TWI679275B - Method and device for enhancing combustion efficiency - Google Patents
Method and device for enhancing combustion efficiency Download PDFInfo
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- TWI679275B TWI679275B TW107132163A TW107132163A TWI679275B TW I679275 B TWI679275 B TW I679275B TW 107132163 A TW107132163 A TW 107132163A TW 107132163 A TW107132163 A TW 107132163A TW I679275 B TWI679275 B TW I679275B
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- 238000002485 combustion reaction Methods 0.000 title claims abstract description 102
- 230000002708 enhancing effect Effects 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 21
- 239000000446 fuel Substances 0.000 claims abstract description 51
- 238000007084 catalytic combustion reaction Methods 0.000 claims abstract description 48
- 239000003595 mist Substances 0.000 claims abstract description 24
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 230000003197 catalytic effect Effects 0.000 claims description 27
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 22
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 19
- 239000007789 gas Substances 0.000 claims description 18
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 230000005540 biological transmission Effects 0.000 claims description 12
- 239000000295 fuel oil Substances 0.000 claims description 12
- 239000003245 coal Substances 0.000 claims description 11
- 239000003345 natural gas Substances 0.000 claims description 11
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 7
- 229910021536 Zeolite Inorganic materials 0.000 claims description 7
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 7
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 7
- 239000004408 titanium dioxide Substances 0.000 claims description 7
- 239000010457 zeolite Substances 0.000 claims description 7
- 238000000889 atomisation Methods 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 23
- 229910052760 oxygen Inorganic materials 0.000 description 23
- 239000001301 oxygen Substances 0.000 description 23
- 230000000694 effects Effects 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 7
- 238000004891 communication Methods 0.000 description 5
- 238000000605 extraction Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000002828 fuel tank Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 238000004774 atomic orbital Methods 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052815 sulfur oxide Inorganic materials 0.000 description 2
- 210000003437 trachea Anatomy 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000003097 hole (electron) Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000003137 locomotive effect Effects 0.000 description 1
- 210000004072 lung Anatomy 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 150000002926 oxygen Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 238000007540 photo-reduction reaction Methods 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000013032 photocatalytic reaction Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
- F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN A CARRIER GAS OR AIR
- F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
- F23C13/08—Apparatus in which combustion takes place in the presence of catalytic material characterised by the catalytic material
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
Abstract
本發明揭露一種強化燃燒效率的方法及利用該方法的設備。該方法包 含步驟:(a)提供一催化助燃劑;(b)霧化該催化助燃劑;(c)將霧化後的該催化助燃劑與空氣混合以形成一混合霧氣;及(d)引導該混合霧氣進入一燃燒室維持在不低於攝氏300℃的燃燒溫度下與一燃料進行燃燒。 The invention discloses a method for enhancing combustion efficiency and a device using the method. The method package Including steps: (a) providing a catalytic combustion aid; (b) atomizing the catalytic combustion aid; (c) mixing the atomized catalytic combustion aid with air to form a mixed mist; and (d) guiding the mixing The mist enters a combustion chamber and is burned with a fuel at a combustion temperature not lower than 300 ° C.
Description
本發明關於一種強化燃燒效率的方法及應用該方法的設備,特別是一種可強化現有燃燒設備,如鍋爐、引擎等之燃燒效率的方法及應用該方法的設備。 The invention relates to a method for enhancing combustion efficiency and a device applying the method, in particular to a method capable of enhancing the combustion efficiency of an existing combustion device, such as a boiler, an engine, and the like, and a device applying the method.
燃燒釋放能量,人類藉由學習控制燃燒而獲得動力,從工業革命至今不斷地改進生活水準。然而,利益興起,弊端亦隨之。生活環境中,大至燃煤發電機,小到汽機車的引擎,在提供便捷的電力或動力的同時,也增加了廢熱與廢氣的排放。理想上,燃燒的廢氣最好只有水蒸氣與二氧化碳,這樣對於環境與人體健康的破壞最小。但因機器老化、燃料成分、燃燒環境等因素,前述設備產生的廢氣常包含一些未完全燃燒物,如碳氫化合物(HC)與一氧化碳(CO),以及有毒廢氣,如氮氧化物(NOx)與硫氧化物(SOx)。尤有甚者,這些排放廢氣還會夾帶一些重金屬或與空氣中塵埃結合,形成對人體氣管及肺部有害的細懸浮微粒(常聽見的PM2.5)。如果該些設備燃燒較有效率,因完全燃燒這些傷害人體及環境的物質也會產生的較少。 Combustion releases energy. Mankind gains power by learning to control combustion. It has continuously improved the standard of living since the Industrial Revolution. However, with the rise of benefits, the disadvantages also follow. In the living environment, as large as a coal-fired generator and as small as an engine of a steam locomotive, while providing convenient electricity or power, it also increases waste heat and exhaust emissions. Ideally, the only waste gas to burn is water vapor and carbon dioxide, so that it will have the least damage to the environment and human health. However, due to machine aging, fuel composition, combustion environment and other factors, the exhaust gas generated by the aforementioned equipment often contains some incomplete combustion materials, such as hydrocarbons (HC) and carbon monoxide (CO), and toxic exhaust gases, such as nitrogen oxides (NOx) With sulfur oxides (SOx). In particular, these emissions will also entrain some heavy metals or combine with airborne dust to form fine suspended particles that are harmful to the human trachea and lungs (PM2.5 often heard). If these devices burn more efficiently, fewer substances will be produced due to the complete combustion of these substances that harm the human body and the environment.
除了環境與健康,設備燃燒效率亦跟成本有關。舉例來說,軋鋼廠的一條產線一年所需要花費的重油,估算接近一億八千多萬。如果可以在 這個部份降低8%~20%的成本,一年計算下來將為企業節省1千4百4拾多萬到3千6百多萬。在微利時代中,這對於提升企業營收有著倍數以上的成長。因此,如何強化燃燒效率一直是相關產業致力研究的重點。 In addition to environment and health, the burning efficiency of equipment is also related to cost. For example, the heavy oil required for one production line of a rolling mill is estimated to be more than 180 million. If you can This part reduces the cost by 8% to 20%. Calculated in one year, it will save the company from 14.4 million to 36 million. In the era of low profits, this has more than doubled the growth of corporate revenue. Therefore, how to strengthen combustion efficiency has been the focus of research in related industries.
本段文字提取和編譯本發明的某些特點。其它特點將被揭露於後續段落中。其目的在涵蓋附加的申請專利範圍之精神和範圍中,各式的修改和類似的排列。 This paragraph extracts and compiles certain features of the invention. Other features will be revealed in subsequent paragraphs. Its purpose is to cover the spirit and scope of the scope of additional patent applications, with various modifications and similar arrangements.
本發明的一目的在於提供一種強化燃燒效率的方法,可應用於現有需要進行燃燒以運作的設備,外燃機(如鍋爐、氧化爐、加熱爐等…(、與內燃機(如汽車引擎、船隻引擎(上,在不改動該些設備的硬體架構下,讓燃燒更完全,進而節省燃料成本與減少有害燃燒廢氣產生。為此,該強化燃燒效率的方法包含步驟:(a)提供一催化助燃劑;(b)霧化該催化助燃劑;(c)將霧化後的該催化助燃劑與空氣混合以形成一混合霧氣;及(d)引導該混合霧氣進入一燃燒室與一燃料進行燃燒,並維持該燃燒室的燃燒溫度不低於攝氏300度。其中,該催化助燃劑的劑量與該燃料的用量間的比率落於一特定比率區間內;該催化助燃劑包含:二氧化鈦(TiO2)0.9至1.1重量份;乙二醇(ethylene glycol)68至72重量份;水(Water)21至25重量份;介面活性劑1.8至2.2重量份;及沸石粉(Zeolite)3.6至4.4重量份。 An object of the present invention is to provide a method for enhancing combustion efficiency, which can be applied to existing equipment that requires combustion to operate, external combustion engines (such as boilers, oxidation furnaces, heating furnaces, etc.) (and internal combustion engines (such as automobile engines, ships, etc.) Engine (above, without changing the hardware structure of these devices, the combustion is more complete, thereby saving fuel costs and reducing harmful combustion exhaust gas generation. For this reason, the method for enhancing combustion efficiency includes steps: (a) providing a catalyst (B) atomizing the catalytic combustion aid; (c) mixing the atomized catalytic combustion aid with air to form a mixed mist; and (d) guiding the mixed mist into a combustion chamber and a fuel for Combustion, and maintain the combustion temperature of the combustion chamber is not lower than 300 degrees Celsius. Among them, the ratio between the dosage of the catalytic accelerant and the amount of the fuel falls within a specific ratio interval; the catalytic accelerant includes: 2 ) 0.9 to 1.1 parts by weight; 68 to 72 parts by weight of ethylene glycol; 21 to 25 parts by weight of water; 1.8 to 2.2 parts by weight of a surfactant; and 3.6 to 4.4 parts by weight of zeolite powder Share
最好,該介面活性劑可為十二烷基硫酸钠(Sodium Dodecyl Sulfate)。 Preferably, the surfactant may be Sodium Dodecyl Sulfate.
依照本發明,若該燃料為重油,則該特定比率區間可為一公升催化助燃劑用於5,040公升至6,560公升重油。若該燃料為天然氣,則該特定比率區間可為一公升催化助燃劑用於5,040度至6,560度天然氣。若該燃料為煤,則該特定比率區間可為一公升催化助燃劑用於11.9公噸至13.1公噸煤。 According to the present invention, if the fuel is heavy oil, the specific ratio range may be one liter of catalytic combustion aid for 5,040 to 6,560 liters of heavy oil. If the fuel is natural gas, the specific ratio range may be one liter of catalytic combustion aid for 5,040 to 6,560 degrees of natural gas. If the fuel is coal, the specific ratio range may be one liter of catalytic combustion aid for 11.9 to 13.1 metric tons of coal.
本發明的另一目的在於依照前述的強化燃燒效率的方法,提供一種強化燃燒效率的設備。該設備包含:一催化助燃劑槽,用於裝盛一催化助燃劑;一霧化模組,與該催化助燃劑槽直接或間接連接,用以將該催化助燃劑槽內的催化助燃劑霧化,便與空氣混合以形成一混合霧氣;一傳輸氣管,傳輸該混合霧氣;及一燃燒室,包括:一入氣孔,與該傳輸氣管開口連接,用以接收該混合霧氣;一燃料入口,用以接收一燃料;一燃燒空間,該混合霧氣與該燃料在此處進行燃燒;及一排氣孔,用以將燃燒後廢氣排出燃燒室。其中,該燃燒室可維持燃燒溫度不低於攝氏300度;該催化助燃劑的劑量與該燃料的用量間的比率落於一特定比率區間內;該催化助燃劑包含:二氧化鈦0.9至1.1重量份;乙二醇68至72重量份;水21至25重量份;介面活性劑1.8至2.2重量份;及沸石粉3.6至4.4重量份。 Another object of the present invention is to provide a device for enhancing combustion efficiency according to the aforementioned method for enhancing combustion efficiency. The device includes: a catalytic accelerant tank for containing a catalytic accelerant; and an atomization module connected directly or indirectly to the catalytic accelerator tank to catalyze the catalytic accelerant mist in the catalytic accelerator tank It is mixed with air to form a mixed mist; a transmission gas pipe transmits the mixed mist; and a combustion chamber includes: an air inlet connected to the transmission gas pipe opening for receiving the mixed mist; a fuel inlet, It is used for receiving a fuel; a combustion space where the mixed mist and the fuel are burned; and an exhaust hole for exhausting the exhaust gas after combustion from the combustion chamber. The combustion chamber can maintain a combustion temperature of not less than 300 degrees Celsius; the ratio between the dosage of the catalytic combustion aid and the amount of the fuel falls within a specific ratio range; the catalytic combustion aid includes: 0.9 to 1.1 parts by weight of titanium dioxide 68 to 72 parts by weight of ethylene glycol; 21 to 25 parts by weight of water; 1.8 to 2.2 parts by weight of a surfactant; and 3.6 to 4.4 parts by weight of a zeolite powder.
最好,該介面活性劑可為十二烷基硫酸钠。 Preferably, the surfactant may be sodium lauryl sulfate.
依照本發明,若該燃料為重油,則該特定比率區間可為一公升催化助燃劑用於5,040公升至6560公升重油。若該燃料為天然氣,則該特定比率區間可為一公升催化助燃劑用於5,040度至6560度天然氣。若該燃料為煤,則該特定比率區間可為一公升催化助燃劑用於11.9公噸至13.1公噸煤。 According to the present invention, if the fuel is heavy oil, the specific ratio interval may be one liter of catalytic combustion aid for 5,040 liters to 6,560 liters of heavy oil. If the fuel is natural gas, the specific ratio range may be one liter of catalytic combustion aid for 5,040 to 6560 degrees of natural gas. If the fuel is coal, the specific ratio range may be one liter of catalytic combustion aid for 11.9 to 13.1 metric tons of coal.
依照本發明,由於催化助燃劑的負氧作用、富氧作用、原子空軌域填補作用與遠紅外線分解作用,於攝氏300度以上、380nm可見光照的環 境,以及控制催化助燃劑的劑量與燃料的用量間的比率,燃燒室內的燃燒就能較沒有使用本發明前更有效率。 According to the present invention, due to the negative oxygen effect, oxygen-enriched effect, atomic orbital filling effect, and far-infrared decomposition effect of the catalytic combustion accelerator, the visible light at a temperature of 300 degrees Celsius and 380 nm is visible. Environment, and controlling the ratio between the amount of catalytic accelerant and the amount of fuel, the combustion in the combustion chamber can be more efficient than before the invention was not used.
10‧‧‧催化助燃劑槽 10‧‧‧catalytic combustion tank
12‧‧‧催化助燃劑連通管 12‧‧‧Catalyst accelerant communication pipe
100‧‧‧催化助燃劑 100‧‧‧catalytic combustion accelerator
120‧‧‧外部空氣 120‧‧‧ outside air
140‧‧‧混合霧氣 140‧‧‧ mixed mist
160‧‧‧廢氣 160‧‧‧ exhaust gas
20‧‧‧霧化模組 20‧‧‧Atomization module
22‧‧‧進量控制馬達 22‧‧‧Feed control motor
24‧‧‧霧化器 24‧‧‧ Atomizer
30‧‧‧抽氣模組 30‧‧‧Exhaust Module
32‧‧‧傳輸氣管 32‧‧‧Transmission trachea
32a‧‧‧開口 32a‧‧‧ opening
40‧‧‧燃燒室 40‧‧‧Combustion chamber
42‧‧‧入氣孔 42‧‧‧air inlet
44‧‧‧燃料入口 44‧‧‧ Fuel inlet
46‧‧‧燃燒空間 46‧‧‧burning space
48‧‧‧排氣孔 48‧‧‧Vent
50‧‧‧燃料槽 50‧‧‧ fuel tank
52‧‧‧燃料連通管 52‧‧‧Fuel connecting pipe
500‧‧‧燃料 500‧‧‧ fuel
圖1為依照本發明實施例的一種強化燃燒效率的方法之流程圖;圖2為依照本發明的另一實施例的一種強化燃燒效率的設備之示意圖;圖3為依照本發明的又一實施例的一種強化燃燒效率的設備之示意圖。 FIG. 1 is a flowchart of a method for enhancing combustion efficiency according to an embodiment of the present invention; FIG. 2 is a schematic diagram of a device for enhancing combustion efficiency according to another embodiment of the present invention; and FIG. 3 is another implementation according to the present invention A schematic diagram of an example of a device for enhancing combustion efficiency.
本發明將藉由參照下列的實施方式而更具體地描述。 The present invention will be described more specifically by referring to the following embodiments.
請見圖1,該圖為依照本發明實施例的一種強化燃燒效率的方法之流程圖。這裡,強化燃燒效率是要讓燃料在不變動燃燒空氣供應的方式下(比如空氣壓縮以增加單位體積含氧量)讓燃料燃燒得更完全,更接近燃燒後元素為水與二氧化碳的目的。該方法首先提供一催化助燃劑(S01)。催化助燃劑是本方法的核心要素,以下茲將其成份與用途進行說明。 Please refer to FIG. 1, which is a flowchart of a method for enhancing combustion efficiency according to an embodiment of the present invention. Here, the enhanced combustion efficiency is to allow the fuel to burn more completely without compromising the supply of combustion air (such as air compression to increase the oxygen content per unit volume), closer to the purpose of the elements being water and carbon dioxide after combustion. The method first provides a catalytic combustion accelerator (S01). The catalytic combustion accelerator is the core element of this method, and its components and uses are described below.
整體而言,經過無數次的試驗及修改配比,催化助燃劑的成分可包含:二氧化鈦(TiO2)0.9至1.1重量份;乙二醇(ethylene glycol)68至72重量份;水(Water)21至25重量份;介面活性劑1.8至2.2重量份;及沸石粉(Zeolite)3.6至4.4重量份。一個比較好的實施態樣是二氧化鈦1重量份、乙二醇70重量份、水23重量份、介面活性劑2重量份及沸石粉4重量份。其它比例的配方,只要落在前述的範圍內,都可以達到強化燃燒效率的目的而為本發明所主張。實作上,介面活性劑可以使用十二烷基硫酸钠(Sodium Dodecyl Sulfate)。 In general, after countless tests and modification of the ratio, the components of the catalytic combustion accelerator may include: 0.9 to 1.1 parts by weight of titanium dioxide (TiO2); 68 to 72 parts by weight of ethylene glycol; and Water 21 To 25 parts by weight; surfactant to 1.8 to 2.2 parts by weight; and Zeolite 3.6 to 4.4 parts by weight. A better embodiment is 1 part by weight of titanium dioxide, 70 parts by weight of ethylene glycol, 23 parts by weight of water, 2 parts by weight of a surfactant, and 4 parts by weight of zeolite powder. Formulas of other proportions, as long as they fall within the aforementioned range, can achieve the purpose of enhancing combustion efficiency and are claimed by the present invention. In practice, the surfactant can be sodium dodecyl sulfate (Sodium Dodecyl Sulfate).
由於催化助燃劑具有上述的成分,因此可以在協助燃料(可以是固態的,比如煤、是液態的,比如重油或汽油,甚至是氣態的,比如天然氣)燃燒時,增加氧氣含量,藉以強化燃燒效率。催化助燃劑增加氧氣含量以強化燃燒效率主要藉由以下幾種作用。 Because the catalytic combustion accelerator has the above-mentioned components, it can increase the oxygen content when assisting the combustion of fuels (which can be solid, such as coal, liquid, such as heavy oil or gasoline, or even gaseous, such as natural gas) to enhance combustion. effectiveness. Catalytic combustion accelerators increase the oxygen content to enhance combustion efficiency mainly through the following effects.
第一、負氧作用。二氧化鈦為種光觸媒原子,在燃燒室內經380nm可見光照射後(一般燃燒都會產生380nm的可見光),電子電洞對(原子)中的電子(帶負電)吸收能量而穿越3.2eV之能隙至導電帶,因電子的光還原(Photo Reduction)作用,使氧變成帶負電之活潑性很高的氧,即活性氧(Activated Oxygen),留在原地(價電帶)之電洞(帶正電),因為電洞的光氧化(Photo Oxidation)作用(汽態),電洞會和二氧化鈦表面上的OH反應(氧化),生成氧化性很高的OH-自由基。活潑的OH-自由基和帶負電之活潑性很高的氧,會把有機物(碳氫化合物)分解,重新降解成為二氧化碳和水。 First, negative oxygen effect. Titanium dioxide is This kind of photocatalyst atom, after being irradiated with visible light at 380nm in the combustion chamber (commonly, visible light at 380nm is generated), the electron hole (electron) in the (atom) absorbs energy and crosses the energy gap of 3.2eV to the conductive band. The photo-reduction effect of the electrons makes the oxygen become highly reactive oxygen with negative charge, that is, Activated Oxygen, which stays in the hole (positive charge) in the place (valence band) because the electricity Photo Oxidation (Vapor state) of holes, holes will react (oxidize) with OH on the surface of titanium dioxide to generate highly oxidizing OH - radicals. Active OH - radicals and negatively charged, highly reactive oxygen will decompose organic matter (hydrocarbons) and degrade into carbon dioxide and water again.
第二、富氧作用。空氣的組成主要是由78%的氮氣、21%的氧氣及1%的稀有氣體和雜質組成的混合物。一般的自然燃燒狀態下,氧氣濃度為21%。如果用比自然狀態下,含氧量高的空氣作為助燃空氣時,即為富氧燃燒。由負氧作用得知帶負電之活潑性很高的氧會與碳氫化合物完全燃燒降解成二氧化碳和水,另電極板效應(水的電解電位為1.23V)又將水(汽態)還原為H+與OH-,如此周而復始循環。依實驗得知,可增加2%~5%的含氧量,此即所謂的富氧作用。此外,伴隨著富氧作用,理論空氣需要量減少,且可提升燃燒時的火焰溫度。此亦為強化燃燒效率之因子。 Second, oxygen enrichment. The composition of air is mainly a mixture of 78% nitrogen, 21% oxygen, and 1% rare gases and impurities. Under normal natural combustion conditions, the oxygen concentration is 21%. If air with higher oxygen content than the natural state is used as combustion air, it will be oxygen-enriched combustion. It is known from the negative oxygen effect that the highly charged and highly reactive oxygen will be completely combusted with hydrocarbons to degrade into carbon dioxide and water. In addition, the electrode plate effect (the electrolysis potential of water is 1.23V) reduces water (vapor state) to H + and OH - cycle again and again. According to the experiments, it can increase the oxygen content of 2% to 5%, which is the so-called oxygen-rich effect. In addition, with the enrichment of oxygen, the theoretical air requirement is reduced and the flame temperature during combustion can be increased. This is also a factor for enhancing combustion efficiency.
第三、原子空軌域填補作用。氮的電子序為7,以學理的角度進行說明。1S2S2P在第二層應該要有4個軌域、8個電子,而氮氣含有7個電子(亦及第層有2個電子、第二層有5個電子)。但以第二層的軌域數來看,應該要達到8個電子才會穩定,但卻少掉3個電子(即所稱的空軌域)。本發明可 利用所產生的電子,將原先空軌域進行填補,使氮達到穩定的狀態,而不與氧氣結合,進而減少NOx產生的機率。但因本發明尚有富氧的效果,因此除了空軌域的機制之外,在氧氣足夠的前提之下,還可降低進風量,減少過多的氮氣,以增進燃燒效率。 Third, the role of atomic orbital filling. The electronic order of nitrogen is 7, which is explained from a scientific point of view. 1S2S2P should have 4 orbitals and 8 electrons in the second layer, and nitrogen contains 7 electrons (also Layer has 2 electrons and the second layer has 5 electrons). However, in terms of the number of orbital domains in the second layer, 8 electrons should be stable before 3 electrons are missing (the so-called empty orbital domain). The invention can use the generated electrons to fill the original empty orbital region to make nitrogen reach a stable state without combining with oxygen, thereby reducing the probability of NOx generation. However, because the present invention still has an oxygen-enriched effect, in addition to the mechanism of the empty orbit area, under the premise of sufficient oxygen, the amount of air intake can be reduced and excessive nitrogen can be reduced to improve combustion efficiency.
第四、遠紅外線分解作用。本發明的催化助燃劑,在電解出氧氣的同時,亦會產生遠紅外線,利用碳分子膨脹係數不同的特性產生磨擦,進而將燃燒室內的結焦與結渣,溫和的進行分解並參與燃燒,以增進燃燒效率。 Fourth, far infrared decomposition. The catalytic combustion accelerator of the present invention also generates far-infrared rays while electrolyzing oxygen, and uses friction characteristics of different expansion coefficients of carbon molecules to generate friction, thereby further coking and slagging in the combustion chamber to gently decompose and participate in combustion, so that Improve combustion efficiency.
由以上的說明,可以很清楚知道催化助燃劑的功能。從而,為了最佳化催化助燃劑的使用,本發明提出的強化燃燒效率的方法的第二個步驟是霧化該催化助燃劑(S02)。霧化的方式很多元,比如以高週波對催化助燃劑液面進行震盪以產生霧化效果、採用傳統霧化噴嘴進行霧化,或是利用加熱的方式進行霧化,都是可行的方式。重點是要能讓催化助燃劑霧化後有效散佈於空氣中。接著,將霧化後的該催化助燃劑與空氣混合以形成一混合霧氣(S03)。最終,引導該混合霧氣進入一燃燒室與一燃料進行燃燒,並維持該燃燒室的燃燒溫度不低於攝氏300度,其維持燃燒溫度不低於攝氏300度的目的是要讓二氧化鈦在奈米結構下,能順利進行光觸媒反應。 From the above description, the function of the catalytic accelerant can be clearly understood. Therefore, in order to optimize the use of the catalytic accelerant, the second step of the method for enhancing combustion efficiency proposed by the present invention is to atomize the catalytic accelerant (S02). There are many ways to atomize, such as oscillating the liquid level of the catalytic accelerant with a high frequency to produce an atomizing effect, atomizing with a conventional atomizing nozzle, or atomizing by heating, which are all feasible methods. The important point is to enable the catalytic combustion promoter to be effectively dispersed in the air after being atomized. Next, the atomized catalytic combustion accelerator is mixed with air to form a mixed mist (S03). Finally, the mixed mist is guided into a combustion chamber for combustion with a fuel, and the combustion temperature of the combustion chamber is not lower than 300 degrees Celsius, and the purpose of maintaining the combustion temperature is not lower than 300 degrees Celsius is to make titanium dioxide in the nanometer Under the structure, the photocatalytic reaction can be performed smoothly.
另外,催化助燃劑的劑量與該燃料的用量間的比率落於一特定比率區間內,也就是使用的催化助燃劑的劑量有一定的限制,過多或太少都不會強化燃燒效率。藉由實驗的結果可知,該特定比率區間因燃料的不同而異。舉例來說,若燃料為重油,則該特定比率區間為一公升催化助燃劑用於5,040公升至6,560公升重油;燃料為天然氣,則該特定比率區間為一公升催化助燃劑用於5,040度至6,560度天然氣;若該燃料為煤,則該特定比率區間為一公升催化助燃劑用於11.9公噸至13.1公噸煤。 In addition, the ratio between the dosage of the catalytic accelerant and the amount of the fuel falls within a specific ratio interval, that is, the dosage of the catalytic accelerant used is limited, and too much or too little will not enhance combustion efficiency. From the results of the experiment, it can be known that the specific ratio interval varies depending on the fuel. For example, if the fuel is heavy oil, the specific ratio range is one liter of catalytic combustion aid for 5,040 liters to 6,560 liters of heavy oil; when the fuel is natural gas, the specific ratio range is one liter of catalytic combustion aid for 5,040 degrees to 6,560. Natural gas; if the fuel is coal, the specific ratio range is one liter of catalytic combustion aid for 11.9 to 13.1 metric tons of coal.
本發明另提出一種強化燃燒效率的設備。請見圖2,該圖為該設備的實施例的之示意圖。該強化燃燒效率的設備包含了:一催化助燃劑槽10、一霧化模組20、一抽氣模組30、一燃燒室40、一燃料槽50、連接催化助燃劑槽10與霧化模組20的一催化助燃劑連通管12、連接抽氣模組30與燃燒室40的一傳輸氣管32,及連接燃料槽50與燃燒室40的一燃料連通管52。 The invention also proposes a device for enhancing combustion efficiency. Please refer to FIG. 2, which is a schematic diagram of an embodiment of the device. The equipment for enhancing combustion efficiency includes: a catalytic combustion aid tank 10, an atomization module 20, an extraction module 30, a combustion chamber 40, a fuel tank 50, and a connection between the catalytic combustion aid tank 10 and the atomization mold. A catalytic accelerant communication pipe 12 of the group 20, a transmission gas pipe 32 connecting the extraction module 30 and the combustion chamber 40, and a fuel communication pipe 52 connecting the fuel tank 50 and the combustion chamber 40.
催化助燃劑槽10,顧名思義,用於裝盛催化助燃劑100。催化助燃劑100的流動可以靠重力,也可以加壓為之。霧化模組20與該催化助燃劑槽10靠催化助燃劑連通管12間接連接。實作上,兩者也可以直接相連。霧化模組20可用以將催化助燃劑槽10內的催化助燃劑100霧化,並與空氣混合以形成一混合霧氣。霧化模組20可進一步包含兩元件:一進量控制馬達22與一霧化器24。進量控制馬達22可以控制單位時間被霧化的催化助燃劑100的量,也就是維持前一實施例中所說的催化助燃劑100的劑量與燃料的用量間的比率落於一特定比率區間內。霧化器24則執行霧化,並將霧化後的催化助燃劑100受傳輸氣管32內的負壓而向傳輸氣管32的一開口32a移動,以便與傳輸氣管32一方來的空氣(細空心箭號)混合形成混合霧氣(開口32a旁之雲霧狀)。 The catalytic accelerant tank 10, as the name suggests, is used to hold the catalytic accelerant 100. The flow of the catalytic combustion aid 100 may be by gravity or it may be pressurized. The atomizing module 20 is indirectly connected to the catalytic accelerant tank 10 via a catalytic accelerant communication pipe 12. In practice, the two can also be directly connected. The atomizing module 20 can be used to atomize the catalytic combustion accelerator 100 in the catalytic combustion tank 10 and mix with the air to form a mixed mist. The atomizing module 20 may further include two components: a feed control motor 22 and an atomizer 24. The feed amount control motor 22 can control the amount of the catalytic accelerant 100 that is atomized per unit time, that is, to maintain the ratio between the dosage of the catalytic accelerant 100 and the amount of fuel in the previous embodiment falling within a specific ratio interval Inside. The atomizer 24 performs atomization, and moves the atomized catalytic combustion aid 100 to an opening 32a of the transmission gas pipe 32 under the negative pressure in the transmission gas pipe 32 so as to communicate with the air (fine hollow from the transmission gas pipe 32) (Arrow) is mixed to form a mixed mist (cloudy mist shape near the opening 32a).
抽氣模組30可以是任何一種有負壓的設備(例如:抽風機、鼓風機、吸風口等),將設備的外部空氣120(粗空心箭號)引入輸氣管32中,以傳送到燃燒室40中與燃料500進行燃燒。傳輸氣管32過了開口32a,用以傳輸該混合霧氣140(細空心虛箭號)。 The extraction module 30 can be any type of equipment with negative pressure (for example: exhaust fan, blower, air inlet, etc.). The external air 120 (thick hollow arrow) of the equipment is introduced into the gas pipe 32 for transmission to the combustion chamber 40 is burned with fuel 500. The transfer gas pipe 32 passes through the opening 32a for transferring the mixed mist 140 (fine hollow virtual arrow).
燃燒室40包括了一入氣孔42、一燃料入口44、燃燒空間46及一排氣孔48。入氣孔42與傳輸氣管32的開口連接,用以接收該混合霧氣140。燃料入口44用以接收燃料500。在本例中,燃料500是靠燃料連通管52來接收的,燃料500的流動是靠重力或壓力則不限定。燃燒空間46(虛線框所繪示)是燃燒發生的場所,燃料500與混合霧氣140經初步混合後即在此處進行燃燒。當 然,這裡所謂的燃燒,其程度較劇烈者可能以爆炸形式呈現。排氣孔48可將燃燒後的廢氣160排出燃燒室40。實作上,燃燒室40的形式可能是個鍋爐、引擎等需要燃燒燃料運作的裝置。 The combustion chamber 40 includes an air inlet 42, a fuel inlet 44, a combustion space 46 and an exhaust hole 48. The air inlet 42 is connected to the opening of the transmission air pipe 32 for receiving the mixed mist 140. The fuel inlet 44 is used to receive the fuel 500. In this example, the fuel 500 is received by the fuel communication pipe 52, and the flow of the fuel 500 is not limited by gravity or pressure. The combustion space 46 (shown by the dotted frame) is the place where the combustion occurs, and the fuel 500 and the mixed mist 140 are burned here after being initially mixed. when Of course, the so-called burning here may be more explosive in the form of an explosion. The exhaust hole 48 can discharge the exhaust gas 160 after combustion to the combustion chamber 40. In practice, the form of the combustion chamber 40 may be a device such as a boiler, an engine, etc. that needs to operate by burning fuel.
如同前一實施例所介紹,燃燒室40可維持燃燒溫度不低於攝氏300度。催化助燃劑100的劑量與燃料500的用量間的比率也落與前述的特定比率區間內。催化助燃劑100包含:二氧化鈦0.9至1.1重量份;乙二醇68至72重量份;水21至25重量份;介面活性劑1.8至2.2重量份;及沸石粉3.6至4.4重量份。該介面活性劑最好是十二烷基硫酸钠。 As described in the previous embodiment, the combustion chamber 40 can maintain the combustion temperature not lower than 300 degrees Celsius. The ratio between the amount of the catalytic combustion aid 100 and the amount of the fuel 500 also falls within the specific ratio range described above. The catalytic combustion accelerator 100 includes: 0.9 to 1.1 parts by weight of titanium dioxide; 68 to 72 parts by weight of ethylene glycol; 21 to 25 parts by weight of water; 1.8 to 2.2 parts by weight of a surfactant; and 3.6 to 4.4 parts by weight of a zeolite powder. The surfactant is preferably sodium lauryl sulfate.
以上的實施例中揭露的強化燃燒效率的設備適用於內燃機,比如車子的引擎;若要應用於外燃機,比如鍋爐上,強化燃燒效率的設備元件可以改為如圖3所示一般。相較於圖2,圖3中的傳輸氣管32沒有開口32a,霧化器24也不再連接開口32a。取而代之的是霧化器24開口直接對上抽氣模組30,霧化的催化助燃劑利用抽氣模組30與設備的外部空氣120混合,之後再送入燃燒室40。 The equipment for enhancing combustion efficiency disclosed in the above embodiments is suitable for internal combustion engines, such as the engine of a car; if it is to be applied to an external combustion engine, such as a boiler, the components of the equipment for enhancing combustion efficiency can be changed to general as shown in FIG. 3. Compared to FIG. 2, the transmission air pipe 32 in FIG. 3 has no opening 32 a, and the atomizer 24 is no longer connected to the opening 32 a. Instead, the opening of the atomizer 24 directly faces the extraction module 30, and the atomized catalytic combustion aid is mixed with the external air 120 of the device by using the extraction module 30 and then sent to the combustion chamber 40.
雖然本發明已以實施方式揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 Although the present invention has been disclosed as above in the embodiments, it is not intended to limit the present invention. Any person with ordinary knowledge in the technical field can make some modifications and retouching without departing from the spirit and scope of the present invention. The protection scope of the present invention shall be determined by the scope of the attached patent application.
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