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TWI594378B - Non-volatile memory cell and manufacture method of the same - Google Patents

Non-volatile memory cell and manufacture method of the same Download PDF

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Publication number
TWI594378B
TWI594378B TW105113815A TW105113815A TWI594378B TW I594378 B TWI594378 B TW I594378B TW 105113815 A TW105113815 A TW 105113815A TW 105113815 A TW105113815 A TW 105113815A TW I594378 B TWI594378 B TW I594378B
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gate
dielectric layer
substrate
erase
volatile memory
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TW105113815A
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TW201640621A (en
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范德慈
陳志民
呂榮章
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北京芯盈速騰電子科技有限責任公司
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B41/00Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates

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  • Non-Volatile Memory (AREA)
  • Semiconductor Memories (AREA)

Description

非揮發性記憶體單元及其製作方法 Non-volatile memory unit and manufacturing method thereof

本發明提出一種非揮發性記憶體及其製作方法,其中非揮發記憶體單元包含選擇閘極、抹除閘極、浮動閘極以及耦合閘極。 The invention provides a non-volatile memory and a manufacturing method thereof, wherein the non-volatile memory unit comprises a selection gate, an erase gate, a floating gate and a coupling gate.

一般來說,非揮發性記憶體多採用三層導體結構來形成分裂式閘極結構。通常以第一導體層形成選擇閘極(Select gate),第二導體層形成浮動閘極(Floating gate),第三多導體層形成耦合閘極(Coupling gate),其中耦合閘極又稱為控制閘極(Coupling gate)。 In general, non-volatile memory uses a three-layer conductor structure to form a split gate structure. A selective gate is generally formed by a first conductor layer, a second gate layer forms a floating gate, and a third multi-conductor layer forms a coupling gate, wherein the coupled gate is also referred to as a control Coupling gate.

在三導體層結構中,浮動閘極以及源極接面的頂部通常完全被耦合閘極所覆蓋。因此,在進行抹除操作並同時使用相對高的電壓對耦合閘極以及源極接面進行充電時,會產生很高的帶間漏電流(Band-to-band leakage current)。為了降低帶間漏電流,通常會藉由源極接面工程(Source junction Engineering)或是在浮動閘極下方增加設置介電層來降低浮動閘極下方的垂直電場。 In a three-conductor layer structure, the floating gate and the top of the source junction are typically completely covered by the coupled gate. Therefore, when the erase operation is performed while charging the coupled gate and the source junction with a relatively high voltage, a high band-to-band leakage current is generated. In order to reduce the leakage current between the strips, the vertical electric field under the floating gate is usually reduced by adding a dielectric layer under the source junction engineering or under the floating gate.

上述方式雖然可以降低帶間漏電流,但同時也會使得記憶體單元的尺寸變大,並且會對記憶體單元的性能表現,例如寫入、讀取或抹 除,造成不利的影響。 Although the above method can reduce the leakage current between the bands, it also makes the size of the memory unit larger, and the performance of the memory unit, such as writing, reading or wiping In addition, it has an adverse effect.

本發明之一目的,在於提供一種非揮發性記憶體單元,包含一選擇閘極、一抹除閘極、一浮動閘極、一耦合閘極以及一個或一個以上的介電層。抹除閘極位於耦合閘極以及第一摻雜區之間,進行抹除操作時,電子可以從浮動閘極穿隧到抹除閘極以完成抹除操作,並且可以降低耦合閘極與第一摻雜區之間的帶間漏電流。 It is an object of the present invention to provide a non-volatile memory cell comprising a select gate, a wipe gate, a floating gate, a coupled gate, and one or more dielectric layers. The erase gate is located between the coupled gate and the first doped region. When the erase operation is performed, electrons can tunnel from the floating gate to the erase gate to complete the erase operation, and the coupled gate and the second can be reduced. Inter-band leakage current between a doped region.

本發明之又一目的,在於提供一種非揮發性記憶體的製作方法,分別沉積並圖案化四個導體層,以形成選擇閘極、抹除閘極、浮動閘極以及耦合閘極。其中抹除閘極位於耦合閘極以及第一摻雜區之間,進行抹除操作時,電子可以從浮動閘極穿隧到抹除閘極以完成抹除操作,並且可以降低耦合閘極與第一摻雜區之間的帶間漏電流。 It is still another object of the present invention to provide a method of fabricating a non-volatile memory by separately depositing and patterning four conductor layers to form a select gate, an erase gate, a floating gate, and a coupled gate. Wherein the erase gate is located between the coupled gate and the first doped region, and when the erase operation is performed, electrons can tunnel from the floating gate to the erase gate to complete the erase operation, and the coupled gate can be lowered Inter-band leakage current between the first doped regions.

本發明之又一目的,在於提供一種非揮發性記憶體的製作方法,使用此方法製作的記憶體單元,浮動閘極靠近抹除閘極的側壁具有一凸出結構。此凸出結構將有利於在進行抹除操作時,電子由浮動閘極注入到抹除閘極之中。 Another object of the present invention is to provide a method for fabricating a non-volatile memory. The memory cell fabricated by the method has a protruding structure on the sidewall of the floating gate adjacent to the erase gate. This protruding structure will facilitate the injection of electrons from the floating gate into the erase gate during the erase operation.

為達到上述目的,本發明提供一種非揮發性記憶體單元,包括:一基板,包括一第一摻雜區及至少一第二摻雜區,其中第一摻雜區與第二摻雜區相鄰;一選擇閘極,設置於基板上,並位於第一摻雜區與第二摻雜區之間;一抹除閘極,位於第一摻雜區上方;一浮動閘極,位於選擇閘極以及抹除閘極之間;一耦合閘極,位於抹除閘極、浮動閘極以及部份 選擇閘極的投影上方;及一個或一個以上的介電層,用以作絕緣層,位於相鄰之選擇閘極、抹除閘極、浮動閘極、耦合閘極或第一摻雜區之間。 To achieve the above objective, the present invention provides a non-volatile memory cell, comprising: a substrate including a first doped region and at least a second doped region, wherein the first doped region and the second doped region are a gate electrode is disposed on the substrate between the first doped region and the second doped region; a wipe gate is located above the first doped region; and a floating gate is located at the select gate And between the erase gates; a coupled gate located at the erase gate, the floating gate and the portion Selecting a top of the projection of the gate; and one or more dielectric layers for the insulating layer, located adjacent to the selected gate, the erase gate, the floating gate, the coupled gate, or the first doped region between.

為達到上述目的,本發明提供一種非揮發性記憶體單元,包括:一基板,包括一第一摻雜區及至少一第二摻雜區,其中第一摻雜區與第二摻雜區相鄰;一選擇閘極,設置於基板上,並位於第一摻雜區與第二摻雜區之間;一抹除閘極,位於第一摻雜區上方;一浮動閘極,位於選擇閘極以及抹除閘極之間;一耦合閘極,位於浮動閘極的投影上方;及一個或一個以上的介電層,用以作絕緣層,位於相鄰之選擇閘極、抹除閘極、浮動閘極、耦合閘極或第一摻雜區之間。 To achieve the above objective, the present invention provides a non-volatile memory cell, comprising: a substrate including a first doped region and at least a second doped region, wherein the first doped region and the second doped region are a gate electrode is disposed on the substrate between the first doped region and the second doped region; a wipe gate is located above the first doped region; and a floating gate is located at the select gate And between the erase gates; a coupled gate located above the projection of the floating gate; and one or more dielectric layers for the insulating layer, adjacent to the selected gate, the erase gate, Between the floating gate, the coupled gate or the first doped region.

為達到上述目的,本發明提供一種非揮發性記憶體單元的製作方法,其步驟包括:提供一基板;形成一位於基板上的選擇閘極;形成一第一襯底介電層覆蓋選擇閘極及基板,並在基板內形成一第一摻雜區;於第一襯底介電層上形成一抹除閘極,其中抹除閘極位於第一摻雜區上方;形成一包覆抹除閘極的抹除閘極介電層;於選擇閘極以及抹除閘極之間形成一浮動閘極;形成一耦合閘極介電層覆蓋裸露出的第一襯底介電層、抹除閘極介電層以及浮動閘極;及於耦合閘極介電層上形成一耦合閘極。 In order to achieve the above object, the present invention provides a method for fabricating a non-volatile memory cell, the method comprising: providing a substrate; forming a selective gate on the substrate; forming a first substrate dielectric layer covering the selected gate And a substrate, and forming a first doped region in the substrate; forming a erase gate on the first substrate dielectric layer, wherein the erase gate is above the first doped region; forming a cladding erase gate a gate dielectric layer is formed by a gate; a floating gate is formed between the gate and the erase gate; and a coupled gate dielectric layer is formed to cover the exposed first substrate dielectric layer and the erase gate a pole dielectric layer and a floating gate; and a coupling gate formed on the coupled gate dielectric layer.

為達到上述目的,本發明提供一種非揮發性記憶體單元的製作方法,其步驟包括:提供一基板;形成一位於基板上的選擇閘極;形成一第一摻雜區、一第一摻雜區介電層、一抹除閘極以及一抹除閘極覆蓋介電層,其中第一摻雜區設置在該基板內,第一摻雜區介電層設置於基板上,並位於第一摻雜區上,抹除閘極設置於第一摻雜區介電層上,而抹除閘極 覆蓋介電層設置於抹除閘極上;移除部分第一摻雜區介電層、部分抹除閘極覆蓋介電層,使得第一摻雜區介電層以及抹除閘極覆蓋介電層的長度或截面積小於抹除閘極;形成一穿隧介電層覆蓋裸露出的選擇閘極、抹除閘極、第一摻雜區介電層、抹除閘極覆蓋介電層以及部分基板的表面;形成一浮動閘極,位於選擇閘極以及抹除閘極之間,其中該浮動閘極靠近該抹除閘極的側壁具有一凸出結構;形成一耦合閘極介電層覆蓋裸露出的穿隧介電層以及浮動閘極;及於耦合閘極介電層上形成一耦合閘極。 To achieve the above object, the present invention provides a method of fabricating a non-volatile memory cell, the method comprising: providing a substrate; forming a selective gate on the substrate; forming a first doped region, a first doping a dielectric layer, a gate removing gate, and a gate removing dielectric layer, wherein the first doping region is disposed in the substrate, and the first doped dielectric layer is disposed on the substrate and is located at the first doping In the region, the erase gate is disposed on the dielectric layer of the first doped region, and the gate is erased The cover dielectric layer is disposed on the erase gate; the portion of the first doped region dielectric layer and the partial erase gate cover the dielectric layer are removed, so that the first doped region dielectric layer and the erase gate cover dielectric The length or cross-sectional area of the layer is smaller than the erase gate; forming a tunneling dielectric layer to cover the exposed selected gate, the erase gate, the first doped dielectric layer, the erase gate cover dielectric layer, and a surface of a portion of the substrate; forming a floating gate between the select gate and the erase gate, wherein the floating gate has a protruding structure adjacent to the sidewall of the erase gate; forming a coupled gate dielectric layer Covering the exposed tunneling dielectric layer and the floating gate; and forming a coupled gate on the coupled gate dielectric layer.

在本發明非揮發性記憶體單元一實施例中,基板包含一表面介電層,位於基板與選擇閘極、浮動閘極及抹除閘極之間。 In an embodiment of the non-volatile memory cell of the present invention, the substrate includes a surface dielectric layer between the substrate and the select gate, the floating gate, and the erase gate.

在本發明非揮發性記憶體單元一實施例中,介電層包括:一第一襯底介電層,包覆選擇閘極的側壁以及上表面,厚度介於10Å到150Å之間;一抹除閘極介電層,包覆抹除閘極周圍,並位於抹除閘極與基板、浮動閘極及耦合閘極之間,厚度介於100Å到600Å之間;一耦合閘極介電層,位於該耦合閘極與抹除閘極、浮動閘極以及選擇閘極之間,厚度介於100Å到300Å之間。 In an embodiment of the non-volatile memory cell of the present invention, the dielectric layer comprises: a first substrate dielectric layer covering the sidewalls and the upper surface of the gate, and having a thickness between 10 Å and 150 Å; a gate dielectric layer encapsulating the periphery of the gate and between the erase gate and the substrate, the floating gate and the coupling gate, and having a thickness between 100 Å and 600 Å; a coupled gate dielectric layer, Located between the coupled gate and the erase gate, the floating gate, and the select gate, the thickness is between 100 Å and 300 Å.

在本發明非揮發性記憶體單元一實施例中,第一襯底介電層、抹除閘極介電層以及耦合閘極介電層的材料為氧化矽或高介電材料複合物。 In an embodiment of the non-volatile memory cell of the present invention, the material of the first substrate dielectric layer, the erase gate dielectric layer, and the coupled gate dielectric layer is a yttria or high dielectric material composite.

在本發明非揮發性記憶體單元一實施例中,介電層包括:一第一襯底介電層,位於浮動閘極與選擇閘極之間以及浮動閘極與基板之間,厚度介於50Å到200Å之間;及一抹除閘極介電層,位於浮動閘極與抹除閘極之間,厚度介於50Å到200Å之間。 In an embodiment of the non-volatile memory cell of the present invention, the dielectric layer includes: a first substrate dielectric layer between the floating gate and the selected gate and between the floating gate and the substrate, and the thickness is between Between 50 Å and 200 Å; and a wiper dielectric layer between the floating gate and the erase gate, between 50 Å and 200 Å thick.

在本發明非揮發性記憶體單元一實施例中,第一襯底介電層及耦合閘極介電層的材料為氧化矽或高介電材料複合物。 In an embodiment of the non-volatile memory cell of the present invention, the material of the first substrate dielectric layer and the coupled gate dielectric layer is a yttria or high dielectric material composite.

在本發明非揮發性記憶體單元一實施例中,介電層包括一選擇閘極覆蓋介電層,設置於選擇閘極的上表面。 In an embodiment of the non-volatile memory cell of the present invention, the dielectric layer includes a selective gate capping dielectric layer disposed on the upper surface of the select gate.

在本發明非揮發性記憶體單元一實施例中,其中選擇閘極的厚度介於200Å到2000Å之間,抹除閘極的厚度介於200Å到2000Å之間,浮動閘極的厚度介於150Å到2000Å之間。 In an embodiment of the non-volatile memory cell of the present invention, wherein the gate thickness of the gate is between 200 Å and 2000 Å, the thickness of the erase gate is between 200 Å and 2000 Å, and the thickness of the floating gate is between 150 Å. Between 2000Å.

在本發明非揮發性記憶體單元一實施例中,其中浮動閘極靠近抹除閘極的側壁為平面結構或具有一凸出結構。 In an embodiment of the non-volatile memory cell of the present invention, the sidewall of the floating gate adjacent to the erase gate is planar or has a convex structure.

在本發明非揮發性記憶體單元一實施例中,其中浮動閘極的凸出結構位於第一摻雜區與抹除閘極之間。 In an embodiment of the non-volatile memory cell of the present invention, the protruding structure of the floating gate is between the first doped region and the erase gate.

在本發明非揮發性記憶體單元的製作方法一實施例中,其中耦合閘極位於抹除閘極、浮動閘極以及部份選擇閘極的投影上方。 In an embodiment of the method of fabricating a non-volatile memory cell of the present invention, the coupling gate is located above the projection of the erase gate, the floating gate, and the portion of the select gate.

在本發明非揮發性記憶體單元的製作方法一實施例中,其中耦合閘極位於浮動閘極的投影上方。 In an embodiment of the method of fabricating a non-volatile memory cell of the present invention, wherein the coupling gate is above the projection of the floating gate.

在本發明非揮發性記憶體單元的製作方法一實施例中,包括以下步驟:於基板中形成一第二摻雜區,其中第一摻雜區與第二摻雜區相鄰。 In an embodiment of the method for fabricating a non-volatile memory cell of the present invention, the method includes the steps of: forming a second doped region in the substrate, wherein the first doped region is adjacent to the second doped region.

在本發明非揮發性記憶體單元的製作方法一實施例中,包括以下步驟:於形成第一襯底介電層之後,形成至少一犧牲間隔物於第一襯底介電層上,其中犧牲間隔物與選擇閘極相鄰;及於形成抹除閘極介電層之後,移除位於抹除閘極以及選擇閘極之間的犧牲間隔物。 In an embodiment of the method for fabricating a non-volatile memory cell of the present invention, the method includes the following steps: after forming the first substrate dielectric layer, forming at least one sacrificial spacer on the first substrate dielectric layer, wherein the sacrificial The spacer is adjacent to the select gate; and after forming the erase gate dielectric layer, the sacrificial spacer between the erase gate and the select gate is removed.

在本發明非揮發性記憶體單元的製作方法一實施例中,包括以下步驟:在形成選擇閘極之後形成一第一襯底介電層覆蓋選擇閘極及基板;形成至少一犧牲間隔物於第一襯底介電層上,其中犧牲間隔物與選擇閘極相鄰;形成一第二襯底介電層覆蓋裸露出的第一襯底介電層以及犧牲間隔物;形成抹除閘極在第二襯底介電層上,其中抹除閘極位於第一摻雜區上方,並位於兩相鄰的犧牲間隔物之間;及於形成抹除閘極覆蓋介電層之後,移除犧牲間隔物、部分第一襯底介電層以及部分第二襯底介電層,保留位於該抹除閘極與該第一摻雜區之間的該第一襯底介電層以及該第二襯底介電層,藉此在該抹除閘極與該第一摻雜區之間形成該第一摻雜區介電層。 In an embodiment of the method for fabricating a non-volatile memory cell of the present invention, the method includes the steps of: forming a first substrate dielectric layer over the select gate and the substrate after forming the select gate; forming at least one sacrificial spacer a first substrate dielectric layer, wherein the sacrificial spacer is adjacent to the select gate; forming a second substrate dielectric layer overlying the exposed first substrate dielectric layer and the sacrificial spacer; forming an erase gate On the second substrate dielectric layer, wherein the erase gate is located above the first doped region and between the two adjacent sacrificial spacers; and after the erase gate is formed to cover the dielectric layer, the erase layer is removed a sacrificial spacer, a portion of the first substrate dielectric layer, and a portion of the second substrate dielectric layer, the first substrate dielectric layer between the erase gate and the first doped region, and the first a second dielectric layer, whereby the first doped dielectric layer is formed between the erase gate and the first doped region.

在本發明非揮發性記憶體單元的製作方法一實施例中,包括以下步驟:於形成選擇閘極之後,在選擇閘極及基板上形成一介電層;移除部分介電層,保留選擇閘極上表面及部分基板上的介電層,藉此在選擇閘極上表面形成一選擇閘極覆蓋介電層,及在部分基板的上表面形成第一摻雜區介電層。 In an embodiment of the method for fabricating a non-volatile memory cell of the present invention, the method includes the steps of: forming a dielectric layer on the select gate and the substrate after forming the select gate; removing a portion of the dielectric layer, retaining the selection a dielectric layer on the upper surface of the gate and a portion of the substrate, whereby a selective gate capping dielectric layer is formed on the upper surface of the selective gate, and a first doped dielectric layer is formed on the upper surface of the portion of the substrate.

1‧‧‧非揮發性記憶體陣列 1‧‧‧Non-volatile memory array

1A‧‧‧非揮發性記憶體單元 1A‧‧‧Non-volatile memory unit

1B‧‧‧非揮發性記憶體單元 1B‧‧‧Non-volatile memory unit

10‧‧‧基板 10‧‧‧Substrate

11‧‧‧選擇閘極 11‧‧‧Selecting the gate

12‧‧‧抹除閘極 12‧‧‧ Wipe the gate

13‧‧‧浮動閘極 13‧‧‧Floating gate

131‧‧‧犧牲間隔物 131‧‧‧ Sacrificial spacers

132‧‧‧開孔 132‧‧‧Opening

14‧‧‧耦合閘極 14‧‧‧coupled gate

15‧‧‧第一摻雜區 15‧‧‧First doped area

16‧‧‧第二摻雜區 16‧‧‧Second doped area

18‧‧‧介電層 18‧‧‧ dielectric layer

181‧‧‧選擇閘極覆蓋介電層 181‧‧‧Selected gate covered dielectric layer

182‧‧‧第一襯底介電層 182‧‧‧First Substrate Dielectric Layer

183‧‧‧第二襯底介電層 183‧‧‧Second Substrate Dielectric Layer

184‧‧‧抹除閘極覆蓋介電層 184‧‧‧Erase the gate covered dielectric layer

185‧‧‧抹除閘極介電層 185‧‧‧ Wipe the gate dielectric layer

186‧‧‧耦合閘極介電層 186‧‧‧coupled gate dielectric layer

187‧‧‧表面介電層 187‧‧‧Surface dielectric layer

191‧‧‧字元線 191‧‧‧ character line

192‧‧‧位元線 192‧‧‧ bit line

2A‧‧‧非揮發性記憶體單元 2A‧‧‧Non-volatile memory unit

2B‧‧‧非揮發性記憶體單元 2B‧‧‧Non-volatile memory unit

20‧‧‧基板 20‧‧‧Substrate

21‧‧‧選擇閘極 21‧‧‧Select gate

22‧‧‧抹除閘極 22‧‧‧ Wipe the gate

23a‧‧‧浮動閘極 23a‧‧‧Floating gate

23b‧‧‧浮動閘極 23b‧‧‧Floating gate

231‧‧‧凸出結構 231‧‧‧ protruding structure

233‧‧‧延伸結構 233‧‧‧Extended structure

24‧‧‧耦合閘極 24‧‧‧coupled gate

25‧‧‧第一摻雜區 25‧‧‧First doped area

26‧‧‧第二摻雜區 26‧‧‧Second doped area

28‧‧‧介電層 28‧‧‧Dielectric layer

281‧‧‧選擇閘極覆蓋介電層 281‧‧‧Selected gate covering dielectric layer

283‧‧‧第一摻雜區介電層 283‧‧‧First doped dielectric layer

284‧‧‧抹除閘極覆蓋介電層 284‧‧‧ Wipe the gate covered dielectric layer

285‧‧‧穿隧介電層 285‧‧‧Tunnel dielectric layer

286‧‧‧耦合閘極介電層 286‧‧‧coupled gate dielectric layer

287‧‧‧表面介電層 287‧‧‧Surface dielectric layer

3‧‧‧非揮發性記憶體單元 3‧‧‧Non-volatile memory unit

30‧‧‧基板 30‧‧‧Substrate

31‧‧‧選擇閘極 31‧‧‧Selecting the gate

32‧‧‧抹除閘極 32‧‧‧ Wipe the gate

33‧‧‧浮動閘極 33‧‧‧Floating gate

34‧‧‧耦合閘極 34‧‧‧coupled gate

35‧‧‧第一摻雜區 35‧‧‧First doped area

36‧‧‧第二摻雜區 36‧‧‧Second doped area

38‧‧‧介電層 38‧‧‧Dielectric layer

381‧‧‧選擇閘極覆蓋介電層 381‧‧‧Selected gate covered dielectric layer

387‧‧‧表面介電層 387‧‧‧Surface dielectric layer

第1圖:為本發明非揮發性記憶體陣列一實施例的俯視圖。 Figure 1 is a plan view of an embodiment of a non-volatile memory array of the present invention.

第2圖:為本發明非揮發性記憶體單元第一實施例的剖面圖。 Figure 2 is a cross-sectional view showing a first embodiment of the non-volatile memory cell of the present invention.

第3A圖至第3F圖:為本發明第一實施例之非揮發性記憶體單元的製造流程示意圖。 3A to 3F are schematic views showing a manufacturing flow of the non-volatile memory unit according to the first embodiment of the present invention.

第4圖:為本發明非揮發性記憶體單元第二實施例的剖面圖。 Figure 4 is a cross-sectional view showing a second embodiment of the non-volatile memory cell of the present invention.

第5A圖至第5F圖:為本發明第二實施例之非揮發性記憶體單元的製造流程示意圖。 5A to 5F are schematic views showing a manufacturing process of a non-volatile memory unit according to a second embodiment of the present invention.

第6圖:為本發明非揮發性記憶體單元第三實施例的剖面圖。 Figure 6 is a cross-sectional view showing a third embodiment of the non-volatile memory cell of the present invention.

第7A圖至第7D圖:為本發明第三實施例之非揮發性記憶體單元的製造流程示意圖。 7A to 7D are schematic views showing a manufacturing flow of a non-volatile memory unit according to a third embodiment of the present invention.

第8圖:為本發明非揮發性記憶體單元第四實施例的剖面圖。 Figure 8 is a cross-sectional view showing a fourth embodiment of the non-volatile memory cell of the present invention.

第9圖:為本發明非揮發性記憶體單元第五實施例的剖面圖。Figure 9 is a cross-sectional view showing a fifth embodiment of the non-volatile memory unit of the present invention.

雖然已透過舉例方式在圖式中描述了本創作的具體實施方式,並在本文中對其作了詳細的說明,但是本創作還允許有各種修改和替換形式。本創作之圖式內容可為不等比例,圖式及其詳細的描述僅為特定型式的揭露,並不為本創作的限制,相反的,依據本創作的專利範圍之精神和範圍內,進行修改、均等構件及其置換,皆為本創作所涵蓋的範圍。 While the specific embodiments of the present invention have been described in the drawings and are described in detail herein, the invention herein The schema content of this creation may be unequal proportions, and the detailed descriptions of the drawings and their detailed descriptions are only for the disclosure of specific types, and are not limited by the scope of the creation. On the contrary, according to the spirit and scope of the patent scope of the creation, Modifications, equal components and their replacements are covered by this creation.

請參閱第1圖至第2圖,分別為本發明非揮發性記憶體陣列的俯視圖以及非揮發性記憶體單元第一實施例的剖面圖。其中第2圖是沿著第1圖的非揮發性記憶體陣列中AA’方向的剖面圖,並包含兩個沿著 X方向相鄰的非揮發性記憶體單元1A。 1 to 2 are a plan view of a non-volatile memory array and a cross-sectional view of a first embodiment of a non-volatile memory unit, respectively. Figure 2 is a cross-sectional view along the AA' direction of the non-volatile memory array of Figure 1, and includes two along Non-volatile memory unit 1A adjacent in the X direction.

為使後續說明可以更加明確,請參閱第1圖以及第2圖中的座標,在本發明的敘述中,定義第一方向X、第二方向Y及第三方向Z,其中第一方向X、第二方向Y及第三方向Z相互垂直,例如第一方向X為水平方向,第二方向Y為垂直方向,且第二方向Y的箭頭指向方向為上方,反之則為下方,而第三方向Z可與第一方向X位在同一水平面上,並分別與第一方向X及第二方向Y垂直。 In order to make the following description more clear, please refer to the coordinates in FIG. 1 and FIG. 2, in the description of the present invention, the first direction X, the second direction Y and the third direction Z are defined, wherein the first direction X, The second direction Y and the third direction Z are perpendicular to each other, for example, the first direction X is a horizontal direction, the second direction Y is a vertical direction, and the arrow direction of the second direction Y is upward, and vice versa, and the third direction Z may be on the same level as the X direction in the first direction and perpendicular to the first direction X and the second direction Y, respectively.

本發明所述之非揮發性記憶體陣列1包括複數個非揮發性記憶體單元1A,其中各個非揮發性記憶體單元1A包括一基板10、一選擇閘極(select gate,SG)11、一抹除閘極(erase gate,ES)12、一浮動閘極(floating gate,FG)13、一耦合閘極(coupling gate,CG)14以及一個或一個以上的介電層18。 The non-volatile memory array 1 of the present invention includes a plurality of non-volatile memory cells 1A, wherein each of the non-volatile memory cells 1A includes a substrate 10, a select gate (SG) 11, and a wipe. In addition to an erect gate (ES) 12, a floating gate (FG) 13, a coupling gate (CG) 14, and one or more dielectric layers 18.

基板10包含一第一摻雜區15以及一第二摻雜區16,且第一摻雜區15與第二摻雜區16相鄰,第一摻雜區15以及第二摻雜區16位於基板10內,並靠近基板10上表面的位置,此外第一摻雜區15與第二摻雜區165之間可存在一設置空間。選擇閘極11設置於基板10上,並位於該第一摻雜區15與該第二摻雜區16的投影或垂直延伸位置之間,例如設置在第一摻雜區15與第二摻雜區165之間的設置空間的投影上方。 The substrate 10 includes a first doped region 15 and a second doped region 16, and the first doped region 15 is adjacent to the second doped region 16, and the first doped region 15 and the second doped region 16 are located. In the substrate 10, and close to the upper surface of the substrate 10, there may be a space between the first doping region 15 and the second doping region 165. The gate 11 is disposed on the substrate 10 between the first doped region 15 and the projected or vertically extended position of the second doped region 16, for example, disposed in the first doped region 15 and the second doped region. Above the projection of the set space between the zones 165.

抹除閘極12位於第一摻雜區15的上方,而浮動閘極13則位於抹除閘極12以及選擇閘極11之間,例如選擇閘極11、浮動閘極13及抹除閘極12沿著第一方向X設置在基板10上,其中浮動閘極13位於第一摻雜區15與第二摻雜區16的投影或垂直延伸位置之間,例如浮動閘極13靠近抹除閘 極12的側壁為平面結構,如第2圖所示。耦合閘極14則位於抹除閘極12、浮動閘極13以及部分選擇閘極11的投影上方,使得浮動閘極13及抹除閘極12位於耦合閘極14與基板10之間。 The erase gate 12 is located above the first doped region 15, and the floating gate 13 is located between the erase gate 12 and the select gate 11, such as the gate 11, the floating gate 13, and the erase gate. 12 is disposed on the substrate 10 along a first direction X, wherein the floating gate 13 is located between the projected or vertically extended positions of the first doped region 15 and the second doped region 16, eg, the floating gate 13 is adjacent to the erase gate The sidewall of the pole 12 is a planar structure as shown in FIG. The coupling gate 14 is located above the projection of the erase gate 12, the floating gate 13 and the partial selection gate 11, such that the floating gate 13 and the erase gate 12 are located between the coupling gate 14 and the substrate 10.

介電層18位於相鄰的選擇閘極11、抹除閘極12、浮動閘極13、耦合閘極14或第一摻雜區15之間。例如介電層18位於相鄰的選擇閘極11以及浮動閘極13之間、浮動閘極13以及抹除閘極12之間、選擇閘極11以及耦合閘極14之間、抹除閘極12以及耦合閘極14之間、浮動閘極13及耦合閘極14之間以及抹除閘極12與第一摻雜區15之間,並且覆蓋於裸露出的選擇閘極11以及基板10的表面。介電層18的作用是用來作為兩相鄰閘極之間的絕緣層,使相鄰的選擇閘極11、抹除閘極12、浮動閘極13、耦合閘極14或第一摻雜區15達到相互絕緣的效果。 The dielectric layer 18 is located between the adjacent select gate 11, the erase gate 12, the floating gate 13, the coupling gate 14, or the first doped region 15. For example, the dielectric layer 18 is located between the adjacent selection gate 11 and the floating gate 13 , between the floating gate 13 and the erase gate 12 , between the selection gate 11 and the coupling gate 14 , and the gate is erased. 12 and between the coupling gates 14, between the floating gates 13 and the coupling gates 14 and between the erase gates 12 and the first doping regions 15, and covering the exposed selection gates 11 and the substrate 10 surface. The function of the dielectric layer 18 is to serve as an insulating layer between two adjacent gates, such that the adjacent selection gate 11, the erase gate 12, the floating gate 13, the coupling gate 14, or the first doping Zone 15 achieves the effect of mutual insulation.

在本發明一實施例中,選擇閘極11的厚度介於200Å至2000Å之間、抹除閘極12的厚度介於200Å至2000Å之間、及/或浮動閘極13的厚度介於150Å至2000Å之間。在本發明實施例中,閘極的厚度是指閘極沿著第二方向Y或垂直基板10表面的方向的長度。例如浮動閘極13的厚度略大於或等於選擇閘極11的厚度,而浮動閘極13及選擇閘極11的厚度則略大於或等於抹除閘極12的厚度。 In an embodiment of the invention, the thickness of the gate 11 is selected to be between 200 Å and 2000 Å, the thickness of the erase gate 12 is between 200 Å and 2000 Å, and/or the thickness of the floating gate 13 is between 150 Å. Between 2000Å. In the embodiment of the present invention, the thickness of the gate refers to the length of the gate along the second direction Y or the direction perpendicular to the surface of the substrate 10. For example, the thickness of the floating gate 13 is slightly greater than or equal to the thickness of the selective gate 11, and the thickness of the floating gate 13 and the selective gate 11 is slightly greater than or equal to the thickness of the erase gate 12.

在本發明一實施例中,第一摻雜區15是作為源極(source),第二摻雜區16是作為汲極(drain)。當然在其他實施例中,第一摻雜區15也可以作為汲極,第二摻雜區16也可作為源極。 In an embodiment of the invention, the first doped region 15 is used as a source and the second doped region 16 is used as a drain. Of course, in other embodiments, the first doping region 15 can also serve as a drain, and the second doping region 16 can also serve as a source.

非揮發性記憶體陣列1由複數個非揮發性記憶體單元1A構成,非揮發性記憶體單元1A沿著互相垂直的第一方向X與第二方向Z排列成 棋盤狀,例如沿著第一方向X形成位元線192(bit line,BL),及沿著第三方向Z形成字元線191(word line,WL)。其中沿著第一方向X排列的相鄰的兩非揮發性記憶體單元1A共用抹除閘極12、耦合閘極14以及第一摻雜區15,如第1圖以及第2圖所示。 The non-volatile memory array 1 is composed of a plurality of non-volatile memory cells 1A arranged in a first direction X and a second direction Z perpendicular to each other. A checkerboard shape, for example, a bit line 192 is formed along the first direction X, and a word line WL is formed along the third direction Z. The adjacent two non-volatile memory cells 1A arranged along the first direction X share the erase gate 12, the coupling gate 14 and the first doping region 15, as shown in FIGS. 1 and 2.

請參閱第3A圖至第3F圖,為本發明第一實施例所述之非揮發性記憶體單元的製造流程示意圖。透過此製造流程,可以製造出如第2圖所示的非揮發性記憶體單元1A。 Please refer to FIG. 3A to FIG. 3F , which are schematic diagrams showing the manufacturing process of the non-volatile memory unit according to the first embodiment of the present invention. Through this manufacturing process, the non-volatile memory unit 1A as shown in Fig. 2 can be manufactured.

請參閱第3A圖,首先提供一基板10,在基板10上形成一第一導體多晶矽層(conductor poly-Si),並圖案化第一導體多晶矽層,以在基板10上形成選擇閘極11。接著在選擇閘極11以及基板10上形成一第一襯底介電層182,並使得第一襯底介電層182包覆選擇閘極11以及基板10裸露出的區域。 Referring to FIG. 3A, a substrate 10 is first provided, a first conductor polysilicon layer (conductor poly-Si) is formed on the substrate 10, and a first conductor polysilicon layer is patterned to form a selective gate 11 on the substrate 10. A first substrate dielectric layer 182 is then formed over the select gate 11 and the substrate 10 such that the first substrate dielectric layer 182 covers the selected gate 11 and the exposed regions of the substrate 10.

在本發明另一實施例中,提供的基板10的表面亦可包括一表面介電層187,厚度介於10Å到150Å之間,如第3A圖中的虛線所示。第一導體多晶矽層(conductor poly-Si)可形成於基板10上的表面介電層187上,而第一導體多晶矽層被圖案畫後,在表面介電層187上形成選擇閘極11。接著在選擇閘極11以及基板10的表面介電層187上形成一第一襯底介電層182,以包覆選擇閘極11以及表面介電層187裸露出的區域。 In another embodiment of the present invention, the surface of the substrate 10 is provided to include a surface dielectric layer 187 having a thickness between 10 Å and 150 Å as indicated by the dashed line in FIG. 3A. A first conductor polysilicon layer (conductor poly-Si) may be formed on the surface dielectric layer 187 on the substrate 10, and after the first conductor polysilicon layer is patterned, a selective gate 11 is formed on the surface dielectric layer 187. A first substrate dielectric layer 182 is then formed over the gate 11 and the surface dielectric layer 187 of the substrate 10 to cover the regions where the gate 11 and the surface dielectric layer 187 are exposed.

在本發明一實施例中,第一襯底介電層182可以透過氧化化學氣相沉積(oxide chemical vapor deposition)的方式來形成,但氧化化學氣相沉積僅為本發明一實施例,並不為本發明之權利範圍的限制,在不同實施例中,亦可使用不同的方式來形成第一襯底介電層182。 In an embodiment of the invention, the first substrate dielectric layer 182 can be formed by means of oxide chemical vapor deposition, but the oxidized chemical vapor deposition is only an embodiment of the invention, and To the extent that the scope of the invention is limited, the first substrate dielectric layer 182 can also be formed in different ways in different embodiments.

請參閱第3B圖,形成第一襯底介電層182之後,在第一襯底介電層182上形成犧性間隔物131(sacrificial dielectric spacer),犧牲間隔物131與選擇閘極11相鄰。犧牲間隔物131的材料可為氮化矽(SiN)或其他合適的材料。兩相鄰的犧牲間隔物131間隔有一開孔132,在開孔132上進行離子佈植,可在基板10中形成一第一摻雜區15,其中第一摻雜區15位於靠近基板10的上表面。換句話說,第一摻雜區15在第一方向X的位置是使用犧牲間隔物131所定義出來的。 Referring to FIG. 3B, after the first substrate dielectric layer 182 is formed, a sacrificial spacer spacer 131 is formed on the first substrate dielectric layer 182, and the sacrificial spacer 131 is adjacent to the selection gate 11. . The material of the sacrificial spacer 131 may be tantalum nitride (SiN) or other suitable material. Two adjacent sacrificial spacers 131 are spaced apart by an opening 132. The ion implantation is performed on the opening 132, and a first doping region 15 is formed in the substrate 10. The first doping region 15 is located adjacent to the substrate 10. Upper surface. In other words, the position of the first doping region 15 in the first direction X is defined using the sacrificial spacer 131.

在本發明一實施例中,犧牲間隔物131的形成方式是透過先在第一襯底介電層182上沉積一犧牲層,再透過蝕刻或顯影的方式移除部分犧牲層,僅保留與選擇閘極11兩側壁相鄰的犧牲層,以形成犧牲間隔物131。 In an embodiment of the invention, the sacrificial spacers 131 are formed by first depositing a sacrificial layer on the first substrate dielectric layer 182, and then removing a portion of the sacrificial layer by etching or developing, leaving only and selecting A sacrificial layer adjacent to both sidewalls of the gate 11 forms a sacrificial spacer 131.

在本發明一實施例中,可以在第一摻雜區15的上表面形成一氧化層,以增加第一摻雜區15與後續形成於第一摻雜區15投影上方的抹除閘極12之間的絕緣性。 In an embodiment of the invention, an oxide layer may be formed on the upper surface of the first doping region 15 to increase the first doping region 15 and the erase gate 12 formed subsequently over the projection of the first doping region 15 Insulation between.

請參閱第3C圖,形成第一摻雜區15之後,在裸露出來的犧牲間隔物131以及裸露出來的第一襯底介電層182的表面形成一第二襯底介電層183。接著在第二襯底介電層183上以第二導體多晶矽層形成抹除閘極12,其中抹除閘極12位於第一摻雜區15的上方,並位於兩相鄰的犧牲間隔物131之間。 Referring to FIG. 3C, after the first doping region 15 is formed, a second substrate dielectric layer 183 is formed on the surface of the exposed sacrificial spacer 131 and the exposed first substrate dielectric layer 182. An erase gate 12 is then formed on the second substrate dielectric layer 183 with a second conductor polysilicon layer, wherein the erase gate 12 is located above the first doped region 15 and is located at two adjacent sacrificial spacers 131. between.

在本發明一實施例中,抹除閘極12的形成方式是先在第二襯底介電層183上形成一第二導體多晶矽層,接著使用回蝕刻平面法(etch back planarized)去除在第一摻雜區15上方投影區域以外的第二導體多晶矽層,藉此在第一摻雜區15上方的投影區域形成一抹除閘極12。 In an embodiment of the invention, the erase gate 12 is formed by first forming a second conductor polysilicon layer on the second substrate dielectric layer 183, and then removing it by using an etch back planarization method. A second conductor polysilicon layer outside the projected region above the doped region 15 forms a wiper gate 12 in the projected region above the first doped region 15.

請參閱第3D圖,在形成抹除閘極12之後,移除部分第二襯底介電層183,僅保留位於抹除閘極12側壁以及下表面的第二襯底介電層183,例如保留抹除閘極12與犧牲間隔物131及第一襯底介電層182之間的第二襯底介電層183。 Referring to FIG. 3D, after the erase gate 12 is formed, a portion of the second substrate dielectric layer 183 is removed, leaving only the second substrate dielectric layer 183 on the sidewalls and the lower surface of the erase gate 12, such as The second substrate dielectric layer 183 between the erase gate 12 and the sacrificial spacer 131 and the first substrate dielectric layer 182 is left.

接著在抹除閘極12上方形成一抹除閘極覆蓋介電層184。為方便後續的說明,在本發明實施例中,將抹除閘極12周圍的第二襯底介電層183及抹除閘極覆蓋介電層184定義為抹除閘極介電層185。第二襯底介電層183及抹除閘極覆蓋介電層184可由相同或不同材料所形成。 A wipe-off dielectric layer 184 is then formed over the erase gate 12. To facilitate the subsequent description, in the embodiment of the present invention, the second substrate dielectric layer 183 and the erase gate capping dielectric layer 184 around the erase gate 12 are defined as the erase gate dielectric layer 185. The second substrate dielectric layer 183 and the erase gate capping dielectric layer 184 may be formed of the same or different materials.

請參閱第3E圖,在形成抹除閘極介電層185之後,移除犧牲間隔物131,並在第一襯底介電層182上以第三導體多晶矽層形成浮動閘極13。浮動閘極13位於選擇閘極11以及抹除閘極12之間。換句話說,浮動閘極13的位置是利用原本位於選擇閘極11以及抹除閘極12之間的犧牲間隔物131所定義出來,這種間隔物型式(spacer type)的浮動閘極13具有對相鄰的抹除閘極12及/或第一摻雜區15接面進行抹除的能力。 Referring to FIG. 3E, after the erase gate dielectric layer 185 is formed, the sacrificial spacer 131 is removed, and the floating gate 13 is formed on the first substrate dielectric layer 182 as a third conductor polysilicon layer. The floating gate 13 is located between the selection gate 11 and the erase gate 12. In other words, the position of the floating gate 13 is defined by the sacrificial spacer 131 originally located between the selection gate 11 and the erase gate 12, and the spacer type floating gate 13 has The ability to erase the adjacent erase gate 12 and/or the first doped region 15 junction.

在本發明一實施例中,浮動閘極13的形成方式是在裸露出來的第一襯底介電層182以及抹除閘極介電層185上沉積一第三導體多晶矽層,再回蝕刻(etch back)以及圖案化第三導體多晶矽層,以形成位於選擇閘極11以及抹除閘極12之間的浮動閘極13。 In an embodiment of the invention, the floating gate 13 is formed by depositing a third conductive polysilicon layer on the exposed first substrate dielectric layer 182 and the erase gate dielectric layer 185, and then etching back ( Etching back) and patterning the third conductor polysilicon layer to form a floating gate 13 between the select gate 11 and the erase gate 12.

請參閱第3F圖,形成浮動閘極13之後,接著依序形成耦合閘極介電層186、耦合閘極14以及第二摻雜區16。耦合閘極介電層186、耦合閘極14以及第二摻雜區16的形成順序可以做調整,例如也可以先形成第二摻雜區16,再形成耦合閘極介電層186以及耦合閘極14,或是先形成耦 合閘極介電層186,接著形成第二摻雜區16,最後再形成耦合閘極14。 Referring to FIG. 3F, after forming the floating gate 13, the coupled gate dielectric layer 186, the coupling gate 14 and the second doping region 16 are sequentially formed. The order of forming the coupled gate dielectric layer 186, the coupling gate 14 and the second doping region 16 can be adjusted. For example, the second doping region 16 can be formed first, and then the coupled gate dielectric layer 186 and the coupling gate can be formed. Pole 14, or form a coupling first The gate dielectric layer 186 is closed, followed by the formation of a second doped region 16, and finally a coupling gate 14 is formed.

第二摻雜區16位於基板10中,並且與第一摻雜區15相鄰。耦合閘極介電層186覆蓋在裸露出的第一襯底介電層182、浮動閘極13以及抹除閘極介電層185上。耦合閘極14位於耦合閘極介電層186上,並位於抹除閘極12、浮動閘極13、以及部分抹除閘極11的投影上方。 The second doped region 16 is located in the substrate 10 and is adjacent to the first doped region 15. A coupled gate dielectric layer 186 overlies the exposed first substrate dielectric layer 182, floating gate 13 and erase gate dielectric layer 185. The coupling gate 14 is located on the coupled gate dielectric layer 186 and over the projections of the erase gate 12, the floating gate 13, and the partial erase gate 11.

在本發明實施例中,選擇閘極11、抹除閘極12、浮動閘極13以及耦合閘極14的材料都是導體,並且使用導體多晶矽(Poly-Si)作為這些閘極的材料,但這並非本發明權利範圍的限制,在不同實施例中,各閘極所使用的材料也可以是其他適合的導體材料。 In the embodiment of the present invention, the materials for selecting the gate 11, the erase gate 12, the floating gate 13, and the coupling gate 14 are all conductors, and a conductor polysilicon (Poly-Si) is used as the material of the gates, but This is not a limitation of the scope of the invention, and in various embodiments, the materials used for the gates may be other suitable conductor materials.

第3F圖與第2圖皆為本發明第一實施例所述之非揮發性記憶體單元1A的剖面圖,包含了相鄰的兩個非揮發性記憶體單元1A,其中兩相鄰的非揮發性記憶體1A共用抹除閘極12、耦合閘極14以及第一摻雜區15。主要差異在於第3F圖將每一個介電層18依製程步驟分層表示,第2圖則是將所有介電層18視為一體。 3F and 2 are cross-sectional views of the non-volatile memory cell 1A according to the first embodiment of the present invention, including two adjacent non-volatile memory cells 1A, two adjacent non- The volatile memory 1A shares the erase gate 12, the coupling gate 14, and the first doping region 15. The main difference is that in Figure 3F, each dielectric layer 18 is layered in accordance with the process steps, and in Figure 2, all of the dielectric layers 18 are considered as one.

而在實際應用時,當第一襯底介電層182、抹除閘極介電層185以及耦合閘極介電層186的材料相同時,非揮發性記憶體單元1A的剖面將很難分辨出不同介電層18的交界,剖面會接近第2圖的構造。反之當第一襯底介電層182、抹除閘極介電層185以及耦合閘極介電層186的材料不同時,非揮發性記憶體單元1A的剖面將較容易分辨出不同介電層18的交界,剖面會接近第3F圖的構造。 In practical applications, when the materials of the first substrate dielectric layer 182, the erase gate dielectric layer 185, and the coupled gate dielectric layer 186 are the same, the profile of the non-volatile memory cell 1A will be difficult to distinguish. At the junction of the different dielectric layers 18, the profile will be close to the configuration of Figure 2. Conversely, when the materials of the first substrate dielectric layer 182, the erase gate dielectric layer 185, and the coupled gate dielectric layer 186 are different, the cross section of the non-volatile memory cell 1A will be easier to distinguish different dielectric layers. At the junction of 18, the profile will be close to the structure of Figure 3F.

在本發明一實施例中,若在第3A圖的步驟中所提供的基板10包含一表面介電層187,則在第3F圖中完成的非揮發記憶體單元1A, 也將會包含一表面介電層187,位於基板10與選擇閘極11、浮動閘極13及抹除閘極12之間,如圖中虛線所示。 In an embodiment of the present invention, if the substrate 10 provided in the step of FIG. 3A includes a surface dielectric layer 187, the non-volatile memory unit 1A completed in FIG. 3F, A surface dielectric layer 187 will also be included between the substrate 10 and the select gate 11, the floating gate 13 and the erase gate 12, as indicated by the dashed lines in the figure.

請參閱第3F圖,並請配合參閱第2圖,在本發明一實施例中,介電層18包括一第一襯底介電層182,厚度介於10Å到150Å之間,包括氧化矽及/或高介電(high K)材料複合物。其中第一襯底介電層182包覆選擇閘極11的兩側壁以及上表面。 Referring to FIG. 3F, and referring to FIG. 2, in an embodiment of the invention, the dielectric layer 18 includes a first substrate dielectric layer 182 having a thickness between 10 Å and 150 Å, including yttrium oxide and / or high dielectric (high K) material composite. The first substrate dielectric layer 182 covers both sidewalls and the upper surface of the gate 11.

在本發明一實施例中,介電層18包括一抹除閘極介電層185,包覆抹除閘極12周圍,並位於抹除閘極12與基板10、浮動閘極13與耦合閘極14之間,厚度介於100Å到600Å之間,包括氧化矽及/或高介電(high K)材料複合物。 In an embodiment of the invention, the dielectric layer 18 includes a erase gate dielectric layer 185 surrounding the erase gate 12 and located between the erase gate 12 and the substrate 10, the floating gate 13 and the coupled gate. Between 14 and between 100 Å and 600 Å thick, including yttria and/or high K material composites.

在本發明一實施例中,介電層18包括一耦合閘極介電層186,位於耦合閘極14與抹除閘極12之間、耦合閘極14與浮動閘極13之間以及耦合閘極14與選擇閘極11之間,厚度介於100Å到300Å之間,包括氧化矽及/或高介電(high K)材料複合物。 In an embodiment of the invention, the dielectric layer 18 includes a coupled gate dielectric layer 186 between the coupled gate 14 and the erase gate 12, between the coupled gate 14 and the floating gate 13 and the coupled gate. Between the pole 14 and the selection gate 11, the thickness is between 100 Å and 300 Å, including yttria and/or high K material composites.

在本發明另一實施例中,介電層18也可包括一個以上的介電層18數目,並且這些介電層18具有同樣的厚度範圍。例如介電層18可包括一第一襯底介電層182以及一抹除閘極介電層185。第一襯底介電層182位於浮動閘極13與選擇閘極11之間以及浮動閘極13與基板10之間,厚度介於50Å到200Å之間,包括氧化矽及或高介電(high K)材料複合物。抹除閘極介電層185則位於浮動閘極13與抹除閘極12之間,厚度介於50Å到200Å之間,包括氧化矽及/或高介電(high K)材料複合物。 In another embodiment of the invention, dielectric layer 18 may also include more than one dielectric layer 18, and these dielectric layers 18 have the same thickness range. For example, the dielectric layer 18 can include a first substrate dielectric layer 182 and a erase gate dielectric layer 185. The first substrate dielectric layer 182 is located between the floating gate 13 and the select gate 11 and between the floating gate 13 and the substrate 10, and has a thickness between 50 Å and 200 Å, including yttrium oxide and or high dielectric (high) K) Material composites. The erase gate dielectric layer 185 is located between the floating gate 13 and the erase gate 12 and has a thickness between 50 Å and 200 Å, including yttria and/or a high-k material composite.

請參閱第4圖,為本發明非揮發性記憶體單元第二實施例 的剖面圖。並請配合參閱第1圖,第4圖是沿著第1圖中的AA’方向剖面所產生,包括兩個沿著第一方向X相鄰的非揮發性記憶體單元1B。非揮發性記憶體單元1B包括一基板10、一選擇閘極11、一抹除閘極12、一浮動閘極13、一耦合閘極14、一選擇閘極覆蓋介電層181以及一個或一個以上的介電層18。非揮發性記憶體單元1B與第一實施例中的非揮發性記憶體單元1A類似,例如上述二個實施例中的浮動閘極13靠近抹除閘極12的側壁皆為平面結構。主要差異在於非揮發性記憶體單元1B還包括了一位於選擇閘極11上表面的選擇閘極覆蓋介電層181,使得選擇閘極11與耦合閘極14在Y方向的距離較浮動閘極13極抹除閘極12與耦合閘極14長。非揮發性記憶體單元1B的其他構造已於第一實施例中說明,在此便不再贅述。 Please refer to FIG. 4, which is a second embodiment of the non-volatile memory unit of the present invention. Sectional view. Please refer to FIG. 1 together. FIG. 4 is a cross section taken along the AA' direction in FIG. 1 and includes two non-volatile memory cells 1B adjacent in the first direction X. The non-volatile memory unit 1B includes a substrate 10, a selection gate 11, an erase gate 12, a floating gate 13, a coupling gate 14, a selective gate capping dielectric layer 181, and one or more Dielectric layer 18. The non-volatile memory cell 1B is similar to the non-volatile memory cell 1A of the first embodiment. For example, the floating gate 13 of the above two embodiments is adjacent to the sidewall of the erase gate 12 and has a planar structure. The main difference is that the non-volatile memory cell 1B further includes a selective gate capping dielectric layer 181 on the upper surface of the select gate 11 such that the distance between the select gate 11 and the coupled gate 14 in the Y direction is shallower than that of the floating gate. The 13-pole erase gate 12 is long with the coupled gate 14. Other configurations of the non-volatile memory unit 1B have been described in the first embodiment and will not be described again.

請參閱第5A圖至第5F圖,為本發明第二實施例所述之非揮發性記憶體單元的製造流程示意圖。非揮發記憶體單元1B的製造流程與第一實施例接近,主要差異在於在第5A圖的步驟是先在基板10上形成選擇閘極11之後,會接著在選擇閘極11上形成選擇閘極覆蓋介電層181,而後才在裸露出來的選擇閘極11、選擇閘極覆蓋介電層181以及基板10表面形成第一襯底介電層182,如第5A圖所示。 Please refer to FIG. 5A to FIG. 5F , which are schematic diagrams showing the manufacturing process of the non-volatile memory unit according to the second embodiment of the present invention. The manufacturing flow of the non-volatile memory unit 1B is similar to that of the first embodiment, and the main difference is that in the step of FIG. 5A, after the selection gate 11 is formed on the substrate 10, a selection gate is subsequently formed on the selection gate 11. The dielectric layer 181 is covered, and then the first substrate dielectric layer 182 is formed on the exposed selection gate 11, the selective gate capping dielectric layer 181, and the surface of the substrate 10, as shown in FIG. 5A.

本發明實施例所述的非揮發記憶體單元1B後續的製造流程,如第5B圖至第5F圖,與第一實施例所述之非揮發性記憶體單元1A的製作方式相近,如第3B至3F圖。形成第一襯底介電層182之後,接著依序形成犧牲間隔物131以及第一摻雜區15,如第5B圖所示。接著依序形成第二襯底介電層183以及抹除閘極12,如第5C圖所示。接著在抹除閘極12以及第二襯底介電層183裸露出的表面形成抹除閘極覆蓋介電層184,並 將第二襯底介電層183以及抹除閘極覆蓋介電層184定義為抹除閘極介電層185,如第5D圖所示。接著移除犧牲間隔物131並形成浮動閘極13,如第5E圖所示。最後,形成耦合閘極介電層186、耦合閘極14以及第二摻雜區16即完成非揮發性記憶體單元1B,如第5F圖所示。 The subsequent manufacturing process of the non-volatile memory unit 1B according to the embodiment of the present invention, as shown in FIGS. 5B to 5F, is similar to the manufacturing method of the non-volatile memory unit 1A described in the first embodiment, such as the 3B. To 3F map. After the first substrate dielectric layer 182 is formed, the sacrificial spacers 131 and the first doping regions 15 are sequentially formed, as shown in FIG. 5B. Next, a second substrate dielectric layer 183 and an erase gate 12 are sequentially formed as shown in FIG. 5C. Forming an erase gate capping dielectric layer 184 on the exposed surface of the erase gate 12 and the second substrate dielectric layer 183, and The second substrate dielectric layer 183 and the erase gate capping dielectric layer 184 are defined as erase gate dielectric layers 185, as shown in FIG. 5D. The sacrificial spacer 131 is then removed and the floating gate 13 is formed as shown in FIG. 5E. Finally, the formation of the coupled gate dielectric layer 186, the coupling gate 14 and the second doped region 16 completes the non-volatile memory cell 1B as shown in FIG. 5F.

第5F圖與第4圖皆為本發明第二實施例所述之非揮發性記憶體單元1B的剖面圖,包含了相鄰的兩個非揮發性記憶體單元1B,其中兩相鄰的非揮發性記憶體1B共用抹除閘極12、耦合閘極14以及第一摻雜區15。主要差異在於第5F圖將每一個介電層依製程需求一一分層表示,第4圖則是將所有的介電層18視為一體。 5F and 4 are cross-sectional views of the non-volatile memory unit 1B according to the second embodiment of the present invention, including two adjacent non-volatile memory cells 1B, two adjacent non- The volatile memory 1B shares the erase gate 12, the coupling gate 14, and the first doping region 15. The main difference is that Figure 5F shows each dielectric layer in a layered manner, and Figure 4 shows all dielectric layers 18 as one.

而在實際應用時,當選擇閘極覆蓋介電層181、第一襯底介電層182、抹除閘極介電層185以及耦合閘極介電層186的材料相同時,非揮發性記憶體單元1B的剖面將很難分辨出不同介電層18的交界,剖面會接近第4圖的構造。反之當選擇閘極覆蓋介電層181、第一襯底介電層182、抹除閘極介電層185以及耦合閘極介電層186的材料不同時,非揮發性記憶體單元1B的剖面將較容易分辨出不同介電層18的交界,剖面會接近第5F圖的構造。 In practical applications, the non-volatile memory is selected when the materials of the gate-covering dielectric layer 181, the first substrate dielectric layer 182, the erase gate dielectric layer 185, and the coupled gate dielectric layer 186 are the same. The cross section of the bulk cell 1B will make it difficult to distinguish the junction of the different dielectric layers 18, and the cross section will be close to the configuration of Fig. 4. Conversely, when the materials of the gate cover dielectric layer 181, the first substrate dielectric layer 182, the erase gate dielectric layer 185, and the coupled gate dielectric layer 186 are different, the profile of the non-volatile memory cell 1B is different. It will be easier to distinguish the junction of the different dielectric layers 18, and the profile will be close to the configuration of Figure 5F.

在本發明一實施例中,非揮發性記憶體單元1B的基板10亦可包含一表面介電層187,位於10基板與選擇閘極11、浮動閘極13及抹除閘極12之間。 In an embodiment of the invention, the substrate 10 of the non-volatile memory cell 1B may also include a surface dielectric layer 187 between the substrate 10 and the select gate 11, the floating gate 13 and the erase gate 12.

請參閱第6圖,為本發明非揮發性記憶體單元第三實施例的剖面圖。並請配合參閱第1圖,第6圖是沿著第1圖中的AA’方向剖面所產生,且包含兩個沿著第一方向X相鄰的非揮發性記憶體單元2A。本發 明所述之非揮發性記憶體單元2A包括一基板20、一選擇閘極21、一抹除閘極22、一浮動閘極23a、一耦合閘極24以及一個或一個以上的介電層28。 Please refer to FIG. 6, which is a cross-sectional view showing a third embodiment of the non-volatile memory unit of the present invention. Please refer to FIG. 1 together. FIG. 6 is a cross section taken along the AA' direction in FIG. 1 and includes two non-volatile memory cells 2A adjacent in the first direction X. This hair The non-volatile memory cell 2A includes a substrate 20, a select gate 21, a erase gate 22, a floating gate 23a, a coupled gate 24, and one or more dielectric layers 28.

請配合參閱第4圖,本發明實施例的非揮發性記憶體單元2A與第二實施例的非揮發性記憶體單元1B類似,主要差異在於本發明實施例的浮動閘極23a靠近抹除閘極22的側壁具有一凸出結構231,例如為凸出的尖角結構,其中凸出結構231由浮動閘極23a朝抹除閘極22的方向延伸,使得部分或全部的凸出結構231位於抹除閘極22與第一摻雜區25之間。而第二實施例中的浮動閘極13靠近抹除閘極12的側壁則為平面結構,如第4圖所示。非揮發性記憶體單元2A所具有的凸出結構將有利於在進行抹除操作時,電子由浮動閘極23a注入到抹除閘極22之中。 Referring to FIG. 4, the non-volatile memory unit 2A of the embodiment of the present invention is similar to the non-volatile memory unit 1B of the second embodiment, and the main difference is that the floating gate 23a of the embodiment of the present invention is close to the erase gate. The sidewall of the pole 22 has a protruding structure 231, such as a convex pointed structure, wherein the protruding structure 231 extends from the floating gate 23a toward the erasing gate 22 such that part or all of the protruding structure 231 is located. The gate 22 is erased between the gate and the first doping region 25. The floating gate 13 in the second embodiment is a planar structure near the sidewall of the erase gate 12, as shown in FIG. The non-volatile memory cell 2A has a protruding structure that facilitates electron injection from the floating gate 23a into the erase gate 22 during the erase operation.

另一主要差異在於本發明實施例第一摻雜區25位於抹除閘極22以及部分浮動閘極23a的投影下方,例如浮動閘極23a中部分或全部的凸出結構231位於第一摻雜區25的投影上方。第二實施例中的第一摻雜區15則是位於抹除閘極12的投影下方,並未位於部分的浮動閘極13的投影下方。 Another major difference is that the first doped region 25 of the embodiment of the present invention is located below the projection of the erase gate 22 and a portion of the floating gate 23a. For example, some or all of the protruding structures 231 of the floating gate 23a are located at the first doping. Above the projection of zone 25. The first doped region 15 in the second embodiment is located below the projection of the erase gate 12 and is not located below the projection of the portion of the floating gate 13.

在本發明實施例中,浮動閘極23a靠近選擇閘極21的側壁亦可能具有一延伸結構233,其中延伸結構233由浮動閘極23a朝選擇閘極21的方向延伸,使得部分或全部的延伸結構233位於選擇閘極22與耦合閘極24之間。 In the embodiment of the present invention, the sidewall of the floating gate 23a adjacent to the selection gate 21 may also have an extension structure 233, wherein the extension structure 233 extends from the floating gate 23a toward the selection gate 21, so that part or all of the extension Structure 233 is located between select gate 22 and coupled gate 24.

請參閱第7A圖至第7D圖,為本發明第三實施例所述之非揮發性記憶體單元的製造流程示意圖。透過此製造流程,可以製造出如第6圖所示的非揮發性記憶體單元2A。 Please refer to FIG. 7A to FIG. 7D , which are schematic diagrams showing the manufacturing process of the non-volatile memory unit according to the third embodiment of the present invention. Through this manufacturing process, the non-volatile memory unit 2A as shown in Fig. 6 can be manufactured.

請參閱第7A圖,首先提供一基板20,在基板20上形成一 選擇閘極21以及一覆蓋在選擇閘極21上的選擇閘極覆蓋介電層281,再依序形成第一摻雜區25、第一摻雜區介電層283、抹除閘極22以及抹除閘極覆蓋介電層284。如圖所示,第一摻雜區25位於基板20中靠近基板20上表面的地方,第一摻雜區介電層283位於基板20的上表面,例如第一摻雜區介電層283位於基板20內的第一摻雜區25上方,抹除閘極22位於第一摻雜區介電層283上,且抹除閘極覆蓋介電層284位於抹除閘極22上。 Referring to FIG. 7A, a substrate 20 is first provided, and a substrate 20 is formed on the substrate 20. Selecting the gate 21 and a selective gate covering the dielectric layer 281 over the selection gate 21, and sequentially forming the first doping region 25, the first doping region dielectric layer 283, the erasing gate 22, and The gate is covered with a dielectric layer 284. As shown, the first doped region 25 is located in the substrate 20 near the upper surface of the substrate 20. The first doped dielectric layer 283 is located on the upper surface of the substrate 20. For example, the first doped dielectric layer 283 is located. Above the first doped region 25 in the substrate 20, the erase gate 22 is on the first doped dielectric layer 283, and the erase gate cover dielectric layer 284 is on the erase gate 22.

在本發明一實施例中,提供的基板20可包括一表面介電層287,如第7A圖中的虛線所示,當基板20包括表面介電層287時,第一摻雜區25將會位於基板20中靠近表面介電層287的地方。 In an embodiment of the invention, the substrate 20 is provided to include a surface dielectric layer 287, as shown by the dashed line in FIG. 7A. When the substrate 20 includes the surface dielectric layer 287, the first doped region 25 will Located in the substrate 20 near the surface dielectric layer 287.

在本發明一實施例中,第7A圖的剖面構造可以是接續在第5A圖至第5D圖的步驟之後所製造出來的,首先可依據第5A圖至第5D圖的步驟,在基板11上形成選擇閘極11、選擇閘極覆蓋介電層181、第一襯底介電層182、犧牲間隔物131、第一摻雜區15、第二襯底介電層183、抹除閘極12及抹除閘極覆蓋介電層184。在形成第5D圖的構造後可移除犧牲間隔物131、部分第一襯底介電層182以及部分第二襯底介電層183,僅保留抹除閘極12/22上方的抹除閘極覆蓋介電層184/284以及抹除閘極12/22與第一摻雜區15/25之間的第一襯底介電層182以及第二襯底介電層183。在本發明實施例中將抹除閘極12/22與第一摻雜區15/25之間層疊的第一襯底介電層182以及第二襯底介電層183定義成第7A圖中的第一摻雜區介電層283。透過上述的內容,可接續在第5D圖之後形成如第7A圖中所示的剖面構造。 In an embodiment of the present invention, the cross-sectional structure of FIG. 7A may be manufactured after the steps of FIGS. 5A to 5D, and may be first performed on the substrate 11 according to the steps of FIGS. 5A to 5D. Forming the select gate 11, the select gate cap dielectric layer 181, the first substrate dielectric layer 182, the sacrificial spacer 131, the first doping region 15, the second substrate dielectric layer 183, and the erase gate 12 And erasing the gate covering dielectric layer 184. The sacrificial spacer 131, a portion of the first substrate dielectric layer 182, and a portion of the second substrate dielectric layer 183 may be removed after forming the configuration of the 5D figure, leaving only the erase gate above the erase gate 12/22 The gate covers the dielectric layer 184/284 and the first substrate dielectric layer 182 and the second substrate dielectric layer 183 between the erase gate 12/22 and the first doped region 15/25. In the embodiment of the present invention, the first substrate dielectric layer 182 and the second substrate dielectric layer 183 stacked between the erase gate 12/22 and the first doped region 15/25 are defined as in FIG. 7A. The first doped region dielectric layer 283. Through the above, the cross-sectional structure as shown in FIG. 7A can be formed after the 5D map.

上述在第5A圖至第5D圖的製程步驟之後,接續進行第 7A圖所述的製程步驟僅為本發明一實施例,並不為本發明之權利範圍的限制。在本發明另一實施例中,亦可透過不同的製程步驟,形成第7A圖所述的構造。例如在基板20上形成選擇閘極21,並在選擇閘極21及基板20上形成介電層,再透過蝕刻的方式保留選擇閘極21上表面及部分基板20上的介電層,藉此在選擇閘極21上表面形成選擇閘極覆蓋介電層281,及在部分基板20的上表面形成第一摻雜區介電層283。而後在第一摻雜區介電層283下方的基板20上形成第一摻雜區25,及在第一摻雜區介電層283上形成抹除閘極22,並在抹除閘極22上形成抹除閘極覆蓋介電層284。 After the above-mentioned process steps of FIGS. 5A to 5D, the following is continued The process steps described in FIG. 7A are only an embodiment of the present invention and are not intended to limit the scope of the invention. In another embodiment of the invention, the configuration described in FIG. 7A can also be formed through different process steps. For example, a selection gate 21 is formed on the substrate 20, a dielectric layer is formed on the selection gate 21 and the substrate 20, and the upper surface of the gate 21 and the dielectric layer on the portion of the substrate 20 are retained by etching. A selective gate capping dielectric layer 281 is formed on the upper surface of the selection gate 21, and a first doping region dielectric layer 283 is formed on the upper surface of the portion of the substrate 20. Then, a first doping region 25 is formed on the substrate 20 under the first doped dielectric layer 283, and an erase gate 22 is formed on the first doped dielectric layer 283, and the gate 22 is erased. An erase gate is formed over the dielectric layer 284.

請參閱第7B圖,完成第7A圖中的構造之後,接著移除部分的選擇閘極覆蓋介電層281、抹除閘極覆蓋介電層284以及第一摻雜區介電層283,使得選擇閘極覆蓋介電層281在第一方向X的長度或在第一方向X及第三方向Z所構成之平面上的截面積小於選擇閘極21的長度或截面積,並使得抹除閘極覆蓋介電層284以及第一摻雜區介電層283在第一方向X的長度或在第一方向X及第三方向Z所構成之平面上的截面積小於抹除閘極22的長度或截面積,如圖所示。換言之,部分選擇閘極21的上表面沒有覆蓋選擇閘極介電層281,而部分抹除閘極22的上表面則沒有覆蓋抹除閘極介電層284,此外部分抹除閘極22與第一摻雜區25及/或基板20之間不存在第一摻雜區介電層283。 Referring to FIG. 7B, after completing the configuration in FIG. 7A, a portion of the selected gate capping dielectric layer 281, the erase gate capping dielectric layer 284, and the first doped region dielectric layer 283 are removed. Selecting a length of the gate-covered dielectric layer 281 in the first direction X or a cross-sectional area in a plane formed by the first direction X and the third direction Z is smaller than a length or a cross-sectional area of the selection gate 21, and causing the erase gate The length of the pole-covered dielectric layer 284 and the first doped dielectric layer 283 in the first direction X or the cross-sectional area in the plane formed by the first direction X and the third direction Z is smaller than the length of the erase gate 22 Or cross-sectional area as shown. In other words, the upper surface of the partial selection gate 21 does not cover the selective gate dielectric layer 281, and the upper surface of the partial erase gate 22 does not cover the erase gate dielectric layer 284, and the partial erase gate 22 is partially There is no first doped dielectric layer 283 between the first doped regions 25 and/or the substrate 20.

在本發明一實施例中,是使用過蝕刻(over-etch)的方式來移除部分的選擇閘極覆蓋介電層281、抹除閘極覆蓋介電層284以及第一摻雜區介電層283。 In an embodiment of the invention, an over-etched portion is used to remove portions of the selected gate capping dielectric layer 281, the erase gate capping dielectric layer 284, and the first doped region dielectric. Layer 283.

請參閱第7C圖,在裸露出的選擇閘極21、選擇閘極覆蓋 介電層281、基板20、第一摻雜區介電層283、抹除閘極22及/或抹除閘極覆蓋介電層284表面形成一穿隧介電層285(tunneling dielectric),並在位於選擇閘極21與抹除閘極22之間的穿隧介電層285上形成浮動閘極23a。 Please refer to Figure 7C, in the bare selected gate 21, select gate coverage Dielectric layer 281, substrate 20, first doped dielectric layer 283, erase gate 22 and/or erase gate cover dielectric layer 284 surface form a tunneling dielectric layer 285 (tunneling dielectric), and A floating gate 23a is formed on the tunnel dielectric layer 285 between the selection gate 21 and the erase gate 22.

浮動閘極23a具有一凸出結構231以及一延伸結構233,其中凸出結構231由浮動閘極23a朝抹除閘極22的方向延伸,使得部分或全部的凸出結構231位於抹除閘極22與第一摻雜區25之間,換句話說,第一摻雜區25位於抹除閘極22以及部分浮動閘極23a的投影下方。凸出結構231的形成是由於在第7B圖的步驟中,使第一摻雜區介電層283在第一方向X的長度或在XZ方向的截面積較抹除閘極22的長度或截面積小,讓抹除閘極22以及第一摻雜區25及/或基板20間具有一容置空間,因此在形成浮動閘極23a時,浮動閘極23a靠近抹除閘極22的側壁會延伸至容置空間內,進而形成凸出結構231。 The floating gate 23a has a protruding structure 231 and an extending structure 233, wherein the protruding structure 231 extends from the floating gate 23a toward the erasing gate 22, so that part or all of the protruding structure 231 is located at the erasing gate. Between 22 and the first doped region 25, in other words, the first doped region 25 is located below the projection of the erase gate 22 and a portion of the floating gate 23a. The protrusion structure 231 is formed because in the step of FIG. 7B, the length of the first doped dielectric layer 283 in the first direction X or the cross-sectional area in the XZ direction is larger than the length of the erase gate 22 or The small area has an accommodating space between the erase gate 22 and the first doped region 25 and/or the substrate 20. Therefore, when the floating gate 23a is formed, the floating gate 23a is close to the sidewall of the erase gate 22. The truss structure 231 is formed by extending into the accommodating space.

延伸結構233則是由浮動閘極23a朝選擇閘極21的方向延伸。延伸結構233的形成是由於在第7B圖的步驟中,使選擇閘極覆蓋介電層281在第一方向X的長度或在XZ方向的截面積較選擇閘極21的長度或截面積小,讓選擇閘極22的上表面以及選擇閘極覆蓋介電層281的側壁之間具有一容置空間,因此在形成浮動閘極23a時,浮動閘極23a靠近選擇閘極21的側壁會延伸至容置空間內,進而形成延伸結構233。 The extension structure 233 extends from the floating gate 23a toward the selection gate 21. The extension structure 233 is formed because, in the step of FIG. 7B, the length of the selective gate capping dielectric layer 281 in the first direction X or the cross-sectional area in the XZ direction is smaller than the length or cross-sectional area of the selection gate 21, There is an accommodating space between the upper surface of the selection gate 22 and the sidewall of the selective gate-covering dielectric layer 281. Therefore, when the floating gate 23a is formed, the floating gate 23a extends to the side wall of the selection gate 21 to The accommodating space further forms an extension structure 233.

請參閱第7D圖,在形成抹除閘極23a之後,接著依序形成耦合閘極介電層286、耦合閘極24以及第二摻雜區26,即可完成本發明實施例的非揮發性記憶體單元2A。其中耦合閘極介電層286、耦合閘極24以及第二摻雜區26的形成順序可以做調整。例如也可以先形成第二摻雜區26,再 形成耦合閘極介電層286以及抹除閘極24,或是先形成耦合閘極介電層286,接著形成第二摻雜區26,最後再形成耦合閘極24。 Referring to FIG. 7D, after forming the erase gate 23a, the coupled gate dielectric layer 286, the coupling gate 24, and the second doping region 26 are sequentially formed to complete the non-volatile embodiment of the present invention. Memory unit 2A. The order in which the coupled gate dielectric layer 286, the coupled gate 24, and the second doped region 26 are formed can be adjusted. For example, the second doping region 26 may be formed first, and then The coupled gate dielectric layer 286 and the erase gate 24 are formed, or the coupled gate dielectric layer 286 is formed first, followed by the second doped region 26, and finally the coupled gate 24 is formed.

在本發明一實施例中,非揮發性記憶體單元2A的基板20亦可包含一表面介電層287,位於基板20與選擇閘極21、浮動閘極23a及抹除閘極22之間。 In an embodiment of the invention, the substrate 20 of the non-volatile memory cell 2A may also include a surface dielectric layer 287 between the substrate 20 and the select gate 21, the floating gate 23a, and the erase gate 22.

第二摻雜區26位於基板20中,與第一摻雜區25相鄰,且第一摻雜區25與第二摻雜區26之間可存在一設置空間。耦合閘極介電層286覆蓋在裸露出的穿隧介電層285、浮動閘極23a以及抹除閘極介電層285上。耦合閘極24位於耦合閘極介電層286上,並且在抹除閘極22、浮動閘極23a、以及部分抹除閘極21的投影上方。 The second doping region 26 is located in the substrate 20 adjacent to the first doping region 25, and an arrangement space may exist between the first doping region 25 and the second doping region 26. A coupled gate dielectric layer 286 overlies the exposed tunnel dielectric layer 285, the floating gate 23a, and the erase gate dielectric layer 285. The coupling gate 24 is located on the coupled gate dielectric layer 286 and over the projections of the erase gate 22, the floating gate 23a, and the partial erase gate 21.

第7D圖與第6圖皆為本發明第三實施例所述之非揮發性記憶體單元2A的剖面圖,包含了相鄰的兩個非揮發性記憶體單元2A,其中兩相鄰的非揮發性記憶體2A共用抹除閘極22、耦合閘極24以及第一摻雜區25。主要差異在於第7D圖將每一個介電層28依製程需求一一分層表示,第6圖則是將所有的介電層28視為一體。 7D and 6 are cross-sectional views of a non-volatile memory cell 2A according to a third embodiment of the present invention, including two adjacent non-volatile memory cells 2A, two adjacent non- The volatile memory 2A shares the erase gate 22, the coupling gate 24, and the first doping region 25. The main difference is that the 7D pattern shows each dielectric layer 28 in a layered manner according to the process requirements. Figure 6 shows all the dielectric layers 28 as one.

而在實際應用時,當選擇閘極覆蓋介電層281、第一摻雜區介電層283、抹除閘極覆蓋介電層284、穿隧介電層285以及耦合閘極介電層286的材料相同時,非揮發性記憶體單元2A的剖面將很難分辨出不同介電層28的交界,剖面會接近第6圖的構造。反之當選擇閘極覆蓋介電層281、第一摻雜區介電層283、抹除閘極覆蓋介電層284、穿隧介電層285以及耦合閘極介電層286的材料不同時,非揮發性記憶體單元2A的剖面將較容易分辨出不同介電層28的交界,剖面會接近第7D圖的構造。 In practical applications, when the gate capping dielectric layer 281, the first doped dielectric layer 283, the erase gate capping dielectric layer 284, the tunneling dielectric layer 285, and the coupled gate dielectric layer 286 are selected. When the materials are the same, the profile of the non-volatile memory cell 2A will be difficult to distinguish the junction of the different dielectric layers 28, and the profile will be close to the configuration of FIG. Conversely, when the materials for selecting the gate capping dielectric layer 281, the first doped dielectric layer 283, the erase gate capping dielectric layer 284, the tunneling dielectric layer 285, and the coupled gate dielectric layer 286 are different, The cross-section of the non-volatile memory cell 2A will make it easier to distinguish the junction of the different dielectric layers 28, and the profile will be close to the configuration of Figure 7D.

請參閱第8圖,為本發明非揮發性記憶體單元第四實施例的剖面圖,包含兩個沿著第一方向X相鄰的非揮發性記憶體單元2B。如圖所示,本發明所述的非揮發性記憶體單元2B包括一基板20、一選擇閘極21、一抹除閘極22、一浮動閘極23b、一耦合閘極24以及一個或一個以上的介電層28。並請配合參閱第6圖以及第7D圖,非揮發性記憶體單元2B與第三實施例中的非揮發性記憶體單元2A類似,主要差異在於非揮發性記憶體單元2B在製作時,並未在選擇閘極21上製作一選擇閘極覆蓋介電層281,因而使得浮動閘極23b靠近選擇閘極21的側壁不具有延伸結構233。本發明所述的非揮發性記憶體單元2B的其他的構造已於第三實施例中說明,在此便不再贅述。 Referring to FIG. 8, a cross-sectional view of a fourth embodiment of a non-volatile memory cell of the present invention includes two non-volatile memory cells 2B adjacent in a first direction X. As shown, the non-volatile memory cell 2B of the present invention includes a substrate 20, a select gate 21, an erase gate 22, a floating gate 23b, a coupled gate 24, and one or more Dielectric layer 28. Referring to FIG. 6 and FIG. 7D together, the non-volatile memory unit 2B is similar to the non-volatile memory unit 2A in the third embodiment, the main difference being that the non-volatile memory unit 2B is in production, and A selective gate capping dielectric layer 281 is not formed on the select gate 21, such that the sidewall of the floating gate 23b adjacent to the select gate 21 does not have the extension structure 233. Other configurations of the non-volatile memory unit 2B of the present invention have been described in the third embodiment and will not be described again.

請參閱第9圖,為本發明非揮發性記憶體單元第五實施例的剖面圖,包含兩個沿著第一方向X相鄰的非揮發性記憶體單元3。非揮發性記憶體單元3包括一基板30、一選擇閘極31、一抹除閘極32、一浮動閘極33、一耦合閘極34以及一個或一個以上的介電層38。 Referring to FIG. 9, a cross-sectional view of a fifth embodiment of a non-volatile memory cell of the present invention includes two non-volatile memory cells 3 adjacent in a first direction X. The non-volatile memory unit 3 includes a substrate 30, a select gate 31, an erase gate 32, a floating gate 33, a coupled gate 34, and one or more dielectric layers 38.

請配合參閱第2圖,本發明所述之非揮發性記憶體單元3的結構與本發明第一實施例之非揮發性記憶體單元1A類似,主要差異在於浮動閘極33以及耦合閘極34在第一方向X及第二方向Y所構成之平面上的截面積較第一實施例小,且耦合閘極34的位置在第二方向Y上較靠近基板30。具體來說本發明實施例的浮動閘極33在第二方向Y上的高度小於選擇閘極31,使得部分的耦合閘極34與選擇閘極31及抹除閘極32於第二方向Y上重疊,例如部分的耦合閘極34位於選擇閘極31及抹除閘極32之間的容置空間內。此外本發明實施例的耦合僅設置在浮動閘極33的投影上,並未設置在 選擇閘極31及抹除閘極32的投影上。 Referring to FIG. 2, the structure of the non-volatile memory unit 3 of the present invention is similar to that of the non-volatile memory unit 1A of the first embodiment of the present invention, and the main difference is the floating gate 33 and the coupling gate 34. The cross-sectional area on the plane formed by the first direction X and the second direction Y is smaller than that of the first embodiment, and the position of the coupling gate 34 is closer to the substrate 30 in the second direction Y. Specifically, the floating gate 33 of the embodiment of the present invention has a height in the second direction Y that is smaller than the selection gate 31 such that a portion of the coupling gate 34 and the selection gate 31 and the erase gate 32 are in the second direction Y. Overlap, for example, a portion of the coupled gate 34 is located in the accommodating space between the select gate 31 and the erase gate 32. In addition, the coupling of the embodiment of the present invention is only disposed on the projection of the floating gate 33, and is not disposed in the The projection of the gate 31 and the erase gate 32 is selected.

另一主要差異在於本發明實施例沿著第一方向X相鄰的兩個非揮發性記憶體單元3僅共用抹除閘極32以及第一摻雜區35,並未共用耦合閘極34。本發明實施例所述的非揮發性記憶體單元3的其他的構造已於第一實施例中說明,在此便不再贅述。 Another major difference is that the two non-volatile memory cells 3 adjacent in the first direction X of the embodiment of the present invention share only the erase gate 32 and the first doped region 35, and do not share the coupled gate 34. Other configurations of the non-volatile memory unit 3 according to the embodiment of the present invention have been described in the first embodiment, and will not be described again.

在本發明一實施例中,基板30包含一表面介電層387,位於30基板與選擇閘極31、浮動閘極33及抹除閘極32之間。如第9圖中的虛線所示,當基板30包括表面介電層387時,第一摻雜區35以及第二摻雜區36將會位於基板30中靠近表面介電層387的位置。 In an embodiment of the invention, the substrate 30 includes a surface dielectric layer 387 between the substrate 30 and the select gate 31, the floating gate 33, and the erase gate 32. As shown by the dashed line in FIG. 9, when the substrate 30 includes the surface dielectric layer 387, the first doped region 35 and the second doped region 36 will be located in the substrate 30 near the surface dielectric layer 387.

在本發明另一實施例中,本發明所述之非揮發性記憶體單元3包含一選擇閘極覆蓋介電層381,其中選擇閘極覆蓋介電層381位於選擇閘極31的上表面。 In another embodiment of the present invention, the non-volatile memory cell 3 of the present invention includes a selective gate capping dielectric layer 381, wherein the selective gate capping dielectric layer 381 is located on the upper surface of the select gate 31.

在本發明另一實施例中,浮動閘極33可以如第三實施例中的浮動閘極23a一樣,在靠近抹除閘極22/32的側壁具有一凸出結構231,如第6圖所示。 In another embodiment of the present invention, the floating gate 33 may have a protruding structure 231 near the sidewall of the erase gate 22/32 as in the floating gate 23a of the third embodiment, as shown in FIG. Show.

本發明實施例所述之非揮發性記憶體單元3的製造方法與本發明第一實施例所述之非揮發性記憶體單元1相似,可以透過第3A至第3F的製程步驟製造。主要差異在於形成浮動閘極33時,浮動閘極33在第二方向Y上的長度較選擇閘極32短。另一主要差異在於形成耦合閘極34時,耦合閘極34於第二方向Y上僅位於浮動閘極33的投影上方,而未位於選擇閘極31以及抹除閘極32的投影上方。 The method for manufacturing the non-volatile memory unit 3 according to the embodiment of the present invention is similar to the non-volatile memory unit 1 of the first embodiment of the present invention, and can be manufactured through the process steps of the third to third embodiments. The main difference is that when the floating gate 33 is formed, the length of the floating gate 33 in the second direction Y is shorter than that of the selection gate 32. Another major difference is that when the coupling gate 34 is formed, the coupling gate 34 is only above the projection of the floating gate 33 in the second direction Y, and not above the projection of the selection gate 31 and the erase gate 32.

說明書中所描述之也許、必須及變化等字眼並非本創作之 限制。說明書所使用的專業術語主要用以進行特定實施例的描述,並不為本創作的限制。說明書所使用的單數量詞(如一個及該個)亦可為複數個,除非在說明書的內容有明確的說明。例如說明書所提及之一個裝置可包括有兩個或兩個以上之裝置的結合,而說明書所提之一物質則可包括有多種物質的混合。 The words, perhaps, and changes described in the manual are not the creation of this work. limit. The technical terms used in the specification are mainly for the description of specific embodiments, and are not intended to be limiting. The single quantifiers (such as one and the one) used in the specification may also be plural, unless explicitly stated in the contents of the specification. For example, a device referred to in the specification may include a combination of two or more devices, and one of the materials mentioned in the specification may include a mixture of a plurality of substances.

以上所述者,僅為本創作之較佳實施例而已,並非用來限定本創作實施之範圍,即凡依本創作申請專利範圍所述之形狀、構造、特徵及精神所為之均等變化與修飾,均應包括於本創作之申請專利範圍內。 The above is only the preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, that is, the equivalent changes and modifications of the shapes, structures, features and spirits described in the scope of the patent application. , should be included in the scope of the patent application of this creation.

1A‧‧‧非揮發性記體單元 1A‧‧‧Non-volatile record unit

10‧‧‧基板 10‧‧‧Substrate

11‧‧‧選擇閘極 11‧‧‧Selecting the gate

12‧‧‧抹除閘極 12‧‧‧ Wipe the gate

13‧‧‧浮動閘極 13‧‧‧Floating gate

14‧‧‧耦合閘極 14‧‧‧coupled gate

15‧‧‧第一摻雜區 15‧‧‧First doped area

16‧‧‧第二摻雜區 16‧‧‧Second doped area

18‧‧‧介電層 18‧‧‧ dielectric layer

Claims (18)

一種非揮發性記憶體單元,包括:一基板,包括一第一摻雜區及至少一第二摻雜區,其中該第一摻雜區與該第二摻雜區相鄰;一選擇閘極,設置於該基板上,並位於該第一摻雜區與該第二摻雜區之間;一抹除閘極,位於該第一摻雜區上方;一浮動閘極,位於該選擇閘極以及該抹除閘極之間;一耦合閘極,位於該抹除閘極、該浮動閘極以及部份選擇閘極的投影上方;及一個或一個以上的介電層,用以作絕緣層,位於相鄰之該選擇閘極、該抹除閘極、該浮動閘極、該耦合閘極或該第一摻雜區之間。 A non-volatile memory cell includes: a substrate including a first doped region and at least a second doped region, wherein the first doped region is adjacent to the second doped region; and a select gate And disposed on the substrate between the first doped region and the second doped region; a wipe gate is located above the first doped region; a floating gate is located at the select gate and Between the erase gates; a coupled gate over the projection of the erase gate, the floating gate and a portion of the select gate; and one or more dielectric layers for the insulating layer, Located adjacent to the select gate, the erase gate, the floating gate, the coupling gate, or the first doped region. 如申請專利範圍第1項所述的非揮發性記憶體單元,該基板包含一表面介電層,位於該基板與該選擇閘極、該浮動閘極及該抹除閘極之間。 The non-volatile memory unit of claim 1, wherein the substrate comprises a surface dielectric layer between the substrate and the select gate, the floating gate and the erase gate. 如申請專利範圍第1項所述的非揮發性記憶體單元,該介電層包括:一第一襯底介電層,包覆該選擇閘極的側壁以及上表面,厚度介於10Å到150Å之間;一抹除閘極介電層,包覆該抹除閘極周圍,並位於該抹除閘極與該基板、該浮動閘極及該耦合閘極之間,厚度介於100Å到600Å之間;一耦合閘極介電層,位於該耦合閘極與該抹除閘極、該浮動閘極以及該選擇閘極之間,厚度介於100Å到300Å之間。 The non-volatile memory unit of claim 1, wherein the dielectric layer comprises: a first substrate dielectric layer covering the sidewalls and the upper surface of the selective gate, and the thickness is between 10 Å and 150 Å. a wiper dielectric layer covering the erase gate and located between the erase gate and the substrate, the floating gate and the coupling gate, and having a thickness between 100 Å and 600 Å a coupled gate dielectric layer between the coupled gate and the erase gate, the floating gate, and the select gate, and having a thickness between 100 Å and 300 Å. 如申請專利範圍第3項所述的非揮發性記憶體單元,該第一襯底介電層、該抹除閘極介電層以及該耦合閘極介電層的材料為氧化矽或高介電材料複合物。 The non-volatile memory cell of claim 3, wherein the first substrate dielectric layer, the erase gate dielectric layer, and the material of the coupled gate dielectric layer are yttrium oxide or high dielectric. Electrical material composite. 如申請專利範圍第1項所述的非揮發性記憶體單元,該介電層包括:一第一襯底介電層,位於該浮動閘極與該選擇閘極之間以及該浮動閘極與該基板之間,厚度介於50Å到200Å之間;及 一抹除閘極介電層,位於該浮動閘極與該抹除閘極之間,厚度介於50Å到200Å之間。 The non-volatile memory cell of claim 1, wherein the dielectric layer comprises: a first substrate dielectric layer between the floating gate and the select gate and the floating gate The thickness between the substrates is between 50 Å and 200 Å; A wiper dielectric layer is located between the floating gate and the erase gate and has a thickness between 50 Å and 200 Å. 如申請專利範圍第5項所述的非揮發性記憶體單元,該第一襯底介電層及該抹除閘極介電層的材料為氧化矽或高介電材料複合物。 The non-volatile memory cell of claim 5, wherein the first substrate dielectric layer and the erase gate dielectric layer are made of yttria or a high dielectric material composite. 如申請專利範圍第1項所述的非揮發性記憶體單元,該介電層包括一選擇閘極覆蓋介電層,設置於該選擇閘極的上表面。 The non-volatile memory cell of claim 1, wherein the dielectric layer comprises a selective gate capping dielectric layer disposed on an upper surface of the select gate. 如申請專利範圍第1項所述的非揮發性記憶體單元,其中該選擇閘極的厚度介於200Å到2000Å之間,該抹除閘極的厚度介於200Å到2000Å之間,該浮動閘極的厚度介於150Å到2000Å之間。 The non-volatile memory unit according to claim 1, wherein the thickness of the selection gate is between 200 Å and 2000 Å, and the thickness of the erase gate is between 200 Å and 2000 Å. The thickness of the pole is between 150Å and 2000Å. 如申請專利範圍第1項所述的非揮發性記憶體單元,其中該浮動閘極靠近抹除閘極的側壁為平面結構或具有一凸出結構。 The non-volatile memory unit of claim 1, wherein the floating gate is adjacent to the sidewall of the erase gate as a planar structure or has a convex structure. 如申請專利範圍第9項所述的非揮發性記憶體單元,其中該浮動閘極的該凸出結構位於該第一摻雜區與該抹除閘極之間。 The non-volatile memory cell of claim 9, wherein the protruding structure of the floating gate is between the first doped region and the erase gate. 一種非揮發性記憶體單元的製作方法,其步驟包括:提供一基板;形成一位於該基板上的選擇閘極;形成一第一襯底介電層覆蓋該選擇閘極及該基板,並在該基板內形成一第一摻雜區;於該第一襯底介電層上形成一抹除閘極,其中該抹除閘極位於該第一摻雜區上方;形成一包覆該抹除閘極的抹除閘極介電層;於該選擇閘極以及該抹除閘極之間形成一浮動閘極;形成一耦合閘極介電層覆蓋裸露出的該第一襯底介電層、該抹除閘極介電層以及該浮動閘極;及於該耦合閘極介電層上形成一耦合閘極。 A method for fabricating a non-volatile memory cell, the method comprising: providing a substrate; forming a selection gate on the substrate; forming a first substrate dielectric layer covering the selection gate and the substrate, and Forming a first doped region in the substrate; forming a erase gate on the first substrate dielectric layer, wherein the erase gate is above the first doped region; forming a wrap-around erase gate a gate dielectric layer is formed, a floating gate is formed between the select gate and the erase gate; and a coupled gate dielectric layer is formed to cover the exposed first substrate dielectric layer, The gate dielectric layer and the floating gate are erased; and a coupling gate is formed on the coupled gate dielectric layer. 如申請專利範圍第11項所述的非揮發性記憶體單元的製作方法,其中該耦合閘極位於該抹除閘極、該浮動閘極以及部份該選擇閘極的投影上方。 The method of fabricating the non-volatile memory unit of claim 11, wherein the coupling gate is located above the projection of the erase gate, the floating gate, and a portion of the select gate. 如申請專利範圍第11項所述的非揮發性記憶體單元的製作方法,其中該耦合閘極位於該浮動閘極的投影上方。 The method of fabricating the non-volatile memory unit of claim 11, wherein the coupling gate is located above the projection of the floating gate. 如申請專利範圍第11項所述的非揮發性記憶體單元的製作方法,包括以下步驟:於該基板中形成一第二摻雜區,其中該第一摻雜區與該第二摻雜區相鄰。 The method for fabricating a non-volatile memory cell according to claim 11, comprising the steps of: forming a second doped region in the substrate, wherein the first doped region and the second doped region Adjacent. 如申請專利範圍第11項所述的非揮發性記憶體單元的製作方法,包括以下步驟:於形成該第一襯底介電層之後,形成至少一犧牲間隔物於第一襯底介電層上,其中該犧牲間隔物與該選擇閘極相鄰;及於形成該抹除閘極介電層之後,移除位於該抹除閘極以及該選擇閘極之間的該犧牲間隔物。 The method for fabricating a non-volatile memory cell according to claim 11, comprising the steps of: forming at least one sacrificial spacer on the first substrate dielectric layer after forming the first substrate dielectric layer The sacrificial spacer is adjacent to the select gate; and after the erase gate dielectric layer is formed, the sacrificial spacer between the erase gate and the select gate is removed. 一種非揮發性記憶體單元的製作方法,其步驟包括:提供一基板;形成一位於該基板上的選擇閘極;形成一第一摻雜區、一第一摻雜區介電層、一抹除閘極以及一抹除閘極覆蓋介電層,其中該第一摻雜區設置在該基板內,該第一摻雜區介電層設置於該基板上,並位於該第一摻雜區上,該抹除閘極設置於第一摻雜區介電層上,而該抹除閘極覆蓋介電層設置於該抹除閘極上;移除部分該第一摻雜區介電層、部分該抹除閘極覆蓋介電層,使得該第一摻雜區介電層以及該抹除閘極覆蓋介電層的長度或截面積小於該抹除閘極;形成一穿隧介電層覆蓋裸露出的該選擇閘極、該抹除閘極、該第一摻雜區介電層、該抹除閘極覆蓋介電層以及部分該基板的表面;形成一浮動閘極,位於該選擇閘極以及該抹除閘極之間,其中該浮動閘極靠近該抹除閘極的一側壁具有一凸出結構;形成一耦合閘極介電層覆蓋裸露出的該穿隧介電層以及該浮動閘極; 及於該耦合閘極介電層上形成一耦合閘極。 A method for fabricating a non-volatile memory cell, the method comprising: providing a substrate; forming a selective gate on the substrate; forming a first doped region, a first doped dielectric layer, and an erase layer a gate electrode and a gate electrode covering the dielectric layer, wherein the first doped region is disposed in the substrate, the first doped region dielectric layer is disposed on the substrate, and is located on the first doped region The erase gate is disposed on the first doped dielectric layer, and the erase gate cover dielectric layer is disposed on the erase gate; removing part of the first doped dielectric layer, part of the Wiping the gate to cover the dielectric layer, such that the first doped region dielectric layer and the erase gate cover dielectric layer have a length or a cross-sectional area smaller than the erase gate; forming a tunneling dielectric layer to cover the bare The selection gate, the erase gate, the first doped dielectric layer, the erase gate cover dielectric layer and a portion of the surface of the substrate; forming a floating gate at the select gate And between the erase gates, wherein a side of the floating gate adjacent to the erase gate has a convex Structure; forming a gate dielectric coupled to cover the bare tunneling dielectric layer and the floating gate; And forming a coupling gate on the coupled gate dielectric layer. 如申請專利範圍第16項所述的非揮發性記憶體單元的製作方法,包括以下步驟:在形成該選擇閘極之後,形成一第一襯底介電層覆蓋該選擇閘極及該基板;形成至少一犧牲間隔物於該第一襯底介電層上,其中該犧牲間隔物與該選擇閘極相鄰;形成一第二襯底介電層覆蓋裸露出的該第一襯底介電層以及該犧牲間隔物;形成該抹除閘極在該第二襯底介電層上,其中該抹除閘極位於該第一摻雜區上方,並位於兩相鄰的該犧牲間隔物之間;及於形成該抹除閘極覆蓋介電層之後,移除該犧牲間隔物、部分該第一襯底介電層以及部分該第二襯底介電層,保留位於該抹除閘極與該第一摻雜區之間的該第一襯底介電層以及該第二襯底介電層,藉此在該抹除閘極與該第一摻雜區之間形成該第一摻雜區介電層。 The method for fabricating a non-volatile memory cell according to claim 16 includes the following steps: after forming the selective gate, forming a first substrate dielectric layer covering the selective gate and the substrate; Forming at least one sacrificial spacer on the first substrate dielectric layer, wherein the sacrificial spacer is adjacent to the select gate; forming a second substrate dielectric layer overlying the exposed first substrate dielectric a layer and the sacrificial spacer; forming the erase gate on the second substrate dielectric layer, wherein the erase gate is above the first doped region and located between two adjacent sacrificial spacers And after forming the erase gate capping dielectric layer, removing the sacrificial spacer, a portion of the first substrate dielectric layer, and a portion of the second substrate dielectric layer, remaining at the erase gate The first substrate dielectric layer and the second substrate dielectric layer are disposed between the first doped region, thereby forming the first doping between the erase gate and the first doped region Miscellaneous dielectric layer. 如申請專利範圍第16項所述的非揮發性記憶體單元的製作方法,包括以下步驟:於形成該選擇閘極之後,在該選擇閘極及該基板上形成一介電層;移除部分該介電層,保留該選擇閘極上表面及部分該基板上的該介電層,藉此在該選擇閘極上表面形成一選擇閘極覆蓋介電層,及在部分該基板的上表面形成該第一摻雜區介電層。 The method for fabricating a non-volatile memory unit according to claim 16, comprising the steps of: forming a dielectric layer on the selection gate and the substrate after forming the selection gate; removing the portion The dielectric layer retains the upper surface of the selective gate and a portion of the dielectric layer on the substrate, thereby forming a selective gate capping dielectric layer on the upper surface of the selective gate, and forming the portion on the upper surface of the substrate The first doped region dielectric layer.
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