TWI359959B - Color filter, adjust method of photo-sensitive res - Google Patents

Description

[1359959 IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to a color (image) display technique of a machine using a color filter such as a color liquid crystal display device. [Prior Art] In a color liquid crystal display device or the like, color (image) display is usually performed using a color filter (c〇1〇r filter). The color filter is usually produced by forming a three-color colored transparent fine pattern (referred to as a pixel) on a transparent substrate such as glass or an opaque substrate such as tantalum. The three primary colors of the above three colors are mainly red (R), green (G), and blue (B). ^ In the liquid crystal display device, the liquid crystal will color the color of one of the pair of polarizing plates by coloring the color filters of the three primary color pixels to reproduce various colors (images), and the light is maximized in all the pixels. In the case of transmission (display white) to the case where the light is minimized in all pixels (black is displayed), various colors are reproduced. In such a liquid crystal display device, in order to improve the power consumption, it is required to increase the luminance of the color filter when white is displayed, and it is required to improve the color reproducibility without lowering the luminance. Therefore, for example, various improvements are made to the resin composition of the pixels of the respective colors for forming the color filter. For example, a radiation sensitive linear resin composition for a blue color filter that sufficiently increases the stimulus value γ (luminance) when white is displayed has been developed, and even if the blue composition is used, the color reproduction range is improved. The pigment concentration can also prevent the luminance of the liquid crystal display device from being lowered (for example, refer to JP-A-2001-147315 (page 2, column 2, line 2 to page 3, right column, line 14)). In addition, a green color filter coating material 315918 5 1359959 which improves the light transmittance in the visible light range has been developed. When the green composition is used, the color reproducibility and brightness of the liquid crystal display device can be improved. (For example, refer to JP-A-1 (M60928 (2nd page, 2nd row to 2nd row, 2nd row), p, 'The average particle size of pigment + is adjusted to the color filter for a given range' The right composition can improve the transmittance and contrast (for example, 'Ref., JP-A-9-197118 (2nd page, left bank, 2nd row to 3rd page, left bank, 35th line)). In addition, color filters need to be improved, for example, JP-A-2001-272523 (page 2, left bank, second row to page 3, left bank, line 9 reveals improvement in transmittance of red, blue, and green pixels). For color filters with color purity, low-consumption power and high color reproduction can be achieved by using this filter. In addition, JP-A-2001_116918 (page 2, left column, line 2 to right-hand, page 27) Revealing the transmission of red pixels and the transmission of green pixels Adjusting the color filter in the specified range can improve the light transmission (displaying the color temperature of white. Φ [Invention] The required characteristics of the liquid crystal display device are not limited to the brightness when displaying white as described above (or white) Color temperature), color reproducibility. In other words, the small deviation of the chromaticity from white to black is also important. This characteristic cannot be displayed only from the display characteristics of any point from white to black. The evaluation is based on the full evaluation of the technology related to the structure of the liquid crystal display device and the technology related to the characteristics of the driving circuit, for example, adjustment by a polarizing film or subtle adjustment of each color pixel. However, the adjustment by the polarizing film is lowered. The contrast of the liquid crystal display device, and the subtle adjustment of each pixel 315918 6 1359959 is extremely cumbersome.

In view of the above, the object (4) provides a technique for reducing the adjustment of the polarizing film or the adjustment of each pixel in the liquid migration display device. The present inventors have made further research results in order to solve the above problems. The big difference from the previous display from the display white i _ white to the black is to reduce the chromaticity shift can only depend on the adjustment of the polarized light in the liquid crystal display device or the like: the common sense of adjustment 'successfully The present invention has been completed. In other words, the three photosensitive resin groups having different colors satisfy the specific conditions to make the balance between the resin compositions appropriate. If the color filter is produced by using three photosensitive resin compositions (groups), the liquid crystal display can be lightened. Adjustment of the polarizing film or adjustment of pixels of each color in the device. The color filter of the present invention has a gradation resin composition film 'a second color resin composition film and a color filter of a third color resin composition film'. The color filter satisfies the following requirements. That is, the resin film of each color of the color filter is sandwiched between a pair of polarizing plates, and is orthogonal to each other when the polarization axes of the polarizing plates are parallel to each other (〇rth〇g〇nal) In the case where the tristimulus values "χ, γ, ζ" of the CIE (International Commission on Illumination) 1931 color system are measured for the resin composition film of each color, the white coordinates (u'white, v) are calculated by the following formula. 'white) and display black coordinates (u'black, v'b丨ack) at coordinates PJO.IS' 0.52), coordinates Q] (〇.25, 0.52), coordinates R (0.23, 0.42), coordinates S The four coordinates of (0.15, 0.42) are within the straight line range. U white — 4Xwhite/(Xwhite+ 1 5 Ywhite + 3ZWhite) v white = 9Ywhite,(X'vhite+l 5Ywhite +3ZWhite) 7 315918 1359959 U black-4Xblack/(Xblack+l 5Yblack + 3Zb) ack) V black 9Yb] Ack/(Xblack+15YbIack + 3Zblack) where 'Xwhite, Ywhite, Zwhite, Xblack, Yblack, Zbiack system ・ The value obtained by the following formula. * Xwhite_(Xl,paralIel + X2,parallel + X3,parallel)/3 -v Ywhite-(Yl,parallel + Y2,parallel + Y3,parallel)/3 - Zwhite (Z],para"ei+Z2,para] Iei+ Z3, paraiiei)/3

Xblack (X1,〇rthogonal+X2,orthogonal+X3, orth ogonal )/3

Yblack (Y), orthogonal+Y2, orthog〇nal + Y3, orthogonaI)/3

Zblack (Zi, orth〇g〇nal+Z2,〇rthogonal+Z3〇rth〇g〇naI)/3 In the formula, "Xl, parallel, Yl parane丨, Z], paranei" will be the first color The resin composition film is sandwiched between the three stimuli values "Χ, γ, ζ" of the transmitted light when the polarizing axes are parallel to each other, and the three-wavelength light source shown in Fig. 1 is used as a backlight (back light). The result of the measurement. "X2, para丨le丨, Y2, paralIeI, Z2, para丨丨el" and "Χ3 ρ_]Η, Y3 paranei, # Z3,para丨丨el" indicate the second color resin composition when the polarization axes are parallel to each other The tristimulus values Γ γ, γ, and z of the film and the third color resin composition film were measured in the same manner as in the case of the first color. Γ X Y , 1 ^orthogonal Y 1,orthogonal

Zl.orthogona] J ' Γ X2,orthogonal ' Y2,orthogonal ' Z29〇rthog〇nal j ^ X3,〇"h〇g〇nai, Y3,orthogonal,z3,orthogonal" means that the polarization axes are orthogonal to each other, The tristimulus values γχ, γ, and z′ of the first-color resin composition film, the second color resin composition film, and the third color resin composition film were measured in the same manner as described above. With this color filter, the balance between white and black is displayed properly. From 315918 8 1359959, white to black shows a decrease in chromaticity deviation, which can reduce the adjustment of the polarizing film in the liquid crystal display and each color pixel. Adjustment. Here, if the chromaticity coordinate of the standard light c developed by the CIE (International Commission on Illumination) is (11'(:, '〇), the distance between the coordinates of the following equation is dc=[(u,c-u'white) ) 2+(v,c_v,white)2]〇.5+ [(u,c· The following is better. Also, if the CIE (International Commission on Illumination) has a standard light Dm with a chromaticity coordinate (U'D65) , V' DM), by the following formula, the distance between coordinates dD65 = [(uWu, white) 2 + (vWv, white) 2],, u'D65-u'b丨- 尸+卜' plus ^^ ^丨...It is better to calculate the coordinate spacing of the coordinates of 60x 10·3 or less. 'c Also, the standard light (3) developed by CJE (International Commission on Illumination) has a reciprocal color temperature of RC 'corresponding to the white coordinate π displayed. -, the reciprocal correlation color temperature is Rwhite, corresponding to the black coordinate Ο, -, V, and the reciprocal correlation color temperature is the Japanese temple, which satisfies (|Rwhite-R<

Rblack-Rc | j^OMK·1 is better. Also, the reciprocal color temperature of the standard aperture 65 developed by CIE (International Commission on Illumination) is RD65 'corresponding to the reciprocal color temperature of the white coordinates (u, —, V, *), which corresponds to the display black. The reciprocal color temperature of the coordinates (u, black, V'buck) is R 眭,, Ge? M p 〇 1 > 丨咐 ’ 'satisfaction (| Rwhite_RD65 I + I Rb] ack_RD65 | ) S9 〇 MK.] is 4 soil. By these, the chromaticity deviation becomes small.

Also 'will be X], parallel, γ K - seven enough, A LParaHei'ZhparaUdm set the first color 315918 9 1359959 the color of the private, by X2, paraile丨, Y2 para丨丨e丨, Z2, para丨] e The chromaticity coordinate of the second color determined by X3, paraUe丨, Y3, paraUd, Z3, para丨w is the chromaticity coordinate of the third color on the UCS chromaticity diagram of CIE 1976. - The area of the triangle is formed, and the area of the triangle is preferably 70 to 21 5% of the area of the triangle formed by calibrating the chromaticity coordinates of NTSC to the ucs color map. Thereby, a display with high color reproducibility can be realized. "one φ and 'this shirt color filter, showing the white coordinates (u, white, v, white) to the black coordinates (u'b丨ack, v, bIack) and the black body trajectory (blackbodylocus ) A slightly parallel is better. Also, the color temperature of the black color (u, biack, v, biack) in the color filter is preferably 5000K or more and 25000K or less. Further, it is preferable that at least one of the resin composition film of the first color resin composition film and the second color resin composition film contains a coloring pigment. In this case, in addition to the coloring pigment, it is more preferable to further contain a filler pigment (extender φ Pigment). In addition, at least one of the resin composition film of the first color resin composition film, the second color resin composition film, and the third color resin composition film preferably contains a component that emits fluorescence. Further, the method of adjusting the photosensitive resin composition group for a color filter of the present invention is a color having a first color photosensitive resin composition, a second color photosensitive resin* composition, and a third color photosensitive resin composition. The calendering sheet is made of a photosensitive tree, and the method for adjusting the composition of the composition comprises the steps of: forming a film of each color photosensitive resin into a film to obtain a film forming step of each color resin composition film; 3J59I8 1359959 The film is sandwiched between a pair of polarizing plates, and the tristimulus values of the CIE (International Commission on Illumination) 1931 color system are measured in the resin film of each color in the case where the polarizing axes of the polarizing plates are parallel to each other. The measurement procedure of "X, Y, Z"; the chromaticity acquisition step of displaying the white coordinate (u white 'V white) and the black coordinate (u'b) ack, v'b ack) by the following formula; at least adjustment One of the components of the photosensitive resin composition does not change the chromaticity coordinate of the first color, the chromaticity coordinate of the second color, and the chromaticity coordinate of the third color to reduce the distance between the white coordinate and the black coordinate. The whole procedure. U white -4Xwhite/(Xwhite+ 15Ywhite + 3Zwhite) V white_9Ywhite/(Xwhite+l SYwhite + SZwhite) U black -4Xbiack/(Xblack+l 5 Yblack+3Zbiack) v biack=9Yblack/(Xblack+15Yb]ack+3Zblack) In the formula, 'Xwhite, Ywhite, Zwhite, Xblack, Yb】ack, Zb, and ack are values obtained by the following formula.

Xwhite-(Xl.paral ]e] + X2, parallel+ X3,paraIIe I )/3

Ywhite-(Yl,parallel + Y2,parallel + Y3,para"el)/3 Zwhite —(Z],para]iei + Z2,para]ie] + Z3,para]]e])/3

Xblack-(X],orthogonal + X2, orthog〇naI","X3, orthogonal )/3

Yblack = (Yl,orthogonal+Y2, orthog〇nal+Y3,orthogonal)/3 Zblack_(^l)orthogonal + Z2s〇rth〇g〇na]+Z3j0rth〇g〇nai)/3 where 'Xl,para 】lel, Y], paraIIel, Ziparand", when the first color resin composition film is sandwiched between one pair of polarizing plates and the polarizing plate is parallel to each other, the third stimulus value "X, Y, Z" of the transmitted light is used in Fig. 1 The three-wavelength tube light 11 315918 1359959 source shown is the result of measurement at the time of backlight measurement. "X2 parailei, Y2 parallei, Z2, para"elJ and "X3,para"e丨,Y3 para丨丨e丨,Z3,parallel" indicate the second color resin composition film and the second when the polarization is parallel to each other. The diacoustic value "X, γ, Z" of the three-color resin composition film is the same as the above-described first color - the values of 疋 and *. "Xl, 〇rthogonal, Y], 〇rth〇g〇nal, Z], orthogona]", ', Y2, 〇rth〇g〇nal, Z2, 〇rthogonal", "X3, orthogonaI, -Y3, orth〇 When g偏nal and Z3orth〇g()na丨” indicate that the polarization axes are orthogonal to each other, the third stimulus value of the i-th color resin composition film, the second color resin composition film, and the third color resin composition film “X” γ, z" are values measured in the same manner as described above. When the film is formed by this adjustment method, the photosensitive resin composition of the photosensitive resin composition can be easily adjusted to form a combination of the photosensitive resin compositions of the color light-emitting sheet of the above invention. The five-week method of the photosensitive resin composition group for other color filters according to the present invention is a color enamel having a first color photosensitive resin composition, a second color photosensitive resin composition, and a third color photosensitive resin composition. The method for adjusting the photosensitive resin composition of the light sheet comprises at least a film forming step, a measuring step, a comparison obtaining step, and an adjusting step. In the 'film step', the photosensitive resin of each color is kneaded and the resultant is formed into a film to obtain a film of each color resin composition. In the measurement step, the resin composition film is sandwiched between a pair of polarizing plates, and the CIE (International Commission on Illumination) 1931 table is measured for each resin composition film when the polarizing axes of the polarizing plates are parallel to each other and are orthogonal to each other. γ within the stimulus value of the color system. 315918 12 1359959 In the comparison obtaining step, the comparison of the films of the respective resin compositions was obtained by the following formula: D, 1, D, 2, τ3. T1~YlsparaJJej/Yi>0rth〇g〇nal ^2~^2>Para,orthogonal T3-Y3,para]lei/Y3,〇rth〇g〇nal where 'Yl'parallel means the first color resin composition When the film is sandwiched between the polarizing plates and the polarizing plate, the γ in the three-stimulus value of the transmitted light is measured by using the three-wavelength tube light source shown in Fig. 1 as the backlight. The measurement results are Y2, paralle丨 and Y3. When the paralie 表示 indicates that the polarized light is parallel to each other, the Y in the tristimulus values of the second color resin composition film and the third color resin composition film is measured in the same manner as in the case of the first color.

Yl, 〇rthog_l, Y2, 0rth0g_丨, Y3, 〇rth〇g〇nal, when the polarization axes are orthogonal to each other, the first color resin composition film, the second color resin composition film, and the third color resin composition film The value of Y in the third stimulation value is measured in the same manner as the above-described parallel. In the adjusting step, at least the composition of any one of the photosensitive resin compositions is adjusted without changing the chromaticity coordinates of the first color, the chromaticity coordinates of the second color, and the chromaticity coordinates of the third color to enhance the composition of each resin The balance of contrast. When the film is formed by this adjustment method, the photosensitive resin composition of the photosensitive resin composition can be easily adjusted to become a combination of photosensitive resin compositions which can form the color light-sensitive film as described above. Preferably, for example, when the photosensitive resin composition corresponding to the film of the lowest comparative resin composition in each resin composition film contains a coloring pigment, the average particle diameter of the coloring pigment can be reduced. Further, for example, when the resin corresponding to the highest contrast in the film of each resin composition is used, and the photosensitive resin composition of the film of the composition contains a coloring pigment, the average particle diameter of the coloring pigment can be increased. Further, for example, when the photosensitive resin composition corresponding to the highest contrast resin composition film in each resin composition film contains a coloring pigment, the photosensitive resin composition containing the colored 'pigment' may be further added with a filler pigment. Further, for example, a photosensitive resin composition corresponding to the highest contrast resin group in each resin composition may be further added with a fluorescent component. The photosensitive resin composition group of the present invention is composed of a first color photosensitive resin composition, a second color photosensitive resin composition, and a third color photosensitive resin composition, and is combined with each other as a filter to transmit light. The color image can be displayed, and the gist of the sigma photosensitive resin composition group has the following characteristics (1). Characteristics (1) The photosensitive resin compositions of the respective colors are separately formed into a film and sandwiched between a pair of polarizing plates, and the CIE (International Illumination) is measured on the films of the respective colors in the case where the polarization axes of the polarizing plates are parallel to each other. Committee) When the three stimulus values "X, Y, Z" of the 1931 color system are expressed by the following formula, the white coordinates (U white, V white) and the black coordinates (U black, V black) are displayed at coordinates. P] (0.l8, 0.52), coordinates QU0.25, 0.52), coordinates R] (〇.23, 0.42), coordinates SJ0.15, 0.42) are within the straight line connecting the four coordinates. U white- 4X\vhiie/(Xwhite +1 5 Ywhhe + SZwhite) V white"" 9 Ywhite/(X\vhite + l 5 Ywhjte + 3Zwhite) U black_ 4XbIack/(Xblack+l 5 Yblack + SZbiack) 3) 5918 1359959 V black- 9Yblack/(Xbl ack + 1 5 Yb]ack + 3Zb] ack) where Xwhite, Ywhite, Zwhite, Xblack Yblack Zblack are values obtained by the following formula.

Xwhite-(X ],paral]el + X2,paraIIel + X3,parallel)/3 Ywhite_(Y],paralle] + Y2,parallel + Y3,parallel)/3 Zwhite_(Z),parauei+Z2,parallel + Z3 ,parallel)/3

Xblacke(-^l,〇rthogona]~^^2,orthogonal^~^-35orthogonal)/3 Yblack_(Y],〇rthogonal + Y2,orthogonal + Y3, orthogonal )/3 Zblack (^lsorthogonaI^~^2, Orthogonal~^^39orthogonal)/3 where 'X】, parallel, Yl, para]Iel, Z], para]]ei" will be the first color

When the film is sandwiched between the polarizing plates and the polarizing plates, the three stimuli values "X, Y, Z" of the transmitted light are measured using the three-wavelength tube light source shown in Fig. 1 as the back light source. "X2, para丨丨e丨, Y2parane丨, Z2paraneIJ, and "X3, para丨丨el, Y3para丨丨e丨, Z3para丨丨e丨" indicate the film of the second color and the third color when the polarization axes are parallel to each other. The value of the tristimulus value "χ, γ, ζ" of the film measured in the same manner as the first color described above. "Χι.灿.pul,

Yl orthogonal > Z,)〇rth〇g〇na] , ^ , Y2 〇rth〇g〇na] χ 2'〇rthog_l" X3 〇rth〇g〇nal, Y3 〇rth〇g〇nai, indicating the polarization axis When the particles are orthogonal to each other, the tristimulus values "X, Y, and z" of the film of the first color, the film of the second color, and the film of the third color are measured in the same manner as the above-described parallel. In the case of CIE (International Photo C, v'c), the chromaticity coordinates of the standard light c determined by the 'Photosensitive Resin Composition of the Invention, Ming Committee' are as follows (u, 315918 15 1359959 coordinates) The distance between the two is _[(110-11;^"6)+('^'.-'\^,)1))2].'5 + [(11'.-11'1>_)2+ Bu '^'1^(;){)2](), 5 calculated distance between coordinates (^ is 75 parent 1 〇 · 3 or less is better. , - Again, this photosensitive resin composition group, to CIE ( The International Commission on Illumination) determines the chromaticity coordinate of the standard light Du as (u' D65, V' DM), which is represented by the following equation: the distance between coordinates dD65 = [(U'D65-U'white) 2 + (v'D65 -V'white)2]0-5 + [( U'D65-U'b丨ack)2+(v'D65-v'b丨ack)2]0·5 Calculated the distance between coordinates dD65 is 60x 10 ·3 or less is preferable. Further, the reciprocal color temperature of the standard light C determined by CIE (International Commission on Illumination) is Rc, which corresponds to the reciprocal color temperature of the white coordinate (u white 'V white). For Rwhite, the reciprocal correlation color temperature corresponding to the display black coordinate (U'bIack, Vbiack) is & Rwhite-Rc | + | Rb】ack-Rc | )$90ΜΚ-] is better. Also, the photosensitive resin composition is C〇 (International Commission on Illumination), and the reciprocal color temperature of the standard light Dm is R〇65. Corresponding to the color of the reciprocal correlation color of the white φ color coordinate (u'white 'v'white), corresponding to the reciprocal color temperature of the black square (U black, V'biack) is Rb 丨 k Satisfied (丨Rwhite-RD65 | + 丨Rblack-RD65 | B90MK-, preferably. This photosensitive resin composition group will be composed of x], pai^M,

Yl, paralle丨, Ziparane] The chromaticity coordinate of the first color, the chromaticity coordinate of the second color determined by X /, m Λ25ρ3Γ3ΐJe] % Y2,paralle], Z2,paralle丨 and X3,para丨lei , Y3, parajle丨, Z3, para丨丨e丨 The chromaticity coordinates of the third color are determined as the area of the triangle on the UCS chromaticity diagram of CIE 1976. The area of the triangle is relative to NTSC. The chromaticity coordinate of RGB is calibrated at 315918 16 1359959. The UCS color circle on the aforementioned UCS color circle is preferably 70 to 215%. * Further, the photosensitive resin composition group of the present invention preferably exhibits a white mark (U'_e 'v'white) to a display color black coordinate (u, _, v, _), and a black body trajectory Parallel is better, and the relative color temperature of Ba A .., · negative non-black coordinates (U, black, v, b, ack) is preferably 5000K or more and 25000K or less. At least one photosensitive tree of the j-th resin composition film, the second color resin composition film, and the third color resin composition film of the photosensitive resin composition group agent, which is determined as a photosensitive tree residue (four) Displaying the white ticket (U':hite, v'whhe) and displaying the black coordinate to show the above characteristic (1)' is better to adjust the coloring pigment such as 'can be adjusted by matching the adjusted average particle size The pigment finishing coloring material 'adjustable coloring material by combining the coloring material and the filling material' can adjust the coloring material by using the coloring material and the fluorescent component in combination. Further, in the photosensitive resin composition composition for the color filter, at least one photosensitive resin of the photosensitive resin composition of the i-th color, the green resin composition film of the 帛2 color, and the photosensitive resin composition film of the second color The composition preferably contains a coloring pigment. At this time, the photosensitive resin composition may further contain a filling pigment. And the composition of the photosensitive resin composition of the filter, the photosensitive resin composition film of the second color photosensitive resin composition film, the second color photosensitive resin composition film, and the third color photosensitive resin composition film are composed of at least one photosensitive resin. It is preferred that the substance contains a fluorescent component. The present invention includes a pattern obtained by sequentially developing a photosensitive composition of the first, second, and third colors, 315918 1359959, on a substrate in an arbitrary order, a color filter including the pattern, and the color The liquid crystal display of the filter is ''device. Hereinafter, the present invention will be described by taking the three primary color photosensitive resin compositions and the composition of the blue photosensitive resin composition, the blue photosensitive resin composition, and the blue photosensitive resin composition as an example, but the photosensitive resin of the present invention. The composition group is not limited to those of the three primary colors. That is, the color matching system of cyan (10) (2), magema, yellow, etc., and the color switching based on the 3 primary colors or the complementary color system are also included in the present invention. The color filter has a plurality of resin composition films (described later in detail), and the resin composition films are prepared by separately forming each photosensitive resin composition in the photosensitive resin composition group for color filters as follows. The color filter is a photosensitive resin composition group which is used to display a color image by combining light transmitted as a filter, for example, a red color photosensitive resin composition (photo: photosensitive light) a resin composition), a green photosensitive resin composition (a second color (four) resin composition), and a blue photosensitive resin composition (a third color photosensitive resin composition). Moreover, the photosensitive resin composition composition It satisfies the characteristics of the following (1). Further, the photosensitive resin composition agent preferably has any of the characteristics of (2) to (8) in addition to the characteristics of (1), or satisfies the characteristics of any combination of the above. Characteristic (1) The photosensitive resin compositions of the respective colors are separately formed into a pair of polarizing plates, and are orthogonal to each other when the polarizing axes of the polarizing plates are parallel to each other. 315918 1359959 If this characteristic (8) is provided, A color display device such as a liquid crystal television display having excellent reproducibility. The photosensitive resin composition group (red type, photosensitive resin composition, green type photosensitive resin composition, and blue type) which exhibits the above characteristics (1) to (8). The photosensitive resin composition is prepared by combining the coloring materials of at least one photosensitive resin composition and the like, and adjusting the remaining photosensitive resin composition in combination. Specifically, for example, the film-forming photosensitive resin composition is colored. In the resin composition film, the resin composition film is sandwiched between a pair of polarizing plates, and the polarization axes of the polarizing plates are parallel to each other and orthogonal to each other, and CIE is determined for each color/resin composition film (International Lighting Commission 931 color system) The third stimulus value "χ, γ, ζ" is obtained by the above formula showing the white coordinates (u, whhe, v, white) and the black coordinates (u, black, v, b) ack). It is necessary to change the red chromaticity coordinates (chromaticity) corresponding to the work color, the green chromaticity coordinate (chroma) of the second color, and the blue chromaticity coordinate (chroma) of the third color to shorten the display of white coordinates and display. It is preferable to adjust the composition of at least one of the photosensitive resin compositions by the distance of the black coordinates. The chromaticity coordinates are determined in the same manner as the characteristics (8). The method of adjusting the icing is not particularly limited, and for example, changing the coloring pigment The type 'changes the blending ratio of the coloring pigments, etc. It is also suitable to be adjusted by the following method. Specifically, the adjusting method includes a film forming step, a measuring step, a comparison obtaining step, and an adjusting step. The film forming step will have the first step. Color photosensitive resin composition 'The second color photosensitive resin composition and the color filter photosensitive resin composition of the third color photosensitive resin composition The photosensitive resin composition of each color is formed into a film to obtain a film of each color resin composition. 3] 5918 25 1359959 In the measuring step, the resin composition film is inflamed in a pair of polarizing plates, respectively, and in the case where the polarizing axes of the polarizing plates are parallel to each other and in the case of being orthogonal to each other, the CIE is determined in each color resin composition film. (International Commission on Illumination) 1931 The color of the three stimulus values "X, Y, Z". Comparison of the steps taken in the comparison step for each resin composition film

Tred, Tg reen, Tb] ue by the subtype red, orthogonal

Tred — Yred,paralle|/Y

Tgreen Ygreen, parallel/Ygreen, orthogona] Tbl ue Ybl ue, paral 】el/Ybl ue,orthogonal. Finally, in the 'adjustment step', it is not necessary to change the red chromaticity coordinates (chroma) corresponding to the first color, the green chromaticity coordinates (chroma) of the second color, and the blue chromaticity coordinates (chroma) of the third color. The compositional adjustment of at least any of the photosensitive resin compositions is carried out by increasing the contrast balance between the films of the respective resin compositions. The chromaticity coordinate characteristics are determined in the same manner as in (8). Specifically, for example, the s of the coloring material in the photosensitive resin composition, the addition of the filler to the photosensitive resin composition, and the addition of the fluorescing component to the photosensitive resin composition. More specifically, for example, after adjusting the coloring material of at least one photosensitive resin composition X to exhibit the above characteristics (丨), at least one photosensitive resin composition is adjusted as necessary for the characteristics of display characteristics (2) to (8). γ colored material. The photosensitive resin composition 4 of the object to be adjusted may be the same as or different from the photosensitive resin composition γ. The specific (four) color material adjustment method can be various, and is not particularly 315918 26 1359959 The particle size of the filler pigment can be selected from the particle size causing the degree of scattering of the rice, for example, when combined with the green series composition, The range of 1 〇〇 nma (preferably 150 nm or more, more preferably 2 〇〇 nm or more), and 40 〇 nm or less (preferably 30 〇 nm or less, more preferably 28 〇 nm or less) is selected. The blending amount of the filler pigment can be appropriately set according to any one of the composition characteristics (丨) to (8), or whether the particle diameter is adjusted, whether or not the fluorescing component is used, the particle diameter of the filler pigment, and the like, and the pigment is filled. The blending amount is 10 parts by mass of the solid content in the resin composition, and is, for example, selected from the range of 〇〇丨〇乂 or more (preferably 0.015% or more, more preferably 0.02% or more). Further, if the amount of the filler pigment is too large, the overall contrast as a color filter is remarkably lowered. Therefore, it is recommended that the balance between the resin compositions (between pixels) and the entire color filter as a color filter can coexist. Next, set the upper limit of the filling pigment. The blending amount of the filler pigment is such that the solid content in the resin composition is 100 parts by weight, such as 〇 1% or less (more preferably 0.08% or less, more preferably 05% or less). In addition, as the filler pigment, a known photosensitive resin composition can be used, for example, an inorganic pigment which will be described later (a fluorescent component such as alumina or titania), and a photosensitive resin composition for the purpose of improving the contrast. The composition does not use the fluorescing component, but a contrast balance can be obtained by using the fluorescing component. Specifically, for example, for the light-resin composition corresponding to the highest contrast film, a fluorescing can be added. Thus, the contrast of the resin composition film formed by forming the photosensitive resin composition is lowered, and the contrast balance between the films can be obtained. ' 315918 29 1359959 As a component of fluorescing light, for example, fluorescent light A pigment, a fluorescent dye, etc. A pigment type or a resin type can be used as the fluorescent pigment, and as the pigment type, an azo (pigment) pigment pigment or a phthalocyanine system can be selected. Anthraquinone pigment pigment, quinophthalone (quinacri (Jn^ pigment pigment, isoindolinone pigment pigment, thi〇indig〇 pigment pigment, (Perylene) is a pigment pigment or a dioxazine dye pigment (more preferably an azo pigment pigment or an isoindole ketone pigment pigment). A pigment type preferred fluorescent pigment is CIpigment yellow. -139, 185, etc. As the resin type, those in which a fluorescent pigment is dispersed or dissolved in a resin matrix can be used. 'The thermosetting resin is, for example, a urea resin, a melamine resin, a benzoguanamine resin, Acrylic resin, vaporized vinyl resin, alkyd resin, allyl maple resin, phenol resin, etc. The preferred resin type fluorescent pigment is a compound in which a fluorescent dye is dissolved in a matrix of a thermosetting resin. The camping dyes are, for example, rhonamine B, rhodamine 6G, xanthene pigments, anal dicyaninyl-2-methyl winter (p-dimethylamino) Cyanine dye, such as styryl)·4Η_pyran (CMD), ethenyl-2-(4_(p-didecylaminophenyl)-, 3-butadienyl) 3⁄4-pyridinium a high-acid salt (D-pyridyl 1) pyridine-based dye, oxazine-based pigment, 1,2-cracked phenanthrene ( Chrysene) pigment, thioflavin, pigment, perylene pigment, pyrene pigment, anthracene pigment, acridone pigment, acridine ) pigment, fluorene dye, terphenyl pigment, ethene pigment, butaene pigment, hexane 30 315918

A 1359959 hexatriene 糸 pigment, chewing 坐 sitting (〇xazo)e) pigment, coumarin pigment, stiibene pigment, di- and triphenylmethane pigment, thiazole (thiazole) is a dye, a thiazine dye, a naphthalimid dye, an anthraquinone dye, or the like. Among them, preferred fluorescent dyes are rhodium-based dyes such as rhodamine B and rhodamine 6G, coumarin dyes, and naphthalene diimine pigments. The blending amount of the component to be fluorescent can be appropriately set according to any one of the composition characteristics 〇) to (8), whether or not the particle diameter is adjusted, whether or not the filler is used, the type of the fluorescent component, and the like, and the coloring component is appropriately selected. The whole time is selected from the range of 0.05 parts by mass or more (preferably, parts by mass or more, more preferably 0.5 parts by mass or more). Further, if the amount of the fluorescent component is too large, the overall contrast as a color filter is remarkably lowered. Therefore, it is recommended that the balance between the resin compositions (between pixels) and the color filter be coexisted. In the range, the upper limit of the amount of the fluorescent component is set. The blending amount of the fluorescing component is 1 part by mass based on the entire coloring component. The ten o' portion is mostly below the third-grain stem (preferably 2 parts by mass or less, more preferably L5 parts by mass or less). Any of the photosensitive resin compositions (red-type photosensitive tree-in-situ composition, green-based photosensitive resin composition, and blue-based photosensitive resin composition) used in the present invention may have and disperse in addition to the above characteristics. A known photosensitive resin composition having a pigment has the same characteristics as a photosensitive resin composition, and is usually compounded with a coloring material (especially a coloring pigment, which may also contain a dye), a binder resin, a photopolymerizable compound, a photopolymerization initiator, and optionally Other additions 315918 1359959 ^ In the case where the photosensitive resin composition of the present invention described above is blended with a filler, there is a case where a component which emits fluorescence is blended. Further, each of these components is dissolved or dispersed in a solvent. The coloring pigment includes an organic pigment (hereinafter referred to as a colored organic pigment), an inorganic pigment (hereinafter referred to as a colored inorganic pigment), and the like, and it is generally simple to use a pigment dispersion resist. Further, as the inorganic pigment, a metal compound such as a metal oxide or a metal salt or the like is used, and specifically, metal oxidation such as 鉄, lead, Shao's recording, error, copper, titanium, magnesium, lanthanum, rhyme, recording, etc. A compound or a composite metal oxide or the like, which is used as a colored inorganic pigment. As the colored organic pigment, for example, a compound classified by a pigment in a color index (published by The Society 0fDyers and Coloursts). Specifically, the following compounds of the color cable (C.I.) number can be exemplified, but are not limited thereto. CI·Pigment Yellow 20, 24, 31, 53, 83, 86, 93, 94, 109, • 110, 117, 125, 137, 138, 139, 147, 148, 150, 153, 154, 166, 173, 180 And 185, etc.; CI pigments 13, 13, 36, 38, 40, 42, 43, 51, 55, 59, 61, 64, 65, and 71; CI pigment red 9 '97, 105, 122, 123, 144 , 149, 166, 168, 176, 177, 180, 192, 215, 216, 224, 242, 254, 255, and 264, etc.; CI Pigment Violet 14, 19, 23, 29, 32, 33, 36, 37, and 38 Etc.; 32 315918 1359959 CI Pigment Blue 15 (15: 3, 15: 4, 15: 6, etc.), 2 Bu 22, 28, 60, 64, and 76; CI Pigment Green 7, 10, 15, 25, 36 and 47, etc.; C-Ι. Pigment Brown 28; CI Pigment Black 1 and 7, etc. The coloring materials containing the coloring pigments described above may be used alone or in combination of two or more. The coloring material is usually based on the total solid fraction i in the photosensitive resin composition, and is usually in the range of 5 to 60 mass y0, more preferably 5 mass%. When the coloring material is within the above-defined range, the color density of the pixels of the film is sufficient, and the elimination property of the non-pixel portion during development is not lowered, and it is preferable that residue is not easily generated. As the binder resin, those having an alkali solubility or a dispersion medium as a coloring material can be used. The preferred binder resin is, for example, a polymer having an unsaturated carboxylic acid (including an acid anhydride) as a constituent monomer, and more preferably a copolymer of an unsaturated carboxylic acid. As the unsaturated carboxylic acid, for example, acrylic acid methacrylic acid or the like is suitably used. These acrylic acid and mercaptoacrylic acid may be used singly or in combination of two. Further, in such acrylic acid and mercaptoacrylic acid, other unsaturated carboxylic acids such as crotonic acid, itaconic acid, maleic acid, fumaric acid, etc. may be used (or Its anhydride). Further, a monomer having a hydroxyl group and a carboxyl group in the same molecule such as α-(hydroxyindenyl)acrylic acid may be used in combination. The constituent unit derived from the unsaturated carboxylic acid in the binder resin is usually present in an amount of 10 to 50% by mass, more preferably 15 to 40% by mass. From the case where the constituent unit of the saturated carboxylic acid is not within the above-mentioned range, the solubility in the developing solution is sufficiently 'the residue is not generated on the substrate of the unexposed portion, and the film portion of the exposed portion is not reduced when the development is not caused, and no It is better to peel off the entire pixel. " A monomer which forms a copolymer together with the aforementioned unsaturated carboxylic acid, and is exemplified by * (mercapto) acrylate. Specific examples of the (mercapto) acrylate include decyl acrylate, ethyl (meth) acrylate, butyl (meth) acrylate, and benzyl (meth) acrylate. a substituted or unsubstituted alkyl ester of (mercapto) acrylate such as 2-hydroxyethyl acrylate and (amino) ethyl methacrylate; (cyclo) (meth) acrylate, (fluorenyl) Cyclohexyl acrylate, decyl cyclohexyl (meth) acrylate, cycloheptyl (meth) octyl acrylate, menthol (meth) acrylate, (fluorenyl) acrylate ring Pentene ester, cyclohexenyl (meth)acrylate, cycloheptenyl (decyl) acrylate, cyclooctene acrylate (meth) acrylate, cappedicarboxylate (meth) acrylate, (meth) acrylate ring Pentadienyl ester, isobornyl (mercapto)acrylate, decyl (meth) acrylate, trimethyl decyl (meth) acrylate, tricyclodecyl oxyethyl (meth) acrylate, (acrylic acid) Adamantyl ester, (mercapto)acrylic acid norbornelate, (mercapto)acrylic acid ester, (fluorenyl) acrylate having an alicyclic group such as dicyclopentenyl (meth)acrylate and dicyclopentenyloxyethyl (meth)acrylate; having oligomeric ethylene glycol of (mercapto)acrylic acid (Alkyl) acrylate having a chain ether group such as a monoalkyl ester; (cyclic group) having a cyclic ether group such as (meth)acrylic acid propyl acrylate or (meth)acrylic acid oxetane Acrylate, etc. Preferred monomers include unsubstituted or substituted alkyl esters of (mercapto)acrylic acid, (fluorenyl) propyl 315918 34 1359959 enoate having an alicyclic group, especially containing bismuth (mercapto) acrylate The ester, benzyl (meth) acrylate. Further, the monomer constituting the copolymer together with the above unsaturated carboxylic acid is preferably (mercapto) acrylate, but may be substituted or substituted with the (fluorenyl) acrylate ( Further, the other monomers are aromatic vinyl compounds such as styrene, α-methylstyrene, and vinyl toluene; vinyl acetates such as vinyl acetate and vinyl propionate; (meth)acrylonitrile and α • aeration The cyanide vinyl nitrile compound;

For example, a maleidin compound such as hydrazine-stupylmametmine or the like can be mentioned. Other monomers such as hydrazine may be used singly or in combination of two or more. The polystyrene-equivalent weight average molecular weight of the binder resin is, for example, 5,000 to 1 〇(), (4) to __, more preferably 7 to 50,000, still more preferably 7 to 30. The weight of the binder polymer is flat = numerator (4) Within the above-defined range, film reduction is less likely to occur during development, and the elimination of non-pixel portions is good at the time of the ghost.

The content of the resin is generally from 5 to 90 in the total solids of the photosensitive resin composition. The amount of the agent is from 0 to 7 % by mass. In the case of the viscous liquid, it is preferable that the (four) t-thousand molecular weight is within the above-mentioned range. It is difficult to cause development residue on the substrate of the non-pixel portion of the display. H: As a photopolymerizable compound, light can be applied to ^π^^^, and can be taken into 1π^. Han Junshu first polymerization initiator 2. Is is not particularly limited, and 2-cell energy monomer can be used. , 3 palaces can be more than the monomer. ...... outside 315918 35 1359959 monofunctional soap body, for example, 壬其笑Ie 本本基卡比醇丙酯, 2- 2-ziridine-3-phenoxypropyl acrylate, 2-7; ^ 曰 曰 ethyl hexyl carbitol acrylate, acrylic acid 2-hydroxyethyl vinegar, N_vinyl pyrrolidine _ and so on. t as a bifunctional monomer, for example, hexanediol di(meth)acrylic acid vinegar, ethylene glycol di(meth)acrylic acid vinegar, pentaerythritol di(methyl) propylene vinegar, triethylene glycol Alcohol di(methyl)-propyl acetoacetate, double-aged bis (acrylic acetoxyacetate) test, 3-methylpental diol bis(indenyl) acrylate vinegar, and the like.

Examples of the trifunctional or higher monomer include, for example, trimethylsulfonyl tris(meth)acrylate, pentaerythritol tris(decyl)acrylate, pentaerythritol tetra(methyl)propionic acid, and dipentaerythritol. ) Propionate vinegar, diquaternary quinone alcohol hexa(meth) acrylate, and the like. A preferred photopolymerizable compound is a monomer having two or more functional groups. The content of the photopolymerizable compound is usually 1 part by mass, and 60 parts by mass, preferably 5 to 5 parts by mass, based on 1 part by mass of the total of the binder resin and the photopolymerizable compound in the photosensitive resin composition. Luminescence of the photopolymerizable compound: S: In the above range, the strength and smoothness of the pixel portion are good. The photopolymerization 5 starting oxime preferably contains a triazine compound, a ketone compound (acetophenone compound, etc.) or a derivative thereof, a biimdaz〇ie compound, a ruthenium (〇xlme) compound, and An initiator system formed by at least one of a polyfunctional thiol (thi) compound. The photosensitive resin composition obtained by using the above-mentioned initiators is highly sensitive, and the film formed is excellent in the strength and surface smoothness of the pixel portion. The photopolymerization initiator may be used singly or in combination of plural. For example, 2,4•bis(trichloroindenyl)_6·(4·曱oxy 315918 36 1359959 basic group)-l,3,5-tri-D-Qin, 2,4-di (trichloromethyl)-6·(4-methoxycaffeyl)-1,3,5-triazine, 2,4-bis(trichloroindenyl)·6·piperon-1,3,5 _Triazine, 2, 'bis(trichloromethyl)_6·(4-decyloxystyryl)_ι,3,5·triazine, 2,4_bis(triseodecyl)-6-[2 -(5-decylfuran-2-yl)vinyl bromide: triazine, 2,4-bis(dioxamethyl)-6-[2-(indol-2-yl)ethenyl] ι,3,5_triazine, 2,4-bis(trimethylmethyl)-6·[2·(4-diethylamino-2-indenylphenyl)vinyl]-1,3, 5-triazine, 2,4-bis(trimethylsulfonyl)-6-[2-(3,4-dimethoxyphenyl)vinyl]-1,3,5.triazine, and the like. The ketone compound or a derivative thereof is, for example, diethoxyphenyl hydrazine, 2-hydroxy-2•methyl-1-phenylpropane-i-one, benzyldidecyl ketal, 2-hydroxyl-l -[4-(2-hydroxyethoxy)phenyl]2-mercaptopropane oxime-ketone, hydroxycyclohexyl phenyl ketone, 2-mercapto-1-(4-mercaptothiophenyl) _2_morpholinylpropanone, 2-=-mercaptobenzyl)-2-morpholinyl-l-(4- mercaptothiophenyl)propane oxime-one, 2-benzyl-2-di Mercaptoamine-1·(4-morpholinylphenyl)butane<• ketone, 2-hydroxy-2-indolyl-1-[4-(indolylvinyl)phenyl]propanone 丨_ ketone oligomers and the like. Further, 2-octanedione, 1-[4-(thenylthio)phenyl]_, 2_(ophloindole) or the like can be used. Further, as described, the biimidazole compound is, for example, 2,2,_bis(2-chlorophenyl)-4,4',5,5'-tetraphenyldidiimidazole, 2,2,_bis (2) (3) diphenyl)-4,4,5,5-tetraphenylbiimidazole (for example, see Japanese Laid-Open Patent Publication (Patent Document 3) and JP-A No. Ml6918 (Patent Document 5)] 2,2,-bis(2-phenylphenyl)·4,4,,5, broad tetraphenylene. Mizozol, 2, wide bis(2-phenylphenyl)-4,4,5,5'-tetrakis(alkoxyphenyl)biimidazole, 2 2,_bis(2' phenyl)-4 , 4',5,5'-tetrakis(dialkoxyphenyl)biimidazole, 2,2, bis(2-phenylphenylhydrazine, 4',5,5'·tetrakis (trisodium oxybenzene) Base) joint two mouth rice saliva (for example, = 315918 37 = jikaikai 6 (10) 2 gazette and special open (9) milk bulletin), ,, 5,5-position phenyl is replaced by a few alkoxy groups Compound (泉昭2, - (2, chaotic base) _4,4,,5,5,_tetraphenyl bisoxazole, 22, diphenyl phenyl hydrazine, 4,, 5, 5, · four Phenyl dioxime. The oxime compound is, for example, a ruthenium-based compound having a compound such as, (4-phenylthiophenyl) It is called phenylthio--Xinxuan-xin heart-burning dione. It is made by benzoic acid benzoate, 1-(4-ylthio-phenyl), octyl alcohol, ".o. acetic acid vinegar, and (4) stupid thiol. -Phenyl)-butanone oxime-〇-acetate, etc. The aforementioned polyfunctional thiol compound is a compound having a plurality of thiol groups in the molecule, in particular, a fat-binding thiol-based fat. Family The sulfur compound is preferred. The aliphatic polyfunctional thiol used in the present invention is, for example, 'hexanedithiol, decanedithiol, M•dimethylweigibenzene, etc.; butanediol dithiopropionic acid from 1 , butanediol dithioethanol _ 'ethylene glycol dithioglycolic acid brewing, • trimethyl ketone trithioglycolic acid vinegar, butane diol dithiopropionic acid vinegar, trimethyl propyl propane trithiopropionate vinegar , a polythiol of a polybasic compound such as trimethylolpropane triglycolic acid, pentaerythritol tetrathioacetic acid vinegar, pentaerythritol tetrathioglycolic acid vinegar or trisyl ethyl trithiopropionate vinegar Alcoholic acid vinegar or polythioacetic acid vinegar, etc. Preferably, the aliphatic polyfunctional thiol comprises trimethyl propylene disulfide acid, three acetylene A, and 7 丞 propane diethylene glycol ester. , pentaerythritol tetrathiopropionate, etc., among which pentaerythritol tetrathiopropionate is preferred. The degree of the effect of the present invention can be used in combination with photopolymerization starting materials commonly used in the field, for example, styrene Marriage (4), 3159J8 38 1359959 benzophenone (benZOPhenone) is a thiophene ketone ketone, which is called an anthraquinone (an-), and others. The other initiators may be used singly or in combination of two or more. The benzoin-based photopolymerization initiators are, for example, benzoin, acetoin, acetoin (10), Benzoin (four), stupid odion, etc. benzophenone photopolymerization initiators, for example, benzophenone, orthophthalic acid

Methyl benzoyl benzoate, 4-lean I 4 base ketone, 4-benzylidene _4,-γ yl base sulphide, 3,3', 4, 4, · four (first Tri-butylperoxy peroxy) benzophenone, 2,4,6-trimercaptobenzophenone, and the like. The oxime 11 ketone photopolymerization initiator is, for example, 2-isopropyl hydrazine, isopropyl thioxanthene, 2,4·diethyl thioketene, -4-propoxy thioxanthone, and the like. . The I-based photopolymerization initiator is, for example, 9,1 〇 曱 曱 曱 葱 葱, 2 —ethyl 9′1 〇 methoxy 蒽, 9,1 〇-diethoxy fluorene, 2-ethyl _9, 1 〇 _ diethyl hydrazine and the like. Other photopolymerization initiators are, for example, 2,4,6•trimethylbenzoyldiphenyl oxide scales, 2,2,·bis (o-p-phenylene M,4,5,5,- Tetraphenyl-1,2,-biplex, 10-butyl-2·chloridone, 2-ethylrone, nodal, 9, ι〇 醌 phenanthraq Uinone, camphor ca (camph 〇rquin〇ne), phenylacetaldehyde 酉 曱 曰 曰 曰 曰 曰 ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti ti It is more preferable that the coloring photosensitive resin composition obtained by the initial additive is more high-sensitivity and it is more preferable to form a color light-receiving sheet when using a coloring or the like. As a photopolymerization initiator, for example, an 'amine-based compound, an oxygen-burning compound is used. The oxime compound 39 315918 1359959, the oxime compound, etc., may be used alone or in combination of two or more. The amine compound is, for example, 'triethanolamine' methyl dipropanolamine. , 4· dimethylamino benzoic acid ", 4 dimethylamino benzoic acid, 4, dimethylamino benzoic acid, benzoic acid, hydrazine, ethylene glycol , 4_ Methylamino-based carbaryl, 2, ethylhexanoic acid, n, n-dimethyl-p-aniline, 4,4'-bis (didecylamino) dimethanol (commonly known as ericone (michWs) Ketone)), 4,4'-bis(diethylamino)dibenzolone, 4 & bis(ethyldecylamino)benzhydryl, etc., of which 4,4,-雔 are preferred. 'Amino" benzophenone. Further, a G-alkoxy alkane compound is, for example, 9,1 〇-dimethoxy oxime, 2, ethane-9,10-dimethoxy fluorene, 9,10-diethoxy fluorene, 2 ethyl·9 1〇_ylamine and the like. A thioxanthone compound, for example, 2-isopropyl thioxanthone, isopropyl thioxanthone, 2,4-liethylthio", 2,4-dichlorothioxanthone, In the case of a photopolymerization initiator, a commercially available one can be used, for example, the product name "EAB-F" (manufactured by Hodogaya Chemical Industry Co., Ltd.). A combination of a photopolymerization initiator and a photopolymerization initiation aid is, for example, diethoxyacetophenone/4,4,bis(diethylamino)benzophenone, 2·indenyl·2· = phenyl-1-(4-mercaptothiophenyl)propane _ι__/4,4,·bis(diethylamine) dioxin, 2-hydroxy-2-methyl-1- Phenylpropane "·ketone/4,4, bis(diethylamino)benzophenone, benzyldidecyl ketal/4,4,·bis(diethylamino)benzophenone, 2-hydroxy-2-indolyl-l-[4-(2-hydroxyethoxy)phenyl]propanone 315918 40 1359959 /4,4'·bis(diethylamino)benzophenone, anthracene _hydroxycyclohexyl phenyl ketone / 4,4, bis (diethylamino) diphenyl fluorenone, 2-hydroxy · 2 fluorenyl methyl vinyl) base] propyl sulphide - 1 嗣 low ^ ^4,4,-bis(diethylamino)-benzophenone, 2-benzyl-2-didecylamino-1-(4-morpholinylphenyl)butane_丨· Ketone/4,4,·bis(diethylamino)diphenyl ketone, 2-(4-methylbenzylmorpholinyl-fluorene oxime methylthiophenyl)propan-1-one/4 ,4,·bis(diethylamino)benzophenone, 2-octanedione, ι_[4·(phenylthio)phenyl]_, 2- (after o-benzidine) / 4, 4, _ bis (diethyl private: base) a combination of ketone, etc., a preferred combination, for example, 2-methyl-2-morpholino-1_(4-oxime Alkylthiophenyl)propan-1-one/4,4,-bis(didecylamine) One oxime. Amount of photopolymerization initiator for the total of the binder resin and the photopolymerizable compound. The mass fraction is usually from 〇 to 40 parts by mass, more preferably from 2 to 30 parts by mass. Further, the amount of the photopolymerization initiation aid is usually from 〇丨 to 5 J) parts by mass based on 100 parts by mass of the total of the binder resin and the photopolymerizable compound, more preferably! Up to 40 parts by mass. The inside of the photopolymerization initiator is in the above range, and the colored photosensitive resin composition is high in sensitivity, and the intensity of the pixel portion formed by arranging the colored photosensitive resin composition is good, and the smoothness of the pixel surface described above is good. When the amount of the photopolymerization start-up aid is within the above range, the sensitivity of the obtained colored photosensitive resin composition is further improved, and the productivity of the color filter formed by using the above-mentioned colored photosensitive resin composition is improved. As the solvent, various solvents used in the field can be used. Specifically, for example, ethylene glycol monoalkyl ethers such as ethylene glycol monoterpene ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether; 315918 41 1359959 diethylene glycol dioxime Ether, diethylene glycol diethyl ether, diethylene glycol dipropyl ether, two. Diethylene glycol dialkyl ether such as diol dibutyl ether; cellosolve acetate; and ethylene glycol alkyl ether acetate of ethyl acetate dissolved fiber; Acid ester, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, methoxybutyl acetate, methoxypentyl acetate, etc. alkanediol alkyl ether acetate; , aromatic hydrocarbons such as toluene, dimethyl benzene, 1,3,5·trimethylbenzene; ketones such as methyl ethyl ketone, acetone, methyl amyl ketone, methyl isobutyl ketone, cyclohexanone An alcohol such as ethanol, propanol, butanol, hexanol, cyclohexanol, ethylene glycol or glycerin; an ester of ethyl 3-ethoxypropionate or decyl 3-methoxypropionate; Such as r-butyrolactone cyclic esters and the like. These solvents may be used alone or in combination of two or more. The amount of the solvent to be used is usually 60 to 90% by mass, preferably 7 to 85% by mass based on the total amount of the photosensitive resin composition containing the solvent. When the content of the solvent is within the above range, the coating property is good. The photosensitive resin composition of the invention may be further added as needed; and two: Guangchuang, a polymer compound, a pigment dispersant, an adhesion promoting anti-cracking agent, an ultraviolet absorber, a coagulation preventing material, and the like. As the filler, for example, glass, silica dioxide, and oxidation are used. Examples of the polymer compound include polyethylene glycol, polyacrylic acid 1 315918 42 1359959, and ethylene glycol mono(tetra)m-based propylene. Further, a thermosetting resin such as an epoxy resin, or a ruthenium such as polyester or polyurethane can be used. As the pigment dispersant, a commercially available interface, a lanthanide, a fluorine-based, an ester-based, a cationic, an anionic or a nonionic system can be used. Surfactants such as amphoteric, etc. The surfactants may be used alone or in combination of two or more. The surfactant may, for example, be a polyethylene oxide, a polyoxyethylene alkyl phenyl ether, a polyethylene glycol diester, a sorbitan fatty acid ester, a fatty acid modified polyester, a tertiary amine denatured polyurethane. Others, such as urethanes and polyethyleneimine, can also be used under the trade name κρ [made by Shin-Etsu Chemical Co., Ltd.], polyfluorinated p〇lyfl〇w [made by Kyoei Chemical Co., Ltd.], F-Top (TOHKEM Products) Manufacturing) Megafax [manufactured by Dainippon Ink Chemical Industry Co., Ltd.], Florard [manufactured by Sumitomo 3M Co., Ltd.], Asahi guard, Surflon [above, manufactured by Asahi Glass Co., Ltd.], SoIsperse [manufactured by ZENECA AG], EFKa (manufactured by EFKa CHEMICALS) , PB821 [made by Ajinomoto Co., Ltd.], etc. As the adhesion promoter, for example, ethylene trimethoxy decane, ethylene triethoxy decane, ethylene tris(2-methoxyethoxy) decane, N-(2-aminoethyl)-3-aminopropyl Methyldimethoxydecane, ^(2-aminoethyl)·3•aminopropyltrimethoxydecane, 3-aminopropyltriethoxydecane, 3—glycidoxy Propyltrimethoxydecane, 3-glycidoxypropylmethyldimethoxycarbazide, 2-(3,4-epoxycyclohexyl)ethyltrimethoxydecane, 3-propylpropyl Methyldimethoxydecane, 3-chloropropyltrimethoxydecane, 3-methylpropoxypropyltrimethoxydecane, 3-mercaptopropyltrimethoxydecane, and the like. The antioxidant is, for example, 2,2,-thiobis(4-mercapto-6-tris-butanol), 43 315918 1359959 2,6-di-tertiary-butyl-4-nonanoic acid or the like. Examples of the ultraviolet absorber include 2_(3·third-butyl-2-hydroxy-'methylphenyl)·5· gas benzotriazole, alkoxybenzophenone, and the like. As the aggregating agent, for example, sodium polyacrylate can be used. - Any of the photosensitive resin compositions (red-type photosensitive resin composition, green-based photosensitive resin composition, and blue-based photosensitive resin composition) of the present invention can be prepared by the following method. In other words, the coloring material is mixed with the solvent in advance, and the average particle diameter of the coloring material is 0.2/zm or less until it is dispersed by a bead mill or the like. For some or all of them, a pigment dispersant or the like may be used as needed, and the remaining binder resin, photosynthetic compound, photopolymerization initiator, and, if necessary, may be added to the obtained millbase. The other components and the solvent to be added as needed are obtained to obtain the desired photosensitive resin composition. (Color filter) I. The photosensitive resin composition obtained by the above-mentioned photosensitive resin composition The pattern is formed on the substrate in any order, and can be replaced by a color filter. The color filter of the present embodiment is formed by forming a photosensitive resin composition of the photosensitive resin composition group f into a predetermined shape. For example, the color filter 1 (shown in FIG. 4) has a transparent formation in each of the openings of the substrate 3 and the lattice-shaped black matrix black matrix BM on which the plurality of openings are formed on the substrate 3. red The resin composition film is permeable to moon, 彔 color; yyue 曰 composition film G and transparent blue resin composition film β. Transparent red resin composition film ruler is as described above for color filter 3159] 8 44 1359959 resin In the composition group, the red photosensitive resin composition is formed into a film of a desired shape. The transparent green resin composition film is a composition of the above composition, and the green photosensitive resin composition is formed into a film of a desired shape, and a transparent blue resin is used. The film B is the coloring resin composition of the above-mentioned grouping agent, and the photosensitive resin composition is used as the light film. The resin composition of the resin composition satisfying the above characteristics (1) is obtained by using the above-mentioned photosensitive resin composition. Further, the resin film of each of the color light-receiving sheets preferably has at least one of the properties of the resin composition film satisfying the above characteristics (2) to (8) or a combination thereof. Therefore, the method of developing each photosensitive resin composition on a substrate, in other words, forming a film in a predetermined shape, can be directly carried out by a known or conventional method or appropriately modified, for example, by the following method. The photosensitive resin composition is spin-coated on a substrate (usually glass), and the solvent is removed by prebake to obtain a smooth coating film. The thickness of the coating film at this time is about 3/m. The coating film thus obtained is exposed to ultraviolet light by exposure to a negative mask for forming an image of interest. Thereafter, the non-exposed portion is dissolved in a developer for development. The above operation is also carried out on the remaining photosensitive resin composition. A resin composition film of each color as a target pixel (pattern) can be formed. A spin coating method is usually used as the coating method, but a slit coating method, a slit, and a spin coating method can also be used. At the time of irradiation, it is preferable to uniformly irradiate parallel light to the body of the exposure portion, and to accurately bond the mask to the substrate, and to use a mask aligner or the like. Further, after development, it can be post-baked after 10 to 60 minutes at 15 to 23 〇 3159 J8 45 1359959 C as needed. As the developing solution, a rare test solution (aqueous solution containing an inactive compound and a surfactant, etc.) is usually used. The above basic compound may be either an inorganic substance or an organic substance. Examples of the inorganic basic compound include sodium hydroxide, hydrazine hydroxide, dihydrogen hydride, dihydrogen hydride, hydrogen sulphate, ammonium dihydrogen phosphate, potassium dihydrogen phosphate, sodium citrate, and citric acid. Potassium, sodium carbonate, potassium carbonate, sodium hydrogencarbonate, hydrogen carbonate, sodium sulphate, boric acid unloading, clock, etc. As the organic basic compound, for example, tetradecyl ammonium hydroxide, 2 • hydroxyethyl trimethyl ammonium hydroxide, monomethylamine, didecylamine, trimethylamine, monoethylamine monoethylamine, triethylamine, single Isopropylamine, diisopropylamine, ethanolamine, and the like. These inorganic and organic basic compounds may be used alone or in combination of two or more. The concentration of the basic compound in the developer is preferably from 0.1 to 10% by mass, more preferably from 0.03 to 5% by mass. The surfactant in the μ developer can be nonionic interfacial activity

2 ^ salts; sodium lauryl sulfate, lauryl-sodium benzoate sodium, dodecapine salts, and the like. An anionic surfactant is, for example, a higher alcohol sulfate salt of the like, such as sodium sulphate, sodium sulphate;

315918 46 1359959 The cationic surfactant may, for example, be an amine salt such as stearylamine hydrochloride or lauryl triammonium chloride or a fourth-order ammonium salt. These surfactants may be used singly or in combination of two or more. The concentration of the surfactant in the developer is usually in the range of from 1 to 1% by mass, preferably from 5 to 8% by mass, more preferably from 5% to 5% by mass. Therefore, the color filter manufactured from the photosensitive resin composition of the present invention has a small film thickness difference in the plane, for example, when the film thickness is 1 to 3//1, the inner film thickness difference may be 〇. L5 / / m or less, more preferably 〇〇 5 y m or less. That is, the color filter of the present invention is excellent in smoothness and transparency, and is assembled to a liquid crystal display device, and can produce excellent quality liquid crystal in high yield. And using the color filter of the present invention to form a liquid crystal display device, which is made of a specific photosensitive resin composition group, and suitably obtains a balance between resin compositions (between pixels), so It is easy to prevent the chromaticity deviation between the display white and the display black. However, the balance between the resin compositions (between the pixels) is appropriately obtained, so that it is easy to increase the color temperature of the display white and increase the temperature of the display black. As the backlight of the liquid crystal display device, a white light source can be used. For example, a two-wavelength light source, a three-wavelength light source, or the like can be used. For example, a two-wavelength light source, for example, a light-emitting diode (LED) and a yellow phosphor Green phosphor A white light source that emits white light. A three-wavelength type light source, for example, a light source such as a '3-wavelength fluorescent tube (Fig. 1); a white LED light source in combination with a red, blue, and green phosphor; A white LED light source that combines red, blue, and green LEDs; an organic electric field emits 315918 47 1359959 light source 荨. As the backlight, a C light source, a D light source, or the like, which is Cjjg, may be used. The following is a more detailed description of the present invention, but the invention is not limited by the following examples, and may be appropriately modified without departing from the scope of the foregoing and the following. It is also included in the technical scope of the present invention. In the following examples, the contents are expressed in % and parts, and unless otherwise specified, based on the mass. Examples 1 to 5 are as shown in Tables i to 3 below. A resin composition composition comprising a red photosensitive resin composition n-based photosensitive resin composition and a blue photosensitive resin composition. χ, each resin composition is a color pigment, a filler pigment, and a pigment. Full amount Mixing with a portion of the solvent of propylene glycol monomethyl ether acetate. The beads are used to fully disperse the coloring pigment. The remaining propylene glycol monoacetic acid in the dispersing agent is prepared by mixing with the remaining components. 315918 48 1359959 (106/6504)ΜΚ·], obtained (丨Rwhhe_RD65 丨+ 丨丨)〇[NTSC ratio] and 'red chromaticity coordinates determined by Xred, para丨丨el, Yred, parallel, Zred, parane丨, by Xgreen: para丨丨ei, Ygreen para"e丨, Zgreen para"e] The green color coordinates defined by Xblue ^anel, Yblue paui]e|, and the blue chromaticity coordinates specified in CIE 1976 UCS color The area of the triangle formed on the graph is the NTSC ratio obtained by calibrating the chromaticity coordinates of the RGB of NTSC to the area of the triangle formed on the UCS color map. [Comparative; | Among the color films, by Y /V v .parallel/ i red,orthogonal ' ^green,parallel/

Yg(10)' Yblue paraiie]/Ybiue 〇rth〇g_i find the comparison T_red, Tgreen, Tb& Further, the contrast Tall (Ywhite/Yblack) is obtained from the luminance (Yblack) when black is displayed and the luminance (Ywhite) when white is displayed. The partial enlargement of the IJCS color diagram of CIE 1976 is also shown in Fig. 2, while the 纟σ fruit is not in Tables 4 to 6. In addition, in the second figure, the white point (the mouth ▲, ^^ table does not display the chromaticity coordinate when white, the black dot (_, ♦ •, ★) indicates the chromaticity coordinate when the black is displayed. 315918 55 1359959 [Table 4 】

Contrast Tblue § § § § § LU 3 ω ϊ N CO CNJ Ο ΙΟ ΙΟ in so 〇〇S ΙΟ LO in so S § 1〇in 1〇s ο 〇〇CNJ 〇1〇m in s ο 00 CM o ?5 1〇1〇ΙΛ S 〇对g一(O oo % ρ 寸 · i〇oo Z 〇(Ο 荛ο ο 对 g <〇ο ο sp inch · ΙΟ S 〇〇 s s Ο) to 苤CO oo S § CO s § od CM g CQ S § ο ο S 〇><0 ζ g ο ο s σ> CO 00 〇〇 Green substrate (GREEN) 壬i has body CO in 〇〇CM τ- 卜<〇<〇寸T_〇> CO fm Μ 卜 5 σ> ίο o CD IT) soo S CQ iri C0 C0 CO S ο 1〇'r—in oi <£><ΝΙ Ο l〇CD CSI co 〇〇tel i〇CM 〇JO 〇y <〇iO p CD GO 〇 CM oso in t— CO οο (Ο ο ο in (Ο CJ CO S Ο σ> wear ό ό 〇 > CO ο οο ρ 3 ΙΛ CM oo O) N. S 〇CO CNJ S CO Oi so Cf> s CNJ CNi ΓΟ οο 05 S ο co oo o S ΓΟ ΓΟ CO CO <c 卜 5 Ο s ϊ <ύ 4 GO 〇寒GO σ> 〇〇05 m in 00 rsi ΙΟ r〇o ?3 T~ 〇<5 to CO o ¢0 CM 〇o co CO OJ ▼— ο ο to co o CO CM Ο ο co CO o 5 Ο back ί3 <〇σ> 荔soo CO σ> system so CO σ> 5 S ο CO to σ> 落S ο CJ〇(O cx> T- 卜 s ο isj ss CO CM V s C> s <〇CM t- s 〇(Ο οι τ- S ο s <〇CM Ο CO IO N- another ο ο /^Ν Nw/ 蝌 蝌 i )m to; <*>, thick 茛Φ I 2· 宕c 0 g) 1 δ ¥ 1 2· .啻c 8> 〇Ϊ © 1 TO i· TO* C ο g) 1 trtr 虿2 w TO* C Ο σ> £ δ, ¥ 1 π ϊ 宝 c ο Q) 1 备 CM CO τ 1〇56 315918 1359959 [Table 5] NTSC ratio [%] 1_ <〇N- CO h- Contrast Tall 〇ΓΟ CD 03⁄4 CO inch CO CD CO CO <J> 1060 pr So Or- σχ <N m Ο in CD CO 1% > X m - ^ Bu Bu 0 (Ο卜〇ό Τ3^ s CO in and Distance of (lTc, V'c) (X 1〇-3) ¢0 σ 00 CO 0 5 co vs. chromaticity coordinates-> 0.5032 0.4837 0.5012 0.4677 0.5036 0.4897 | 0.5005 0.4549 | 0.5035 0.4538 - 0.1950 0.19001 0,1966 0.2049 0.1955 0.2002 0.1977 0.2417 0.1965 0.1891 Average tristimulus value rsi 14.265 0.03021 14.195 0.030 1 14.414 0.0267 14.1V; 45 0.0246 | 14.294 0.0263 >- 21.260 0.0332 20.514 0.0277 21.644 0.0326 20.307 0.02056 | 21.460 0.0202 X 18.537 0.0294 18.104 0.0273 18.909 0.0300 18.0491 0.02458 | 18.844 0.0190 4 m 2^ Light occlusion When (black) light is transmitted (white) when light is blocked (black) when light is transmitted (white) when light is blocked (black) when light is transmitted (white) when light is blocked (black) when light is transmitted (white) light Interruption (black) Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5

57 315918 1359959 [Table 6]

• STS' ir —+ divination — CO on < rT l 〇〇> 〇yr^ to 5 CD η IRwhite-Rcl +|Rblack-Rc| (ΜΚ·” JB SS CD o' 05 CO ia <〇 %r> CD Bu V CM GO CN 5Ϊ σ> OI <〇1〇7 CD CO m σ> Another to σ> 毋ω color C>4 柘·4 Related color craving TwhiteorTbalck (K) ΓΟ <£) CD ΙΟ CO QO S ΓΜ in § CO to CO ίο ΓΟ 〇〇> 0.50321 | 0.4837| 1 0.5012| | 0.4677| 0.5036 1 0.48971 | 0.50051 | 0.45491 1 0.50351 | 0.4538 -3 S 03 〇§ ίΒ ο 1 CM § h - 〇> nr* S Ο ▼· 〇> 00 〇〇ό 〇〇Ο Ο o Ο 〇 bee V -3⁄4 百«Γ <«-N • δ 3 (0 3 JZ t (0 5 Z color Π ) Ξ 1 CO S !c (Ό SX 峤μ ilm si4 ancient t S* m ns; s CM CO inch ΙΛ 58 315918 1359959 (u ^ c, v ^ c) = (0.200886, 0.460892) (u D65, v D65 )=(0.197845,0.468369)

Rc=106/6774(MK·))

Rd65=1〇6/6504 (MK·1) It is understood from Tables 1 to 6 that the contrast of the green resin composition in the photosensitive resin composition group of Example 4 is too high, resulting in a red resin composition and a blue resin. The composition is not balanced. Specifically, the chromaticity coordinates when black is displayed are largely biased toward the purple direction (the black body trajectory is roughly orthogonal to the direction). When the color filter for liquid crystal is produced by using the resin composition agent, it is difficult to adjust the color of the liquid crystal display even if the characteristics of the structure of the liquid crystal display element and the characteristics of the driving circuit are adjusted. In contrast to the photosensitive resin composition composition of Test Example 1, Putian pigmented the fluorescent pigment (c] Pigment Yellow _185) in an appropriate manner in the green resin composition, and the color system and the green color were used. In the photosensitive resin composition group of the blue tree, the dream: the pigment having a large average particle size is appropriately kept in red $, green $, ^ = : Balance between. The photosensitive resin composition group of Experimental Example 3 appropriately maintained the balance between the red and cerium (tetra) lipid compositions by blending the filler pigment. Thus, in Example ii3, it is balanced with respect to the green resin composition film which is easily disproportionately increased, and the contrast between the three color resin composition films is appropriately maintained. Further, in Example 5, by comparing the Tgreen of the green 315918 59 1359959 color-based resin composition film with the pigment showing the glory, the average particle diameter of the colored pigment by shrinking the red-type resin composition film, Improve the contrast of other red color ratios compared to the red resin composition film that is easily and significantly reduced. Therefore, it is appropriate to maintain the balance of contrast between the colors, and it is possible to improve the overall contrast. - In addition, 'in particular,' in these experimental examples 1 to 3, 5, the combination of the chromaticity coordinates when black is displayed and the chromaticity coordinates when white is displayed, Lu is the color associated with the display of black The combination of higher temperature also becomes higher. It is also composed of a combination of white brightness (average Y value) and high. Further, in Experimental Example 1, the combination of the chromaticity coordinate track from the display of white to the black color and the black body trajectory is approximately parallel. Therefore, when the liquid crystal color filter is produced by using the resin composition group agent, the color balance is maintained at an appropriate balance, and the color adjustment during liquid crystal display is also simple. In 'Experimental Examples 1 to 3 and 5, the distance dc between coordinates is 75x 1〇_3 or less, and the distance dD65 between coordinates is 60x 10·3 or less, which satisfies (| Rwhite_Rc • I + I Rbiack-Rc | g^MK- 1. Satisfy (| Rwhite-RD65 | + | Rbiack-R〇65 IS 90MK·1, the NTSC ratio is within 70 to 215%. [Industrial Applicability] The resin composition is appropriately obtained from the color filter of the present invention. Since the balance between the physical films is appropriate, the balance between the pixels when the color filter is used can be appropriately obtained. The color adjustment of the liquid crystal display is simple, and is particularly applicable to a color filter for television. The color filter of the present invention is used. By using a photosensitive resin composition grouping agent and an adjusting method thereof, 60 315918 between the components in the photosensitive resin composition group agent is appropriately obtained.

Claims (1)

1359959 ’ Patent Application No. 93116646, 'October 28, pp. 28, Amendment Replacement Page X. Patent Application Scope: L A color twilight film has the number! The coloring resin composition film, the second color resin composition film, and the third color resin composition film are sandwiched between the respective color trees and the film, and a pair of polarizing plates are respectively disposed on the polarizing axes of the respective polarizing plates. When the three-stimulus values "X, Y, Z" of the CIE (International Commission on Illumination) 193i color system are measured for each color resin composition film, the following is the case where the two sides are orthogonal to each other. The calculated white coordinates (u white, v white) and the displayed black coordinates (u, biack, VMack) are at coordinates 1 (〇.18, 〇.52), coordinates 卩1 (〇.25, 〇.52). , the color filter formed by the four coordinates of coordinates 111 (〇.23, 0.42), coordinates SJ0.15, 0.42); u white=4Xwhite/(Xwhite+l5Ywhite+3Zwhite) , v white=9Ywhite /(Xwhite+l 5Ywhite+3Zwhite) * u black-4Xblack'(Xblack+ 1 5Yblack+3Zblack) v black~9Ybjac]c/(Xbjack+ 1 5 Yb]ack + 3Zblack) where Xwhite, Ywhite, Zwhite, Xblack, Yblack and Zblack are values obtained by the following formula; Xwhite (Xl, parallel+X2, parallel + X3, parallel)/3 Yvvhite-( Yl,paral Lel+Y2,parallel+Y3,paraIlel)/3 Zwhite—(Z i,paranei+Z2,parallel + Z3,pai*allel)/3 Xblack—(X 1,〇rthogonal+X2, orthogonal + X 3,orthogonal) /3 Yblack—(Yl,〇rthogonal + Y2,orthogonal+Y3,orthogonal)/3 Zb lack" 1, orthogonal ^"^2, orthogonal-^ ^3,orthogonal )/3 where 'X1,parallel,Y1 , Parallel, Z i, paraiiei", the first color resin 62 315918 revised version 1359959, the patent application No. 93116646, the modified page composition on October 28, 100, when the polarizing plates are parallel to one another, the polarizing plate is parallel to each other. The diffracted value "X, Y, Z" of the transmitted light is measured using the three-wavelength tube light source shown in Fig. 1 as a backlight; "x2, parallel, 2'paraliel Z2 paraUel", and Γ _, Γ3 ρ打(1)e], Z3 parallel" The three stimulus values "χ, γ, z" of the second color resin composition film and the third color resin composition film when the non-polarization axes are parallel to each other are the same as the aforementioned i-th color The value at the time of the measurement; "Χι". —, '—I, Zl,〇rthog〇nal J ' Γ X2>〇rth〇g〇nal >Y2>orthogonal>Z2>orthogonal j > Factory X v 3,〇rthog〇nai, Y3 〇rth〇 g()nai, &,. Can. § Just 1" indicates that the three-stimulus values "χ, γ, z" of the first color resin composition film, the second color resin composition film, and the third color resin film are perpendicular to each other when the polarization axes are orthogonal to each other. The values when measured in parallel are the same. 2. For the color filter of the scope of the patent application, in which the chromaticity coordinates of the standard light C defined by the CIE (International Commission on Illumination) are (u, c, v, c), The distance dc between coordinates is 75χ1〇·3 or less: Distance between coordinates dC=[(u,cu,white)2+(v,c_v,white)2]0.5+[(u,c_ U black) +(V C- V'biack) 2] 0·5. 3. If the color filter of the first or second patent application scope is applied, the CIE (International Commission on Illumination) determines the chromaticity coordinate of the standard aperture 65 (U'D65, V'D65). The distance between the coordinates calculated by the above equation is 65 〇xlO 3 or less: the distance between coordinates dD65=[(u'D65-u, white)2+(v, D65_v, white) 2] Q.5 + [(u, D65-U'black)2+(V'D65-V'black)2]0·5. 4. For the application of patent scope 帛i or item 2 of the color enamel film, among them, 315918 revised version 63 1359959 No. 93116646 patent application October 28, 100 revised replacement page CIE (International Commission on Illumination) - Bessie) The reciprocal color temperature of the standard light C is Rc, which corresponds to the white coordinate (A-, ν'*. The reciprocal color temperature is Rwhlte, which corresponds to the display black coordinate (u, _, v). , _) The reciprocal correlation color temperature is Rblack, which satisfies (|~"etch +|. Rblack-Rc 丨90MK1. 5. If you apply for a patent range! The color filter of item 2 or 2, wherein (10) (International Commission on Illumination) determines the reciprocal color temperature of the standard aperture 65, corresponding to the reciprocal color temperature of the white coordinate (U, ·, A·) For Rwhite, corresponding to the first reciprocal correlation color temperature: ^ I + I RbiaCk-RD65 I igOMK·1. 6. For the color filter of claim 3, wherein (10) (International Commission on Illumination), the reciprocal color temperature of the standard light Du is corresponding to the white coordinate (u, white, v, *) The reciprocal correlation color temperature is Rwhite 'corresponding to the display black coordinate (u, black, V, the reciprocal correlation color temperature is Rblack, which satisfies (丨Rwhite_RD65 ^ + I Rbiack-RD65 I 90MK-). 7. Item or the color filter of item 2, wherein the jth color is determined by X], para丨丨e丨, Y丨, para丨丨el, 2l para丨lel, by X2paralle丨, Y2 The second color chromaticity seat defined by parai丨d, Z2, paraUe丨 and the third color chromaticity coordinate (plot) determined by X3 para丨丨e丨, Y3, para丨丨e丨, Z3 para丨丨e丨The triangular area made on the UCS chromaticity diagram of CIE 1976, the triangular area of the NTSC RGB chromaticity coordinates on the UCS chromaticity diagram is 7〇 to 215%. 64 315918 Revision Patent Application No. 93116646 丄. October 28th, revised replacement page\application In the color grading sheet of item 1 or item 2, the color temperature of the color of the color seat MU black, V black is 5 〇〇〇 or more and 25,000 Κ or less. Item or the color light-emitting sheet of item 2, wherein at least one of the resin film of the first color resin composition film, the second color (four) composition film, and the third color resin composition film contains coloring 10. A color light film according to claim 9 of the patent application, wherein the resin composition film contains not only a coloring pigment but also a filler pigment. Spring 11 = application for the full color of the first or second color 遽In the light sheet, at least one of the first color tree test material film, the second color resin composition film, and the third color resin composition film contains a fluorescent component. Color; the method for adjusting the photosensitive resin composition of the light-receiving sheet, and the photosensitive resin composition of the first color, the composition of the color resin; the color filter of the third color photosensitive resin composition The method for adjusting the composition of the agent, including the following Step: forming a film of each color photosensitive resin composition into a film to obtain a film forming step of each color resin composition film; and sandwiching the resin composition film on a pair of polarizing plates, respectively, in which the polarization axes of the polarizing plates are parallel to each other The measurement procedure of the diacoustic value "X, γ, Z" of the CIE (International Commission on Illumination) 1931 color system of each color resin composition is measured under the condition of being orthogonal to each other; the white coordinate (u' is obtained by the following formula White, v, white) and display 315918 revision 65 1359959 Patent No. 93110640, October 28, 100, revised the chromaticity acquisition step of the replacement page black coordinate (u'black 'v'black); and at least one of The composition of the photosensitive resin composition is not changed. The chromaticity coordinates of the first color, the chromaticity coordinates of the second color, and the chromaticity coordinates of the third color are changed to reduce the aforementioned white coordinates and the display. Step of adjusting the distance between the black coordinates; , u wliite_4Xwhite/(Xwhite+ 1 5Ywhite+3Zwhite) v white —9Ywhite/(Xwhite+ 1 5 Ywhite+izwhite) φ u biack=4Xblack/ (Xblack+15Yblack+3Zblack) v black=9Ybiack/(Xblack+l 5 Ybiack+3Zb]ack) where xwhite, Ywhite, zwhite, xbIack, yblack, and zblack are values obtained by the following formula; Xwhite=( Xl, parallel+X2, parallel+X3, parallel)/3 Ywhite-(Yl, parallel+Y2, parallel + Y3, parallel)/3 Zwhite - (Zi, parallel+Z2, paraiiei+Z3, parallel)/3 Xblack(Xl,〇rthogonal + X2,orthogonal + X?, orthogonal)/3 Yblack (Yl,orthogonal+Y2,orthogonal + Y3,orthog〇nal)/3 Zblack—(Zi,0rth0g0nai+Z2,orth〇g〇 Nal + Z3, orthog〇na]) / 3 In the formula, "Xl, parallel, Yl parallel, Zi, paranei" is a method in which a film of a first color tree is sandwiched between a polarizing plate and a pair of polarizing plates. The light-stimulus value "X, Y, Z" is measured using the three-wavelength tube light source shown in Fig. 1 as a backlight; "X2, pai_allel, Y2, parallel, Z2, parallel" and "X3 parallel" , Y3 parallel, Z3 parallel" represents the third stimulus value "X, γ, Z" of the second color resin composition film and the third color resin composition film when the polarization axes are parallel to each other, and the aforementioned i 66 315918 revision 1359959 Patent application No. 93116646, October 28, 100, revised the replacement page color with the same day, the law: 1 Ζι,0Γ "When the X phase is orthogonal, the tristimulus values "X, γ, ζ" of the first color resin composition film, the second color resin composition film, and the third color resin composition film are the same as those described above. The value at the time of the measurement. A method for adjusting a photosensitive resin composition group for a 13' color filter, which is a color filter for a color filter having a first color photosensitive resin composition, a second color photosensitive resin composition, and a third color photosensitive resin composition The method for adjusting the composition of the resin composition comprises the steps of: forming a film of the photosensitive resin composition as described above to obtain a film forming step of the resin composition of each color; and sandwiching the film of the resin composition on a pair of polarizing plates, respectively The measurement step of γ in the tristimulus value of the CIE (International Commission on Illumination) 1931 color system of each resin composition film is measured under the condition that the polarization axes of the polarizing plates are parallel to each other; Obtaining a comparison obtaining step of the comparison of the respective resin composition films T1, τ2, τ3; and adjusting at least one of the photosensitive resin composition components without changing the chromaticity coordinates of the first color, the chromaticity of the second color a coordinate and a chromaticity coordinate of the third color to adjust a balance of the aforementioned contrast between the respective resin composition films; 67 315918 Rev. 1359959 Patent No. 93116646, October 28, 100, revised replacement page T3_Y3, parallel/Y; J.orthogonal where 'Yl, parallel indicates that the first color resin composition film is sandwiched by the polarizing axis One of the γ stimuli of the transmitted light at the time of the polarizing plate is the result of the measurement using the three-wavelength tube light source shown in Fig. 1 as the backlight. 丫2, Parallel and Y3, paralle丨 respectively indicate polarized light. When the axes are parallel to each other, the Y in the tristimulus values of the second color resin composition film and the third color resin composition film are measured in the same manner as in the case of the first color, 'Yl'orthogonal, Y2, 〇rthogonal, Y3, 〇rthogonal, when the polarization axes are orthogonal to each other, the γ in the tristimulus values of the ninth resin composition film, the second color resin composition film, and the third color resin composition film are measured in the same manner as the above-described parallel The value of the time. A photosensitive resin composition composition for a color filter, which is composed of a first color photosensitive resin composition, a second color photosensitive resin composition, and a third color photosensitive tree composition, by combining with each other a 3 color dye photosensitive resin composition group for transmitting a color image through a light filter, wherein the photosensitive resin composition group is formed by separately forming a photosensitive resin composition of each color and sandwiching it on a pair of polarizing plates, respectively, in a polarizing plate When the polarization axes are parallel to each other and the three-stimulus values rx, γ, and z" of the CIE (International Commission on Illumination) 1931 color system of the film of each color are measured, the white color obtained by the following formula is displayed. Coordinates (/heart as ^'-^^ and display black coordinates (u biack, v'black) at coordinates Pl (0 18, 0.52), coordinates QK0.25, 〇·52), coordinates 1 (0.23, 0.42), The coordinate of the four coordinates of the coordinates SK0.15, 0.42) is within the range of the line; 9 u white—4Xwhite/(xwhite+i5Ywhite+3Zwhite) 68 315918 revision 1359959 Patent No. 93116646, October 28, 100, revised replacement page V White —9 Ywhite/(X\vhite+ 1 5 Ywhite+] Zwhi Te) U black—4Xblack'(Xblack+15Yblack+3Zblack) ) V black—9Yblack/(Xblack+ 15Yblack+3Zblack) where Xwhite, Ywhite, Z white, Xblack, Yblack, and Zbiack are values obtained by the following formula; Xwhite_(X 1, parallel + X2, parallel + X3 , parallel) / 3 Ywhite = (Yi, paraiiei + Y2, parallel + Y3, parallel) / 3 ^ white (Z i , parallel~^^2, parallel^" 23,parallel)/3 Xblack (Xi,orth〇g〇nal+X2,ortliogonal + X3,orthogonal)/3 Yblack (Yl,orthogonal+Y2,orthogonal + Y3,〇rthogonal)/3 Zblack (Zi,orth〇g 〇nal+Z2,orthogonal + Z3,〇rth〇g〇nal)/3 Xl, parallel, Y, parallel, Zi, para"ei" in the gas is one of the films of the first color sandwiched by the polarization axis For the polarizing plate, the three-stimulus value "X, Y, z" of the transmitted light is measured using the three-wavelength tube light source shown in Fig. 1 as a backlight; "X2 parauei, 2, parallel" g and 3, parallel, Y3, parallel, Z3, and paraUel" indicate the third stimulus of the film when the polarization axes are parallel to each other and the three stimulus values X, Y, and Z of the film of the third color. The value when the above-mentioned third color is measured in the same manner; l'. Rthogonai Y1〇rth〇g〇nai, Zi 〇rth〇g_i", "X2,.r-g〇nai, ^2,orthogonal ' Λ ., , ., "Y ” 'orthogonal" X3, 〇rth〇gonai, Y3〇rth〇g〇nal, 3, or orthogonalJ, when the polarization axes are orthogonal to each other, the three stimulus values "x, Y, z" of the film of the first color, the film of the second color, and the film of the third color are as described above. The value when measured in parallel with the same situation. 15. The pattern will be the first in the scope of patent application 14! Color, 2, 315, 918, revised version 69 1359959 _ Patent No. 93116646, October 28, 100, revised replacement page 'The color and the third color photosensitive resin composition are sequentially developed on the substrate in any order. • 16. A color filter containing the pattern of item 15 of the patent application. ' 17. Liquid crystal display device < A color filter having a patent application range of item 16. 70 315918 revision