TWI579849B - Memory device and method of manufacturing the same - Google Patents
Memory device and method of manufacturing the same Download PDFInfo
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- TWI579849B TWI579849B TW104122922A TW104122922A TWI579849B TW I579849 B TWI579849 B TW I579849B TW 104122922 A TW104122922 A TW 104122922A TW 104122922 A TW104122922 A TW 104122922A TW I579849 B TWI579849 B TW I579849B
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- 238000004519 manufacturing process Methods 0.000 title claims description 18
- 239000003990 capacitor Substances 0.000 claims description 95
- 239000000758 substrate Substances 0.000 claims description 67
- 238000000034 method Methods 0.000 claims description 42
- 229910052751 metal Inorganic materials 0.000 claims description 39
- 239000002184 metal Substances 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 38
- 125000006850 spacer group Chemical group 0.000 claims description 23
- 230000001681 protective effect Effects 0.000 claims description 17
- 238000000059 patterning Methods 0.000 claims description 3
- 239000004020 conductor Substances 0.000 description 13
- 238000005137 deposition process Methods 0.000 description 8
- 239000010936 titanium Substances 0.000 description 8
- 239000010949 copper Substances 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 238000005229 chemical vapour deposition Methods 0.000 description 6
- 238000001312 dry etching Methods 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- MZLGASXMSKOWSE-UHFFFAOYSA-N tantalum nitride Chemical compound [Ta]#N MZLGASXMSKOWSE-UHFFFAOYSA-N 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000003989 dielectric material Substances 0.000 description 4
- 150000004767 nitrides Chemical class 0.000 description 4
- MAKDTFFYCIMFQP-UHFFFAOYSA-N titanium tungsten Chemical compound [Ti].[W] MAKDTFFYCIMFQP-UHFFFAOYSA-N 0.000 description 4
- 229910000314 transition metal oxide Inorganic materials 0.000 description 4
- 238000005240 physical vapour deposition Methods 0.000 description 3
- 229910001925 ruthenium oxide Inorganic materials 0.000 description 3
- WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 238000001459 lithography Methods 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
- 229910052684 Cerium Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 1
- PMHQVHHXPFUNSP-UHFFFAOYSA-M copper(1+);methylsulfanylmethane;bromide Chemical compound Br[Cu].CSC PMHQVHHXPFUNSP-UHFFFAOYSA-M 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- Semiconductor Memories (AREA)
Description
本發明是有關於一種半導體元件及其製造方法,且特別是有關於一種記憶元件及其製造方法。 The present invention relates to a semiconductor device and a method of fabricating the same, and more particularly to a memory device and a method of fabricating the same.
電阻式隨機存取記憶體(Resistive Random Access Memory,RRAM)是目前積極發展的一種下一世代非揮發性記憶體。電阻式隨機存取記憶體是一種簡單的金屬-絕緣-金屬(MIM)結構,可以透過額外的兩個罩幕步驟整合到後段的金屬製程。然而,透過上述方式所形成的電阻式隨機存取記憶體,可能會因為後段沈積製程與乾式蝕刻製程,而導致電漿損害(Plasma Induced Damage,PID)的產生。上述電漿損害不僅影響記憶元件的電性表現,還會降低產品的可靠度(Reliability)與良率(Yield)。 Resistive Random Access Memory (RRAM) is a next-generation non-volatile memory that is currently actively developed. Resistive random access memory is a simple metal-insulator-metal (MIM) structure that can be integrated into the back-end metal process through an additional two mask steps. However, the resistive random access memory formed by the above method may cause plasma inductive damage (PID) due to the subsequent deposition process and the dry etching process. The above plasma damage not only affects the electrical performance of the memory element, but also reduces the reliability and yield of the product.
本發明提供一種記憶元件及其製造方法,其可減少電漿損害的產生,以提升產品的可靠度與良率。 The invention provides a memory element and a manufacturing method thereof, which can reduce the generation of plasma damage to improve the reliability and yield of the product.
本發明提供一種記憶元件,包括基底、電容器、保護元件、第一金屬內連線以及第二金屬內連線。基底具有第一區與第二區。電容器位於第一區的基底上。電容器包括多個下電極、上電極以及電容介電層。上電極具有第一部分以及第二部分。所述第一部分覆蓋下電極,而所述第二部分延伸至第二區的基底上。電容介電層位於下電極與上電極的第一部分之間。保護元件位於第二區的基底中。第一金屬內連線位於電容器與基底之間,其將下電極電性連接至基底。第二金屬內連線位於上電極的第二部分與保護元件之間,其將上電極的第二部分電性連接至保護元件。 The present invention provides a memory device including a substrate, a capacitor, a protection element, a first metal interconnect, and a second metal interconnect. The substrate has a first zone and a second zone. The capacitor is located on the substrate of the first zone. The capacitor includes a plurality of lower electrodes, an upper electrode, and a capacitor dielectric layer. The upper electrode has a first portion and a second portion. The first portion covers the lower electrode and the second portion extends onto the substrate of the second region. A capacitor dielectric layer is between the lower electrode and the first portion of the upper electrode. The protective element is located in the base of the second zone. The first metal interconnect is located between the capacitor and the substrate, which electrically connects the lower electrode to the substrate. A second metal interconnect is located between the second portion of the upper electrode and the protective element that electrically connects the second portion of the upper electrode to the protective element.
在本發明的一實施例中,所述電容介電層為連續平面結構、連續凹凸結構或非連續平面結構。 In an embodiment of the invention, the capacitor dielectric layer is a continuous planar structure, a continuous relief structure or a discontinuous planar structure.
在本發明的一實施例中,所述上電極的所述第一部分為連續平面結構或是連續凹凸結構。 In an embodiment of the invention, the first portion of the upper electrode is a continuous planar structure or a continuous concave-convex structure.
在本發明的一實施例中,所述記憶元件更包括介電層位於下電極之間。電容介電層為連續平面結構,且覆蓋下電極以及介電層的頂面。 In an embodiment of the invention, the memory element further includes a dielectric layer between the lower electrodes. The capacitor dielectric layer is a continuous planar structure and covers the lower electrode and the top surface of the dielectric layer.
在本發明的一實施例中,所述電容介電層為連續凹凸結構,且覆蓋所述下電極的頂面與側壁。 In an embodiment of the invention, the capacitor dielectric layer is a continuous relief structure and covers a top surface and a sidewall of the lower electrode.
在本發明的一實施例中,所述電容介電層為非連續平面結構,覆蓋下電極的頂面。 In an embodiment of the invention, the capacitive dielectric layer is a discontinuous planar structure covering a top surface of the lower electrode.
在本發明的一實施例中,所述記憶元件更包括多個間隙壁分別位於下電極以及電容介電層的側壁。 In an embodiment of the invention, the memory element further includes a plurality of spacers respectively located on the lower electrode and sidewalls of the capacitor dielectric layer.
在本發明的一實施例中,所述保護元件為二極體、雙載子接面電晶體或其組合。 In an embodiment of the invention, the protection element is a diode, a bipolar junction transistor, or a combination thereof.
在本發明的一實施例中,所述電容介電層的材料為可變電阻材料。 In an embodiment of the invention, the material of the capacitor dielectric layer is a variable resistance material.
在本發明的一實施例中,所述可變電阻材料為氧化矽或是過渡金屬氧化物。所述過渡金屬氧化物為ZrO2、HfO2、Ta2O5、Al2O3、TiO2或其組合。 In an embodiment of the invention, the variable resistance material is ruthenium oxide or a transition metal oxide. The transition metal oxide is ZrO 2 , HfO 2 , Ta 2 O 5 , Al 2 O 3 , TiO 2 or a combination thereof.
本發明提供一種記憶元件的製造方法,其步驟如下。提供基底。基底具有第一區與第二區。於第一區的基底上形成電容器。電容器包括多個下電極、上電極以及電容介電層。上電極具有第一部分以及第二部分。所述第一部分覆蓋下電極,而所述第二部分延伸至第二區的基底上。電容介電層位於下電極與上電極的第一部分之間。於第二區的基底中形成保護元件。於電容器與基底之間形成第一金屬內連線。第一金屬內連線電性連接下電極與基底。於上電極的第二部分與保護元件之間形成第二金屬內連線。第二金屬內連線電性連接上電極的第二部分與保護元件。 The present invention provides a method of manufacturing a memory element, the steps of which are as follows. A substrate is provided. The substrate has a first zone and a second zone. A capacitor is formed on the substrate of the first region. The capacitor includes a plurality of lower electrodes, an upper electrode, and a capacitor dielectric layer. The upper electrode has a first portion and a second portion. The first portion covers the lower electrode and the second portion extends onto the substrate of the second region. A capacitor dielectric layer is between the lower electrode and the first portion of the upper electrode. A protective element is formed in the substrate of the second region. A first metal interconnect is formed between the capacitor and the substrate. The first metal interconnect is electrically connected to the lower electrode and the substrate. A second metal interconnect is formed between the second portion of the upper electrode and the protective element. The second metal interconnect is electrically connected to the second portion of the upper electrode and the protection element.
在本發明的一實施例中,於第一區的基底上形成電容器的方法如下。於基底上形成下電極。於基底上形成介電層。介電層配置於下電極之間。於下電極上形成電容介電層。電容介電層覆蓋下電極以及介電層的頂面。於電容介電層上形成上電極。 In an embodiment of the invention, a method of forming a capacitor on a substrate of the first region is as follows. A lower electrode is formed on the substrate. A dielectric layer is formed on the substrate. The dielectric layer is disposed between the lower electrodes. A capacitor dielectric layer is formed on the lower electrode. A capacitor dielectric layer covers the lower electrode and the top surface of the dielectric layer. An upper electrode is formed on the capacitor dielectric layer.
在本發明的一實施例中,所述介電層與下電極為共平面,且電容介電層為連續平面結構。 In an embodiment of the invention, the dielectric layer and the lower electrode are coplanar, and the capacitor dielectric layer is a continuous planar structure.
在本發明的一實施例中,於第一區的基底上形成電容器的方法如下。於基底上形成下電極。於下電極上共形地形成電容介電層。電容介電層覆蓋下電極的頂面與側壁。於電容介電層上形成上電極。 In an embodiment of the invention, a method of forming a capacitor on a substrate of the first region is as follows. A lower electrode is formed on the substrate. A capacitor dielectric layer is conformally formed on the lower electrode. A capacitor dielectric layer covers the top and side walls of the lower electrode. An upper electrode is formed on the capacitor dielectric layer.
在本發明的一實施例中,所述電容介電層與其上方的上電極為連續凹凸結構。 In an embodiment of the invention, the capacitor dielectric layer and the upper electrode above it are continuous relief structures.
在本發明的一實施例中,於第一區的基底上形成電容器的方法如下。於基底上依序形成下電極以及電容介電層。所述電容介電層為非連續平面結構,覆蓋下電極的頂面。於下電極與電容介電層的側壁上分別形成多個間隙壁。於電容介電層上形成上電極。上電極覆蓋電容介電層的頂面以及間隙壁的頂面與側壁。 In an embodiment of the invention, a method of forming a capacitor on a substrate of the first region is as follows. A lower electrode and a capacitor dielectric layer are sequentially formed on the substrate. The capacitor dielectric layer is a discontinuous planar structure covering the top surface of the lower electrode. A plurality of spacers are respectively formed on sidewalls of the lower electrode and the capacitor dielectric layer. An upper electrode is formed on the capacitor dielectric layer. The upper electrode covers a top surface of the capacitor dielectric layer and a top surface and a sidewall of the spacer.
在本發明的一實施例中,於下電極與電容介電層的側壁上分別形成間隙壁的方法如下。於電容介電層上分別形成多個犧牲層。於犧牲層上共形地形成間隙壁材料層。移除犧牲層的頂面上的間隙壁材料層,以於下電極與電容介電層的側壁上分別形成間隙壁。移除犧牲層。 In an embodiment of the invention, the method of forming the spacers on the sidewalls of the lower electrode and the capacitor dielectric layer is as follows. A plurality of sacrificial layers are respectively formed on the capacitor dielectric layer. A layer of spacer material is conformally formed on the sacrificial layer. The layer of spacer material on the top surface of the sacrificial layer is removed to form spacers on the sidewalls of the lower electrode and the capacitor dielectric layer, respectively. Remove the sacrificial layer.
在本發明的一實施例中,所述犧牲層的材料包括氧化物、氮化物或其組合。 In an embodiment of the invention, the material of the sacrificial layer comprises an oxide, a nitride, or a combination thereof.
在本發明的一實施例中,所述間隙壁材料層的材料包括氮化物、氧化鋁或其組合。 In an embodiment of the invention, the material of the spacer material layer comprises nitride, aluminum oxide or a combination thereof.
在本發明的一實施例中,在形成所述電容器之後,更包括圖案化所述上電極,以形成多個條狀上電極。 In an embodiment of the invention, after forming the capacitor, patterning the upper electrode further includes forming a plurality of strip-shaped upper electrodes.
基於上述,本發明將上電極電性連接至保護元件,其可避免後段沈積製程與乾式蝕刻製程所導致電漿損害(PID),進而提升產品的可靠度與良率。 Based on the above, the present invention electrically connects the upper electrode to the protective element, which can avoid plasma damage (PID) caused by the post-deposition process and the dry etching process, thereby improving product reliability and yield.
為讓本發明的上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。 The above described features and advantages of the invention will be apparent from the following description.
10、20、30‧‧‧記憶元件 10, 20, 30‧‧‧ memory components
100‧‧‧基底 100‧‧‧Base
104、110、116‧‧‧介電層 104, 110, 116‧‧‧ dielectric layer
106、107、112、206、212‧‧‧接觸插塞 106, 107, 112, 206, 212‧‧‧ contact plugs
108、109、208‧‧‧圖案化導體層 108, 109, 208‧‧‧ patterned conductor layers
105、205‧‧‧金屬內連線 105, 205‧‧‧Metal interconnection
114、214、314‧‧‧下電極 114, 214, 314‧‧‧ lower electrode
118、218、318‧‧‧電容介電層 118, 218, 318‧‧‧ capacitor dielectric layer
120、220、320‧‧‧上電極 120, 220, 320‧‧‧ upper electrode
120a、220a、320a‧‧‧第一部分 120a, 220a, 320a‧‧‧ first part
120b、220b、320b‧‧‧第二部分 120b, 220b, 320b‧‧‧ Part II
130、230、330‧‧‧電容器 130, 230, 330‧ ‧ capacitors
202‧‧‧保護元件 202‧‧‧Protection components
322‧‧‧犧牲層 322‧‧‧sacrificial layer
324‧‧‧間隙壁 324‧‧‧ spacers
D1、D2‧‧‧凹陷 D1, D2‧‧‧ dent
R1‧‧‧第一區 R1‧‧‧ first district
R2‧‧‧第二區 R2‧‧‧Second District
S1‧‧‧表面 S1‧‧‧ surface
圖1A至圖1C為本發明第一實施例之記憶元件的製造流程的剖面示意圖。 1A to 1C are schematic cross-sectional views showing a manufacturing process of a memory element according to a first embodiment of the present invention.
圖2A至圖2C為本發明第二實施例之記憶元件的製造流程的剖面示意圖。 2A to 2C are schematic cross-sectional views showing a manufacturing process of a memory element according to a second embodiment of the present invention.
圖3A至圖3C為本發明第三實施例之記憶元件的製造流程的剖面示意圖。 3A to 3C are schematic cross-sectional views showing a manufacturing process of a memory element according to a third embodiment of the present invention.
圖1A至圖1C為本發明第一實施例之記憶元件的製造流程的剖面示意圖。 1A to 1C are schematic cross-sectional views showing a manufacturing process of a memory element according to a first embodiment of the present invention.
請參照圖1A,提供基底100。基底100具有第一區R1與第二區R2。在本實施例中,基底100並沒有特別地限制。舉例來說,基底100可為任意的半導體基底、可為具有其他膜層於其上的基底,或可為具有其他元件於其中的基底。在一實施例中, 第一區R1可例如是記憶胞區,第二區R2可例如是保護元件區或是周邊電路區。 Referring to FIG. 1A, a substrate 100 is provided. The substrate 100 has a first region R1 and a second region R2. In the present embodiment, the substrate 100 is not particularly limited. For example, substrate 100 can be any semiconductor substrate, can be a substrate having other film layers thereon, or can be a substrate having other components therein. In an embodiment, The first region R1 may be, for example, a memory cell region, and the second region R2 may be, for example, a protection element region or a peripheral circuit region.
接著,於第二區R2的基底100中形成保護元件202。在一實施例中,保護元件202可例如是二極體、雙載子接面電晶體或其組合。只要是能避免後段沈積製程與乾式蝕刻製程所導致電漿損害的保護元件即可,本發明之保護元件的種類、材料與尺寸可依需求來調整。 Next, a protective element 202 is formed in the substrate 100 of the second region R2. In an embodiment, the protective element 202 can be, for example, a diode, a bipolar junction transistor, or a combination thereof. The type, material and size of the protective element of the present invention can be adjusted as needed, as long as it is a protective element that can avoid plasma damage caused by the subsequent deposition process and the dry etching process.
之後,於基底100上形成介電層104、110。介電層104、110的材料例如是低介電常數材料(low K material)或氧化矽。低介電常數材料例如是碳氧化矽(SiOC)。介電層104、110的形成方法可例如是化學氣相沈積法。 Thereafter, dielectric layers 104, 110 are formed on substrate 100. The material of the dielectric layers 104, 110 is, for example, a low K material or yttrium oxide. The low dielectric constant material is, for example, cerium oxycarbide (SiOC). The method of forming the dielectric layers 104, 110 may be, for example, a chemical vapor deposition method.
然後,於第一區R1的基底100上形成金屬內連線105。於第二區R2的基底100上形成金屬內連線205。在本實施例中,金屬內連線105與金屬內連線205可同時形成。但本發明不以此為限,在其他實施例中,可先形成金屬內連線105,而後形成金屬內連線205。反之,亦可先形成金屬內連線205,而後形成金屬內連線105。舉例來說,金屬內連線105與金屬內連線205的形成方法如下。於第一區R1與第二區R2的介電層104中形成多個接觸窗開口,所述接觸窗開口暴露基底100的表面(未繪示)。之後,將導體材料填入所述接觸窗開口,以形成接觸插塞106、107、206(如圖1A所示)。接著,於第一區R1與第二區R2的介電層104上形成圖案化導體層108、109、208。圖案化導體層108電性連接 至接觸插塞106;圖案化導體層109電性連接至接觸插塞107;圖案化導體層208電性連接至接觸插塞206。然後,再於第一區R1與第二區R2的介電層110中形成多個接觸窗開口,所述接觸窗開口分別暴露圖案化導體層108、208的表面(未繪示)。之後,將導體材料填入所述接觸窗開口,以形成接觸插塞112、212(如圖1A所示)。在一實施例中,圖案化導體層109與接觸插塞107可視為電性連接至基底100中的源極;金屬內連線105可視為電性連接至基底100中的汲極;而金屬內連線205則可視為電性連接至第二區R2的基底100中的保護元件202,但本發明不以此為限。 Then, a metal interconnect 105 is formed on the substrate 100 of the first region R1. A metal interconnect 205 is formed on the substrate 100 of the second region R2. In this embodiment, the metal interconnects 105 and the metal interconnects 205 can be formed simultaneously. However, the present invention is not limited thereto. In other embodiments, the metal interconnect 105 may be formed first, and then the metal interconnect 205 is formed. Conversely, the metal interconnect 205 may be formed first, and then the metal interconnect 105 is formed. For example, the method of forming the metal interconnect 105 and the metal interconnect 205 is as follows. A plurality of contact openings are formed in the dielectric layer 104 of the first region R1 and the second region R2, the contact opening exposing a surface (not shown) of the substrate 100. Thereafter, a conductor material is filled into the contact opening to form contact plugs 106, 107, 206 (as shown in Figure 1A). Next, patterned conductor layers 108, 109, 208 are formed on the dielectric layer 104 of the first region R1 and the second region R2. The patterned conductor layer 108 is electrically connected To the contact plug 106; the patterned conductor layer 109 is electrically connected to the contact plug 107; the patterned conductor layer 208 is electrically connected to the contact plug 206. Then, a plurality of contact window openings are formed in the dielectric layer 110 of the first region R1 and the second region R2, and the contact window openings respectively expose surfaces (not shown) of the patterned conductor layers 108, 208. Thereafter, a conductor material is filled into the contact opening to form contact plugs 112, 212 (as shown in Figure 1A). In an embodiment, the patterned conductor layer 109 and the contact plug 107 can be electrically connected to the source in the substrate 100; the metal interconnect 105 can be electrically connected to the drain in the substrate 100; The connection 205 can be regarded as a protection element 202 electrically connected to the substrate 100 of the second region R2, but the invention is not limited thereto.
在一實施例中,接觸插塞106、107、206與接觸插塞112、212的材料可例如是鈦(Ti)、氮化鈦(TiN)、氮化鉭(TaN)、鎢(W)、鈦鎢(TiW)、鋁(Al)、銅(Cu)或其組合。圖案化導體層108、109、208的材料可例如是鈦(Ti)、鎢(W)、鋁(Al)、銅(Cu)或其組合。接觸插塞106、107、206、112、212的材料與圖案化導體層108、109、208的材料可以相同,亦或可以不同。接觸插塞106、107、206、112、212與圖案化導體層108、109、208的形成方法可例如是物理氣相沈積法或化學氣相沈積法。 In an embodiment, the material of the contact plugs 106, 107, 206 and the contact plugs 112, 212 may be, for example, titanium (Ti), titanium nitride (TiN), tantalum nitride (TaN), tungsten (W), Titanium tungsten (TiW), aluminum (Al), copper (Cu), or a combination thereof. The material of the patterned conductor layers 108, 109, 208 may be, for example, titanium (Ti), tungsten (W), aluminum (Al), copper (Cu), or a combination thereof. The material of the contact plugs 106, 107, 206, 112, 212 may be the same as or different from the material of the patterned conductor layers 108, 109, 208. The method of forming the contact plugs 106, 107, 206, 112, 212 and the patterned conductor layers 108, 109, 208 may be, for example, a physical vapor deposition method or a chemical vapor deposition method.
接著,於第一區R1的介電層110上形成多個下電極114。每一個下電極114電性連接至所對應的金屬內連線105。下電極114的材料可例如是鈦、氮化鈦、氮化鉭、鎢、鈦鎢、鋁、銅或其組合。下電極114的形成方法例如是物理氣相沈積法或化學氣相沈積法。之後,於下電極114之間形成介電層116。介電層116的 形成方法可例如是先於基底100上形成介電材料層,以覆蓋下電極114的頂面與側壁以及介電層110的頂面(未繪示)。之後,進行化學機械研磨(CMP)製程,以暴露出下電極114的頂面。在一實施例中,介電材料層的材料可例如是氧化矽、氮化矽、硼磷矽玻璃或其組合,其形成方法可例如是化學氣相沈積法。在其他實施例中,下電極114的形成步驟亦可例如是先在接觸插塞112上方沈積介電材料層,再圖案化介電材料層,以定義後續所形成的下電極114位置。之後,於介電層116之間填入下電極材料層。然後,進行化學機械研磨(CMP)製程,平坦化並暴露出下電極114的頂面。在一實施例中,下電極材料層的材料可例如是鈦、氮化鈦、氮化鉭、鎢、鈦鎢、鋁、銅或其組合。 Next, a plurality of lower electrodes 114 are formed on the dielectric layer 110 of the first region R1. Each lower electrode 114 is electrically connected to the corresponding metal interconnect 105. The material of the lower electrode 114 may be, for example, titanium, titanium nitride, tantalum nitride, tungsten, titanium tungsten, aluminum, copper, or a combination thereof. The formation method of the lower electrode 114 is, for example, a physical vapor deposition method or a chemical vapor deposition method. Thereafter, a dielectric layer 116 is formed between the lower electrodes 114. Dielectric layer 116 The forming method may be, for example, forming a dielectric material layer on the substrate 100 to cover the top surface and the sidewall of the lower electrode 114 and the top surface (not shown) of the dielectric layer 110. Thereafter, a chemical mechanical polishing (CMP) process is performed to expose the top surface of the lower electrode 114. In an embodiment, the material of the dielectric material layer may be, for example, ruthenium oxide, tantalum nitride, borophosphonium glass or a combination thereof, and the formation method thereof may be, for example, a chemical vapor deposition method. In other embodiments, the forming step of the lower electrode 114 may also be, for example, first depositing a layer of dielectric material over the contact plug 112 and then patterning the layer of dielectric material to define the location of the subsequently formed lower electrode 114. Thereafter, a layer of the lower electrode material is filled between the dielectric layers 116. Then, a chemical mechanical polishing (CMP) process is performed to planarize and expose the top surface of the lower electrode 114. In an embodiment, the material of the lower electrode material layer may be, for example, titanium, titanium nitride, tantalum nitride, tungsten, titanium tungsten, aluminum, copper, or a combination thereof.
請參照圖1B,於下電極114上形成電容介電層118。電容介電層118覆蓋下電極114以及介電層116的頂面。在一實施例中,介電層116與下電極114可例如是共平面,其可使得位於其上的電容介電層118的表面S1亦為一平面。由於電容介電層118為連續平面結構且後續形成的上電極120亦為連續平面結構(如圖1C所示),其可增加後續沈積製程與微影製程裕度(window),以及避免單一記憶胞(unit cell)於蝕刻圖案化時發生側壁損傷並影響其可靠度,進而提升製程良率。在一實施例中,電容介電層118的材料可例如是可變電阻材料。可變電阻材料可例如是氧化矽或是過渡金屬氧化物。所述過渡金屬氧化物可例如是ZrO2、HfO2、Ta2O5、Al2O3、TiO2或其組合。但本發明並不限於此,在其他實施 例中,電容介電層118的材料可例如是高介電常數材料層,其材料例如是下述元素的氧化物,如:鉿、鋯、鋁、鈦、鑭、釔、釓或鉭,又或是氮化鋁,或是上述任意組合。 Referring to FIG. 1B, a capacitor dielectric layer 118 is formed on the lower electrode 114. Capacitive dielectric layer 118 covers lower electrode 114 and the top surface of dielectric layer 116. In an embodiment, the dielectric layer 116 and the lower electrode 114 may be, for example, coplanar, such that the surface S1 of the capacitive dielectric layer 118 located thereon is also a plane. Since the capacitor dielectric layer 118 has a continuous planar structure and the subsequently formed upper electrode 120 is also a continuous planar structure (as shown in FIG. 1C), it can increase the subsequent deposition process and the lithography process window, and avoid single memory. When the unit cell is etched and patterned, sidewall damage occurs and its reliability is affected, thereby improving the process yield. In an embodiment, the material of the capacitor dielectric layer 118 can be, for example, a variable resistance material. The variable resistance material may be, for example, ruthenium oxide or a transition metal oxide. The transition metal oxide may be, for example, ZrO 2 , HfO 2 , Ta 2 O 5 , Al 2 O 3 , TiO 2 or a combination thereof. However, the present invention is not limited thereto. In other embodiments, the material of the capacitor dielectric layer 118 may be, for example, a high dielectric constant material layer, such as an oxide of the following elements, such as germanium, zirconium, aluminum, Titanium, tantalum, niobium, tantalum or niobium, or aluminum nitride, or any combination of the above.
請參照圖1C,於電容介電層118上形成上電極120。上電極120具有第一部分120a以及第二部分120b。第一部分120a覆蓋電容介電層118。第二部分120b延伸至第二區R2的基底100上。因此,本實施例之上電極120可藉由金屬內連線205電性連接至保護元件202,以避免後段沈積製程與乾式蝕刻製程所導致電漿損害,進而提升產品的可靠度與良率。在一實施例中,上電極120的材料可例如是鈦、氮化鈦、氮化鉭、鎢、鈦鎢、鋁、銅或其組合。上電極120的形成方法例如是物理氣相沈積法或化學氣相沈積法。 Referring to FIG. 1C, an upper electrode 120 is formed on the capacitor dielectric layer 118. The upper electrode 120 has a first portion 120a and a second portion 120b. The first portion 120a covers the capacitive dielectric layer 118. The second portion 120b extends onto the substrate 100 of the second region R2. Therefore, the upper electrode 120 of the embodiment can be electrically connected to the protection component 202 through the metal interconnection 205 to avoid plasma damage caused by the subsequent deposition process and the dry etching process, thereby improving product reliability and yield. In an embodiment, the material of the upper electrode 120 may be, for example, titanium, titanium nitride, tantalum nitride, tungsten, titanium tungsten, aluminum, copper, or a combination thereof. The formation method of the upper electrode 120 is, for example, a physical vapor deposition method or a chemical vapor deposition method.
此外,在形成電容器130之後,本實施例還可以圖案化上電極120,以形成多個條狀上電極(未繪示)。所述條狀上電極可與後續形成的位元線平行,藉此降低所述位元線的負載(loading),以更進一步提升產品的可靠度與良率。 In addition, after forming the capacitor 130, the embodiment may further pattern the upper electrode 120 to form a plurality of strip-shaped upper electrodes (not shown). The strip-shaped upper electrode may be parallel to the subsequently formed bit line, thereby reducing the loading of the bit line to further improve product reliability and yield.
請參照圖1C,本發明提供一種記憶元件10,包括基底100、介電層116、電容器130、保護元件202、金屬內連線105以及金屬內連線205。基底100具有第一區R1與第二區R2。電容器130位於第一區R1的基底100上。電容器130包括多個下電極114、上電極120以及電容介電層118。介電層116位於下電極114之間。上電極120具有第一部分120a以及第二部分120b。第一部 分120a覆蓋下電極114與介電層116的頂面,而第二部分120b延伸至第二區R2的基底100上。電容介電層118位於下電極114與上電極120的第一部分120a之間。保護元件202位於第二區R2的基底100中。金屬內連線105位於電容器130與基底100之間。金屬內連線105可將下電極114電性連接至基底100。金屬內連線205位於上電極120的第二部分120b與保護元件202之間。金屬內連線205可將上電極120的第二部分120b電性連接至保護元件202,以避免後段沈積製程與乾式蝕刻製程所導致電漿損害,進而提升產品的可靠度與良率。在一實施例中,電容器130可例如是電阻式隨機存取記憶體(RRAM)、動態隨機存取記憶體(DRAM)或其組合,本發明不以此為限。 Referring to FIG. 1C, the present invention provides a memory device 10 including a substrate 100, a dielectric layer 116, a capacitor 130, a protection element 202, a metal interconnect 105, and a metal interconnect 205. The substrate 100 has a first region R1 and a second region R2. The capacitor 130 is located on the substrate 100 of the first region R1. The capacitor 130 includes a plurality of lower electrodes 114, an upper electrode 120, and a capacitor dielectric layer 118. Dielectric layer 116 is located between lower electrodes 114. The upper electrode 120 has a first portion 120a and a second portion 120b. First The minute 120a covers the top surface of the lower electrode 114 and the dielectric layer 116, while the second portion 120b extends to the substrate 100 of the second region R2. Capacitive dielectric layer 118 is between lower electrode 114 and first portion 120a of upper electrode 120. The protective element 202 is located in the substrate 100 of the second zone R2. Metal interconnect 105 is located between capacitor 130 and substrate 100. The metal interconnect 105 can electrically connect the lower electrode 114 to the substrate 100. Metal interconnect 205 is between second portion 120b of upper electrode 120 and protective element 202. The metal interconnect 205 can electrically connect the second portion 120b of the upper electrode 120 to the protection element 202 to avoid plasma damage caused by the subsequent deposition process and the dry etching process, thereby improving product reliability and yield. In one embodiment, the capacitor 130 can be, for example, a resistive random access memory (RRAM), a dynamic random access memory (DRAM), or a combination thereof, and the invention is not limited thereto.
以下的實施例中,相同或相似的元件、構件、層以相似的元件符號來表示。舉例來說,圖1C之電容器130與圖2C之電容器230以及圖3C之電容器330為相同或相似的構件。上述相同或相似的構件的材料與形成方法於此不再逐一贅述。 In the following embodiments, the same or similar elements, members, and layers are denoted by like reference numerals. For example, capacitor 130 of FIG. 1C is the same or similar component as capacitor 230 of FIG. 2C and capacitor 330 of FIG. 3C. The materials and forming methods of the same or similar members described above will not be described one by one.
圖2A至圖2C為本發明第二實施例之記憶元件的製造流程的剖面示意圖。 2A to 2C are schematic cross-sectional views showing a manufacturing process of a memory element according to a second embodiment of the present invention.
請同時參照圖1A與圖2A,圖1A與圖2A基本上相似,兩者不同之處在於:圖2A僅在第一區R1的介電層110上形成多個下電極214,而不具有配置在下電極114之間的介電層116。 Referring to FIG. 1A and FIG. 2A simultaneously, FIG. 1A is substantially similar to FIG. 2A, and the difference is that FIG. 2A forms only a plurality of lower electrodes 214 on the dielectric layer 110 of the first region R1 without configuration. A dielectric layer 116 between the lower electrodes 114.
請參照圖2B,於下電極214上共形地形成電容介電層218。電容介電層218覆蓋下電極214的頂面與側壁以及介電層110 的頂面。由於電容介電層218共形地覆蓋下電極214的頂面與側壁以及介電層110的頂面,因此,電容介電層218可例如是連續凹凸結構。 Referring to FIG. 2B, a capacitor dielectric layer 218 is conformally formed on the lower electrode 214. The capacitor dielectric layer 218 covers the top and sidewalls of the lower electrode 214 and the dielectric layer 110 The top surface. Since the capacitive dielectric layer 218 conformally covers the top surface and sidewalls of the lower electrode 214 and the top surface of the dielectric layer 110, the capacitive dielectric layer 218 can be, for example, a continuous relief structure.
之後,請參照圖2C,於電容介電層218上形成上電極220。上電極220具有第一部分220a以及第二部分220b。第一部分220a覆蓋第一區R1的電容介電層218。電容介電層218配置於第一部分220a與下電極214之間。第二部分220b延伸至第二區R2的基底100上,且藉由金屬內連線205電性連接至保護元件202。 Thereafter, referring to FIG. 2C, the upper electrode 220 is formed on the capacitor dielectric layer 218. The upper electrode 220 has a first portion 220a and a second portion 220b. The first portion 220a covers the capacitive dielectric layer 218 of the first region R1. The capacitor dielectric layer 218 is disposed between the first portion 220a and the lower electrode 214. The second portion 220b extends to the substrate 100 of the second region R2 and is electrically connected to the protective member 202 by a metal interconnect 205.
請參照圖2C,本發明之第二實施例的記憶元件20與本發明之第一實施例的記憶元件10基本上相似,兩者不同之處在於:記憶元件20的電容介電層218可例如是連續凹凸結構。因此,配置於電容介電層218上方的上電極220亦可例如是連續凹凸結構。在一實施例中,對應於相鄰下電極214之間的上電極220的表面具有凹陷D1。 Referring to FIG. 2C, the memory element 20 of the second embodiment of the present invention is substantially similar to the memory element 10 of the first embodiment of the present invention, except that the capacitive dielectric layer 218 of the memory element 20 can be, for example, It is a continuous concave-convex structure. Therefore, the upper electrode 220 disposed above the capacitor dielectric layer 218 may also be, for example, a continuous relief structure. In an embodiment, the surface corresponding to the upper electrode 220 between adjacent lower electrodes 214 has a recess D1.
圖3A至圖3C為本發明第三實施例之記憶元件的製造流程的剖面示意圖。 3A to 3C are schematic cross-sectional views showing a manufacturing process of a memory element according to a third embodiment of the present invention.
請同時參照圖1A與圖3A,圖1A與圖3A基本上相似,兩者不同之處在於:圖3A的第一區R1的介電層110上依序形成多個下電極314、多個電容介電層318以及多個犧牲層322。圖3A的電容介電層318可視為非連續平面結構,其覆蓋下電極314的頂面。在一實施例中,犧牲層322的材料可例如是氧化物、氮化 物或其組合。犧牲層322的形成方法可例如是化學氣相沈積法。 Referring to FIG. 1A and FIG. 3A simultaneously, FIG. 1A is substantially similar to FIG. 3A, and the difference is that a plurality of lower electrodes 314 and a plurality of capacitors are sequentially formed on the dielectric layer 110 of the first region R1 of FIG. 3A. A dielectric layer 318 and a plurality of sacrificial layers 322. The capacitive dielectric layer 318 of FIG. 3A can be viewed as a discontinuous planar structure that covers the top surface of the lower electrode 314. In an embodiment, the material of the sacrificial layer 322 may be, for example, an oxide or a nitride. Or a combination thereof. The formation method of the sacrificial layer 322 may be, for example, a chemical vapor deposition method.
請參照圖3B,於下電極314、電容介電層318以及犧牲層322的側壁上形成間隙壁324。詳細地說,間隙壁324的形成方法如下。於犧牲層322上共形地形成間隙壁材料層,間隙壁材料層覆蓋下電極314、電容介電層318的側壁、犧牲層322的頂面與側壁以及介電層110的頂面(未繪示)。進行蝕刻製程,移除部分間隙壁材料層,以暴露犧牲層322的頂面以及介電層110的頂面。在一實施例中,間隙壁材料層的材料可例如是氮化物、氧化鋁或其組合。 Referring to FIG. 3B, a spacer 324 is formed on the sidewalls of the lower electrode 314, the capacitor dielectric layer 318, and the sacrificial layer 322. In detail, the method of forming the spacer 324 is as follows. A spacer material layer is formed conformally on the sacrificial layer 322, the spacer material layer covering the lower electrode 314, the sidewall of the capacitor dielectric layer 318, the top surface and the sidewall of the sacrificial layer 322, and the top surface of the dielectric layer 110 (not drawn Show). An etching process is performed to remove a portion of the spacer material layer to expose the top surface of the sacrificial layer 322 and the top surface of the dielectric layer 110. In an embodiment, the material of the spacer material layer may be, for example, nitride, aluminum oxide, or a combination thereof.
請參照圖3C,移除犧牲層322之後,於電容介電層318上形成上電極320。上電極320具有第一部分320a以及第二部分320b。第一部分320a覆蓋第一區R1的電容介電層318的頂面以及間隙壁324的頂面與側壁。第二部分320b延伸至第二區R2的基底100上,且藉由金屬內連線205電性連接至保護元件202。 Referring to FIG. 3C, after the sacrificial layer 322 is removed, the upper electrode 320 is formed on the capacitor dielectric layer 318. The upper electrode 320 has a first portion 320a and a second portion 320b. The first portion 320a covers the top surface of the capacitive dielectric layer 318 of the first region R1 and the top and sidewalls of the spacer 324. The second portion 320b extends to the substrate 100 of the second region R2 and is electrically connected to the protective member 202 by a metal interconnect 205.
請參照圖3C,本發明之第三實施例的記憶元件30與本發明之第一實施例的記憶元件10基本上相似,兩者不同之處在於:記憶元件30的電容介電層318可例如是非連續平面結構,其覆蓋下電極314的頂面。因此,配置於電容介電層318上的上電極320則可視為連續凹凸結構。在一實施例中,對應於相鄰下電極314之間的上電極320的表面具有凹陷D2。 Referring to FIG. 3C, the memory element 30 of the third embodiment of the present invention is substantially similar to the memory element 10 of the first embodiment of the present invention, except that the capacitive dielectric layer 318 of the memory element 30 can be, for example, It is a discontinuous planar structure that covers the top surface of the lower electrode 314. Therefore, the upper electrode 320 disposed on the capacitor dielectric layer 318 can be regarded as a continuous uneven structure. In an embodiment, the surface corresponding to the upper electrode 320 between adjacent lower electrodes 314 has a recess D2.
綜上所述,本發明將上電極電性連接至保護元件,其可避免後段沈積製程與乾式蝕刻製程所導致電漿損害,進而提升產 品的可靠度與良率。此外,由於本發明之第一實施例的電容介電層為連續平面結構且後續形成的上電極亦為連續平面結構,其可增加後續沈積製程與微影製程裕度,以更進一步地提升製程良率。 In summary, the present invention electrically connects the upper electrode to the protection element, which can avoid plasma damage caused by the post-deposition process and the dry etching process, thereby improving production. Product reliability and yield. In addition, since the capacitor dielectric layer of the first embodiment of the present invention has a continuous planar structure and the subsequently formed upper electrode is also a continuous planar structure, it can increase the subsequent deposition process and the lithography process margin to further improve the process. Yield.
雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。 Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention, and any one of ordinary skill in the art can make some changes and refinements without departing from the spirit and scope of the present invention. The scope of the invention is defined by the scope of the appended claims.
10‧‧‧記憶元件 10‧‧‧ memory components
100‧‧‧基底 100‧‧‧Base
104、110、116‧‧‧介電層 104, 110, 116‧‧‧ dielectric layer
106、107、112、206、212‧‧‧接觸插塞 106, 107, 112, 206, 212‧‧‧ contact plugs
108、109、208‧‧‧圖案化導體層 108, 109, 208‧‧‧ patterned conductor layers
105、205‧‧‧金屬內連線 105, 205‧‧‧Metal interconnection
114‧‧‧下電極 114‧‧‧ lower electrode
118‧‧‧電容介電層 118‧‧‧Capacitive dielectric layer
120‧‧‧上電極 120‧‧‧Upper electrode
120a‧‧‧第一部分 120a‧‧‧Part 1
120b‧‧‧第二部分 120b‧‧‧Part II
130‧‧‧電容器 130‧‧‧ capacitor
202‧‧‧保護元件 202‧‧‧Protection components
R1‧‧‧第一區 R1‧‧‧ first district
R2‧‧‧第二區 R2‧‧‧Second District
S1‧‧‧表面 S1‧‧‧ surface
Claims (12)
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