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TWI455960B - Thermoset coating-forming resin composition - Google Patents

Thermoset coating-forming resin composition Download PDF

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Publication number
TWI455960B
TWI455960B TW097122469A TW97122469A TWI455960B TW I455960 B TWI455960 B TW I455960B TW 097122469 A TW097122469 A TW 097122469A TW 97122469 A TW97122469 A TW 97122469A TW I455960 B TWI455960 B TW I455960B
Authority
TW
Taiwan
Prior art keywords
component
resin composition
forming
formula
film
Prior art date
Application number
TW097122469A
Other languages
Chinese (zh)
Other versions
TW200914494A (en
Inventor
Tadashi Hatanaka
Junpei Kobayashi
Daniel Antonio Sahade
Original Assignee
Nissan Chemical Ind Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nissan Chemical Ind Ltd filed Critical Nissan Chemical Ind Ltd
Publication of TW200914494A publication Critical patent/TW200914494A/en
Application granted granted Critical
Publication of TWI455960B publication Critical patent/TWI455960B/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
    • C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/133711—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by organic films, e.g. polymeric films
    • G02F1/133723—Polyimide, polyamide-imide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2379/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08J2361/00 - C08J2377/00
    • C08J2379/04—Polycondensates having nitrogen-containing heterocyclic rings in the main chain; Polyhydrazides; Polyamide acids or similar polyimide precursors
    • C08J2379/08—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Mathematical Physics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Claims (13)

一種形成熱硬化膜用樹脂組成物，其特徵為含有下列(A)成分及(B)成分；(A)成分：具有由下列式(1)及式(2)所表示之構造單位之聚醯亞胺前驅物；(B)成分：雙馬來醯亞胺化合物； (式中，A1 為包含脂環構造之有機基，A2 為包含脂肪族環與苯環產生縮合後之構造之有機基，B1 及B2 當中至少一方為包含-SO2 -構造之有機基，R1 、R2 、R3 及R4 分別獨立，表示氫原子或碳原子數1至7之有機基)。A resin composition for forming a thermosetting film, which comprises the following components (A) and (B); and component (A): a polyfluorene having a structural unit represented by the following formulas (1) and (2) An imine precursor; (B) component: a bismaleimide compound; (in the formula, A1 Is an organic group containing an alicyclic structure, A2 An organic group containing a structure in which an aliphatic ring and a benzene ring are condensed, B1 And B2 At least one of them contains -SO2 - constructed organic base, R1 , R2 , R3 And R4 Individually independent, representing a hydrogen atom or an organic group having 1 to 7 carbon atoms). 如申請專利範圍第1項之形成熱硬化膜用樹脂組成物，其中，(A)成分為以7：3至4：6的比例包含由式(1)所表示之構造單位與由式(2)所表示之構造單位之聚醯亞胺前驅物。 The resin composition for forming a thermosetting film according to the first aspect of the invention, wherein the component (A) comprises a structural unit represented by the formula (1) and a formula (2) in a ratio of 7:3 to 4:6. The polyimine precursor of the structural unit represented. 一種形成熱硬化膜用樹脂組成物，其特徵為： 係含有下列(A)成分及(B)成分；(A)成分：使包含由式(a1)及式(a2)所表示之四羧酸二酐之酸成分，與包含於分子中具有-SO2 -構造之二胺化合物之二胺成分進行反應而得之聚醯亞胺前驅物； (式中，A1 為包含脂環構造之有機基，A2 為包含脂肪族環與苯環產生縮合後之構造之有機基)；(B)成分：雙馬來醯亞胺化合物。A resin composition for forming a thermosetting film, which is characterized by: The component (A) and the component (B) are contained; (A) component: an acid component containing the tetracarboxylic dianhydride represented by the formula (a1) and the formula (a2), and -SO2 contained in the molecule a polyimine precursor obtained by reacting a diamine component of the diamine compound; (in the formula, A1 Is an organic group containing an alicyclic structure, A2 An organic group having a structure in which an aliphatic ring and a benzene ring are condensed; (B) component: a bismaleimide compound. 如申請專利範圍第3項之形成熱硬化膜用樹脂組成物，其中，前述酸成分為以莫耳比7：3至4：6的比例包含由式(a1)所表示之四羧酸二酐與由式(a2)所表示之四羧酸二酐之酸成分。 The resin composition for forming a thermosetting film according to the third aspect of the invention, wherein the acid component comprises a tetracarboxylic dianhydride represented by the formula (a1) in a molar ratio of from 7:3 to 4:6. An acid component of the tetracarboxylic dianhydride represented by the formula (a2). 如申請專利範圍第1至4項中任一項之形成熱硬化膜用樹脂組成物，其中，(A)成分之聚醯亞胺前驅物的重量平均分子量為1,000至10,000。 The resin composition for forming a thermosetting film according to any one of claims 1 to 4, wherein the polyiminoimine precursor of the component (A) has a weight average molecular weight of 1,000 to 10,000. 如申請專利範圍第1項之形成熱硬化膜用樹脂組成物，其中，依據(A)成分的100質量份，係含有1至100質量份之(B)成分。 The resin composition for forming a thermosetting film according to the first aspect of the invention, wherein the component (B) is contained in an amount of from 1 to 100 parts by mass based on 100 parts by mass of the component (A). 一種硬化膜，其特徵為：係從申請專利範圍第1至6項中任一項之形成熱硬化 膜用樹脂組成物所得。 A cured film characterized by being thermally hardened according to any one of claims 1 to 6. The film was obtained from a resin composition. 一種平坦化膜，其特徵為：係從申請專利範圍第1至6項中任一項之形成熱硬化膜用樹脂組成物所得。 A flattening film obtained by forming a resin composition for a thermosetting film according to any one of claims 1 to 6. 一種液晶配向膜，其特徵為：係從申請專利範圍第1至6項中任一項之形成熱硬化膜用樹脂組成物所得。 A liquid crystal alignment film obtained by forming a resin composition for a thermosetting film according to any one of claims 1 to 6. 一種平坦化兼液晶配向膜，其特徵為：係從申請專利範圍第1至6項中任一項之形成熱硬化膜用樹脂組成物所得。 A flattening and liquid crystal alignment film obtained by forming a resin composition for a thermosetting film according to any one of claims 1 to 6. 一種顯示元件，其特徵為：係具有申請專利範圍第7項之硬化膜。 A display element characterized by having a cured film of claim 7 of the patent application. 一種液晶顯示元件，其特徵為：係具有申請專利範圍第7項之硬化膜。 A liquid crystal display element characterized by having a cured film of claim 7 of the patent application. 一種光學薄膜，其特徵為：係具有申請專利範圍第7項之硬化膜。An optical film characterized by having a cured film of claim 7 of the patent application.
TW097122469A 2007-06-15 2008-06-13 Thermoset coating-forming resin composition TWI455960B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2007159054 2007-06-15

Publications (2)

Publication Number Publication Date
TW200914494A TW200914494A (en) 2009-04-01
TWI455960B true TWI455960B (en) 2014-10-11

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Country Status (5)

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JP (1) JP5382346B2 (en)
KR (1) KR101486301B1 (en)
CN (1) CN101679633B (en)
TW (1) TWI455960B (en)
WO (1) WO2008153101A1 (en)

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JP6256679B2 (en) * 2013-10-22 2018-01-10 日産化学工業株式会社 Resin composition for display substrate
TWI473838B (en) 2013-11-13 2015-02-21 財團法人工業技術研究院 Polyamic acid, polyimide, and method for manufacturing graphite sheet
CN105086316B (en) * 2014-05-15 2018-01-30 捷恩智株式会社 Thermosetting composition, cured film, colored filter, liquid crystal display cells, solid-state imager and LED illuminant heart
CN106662780B (en) * 2014-06-25 2019-12-31 日产化学工业株式会社 Liquid crystal display element
JP2016148777A (en) * 2015-02-12 2016-08-18 アーゼッド・エレクトロニック・マテリアルズ（ルクセンブルグ）ソシエテ・ア・レスポンサビリテ・リミテ Composition for forming underlay film, and formation method of underlay film using same
JP6724418B2 (en) * 2016-02-29 2020-07-15 Jsr株式会社 Liquid crystal aligning agent, liquid crystal aligning film and its manufacturing method, and liquid crystal element
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Also Published As

Publication number Publication date
JPWO2008153101A1 (en) 2010-08-26
KR20100034744A (en) 2010-04-01
KR101486301B1 (en) 2015-01-26
JP5382346B2 (en) 2014-01-08
CN101679633A (en) 2010-03-24
WO2008153101A1 (en) 2008-12-18
CN101679633B (en) 2012-09-19
TW200914494A (en) 2009-04-01

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