TWI299068B - - Google Patents

Description

1299068 V. INSTRUCTIONS (Invention 篏"# The present invention relates to grafted polymer coatings, especially to cotton and cotton fibers and fabrics, with respect to color, color fastness, shrinkage, abrasion resistance; The field of 3 dyeability and feel f. In a specific embodiment Γ The invention also relates to the addition of a stretch recovery rate to cotton and cotton polyester fibers. BACKGROUND OF THE INVENTION A fabric for use in children's wear should have such softness Degree, excellent colorability, color fastness and the characteristics of the ochre color. In addition, the clothes are preferably micro-durable. Many consumers prefer cotton, not only because they are natural fibers, but also because they are typically equivalent. Soft. However, fabrics used in children's wear and similar applications typically have poor performance in terms of color, abrasion resistance, color fastness, stain resistance, and shrinkage. Cost is an important factor in children's wear. The materials processing and dyeing methods used in the manufacture of children's clothing are different from those of applications such as adult clothing. For example, children's clothing can be pigmented compared to the more expensive reactive wood used in adult clothing. Combination printing of viscous glue. Since the colorant pigment is not easily transferred into or fixed to the cellulose fiber, the fixer is typically used for improved fastness. A soft polymeric adhesive or resin is used as a fixer. Useful fixers include Mingfan, casein, starch, acrylic, rosin, polyvinyl alcohol, and cationic colorant fixers, which improve durability by encapsulating and bonding pigments to the fiber surface. Adhesives and resin-based surface treatment agents, which generally only have a degree of fastness, so that they only moderately improve durability. The combination of a solvent or a resin also hardens the appearance of a textile like it, and it usually has a liquid distribution. This paper scale applies to China's National Standard (CNS) A4 specification (plus x 297 public praise) 1299068 A7 _— _____Β7 V. Invention description (2—) ' '~ -- and the absorption properties have a negative effect. It is mainly transferred from the surface of the colored fabric to the adjacent area or the other surface of the fabric via friction. The color fastness is the color fastness to the rubbing. Shadows require excess _ and sticky m _ fat, which are easily rubbed off or tarnished. Using this dyeing method to produce a dark blue color with acceptable ochre will result in unacceptably stiff clothing. The colour fastness/colour fastness of dyed textiles is a continuing problem in the textile industry. The current improvement of one or more properties, such as the technique of ochre, leads to at least the feel of the hand and usually also shrinks. Furthermore, the performance of the treatment agent is not good for the fabric during the washing process. It is known to graft a specific chemical substance onto the cotton fiber. U.S. Patent No. 2,789,030 discusses the use of glyoxal. A method of modifying a cellulosic fabric with a modified acrylate monomer. Professor U.S. Patent No. 3,989,454 uses high energy gamma radiation as an initiator and water/methanol as a solvent to uronic acid ester, especially ethyl acrylate monomer. Grafted onto cotton and mercerized cotton. U.S. Patent No. 4,901,398 teaches a grafting reaction of a fibrous material in which a free radical is formed and then a grafted fluorinated monomer, especially a fluorinated acrylate, is added. Grafting can advantageously be facilitated by the addition of a graftable derivative of morphine, i.e., ethyl morpholine acrylate. U.S. Patent No. 4,73,15,6, discloses the use of cationic cellulose graft copolymers to improve dye fastness to dyed textile substrates via post-dye coating (top up). A latex coating composition of an emulsion of an acrylate monomer and a glyoxal curing resin is disclosed in U.S. Patent No. 4,524,093. -6 - This paper scale applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 1299068 A7 _________B7 V. Invention Description ~~ ----- One method of Wenliang feel is to treat the fabric with soft and fine. It has been well known for a while to use polyfluorene to soften the fabric, i.e. to provide a moisturizing effect between the fibers and the yarn so that it can more easily move over each other. In addition, there have been many documents describing the use of organically modified polysulfide as a textile treatment for many years (Mc. U.S. Patent No. 4,62,878, 47,57,4,*, U.S., 4,824,877, U.S. Patent Nos. 4,824,890, issued toK. Typically this type of polyfluorene is delivered to the textile as an aqueous emulsion. Other polyoxygenated fluids, such as polydioxane, provide additional benefits such as improved fabric texture. An example of such pre-emulsified polyfluorene is a (4) emulsion (350 cs) of polydimethyl sulphur oxide sold by Dow Corning Corporation (Dow Conung Corporatl) under the trade name D〇w CORNING 1157 (TM) Flu_ Singular company (General Electnc. Claw to 叮) by trade name

General Electric SM 2140(TM) Silicones Locked 50% Emulsion (10,000 Å) of Polymeteoxime. This composition is typically added to laundry or washing water for washing operations. A water-based, water-dispersible microemulsion of from about 1% to about 5% by weight of the microemulsion functional polyoxyl. The composition is diluted in a wash or rinse. U.S. Patent No. 5,61,758, the disclosure of which is incorporated herein by reference. Cationic polyoxo compositions of vinegar, nylon, acrylic, aryl decylamine, cotton, wool, and blends thereof. It is known in the art to use a poly ΐ ΐ compound to treat synthetic fibers. For example, the discussion of epoxy polyoxyl in U.S. Patent No. 2,947 W i. This polyoxyxide can increase the lubricity of the right fiber and the improved fabric of the fiber made therefrom. Applicability to China National Standard (CNS) Λ4 Specifications (210 X 297 mm) 1299068 A7

degree. However, epoxy polyoxyxene has the disadvantage of having only limited durability when it is used in synthetic fibers. Specific amine polyfluorene oxides are also used in the art to treat fibers. Since these polyoxygens do not have a net charge, they are not effectively adhered (generally by electrical attraction) to cellulose or protein-containing materials. In fact, when used in combination with conventional polyester fiber/cotton blends, the amine polyoxyl oxide will only stick to the polyester within the blend. In an attempt to overcome these problems, it is known to use a cationic compound adhered to a cellulosic material. Particular cationic compounds are known in the art, such as some specific cationic polyorganodioxanes (see, for example, U.S. Patent No. 4,472,566) and fourth nitrogen derivatives of organooxanes (such as those discussed in U.S. Patent 4, 185, 〇 87). Other suitable fabric softening compounds are non-fourth guanamine and non-fourth amine. One commonly cited material is the reaction product of a hydrazine fatty acid with a hydroxyalkylalkylene diamine. See U.S. Patent Nos. 4,460,485, 4,421,792, and 4,327,133. U.S. Patent No. 2,952,892 describes a method of modifying cellulose fibers with a composition comprising an acrylic prepolymer and a polyoxosiloxane such as an alkyl polyoxyalkylene. U.S. Patent No. 5,951,7, the disclosure of which is hereby incorporated by reference in its entirety in its entirety in the entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire entire content To improve the color fastness on dyed cotton. U.S. Pat. Ester, a method of chemical bonding to many fibers 'including cellulosic cotton. This patent describes the use of graft initiators. This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1299068

Such as iron salts: peroxides such as urea peroxide. The purpose of grafting is to provide a surface that can be combined with ink jet printing for high resolution imaging. U.S. Patent No. 5,552,472, the disclosure of which is hereby incorporated hereinby incorporated by reference in its entirety in its entirety in the the the the the the the the the the the the the The branches control the porosity of the fabric and are used to control the permeability of the air bag. A composition comprises a grafting initiator such as a metal ion; a catalyst such as a peroxide, peroxy &L or per phthalate, Branched prepolymers, such as water-dispersible amine-based SiL S 曰 ' and monomers, such as propyl acrylate. U.S. Patent No. 5,763, 557, the disclosure of which is incorporated herein by reference The chemically grafted coated polymeric composition 'includes the use of a monomer/prepolymer, a catalyst, a graft initiator, and other components of the composition. The coating can be advantageously applied to reemay and satin The acetate fabric is graft polymerized to form a polymeric film that is strongly bonded to the textile substrate by a strong adhesion. Preferred compositions comprise a grafting initiator such as a metal ion; a catalyst such as a peroxide a graft prepolymer such as a urethane and/or an acrylic; a monomer such as an acrylic; and a sodium salt of an AMPS monomer. US Patent No. 6, 165, 919 teaches a cellulose material such as a cotton fabric and paper with a polymer comprising (A) an ethylenically unsaturated polycarboxylic acid monomer or a salt thereof, a shell having one or more dicarboxy groups (wherein the carboxyl group is on an adjacent carbon atom); a saturated α-hydroxypolycarboxylic acid or a salt thereof; and (C) a composition of one or more curing catalysts which are crosslinked and heated to react with a carboxyl group in a reaction product of (Α) and (Β) with a cellulose hydroxyl group. The method of esterification and cross-linking of cellulose is produced. -9- The paper scale is applicable to China National Standard (CNS) Λ4 specification (210 X 297 mm) 1299068 A7 B7 V. Invention description (6 ) Used formaldehyde base Reagents such as dimethanol dihydroxyacetamide, urea-aged, and melamine-formaldehyde are used as wet strength agents to treat paper, while imparting such valuable properties to cellulose fibers. However, formic acid stimulators and known Carcinogens. In addition, 'formaldehyde-based reagent fibers There is a serious loss of strength in the fabric. Therefore, there are severe restrictions on the manufacture of aldehydes from textile garments. It is also known to use glyoxylated polypropylene decylamine-diallyldimethylammonium hydride copolymer resin as Paper Dry Strength and Temporary Wet Strength Resin. Many formulations that improve color fastness, improved hand feel, and reduced shrinkage are taught in the art. There is a need for an easy treatment of fabrics, especially cotton and cotton-polymeric pushers to reduce An inexpensive composition and method for color fastening, improved color fastness, and reduced shrinkage, wherein such a treating agent does not adversely affect the hand. The treating agent can withstand at least 20 washing cycles with less performance degradation. A treatment agent applied to the fabric without adding a special processing step is preferred. The treatment agent can advantageously be a single stable composition having a shelf life of at least two months. The compositions of the present invention address these needs. SUMMARY OF THE INVENTION The present invention is directed to compositions and methods for improving the stain resistance, color fastness, bleed fastness, shrinkage, and abrasion resistance of textile fibers without adversely affecting the hand of the textile product. The composition comprises a formulation of a particular formulation of a monomer (which is a prepolymer herein), a prepolymer, a catalyst, an initiator, a crosslinking agent, and a specific mixture of polyoxo softener. When the composition is applied to a textile (preferably as a cotton textile), it produces a graft polymerization 'and thus forms a covalent bond to at least a portion of the fibers to the fibers - 10 _ this paper scale applies the fw 豕 standard ( CNS) A4 specification --- 1299068 V. Description of invention (7) Film. Polymerization in conventional heating and drying methods. DETAILED DESCRIPTION OF THE INVENTION Further, the mouth can be coated with 'm胄mu' and its analogs by painting, spraying, rolling, and the like. The composition may advantageously be in a specific embodiment of the present invention relating to a core liquid for forming a graft substrate comprising: a grafting primer for activating a site having active hydrogen on the substrate, the first component And comprising reacting with an activated site on the substrate to graft the first component with the functional component of the active component on the first component; and a second component comprising the substrate or the first component The activation site reacts and forms a functional group of the active site on the second component. The first and second components are grafted onto the substrate upon contact with the solution to form a grafted substrate, and one of the first and second components includes imparting softness and stain resistance to the grafted substrate. The structure, and the other of the first and second components, enhances the edge of the graft. In a specific embodiment, the invention comprises treating with a stable liquid composition comprising an activator, a catalyst, and at least 5%, at least 7% more polymerizable softener, and a sufficient amount of selected monomers or prepolymers. Cotton or cotton-polymer fibers, such as cotton/polyester, are added to the fabric of the substrate fibers by polymerization to impart softness to the fabric. In another embodiment, the invention relates to a stability formulation for a treatment composition. The formulation includes an activator, a catalyst, and at least 5%, at least 7%, more preferably a polymerizable softener, and a sufficient amount of selected monomers to add a softening polymer via polymerization to impart softness to the fabric. The so-called stability -11 - This paper scale applies to the Chinese National Standard (CNS) A4 specification (210X 297 mil) 1299068 A7 ---- —__B7 . __ V. Description of invention (8) means that the composition remains fluid and During storage for at least 2 months at a temperature of about 6 inches and about 9 inches, there is less than about 5 Å/〇 in the composition, and less than about 2% of the preferred prepolymer is self-polymerized therein. That forms an insoluble/non-suspended polymer. The fluid contains the activator and catalyst, but it does not activate at a significant rate until the fluid is exposed to high temperatures in situ in the drying and activation process. In another embodiment, the present invention is directed to a stable concentrate that can be diluted with water or other bathing agents to form the aforementioned stable formulation. The preferred softener is an aqueous emulsion of polyoxyxide oil for cotton fibers and a modified or unmodified organic polyoxane for cotton/polyester fibers. In the special case of printing cotton comprising pigments adhered to cotton fibers by glue or other adhesives, preferred soft-modified or unmodified organic polyoxane, high density polyethylene, And a combination of polyamines. : The terms fiber, yarn, filament, staple fiber and fabric are well known to those skilled in the art of textiles. In addition, the coating and handling operations mentioned are well known. However, the term "fiber" as used herein refers to individual fibers, yarns, staple fibers, and filaments, as well as to fabrics (including woven and non-woven fabrics), and to articles made of fibers and/or fabrics. The cellulose textile fiber is derived from natural glutinous rice, such as cotton, esparto grass, milkweed, rice blast, main early, ramie, and bagasse. The composition is useful for all natural fibers. Those skilled in the art of textiles are familiar with blends such as cotton/polyester blends; fabrics. 'terminology' color fastness' and/or "fastness" means when exposed To the test, p, such as -12- 1299068 A7 B7 5, invention description (9), the degree of fading or discoloration of sunlight, reactive gases, chemicals, solvents and their analogues. Color fastness or fastness Standard test methods can be utilized, such as, for example, AATCC Test Method 3-1989. The term "color" or "brightness" used herein refers to the color of the dyed fabric by friction. The extent to which the surface is transferred to another surface. Standard test procedures and equipment, such as, for example, AATCC colour meter CM.5 from Atlas Electnc Devices c., Chicago, USA, can be used for color test . The term "dyed cotton" as used herein, and dyed cotton/polyg, refers to fibers that are exposed to and incorporate at least one reactive dye. The disperse dye is used to dye the polyester. The term "reactive dye" as used herein refers to an acid, base or mordant dye having an attachment reactive group covalently bonded to the cellulosic fiber. Although reactive dyes, dyes and sulfur dyes appear to work well Used in cellulosic fibers, but the application of such dyes requires more than one process step, and it is often hindered by the slow line speeds required to achieve the proper reaction time. The term "printed cotton,. and,,, as used herein, Printed cotton/polyacetate refers to a fiber that is exposed to a pigment and an adhesive that helps bond the pigment to the fiber. Also known as one of viscous adhesives, such an adhesive is a carboxylated butadiene acrylonitrile. The term, catalyst, is used herein to mean an activity comprising J, such as a peroxide or a metabisulfite. From 0.01 N to about 1 N solution, the 〇1N solution is preferably 'typically not-defined as a fluid formulation dissolved in water. The catalyst can advantageously be added to the composition as a solution. The term "graft initiator" as used herein refers to an active ingredient, for example -13-

1299068 A7 __________B7 _— :__ V. Description of the invention (1〇) If the iron salt is from about 0.01 N to about 1 N solution, the I N solution is preferably not necessarily a fluid formulation dissolved in water. The graft initiator can advantageously be added to the composition as a solution. The compositions used herein are stated in weight percent unless otherwise indicated. The invention can be applied to the use of any polymerizable monomer such as: vinylidene gas, butadiene, isoprene, dimethylaminoethyl methacrylate, styrene, dimercaptoacrylic acid 1,3 -butyl diester, hydroxyethyl methacrylate, isobutyl vinyl ether, acrylonitrile, acrylamide, N-vinyl lauridine, glycidyl methacrylate; N-vinyl caprolactam, N-vinylpyrrolidone, N-vinylcarbazole, acrylic acid, methacrylic acid, ethyl acrylate, ethyl methacrylate, itaconic acid, isobutyl methacrylate, acrylic acid, phenethyl hydrazine Sustained sodium, ethyl phthalocyanine, diethylene glycol of ethylene glycol, divinyl ether of butanediol, vinyl toluene, vinyl acetate, octadecyl ethyl ether, and mixtures thereof And prepolymer. However, it has been found that specific combinations of monomers and prepolymers provide exceptionally good properties, including stain resistance, color fastness, and hand feel. In addition, the composition of the composition 'includes acrylic, elastomer latex, urethane, eucalyptus oil, polyamide, urethane acrylate, polyethylene dioxime - acetoin S, Nanxun B-baked, and sodium sulphate, a combination of monomers and/or prepolymers, and more particularly, a formulation of monomers and prepolymers that are commercially available. The term "prepolymer," as used herein, includes monomers, polymeric sites, short bonds, pseudo-stable polymeric chains of polymers that are generally added to the polymerization, and can react with other compounds to form polymerizable monomers.

This paper scale applies to Chinese National Standard (CNS) A4 size (2U) x 297 mm) 1299068

Or the formulation of the oligomer. The term "acrylic prepolymer" as used herein refers to a low molecular weight polymer chain having a molecular weight of less than 6,000 and preferably from about 200 to 1200. Particularly suitable for the η 仃 monomer of the present invention includes an acrylic monomer having a hydroxyl group, a carboxyl group, an epoxy group, an amine group, a hydride group and a glycidyl group functional group, that is, mercapto acrylic acid via Ethyl or Cyan , dimethyl and methacrylic acid methacrylate and diethylamine ethyl ester, acrylic acid and methyl methacrylate, ethyl ester, butyl ester, and other alkyl esters, glycidyl methacrylate, or a mixture thereof. Any of the foregoing monomers may be used alone or may be incorporated into the prepolymer. Dipropylene roasting vinegar and triacrylate can cause undesired cross-linking, so that they are present in a small amount at most. For example, 'preferred acrylic prepolymers include HELASTIC W〇-8001(TM), HELASTIC WO-8041, available from Wilmington Leather Co., New Castle, Delaware. (TM), and HELASTIC WO-8061. It is characterized by soft tensile strength, adhesion, and color stability. Other materials include ECCO-REZ 907 from Advanced Polymer, Saddlebrook, Ou. It has been found that different acrylic prepolymers produce different results' and that the optimum formulation comprises a predetermined amount of several acrylic prepolymers. The B-S resin pre-polymer is available from Eastern Color & Chemical's ECCORE GB 404(TM) formulation. More preferred is RESIN KLF (TM), which is a small amount of glyoxal resin produced by furfural. Several formulations utilize polymerizable polyoxyxides, preferably in the form of aqueous emulsions or microemulsions of polyoxygenated oils. Polyoxygenated oil-softening system: -15 in E-side. This paper scale is applicable to China National Standard (CNS) A4 specification (210X297 mm) 1299068 A7 B7 V. Inventive Note (12) Water-based polyfluorene The amount of oil emulsion is specified. Polyoxyphthalic acid and organopolyoxyalkylene provide a better hand and also improve the abrasion resistance, chemical resistance, and stain resistance. Non-functional and functional helioxanes having the above characteristics may be monomers (low molecular weight), or oligomeric or polymeric (high molecular weight), and are linear, branched or cyclic. Examples of polymeric oxoxane compounds include non-functional and organofunctional polyoxyalkylenes, including dimethyl polyoxyalkylene, mercaptohydrogen polyoxyalkylene, mercaptoalkyl polyoxyalkylene, methylaryl polyfluorene. Oxyalkane, methylfluoroalkyl polyoxyalkylene, and organofunctional methyl polyoxyalkylene such as amine alkyl methyl polyoxyalkylene, hydroalkyl methyl polyoxyalkylene, haloalkyl fluorenyl polyfluorene Oxyalkane, and vinylmethyl polyoxyalkylene. Examples of the monomer or polyoxyalkylene oxide include Me〇Si(Me)2-〇Me, Me3SiOMe, Me3Si(OMe)2, Si(OMe)4, Si(OEt)4, MeSi(Me)2-OSi ( Me) 2-Me, HOOC--(CH2)3-Si(Me)2-〇-Si(Me)2-(CH2)3--COOH. Examples of the cyclopentane condensate include octamethylcyclotetraoxane and decamethylcyclopentene. A preferred polyoxyxide emulsion is SEQUASOFT 69 (TM) available from Gen Corp. (Chester, SC). A preferred high molecular weight polyaerator is HELASTIC WO-8(R) 26(TM) from Wilmington Leather Company, Newcastle, Delaware. A preferred modified organopolyoxane emulsion is APS V-SOFT (TM), an advanced polymer available from Saddle Brook, New York. Polyamine prepolymer is purchased from Union Camp (Jacksonville, FL)

MICROMID 63 2HPL(TM) dispersion. A preferred urethane prepolymer is SR 9035 (TM), a preferred amino decyl acrylate is SR 9035 (TM), and a preferred polyethylene glycol diacrylate prepolymer is SR. -16- The paper size is applicable to China National Standard (CNS) A4 specification (21ΌΧ297 mm) 1299068 A7 B7 V. Invention description (13) 344(TM) 'These are purchased from Pentax Saudi Arabia (Sart〇mer c 〇). Another urethane prepolymer emulsion was rESAMINE (jMT 171(TM). The anti-chrome nonionic dispersant was CROCKFAST 2 (TM) from Aml Techn〇1〇gy (〇xf〇rd, NY). A preferred elastomer latex prepolymer is HISTRETCH V-43, available from β FG〇odrich (Cleveland, OH). #系, a highly elastic polymer with a memory that restores shape after stretching. Ethylene prepolymer emulsion is purchased from

MYKON HD from Gen Corp. (Chester, SC). The carboxylated butadiene acrylonitrile prepolymer was purchased from Re1 Chold Cheimcals (Research Triangle, NC). The grafted polymer chain is formed from monomers and prepolymers comprising groups of suitable polymerizable functionalities such as, for example, hydroxyl, carboxyl, #oxy, decylamine, amine, hydride, and the like. The triacrylate is maintained at a low level, which is undesirable for cross-linking. The water used herein is typically deionized water. Other ingredients such as alcohols, alkyl glycols, and other organic solvents can be used. One of the main purposes of the present invention is to provide chemical bonding, i.e., covalent bonding to, and what? The fiber and fabric material of the coated K material. The invention can be applied to any suitable textile material 'including acetic acid vinegar, 'cool, polypropylene; material, yoke, poly yttrium, fiber glass, acrylic acid, cellulose, poly, polyvinyl chloride, polycarbonate _, and its analogues. The invention is directed to cotton and cotton-containing fabrics. You're using cotton as the main textile fiber. Typically, it is made from cellulose between (4). The cellulose system consists essentially of a linear molecular chain. -17- 1299068 V. Inventive Note (14) A natural compound high polymer, i.e., a polysaccharide, composed of an anhydrous glucose unit bound by an oxygen chain. &7 The grafting of the polymeric material onto the fibers is accomplished by chemically bonding the octamer to the fabric substrate molecules by covalently building a surname. The grafting of the cotton fabric surface = layer can be described as including a method of activating the cellulosic molecule, attaching the monomer to the reactive site, and then increasing the chain on the attached monomer. Salty chemical grafting involves activation of the substrate (i.e., the fabric to be treated) as a first step. A method in which a free radical initiates chemical grafting of a polymeric layer onto a surface of a fabric. The acidic protons from the monomer or from the substrate are removed by the grafting initiator, thus forming free radicals. In particular, a method of chemically grafting a polymeric layer to the surface of a cotton fabric involves abstracting (acidic) hydrogen atoms from the hydroxyl groups of the cellulose molecules to form free radicals. The free radicals then initiate the formation of polymer chains. A graft initiator is used to activate the surface of the fabric and initiate polymerization. The grafting initiator is selected to capture active hydrogen from the substrate filaments or yarns to which the #枝聚合物 is bonded. The initiator is preferably a metal ion provided by ionization of a metal salt. Ferrous ions derived from ferrous ferrous sulfate, and other metal ions derived from their respective salt solutions, such as Ag+, c〇+2, and Cu+2, have active hydrogen removed, and are accompanied by initiation of active hydrogen. The ability to remove the growth of the polymer chain at the t site. Silver ions and ferrous and iron ions are preferred, although other metal salts may be advantageously utilized. The graft initiator advantageously comprises an effective concentration of metal ions selected from the group consisting of + 2, Ag + , Co , and Cu 2 . Since once the site is activated, the growth effect η can last as it does in the autocatalytic process at that site, so that the amount does not need to be large. Between 1 and 1000 ppm' 本iTis fresh (CNS) weave (2igx297 metric) on the paper scale of 丨〇 and 1 〇〇卯 • • 18-1299068 A7 __ B7 V. Description of invention (15) A preferred graft initiator is usually sufficient. When ammonium ferrous sulfate is used as the graft initiator, the salt is preferably present in the graft composition in an amount of from about 0.00 I to about 0.2 by weight π of the composition, in the group > From about 〇〇t to about 〇. 1% by weight is better. Certain iron salts perform particularly well, however they contribute to yellowing and may be less desirable for a particular application. In one embodiment of the invention, the chemical grafting of a natural or polymeric filament or yarn substrate is initiated by the reaction of a metal ion with a grafting initiator and a substrate, active hydrogen. Other specific embodiments include other methods of initiating grafting, including radiation, high or low pH, electrical processing, or combustion, and may reduce or eliminate the amount of grafting initiator in the treatment composition. In one embodiment, the initiator can be ozone or other known free radical formers. However, in such cases, the composition will not be readily available for use in yarn and fabric manufacturers. Coated and cured self-contained single-formulation composition. Active hydrogen is a hydrogen that can be relatively easily removed from the substrate by the grafting initiator. The third-order carbon, for example, is kept weaker than the hydrogen atom with the second-order carbon. a valence bond, and the hydrogen atom will be one type of active hydrogen. Other types include n_h, -OH, -COOH, -COOR-H, etc. Regarding the cellulose structure, the salt graft initiator is from cellulose-CH2 〇H removes active hydrogen, while Cellulose · CP ^ cr. Graft initiator can be removed: the active hydrogen alone, resulting in the formation of cationic sites; active hydrogen and an electron, resulting in the site free radical position; or active hydrogen and two electrons, resulting in the substrate Forming an anion position. Hydrogen abstraction produces an activation site on a substrate bonded to a monomer or prepolymer, especially a vinyl monomer. A radical radical followed by a first component or a -19- paper scale Applicable to China's national standard (CNS) A4 specification (210 X 297 public sauce) one ~ ----~ 1299068 A7

1299068 A7 B7 V. Inventive Note (17) 〇.〇 1 to about 0.1% by weight is better. The fabric according to the present invention has a graft polymer layer prepared by a method comprising treating a fabric surface with a graft initiator which is effective for chemically activating the surface of the fabric. The chemically activated surface is then contacted (or simultaneously) with an agent comprising a polymerizable monomer and a prepolymer which reacts with the surface of the activated fabric to form a polymeric layer that is grafted (i.e., chemically bonded) to the surface of the fabric. It is not expected that all of the polymerizable materials in the treatment composition will form a graft on the substrate fibers. Preferably, at least about 20% of the polymerizable material is grafted to the substrate fibers, preferably at least about 50%. The presence of grafting is confirmed when the fibers do not lose more than 50% of the treating agent after at least one wash with a general cleaning agent. Of course, the graft polymer can also be crosslinked to other grafted or ungrafted polymers. At least some of the polymerizable prepolymers have functional side chains such as a hydroxyl group, a carboxy group and a second or third amine group. The illustrated formulation is selected to provide a grafted product that provides improved texture, shrinkage, stain resistance, color fastness, and color fastness to the treated fiber. ^ The field is feasible. The reaction of the present invention utilizes an emulsion or an aqueous solution to minimize the environmental release of the organic solvent. In this regard, methods have been developed to dissolve the desired organic materials in water and to maintain a stable fluid composition. In addition, the reaction typically depletes the organic reactants with little or no organic waste left. This invention relates to the formation of graft polymers on fibers comprising cotton. The method of the present invention for chemically bonding a polymeric material to a fabric surface comprises: (a) treating the surface of the fabric with an effective grafting initiator to produce a chemically activated fabric surface; (b) rendering the activated fabric Surface and inclusion of poly = single-21- 〇

This paper scale is suitable for the country's S standard (C Qing A4 regulations to 21GX 297 public hair T 1299068 V. Invention description (18 = polymer: reagent contact, resulting in the polymer layer grafted fabric table surname After the layer is grafted onto the surface of the fabric, the chemical grafting is terminated via free radicals...3 or other mechanisms. Accordingly, the present invention provides a fabric surface for providing improved color and color, abrasion resistance, resistance Contaminant and hand-feeling properties, as well as compositions and methods for fabrics that reduce shrinkage. Polymeric materials are chemically grafted onto fabric multi-enzymes to form durable treatments.石 来 石 氧基 氧基 氧基 氧基 及 及 and at least two selected prepolymers. Grafting is initiated by a grafting initiator. Another advantage of the present invention is that the formulation is stable at room temperature, which can be obtained from concentrates, and In a preferred embodiment, all of the desired ingredients are present in a single fluid composition. The grafting initiator and catalyst are thermally activated, for example, to about 340 Torr for about 1 minute. Good self-contained Although it is not necessary to do so, it is also conceivable to use, for example, ozone or irradiation to activate cotton fibers before or during moisture absorption as a specific embodiment of the reaction. In this case, there is no activator or catalyst. The formulation will be more stable to temperature changes. An important example of the present invention is to provide a stable composition for treating fibers. The single composition concentrate of the privet (which contains all components except the solvent) is particularly advantageous. The premixing of the concentrate allows for better measurement and control of the resulting treatment formulation. The Applicant has found that the specific ratio of the particular treatment compound, as well as the concentration of several treatment components, is of considerable importance. Furthermore, the concentrate can reduce shipping and The cost of handling chemical substances. The special monomers and prepolymers used in the present invention, and the amount of their use are -22. The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) Binding 1299068 A7

No dyeing, depending on the nature of the cotton-visible cotton as known in the art. The nature of the cotton depends on whether it is a pigment, whether the cotton has other adjuvant polymeric compositions, and the like. The absolute amount of the chemical substance is not more important than the composition ratio in the composition, and the bonding sites provide the cross-linking, such as diacrylate, dipropylene vinegar, and uronic acid uric acid vinegar. Preferably, less than 1% of the generally polymerizable composition is included in a small amount, and less than (4) of the polymerizable composition is preferred. The m n softener provides at least 30% of the polymerizable (d), preferably at least 30% and, in most cases, at least m. Dyed cotton and undyed cotton As used herein, "dyed cotton, which is cotton that reacts with reactive dyes. Therefore, dyed cotton requires less protection to maintain resistance to tangency and color fastness. The reactive dyes change the fibers' and the specially adjusted treatment composition can provide an excellent combination of very soft hand, good color fastness and color fastness, and good anti-contamination and abrasion resistance. A sad method is a method of treating cotton fibers comprising the first step of providing a stability composition comprising: a glyoxal prepolymer between about 4% and about 5 Å/〇; 1% and about 3% elastomeric latex prepolymer; between about 6% and about 35% aqueous polyoxo oil emulsion; between about 0.2% and about 5% urethane An ester prepolymer emulsion; a catalyst between about 002% and about 0.3%; and a graft initiator between about 0.002% and about 0.3%. Preferably, the foregoing formulation further comprises about 0.02% and about a high molecular weight polyfluorene gas between 2%; an urethane urethane prepolymer between about 0.002% and about 0.15%; Between about 0.002% and 0.15% of polyethylene glycol dipropyl China -23- applies the present Scale ® sheet of Standards (CNS) A4 size (210 x 297 mm) bookbinding

20 V. Description of the invention The olefinic acid is cool; and the polyethylene glycol is between about 0.004% and about 2%. This, 'and. The material is stable to less than 5% of the prepolymer self-polymerization during storage for a period of at least 2 months at a temperature between about 60 Torr and 90 Torr. The ampoule composition has a solids content of at least about 5 weight percent when dried. The formulation is contacted to cotton, fibers in a second step to allow about 100 grams of cotton fibers to absorb between about 40 grams and about 120 grams of the stability composition. Contact and control moisture absorption! The method can be any method known in the art. In the third step, polymerization is carried out by polymerization to a prepolymer and polyphosphorus oil sufficient to at least 2% by weight (at least 5% by weight, preferably at least 8% by weight) to be polymerized on cotton fibers. The temperature of the object while drying the cotton fibers. It is known that some prepolymerization fields will self-polymerize during the drying step and these polymers can advantageously be loosely bonded to the fibers. This is a prior art form - it is known to crosslink the processing chemical f to itself. This treatment loses its effectiveness when the treatment chemistry is removed. However, the treatment chemicals of the present invention are grafted to the fibers in substantial proportions and, therefore, are not easily removed by grinding and washing. One of the advantages of this method is that the treatment chemistry is first applied followed by drying (typically at temperatures between 300 T and 400 T), for example, routinely on the end frame during stretching. In one embodiment, the treatment composition is a stable single contact formulation wherein the activator and catalyst are co-present in the stability formulation with the prepolymer. This formulation can be stored and used at normal ambient temperatures without condensation or polymerization. In a more preferred embodiment, the cotton fiber is coated with a stability composition comprising the following ingredients: at about 0.8% and about 3.5 Å/. Glyoxal prepolymer between; applicable to Chinese National Standard (CNS) A4 specification (210X297 mm) at -24- paper scale 1299068 A7 _ B7 V. Invention description (21) About 0.2% and about 2% An elastomeric latex prepolymer; an aqueous polyoxo oil emulsion between about 8% and about 30%; a urethane prepolymer emulsion between about 0.8% and about 4%; 0.006% and about 0.2% of the catalyst; and between about 0.006% and about 0.2% of the graft initiator. Preferably, the stabilization composition further comprises between about 0.1% and about 1.5% high molecular weight polyoxynium; between about 0.004% and about 0.08% of the urethane urethane prepolymer; at about 0.004% And between about 0.08% of polyethylene glycol diacrylate; and between about %/〇 and about 1% of polyethylene glycol. Concentrations and moisture uptakes conflict to some extent, but have particular advantages in more concentrated formulations' including less solvent for evaporation. In one embodiment, the contact will absorb between about 60 grams and about 1 gram of the composition, and the composition will absorb up to about 100 grams of cotton fibers. The drying temperature is between about 110 °F and 440 °F, preferably between about 250 T and 400 ° Fi, say about 340 ° F, and the drying time is between about 10 seconds and 10 minutes, for example. About 1 minute. Not based on theory, it is believed that both water loss due to drying and high temperatures promote efficient grafting and polymerization. A preferred treatment formulation comprises: between about 1% and about 3% of the oxalic acid prepolymer; between about 0.4% and about 1.5% of the elastomer latex prepolymer; at about 10% and An aqueous polyoxo oil emulsion of between about 30%; a urethane prepolymer emulsion between about 1% and about 3.5%; a high molecular weight polyoxymethylene between about 0.2 and about 1%; An acrylic urethane prepolymer between about 1% and about 0.05%; between about 0.01% and about 0.05% polyethylene glycol diacrylate; at about 0.01% and about 0.05 °/. a catalyst between: about 0.01% and about 0.05% of a grafting initiator; and between about 0.16% and about 0.8% of poly-25-paper strips are applicable to the Chinese National Standard (CNS) A4 specification. (210 X 297 mm) 1299068 A7 B7 V. Description of invention (22) Ethylene glycol. Cotton is treated in this formulation, especially dyed cotton, to produce a fabric having a good hand and a tingling factor of from about 4 to about 4.5 on a standard scale of from 1 (poor) to 5 (excellent). The fabric thus treated also has excellent color fastness and low shrinkage, for example, close to about 3.55 to 4%, wherein the untreated cotton exhibits a shrinkage of about 8%. In one embodiment, the "stabilized treatment composition is provided by mixing a stable concentrated composition with water or other solvent. The concentrate comprises between about 2% and about 10% glyoxal prepolymer; between about 0.5% and about 6% of the elastomer latex prepolymer; between about 30% and about 70% An aqueous polyoxo oil emulsion; between about 1% and about 10% urethane prepolymer emulsion; between about 0.01% to about 0.6% of the catalyst; and at about 0.01% to about 〇 a graft initiator between .6%. A preferred formulation further comprises: about 1% and about 4% of the south molecular weight poly-crushed oxygen; between about 0.01% and about 0. 3 % of the ethyl acetoacetate Prepolymer; between about 0.2% and about 4% polyethylene glycol; and between about 0.01% and about 0.3% polyethylene glycol diacrylate. The concentrated composition is, for example, in a weight ratio of from about 2 parts concentrate: 100 parts water to about 1 part concentrate: 100 parts water (from about 4 parts concentrate: 100 parts water to about 5 parts) Concentrate · 100 parts of water is preferred, from about 1 part of the concentrate: 1 part of water to about 25 wounds; Chen shrinkage · 100 parts of water is better) diluted with water. In a preferred embodiment, the treatment composition is formed by adding 1 part concentrate to between 2 and 4 parts water or other solvent. Similarly, the concentrated solution is preferably stabilized under normal storage conditions, such as a concentrated composition that is stored for a period of at least 2 months at a temperature between about 60 T and 90 T, which is less than 5 〇/〇. The prepolymer is self-polymerized. This stabilized concentrated composition, when dried, is typically included in the -26 - this paper scale for the Chinese National Standard (CNS) Αϋ (210 χ 297 mm) —-

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1299068 23 DESCRIPTION OF THE INVENTION Solids between about 10 〇/〇 and about 3 5%. In "p, the example of a stable concentrated composition comprises: between about 4% and about 7/〇, for example about 5.6% of a glyoxal prepolymer; at about 1% and about 4% For example, about 2.8% of the elastomer latex prepolymer; between about 4% and about 6〇0/〇, for example about 56.1% of the aqueous polyoxyxide emulsion; at about 4% and about 8% Between, for example, about 5.6% of the urethane prepolymer emulsion; between about 0.03% and about 2.2/〇, such as about 0.06% of the catalyst; and at about 0.03% and about 0.2%, for example , sentence 〇.06% of the graft initiator. Preferably, the formulation comprises between about 5% and about 3%, for example about 63% of high molecular weight polyoxyxene; between about 0.02% and about 0.15%, for example about 56 〇/〇. The acrylamide urethane prepolymer; between about 0.5% and about 2%, for example about 1% polyethylene glycol (preferably diethylene glycol); and at about 0.02% and about 〇 Between 5%, for example about 0.06% of polyethylene glycol diacrylate. The stabilized concentrated composition contains between about 20% and about 32% solids when dried. In yet another embodiment, the stable concentrated composition comprises: between about 4% and about 7% of the glyoxal prepolymer; between about 1% and about 4% of the elastomer latex prepolymer An aqueous polyoxo oil emulsion between about 40% and about 60%; a urethane prepolymer emulsion between about 4% and about 8%; between about 0.5% and about 3% High molecular weight polyoxymethylene; between about 0.02% and about 0.15% of urethane urethane prepolymer; between about 0.5% and about 2% polyethylene glycol (diethylene glycol compared Good); and between about 0.02% and about 0.15% polyethylene glycol diacrylate. In this embodiment, the catalyst and graft initiator are added individually or alternatively, using ozone and/or light and/or another method of initiating and growing the grafted polymer. -27- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 public fund) 1299068 A7 B7 V. Inventive Note (24) In another specific embodiment, the stabilized concentrated composition comprises: at about 5 Between about 6% and about 6% of a slightly prepolymer, between about 2% and about 3% of the amylose latex prepolymer; between about 52% and about 60% of the aqueous polyoxygenated oil Emulsion; a urethane prepolymer emulsion between about 5% and about 7%; a catalyst between about 〇3〇/〇 to about 0. 1%, at about 0. 03% to a graft initiator between about 1%; a high molecular weight polyoxymethane between about 1% and about 2%; an urethane urethane pre-prepared between about 0 04 〇/〇 to about 0.1% a polymer; between about 4% and about 0. 1% of polyethylene glycol S-acrylic acid; and between about 65% and about 16% polyethylene glycol. This stabilized concentrated composition contains between about 25% and about 30% solids when dry. The graft initiator may include a salt of Fe, Ag, Co, Cu, or a mixture thereof. These metal salts are preferably used in combination with a catalyst to regenerate the graft initiator. The like agent includes a strong oxidizing agent such as a peroxide, a peroxyacid, a perbenzoate, or a mixture thereof. The glyoxal prepolymer is a low formaldehyde prepolymer such that the polymer produces less than 3 〇 p p m of formic acid in the treated fiber. If the cotton fiber comprises undyed cotton, the foregoing stabilization treatment composition is preferably further comprised between about 0.4% and about 8%, preferably between about 0.8% and about 6%, at about 1.2%. More preferably between about 4.5% fluoroalkyl acrylate. Preferably, the aforementioned concentrated stabilizer composition further comprises between about 2% and about 16%, preferably between about 4% and about 12%, more preferably between about 6% and about 9%. Fluorine* burned ester. The treatment composition is applied to the fibers by any method, such as to the fabric, and then typically (but not necessarily) is polymerized via application of heat (e.g., about 3400 Torr for about 3 sec to about 5 minutes). Grafted to fiber and crosslinked, 3 coated -28 -

1299068 A7 B7 V. INSTRUCTIONS INSTRUCTIONS (1)—=: Use tamping, soaking, spraying, or the like. The cellulose fabric can be immersed in the tank of the treatment solution. The group may be emulsified non-material or ionic. The dry, sputum may require longer heating at higher temperatures. The thicker fabric may be at about 3 2 〇V $ 1 7 ςτ, to Preferably, the curing of the oven at j 7 5 F is about 1 to 15 minutes. The invention includes both treatment compositions and methods of treatment. The present invention also encompasses the treatment of cotton fibers and/or fabrics using the treatment compositions described above. Preferably, the fabric made from treated cotton has a shrinkage of less than about 4.5%, preferably less than about 4%, at least * of the color fastness under standard test, and a good hand. Dyed cotton/polyester and undyed cotton/polyester, although the composition of the dyed cotton and undyed cotton is also suitable for cotton/polyester blends, but different formulations are available. More superior properties are provided for cotton/polyester blends. One embodiment of the invention pertains to one A method of cotton/polyester comprising 'providing a stable fluid composition comprising: between about 1.6% and about 18% of an acrylic prepolymer at about 〇丨% and about 3 〇/〇 An elastomeric latex prepolymer having between about 6% and about 35%, and an amine phthalate prepolymer having a concentration of between about 0.1% and about 3%. An emulsion, a catalyst between about 0.002% and about 3%, and a graft initiator between about 002% and about 0.3%. The treatment fluid is preferably also contained in about 〇2〇/〇. And about 0.2% of polyethylene glycol diacrylate. In another embodiment, the composition also includes between about 0.002% and about 0.2% of surfactant monomer. Similarly, the treatment composition Should be stable under ambient storage conditions at least 2 -29- This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1299068 A7 B7

Months. Similarly, stability means that less than 5% of the prepolymer is self-polymerized during storage for at least 2 months at a temperature between about 6 and 9 Torr, and wherein the stability composition is dry when The solids content is about 5 weight percent. The treatment fluid is contacted with cotton/polyester fibers to absorb a stability composition between about 4 grams and about 120 grams, for example between about 60 grams and about 1 gram, to about 10 grams of cotton per Ester fiber. The amount of fluid remaining after contact with the fluid, and any fluid removal, is referred to as the percent moisture absorption. The polymerizable component of the treatment fluid is then grafted onto the cotton/polyester fibers. In one embodiment, the polymerization is accomplished by exposing the cotton fibers to a temperature sufficient to polymerize at least half of the prepolymer and the organopolysiloxane to polymerize the polymer onto the cotton fibers. In one embodiment, the drying temperature is between about 250 °F and 400 Torr, and the drying time is between about 10 seconds and 10 minutes. The stabilizer composition in another embodiment comprises: between about 32% and about 15% of an acrylic prepolymer; at about 〇.2. An elastomer latex prepolymer between /0 and about 2%; an organic polyoxo-oxygen emulsion between about 8% and about 30%; an aminocarboxylic acid between about 0.2% and about 2% An ester prepolymer emulsion; between about 0.004% and about 0.1% of a catalyst; and a grafting initiator between about 00% and about 1%. Preferably, the stabilizer composition further comprises between about 0 004% and about 0.1% polyethylene glycol diacrylate vinegar; and between about 0 002% and about 0.2% of the surfactant monomer. In a preferred embodiment of the treated cotton/polyester fiber, the stability composition comprises: between about 4% and about 12% of an acrylic prepolymer; between about 4% and about 1.5% Elastomeric latex prepolymer; between 9% and about 26% -30- ΐ paper scale applicable to China National Standard (CNS) A4 specification (210 X 297 mm) ' "

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Line 1299068 A7 ____ B7 V. INSTRUCTION DESCRIPTION (27) Organic polyoxetane emulsion; between about 0.4% and about 1.5% urethane prepolymer emulsion; at about 0.006% and about 〇〇5 a catalyst between %; a graft initiator between about 0.006% and about 〇 〇 5%; a polyethylene glycol diacrylate between about 6 〇 / 〇 and about 0.05%; A surfactant monomer between about 6% and about 0.05%. The treatment composition is preferably provided as a single composition fluid concentrate. The fluid concentrate may comprise between about 8% and about 35% of an acrylic prepolymer; between about 0.5% and about 6% of the elastomer latex prepolymer; at about 3% and about 70% Between the organic polyoxane emulsions; between about 5% and about 6% of the urethane prepolymer emulsion; between about 〇丨% and about 4% of the catalyst; A graft initiator between about 0 · 01 / ί > and about 〇 · 4%. If the treating agent also comprises between about 0.01% and about 0.4% of polyethylene glycol diacetate vinegar and between about 5% and about 0.4% of the surfactant monomer, it will provide an excellent product. Similarly, the 'concentrated composition is stable during storage for at least 2 months at a temperature between about 60 Å and 90 Å. It has less than 5% prepolymer self-polymerization, and this stable concentrated combination The solids comprise between about 10% and about 35 Å/〇 of solids when dry. The fluid concentrate is diluted with the same dilution ratio as previously described, and water can be added in a weight ratio of from about 2 parts concentrate: 1 part water to about 1 part concentrate to 1 part water. From about 4 parts concentrate: 100 parts water to about 5 parts concentrate: 100 parts water preferably, from about 10 parts concentrate: 100 parts water to about 25 parts concentrate · 100 parts water is more preferred. In a preferred embodiment, the treatment composition is formed by adding 1 part concentrate to between 2 and 4 parts water or other solvent. -31 - This paper size applies to the Chinese National Standard (CNS) Α4 specification (210 X 297 mm) 1299068 A7 B7 V. Inventive Note (28) The stabilized concentrated composition in a specific embodiment includes: at about 16 Between about 30% and about 30% of the acrylic prepolymer; between about 1% and about 4% of the elastomer latex prepolymer; between about 38% and about 60% of the organic polyoxane emulsion : a urethane prepolymer emulsion between about 1% and about 4%; a catalyst between about 0.02% and about 0.2%; a graft initiator between about 0.02% and about 0.2% . The concentrate may also comprise between about 0.02% and about 0.2% polyethylene glycol diacrylate and between about 0.02% and about 0.2% surfactant monomer. In another embodiment, the stabilized concentrated composition comprises between about 20% and about 24% of an acrylic prepolymer; between about 2% and about 3% of an elastomeric latex prepolymer; About 46% and about 52% of the organopolyoxane emulsion: between about 2% and about 3% of the urethane prepolymer emulsion; at about 0.03 ° /. And a catalyst of between about 0.1%; between about 0.03% and about 0.1% of the polyethylene glycol diacrylate; between about 0.03% and about 0.1% of the surfactant monomer; A graft initiator between 0.03% and about 0.1%. Preferably, the concentrate has between about 25% and about 32% solids when dry, and preferably between about 25% and about 30% solids. The surfactant monomer can be any surfactant monomer, which is also known as an ionic monomer. The monomer may comprise a sulfonate group such as sodium vinyl sulfonate, sodium p-styrene sulfonate, sodium methallyl sulfonate, sodium p-sulfonic acid phenyl methyl allyl ether, or 2-methyl -2-Sodium acrylamide sulfonate. These groups are known to increase hydrophilicity. Co-monomers containing carboxylic acid esters, such as itaconic acid, are also surfactant monomers. A preferred surfactant monomer is sodium vinyl sulfonate. As mentioned above, the graft initiator can be one or more of Fe, Ag, Co, Cu -32 - This paper size is suitable for home (CNS) A4 specification (2l〇x 297 public) "'"

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1299068 A7 ------- - A B7 V. INSTRUCTIONS (29) Salts, or mixtures thereof. Similarly, the catalyst can be a peroxide, a peroxyacid, a stupoformate, or a mixture thereof. If the cotton/polyester fiber comprises undyed cotton/polyester fibers, the stabilizer composition preferably further comprises between about 0.4% and about 8% fluoroalkyl acrylate, for example at about 0.8% and about 6%. Preferably, the fluoroalkyl acrylate is between about 12% and about 4.5% of fluoroacetate propyl acrylate. The concentrated stabilized composition providing a preferred treated undyed cotton/polyester fiber further comprises between about 2% and about 16% of a fluoroalkyl acrylate, for example between about 4% and about 12% of fluoroacrylate. The alkyl esters are preferably fluoroalkyl acrylates between about 6% and about 9%. As such, the invention also relates to treated products, as well as articles, fabrics, yarns, and staple fibers comprising treated fibers. The present invention also relates to both a stable treatment fluid and a stable agricultural shrinkage composition for treating cotton/polyester fibers. Printing Cotton A method of treating previously dyed cotton fibers comprises providing a stable fluid composition comprising: between about 1% and about 12% of an acrylic prepolymer; at about 0.08% and about 2%. Stretch latex prepolymer: between about 3% and about 25% of an organopolyoxane emulsion; between about 0.08% and about 2% of an amino phthalate prepolymer emulsion; a high density polyethylene prepolymer between about 1.4% and about 11.5%; a polyamido prepolymer between about 0.8% and about 9%; a catalyst between about 0.0004% and about 0.15%; A graft initiator between about 0.0004% and about 0.15%. It is also desirable to include a nonionic dispersant between about 0.08% and about 2%; at about 0.0004% and about -33 - this paper scale applies to the Chinese National Standard (CNS) Λ4 specification (210 X 297 mm) &quot ;"~"" 1299068 A7 _ B7 V. Description of invention (30) 〇. 15% between polyethylene glycol diacrylate; and at about 〇0004〇/〇 and about 〇. 1 5% Acryl amide. Similarly, the treatment composition is stored at a temperature between about 60 T and 90 °F for at least 2 months - stability, while less than 5% of the prepolymer is self-polymerized. The stability composition has a solids content of at least about 5 weight percent when dried. The treatment fluid is contacted with the printed cotton fibers to absorb the stability composition between about 4 grams and about 12 grams to about 100 grams of cotton fibers, preferably at about 60 grams and about 1 gram. The stabilizing composition absorbs to about 1 q gram of printed cotton fiber' Finally, the method involves forming a graft polymer. In one embodiment, this occurs as a result of drying the cotton fibers by exposure to a temperature sufficient to polymerize at least half of the prepolymer and polysulfuric oil into a polymer grafted onto the printed cotton fibers. For example, the drying temperature can be between about 25 Torr and 400, and the drying time is between about 10 seconds and 10 minutes. In a specific embodiment, the stabilization composition comprises: between about 16% and about 10% of an acrylic prepolymer; between about 0% and about 5% of the elastomer latex. An organic polyoxo-emulsion emulsion between about 5% and about 23%: between about 0.2% and about 1.5% urethane prepolymer emulsion; at about 2% and about 10% a high density polyethylene prepolymer; between about 14% and about 7.5% polyamine prepolymer; between about 02% and about 1%; and at about 0.002% And a graft initiator between about 0.1%. Similarly, there is between about 0.2% and about 1.5% nonionic dispersant; between about 0.002% and about 0.1% polyethylene glycol diacrylate; and at about 0.002°/ 〇和约〇. 1% of the urethane acrylate can be selected for better production -34- This paper scale is applicable to China National Standard (CNS) Α4 specification (210 X 297 mm) 1299068 A7 _ B7 , invention description (31) products. Of course, the fluid should be stable. In one embodiment, the stability composition for treating printed cotton comprises between about 2.4% and about 8% of an acrylic prepolymer; between about 0.3% and about 1% of the elastomer latex prepolymer An organopolyoxane emulsion between about 6% and about 20%; a urethane prepolymer emulsion between about 0.3% and about 1%: at about 2.6% and about 8.5% a high density polyethylene prepolymer; between about 2% and about 6% of a polyamido prepolymer; between about 0.006% and about 05% of the catalyst; at about 0.006% and about 0.05% a graft initiator between: about 0.3% and about 1% nonionic dispersant; between about 6% and about 0.05% polyethylene glycol diacrylate; 〇〇〇 6% and about 0.05% of urethane acrylate. In yet another embodiment, the stability composition is provided by mixing a concentrated concentrate composition comprising the following ingredients with water or another solvent: between about 5% and about 24% of the acrylic prepolymer; Between about 0.4% and about 4% of the elastomer latex prepolymer; between about 15% and about 50% of the organopolyoxane emulsion; between about 0.4% and about 4% of the amine hydrazine An acid ester prepolymer emulsion; between about 7% and about 23% high density polyethylene prepolymer; between about 4% and about 18% polyamine prepolymer; at about 0.002% and about a catalyst between 0.3%, and a graft initiator between about 0.002% and about 0.3%. The concentrated composition may further comprise between about 0.4% and about 4% of a nonionic dispersing agent; between about 0.002% and about 0.3% of polyethylene glycol diacrylate; and at about 0.002% and about 0.3% acrylic urethane. The dilution of the diazepam concentrate is the same as previously described for other stable concentrates. The concentrated composition is stored at a temperature of between about 60 °F and 90 °F for at least 2 -35- This paper scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1299068 A7 B7 V. Invention Indicates that (32) is stable during the month's period and less than 5% of the prepolymer is self-polymerized. The stabilized concentrated composition comprises between about 10% and about 35% solids when dry' preferably between about 25% and about 32% solids. The concentrate is preferably diluted with water prior to use. The concentrate may be diluted with water added from a weight ratio of about 2 parts of concentrate: 10 0 parts of water to about 1 part by weight of concentrate to 100 parts of water, from about 4 parts of concentrate · 100 parts of water to About 50 parts of the concentrate: 1 part of water is preferred, from about 1 part concentrate: 100 parts water to about 25 parts concentrate: 100 parts water is more preferred. In a specific embodiment, the stabilized concentrated composition comprises: between about 8% and about 20% of an acrylic prepolymer; between about 1% and about 3% of an elastomeric latex prepolymer; About 25% and about 46% of an organopolyoxane emulsion; between about 1% and about 3% of a urethane prepolymer emulsion; between about 1% and about 20% a high density polyethylene prepolymer; between about 7% and about 15% polyamine prepolymer; between about 0.01% and about 0.2% of the catalyst; and between about 0.01% and about 0.2% The graft initiator. The concentrate may further comprise a nonionic dispersing agent comprised between about 1% and about 3%; between about 0.01% and about 0.2% of polyethylene glycol diacrylate; and at about 0.01% and about Improved between 0.2% urethane acrylate. In yet another preferred embodiment, the stabilized concentrated chelate comprises: between about 12% and about 16% of an acrylic prepolymer; between about 1.5% and about 2% of elastomeric latex a prepolymer; between about 30% and about 40% of an organopolyoxane emulsion; between about 1.5% and about 2% of a urethane prepolymer emulsion; at about 13% and about 17 Between the high-density polyethylene prepolymers; between about 10% and about 12% of the polyamide precursor; at about 0.03% and about 0.1% -36 - the paper size applies to t countries National Standard (CNS) A4 Specification (210 X 297 mm) 1299068 A7 _______B7 V. Inventive Note (33) ~ ^-catalyst; graft between about 0.03% and about Gl% (four) agent: at about L5 Between 2% and about 2% of a nonionic dispersing agent; between about 3% and about 5% of polyethylene glycol diacrylate; and between about 3% and about 〇丨% ° Acrylic urethane. The stabilized concentrated composition contains between about 25% and about 30% solids when dry. Likewise, the graft initiator preferably comprises Fe, Ag, co, or a plurality of salts thereof, or a mixture thereof. The initiator can include a magnesium salt. The catalyst includes a strong oxidizing agent such as a peroxide, a peroxyacid, a perbenzoate, or a mixture thereof. Urea peroxide is the best. As such, the invention also relates to treated products, as well as articles, fabrics, yarns, and staple fibers comprising treated fibers. The invention also relates to both a stable treatment fluid and a wave-forming composition for treating cotton/polyester maiden. Printing cotton/polyacetate A treatment composition particularly suitable for previously dyed cotton/polyester fibers is described herein. The printed cotton/polyester fiber is contacted with a stable fluid composition comprising: between about 1% and about 2% of an acrylic prepolymer; between about 0.08% and about 2% of the elastomer a latex prepolymer; between about 6% and about 35% of an organopolyoxane emulsion; between about 8% and about 2% of a polyamido prepolymer; at about 2% and a binder of between about 4%, such as a carboxylated butylene acrylonitrile prepolymer; a catalyst between about 0.001% and about 0.15%; a graft between about 0.001% and about 0.15% An initiator; and preferably between about 0.001% and about 0.15% polyethylene glycol diacrylate; and between about 0.001% and about 0,15% surfactant monomer. This composition is suitable for China National Standard (CNS) A4 specification (210 X 297 public) at about 6〇 -37- this paper k degree.

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1299068 A7

The temperature between F and 90 F is stored for at least 2 months during the period of stability, and there is a lower self-polymerization than the X prepolymer. The stabilizer composition has a solids content of at least about 5 weight percent when dried. It can be contacted by any method, and it is preferred that the printing cotton/polyester fiber absorbs the stability composition between York and about 12 grams to about 1 gram of cotton fiber, which will be between about 60 grams and about 100 grams. It is preferred that the composition absorbs to about 1 inch of printed cotton/polyester. Finally, the polymerizable material in the treatment composition is polymerized onto the printing cotton/polyester fibers' to form a graft polymer. The formation of the grafted polymer can be carried out by drying the printed cotton/polyester fibers at a temperature sufficient to synthesize at least half of the prepolymer and the organopolyfluorene to form a polymer grafted onto the printing cotton. Quoted. The drying temperature can be between about 205 and 4,000 Å, and the drying time can be between about 10 seconds and 10 minutes. In a specific embodiment, the "stabilizing composition comprises: between about 2% and about 15% of an acrylic prepolymer; between about 2% and about 1.5% of the elastomeric latex prepolymer; An organopolyoxane emulsion between about 8% and about 30%; a polyamido prepolymer between about 0.2% and about 1.5%; a carboxylation between about 4% and about 3% Butadiene acrylonitrile prepolymer; between about 0.002% and about 0.05% catalyst; between about 0.002% and about 0.05% graft initiator; and preferably at about 0.002% and about 0.05% Polyethylene glycol diacrylate; and between about 0.002% and about 0.05% of the surfactant monomer. The stabilizer composition in a specific embodiment comprises between about j.6% and about 12% of an acrylic prepolymer; between about 0.3% and about 1.25% of an elastomer latex prepolymer; 9% and about 27% organic polyoxane emulsion; in -38- paper quality applies Chinese National Standard (CNS) A4 specification (210X 297 mm) 1299068 A7 ___ B7 V. Invention description (35) a polyamidamide prepolymer having between about 0.3% and about 1.25%; a slow acidified butadiene-acrylonitrile prepolymer having a concentration of between about 6% and about 25%; at about 4% and about催化剂· 〇3 % of the catalyst; between about 0.004% and about 3% of the graft initiator; between about 0.004% and about 0.03% of the polyethylene glycol diacrylate; A surfactant monomer between 0 · 0 0 4 % and about 0.0 3 %. In yet another embodiment, the stability composition is provided by mixing a stable concentrated composition comprising the following ingredients with a solvent (eg, water): between about 5% and about 40% of the acrylic prepolymer. An elastomeric latex prepolymer between about 4% and about 4%; an organopolyoxane emulsion between about 30% and about 70%; between about 0.4% and about 4% a polyamide precursor; a carboxylated butadiene acrylonitrile prepolymer between about 1% and about 8%; a catalyst between about 0.005% and about 0.3%; and at about 0.005% and about 0.3 A graft initiator between %. Preferably, the concentrate also comprises between about 0.005% and about 0.3% polyethylene glycol diacrylate and between about 0.005% and about 0.3% surfactant monomer. The concentrated composition is stable during storage for a period of at least 2 months at a temperature between about 60 Torr and 90 °F, while less than 5% of the prepolymer is self-polymerized. The stable concentrated composition comprises between about 10% and about 35% solids when dry, preferably between about 25% and about 32% solids, between about 25% and about 30%. The solid is better. In one embodiment, the stabilized concentrated composition comprises between about 10% and about 30% of an acrylic prepolymer; between about 1% and about 3% of an elastomeric latex prepolymer; About 40% and about 60% organic polyalkylene emulsion; between about 1% and about 3% polyamido prepolymer; between about 2% and about 6% -39- paper The scale applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1299068 A7 ___ B7 V. Invention description (36) Carboxylated butadiene acrylonitrile prepolymer; at about 0.01% and about 〇·丨. /. a catalyst between; and between about 0.01% and about 0.1% of a graft initiator. Preferably, the stabilized concentrated composition further comprises between about 0.1% and about 0.1% polyethylene glycol diacrylate and between about 0.01% and about 0.1% surfactant. monomer. In a preferred embodiment, the 'stabilized concentrated composition comprises between about 18% and about 24% of an acrylic prepolymer; between about 1.5% and about 2.5% of an elastomeric latex prepolymer; An organic polyoxane emulsion between about 46% and about 54%; a polyamido prepolymer between about 1.5% and about 2.5%; a carboxylated butyl group between about 3% and about 5% a diene acrylonitrile prepolymer; between about 0.02% and about 0.06% of a catalyst; between about 0.02% and about 0.06% of a grafting initiator; between about 0.02% and about 0.06% of polyethylene. a diol diacrylate; and between about 0.02% and about 0.06% of a surfactant monomer. The method of treating printed cotton/polyester fibers can be carried out when the fibers are in the form of a textile. In a specific embodiment, the grafting initiator comprises one or more salts of Fe, Ag, Co, Cii, or a mixture thereof. In another embodiment, the initiator comprises a salt of Fe, Mg, or a mixture thereof. The catalyst comprises a peroxide, a peroxyacid, a perbenzoate, or a mixture thereof. Similarly, the invention also relates to treated products, as well as articles, fabrics, yarns, and staple fibers comprising treated fibers. The invention also relates to both a stable treatment fluid and a concentrated composition for treating the stability of printed cotton/polyester fibers. Cotton stretch component -40 - The paper scale is suitable for the Sichuan National Standard (CNS) A4 regulation (2Π) X 297 public Chu) 1299068 A7 B7

V. INSTRUCTIONS (37) Cotton fibers are sometimes used in stretch compositions. It has been surprisingly found that cotton fibers with a high loading of a special prepolymer graft combination not only exhibit excellent stain resistance, good hand feel, and excellent color fastness, but also exhibit excellent recovery after stretching. rate. One commercial blend for this purpose is a mechanical blend of cotton (about 95%) and SPANDEX (TM) or LYCRA (TM). Although the formulation described above is quite suitable for processing cotton fibers for this purpose, there are special stability fluid formulations for imparting stretchability and recovery of cotton fibers comprising between about 0.8% and about 15% acrylic pre-forms. a polymer; between about 0.4% and about 9%, a high molecular weight polyoxo oxygen; between about 6% and about 35% of a polyoxygenated oil emulsion; between about 1.5% and about 12% amine a carboxylic acid; a catalyst of between about 0.0004% and about 0.15%; and a graft initiator between about 4% and about 15%. Preferably, the treatment composition also comprises between about 0.0004% and about 0.15% polyethylene glycol diacrylate and between about 0.0004% and about 15% of the urethane urethane prepolymer. Things. Unlike other composition treating agents which preferably have a loading of between about 2 and about 6% after grafting and polymerization, the loading of cotton is preferably between about 3% and about 10%. For example, between about 5% and about 7%. This loading will allow the fabric to be stretched to about 15% of its original length for 30 seconds. After the fabric is allowed to relax for another 30 seconds, the fabric will return to about 95% of its original size. Approximately 115% is preferred between about 97% and about 1.08%. This can be repeated at least 5 times on the treated fabric, and preferably at least 1 turn, with substantially the same result. The composition may advantageously be stored at a temperature between about 60 T and 90 T for > 2 months, while less than 5% of the prepolymer is self-polymerized. -41 - This paper size is applicable to China National Standard (CNS) A4 specification (21〇Χ297 mm) 1299068 A7 ----------- B7_— ____^ V. Invention Description - Make stretchable cotton fiber The treatment composition is contacted to absorb between about 40 grams and 200 grams of the stability composition to about 100 grams of cotton fibers, preferably between about 60 grams and about 14 grams. Preferably, the fibers are in contact with the treatment composition for drying to enhance migration of the fluid into the fibrous structure. The prepolymer in the treatment fluid is then grafted and polymerized onto the stretchable cotton fibers', for example, by exposure to sufficient polymerization of at least half of the prepolymer and the polyoxygenated oil to be grafted onto the stretchable cotton fibers. The temperature of the polymer. A drying time of between about 1 Torr and 1 Torr at a drying temperature between about 250 °F and 400 Torr is sufficient for most fabrics. In a specific embodiment, the stabilization composition comprises between about 2% and about 10% of an acrylic prepolymer; between about 0.8% and about 7% of a high molecular weight polyoxyxene; at about 8% and a polyoxo-oil emulsion of between about 30%; a urethane between about 1.2% and about 8%; a catalyst between about 0.002% and about 0.1%; at about 0.002% and about a graft initiator between 0.1%; and preferably between about 0.002% and about 0.1% of polyethylene glycol diacrylate and between about 0.002% and about 0.1% of urethane urethane pre- Polymer. The stabilizer composition in a preferred embodiment comprises between about 2.4% and about 8% of an acrylic prepolymer; between about 1.2% and about 5% of a high molecular weight polyxylene; at about 10 a polyoxo-oil emulsion between about % and about 27%; a urethane between about 1.6% and about 6%; a catalyst between about 0.006% and about 0.05%; at about 〇.〇06 a graft initiator between about 5% and about 5%; between about 0.006% and about 0.05% of polyethylene glycol diacrylate; and between about 0.006% and about 0.05% of an amine acrylate Formate prepolymer. -42- The paper size applies to the Chinese National Standard (C NS) A4 specification (210 X 297 mm) 1299068 A7 _— _B7_ _ V. Illustrative (39) The stability composition can be stabilized by a concentrated fluid that will include the following ingredients The composition is blended to provide: between about 4% and about 30% of an acrylic prepolymer: between about 2% and about 18% high molecular weight polyoxyxene; at about 3% and about 70% Interpolymerized oxime oil emulsion; urethane at about 3% and about 24% winter; catalyst between about 0.002% and about 0.3%; graft between about 0.002% and about 0.3% An initiator; and preferably between about 0.002% and about 0.3% of polyethylene glycol diacrylate and between about 〇2〇2% and about 3% of the pre-polymerization of glyceryl methionate Things. Similarly, the concentrated composition is stable during storage for a period of at least 2 months at a temperature between about 60 T and 90 °F, while the prepolymer having less than 5 Å/〇 is self-polymerized. The stabilized concentrated composition comprises between about 10% and about 35% solids when dry to preferably contain between about 25% and about 32% solids when dry. In a specific embodiment, the stable concentrated composition comprises between about 1% and about 20% of an acrylic prepolymer; between about 4% and about 14% of high molecular weight polyoxyxide; A polyoxon oil emulsion between about 40% and about 60%; between about 6% and about 16% urethane; at about 〇.〇1〇/. And a catalyst of between about 0.2%, between about 0.01% and about 0.2% of a graft initiator; and preferably between about 0.01% and about 0.2% of polyethylene glycol diacrylate; About 0.01% and about 0.2% of an urethane urethane prepolymer. In a preferred embodiment, the stable concentrated composition comprises between about 12% and about 16% of an acrylic prepolymer; between about 6% and about 10% of high molecular weight polyoxyxene; About 50% and about 55% of a polyoxylized oil emulsion-43-

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The paper is suitable for the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1299068 V. Description of the invention (40); between about 8% and about 12% of the urethane; at about 0.03% And a grafting initiator of between about 0.03% and about 0.1%; a polyethylene glycol diacrylate of between about 0.03% and about 0.1%; An acrylic urethane prepolymer having between about 0.03% and about 0.1%. The stabilized concentrated composition contains between about 25% and about 30% solids when dry. The stretchable cotton fiber is preferably in the form of a textile. The graft initiator in one embodiment includes one or more salts of Fe, Ag, c〇, Cu, or a mixture thereof. In another embodiment, the initiator comprises one or more salts of Fe, Mg, or a mixture thereof. The catalyst in one embodiment is a peroxide, peroxyacid, perbenzoate, perrhenate, or a mixture thereof. Non-reactive pigments are known to be printed on cotton and cotton/polyester. One type of adhesive includes a few acidified butyl succinimide, and many other viscous gels are known. It has been surprisingly found by the addition of a small amount of cross-linking agent, especially between about 0.01% and 0.3%, preferably between about 00.02% and about %1% at about 0'03% and 0.06%. It is better to at least cross-link the prepolymer to improve color fastness and color fastness. A preferred composition also has an acetoamine group present in the decanolated acrylonitrile in the range of the above-mentioned extent? Sour acid and polyethylene glycol acrylate. It may be necessary to add a small amount of water, for example about 1%, to stabilize the polymer composition. Compatible adjuvants can be added to the compositions herein based on their known use. Such zoles include, but are not limited to, 'viscosity control agents, perfumes, emulsifiers, preservatives, ultraviolet light absorbers, anti-gasifiers, bactericides, fungicides -44 - 1299068 A7

V. INSTRUCTION OF THE INVENTION (42) Regarding each cotton and cotton/polyacetate fiber, the formulation described above is advantageous because it is coated by a device or a processing step. At any stage of the hairdressing, ... "", the fiber and the yarn and the fabric are in virtual contact. The grafting solution can be applied to the cut fiber or the filament fiber, the yarn or the forming fabric. Skilled on the filament, and knowing the sorcerer, up to L σ material broken m ", / become a fabric. Further, the yarn can be formed into a woven fabric by grafting length: wide, and then. Alternatively, the yarn may be formed from un-grafted filaments and then the treatment composition is grafted (tetra) to form a fabric. ‘傻傻冉"

The treatment composition may also be grafted onto the staple fibers prior to spinning the stapled staple fibers into yarns. The grafted filaments can be cut into staple fibers, which are then spun into yarns. The filaments or yarns or fabrics may be contacted with a solution of the first component by bear coating, troweling, or coating operations. It is further contemplated that the fibers or yarns may be contacted with the grafting solution after chemical or mechanical manufacturing operations such as wire coating, coating U 4 on H or after. Further, the graft solution may be applied to the fabric after the yarn or the fiber is formed. The fabric can be contacted with the grafting solution in or after chemical or mechanical coatings such as 4, or after, the coating fabric is softened or extended. The treatment of the polymer on the fabric can be performed using the specific test described here -46 - χ299〇68 Α7 Β7

Fifth, the invention description Inference. A sample of 18 inches of 吋 8 inches of fabric generally used for shrinkage testing was used as a test sample. The shrinkage of the sample should be indicated in a normal manner as additional shrinkage data is obtained during the polymer test. Approximately half a teaspoon of each Heinz(TM) tomato sauce, Hersey, s(TM) chocolate syrup, and Welch's (TM) grape juice were placed in a 18-inch by 18-inch sample. Force contaminants into the fabric and wipe off excess with a clean paper towel. The fabric is then washed in a normal cycle in warm water (105T) using a detergent such as Tlde Ultra clean (TM). After washing, the sample was dried. Both stains should be removed completely (or nearly completely). Dirty is evaluated by the rating of 1, , , , where "5" indicates no color, 4" indicates light color, "3" indicates some colors, "2" indicates many colors, and "丨" indicates large s color. The treated fabric will have a rating greater than 3.5 and preferably greater than 4. Untreated cotton has a pollution value of 1-2. The shrinkage of the treated fibers in the form of the fabric will be less than 45%, preferably less than 4%, and most preferably less than 3.5%. Untreated fabrics have a shrinkage of 75 to 9%. The weight of the loading on the fiber or fabric will depend on the desired end use and cost factors. Applicants have surprisingly found that good hand, color fastness, stain resistance, shrinkage, and abrasive properties increase with the carrying amount of the processing chemical grafted thereon. Economic considerations limit the amount to approximately less than about 10 weight percent. Excellent fabric properties were observed for loadings between about 2% and about 7%, preferably between about 3% and about 5%. The loading of the treating agent after about 15 washes should be at least half of the initial treating agent. -47- This paper-like® fresh _S) A4 secret (10) X 297 public goods) ------— 1299068 A7

The medium-hexane is prepared by adding a pre-calculated amount of the desired prepolymer to the vessel combination: a monomer, a prepolymer, a catalyst, a graft initiator, and other components are added thereto. Each component is used in a concentration ratio (in terms of 4) as indicated by the composition as described herein. Mix the contents (4) into the uniforms. The system will be processed in the next recipe. (4) Test fabric: softness feel) is a reasonable judgment of the independent tester when compared with 100°/. cotton fabric. The color is tested by AATCC test method. B is tested by wet color and dry state. Rating by "grade, 纟中,,5" indicates no color turn "4" indicates light color shift '"3" indicates _ some color shifts, ''2' indicates many color shifts, and "丨&quot Indicates a large color shift. Color fastness is tested using the AATCC Test Method 6丨11Α. Shrinkage is measured using Aatcc. Test Method 1 35-1 992-1VA 111. Abrasion Resistance Test Method ASTM D 1376 (30) Minutes) Test Example 1 A formulation having the composition shown in Table 1 was prepared. This formulation was found to be diluted in a range from about 2 parts water to 1 part formulation to about 4 parts water to i part of the formulation. 60% moisture absorption is applied to the fabric, and when dried at a temperature of about 34 Torr, it provides a good hand, a shrinkage of less than 4%, a color fastness of at least 4, and an abrasion resistance test. There are no hair balls and at least 35 anti-pollution fabrics. The compound is stable in the period of storage at room temperature for more than 3 months without visible sedimentation. Table 1. Formulations for dyed cotton fabrics -48- This paper scale applies to the National Threshold National Standard Rate (CNS) A 4 size (210 X 297 mm) 1299068 A7 B7 V. Description of invention (45) Parts by weight Glyoxal resin prepolymer, Ecco Res GB 404 (ΤΜ) 5.6 Aurethane prepolymer, ResammUMT171 ( TM) 5.6 High molecular weight polyoxyl softener, Helastic WO-8026(TM) 1.63 Poly stone softener, Sequasoft69(TM) 56.13 Elastomer latex, Hystretch V-43(TM) 2.80 Deionized water 27.0 Diethylene glycol 1.0 Acrylic urethane, SR-9035(TM) 0.06 Polyethylene glycol diacrylate, SR 344(TM) 0.06 Urea peroxide (〇·1% soluble in DIW) 0.06 Ammonium sulphate solution (0.1 N) 0.06 In another composition, the diethylene glycol is replaced by additional water, and the degradation of the fabric properties is minimally accomplished. In another composition, the ethylene resin prepolymer Resin KLF (TM) is substituted. Glyoxal resin prepolymer Ecco Res GB 404(TM), and the brewing in the fabric is reduced to less than 30 Ppm Example 2 A formulation having the composition shown in Table 2 was prepared which was found to be diluted from about 2 parts water to 1 part formulation to about 4 parts water to 1 part formulation and about 60% The moisture absorption amount is applied to the fabric, and when dried at a temperature of about 340 °F, it can provide a good hand feeling, a shrinkage ratio of less than 4%, a color fastness of at least 4, and no abrasion resistance test. Raising balls, and at least 3.5 stain resistant fabrics. -49 - This paper size applies to Chinese National Standard (CNS) A4 specification (210 x '297 mm) 1299068 A7 B7 V. Description of invention (46) Table 2, Formulated by weight of acrylic cotton/polyester fabric Prepolymer, Helastic 800(TM) 4.86 urethane prepolymer, Resamme UMT 171(TM) 2.43 Acrylic prepolymer, EccoRez 907(TM) 2.43 Soft fine polyoxyl, APS V- Soft(TM) 48.7 Acrylic Prepolymer, Helastic WD 8061 (TM) 14.61 Elastomeric Latex, Hisretch V-43(TM) 2.43 Deionized Water 24.3 Polyethylene Glycol Diacrylate, SR 344(TM) 0.05 Vinyl Sulfonic Acid Sodium 0.05 Urea peroxide 0.1 N solution 0.05 Ammonium sulphate ferrous 0.1 N solution 0.05 Real Example '3 A formulation having the composition shown in Table 3 was prepared. Table 3, Formula Weight % for Printing Cotton Fabrics Polyamide Prepolymer Dispersion, Micromid 632MPL(TM) 10.89 Aminophthalate Prepolymer Emulsion, Resamine UMT 171(TM) 1.80 Acrylic Prepolymer , Helastic WD 8061 (TM) 14.52 elastomer latex, Hisretch V-43 (TM) 1.80 high density polyethylene prepolymer, Mykon HD (TM) 14.52 modified organic polyoxane, APS V-soft (TM) 36.31 Non-ionic dispersant, Crockfast2(TM) 1.80 -50- This paper scale is applicable to China National Standard (CNS) A4 specification (210 x 297 mm) 1299068 A7 B7 V. INSTRUCTION DESCRIPTION 47 Deionized water 18.2 Acrylate amine Formate, Sr_9035(TM) 0.04 Polyethylidene diacrylate, sr_344(TM) 0.04 Gland peroxide 0. 1 N solution 0.04 Ammonium sulphate. 1 N solution 0.04 This formula was found to be Approximately 2 parts of water is diluted to the range of the formulation from 4 parts of water to 4 parts by weight, and coated to the fabric with a moisture absorption of about 6% by weight, and provided to be good when dried at a temperature of about 3 40 F. Feel, shrinkage below 4%, color fastness of at least 4, no fluff in the abrasion test And contamination resistance of the fabric is at least 3.5. Example 4 A formulation having the composition shown in Table 4 was prepared. This formulation was found to be diluted to about 1 part formulation from about 2 parts water to about 4 parts water to 1 part formulation, and to a fabric at a moisture absorption of about 6%, and dried at a temperature of about 340T. It can provide a fabric with a good hand, a shrinkage of less than 4%, a color fastness of at least 4, no fluff in the abrasion resistance test, and a stain resistance of at least 3.5. Table 4, Formulated by Weight of Polyester Fabric for Printing Cotton Polyester Prepolymer, Helastic 8001(TM) 11.75 Acrylic Prepolymer, Helastic WD 806 1(TM) 7.83 Acrylic Prepolymer, Helastic 804 1(TM) 1.96 elastomer latex, Hisretch V-43(TM) 1.96 deionized water 19.6 -51 - This paper scale applies to Chinese National Standard (CNS) A4 specification (210.X 297 mm) 1299068 A7 B7, invention Description (48) Polyamide prepolymer dispersion, Micromid 632MPL(TM) 1.96 modified organic polyoxane, APS V-soft(TM) 50.9 carboxylated butadiene acrylonitrile Tylac 68805(TM) 3.91 Ethylene glycol diacrylate, SRo44(TM) 0.04 sodium sulphate 0.04 urea peroxide 0.1 N solution 0.04 ammonium sulphate ferrous 0.1 N solution 0.04 Example 5 A formulation having the composition shown in Table 5 was prepared. The formulation was found to be diluted from about 2 parts water to 1 part formulation to about 4 parts water to 1 part formulation, and applied to the fabric at a moisture uptake of about 60%, and at a temperature of about 340 °F. When dry, it provides a fabric with good hand, less than 4% shrinkage, no fluff in the abrasion test, and at least 3.5 stain resistance. - Table 5, parts by weight of cotton fabric, % by weight of oxalic acid resin prepolymer, Ecco Res GB 404(TM) 5.6 urethane prepolymer, Resamin UMT171(TM) 5.6 High molecular weight polyoxyl soft Fine, Helastic WO-8026(TM) 1.63 Ju Shi Xi Oxygen Softener, Sequasoft 69(TM) 56.13 Elastomeric Latex, Hystretch V-43(TM) 2.80 Fluoroacrylate Copolymer Dispersion, Texfluor UPL(TM) 8.0 Deionized water (DIW) 19 Amino phthalate acrylate, SR-9035(TM) 0.06 Polyethylene glycol diacrylate, SR 344(TM) 0.06 -52- This paper scale applies to China National Standard (CNS) A4 specification (210X 297 public)

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▲ 1299068 A7 B7 V. INSTRUCTIONS (49) Urea peroxide (〇. 1% dissolved in DIW) 0.06 Ammonium sulphate solution (0.1 N) 0.06 Diethylene glycol 1.0 In another composition, additional Water replaces diethylene glycol with little degradation of the properties of the fabric. In another composition, the Ethylene Resin Prepolymer Ecco Res GB 404(TM) was replaced with the Ethylene Resin Prepolymer Resin KLF (TM), and the A1 in the fabric was reduced to less than 30 ppm. EXAMPLES Formulations having the compositions shown in Table 6 were prepared. The formulation was found to be diluted from about 2 parts water to 1 part formulation to about 4 parts water to 1 part formulation, and applied to the fabric at a moisture uptake of about 60%, and a spread at about 340 °F. When dried, it provides a fabric with a good hand, a shrinkage of less than 4%, no fluff in the abrasion resistance test, and a stain resistance of at least 3.5. Table 6. Formulations for cotton/polyester fabrics, parts by weight, acrylic prepolymer, Helastic 8001(TM) 4.86 urethane prepolymer, Resamin UMT 171(TM) 2.43 acrylic prepolymer, EccoRez 907 (TM) 2.43 Soft Polyoxyalkylene, APS V-soft(TM) ' 48.7 Acrylic Prepolymer, Helastic WD 806 1 (TM) 14.61 Elastomeric Latex, Hisretch V-43(TM) 2.43 Fluoroalkyl acrylate Copolymer dispersion, Texfluor UPL(TM) 8.0 Deionized water 16.3 -53 - This paper scale applies to Chinese National Standard (CNS) A4 size Γ210 X 297 mm)

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1299068 A7 B7 V. INSTRUCTIONS (50) Polyethylene glycol diacrylate 'SRJ44(TM) 0.05 Sodium vinyl sulfonate 0.05 Urea peroxide 0.1 N solution 0.05 Ammonium sulphate 0.1 N solution 0.05 Example 7 Preparation Formulations having the compositions shown in Table 7. The formulation was found to be diluted to about 1 part formulation from about 2 parts water to about 4 parts water to 1 part formulation and applied to the fabric at a moisture uptake of about 80% and dried at a temperature of about 340T. It provides fabrics with excellent stretch and recovery characteristics, as well as good hand feel, shrinkage below 4%, no fluff in the abrasion test, and at least 3.5 stain resistance. Table 7, Formulations for Cotton Fabrics, Parts by Weight, Acrylic Prepolymer, Helastic 800 1 (TM) 13.53 Urethane Prepolymer, Resamine UMT 171(TM) 10.25 High Molecular Weight Polyoxyl Softener, Helastic WO-8026(TM) 8.12 Ju Shi Xi Oxygen Softener, Sequasoft 69(TM) 53.6 Deionized Water 14.21 Polyethylene Glycol Diacrylate, SR344(TM) 0.06 Acrylic Amino Acid, SR-9035(TM) 0.06 Urea peroxide 0.1 N solution 0.06 Ammonium sulphate ferrous 0.1 N solution 0.06 Example 8 Treated and untreated fabric printing dye composition and glue, where glue -54 - This paper scale applies to Chinese national standard (CNS ) A4 size (210 x 297 gong)

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1299068 A7 B7 V. INSTRUCTIONS (51 includes 99.5% carboxylated butadiene acrylonitrile, 〇〇4% acrylic urethane, and 0.04% polyethylene glycol diacrylate, and a small amount of water as a solvent. Fabrics treated with this composition and dried at a temperature sufficient to promote cross-linking (ie, 34 Torr) have a grade of 1 to 5 better than dyed only with polyethylene glycol diacrylate and at 340 °F. The dried similar fabric has a ochre nature of at least about 0.5 and up to 2 units. Example 9 A formulation having the composition shown in Table 8 was prepared. This formulation was found to range from about 2 parts water to 1 part formulation. Approximately 4 parts of water are diluted in the range of the formulation and applied to the fabric at a moisture uptake of about 80%, and when dried at a temperature of about 340 Å, it provides moderate stretch and recovery characteristics, and good hand feel, low Fabrics with a shrinkage of 5%, no fluffing balls in the abrasion resistance test, good wet fastness and acceptable dry fastness, and at least 3.5 stain resistance. Table 8 Acrylic prepolymers , Helastic 8001 (ΤΜ) deionized water-elastic latex, Hisretch V-43(TM) K F(TM)28/30% soluble in water high molecular weight polyoxyl softener, Helastic WO-8026(TM) acrylic prepolymer, Helastic WD 8041 (TM) KF 874 (10% soluble in IPA) Aurasoft 280 B Sparse acid sodium parts by weight 12.9 25. 1 1.29 44.08 3.87 2.15 1.29 8.6 0.04 Urea peroxide (0.1%) 0.04 -55- Wood paper scale applicable to national standard (CNS) A4 size (210X297 mm)

Binding

1299068 A7 B7 V. INSTRUCTIONS (52) Ammonium sulphate (0.1%) 〇 04 This formulation was tested on cotton dark blue spots and the results are shown in Table 9. _______ Table 9 Standard Specifications Actually Complete 100% Dissolved 100% Dissolved 50% Solution 50% Solution Specification Liquid Velvet Spotted Fleece Cloth Weave Spotted Spotted Spot Printed Printing Paste Blasting * 60 92 112 110 105 105 oz Weight 6.5 6.3 7.75 7.6 7.25 7.3 Shrinkage 7x7 5 · 0x6.0 4.0x5.0 5.0x0 4.0x4.0 4.2x0.6 Stretch 40 40 42 50 45 45 Reply 80 97 95 95 95 90 Twilight W/D 2.0/3.0 2.0/ 3.0 5.0/3.5 5.0/3.5 5.0/4.0 4.5/3.5 Hairball 3 2.0 5.0 5.0 5.0 5.0 *Mellens' burst test

The Melan blasting test measures the force required to press a ball of about 1 inch in diameter over the fabric to measure the tensile strength of the fabric. The tensile strength of the fabric used herein is defined as the force required to push the ball through the fabric in accordance with the Mehran test procedure. The intensity ratio is the force required to push the ball through the fabric divided by the force required to push the same ball through a similar but untreated fabric. This value is related to seamability and wearability. The resin coated to cotton typically reduces the tensile strength of the cotton fabric. Applicants have surprisingly found that treating the fibers of the fabric with a large loading of polymer as previously indicated increases the strength ratio to 150% (100% is the same strength of the untreated fabric). A smaller loading increases the strength ratio to U 5%, and a preferred loading increases the strength ratio to at least 125%. -56· I paper size applies to China National Standard (CNS) A4 specification (210 X 297 mm) ' """

k 1299068 A7 B7 V. INSTRUCTIONS (53) Example 1 0 A formulation having the composition shown in Table 10 was prepared. The formulation was found to be diluted from about 2 parts water to 1 part formulation to about 4 parts water to 1 part formulation and applied to the fabric at a moisture uptake of about 80%, and at a temperature of about 340 °F. When dry, it provides a fabric with excellent stretch and recovery characteristics, as well as a good hand, a shrinkage of less than 5.4%, no fluffing ball in the abrasion resistance test, and excellent color fastness. The test data on cotton with dark blue spots are shown in Table 11. Table 10 parts by weight urethane prepolymer, Resamine UMT 171(TM) 15.42 Polyamidide prepolymer dispersion, Micromid 632MPL(TM) 2.57 polyoxyl softener, Sequasoft 69(TM) 43.18 High molecular weight Polyoxyl softener, Helastic W〇-8026(TM) 5.14 Aurasoft 280(TM) 7.71 Deionized water 25.7 Aurawet 634(TM) 0.22 Amino acrylate, SR-9035(TM) 0.005 Ethyl citrate 0.005 sodium metabisulfite (0.1N solution) 0.05 -57- This paper size is applicable to China _ home standard (CNS) A4 specification (210 X 297 mm) 1299068 A7 B7 V. Invention description (54 ) Table 1 1 Standard specifications Actually completed specifications 100% solution flannel spots 100% solution flannel spot printing paste 5 0% solution flannel spots 5 0% solution flannel spot printing paste blasting * 60 60 90 92 88 90 ounces weight 6.0 5.9 7.4 7.1 6.5 6.4 Shrinkage 8x8 6.0x60 5.4x1.0 5.0x1.5 5. Ox 1.5 5.2x2.0 Stretch 40 40 35 40 30 38 Reply 80 90 95 95 95 95 Twilight W/D 2.0/3.0 2.0/3.0 4.5/4.0 4.5/3.5 4.5/4.0 4.5/4.0 Hairball 3 3 5.0 5.0 5.0 5.〇

Loading *Melan Burst Test Example 11 -1 3 Three formulations having the compositions shown in Table 12 were prepared, and the test data are shown in Table 13. This example shows how sensitive the test results are to minor formulation changes. Table 12 Example 11 12 13 Ingredients, % by weight E % Ecco Res GB 404 5.0 6.5 5.6 Aurethane prepolymer, Resamine UMT 171(TM) 4.8 6.8 5.6 High molecular weight polyoxyl softener, Helastic WO -8026(TM) 1.4 2.5 1.69 -58 - This paper size is applicable to China National Standard (CMS) A4 specification (210 X 297 mm)

1299068 A7 B7 V. Description of invention (55)

Sequasoft V-43(TM) 55.0 60.0 56.13 Elastomeric latex, Hisretch V-43(TM) 2.33 3 5 2.80 Water 30.6 20.46 28.0 Acrylic urethane, SR 9035(TM) 0.04 0.07 0.06 Polyethylene glycol diacrylate Ester SR 344(TM) 0.05 0.07 0.06 Urea peroxide (0.1%) 0.05 0.055 0.06 Ammonium sulphate solution (0.01) 0.04 0.045 0.06 Table 13. Example 11 12 13 Blasting 83 112 92 ounces weight 5.64 7.5 6.9 Shrinkage % 7x5 6x5 3.8x3 .1 Stretch % 40 30 55 Reply % 97 98 95 Twilight Wet/Dry 5/5 2/4 4/4.5 Fleece Ball 3.5 4 5 Soft and soft in the hand, although it is clearly visible The invention is fully contemplated to achieve the aforesaid purposes. It is to be understood by those skilled in the art that Modifications and specific embodiments. This paper scale applies to China National Standard (CNS) A4 specification (21〇x 297 mm) -59- i2mmzT^ Announcement 1 f IJ X A1 Please ·&One case number, ff 〇" Category Dob H < Vo^ (The above columns are filled by this Council) A4 C4 Chinese manual revision page (April 1992) J-enriched patent specification I. Invented Lunxin new name Chinese made with soft hand and good color fastness, color fast Method for the production of abrasion, abrasion and anti-fouling fibers' fabrics made from the same, and printing on fibers including cotton. English METHOD FOR MAKING FIBER WITH SOFT HAND AND GOOD CROCK-FASTNESS, COLOR-FASTNESS, ABRASION RESISTANCE , AND STAIN RESISTANCE, AND FABRIC PREPARED THEREBY, AND METHOD FOR PRINTING ON FIBER COMPRISING COTTON I. Invention λ A Creator Name Nationality Residence, Residence 1 · Mohan L. Shan Dujie MOHAN L. SANDUJA 2. Karl Harlow CARL HOROWITZ 3. Izabella ZILBERT 4. Paul Sota Hill PAUL THOTTATHIL 1.-4. Both USA 1 · Room 516, 144-90, 41st Avenue, Fleet, New York, USA 144 -90 41st AVEN UE, #516 FLUSHING, NY 11355 US 22719 WHITMAN DRIVE, BROOKLYN, NY 11234 US 3.25 White House, Brooklyn, NY, USA #5A BROOKLYN, NY 11234 US 4·17, Pauyan Avenue, New Hyde Park, New York, USA BRYANT AVENUE, NEW HYDE PARK, NY 11040 US III. Name of Applicant (Name) Nationality Residence, Residence (Company) Representative The name of the company is Hanstek apparel company HEALTHTEX APPAREL CORP. United States USA United States Delaware, Wisconsin, 3411, Silverside Road, No. 3411, Bena Building, Room 201, 3411 SILVERSIDE ROAD, 201 BAYNARD BUILDING, WILMINGTON, DE 19810 US Helen L. Wins HELEN L. WINSLOW -1 - This paper size applies to the Chinese National Standard (CNS) A4 specification (210X 297 mm)

Claims (1)

129 full 6 &amp; 〇 6848 patent application Chinese patent application scope replacement (April 1993) Patent application Fan Park a fiber with a soft hand and good tear fastness, color, sex, and pollution resistance a method, wherein the method comprises: contacting a cellulosic fiber with an activated grafting initiator to form a position at which the polymer can be attached and polymerized; and hydrating the cellulosic fiber with a composition comprising the following ingredients in the composition a condition that can form a grafted yarn on a cellulosic fibrous substrate; a contact: at least '5 weight percent of a polymerizable cerium-containing compound selected from the group consisting of an organopolysiloxane, a polymerizable polyoxyxene, or a mixture thereof; a polymerizable prepolymer; and a second polymerizable prepolymer; wherein the first and second prepolymers are different, and wherein the activated graft initiator comprises an effective concentration selected from the group consisting of Fe + 3 in the composition a metal ion of the group consisting of Fe + 2 , Ag 1 , Co + 2, Cu + 2 and a mixture thereof, and wherein the first polymerizable prepolymer and the second polymerizable prepolymer are selected from the group consisting of Group: B2 Aldehyde prepolymer, elastomer latex prepolymer, and urethane prepolymer; acrylic prepolymer, elastomer latex prepolymer, and urethane prepolymer; acrylic prepolymer , carbamic acid _ prepolymer, high density polyethylene prepolymer, and polyamidomethine prepolymer; or acrylic prepolymer, urethane formic acid prepolymer, carboxylated butadiene acrylonitrile prepolymer , high density polyethylene prepolymer, and polyamide precursor. O:\77\77652-930427.doc This paper scale applies to China National Standard (CNS) A4 specification (210X297 mm) 1299068 as B8 C8 ______D8 VI. Patent application scope ~ *-*- 2· One kind of manufacturing has a soft touch and A method of good culling &amp; $ </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> </ RTI> <RTIgt; Forming an attachable and polymerizable polymer where the grafting initiator comprises an effective amount of one or more metal ions, radiation, ozone, or plasma, derived from the fibers to capture hydrogen atoms to form an active site on the fibers; And contacting the cellulosic fibers with a composition comprising: a composition capable of forming a graft copolymer on the cellulosic fibrous substrate: at least 5 weight percent of the polymerizable organic cerium-containing compound; a second polymerizable prepolymer; and a third polymerizable prepolymer; wherein the first polymerizable prepolymer, the second polymerizable prepolymer, and the third polymerizable prepolymer are selected from the group consisting of Group Cheng Zhiqun: Glyoxal prepolymer, elastomer latex prepolymer, and urethane prepolymer prepolymer; propylene glycol prepolymer, elastomer latex prepolymer, and urethane pre-pre Acrylic prepolymer, urethane prepolymer, high density polyethylene prepolymer, and polyamidomethine prepolymer; or acrylic prepolymer, urethane prepolymer, Carboxylated butadiene propylene gambling prepolymer, high density polyethylene prepolymer, and polyamide precursor. -2- O:\77\77652-930427.doc This paper size applies to the Chinese National Standard (CNS) A4 specification (21〇 x 297 mm) 1299068 3: According to the method of claim 1 or 2, wherein the contact will be between 40 injures and 120 parts by weight of the composition, the weight of the fiber, the quasi-, and the graft polymer Formed by typhoon contacting the fibers of the contact composition to a temperature between 250 F and 400 Torr between 1 sec and 1 〇, wherein the graft polymer comprises fibers 2 and Between 10 weight percent and 100%, and the strength of the graft fiber is at least about 5% of the strength of the fabric made from ungrafted fibers. 4. The method of claim 2 or 2, wherein the composition comprises between 3 and 35 weight percent of an aqueous polyoxo oil emulsion, an aqueous organopolyoxane emulsion, or a mixture thereof, wherein The first polymerizable prepolymer and the second polymerizable prepolymer are selected from the group consisting of a glyoxal prepolymer, an elastomer latex prepolymer, or a urethane prepolymer emulsion, and The grafted polymer comprises fibers between 2 and 1 weight percent. 5. The method of any one of clauses 1 or 2, wherein the cellulosic fiber comprises cotton, and the composition comprises: an aqueous polyoxo oil emulsion between 3% and 35°/〇; 0.4% and 5% of the glyoxal prepolymer; and at 0.2 ° /. And an amine methyl ester prepolymer emulsion between 5%; and between 0.004% and 2% glyoxal or a latex latex prepolymer between 0.1% and 3°/〇. 6. The method according to claim 1 or 2, wherein the composition comprises: a glyoxal prepolymer between 0.4% and 5%; and an amine group between 0.2% and 5% Acid ester prepolymer emulsion; high molecular weight organic polyoxyxide suspension between 0.02% and 2%; -3 - O:\77\77652-930427.doc This paper scale applies to China National Standard (CNS) A4 specification (210X297 mm) 1299068 - C8 D8 VI. Acrylic urethane prepolymer with a patent range of 0.002% and 0.15%; elastomer latex prepolymer between 0.1% and 3%; Polyethylene glycol diacrylate between 0.002% and 0.15%; aqueous polyoxyxide emulsion between 6% and 35%; polyethylene glycol between 0.004% and 2%; at 0.002% and An oxidizing agent catalyst between 0.3%; and a grafting initiator between 0.002% and 0.3%, wherein the composition has a solid content of at least 5 weight percent when dried, and wherein the composition is at 60 °F and 90 The temperature between °F is stored for at least 2 months, and less than 5% of the polymerizable material is self-polymerized. 7. The method of claim 1 or 2, wherein the composition comprises: between 0.8% and 3.5% of a glyoxal prepolymer; between 0.2% and 2% of the elastomer latex prepolymer Aqueous polyoxyxide emulsion between 8% and 30%; urethane prepolymer emulsion between 0.8% and 4%; high molecular weight organic polymerization between 0.1% and 1.5% An oxirane suspension; between 0.004% and 0.08% of urethane urethane prepolymer; between 0.004% and 0.08% of polyethylene glycol diacrylate; between 0.1% and 1% Polyethylene glycol; and a graft initiator between 0.006% and 0.2%. 8. The method according to claim 1 or 2, wherein the composition is formed by mixing a concentrate comprising the following components between 4 parts and 50 parts by weight with a solvent comprising water to form 100 parts by weight of the composition. Provided: Glyoxal prepolymer between 2% and 10%; O:\77\77652-930427.doc - 4 - This paper scale applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1299068 as C8 ___ D8 VI. Application of latex latex prepolymer with a patent range of 0.5% and 6%; waterborne polyoxo oil emulsion between 30% and 70%; at 1% and 10% A urethane prepolymer emulsion between. 9. The method of claim 8, wherein the concentrate further comprises: at 0.1 ° /. And a high molecular weight organopolyoxygen suspension of between 4%; an urethane urethane prepolymer between 0.01% and 0.3%; a polyethylene glycol between 0.2% and 4%; Between 0.01% and 0.3% of polyethylene glycol diacrylate; between 0.01% and 0.6% of the catalyst; between 0.01% and 0.6% of the graft initiator; wherein the concentrate is at 60 °F And a self-polymerizing stabilizer fluid having a polymerizable material of less than 5 Å/〇 during a period of at least 2 months of storage at a temperature between 90 °F, and wherein the stabilized concentrated composition is contained at 1% by weight when dried And between 35% solids. The method of claim 8, wherein the cellulosic fiber comprises undyed cotton, and the concentrate further comprises between 2% and 16% of a fluoroacetic acid S suspension. The method of claim 1 or 2, wherein the composition comprises between 0.4% and 8% of a polymerizable fluoroalkyl acrylate suspension. 12. The method of claim 1 or 2, wherein the composition comprises between 6 and 35 weight percent of an aqueous organopolyoxane emulsion, wherein the first polymerizable prepolymer and the second The polymeric prepolymer is selected from the group consisting of acrylic prepolymers, elastomer latex prepolymers, and amine phthalate prepolymer emulsions. O:\77\77652-930427.doc -5- A BCD 1299068. The scope of the patent application of claim 1 wherein the cellulosic fiber comprises a cotton/polyester blend, and the composition comprises: between 1.6% and 18% Acrylic prepolymer; between 0.1% and 3% of elastomer latex prepolymer, urethane prepolymer emulsion, or both; and between 6% and 35% organic polyfluorene Oxygen emulsion. 14. The method of claim 12, wherein the composition comprises: between 3.2% and 15% of an acrylic prepolymer; between 0.2% and 2% of an elastomer latex prepolymer; Between 8% and 30% of a polymerizable organopolyoxane emulsion; and between 0.2% and 2% of a urethane prepolymer emulsion, wherein the temperature of the polymerization process is 250 °F and 400 °F is between 10 seconds and 10 minutes. 15. The method of claim 12, wherein the composition comprises: between 4% and 12% of an acrylic prepolymer; between 0.4% and 1.5% of a latex latex prepolymer; Between 9% and 26% organic polyoxane emulsion; between 0.4% and 1.5% urethane prepolymer emulsion; between 0.006% and 0.05% catalyst; at 0.006% and 0.05 a graft initiator between %; between 0.006% and 0.05% of polyethylene glycol diacrylate; and between 0.006% and 0.05% of surfactant monomer. 16. The method of claim 12, wherein the composition is prepared by mixing between 4 parts and 50 parts by weight of a concentrate comprising the following ingredients: O:\77\77652-930427.doc - 6 - This paper scale applies to China National Standard (CNS) A4 specification (210 X 297 mm) 1299068 - C8 ' D8 VI. Patent application scope: Acrylic prepolymer between 8% and 35%; at 0.5% and 6% between the elastomer latex prepolymer; between 30% and 70% of the organopolyoxane emulsion; and between 0.5% and 6% of the urethane prepolymer emulsion. 17. The method of claim 16, wherein the concentrate comprises: an acrylic prepolymer between 8% and 35°/〇; and an elastomer latex prepolymer between 0.5% and 6%. An organopolyoxane emulsion between 30% and 70%; a urethane prepolymer emulsion between 0.5% and 6%; a catalyst between 0.01% and 0.4%; at 0.01% And a graft initiator between 0.4%; between 0.01% and 0.4% of polyethylene glycol diacrylate; and between 0.01% and 0.4% of the surfactant monomer, wherein the stable concentrate is Storing at a temperature between 60 °F and 90 °F for at least 2 months, and less than 5% of the polymerizable material from polymerization 0. 18. According to the method of claim 16, wherein the fiber Including undyed cotton, and the concentrate further comprises between 2% and 16% of a fluoroalkyl acrylate suspension. 19. The method of claim 12, wherein the composition comprises between 0.4% and 8% of a polymerizable fluoroalkyl acrylate suspension. 20. The method of claim 1 or 2, wherein the composition comprises: between 3 and 35 weight percent of an aqueous polyoxo oil emulsion, aqueous O:\77\77652-930427.doc - 7 - This paper scale is applicable to China National Standard (CNS) A4 specification (210X297 mm) 1299068 - C8 D8 6. Patent application range Organic polyoxane emulsion, or a mixture thereof, wherein the first polymerizable prepolymer and the first The dipolymerizable prepolymer is selected from the group consisting of an acrylic prepolymer, a urethane prepolymer emulsion, a high density polyethylene prepolymer emulsion, and a polyamide precursor prepolymer dispersion. 21. The method of claim 20, wherein the composition comprises: between 1% and 12% of an acrylic prepolymer; between 3% and 25% of an organopolyoxane emulsion; a high density polyethylene prepolymer emulsion between 1.4% and 11.5%; and a polyamidoprepolymer dispersion between 0.8% and 9%. 22. The method of claim 21, wherein the fiber comprises printed cotton, and the composition comprises: between 0.0004% and 0.15% of a grafting initiator, and at least three of the following: at 0.0004% And 0.15% catalyst; between 0.08% and 2% elastomer latex prepolymer; between 0.08% and 2% urethane prepolymer emulsion; at 0.08% and 2% Non-ionic dispersing agent; between 0.0004% and 0.15% of polyethylene glycol diacrylate; and between 0.0004% and 0.15% of urethane amide, wherein the composition when dried The solids content is at least 5 weight percent. 23. The method of claim 20, wherein the fluid composition comprises: between 1% and 12% of an acrylic prepolymer; O:\77\77652-930427.doc - 8 - the paper size Applicable to China National Standard (CNS) A4 Specification (210X297 mm) 1299068 - C8 D8 VI. Application of elastomeric latex prepolymer with a patent range of 0.08% and 2%; organic between 3% and 25% Polyoxane emulsion; urethane prepolymer emulsion between 0.08% and 2%; high density polyethylene prepolymer emulsion between 1.4% and 11.5%; at 0.8% and 9% a polyammine prepolymer dispersion; and a graft initiator between 0.0004% and 0.15%, wherein the composition is stored at a temperature between 60 °F and 90 °F for at least 2 months Medium and stable, while less than 5% of the polymerizable material self-polymerizes. 24. The method of claim 20, wherein the composition comprises: between 2.4% and 8% of an acrylic prepolymer; between 0.3% and 1% of a latex latex prepolymer; Between 6% and 20% organic polyoxane emulsion; between 0.3% and 1% urethane prepolymer emulsion; between 2.6% and 8.5% high density polyethylene prepolymer Emulsion; 2% and 6% polyammine prepolymer dispersion; between 0.006% and 0.05% catalyst; between 0.006% and 0.05% graft initiator; at 0.3% and 1 a nonionic dispersant between %; between 0.006% and 0.05% of polyethylene glycol diacrylate; and between 0.006% and 0.05% of the amino acid phthalate. 25. The method according to claim 20, wherein the composition is formed by mixing a concentrate comprising the following components between 4 parts by weight and 50 parts by weight with a solvent comprising water to form 100 parts by weight of the composition. Provide: Acrylic prepolymer between 5% and 24%; O:\77\77652-930427.doc - 9 - This paper scale applies to Chinese National Standard (CNS) A4 specification (210X297 mm) 1299068 - C8 D8 VI. Application of a rubber latex prepolymer with a patent range of 0.4% and 4%; an organic polyoxane emulsion between 15% and 50%; an amine group between 0.4% and 4% Emulsion prepolymer emulsion; high density polyethylene prepolymer emulsion between 7% and 23%; polyamine dispersion prepolymer dispersion between 4% and 18%. 26. The method of claim 25, wherein the concentrate comprises: between 0.002% and 0.3% of a catalyst; between 0.002% and 0.3% of a grafting initiator, wherein the concentrate is at 60° Store at a temperature between 90 °F and 90 °F for at least 2 months, while less than 5% of the polymerizable material is self-polymerized, and the concentrate is between 10% and 35% when dry. Solid. 27. The method of claim 1 or 2, wherein the composition comprises: between 6 and 35 weight percent of an aqueous organopolyoxane emulsion, wherein the first polymerizable prepolymer and the second The polymerizable prepolymer is selected from the group consisting of acrylic prepolymers, urethane prepolymer emulsions, carboxylated butadiene acrylonitrile prepolymers, high density polyethylene prepolymer emulsions, and polyamine prepolymerization. a group of liquid dispersions. 28. The method according to claim 27, wherein the composition comprises: an organic polyoxane emulsion; a graft initiator, and at least four of the following components: an acrylic prepolymer; Polyamide transpolymer dispersion; O:\77\77652-930427.doc - 10 - This paper scale applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1299068 - C8 D8 VI. Application Patented range of carboxylated butadiene acrylonitrile prepolymers; polyethylene glycol diacrylate; or surfactant monomers. 29. The method of claim 27, wherein the composition comprises: between 1% and 20% of an acrylic prepolymer; between 0.08% and 2% of a latex latex prepolymer; Between 6% and 35% of organic polyoxane emulsion; between 0.08% and 2% of polyamido prepolymer dispersion; between 0.2% and 4% of carboxylated butadiene acrylonitrile And a cellulose fiber comprising the previously dyed cotton/inflammation ester fiber. The method of claim 27, wherein the composition comprises: between 0.002% and 0.05% of the catalyst; between 0.002% and 0.05% of the graft initiator; at 3.6% and 12% Acrylic prepolymer; between 0.3% and 1.25% elastomer latex prepolymer; between 9% and 27% organic polyoxane emulsion; between 0.3% and 1.25% Polyamylamine prepolymer dispersion; between 0.6% and 2.5% of carboxylated butadiene acrylonitrile; between 0.005% and 0.3% of polyethylene glycol diacrylate; and at 0.005% and 0.3% Between the surfactant monomers, wherein the composition is stable during storage for at least 2 months at a temperature between 60 °F and 90 °F, and less than 5% of the polymerizable material is self-polymerized. 3 1. According to the method of claim 27, wherein the composition is via O:\77\77652-930427.doc - 1 1 - the paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 PCT) 1299068 - C8 D8 VI. Scope of Application The mixture of 4 parts by weight and 50 parts by weight of a concentrate comprising the following ingredients is mixed with a solvent comprising water to form a composition of 100 parts by weight: And 40% acrylic prepolymer; between 0.4% and 4% elastomer latex prepolymer; between 30% and 70% organic polyoxane emulsion; at 0.4% and 4% a polyammine prepolymer dispersion; between 1% and 8% of a carboxylated butadiene acrylonitrile prepolymer; and wherein the concentrate is between 10% and 35% when dried solid. 32. The method of claim 31, wherein the concentrate comprises: between 0.005% and 0.3% of a catalyst; and between 0.005% and 0.3% of a grafting initiator, wherein the concentrate is at 60 Storage at temperatures between °F and 90°F for at least 2 months, while less than 5% of polymerizable materials self-polymerize. 33. The method of claim 31, wherein the concentrate comprises: between 10% and 30% of an acrylic prepolymer; between 1% and 3% of a latex latex prepolymer; 40% and 60% organic polyoxane emulsion; between 1% and 3% of polyamido prepolymer dispersion; between 2% and 6% of carboxylated butadiene acrylonitrile pre Polymer; between 0.01% and 0.1% of the catalyst; between 0.01% and 0.1% of the graft initiator; wherein the concentrate contains between 25% and 35% solids when dry. 34. The method according to claim 1 or 2, wherein the composition comprises: O:\77\77652-930427.doc - 12 - The paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 PCT) 1299068 A8 B8 C8 D8, at least 5% of a polymerizable polyoxyxide emulsion, a high molecular weight polymerizable organopolyoxygen suspension, or a mixture thereof; and at least 1% urethane Prepolymer emulsion. 35. A method of making a stretchable fiber having a soft hand and good color fastness, color fastness, abrasion resistance, and stain resistance, the method comprising: comprising a cellulosic fiber substrate having active hydrogen and including The composition of the following components is contacted: a grafting initiator which activates a site on the cellulose fiber; a catalyst which activates the grafting initiator, wherein the grafting initiator comprises an effective concentration selected from the group consisting of Fe + 3 and Fe + 2. A metal ion of a group consisting of Ag+1, Co+2, Cu+2 and a mixture thereof; a first polymerizable prepolymer comprising reacting with an activated site on the substrate to graft the first component And a functional group forming an active site on the first component; the second polymerizable prepolymer comprising reacting with the activated site on the substrate or the first component, and forming an active site on the second component a functional group; and a b 1 ' 苐 dimerizable component, comprising an organopolyphosphoric acid functional group, wherein the first polymerizable prepolymer, the second polymerizable prepolymer, and the third component are formed by solution contact Polymer on the substrate Forming a graft substrate; wherein the second polymerizable prepolymer comprises a material that imparts increased resilience to the graft substrate, and the first polymerizable prepolymer comprises imparting flexibility or softness to the graft substrate a material, and the first polymerizable prepolymer and the second polymerizable prepolymer thereof: O:\77\77652-930427.doc -13- 1299068 Patent application A8 B8 C8 D8 is selected from the group consisting of the following : 乙二骏 prepolymer, elastomer latex prepolymer, and urethane prepolymer; propionic acid prepolymer, elastomer latex prepolymer, and amino phthalic acid _ prepolymer; Propionic acid prepolymer, carbaryl prepolymer, high density polyethylene prepolymer, and polyamido prepolymer; or acrylic prepolymer, urethane prepolymer, Carboxylated butadiene acrylonitrile prepolymer, high density polyethylene prepolymer, and polyamidamine prepolymer. 36. The method of claim 1, wherein the cellulosic fiber comprises cotton, the composition comprising an acrylic prepolymer and a urethane prepolymer between 1% and 15% Emulsion. 37. The method of claim 1, 2 or 35, wherein the composition comprises: between 0.8% and 15% of an acrylic prepolymer; a high molecular weight polymerizable between 0.4% and 9% Organic polyoxyxide suspension; a polymerizable polyoxyxide oil emulsion between 6% and 35%; and a mercaptocarboxylic acid_prepolymer emulsion between 10.5% and 12%; wherein the grafting 1 The composition comprises fibers between 2 and 12 weight percent. 38. The method of claim i, 2 or 35, wherein the composition comprises: between 0.0004% and 0.15% of a grafting initiator; and -14-O:\77\77652-930427.doc This paper scale is applicable to China National Standard (CNS) A4 specification (210 X 297 mm) 1299068 έ88 C8 D8 6. The catalyst with a patent range of 0.0004% and 0.15%, wherein the composition is at 60°F and 90°. The temperature between F is stored for at least 2 months during the period of stability, while less than 5% of the polymerizable material is self-polymerized. 39. The method of claim 1, 2 or 35, wherein the composition comprises: between 2% and 10% of an acrylic prepolymer; between 0.8% and 7% of high molecular weight organic polyfluorene Oxygen suspension; between 8% and 30% polyoxo oil emulsion; between 1.2% and 8% urethane prepolymer emulsion; between 0.002% and 0.1% catalyst; a graft initiator between 0.002% and 0.1%; a polyethylene glycol diacrylate between 0.0004% and 0.15%; and an urethane urethane prepolymer between 0.0004% and 0.15%. 40. The method of claim 1, 2 or 35, wherein the composition is formed by mixing a concentrate comprising the following ingredients between 4 parts and 50 parts by weight with a solvent comprising water to form 100 parts by weight. The composition provides: an acrylic prepolymer between 4% and 30%; a high molecular weight organopolyoxygen suspension between 2% and 18%; a polyfluorene between 30% and 70% Oxygen oil emulsion; and a urethane prepolymer emulsion between 3% and 24%. 41. The method according to claim 40, wherein the concentrate comprises: between 0.002% and 0.3% of polyethylene glycol diacrylate; between 0.002% and 0.3% of acrylamide phthalate Prepolymer; catalyst between 0.002% and 0.3%: and O:\77\77652-930427.doc - 15 - This paper scale applies to Chinese National Standard (CNS) A4 specification (210 X 297 mm) 1299068 a graft initiator having a patent range of between 0.002% and 0.3%, wherein the concentrate is stable during storage for at least 2 months at a temperature between 60 F and 90 T, and less than 5%. The polymeric material is self-polymerized, and wherein the stable concentrate comprises a solid between 1 Torr/0 and 35 Torr/〇 when dried. 42. The method of claim 4, wherein the fiber is formed into a fabric, wherein the fabric has at least 4% graft polymer, and wherein the fabric is stretched to 15 times its original length 3 When the leap seconds are relaxed and relaxed, it will return to between 95% and 11% of its original size within 30 seconds. The method of claim 2, wherein the fiber is formed into a fabric, wherein when the fabric is stretched and returned for five cycles, it will return to its original size at 95% in each cycle. Between ii and 〇%. 44. The method according to the scope of claim 2, paragraph 2 or 35, may be achieved by the fiber, yarn, or fabric, and the contact of the fibers in it = bear coating, spraying, or coating operation. 45. The method of claim 2, wherein the composition further comprises a viscosity control agent, a fragrance, an emulsifier, a preservative, an ultraviolet light absorber, an antioxidant, a bactericide, a fungicide, One or more of a colorant, a dye, a fluorescent dye, a whitening agent, a hiding agent, a wettability improver, a soil release agent, a flame retardant, and a shrinkage controlling agent. The method according to claim 45, wherein the wettability improver is added to the graft copolymerization in a manner sufficient to make the fiber more hydrophobic than the fiber treated with the composition not including the wettability improver. Matter polymer. 47. According to the method of claim 45, wherein the wettability improver O: \77\77652-930427.doc ^ paper scale suitable for g Η 鲜 fresh (CNS) A4 specification 16-1299068 patent application scope A8 B8 C8 D8 is a polymerizable prepolymer which is added to the graft copolymer in a state which is more hydrophilic than a fiber which is treated with a composition which is not white &amp; does not include a wettability improver. 48. The method according to the scope of the patent application, wherein the wettability improver comprises a polymerizable prepolymer of acid, sulphuric acid, sd or carboxy group. The method of claim </ RTI> wherein the bactericide is a polymerizable prepolymer added to the graft copolymer in an amount sufficient to render the fiber more resistant to fine growth than the fiber treated with the composition not comprising the bactericide. 50. The method of claim 49, wherein the bactericide is a polymerizable prepolymer comprising a protonated amine. 51. The method according to the patent application range 45 g, wherein the flame retardant The agent is more resistant to flames than fibers treated with a composition which does not include bismuth and 阻燃 ^ ^ 阻燃 阻燃 加 加 加 加 见 见 可 可 可 可 可 可 可 可Prepolymer. 5 2 · A method according to the scope of claim 1, wherein the flame retardant comprises a polymerizable prepolymer of chlorine or bromine. 53. According to the scope of claim 2 or 2 a method wherein the graft initiator comprises a salt of the compound, or a mixture thereof, wherein the composition comprises a catalyst comprising a peroxide, a peroxyacid, a perbenzoate, or a mixture thereof. a metabisulfite, or a mixture thereof. 55. The method according to claim 1, 2 or 35, wherein the cellulose fiber is in the form of a fabric. A fabric made by the method of Patent No. 2 or 35. O:\77\77652-930427.doc 17- 1299068 57. A fabric according to item 56 of the patent application for the preparation of a yarn. 58. The fabric of claim 56, wherein the graft copolymer comprises from 2 to 1 weight percent of the fabric. 59. A fabric according to item 58 of the patent application, which is used for the preparation of a yarn. 6. The method according to claim 1, 2 or 35, further comprising the steps of: fabricating the fiber with at least one polymerizable printing comprising a pigment, a viscous glue, a solvent, and between 0.01% and 2% The composition of the prepolymer is contacted; and the printing prepolymer is polymerized such that the pigment adheres to the fibers such that the color fastness of the pigment is greater than the fiber treated by the composition consisting essentially of the adhesive and pigment. Excellent color fastness. The method of claim 6, wherein the viscous gel comprises carboxylated butadiene acrylonitrile, and at least one of the prepolymers has at least two functionalities that promote cross-linking. 62. The method of claim 6 wherein the composition comprises a carboxylated butadiene acrylonitrile gel, between 1% and 1% water, between 1% and 0.1% A method for printing on a fiber comprising cotton, and a method for printing on a fiber comprising cotton, wherein the urethane urethane is between 1% and 1% of 〇〇1*S? dipropionic acid vinegar 0 63. : contacting the fiber with a composition comprising a pigment, a viscous glue, a solvent, and at least one polymerizable prepolymer between 1% and 2%; and polymerizing the prepolymer, wherein the viscous gel comprises Carboxylated butadiene acrylonitrile, and at least one of the prepolymers thereof has at least two functionalities to promote crosslinking, and the composition -18-O:\77\77652-930427.doc This paper scale is applicable to Chinese national standards (CNS) A4 size (210X297 metric tons) 1299068 - C8 D8 6. The patent application scope includes water between 0.05 and 10%, wherein the composition includes urethane acrylate, polyethylene glycol diacrylate, Or a mixture thereof. 64. The method of claim 63, wherein the composition comprises carboxylated butadiene acrylonitrile, between 0.1% and 1% water, between 0.01% and 0.1% acrylamide carboxylic acid Ester, and polyethylene glycol diacrylate between 0.01% and 0.1%. O:\77\77652-930427.doc - 19 - This paper size applies to the Chinese National Standard (CNS) A4 specification (210 X 297 mm)