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TWI302101B - Method for producing saponin extract from soapnuts - Google Patents

Method for producing saponin extract from soapnuts Download PDF

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Publication number
TWI302101B
TWI302101B TW95121482A TW95121482A TWI302101B TW I302101 B TWI302101 B TW I302101B TW 95121482 A TW95121482 A TW 95121482A TW 95121482 A TW95121482 A TW 95121482A TW I302101 B TWI302101 B TW I302101B
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Taiwan
Prior art keywords
fruit
sapindus
producing
saponin
saponin extract
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TW95121482A
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Chinese (zh)
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TW200800246A (en
Inventor
Chun Han Ko
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Forestry Bureau Council Of Agriculture Executive Yuan
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Priority to TW95121482A priority Critical patent/TWI302101B/en
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  • Saccharide Compounds (AREA)

Description

1302101 九、發明說明: 【發明所屬之技術領域】 本案係關於一種產生皂素萃取液之方法,尤指一種自 無患子果實產生皂素萃取液之方法。 【先前技術】 無患子為無患子科(Sapindeceae)植物,其長的很像 龍眼,係為一種自古以來即已存在之植物,在記載中亦稱 黃目子,早期人們發覺取無患子果實(稍加破裂尤佳)置 於水中用雙手加以搓揉,可以搓出泡沫而可以清潔手掌, 遂被先民利用來作為清潔劑使用,舉凡對身體或家居生活 中所使用的物品都可用無患子來清洗。後來文明日進,各 種肥皂、香皂、清潔劑大量出現,因此無患子之使用逐漸 為人所遺忘。近年來,環保意識抬頭,無患子的使用又被 人重視,因此坊間即有多種相關之清潔用品問世。而目前 使用無患子果實製造成清潔劑所採行之製造方法,係將無 患子果實收集後略加敲擊破裂,然後加水燉煮,使無患子 皂素溶入熱水中待停止加熱後經過簡單過濾即為無患子 粗萃取液,即以之作為原料再進行後續加工製造成各種成 品。 有鑑於京都議定書通過後,皂素等天然界面活性劑必 將大幅取代由石化產品合成之界面活性劑,故本發明人對 1302101 無患子產品的使用深感興趣,因此對無患子皂素之製造方 法進行深入研究,遂發覺一般習知以上述燉煮方法所取得 之無患子萃取液,實際上皂素已遭加熱而破壞,以致品質 不佳,故以之再加工製造出後績產品’亦為品質不佳者。 究其原因即在於以加熱燉煮無患子果實的方法完全不正 確,只是因製造業者不察,以致長期以來皆沿襲此方法, 而無從改進。針對此種缺失,本發明人乃構思加以改善, 經實作試驗,終發明出本發明之方法。 【發明内容】 本案之主要目的在於提供一種自無患子果實產生皂素 萃取液之方法,其係利用碾壓處理及加氣浮選處理來取得 品質不遭破壞之無患子萃取液,以改善傳統之加熱燉煮法 會破壞皂素成分之缺點。 為達上述目的,本案之一較廣義實施樣態為提供一種 自無患子果實產生皂素萃取液之方法,係包含下列步驟: 將無患子果實進行粗碎裂;以水浸泡該經碎裂之無患子果 實;對該無患子果實水液進行加氣浮選處理,以產生泡 沫;以及收集該泡沫並加以靜置,以得到皂素萃取液。 根據本案上述之構想,其中該自無患子果實產生皂素 萃取液之方法係以碾壓處理將無患子果實進行粗碎裂。該 碾壓處理係以機械式碾壓機進行,且該碾壓機具有二相對 設置及轉動之滾輪。而該無患子果實係自該二滾輪之間經 1302101 過而被礙破碎裂。 根據本案上述之構想,其中在該碾壓處理過程中,可 加水潤滑,以幫助該無患子果實擠壓通過該等滾輪。 根據本案上述之構想,其中該加氣浮選處理係打入加 壓氣體至該無患子果實水液,用以增加該無患子果實與水 液間之摩擦搓揉,以促使泡沫之產生。 根據本案上述之構想,其中該加氣浮選處理係以空壓 機輸出加壓氣體。 本案之另一廣義實施樣態為提供一種皂素萃取液,其 係以上述構想所述之方法所製造。 【實施方式】 體現本案特徵與優點的一些典型實施例將在後段的說 明中詳細敘述。應理解的是本案能夠在不同的態樣上具有 各種的變化,其皆不脫離本案的範圍,且其中的說明及圖 式在本質上係當作說明之用,而非用以限制本案。 本案之皂素萃取液係以無患子果實為材料,再依本發 明所揭示之方法進行製作。有鑑於傳統以加熱燉煮無患子 果實來產生皂素萃取液的方法中,皂素會因加熱而被破 壞,導致所製成之皂素產品品質不佳,因此本案所採行的 方法係完全不對無患子果實進行加熱,以避免皂素在萃取 過程中被破壞。 請參閱第一圖,其係為本案自無患子果實產生皂素萃 1302101 取液之方法流程圖。如第一圖所示,本案產生皂素萃取液 之方法係首先將無患子果實進行粗碎裂(步驟si),再以 水浸泡該經碎裂之無患子果實(步驟S2),接著對該無患 子果實水液進行加氣浮選處理,以產生泡沫(步驟S3), 最後再收集該泡沫並加以靜置(步驟S4 ),待該泡泳恢復 成液體狀態,即可得到品質不遭破壞之皂素萃取液。以下 將更詳細說明本案自無患子果實產生皂素萃取液之方法。 根據本案之較佳實施例,步驟S1係透過碾壓處理來對 無患子果實進行粗碎裂,使無患子果實破碎,以利增加其 外果皮與外界之接觸面積。請參閱第二圖,其係為本案碾 壓處理之示意圖。此輾壓處理係以機械式輾壓機20為之, 其主要具有二相對設置之滾輪201、202,而兩滾輪201、 202中間具有約0.1-0.5公分之間隙。兩滾輪201、202係 藉由馬力帶動而相對向内轉動,亦即向兩滾輪201、202 間之間隙方向轉動(如圖中箭頭所示),而無患子果實10 即自兩滾輪201、202中間經過,因此可被滾輪201、202 輾破碎裂,得到呈碎裂狀態之無患子果實10’ ,而其碎裂 情形以粗碎裂即可,不必過於細碎裂。另外,在輾壓處理 之過程中,亦可加水潤滑,以幫助無患子果實10擠壓通 過滾輪201、202。 當然,將無患子果實進行粗碎裂之方法並不限於上述 之碾壓處理,其他可將無患子果實碎裂之方法,如敲打或 重壓,亦在本案技術範圍内。 接著自輾壓機20下方收集呈碎裂狀態之無患子果實 1302101 10’ ,並投注入容器中,再加入大量水份浸泡(步驟S2 ), 然後即對該容器之水液進行加氣浮選處理(步驟S3)。請參 閱第三圖,其係為本案加氣浮選處理之示意圖。此加氣浮 選處理係利用一空壓機30來進行,該空壓機30具有一管 路301牽至盛裝該無患子果實水液之容器底部。空壓機30 可輸出經適當加壓之氣體,並藉由管路301打氣至該容器 内之水液内,使氣體向上衝出,而其作用乃幫助無患子果 實10’之碎裂果皮與水液間摩擦搓揉,以促使皂素釋放, 因此會自然產生大量泡沫40向上堆積。接著,即另以小 容器收集泡沫40並加以靜置(步驟S4),使泡洙40恢復 成液體狀態,如此即得到品質不受損害的皂素萃取液。 以下說明根據本案之方法自無患子果實產生皂素萃取 液之一實例。 實例1 : 以無患子果實為材料,使用一馬力帶動之輾壓機將無 患子果實進行輾壓處理,輾壓滾輪間隙為0.3公分,接著 將自輾壓機下方收集之碎裂狀態之無患子果實置入容器 中,以一公斤果實對十公升水份之比例浸泡三十分鐘,然 後對該容器之水液進行加氣浮選處理,即自空壓機輸出每 分鐘一公升之氣體,使打氣向上衝出,其作用乃幫助無患 子果實之碎裂果皮與水液間摩擦搓揉,因此會自然產生大 量泡沫向上堆積。接著,另以小容器收集泡沫並加以靜置 使恢復成液體狀態,如此即得到品質不受損害的皂素萃取 液,依據CNS 9429測得每公升萃取液有50g的皂素含量。 .1302101 綜上所述,本案係提出一種新穎的自無患子果實產生 皂素萃取液之方法,其所採行之方法係完全不對無患子果 實進行加熱,故在萃取過程中完全不破壞萃取液内的皂素 成分及品質,所以可以取得品質保持純淨不受破壞之無患 子萃取液,而以之作為原料再進一步做後續加工為其他清 潔產品時,當然也能確保品質能更為精進。本案之方法有 別於傳統之加熱燉煮法,可保存I素成分並降低有機酸之 含量,使產品更易於保存。因此,本案之方法可提升產品 穩定性,使無患子產品更易於保存,炎進一步提升無患子 加工規模化生產之可行性,增加林農造林之收益及意願, 極具產業利用之價值,爰依法提出申讀。 本案得由熟知此技術之人士任施處思而為諸般修飾, 然皆不脫如附申請專利範圍所欲保護I。 -1302101 【圖式簡單說明】 法流· #、為杨自無患子果實赵I素萃取液之方 圖·係為本案碾壓處理之示意圖。 第一圖·係為本案加氣浮選處理之示意圖。 •【主要元件符號說明】 S1-S4:自無患子果實產生皂素萃取液之步驟 1 〇 :無患子果實 10’ :呈碎裂狀態之無患子果實 20 :礙壓機 201、202 :滚輪 30 :空壓機 % 301 :管路 40 :泡沫 111302101 IX. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a method for producing an saponin extract, and more particularly to a method for producing a saponin extract from sapindus fruit. [Prior Art] Sapindus is a Sapindeceae plant, which is very long like a longan. It is a plant that has existed since ancient times. It is also known as the yellow eye in the records. In the early days, people found the fruit of the sapindus (slightly ruptured).尤佳) Put it in the water and rub it with both hands. It can remove the foam and clean the palm of your hand. It is used by the ancestors as a cleaning agent. It can be cleaned with all the things used in the body or in the home life. Later, as civilization progressed, various soaps, soaps, and detergents appeared in large numbers, so the use of the scorpion was gradually forgotten. In recent years, the awareness of environmental protection has risen, and the use of harmless children has been taken seriously. Therefore, a variety of related cleaning products have been introduced. At present, the manufacturing method adopted by the use of Sapindus fruit as a cleaning agent is to collect the saponin of the saponin and then smash it slightly, and then add water to cook, so that the saponin is dissolved in the hot water to be heated, and then simply filtered. The crude extract of Sapindus is used as a raw material and then processed into various finished products. In view of the adoption of the Kyoto Protocol, natural surfactants such as saponin will greatly replace the surfactants synthesized by petrochemical products. Therefore, the inventors are deeply interested in the use of the 1302101 Sapindus product, and therefore the manufacturing method of Sapindus saponin is carried out. In-depth study, I found that the saponin obtained by the above-mentioned stewing method is actually destroyed by the above-mentioned stewing method. In fact, the saponin has been damaged by heating, so that the quality is not good, so the product is reprocessed to produce the product. Good. The reason for this is that the method of heating and stewing the fruit of the sorrel is completely incorrect, but it is not observed by the manufacturers, so that this method has been followed for a long time, and there is no improvement. In view of such a deficiency, the inventors have conceived and improved the method, and the invention has finally invented the method of the present invention. SUMMARY OF THE INVENTION The main purpose of the present invention is to provide a method for producing a saponin extract from sapindus fruit by using a roller compaction treatment and an aerated flotation treatment to obtain a saprophytic extract which is not damaged in quality, thereby improving the conventional heating. Sterilization can destroy the shortcomings of saponin. In order to achieve the above object, one of the broader aspects of the present invention provides a method for producing a saponin extract from sapindus fruit, which comprises the steps of: coarsely breaking the fruit of the sapindus; soaking the fragmented sachetberry fruit with water The agaric fruit water is subjected to aerated flotation treatment to produce a foam; and the foam is collected and allowed to stand to obtain a saponin extract. According to the above concept of the present invention, the method for producing a saponin extract from the fruit of the Sapindus is to crush the sapindus fruit by crushing. The roller compaction process is carried out by a mechanical roller compactor, and the roller compactor has two rollers that are oppositely disposed and rotated. The fruit of the Sapindus was blocked by the 1302101 between the two rollers. According to the above concept of the present invention, in the rolling process, water lubrication may be applied to help the sapindus fruit to be squeezed through the rollers. According to the above concept of the present invention, the aerated flotation treatment drives a pressurized gas to the fruit water of the fruitless fruit to increase the frictional entanglement between the fruit and the liquid of the sapindus to promote the generation of foam. According to the above concept of the present invention, the aerated flotation process outputs a pressurized gas as an air compressor. Another broad aspect of the present invention provides a saponin extract prepared by the method described above. [Embodiment] Some exemplary embodiments embodying the features and advantages of the present invention will be described in detail in the following description. It is to be understood that the present invention is capable of various modifications in various embodiments, and is not intended to limit the scope of the invention. The saponin extract of the present invention is prepared by using the fruit of the sarcoid fruit as disclosed in the present invention. In view of the traditional method of heating and stewing the fruit of the saponin to produce the saponin extract, the saponin is destroyed by heating, resulting in poor quality of the saponin product. Therefore, the method adopted in this case is completely wrong. The fruit of the saponin is heated to prevent saponin from being destroyed during the extraction process. Please refer to the first figure, which is a flow chart of the method for extracting saponin extract 1302101 from the fruit of Sapindus. As shown in the first figure, the method for producing a saponin extract in the present invention firstly coarsely disintegrates the fruit of the sapindus (step si), and then soaks the fragmented sapindus fruit with water (step S2), followed by the sapindus fruit. The aqueous liquid is subjected to aerated flotation treatment to produce a foam (step S3), and finally the foam is collected and allowed to stand (step S4), and when the bubble is returned to a liquid state, the saponin whose quality is not destroyed can be obtained. Extract. The method for producing a saponin extract from the fruit of Sapindus in the present case will be described in more detail below. According to a preferred embodiment of the present invention, the step S1 is performed by crushing to coarsely break the fruit of the sarcoid fruit, thereby breaking the fruit of the sarcoid, so as to increase the contact area between the outer pericarp and the outside. Please refer to the second figure, which is a schematic diagram of the rolling treatment of this case. The rolling process is based on a mechanical squeezing machine 20 having two oppositely disposed rollers 201, 202 with a gap of between about 0.1 and 0.5 cm between the two rollers 201, 202. The two rollers 201, 202 are rotated inward by the horsepower, that is, to the direction of the gap between the two rollers 201, 202 (as indicated by the arrow in the figure), and the fruit of the fruitless child 10 is from the middle of the two rollers 201, 202. After passing, it can be crushed by the rollers 201, 202, and the fruit of the sarcoid fruit 10' in a fragmented state is obtained, and the fragmentation condition can be coarsely broken, and it is not necessary to be too finely broken. In addition, during the rolling process, water lubrication may be added to help the sapindus fruit 10 to be squeezed through the rollers 201, 202. Of course, the method of coarsely breaking the fruit of the sapindus is not limited to the above-mentioned rolling treatment, and other methods for fragmenting the fruit of the sarcoid, such as tapping or heavy pressing, are also within the technical scope of the present invention. Then, the sachetberry fruit 1302101 10' in a fragmented state is collected from the bottom of the rolling machine 20, and injected into the container, and then a large amount of water is added for soaking (step S2), and then the water of the container is subjected to aerated flotation treatment. (Step S3). Please refer to the third figure, which is a schematic diagram of the aerated flotation process for this case. This aerated flotation process is carried out by means of an air compressor 30 having a pipe 301 which is carried to the bottom of the vessel containing the water of the fruit of the fruit. The air compressor 30 can output a properly pressurized gas and pump it into the water in the container by the pipe 301 to make the gas rush upward, and the effect is to help the fruit of the sapindus fruit to be broken and peeled. The liquid rubs against the sputum to promote the release of saponin, so naturally a large amount of foam 40 is accumulated upward. Next, the foam 40 is additionally collected in a small container and allowed to stand (step S4), so that the foam 40 is returned to a liquid state, whereby a saponin extract having an unaffected quality is obtained. An example of the production of a saponin extract from Sapindus fruit according to the method of the present invention is described below. Example 1: Using the fruit of the sapindus as a material, the fruit of the sapindus was subjected to rolling treatment using a horsepower-driven tamping machine, and the gap between the rolling rollers was 0.3 cm, and then the fruit of the sclerotium collected from the crushing state collected from the squeezing machine was placed. In the container, soak for 30 minutes in a ratio of one kilogram of fruit to ten liters of water, and then perform aerated flotation treatment on the water of the container, that is, output one liter of gas per minute from the air compressor, so that the gas is rushed upward. Out, its role is to help the fruit of the sapindus fruit to rub between the skin and the water, so naturally a large amount of foam will accumulate. Next, the foam was collected in a small container and allowed to stand to return to a liquid state, so that a saponin extract having an unaffected quality was obtained, and a saponin content of 50 g per liter of the extract was measured in accordance with CNS 9429. .1302101 In summary, this case proposes a novel method for producing saponin extract from the fruit of Sapindus. The method adopted is that the fruit of the Sapindus is not heated at all, so the extraction solution is not destroyed at all. The composition and quality of saponin make it possible to obtain a Sapindus extract that is pure and unspoiled, and as a raw material, it can be further refined to be further refined when it is further processed into other cleaning products. The method of this case is different from the traditional heating stewing method, which can preserve the components of the element and reduce the content of organic acids, making the product easier to store. Therefore, the method of the present case can improve the stability of the product, make the product of the harmless product easier to preserve, and further improve the feasibility of large-scale production of the harmless child, increase the income and willingness of the forestry afforestation, and have the value of industrial utilization, and apply for the law according to law. . This case has been modified by people who are familiar with the technology, and is not intended to be protected as intended. -1302101 [Simple description of the diagram] Method flow · #, is the side of the extract of Yang Zizhizi fruit Zhao I Su. The diagram is the schematic diagram of the roller compaction treatment of this case. The first picture is a schematic diagram of the aerated flotation process for this case. • [Main component symbol description] S1-S4: Step 1 of producing saponin extract from Sapindus fruit 〇: Sapindus fruit 10': Sapindus fruit in fragmented state 20: Barrier press 201, 202: Roller 30: Air pressure Machine % 301 : Line 40: Foam 11

Claims (1)

4 1302101 1 . 二補充」 十、申請專利範圍: — 1. 一種自無患子果實產生皂素萃取液之方法,係包含下列 ^ 步驟: 將無患子果實進行粗碎裂; 以水浸泡該經碎裂之無患子果實; 對該無患子果實水液進行加氣浮選處理,以產生泡 肇沫;以及 收集該泡沫並加以靜置,以得到皂素萃取液。 2. 如申請專利範圍第1項所述之自無患子果實產生皂素 萃取液之方法,其係以碾壓處理將無患子果實進行粗碎 3. 如申請專利範圍第2項所述之自無患子果實產生皂素 萃取液之方法,其中該碾壓處理係以機械式碾壓機進行。 4. 如申請專利範圍第3項所述之自無患子果實產生皂素 • 萃取液之方法,其中該碾壓機具有二相對設置及轉動之滚 輪。 5. 如申請專利範圍第4項所述之自無患子果實產生皂素 萃取液之方法,其中該無患子果實係自該二滾輪之間經過 而被碾破碎裂。 6. 如申請專利範圍第5項所述之自無患子果實產生皂素 萃取液之方法,其中在該碾壓處理過程中,可加水潤滑, 以幫助該無患子果實擠壓通過該等滾輪。 7. 如申請專利範圍第1項所述之自無患子果實產生皂素 12 ' 1302101 ι 萃取液之方法,其中該加氣浮選處理係打入加壓氣體至該 無患子果實水液。 8. 如申請專利範圍第7項所述之自無患子果實產生皂素 . 萃取液之方法,其中該加氣浮選處理係以空壓機輸出加壓 氣體。 9. 如申請專利範圍第7項所述之自無患子果實產生皂素 萃取液之方法,其中該加氣浮選處理係用以增加該無患子 • 果實與水液間之摩擦搓揉,以促使泡沫之產生。4 1302101 1 . 2 Supplements IX. Scope of Application: 1. A method for producing a saponin extract from the fruit of Sapindus, comprising the following steps: coarsely breaking the fruit of the sapindus; soaking the fragmentation with water Sapindus fruit; aerated flotation treatment of the fruit water of the Sapindus fruit to produce foaming foam; and collecting the foam and allowing to stand to obtain a saponin extract. 2. A method for producing a saponin extract from sapindus fruit as described in claim 1 of the patent application, which comprises crushing the fruit of the sarcoid fruit by crushing treatment. 3. The fruit of the saintberry as described in claim 2 A method of producing a saponin extract, wherein the roller compaction treatment is carried out by a mechanical roller compactor. 4. A method of producing a saponin extract from Sapindus fruit as described in claim 3, wherein the roller compactor has two oppositely disposed and rotating rollers. 5. A method of producing a saponin extract from Sapindus fruit as described in claim 4, wherein the Sapindus fruit is crushed by passing between the two rollers. 6. A method of producing a saponin extract from Sapindus fruit as described in claim 5, wherein during the roller compaction treatment, water lubrication is applied to help the sapindus fruit to be squeezed through the rollers. 7. The method of producing a saponin 12 '1302101 ι extract from Sapindus fruit according to claim 1, wherein the aerated flotation treatment is to inject a pressurized gas into the water of the Sapindus fruit. 8. The method for producing a saponin from a fruit of a sarcoid, as described in claim 7, wherein the aerated flotation treatment outputs a pressurized gas by an air compressor. 9. A method for producing a saponin extract from Sapindus fruit as described in claim 7 wherein the aerated flotation treatment is used to increase the friction between the sapindus and the fruit to promote foaming. Produced. 1313
TW95121482A 2006-06-15 2006-06-15 Method for producing saponin extract from soapnuts TWI302101B (en)

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