TWI568054B - Organic light - emitting diodes and their packaging methods - Google Patents
Organic light - emitting diodes and their packaging methods Download PDFInfo
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Description
本發明是有關於一種有機發光二極體及其封裝方法,特別是指一種有助於提升產品使用壽命,及封裝良率的有機發光二極體,以及該有機發光二極體的封裝方法。 The invention relates to an organic light emitting diode and a packaging method thereof, in particular to an organic light emitting diode which contributes to improving the service life of the product and the package yield, and a packaging method of the organic light emitting diode.
相較於液晶顯示器(Liquid Crystal Display,簡稱LCD)技術而言,採用有機發光二極體(Organic Light-Emitting Diode,簡稱OLED)顯示器技術具有許多優勢,例如:輕薄(厚度可低於1mm)、廣視角(可達170度)、毋須背光源、應用溫度範圍大(-40℃~70℃)、微秒級的反應時間(Response Time)以及應用於可撓式和穿透式領域的優勢。然而,有機發光二極體中的有機發光層材料或是高活性陰極金屬,因為對水氣及氧氣分別存有高敏感反應的特性,使得有機發光二極體在成為產品之前皆須加以封裝,以便提升產品的穩定度並延長其使用壽命。 Compared with liquid crystal display (LCD) technology, the use of Organic Light-Emitting Diode (OLED) display technology has many advantages, such as: light and thin (less than 1mm thickness), Wide viewing angle (up to 170 degrees), no need for backlight, high application temperature range (-40°C~70°C), microsecond response time (Response Time) and advantages in flexible and transmissive fields. However, the organic light-emitting layer material in the organic light-emitting diode or the high-activity cathode metal has a high sensitivity reaction to moisture and oxygen, so that the organic light-emitting diode must be packaged before it becomes a product. In order to improve the stability of the product and extend its service life.
現有的封裝方法大致有: The existing packaging methods are roughly as follows:
一、應用於硬式基板的氣密封裝,如(a)Glue & Getter封裝製程,主要是利用一玻璃或是金屬所製的蓋板,在其內表面設 置吸氣劑(Getter),並結合於一已形成有機發光單元且周邊塗設有感光膠(Glue)的基板後,再照射紫外光使該感光膠固化而完成封裝作業,其中,所述有機發光單元包括一陽極、一有機發光層及一陰極;及(b)Frit glass封裝製程,是利用雷射光束將待燒結玻料(Frit glass)熔融於玻璃所製的該蓋板與該基板之間,此封裝技術需注意的是待燒結玻料的熱膨脹係數(Coefficient of Thermal Expansion,簡稱CTE)需接近該基板與該蓋板,藉此才能避免熱膨脹係數過大而導致封裝時的對位偏差。 1. Hermetic packaging for hard substrates, such as (a) Glue & Getter packaging process, mainly using a glass or metal cover, on its inner surface And a getter is combined with a substrate on which an organic light-emitting unit is formed and coated with a photoresist (Glue), and then irradiated with ultraviolet light to cure the photoresist to complete a packaging operation, wherein the organic The light emitting unit includes an anode, an organic light emitting layer and a cathode; and (b) a Frit glass packaging process for melting the glass to be sintered (Frit glass) onto the glass and the substrate by using a laser beam In this packaging technology, it should be noted that the coefficient of thermal expansion (CTE) of the glass to be sintered needs to be close to the substrate and the cover plate, so as to avoid excessive deviation of the thermal expansion coefficient and cause alignment deviation during packaging.
二、能應用於可撓式基板的氣密封裝,如(a)薄膜封裝製程,主要是在已形成有機發光單元的可撓式基板上,繼續沉積多層無機薄膜與有機薄膜以阻絕外界的水氣與氧氣,是一種因應產品薄型化趨勢而發展出的一種封裝製程,惟其缺點是薄膜沉積過程不但耗時,且所需使用的製膜設備也較昂貴;及(b)壓敏膠封裝製程,主要是在已形成有機發光單元的可撓式基板上,直接貼上一層不透氣的壓敏膠帶(Pressure Sensitive Adhesive Tape,簡稱PSA tape)後,便可將該蓋板結合於該基板上,是一種特別適合應用於大尺寸平面顯示器的封裝技術,不僅封裝速度快而有助於量產之外,也能有效降低封裝成本。 Second, it can be applied to the hermetic packaging of flexible substrates, such as (a) thin film packaging process, mainly on the flexible substrate on which the organic light-emitting unit has been formed, and continue to deposit multiple layers of inorganic film and organic film to block the outside water Gas and oxygen are a kind of packaging process developed in response to the trend of thinning products, but the disadvantage is that the film deposition process is not only time consuming, but also the film forming equipment required is expensive; and (b) pressure sensitive adhesive packaging process The cover plate can be bonded to the substrate by directly attaching a layer of pressure sensitive adhesive tape (PSA tape) to the flexible substrate on which the organic light-emitting unit has been formed. It is a packaging technology that is especially suitable for large-scale flat-panel displays. It not only has a fast packaging speed, but also facilitates mass production, and can also effectively reduce packaging costs.
然而,壓敏膠帶封裝製程技術因為是直接將壓敏膠帶貼附於有機發光單元的頂面,因此,壓敏膠帶內的黏膠基材實質上 會直接傷害有機發光單元而導致其載子遷移率(Mobility)降低,除此之外,因為有機發光單元與基板間的附著力不佳,因此,當壓敏膠帶直接接觸於有機發光單元時,有機發光單元便會因壓敏膠帶本身黏著拉力(Adhensive Tension)的作用而產生非必要缺陷(Defect),且在較強黏著拉力的作用下,也會使有機發光單元脫附於基板而產生剝離,從而存有不利於提升產品良率的缺憾。 However, the pressure-sensitive adhesive tape packaging process technology directly attaches the pressure-sensitive adhesive tape to the top surface of the organic light-emitting unit, and therefore, the adhesive substrate in the pressure-sensitive adhesive tape is substantially The organic light-emitting unit is directly damaged, resulting in a decrease in carrier mobility (Mobility). In addition, since the adhesion between the organic light-emitting unit and the substrate is poor, when the pressure-sensitive adhesive tape is in direct contact with the organic light-emitting unit, The organic light-emitting unit will produce a non-defective defect due to the action of the pressure-sensitive adhesive tape itself, and the organic light-emitting unit will be desorbed from the substrate to cause peeling under the action of strong adhesive force. Therefore, there are shortcomings that are not conducive to improving product yield.
另外,壓敏膠帶不僅無法吸收來自於外界的氣體之外,也可能因黏膠基材中存有易脫氣(Out-gassing)成分的材料,使得由該基板與該蓋板所界定出的封裝空間內的水氣及氧氣過多,進一步影響有機發光單元的穩定度並導致其使用壽命縮短。 In addition, the pressure-sensitive adhesive tape not only cannot absorb the gas from the outside, but may also be defined by the substrate and the cover plate due to the presence of an material having an out-gassing component in the adhesive substrate. Excessive moisture and oxygen in the package space further affect the stability of the organic light-emitting unit and lead to a shortened service life.
因此,本發明之目的,即在提供一種能提升產品良率、有助於量產,且能保持良好阻氣效果並能吸收封裝空間中的水氣及氧氣,藉此提升產品使用壽命的有機發光二極體。 Therefore, the object of the present invention is to provide an organic product which can improve product yield, contribute to mass production, and maintain good gas barrier effect and absorb moisture and oxygen in the package space, thereby improving product service life. Light-emitting diode.
本發明之另一目的,即在提供一種有機發光二極體之封裝方法。 Another object of the present invention is to provide a method of packaging an organic light emitting diode.
本發明之另一目的,即在提供另一種有機發光二極體之封裝方法。 Another object of the present invention is to provide a packaging method for another organic light emitting diode.
於是,本發明有機發光二極體,包含一基板及一相對應該基板的蓋板、一有機發光單元、一壓敏膠,及一間隔吸濕單元。 Therefore, the organic light emitting diode of the present invention comprises a substrate and a cover plate corresponding to the substrate, an organic light emitting unit, a pressure sensitive adhesive, and a spacer moisture absorbing unit.
該基板與該蓋板彼此相配合界定出一封裝空間,該基板包括一上表面,該蓋板包括一下表面。 The substrate and the cover plate cooperate with each other to define a package space, and the substrate includes an upper surface, and the cover plate includes a lower surface.
該有機發光單元設置於該基板的上表面。 The organic light emitting unit is disposed on an upper surface of the substrate.
該壓敏膠設置於該蓋板的下表面,用以將該蓋板穩固地黏著於該基板。 The pressure sensitive adhesive is disposed on a lower surface of the cover plate for firmly adhering the cover to the substrate.
該間隔吸濕單元設置於該壓敏膠與該有機發光單元之間,用以將該有機發光單元與該壓敏膠隔開,並維持該封裝空間之乾燥,當該壓敏膠本身的黏著拉力使該間隔吸濕單元脫附於該有機發光單元時,無法連動使該有機發光單元脫附於該基板的上表面。 The interval moisture absorbing unit is disposed between the pressure sensitive adhesive and the organic light emitting unit to separate the organic light emitting unit from the pressure sensitive adhesive, and maintain the drying of the packaging space, when the pressure sensitive adhesive itself adheres When the pulling force desorbs the interval absorbing unit to the organic light emitting unit, the organic light emitting unit cannot be decoupled from the upper surface of the substrate.
本發明有機發光二極體之功效,在於利用該間隔吸濕單元來避免該壓敏膠的黏著拉力直接作用於該有機發光單元,藉此提升產品良率,另外,該間隔吸濕單元還兼具用以乾燥該封裝空間之作用,使得對水氣與氧氣較具高敏感反應的該有機發光單元,能因較乾燥的該封裝空間而增加使用壽命。 The effect of the organic light-emitting diode of the present invention is that the spacer moisture absorbing unit is used to prevent the adhesive force of the pressure sensitive adhesive from directly acting on the organic light-emitting unit, thereby improving the product yield, and the interval moisture absorbing unit is also The organic light-emitting unit has a function of drying the package space, so that the water-vapor and the oxygen-sensitive reaction can increase the service life due to the dry package space.
本發明有機發光二極體的封裝方法是用來製造如上述所述的有機發光二極體,並且包含下列步驟:(A)備料作業:準備一具有一有機發光單元的基板、一包括一下表面的蓋板、一間隔吸濕單元,及一設置於該蓋板下表面的壓敏膠,該壓敏膠包括一底面。(B)前置作業:將該間隔吸濕單元設置於該壓敏膠的底面。(C)壓合作業:利用該壓敏膠的黏性將該蓋板穩固地結合於該基板,其 中,當該壓敏膠本身的黏著拉力使該間隔吸濕單元脫附於該有機發光單元時,無法連動使該有機發光單元脫附於該基板的上表面。 The encapsulation method of the organic light-emitting diode of the present invention is used to manufacture the organic light-emitting diode as described above, and comprises the following steps: (A) preparation operation: preparing a substrate having an organic light-emitting unit, including a lower surface a cover plate, a spacer moisture absorbing unit, and a pressure sensitive adhesive disposed on a lower surface of the cover plate, the pressure sensitive adhesive comprising a bottom surface. (B) Pre-operation: The interval moisture absorbing unit is placed on the bottom surface of the pressure-sensitive adhesive. (C) Pressure bonding industry: the cover plate is firmly bonded to the substrate by the adhesiveness of the pressure sensitive adhesive, When the adhesive tension of the pressure sensitive adhesive itself causes the interval moisture absorbing unit to be desorbed to the organic light emitting unit, the organic light emitting unit cannot be decoupled from the upper surface of the substrate.
本發明有機發光二極體的封裝方法之功效,在於本發明不僅製程步驟少、簡單且省時而有助於量產之外,本發明利用該間隔吸濕單元將該有機發光單元與該壓敏膠彼此隔開的設計,也能有助於提升封裝良率。 The method of the method for encapsulating the organic light-emitting diode of the present invention is that the invention not only has a small number of process steps, is simple and time-saving, but also facilitates mass production. The present invention utilizes the interval moisture absorbing unit to press the organic light-emitting unit with the pressure. The design of the sensitive gels separated from each other can also help to improve the package yield.
本發明另一種有機發光二極體的封裝方法是用來製造如上述所述的有機發光二極體,並且包含下列步驟:(A)備料作業:準備一具有一有機發光單元的基板、一包括一下表面的蓋板、一間隔吸濕單元,及一設置於該蓋板下表面的壓敏膠,該有機發光單元包括一頂面。(B)前置作業:將該間隔吸濕單元置放於該有機發光單元的頂面。(C)壓合作業:利用該壓敏膠的黏性將該蓋板穩固地結合於該基板,其中,當該壓敏膠本身的黏著拉力使該間隔吸濕單元脫附於該有機發光單元時,無法連動使該有機發光單元脫附於該基板的上表面。 Another method for packaging an organic light-emitting diode according to the present invention is for manufacturing the organic light-emitting diode as described above, and comprises the following steps: (A) preparing a material: preparing a substrate having an organic light-emitting unit, including a surface cover, a spacer moisture absorbing unit, and a pressure sensitive adhesive disposed on the lower surface of the cover, the organic light emitting unit including a top surface. (B) Pre-operation: The interval moisture absorbing unit is placed on the top surface of the organic light-emitting unit. (C) pressure bonding industry: the cover plate is firmly bonded to the substrate by the adhesiveness of the pressure sensitive adhesive, wherein the adhesive absorption force of the pressure sensitive adhesive itself causes the interval moisture absorbing unit to be desorbed to the organic light emitting unit At this time, the organic light emitting unit cannot be decoupled from the upper surface of the substrate.
本發明另一種有機發光二極體的封裝方法之功效,同樣也能達成提升封裝良率,以及因為製程步驟簡單而有助於量產的目的。 The efficacy of the encapsulation method of another organic light-emitting diode of the present invention can also achieve the purpose of improving the package yield and facilitating mass production because of the simple process steps.
1‧‧‧基板 1‧‧‧Substrate
10‧‧‧封裝空間 10‧‧‧Package space
11‧‧‧上表面 11‧‧‧ upper surface
2‧‧‧蓋板 2‧‧‧ Cover
21‧‧‧下表面 21‧‧‧ Lower surface
3‧‧‧有機發光單元 3‧‧‧Organic lighting unit
3’‧‧‧有機發光單元 3'‧‧‧Organic lighting unit
31‧‧‧頂面 31‧‧‧ top surface
32‧‧‧陽極 32‧‧‧Anode
33‧‧‧有機發光層 33‧‧‧Organic light-emitting layer
34‧‧‧陰極 34‧‧‧ cathode
4‧‧‧壓敏膠 4‧‧‧ Pressure sensitive adhesive
41‧‧‧底面 41‧‧‧ bottom
5‧‧‧間隔吸濕單元 5‧‧‧Interval moisture absorption unit
100‧‧‧備料作業 100‧‧‧Stocking operations
100’‧‧‧備料作業 100’‧‧‧Stocking operations
200‧‧‧前置作業 200‧‧‧Pre-installation
200’‧‧‧前置作業 200’‧‧‧Pre-installation
300‧‧‧壓合作業 300‧‧‧Compression cooperation
300’‧‧‧壓合作業 300’‧‧‧Compound cooperation
本發明之其他的特徵及功效,將於參照圖式的實施方 式中清楚地呈現,其中:圖1是一俯視示意圖,說明本發明有機發光二極體的一實施例;圖2是一剖面示意圖,說明沿圖1的II-II割面線方向;圖3是一俯視示意圖,說明一種採用複數本發明有機發光二極體來顯示影像的平面顯示器;圖4是一剖面示意圖,說明沿圖3的IV-IV割面線方向;圖5是一示意圖,說明本發明該實施例的一間隔吸濕單元呈片狀;圖6是一示意圖,說明本發明該實施例的該間隔吸濕單元的一變化例,在該變化例中,該間隔吸濕單元呈漿狀;圖7是一示意圖,說明本發明該實施例的該間隔吸濕單元的另一變化例,在該另一變化例中,該間隔吸濕單元呈粉粒狀;圖8是本發明有機發光二極體的封裝方法的一第一實施例之流程圖;圖9是本發明有機發光二極體的封裝方法的該第一實施例之一備料作業示意圖;圖10是本發明有機發光二極體的封裝方法的該第一實施例之一前置作業示意圖;圖11是本發明有機發光二極體的封裝方法的該第一實施例之一壓合作業示意圖; 圖12是本發明有機發光二極體的封裝方法的一第二實施例之流程圖;圖13是本發明有機發光二極體的封裝方法的該第二實施例之一備料作業示意圖;圖14是本發明有機發光二極體的封裝方法的該第二實施例之一前置作業示意圖;及圖15是本發明有機發光二極體的封裝方法的該第二實施例之一壓合作業示意圖。 Other features and effects of the present invention will be directed to the implementation of the drawings. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a top plan view showing an embodiment of an organic light emitting diode of the present invention; FIG. 2 is a schematic cross-sectional view showing the direction along the line II-II of FIG. 1; It is a top view showing a flat display using a plurality of organic light emitting diodes of the present invention to display images; FIG. 4 is a schematic cross-sectional view showing the direction of the IV-IV cut line in FIG. 3; FIG. 5 is a schematic view illustrating An interval moisture absorbing unit of the embodiment of the present invention is in the form of a sheet; FIG. 6 is a schematic view showing a variation of the interval absorbing unit of the embodiment of the present invention, in which the interval absorbing unit is Fig. 7 is a schematic view showing another variation of the interval absorbing unit of the embodiment of the present invention, in which the interval absorbing unit is in the form of powder and granules; A flow chart of a first embodiment of a method for packaging an organic light-emitting diode; FIG. 9 is a schematic view showing a preparation operation of the first embodiment of the method for packaging an organic light-emitting diode of the present invention; FIG. Diode packaging method A schematic view of one embodiment of the pre-job first embodiment; FIG. 11 is a schematic view of one embodiment of a first embodiment of the pressure sector cooperation encapsulation method OLED of the present invention; 12 is a flow chart of a second embodiment of a method for packaging an organic light-emitting diode according to the present invention; FIG. 13 is a schematic view showing a preparation operation of the second embodiment of the method for packaging an organic light-emitting diode according to the present invention; A front view of the second embodiment of the method for packaging an organic light emitting diode of the present invention; and FIG. 15 is a schematic view of the second embodiment of the method for packaging the organic light emitting diode of the present invention. .
以下,針對本發明參照圖式進行說明,需注意的是,各圖式中所示厚度及長度等尺寸與實際物品不同。 Hereinafter, the present invention will be described with reference to the drawings, and it should be noted that dimensions such as thickness and length shown in the respective drawings are different from actual articles.
參閱圖1與圖2,本發明有機發光二極體的一實施例,包含一基板1及一相對應該基板1的蓋板2、一有機發光單元3、一壓敏膠4,及一間隔吸濕單元5。在此能理解的是,在該基板1上沉積複數個有機發光單元3、3'且以陣列形式展開,便可獲得一種用以顯示影像的平面顯示器,如圖3與圖4所示。 Referring to FIG. 1 and FIG. 2, an embodiment of the organic light emitting diode of the present invention comprises a substrate 1 and a cover plate 2 corresponding to the substrate 1, an organic light emitting unit 3, a pressure sensitive adhesive 4, and a spacer. Wet unit 5. It can be understood that a plurality of organic light-emitting units 3, 3' are deposited on the substrate 1 and deployed in an array to obtain a flat display for displaying images, as shown in FIGS. 3 and 4.
該基板1與該蓋板2均是用來保護及封裝該有機發光單元3,且彼此相配合界定出一封裝空間10。該基板1包括一上表面11,該基板1的材料能採用玻璃、陶瓷、金屬與塑膠材料中的其中一者,在本實施例中,該基板1採用具有阻氣功能之塑膠材料。 補充說明的是,所述塑膠材料能採用聚對苯二甲酸乙二酯(Polyethylene Terephthalate,簡稱PET)、聚醯亞胺(Polyimides,簡稱PI)或聚萘二甲酸乙二酯(Polyethylene Naphthalate,簡稱PEN)。另外,該基板1不論是透明狀或是不透明狀皆可。 The substrate 1 and the cover 2 are both used to protect and package the organic light emitting unit 3, and cooperate with each other to define a package space 10. The substrate 1 includes an upper surface 11. The material of the substrate 1 can be one of glass, ceramic, metal and plastic materials. In the embodiment, the substrate 1 is made of a plastic material having a gas barrier function. In addition, the plastic material can use polyethylene terephthalate (PET), polyimides (PI) or polyethylene naphthalate (Polyethylene Naphthalate). PEN). Further, the substrate 1 may be transparent or opaque.
該蓋板2包括一下表面21,該蓋板2的材料能採用玻璃、陶瓷、金屬與塑膠材料中的其中一者,在本實施例中,該蓋板2採用具有阻氣功能之塑膠材料。由於該基板1與該蓋板2兩者各自材料之選用,為此技術領域者具有通常知識者所熟悉且非本發明之技術重點,在此便不再詳細。 The cover plate 2 includes a lower surface 21, and the cover plate 2 can be made of one of glass, ceramic, metal and plastic materials. In the embodiment, the cover plate 2 is made of a plastic material having a gas barrier function. The selection of the respective materials of the substrate 1 and the cover plate 2 is well known to those skilled in the art and is not the technical focus of the present invention, and will not be described in detail herein.
該有機發光單元3設置於該基板1的該上表面11。該有機發光單元3包括一頂面31、一形成於該基板1的陽極32(Anode)、一形成於該陽極32上的有機發光層33(Light-emitting Layer),及一形成於該有機發光層33上的陰極34(Cathode)。較佳地,該有機發光單元3還能包括一介於該陽極32與該有機發光層33間的電洞傳輸層(圖未示),及一介於該有機發光層33與該陰極34間的電子傳輸層(圖未示),藉此提升該有機發光單元3的發光效率。 The organic light emitting unit 3 is disposed on the upper surface 11 of the substrate 1. The organic light emitting unit 3 includes a top surface 31, an anode 32 formed on the substrate 1, an organic light emitting layer 33 formed on the anode 32, and a light emitting layer formed on the anode 32. Cathode 34 on layer 33. Preferably, the organic light emitting unit 3 further includes a hole transport layer (not shown) interposed between the anode 32 and the organic light emitting layer 33, and an electron between the organic light emitting layer 33 and the cathode 34. A transport layer (not shown) is used, thereby increasing the luminous efficiency of the organic light-emitting unit 3.
該陽極32材料並無特別限定,通常為高功函數(Work Function)的金屬氧化物,如氧化銦錫(Indium Tin Oxide)、氧化鋅錫(Znic Tin Oxide)、氧化銦鋅(Indium Znic Oxide)等透明導 電氧化物(Transparent Conductive Oxides,簡稱TCOs)。該陰極34材料並無特別限定,通常為低功函數的鎂(Mg)、鎂銀合金(Mg-Ag)、鋰(Li),及鈣(Ca)等材料。由於,該有機發光單元3的組成結構及材料之選用非本發明之技術重點,在此便不再贅述。 The material of the anode 32 is not particularly limited, and is usually a metal oxide of a high work function such as Indium Tin Oxide, Znic Tin Oxide, and Indium Znic Oxide. Transparent guide Transparent Conductive Oxides (TCOs). The material of the cathode 34 is not particularly limited, and is usually a material having a low work function of magnesium (Mg), magnesium silver alloy (Mg-Ag), lithium (Li), and calcium (Ca). Since the composition and structure of the organic light-emitting unit 3 are not the technical focus of the present invention, they will not be described herein.
該壓敏膠4設置於該蓋板2的下表面21,包括一底面41並用以將該蓋板2穩固地黏著於該基板1。補充說明的是,該壓敏膠4除了會黏著於該基板1的上表面11之外,實質上也會黏觸於已圖案化的陽極32走線,如圖2所示。 The pressure sensitive adhesive 4 is disposed on the lower surface 21 of the cover 2, and includes a bottom surface 41 for firmly adhering the cover 2 to the substrate 1. It should be noted that, in addition to being adhered to the upper surface 11 of the substrate 1, the pressure sensitive adhesive 4 substantially adheres to the patterned anode 32 trace, as shown in FIG.
該間隔吸濕單元5設置於該壓敏膠4與該有機發光單元3之間,更具體的說,該間隔吸濕單元5是設置於該壓敏膠4的底面41,用以將該有機發光單元3與該壓敏膠4隔開,並維持該封裝空間10之乾燥。詳細說明的是,由於該間隔吸濕單元5間隔設置於該有機發光單元3與該壓敏膠4之間,使得該壓敏膠4本身的黏著拉力實質上僅能影響該間隔吸濕單元5脫附於該有機發光單元3,而無法進一步地連動該有機發光單元3脫附於該基板1的上表面11,也就是說,因為該壓敏膠4本身的黏著拉力無法直接影響該有機發光單元3,故能降低該有機發光單元3因該壓敏膠4本身的黏著拉力而產生缺陷的情形發生,以及避免該有機發光單元3與該基板1之間產生剝離。 The interval absorbing unit 5 is disposed between the pressure sensitive adhesive 4 and the organic light emitting unit 3, and more specifically, the spaced absorbing unit 5 is disposed on the bottom surface 41 of the pressure sensitive adhesive 4 for The light emitting unit 3 is spaced apart from the pressure sensitive adhesive 4 and maintains the drying of the package space 10. In detail, since the interval absorbing unit 5 is disposed between the illuminating unit 3 and the pressure sensitive adhesive 4, the adhesive tension of the pressure sensitive adhesive 4 itself can only affect the interval absorbing unit 5 substantially. Desorbed from the organic light-emitting unit 3, and the organic light-emitting unit 3 cannot be further decoupled from the upper surface 11 of the substrate 1, that is, because the adhesive force of the pressure-sensitive adhesive 4 itself cannot directly affect the organic light-emitting The unit 3 can reduce the occurrence of defects in the organic light-emitting unit 3 due to the adhesive force of the pressure-sensitive adhesive 4 itself, and avoid peeling between the organic light-emitting unit 3 and the substrate 1.
在本實施例中,該間隔吸濕單元5包括一具間隔吸濕 功能的主基材51,及一用以與該主基材51混合而形成片狀的次基材52,如圖5所示。該間隔吸濕單元5所含的具間隔吸濕功能的該主基材51能選自於鋯(Zr)、鈦(Ti)、鉿(Hf)、鈮(Nb)、鉭(Ta)、鉻(Cr)、鉬(Mo)、鐵(Fe)、釕(Ru)、鎳(Ni)以及鈷(Co)所組成之群組,較佳地,也能選自於氧化鈣(CaO)、氧化鋇(BaO)、碳酸鈣(CaCO3)、五氧化二磷(P2O5)、沸石(Zeolite)、矽膠(Silica Gel)以及氧化鋁(Alumina)所組成之群組,在本實施例中,該主基材51採用碳酸鈣。該間隔吸濕單元5的該次基材52為聚乙烯(Polyethylene,簡稱PE)、聚對苯二甲酸乙二酯、聚碳酸酯(Polycarbonate,簡稱PC),及聚丙烯(Polypropylene,簡稱PP)中之其中一者,在本實施例中,該次基材52為聚乙烯,另需說明的是,該次基材52也能採用其他適用於低溫加工成型之材料,故不需以所述塑料為限。 In the present embodiment, the spacer unit 5 includes a main substrate 51 having a function of absorbing moisture, and a sub-substrate 52 for mixing with the main substrate 51 to form a sheet, as shown in FIG. Show. The main substrate 51 having the function of absorbing moisture contained in the interval absorbing unit 5 can be selected from the group consisting of zirconium (Zr), titanium (Ti), hafnium (Hf), niobium (Nb), tantalum (Ta), and chromium. a group consisting of (Cr), molybdenum (Mo), iron (Fe), ruthenium (Ru), nickel (Ni), and cobalt (Co), preferably, also selected from calcium oxide (CaO), oxidation a group consisting of BaO, CaCO 3 , P 2 O 5 , Zeolite, Silica Gel, and Alumina, in this embodiment The main substrate 51 is made of calcium carbonate. The sub-substrate 52 of the inter-hygroscopic unit 5 is made of polyethylene (PE), polyethylene terephthalate, polycarbonate (Polycarbonate, PC for short), and polypropylene (PP). In one embodiment, in the embodiment, the sub-substrate 52 is made of polyethylene. In addition, the sub-substrate 52 can also adopt other materials suitable for low-temperature processing, so that it is not required to be described. Plastic is limited.
在本實施例中,該間隔吸濕單元5呈片狀,且製備方式是先將粉粒狀的該主基材51與錠狀的該次基材52彼此混合並加熱融化,接著再利用機器將其滾壓成約為20微米(μm)至100微米之間的厚度。補充說明的是,該間隔吸濕單元5的厚度一般實際應用約莫在10微米至1毫米(mm)之間,但不以此為限。另外,在俯視狀態下,該間隔吸濕單元5周緣鄰近於該有機發光單元3周緣,該間隔吸濕單元5周緣能位於該有機發光單元3周緣內,且兩者間 距不大於1毫米,如圖1所示;該間隔吸濕單元5周緣也能圍繞該有機發光單元3周緣,且兩者間距不大於2毫米;也能理解的是,該間隔吸濕單元5周緣也能實質上重疊於該有機發光單元3周緣。 In the present embodiment, the interval absorbing unit 5 is in the form of a sheet, and is prepared by mixing the main substrate 51 in the form of powder and the sub-substrate 52 in the form of a pellet, and heating and melting, and then using the machine. It is rolled to a thickness of between about 20 micrometers (μm) and 100 micrometers. It should be noted that the thickness of the interval absorbing unit 5 is generally between about 10 micrometers and 1 millimeter (mm), but not limited thereto. In addition, in a plan view, the peripheral edge of the interval moisture absorbing unit 5 is adjacent to the periphery of the organic light emitting unit 3, and the peripheral edge of the interval moisture absorbing unit 5 can be located in the periphery of the organic light emitting unit 3, and between the two The distance is not more than 1 mm, as shown in FIG. 1; the periphery of the interval moisture absorbing unit 5 can also surround the periphery of the organic light emitting unit 3, and the distance between the two is not more than 2 mm; it can also be understood that the interval moisture absorbing unit 5 The periphery can also substantially overlap the periphery of the organic light-emitting unit 3.
參閱圖6,該間隔吸濕單元5的一變化例。在此變化例中,該間隔吸濕單元5包括具間隔吸濕功能的該主基材51,及一用以與該主基材51混合而形成漿狀的次基材53。該次基材53為無水溶劑(Anhydrous Solvent),如此,便能獲得呈漿狀的該間隔吸濕單元5。 Referring to Figure 6, a variation of the intervening moisture absorbing unit 5 is shown. In this variation, the spacer unit 5 includes the main substrate 51 having a function of absorbing moisture, and a sub-substrate 53 for mixing with the main substrate 51 to form a slurry. The sub-substrate 53 is an anhydrous solvent (Anhydrous Solvent), and thus, the intervening moisture absorbing unit 5 in a slurry form can be obtained.
參閱圖7,該間隔吸濕單元5的另一變化例。在此變化例中,該間隔吸濕單元5的形態為粉粒狀,且製備方式是將粒徑較小的該主基材51與粒徑較大的該次基材52彼此均勻混合,以獲得具一定體積的該間隔吸濕單元5。值得說明的是,當該主基材51的粒徑具一定尺寸而能有效讓該壓敏膠4不直接接觸於該有機發光單元3時,呈粉粒狀的該間隔吸濕單元5也能僅由具有間隔吸濕功能的該主基材51所組成。 Referring to Fig. 7, another variation of the interval moisture absorbing unit 5 is shown. In this variation, the interval of the moisture absorbing unit 5 is in the form of powder and granules, and is prepared by uniformly mixing the main substrate 51 having a smaller particle diameter and the sub-substrate 52 having a larger particle diameter with each other. The spaced apart moisture absorbing unit 5 is obtained in a volume. It should be noted that when the particle diameter of the main substrate 51 is sized to effectively prevent the pressure sensitive adhesive 4 from directly contacting the organic light emitting unit 3, the spacer moisture absorbing unit 5 in the form of powder can also be used. It consists only of the main substrate 51 having a space-absorbing function.
參閱圖8為本發明有機發光二極體的封裝方法之一第一實施例的流程圖,本發明有機發光二極體的封裝方法之該第一實施例,包含下列步驟: 8 is a flowchart of a first embodiment of a method for packaging an organic light emitting diode according to the present invention. The first embodiment of the method for packaging an organic light emitting diode according to the present invention includes the following steps:
步驟一、如圖9所示,備料作業100:準備一具有一有機發光單元3的基板1、一包括一下表面21的蓋板2、一間隔吸濕 單元5,及一設置於該蓋板2的下表面21的壓敏膠4。該壓敏膠4包括一底面41。 Step 1, as shown in FIG. 9, the preparation operation 100: preparing a substrate 1 having an organic light-emitting unit 3, a cover plate 2 including a lower surface 21, and a spacer moisture absorption The unit 5, and a pressure sensitive adhesive 4 disposed on the lower surface 21 of the cover plate 2. The pressure sensitive adhesive 4 includes a bottom surface 41.
步驟二、如圖10所示,前置作業200:將該間隔吸濕單元5設置於該壓敏膠4的底面41。 Step 2: As shown in FIG. 10, the pre-work 200: the interval moisture absorbing unit 5 is disposed on the bottom surface 41 of the pressure sensitive adhesive 4.
步驟三、如圖11所示,壓合作業300:於低氧乾燥的環境下,利用該壓敏膠4的黏性將該蓋板2穩固地結合於該基板1。 Step 3: As shown in FIG. 11, the press cooperative 300: firmly bonds the cover 2 to the substrate 1 by utilizing the adhesiveness of the pressure sensitive adhesive 4 in a low oxygen dry environment.
詳細說明的是,當該步驟一所準備的該間隔吸濕單元5是呈片狀或粉粒狀時,封裝人員或機器於該步驟二中,能先將該間隔吸濕單元5設置於該壓敏膠4的底面41上的預設位置,並透過精準對位後,再以滾筒(Roller)壓合方式進行該步驟三的壓合作業300。 In detail, when the interval moisture absorbing unit 5 prepared in the first step is in the form of a sheet or a powder, the package person or the machine can first set the interval moisture absorbing unit 5 in the second step. The preset position on the bottom surface 41 of the pressure sensitive adhesive 4 is passed through the precise alignment, and then the press cooperation 300 of the third step is performed by roller (roller) pressing.
也詳細說明的是,當該步驟一所準備的該間隔吸濕單元5是呈漿狀時,封裝人員或機器會於該步驟二中,將該間隔吸濕單元5塗設於該壓敏膠4的底面41上的預設位置,呈漿狀的該間隔吸濕單元4能經由紫外光固化(Ultraviolet Curing)或是真空固化(Vacuum Hardening)而成為固體,最後再以滾筒壓合方式進行該步驟三的壓合作業300。在此需說明的是,固化作業非必要步驟,如此,也能達成相同的目的。 In addition, when the interval moisture absorbing unit 5 prepared in the first step is in a slurry form, the packager or the machine may apply the interval moisture absorbing unit 5 to the pressure sensitive adhesive in the second step. The predetermined position on the bottom surface 41 of the 4, the spacer-shaped moisture absorbing unit 4 can be solidified by ultraviolet curing or vacuum hardening, and finally the roller is pressed. Step 3 of the cooperative industry 300. It should be noted here that the curing operation is not a necessary step, and thus the same purpose can be achieved.
如此,無論該間隔吸濕單元5是呈片狀、漿狀,或是粉粒狀,利用本發明的封裝方法便能提供一種低成本而有助於量 產,且能保持良好阻氣效果並能吸收該封裝空間中的水氣及氧氣的有機發光二極體。 Thus, regardless of whether the intervening moisture absorbing unit 5 is in the form of a sheet, a slurry, or a powder, the packaging method of the present invention can provide a low cost and a useful amount. An organic light-emitting diode that produces a good gas barrier effect and absorbs moisture and oxygen in the package space.
參閱圖12為本發明有機發光二極體的封裝方法之一第二實施例的流程圖,本發明有機發光二極體的封裝方法之該第二實施例,包含下列步驟: 12 is a flowchart of a second embodiment of a method for packaging an organic light-emitting diode according to the present invention. The second embodiment of the method for packaging an organic light-emitting diode according to the present invention includes the following steps:
步驟一、如圖13所示,備料作業100’:準備一具有一有機發光單元3的基板1、一包括一下表面21的蓋板2、一間隔吸濕單元5,及一設置於該蓋板2的下表面21的壓敏膠4。該有機發光單元3包括一頂面31。 Step 1, as shown in FIG. 13, the preparation operation 100': preparing a substrate 1 having an organic light-emitting unit 3, a cover plate 2 including a lower surface 21, a spacer moisture absorbing unit 5, and a cover plate The pressure sensitive adhesive 4 of the lower surface 21 of 2. The organic light emitting unit 3 includes a top surface 31.
步驟二、如圖14所示,前置作業200’:將該間隔吸濕單元5設置於該有機發光單元3的頂面31。 Step 2, as shown in FIG. 14, the pre-operation 200': the interval moisture absorbing unit 5 is disposed on the top surface 31 of the organic light-emitting unit 3.
步驟三、如圖15所示,壓合作業300’:於低氧乾燥的環境下,利用該壓敏膠4的黏性將該蓋板2穩固地結合於該基板1。 Step 3: As shown in FIG. 15, the press bonding industry 300': the cover plate 2 is firmly bonded to the substrate 1 by the adhesiveness of the pressure sensitive adhesive 4 in a low oxygen drying environment.
詳細說明的是,當該步驟一所準備的該間隔吸濕單元5是呈片狀或粉粒狀時,封裝人員或機器能於該步驟二中,直接將具有預定尺寸的該間隔吸濕單元5置放於該有機發光單元3的頂面後,再以滾筒壓合方式進行該步驟三的壓合作業300’。 In detail, when the interval moisture absorbing unit 5 prepared in the first step is in the form of a sheet or a powder, the packager or the machine can directly use the interval moisture absorbing unit having a predetermined size in the second step. After being placed on the top surface of the organic light-emitting unit 3, the press-working industry 300' of the third step is performed by roller pressing.
也詳細說明的是,當該步驟一所準備的該間隔吸濕單元5是呈漿狀時,封裝人員或機器會於該步驟二中,將該間隔吸濕單元5塗設於該有機發光單元3的頂面31,呈漿狀的該間隔吸濕單 元5能經由紫外光固化或是真空固化而成為固體,最後再以滾筒壓合方式進行該步驟三的壓合作業300’。補充說明的是,固化作業非必要步驟。 In addition, when the interval moisture absorbing unit 5 prepared in the first step is in a slurry state, the package person or machine may apply the interval moisture absorbing unit 5 to the organic light emitting unit in the second step. The top surface 31 of the slurry, the interval moisture absorption sheet The element 5 can be solidified by ultraviolet light curing or vacuum curing, and finally the press bonding industry 300' of the third step is carried out by roller pressing. It is added that the curing operation is not a necessary step.
如此,本發明封裝方法的該第二實施例,也可達到與上述本發明封裝方法的該第一實施例相同的目的與功效。 Thus, the second embodiment of the packaging method of the present invention can achieve the same objects and effects as the first embodiment of the above-described packaging method of the present invention.
經由以上的說明,可再將本發明有機發光二極體及其封裝方法的優點歸納如下: Through the above description, the advantages of the organic light-emitting diode of the present invention and the packaging method thereof can be summarized as follows:
一、本發明利用該間隔吸濕單元5來避免該有機發光單元3直接受該壓敏膠4的黏著拉力的作用而脫附於該基板1,故能避免該有機發光單元3與該基板1之間產生剝離,也能防止該有機發光單元3受到該壓敏膠4本身黏著拉力而產生缺陷的情形,藉此提升產品封裝作業時的良率。 1. The present invention utilizes the spacer moisture absorbing unit 5 to prevent the organic light emitting unit 3 from being directly attached to the substrate 1 by the adhesive force of the pressure sensitive adhesive 4, so that the organic light emitting unit 3 and the substrate 1 can be avoided. The peeling occurs therebetween, and the organic light-emitting unit 3 can be prevented from being damaged by the adhesive force of the pressure-sensitive adhesive 4 itself, thereby improving the yield of the product packaging operation.
二、本發明該間隔吸濕單元5除了能吸收來自於該有機發光單元3因老化(Aging)或相態(Phase)變化所產生的氣體之外,也能吸收來自該壓敏膠4所脫氣的氣體,也就是說,本發明因為能有效乾燥該封裝空間10,而更進一步地增加該有機發光單元3的使用壽命。 2. The spacer moisture absorbing unit 5 of the present invention can absorb the gas from the pressure sensitive adhesive 4 in addition to the gas generated by the aging (Aging) or phase change of the organic light-emitting unit 3. The gas of gas, that is, the present invention further increases the service life of the organic light-emitting unit 3 because it can effectively dry the package space 10.
三、本發明所提供的封裝方法,除了步驟簡單且不費時而有助於量產之外,也因為封裝設備便宜而有利於降低成本,故能提升產品本身的競爭優勢。更佳地,現有的卷對卷貼合(Roll to Roll)、卷對片貼合(Roll to Sheet),或是片對片貼合(Sheet to Sheet)等生產設備均能採用本發明所提供的封裝方法來進行封裝作業。 3. The packaging method provided by the present invention can improve the competitive advantage of the product itself, in addition to being simple and time-consuming to facilitate mass production, and also because the packaging equipment is cheap and beneficial to reduce costs. More preferably, the existing roll-to-roll fit (Roll to The production methods such as Roll), Roll to Sheet, or Sheet to Sheet can be packaged by the packaging method provided by the present invention.
綜上所述,本發明有機發光二極體及其封裝方法確實能達成本發明之目的。 In summary, the organic light-emitting diode of the present invention and its packaging method can achieve the object of the present invention.
惟以上所述者,僅為本發明之實施例而已,當不能以此限定本發明實施之範圍,凡是依本發明申請專利範圍及專利說明書內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。 However, the above is only the embodiment of the present invention, and the scope of the invention is not limited thereto, and all the equivalent equivalent changes and modifications according to the scope of the patent application and the patent specification of the present invention are still The scope of the invention is covered.
1‧‧‧基板 1‧‧‧Substrate
10‧‧‧封裝空間 10‧‧‧Package space
11‧‧‧上表面 11‧‧‧ upper surface
2‧‧‧蓋板 2‧‧‧ Cover
21‧‧‧下表面 21‧‧‧ Lower surface
3‧‧‧有機發光單元 3‧‧‧Organic lighting unit
31‧‧‧頂面 31‧‧‧ top surface
32‧‧‧陽極 32‧‧‧Anode
33‧‧‧有機發光層 33‧‧‧Organic light-emitting layer
34‧‧‧陰極 34‧‧‧ cathode
4‧‧‧壓敏膠 4‧‧‧ Pressure sensitive adhesive
41‧‧‧底面 41‧‧‧ bottom
5‧‧‧間隔吸濕單元 5‧‧‧Interval moisture absorption unit
Claims (10)
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| TW104131224A TWI568054B (en) | 2015-09-22 | 2015-09-22 | Organic light - emitting diodes and their packaging methods |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5401536A (en) * | 1992-01-10 | 1995-03-28 | Shores; A. Andrew | Method of providing moisture-free enclosure for electronic device |
| US6897474B2 (en) * | 2002-04-12 | 2005-05-24 | Universal Display Corporation | Protected organic electronic devices and methods for making the same |
| US20060100299A1 (en) * | 2002-07-24 | 2006-05-11 | Ranjit Malik | Transformable pressure sensitive adhesive tape and use thereof in display screens |
| TW201038111A (en) * | 2009-02-13 | 2010-10-16 | Qualcomm Mems Technologies Inc | Display device with desiccant |
| US8022624B2 (en) * | 2007-04-25 | 2011-09-20 | Global Oled Technology Llc | Moisture protection for OLED display |
-
2015
- 2015-09-22 TW TW104131224A patent/TWI568054B/en not_active IP Right Cessation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5401536A (en) * | 1992-01-10 | 1995-03-28 | Shores; A. Andrew | Method of providing moisture-free enclosure for electronic device |
| US6897474B2 (en) * | 2002-04-12 | 2005-05-24 | Universal Display Corporation | Protected organic electronic devices and methods for making the same |
| US20060100299A1 (en) * | 2002-07-24 | 2006-05-11 | Ranjit Malik | Transformable pressure sensitive adhesive tape and use thereof in display screens |
| US8022624B2 (en) * | 2007-04-25 | 2011-09-20 | Global Oled Technology Llc | Moisture protection for OLED display |
| TW201038111A (en) * | 2009-02-13 | 2010-10-16 | Qualcomm Mems Technologies Inc | Display device with desiccant |
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