TWI264469B - Copper-nickel-alloy and production method for its container - Google Patents
Copper-nickel-alloy and production method for its container Download PDFInfo
- Publication number
- TWI264469B TWI264469B TW090116478A TW90116478A TWI264469B TW I264469 B TWI264469 B TW I264469B TW 090116478 A TW090116478 A TW 090116478A TW 90116478 A TW90116478 A TW 90116478A TW I264469 B TWI264469 B TW I264469B
- Authority
- TW
- Taiwan
- Prior art keywords
- alloy
- copper
- nickel
- melt
- container
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 229910000990 Ni alloy Inorganic materials 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910000881 Cu alloy Inorganic materials 0.000 claims abstract description 12
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052802 copper Inorganic materials 0.000 claims abstract description 6
- 239000010949 copper Substances 0.000 claims abstract description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 4
- 239000011777 magnesium Substances 0.000 claims abstract description 4
- 229910052796 boron Inorganic materials 0.000 claims abstract description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 239000011574 phosphorus Substances 0.000 claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 3
- 229910000570 Cupronickel Inorganic materials 0.000 claims description 2
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 238000005482 strain hardening Methods 0.000 claims 2
- 239000012080 ambient air Substances 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 230000003068 static effect Effects 0.000 claims 1
- 239000000758 substrate Substances 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
- 238000003466 welding Methods 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract description 2
- 230000000930 thermomechanical effect Effects 0.000 abstract description 2
- 229910052726 zirconium Inorganic materials 0.000 abstract description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 229910052791 calcium Inorganic materials 0.000 abstract 1
- 239000011575 calcium Substances 0.000 abstract 1
- 239000000356 contaminant Substances 0.000 abstract 1
- 230000004927 fusion Effects 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 238000001816 cooling Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000004881 precipitation hardening Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- -1 ferrous metals Chemical class 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910000601 superalloy Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/059—Mould materials or platings
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/06—Alloys based on copper with nickel or cobalt as the next major constituent
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Crucibles And Fluidized-Bed Furnaces (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Arc Welding In General (AREA)
- Conductive Materials (AREA)
Abstract
Description
12644691264469
If- f ,,:ri - — . __ _____ 乂 . .___ J五、發明說明(1 ) 本發明一方面係關於應用銅合金作爲非析出硬化狀態 之材料’以製造容納金屬熔體之容器,例如熔體和非熔體 設備用之坩渦。 本發明另方面針對銅-鎳合金所構成,可容納金屬熔體 的容器之製法。 熔體和非熔體製法在實務上已屬公知。旨在改善鋼, 和以鐵、鎳或鈷爲基礎的超合金之品質。又一應用範圍是 製造非鐵金屬,例如鉬、鈦、鉬或锆。 製造ί甘禍所用材料,通常是銅和銅合金,具有高度熱 傳導性。 無縫焊接或其他裝設的坩堝,通常呈圓管形或正方形 的基本型式。另外可有多角形或四方形基本型式。因此, 個別可有如此應用型式,即適合完成構件之最終型式,例 如彎曲波浪或壓力容器。 容納金屬熔體的容器,例如坩堝,有通常的長度,最 大4公尺,直徑達1.5公尺。 在熔體和非熔體設備內,坩堝原則上被冷卻套筒所包 圍,用來引出製程熱。冷卻套筒本身爲鋼構造,另外亦可 構成把冷卻水導件以細縫或冷卻孔型式整合於銅合金壁上 〇 由美國專利2 1 5 5 40 5號已知一種銅合金,含0 . 25-3% 鎳,0.05-0.6磷,其餘爲銅。此爲導電値預設之合金。 具有導電性67% I ACS和較高的抗拉強度。 1264469 xf, I Q t|If-f,,:ri - — . __ _____ 乂. .___ J V. Description of the Invention (1) One aspect of the present invention relates to the use of a copper alloy as a material in a non-precipitation hardened state to manufacture a container for containing a metal melt, For example, vortexes for melt and non-melt equipment. Another aspect of the invention is directed to a method of making a container of a metal melt which is constructed of a copper-nickel alloy. Melt and non-melt processes are well known in practice. Designed to improve the quality of steel, and superalloys based on iron, nickel or cobalt. Yet another range of applications is in the manufacture of non-ferrous metals such as molybdenum, titanium, molybdenum or zirconium. The materials used to make 355 are usually copper and copper alloys with high thermal conductivity. Seamlessly welded or otherwise mounted 坩埚, usually in the form of a circular tube or square. In addition, there may be a polygonal or square basic pattern. Thus, individual applications may be of a type that is suitable for completing the final version of the component, such as a curved wave or pressure vessel. Containers containing metal melt, such as crucibles, have a typical length of up to 4 meters and a diameter of up to 1.5 meters. In melt and non-melt equipment, the crucible is in principle surrounded by a cooling jacket for introducing process heat. The cooling sleeve itself is of a steel construction, and may also be configured to integrate the cooling water guide into the copper alloy wall in the form of a slit or a cooling hole. A copper alloy is known from US Pat. No. 2 1 5 5 40 5 and contains 0. 25-3% nickel, 0.05-0.6 phosphorus, the balance being copper. This is the alloy of the conductive iridium preset. It has conductivity of 67% I ACS and high tensile strength. 1264469 xf, I Q t|
’㈣修(家)jL本J 五、發明說明(2 ) 又由EP-A1-ο 249 740號已知有析出硬化性銅合金, 由0.2-1.2%鎳和0.04 - 0.25%磷組成。此合金可應用在連 續鑄型之製造材料,以連續鑄造高熔點金屬。基於數小時 的析出硬化處理,此材料可達成硬度ΗΒ 2.5/62.5超過 1 1 5 〇 本發明之目的,在於提供宜作爲坩堝加入熔體和非熔 體設備內所用之材料,除所需熱機械特性外,具有傑出的 焊接性。 另方面提供視需要由多成份組成的金屬熔體用容器之 適當製法。 此目的之解決方式,一方面在於應用一種銅合金,包 含0.2-1.5%鎳,0.002-0.12%選自包含磷、銘、猛、鋰、 15、鎂、砂、硼組群之至少一元素,選用達〇 · 3%銷,其 餘爲包含銅而視製造狀況而定之雜質,作爲材料,以非析 出硬化狀態,來製造容納金屬熔體之容器,例如熔體和非 熔體設備用之坩堝。 本發明所應用合金更好是含0.6-1.3%鎳,〇.〇 u.Q6% 選自包含硼、鎂和磷組群之至少一元素,基餘爲包含銅而 視製造情況而定之雜質。 爲提高強度,合金內宜引進0·01至頂多0.3 %銷。 本發明目的之製法部份的解決方式,列於申請專利範 圍第5至6項。</ br> (4) 修 (家) jL本J. 5. Description of the invention (2) A precipitation hardenable copper alloy is known from EP-A1-o-249,740, which consists of 0.2-1.2% nickel and 0.04 - 0.25% phosphorus. This alloy can be applied to continuous casting of the material to continuously cast high melting point metals. Based on a few hours of precipitation hardening treatment, the material can achieve a hardness of 2.5/62.5 over 1 15 〇. The object of the invention is to provide a material suitable for use in the incorporation of melt and non-melt equipment, in addition to the required thermomechanical In addition to the characteristics, it has outstanding weldability. On the other hand, a suitable method for forming a container for a metal melt composed of a plurality of components as needed is provided. The solution to this object is, on the one hand, the use of a copper alloy comprising 0.2-1.5% nickel, 0.002-0.12% being selected from at least one element comprising phosphorus, Ming, Meng, Li, 15, magnesium, sand, boron groups, The Daxie 3% pin is used, and the rest is an impurity containing copper depending on the manufacturing conditions, and as a material, a non-precipitation hardening state is used to manufacture a container for accommodating the metal melt, such as a melt and a non-melt device. Preferably, the alloy used in the present invention contains 0.6-1.3% nickel, and 6%.〇 u. Q6% is selected from at least one element comprising a group of boron, magnesium and phosphorus, the basis being impurities comprising copper depending on the production. In order to improve the strength, the alloy should be introduced from 0. 01 to the top 0.3% pin. The solution to the method part of the object of the present invention is listed in items 5 to 6 of the patent application.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10032627A DE10032627A1 (en) | 2000-07-07 | 2000-07-07 | Use of a copper-nickel alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI264469B true TWI264469B (en) | 2006-10-21 |
Family
ID=7647847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW090116478A TWI264469B (en) | 2000-07-07 | 2001-08-02 | Copper-nickel-alloy and production method for its container |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US20020005235A1 (en) |
| EP (1) | EP1170074A1 (en) |
| JP (1) | JP2002053921A (en) |
| KR (1) | KR20020003507A (en) |
| CN (1) | CN1261604C (en) |
| AR (1) | AR029563A1 (en) |
| AU (1) | AU5403801A (en) |
| BR (1) | BR0102767A (en) |
| CA (1) | CA2352638A1 (en) |
| CZ (1) | CZ20012424A3 (en) |
| DE (1) | DE10032627A1 (en) |
| MX (1) | MXPA01006886A (en) |
| PL (1) | PL348478A1 (en) |
| RU (1) | RU2001119000A (en) |
| TR (1) | TR200101997A3 (en) |
| TW (1) | TWI264469B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10237052A1 (en) * | 2002-08-09 | 2004-02-19 | Km Europa Metal Ag | Use of a low-alloy copper alloy and hollow profile component made from it |
| CN100545282C (en) * | 2004-02-27 | 2009-09-30 | 古河电气工业株式会社 | Copper alloy |
| JP4312641B2 (en) * | 2004-03-29 | 2009-08-12 | 日本碍子株式会社 | Copper alloy having both strength and conductivity and method for producing the same |
| CN1300353C (en) * | 2004-05-28 | 2007-02-14 | 四川省宇太科技有限公司 | Copper alloy with high thermal conductivity |
| US8956600B2 (en) | 2009-08-10 | 2015-02-17 | Taiwan Liposome Co. Ltd. | Ophthalmic drug delivery system containing phospholipid and cholesterol |
| JP2012051766A (en) * | 2010-09-02 | 2012-03-15 | Sumco Corp | Continuous casting method of silicon ingot |
| CN109079116A (en) * | 2018-07-10 | 2018-12-25 | 浙江力博实业股份有限公司 | A kind of preparation method of electrode material corson alloy |
| DE102018122574B4 (en) * | 2018-09-14 | 2020-11-26 | Kme Special Products Gmbh | Use of a copper alloy |
| CN109706343A (en) * | 2018-12-10 | 2019-05-03 | 上海海亮铜业有限公司 | A kind of nickel doping C12200 red copper alloy |
| JP7545257B2 (en) * | 2020-08-06 | 2024-09-04 | 東邦チタニウム株式会社 | Hearthstone |
| CN112375939B (en) * | 2020-11-16 | 2021-11-09 | 福州大学 | Cu-Ni-Zr-V-B copper alloy material and preparation method thereof |
| CN114540660A (en) * | 2021-11-11 | 2022-05-27 | 佛山中国发明成果转化研究院 | High-strength high-conductivity copper alloy and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2155405A (en) * | 1938-04-28 | 1939-04-25 | Chase Brass & Copper Co | Electrical conductor |
| EP0249740B1 (en) * | 1986-06-20 | 1989-10-25 | KM-kabelmetal Aktiengesellschaft | Using a copper alloy |
| DE3620654A1 (en) * | 1986-06-20 | 1987-12-23 | Kabel Metallwerke Ghh | COPPER ALLOY |
| DE3725950A1 (en) * | 1987-08-05 | 1989-02-16 | Kabel Metallwerke Ghh | USE OF A COPPER ALLOY AS A MATERIAL FOR CONTINUOUS CASTING MOLDS |
| DE4427939A1 (en) * | 1994-08-06 | 1996-02-08 | Kabelmetal Ag | Use of a hardenable copper alloy |
-
2000
- 2000-07-07 DE DE10032627A patent/DE10032627A1/en not_active Withdrawn
-
2001
- 2001-06-25 AU AU54038/01A patent/AU5403801A/en not_active Abandoned
- 2001-06-27 KR KR1020010036911A patent/KR20020003507A/en not_active Ceased
- 2001-06-29 CZ CZ20012424A patent/CZ20012424A3/en unknown
- 2001-06-30 EP EP01116000A patent/EP1170074A1/en not_active Withdrawn
- 2001-07-04 AR ARP010103193A patent/AR029563A1/en unknown
- 2001-07-05 MX MXPA01006886A patent/MXPA01006886A/en unknown
- 2001-07-05 PL PL01348478A patent/PL348478A1/en not_active Application Discontinuation
- 2001-07-06 JP JP2001206482A patent/JP2002053921A/en not_active Withdrawn
- 2001-07-06 CA CA002352638A patent/CA2352638A1/en not_active Abandoned
- 2001-07-06 CN CNB011217537A patent/CN1261604C/en not_active Expired - Fee Related
- 2001-07-06 BR BR0102767-0A patent/BR0102767A/en not_active Application Discontinuation
- 2001-07-06 TR TR2001/01997A patent/TR200101997A3/en unknown
- 2001-07-06 RU RU2001119000/02A patent/RU2001119000A/en not_active Application Discontinuation
- 2001-08-02 TW TW090116478A patent/TWI264469B/en not_active IP Right Cessation
- 2001-09-10 US US09/950,382 patent/US20020005235A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CZ20012424A3 (en) | 2002-07-17 |
| BR0102767A (en) | 2002-02-19 |
| CA2352638A1 (en) | 2002-01-07 |
| KR20020003507A (en) | 2002-01-12 |
| AR029563A1 (en) | 2003-07-02 |
| CN1261604C (en) | 2006-06-28 |
| TR200101997A2 (en) | 2002-02-21 |
| CN1332258A (en) | 2002-01-23 |
| EP1170074A1 (en) | 2002-01-09 |
| JP2002053921A (en) | 2002-02-19 |
| MXPA01006886A (en) | 2003-08-20 |
| TR200101997A3 (en) | 2002-02-21 |
| PL348478A1 (en) | 2002-01-14 |
| AU5403801A (en) | 2002-01-10 |
| DE10032627A1 (en) | 2002-01-17 |
| RU2001119000A (en) | 2003-06-27 |
| US20020005235A1 (en) | 2002-01-17 |
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| MM4A | Annulment or lapse of patent due to non-payment of fees |