TWI507296B - Green paper and its manufacturing method - Google Patents
Green paper and its manufacturing method Download PDFInfo
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- TWI507296B TWI507296B TW100116373A TW100116373A TWI507296B TW I507296 B TWI507296 B TW I507296B TW 100116373 A TW100116373 A TW 100116373A TW 100116373 A TW100116373 A TW 100116373A TW I507296 B TWI507296 B TW I507296B
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- 238000004519 manufacturing process Methods 0.000 title claims description 29
- 239000000463 material Substances 0.000 claims description 73
- 239000002861 polymer material Substances 0.000 claims description 44
- 239000000843 powder Substances 0.000 claims description 41
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 35
- 229910010272 inorganic material Inorganic materials 0.000 claims description 35
- 239000011147 inorganic material Substances 0.000 claims description 35
- 239000002245 particle Substances 0.000 claims description 35
- 238000003490 calendering Methods 0.000 claims description 28
- 239000011368 organic material Substances 0.000 claims description 27
- 238000002156 mixing Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 21
- 238000009472 formulation Methods 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 17
- 239000004698 Polyethylene Substances 0.000 claims description 14
- 229920000573 polyethylene Polymers 0.000 claims description 14
- 239000004743 Polypropylene Substances 0.000 claims description 12
- -1 polypropylene Polymers 0.000 claims description 12
- 229920001155 polypropylene Polymers 0.000 claims description 12
- 239000004088 foaming agent Substances 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- 235000012211 aluminium silicate Nutrition 0.000 claims description 5
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 5
- 239000004626 polylactic acid Substances 0.000 claims description 5
- 238000005096 rolling process Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 4
- 238000004898 kneading Methods 0.000 claims description 3
- 241000609240 Ambelania acida Species 0.000 claims description 2
- 244000017020 Ipomoea batatas Species 0.000 claims description 2
- 235000002678 Ipomoea batatas Nutrition 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- 238000004026 adhesive bonding Methods 0.000 claims description 2
- 239000010905 bagasse Substances 0.000 claims description 2
- 235000005822 corn Nutrition 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims description 2
- 229920001592 potato starch Polymers 0.000 claims 1
- 239000000123 paper Substances 0.000 description 150
- 238000005516 engineering process Methods 0.000 description 14
- 230000007613 environmental effect Effects 0.000 description 13
- 229920001131 Pulp (paper) Polymers 0.000 description 12
- 238000004064 recycling Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- 239000000835 fiber Substances 0.000 description 8
- 238000000227 grinding Methods 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000004806 packaging method and process Methods 0.000 description 7
- 230000008569 process Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 229920002472 Starch Polymers 0.000 description 5
- 239000004566 building material Substances 0.000 description 5
- 238000005520 cutting process Methods 0.000 description 5
- 230000001965 increasing effect Effects 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 4
- 238000011049 filling Methods 0.000 description 4
- 235000012055 fruits and vegetables Nutrition 0.000 description 4
- 239000010893 paper waste Substances 0.000 description 4
- 239000004575 stone Substances 0.000 description 4
- 230000003139 buffering effect Effects 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 240000007182 Ochroma pyramidale Species 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000003851 corona treatment Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000004079 fireproofing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000003911 water pollution Methods 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 244000061456 Solanum tuberosum Species 0.000 description 1
- 235000002595 Solanum tuberosum Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 235000021022 fresh fruits Nutrition 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000036561 sun exposure Effects 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Landscapes
- Paper (AREA)
Description
本發明係有關於一種綠色環保紙及其製造方法，尤指一種採用包括有高分子材料與無機材料所組成之特殊配方材料，進而混製而成環保紙的技術。The invention relates to a green environmental protection paper and a manufacturing method thereof, in particular to a technology comprising a special formulation material comprising a polymer material and an inorganic material, and then mixed into an environmentally friendly paper.
依據目前所知，每生產一公噸的紙漿需要四公噸的木片，相當於砍伐二十三株左右的樹木，由於紙漿需求量的大增，以致大量砍伐森林之情事非常普遍，因而連帶使得各地森林面積逐漸的縮小。大量砍伐森林不僅會影響到自然生態的平衡，而且是地球暖化的元兇之一。此外，傳統紙漿製紙法必須利用大量的水及化學藥劑來漂白木漿，從而造成河川及海洋等寶貴水資源遭受到污染，因此，世界各國無不一方面擴大人工造林的面積，另一方面積極開發紙漿的替代品。According to current knowledge, for every metric ton of pulp produced, four metric tons of wood chips are required, which is equivalent to cutting down about 23 trees. Due to the large increase in pulp demand, a large number of deforestation is very common, which leads to the forests everywhere. The area is gradually shrinking. A large number of deforestation will not only affect the balance of natural ecology, but also be one of the culprit of global warming. In addition, the traditional pulp papermaking method must use a large amount of water and chemicals to bleach the wood pulp, thereby causing pollution of valuable water resources such as rivers and oceans. Therefore, all countries in the world have expanded the area of artificial afforestation on the one hand, and actively Develop alternatives to pulp.
有鑑於習知以木漿製造紙張所產生的嚴重環保問題，已有許多的研究者投入在綠色環保紙的研究，綠色環保紙俗稱石頭紙，是紙漿替代品中較為可行的新興商品選項。環保紙的製備方法是以大量之無機礦粉配合樹脂所混製而成。由於上述環保紙可經日曬後自行脆化而回歸大地，所以不會造成環境上的二次污染，且經過回收的紙張可直接送進焚化爐內焚燒，不會產生黑煙與毒氣，故餘留下的無機礦粉可以再次地回歸大地。再者，環保紙非以木漿製成，於製造過程中不再需要木漿，故而不需要為了製造紙張而大量砍伐樹木，而且也不需要使用大量的水源來調製木漿，故不會有水源污染的問題產生，更何況，使用過的廢紙可以回收再生以及回收掩埋，因此，上述環保紙已逐漸受到世人的矚目與重視。In view of the serious environmental problems caused by the use of wood pulp to make paper, many researchers have invested in green paper research. Green paper, commonly known as stone paper, is a viable emerging commodity option in pulp substitutes. The preparation method of environmentally friendly paper is a mixture of a large amount of inorganic mineral powder and a resin. Since the above-mentioned environmentally-friendly paper can return to the earth after self-embroiding after sun exposure, it will not cause secondary pollution on the environment, and the recycled paper can be directly sent to the incinerator for incineration without causing black smoke and poisonous gas. The remaining inorganic mineral powder can return to the earth again. Furthermore, environmentally friendly paper is not made of wood pulp, and no wood pulp is needed in the manufacturing process. Therefore, it is not necessary to cut down trees in order to manufacture paper, and it is not necessary to use a large amount of water to prepare wood pulp, so there is no The problem of water pollution has arisen. Moreover, used waste paper can be recycled and recycled. Therefore, the above-mentioned environmentally-friendly paper has gradually attracted the attention and attention of the world.
目前習知的環保紙雖具有環保的功效，惟通常所使用的環保紙其所添加之無機礦粉的粒徑大多為10um以上，其紙張表面粗糙度很高，不僅紙張品質不佳，而且手模觸感不良。再者有特殊使用的環保紙其無機材料的粒徑是奈米級，雖可使紙張表面平滑，但成本極高。雖有許多研究者或廠商針對環保紙進行研發及改善，並申請為如下所列之專利申請案，但由於目前習知及前案技術在製造上仍有許多待努力克服的問題，例如配方的設計及成型技術相互搭配等問題，以致目前尚無一種較具有經濟價值的環保紙被大量地推廣。At present, the environmentally-friendly paper of the prior art has an environmentally-friendly effect, but the particle size of the inorganic mineral powder added by the commonly used environmentally-friendly paper is mostly 10 um or more, and the surface roughness of the paper is high, not only the paper quality is poor, but also the hand The mold is not pleasant to touch. In addition, there is a special use of environmentally friendly paper whose inorganic material has a particle size of nanometer, which makes the paper surface smooth, but the cost is extremely high. Although many researchers or manufacturers have developed and improved environmentally-friendly papers and applied for the patent applications listed below, there are still many problems to be overcome in the manufacture of conventional and prior-art technologies, such as formulas. The design and molding technology are intertwined, so that there is no more economical value of environmentally friendly paper.
前述所提的專利案，例如台灣發明公告第581791號『高光澤碳酸鈣塗料組合物及經塗覆紙張以及由其製得之紙板』專利案，其包含第一及第二不連續文石沉澱碳酸鈣(PCC)粒子之摻配物，第一種澱碳酸鈣(PCC)粒子之平均粒徑(APS)約0.4微米，第二種粒子澱碳酸鈣(PCC)之平均粒徑(APS)約0.5微米，第一種0.4微米粒子對第二種0.5微米粒子的重量比例為由約50：50到約80：20，更佳為60：40重量比例。該習用結構雖然具有符合環保需求、回收再生以及回收掩埋等之特點，惟，該習用結構仍有下列之缺點：The aforementioned patents, for example, Taiwan Inventions Publication No. 581791 "High-gloss calcium carbonate coating composition and coated paper and paperboard made therefrom", including first and second discontinuous aragonite precipitates A blend of calcium carbonate (PCC) particles, an average particle size (APS) of the first calcium carbonate (PCC) particles of about 0.4 microns, and an average particle size (APS) of the second particle calcium carbonate (PCC). 0.5 microns, the weight ratio of the first 0.4 micron particle to the second 0.5 micron particle is from about 50:50 to about 80:20, more preferably 60:40 by weight. Although the conventional structure has the characteristics of meeting environmental protection requirements, recycling, and recycling, the conventional structure still has the following disadvantages:
1.該專利案之第一、第二種粒子澱碳酸鈣之平均粒徑(APS)分別為0.4及0.5微米，所以石材必須經過特殊的研磨製程，機械設備成本高，致使製造成本相對大幅增加，由於成本價格較一般紙張高，所以該習用結的經濟價值不高，因而無法有效大量產製而普及。1. The average particle size (APS) of the first and second particle-calcium carbonates in the patent case is 0.4 and 0.5 micron, respectively, so the stone must undergo a special grinding process, and the cost of mechanical equipment is high, resulting in a relatively large increase in manufacturing costs. Since the cost price is higher than that of ordinary paper, the economic value of the conventional use is not high, so it cannot be effectively mass-produced and popularized.
2.該專利案之技術，單純以高分子及微粒徑無機材料混製，所製成之紙張因無機材料重，過於柔軟，紙質無法接近一般木漿紙，使用上仍存在諸多不便的缺失，故而無法大量普及。2. The technology of the patent case is simply mixed with polymer and micro-sized inorganic materials. The paper made is too heavy due to inorganic materials, and the paper cannot be close to the general wood pulp paper. There are still many inconveniences in use. Therefore, it cannot be widely used.
3.該專利案之技術並無添加發泡劑，因此，依其方法所產製的環保紙無法減輕重量及降低成本，以致無法作為具備緩衝功效之裝運填充紙材、包裝紙、瓦楞紙或是紙箱等之用途。3. The technology of this patent does not add a foaming agent. Therefore, the environmentally-friendly paper produced by the method cannot reduce the weight and reduce the cost, so that it cannot be used as a buffering paper, wrapping paper, corrugated paper or The use of cartons, etc.
4.該專利案之技術並無添加防火材料，因此，依其方法所產製的環保紙不具防火功能。4. The technology of this patent does not add fireproof materials. Therefore, the environmentally friendly paper produced according to the method does not have a fireproof function.
再者，例如台灣發明公開第31024501『石頭紙之製造技術』，係由PE與奈米碳酸鈣所共同混合而成，其中PE塑膠材料介所佔之填充量為3~90%，奈米碳酸鈣係由粒徑大小介於30~100nm之奈米顆粒之碳酸鈣所聚結構成，奈米碳酸鈣填充量可於石頭紙內佔10~97%。該習用結構雖然添加有高分子材料如聚丙烯(PP)以及聚乙烯(PE)，因而使得其製成的紙張質地相對較台灣發明第581791號專利為柔軟，惟，該習用結構仍有下列之缺點：Furthermore, for example, Taiwan Invention Disclosure No. 31024501 "Manufacturing Technology of Stone Paper" is made by mixing PE and nano calcium carbonate, wherein the filling amount of PE plastic material is 3 to 90%, and nanocarbonic acid is used. Calcium is formed by the aggregation of calcium carbonate with a particle size of 30-100 nm. The filling amount of nano-calcium carbonate can account for 10~97% in stone paper. Although the conventional structure is added with a polymer material such as polypropylene (PP) and polyethylene (PE), the texture of the paper made is relatively softer than the patent of Taiwan Invention No. 581791, but the conventional structure still has the following Disadvantages:
1.該專利案之奈米碳酸鈣平均粒徑介於30~100奈米，粒徑微小，必須經過特殊的研磨製程方能使粒徑達到奈米的等級，機械設備成本高，致使製造成本相對大幅增加，由於成本價格較一般紙張高，所以該習用結的經濟價值不高，因而無法有效大量產製而普及。1. The average particle size of nano calcium carbonate in the patent case is between 30 and 100 nanometers, and the particle size is small. It must be subjected to a special grinding process to achieve the particle size of nanometer, and the cost of mechanical equipment is high, resulting in manufacturing cost. Relatively large increase, because the cost price is higher than the average paper, the economic value of the customary knot is not high, so it cannot be effectively mass-produced and popularized.
2.該專利案僅由塑膠及奈米碳酸鈣混製而成，並無添加有機材料如植物纖維或是植物澱粉，因奈米碳酸鈣重量大，過於柔軟，紙質無法接近一般木漿紙，使用上仍存在諸多不便的缺失，大幅影響紙張的應用層面，故而無法大量普及。2. The patent case is only made of plastic and nano calcium carbonate. There is no organic material such as plant fiber or vegetable starch. The nanometer calcium carbonate is too heavy and too soft, and the paper cannot be close to the general wood pulp paper. There are still many inconveniences in use, which greatly affect the application level of paper, so it cannot be widely used.
3.該專利案之技術並無添加發泡劑，因此，依其方法所產製的環保紙無法減輕重量及降低成本，以致無法作為具備緩衝功效之裝運填充紙材、包裝紙、瓦楞紙或是紙箱等之用途。3. The technology of this patent does not add a foaming agent. Therefore, the environmentally-friendly paper produced by the method cannot reduce the weight and reduce the cost, so that it cannot be used as a buffering paper, wrapping paper, corrugated paper or The use of cartons, etc.
4.該專利案之技術並無添加防火材料，因此，依其方法所產製的環保紙不具防火功能。4. The technology of this patent does not add fireproof materials. Therefore, the environmentally friendly paper produced according to the method does not have a fireproof function.
本發明第一目的，在於提供一種增進綠色環保紙之可行性的製造方法，本發明採用之礦石粉體粒徑不需研磨至極微小甚至到奈米的程度即可與高分子材料共混製成表面平滑的環保紙，不僅可以降低設備成本，而且生產速度快，並可放大生產，使環保紙普及而取代傳統紙張的可行性大為增加，因而具有成本低、不用水資源、不用紙漿、無廢水污染、不需砍樹、不用鍋爐與蒸汽以及較不耗能源不會產生造紙污泥等特點。為達成前述第一目的，本發明之技術手段，係採用15~25%重量百分比的高分子材料及75~85%重量百分比且粒徑介於1~5μm之間的礦石粉體，經壓延成型技術而成型環保紙。The first object of the present invention is to provide a manufacturing method for improving the feasibility of green paper. The ore powder particle size used in the present invention can be blended with a polymer material without grinding to a very small degree or even to a nanometer. The smooth surface of the environmentally-friendly paper not only can reduce the equipment cost, but also has a high production speed and can enlarge the production. The feasibility of replacing the traditional paper is greatly increased, so the cost is low, no water resources, no pulp, no Wastewater pollution, no need to cut trees, no boilers and steam, and less energy consumption will not produce paper sludge. In order to achieve the foregoing first object, the technical means of the present invention is to use 15 to 25% by weight of a polymer material and 75 to 85% by weight of ore powder having a particle diameter of between 1 and 5 μm, and calendered. Technology and molding of environmentally friendly paper.
本發明第二目的，在於提供一種利用天然有機材料以改良其特性之綠色環保紙及其製造方法，主要係由製程中添加有機材料來取代部分之高分子材料，藉以降低生產成本，不僅具有第一目的的功效，而且可以增加紙張的挺度，使環保紙更接近木漿紙的質地，因而具有符合環保的需求、可增強紙張的接著性及挺度、廢棄紙張可重復回收再利用、可生物分解、廢棄蔬果可再利用、維護自然生態平衡、擴大環保紙應用層面及有效普及等諸多功效與優點。為達成前述第二目的，本發明之技術手段，係採用10~25%重量百分比的高分子材料、55~85%重量百分比且粒徑介於1~5μm之間的礦石粉體及10~25%重量百分比的有機材料，經壓延成型技術而成型環保紙。A second object of the present invention is to provide a green paper and a method for manufacturing the same by using a natural organic material to improve its characteristics, mainly by adding an organic material to replace a part of the polymer material in the process, thereby reducing the production cost, and not only having the first The purpose of the purpose, but also can increase the stiffness of the paper, so that the environmentally friendly paper is closer to the texture of wood pulp paper, so it has the requirements of environmental protection, can enhance the adhesion and stiffness of the paper, and can be recycled and reused. Bio-decomposition, waste of fruits and vegetables can be reused, maintain natural ecological balance, expand the application level of environmentally friendly paper and effectively popularize many functions and advantages. In order to achieve the foregoing second object, the technical means of the present invention is to use 10 to 25% by weight of a polymer material, 55 to 85% by weight of ore powder having a particle diameter of between 1 and 5 μm, and 10 to 25 % by weight of organic material, formed by environmental engineering using calendering technology.
本發明第三目的在於提供一種具緩衝功效並可減輕重量以降低生產成本的綠色環保紙，不僅具有第一目的的功效，而且可以取代傳統之包裝用紙、紙箱、包裝緩衝紙材或是瓦楞紙。為達成前述第三目的，本發明採用之技術手段，係採用10~25%重量百分比的高分子材料、55~85%重量百分比且粒徑介於1~5μm之間的礦石粉體及特定量的發泡劑，經壓延成型技術而成型環保紙。A third object of the present invention is to provide a green paper with cushioning effect and light weight reduction to reduce production cost, which not only has the first purpose effect, but also can replace the traditional packaging paper, carton, packaging cushion paper or corrugated paper. In order to achieve the foregoing third object, the technical means adopted by the present invention is to use 10 to 25% by weight of a polymer material, 55 to 85% by weight of ore powder having a particle diameter of between 1 and 5 μm, and a specific amount. The foaming agent is formed into a green paper by calendering technology.
本發明第四目的在於提供一種具防火功效的綠色環保紙，不僅具有第一目的的功效，而且可作為防火材以應用在各式防火披覆材料的用途領域上，藉以取代傳統壁紙或是作為建材、傢俱披覆層的貼皮。為達成前述第四目的，係採用10~25%重量百分比的高分子材料、55~85%重量百分比且粒徑介於1~5μm之間的礦石粉體及特定量的防火材料，經壓延成型技術而成型環保紙。The fourth object of the present invention is to provide a green paper with fireproof effect, which not only has the effect of the first purpose, but also can be used as a fireproof material in the field of use of various fireproof covering materials, thereby replacing the traditional wallpaper or The skin of building materials and furniture coverings. In order to achieve the above fourth objective, 10 to 25% by weight of polymer material, 55 to 85% by weight of ore powder having a particle diameter of between 1 and 5 μm, and a specific amount of fireproof material are used for calendering. Technology and molding of environmentally friendly paper.
本發明之技術概念在於具體實現綠色環保紙之可行性，並且可以依據紙張的應用特性而選擇不同配方，以製備出不同材料特性的綠色環保紙，例如一般書寫紙張、印刷用紙張、包裝用紙、裝運用途之填充紙材、紙箱、防火塗佈紙材、壁紙或是傢俱、建材的防火貼皮等。並可由廢棄回收的蔬果或是新鮮蔬果中採集植物纖維，以改良紙張的特性，不僅紙張具環保，可廢物利用，而且植物纖維中的天然色素，可使紙張自然具備顏色效果。此外，本發明採用之礦石粉體粒徑不需研磨至極微小甚至到奈米的程度(本發明初步推估粒徑約0.5μm~10μm之間，而實作上粒徑約在1μm~5μm之間)，即可與高分子材料共混製成環保紙，不僅可以大幅降低生產成本，並可放大生產，進而使得環保紙普及而取代傳統紙張的可行性大為增加。再者，藉由製程中所添加之植物纖維或是澱粉等有機材料，不僅可以增加紙張挺度，使環保紙更接近木漿紙的質地，而可增進使用方便性及增加環保紙的應用層面，因而具有符合環保需求、具防水特性、廢棄紙張重復回收循環再利用、可將廢棄的天然蔬果再利用、維護自然生態的平衡等諸多的特點。The technical concept of the present invention is to realize the feasibility of concrete green paper, and different formulas can be selected according to the application characteristics of paper to prepare green paper with different material properties, such as general writing paper, printing paper, packaging paper, Filling paper, carton, fire-resistant coated paper, wallpaper for shipping purposes, or fireproof covering for furniture and building materials. The plant fiber can be collected from discarded fruits and vegetables or fresh fruits and vegetables to improve the characteristics of the paper. The paper is environmentally friendly and can be used for waste, and the natural pigment in the plant fiber can make the paper naturally have a color effect. In addition, the ore powder particle size used in the present invention does not need to be ground to a very small extent or even to the extent of nanometer (the present invention preliminarily estimates that the particle diameter is between about 0.5 μm and 10 μm, and the actual particle diameter is about 1 μm to 5 μm. In addition, it can be blended with polymer materials to make environmentally-friendly paper, which not only can greatly reduce the production cost, but also can enlarge the production, and the feasibility of replacing the traditional paper with the popularity of environmentally-friendly paper is greatly increased. Furthermore, by adding plant fibers or organic materials such as starch in the process, it is possible not only to increase the stiffness of the paper, but also to make the environmentally friendly paper closer to the texture of the wood pulp paper, thereby improving the usability and increasing the application level of the environmentally friendly paper. Therefore, it has many characteristics such as meeting environmental protection requirements, waterproofing characteristics, recycling and recycling of waste paper, recycling of discarded natural fruits and vegetables, and maintaining the balance of natural ecology.
再者，可於製程中添加有機材料來取代部分之高分子材料，藉以更進一步降低生產成本，不僅可以增加紙張的延展性、可彎折性以及挺度，並可透過生物分解而回歸大地，因而具有符合環保的需求、可增強紙張的接著性及挺度、廢棄紙張可重復回收再利用、廢棄蔬果可再利用以及維護自然生態平衡等諸多的特點。Furthermore, organic materials can be added to the process to replace some of the polymer materials, thereby further reducing the production cost, not only increasing the ductility, bendability and stiffness of the paper, but also returning to the earth through biolysis. Therefore, it has the characteristics of complying with environmental protection, enhancing the adhesion and stiffness of paper, recycling and recycling of waste paper, recycling of discarded fruits and vegetables, and maintaining natural ecological balance.
請參看第一、七圖所示，本發明為達成前述第一目的之具體實施例，其環保紙(10)是由第一材料配方混煉並利用壓延成型技術所製造而成，環保紙(10)成品之紙張厚度介於50~700μm之間。第一材料配方包括高分子材料(1a)與無機材料(1b)，其中，高分子材料(1a)佔15~25%重量百分比，無機材料(1b)佔75~85%重量百分比，且無機材料(1b)之平均粒徑介於1μm~5μm之間，而可獲得表面平滑的環保紙(10)成品。至於高分子材料(1a)的具體實施例可以是聚丙烯(PP)、聚乙烯(PE)或是聚乳酸(Poly Lactic Acid,PLA)至少其中一種塑膠材料，無毒性，且具有可分解特性。本發明無機材料(1b)之具體實施例可以碳酸鈣粉(Calcium Carbonate)、高嶺土或是二氧化鈦(TiO2 )至少其中一種礦石粉體，實驗例中礦石粉體經篩選為平均粒徑介於1~5μm之間。Referring to the first and seventh figures, the present invention is a specific embodiment for achieving the foregoing first object, and the environmentally friendly paper (10) is prepared by kneading a first material formulation and using a calendering technique, and the eco-friendly paper ( 10) The paper thickness of the finished product is between 50 and 700 μm. The first material formulation comprises a polymer material (1a) and an inorganic material (1b), wherein the polymer material (1a) accounts for 15 to 25% by weight, the inorganic material (1b) accounts for 75 to 85% by weight, and the inorganic material (1b) The average particle size is between 1 μm and 5 μm, and a smooth surface of the environmentally friendly paper (10) can be obtained. As a specific example of the polymer material (1a), it may be at least one of polypropylene (PP), polyethylene (PE) or polylactic acid (PLA), which is non-toxic and has decomposable properties. The specific embodiment of the inorganic material (1b) of the present invention may be at least one of ore powder of calcium carbonate powder, kaolin or titanium dioxide (TiO 2 ). In the experimental example, the ore powder is screened to have an average particle diameter of 1 ~5μm between.
於本發明的一種實驗例中，無機材料(1b)與高分子材料(1a)的混合比例為80：20重量百分比時，由於高分子材料(1a)的成本較高，故可藉由減少高分子材料(1a)的添加比例來降低生產成本，並可加快環保紙的生產速度；又，本發明人於實驗例中發現，當礦石粉體平均粒徑在1~5μm之間時，不僅，無機材料(1b)於環保紙中的填充率可達百分之八十，紙張的表面平滑度較佳，而且可以降低無機材料(1b)(即礦石粉體)的研磨成本，亦即可使紙張表面平滑度與研磨成本之間取得平衡。In an experimental example of the present invention, when the mixing ratio of the inorganic material (1b) and the polymer material (1a) is 80:20% by weight, since the cost of the polymer material (1a) is high, it can be reduced by The addition ratio of the molecular material (1a) reduces the production cost and accelerates the production speed of the environmentally-friendly paper. Moreover, the inventors found in the experimental example that when the average particle diameter of the ore powder is between 1 and 5 μm, not only The filling rate of the inorganic material (1b) in environmentally friendly paper can reach 80%, the surface smoothness of the paper is better, and the grinding cost of the inorganic material (1b) (ie, ore powder) can be reduced, and A balance is achieved between paper surface smoothness and grinding costs.
請參看第二、七圖所示，本發明為達成前述第二目的之具體 實施例，其環保紙(10)是由第二材料配方混煉並利用壓延成型技術所製造而成，主要是添加有機材料以取代部分的高分子材料，藉以降低生產成本，以及增加紙張的挺度，使所製成之環保紙更接近木漿紙之質地。本發明在此實施例所製成的環保紙(10)的紙張厚度約為50μm左右，以符合更大眾化需求。而且本發明環保紙(10)因添加有機材料，可透過水或是太陽照射而自然分解，或者是透過生物(如生菌)以加快環保紙(10)的分解速度。Please refer to the second and seventh figures, the specifics of the present invention for achieving the aforementioned second object. In an embodiment, the environmentally friendly paper (10) is prepared by mixing a second material formulation and using a calendering technique, mainly by adding an organic material to replace a part of the polymer material, thereby reducing the production cost and increasing the paper. Degree, so that the made environmentally friendly paper is closer to the texture of wood pulp paper. The paper sheet (10) produced by the embodiment of the present invention has a paper thickness of about 50 μm to meet more popular requirements. Moreover, the environmentally-friendly paper (10) of the present invention can be naturally decomposed by water or sun irradiation by adding an organic material, or can be accelerated by an organism (such as a living bacteria) to accelerate the decomposition speed of the eco-friendly paper (10).
本實施例中之第二材料配方包括高分子材料(1a)、無機材料(1b)及有機材料(1c)，其中，高分子材料(1a)所佔重量百分比為10~25%，無機材料(1b)佔55~85%重量百分比，至於有機材料(1c)則佔10~25%重量百分比。高分子材料(1a)之具體實施例可以是聚丙烯(PP)、聚乙烯(PE)或是聚乳酸(Poly Lactic Acid,PLA)至少其中一種塑膠材料；另，無機材料(1b)之具體實施例可以碳酸鈣粉(Calcium Carbonate)、高嶺土或是二氧化鈦(TiO2 )至少其中一種礦石粉體，本發明推估可行的實施例，礦石粉體平均粒徑介於0.5μm~10μm之間。有機材料(1c)之具體實施例可以是植物纖維或是植物澱粉，進一步而言，有機材料(1c)可以是樹薯粉、玉米粉、地瓜粉、甘蔗渣粉、植物纖維粉、蔬果纖維粉、木屑或是澱粉的至少其中一種粉體，有機材料(1c)粉體平均粒徑在1~5μm之間。The second material formulation in this embodiment comprises a polymer material (1a), an inorganic material (1b) and an organic material (1c), wherein the polymer material (1a) accounts for 10 to 25% by weight of the inorganic material ( 1b) accounts for 55~85% by weight, and organic material (1c) accounts for 10~25% by weight. The specific embodiment of the polymer material (1a) may be at least one plastic material of polypropylene (PP), polyethylene (PE) or poly Lactic Acid (PLA); and the specific implementation of the inorganic material (1b) For example, calcium carbonate powder (Calcium Carbonate), kaolin or titanium oxide (TiO 2 ) may be at least one of the ore powders. According to the present invention, the average particle diameter of the ore powder is between 0.5 μm and 10 μm. The specific embodiment of the organic material (1c) may be plant fiber or vegetable starch. Further, the organic material (1c) may be potato powder, corn flour, sweet potato powder, bagasse powder, plant fiber powder, vegetable fiber powder. At least one of the powder of wood chips or starch, and the average particle size of the organic material (1c) powder is between 1 and 5 μm.
於本發明的一種實驗例中，無機材料(1b)、高分子材料(1a)以及有機材料(1c)的混合比例為80：10：10重量百分比時，藉由有機材料的添加可以有效減少高分子材料(1a)的添加比例，藉以降 低生產成本，並使環保紙達到較佳的紙張的挺度及接著性，使環保紙更接近木漿紙的質地，增進使用上的方便性及應用層面。又，本發明於實驗例中，當礦石粉體平均粒徑在1~5μm之間時，不僅紙張的表面平滑度較佳，而且可以降低礦石粉體的研磨成本，換言之，亦即可使紙張表面平滑度與研磨成本之間取得平衡。In an experimental example of the present invention, when the mixing ratio of the inorganic material (1b), the polymer material (1a), and the organic material (1c) is 80:10:10% by weight, the addition of the organic material can effectively reduce the height The proportion of molecular material (1a) added, thereby The low production cost and the environmentally friendly paper achieve better paper stiffness and adhesion, so that the environmentally friendly paper is closer to the texture of wood pulp paper, and the convenience and application level of use are enhanced. Moreover, in the experimental example, when the average particle diameter of the ore powder is between 1 and 5 μm, not only the surface smoothness of the paper is good, but also the grinding cost of the ore powder can be reduced, in other words, the paper can be made. A balance is achieved between surface smoothness and grinding costs.
請參看第三、七圖所示，本發明為達成前述第三目的之具體實施例，其環保紙(10)是由第三材料配方混煉並利用壓延成型技術所製造而成，第三材料配方主要包括高分子材料(1a)、無機材料(1b)及發泡劑(1d)，以成型作為包裝緩衝材，藉以取代傳統之包裝用紙、紙箱、裝運之填充紙材或是瓦楞紙，並可減輕重量而降低生產成本，且環保紙(10)成品的紙張厚度約為700μm左右。本發明實驗例中，第三材料配方包括高分子材料、無機材料、有機材料及發泡劑，其中，高分子材料所佔的重量百分比為10~25%，無機材料(1b)所佔的重量百分比則為55~85%，有機材料所佔的重量百分比為10~25%，發泡劑(1d)所佔的重量百分比則為0.1~5%。實驗例中，高分子材料(1a)可為聚丙烯(PP)、聚乙烯(PE)或是聚乳酸(Poly Lactic Acid,PLA)至少其中一種塑膠材料。而無機材料(1b)可為碳酸鈣粉(Calcium Carbonate)、高嶺土或是二氧化鈦(TiO2 )至少其中一種礦石粉體，此礦石粉體平均粒徑介於1~5μm之間。實驗例中，第三材料配方添加有機材料，其所製成之環保紙可供製成包裝用紙、紙箱、裝運填充紙材以及瓦楞紙，用以增加紙張的延展性、可彎折性、挺度以及接著性，並可透過水或陽光以進行生物自然分解。Referring to Figures 3 and 7, the present invention is a specific embodiment for achieving the foregoing third object, wherein the environmentally friendly paper (10) is compounded by a third material formulation and manufactured by calendering technology, and the third material is used. The formula mainly includes polymer material (1a), inorganic material (1b) and foaming agent (1d), which is used as a packaging cushioning material to replace traditional packaging paper, carton, shipping paper or corrugated paper, and The weight is reduced to reduce the production cost, and the paper thickness of the finished paper of environmentally friendly paper (10) is about 700 μm. In the experimental example of the present invention, the third material formulation comprises a polymer material, an inorganic material, an organic material and a foaming agent, wherein the weight percentage of the polymer material is 10 to 25%, and the weight of the inorganic material (1b) The percentage is 55~85%, the weight percentage of organic materials is 10~25%, and the weight percentage of foaming agent (1d) is 0.1~5%. In the experimental example, the polymer material (1a) may be at least one of polypropylene (PP), polyethylene (PE) or polylactic acid (PLA). The inorganic material (1b) may be at least one of ore powder of calcium carbonate powder, kaolin or titanium dioxide (TiO 2 ), and the ore powder has an average particle diameter of between 1 and 5 μm. In the experimental example, the third material formula is added with organic materials, and the environmentally-friendly paper made thereof can be used for packaging paper, carton, shipping paper and corrugated paper to increase the ductility, bendability and stiffness of the paper. And the adhesion, and through the water or sunlight for the natural decomposition of the organism.
請參看第四、七圖所示，本發明為達成前述第四目的之具體實施例，其環保紙(10)是由第四材料配方混煉並利用壓延成型技術所製造而成，第四材料配方主要包括高分子材料(1a)、無機材料(1b)及防火材料(1e)，以成型作為防火材，而可應用在防火披覆材料的用途領域上，例如壁紙、傢俱或是建材的貼皮。本發明實驗例中，第四材料配方包括高分子材料、無機材料、有機材料及防火材料，其中，高分子材料所佔的重量百分比為10~25%，無機材料(1b)所佔的重量百分比則為55~85%，有機材料所佔的重量百分比為10~25%，防火材料所佔的重量百分比則為0.1~5%。本實驗例中，高分子材料可為聚丙烯(PP)、聚乙烯(PE)或是聚乳酸(Poly Lactic Acid,PLA)至少其中一種塑膠材料。無機材料可為碳酸鈣粉(Calcium Carbonate)、高嶺土或是二氧化鈦(TiO2 )至少其中一種礦石粉體，此礦石粉體平均粒徑介於1~5μm之間。本實驗例中，第四材料配方中添加有機材料，使得依據第四材料配方所製成的壁紙、傢俱貼皮以及建材貼皮可以增加紙張的挺度及接著性，增進使用上的方便性及應用層面，並可透過水或陽光以進行生物自然分解。Referring to the fourth and seventh figures, the present invention is a specific embodiment for achieving the foregoing fourth object, wherein the environmentally friendly paper (10) is prepared by mixing a fourth material formulation and using a calendering technique, the fourth material. The formula mainly includes polymer material (1a), inorganic material (1b) and fireproof material (1e), which can be used as a fireproof material, and can be applied to the application field of fireproof covering materials, such as wallpaper, furniture or building materials. skin. In the experimental example of the present invention, the fourth material formulation comprises a polymer material, an inorganic material, an organic material and a fireproof material, wherein the weight percentage of the polymer material is 10 to 25%, and the weight percentage of the inorganic material (1b) It is 55~85%, the weight percentage of organic materials is 10~25%, and the weight percentage of fireproof materials is 0.1~5%. In the experimental example, the polymer material may be at least one of polypropylene (PP), polyethylene (PE) or polylactic acid (PLA). The inorganic material may be at least one of ore powder of calcium carbonate powder, kaolin or titanium dioxide (TiO 2 ), and the ore powder has an average particle diameter of between 1 and 5 μm. In the experimental example, the organic material is added to the fourth material formula, so that the wallpaper, the furniture skin and the building material skin made according to the fourth material formula can increase the stiffness and the adhesion of the paper, and the convenience of use is improved. At the application level, it can be naturally decomposed by water or sunlight.
請參看第一至四圖所示，本發明製備環保紙(10)的方法，係準備上述之第一材料配方、第二材料配方、第三材料配方或是第四材料配方。依據產製需求而由使用者選擇將第一材料配方、第二材料配方、第三材料配方或第四材料配方送入壓延成型手段(20)中，以壓延成型手段(20)製備出薄片狀的環保紙(10)，經裁切後所得之環保紙(10)成品則如第九圖所示。Referring to Figures 1 to 4, the method for preparing the environmentally friendly paper (10) of the present invention is to prepare the above first material formulation, second material formulation, third material formulation or fourth material formulation. According to the production demand, the user selects the first material formula, the second material formula, the third material formula or the fourth material formula into the calendering means (20), and prepares the flakes by the calendering means (20). The environmentally friendly paper (10), the finished product of the environmentally friendly paper (10) obtained after cutting, is shown in the ninth figure.
本發明所採用的壓延成型手段(20)，其具體實施例係為一種可以高速產製環保紙的機械設備，該機械設備之具體構造包含一研磨機(21)、一進料機(22)、一配方控制單元(23)、一自動計量單元(24)、一混合裝置(25)、一密封式混煉裝置(26)、一第一混煉軋輪裝置(27)、一第二混煉軋輪裝置(28)、一過濾壓出單元(29)、一壓延成型裝置(30)、一冷卻壓平裝置(31)及一自動捲紙裝置(33)，機械設備的方塊圖則如第六圖所示。其中，如第七圖所示，若因需要而須在環保紙上塗覆材料，則在冷卻壓平裝置(31)之後加裝一電暈處理裝置(32)，如此所製成的環保紙，即可供再行塗覆一層材料。再者，如第八圖所示，在自動化製造完成之後，可再於自動捲紙裝置之後加裝一裁切裝置(34)，以將環保紙裁切成所需之大小。The calendering means (20) used in the present invention is a mechanical device capable of producing environmentally-friendly paper at a high speed, and the specific structure of the mechanical device comprises a grinder (21) and a feeder (22). a recipe control unit (23), an automatic metering unit (24), a mixing device (25), a sealed mixing device (26), a first mixing wheel device (27), and a second mixing a refining wheel device (28), a filter extrusion unit (29), a calendering device (30), a cooling and flattening device (31) and an automatic reeling device (33), and the block diagram of the mechanical device is as follows The sixth picture is shown. Wherein, as shown in the seventh figure, if it is necessary to coat the material on the environmentally-friendly paper, a corona treatment device (32) is added after the cooling and flattening device (31), and the environmentally-friendly paper thus produced, That is, it can be coated with a layer of material. Furthermore, as shown in the eighth figure, after the automated manufacturing is completed, a cutting device (34) can be added after the automatic paper winding device to cut the environmentally-friendly paper to a desired size.
請參看第五圖所示，本發明壓延成型手段(20)於製備環保紙(10)的過程中，係包括以下之步驟：Referring to the fifth figure, the calendering means (20) of the present invention comprises the following steps in the process of preparing the environmentally friendly paper (10):
進料混煉步驟：請參看第五、六圖所示，首先置入高分子材料(1a)與無機材料(1b)後予以均勻混合，並對混合之高分子材料(1a)與無機材料(1b)以攝氏90~200度之間的高溫混合煉製為一混合材料。Feed mixing step: Please refer to the fifth and sixth figures. Firstly, the polymer material (1a) and the inorganic material (1b) are placed and uniformly mixed, and the mixed polymer material (1a) and inorganic material ( 1b) Refining to a mixed material at a high temperature between 90 and 200 degrees Celsius.
軋輪膠合步驟：係對第一混煉軋輪裝置(27)與第二混煉軋輪裝置(28)之第一滾輪組加溫至攝氏90~200度，再高溫輥壓該混合材料，以對混合材料做進一步的混煉。Roller gluing step: heating the first roller set of the first mixing and rolling device (27) and the second mixing and rolling device (28) to 90 to 200 degrees Celsius, and then pressing the mixed material at a high temperature. Further mixing of the mixed materials.
壓延步驟：係對壓延成型裝置(30)之第二滾輪組加溫至攝氏90~200度左右，以該滾輪組將該混合材料再做進一步的高溫輥壓，使該混合材料被壓延成為厚度均勻的薄片體。The calendering step is: heating the second roller set of the calendering device (30) to about 90 to 200 degrees Celsius, and further rolling the mixed material into a high temperature by the roller group, so that the mixed material is calendered into a thickness. A uniform sheet.
冷卻定型步驟：係以冷卻壓平機(31)之第三滾輪組將薄片體予以冷卻輥壓，使薄片體被壓平定型為薄片狀且具柔軟特性的環保紙(10)。Cooling and setting step: the sheet is cooled and rolled by a third roller set of the cooling and flattening machine (31), and the sheet is flattened into a sheet-like and soft-colored environmentally friendly paper (10).
包裝步驟：以自動捲紙機(33)將薄片狀的環保紙(10)捲繞成為紙捲成品；再以裁切機(34)將紙捲成品裁切為預定尺寸的平板紙成品；再將平板紙成品予以包裝，如此即可等待出貨。Packing step: the sheet-shaped eco-friendly paper (10) is wound into a finished product of the paper roll by an automatic reeling machine (33); and the finished product of the paper roll is cut into a finished product of a predetermined size by a cutting machine (34); Pack the finished flat paper so that you can wait for shipment.
請參看第六圖所示，上述進料混煉步驟的具體實施例更包含以下之步驟：Referring to the sixth figure, the specific embodiment of the above feed mixing step further comprises the following steps:
(1)以研磨機(21)將石材粉碎研磨至粒徑介於1~5μm之間，以成為碳酸鈣粉(即無機材料)。(1) The stone is pulverized and ground by a grinder (21) to have a particle diameter of between 1 and 5 μm to become a calcium carbonate powder (i.e., an inorganic material).
(2)將高分子材料(1a)、有機材料(1c)、發泡劑(1d)、防火材料(1e)以及助劑分別置入至一進料機(22)內。(2) The polymer material (1a), the organic material (1c), the foaming agent (1d), the fireproofing material (1e), and the auxiliary agent are separately placed in a feeder (22).
(3)以配方控制單元(23)控制進料機(22)輸入所需的上述材料，並提供一操控界面供使用者操控，以決定第一材料配方、第二材料配方、第三材料配方或是第四材料配方為製備環保紙(10)的配方。(3) The recipe control unit (23) controls the feeder (22) to input the required materials, and provides a manipulation interface for the user to control to determine the first material formula, the second material formula, and the third material formula. Or the fourth material formula is a formula for preparing environmentally friendly paper (10).
(4)讓自動計量單元(24)依據配方控制單元(23)所選定配方來控制進料的比例，假設選定為第一材料配方時，自動計量單元(24)則使無機材料(1b)進料的比例為75~85%重量百分比，高分子材料(1a)的比例則為15~25%重量百分比，助劑則控制在一特定量的比例。(4) Let the automatic metering unit (24) control the proportion of the feed according to the recipe selected by the formula control unit (23), and assume that the automatic metering unit (24) causes the inorganic material (1b) to enter when the first material formula is selected. The ratio of the material is 75 to 85% by weight, and the ratio of the polymer material (1a) is 15 to 25% by weight, and the auxiliary agent is controlled to a specific amount.
(5)以混合裝置(25)將混合之各材料予以高速均勻混合。(5) The mixed materials are uniformly mixed at a high speed by a mixing device (25).
(6)以密封式混煉裝置(26)將混合之各材料以攝氏90~200度的高溫混煉製成上述的混合材料。(6) The mixed materials are kneaded at a high temperature of 90 to 200 degrees Celsius in a sealed kneading device (26) to prepare the above-mentioned mixed material.
因此，藉由上述技術特徵的設置，本發明確實具有下列的特點：Therefore, with the above technical features, the present invention does have the following features:
1.本發明所採用之礦石粉體粒徑不需研磨至極微小甚至到奈米的程度即可與高分子材料共混製成環保紙，不用鍋爐和蒸汽，較不耗能源，設備成本低，不需如紙漿造紙的設備投入成本高，而生產速度快，故而成本低。再者，不用水資源，無廢水污染，不用紙漿，不需砍樹，不會產生造紙污泥，故而具極佳環保功能。此外，因原料粒徑小(1μm~5μm)，產品表面平滑。因此，使環保紙普及而取代傳統紙張的可行性大為提高。1. The ore powder particle size used in the invention can be blended with a polymer material to form an environmentally friendly paper without grinding to a very small or even nanometer level, without using boiler and steam, less energy consumption, and low equipment cost. There is no need for high cost of equipment such as pulp and paper, and the production speed is fast, so the cost is low. Moreover, there is no need for water resources, no waste water pollution, no pulp, no need to cut trees, no paper sludge, so it has excellent environmental protection. In addition, the surface of the product is smooth due to the small particle size (1 μm to 5 μm). Therefore, the feasibility of making environmentally friendly papers popular and replacing traditional papers has been greatly improved.
2.本發明可藉由高分子材料、礦石粉及添加植物纖維或是澱粉等有機材料所構成的特殊配方，所製成之環保紙，不僅如前述具有成本低、極佳環保及表面平滑等功效，並利用有機材料部份取代高分子材料，進一步降低成本，而且可以增加紙張的挺度，使環保紙更接近木漿紙之質地，增進使用上的方便性及應用層面，並具生物分解性，而可擴大環保紙的應用層面，因而具有符合環保需求、具防水特性、廢棄紙張重復回收循環再利用、不會污染水源以及不需砍伐樹林以維護自然生態的平衡等諸多的特點。2. The invention can be made of a special formula composed of a polymer material, an ore powder and an organic material such as plant fiber or starch, and the environmentally-friendly paper prepared is not only low in cost, excellent in environmental protection, and smooth in surface as described above. Efficacy, and the use of organic materials to replace the polymer material, further reduce the cost, and can increase the stiffness of the paper, make the environmentally friendly paper closer to the texture of wood pulp paper, improve the convenience and application level of use, and have biological decomposition It can expand the application level of environmentally friendly paper, so it has many characteristics such as environmental protection requirements, waterproof characteristics, repeated recycling and recycling of waste paper, no pollution of water sources, and no need to cut down trees to maintain the balance of natural ecology.
3.本發明可藉由高分子材料、礦石粉及添加發泡劑等所構成的特殊配方，所製成之環保紙，不僅如前述具有成本低、極佳環保及表面平滑等功效，並具生物分解性，而且使環保紙具備緩衝功效，並可減輕重量以降低生產成本，藉以取代傳統之包裝用紙、紙箱、裝運之填充紙材或是瓦楞紙。3. The invention can be made of a special formula composed of a polymer material, an ore powder and a foaming agent, and the environmentally-friendly paper prepared by the invention has the advantages of low cost, excellent environmental protection and smooth surface as described above. It is biodegradable, and it enables the environmentally friendly paper to have a buffering effect and can reduce the weight to reduce the production cost, so as to replace the traditional packaging paper, carton, shipping paper or corrugated paper.
4.本發明可藉由高分子材料、礦石粉及添加防火材料所構成的特殊配方，其所製成之環保紙，不僅如前述具有成本低、極佳環保及表面平滑等功效，而且使環保紙具備防火功效，故可應用在防火披覆材料之用途領域上，藉以取代傳統壁紙或是作為建材、傢俱披覆層的貼皮。4. The invention can be made of a special formula composed of a polymer material, an ore powder and a fireproofing material, and the environmentally-friendly paper prepared by the invention not only has the advantages of low cost, excellent environmental protection and smooth surface, but also environmental protection. Paper has a fire-proof effect, so it can be used in the field of fire-proof covering materials to replace traditional wallpaper or as a covering for building materials and furniture coverings.
以上所述，僅為本發明之一可行實施例，並非用以限定本發明之專利範圍，凡舉依據下列請求項所述之內容、特徵以及其精神而為之其他變化的等效實施，皆應包含於本發明之專利範圍內。本發明所具體界定於請求項之結構特徵，未見於同類物品，且具實用性與進步性，已符合發明專利要件，爰依法具文提出申請，謹請 鈞局依法核予專利，以維護本申請人合法之權益。The above is only one of the possible embodiments of the present invention, and is not intended to limit the scope of the patents of the present invention, and the equivalent implementations of other changes according to the contents, features and spirits of the following claims are It should be included in the scope of the patent of the present invention. The invention is specifically defined in the structural features of the request item, is not found in the same kind of articles, and has practicality and progress, has met the requirements of the invention patent, and has filed an application according to law, and invites the bureau to approve the patent according to law to maintain the present invention. The legal rights of the applicant.
(1a)．．．高分子材料(1a). . . Polymer Materials
(1b)．．．無機材料(1b). . . Inorganic material
(1c)．．．有機材料(1c). . . organic material
(1d)．．．發泡劑(1d). . . Foaming agent
(1e)．．．防火材料(1e). . . Fireproof Materials
(10)．．．環保紙(10). . . Environmentally friendly paper
(20)．．．壓延成型手段(20). . . Calendering means
(21)．．．研磨機(twenty one). . . Grinder
(22)．．．進料機(twenty two). . . Feeder
(23)．．．配方控制單元(twenty three). . . Recipe control unit
(24)．．．自動計量單元(twenty four). . . Automatic metering unit
(25)．．．混合裝置(25). . . Mixing device
(26)．．．密封式混煉裝置(26). . . Sealed mixing device
(27)．．．第一混煉軋輪裝置(27). . . First mixing wheel device
(28)．．．第二混煉軋輪裝置(28). . . Second mixing wheel device
(29)．．．過濾壓出單元(29). . . Filtration extrusion unit
(30)．．．壓延成型裝置(30). . . Calendering device
(31)．．．冷卻壓平機(31). . . Cooling press
(32)．．．電暈處理裝置(32). . . Corona treatment device
(33)．．．自動捲紙機(33). . . Automatic reel
(34)．．．裁切機(34). . . Cutting machine
第一圖係本發明第一材料配方之製備方塊示意圖。The first figure is a schematic block diagram of the preparation of the first material formulation of the present invention.
第二圖係本發明第二材料配方之製備方塊示意圖。The second figure is a schematic block diagram of the preparation of the second material formulation of the present invention.
第三圖係本發明第三材料配方之製備方塊示意圖。The third figure is a schematic block diagram of the preparation of the third material formulation of the present invention.
第四圖係本發明第四材料配方之製備方塊示意圖。The fourth figure is a schematic block diagram of the preparation of the fourth material formulation of the present invention.
第五圖係本發明壓延成型手段之製備步驟的示意圖。The fifth drawing is a schematic view showing the preparation steps of the calendering means of the present invention.
第六圖係本發明壓延成型手段之第一種具體架構示意圖。The sixth drawing is a first specific schematic diagram of the calendering means of the present invention.
第七圖係本發明壓延成型手段之第二種具體架構示意圖。The seventh figure is a second specific schematic diagram of the calendering means of the present invention.
第八圖係本發明壓延成型手段之第三種具體架構示意圖。The eighth figure is a third specific schematic diagram of the calendering means of the present invention.
第九圖係本發明環保紙成品之外觀示意圖。The ninth drawing is a schematic view of the appearance of the finished green paper of the present invention.
(1a)．．．高分子材料(1a). . . Polymer Materials
(1b)．．．無機材料(1b). . . Inorganic material
(10)．．．環保紙(10). . . Environmentally friendly paper
(20)．．．壓延成型手段(20). . . Calendering means
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW100116373A TWI507296B (en) | 2011-05-10 | 2011-05-10 | Green paper and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW100116373A TWI507296B (en) | 2011-05-10 | 2011-05-10 | Green paper and its manufacturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201244941A TW201244941A (en) | 2012-11-16 |
| TWI507296B true TWI507296B (en) | 2015-11-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW100116373A TWI507296B (en) | 2011-05-10 | 2011-05-10 | Green paper and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| TW (1) | TWI507296B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11401391B2 (en) | 2018-07-23 | 2022-08-02 | Don Jia Poly Plastic Ltd. | Oyster paper and manufacturing method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW247295B (en) * | 1993-04-17 | 1995-05-11 | Nanya Plastics Corp | Process for producing polypropylene (PP) pearling synthetic paper |
| TW201033283A (en) * | 2008-11-05 | 2010-09-16 | Teijin Chemicals Ltd | Polylactic acid compositions and molded articles thereof |
-
2011
- 2011-05-10 TW TW100116373A patent/TWI507296B/en not_active IP Right Cessation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW247295B (en) * | 1993-04-17 | 1995-05-11 | Nanya Plastics Corp | Process for producing polypropylene (PP) pearling synthetic paper |
| TW201033283A (en) * | 2008-11-05 | 2010-09-16 | Teijin Chemicals Ltd | Polylactic acid compositions and molded articles thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11401391B2 (en) | 2018-07-23 | 2022-08-02 | Don Jia Poly Plastic Ltd. | Oyster paper and manufacturing method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| TW201244941A (en) | 2012-11-16 |
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