1231746 九、發明說明： 【發明所屬之技術領域】 本發明係有關於一種含有動物性蛋白質之營養補 充品的脫鹽方法及其離子交換樹脂的再生處理方式，尤 指一種含動物性蛋白質之營養補充品的半成品經過離 子交換裝置並予以濃縮後，即可形成一脫鹽的營養補充 品，同時，在脫鹽過程中所使用離子交換樹脂則可經再 生處理，使其可回收循環使用。 【先前技術】 按，華人食補的觀念由來已久，即使是物產豐富、 營養來源不虞匱的今日，食補仍是華人的最受，且不曾 稍減，尤其是生病初癒、開刀後、月經過後、甚至是平 常時，總是會利用食補作為營養的補充，以期身體能早 曰恢復元氣、增加抵抗力，但是，因工商業社會較為繁 忙，且目前之家庭大都屬於雙薪小家庭，也就是夫妻都 須外出工作，所以，花時間買食物回家燉煮、熬湯較不 可行，尤其對於不擅烹煮的婦女而言，更難以達成；於 是，近年來一種快速、簡便的食補新型態，便逐漸被發 展、推廣起來，這種新的食補型態強調消費者可隨時、 隨地飲用，既方便又快速的補充體力，故而深受消費者 喜愛。 而通常這種食補的營養補充品皆是以動物性組織 為主要原料，將之經過燉煮、濃縮後，即成一含有動物 性蛋白質及高濃縮的機能活性成份之營養補充品，且由 1231746 於該營養補充品的蛋白質是經過萃取，已成為較易於為 腸胃吸收之蛋白質，所以其具有可以迅速恢復體力及增 強精神集中。 然，此種含動物性蛋白質的營養補充品雖可達上述 多項良好的效果，但是，並不是每個人都適合飲用；其 主要是因為該營養補充品中除含有蛋白質外，因其經過 濃縮，使其含鹽成份亦相對較高，尤其是鈉鹽，這就是 為什麼該營養補充品鹽份南的原因；正因如此，對於習 慣清淡飲食的消費者而言，便較不能接受，而對於具有 心企管疾病、腎臟病、高血壓患者及兒童等，也較不適 宜飲用，致使此種營養補充品可供飲用的對象受到限 制，無法達到成為大眾化、普遍化之營養補給品。 因此，如何才能將含動物性蛋白質的營養補充品中 所含之鹽予以降低，藉以改善口感、且對於具有心血管 疾病、腎臟病、高血壓患者及兒童適宜飲用，為業者積 極研發的目標；商業上，脫鹽方法很多，離子交換法是 諸多方法中之一種。由於動物性蛋白質的營養補充品， 經離子交換脫鹽時，存在於動物性蛋白質營養補充品中 ^部份蛋白質，會在脫鹽步驟同時為樹脂吸附損失，這 疋離子交換脫鹽的一大障礙。而本發明人即是鑑於上述 之情形，不斷的研發、試驗，乃在今日研發出一種可將 含有動物性蛋白質的營養補充品進行損失蛋白質最少 的脫鹽程序，並令在脫鹽程序中所使用之離子交換樹脂 得以再生之方法。 曰 【發明内容】 1231746 之总春主要目的’係提供—種含有動物性蛋白質 充品的半成品依序經過一雜工丄“礼…俊吕脣補 .^ x斤左過離子交換裝置的兩支管柱，且 離早二# t別置以強酸性陽離子交換樹脂、強驗性陰 陽齙二’以令營養補充品之半成品首先經強酸性 與樹脂該半成品之陽離子〔含納離子〕會 $ ‘子乂換，待再經過強鹼性陰離子交換樹脂 H 中之陰離子會與樹脂之氫氧根離子交換，最 後經浪縮，即可成—含鹽量低、且澄清的營養補充品。 本發明之另-主要目的，係提供—種含有動物性蛋 白質之脫鹽營養補充品的離子交換樹脂的再生處理方 式，其主要雜離子交換裝置巾的兩餘先分別以水逆 洗出沉積於管柱内含蛋白f之物f，並予以沈殿回收， 接著丄以回收之氫氧化鈉、水、鹽酸、水依序通過具陽 離子交換樹脂之管柱，且該鹽酸可回收，供下次陰離子 交換樹脂再生前段處理使用，而以回收之鹽酸、水、氫 ，化鈉、水依序通過具陰離子交換樹脂之管柱，同時， 氫氧化鈉可回收，供下次再生時陽離子交換樹脂前段處 理使用’以達離子交換樹脂的再生循環使用。 【實施方式】 而為令本發明之技術手段、創作目的及其所能達成 之效果能夠易於明白了解，茲請一併參閱所揭之圖式及 附表’並詳細說明如下： 首先，本發明之含有動物性蛋白質之營養補充品的 脫鹽流程為： 1231746 (1) 將動物性組織經過初步的處理後，再與水以 ，解，以使缴煮或水： 3補充―有讀動物性組織所具的各種; (2) 接著，將燉煮後動物性組織的肉敍油料 令營養補充品半成品中不含脂肪； 示 ⑽·之營養補充品半成品予以過據 充品半成品不含雜質，更為純淨； us養補 咖將過舰之純淨營養補充品半成品的溫度 °C〜55°C之間，並以每分鐘約U至，M.3倍樹脂在體^ (bed v〇lume)量的流速〔SV約65〜8〇〕’流經過一早 =換裝置，雜子交減置+财二管柱，於一 官柱中充填具強酸性陽離子交換樹脂，且該陽離 換樹脂是採以氫離子形式，其之種類、規格為心⑽ SK1B ’而另-管柱中則填充具強驗性陰離子交 脂，該陰離子交換樹脂則是採氫氧根離子形式，其之 種類、規格為DIAION NSA100 ; 八 (9首先，先令營養補充品半成品控制流量在7· 〇到〇 倍陰離子交換樹脂體積内，流經其一管柱内的強酸性 陽離子交換樹脂，使營養補充品半成品中之陽離子〔含 鈉離子〕與陽離子交換樹脂之氫離子交換； 3 (6)，令營養補充品半成品流經另—填充以強驗性陰離子 父換樹脂之管柱，此時營養補充品半成品中之陰離子 會與陰離子交換樹脂之氫氧根離子交換； ⑺經過上述之離子交換裝置後，該t養補充品半成品便 1231746 形成一低鹽含量之營養補充品半成品，即其pH值可控 制在5. 85以上，請參附表一及附表二，其分別為營養 補充品半成品在未經過離子交換裝置前及經過雜子交 換裝置後之成份比較表〔其中，此處之營養補充品半 成品係以雞湯及牛肉湯為實施例〕，由附表一及附表二 的相互比較後，可知營養補充品半成品經過離子交換 裝置後之去除鹽的效果達80%以上； (8)最後，將低鹽含量之營養補充品半成品再經濃縮處 理，即可得到風味良好，且澄清金黃色之低鹽營養補 充品。 附表一、營養補充品半成品在未經離子交換樹脂處理 前之成份 未經離子交換處理雞湯 未經離子交換處理牛肉湯 Na 550 ppm 418 ppm K 1050 ppm 1276 ppm Cl 1290 ppm 542 ppm P 392 ppm 73 ppm 蛋白質 4.6 % 8.3 °/o Ash 0. 38 % 未測 Brix° 6 7.2 pH 5.9 5.87 9 1231746 附表二、 呂養補充品半成品在經離子交換樹脂處理後 之成份 矣處理雞湯 經離子交換處理牛肉湯 Na -ppm < 190 ppm K -^^30 ppm 〈1〇 ppm Cl J)U. <230 ppm P -B ppm 1· 6 ppm 蛋白質 ——% 4.2 % Ash _Ml % 未測 Brix° ——_ 5.2 ^ pH -6.31 6. 11 古士· m 志去也&, 一 註：Ν· D表未檢夠到 另，本發明在完成營養補充品的製造後，為進行二 管柱中所充填的陽離子交換樹脂及陰離子交換樹脂 再生處理的流程為： 曰、 ⑴將二離子交換裴置之管柱分別先以1〇倍樹脂體積 (bed volume)量的水逆洗出沉積於管柱内的含蛋白質 物質，並給予沉殿回收； (2) 繼於充填有陽離子交換樹脂的管柱中，以流速每分鐘 0.1倍樹脂體積量的速度將1·5Ν氫氧化鈉溶液以2倍 樹脂體積量的流量通過； ° (3) 接著，以12倍樹脂體積量的水與2倍樹脂體積量的 2Ν鹽酸分別順流通過陽離子交換樹脂； (4) 再以2倍樹脂體積量的水順洗和10倍樹脂體積量的 10 1231746 逆流通過％離子交換樹脂； (3又，純填有陰離子交換樹脂的管柱中，先以流速每 ?鐘”倍樹脂體積量的速度將2N鹽酸溶液以2倍樹 脂體積量的流量通過； 6)f St 12倍樹脂體積量的水與2倍樹脂體積量的 • 5N風氧化納溶液分別順流通過該陰離子交換樹脂； ⑺以2倍樹脂體積量的水順洗和ι〇倍樹脂體積量 的水逆流通過陰離子交換樹脂； « j此’即可H柱中各別所具之陽離子交換樹脂 及陰離子交換樹脂再生利用。 口再者，於具陽離子交換樹脂的管柱中，所通過鹽酸 可予以回收’供下次欲通過具陰離子交換樹脂之管柱使 而具陰離子交換樹脂的管柱，其所通過的氫氧化納 /合液亦可回收，供給下次其欲通過陽離子交換樹脂之管 柱利用。 又，營養補充品半成品在流經離子交換裝置時，其 =留時間的控制與樹脂交換能力的管制，都與去除鹽後 、pH值有相關係’且為影響產品品質的重要關鍵。 以流之外，若直接市售未經去鹽處理的營養補充品 之後再每分鐘丨·2倍樹脂體積量通過該離子交換裝置， 之附鉍濃縮至Brix。 12時，則得之除鹽效果如下面 〔其係以市售之雞精為實施例〕，其鈉離子 、欵果達84· 9%，且其外觀仍保留澄清之金黃色。 1231746 附表三、營養補充品經離子交換樹脂處理前後之比較 未經處理雞精 經處理雞精 Na 883 ppm 133 ppm K 1010 ppm 90. 6 ppm P 838 ppm 131 ppm Ca 13.3 ppm 13. 1 ppm Mg 68. 6 ppm 59.3 ppm Brix° 12 12 pH 5. 95 6.4 由於過去只有一些牛奶乳清中去除鈉鹽的研究，但 在營養補充品中去除鹽的研究則幾乎沒有；今，本發明 即可提供低鈉的營養補充品，且可保存其原有之風味與 澄清之外觀，故，其不但可改善口感，而且適宜腎臟病、 心血管疾病、高血壓、曱狀腺腫大患者與兒童飲用，使 其形成大眾化的營養補充品者。 綜上所述，本發明實施例確能達到所預期之使用功 效，又其所揭露之具體構造，不僅未曾見於同類產品 中，亦未曾公開於申請前，誠已完全符合專利法之規定 與要求，爰依法提出發明專利之申請，懇請惠予審查， 並賜准專利，則實感德便。 12 1231746 【圖式簡單說明】 第一圖：係本發明之脫鹽方法的流程圖 第二圖：係本發明之離子交換樹脂的再生處理流程圖 131231746 IX. Description of the invention: [Technical field to which the invention belongs] The present invention relates to a method for desalination of nutritional supplements containing animal protein and the regeneration treatment method of ion exchange resin, especially a nutritional supplement containing animal protein After the semi-finished product is passed through the ion exchange device and concentrated, a desalted nutritional supplement can be formed. At the same time, the ion exchange resin used in the desalination process can be recycled to make it recyclable. [Previous technology] According to the Chinese people, the concept of food supplement has a long history. Even today, the product is rich and the nutrition source is not scarce. Today, the food supplement is still the most popular among the Chinese, and it has not been slightly reduced, especially after the illness is healed, after the operation, and after menstruation. Or even in normal times, they always use food supplements as nutritional supplements, in order to restore their vitality and increase their resistance early. However, due to the busy industrial and commercial society, and most of the current families belong to small families with double pay, that is, both husband and wife. You have to go out to work, so it ’s not feasible to spend time buying food to go home to stew and boil, especially for women who are not good at cooking. So, in recent years, a new type of fast and easy tonic, It has gradually been developed and promoted. This new type of food supplement emphasizes that consumers can drink at any time and any place, which is convenient and fast to replenish their physical strength, and is therefore loved by consumers. Generally, this kind of nutritional supplements are based on animal tissues. After being boiled and concentrated, they become a nutritional supplement containing animal protein and highly concentrated functional active ingredients. The protein of the nutritional supplement is extracted, and has become a protein that can be easily absorbed by the stomach and intestines, so it can quickly restore physical strength and enhance mental concentration. Of course, although this kind of nutritional supplement containing animal protein can achieve many of the above good effects, it is not suitable for everyone to drink; it is mainly because the nutritional supplement contains protein in addition to its concentration, It also has a relatively high salt content, especially sodium salt, which is why the nutritional supplement has a low salt content; for this reason, it is less acceptable for consumers who are used to a light diet, and for those who have a light diet. Cardiovascular diseases, kidney diseases, patients with hypertension, and children are also less suitable for drinking. As a result, the number of people who can drink this nutritional supplement is limited, and it cannot reach a universal and universal nutritional supplement. Therefore, how to reduce the salt content of nutritional supplements containing animal protein to improve the taste and to be suitable for patients with cardiovascular disease, kidney disease, hypertension and children, is the goal of active research and development by the industry; Commercially, there are many desalination methods, and ion exchange is one of many methods. Due to the nutritional supplements of animal proteins, some of the proteins present in the animal protein nutritional supplements during ion exchange desalination will lose resin adsorption during the desalination step, which is a major obstacle to ion exchange desalination. In view of the above situation, the present inventors have continuously researched and developed, and today they have developed a desalting procedure that can minimize the loss of protein in nutritional supplements containing animal protein, and make the use in the desalting procedure. Method for regenerating ion exchange resin. [Abstract] The main purpose of the total spring of 1231746 'is to provide—a semi-finished product containing animal protein fillings is sequentially passed through a handyman's ceremonial “Li ... Junlu lip supplement. ^ X cat left through the two columns of the ion exchange device In addition, from the early second #t, a strong acidic cation exchange resin and a strong yin and yang yin are placed separately so that the semi-finished product of the nutritional supplement is first subjected to strong acidity and the cation of the semi-finished product (containing sodium ions) will be In other words, the anions in the strongly basic anion exchange resin H will be exchanged with the hydroxide ions of the resin, and finally, after wave reduction, a low-salt, clear nutritional supplement can be formed. Another aspect of the present invention -The main purpose is to provide a regeneration treatment method of ion exchange resin containing desalinated nutritional supplements containing animal protein. The two remaining major ion exchange device towels are first washed with water to deposit the protein contained in the column. The f of f is recovered by Shen Dian, and then the recovered sodium hydroxide, water, hydrochloric acid, and water are sequentially passed through a column with a cation exchange resin, and the hydrochloric acid can be recovered for the next time Ion exchange resin is used in the first stage of regeneration, and the recovered hydrochloric acid, water, hydrogen, sodium chloride, and water are passed through a column with an anion exchange resin in sequence. At the same time, sodium hydroxide can be recovered for the next stage of cation exchange resin in the next regeneration. Process and use 'to reach the regeneration cycle of ion exchange resin. [Embodiment] In order to make the technical means, creative purpose, and effect of the present invention easy to understand, please refer to the drawings And the attached table 'and the details are as follows: First, the desalination process of the animal protein-containing nutritional supplement of the present invention is: 1231746 (1) After preliminary processing of animal tissues, and then with water to resolve, Cooking or water: 3 supplements-there are various types of animal tissues; (2) Next, the meat of the animal tissues after stewing will make the semi-finished products of nutrition supplements free of fat; The semi-finished product is processed according to the filling. The semi-finished product contains no impurities and is more pure; us nourishing coffee will pass the temperature of the semi-finished product of pure nutritional supplements of the ship between ° C ~ 55 ° C, and At a flow rate of about U to M. 3 times the bed volume (bed v. 0lume) per minute [SV about 65 ~ 80], flow through the morning = change the device, reduce the number of heterozygotes + the second column A strong acidic cation exchange resin is filled in an official column, and the cation exchange resin is in the form of hydrogen ions, and its type and specification are heart SK1B ', and the other-the column is filled with strong anion Cross-fat, the anion exchange resin is in the form of hydroxide ion, its type and specifications are DIAION NSA100; eight (9 First, the semi-finished product of nutritional supplements should be controlled to a flow rate of 7.0 to 0 times the volume of the anion exchange resin Strongly acidic cation exchange resin flowing through one of the columns, so that the cations [containing sodium ions] in the semi-finished product of nutritional supplements exchange with the hydrogen ions of the cation exchange resin; 3 (6), the semi-finished product of nutritional supplements flows through the other —Filled with a column with strong anionic parent exchange resin, at this time, the anions in the semi-finished product of nutritional supplements will be exchanged with the hydroxide ion of anion exchange resin; ⑺ After passing through the above ion exchange device, the semi-finished product of t nutrition supplements 123 1746 Forms a semi-finished nutritional supplement with a low salt content, that is, its pH value can be controlled above 5. 85. Please refer to the attached table 1 and 2. The semi-finished nutritional supplement is before and after passing through the ion exchange device. Comparison table of the components after the hybrid exchange device [wherein the semi-finished products of nutritional supplements are chicken broth and beef broth as examples] From the comparison between the first and second schedules, it can be seen that the semi-finished products of nutritional supplements undergo ion The effect of removing salt after the exchange device is more than 80%; (8) Finally, the semi-finished nutritional supplements with low salt content can be concentrated to obtain low salt nutritional supplements with good flavor and clear golden color. Attached Table I: Ingredients of semi-finished products of nutritional supplements before ion exchange resin treatment. Non ion exchange treated chicken soup. Non ion exchange treated beef soup. Na 550 ppm 418 ppm K 1050 ppm 1276 ppm Cl 1290 ppm 542 ppm P 392 ppm 73 ppm protein 4.6% 8.3 ° / o Ash 0. 38% not measured Brix ° 6 7.2 pH 5.9 5.87 9 1231746 Table II. Ingredients of Lu Yang supplements semi-finished products after being treated with ion exchange resin 矣 Treated chicken soup with ion exchange processed beef Soup Na -ppm < 190 ppm K-^^ 30 ppm <10ppm Cl J) U. < 230 ppm P -B ppm 1.6 ppm protein-% 4.2% Ash _Ml% not measured Brix ° ---- _ 5.2 ^ pH -6.31 6. 11 Gu Shi · Shi Zhiye &, Note: The ND table is not detected enough. In addition, after the nutritional supplement is manufactured, the present invention is performed in a two-column column. The process of filling the cation exchange resin and anion exchange resin is as follows: First, the two ion exchange columns are placed in the column with 10 times the resin volume (bed volume). Protein-containing substance and give Shen Dian back (2) Following the column filled with cation exchange resin, pass a 1.5N sodium hydroxide solution at a flow rate of twice the resin volume at a flow rate of 0.1 times the resin volume per minute; ° (3) Next , 12 times the resin volume of water and 2 times the resin volume of 2N hydrochloric acid were passed through the cation exchange resin in parallel; (4) 2 times the resin volume of water was washed forward and 10 times the resin volume of 10 1231746 was passed countercurrently. % Ion exchange resin; (3, in a purely filled anion exchange resin column, first pass a 2N hydrochloric acid solution at a flow rate of 2 times the volume of resin at a flow rate of one second per volume of resin; 6) f St 12 times the volume of resin and 2 times the volume of resin • 5N wind-oxidized sodium solution pass through the anion exchange resin, respectively; 顺 Wash with 2 times the volume of resin and water countercurrently Through anion exchange resin; «jthis' can regenerate the cation exchange resin and anion exchange resin in the H column. Furthermore, in the column with cation exchange resin, the hydrochloric acid can be recovered. 'For the next time the column with anion exchange resin is used to pass through the column with anion exchange resin, the sodium hydroxide / liquid passed through it can also be recovered and used for the next time it is used through the column with cation exchange resin. . In addition, when the semi-finished product of nutritional supplements flows through the ion exchange device, the control of the retention time and the control of the resin exchange capacity are both related to the pH value after salt removal, and it is an important key that affects the product quality. In addition to the flow, if a commercially available nutritional supplement without desalting treatment is directly sold and then twice the resin volume per minute passes through the ion exchange device, the attached bismuth is concentrated to Brix. At 12 o'clock, the salt removal effect is as follows [It is a commercially available chicken essence as an example], its sodium ion and capsule fruit reach 84.9%, and its appearance still retains a clear golden yellow. 1231746 Table III. Comparison of nutritional supplements before and after ion exchange resin treatment. Untreated chicken essence treated chicken essence Na 883 ppm 133 ppm K 1010 ppm 90. 6 ppm P 838 ppm 131 ppm Ca 13.3 ppm 13. 1 ppm Mg 68. 6 ppm 59.3 ppm Brix ° 12 12 pH 5. 95 6.4 As there have been only a few studies on removing sodium salts from milk whey in the past, there have been few studies on removing salts from nutritional supplements; today, the present invention can provide low sodium Nutritional supplement, which can preserve its original flavor and clarified appearance, so it can not only improve the taste, but also suitable for patients with kidney disease, cardiovascular disease, hypertension, splenomegaly and children to drink, so that it can form Popular nutritional supplements. In summary, the embodiments of the present invention can indeed achieve the expected use effect, and the specific structure disclosed is not only not seen in similar products, nor disclosed before the application, and has fully complied with the provisions and requirements of the Patent Law. If you apply for an invention patent in accordance with the law, you are kindly requested to review it and grant the patent. 12 1231746 [Brief description of the figure] The first picture: a flow chart of the desalination method of the present invention The second picture: a flow chart of the regeneration process of the ion exchange resin of the present invention 13