, this product is a 30% aqueous solution of coconut oil glutamate glutamate TEA, "6" in the table means that the conversion is only Coconut oil glutamic acid TEA content value; the same below.))
月桂醯基天冬胺酸鈉：商品名胺基AminoFoamer FLDS-L(旭化成化學(股份)製(此外，該商品為月桂醯基天冬胺酸鈉的25%水溶液，表中的“6”表示換算為僅有月桂醯基天冬胺酸鈉的含量的值；以下相同。)) Sodium lauryl aspartate: Trade name AminoFoamer FLDS-L (manufactured by Asahi Kasei Chemicals Co., Ltd. (In addition, this product is a 25% aqueous solution of sodium lauryl aspartate, "6" in the table Converted to a value containing only sodium lauryl aspartate; the same applies below.))
椰油醯基甲基牛磺酸鈉：商品名NIKKOL CMT-30N(日光化學公司製造(此外，該商品為椰油醯基甲基牛磺酸鈉的30%水溶液，表中的“6”表示換算為僅有椰油醯基甲基牛磺酸鈉的含量的值；以下相同。)) Coconut Oil Sodium Methyl Taurine: Trade Name NIKKOL CMT-30N (manufactured by Nikko Chemical Co., Ltd. (In addition, this product is a 30% aqueous solution of Coconut Oil Acetyl Methyl Taurine, "6" in the table indicates Converted to a value containing only the content of sodium cocoyl methyl taurine; the same below.))
月桂醯基肌胺酸鈉：商品名NIKKOL Sarcosinate LN(日光化學公司製造) Sodium lauryl sarcosinate: trade name NIKKOL Sarcosinate LN (manufactured by Nikko Chemical Co., Ltd.)
椰油醯基羥基乙磺酸鈉：商品名Jordapon CI P(日本巴斯夫公司製造) Sodium Cocoyl Acetyl Isethionate: Trade Name Jordapon CI P (made by BASF Japan)
椰油醯兩性基乙酸鈉：和試驗例1相同。 Coconut oil amphoteric sodium acetate: same as test example 1.
阿拉伯膠：和試驗例1相同。 Gum Arabic: Same as Test Example 1.
2-2.泡沫的彈性評價 2-2. Elastic evaluation of foam
使用所獲得的清洗製品(實施例2-1b~2-6b)及比較製品(比較例2-1b~2-6b)而評價所噴出的泡沫的彈性。具體而言，從泡沫噴出器對手掌噴出所述清洗用組成物或比較組成物3次，用手進行搓洗，針對這時的泡沫的彈力，由5名專業感官評價人員分5個等級進行評價。將作為標準的由沒有並用阿拉伯膠的各比較組成物(表中，各比較例)所形成的泡沫的彈力評價為0分，並設為以下標準。將5名感官評價人員的評分的平均分示於表3。 The elasticity of the foam ejected was evaluated using the obtained cleaning products (Examples 2-1b to 2-6b) and comparative products (Comparative Examples 2-1b to 2-6b). Specifically, the cleaning composition or the comparative composition was sprayed three times from the palm of the foam sprayer and rubbed by hand, and the elasticity of the foam at this time was evaluated in 5 levels by five professional sensory evaluators. The elasticity of the foam formed by each comparative composition (in the table, each comparative example) without using gum arabic as a standard was evaluated as 0 points, and set as the following standard. Table 3 shows the average scores of the five sensory appraisers.
2分：和標準相比，彈力非常優異 2 points: Compared with the standard, the elasticity is very excellent
1分：和標準相比，彈力稍優異 1 point: Compared with the standard, the elasticity is slightly better
0分：彈力和標準相同 0 points: the elasticity is the same as the standard
-1分：和標準相比，彈力稍遜色 -1 points: Compared with the standard, the elasticity is slightly inferior
-2分：和標準相比，彈力非常差 -2 points: Compared with the standard, the elasticity is very poor
另外，基於所算出的所述平均分，如下所述評價提高泡沫彈力的效果。 In addition, based on the calculated average score, the effect of improving foam elasticity is evaluated as follows.
平均分大於1分且2分以下◎：提高泡沫彈力的效果優異 Average score is greater than 1 point and less than 2 points ◎: The effect of improving foam elasticity is excellent
平均分大於0分且1分以下○：有少許提高泡沫彈力的效果 The average score is greater than 0 points and less than 1 point ○: There is a little effect to increase the elasticity of the foam
平均分為-2分以上且0分以下×：沒有提高泡沫彈力的效果 Average score is -2 points or more and 0 points or less ×: No effect to increase foam elasticity
將結果示於表2。 The results are shown in Table 2.
由表2明確可知，實施例2-1a~2-6a(2-1b~2-6b)都藉由非皂類陰離子性表面活性劑和阿拉伯膠的並用，而提高了泡沫的彈力。 As is clear from Table 2, Examples 2-1a to 2-6a (2-1b to 2-6b) all use the combination of non-soap anionic surfactant and gum arabic to increase the elasticity of the foam.
使用所述清洗製品(實施例2-1b~2-6b)及比較製品(比較例2-1b~2-6b)，對所噴出的泡沫的穩定性進行了評價。 具體而言，從泡沫噴出器中向200mL量筒噴出所述清洗用組成物或比較組成物15次，測定在25℃下噴出5分鐘後留在量筒底的液量(排液量)。另外，測定在量筒底排液達到10mL所耗費的時間。將結果示於表3。 Using the aforementioned cleaning products (Examples 2-1b to 2-6b) and comparative products (Comparative Examples 2-1b to 2-6b), the stability of the ejected foam was evaluated. Specifically, the cleaning composition or the comparative composition was sprayed 15 times from a foam sprayer to a 200 mL measuring cylinder, and the amount of liquid (discharge volume) remaining at the bottom of the measuring cylinder after being sprayed at 25°C for 5 minutes was measured. In addition, the time taken for the liquid to drain to 10 mL at the bottom of the measuring cylinder was measured. The results are shown in Table 3.
[表3]
由表3明確，在使用椰油醯基甘胺酸鉀作為非皂類陰離子性表面活性劑的情況下，沒有並用阿拉伯膠時的5分鐘後 的排液量為5mL，排液達到10mL所需要的時間為12.8分鐘。相對於此，在將椰油醯基甘胺酸鉀和阿拉伯膠並用時，5分鐘後的排液量大幅度降低到2mL，排液達到10mL所需要的時間也為21.5分鐘，而非常遲緩。 It is clear from Table 3 that when potassium coconut glycylglycine is used as a non-soap anionic surfactant, after 5 minutes without using gum arabic The discharge volume is 5mL, and the time required for the discharge to reach 10mL is 12.8 minutes. On the other hand, when using cocoa potassium glycinate and gum arabic together, the discharge volume after 5 minutes was significantly reduced to 2 mL, and the time required for the discharge to reach 10 mL was also 21.5 minutes, which was very slow.
另外，在使用椰油醯基穀胺酸TEA、月桂醯基天冬胺酸鈉、椰油醯基甲基牛磺酸鈉、月桂醯基肌胺酸鈉、椰油醯基羥基乙磺酸鈉代替椰油醯基甘胺酸鉀作為非皂類陰離子性表面活性劑的情況下，並用阿拉伯膠時的5分鐘後的排液量和沒有並用阿拉伯膠時的5分鐘後的排液量相比，也大幅度降低，排液達到10mL所需要的時間也大幅度延遲。 In addition, the use of coconut glutamate glutamate TEA, sodium lauryl aspartate, sodium coconut methyl taurate, sodium lauryl sarcosinate, sodium coconut hydroxy isethionate In the case of substituting non-soap anionic surfactant with potassium coconut amidylglycine as a non-soap anionic surfactant, the displacement after 5 minutes when using gum arabic is compared with the displacement after 5 minutes without using gum arabic It is also greatly reduced, and the time required for the discharge to reach 10mL is also greatly delayed.
由此可知，藉由非皂類陰離子性表面活性劑和阿拉伯膠的並用，泡沫的穩定性提高，即泡沫持久性得到非常大的改善。 From this, it can be seen that by using a combination of non-soap anionic surfactant and gum arabic, the stability of the foam is improved, that is, the foam durability is greatly improved.
4-1.清洗用組成物及清洗製品的製造 4-1. Manufacture of cleaning compositions and cleaning products
將下述表4所示的成分以總量達到100重量%的方式和所述試驗例同樣地進行混合，而製造清洗用組成物(實施例3-1a及3-2a)及比較組成物(比較例3-1a及3-2a)。將所獲得的組成物和所述同樣地分別填充到泡沫噴出器中，而製造清洗製品(實施例3-1b及3-2b)及比較製品(比較例3-1b及3-2b)。此外，表中的各成分和所述相同，聚季銨鹽-7(重均分子量12萬)為商品名Merquat 740(日本路博潤公司製 造)。 The components shown in Table 4 below were mixed in the same manner as in the test example so that the total amount reached 100% by weight, to produce cleaning compositions (Examples 3-1a and 3-2a) and comparative compositions ( Comparative Examples 3-1a and 3-2a). The obtained composition was filled into a foam ejector in the same manner as described above, to produce cleaning products (Examples 3-1b and 3-2b) and comparative products (Comparative Examples 3-1b and 3-2b). In addition, the components in the table are the same as described above, and polyquaternium-7 (weight average molecular weight 120,000) is trade name Merquat 740 (manufactured by Japan Lubrizol Corporation) Made).
4-2.泡沫的黏膩感評價 4-2. Evaluation of stickiness of foam
使用所獲得的清洗製品(實施例3-1b及3-2b)及比較製品(比較例3-1b及3-2b)，對所噴出的泡沫的黏膩感進行評價。具體而言，從泡沫噴出器中對濕潤的手掌噴出清洗用組成物或比較組成物2次，雙手揉搓15次後，在流水下雙手揉搓15次而進行沖洗。利用紙巾擦拭水，對擦乾時的手掌的黏膩感進行感官評價。黏膩感係由5名專業感官評價人員基於以下標準以0.5分為單位分5個等級進行評價。將最好的結果設為3分，將最差的結果設為1分。將5名感官評價人員的評分的平均分示於表4。 Using the obtained cleaning products (Examples 3-1b and 3-2b) and comparative products (Comparative Examples 3-1b and 3-2b), the stickiness of the ejected foam was evaluated. Specifically, the cleaning composition or the comparative composition was sprayed from the foam sprayer to the wet palm twice, and after rubbing both hands 15 times, the hands were rubbed 15 times under running water to rinse. Wipe the water with a paper towel to make a sensory evaluation of the sticky feeling of the palm when drying. The sticky feeling was evaluated by 5 professional sensory appraisers based on the following criteria and divided into 5 grades in units of 0.5 points. Set the best result to 3 points and the worst result to 1 point. Table 4 shows the average scores of the five sensory appraisers.
3分：完全沒有感覺到黏膩感 3 points: No stickiness at all
2分：稍微感覺到黏膩感 2 points: slightly sticky
1分：強烈感覺到黏膩感 1 point: Strong sense of stickiness
另外，對根據有沒有並用阿拉伯膠而產生的改善黏膩感的效果進行如下評價。 In addition, the effect of improving the stickiness due to the use of gum arabic in combination was evaluated as follows.
在並用阿拉伯膠時評分高◎：有改善黏膩感的效果 High score when using gum arabic in combination ◎: Has the effect of improving stickiness
在沒有沒並用阿拉伯膠方面評分相同或在並用阿拉伯膠時評分低×：沒有改善黏膩感的效果 The score is the same in the absence of the use of gum arabic or the score is low when the gum arabic is used ×: no effect to improve stickiness
將結果示於表4。 The results are shown in Table 4.
由表4明確可知，實施例3-1a及3-2a的清洗用組成物都藉由非皂類陰離子性表面活性劑和阿拉伯膠的並用，而改善了黏膩感。 As is clear from Table 4, the cleaning compositions of Examples 3-1a and 3-2a all improved the stickiness by using a combination of non-soap anionic surfactant and gum arabic.
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| TW201626984A (en) | 2016-08-01 |
| KR20170095258A (en) | 2017-08-22 |
| WO2016098649A1 (en) | 2016-06-23 |
| JPWO2016098649A1 (en) | 2017-09-21 |
| CN106999391A (en) | 2017-08-01 |
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