100年12月26日修正替換頁 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種具透明彩色圖像球體之製造方 法，尤指補強層與透明層中間，夾合一彩色圖像；其係 在多孔性薄膜上印刷圖像’再將已印刷好圖像的彩色薄 膜，經熱壓或射出方式先與透明層粘貼結合成一複合 層’再裁切成可拼湊成球體外表之多片體，將此多片的 複合層粘貼於内膽球層或補強層，而複合層需進一步硫 化交聯反應’並置於二半球模具中硫化成形，即可完成 由最外層直接透視内部的彩色圖像，達到良好的透視效 果者。 【先前技術】 球的製造按，習用球體如：籃球、足球、排球、手 球、躲避球、美式足球、橄欖球、練習球、玩具球等等， 依製造法可區分為手縫球與非手縫球，而非手縫球一般 的結構及製造概述如下：以結構區分為有纏繞層與不具 纏繞層二類： A、具纏繞層（with wrapped layer)分手貼皮球與橡膠 成形球。 1、手貼皮球（積層球laminated balls ) 一充氣内膽（bladder)，再加上一單條紗線或多條紗 1364305 100年12月26日修正替換頁 線’纏繞於内膽外表（該單條紗線或多條紗線均預浸乳 膠）形成纏繞層，其作用在於補強球.體内膽尺寸之安定 性與不變形的特性，之後在外表加一胎體層（carcass )， 在模具中硫化形成之球體亦稱為中胎，中胎球表上具定 位美觀功能之線條溝，隔成多塊球表區，而此多塊球表 區域，可凑成-球表面，一般為8_工2塊球表區（a 馨 PlUrallty 〇f area )’最後再將這-組多塊可拼凑成球之對 應橢圓表皮（a plurality of panels皮革或合成材質），以 PU點著劑貼覆於胎體層（中胎），即完成球體成品。而 這些皮革可預先選擇材質、種類、顏色、印刷、烙印、 燙烙、文字、圖像浮雕、商標和皮革紋路。 2、橡膠成形球（molded rubber baU ) 將已纏繞好之球胜，直接將未硫化之橡膠生片覆在外 • 表’置入-個具二半球形模具中加壓、加熱產生硫化交 聯反應直接硫化成形’其球表外表紋路區分溝、條等均 在模具中一次成形。 B、不含纏繞補強層 類似A項中1、2作法， 或再貼覆橡膠外層硫化成形 外表顏色和路印製造方法 在内膽形成後，可以用手貼合 。一般以軟性玩具球居多。 且為单一顏色 以上習用球體’外表均為不透明材質 4 丄％ 305 「 100年12月26日修正替換頁 或只是多種單一顏色區塊所造成，在美觀美學（aesthet ic ) 上顯得相當單調，所以經常在外表上再加彩色或烙印，其 方法如下： 1、 手貼球（積層球）直接用網版印刷或以轉印方式，將 圖像印於皮革或合成皮上，再依需要用高週波或烫金 機烙印加工方式，將圖案壓成浮雕後，再貼於球表。 2 '橡膠成形球：將所需要圖案圖像印於一玻璃紙或離型 紙上（cellophane 或 polyester fiira)，再將此圖像 低貼於未硫化之外表橡膠層上並定位，將此橡膠片貼 於球胚上，圖像在球體外表，然後將整個球體置入一 個具二個半球形模具中加熱、加壓、硫化後，將玻璃 紙或離型紙撕去，顏色圖像層則留於橡膠球體外表， _ 而形成外表具彩色圖像之橡膠球。 以上均是將彩色圖像置於球表面之方法，但是具以 下缺點： 1 '隨著球使用，顏色圖像會磨耗、退化、消失。 2、 限於橡膠片或玻璃紙為圖像附著材料，所印刷方式為傳 統網版印刷，圖像解析度及彩色印刷均非 ，卜节有限，圖像 品質粗糙，不夠精緻色彩不夠鮮艷，無法印刷類似⑽〇 5 1364305 '•广 ！------- ，： 100年12月26日修正替換頁 萬畫數解析度以上之自然全彩品質之圖像。 3、隨著球表紋路，圖像和顏色會產生不連續斷線、斷層現 象，視覺效果不佳。 4、 橡膠或皮革的底色限制了顏色圖像的鮮艷品質。 5、 多色網版印刷費用較昂貴。 有人為了改善以上的缺點，而發明將顏色圖像層置於 球胚”透月外表層中間，改善了对磨耗與橡膠底色的問 題如美國專矛j 5,320,345㉟；但它的方法係將彩色圖像 先印刷或轉印於外表的透過橡膠片上後再將透明橡膠片 (彩色圖像在内表面），覆蓋於球胚上，—起置人模具中加 熱而成顏色®像層在—透明球表層保護之球。此方法雖然 改善了部份傳統的彩色圖像球之缺點，但亦有許多缺點無 法改善’同樣具以下缺點： 、直接以網版印刷方法將彩色圖$印刷於透明橡膠片，無 法得到到目前解析度在30。萬畫數以上品質類似照片： 質之彩色圖像。 由於橡膠片很難以自動化印刷或自動化轉印方式，必須 用人工-片-片的印刷，生產成本提高，尤其在需求多 種顏色、套色的狀態下。 、無法大面積或在球表面彩印，所以由球外觀透視時，除 了圖像之外部份透明無印刷之處可直視内部的纏繞 6 1364305 »^ 100年12月26日修正替換頁 層’相當粗糙與難看。 4作法須瑣工序複雜。 【發明内容】 有馨於前述所揭露的技術仍然存在缺點問題，本發明 之具透明彩色圖像球體之製造方法，其解決習用球體球， 如欲製成具有透明之彩色圖像’必須使用轉印方式來處理 馨色圖像’且無法提高圖像的晝數，為其主要目的。 本發明案次-目的在於，以多孔性薄膜作為印刷的主 體使此多孔性薄臈得以與印刷設備配合，製成可供複 合之彩色薄膜’此-方式可作為大量印刷且得更高晝數之 需求。 本發明其結構包含有：一充氣用之内膽球層、一縷繞 紗加強用之補強層以及最外層的透明層所組合而成，其中 ♦該彩色圖像係置於補強層與透明層中間；而該彩色圖像之 製造方法，係選擇一種多讲极键睹r ―你夕 !夕札性溥膜（或稱多孔性材質）作[Description of the invention on December 26, 2014] Description of the Invention: [Technical Field] The present invention relates to a method for manufacturing a transparent color image sphere, in particular, a sandwich between a reinforcing layer and a transparent layer Image; print the image on the porous film' and then print the color film of the image, and then combine it with the transparent layer by hot pressing or injection to form a composite layer, and then cut into a spherical outer surface. Multi-sheet, the multi-layer composite layer is adhered to the inner spherical layer or the reinforcing layer, and the composite layer needs to be further vulcanized and cross-linked and placed in a two-hemispherical mold for vulcanization molding, thereby completing the direct inner perspective of the outer layer. Color images that achieve good perspective effects. [Prior Art] The manufacture of the ball, such as: basketball, football, volleyball, handball, dodgeball, American football, football, practice ball, toy ball, etc., can be divided into hand-stitched ball and non-hand-sewn according to the manufacturing method. The general structure and manufacture of the ball, not the hand-sewn ball, is summarized as follows: the structure is divided into two types: a wound layer and a non-winding layer: A. With a wrapped layer, a hand-bonded ball and a rubber-shaped ball. 1. Hand-balls (laminated balls) A bladder (bladder), plus a single yarn or a plurality of yarns 1364430. December 26, 100 revised replacement page line 'wrap around the liner's appearance (this single The yarn or a plurality of yarns are pre-impregnated with latex to form a wound layer, which functions to reinforce the ball. The stability and non-deformation characteristics of the bladder size in the body, and then add a carcass layer on the outer surface to vulcanize in the mold. The formed sphere is also called the middle tire. The middle tire ball has a line groove with a positioning function, which is divided into a plurality of ball table areas, and the plurality of ball table areas can be made into a ball surface, generally 8_work 2 ball table areas (a PlUrallty 〇f area )' Finally, this group can be put together to form the corresponding elliptical skin of the ball (a plurality of layers of leather or synthetic material), and the PU point agent is applied to the tire. The body layer (middle tire), that is, the finished ball. These leathers can be pre-selected in materials, types, colors, printing, branding, ironing, text, image relief, trademarks and leather lines. 2, rubber forming ball (molded rubber baU) will be wrapped around the ball wins, directly un-vulcanized rubber green sheet over the surface • Table 'insert - a two-hemispherical mold pressure, heating to produce vulcanization cross-linking reaction Direct vulcanization forming 'the outer surface of the ball surface is divided into grooves and strips, which are formed in the mold at one time. B. No entanglement and reinforcement layer Similar to the first and second methods in item A, or re-applied rubber outer layer vulcanization. Appearance color and road printing manufacturing method After the inner liner is formed, it can be attached by hand. Generally, soft toy balls are mostly used. It is a single color or more. The appearance of the sphere is opaque material. 4 丄% 305 "The December 26th revision of the replacement page or just a variety of single color blocks is quite monotonous in aesthetics (aesthet ic), so Frequently add color or branding on the exterior, the method is as follows: 1. Hand-picked ball (stacked ball) directly printed on the leather or synthetic leather by screen printing or transfer, and then used as needed Zhou Bo or bronzing machine branding processing method, press the pattern into embossed, and then stick it on the ball table. 2 'Rubber forming ball: print the desired pattern image on a cellophane or release paper (cellophane or polyester fiira), and then The image is low on the unvulcanized rubber layer and positioned. The rubber sheet is attached to the bulb, the image is on the outer surface of the sphere, and then the entire sphere is placed in a mold with two hemispheres. After vulcanization, the cellophane or the release paper is torn off, and the color image layer is left on the outer surface of the rubber ball, and the rubber ball having the color image on the outer surface is formed. The above is the color image placed on the ball table. The method, but has the following disadvantages: 1 'With the use of the ball, the color image will wear, degrade, and disappear. 2. Limited to rubber sheet or cellophane as image attachment material, the printing method is traditional screen printing, image analysis Degree and color printing are not, the festival is limited, the image quality is rough, not enough exquisite color is not bright enough, can not print similar (10) 〇 5 1364305 '• Wide!-------,: December 26, 100 revised replacement The image of the natural full-color quality above the resolution of the page is 3. The image and color will produce discontinuous disconnection and fault phenomenon with poor visual effect. 4. Rubber or leather bottom Color limits the vivid quality of color images. 5. Multi-color screen printing is more expensive. In order to improve the above shortcomings, some people have invented the color image layer in the middle of the outer layer of the eclipse, which improves the wear and tear. The problem with the rubber color is as in the US special spear j 5,320,34535; but its method is to print or transfer the color image to the outer surface of the rubber sheet and then the transparent rubber sheet (color image on the inner surface), covering The globular embryo, - from human opposed mold heating from the color image layer ® - a transparent protection sphere ball surface. Although this method improves the shortcomings of some traditional color image spheres, there are also many shortcomings that cannot be improved. 'There are the following disadvantages: Directly printing the color map on a transparent rubber sheet by screen printing method, it is impossible to obtain the current The resolution is at 30. More than a thousand paintings of similar quality: quality color images. Since the rubber sheet is difficult to automate printing or automated transfer, it is necessary to use manual-sheet-sheet printing, and the production cost is increased, especially in a state in which a plurality of colors and colors are required. Can not be printed on a large area or on the surface of the ball, so when the perspective of the ball is seen, in addition to the image, some of the transparent and non-printed places can look directly at the inner winding. 6 1364305 »^ December 26, revised the replacement page layer 'equivalent Rough and ugly. 4 practices must be complicated. SUMMARY OF THE INVENTION There is still a problem in the above-mentioned disclosed technology. The method for manufacturing a transparent color image sphere of the present invention solves the problem of using a spherical sphere, which is to be made into a transparent color image. Printing to handle the sinuous image' and not improving the number of images is the main purpose. The present invention is directed to the use of a porous film as a main body of printing to enable the porous film to be combined with a printing apparatus to form a color film that can be composited. This method can be used as a large amount of printing and has a higher number of turns. Demand. The structure of the present invention comprises: a combination of a balloon layer for inflation, a reinforcing layer for reinforcing the winding yarn, and a transparent layer for the outermost layer, wherein the color image is placed between the reinforcing layer and the transparent layer. And the method of manufacturing the color image is to select a multi-speaker key 睹r ―你夕! 夕札性溥膜 (or porous material)
為印刷之主體，將已印刷奸夕必AI |則野之衫色溥膜與透明層複合，形 成一複合層，此一複合薄ΜΙ/!** n r « » ，寻月其厚度在〇. 5〜3. 〇職之間，再 裁切此一複合層成為可拼基士七 1 研晏成球體外表之多片體，將此多 片的複合層枯貼於補強層之上 〈上，而複合層需視材料的不同 選擇硫化與否’如需進一步石样S由 7 &化交聯反應，則置於二半球 模具中硫化成形’即可完成且读aH Λ/ Α θ J凡驭具透明衫色圖像球體。 7 1364305 — ---- 100年12月26日修正替換頁 本發明之所以選擇多孔性薄膜，因其具多孔性的關係 可與橡膠、塑膠·、樹脂·、油墨粘劑等高分子物質具有優異· 的物理粘合力，因為高分子物質在加工過程中，可輕易的 滲入多孔性薄膜之孔隙中，待成型後形成粘鎖，並具優異 ' 的粘合力，而此種粘合力使球體各層之間，不致產生剝離 現象。 ^ 1.上述多孔性薄膜材料（或稱多孔性材質），其係以可以被 印刷之材質為主，如：紙（papers)、合成紙（synthetic papers)、纖維布織品（fiber)、塑膠料薄膜等，而塑膠For the main body of printing, the printed eclipse AI | the wild shirt color enamel film and transparent layer composite, forming a composite layer, this composite thin ΜΙ /! ** nr « », the thickness of the moon is in 〇. 5~3. Between the dereliction of duty, and then cut this composite layer into a multi-piece of the outer surface of the ball that can be spliced into the outer surface of the ball, and the multi-layer composite layer is pasted on the reinforcing layer. The composite layer needs to be vulcanized depending on the material. If further stone sample S is to be cross-linked by 7 & cross-linking reaction, it can be vulcanized in a two-hemisphere mold to complete and read aH Λ / Α θ J Cookware transparent shirt color image sphere. 7 1364305 — ---- December 26, 2014 Correction Replacement Page The reason why the porous film is selected in the present invention is that it has a porous relationship with a polymer material such as rubber, plastic, resin, or ink adhesive. Excellent physical adhesion, because the polymer material can easily penetrate into the pores of the porous film during processing, form a viscous lock after molding, and have excellent 'adhesive strength, and such adhesion The peeling phenomenon is not caused between the layers of the sphere. ^ 1. The above porous film material (or porous material), which is mainly made of materials that can be printed, such as: papers, synthetic papers, fiber, plastic materials Film, etc., and plastic
料薄膜泛指：聚乙稀（p〇1yethylene )、聚丙稀 (polypropylene ) > PET > TPU ( thermoplastic urethane ) . PVC ( poly vinyl chloride ) > TPE (ThermoplasticElastomer)等，當主材料經摻配各種 • ㈤材料後製做而& ’並得以印刷成彩色薄膜而言。 而印刷廣泛指的是平版印刷、凸版印刷、鍾射印刷或 噴墨印刷等自動化可完成之印刷方式，由於這一類的自動 =印刷可以得到_萬畫數以上的品質，並且可輕易印 t，這均為選擇多孔性薄膜主要之考量。 另圖像與透明層的複合方法可以依材料的不同，可分 已印刷完成 射出成型方法，直接將透明層材料射於 8 1364305 _________________ '·· 100年12月26日修正替換頁 之多孔性薄膜上，形成具有彩色圖像之彩色薄膜複合 層，此一複合層係一層透明層及一層多孔性薄膜；形 成二層結構；或者第一層為透明層，中間層多孔性薄 • 膜，底層可以是透明層或非透明層，形成如三明治之 三層結構。 二、 高週波成型方式，如透明材質以PVC或TPU等塑料薄 膜為主，則以高週波將透明層與彩色多孔性薄膜熔 合，形成具有彩色圖像之複合層；同上述可為二層或 三廣結構。 三、 押出成型方法，以平板加壓（plate press )或押延出 片機（Calender)，將多孔性薄膜經熱壓熔合多，形成具 有彩色圖像之複合層；同上述可為二層或三層結構。 上述複合方式雖因材質與複合設備的不同，仍可以達 成二層或三層的複合層結構。 上述透明層其材質可以是 PVC ( poly vinyl chloride ) 、 SBS ( styrene-butadiene-styrene copolymer ) 、 SIS ( styrene-Isoprene-styrene copolymer) 、 SEBS ( styrene-ethylene butylene styrene copolymer )、SEPS ( styrene-ethylene propylene styrene copolymer) 、 TPU ( thermoplastic polyurethane) 、 POE (poly olefin elastomer)、EPR (ethylene- propylene 9 1364305 --- 、Λ ../ 100年12月26日修正替換頁 rubber )、EPDM ( ethylene- propylene-diene rubber) ' BR ( butadiene' rubber ) ' SSBR ( solution styrene-butadiene rubber) ' IR ( Isoprene rubber) ' PUR ( poly urethane rubber)等，此透明層如需硫化，則在複合前可 加入過氧物或交聯劑樹脂當架橋劑或交聯劑，此過氧化物 (peroxide)可以是 DCP( di cumyl peroxide)、BP0( benzo peroxide)' MEKPO (methyl ethyl ketone peroxide) .... 等，添加量約在 0.卜8phr ( parts per hundred resin)。 藉由上述之說明，本發明確實可獲得功效’達成功效 如下列： 1.本發明由於先將多孔性薄膜先行印刷，其再與透明層複 合，達成3 0 0萬以上的畫數，因此可以得到絕佳的印刷 品質。 φ 2.本發明的印刷層在透明層内，可由最外表的透明層，直 視内部的彩色圖樣，使球體圖像立體化。 3.本發明的多孔性薄膜，可以自動化印刷生產，其與透明 層複合時，不虞有材質上的限制，適用範圍廣。 【實施方式】 明之 暸解； 本發明具透明彩色圖像球體之製造方法，採-較佳可行 之實施例’並配合圖式詳細說明於後，俾增加對本發 10 1364305 ；Λ _ .-t 100年12月26日修正替換頁 清參閱第一圖所示’其係習用球體製造流程圖：先選擇 内膽材料’經捏合機混合再出片，再將片體重疊多層（按： 個籃球為八片體所組合而成），並以橢圓形刀裁斷所需之 八片體，將該片體與片體間之邊緣熔合在一起，置入氣嘴 經充氣後呈一球形，再置入二半球模具中硫化成形，形成 内膽，並在内膽外表上纏繞紗線（預先浸好乳膠）形成加 •強層，加強層外表再加入橡膠片，再進一步置入二半球模 具中硫化，成形後即為傳統的橡膠球。 再叫參閱第二圖為本發明之彩色薄膜製作流程圖，其先 選擇多孔性薄媒材料，經由印刷形成彩色薄膜，此處所稱 彩色薄膜印刷」，特別指的是可利用自動化印刷設傷，大 量印刷而言。 再請參閱圖三，為本發明彩色薄膜與透明層之複合流程 圖’其複合方式因材質不同而有不同的作法，例如第一種 複合製作法為射出成型’需先將已印刷完成之彩色薄膜置 入射出成型模具中，經與塑料射出成型後，形成具 圖像之複合層’此複合層因屬手貼球，在後期製作是不^ 要硫化的透明複合層。 第二種高週波熔合製作法，其 入彩色薄膜，經高 作為透明層的材料，同樣加 選擇如或TPU薄膜等 週波炫合形 11 1364305 、夕 _ 100年12月26日修正替換頁 丨 , 成具有彩色圖像之複合層；與第一種複合製作法相同，其 複合後之複合層’將在最後流程中被貼於加強層之上形成 手貼球’屬於最後不需要硫化之透明複合層球種。 本發明第三種複合製作法’先經捏合機混煉後先行出 片’此一片體即為透明層再與彩色薄膜21，一起置入 平板加壓機或押延出片機，經上述設備複合成形後，成為 • 具有彩色圖像的複合層20,此處的複合層20最後是需要 再硫化的透明複合層橡膠球。圖三第四種複合方法為習用 方法’凊參考第一圖之說明。 再请參閱第四圖，係由第三圖的第一〜三種複合製作法 完成後之剖面圖，其中該複合層20如圖四Α為複合成三層 樣式，其有—透明層、一底層11以及中間為彩色薄膜 21所組合而成；而圖四B則為二層之結構，其為因應印刷 與球體效果則無底層11之設計，上述三種複合方法，均可 以將複σ層20的厚度製成介於〇·5〜3.0mm之間，因此複合 層20至少為二層以上，其至少包括一透明層10及一彩色 薄膜21所形成。 請參閱第五圖，在最後需硫化的球體製程中，在加強層 凡成後，加入由第三種複合製作法，所完成的具有彩色圖 像之複口層’其置入一半球模具中硫化，硫化後的球體表 12 1364305 100年12月26日修正替換頁 面有一球線溝，該球線溝具有定位及美觀之功能，最後再 一次硫化成為具有透明彩色圖像之橡膠.成品球。 而不需要硫化的球體製造流程’同樣在加強層完成 後，在球體外表覆上-層胎體層（硫化後俗稱中胎），該胎 體層經硫化後，形成有球線溝，並藉球線溝將球體區分成 8塊區域（較常見為8~12塊），再將已複合彩色薄膜與透 明層之複合層’用PU㈣貼上去即完成具有透明彩色圖像 之手貼成品球。 再請參閱第六圖，為根據第五圖之不需要硫化的球體 (即手貼球)’所完成之球體，面圖，其顯示整個球體之結 構’其除有球線溝m夕卜並可由A視圖中看出有一充氣 用之内膽球層“、一纏繞紗之加強層13、一胎體層心 及具彩色圖像的複合層20,其中 卉中該複合層20為透明層10 、底層11包覆著彩色薄膜21所構成之三層結構；而b視 圖中的複合層20僅透明層1G與彩色薄膜2ι二層社構。 第七圖其顯示具透明彩色圖像球體之立體圖，其將複 :層分別㈣於球體之上，使完成具透明彩色圖像球體， 由於彩色圖像破置入於透明層1〇内部， 除該彩色圖像不致 t虞，其由透明層1〇内部顯示出來的圖像更立體更 多π化。 由於該彩色 本發明具透明彩色圖像球體之製造方法 13 1364305The film generally refers to: polyethylene (p〇1yethylene), polypropylene (polypropylene) > PET > TPU (plastic urethane) . PVC (poly vinyl chloride ) > TPE (ThermoplasticElastomer), etc., when the main material is blended Various • (5) Materials are made and & 'and can be printed into a color film. Printing generally refers to automated printing methods such as lithography, letterpress printing, clock printing or inkjet printing. Because of this type of automatic printing, you can get more than _ 10,000 paintings and can easily print t. This is the main consideration for the selection of porous films. The composite method of the image and the transparent layer can be divided into printed and finished injection molding methods according to different materials, and the transparent layer material is directly injected on the porous film of the replacement page of 8 1364305 _________________ '·· December 26, 100 Forming a color film composite layer having a color image, the composite layer is a transparent layer and a porous film; forming a two-layer structure; or the first layer is a transparent layer, and the intermediate layer is porous; the bottom layer can be It is a transparent layer or a non-transparent layer, forming a three-layer structure such as a sandwich. Second, the high-frequency forming method, such as transparent material is mainly PVC or TPU plastic film, the high-frequency transparent layer and the color porous film are fused to form a composite layer with color images; the same as the above can be two-layer or Sanguang structure. Third, the extrusion molding method, using a plate press or a calender, the porous film is fused by hot pressing to form a composite layer having a color image; the same may be a second layer or Three-tier structure. Although the above composite method can achieve a two-layer or three-layer composite layer structure due to the difference between the material and the composite device. The transparent layer may be made of PVC (poly vinyl chloride), SBS (styrene-butadiene-styrene copolymer), SIS (styrene-Isoprene-styrene copolymer), SEBS (styrene-ethylene butylene styrene copolymer), SEPS (styrene-ethylene propylene) Styrene copolymer), TPU (plastic polyurethane), POE (poly olefin elastomer), EPR (ethylene propylene 9 1364305 ---, Λ .. / December 26, revised correction page rubber), EPDM (ethylene- propylene- Diene rubber) 'BR (butadiene' rubber ) ' SSBR ( solution styrene-butadiene rubber) ' IR ( Isoprene rubber) ' PUR ( poly urethane rubber), etc., if the transparent layer needs to be vulcanized, it can be added with peroxide before compounding. Or a crosslinking agent resin as a bridging agent or a crosslinking agent, the peroxide may be DCP (di cumyl peroxide), BP0 (benzo peroxide)' MEKPO (methyl ethyl ketone peroxide) ..., etc. About 0 phr (part per hundred resin). According to the above description, the present invention can surely obtain the efficacy's achievement as follows: 1. The present invention firstly prints the porous film, and then recombines with the transparent layer to achieve a drawing number of more than 300,000. Get great print quality. φ 2. The printed layer of the present invention is in the transparent layer, and the spherical image can be made stereoscopic by the outermost transparent layer and looking directly at the internal color pattern. 3. The porous film of the present invention can be produced by automated printing, and when it is combined with a transparent layer, there is no limitation on the material, and the application range is wide. [Embodiment] It is understood that the present invention has a method for manufacturing a transparent color image sphere, and a preferred and feasible embodiment is described in detail with reference to the figure, and 俾 is added to the present invention 10 1364305; Λ _ .-t 100 On December 26th, the revised replacement page is as shown in the first figure. 'The flow chart of the custom ball manufacturing process: first select the inner liner material' and mix it with the kneading machine to re-send the film, and then overlap the multi-layer (by: basketball) The eight pieces are combined, and the eight pieces required are cut by an elliptical knife, and the edge between the piece and the piece is fused together, and the gas nozzle is inflated to form a spherical shape, and then placed. The two hemisphere molds are vulcanized and formed into a liner, and the yarn is wound on the outer surface of the inner liner (pre-impregnated with latex) to form a strong layer, and the outer layer of the reinforcing layer is further added with a rubber sheet, and further placed in a two-hemisphere mold for vulcanization. After forming, it is a traditional rubber ball. Referring to the second figure, a flow chart of the color film production of the present invention is firstly selected from a porous thin material, and a color film is formed by printing, which is referred to herein as a color film printing. In terms of mass printing. Referring to FIG. 3 again, the composite flow chart of the color film and the transparent layer of the present invention has a different composite method depending on the material. For example, the first composite production method is injection molding, and the color that has been printed must be printed first. The film is placed in the molding die, and after being injection molded with the plastic, a composite layer having an image is formed. This composite layer is a transparent composite layer which is not vulcanized in the post-production because of the hand-applied ball. The second high-frequency fusion fusion method, which is incorporated into a color film, and which is high as a transparent layer material, is also selected such as a TPU film or the like, such as a TSU film 11 11364305, and an eve _ 100 December 26 revision replacement page 丨, A composite layer having a color image; as in the first composite fabrication method, the composite composite layer 'will be attached to the reinforcement layer in the final flow to form a hand-applied ball' Layer ball. The third composite production method of the present invention is firstly produced by kneading after kneading, and the piece is a transparent layer and then colored film 21, and placed together with a flat plate press or an ejecting machine, through the above device. After the composite molding, it becomes a composite layer 20 having a color image, and the composite layer 20 here is finally a transparent composite rubber ball which needs to be re-vulcanized. Figure 3 The fourth composite method is the conventional method 凊 reference to the description of the first figure. Referring to the fourth figure, the cross-sectional view is completed by the first to third composite fabrication methods of the third figure, wherein the composite layer 20 is composited into a three-layer pattern, which has a transparent layer and a bottom layer. 11 and the middle are combined with the color film 21; and FIG. 4B is a two-layer structure, which is designed without the bottom layer 11 in response to the printing and the sphere effect, and the above three composite methods can all form the complex σ layer 20 The thickness is made between 〇·5 and 3.0 mm, so that the composite layer 20 is at least two or more layers, and at least includes a transparent layer 10 and a color film 21. Please refer to the fifth figure. In the last ball system to be vulcanized, after the reinforcement layer is added, the third composite method is used to complete the multi-layered layer with color image, which is placed in the half-ball mold. Vulcanized, vulcanized spheres 12 1364305 On December 26, 100, the replacement page has a ball groove that has the function of positioning and aesthetics, and finally vulcanized into a rubber with a transparent color image. The finished ball. The ball manufacturing process that does not require vulcanization is also applied to the outer surface of the ball after the reinforcing layer is completed. The carcass layer is layered (the vulcanized layer is commonly called the middle tire). After the carcass layer is vulcanized, a ball line groove is formed, and the ball line is formed. The groove divides the sphere into 8 regions (more commonly 8 to 12 blocks), and then pastes the composite layer of the composite color film and the transparent layer with PU (4) to complete the finished ball with transparent color image. Please refer to the sixth figure again, which is a sphere completed by the sphere (not hand-ball) which is not required to be vulcanized according to the fifth figure, which shows the structure of the entire sphere. It can be seen from the A view that there is a balloon layer for inflation, a reinforcing layer 13 for winding the yarn, a carcass layer core and a composite layer 20 with a color image, wherein the composite layer 20 is a transparent layer 10 The bottom layer 11 is covered with a three-layer structure composed of the color film 21; and the composite layer 20 in the b view is only a transparent layer 1G and a color film 2 ι. The seventh figure shows a perspective view of a transparent color image sphere. It will be complexed: the layers are respectively (4) on the sphere, so that the transparent color image sphere is completed, and the color image is broken into the transparent layer 1〇, except that the color image is not t虞, and the transparent layer is The image displayed inside is more stereoscopic and more π. Due to the color, the method of manufacturing the transparent color image sphere of the present invention 13 1364305
薄膜可利用自動化印刷設備，印刷在多孔性薄膜之上並且 達成300萬畫數以上之圖像品質，有效提高生產量、高品 質之圖像球體；其應用之手段與方法更是前所未見，已具 進步〖生及產業上利用價值’完全符合發明專利之要件;惟、 ::料者，僅為本創作之-較佳實施範例，當不能以之 作為限定本創作實施 範圍，凡依本發明申請專利範圍所 W之均等變化修拙 . ’仍應屬本發明專利涵蓋之範圍内。 1364305 _ ···- 100年12月26日修正替換頁 【圖式簡單說明】 第一圖：為習用球體之製造流程圖。 第二圖：為本發明多孔性薄膜成形製造流程圖。 第三圖：為本發明案複合層製作流程圖。 第四圖：為本發明案複合層剖面圖。 第五圖：為本發明案球體製造製造流程圖。 第六圖：為本發明案球體斷面圖。 • 第七圖：為本發明案球體立體圖。 【主要元件符號說明】 1 球體 10 透明層 11 底層 12 胎體層 13 加強層 14 内膽球層 101 球線溝 20 複合層 21 彩色薄膜 201 彩色圖像 15The film can be printed on the porous film by using automatic printing equipment and achieves image quality of more than 3 million paintings, effectively increasing the production volume and high quality image sphere; the application methods and methods are unprecedented. , has made progress 〖Life and industrial use value' is in full compliance with the requirements of the invention patent; only, :: material, only for this creation - the preferred embodiment, when it can not be used as a limit to the scope of this creative implementation, Fanyi Modifications to the equivalent variations of the scope of the invention are still within the scope of the invention. 1364305 _ ···- December 26, 100 revised replacement page [Simple description of the diagram] The first picture: the flow chart for the production of the custom sphere. Second: A flow chart for forming a porous film of the present invention. The third figure is a flow chart for making the composite layer of the invention. Figure 4: A cross-sectional view of the composite layer of the present invention. Fig. 5 is a flow chart showing the manufacturing process of the sphere of the present invention. Figure 6 is a cross-sectional view of the sphere of the present invention. • Figure 7: A perspective view of the sphere of the present invention. [Main component symbol description] 1 sphere 10 transparent layer 11 bottom layer 12 carcass layer 13 reinforcement layer 14 inner spherical layer 101 ball groove 20 composite layer 21 color film 201 color image 15