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TWI672695B - Non-volatile transistor element including a buried ferroelectric material based storage mechanism - Google Patents

Non-volatile transistor element including a buried ferroelectric material based storage mechanism Download PDF

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TWI672695B
TWI672695B TW107114780A TW107114780A TWI672695B TW I672695 B TWI672695 B TW I672695B TW 107114780 A TW107114780 A TW 107114780A TW 107114780 A TW107114780 A TW 107114780A TW I672695 B TWI672695 B TW I672695B
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storage
channel region
storage mechanism
ferroelectric material
transistor
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TW201909175A (en
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史蒂芬 杜恩柯爾
拉夫 尹葛恩
瑞夫 理查
索倫 傑生
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美商格芯(美國)集成電路科技有限公司
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    • G11INFORMATION STORAGE
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    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/21Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using electric elements
    • G11C11/22Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using electric elements using ferroelectric elements
    • G11C11/225Auxiliary circuits
    • HELECTRICITY
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    • H10BELECTRONIC MEMORY DEVICES
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    • H10B43/30EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/005Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor comprising combined but independently operative RAM-ROM, RAM-PROM, RAM-EPROM cells
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/21Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using electric elements
    • G11C11/22Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using electric elements using ferroelectric elements
    • G11C11/223Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using electric elements using ferroelectric elements using MOS with ferroelectric gate insulating film
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/21Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using electric elements
    • G11C11/22Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using electric elements using ferroelectric elements
    • G11C11/225Auxiliary circuits
    • G11C11/2275Writing or programming circuits or methods
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C11/00Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/56Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using storage elements with more than two stable states represented by steps, e.g. of voltage, current, phase, frequency
    • G11C11/5657Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using storage elements with more than two stable states represented by steps, e.g. of voltage, current, phase, frequency using ferroelectric storage elements
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C16/00Erasable programmable read-only memories
    • G11C16/02Erasable programmable read-only memories electrically programmable
    • G11C16/04Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS
    • G11C16/0466Erasable programmable read-only memories electrically programmable using variable threshold transistors, e.g. FAMOS comprising cells with charge storage in an insulating layer, e.g. metal-nitride-oxide-silicon [MNOS], silicon-oxide-nitride-oxide-silicon [SONOS]
    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C16/00Erasable programmable read-only memories
    • G11C16/02Erasable programmable read-only memories electrically programmable
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    • GPHYSICS
    • G11INFORMATION STORAGE
    • G11CSTATIC STORES
    • G11C16/00Erasable programmable read-only memories
    • G11C16/02Erasable programmable read-only memories electrically programmable
    • G11C16/06Auxiliary circuits, e.g. for writing into memory
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    • HELECTRICITY
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    • H10BELECTRONIC MEMORY DEVICES
    • H10B51/00Ferroelectric RAM [FeRAM] devices comprising ferroelectric memory transistors
    • H10B51/30Ferroelectric RAM [FeRAM] devices comprising ferroelectric memory transistors characterised by the memory core region
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    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/69IGFETs having charge trapping gate insulators, e.g. MNOS transistors
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    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/701IGFETs having ferroelectric gate insulators, e.g. ferroelectric FETs
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D30/00Field-effect transistors [FET]
    • H10D30/60Insulated-gate field-effect transistors [IGFET]
    • H10D30/711Insulated-gate field-effect transistors [IGFET] having floating bodies
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D64/00Electrodes of devices having potential barriers
    • H10D64/01Manufacture or treatment
    • H10D64/031Manufacture or treatment of data-storage electrodes
    • H10D64/033Manufacture or treatment of data-storage electrodes comprising ferroelectric layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10DINORGANIC ELECTRIC SEMICONDUCTOR DEVICES
    • H10D64/00Electrodes of devices having potential barriers
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    • H10D64/031Manufacture or treatment of data-storage electrodes
    • H10D64/037Manufacture or treatment of data-storage electrodes comprising charge-trapping insulators

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Abstract

本揭露提供儲存元件,例如儲存電晶體,其中,基於在SOI電晶體架構的埋藏絕緣層中所形成的鐵電材料提供至少一個儲存機制。在另外的示例實施例中,在該閘極電極結構中實施一個另外的儲存機制,以提供增加的總體資訊密度。在一些示例實施例中,該閘極電極結構中的該儲存機制以鐵電材料形式提供。 The present disclosure provides a storage element, such as a storage transistor, wherein at least one storage mechanism is provided based on the ferroelectric material formed in the buried insulating layer of the SOI transistor architecture. In a further exemplary embodiment, an additional storage mechanism is implemented in the gate electrode structure to provide an increased overall information density. In some example embodiments, the storage mechanism in the gate electrode structure is provided in the form of a ferroelectric material.

Description

包含基於埋藏鐵電材料之儲存機制的非揮發性電晶體元件  a non-volatile transistor element comprising a storage mechanism based on buried ferroelectric materials  

本揭露通常關於利用鐵電材料的特性在電路元件例如場效應電晶體中設置非揮發性儲存機制(non-volatile storage mechanism)的技術。 The present disclosure generally relates to techniques for utilizing the characteristics of ferroelectric materials to provide a non-volatile storage mechanism in circuit elements such as field effect transistors.

在許多類型的電子元件中,可能必須實施資料儲存技術以保證相應技術系統的正常功能。例如,在許多應用中,必須處理並因此儲存不同類型的資訊,其通常基於數位資料實施。基本的資訊實體可被視為如下實體:能夠呈現不同的邏輯狀態,從而在硬體中的相應邏輯狀態的實施需要能夠“佔據”相應不同的物理狀態例如不同的電壓狀態、電流狀態等的合適電子配置,其相應地可適當地與該相應邏輯狀態關聯。 In many types of electronic components, data storage techniques may have to be implemented to ensure proper functioning of the corresponding technical system. For example, in many applications, different types of information must be processed and therefore stored, which is typically implemented based on digital data. A basic information entity can be viewed as an entity that is capable of presenting different logical states such that implementation of a corresponding logical state in the hardware requires the ability to "occupy" a correspondingly different physical state, such as a different voltage state, current state, etc. An electronic configuration, which can accordingly be associated with the respective logical state.

因此,當提供合適的電子架構時,可有效檢測這些不同的物理狀態(在複雜積體電路中主要以不同的電子狀態形式實施),以允許可靠地檢測相應不同的特 性,例如電容器的電荷狀態,相應導體例如場效應電晶體的溝道區(channel region)中的電流量等。因此,當適當操控相應電子特性例如電荷狀態、電流驅動能力等時,可將相應電子狀態以及因此邏輯狀態程式設計於下方電子結構中,其中,依據基本電子結構的總體配置,該相應電子特性以及因此該邏輯狀態可經程式設計以永久儲存,也就是,在關閉電源供應並向相應結構重新供電以後,該相應電子特性可被有效恢復,而在其它情況下,該相應電子特性以及因此與其關聯的邏輯狀態僅可在供應電壓存在時獲得,而在關閉該供應電壓時,相應資訊可能丟失。前面的儲存機制也可被稱為“非揮發性”,而在本案的上下文中,此術語可主要用以說明儲存機制,與資訊的相應程式設計可能是基於在基本不可逆的過程基礎上實施的一次性程式的機制相比,該“非揮發性”儲存機制還可允許經常性地重新程式設計相應儲存機制。為實施如上所定義的非揮發性儲存機制以及揮發性儲存機制,多種多樣的電子配置例如寄存器、儲存單元、儲存電晶體等為現有技術所熟知,其中,各種類型的儲存結構可呈現特定的操作優點及缺點。 Thus, when a suitable electronic architecture is provided, these different physical states (implemented primarily in different electronic states in complex integrated circuits) can be effectively detected to allow reliable detection of corresponding different characteristics, such as the state of charge of the capacitor. The corresponding conductor, such as the amount of current in the channel region of the field effect transistor, and the like. Therefore, when appropriate electronic characteristics such as charge state, current drive capability, etc. are appropriately manipulated, the corresponding electronic state, and thus the logic state, can be programmed into the lower electronic structure, wherein the corresponding electronic properties are based on the overall configuration of the basic electronic structure and Thus the logic state can be programmed to be permanently stored, that is, after the power supply is turned off and re-powered to the corresponding structure, the corresponding electronic characteristic can be effectively recovered, and in other cases, the corresponding electronic characteristic and thus associated with it The logic state can only be obtained when the supply voltage is present, and the corresponding information may be lost when the supply voltage is turned off. The previous storage mechanism may also be referred to as "non-volatile", and in the context of this case, the term may be used primarily to describe the storage mechanism, and the corresponding programming of the information may be based on a substantially irreversible process. This "non-volatile" storage mechanism also allows for frequent re-programming of the corresponding storage mechanism as compared to the one-time program mechanism. To implement the non-volatile storage mechanisms and volatile storage mechanisms as defined above, a wide variety of electronic configurations such as registers, storage units, storage transistors, and the like are well known in the art, wherein various types of storage structures can present particular operations. Advantages and disadvantages.

例如,若要在電子裝置例如電腦、微處理器等中臨時儲存大量資料,則可能需要頻繁存取該資料。如果極高的存取速度不是最優先的,則可能經常使用所謂的“動態儲存裝置器”,該動態儲存裝置器可被有效實施為需要單個儲存電容器及一個電晶體以實現單位資訊的積體電路區域。在此方面,單位資訊將被理解為能夠假定兩種 不同的電子狀態的任意電子機制,該兩種不同的電子狀態相應地與兩種不同的邏輯狀態關聯。由於在相應儲存電容器中的電荷必須定期刷新的事實,且由於需要在程式設計相應儲存電容器時遷移較高的電荷量,因此與所謂的“靜態記憶體結構”相比,可實現的延遲較大。在這些靜態記憶體結構中,特定的邏輯狀態可由電路元件例如電晶體的導電狀態確定,且該邏輯狀態的變化通過改變該電路元件的狀態實施,從而實現基本上由相關電路元件的開關時間確定的延遲。因此,在此情況下,靜態記憶體單元的邏輯狀態的改變可在所考慮的技術節點的相應電晶體元件的開關時間的量級上實施。儘管上述儲存技術可代表容易實施於任意類型的積體電路中的高效機制,但由於此機制的揮發性本質而使資料儲存被限制於向裝置供應電壓的次數,因為任何資訊都在切斷該供應電壓時丟失。 For example, if a large amount of data is to be temporarily stored in an electronic device such as a computer, a microprocessor, or the like, it may be necessary to frequently access the material. If extremely high access speeds are not the most preferred, so-called "dynamic storage devices" may often be used, which can be effectively implemented as a single storage capacitor and a transistor to achieve unit information integration. Circuit area. In this regard, unit information will be understood as any electronic mechanism capable of assuming two different electronic states, which are associated with two different logic states, respectively. Due to the fact that the charge in the corresponding storage capacitor must be periodically refreshed, and because of the need to migrate a higher amount of charge when programming the corresponding storage capacitor, the achievable delay is greater compared to the so-called "static memory structure" . In these static memory structures, a particular logic state can be determined by the conductive state of a circuit component, such as a transistor, and the change in logic state is implemented by changing the state of the circuit component such that substantially the switching time of the associated circuit component is determined. Delay. Thus, in this case, the change in the logic state of the static memory cells can be implemented on the order of the switching time of the respective transistor elements of the technology node under consideration. Although the above described storage techniques may represent an efficient mechanism that is easily implemented in any type of integrated circuit, due to the volatile nature of this mechanism, data storage is limited to the number of times the voltage is supplied to the device, since any information is cutting off the Lost when supplying voltage.

由於邏輯狀態的永久儲存(結合其可程式設計能力)常常是必要的,因此已開發許多非揮發性資料儲存技術,其中,尤其,基於磁儲存裝置的許多大容量儲存系統、光儲存技術等由於在硬體及軟體方面尤其是較長的存取時間方面的大量開銷而可能不與多個應用相容。因此,為實施非揮發性儲存機制已作了大量的努力,以補充或替代時間效率較低的儲存結構。例如,可使用快閃記憶體作為非揮發性儲存結構,其中,在電晶體配置中使用具有可被動態重新配置的可能性的經適當設計的電容結構,以專門影響電晶體特性,例如閾值(threshold)電壓等。 Since permanent storage of logic states (in combination with their programmable capabilities) is often necessary, many non-volatile data storage technologies have been developed, in particular, many large-capacity storage systems based on magnetic storage devices, optical storage technologies, etc. due to A large amount of overhead in terms of hardware and software, especially long access times, may not be compatible with multiple applications. Therefore, a great deal of effort has been made to implement non-volatile storage mechanisms to supplement or replace time-efficient storage structures. For example, flash memory can be used as a non-volatile storage structure in which a suitably designed capacitive structure with the potential to be dynamically reconfigured is used in the transistor configuration to specifically affect transistor characteristics, such as thresholds ( Threshold) voltage, etc.

場效應電晶體的閾值電壓可被理解為施加於溝道區的部分上的裝置特定電壓,以實現該溝道區的電流驅動能力的顯著改變。例如,該閾值電壓可代表一點:在該點,當沒有或僅有很低的電壓施加於該溝道區的各端子(通常被稱為源漏端子或區)之間時,控制電壓的進一步增加可導致經過溝道區的電流的顯著增加或溝道電阻的顯著降低。 The threshold voltage of a field effect transistor can be understood as a device specific voltage applied to a portion of the channel region to achieve a significant change in the current drive capability of the channel region. For example, the threshold voltage can represent a point at which further control voltage is applied when no or only a very low voltage is applied between the terminals of the channel region (commonly referred to as source/drain terminals or regions). The increase can result in a significant increase in current through the channel region or a significant decrease in channel resistance.

例如,在快閃記憶體中所使用的上述儲存機制中,可將電荷載流子注入電晶體溝道附近的介電材料中或自其移除,以基於該介電材料內的該電荷載流子控制電晶體特性。也就是說,注入該介電材料中的電荷載流子的存在或不存在可例如以相應閾值電壓的形式顯著影響該溝道區,從而有效地允許在操作該電晶體時檢測電晶體特性的差異。因此,電容配置的特定狀態(包括具有變化的線電荷載流子的介電材料)可反映所需的邏輯狀態且因此可被有效“讀出”。另一方面,通過改變介電材料中的電荷載流子的量,可在其中儲存所需的邏輯狀態,這通常通過建立特定的操作環境實施,以注入或移除該線電荷載流子。以此方式,單個電晶體可足以儲存單位資訊,從而顯著地促進電子可程式設計非揮發性儲存裝置的優越的資訊密度。儘管快閃記憶體結構的此類儲存電晶體(其中,可自該電晶體的閘極電性結構的特定部分捕獲或釋放電荷)可代表儲存單位資訊的很有效的解決方案,但結果表明,尤其,先進半導體裝置的不斷微縮可能導致較大的困難。例如, 此類儲存電晶體的總體閘極尺寸的進一步縮小可能需要高度複雜的技術來形成相應的閘極電極結構。因此,實施此類浮置閘極類型儲存電晶體可導致較大的挑戰,從而需要額外的努力並增加製程的複雜性。 For example, in the above described storage mechanism used in flash memory, charge carriers can be injected into or removed from a dielectric material near the channel of the transistor to be based on the charge within the dielectric material. The flow control controls the characteristics of the transistor. That is, the presence or absence of charge carriers injected into the dielectric material can significantly affect the channel region, for example, in the form of respective threshold voltages, thereby effectively allowing detection of transistor characteristics when operating the transistor. difference. Thus, the particular state of the capacitor configuration (including dielectric materials with varying line charge carriers) can reflect the desired logic state and can therefore be effectively "read". Alternatively, by varying the amount of charge carriers in the dielectric material, the desired logic state can be stored therein, typically by establishing a particular operating environment to inject or remove the line charge carriers. In this way, a single transistor can be sufficient to store unit information, thereby significantly facilitating the superior information density of electronically programmable non-volatile storage devices. Although such a storage transistor of a flash memory structure in which a charge can be captured or released from a particular portion of the gate's electrical structure can represent a very efficient solution for storing unit information, the results indicate that In particular, the constant shrinkage of advanced semiconductor devices may lead to greater difficulties. For example, further shrinking of the overall gate size of such storage transistors may require highly sophisticated techniques to form corresponding gate electrode structures. Therefore, implementing such a floating gate type storage transistor can lead to greater challenges, requiring additional effort and increasing process complexity.

因此,最近提出其它方法,其中,利用鐵電效應來設置電路元件,例如電阻器、電晶體等,其中,可極化鐵電材料以適當影響操作行為。然後,可將相應極化狀態視為相應邏輯狀態,因此可將其寫入包括該可極化鐵電材料的相應電路元件中或自其讀出。例如,在複雜鐵電電晶體中,可將鐵電材料包含於閘極電極結構的介電材料中或在其附近,從而依據鐵電材料的極化狀態顯著影響溝道區的電子特性。 Therefore, other methods have recently been proposed in which a ferroelectric effect is utilized to set circuit elements such as resistors, transistors, etc., wherein the ferroelectric material can be polarized to appropriately affect the operational behavior. The respective polarization states can then be considered as corresponding logic states, so they can be written to or read from corresponding circuit elements comprising the polarizable ferroelectric material. For example, in a complex ferroelectric crystal, a ferroelectric material can be included in or near the dielectric material of the gate electrode structure, thereby significantly affecting the electronic properties of the channel region depending on the polarization state of the ferroelectric material.

請參照第1A至1D圖,詳細說明典型的傳統鐵電現有技術電晶體,其中,如上所述的電晶體可被用作非揮發性儲存電晶體。 Referring to Figures 1A through 1D, a typical conventional ferroelectric prior art transistor is described in detail, wherein the transistor as described above can be used as a non-volatile storage transistor.

第1A圖示意顯示電晶體100的剖視圖,該電晶體可以SOI(絕緣體上矽或絕緣體上半導體)架構的形式設置,在該架構中,埋藏絕緣層(buried insulating layer)例如二氧化矽層102將實際的“主動”半導體材料103例如矽材料、矽/鍺材料等與以矽、鍺等形式設置的半導體襯底材料101隔開。應當瞭解,在複雜應用中,當要設置基本耗盡的SOI配置時,主動半導體層103可設有僅數奈米的適當降低的厚度。在其它情況下,可使用半導體層103的任意其它合適的厚度,取決於總體設計要求。而且,在其 它情況下,可不實施SOI架構且半導體層103可形成於襯底材料101的部分上方或作為其部分。 1A is a cross-sectional view showing the transistor 100, which may be provided in the form of an SOI (insulator on insulator or semiconductor on insulator) architecture in which a buried insulating layer such as a ceria layer 102 is buried. The actual "active" semiconductor material 103, such as tantalum material, tantalum/niobium material, etc., is separated from the semiconductor substrate material 101 disposed in the form of tantalum, niobium or the like. It will be appreciated that in complex applications, when a substantially depleted SOI configuration is to be provided, the active semiconductor layer 103 can be provided with a suitably reduced thickness of only a few nanometers. In other cases, any other suitable thickness of the semiconductor layer 103 can be used, depending on overall design requirements. Moreover, in other cases, the SOI architecture may not be implemented and the semiconductor layer 103 may be formed over or as part of the portion of the substrate material 101.

電晶體100還可包括閘極電極結構110,其經設置及配置以控制半導體層103中所形成的溝道區106,從而依據電晶體100的總體配置以及施加於半導體層103中所形成的源區104與汲區105之間的閘極電極結構110的電壓提供導電溝道。應當瞭解,術語“源區”及“汲區”可互換,取決於可操作電晶體100的特定環境。而且,未顯示關於源汲區104、105的任意相應細節,例如關於摻雜物濃度等。如上所述,在複雜應用中,源汲區104、105結合溝道區106可代表全耗盡電晶體架構,其中,溝道區106可保持基本未摻雜或者可呈現很低的摻雜物濃度,從而當向閘極電極結構110施加相應控制電壓時,相應耗盡區可基本佔據整個溝道區。 The transistor 100 can also include a gate electrode structure 110 that is configured and configured to control the channel region 106 formed in the semiconductor layer 103, depending on the overall configuration of the transistor 100 and the source formed in the semiconductor layer 103. The voltage of the gate electrode structure 110 between the region 104 and the germanium region 105 provides a conductive channel. It should be understood that the terms "source zone" and "deuterium zone" are interchangeable depending on the particular environment in which the transistor 100 can be operated. Moreover, any corresponding details regarding the source germanium regions 104, 105 are not shown, such as with respect to dopant concentration and the like. As noted above, in complex applications, the source germanium regions 104, 105 in combination with the channel region 106 can represent a fully depleted transistor architecture, wherein the channel region 106 can remain substantially undoped or can exhibit very low dopants. The concentration, such that when a corresponding control voltage is applied to the gate electrode structure 110, the corresponding depletion region can occupy substantially the entire channel region.

通常,閘極電極結構110可包括基於半導體材料例如多晶矽、鍺等的具有任意合適配置的電極材料,可能結合含金屬電極材料。例如,在製造閘極電極結構110的任意特定狀態下,部分半導體材料可被轉換成金屬-半導體-化合物,例如金屬矽化物等,這是用以增強基於半導體的區域的總體導電性的成熟概念。而且,在複雜應用中,結合基於半導體的材料可設置相應的含金屬材料,例如氮化鈦等。出於方便,第1A圖中僅顯示電極材料111及112,不過,可應用任意其它配置,如上所述。而且,可設置介電材料113(其部分以鐵電材料的形式設置),以將導電電極 材料111與溝道區106隔開,如針對典型場效應電晶體架構所熟知的那樣。應當瞭解,具有縮小的總體電晶體尺寸(尤其具有縮小的閘極長度(也就是第1A圖中,閘極電極材料113的水平延伸))的複雜應用可能需要閘極電極(也就是導電材料,例如包含於其中的電極材料111)與溝道區106之間的優越的電容耦合,以允許充分且可靠地控制溝道區106。因此,常常使用所謂的“高k”介電材料(也就是具有10.0或顯著更高的介電常數的介電材料),可能結合“傳統”介電材料,例如二氧化矽、氮化矽、氮氧化矽等。例如,基於氧化鉿的介電材料常常可用於高k閘極電極結構的背景中,其中,同時,基於氧化鉿的介電材料也可呈現鐵電特性,從而使這些材料成為被包含於鐵電電晶體元件中的可行候選材料。不過,應當瞭解,也可使用其它鐵電材料來實施鐵電電晶體。閘極介電材料113的最終組成及其厚度可經適當選擇以符合總體裝置要求。尤其,介電材料113的位置、厚度及組成經選擇以提供建立所需極化狀態的能力,也就是建立具有至少兩種不同晶體狀態的可能性的晶體配置,以形成基本垂直於溝道區106中的電流方向的永久電場。溝道區106中的電流方向可與第1A圖的水平方向基本一致。 In general, the gate electrode structure 110 can comprise an electrode material having any suitable configuration based on a semiconductor material such as polysilicon, germanium, etc., possibly in combination with a metal-containing electrode material. For example, in any particular state in which the gate electrode structure 110 is fabricated, a portion of the semiconductor material can be converted into a metal-semiconductor-compound, such as a metal telluride or the like, which is a mature concept for enhancing the overall conductivity of a semiconductor-based region. . Moreover, in complex applications, a combination of semiconductor-based materials can be provided with corresponding metal-containing materials, such as titanium nitride. For convenience, only the electrode materials 111 and 112 are shown in Fig. 1A, however, any other configuration may be applied as described above. Moreover, a dielectric material 113 (partially disposed in the form of a ferroelectric material) may be provided to separate the conductive electrode material 111 from the channel region 106, as is well known for typical field effect transistor architectures. It will be appreciated that a complex application with a reduced overall transistor size (especially with a reduced gate length (i.e., horizontal extension of gate electrode material 113 in Figure 1A) may require a gate electrode (i.e., a conductive material, For example, superior capacitive coupling between the electrode material 111) and the channel region 106 is included to allow sufficient and reliable control of the channel region 106. Therefore, so-called "high-k" dielectric materials (that is, dielectric materials having a dielectric constant of 10.0 or significantly higher) are often used, possibly in combination with "conventional" dielectric materials such as hafnium oxide, tantalum nitride, Niobium oxynitride and the like. For example, yttria-based dielectric materials are often used in the context of high-k gate electrode structures, wherein, at the same time, yttria-based dielectric materials can also exhibit ferroelectric properties, thereby making these materials included in ferroelectrics. A viable candidate material in a crystal element. However, it should be understood that other ferroelectric materials may also be used to implement the ferroelectric crystal. The final composition of the gate dielectric material 113 and its thickness can be suitably selected to meet the overall device requirements. In particular, the location, thickness, and composition of the dielectric material 113 are selected to provide the ability to establish the desired polarization state, that is, to establish a crystal configuration having the possibility of having at least two different crystal states to form substantially perpendicular to the channel region. A permanent electric field in the direction of current in 106. The direction of current flow in channel region 106 may substantially coincide with the horizontal direction of Figure 1A.

而且,閘極電極結構110通常可包括由任意合適的介電材料形成並沿電晶體長度方向(也就是第1A圖中的水平方向)具有任意合適的尺寸的間隙壁結構114,以符合總體裝置要求。 Moreover, the gate electrode structure 110 can generally comprise a spacer structure 114 formed of any suitable dielectric material and having any suitable dimensions along the length of the transistor (ie, the horizontal direction in FIG. 1A) to conform to the overall device. Claim.

第1A圖的電晶體100可基於成熟的製造技術形成,其中,半導體層103可通過外延生長技術等形成,以在材料組成、初始摻雜等方面具有所需的總體配置。埋藏絕緣層102可能已存在或者可依據成熟的製程技術形成。隨後,可執行相應的製程式列,以沉積及/或另外形成介電基材,例如二氧化矽、氮氧化矽等,接著形成並處理其它介電組分(component),例如基於氧化鉿的介電材料,其中,通常也可設置含金屬材料,以適當限制下方的敏感介電材料。在沉積一種或多種另外的電極材料以後,依據所需的總體電晶體尺寸,可基於複雜光刻及蝕刻技術實施閘極電極結構110的圖案化。閘極電極結構110還可容置間隙壁結構114,且可執行額外的製程以設置具有適當電子特性的源汲區104、105。例如,摻雜物種類可通過例如外延生長技術、注入等納入。而且,可執行其它合適的製程,例如退火製程等,以獲得電晶體100的最終電子配置。接著,可執行另外的製程,以為基礎電晶體結構以及與源汲區104、105及閘極電極結構110以及可能與半導體層103(如需要)連接的高導電接觸提供封裝107。 The transistor 100 of FIG. 1A can be formed based on a well-established fabrication technique in which the semiconductor layer 103 can be formed by an epitaxial growth technique or the like to have a desired overall configuration in terms of material composition, initial doping, and the like. Buried insulating layer 102 may already be present or may be formed in accordance with well-established process techniques. Subsequently, a corresponding programming sequence can be performed to deposit and/or otherwise form a dielectric substrate, such as hafnium oxide, hafnium oxynitride, etc., followed by formation and processing of other dielectric components, such as yttria-based. A dielectric material in which a metal-containing material is usually also provided to appropriately limit the underlying sensitive dielectric material. After deposition of one or more additional electrode materials, patterning of the gate electrode structure 110 can be performed based on complex lithography and etching techniques depending on the desired overall transistor size. The gate electrode structure 110 can also house the spacer structure 114 and an additional process can be performed to set the source germanium regions 104, 105 with appropriate electronic characteristics. For example, the dopant species can be incorporated by, for example, epitaxial growth techniques, implantation, and the like. Moreover, other suitable processes, such as an annealing process, etc., can be performed to obtain the final electronic configuration of the transistor 100. Next, an additional process can be performed to provide the package 107 for the underlying transistor structure and the high conductive contact with the source germanium regions 104, 105 and the gate electrode structure 110 and possibly the semiconductor layer 103 (if desired).

第1B圖示意顯示處於操作模式的電晶體100,在該操作模式,在介電材料113附近所形成的鐵電材料具有第一極化狀態113A,其中,如上所述,可建立晶體配置以獲得基本垂直於溝道區106的電流方向的特定電場。可假定極化狀態113A可導致吸引負電荷載流子,從而溝道區106可富有負電荷載流子,例如電子,以顯著影 響電晶體100的電子行為。例如,當假定基本上為N型配置時,對於施加於閘極電極結構110的給定電壓,極化狀態113A可導致降低的總體溝道電阻或較早的電流產生。也就是說,對於N型電晶體,當極化狀態113A有效時,為實現經過溝道區106的所需電流,需要施加降低的閘極電壓。 Figure 1B is a schematic illustration of a transistor 100 in an operational mode in which a ferroelectric material formed adjacent the dielectric material 113 has a first polarization state 113A, wherein, as described above, a crystal configuration can be established A particular electric field is obtained that is substantially perpendicular to the direction of current flow in channel region 106. It can be assumed that the polarization state 113A can result in the attraction of negative charge carriers such that the channel region 106 can be rich in negative charge carriers, such as electrons, to significantly affect the electronic behavior of the transistor 100. For example, when a substantially N-type configuration is assumed, the polarization state 113A may result in reduced overall channel resistance or earlier current generation for a given voltage applied to the gate electrode structure 110. That is, for an N-type transistor, when the polarization state 113A is active, in order to achieve the desired current through the channel region 106, a reduced gate voltage needs to be applied.

也就是說,通過在閘極電極結構110的端子110T與連接半導體材料103的“接地”端子103T之間施加合適的程式設計電壓,可在材料113中建立極化狀態113A。應當瞭解,第1B圖僅示意顯示該程式設計機制,假定塊體配置,在該塊體配置中可能需要接地端子103T,以在溝道區106上獲得所需電場。在其它情況下,當使用全耗盡裝置配置(也如上所述)時,漏極及/或源極105、104可通過相應端子105T、104T與合適的參考電壓連接,例如接地電位,從而也在溝道區106上建立相應的所需電場。 That is, the polarization state 113A can be established in the material 113 by applying a suitable programming voltage between the terminal 110T of the gate electrode structure 110 and the "ground" terminal 103T connecting the semiconductor material 103. It should be understood that FIG. 1B only schematically illustrates the programming mechanism, assuming a bulk configuration in which a ground terminal 103T may be required to obtain the desired electric field on the channel region 106. In other cases, when a fully depleted device configuration (also described above) is used, the drain and/or source 105, 104 may be connected to a suitable reference voltage through respective terminals 105T, 104T, such as a ground potential, thereby also A corresponding desired electric field is established on the channel region 106.

第1C圖示意顯示電晶體100,其中,例如通過如上所述在端子110T、103T及/或端子105T、104T處的合適電壓向介電材料113施加具有反向極性的電場,已建立與極化狀態113A相反的第二極化狀態113B。在此情況下,例如通過移除電子可將正電荷載流子吸引至溝道區106中,從而針對N型電晶體的給定閘極電壓,有助於增加溝道電阻。也就是說,與參照第1B圖所述的情形相比,對於給定的閘極電壓,在溝道區106中的導電溝道的形成可被顯著抑制。因此,與第1B圖的情形相比,在溝 道區106中的導電溝道的形成僅可在顯著較高的閘極電壓下實現。也就是說,具有兩種不同極化狀態(也就是狀態113A、113B)的電晶體100的閾值電壓彼此可明顯不同,且可可靠地使用此差別以基於例如不同的電流驅動能力檢測不同的閾值電壓。應當瞭解,在電晶體的“常規”操作期間,與可導致晶體配置與外部施加的程式設計電場對齊的程式設計電壓相比,可使用顯著降低的閘極電壓控制溝道區106。例如,程式設計電壓可在5V的量級,而標準操作電壓可為約1V或更小。 1C schematically shows a transistor 100 in which an electric field having a reverse polarity is applied to the dielectric material 113, for example, by a suitable voltage at terminals 110T, 103T and/or terminals 105T, 104T as described above. The state 113A is opposite to the second polarization state 113B. In this case, positive charge carriers can be attracted into the channel region 106, for example by removing electrons, thereby contributing to an increase in channel resistance for a given gate voltage of the N-type transistor. That is, the formation of the conductive channel in the channel region 106 can be significantly suppressed for a given gate voltage as compared with the case described with reference to FIG. 1B. Thus, the formation of the conductive channel in the trench region 106 can only be achieved at significantly higher gate voltages than in the case of Figure 1B. That is, the threshold voltages of the transistors 100 having two different polarization states (i.e., states 113A, 113B) can be significantly different from each other, and this difference can be reliably used to detect different thresholds based on, for example, different current drive capabilities. Voltage. It will be appreciated that during "normal" operation of the transistor, the channel region 106 can be controlled using a significantly reduced gate voltage as compared to a programmed voltage that can cause the crystal configuration to align with an externally applied programming electric field. For example, the programming voltage can be on the order of 5V, while the standard operating voltage can be about 1V or less.

第1D圖示意顯示具有第1B及1C圖的不同電子配置的裝置100的不同行為。第1D圖顯示針對不同閘極電壓的源/漏電流,其中,沿水平軸繪製閘極電壓,沿垂直軸繪製電流。從第1D圖可見並如上所述,對於N型配置,在低閘極電壓,針對極化狀態113A可觀察到源/漏電流的顯著增加,從而導致曲線A。另一方面,對於相同的閘極電壓,極化狀態113B可導致基本沒有電流,因此,可能需要顯著較高的閘極電壓以最終誘發源/漏電流的顯著增加。因此,引起電流顯著增加的閘極電壓可被稱為相應的閾值電壓,以表示極化狀態113A導致低閾值電壓,而極化狀態113B導致N型電晶體配置的高閾值電壓。應當瞭解,對於P型鐵電電晶體也可獲得相應的功能行為,不過,其中,任意相關的極性及極化是相反的。不過,在此情況下,也可實現所得閾值電壓的顯著差別並將其用作儲存機制。應當瞭解,一旦建立特定的極化狀態,此狀態 即可持續,即使是在切斷供應電壓以後,從而提供非揮發性儲存機制。另一方面,通過施加相應的程式設計電壓,可在電晶體100的操作期間隨時依據要實施於電晶體100中的所需邏輯狀態調節該極化狀態。 Figure 1D schematically illustrates the different behavior of apparatus 100 having different electronic configurations of Figures 1B and 1C. Figure 1D shows source/drain currents for different gate voltages, where the gate voltage is plotted along the horizontal axis and the current is plotted along the vertical axis. As can be seen from Figure 1D and as described above, for the N-type configuration, at the low gate voltage, a significant increase in source/drain current is observed for the polarization state 113A, resulting in curve A. On the other hand, for the same gate voltage, the polarization state 113B can result in substantially no current, and therefore, a significantly higher gate voltage may be required to ultimately induce a significant increase in source/drain current. Thus, the gate voltage that causes a significant increase in current can be referred to as a corresponding threshold voltage to indicate that polarization state 113A results in a low threshold voltage, while polarization state 113B results in a high threshold voltage of the N-type transistor configuration. It should be understood that corresponding functional behavior can also be obtained for P-type ferroelectric crystals, however, any associated polarity and polarization are reversed. However, in this case, a significant difference in the resulting threshold voltage can also be achieved and used as a storage mechanism. It should be understood that this state is sustainable once a particular polarization state is established, even after the supply voltage is turned off, thereby providing a non-volatile storage mechanism. Alternatively, by applying a corresponding programming voltage, the polarization state can be adjusted at any time during operation of the transistor 100 in accordance with the desired logic state to be implemented in the transistor 100.

結果表明,如上所述,儘管可使用針對非揮發性可程式設計儲存機制的多種可行方法,其中,尤其,該鐵電電晶體概念可與複雜總體製造技術高度相容,但仍存在增加總體位元密度及/或在設置非揮發性儲存機制方面提供優越的操作環境及靈活性的需求。例如,已建議通過適當控制向電晶體的浮置閘極中的電荷載流子的注入及移除來差別化操控在浮置閘極介電材料的各端所捕獲的電荷,從而使快閃儲存電晶體的位元密度加倍。也就是說,在沿電晶體長度方向的浮置閘極的一端,可施加特定的控制方案,以允許在此區域中的電荷載流子的注入或移除,而在浮置閘極的相對端,可自另一端獨立地注入或移除電荷載流子,從而提供在單個電晶體內獨立儲存兩位元的可能性。針對讀出該兩個不同的位元,例如,可觀察到沿兩個相反方向的電流,且相應電流值及方向可與相應邏輯狀態關聯。 The results show that, as described above, although a variety of possible methods for non-volatile programmable storage mechanisms can be used, wherein, in particular, the ferroelectric crystal concept can be highly compatible with complex overall manufacturing techniques, there is still an increase in overall bits. Density and/or the need to provide superior operating environment and flexibility in setting up non-volatile storage mechanisms. For example, it has been proposed to differentially manipulate the charge trapped at each end of the floating gate dielectric material by appropriately controlling the injection and removal of charge carriers into the floating gate of the transistor, thereby enabling flashing The bit density of the storage transistor is doubled. That is, at one end of the floating gate along the length of the transistor, a specific control scheme can be applied to allow injection or removal of charge carriers in this region, while the opposite of the floating gate At the end, charge carriers can be injected or removed independently from the other end, providing the possibility of independently storing two bits within a single transistor. For reading the two different bits, for example, currents in two opposite directions can be observed, and the respective current values and directions can be associated with respective logic states.

儘管這種在浮置閘極配置的不同區域的獨立電荷載流子捕獲及移除概念可提供增加的總體位元密度,但結果表明需要大量額外的努力來實施雙位元配置,同時仍須考慮與複雜裝置技術僅為中等的相容性,也如上面參照單位快閃電晶體所述。 Although this concept of independent charge carrier trapping and removal in different regions of the floating gate configuration can provide increased overall bit density, the results indicate that a significant amount of additional effort is required to implement the dual bit configuration while still having to Consider only moderate compatibility with complex device technology, as also described above with reference to the unit fast lightning crystal.

因此,鑒於上述情形,本揭露涉及一些技術,其中,可至少部分地基於鐵電材料設置非揮發性儲存元件例如場效應電晶體,同時避免或至少減輕上述問題的其中一個或多個的影響。 Accordingly, in view of the above, the present disclosure is directed to techniques in which a non-volatile storage element, such as a field effect transistor, can be disposed based, at least in part, on a ferroelectric material while avoiding or at least alleviating the effects of one or more of the above problems.

下面提供本發明的簡要總結,以提供本發明的一些態樣的基本理解。本發明內容並非詳盡概述本發明。其並非意圖識別本發明的關鍵或重要元件或劃定本發明的範圍。其唯一目的在於提供一些簡化形式的概念,作為後面所討論的更詳細說明的前序。 A brief summary of the invention is provided below to provide a basic understanding of some aspects of the invention. This summary is not an extensive overview of the invention. It is not intended to identify key or critical elements or the scope of the invention. Its sole purpose is to present some concepts in the form of a

基本上,已認識到,在SOI架構中,基於鐵電材料的高效儲存機制可實施於該SOI配置的埋藏絕緣層中,從而有助於在設計相應SOI儲存電晶體方面的優越的靈活性。例如,與所述在該埋藏絕緣層中實施該儲存機制關聯的該優越的靈活性可導致不太關鍵的用以形成尺寸縮小的複雜閘極電極結構的製程技術,從而因基本不變的總體電極配置而潛在地有助於優越的操作行為,同時仍提供非揮發性儲存機制。在其它示例實施例中,基於埋藏絕緣層實施的該儲存機制可與另外的非揮發性儲存機制有效結合,從而總體上可獲得增加的位元密度。在一些示例實施例中,基於埋藏絕緣層的該儲存機制可與實施於閘極電極結構中(基於設於其中的鐵電材料)的儲存機制結合,而在其它示例實施例中,成熟的浮置閘極配置可由埋藏絕緣層中的該基於鐵電材料的儲存機制補充,從而也增強這些 傳統浮置閘極方法的總體效率。 Basically, it has been recognized that in an SOI architecture, an efficient storage mechanism based on ferroelectric materials can be implemented in the buried insulating layer of the SOI configuration, thereby contributing to superior flexibility in designing the corresponding SOI storage transistor. For example, this superior flexibility associated with the implementation of the storage mechanism in the buried insulating layer can result in less critical process techniques for forming a reduced gate electrode structure, resulting in a substantially constant overall The electrode configuration potentially contributes to superior operational behavior while still providing a non-volatile storage mechanism. In other example embodiments, the storage mechanism implemented based on the buried insulating layer can be effectively combined with additional non-volatile storage mechanisms such that an increased bit density is generally achieved. In some example embodiments, the storage mechanism based on the buried insulating layer may be combined with a storage mechanism implemented in the gate electrode structure (based on the ferroelectric material disposed therein), while in other example embodiments, the mature floating The gate configuration can be supplemented by the ferroelectric material based storage mechanism in the buried insulating layer, thereby also enhancing the overall efficiency of these conventional floating gate methods.

本文中所揭露的一個示例實施例涉及非揮發性儲存元件。該儲存元件包括形成於半導體材料中的溝道區以及經設置以控制經過該溝道區的電流的控制電極結構。該非揮發性儲存元件更包括第一儲存機制,其經設置以調節該溝道區的閾值電壓的值。而且,第二儲存機制經設置以調節該閾值電壓的該值,其中,該第二儲存機制包括鐵電材料並經配置以能夠結合該第一儲存機制選擇該溝道區的該閾值電壓的兩個以上不同的值。 One example embodiment disclosed herein relates to a non-volatile storage element. The storage element includes a channel region formed in the semiconductor material and a control electrode structure disposed to control current flow through the channel region. The non-volatile storage element further includes a first storage mechanism configured to adjust a value of a threshold voltage of the channel region. Moreover, a second storage mechanism is provided to adjust the value of the threshold voltage, wherein the second storage mechanism comprises a ferroelectric material and is configured to be capable of selecting the threshold voltage of the channel region in conjunction with the first storage mechanism More than one different value.

依據本文中所揭露的另一個示例實施例,一種非揮發性儲存電晶體元件包括:溝道區以及經設置以控制該溝道區中的電流的閘極電極結構。該非揮發性儲存電晶體元件更包括形成於該溝道區下方的埋藏絕緣層,其中,該埋藏絕緣層包括鐵電材料,以提供以非揮發性方式儲存資訊的儲存機制。 In accordance with another example embodiment disclosed herein, a non-volatile storage transistor component includes a channel region and a gate electrode structure configured to control current in the channel region. The non-volatile storage transistor component further includes a buried insulating layer formed under the channel region, wherein the buried insulating layer comprises a ferroelectric material to provide a storage mechanism for storing information in a non-volatile manner.

在本文中所揭露的又一個示例實施例,提供一種方法。該方法包括選擇在電晶體元件的溝道區附近所形成的鐵電材料的第一極化狀態。而且,該方法包括選擇在該溝道區附近所形成的電荷捕獲材料及第二鐵電材料的至少其中之一的第一儲存狀態。而且,該方法包括向由該第一極化狀態及該第一儲存狀態誘發的第一溝道環境分配第一邏輯狀態。此外,該方法包括選擇電荷捕獲材料及第二鐵電材料的該至少其中之一的第二儲存狀態。而且,向由該第一極化狀態及該第二儲存狀態誘發的第二溝道環 境分配第二邏輯狀態。此外,該方法包括:當結合該鐵電材料的第二極化狀態時,向該第一及第二儲存狀態的其中之一分配至少一個另外的邏輯狀態,其中,該第一與第二極化狀態互逆。 In yet another example embodiment disclosed herein, a method is provided. The method includes selecting a first polarization state of a ferroelectric material formed adjacent a channel region of the transistor element. Moreover, the method includes selecting a first storage state of at least one of the charge trapping material and the second ferroelectric material formed adjacent the channel region. Moreover, the method includes assigning a first logic state to the first channel environment induced by the first polarization state and the first storage state. Additionally, the method includes selecting a second storage state of the at least one of the charge trapping material and the second ferroelectric material. Moreover, a second logic state is assigned to the second channel environment induced by the first polarization state and the second storage state. Moreover, the method includes assigning at least one additional logic state to one of the first and second storage states when the second polarization state of the ferroelectric material is combined, wherein the first and second poles The state is reciprocal.

100‧‧‧電晶體 100‧‧‧Optoelectronics

101‧‧‧半導體襯底材料 101‧‧‧Semiconductor substrate material

102‧‧‧絕緣層 102‧‧‧Insulation

103‧‧‧半導體層 103‧‧‧Semiconductor layer

103T、104T、105T、110T‧‧‧端子 103T, 104T, 105T, 110T‧‧‧ terminals

104‧‧‧源區 104‧‧‧ source area

105‧‧‧汲區 105‧‧‧汲

106‧‧‧溝道區 106‧‧‧Channel area

107‧‧‧封裝 107‧‧‧Package

110、210‧‧‧閘極電極結構 110, 210‧‧‧ gate electrode structure

111、112、211‧‧‧電極材料 111, 112, 211‧‧‧ electrode materials

113‧‧‧介電材料 113‧‧‧ dielectric materials

113A‧‧‧第一極化狀態 113A‧‧‧First polarization state

113B‧‧‧第二極化狀態 113B‧‧‧second polarization state

114‧‧‧間隙壁結構 114‧‧‧ spacer structure

200‧‧‧電晶體元件 200‧‧‧Optoelectronic components

201‧‧‧襯底材料 201‧‧‧Substrate material

201V、210V‧‧‧電壓 201V, 210V‧‧‧ voltage

202‧‧‧絕緣層 202‧‧‧Insulation

202A、202B‧‧‧介電材料 202A, 202B‧‧‧ dielectric materials

202F‧‧‧鐵電材料 202F‧‧‧ Ferroelectric materials

203‧‧‧半導體層 203‧‧‧Semiconductor layer

204、205‧‧‧半導體區 204, 205‧‧‧ semiconductor area

206‧‧‧溝道區 206‧‧‧Channel area

207‧‧‧隔離結構 207‧‧‧Isolation structure

212‧‧‧覆蓋層 212‧‧‧ Coverage

213‧‧‧介電材料 213‧‧‧ dielectric materials

214‧‧‧間隙壁結構 214‧‧‧ spacer structure

300‧‧‧元件 300‧‧‧ components

300A‧‧‧第一儲存機制 300A‧‧‧First storage mechanism

300B‧‧‧第二儲存機制 300B‧‧‧Second storage mechanism

302A、302B、313A、313B‧‧‧極化狀態 302A, 302B, 313A, 313B‧‧‧Polarization status

302F‧‧‧埋藏鐵電材料 302F‧‧‧buried ferroelectric materials

306‧‧‧溝道區 306‧‧‧Channel area

310‧‧‧閘極電極結構 310‧‧‧Gate electrode structure

311F‧‧‧鐵電材料 311F‧‧‧ Ferroelectric materials

參照下面結合附圖所作的說明可理解本揭露,該些附圖中類似的附圖標記表示類似的元件,且其中:第1A圖示意顯示傳統現有技術鐵電電晶體元件的剖視圖;第1B及1C圖示意顯示處於兩種不同的極化狀態的傳統現有技術鐵電電晶體元件的剖視圖;第1D圖示意顯示與第1B及1C圖的不同極化狀態對應的現有技術鐵電電晶體元件的不同驅動電流能力以及由此導致的閾值電壓;第2圖示意顯示依據本揭露的示例實施例包括基於埋藏絕緣層中所設置的鐵電材料的至少一個儲存機制的儲存電晶體元件的剖視圖;第3A至3D圖示意顯示依據本揭露的另外的示例實施例包括兩個儲存機制的儲存電晶體元件的剖視圖,該兩個儲存機制的至少其中之一是基於設於埋藏絕緣層中的鐵電材料;以及第3E圖示意顯示與第3A至3D圖中所示的儲存電晶體元件的不同電子配置對應的不同電子狀態例如不同閾值電壓值的圖。 The disclosure may be understood by reference to the following description taken in conjunction with the accompanying drawings, in which like reference numerals indicate like elements, and wherein: Figure 1A shows a cross-sectional view of a conventional prior art ferroelectric transistor element; 1C is a cross-sectional view showing a conventional prior art ferroelectric transistor element in two different polarization states; FIG. 1D is a view schematically showing a prior art ferroelectric transistor element corresponding to the different polarization states of FIGS. 1B and 1C. Different driving current capabilities and resulting threshold voltages; FIG. 2 is a cross-sectional view schematically showing a storage transistor element including at least one storage mechanism based on ferroelectric material disposed in a buried insulating layer in accordance with an exemplary embodiment of the present disclosure; 3A through 3D are schematic cross-sectional views showing a storage transistor element including two storage mechanisms in accordance with further example embodiments of the present disclosure, at least one of which is based on iron disposed in a buried insulating layer Electrical material; and FIG. 3E schematically shows different electronic shapes corresponding to different electronic configurations of the storage transistor elements shown in FIGS. 3A to 3D FIG e.g. different threshold voltage values.

儘管本文中所揭露的發明主題容許各種修改及替代形式,但本發明主題的特定實施例以示例方式顯示於附圖中並在本文中作詳細說明。不過,應當理解,本文中有關特定實施例的說明並非意圖將本發明限於所揭露的特定形式,相反,意圖涵蓋落入由所附申請專利範圍定義的本發明的精神及範圍內的所有修改、均等及替代。 The specific embodiments of the inventive subject matter are shown by way of example in the drawings and are described in detail herein. It should be understood, however, that the description of the specific embodiments of the present invention is not intended to be limited to the specific forms disclosed. Equal and alternative.

下面說明本發明的各種示例實施例。出於清楚目的,不是實際實施中的全部特徵都在本說明書中進行說明。當然,應當瞭解,在任意此類實際實施例的開發中,必須作大量的特定實施決定以實現開發者的特定目標,例如符合與系統相關及與商業相關的約束條件,該些決定將因不同實施而異。而且,應當瞭解,此類開發努力可能複雜而耗時,但其仍然是本領域的普通技術人員借助本揭露所執行的常規程式。 Various exemplary embodiments of the invention are described below. For the sake of clarity, not all features of an actual implementation are described in this specification. Of course, it should be understood that in the development of any such actual embodiment, a large number of specific implementation decisions must be made to achieve a developer's specific goals, such as compliance with system-related and business-related constraints, which will vary from one decision to another. Implementation varies. Moreover, it should be appreciated that such development efforts can be complex and time consuming, but still be conventional routines performed by one of ordinary skill in the art in view of the present disclosure.

現在將參照附圖來說明本揭露。附圖中示意各種結構、系統及裝置僅是出於解釋目的以及避免使本揭露與本領域技術人員已知的細節混淆,但仍包括該些附圖以說明並解釋本揭露的示例。本文中所使用的詞語和片語的意思應當被理解並解釋為與相關領域技術人員對這些詞語及片語的理解一致。本文中的術語或片語的連貫使用並不意圖暗含特別的定義,亦即與本領域技術人員所理解的通常慣用意思不同的定義。若術語或片語意圖具有特定意思,亦即不同於本領域技術人員所理解的意思,則此類 特別定義會以直接明確地提供該術語或片語的特定定義的定義方式明確表示於說明書中。 The disclosure will now be described with reference to the drawings. The drawings illustrate various structures, systems, and devices that are for the purpose of explanation and are not to be construed as a limitation of the details of the disclosure. The meaning of the words and phrases used herein should be understood and interpreted as being consistent with the understanding of those words and phrases. The coherent use of the terms or phrases herein is not intended to imply a particular definition, i.e., a definition that is different from what is conventionally understood by those skilled in the art. If a term or phrase is intended to have a specific meaning, that is, different from the meaning as understood by those skilled in the art, such a particular definition will be clearly indicated in the specification in a manner that clearly defines the specific definition of the term or phrase. .

本揭露是基於通過利用電晶體元件中的SOI架構的總體配置改進非揮發性儲存元件例如電晶體元件的資訊密度及/或設計靈活性的概念,其中,埋藏絕緣材料層可部分或完全地由鐵電材料替代,以提供以非揮發性方式儲存資訊的機制,在操作該電晶體元件期間可讀出該資訊。也就是說,儘管基本上保持該SOI架構,但可提供額外的非揮發性控制以及由此導致的儲存機制,其原則上可支援與傳統電晶體相比沒有顯著改變的成熟閘極電極結構的形成,從而提供額外程度的設計靈活性,因為可依據設計複雜電晶體元件時所要考慮的標準之外的設計標準選擇相應閘極電極結構的配置。在本文中所揭露的一些示例實施例中,可有利地使用該額外的設計靈活性來提供通過設置例如形成於相應閘極電極結構中的額外儲存機制來提供增加的位元密度的非揮發性儲存元件。也就是說,在一些示例實施例中,該額外儲存機制可設於閘極電極結構中,以適當影響溝道區,該溝道區因此可被夾置於設於埋藏絕緣層中的鐵電材料與設於閘極電極結構中的儲存機制之間。在一些示例實施例中,在閘極電極結構中或附近設置該額外儲存機制的過程中,該儲存機制可基於鐵電材料實施。以此方式,可將針對複雜電晶體元件可用的高效製造技術應用於例如參照第1A至1D圖所述的閘極電極結構,同時,基於埋藏絕緣層中的鐵電材料所設置的儲存機 制可導致較高數目的不同電子配置,可將該不同電子配置分配給相應的邏輯狀態。因此,所述可單獨控制的兩個儲存機制可提供增加的位元密度,例如,可將至少兩個不同的位元“儲存”於相應儲存電晶體元件中,而另一方面,總體電晶體尺寸及基本電晶體配置可能不需要顯著修改。 The present disclosure is based on the concept of improving the information density and/or design flexibility of a non-volatile storage element, such as a transistor element, by utilizing the overall configuration of the SOI architecture in the transistor element, wherein the buried insulating material layer may be partially or completely Ferroelectric materials are substituted to provide a mechanism for storing information in a non-volatile manner that can be read during operation of the transistor element. That is, while substantially maintaining the SOI architecture, additional non-volatile control and resulting storage mechanisms can be provided that in principle support mature gate electrode structures that do not significantly change compared to conventional transistors. Formed to provide an additional degree of design flexibility because the configuration of the respective gate electrode structure can be selected in accordance with design criteria other than the criteria to be considered when designing complex transistor components. In some example embodiments disclosed herein, this additional design flexibility may be advantageously used to provide non-volatile that provides increased bit density by providing additional storage mechanisms, such as those formed in respective gate electrode structures. Store components. That is, in some example embodiments, the additional storage mechanism may be disposed in the gate electrode structure to appropriately affect the channel region, which may thus be sandwiched between ferroelectrics disposed in the buried insulating layer. The material is between the storage mechanism disposed in the gate electrode structure. In some example embodiments, the storage mechanism may be implemented based on a ferroelectric material during the provision of the additional storage mechanism in or near the gate electrode structure. In this way, efficient manufacturing techniques available for complex transistor elements can be applied to, for example, the gate electrode structures described with reference to Figures 1A through 1D, while the storage mechanism based on the ferroelectric material in the buried insulating layer can be used. This results in a higher number of different electronic configurations that can be assigned to the corresponding logical state. Thus, the two separately controllable storage mechanisms can provide increased bit density, for example, at least two different bits can be "stored" in the respective storage transistor elements, and on the other hand, the overall transistor Dimensions and basic transistor configurations may not require significant modifications.

在其它示例實施例中,與閘極電極結構關聯的該儲存機制可基於電荷捕獲層(也就是基於浮置閘極類型閘極結構)設置,而基於鐵電材料的位於埋藏絕緣層中的另一個儲存機制可額外地提供電晶體的另外的不同電子狀態及由此導致的邏輯狀態。例如,如上所述,成熟的浮置閘極類型電晶體可容置基於包含於埋藏絕緣層中的鐵電材料的儲存機制,從而可能使由基於該電荷捕獲層的機制所提供的資訊密度加倍。如上所述,包括該電荷捕獲層的閘極電極結構可提供單位資訊,或在其它情況下,可提供雙位元配置。通過將此機制與埋藏鐵電材料組合,可實現位元密度的相應倍增。 In other example embodiments, the storage mechanism associated with the gate electrode structure may be based on a charge trapping layer (ie, based on a floating gate type gate structure), while the ferroelectric based material is located in the buried insulating layer. A storage mechanism can additionally provide additional different electronic states of the transistor and the resulting logic states. For example, as described above, a mature floating gate type transistor can accommodate a storage mechanism based on a ferroelectric material contained in a buried insulating layer, thereby possibly doubling the information density provided by the mechanism based on the charge trap layer . As noted above, the gate electrode structure including the charge trapping layer can provide unit information, or in other cases, a dual bit configuration can be provided. By combining this mechanism with buried ferroelectric materials, a corresponding doubling of the bit density can be achieved.

在一些示例實施例中,基於埋藏鐵電材料的儲存機制與基於鐵電材料實施於閘極電極結構中或附近的儲存機制可使溝道區中的電流的相關控制機制具有不同的“強度”或“效率”,例如由於該鐵電材料的不同組成、被相應鐵電材料佔據的不同區域等。由於此機制,可有效調節該兩個基於鐵電材料的儲存機制的總體控制效果,以在溝道區中獲得充分不同的驅動電流行為。例如,設於埋藏絕緣材料中並與溝道區接觸或在其附近的鐵電材料區域可 因鐵電材料也經設置而與電晶體的源汲區至少部分接觸或設於其附近的事實而增加影響。在其它情況下,可對位於埋藏絕緣層內及位於閘極電極結構內的鐵電材料的有效距離進行不同的調節,以提供用以微調溝道區對閘極電極結構及埋藏絕緣層中的相應鐵電材料的總回應的額外控制機制。 In some example embodiments, the storage mechanism based on the buried ferroelectric material and the storage mechanism based on the ferroelectric material implemented in or near the gate electrode structure may have different "strength" related control mechanisms of current in the channel region. Or "efficiency", for example due to the different composition of the ferroelectric material, the different regions occupied by the corresponding ferroelectric material, and the like. Due to this mechanism, the overall control effect of the two ferroelectric material-based storage mechanisms can be effectively adjusted to achieve sufficiently different drive current behavior in the channel region. For example, the region of the ferroelectric material disposed in the buried insulating material and in contact with or in the vicinity of the channel region may be at least partially in contact with or disposed adjacent to the source region of the transistor due to the arrangement of the ferroelectric material. Increase the impact. In other cases, the effective distance of the ferroelectric material located in the buried insulating layer and within the gate electrode structure can be adjusted differently to provide fine adjustment of the channel region to the gate electrode structure and the buried insulating layer. Additional control mechanisms for the overall response of the corresponding ferroelectric materials.

因此,對於另外給定的總體電晶體配置,當埋藏絕緣層中的鐵電材料處於第一極化狀態時,可將相應的電晶體特性例如閾值電壓及/或電流驅動能力等分配給相應數目的邏輯狀態。類似地,當埋藏絕緣層中的鐵電材料處於第二極化狀態時,可將相應的電晶體狀態分配給相應的邏輯狀態,只要所得的電晶體狀態彼此可充分區別,從而允許在儲存電晶體元件的常規操作期間可靠地檢測不同的電晶體狀態以及由此導致的邏輯狀態。例如,當可設置兩個儲存機制,每個儲存機制具有兩種不同的電子狀態以及由此導致的邏輯狀態時,該單獨控制的儲存機制的組合效果可導致四種不同的電晶體狀態以及由此導致的邏輯狀態,當適當配置總體電晶體配置時,可充分區別這些邏輯狀態,從而在與單個電晶體元件對應的裝置區域內提供兩位元資訊。以此方式,位元密度可被加倍,而沒有過度修改總體電晶體配置。 Thus, for a given overall transistor configuration, when the ferroelectric material in the buried insulating layer is in the first polarization state, corresponding transistor characteristics such as threshold voltage and/or current drive capability, etc., can be assigned to the corresponding number. The logical state. Similarly, when the ferroelectric material in the buried insulating layer is in the second polarization state, the corresponding transistor states can be assigned to corresponding logic states as long as the resulting transistor states are sufficiently distinguishable from each other, thereby allowing storage of electricity. Different transistor states and resulting logic states are reliably detected during normal operation of the crystal element. For example, when two storage mechanisms can be set up, each storage mechanism having two different electronic states and the resulting logical state, the combined effect of the separately controlled storage mechanism can result in four different transistor states as well as The resulting logic state, when properly configured for the overall transistor configuration, can be sufficiently differentiated to provide two-dimensional information in the device region corresponding to a single transistor component. In this way, the bit density can be doubled without over-modifying the overall transistor configuration.

請參照第2及3A至3E圖,現在將詳細說明另外的示例實施例,其中,如合適,也可參照第1A至1D圖。 Referring to Figures 2 and 3A through 3E, additional exemplary embodiments will now be described in detail, wherein, as appropriate, reference may also be made to Figures 1A through 1D.

第2圖示意顯示非揮發性儲存元件的剖視圖,在一些示例實施例中,將該非揮發性儲存元件設為電晶體元件200,其可包括形成於合適的半導體層203中並被適當摻雜的半導體區204、205橫向包圍的溝道區206,該半導體區204、205在本文中也可被分別稱為源汲區。在此情況下並如上所述,依據其中可使用元件200的總體電路配置,術語“源區”與“汲區”也可互換。關於用以在其中形成源汲區205、204及溝道區206的半導體材料203,可使用基本上任意合適的材料及摻雜物分佈,以符合總體裝置要求。例如,如前所述,在複雜應用中,依據設計要求,半導體層203的初始層厚度可在約10奈米與3奈米之間。而且,半導體層203可包括任意合適的材料,例如矽、矽/鍺、矽/碳、第III-V族半導體化合物等。出於方便,未顯示源汲區205、204的具體摻雜物分佈。 2 is a cross-sectional view showing a non-volatile storage element, which in some exemplary embodiments is a transistor element 200, which may be formed in a suitable semiconductor layer 203 and suitably doped The semiconductor regions 204, 205 are laterally surrounded by a channel region 206, which may also be referred to herein as a source germanium region, respectively. In this case and as described above, the terms "source zone" and "deuterium zone" are also interchangeable depending on the overall circuit configuration in which component 200 can be used. With respect to the semiconductor material 203 used to form the source germanium regions 205, 204 and the channel region 206 therein, substantially any suitable material and dopant profile can be used to meet overall device requirements. For example, as previously discussed, in complex applications, the initial layer thickness of the semiconductor layer 203 may be between about 10 nanometers and 3 nanometers, depending on design requirements. Moreover, the semiconductor layer 203 may include any suitable material such as ruthenium, osmium, iridium, iridium/carbon, a Group III-V semiconductor compound, and the like. The specific dopant distribution of the source germanium regions 205, 204 is not shown for convenience.

而且,常常可應用所謂的“抬升式源漏配置”,其中,在半導體層203的初始材料中或上可形成額外半導體材料(未顯示),以提供具有所需高摻雜物濃度的合適接觸區。任意此類抬升式源汲區可基於外延生長技術等形成。而且,為控制沿電流方向(也就是,第2圖中的水平方向)的溝道區206內的導電性及電流,閘極電極結構210可設有合適的尺寸及組成,以與溝道區206具有合適的電容耦合,從而適當控制其中的電流。在一些示例實施例中,閘極電極結構210可代表複雜閘極電極結構,可能包括高k介電材料,通常結合設於該高k介電材料附近的含金屬 電極材料,以在溝道區206處及內提供合適的環境。也就是說,在這些示例實施例中,閘極電極結構210基本可代表主要為實現適當的電晶體操作而設計的“傳統”複雜閘極電極結構,而所需的非揮發性儲存機制可實施於在溝道區206下方及襯底材料201上方所形成的埋藏絕緣層202中,如後面詳細所述。 Moreover, so-called "lift-up source-drain configurations" are often applied in which additional semiconductor material (not shown) may be formed in or on the starting material of the semiconductor layer 203 to provide suitable contact with the desired high dopant concentration. Area. Any such raised source region can be formed based on epitaxial growth techniques or the like. Moreover, to control the conductivity and current in the channel region 206 along the current direction (ie, the horizontal direction in FIG. 2), the gate electrode structure 210 can be provided with a suitable size and composition to interface with the channel region. 206 has a suitable capacitive coupling to properly control the current therein. In some example embodiments, the gate electrode structure 210 may represent a complex gate electrode structure, possibly including a high-k dielectric material, typically in combination with a metal-containing electrode material disposed adjacent to the high-k dielectric material to be in the channel region Provide suitable environment at 206 and within. That is, in these exemplary embodiments, the gate electrode structure 210 can substantially represent a "traditional" complex gate electrode structure designed primarily to achieve proper transistor operation, while the required non-volatile storage mechanism can be implemented. The buried insulating layer 202 formed under the channel region 206 and over the substrate material 201 is described in detail later.

就不需要額外儲存機制的標準閘極電極結構而言,閘極電極結構210可包括例如基於傳統介電材料如二氧化矽、氮化矽、氮氧化矽等形成的介電材料213,可能結合任意類型的高k介電材料,其中,可依據與提供鐵電儲存機制無關的裝置要求選擇該高k介電材料類型。而且,在這樣的情況下,可設置特定的覆蓋層212,例如氮化鈦等,結合額外的基於半導體的電極材料211,該額外的基於半導體的電極材料可部分由另外的含高導電金屬的材料替代,如上面在第1A圖的上下文中所述。而且,通常可設置間隙壁結構214,以適當包覆閘極電極結構210的敏感材料並提供用於分佈源汲區205、204中的摻雜物濃度的掩膜(如需要的話)。 For a standard gate electrode structure that does not require an additional storage mechanism, the gate electrode structure 210 can include, for example, a dielectric material 213 formed based on a conventional dielectric material such as hafnium oxide, tantalum nitride, hafnium oxynitride, or the like, possibly combined Any type of high-k dielectric material in which the high-k dielectric material type can be selected in accordance with device requirements that are independent of the ferroelectric storage mechanism. Moreover, in such a case, a specific cover layer 212, such as titanium nitride or the like, may be provided in combination with an additional semiconductor-based electrode material 211 which may be partially comprised of another highly conductive metal-containing material Material substitution, as described above in the context of Figure 1A. Moreover, a spacer structure 214 can generally be provided to properly cover the sensitive material of the gate electrode structure 210 and provide a mask for distributing the dopant concentration in the source regions 205, 204, if desired.

而且,元件200可包括埋藏絕緣材料202,該埋藏絕緣材料可包括鐵電材料202F,其具有在鐵電材料202F中建立相應的極化狀態後適當影響溝道區206所需的任意合適的晶體配置及厚度。例如,埋藏絕緣層202可具有約10至50奈米甚至更高的的總體厚度,其中,至少在元件200的區域(被適當的隔離結構207例如淺溝槽隔離橫 向限定)內,特定部分可由鐵電材料202F形成或者可包括鐵電材料202F。在一些示例實施例中,埋藏絕緣層202可包括傳統介電材料,例如二氧化矽、氮化矽、氮氧化矽,其可經適當設置以夾置鐵電材料202F,從而相對溝道區206及/或襯底材料201提供優越的介面特性。例如,傳統介電材料202A可形成於鐵電材料202F下方,從而與襯底材料201形成基本上為惰性的介面。類似地,在一些示例實施例中,傳統介電材料202B可形成於鐵電材料202F上,從而也提供與相鄰溝道區206及源汲區205、204的優越的介面特性。在其它情況下,通過鐵電材料202F與半導體層203及/或襯底材料201中的區域基本直接接觸所實現的介面特性可能是可以接受的,因此,可省略介面介電材料202A、202B的其中一者或兩者。在一些示例實施例中,可基於氧化鉿材料設置鐵電材料202F,氧化鉿材料是成熟的介電材料,它也可被用作複雜閘極電極結構中的高k介電材料。因此,適當的用於沉積、圖案化並處理鐵電材料202F以建立所需晶體配置的技術是成熟的且可被用於形成鐵電材料202F。應當瞭解,鐵電材料202F可經形成以使相應極化狀態可具有基本垂直於溝道區206中的電流方向的方向,從而在鐵電材料202F中建立所需極化狀態後高效控制溝道區206中的導電狀態或電流。在一些實施例中,作為基於氧化鉿的材料的附加或替代,可使用其它鐵電材料。 Moreover, component 200 can include buried insulating material 202, which can include ferroelectric material 202F having any suitable crystals needed to properly affect channel region 206 after establishing a corresponding polarization state in ferroelectric material 202F. Configuration and thickness. For example, the buried insulating layer 202 can have an overall thickness of about 10 to 50 nanometers or more, wherein at least in a region of the component 200 (defined by a suitable isolation structure 207, such as a shallow trench isolation laterally), a particular portion can be Ferroelectric material 202F is formed or may include ferroelectric material 202F. In some example embodiments, buried insulating layer 202 may comprise a conventional dielectric material, such as hafnium oxide, tantalum nitride, hafnium oxynitride, which may be suitably disposed to sandwich ferroelectric material 202F such that relative channel region 206 And/or substrate material 201 provides superior interface characteristics. For example, conventional dielectric material 202A can be formed under ferroelectric material 202F to form a substantially inert interface with substrate material 201. Similarly, in some example embodiments, conventional dielectric material 202B may be formed on ferroelectric material 202F to also provide superior interfacial properties with adjacent channel region 206 and source germanium regions 205, 204. In other cases, interface characteristics achieved by substantially direct contact of ferroelectric material 202F with regions in semiconductor layer 203 and/or substrate material 201 may be acceptable, and thus interface dielectric materials 202A, 202B may be omitted. One or both. In some example embodiments, ferroelectric material 202F may be provided based on a yttria material, which is a mature dielectric material that may also be used as a high-k dielectric material in a complex gate electrode structure. Accordingly, suitable techniques for depositing, patterning, and processing ferroelectric material 202F to establish a desired crystal configuration are well established and can be used to form ferroelectric material 202F. It will be appreciated that the ferroelectric material 202F can be formed such that the respective polarization states can have a direction that is substantially perpendicular to the direction of current flow in the channel region 206, thereby efficiently controlling the channel after establishing the desired polarization state in the ferroelectric material 202F. The conductive state or current in region 206. In some embodiments, other ferroelectric materials may be used in addition to or instead of the yttria-based material.

當設置半導體材料203並形成閘極電極結 構210及源汲區205、204時,基於成熟的材料依據成熟的製程技術可形成元件200,其中,如上所述,尤其可遵守形成結合元件200的其它複雜電晶體元件所需的設計標準。在形成閘極電極結構210之前,可將鐵電材料202F納入埋藏絕緣材料202中,這可在形成隔離結構207之前或之後實施,而在其它情況下,在形成結構207之前可執行一些製程步驟,在完成隔離結構207以後可執行其它製程步驟。例如,當自基本上為塊體類型的襯底配置開始時,可形成埋藏絕緣材料202,例如通過例如基於氧化、沉積等形成層202A,接著沉積鐵電材料202F的基材。可基於成熟的沉積技術執行該沉積,該成熟的沉積技術也通常用於形成閘極電極結構的複雜高k介電層。例如,可應用化學氣相沉積、物理氣相沉積、原子層沉積等。隨後,如需要,可形成層202B,例如通過沉積,接著使用外延生長技術,其中,可使用橫向設置的晶種材料來生長半導體材料203,隨後可基於成熟的拋光技術將該半導體材料平坦化並薄化至合適的厚度。 When the semiconductor material 203 is disposed and the gate electrode structure 210 and the source germanium regions 205, 204 are formed, the component 200 can be formed based on mature materials in accordance with well-established process techniques, wherein, as described above, other formation of the bonding component 200 can be specifically observed Design criteria required for complex transistor components. Prior to forming the gate electrode structure 210, the ferroelectric material 202F can be incorporated into the buried insulating material 202, which can be performed before or after the isolation structure 207 is formed, while in other cases, some process steps can be performed prior to forming the structure 207. Other process steps can be performed after the isolation structure 207 is completed. For example, when starting from a substantially bulk type substrate configuration, buried insulating material 202 can be formed, such as by forming layer 202A, for example, based on oxidation, deposition, etc., followed by deposition of a substrate of ferroelectric material 202F. This deposition can be performed based on well-established deposition techniques, which are also commonly used to form complex high-k dielectric layers of gate electrode structures. For example, chemical vapor deposition, physical vapor deposition, atomic layer deposition, or the like can be applied. Subsequently, layer 202B may be formed, if desired, for example by deposition, followed by epitaxial growth techniques in which the semiconductor material 203 may be grown using a laterally disposed seed material, which may then be planarized based on mature polishing techniques and Thin to a suitable thickness.

在其它示例實施例中,例如通過選擇性蝕刻技術可移除埋藏絕緣材料202的部分,這可通過形成隔離結構207的相應溝槽並引入高選擇性蝕刻化學選擇性移除埋藏絕緣層202的材料來實施。接著,鐵電材料202F可被沉積於隔離結構207的相應開口中,從而也可被至少部分沉積於先前通過該選擇性蝕刻製程所形成的任意空腔內。在其它情況下,在初始半導體材料203中可形成多個 開口(未顯示),例如多個溝槽,其中,基本的埋藏絕緣材料202可被移除並由鐵電材料202F替代,可能結合傳統的介電材料202A及/或202B。在此情況下,鐵電材料202F可能不連續設於溝道區206及源汲區205、204下方,而是可設置相應的島,不過,該些島足以適當地支持溝道區206的控制。 In other example embodiments, portions of the buried insulating material 202 may be removed, such as by a selective etch technique, which may selectively remove the buried insulating layer 202 by forming a corresponding trench of the isolation structure 207 and introducing a highly selective etch. Materials to implement. Next, ferroelectric material 202F can be deposited in corresponding openings of isolation structure 207, and thus can also be at least partially deposited in any of the cavities previously formed by the selective etching process. In other cases, a plurality of openings (not shown) may be formed in the initial semiconductor material 203, such as a plurality of trenches, wherein the substantially buried insulating material 202 may be removed and replaced by ferroelectric material 202F, possibly in combination with conventional Dielectric material 202A and/or 202B. In this case, the ferroelectric material 202F may not be continuously disposed under the channel region 206 and the source germanium regions 205, 204, but may be provided with corresponding islands, however, the islands are sufficient to properly support the control of the channel region 206. .

在其它示例實施例中,可將襯底材料201設為載體襯底,可通過氧化、沉積等形成埋藏絕緣層202,而且至少在特定區域中,可基於任意成熟的製程方案形成鐵電材料202F。隨後,例如通過應用晶圓接合技術可形成初始半導體層203。在此情況下,例如以二氧化矽層的形式設置介電材料202B可提供與用於在基於氧化矽的介電材料上形成所需的基於矽的半導體材料的傳統晶圓接合技術基本類似的表面環境。 In other exemplary embodiments, the substrate material 201 may be a carrier substrate, and the buried insulating layer 202 may be formed by oxidation, deposition, or the like, and at least in a specific region, the ferroelectric material 202F may be formed based on any mature process scheme. . Subsequently, the initial semiconductor layer 203 can be formed, for example, by applying a wafer bonding technique. In this case, the provision of dielectric material 202B, for example in the form of a hafnium oxide layer, can provide substantially similar to conventional wafer bonding techniques for forming desired germanium-based semiconductor materials on yttria-based dielectric materials. Surface environment.

因此,在埋藏絕緣層202中設置鐵電材料202F以後,可繼續進一步的製程(如上所述),以形成元件200的其餘部分。 Thus, after the ferroelectric material 202F is disposed in the buried insulating layer 202, a further process (as described above) can be continued to form the remainder of the component 200.

當操作元件200時,可施加所需的閘極電壓210V,以控制溝道區206中的電流,這通常也是傳統電晶體元件中的情況。而且,通過在埋藏絕緣材料202上施加相應電壓201V可實現額外的控制,從而實現溝道區206的優越控制(如需要)。應當瞭解,在常規操作期間,可在一定範圍內選擇電壓210V及201V,該範圍顯著超出用以在鐵電材料202F中建立特定極化狀態所需的任意電壓範 圍,也如上面在第1A及1B圖的上下文中所述。例如,針對元件200的常規操作,控制溝道區206的電壓可在約2V及顯著更小的範圍內,例如約1V,而用以在材料202F中建立所需極化狀態的電壓201V可在數伏的範圍內,例如約5V。應當瞭解,當“程式設計”元件200(也就是在鐵電材料202F中建立所需的極化狀態)時,依據該所需極化狀態可改變電壓201V的極性。因此,通過選擇具有合適極性的足夠高的電壓201V可實施元件200的程式設計,隨後,基於在常規供應電壓範圍內的電壓210V以及可能基於與該程式設計電壓相比顯著較低的電壓201V,可實現常規操作。 When operating element 200, the desired gate voltage 210V can be applied to control the current in channel region 206, which is also typically the case in conventional transistor components. Moreover, additional control can be achieved by applying a corresponding voltage 201V across the buried insulating material 202, thereby achieving superior control of the channel region 206 (if desired). It will be appreciated that during normal operation, the voltages 210V and 201V may be selected within a range that significantly exceeds any voltage range required to establish a particular polarization state in the ferroelectric material 202F, as also above in Section 1A and As described in the context of Figure 1B. For example, for normal operation of component 200, the voltage controlling channel region 206 can be in the range of about 2V and significantly less, such as about 1V, and the voltage 201V used to establish the desired polarization state in material 202F can be Within a range of a few volts, for example about 5V. It will be appreciated that when the "programming" component 200 (i.e., the desired polarization state is established in the ferroelectric material 202F), the polarity of the voltage 201V can be varied depending on the desired polarization state. Thus, the programming of component 200 can be implemented by selecting a sufficiently high voltage 201V of suitable polarity, and then based on a voltage 210V over a conventional supply voltage range and possibly based on a significantly lower voltage 201V compared to the programmed voltage, Regular operation is possible.

在另一個示例實施例中,閘極電極結構210可經配置以實施額外儲存機制,也就是說,除了通過鐵電材料202F結合用以施加幅度足以程式設計鐵電材料202F(也就是建立特定極化狀態)的電壓201V的配置所提供的儲存機制之外,如上所述。在一個示例實施例中,在閘極電極結構210的背景下的該儲存機制可基於另外的鐵電材料實施,也就是說,介電層213可具有鐵電材料包含於其中,例如基於氧化鉿的鐵電材料,也如上面在第1A圖的上下文中所述。因此,可應用結合控制電壓210V包括該鐵電材料的介電層213,以與針對包括該介電材料的介電層213的程式設計電壓對應,從而提供另外的儲存機制。因此,層213中的該鐵電材料及埋藏絕緣層202中的鐵電材料202F可被獨立地極化(也就是程式設計),以在溝 道區內提供疊加電場,這可導致相應不同的溝道導電性或驅動電流(例如由閾值電壓值的相應差別表達),從而提供建立兩個以上不同的溝道狀態以及由此導致的邏輯狀態的可能性。 In another example embodiment, the gate electrode structure 210 can be configured to implement an additional storage mechanism, that is, in addition to being combined by the ferroelectric material 202F to apply an amplitude sufficient to program the ferroelectric material 202F (ie, to establish a particular pole) In addition to the storage mechanism provided by the configuration of the voltage 201V, as described above. In an exemplary embodiment, the storage mechanism in the context of the gate electrode structure 210 can be implemented based on additional ferroelectric material, that is, the dielectric layer 213 can have a ferroelectric material contained therein, such as based on yttrium oxide. The ferroelectric material is also as described above in the context of Figure 1A. Thus, a dielectric layer 213 comprising the ferroelectric material in conjunction with the control voltage 210V can be applied to correspond to a programming voltage for the dielectric layer 213 comprising the dielectric material to provide an additional storage mechanism. Thus, the ferroelectric material in layer 213 and the ferroelectric material 202F in buried insulating layer 202 can be independently polarized (ie, programmed) to provide a superimposed electric field within the channel region, which can result in correspondingly different Channel conductivity or drive current (e.g., expressed by a corresponding difference in threshold voltage values) provides the possibility to establish more than two different channel states and resulting logic states.

應當瞭解,依據成熟的製程技術可形成包括該鐵電材料的介電層213,如上參照第1A圖的電晶體元件100所述。 It will be appreciated that a dielectric layer 213 comprising the ferroelectric material can be formed in accordance with well-established process techniques, as described above with reference to transistor element 100 of FIG. 1A.

在另外的示例實施例中,該閘極電極結構可包括基於浮置閘極配置所形成的額外儲存機制,其中,介電層213的至少部分可包括用以捕獲電荷載流子的層或區域,通過施加適當的程式設計電壓或擦除電壓,可向該電荷載流子捕獲區域注入或自其移除電荷載流子,如針對浮置閘極類型電晶體所熟知的那樣。因此,也在此情況下,結合相應施加具有足夠高度的電壓210V的能力,介電層213可代表另外的儲存機制,以結合鐵電材料202F提供兩個以上不同的電晶體狀態以及由此導致的邏輯狀態。 In further example embodiments, the gate electrode structure can include an additional storage mechanism formed based on a floating gate configuration, wherein at least a portion of the dielectric layer 213 can include a layer or region to capture charge carriers The charge carrier can be injected into or removed from the charge carrier capture region by applying an appropriate programming voltage or erase voltage, as is well known for floating gate type transistors. Therefore, also in this case, in conjunction with the corresponding ability to apply a voltage of 210V of sufficient height, the dielectric layer 213 can represent an additional storage mechanism to provide more than two different transistor states in combination with the ferroelectric material 202F and thereby The logical state.

應當瞭解,該浮置閘極類型電極結構可基於成熟的製程方案形成,例如提供合適的介電層堆疊,例如氧化物-氮化物-氧化物等,其中,這些層的其中之一(通常為中間層)可充當電荷捕獲層。在其它情況下,由介電材料213(包括電荷捕獲層)提供的該儲存機制可具有本身可提供兩個或更多晶體管狀態以及由此導致的邏輯狀態的配置,其中,通過鐵電材料202F的相應極化狀態可適當修改這些狀態的至少其中一些,從而進一步增加不同電晶體 狀態的數量。例如,如上所述,複雜快閃電晶體技術可包括閘極電極結構及用以施加適當的閘極電壓以建立兩位元資訊的相應模式,其中,通過適當調節並因此選擇鐵電材料202F的極化狀態可增加資訊密度。 It should be understood that the floating gate type electrode structure can be formed based on a well-established process scheme, such as providing a suitable dielectric layer stack, such as an oxide-nitride-oxide, etc., wherein one of the layers (usually The intermediate layer) can serve as a charge trapping layer. In other cases, the storage mechanism provided by the dielectric material 213 (including the charge trapping layer) can have a configuration that itself can provide two or more transistor states and resulting logic states, wherein the ferroelectric material 202F is passed. The corresponding polarization state may suitably modify at least some of these states to further increase the number of different transistor states. For example, as described above, the complex fast lightning crystal technique can include a gate electrode structure and a corresponding mode for applying an appropriate gate voltage to establish two-bit information, wherein the pole of the ferroelectric material 202F is appropriately adjusted and thus selected The state can increase the information density.

第3A至3D圖示意顯示包括兩個獨立的儲存機制以實施一位元以上資訊的儲存元件例如場效應電晶體的剖視圖。 Figures 3A through 3D schematically show cross-sectional views of a storage element, such as a field effect transistor, that includes two independent storage mechanisms to implement one bit or more of information.

第3A圖示意顯示元件300的剖視圖,該元件可代表具有閘極電極結構310及埋藏鐵電材料302F的儲存電晶體,閘極電極結構310及埋藏鐵電材料302F可夾置相應溝道區306,該溝道區的導電狀態或驅動電流能力將受相應儲存機制控制。在一個示例實施例中,閘極電極結構310可包括儲存機制300A,其可基於設於閘極電極結構310中的鐵電材料311F。而且,基於鐵電材料302F所形成的第二儲存機制300B可被設為用以在元件300中建立一個以上資訊位元的獨立機制。應當瞭解,元件300以示意的方式顯示,且當提到包括至少兩個獨立儲存機制的配置時,可具有如前面在第2圖的元件200的上下文中所述的配置。在第3A圖中所示的實施例中,兩個儲存機制都可基於鐵電材料,例如鐵電材料311F及埋藏鐵電材料302F。在其它示例實施例(未顯示)中,第一儲存機制300A可基於電荷載流子捕獲材料實施,如上參照第2圖所述。 3A is a cross-sectional view showing the display element 300, which may represent a storage transistor having a gate electrode structure 310 and a buried ferroelectric material 302F, and the gate electrode structure 310 and the buried ferroelectric material 302F may sandwich corresponding channel regions. 306, the conduction state or drive current capability of the channel region will be controlled by a corresponding storage mechanism. In an example embodiment, the gate electrode structure 310 can include a storage mechanism 300A that can be based on a ferroelectric material 311F disposed in the gate electrode structure 310. Moreover, the second storage mechanism 300B formed based on the ferroelectric material 302F can be set as an independent mechanism for establishing more than one information bit in the component 300. It will be appreciated that element 300 is shown in a schematic manner, and when referring to a configuration including at least two independent storage mechanisms, may have the configuration as previously described in the context of element 200 of FIG. In the embodiment shown in FIG. 3A, both storage mechanisms may be based on ferroelectric materials, such as ferroelectric material 311F and buried ferroelectric material 302F. In other example embodiments (not shown), the first storage mechanism 300A can be implemented based on charge carrier capture material, as described above with reference to FIG.

因此,鐵電材料311F可具有合適的配置, 以能夠建立兩種不同的(也就是相反的)極化狀態,其方向可基本上垂直於溝道區306的電流方向。該電流方向(如上在第1A及2圖的上下文中所述)可代表第3A圖中的水平方向。建立所需極化狀態的基本概念可與上面參照元件100及200所述相同。因此,儲存機制300A可具有如上所述通過適當程式設計鐵電材料311F所獲得的第一極化狀態313A,且儲存機制300B可具有第一極化狀態302A,極化狀態302A也可基於上面參照第2圖所述的方案建立。在第3A圖中所示的情況中,兩種極化狀態313A、302A可指向同一方向,以提供特定的導電狀態或電流驅動能力,也如上所述。 Thus, the ferroelectric material 311F can have a suitable configuration to enable the creation of two different (i.e., opposite) polarization states, the direction of which can be substantially perpendicular to the direction of current flow of the channel region 306. This current direction (as described above in the context of Figures 1A and 2) may represent the horizontal direction in Figure 3A. The basic concept of establishing the desired polarization state can be the same as described above with reference to elements 100 and 200. Thus, the storage mechanism 300A can have a first polarization state 313A obtained by properly programming the ferroelectric material 311F as described above, and the storage mechanism 300B can have a first polarization state 302A, which can also be based on the above reference. The scenario described in Figure 2 is established. In the case shown in Figure 3A, the two polarization states 313A, 302A can be directed in the same direction to provide a particular conductive state or current drive capability, as also described above.

第3B圖示意顯示元件300,其中,保留機制300B的極化狀態302A,而反轉機制300A的極化狀態,以313B表示。因此,極化狀態313B與302A可彼此部分補償,從而導致相應導電狀態不同於第3A圖中的組合極化的導電狀態。 Figure 3B illustrates display element 300 in which polarization state 302A of mechanism 300B is retained and polarization state of inversion mechanism 300A is indicated by 313B. Thus, polarization states 313B and 302A can be partially compensated for each other, resulting in a conductive state that is different from the combined polarization in Figure 3A.

第3C圖示意顯示元件300,其中,反轉機制300B的極化狀態,以302B表示,因此,該兩個極化狀態具有相同的方向,從而增加溝道區306中的電場。 3C illustrates display element 300 in which the polarization state of inversion mechanism 300B is indicated by 302B, and thus, the two polarization states have the same direction, thereby increasing the electric field in channel region 306.

第3D圖示意顯示元件300,其中,保留有關第3C圖中的極化的極化狀態300B,而將機制300A程式設計於與第3B及3C圖中所示的狀態相反的極化狀態313A中,該極化狀態因此對應第3A圖中所示的狀態。在此情況下,相應極化的組合與第3A至3C圖中所示的元件 300的組合極化效應相比也可在溝道區306中有所不同。 Figure 3D shows display element 300 in which polarization state 300B relating to polarization in Figure 3C is retained, and mechanism 300A is programmed to be opposite polarization state 313A as shown in Figures 3B and 3C. In this case, the polarization state thus corresponds to the state shown in FIG. 3A. In this case, the combination of the respective polarizations may also differ in the channel region 306 as compared to the combined polarization effect of the element 300 shown in Figures 3A through 3C.

應當瞭解,如上所述,在示例實施例中,一方面的極化狀態313A、313B的相應“效率”或“強度”與另一方面的302A、302B可不同,以使第3B及3D圖中所示的相應“混合”狀態都可對溝道區306產生不同的最終效應。例如,可假定,基本上,極化狀態313A、313B在影響溝道區306方面不太有效,因為與埋藏鐵電材料302F相比,被相應鐵電材料311F覆蓋的總體面積較小。在其它情況下,可基於其它參數例如相應鐵電材料至溝道區306的有效距離調節相應極化的效率或強度,這可通過選擇任意介面材料(例如第2圖中所示的材料202A、202B)的合適厚度以及/或者通過任意傳統介電材料實施,該傳統介電材料可結合閘極電極結構310中的該鐵電材料設置,也如第1A圖及第2圖的上下文中所述。 It will be appreciated that, as described above, in an exemplary embodiment, the respective "efficiency" or "intensity" of the polarization states 313A, 313B on the one hand may be different from 302A, 302B on the other hand, such that in the 3B and 3D diagrams The respective "mixed" states shown can produce different final effects on channel region 306. For example, it can be assumed that, substantially, the polarization states 313A, 313B are less effective in affecting the channel region 306 because the overall area covered by the corresponding ferroelectric material 311F is smaller than the buried ferroelectric material 302F. In other cases, the efficiency or intensity of the respective polarization may be adjusted based on other parameters, such as the effective distance of the respective ferroelectric material to channel region 306, which may be by selecting any interface material (eg, material 202A shown in FIG. 2, A suitable thickness of 202B) and/or by any conventional dielectric material that can be placed in conjunction with the ferroelectric material in the gate electrode structure 310, as also described in the context of FIGS. 1A and 2 .

因此,可用多個機制來調節相應鐵電材料的效率或強度,從而實現第3B與3D圖中所示混合狀態之間的充分差別。 Thus, multiple mechanisms can be used to adjust the efficiency or strength of the respective ferroelectric material to achieve a sufficient difference between the mixed states shown in Figures 3B and 3D.

第3E圖示意顯示與第3A至3D圖所示的四種不同狀態對應電流行為的圖形。也就是說,曲線AA對應第3A圖中所示的配置,其中,兩個儲存機制300A、300B具有“向下的”極化狀態313A、302A。因此,對於元件300的N型配置,可獲得最小閾值電壓,因為在此情況下,溝道區306的電阻最低。 Fig. 3E is a view schematically showing a graph of current behavior corresponding to four different states shown in Figs. 3A to 3D. That is, curve AA corresponds to the configuration shown in FIG. 3A, where the two storage mechanisms 300A, 300B have "downward" polarization states 313A, 302A. Thus, for the N-type configuration of component 300, a minimum threshold voltage can be obtained because in this case, the resistance of channel region 306 is the lowest.

曲線BB對應第3C圖中所示的元件300的 配置。也就是說,在此配置中,兩種極化狀態可對應“向上的”方向,因此,在溝道區306上的組合效應可導致最高閾值電壓值,因為在此情況下,也就是對於N形配置,正電荷載流子可能傾向於累積於溝道區306中,從而導致最高溝道電阻。 Curve BB corresponds to the configuration of element 300 shown in Figure 3C. That is, in this configuration, the two polarization states may correspond to the "upward" direction, and thus, the combined effect on the channel region 306 may result in the highest threshold voltage value, since in this case, that is, for N In a configuration, positive charge carriers may tend to accumulate in channel region 306, resulting in the highest channel resistance.

曲線AB對應第3D圖中所示的配置,其中,顯然,極化狀態302B的效應可由極化狀態313A的效應部分補償。不過,由於如上所述這些極化狀態的不同效率或強度,向降低閾值電壓值的偏移(也就是在第3E圖中,向左手側偏移)與曲線BA的向右偏移(與第3B圖中所示的配置對應)相比不太明顯。也就是說,極化狀態313B抵消極化狀態302A。不過,由於不同的強度,最終獲得的閾值電壓值仍可區別於曲線AB的閾值電壓值。因此,由第3B及3D圖表示的混合狀態很容易彼此區別,而由第3A及3D圖表示的“純粹”的狀態可代表可用的最大及最小閾值電壓值。 The curve AB corresponds to the configuration shown in the 3D diagram, wherein it is apparent that the effect of the polarization state 302B can be compensated for by the effect portion of the polarization state 313A. However, due to the different efficiencies or intensities of these polarization states as described above, the shift to the reduced threshold voltage value (i.e., offset to the left hand side in Figure 3E) is offset to the right of the curve BA (and The configuration shown in Figure 3B corresponds to) is less obvious. That is, the polarization state 313B cancels the polarization state 302A. However, due to the different intensities, the resulting threshold voltage value can still be distinguished from the threshold voltage value of curve AB. Therefore, the mixed states represented by the 3B and 3D maps are easily distinguished from each other, and the "pure" states represented by the 3A and 3D graphs can represent the maximum and minimum threshold voltage values that are available.

因此,通過設置合適的周邊元件來建立電壓210V及201V(見第2圖),儲存機制300A、300B可彼此獨立程式設計,從而提供在溝道區306內有效的總體極化的不同組合。在適當選擇極化狀態的單獨效率或強度後,任意混合狀態也可彼此充分不同,從而獲得例如由四個不同閾值電壓值表示的元件300的功能行為的四種不同狀態。因此,當基於常規操作電壓操作元件300時,相應的電流驅動能力很容易被識別並可與相應的邏輯狀態關 聯。也就是說,極化狀態313A可與針對埋藏鐵電材料302F的不同極化狀態由曲線AA、AB表示的閾值電壓值對應的邏輯狀態關聯。類似地,材料311F的極化狀態313B可被分配給針對材料302F的不同極化狀態由曲線BA、BB表示的閾值電壓值對應的相應邏輯狀態。 Thus, by setting the appropriate peripheral components to establish voltages 210V and 201V (see FIG. 2), the memory mechanisms 300A, 300B can be programmed independently of one another to provide different combinations of effective overall polarizations in the channel region 306. After appropriate selection of the individual efficiencies or intensities of the polarization states, the arbitrary mixing states can also be sufficiently different from one another to obtain, for example, four different states of the functional behavior of the component 300, represented by four different threshold voltage values. Thus, when the component 300 is operated based on conventional operating voltages, the corresponding current drive capability is readily identifiable and can be associated with a corresponding logic state. That is, polarization state 313A may be associated with a logic state corresponding to a threshold voltage value represented by curves AA, AB for different polarization states of buried ferroelectric material 302F. Similarly, polarization state 313B of material 311F can be assigned to a respective logic state corresponding to a threshold voltage value represented by curves BA, BB for different polarization states of material 302F.

應當瞭解,上面的考慮均等地適用於元件300的P型配置。例如,P型鐵電電晶體可通過適當反轉所使用的任意摻雜獲得,而與第3E圖中所示的情形相比,相應極化方向也可對於相應閾值電壓具有反向效應。 It should be appreciated that the above considerations apply equally to the P-type configuration of component 300. For example, a P-type ferroelectric crystal can be obtained by any doping used by appropriate inversion, and the corresponding polarization direction can also have an inverse effect on the corresponding threshold voltage as compared with the case shown in FIG. 3E.

因此,本揭露提供儲存元件,例如儲存電晶體,其中,基於埋藏鐵電材料(例如,通過在SOI電晶體架構的埋藏絕緣層中納入鐵電材料)可提供至少一個儲存機制。以此方式,可增強總體設計靈活性。而且,在示例實施例中,例如基於電荷捕獲層(如通常被用於浮置閘極類型儲存電晶體中的那樣)可提供至少一個另外的儲存機制,而在其它示例實施例中,在該閘極電極結構中可設置另外的鐵電材料,從而有助於增加資訊密度,同時仍保留與複雜全耗盡SOI電晶體中所使用的當今複雜高k金屬閘極電極結構的高度相容性。 Accordingly, the present disclosure provides storage elements, such as storage transistors, wherein at least one storage mechanism can be provided based on buried ferroelectric materials (eg, by incorporating ferroelectric materials into the buried insulating layer of the SOI transistor architecture). In this way, overall design flexibility can be enhanced. Moreover, in an exemplary embodiment, at least one additional storage mechanism may be provided, for example based on a charge trapping layer (as is commonly used in floating gate type storage transistors), while in other example embodiments, Additional ferroelectric materials can be placed in the gate electrode structure to help increase information density while still retaining high compatibility with today's complex high-k metal gate electrode structures used in complex fully depleted SOI transistors. .

由於本發明可以本領域的技術人員借助本文中的教導而明白的不同但均等的方式修改並實施,因此上面所揭露的特定實施例僅為示例性質。例如,可以不同的循序執行上述製程步驟。而且,本發明並非意圖限於本文中所示的架構或設計的細節,而是如下面的申請專利範 圍所述。因此,顯然,可對上面所揭露的特定實施例進行修改或變更,且所有此類變更落入本發明的範圍及精神內。要注意的是,用於說明本說明書以及所附申請專利範圍中的各種製程或結構的例如“第一”、“第二”、“第三”或者“第四”等術語的使用僅被用作此類步驟/結構的快捷參考,並不一定意味著按排列循序執行/形成此類步驟/結構。當然,依據準確的申請專利範圍語言,可能要求或者不要求此類製程的排列順序。因此,本發明請求保護的範圍如下面的申請專利範圍所述。 The specific embodiments disclosed above are merely exemplary in nature, as the invention may be modified and carried out in a different and equivalent manner. For example, the above process steps can be performed in different steps. Moreover, the invention is not intended to be limited to the details of the architecture or design shown herein, but as described in the following claims. Therefore, it is apparent that modifications and variations can be made to the specific embodiments disclosed above, and all such modifications are within the scope and spirit of the invention. It is to be noted that the use of terms such as "first", "second", "third" or "fourth", used to describe various processes or structures in the specification and the appended claims, is only used. Making a quick reference to such steps/structures does not necessarily mean that such steps/structures are performed/formed in order. Of course, depending on the exact language of the patent application, the order of such processes may or may not be required. Accordingly, the scope of the claimed invention is as described in the following claims.

Claims (20)

一種非揮發性儲存元件,包括:溝道區,形成於半導體材料中;控制電極結構,經設置以控制經過該溝道區的電流;第一儲存機制,經設置以調節該溝道區的閾值電壓的值;以及第二儲存機制,經設置以調節該閾值電壓的該值,該第二儲存機制包括鐵電材料並經配置以能夠結合該第一儲存機制選擇該溝道區的該閾值電壓的兩個以上不同的值。 A non-volatile storage element comprising: a channel region formed in a semiconductor material; a control electrode structure configured to control current flow through the channel region; a first storage mechanism configured to adjust a threshold of the channel region a value of the voltage; and a second storage mechanism configured to adjust the value of the threshold voltage, the second storage mechanism comprising a ferroelectric material and configured to select the threshold voltage of the channel region in conjunction with the first storage mechanism Two or more different values. 如申請專利範圍第1項所述的非揮發性儲存元件,其中,該第一儲存機制與該第二儲存機制的該鐵電材料經設置以沿相對該溝道區的電流方向基本垂直的方向夾置該溝道區。 The non-volatile storage element of claim 1, wherein the first storage mechanism and the ferroelectric material of the second storage mechanism are disposed to be substantially perpendicular to a direction of current flow relative to the channel region. The channel region is sandwiched. 如申請專利範圍第1項所述的非揮發性儲存元件,其中,該第二儲存機制的該鐵電材料設於與該溝道區接觸形成的埋藏絕緣層中。 The non-volatile storage element of claim 1, wherein the ferroelectric material of the second storage mechanism is disposed in a buried insulating layer formed in contact with the channel region. 如申請專利範圍第1項所述的非揮發性儲存元件,其中,該第一儲存機制包括另外的鐵電材料。 The non-volatile storage element of claim 1, wherein the first storage mechanism comprises an additional ferroelectric material. 如申請專利範圍第1項所述的非揮發性儲存元件,其中,該第一儲存機制包括電荷捕獲層。 The non-volatile storage element of claim 1, wherein the first storage mechanism comprises a charge trapping layer. 如申請專利範圍第1項所述的非揮發性儲存元件,其中,該第二儲存機制的該鐵電材料形成於該控制電極 結構中。 The non-volatile storage element of claim 1, wherein the ferroelectric material of the second storage mechanism is formed on the control electrode In the structure. 如申請專利範圍第1項所述的非揮發性儲存元件,其中,該第一儲存機制具有用以調節該閾值電壓的該值的第一效率且該第二儲存機制具有用以調節該閾值電壓的該值的第二效率,以及其中,該第一效率不同於該第二效率。 The non-volatile storage element of claim 1, wherein the first storage mechanism has a first efficiency for adjusting the value of the threshold voltage and the second storage mechanism has a threshold voltage for adjusting the threshold voltage The second efficiency of the value, and wherein the first efficiency is different from the second efficiency. 如申請專利範圍第1項所述的非揮發性儲存元件,其中,該第一儲存機制實施於該控制電極結構中。 The non-volatile storage element of claim 1, wherein the first storage mechanism is implemented in the control electrode structure. 如申請專利範圍第1項所述的非揮發性儲存元件,更包括與該溝道區連接的汲區及源區,以基於埋藏絕緣層形成電晶體配置。 The non-volatile storage element of claim 1, further comprising a germanium region and a source region connected to the channel region to form a transistor configuration based on the buried insulating layer. 一種非揮發性儲存電晶體元件,包括:溝道區;閘極電極結構,經設置以控制該溝道區中的電流;以及埋藏絕緣層,形成於該溝道區下方,該埋藏絕緣層包括鐵電材料,以提供以非揮發性方式儲存資訊的儲存機制。 A non-volatile storage transistor component, comprising: a channel region; a gate electrode structure disposed to control current in the channel region; and a buried insulating layer formed under the channel region, the buried insulating layer including Ferroelectric materials to provide a storage mechanism for storing information in a non-volatile manner. 如申請專利範圍第10項所述的非揮發性儲存電晶體元件,其中,該閘極電極結構包括另外儲存機制,該另外儲存機制結合該儲存機制提供兩個以上非揮發性邏輯狀態。 The non-volatile storage transistor component of claim 10, wherein the gate electrode structure comprises an additional storage mechanism that provides more than two non-volatile logic states in conjunction with the storage mechanism. 如申請專利範圍第10項所述的非揮發性儲存電晶體元件,其中,該閘極電極結構包括鐵電材料作為該另外儲 存機制的組分。 The non-volatile storage transistor component of claim 10, wherein the gate electrode structure comprises a ferroelectric material as the additional storage The components of the deposit mechanism. 如申請專利範圍第10項所述的非揮發性儲存電晶體元件,其中,該閘極電極結構包括鐵電材料及電荷捕獲材料的至少其中之一作為該另外儲存機制的組分。 The non-volatile storage transistor component of claim 10, wherein the gate electrode structure comprises at least one of a ferroelectric material and a charge trapping material as a component of the additional storage mechanism. 如申請專利範圍第11項所述的非揮發性儲存電晶體元件,其中,該儲存機制具有用以調節該溝道區的閾值電壓的值的第一效率且該另外儲存機制具有用以調節該閾值電壓的該值的第二效率,以及其中,該第一效率不同於該第二效率。 The non-volatile storage transistor component of claim 11, wherein the storage mechanism has a first efficiency to adjust a value of a threshold voltage of the channel region and the additional storage mechanism has a A second efficiency of the value of the threshold voltage, and wherein the first efficiency is different from the second efficiency. 如申請專利範圍第10項所述的非揮發性儲存電晶體元件,更包括形成於該埋藏絕緣層下方以在該鐵電材料中施加電場的電極材料。 The non-volatile storage transistor element of claim 10, further comprising an electrode material formed under the buried insulating layer to apply an electric field in the ferroelectric material. 一種操作非揮發性儲存元件的方法,該方法包括:選擇在電晶體元件的溝道區附近所形成的鐵電材料的第一極化狀態;選擇在該溝道區附近所形成的電荷捕獲材料及第二鐵電材料的至少其中之一的第一儲存狀態;向由該第一極化狀態及該第一儲存狀態誘發的第一溝道環境分配第一邏輯狀態;選擇電荷捕獲材料及第二鐵電材料的該至少其中之一的第二儲存狀態;向由該第一極化狀態及該第二儲存狀態誘發的第二溝道環境分配第二邏輯狀態;以及當結合該鐵電材料的第二極化狀態時,向該第一 及第二儲存狀態的其中之一分配至少一個另外的邏輯狀態,該第一與第二極化狀態互逆。 A method of operating a non-volatile storage element, the method comprising: selecting a first polarization state of a ferroelectric material formed adjacent a channel region of a transistor element; selecting a charge trapping material formed adjacent the channel region And a first storage state of at least one of the second ferroelectric materials; assigning a first logic state to the first channel environment induced by the first polarization state and the first storage state; selecting a charge trapping material and a second storage state of the at least one of the ferroelectric materials; assigning a second logic state to the second channel environment induced by the first polarization state and the second storage state; and when bonding the ferroelectric material The second polarization state, to the first And one of the second storage states is assigned at least one additional logic state, the first and second polarization states being reciprocal. 如申請專利範圍第16項所述的方法,其中,該第一及第二儲存狀態分別對應該第二鐵電材料的第一及第二極化狀態。 The method of claim 16, wherein the first and second storage states respectively correspond to the first and second polarization states of the second ferroelectric material. 如申請專利範圍第16項所述的方法,其中,該第一及第二儲存狀態分別對應該電荷捕獲材料的第一及第二電荷捕獲狀態。 The method of claim 16, wherein the first and second storage states respectively correspond to first and second charge trapping states of the charge trapping material. 如申請專利範圍第16項所述的方法,其中,該第一及第二溝道環境由該溝道區的閾值電壓的值確定。 The method of claim 16, wherein the first and second channel environments are determined by values of threshold voltages of the channel region. 如申請專利範圍第19項所述的方法,其中,向該閾值電壓的至少四個不同值分配邏輯狀態。 The method of claim 19, wherein the logic state is assigned to at least four different values of the threshold voltage.
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