TWI253315B - Forming pattern on the anodized surface of an object and a portable electronic device cover with the pattern - Google Patents
Forming pattern on the anodized surface of an object and a portable electronic device cover with the pattern Download PDFInfo
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- TWI253315B TWI253315B TW091114249A TW91114249A TWI253315B TW I253315 B TWI253315 B TW I253315B TW 091114249 A TW091114249 A TW 091114249A TW 91114249 A TW91114249 A TW 91114249A TW I253315 B TWI253315 B TW I253315B
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- 239000000758 substrate Substances 0.000 claims abstract description 23
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- 239000002184 metal Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 21
- 238000004040 coloring Methods 0.000 claims description 11
- 238000007743 anodising Methods 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 230000000750 progressive effect Effects 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 4
- 238000006386 neutralization reaction Methods 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims 1
- 239000010407 anodic oxide Substances 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- 238000005562 fading Methods 0.000 claims 1
- 230000001678 irradiating effect Effects 0.000 claims 1
- 239000010410 layer Substances 0.000 description 10
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 239000000956 alloy Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- -1 bismuth metals Chemical class 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/18—After-treatment, e.g. pore-sealing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
Description
1253315 九、發明說明: 【發明所屬之技術領域】 本發明係關於一種在物體表面製作圖案之方法及使用該方法製造 之攜帶式電子裝置外殼。 【先前技術】 、韃金屬如鋁及鋁合金、鈦及鈦合金等在製造工業上應用愈來愈廣 ’乏為提咼該等製品之抗腐蝕性能及表面裝飾性而將製品進行陽極處 理,,於其表面形成氧化膜保護層,該氧化膜具有高硬度、高耐磨損 性、高光澤、易於著色等特性,且氧化膜之耐熱性及其與襯底間附著 性能均較佳,是以非常適於用作製品表面保護及裝飾豸。而在多數情 况下需要於製品表面形成裝侧案,如字母數字符號、裝飾網印刷、 黏貼等方法工藝雜較繁項,且在許錯況下从滿足要求。近年來 ,多廠商已開發並利用雷射光照射方法標記陽極氧化處理表面,主要 是於,製品陽極氧化表刺成標記之區域上,提供—種雷射光照射影 響下能改贿色之塗層,並於其上藉由雷射光照射從而進行標記,其 缺點係該陽極氧化處理層要配置另一塗層因而增加成本,且該塗層^ 抗磨損性、硬度、耐熱性及耐腐蝕性等不及於陽極氧化層,是以^圮 易於脫落或磨損。另,亦有不·雷射光照射下改變顏^特殊:質 之雷射光標記方法,例如2002年2月20日公開之中國專利公開第 CN1336878A號揭示的於具有襯底及陽極氧化處理外層之减銘人金 物件表面提供標記之方法,錢由雷射光賴鶴魏化表面形^ 就區域,控制f射光束以使其較大部分透過氧化層,且 : 襯底的陽極氧化處理外層的局部區域引起至少一個可視特性 ^ 而得到人眼可觀察_標記,該方法形成之標記牢固且 = 化膜基體之賴,惟該方法形成之標記色軸較單調,因而=才 光束只使接近襯底的陽極氧化處理外層局部區域可視 射 控製,不宜形成形狀複雜之標記或圖案,二 述雷射先軚纪方法均有設備成本及能耗較高之缺陷。 叮 【發明内容】 6 本^之目的在於提供—種於驗氧化表面形成圖案之方法該 方法工藝簡便,成本較低。 幽6本發明之次—目的在於提供—種於陽極氧化表面形成的具有色彩 豆备、圖案牢固、形狀複雜之圖案。 本發明之另-目的在於提供一種具有陽極處理製品底色漸進之圖 業’所形成之圖案更美觀且富有層次感。 本發明之再—目的在於提供—種具有以上所麟徵之目案之攜帶 式電子裝置外殼。 壯本發明揭示-種製作圖案之方法及使用該方法製造之攜帶式電子 ^置外殼。其中該製造方法包括如下麵:首先對金屬基體或鏡有金 屬層之塑縣體進行聽理,再經過陽極氧化及著色纽使基體表面 =成有^陽極氧賴,最後藉紫外級過_具有預定圖案形狀之模板 ^上述著色後的陽極氧化表面進行照射,使被照射之陽極氧化表面部 域色,直至形成翻色調之酸,該色調可為底色色系之任一顏色, 色調廣泛。另,藉由此製作方法亦可形成具有陽極氧化表面底色漸進 之圖案,且成本較低、工藝較為簡便。藉由該方法製造之便攜式電子 裝置外殼,其殼體上可獲得較殼體顏色淺之同色系彩色随或漸進色 圖案。 【實施方式】 請參閱第-圖及第二圖所示,其揭示之製品丨包括概底1G及一陽 極氧化膜層12。該製品之製造方法包括:將銘祕合金材料經衝壓或 其他習知加王方法製成製品,並藉由習知方法進行脫脂、水洗、驗钱 洗、中和、抛光紅序進行預處理以清除製品表面存在的污垢和缺陷 而露出純淨的鋁基體即襯底10,俾利陽極氧化及著色處理順利進行; 之後以上雜轴合金製品為陽極,贿為陰極,在⑽_2Q()g/L的硫 酸溶液中直流陽極氧化,直流電壓為8-16V,電流密度為 ^0.0-200·()ΑΛη2,經3請分鐘氧化處理即可形成厚度為仙2〇二二 陽極氧化膜;陽極氧化之鋁製品經水洗後置入著色槽中,著色槽内盛 有濃度為Ι-lg/L的有機染料溶液,鋁製品在有機染料溶液中浸泡5_2〇 分鐘後取出進行乾燥,如是製品i表面便形成彩色陽極氧化膜12;請 參閱第三圖、第四圖及第五圖所示,製作一玻璃模板2,模板2上具有 與製品1表面預形成之圖案15輪廓相同之圖案25,紫外光3可透過哕 模板圖案25,而模板2上除圖案25外之其他區域上塗有隔離層以阻止 紫外光透過,使紫外光3透過模板2照射陽極氧化膜12,在照射區紫 外光使1%極氧化膜中有機染料分子部分分解而褪色。控制照射時間^ 至得到預期色調之圖案15,該圖案15相對於陽極氧化膜12之底色較 淺。 、/上述模板2可藉由習知方法如將預定形成的圖案輸入電腦系統並 進行漸進色編輯處理從而使製得之模板在各區域對紫外光之透過率不 ,,當紫外光透過該模板對待形成圖案之製品進行照射時,被照射之 陽極氧化表面發生不同程度褪色從而形成底色漸進色系之圖案了所形 成之圖案更美觀,且具有層次感。 〆 上述襯底10可以是鋁合金或其他輕金屬,或者係在射出成型後的 塑勝基體上經齡塗錢鍍等方法難或|3合金或其他 膠基體上-成,随15亦可驗品或標記等,且可製成各種开 1 狀。 —另,上述陽極氧化處理可由習知陽極處理之任一方法實現。同理, ^色處理亦可由自然著色或電解著色等習知方法實現,在此不作詳細 έ先明。 可以轉,將上述方賴_帶«?裝置外殼之製造中,即可 又j寻/、有夕種外觀顏色且具有以上所述特徵之標誌、或圖案之電子裝置 外殼。 岛a月氣作圖案之方法’因其於陽極氧化表面藉紫外光照射褪 :疋,該方法簡便易行,成本較低,形成之圖案牢固,且帶有圖案 =氧化膜層對製品具有較佳的保護效果及裝飾效果。另,藉由該 作=法可形成底色漸進色之_,富有層次感,因而使製品更美觀。 惟,^上所述’本發明已符合發明專利要件,爰依法提出專利申請。 ’以上所述者僅為本發明之較佳實細,舉凡熟悉本案技藝之人士, 1253315 在援依本案發明精神所作之等效修飾或變化者,皆應包含於以下之申 請專利範圍内。 【圖式簡單說明】 第一圖係本發明實施例之製品其表面未形成圖案之示意圖; 第二圖係第一圖所示製品沿II-II線之剖視圖; 第三圖係於製品表面製作標記之操作示意圖; 第四圖係本發明實施例之製品其表面形成圖案之示意圖; 第五圖係第四圖所示製品沿V-V線之剖視圖。 【主要元件符號說明】 製品 1 襯底 10 陽極氧化膜 12 製品圖案 15 模板 2 模板圖案 25 紫外光 31253315 IX. Description of the Invention: [Technical Field] The present invention relates to a method of patterning an object surface and a portable electronic device casing manufactured using the same. [Prior Art], bismuth metals such as aluminum and aluminum alloys, titanium and titanium alloys are becoming more and more widely used in the manufacturing industry. 'There is no need to improve the corrosion resistance and surface decoration of these products, and the products are anodized. Forming an oxide film protective layer on the surface thereof, the oxide film has characteristics of high hardness, high abrasion resistance, high gloss, easy coloring, etc., and the heat resistance of the oxide film and the adhesion property to the substrate are both better. It is very suitable for use as a surface protection and decoration for products. In most cases, it is necessary to form a side case on the surface of the product, such as alphanumeric symbols, decorative screen printing, pasting, etc., which are complicated and complicated, and satisfy the requirements under the circumstance. In recent years, many manufacturers have developed and used the laser light irradiation method to mark the anodized surface, mainly in the area where the anodized surface of the product is punctured into a mark, providing a coating that can change the color of the color under the influence of the laser light irradiation. And marking thereon by laser irradiation, the disadvantage is that the anodized layer is disposed with another coating layer, thereby increasing the cost, and the coating is less resistant to abrasion, hardness, heat resistance and corrosion resistance. In the anodized layer, it is easy to fall off or wear. In addition, there is also a method for changing the color of the laser light under the illumination of the laser light, such as the substrate and the anodized outer layer disclosed in Chinese Patent Publication No. CN1336878A, published on Feb. 20, 2002. The method of providing marking on the surface of the gold object of the inscription, the money is made by the laser light, and the surface is shaped to control the f-beam to pass a larger portion thereof through the oxide layer, and: the local region of the outer layer of the anodized surface of the substrate Inducing at least one visual characteristic ^ to obtain a human eye observable _ mark, the method forms a mark firmly and = the film base depends, but the method of forming the color axis of the mark is more monotonous, so that the beam only closes the substrate The localized area of the outer layer of the anodizing treatment can be controlled by light, and it is not suitable to form a mark or pattern with complicated shapes. The second method of the first-stage laser has the defects of high equipment cost and high energy consumption.叮 【Contents】 6 The purpose of this is to provide a method for forming a pattern on an oxidized surface. The method is simple in process and low in cost. The second aspect of the invention is to provide a pattern of colored beans, a strong pattern, and a complex shape formed on the anodized surface. Another object of the present invention is to provide a pattern having a progressive color of an anodized article which is more aesthetically pleasing and layered. A further object of the present invention is to provide a portable electronic device housing having the above-mentioned items. The invention discloses a method for making a pattern and a portable electronic housing manufactured by the method. The manufacturing method includes the following: firstly, the metal substrate or the plastic body having the metal layer of the mirror is subjected to auditory treatment, and then the anodizing and coloring are performed to make the surface of the substrate have an anode oxygen dialysis, and finally the ultraviolet level is over _ The template of the predetermined pattern shape is irradiated with the anodized surface after the coloring, so that the surface of the anodized surface to be irradiated is colored until a tone acid is formed, and the color tone can be any color of the background color system, and the color tone is wide. In addition, by this manufacturing method, a pattern having a gradual color of the anodized surface can be formed, and the cost is low and the process is simple. The portable electronic device casing manufactured by the method can obtain a homochromatic color or progressive color pattern which is lighter in color than the casing. [Embodiment] Referring to the first and second figures, the article disclosed therein includes a base 1G and an anode oxide film layer 12. The method for manufacturing the product comprises: preparing the alloy material by stamping or other conventional methods, and performing pretreatment by degreasing, water washing, money washing, neutralization, and polishing red order by a conventional method. The dirt and defects existing on the surface of the product are removed to expose the pure aluminum substrate, that is, the substrate 10, and the anodic oxidation and coloring treatment are smoothly carried out; after that, the above hetero-ax alloy products are anodes, bribes are cathodes, and (10)_2Q()g/L DC anodizing in sulfuric acid solution, DC voltage is 8-16V, current density is ^0.0-200·()ΑΛη2, after 3 minutes oxidation treatment can form a thickness of 2〇2 2 anodized film; anodized aluminum The product is washed into water and placed in a coloring tank. The coloring tank contains an organic dye solution having a concentration of Ι-lg/L. The aluminum product is immersed in the organic dye solution for 5-2 minutes, and then taken out for drying. If the surface of the product i is colored, the color is formed. Anodized film 12; please refer to the third, fourth and fifth figures to fabricate a glass template 2 having a pattern 25 having the same contour as the pattern 15 pre-formed on the surface of the article 1, UV light 3 through The template pattern 25 is passed through, and the other areas of the template 2 except the pattern 25 are coated with an isolation layer to block the transmission of ultraviolet light, so that the ultraviolet light 3 is irradiated through the template 2 to the anodized film 12, and the ultraviolet light in the irradiation region is 1%. The organic dye molecules in the film partially decompose and fade. The irradiation time is controlled to obtain a pattern 15 of a desired hue which is shallow relative to the undertone of the anodized film 12. The template 2 can be input into a computer system by a conventional method such as inputting a predetermined pattern into a computer system and performing progressive color editing processing so that the transmittance of the template to ultraviolet light is not in each region, when ultraviolet light is transmitted through the template. When the patterned article is irradiated, the illuminated anodized surface is discolored to a different extent to form a pattern of the background color progressive color, and the formed pattern is more beautiful and has a layered feeling. The above substrate 10 may be an aluminum alloy or other light metal, or may be difficult to be coated on the plastic substrate after injection molding, or may be alloyed on other alloys or other adhesive substrates. Or marking, etc., and can be made into a variety of open 1 shape. Alternatively, the anodizing treatment described above can be carried out by any of the conventional anodizing methods. Similarly, the color processing can also be realized by a conventional method such as natural coloring or electrolytic coloring, and will not be described in detail herein. In the manufacture of the above-mentioned device, it is possible to find the electronic device casing which has the appearance of the color and has the above-mentioned features or the pattern. The method of the island a month gas pattern is because the anodic oxidation surface is exposed by ultraviolet light: 疋, the method is simple and easy, the cost is low, the formed pattern is firm, and the pattern = oxide film layer has a comparative effect on the product. Good protection effect and decorative effect. In addition, by using the method, the gradual color of the ground color can be formed, which is rich in layering, thereby making the product more beautiful. However, the above description has been made in accordance with the invention patent requirements, and the patent application is filed according to law. The above is only the preferred embodiment of the present invention. Those who are familiar with the art of the present invention, 1253315, equivalent modifications or variations in the spirit of the invention, should be included in the following claims. BRIEF DESCRIPTION OF THE DRAWINGS The first drawing is a schematic view of a product of the embodiment of the present invention, and the surface thereof is not patterned; the second drawing is a cross-sectional view of the product shown in the first figure along line II-II; The schematic diagram of the operation of the mark; the fourth figure is a schematic view of the surface of the product of the embodiment of the present invention; the fifth figure is a cross-sectional view of the article shown in the fourth figure along the line VV. [Main component symbol description] Product 1 Substrate 10 Anodized film 12 Product pattern 15 Template 2 Template pattern 25 Ultraviolet light 3
Claims (1)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW091114249A TWI253315B (en) | 2002-06-28 | 2002-06-28 | Forming pattern on the anodized surface of an object and a portable electronic device cover with the pattern |
| KR1020020068380A KR20040002357A (en) | 2002-06-28 | 2002-11-06 | Method of forming patterns on anodized surfaces of objects and portable electronic device cover produced thereby |
| US10/299,247 US20040000490A1 (en) | 2002-06-28 | 2002-11-18 | Method of forming mark on anodized surface of aluminum object |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW091114249A TWI253315B (en) | 2002-06-28 | 2002-06-28 | Forming pattern on the anodized surface of an object and a portable electronic device cover with the pattern |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TWI253315B true TWI253315B (en) | 2006-04-11 |
Family
ID=29778240
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW091114249A TWI253315B (en) | 2002-06-28 | 2002-06-28 | Forming pattern on the anodized surface of an object and a portable electronic device cover with the pattern |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US20040000490A1 (en) |
| KR (1) | KR20040002357A (en) |
| TW (1) | TWI253315B (en) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2257216B1 (en) * | 2005-09-22 | 2007-03-16 | Marcajes Telleria, S.L. | PROCEDURE FOR THE ENGRAVING OF METAL PLATES. |
| US20080312654A1 (en) * | 2007-06-15 | 2008-12-18 | Pioneer Surgical Technology, Inc. | Method for Marking Orthopedic Implant |
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-
2002
- 2002-06-28 TW TW091114249A patent/TWI253315B/en not_active IP Right Cessation
- 2002-11-06 KR KR1020020068380A patent/KR20040002357A/en not_active Withdrawn
- 2002-11-18 US US10/299,247 patent/US20040000490A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| KR20040002357A (en) | 2004-01-07 |
| US20040000490A1 (en) | 2004-01-01 |
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