[go: up one dir, main page]

TW384313B - High strength steels having high impact energy absorption properties and a method for producing the same - Google Patents

High strength steels having high impact energy absorption properties and a method for producing the same Download PDF

Info

Publication number
TW384313B
TW384313B TW086117962A TW86117962A TW384313B TW 384313 B TW384313 B TW 384313B TW 086117962 A TW086117962 A TW 086117962A TW 86117962 A TW86117962 A TW 86117962A TW 384313 B TW384313 B TW 384313B
Authority
TW
Taiwan
Prior art keywords
iron
distortion
less
temperature
deformation
Prior art date
Application number
TW086117962A
Other languages
Chinese (zh)
Inventor
Yukihisa Kuriyama
Manabu Takahashi
Osamu Kawano
Riki Okamoto
Yuzo Takahashi
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27521028&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=TW384313(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from JP33138096A external-priority patent/JPH10158735A/en
Priority claimed from JP22300597A external-priority patent/JPH1161326A/en
Priority claimed from JP25888797A external-priority patent/JP3530355B2/en
Priority claimed from JP25883497A external-priority patent/JP3530353B2/en
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Application granted granted Critical
Publication of TW384313B publication Critical patent/TW384313B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0226Hot rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/001Austenite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/002Bainite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/005Ferrite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D2211/00Microstructure comprising significant phases
    • C21D2211/008Martensite
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0221Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
    • C21D8/0236Cold rolling
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
    • C21D8/0247Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
    • C21D8/0273Final recrystallisation annealing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Heat Treatment Of Sheet Steel (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The present invention provides high strength steels having high impact energy absorption properties used for energy absorbing automotive components, such as front side members, and also provides a method for producing the same. The high strength steels having high impact energy absorption properties, according to the present invention, are the steels which have the microstructure of mixtures of ferrite and/or bainite with the third component including retained austenite of the volume fraction between 3% and 50%, with the dominating microstructural component of either ferrite or bainite, and the average flow stress sigma dyn (Mpa) between 3 and 10% of equivalent strain, should be greater than the value of 0.776 x TS + 250, where TS(Mpa) is the maximum flow stress obtained by static tensile test at 5x10<-4>~5x10<-3>(1/s) of strain rate before the pre-deformation, as well as the work hardening coefficient between 1~5% of strain greater than 0.080.

Description

A7 B7A7 B7

鯉濟部中央裸準局工消费i作杜印IL 五、發明说明( 本發明係有關於具有高動態變形抵抗之高強度熱札麵 板舆冷札納板以及其製造方法。該等麵板因能有效吸收碰 撞時之沖擊能量,對於車輛搭乘人員可確實提供安全性而 被使用於汽車構件。 近年,汽車碰撞時能保護搭乘人員係被認為是汽車之 最重要性能,且對此具有較高之高速變形抵抗之材料已成 為眾所企盼。例如在載客汽車前螭衝撞時,如將此種材料 使用於所謂車架前端邊樑時’藉該材料被壓溃即可吸收沖 擊能量,而緩和該種衝擊對於搭乘人貝之影響。 由於汽車碰撞時之各部位所受變形之畸變速度可達 103(l/s)程度’如自材料之衝擊吸收能加以考量,就須明 硖地解剖如是高畸變速度下之動態變形抵抗。亦須考量如 何使能源節省,削減C〇2之排出並同時達成汽車車艚輕量 化之目標’故對此有效之高強度鋼板之需要乃增高β 例如,本發明人等在 CAMP-ISIJVol. 9 (1996) ρρ. 1112 〜1115所作高強度鋼板之高速變形特性及衝擊能董吸收能 之報告中,曾提示過l〇3(l/s)程度高畸變速度領域之動態 強度比較l〇_3(i/s)低畸變速度下之靜態強度可大幅上升 ,及藉強化材料之結構可變更其變形抵抗之畸變速度依賴 性,以及其中TRIP(變態誘導塑性)型鋼及DP(肥粒鐵/麻 田散鐵雙相)型銅較其他之高強度鋼板更具有卓越成型性 及衝擊吸收能。 又,以可提供含有殘留沃斯田鐵且耐衝擊特性較佳之 高強度鋼板及其製造方法而言,在特開平7-18372號公報 本纸張 XA 適樣率 T^^Ui()x297i:in ----------cf, {請先《讀背面之注意事項再镇寫本頁) 訂' Μ濟部中央標準局Λ工消费合作社印裝 A7 __B7_ 五、發明説明(2 ) 乃開示有將衝擊吸收能僅由隨伴變形速度上升致使降伏應 力上升即可解決乙節,卻未明確表示為了提升沖擊吸收能 ,除殘留沃斯田鐵之量以外應如何控制殘留沃斯田鐵之特 性。 如是,對於汽車衝撞時之沖擊能量吸收能具有影響之 零件構成材料之動態變形特性雖稍些地逐步被解明,然, 以具較佳沖擊能量吸收能之汽車構件用鋼材而言,應注意 那些特性及應依據何種基準選擇材料則尚未被解明&quot;又, 汽車構件用鋼材乃經壓榨成型並被成型為所需構件形狀後 ,通常再塗裝焙烤並組裝於汽車才面對實際衝撞現象。但 ,對於進行如此予先變形+焙烤處理後之鋼材,為提升其 衝撞時之沖擊能量吸收能應適用何種鋼材強化結構較宜則 尚未被解明》 因此,本發明之目的係在提供一種可顯示高沖擊能量 吸能之高強度鋼板及其製造方法。該高強度鋼板乃是一種 能加工成型為汽車衝撞時可吸收車架前端邊樑之沖擊能量 之構件用鋼材。 爰是本發明之可顯示高沖擊能量吸收能之高強度鋼板 即是: (1)其最後所獲鋼板之微視組織乃含有肥粒鐵及/或 變韌鐵,為一種以其中任一為主相舆含有體積分率3〜50 %殘留沃斯田鐵之第3相複合之組織,且其經等效畸變〇% 以上10%以下予先變形後再於5X102〜5X103 (Ι/s)畸變 速度範圍變形時之3〜10%等效畸變範圍之變形應力平均 本紙張尺度適用+國國家標準(CMS ) A4規格(210X297公釐) L—Il·----C飞裝—— (請先鬩讀背面之注$項再填寫本頁)Consumption of the central naked quasi-stationary worker of the Ministry of Economic Affairs of the People's Republic of China Du Duan IL 5. Description of the invention (The present invention relates to a high-strength hot-stamped panel with high dynamic deformation resistance, a cold-stamped panel, and a manufacturing method thereof. Because it can effectively absorb the impact energy at the time of collision, it can be used for automobile components to provide safety for vehicle occupants. In recent years, the protection of passengers during automobile collisions is considered to be the most important performance of automobiles. High-speed high-speed deformation resistance materials have become much anticipated. For example, when a passenger car crashes in the front, if this material is used in the so-called front end side frame of the frame, 'the impact energy can be absorbed by the material being crushed, And to mitigate the impact of this kind of impact on passengers. As the distortion speed of various parts of the car during collision can reach 103 (l / s), if the impact absorption energy of the material is considered, it must be clearly understood. If the anatomy is the resistance to dynamic deformation at high distortion speeds, it is also effective to consider how to save energy, reduce the emission of C02, and simultaneously achieve the goal of lightweight car weight. The need for high-strength steel plates is to increase β. For example, the inventors have suggested in the report of high-speed deformation characteristics and impact energy of high-strength steel plates made by CAMP-ISIJVol. 9 (1996) ρρ. 1112 to 1115. l03 (l / s) dynamic strength comparison in the field of high distortion speed l0_3 (i / s) static strength at low distortion speed can be greatly increased, and the deformation resistance can be changed by the structure of the reinforcing material Speed dependence, and TRIP (Metamorphically Induced Plasticity) steel and DP (Fat Grain Iron / Matian Loose Iron Duplex) type copper are more excellent in formability and impact absorption energy than other high-strength steel plates. For the high-strength steel sheet with residual Vostian iron and good impact resistance, and its manufacturing method, the paper XA sample rate T ^^ Ui () x297i: in ----- ----- cf, {Please read the “Notes on the back side before writing this page”) Order 'Μ Printed by the Central Standards Bureau of the Ministry of Economic Affairs Λ_Consumer Cooperative Cooperative A7 __B7_ V. Description of the invention (2) It will be affected by the disclosure Absorptive energy can only be solved by the rise of the falling stress caused by the accompanying increase in the deformation speed Section, but did not expressly order to enhance the impact absorption energy, in addition to the amount of residual austenite of how to control the characteristics of the residual austenite. If so, although the dynamic deformation characteristics of parts constituting materials that have impact energy absorption energy at the time of a car collision have been gradually explained, of course, for steel materials for automobile components with better impact energy absorption energy, attention should be paid to those The characteristics and selection of materials based on which standards have not yet been explained. Also, after the steel for automobile components is pressed and formed into the shape of the required component, it is usually painted, baked and assembled in the automobile to face the actual collision phenomenon. . However, it is not clear which steel should be used to strengthen the structure of the steel material after such pre-deformation + baking treatment to improve its impact energy absorption energy during impact. Therefore, the object of the present invention is to provide a High-strength steel plate showing high impact energy absorption and manufacturing method thereof. This high-strength steel plate is a steel material that can be processed into a component that can absorb the impact energy of the front side frame of a frame when a car crashes.爰 is the high-strength steel plate of the present invention which can display high impact energy absorption energy, namely: (1) the microscopic structure of the steel plate finally obtained contains fat iron and / or toughened iron, The main phase contains a volume fraction of 3 ~ 50% of the residual third-phase composite structure of Vostian Iron, and its equivalent distortion is 0% or more and 10% or less before it is deformed and then 5X102 ~ 5X103 (I / s) Distortion speed range 3 ~ 10% of equivalent distortion range equivalent deformation stress during deformation This paper size is applicable + National National Standard (CMS) A4 specification (210X297 mm) L—Il · ---- C Fly-mounted—— ( (Please read the note on the back before filling in this page)

*tT i/w -6 - A7 __ ._B7_ 五、發明説明(3 ) 值adyn(MPa),可滿足其施加予先變形前在5X10·4〜5X 1〇·3 (Ι/s)畸變速度範面測得之靜態拉力試驗之最大應 力TS(MPa)所表示算式adyn20.766XTS + 250、並其畸 變1〜5%之加工硬化指數可滿足0.080以上具有高動態變 形抵抗之高強度鋼板。亦是, (2) 上述(1)之其降伏強度X畸變1〜5%之加工硬化指 數值更能滿足40以上之具有高動態變形抵抗之高強度鋼板 。亦是, (3) 其最後所獲鋼板之微視組織含有肥粒鐵及/或變 韌鐵,為一種以其中任一為主相舆含有艟積分率3〜50% 殘留沃斯田鐵之第3相複合之組織,且其經等效畸變〇%以 上10%以下予先變形後再於5X102〜5X 1〇3 (Ι/s)畸變速 度範面變形時之3〜10%等效畸變範圍之變形應力平均值 經濟部中央揉準局W?工消费合作杜印氧 (請先閱讀背面之注$項再填寫本頁) -crdyWMPa),可滿足其施加予先變形前在5ΧΗΤ»〜5x10-3 (1/ s)畸變速度範圍測得之势態拉力試驗之最大應力 TS(MPa)所表示算式σ dyn 2 0.766 X TS + 250,並上述殘 留沃斯田鐵t固溶〔C〕舆鋼材平均Μη等量{Mn eq = Mn + (Ni+Cr+Cu + Mo)/2}所決定之值(Μ) M=678 —428 X〔C〕一 33Mn eq為70以上250以下,復又可滿足其予先 變形前之殘留沃斯田鐵艎積分率與其經等效畸變5%予先 變形後之殘留沃斯田鐵體積分率之差為施加予先變形前之 殘留沃斯田鐵艎積分率3%以上、及畸變1〜5%之加工硬 化指數0.080以上,及上述殘.留沃斯田鐵之平均結晶粒徑 為5 以下,及上述殘留沃斯田鐵之平均結晶粒徑與主 本纸張尺度適用中國國家揉準(CNS ) Μ規格(210X297公釐) 7 . A7 B7 五、發明説明(4 ) 相之肥粒鐵或變韌鐵之平均結晶粒徑之比為0.6以下、且 主相之平均粒徑10#m以下最好為6/zm以下,及麻田散鐵 «積分率為3〜30%,該麻田散鐵之平均結晶粒徑10/zm 以下最好為5 以下,及肥粒鐵饉積分率為40%以上, 及降伏比為85%以下,拉力強度X總延伸率之值為20,000 以上、之任一項之具有高動態變形抵抗之高強度鋼板。亦 是, (4) 以重量計,含有C : 0.03%以上0.3%以下,Si舆A1 之一方或雙方合計0.5%以上3.0%以下,及因應所需含有 河11、1^、(:1'、0:11、1^〇中之一種或兩種以上合計0.5%以 上3.5%以下,且其餘為以Fe為主成份之高強度鋼板,或 該高強度鋼板依需更含有1^、1'丨、乂、?、8、€3、1^1^ 之一種或兩種以上,其中Nb、Ti、V之一種或兩種以上合 計為0.3%以下,P為0.3%以下,B為0.01%以下,Ca為0.0005 %以上0.01%以下,REM : 0.005%以上0.05%以下,其餘 則以Fe為主成份之具高動態變形抵抗之高強度鋼板。 經濟部中央橾準局負工消費合作杜印製 (請先Μ讀背面之注$項再填寫本頁) (5) 本發明之具有高動態變形抵抗之高強度熱軋鋼板之 製造方法係為將具有上述(4)所示組成成份之連續鑄造扁 鋼胚,以鑄造原樣直送熱軋工程,或經冷卻再加熱後予以 熱軋,即以Ar3 — 50aC〜Ar3 + 120°C之加工溫度完成熱軋 ,並繼該熱軋在冷卻過程經過平均冷卻速度5t/秒以上 '&quot; ----- - v 冷卻後,以500t以下溫度加以繞取熱軋鋼板為特徵者。 而該熱軋鋼板之微視組織乃含有肥粒鐵及/或變韌鐵,是 一種以其中任一為主相與含有體積分率3〜50%殘留沃斯 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 經濟部中央揉準局負工消费合作社印装 A7 B7 五、發明説明(5 ) 田鐵之第3相複合之組織,且其經等效畸變0%以上10%以 下予先變形後再於5X102〜5Xl03(l/s)畸變速度範面變 形時之3〜10%等效畸變範圍之變形應力平均值σ dyn (1^?3),可滿足其施加予先變形前在5父1〇-4〜5父1〇-3(1/3) 畸變速度範圍測得之靜態拉力試驗之最大應力TS(MPa)所 表示算式adyn2 0.766XTS + 250、並其畸變1〜5%之加 工硬化指數可滿足0.080以上具有高動態變形抵抗之高強 度熱軋鋼板製造方法。亦是, (6)上述(5)之熱軋加工溫度為Ar3 - 50°C〜Ar3 + 120°C 之溫度輯面時,進行其金屬參數:A可滿足下列(1)式及(2) 式之熱軋,且將流出台之平均冷卻速度設成5°C/秒以上 ,及上述金屬參數:A與繞取溫度(CT)之關係可滿足(3)式 之條件,而加以繞取之具有高動態變形抵抗之高強度熱軋 鋼板製造方法》 9^1ogA^18 (1) △ T221XlogA- 178 (2) CTS6XlogA+312 ........(3) (7)又,本發明之具有高動態變形抵抗之高強度冷軋 鋼板之製造方法為將具有上述(4)所示組成成份之連續鑄 造扁鋼胚,以鑄造原樣直送熱軋工程,或經冷卻再加熱後 予以熱軋,且將熱軋後繞取之熱軋鋼板施以酸洗冷軋,£ 經連續退火工程加以退火製成最後產品時,在〇.IX (Ac3 —Ac丨)+ Ac/C以上Ac3 + 50°C以下溫度退火10秒〜3分鐘 後,以1〜10°C/秒之一次冷卻速度冷卻至550〜700°C範 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) L--------ci------tr-----Q (請先Μ讀背面之注f項再填寫本頁) -9 - 經濟部中央橾準局w;工消费合作社印氧 A7 B7 五、發明説明(6 ) 圍之一次冷卻停止溫度’炎繼之以10〜20〇°c/秒之二次 冷卻速度冷卻至15〇〜450&lt;^之二次冷卻停止溫度後,在150 〜500°C溫度範園保持15粆〜20分鐘再予以冷卻至室溫, 且其更具邋之退火後冷卻條件為於0丄&gt;&lt; (Ac3 - Ac D + Ac, °C以上Ac3 + 50°C以下溫度退火10秒〜3分鐘後,以1〜l〇 eC/秒之一次冷卻速度冷卻至550〜720°C範团之二次冷卻 開始溫度Tq,並繼之以〜200°C/秒之二次冷卻速度冷 卻至由鋼材成份及退火温度To所決定之溫度Tem — lOOt 以上Tem以下之二次冷卻终了溫度!^後,於Te-50°C以上 500°C以下溫度Toa保持15秒〜20分鐘再予冷卻至室溫為特 徵,而其最後所獲冷軋鋼板之微視組織乃含有肥粒鐵及/ 或變韌鐵,是一種以其中任一為主相與含有體積分率3〜5〇 %殘留沃斯田鐵之第3相複合之組織’且其經等效畸變〇% 以上10%以下予先變形後再於5X 1〇2〜5X103 (Ι/s)之畸 變速度範团變形時之3〜10%等效畸變範圍之.變形應力 平均值σ dyn(MPa)、可滿足其施加予先變形前在5X 1〇'4 〜5父10〇(1/3)畸變速度範圍測得之靜態拉力試驗之最大 應力TS(MPa)所表示算式(Tdyn20.766XTS + 250、及其碑 變1〜5%之加工硬化指數可滿足0.080以上具有高動態變 形抵抗之高強度冷軋鋼板製造方法。 圈示之簡單說明 第1圈為本發明衝撞時沖擊能量吸收能指標之在5X 102〜5 X l〇3(i/s)畸變速度範圍變形時之3〜10%等效畸 變範圍之變形應力平均值(jdyn-TS與TS之關係表示圖; 本紙張尺度逋用中國國家棣準(CNS ) A4规格(210X297公釐) (請先閱讀背面之注f項再填寫本3f) •裝· 訂 A7 B7 經濟部中央揉準局貝工消费合作社印裝 五、發明説明( 第2圖為鋼板之畸變1〜5%加工硬化指數與動態能量 吸收量(J)之關係表示圖; 第3圈為鋼板之降伏強度X畸變1〜5%加工硬化指數 與動態能量吸收量(J)之關係表示圖; 第4a圖為第3圖之動態能量吸收量測定用衝擊壓溃試 驗構件(帽型)之概略圖; 第4b圖為第4aJ0所用試片斷面圖; 第4c圖為衝擊壓溃試驗方法模式圈; 萆5圖為本發明之熱軋工程之△!:與金屬參數A之關係 顯示圖; 第6圈為本發明熱軋工轾之繞取溫度與金屬參數A之 關係顯示圖; 第7圖為本發明之連續退火工程之退火循環棋式顯示 圖; 第8圖為本發明之連續退火工程之二次冷卻停止溫度 (Te)與其後保持溫度(Toa)之關係顯示圖。 汽車等之車架前端邊樑等衝撞時之沖擊吸收用構件、 乃是將鋼板施以彎曲加工及鍛壓成形加工而製成。汽車之 衝撞時之沖擊即是如此加工後經過通常之塗裝焙烤再施加 者。因此就需要經過如此構件之加工·焙烤後尚還有高沖 擊能量吸收能之鋼板。 本發明人等經長年研究可滿足上述要求之沖擊吸收用 構件結果,了解如此成形加工之實際構件如其鋼板含有適 量殘留沃斯田鐵時,更適為具卓越沖擊吸收特性之高強度 本紙張尺度適用中國困家橾準(CNS ) A4規格(210X297公釐) l·---^-----07^.------1T----- (請先閱讀背面之注$項再填寫本頁) 11 經濟部中央揉準局負工消费合作社印装 A7 B7 五、發明説明(8 ) 鋼板。亦即發覺最適宜之微視組織乃是含有由種種置換型 元素容易固溶強化之肥粒鐵及/或變韌鐵,並以其中任一 為主相與含有體積分率3〜50%且在變形中可變態為硬質 麻田散鐵之殘留沃斯田鐵之第3相呈複合組織時具有高動 態變形抵抗。亦判明初期微視組織之第3相如為含有麻田 散鐵之複合組織,且可滿足某特定條件時,可獲得具有高 動態變形抵抗之高強度銅板。 繼之,本發明人等根據上述認知再進行實驗*檢討結 果,又發覺車架前端邊樑等之沖擊吸收用構件其相當於成 形加工之予先變形量,乃隨部位之不同有時會達最高20% 以上,卻以等效畸變0%以上10%以下為大半,因此藉把 握此範圍之予先變形效果,而可推定構件全體經予先變形 後之舉動。是故,本發明乃選擇等效畸變0%以上10%以 下之變形作為構件加工時所賦予之予先變形量。 第1圖為本發明衝擊時沖擊能董吸收能指標之在5Χ 102〜5Χ 103(l/s)畸變速度範園變形時之3〜10%等效畸 變範圍之變形應力平均值σ dyn舆靜態原材料強度(TS) { 此為在5X10·4〜5X10_3(1/s)畸變速度範圍所測得之靜態 拉力試驗之最大應力TS(MPa)}之關係顯示者。 車架前端邊樑之沖擊吸收用構件乃具有帽型斷面形狀 ,經本發明人等解析該等構件經高速衝撞歷溃時之變形結 果,發覺雖進行至最大40%以上之高畸變變形,但全部吸 收能量之70%以上係於高速應力一畸變線圖之10%以下被 吸收。因此即採用10%以下高速變形時之動態變形抵抗作 本紙張尺度適用中國國家梂準(CNS) A4—規格(2丨0X297公釐) -- (請先閾讀背面之注意事項再填寫本頁)* tT i / w -6-A7 __ ._B7_ V. Description of the invention (3) The value adyn (MPa) can meet the distortion speed of 5X10 · 4 ~ 5X 10.3 · (1 / s) before applying the pre-deformation. The maximum stress TS (MPa) in the static tensile test measured by the standard surface is expressed by the formula adyn20.766XTS + 250, and its work hardening index of distortion of 1 to 5% can meet the high strength steel plate with high dynamic deformation resistance above 0.080. Also, (2) The above-mentioned (1) work hardening index with a drop strength X distortion of 1 to 5% can more satisfy a high-strength steel plate with a high dynamic deformation resistance of more than 40. Also, (3) The microscopic structure of the finally obtained steel sheet contains ferrous iron and / or toughened iron, which is a kind of steel containing any one of the main phases and containing 3 to 50% of the residual Vostian iron. The 3rd phase compound structure, and its equivalent distortion is 0% to 10%, and then it is deformed first and then deformed at 5X102 ~ 5X 103 (Ι / s). The average value of deformation stress in the scope of the Ministry of Economic Affairs, Central Bureau of Standards, W? Industrial Consumption Cooperation, Du Yinxian (please read the note on the back, and then fill out this page) -crdyWMPa), which can be satisfied before it is applied to the first deformation. 5x10-3 (1 / s) distortion stress range measured in the state of maximum stress TS (MPa) expressed by the formula σ dyn 2 0.766 X TS + 250, and the above residual Vostian iron t solid solution [C] The average Mn of steel is equal to the value determined by {Mn eq = Mn + (Ni + Cr + Cu + Mo) / 2} (M) M = 678 —428 X [C] —33 Mn eq is 70 or more and 250 or less. It can also satisfy the difference between the residual Vostian iron scoring ratio before the pre-deformation and the residual Vostian iron volume fraction after the equivalent distortion of 5% after the pre-deformation is the residual Tian Tiehuan's integral rate is above 3%, and the work hardening index of distortion of 1 ~ 5% is above 0.080, and the above-mentioned residues. The average crystal grain size of Resota Tin is 5 or less, and the average crystals of the above-mentioned residual Vosda Iron The ratio of the particle size to the size of the main paper is applicable to the Chinese National Standard (CNS) M specification (210X297 mm) 7. A7 B7 V. Description of the invention (4) Average grain size of ferrous iron or toughened iron in the phase It is 0.6 or less, and the average particle size of the main phase is 10 # m or less, preferably 6 / zm or less, and the Asta scattered iron «integration rate is 3 to 30%, and the average crystal grain size of the Asada loose iron is 10 / zm or less. It is preferably 5 or less, the integral rate of the ferrite grain iron is 40% or more, and the drop ratio is 85% or less. The value of the tensile strength X total elongation is 20,000 or more. Any of the high strengths with high dynamic deformation resistance. Steel plate. Also, (4) Contains C: 0.03% or more and 0.3% or less by weight, and one or both of Si1 and A1 total 0.5% or more and 3.0% or less, and it contains He 11, 1 ^, (: 1 'as required) One or two of 0,11,1 ^ 〇, totaling 0.5% to 3.5%, and the rest are high-strength steel plates with Fe as the main component, or the high-strength steel plates may further contain 1 ^, 1 'as required. One, two or more of 丨, 3,?, 8, € 3, 1 ^ 1 ^, where one or two or more of Nb, Ti, and V total 0.3% or less, P is 0.3% or less, and B is 0.01% Below, Ca is 0.0005% or more and 0.01% or less, REM: 0.005% or more and 0.05% or less, and the rest are Fe-based high-strength steel plates with high dynamic deformation resistance. (Please read the note $ on the back side before filling this page) (5) The manufacturing method of the high-strength hot-rolled steel sheet with high dynamic deformation resistance according to the present invention is a continuous method having the composition shown in (4) above. Flat steel blanks are cast and sent directly to the hot-rolling project as they are, or hot-rolled after cooling and heating, that is, Ar3 — 50aC ~ Ar3 + 120 ° C plus The hot rolling is completed at a temperature, and the hot rolling is followed by an average cooling rate of 5 t / sec or more in the cooling process. &Quot; ------v After cooling, the hot rolled steel sheet is wound at a temperature of 500 t or less. The microscopic structure of hot-rolled steel sheet contains ferrous iron and / or toughened iron. It is a kind of main phase and contains 3 ~ 50% residual Voss by volume fraction. This paper applies Chinese national standards (CNS). A4 specification (210X297 mm) Printed by the Central Ministry of Economic Affairs of the Central Bureau of Work, Consumer Cooperatives A7 B7 V. Description of the invention (5) Tiantie's third-phase composite organization, and its equivalent distortion is 0% to 10% The average deformation stress σ dyn (1 ^? 3) of 3 to 10% of the equivalent distortion range when deforming at the deformation speed range of 5X102 ~ 5X103 (l / s) after the first deformation can satisfy the pre-deformation The expression adyn2 0.766XTS + 250 expressed in the maximum tensile stress TS (MPa) of the static tensile test measured in the range of distortion speed range of 5 fathers 10-4 to 5 fathers 10-3 (1/3), and its distortion 1 ~ A work hardening index of 5% can meet the manufacturing method of high-strength hot-rolled steel plates with high dynamic deformation resistance above 0.080. Also, ( 6) When the hot rolling processing temperature of (5) above is Ar3-50 ° C ~ Ar3 + 120 ° C, the metal parameters are carried out: A can meet the following hot rolling formulas (1) and (2) And the average cooling rate of the outflow table is set to 5 ° C / sec or more, and the above-mentioned metal parameter: the relationship between A and the winding temperature (CT) can satisfy the condition of formula (3), and the winding has high dynamics Method for manufacturing high-strength hot-rolled steel sheet with resistance to deformation "9 ^ 1ogA ^ 18 (1) △ T221XlogA- 178 (2) CTS6XlogA + 312 ........ (3) (7) Furthermore, the invention has high A method for manufacturing a high-strength cold-rolled steel sheet resistant to dynamic deformation is to continuously cast a flat steel blank having the composition shown in the above (4), and directly send it to the hot-rolling project as it is, or after hot-rolling after cooling and heating, and The hot-rolled steel sheet coiled after hot rolling is subjected to pickling and cold rolling. When the final product is annealed by continuous annealing process, the temperature is below IX (Ac3 —Ac 丨) + Ac / C above Ac3 + 50 ° C After annealing for 10 seconds to 3 minutes, it is cooled to 550 ~ 700 ° C at a cooling rate of 1 ~ 10 ° C / s. The paper size is applicable to Chinese National Standard (CNS) A4. Specifications (210X297 mm) L -------- ci ------ tr ----- Q (Please read the note f on the back before filling in this page) -9-Central Ministry of Economic Affairs橾 Associate Bureau w; Industrial and Consumer Cooperatives Printed Oxygen A7 B7 V. Invention Description (6) The primary cooling stop temperature 'Yan' is followed by a secondary cooling rate of 10 ~ 20 ° C / sec to cool to 15 ~ 450 &lt; After the secondary cooling stop temperature, the fan garden was kept at a temperature of 150 to 500 ° C for 15 to 20 minutes and then cooled to room temperature, and the cooling condition after annealing was 0 ° &gt; &lt; ( Ac3-Ac D + Ac, above ° C, above Ac3 + below 50 ° C, annealing for 10 seconds to 3 minutes, and then cooling to a secondary cooling rate of 550 ~ 720 ° C at a cooling rate of 1 ~ 10eC / sec. Start temperature Tq, and then cool at a secondary cooling rate of ~ 200 ° C / s to a temperature Tem determined by the steel composition and annealing temperature To — the secondary cooling end temperature above 100t and below Tem! ^ After that, Toa is maintained at a temperature above Te-50 ° C and below 500 ° C for 15 seconds to 20 minutes and then cooled to room temperature. The microscopic structure of the cold-rolled steel plate finally obtained contains ferrous iron and / Or toughened iron is a structure in which any one of the main phases is combined with the third phase containing 3 ~ 50% residual Vostian iron, and its equivalent distortion is 0% to 10%. Deformed first and then within 3 to 10% of the equivalent distortion range when deformed at a distortion speed range of 5X 102 to 5X103 (1 / s). The average deformation stress σ dyn (MPa) can meet the requirements of its application. The formula (Tdyn20.766XTS + 250, and its monumental change 1 ~) expressed in the maximum stress TS (MPa) of the static tensile test measured in the range of distortion speed of 5X 1〇'4 to 5 father 10 (1/3) before deformation. A 5% work hardening index can meet the manufacturing method of high-strength cold-rolled steel plates with high dynamic deformation resistance above 0.080. Brief description of the circle The first circle is 5X 102 ~ 5 X l 〇3 (i / s) distortion speed range deformation of 3 to 10% equivalent distortion range of the average deformation stress (jdyn-TS and TS relationship diagram; This paper uses China National Standard (CNS) A4 size (210X297 mm) (please read Note f on the back before filling in this 3f) • Binding and ordering A7 B7 Printed by the Central Government Bureau of the Ministry of Economic Affairs 5. Description of the invention (Figure 2 shows the relationship between the deformation hardening index of the steel plate 1 ~ 5% and the dynamic energy absorption (J); the third circle shows the yield strength X distortion of the steel plate 1 ~ 5% work hardening index A diagram showing the relationship with the dynamic energy absorption (J); Figure 4a is a schematic diagram of the impact crush test member (cap type) for measuring the dynamic energy absorption in Figure 3; Figure 4b is a test piece surface used in Section 4aJ0 Fig. 4c is a model circle of the impact crush test method; 为本 5 is the △! Of the hot rolling process of the present invention: the relationship between the metal parameter A and the circle; The relationship between the temperature and the metal parameter A is displayed. Figure 7 is a graph showing the annealing cycle of the continuous annealing process of the present invention. Figure 8 is the secondary cooling stop temperature (Te) of the continuous annealing process of the present invention and maintained thereafter. Relationship between temperature (Toa). The impact absorbing member at the front end of the frame, such as the impact absorbing member, is made by bending and forging the steel plate. The impact during the collision of the car is such that it is processed and baked before being applied. Therefore, steel plates with high impact energy absorption are still required after processing and baking of such components. The inventors have studied the results of impact absorbing components that can meet the above requirements for many years, and understand the actual components such as steel plates that are formed and processed. When it contains an appropriate amount of residual Vostian iron, it is more suitable for high strength with excellent impact absorption characteristics. The paper size is applicable to China Standards (CNS) A4 (210X297 mm) l · --- ^ ----- 07 ^ .------ 1T ----- (Please read the note on the back before filling in this page) 11 Printed A7 B7 printed by the Consumers Cooperative of the Central Bureau of the Ministry of Economic Affairs V. Invention Description (8 ) Steel plate. That is, the most suitable micro-vision tissue is found to contain ferrous iron and / or toughened iron that are easily solidified and strengthened by various replacement elements, and any of them is the main phase and contains 3 to 50% by volume. In the deformation, the residual phase 3 of the hard Asada loose iron, Wastfield iron, has a high dynamic deformation resistance when the third phase has a composite structure. It was also determined that the third phase of the early micro-vision structure is a composite structure containing Asada loose iron, and when a certain condition can be satisfied, a high-strength copper plate with high dynamic deformation resistance can be obtained. Then, the inventors conducted experiments and review results based on the above-mentioned cognition, and found that the shock-absorbing member such as the front end side frame of the frame is equivalent to the pre-deformation amount of the forming process, and sometimes it may reach The maximum is more than 20%, but the equivalent distortion is greater than 0% and less than 10%. Therefore, by grasping the effect of pre-deformation in this range, the behavior of the entire member after pre-deformation can be estimated. Therefore, in the present invention, the equivalent distortion of 0% to 10% is selected as the pre-deformation amount given when the component is processed. Figure 1 shows the mean value of the deformation stress of the shock energy absorbed energy index of the present invention at the time of 5 × 102 ~ 5 × 103 (l / s) distortion rate. The equivalent deformation stress range of the 3 ~ 10% equivalent distortion range during deformation is dyn Raw material strength (TS) {This is the relationship between the maximum stress TS (MPa) in the static tensile test measured in the range of 5X10 · 4 ~ 5X10_3 (1 / s) distortion speed. The shock absorbing member of the front end side frame of the frame has a hat-shaped cross-sectional shape. According to the analysis by the inventors, the deformation results of these members when they are crushed by high-speed impact are found to have reached a maximum distortion of 40% or more, but More than 70% of the total absorbed energy is absorbed by less than 10% of the high-speed stress-distortion diagram. Therefore, the dynamic deformation resistance during high-speed deformation below 10% is used as the paper size. This paper is applicable to China National Standards (CNS) A4—Specifications (2 丨 0X297 mm)-(Please read the precautions on the back before filling this page. )

,1T -12 - A 7 __;_B7_ 五、發明説明(9) 為高速衝撞能董之吸收能指標。特別是,由於變量以3 〜10%範圍最為重要,故乃以在高速拉力變形5X102〜5 X103 (Ι/s)畸變速度範圍變形時之等效畸變3〜10%範 圍之平均應力¢7dyn作為沖擊能量吸收能之指標》 經濟部中央揉準局貝工消费合作社印装 (請先聞讀背面之注f項再填寫本頁) 該高速變形時之3〜10%之平均應力adyn通常係隨 著予先變形及焙烤處理前之鋼材靜態拉力強度{5X10·4 〜5Xl(T3(l/s)畸變速度範圍所測定靜態拉力試驗之最大 應力:TS(MPa)}之上升而增大》因此增大鋼材之靜態拉 力強度(舆靜態原材料強度同意義)即能直接促進構件提f 沖擊能量吸收能。然,鋼材強度愈提升構件成形性愈劣化 ,致較難獲得所需構件形狀。是故#具同一拉力強度(TS) 8^乂具高crdyn之鋼材較為適宜。由於此種關係,鋼材經0 %以上10%以下予先變形後再於5X102〜5X103(1/s)畸 變填度範圍變形時之3〜10%等效畸變範圍之變形應力平 均值ordyn,如能滿足未施加予先變形前在5X 10·4〜5X 10_3(l/s)畸變速度範園測得之靜態拉力試驗之最大應力 TS (MPa)所表示算式 〇rdyn-TS2-0.234xTS + 250時,其 當作實際構件之沖擊能量吸收能乃較其他鋼材為高,並不 必增加構件總重量即能提升沖擊能量吸收能,而可提供為 具有高動態變形抵抗之高強度鋼板。又,上述關係式cr dyn —丁8 2-0.234父丁8 + 250與(7 4丫112 0.766父丁8 + 250為等償 、以下即採用£7dyn20.766XTS + 250之算式進行說明。 其次,本發明人等亦發覺為提升耐衝撞安全性,可藉 提高以畸變1〜5%加工硬化指數所示予先加工時之加工硬 本紙張尺度適用中·國國家榡準(CNS ) A4规格(210X297公釐) -13 - A7 B7 經濟部中夬揉丰局貝工消费合作社印簟 五、發明説明(10) 化’以增強衝撞開始時之初期變形抵抗,同時有必要藉f 今變形時變態之麻田散鐵存在提高衝撞變形中之加工破北 及提高(Tdyn。即如上述將鋼材之微視組織予以控制,則 如第2圈及第3圈所示,可藉使銅之加工硬化指數為0.080以 上最好0.108以上,及使其降伏強度X畸變之加工硬 化指色為40以上最好54以上,而提升上述耐衝撞安全性》 以汽車用構件之耐衝撞安全性指棵之動態能量吸收量及鋼 板加工璜化指數舆降伏強度X加工硬化指數之關係加以觀 察’可知這些數值如增大可提升動態能量吸收量,故對於 汽車用構件之耐衝撞安全性指標而言,如降伏強度相同水 辛時以加工硬化指數,如降伏強度相異則ρ銅板降伏強摩 X加工硬化指數,分別予以評價還算妥當β 動態能量吸收量乃藉第4a圈、第4b圈及第c圖所示衝 擊壓溃試驗法如下述求出。即,將鋼板成&amp;為如第4b圖所 示試片形狀(角fSR= 5mm)後,以尖端徑5.5mm電極使用 可產生塵埃雹流〇.9倍之電流予以35mm間隔之點焊3,形 成為如第4a圖所示兩天花板1之問配設一試片2之構件(帽 形模型)、且進行170°C X20分鐘之焙烤塗裝後,再如第4c 圖所示將約15〇Kg落錘4自10m高予以落下,將置於設有減 震器6之座台5上面之構件由其較長方向加以壓溃,並自其 當時之荷載位移線圈上之面積算出變位=0〜150mm之變 形工作量作為動態能量吸收量。 鋼板之畸變1〜5%之加工硬化指數,降伏強度X畸變 1〜5%之加工硬化指數則由下述加以求出。即,將鋼板加 ( CNS ) Α4Λ#- ( 210X297^ ) IJ---?----------1T------ο (請先閾讀背面之注$項再填寫本頁) 14 -, 1T -12-A 7 __; _ B7_ V. Description of the invention (9) It is the energy absorption index of high-speed impact energy. In particular, since the variable is most important in the range of 3 to 10%, the average stress in the range of equivalent distortion of 3 to 10% when deforming in the high speed tensile deformation range of 5X102 to 5 X103 (Ι / s) distortion speed is taken as 7dyn. Indicators of energy absorption of impact energy》 Printed by the Central Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives (please read the note f on the back, and then fill out this page). The average stress of 3 to 10% during high-speed deformation, adyn, usually follows The static tensile strength of the steel before the pre-deformation and baking treatment {5X10 · 4 ~ 5Xl (T3 (l / s) distortion speed range measured in the maximum tensile static stress test: TS (MPa)} increases and increases "therefore Increasing the static tensile strength of the steel (the static raw material strength has the same meaning) can directly promote the component to increase the impact energy absorption energy. However, the higher the strength of the steel, the more the moldability of the component is deteriorated, making it more difficult to obtain the required component shape. #Steel with the same tensile strength (TS) 8 ^ 乂 High crdyn is more suitable. Due to this relationship, the steel is deformed after 0% to 10% and then deformed in the range of 5X102 ~ 5X103 (1 / s). 3 ~ 10% of equivalent distortion range during deformation The average deformation stress ordyn, if it can meet the maximum stress TS (MPa) expressed in the static tensile test measured at 5X 10 · 4 ~ 5X 10_3 (l / s) distortion speed before the prior deformation is applied. -TS2-0.234xTS + 250, the impact energy absorption energy of actual components is higher than other steels, and it is not necessary to increase the total weight of the component to increase the impact energy absorption energy, but it can be provided with high dynamic deformation resistance High-strength steel plate. Also, the above-mentioned relation cr dyn — Ding 8 2-0.234 Father Ding 8 + 250 and (7 4 Ya 112 0.766 Father Ding 8 + 250 are equal compensation, the following is calculated using the formula of £ 7dyn20.766XTS + 250 Note: Secondly, the inventors also found that in order to improve the safety of impact resistance, it is possible to increase the processing hard paper size when the pre-processing is indicated by the distortion 1 to 5% work hardening index. ) A4 size (210X297mm) -13-A7 B7 Printed by the Ministry of Economic Affairs, China Food and Beverage Bureau, Shellfisher Consumer Cooperative, Co., Ltd. 5. Description of the invention (10) To increase the initial deformation resistance at the beginning of the collision, it is necessary to borrow f The existence of metamorphic Asada scattered iron in the present deformation North breakage and improvement in high impact deformation (Tdyn. That is, as described above, the microscopic structure of the steel is controlled, as shown in the second and third laps, it is best to use copper's work hardening index of 0.080 or more 0.108 or more, and the work hardening finger color that reduces its drop strength X distortion is 40 or more, preferably 54 or more, and improve the impact safety mentioned above. "The impact safety of automotive components refers to the dynamic energy absorption and steel plate processing." Observe the relationship between the chemical index and the yield strength X work hardening index. It can be seen that if these values are increased, the dynamic energy absorption can be increased. Therefore, for the crash safety index of automotive components, if the yield strength is the same, Work hardening index, if the drop strength is different, ρ copper plate drop strength X work hardening index, respectively evaluated and considered to be appropriate β dynamic energy absorption is based on the impact crush test shown in Figures 4a, 4b and c It was obtained as follows. That is, after forming the steel plate into a test piece shape (angle fSR = 5 mm) as shown in Fig. 4b, spot welding with a current of 0.9 times the dust hail current with an electrode having a tip diameter of 5.5 mm was performed at 35 mm intervals. 3 After forming a component (hat-shaped model) with a test piece 2 on the two ceilings 1 as shown in Fig. 4a, and baking and coating at 170 ° C for 20 minutes, then approximately as shown in Fig. 4c The 15Kg drop weight 4 was dropped from a height of 10m, and the component placed on the seat 5 with the shock absorber 6 was crushed in the longer direction, and the change in area from the load displacement coil at that time was calculated. The deformation workload of bit = 0 ~ 150mm is taken as the dynamic energy absorption. The work hardening index of the distortion of the steel plate is 1 to 5%, and the work hardening index of the yield strength X distortion of 1 to 5% is obtained from the following. That is, add the steel plate (CNS) Α4Λ #-(210X297 ^) IJ ---? ---------- 1T ------ ο (please read the note $ on the back before filling (This page) 14-

五、發明説明(u) 工為JIS-5號試片(標點距離50mra,平行部幅度25mm)、復 以畸變速度0_001/S進行拉力試驗,而求出降伏強度及加 工硬化指數(畸變1〜5%之n值)。 以下即就本發明鋼材之微視组織加以說明。 鋼鐵如有適置之殘留沃斯田鐵存在,由於變形時(成 形時)受到料致會變態呈異常,故具有 提升加工硬化指數及抑制頸缩以提升成形性之作用。上述 適量之殘留沃斯田鐵則以3%〜50%為宜。即,殘留沃斯 田鐵之髖積分率如未滿3%,則成形後樽件受到衝撞變形 時無法發揮其車越加工硬化性能,呈變形荷載止於低水準 而變形工作量趨小,及動態能量吸收董較低,以致無法獲 得較高之拉力強度X總延長率。另,如殘留沃斯田鐵之體 積分率超過50%,則稍有成形加工畸變就會產生連鏑性加 工惹起之麻田散鐵變態,無法期盼拉力強度X總延長率之 提升,反而由於沖切時之顯著硬化致擴徑比劣化,且就算 可勉強進行構件成形但在成形構件遭受磋·撞變形時亦無法 發揮卓越加工硬性能,故應由此觀點來決定上述殘留沃斯 田鐵之量。 又’除上述殘留沃斯田鐵之«積分率3%〜50%為條 件之外’該殘留沃斯田鐵之平均結晶粒徑為以下最 好為3以m以下亦是較佳條件之_。因為,假如殘留沃斯 田鐵之鳆積分率雖為3〜50%,但其平均結晶粒徑如超過5 ,則麵中殘留沃斯田鐵無法分散細緻,致該殘留沃斯 田鐵所具特性之向上作用僅止於局部而不適妥。且亦碎明 本纸張纽逋用CNS…狀(2丨公釐) -一 (讀先聞讀背面之注意事項再填寫本頁) 訂 6 經濟部中央揉率扃員工消费合作社印製 -15 - 經濟部中央揉率局貝工消费合作杜印簟 A7 _ B7_;_ 五、發明説明(12) ,上述殘留沃斯田鐵之平均結晶粒徑舆主相肥粒鐵或變勒 鐵之平均粒徑比為〇·6以]7,並主相之平均結晶粒徑為1〇 以下声好為6#ιη以下之微視組織時,最能顯出其卓越 耐衝撞安全性及成形性。 本發明人等更發覺於同一水準之拉力強度(TS : MPa) 下,上述等效畸變3〜10%範圍之平均應力adyn乃根據構件 加工前鐵板所含殘留沃斯田鐵中之固溶碳量{以〔C〕表 示,(重量%)}舆鋼材之平均Μη等量(Mn eq)Mn eq=Mn + (Ni+Cr+Cu + Mo)/2而變化。該殘留沃斯田鐵中之碳濃 度可由X線解析及移斯堡爾分光試驗加以求出,例如可藉 使用Mo之Κα線之X線解析,利用肥粒鐵之(200)面,(211) 面及沃斯田鐵之(200)面、(220)面、(311)面之積分反射強 度,以 Journal of The Iron and Steel Institute,206 (1968), p60所示方法加以算出。在本#明人等所進行實驗結果亦 同時發覺,如是所獲得殘留沃斯田鐵中固溶碳量〔C〕舆 自添加於鋼材之置換型合金元素所得Mn eq加以計算之值 Μ 為 M= 678-428 X〔C〕一33XMn eq 為 70 以上 250 以下 ,且施加予先變形前之殘留沃斯田鐵髖積分率(V0)舆以等 效畸變5%施加予先變形後之殘留沃斯田鐵體積分率(V5) 之差:{(V())-(VS)}為施加予先變形前之殘留沃斯田鐵艘 積分率之30%以上時,錐屬同一靜態拉力強度但更能顯示 較大adyn。此時,如Μ&gt; 250,實質上由於變形中之殘留 沃斯田鐵變態所造成強度提升效果僅止於甚低畸變範園, 致在構件予先變形時浪费掉幾乎全部殘留沃斯田鐵,而對 本紙張尺度逍用中國國家標準(CNS ) Α4规格(210X297公釐) L——.----oi------1T---------Q (婧先聞讀背面之注$項再填寫本頁〕 A7 _ ._ B7 _ 五、發明説明(13) 於提升高速變形時之crdyn無法有所功效,故即以25〇為&amp; 之上限。又,Μ如未滿70時,雖在變形途中殘留沃斯田鐵 變態還繼續進行,但在低畸變範圍未能產生充分進行變態 ’至等效畸變3〜10%範園之平均應力adyn仍舊保持於麵 低程度,而靜態拉力強度TS無法滿足(7dyn20.766xTS + 250之關係,故將μ之下限定於70。 又,關於殘留沃斯田鐵之存耷位置,由於軟質靶教鐵 在變形時為主要畸變接受對象,致不鄒接於肥粒鐵之殘留 Τ(沃斯田鐵)較難受到βή·變’其結果在1〜5%程度之變形 乃難變態為麻田散鐵致減弱其效果,故宜使殘留沃斯田鐵 都接於肥粒鐵較妥。因此肥粒鐵之饉積分率應為40%以上 最好為60%以上。且其平均結晶粒徑(平‘均等量圓直徑)為 ΙΟ/zm以下最好為以下較宜。如上述肥粒鐵在紐織構 成t為最軟質之組織,乃是決定降伏強度X畸變1〜5%之 加工硬化指數及降伏比之重要因素,所以值量控制於上述 «積分率規定值内較宜。且,藉肥粒鐵之饉積分率増加及 細粒化,可使未變態沃斯田鐵之碳渡度增加並細緻分散化 ,俾有效作用於未變態沃斯田鐵所生成麻田散鐵及殘餘組 織細緻化舆殘留沃斯田鐵之占空因素增加.細緻化,故有 助於耐衝撞安全性及成形性之提升。 其次,麻田散鐵宜為體積分率3%〜30%且其平均結 . ..... 辱粒徑(平均等量圓直徑)為10 以下最好為6#m以下。 該麻田散鐵主要係藉周圍肥粒鐵之產生可動位錯以貢獻·降 伏比之減低及提升加工硬化指數,並藉其滿足上述規範值 本纸張尺度適用中國國家揉準(CT^ ) A4规格(210X 297公釐) I卜---V----0^! f許先网讀背面之注far再填寫本頁) -訂* 經濟部中央棣準局貝工消费合作社印釁 17 A7 B7 修正 五、發明説明(14) (請先W讀背面之注$項再填寫本頁) 可使耐衝撞安全性及成形性更加提升,而達成更佳特性水 準之降伏強度X畸變1〜5%之加工硬化指數2 54及降伏比 S 85%。該麻田散鐵之體積分率與平均結晶粒徑之關係乃 是體積分率過少平均結晶粒徑過大均會促使其作用僅止於 局部影響,致無法達成上述特性。又,關於上述麻田散鐵 之存在位置,如該麻田散鐵不鄰接於肥粒鐵時,由麻田散 鐵之可動位錯不易及於肥粒鐵致效果較薄》故宜使麻田散 鐵鄹接於肥粒鐵較佳》 經濟部智慧財產局貝工消費合作社印製 茲即就上述微視組織及造成種種特性之高強度鋼板之 化學成份舆其含量規範值加以說明。本發明所使用高強度 鋼板,以重量%計乃含有〇:0.03%〜0.3%、8丨與八1之一 方或雙方合計0.5%〜3.0%、及依需Mn、Ni、Cr、Cu、Mo 之一種或兩種以上合計0.5%〜3.5%以下、且殘餘以Fe為 主成份。或該高強度鋼板依需更含有Nb、Ti、V、P、B、 Ca及REM之一種或兩種以上,即Nb、Ti'V之一種或兩種 以上合計0.3%以下、P 0.3%以下、B 0.01%以下、Ca 0.0005 %以上0.01%以下、REM 0.005以上0.05%以下,且殘餘 以Fe為主成份之具有高動態變形抵抗之高強度鋼板。以下 即詳述該等化學成份及其含量(均為重量%)。 C: C為在室溫安定沃斯田鐵殘留所需之對於沃斯田 鐵安定化最具貢獻之廉償元素,故可謂本發明最為重要之 元素。鋼材之平均C量不僅影響室溫所能確保之殘留沃斯 田鐵饉積分率外,且可藉在製造加工處理過程將之濃化於 未變態沃斯田鐵之,而提升殘留沃斯田鐵加工時之安定性 18 本紙張尺度逍用中國國家梂準(CNS ) A4规格(210X297公釐) 經濟部中央橾率局貝工消费合作社印製 A7 B7 五、發明説明(15) 。但,其添加董未滿0.03%時,终究無法將殘留沃斯田鐵 確保於3%以上,故乃以0.03%為其下限》另,隨鋼材平 均C量之增加可確保殘留沃斯田鐵醴積分率之增加,並可 一邊確保沃斯田鐵髏積分率一邊確保殘留沃斯田鐵之安定 性。唯如鋼材之C添加量過高時,將使鋼材強度提升所需 程度以上,致不只阻礙鍛壓加工等之成形性,比及靜態強 度之上升更加阻礙動態應力之上升,同時亦因溶接性之劣 化而限制鋼材之運用於構件,故即以0.3%為上限》V. Description of the invention (u) The test piece is JIS-5 (punctuation distance 50mra, parallel width 25mm), and the tensile test is performed at a distortion speed of 0_001 / S, and the yield strength and work hardening index (distortion 1 ~ 5% of n). The microstructure of the steel of the present invention will be described below. If there is an appropriate residual Vostian iron in the steel, the deformation will be abnormal when it is deformed (formed), so it can improve the work hardening index and inhibit necking to improve formability. The above-mentioned appropriate amount of residual Vostian iron is preferably 3% to 50%. That is, if the hip integral rate of the residual Vostian iron is less than 3%, the post-forming bottle parts cannot exhibit their work-hardening performance when they are subjected to impact deformation. The deformation load is stopped at a low level and the deformation workload is reduced, and The dynamic energy absorption is lower so that a higher tensile strength X total elongation cannot be obtained. In addition, if the volume fraction of the residual Vostian iron exceeds 50%, a slight deformation of the forming process will cause the abnormal deformation of the Asada iron caused by flail processing, and it is impossible to expect an increase in the tensile strength X total elongation rate. Significantly hardening during punching causes deterioration of the diameter expansion ratio, and even if the forming of the component can be performed barely, the excellent processing hard performance cannot be exerted when the formed component is subjected to colliding and colliding deformation. Therefore, the above-mentioned residual Vostian iron should be determined from this viewpoint. The amount. Also 'except for the above condition of «integration rate of 3% to 50% of the residual Vostian iron', the average crystal grain size of the residual Vostian iron is preferably the following, preferably 3 to m, which is also a better condition_ . Because, if the residual Vosstian iron's integral rate is 3 ~ 50%, but if its average crystal grain size exceeds 5, the residual Vosstian iron in the surface cannot be dispersed and fine, resulting in The upward action of the characteristic is only local and not appropriate. Also use this paper as a CNS ... (2 丨 mm)-one (read the notes on the back and then fill out this page) Order 6 Printed by the Central Ministry of Economic Affairs 印 Printed by the employee consumer cooperatives -15 -Shellfish consumer cooperation of the Central Rubbing Bureau of the Ministry of Economic Affairs, Du Yinyu A7 _ B7 _; _ 5. Description of the invention (12), the average crystal grain size of the above-mentioned residual Vostian iron is the average of the main phase fertilized iron or altered iron When the particle size ratio is 0.6 to 7 and the average crystal grain size of the main phase is 10 or less, and the microscopic structure is 6 # or less, it has the best impact safety and formability. The inventors have found that at the same level of tensile strength (TS: MPa), the average stress adyn in the above equivalent distortion range of 3 to 10% is based on the amount of solid dissolved carbon in the residual Vostian iron contained in the iron plate before the component is processed. {Expressed as [C] (weight%)} The average Mη of the steel material is changed by the same amount (Mn eq) Mn eq = Mn + (Ni + Cr + Cu + Mo) / 2. The carbon concentration in the residual Vosstian iron can be obtained by X-ray analysis and shifting spectroscopy. For example, by using X-ray analysis using κα line of Mo, using the (200) plane and (211) plane of the ferrous grain iron. The integrated reflection intensity of the (200) plane, (220) plane, and (311) plane of Vostian Iron was calculated by the method shown in the Journal of The Iron and Steel Institute, 206 (1968), p60. The experimental results conducted in this #mingren et al. Also found that if it is the solid solution carbon content [C] in the obtained residual Vostian iron, the value calculated from the Mn eq obtained from the replacement alloy element added to the steel M is M = 678 -428 X [C] -33XMn eq is 70 or more and 250 or less, and the residual Vostian iron hip integral rate (V0) before the first deformation is applied to the residual Vostian after the first deformation at an equivalent distortion of 5%. Difference in iron volume fraction (V5): {(V ())-(VS)} is more than 30% of the integral rate of the residual Vostian iron ship before the previous deformation, the cones have the same static tensile strength but more Can display larger adyn. At this time, such as M &gt; 250, the strength improvement effect caused by the deformation of the residual Vosstian iron in deformation is limited to the very low distortion range, so that almost all of the residual Vosstian iron is wasted when the component is deformed in advance. For the standard of this paper, the Chinese National Standard (CNS) Α4 specification (210X297 mm) L ——.---- oi ------ 1T --------- Q (Jing Xianwen Read the note on the back of the page and fill in this page] A7 _ ._ B7 _ V. Description of the invention (13) The crdyn can not have any effect when the high-speed deformation is improved, so the upper limit of 25 is &amp; If it is less than 70, although the residual Vastian iron metamorphism continues during the deformation process, it does not produce sufficient metamorphosis in the low distortion range 'to the equivalent distortion of 3 to 10% Fanyuan's average stress adyn still remains in the face Low degree, and the static tensile strength TS cannot satisfy the relationship (7dyn20.766xTS + 250), so the lower limit of μ is limited to 70. Also, regarding the location of the residual Vostian iron, the soft target teaches iron when deformed as The main recipient of distortion is that it is difficult to receive β-change after leaving the residual T (Wotian Iron) that is not iron. As a result, the deformation at the level of 1 to 5% is difficult to metamorphose, and its effect is weakened by loose iron in Asada. Therefore, it is appropriate to connect the residual Vostian iron to the fertile iron. Therefore, the integral rate of ferrite iron should be 40. % Or more is preferably 60% or more. And its average crystal grain size (flat 'equal circle diameter) is preferably 10 / zm or less, preferably the following. As the above-mentioned fertilized iron constitutes the softest structure in the knitting structure, t , Is an important factor that determines the work hardening index and the yield ratio of the yield strength X distortion of 1 to 5%, so it is better to control the value within the above specified value of the integral rate. In addition, the integral rate of the ferrous grain iron is increased and Fine graining can increase the carbon fertility of the unaltered Vosstian iron and finely disperse it. It effectively acts on the Asa loose iron and residual tissue produced by the unorthodox Vostian iron to refine the residual Vosstian iron's share. The air factor is increased. Refined, it is helpful to improve the crash safety and formability. Secondly, it should be 3% ~ 30% by volume and its average knot. The average equal circle diameter) is 10 or less, preferably 6 # m or less. The generation of movable dislocations of granular iron contributes to the reduction of the reduction ratio and the improvement of the work hardening index, and meets the above-mentioned normative values. The paper size is applicable to the Chinese national standard (CT ^) A4 (210X 297 mm) I --- V ---- 0 ^! F Xu first read the note far on the back and then fill out this page)-Order * Printed by the Central Laboratories Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives 17 A7 B7 Amendment V. Description of Invention (14 ) (Please read the note on the back before filling in this page) The impact safety and formability can be improved to achieve a better level of characteristics. Descent strength X distortion 1 ~ 5% work hardening index 2 54 and The step-down ratio S is 85%. The relationship between the volume fraction and average crystal grain size of the Asada loose iron is that too small a volume fraction and too large an average crystal grain size will cause its effect to be limited to local influences, making it impossible to achieve the above characteristics. In addition, regarding the existence of the above-mentioned Asada loose iron, if the Asada loose iron is not adjacent to the fat iron, the movable dislocation of the Asada loose iron is not easy to cause the effect of the thin iron to be thin. It is better to be connected with fertilizer and iron. ”The printed material of the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs is here to explain the chemical composition of the above-mentioned microstructure and high-strength steel plates that have various characteristics and their content specification values. The high-strength steel sheet used in the present invention contains 0: 0.03% to 0.3% by weight, 0.5% to 3.0% of one or both of 8 丨 and 81, and Mn, Ni, Cr, Cu, and Mo as required. One or two or more of them are 0.5% to 3.5% in total, and the residual is mainly composed of Fe. Or the high-strength steel sheet further contains one or two or more of Nb, Ti, V, P, B, Ca, and REM as required, that is, one or two or more of Nb, Ti'V, or 0.3% or less and P 0.3% or less in total , B 0.01% or less, Ca 0.0005% or more and 0.01% or less, REM 0.005 or more and 0.05% or less, and the remaining high strength steel sheet with high dynamic deformation resistance mainly composed of Fe. The following is a detailed description of these chemical components and their contents (both by weight). C: C is the cheapest element that contributes to the stabilization of Vosstian iron at room temperature and is the most important element of the present invention. The average C content of steel not only affects the integral rate of residual Vosstian iron that can be ensured at room temperature, but also can be enhanced by concentrating it in the undistorted Vosstian iron during the manufacturing process. Stability during iron processing 18 This paper size is in accordance with China National Standard (CNS) A4 (210X297 mm). Printed by A7 B7, Shellfish Consumer Cooperative, Central Bureau of the Ministry of Economic Affairs. 5. Description of invention (15). However, when the amount of added Dong is less than 0.03%, the residual Vostian iron cannot be guaranteed to be more than 3%, so 0.03% is the lower limit. In addition, as the average C content of steel increases, the residual Vostian iron can be ensured.之 The increase of the integral rate can ensure the stability of the residual Vostian Iron while ensuring the Vostian Iron Skeleton integral rate. For example, when the C content of steel is too high, it will increase the strength of the steel by more than necessary, which will not only hinder the formability of forging and processing, but also increase the dynamic stress more than the increase in static strength. Deterioration restricts the use of steel for components, so the upper limit is 0.3% "

Si、A1 : Si、A1均為肥粒鐵之安定化元素,具有藉增 加肥粒鐵髏積分率促使銅材之加工性提升之功效。又,Si 、A1均可抑制雪明碳鐵之產生,有效使C濃化於沃斯田鐵 之中,故是為在室溫令適當艎積分率之沃斯田鐵予以殘留 所不可欠之添加元素。此種具可抑制雪明碳鐵產生功效之 添加元素,除Si、Al以外尚可舉?與〇11、Cr、Mo等,如適 量添加該等元素亦可期待相同效果。不過,Si舆A1之一種 或兩種合計未滿0.5%時,雪明碳鐵產生之抑制效果並不 充足,其為沃斯田鐵安定化最具效果所添加之C大都均被 以碳化物形態浪费掉,致無法確保本發明所需殘留沃斯田 鐵體積分率、或因確保殘留沃斯田鐵所須製造條件不適於 大量生產工程條件,故乃以0.5%以下為下限》又,Si與A1 之一種或兩種合計超過3.0%時,將招惹其為母相之肥粒 鐵或變韌鐵硬質化或脆性化,不僅阻礙藉畸變速度上升以 增高變形抵抗,更會引起鋼材加工性下降,韌性下降甚至 提升鋼材成本,且化學處理等之表面處理特性亦顯著劣化 本紙張尺度適用中國國家棣準(CNS ) Α4规格( 210Χ297公釐) !-I-^----------1T——----ο (諳先Η讀背面之注意事項再填寫本頁) 19 經濟部中央揉牟局負工消费合作社印製 A7 B7 五、發明説明(16) ,故以3.0%為上限。而當被要求表面性狀需特別優越時 ,則須考慮使以避免產生Si銹皮,或反之使Sig 1,0%以全面產生si銹皮避免其強眼。Si, A1: Si and A1 are the stabilizing elements of ferrous grain iron, and have the effect of increasing the processing rate of copper by increasing the integral rate of fat grain iron skeleton. In addition, both Si and A1 can suppress the production of Xueming carbon iron, and effectively condense C in Vosstian iron. Therefore, it is an indispensable addition for the retention of Vostian iron with an appropriate rate of integration at room temperature. element. This kind of additive element that can inhibit the production of Xueming carbon iron can be used besides Si and Al? The same effect can be expected with 〇11, Cr, Mo, etc. if these elements are added in an appropriate amount. However, when one or both of Siyu A1 is less than 0.5% in total, the inhibitory effect of Xueming carbon iron is not sufficient, and most of the C added for the stabilization of Vostian Iron are all carbides. The form is wasted, so that the volume fraction of the residual Vosstian iron required by the present invention cannot be ensured, or the manufacturing conditions required to ensure the residual Vosstian iron are not suitable for mass production engineering conditions, so the lower limit is 0.5% or less. When the total of one or both of Si and A1 exceeds 3.0%, it will provoke the fertilized iron or toughened iron that is the parent phase to harden or brittle, which will not only prevent the deformation rate from increasing to increase the deformation resistance, but also cause steel processing. Reduced toughness, reduced toughness, and even increased steel costs, and surface treatment characteristics such as chemical treatment are also significantly degraded. This paper size is applicable to China National Standard (CNS) A4 specification (210 × 297 mm)! -I-^ ------ ---- 1T ——---- ο (谙 Read the precautions on the back before filling out this page) 19 Printed by the Central Ministry of Economic Affairs Bureau Consumers Cooperatives A7 B7 V. Invention Description (16), so The upper limit is 3.0%. When the surface properties are required to be particularly superior, consideration must be given to avoid the generation of Si scale, or vice versa to make Sig 1,0% in order to fully produce the Si scale to avoid its strong eyes.

Mn、Ni、Cr、Cu、Mo : Mn、Ni、Cr、Cu、Mo均為 沃斯田鐵安定化元素’係是在室溫使沃斯田鐵安定化有效 之元素。尤其,因溶接性關係致c之添加量受限制時,藉 .添加適量此類沃斯田鐵安定化元幸而可有效地促進沃斯田 鐵之殘留·又,該等元素雖不及A1舆Si但還具有可抑制雪 明碳鐵產生之效果,益具可助力C濃化於沃斯田鐵之作用 «•且,該等元素可藉固溶強化舆A卜Si共同呈母逋之肥粒 鐵或變軔鐵,而具有提升高速時之動態變形抵抗之作用。 然,該等元素之一種或兩種以上之添加量合計未滿0.5 % 時,則無法確保所需之殘留沃斯田鐵同時,鋼材強度亦即 下降,致不能有效達成車艘輕量化,故以0.5%為下限。 又,此等元素合計超過3.5%時,將招惹其為母相之肥粒 鐵或變軔鐵硬質化,致阻礙藉畸變速度之上升以增加變形 抵抗,並引起鋼材加工性之下降與韌性下降以及鋼材成本 之上升,故以3.5%為其上限。 依需所添加之Nb、Ti、V可藉其形成為破化物、氮化 物或礙氣化合物而使銅材高強度化,但其合計如超過0.3 %時,則其為母相之祀粒鐵或變韌鐵粒子内及粒子界域會 析出多量該等碳化物、氮化物或碳氮化合物,致形成高速 變形時之可動位錯發生源而無法獲得高動態變形抵抗,且 碳化物之產生對於本發明最重要之將C濃化於殘留沃斯田 本纸張尺度適用中國國家橾準(CNS ) A4规格(210X297公釐) 1.-:-------------.ΤΓ------ο (請先《讀背面之注f項再填窝本頁) 20 經濟部中央搮準局貝工消费合作社印笨 A7 B7 五、發明説明(17) 鐵構成阻礙並浪费C,故乃以0.3%為其上限。 又,依據需要亦會添加B或P。其中B雖對於強化粒子 界域及銅材之高強度化有效,但添加量如超過0.01%時’ 其效果會呈飽和同時亦使鋼板強度提升至所需程度以上’ 致阻礙提升高速成形時之變形抵抗並促使構件加工性下降 ,故以0.01%為其上限·又,P對於鋼材之高強度化及確 保殘留沃斯田鐵雖具成效,然如超過0.2%時不只會引起 鋼材成本之上昇,更會使其主相之肥粗鐵、變韌鐵之變形 抵抗提升至所需程度以上,致阻礙高速變形時之變形抵抗 上升及引起耐自然裂開性之劣化舆疲勞特性、韌性之劣化 ,故以0.2%為上限。並以防止二次加工性、軔性、點焊 性及再利用性劣化之觀點而言乃宜定於0.02%以下較妥, 又’其所含不可避免之夾雜物S,則自防止硫化系物之介 存影響成形性(特別是擴孔比)及點焊性之劣化加以考量, 應定於0.01%以下較宜。 且,Ca為可藉硫化物系介存物之形態控制(球狀化)以 提升成形性(特別是擴孔比)而被添加0.0005%以上,但自 效果之俄和及上述介存物之增加引起反面效果(擴孔比劣 化)加以考量,即以0.01%為其上限。又,REM亦具有與Ca 相同效果,故其添加量定於0.005%〜0.05% » 其次,即就為獲得本發明高強度鋼板分別詳述說明熱 軋鋼板及冷軋鋼板之製造方法。 本發明之具高動態變形抵抗之高強度熱軋鋼板及冷軋 鋼板之製造方法,乃將具上述成份組成之連續鑄造扁鋼胚 本纸張尺度適用中國國家梂準(CNS ) A4规格(210X297公釐) ΟΊ------tr------ (請先閱讀背面之注f項再填寫本頁) 21 ,成形性劣化。如超過Ar 大化等致動態變形抵抗σ A7 B7 五、發明説明(18) 以其鑄造原樣直送至熱軋工程,或經冷抑後再加熱進行熱 軋。此種熱軋,除通常之連續鎊造外亦可適用薄片連續鑄 造及熱軋連續化技術(無端軋壓),但如考慮肥粒鐵饉積分 率之下降,薄鋼板微祝組織之平均結晶粒徑之粗大化,其 逸入加工熱軋蟪之鋼板厚(初期麵板羼呈25mm以上較 宜。又,在該熱軋過程之最後徑道熱軋速度亦由於上述問 ——' 題致應進行500mpm以上最好為600mpm以上之熱軋較宜。 尤其,在高強度熱軋銅板之製造時,其上述熱軋加工 溫度宜設定於由鋼材化學成份所決定之Ar3 — 50°C〜Αγ3 + 120°C溫度範团來進行。因為如未滿Ar3-50°C則產生加工 犯粒鐵易使動態變形抵拉^adyn、1〜5兕之加工硬化性能 3+ 12(TC則因錮板微視组織之粗 dyn、1〜5%加工硬化性能等劣 化同時,自銹皮傷痕之觀kfe言之亦不大妥宜。經上述熱軋 所成鋼板即進入繞取工程,且宜以500°C以下繞取溫度予 以繞取較妥。如繞取溫度超過500°C即引起殘留沃斯田鐵 占空因素下降。又,如欲得到麻田散鐵時可將該繞取溫度 定於350°C以下。又上述繞取條件為繞取後以熱軋鋼板供 應時之條件,如更加冷軋·退火再供應使用之冷軋鋼板則 不必受上述條件控制,乃可以通常之製造條件予以繞取無妨。 尤其,在本發明可發覺熱軋工程之加工溫度,加工進 入側溫度及繞取溫度之間具有相連關係。即,如第5圈及 第6圈所示,上述加工溫度,加工進入側溫度及繞取溫度 之間具有一義決定之特定條件。即,在熱軋加工溫度Ar, 本紙張尺度遑用中國國家梯準(CNS ) A4规格(210X297公釐) ------IT--------D (請先K讀背面之注$項再*窝本頁) 經濟部中央橾车局貞工消费合作社印装 22 經濟部中央揉準局貞工消费合作社印製 A7 B7 五、發明説明(19) —50t〜Ar3+ 120°C溫度範圍進行其金屬參數:A可滿足 下述(1)式及(2)式之熱軋,但上述金屬參數:A可如下述 表示之。 A= e*Xexp { (75282-42745 XCeq)/ ( 1.978X(FT + 273)〕} 但、FT :加工溫度(。C)Mn, Ni, Cr, Cu, Mo: Mn, Ni, Cr, Cu, and Mo are all Vostfield iron stabilizers' are elements that stabilize Vastfield iron at room temperature. In particular, when the addition amount of c is limited due to the solubility relationship, the addition of an appropriate amount of this type of Vostian iron can stabilize the residue of Vostian iron, and these elements are not as good as A1 and Si. However, it also has the effect of suppressing the production of Xueming carbon iron, which can help C thicken the role of Vostian Iron «• Moreover, these elements can be strengthened by solid solution A and Si together to form the mother grains. Iron or iron can increase the resistance to dynamic deformation at high speeds. However, when the total amount of one or two of these elements is less than 0.5%, the required residual Vostian iron cannot be ensured. At the same time, the strength of the steel is reduced, which makes it impossible to effectively reduce the weight of the vehicle. The lower limit is 0.5%. In addition, when the total of these elements exceeds 3.5%, it will provoke hardening of the fertile grain iron or dysprosium iron that is the parent phase, which will hinder the increase in deformation resistance by increasing the deformation resistance, and cause the decline in the workability and toughness of the steel As well as the rise in steel costs, 3.5% is the upper limit. The Nb, Ti, and V added as required can increase the strength of the copper material by forming into broken compounds, nitrides, or gas barrier compounds, but if the total exceeds 0.3%, it is the parent iron grain. Or, a large amount of these carbides, nitrides, or carbonitrides will be precipitated in the toughened iron particles and in the particle boundary, resulting in the formation of a source of movable dislocations during high-speed deformation, and high dynamic deformation resistance cannot be obtained. The most important aspect of the present invention is to concentrate C in the residual Vosda paper. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 1 .-: ------------- .ΤΓ ------ ο (please read "Note f on the back side before filling in this page") 20 Central Bureau of Standards, Ministry of Economic Affairs, Shellfish Consumer Cooperative, India Ben A7 B7 V. Description of Invention (17) Iron constitutes obstacles And waste C, so 0.3% is the upper limit. Also, B or P may be added as needed. Among them, B is effective for strengthening the particle boundary and the high strength of the copper material. However, if the amount of B exceeds 0.01%, the effect will be saturated and the strength of the steel plate will be increased above the required level. This will hinder the improvement of high-speed forming. The deformation resistance promotes the reduction of the component workability, so 0.01% is the upper limit. Moreover, although P is effective in increasing the strength of the steel and ensuring the residual Vostian iron, if it exceeds 0.2%, it will not only cause the cost of steel to rise. In addition, it will increase the deformation resistance of the fat iron and toughened iron of the main phase above the required level, which will hinder the increase of deformation resistance during high-speed deformation and cause deterioration of natural crack resistance, fatigue characteristics, and deterioration of toughness. , So the upper limit is 0.2%. From the viewpoint of preventing the deterioration of secondary workability, creep, spot weldability and recyclability, it is appropriate to set it to 0.02% or less. Also, 'the unavoidable inclusion S contained in it, self-preventing vulcanization system The deterioration of the formability (especially the hole expansion ratio) and spot weldability due to the presence of the material should be considered, and it should be set to 0.01% or less. In addition, Ca can be added by 0.0005% or more by improving the formability (especially the hole expansion ratio) by controlling the morphology (spheroidization) of sulfide-based intermediaries. Increase the negative effect (deterioration of the hole expansion ratio) to consider, that is, 0.01% as the upper limit. In addition, REM also has the same effect as Ca, so its addition amount is set to 0.005% to 0.05% »Secondly, in order to obtain the high-strength steel sheet of the present invention, the manufacturing methods of the hot-rolled steel sheet and the cold-rolled steel sheet are described in detail. The manufacturing method of the high-strength hot-rolled steel sheet and cold-rolled steel sheet with high dynamic deformation resistance according to the present invention is to apply the continuous casting flat steel blank with the above composition to the paper size of China National Standard (CNS) A4 (210X297) Mm) 〇Ί ------ tr ------ (Please read the note f on the back before filling in this page) 21, the formability is deteriorated. If it exceeds Ar, the dynamic deformation resistance σ A7 B7 V. Description of the invention (18) Directly send it to the hot rolling project as it is, or heat-rolled after cooling. In addition to the usual continuous pounding, this type of hot rolling can also be applied to continuous thin sheet casting and hot rolling continuous technology (endless rolling). However, if the reduction in the percentage of ferrite grain iron is considered, the average crystallization of the microstructure of the thin steel plate The coarsening of the particle size causes the thickness of the steel sheet to be processed into the hot-rolled slab (the initial panel slab is preferably 25 mm or more. In addition, the hot rolling speed in the final path of the hot-rolling process is also due to the above-mentioned problem-- " Hot rolling should be performed at 500 mpm or more, and preferably at least 600 mpm. Especially in the manufacture of high-strength hot-rolled copper plates, the above-mentioned hot-rolling processing temperature should be set to Ar3-50 ° C ~ Αγ3 determined by the chemical composition of the steel. + 120 ° C temperature range. Because if it is less than Ar3-50 ° C, it will produce machining grain iron, which will cause dynamic deformation and tensile resistance ^ adyn, work hardening performance of 1 ~ 5 兕 3+ 12 (TC is due to 锢At the same time, the coarse dyn of the microstructure of the plate and the work hardening performance of 1 ~ 5% are degraded. At the same time, the kfe from the rust scale is not appropriate. The steel plate formed by the above hot rolling will enter the winding process, and it should be It is better to coil at a temperature below 500 ° C. If the temperature exceeds 500 ° C This will cause the reduction of the duty factor of the residual Vosstian iron. In addition, if you want to obtain Asada loose iron, you can set the winding temperature below 350 ° C. The above winding conditions are when the hot rolled steel plate is supplied after winding. Conditions, such as cold-rolled and annealed cold-rolled steel sheets, are not subject to the above-mentioned conditions, but can be bypassed under normal manufacturing conditions. In particular, in the present invention, the processing temperature of the hot-rolling process can be found, and the processing enters the side. There is a connected relationship between the temperature and the winding temperature. That is, as shown in the 5th and 6th circles, the above-mentioned processing temperature, the temperature on the processing entry side, and the winding temperature have specific conditions that are uniquely determined. That is, in hot rolling Processing temperature Ar, this paper size adopts China National Standard (CNS) A4 specification (210X297 mm) ------ IT -------- D (Please read the note of the $ on the back before reading) * Nest page) Printed by Zhengong Consumer Cooperative of Central Ministry of Economic Affairs 22 Printed by Zhengong Consumer Cooperative of Central Government Bureau of Economic Affairs A7 B7 V. Description of the invention (19) —50t ~ Ar3 + 120 ° C temperature range Metal parameters: A can satisfy the following hot rolling formulas (1) and (2) , But the above metal parameters: A can be expressed as follows: A = e * Xexp {(75282-42745 XCeq) / (1.978X (FT + 273)]} But, FT: processing temperature (.C)

Ceq :碳當量= C + Mneq/6(%)Ceq: carbon equivalent = C + Mneq / 6 (%)

Mneq:鏟當量=Mn+(Ni+Cr+Cu+Mo)/2(%) 最後徑道畸變速度(s·1) £ - (v/^/if xA,)x (l/ Vr)x /n{l/(l—r)} h:最後徑道進入端板厚 h2 :最後徑道出口端板厚 r : (h,-h2)/h1 R:軋輥直徑 v;最後徑道出口側速度 △ T:加工溫度(最後徑道出口端加工溫度)一加 工進入端溫度(第1徑道進入端加工溫度) Αγ3 : 901 - 325C% + 33Si% - 92Mneq 然後,將流出台平均冷卻速度設於5°C/秒以上,並 以上述金屬參數:A與繞取溫度(CT)之關係可滿足(3)式之 條件予以繞取較宜。 9^1ogA^18 (1) AT&gt;2lXlogA- 178 (2) CT^6XlogA+312 ........(3) 本紙張尺度逋用中國國家標準(CNS ) A4规格(210X297公釐) (請先聞讀背面之注$項再填寫本頁) 訂 ο. 23 錄濟部中央揉準Λ負工消费合作社印笨 A7 B7 五、發明说叼(20) 在上述(1)式,如logA未滿9則自殘留r之生成及微視 組織細緻化之觀點言之尚充足,致會促使動態變形抵抵σ dyn、1〜5%之加工硬化性能劣化。又如i〇gA超過18則為 達成之設備需較為過扮魔大》且在(2)式,如無法滿足(2) 式之條件則殘留7呈過份安定,雖可進行變形途中之殘留 r變態’卻在低畸變範圍無法充份進行變態,致會使動態 變形抵抗adyn、1〜5%之加工硬化性能等劣化。又如(2) 式所示,ΔΤ之下限可由減低i〇gA加以緩和。並自設備之 應大化,殘留沃斯田鐵之饉積分率降低及微視組織之粗大 化加工觀之’ ΔΤ之上限宜設於3〇〇°C較妥。且,如繞取溫 度未滿足(3)式關係時,對於確保殘留了量會產生不良影 響❶或雖得到殘留T時該殘留r亦呈過份安定,或在變形 途中仍會進行殘留r變態,卻在低畸變範圍無法充分進行 變態’致會使動態變形抵抗adyn、1〜5%之加工硬化性 .. · « 能劣化。又該繞取溫度之界限乃可藉增大l〇gA予以緩和。 另,初期麻田散鐵之占空因素23%時可使ct各35(TC ,但,以抑制麻田散鐵之過度產生加以考慮,宜使CTg25〇 °C較佳β 其次,本發明之冷軋鋼板乃是將經過熱軋,線取後之 各工程之銅板以滾軋率40%以上交付給冷軋,再將經上述 冷軋之鋼板交給退火。該退火以具有如第7圖所示退火播 環加以進行最為合適,且在此連續退火工程予以退火完成 最後製品時,於0_1X(Ac3-Ac丨)+Ac,°C以上Ac3+50°C以 下溫度To經10秒〜3分鐘退火後,以1〜10°C/秒之一次&gt; 本紙張尺度適用中國國家標準(CNS ) Α4规格(210Χ 297公釐) -*\p 、&quot;\ o·^------tr------ (請先閲讀背面之注意Ϋ項再填窝本霣) 24 經濟部中夬梯準局員工消费合作社印簟 A7 - _B7_五、發明説明(21 ) 卻速度予以冷卻至550〜720°C範圍之一次冷卻停止溫度 Tq,繼之再以10〜200°C/秒之二次冷卻速度予以冷卻至 二次冷卻停止溫度Te後,並在Toa保持15秒〜20分鐘再冷 卻至室溫》該退火溫度如未滿以鋼材化學成份所決定溫度 Ac丨及Ac3溫度(如丸善出版;W. C. Leslie著「銅鐵材料學 」p273)所表示O.lXiAc^-AcO + Ac/C時,由於在退火溫 度所獲沃斯田鐵量太少,致無法於最後鋼板中安定地留住 殘留沃斯田鐵,故以0.1 X(Ac3 — Ac丨)+ Ac/C為下限。又 ,退火溫度如超過Ac3+50°C時亦無法改善任何鋼鐵特性 ,徒會招惹成本上昇,故乃以Ac3 + 5(TC為退火溫度之上 限。在該溫度之退火時間為鋼板溫度之均句化及確保沃斯 田鐵量起見最低需要10秒鐘以上,但如超過3分鐘上述效 果即呈飽和致會形成成本上昇之原因。 上述一次冷卻對於促進自沃斯田鐵變態為肥粒鐵,使 C濃化於未變態灰斯田鐵中,以圖沃斯田鐵之安定化而言 乃屬十分重要。其冷卻速度如未滿It/秒則需龐大生產 線致生產性不良,故以1°C/秒為下限。又如冷卻速度超 過10°C/秒時則無法充份促成祀粒鐵變態,最後鋼板中之 確保殘留沃斯田鐵變成困難,故乃以l〇°C/秒為上限。該 一次冷卻如進行至未滿550°C時,由於冷卻中會產生波來 鐵,致浪费沃斯田鐵之安定化元棄C,最後無法獲得充足 之殘留沃斯田鐵量。又,上述冷卻如僅進行至超過720°C 時則無法充份促進肥粒鐵變態。 繼績進行之二次冷卻之快速冷卻,為避免冷卻中產生 (請先閩靖背面之注意事項再填寫本頁) d 裝. ,tr 本紙張又度適用中國國家揉準(CNS〉A4規格(210X297公釐) -25 - 經濟部中央揉準局貝工消费合作社印裝 A7 B7 ------------ - 五、發明说明(22) 波來鐵變態及碳鐵化合物之析出,其冷卻速度最低亦須保 持於i〇r/秒以上,但如超過2〇〇r/秒則造成設備能力 上之因難。文該二次冷卻之冷卻伴止温度未滿15〇°c時, 冷卻前所殘留之沃斯田鐵幾乎全部變態為麻田散鐵,致最 後無法確保殘留沃斯田鐵β且該冷卻停土沒度如超過450 °C,最後所獲得之動態變形抵抗adyn即行降低。 為使鋼板中所殘留沃斯田鐵在室溫安定,藉將其中一 部份變態為變韌鐵以更加提高沃斯田鐵t碳濃度較宜ό二 次冷卻停止溫度如較低於為變韌鐵變態處理所保持溫度時 則應加熱至該保持溫度。此時之加熱速度如保持於5°c/ 秒〜50°c/秒之範園即不致於使銅板之最後特性劣化。又 ’反之如二次冷卻停止溫度較變韌鐵處理溫度為高時,如 以5°C/秒〜20CTC/秒之冷卻速度予以強制性冷卻至變韌 鐵處理溫度,則就算直接被搬送至予先設定有目標溫度之 加熱帶域,亦不致構成鋼板之最後特性劣化β另,鋼板以 未滿150°C受保持時,或以超過50(TC受保持時,均無法確 保充份量之殘留沃斯田鐵,故乃以15〇t〜500eC為保持溫 度範团。此時,如15(TC〜500t之保持時間未逮15秒鐘, 則因變知鐵變態進行不充份致無法獲得最终所需殘留沃斯 田鐵量,復又如超過20分鐘時,由於在變韌鐵變態後會析 出碳鐵化合物或產生波來鐵變態,致浪费生成殘留沃斯田 鐵所需之C ’而無法獲得所需量殘留沃斯田鐵,故以15秒 〜20分鐘範团定為保持時間。且為促進變韌鐵變態進行所 保持15〇°c〜5〇〇°c,不關是等溫保持,或在該溫度範圍内 本紙張ΛΑ適用中家榡準(CNS )从胁(公兼) •^1-1-1 II— 11^-1 *^1 H— —^1 —Λιν— I I (請先聞讀背面之注f項再填寫本頁) 訂 -Γ·. 26 A7 B7 鍾濟部中夬揲準Λ貞工消费合作社印¾ 五、發明説明(23 ) 有意地予以變化温度,均不致使鋼板之最後特性劣化。 本發明退火後之較佳冷卻條件,係為m〇1x(Ac3_ ACD + Ac/C以上Α(:3 + 50°C以下溫度退火1〇秒〜3分鏤後 ,以1〜10°C/秒之一次冷卻溫度冷卻至55〇〜72〇。〇範圍 之二次冷卻開始温度Tq,繼之以1〇〜2〇〇它/秒之二次冷 卻速度冷卻至藉麵材成份舆退火溫度T〇所決定溫度:Tem 一 100°C以上Tem以下之二次冷卻终了溫度Te,再以Te_5〇 C以上500 C以下溢度Toa予以保持μ秒〜2〇分錄並冷卻至 室溫之方法。此乃將第8圈所示連續退火循環之急冷终了 溢度以成份舆退火溫度To之函數加以表示,並在某界限 值以下予以退火之方法,且將過時效溫度T〇a範園舆上述 急冷终了溫度Te之關係予以規範者β 在此,Tem為急冷開始溫度Tq時所殘留之沃斯田鐵之 麻田散鐵變態開始溫度·即,Tem乃為除去沃斯田鐵中C 濃度所影響之值(T1)舆表示C濃度影響之值(T2)之差:Tem = T1 —T2。在此T1為依據C除外之固溶元素濃度所計算之 溫度,Τ2為由鋼板成份設定之及退火溫度所決 定之Tq時之自殘留沃斯田鐵中c濃度加以計算之溫度。又 ’ Ceq_則為上述退火溫度To時殘留於沃斯田鐵中之碳當量 。因此T1為,T1 = 561 - 33 X { Mn% + (Ni+ Cr+ Cu+ Mo)/2 } ' 又T2乃是, Ac, = 723 - 0.7 X Μη% - 16·9 XNi% + 29.1 X Si% + 16.9XCr%、及 {請先閱讀背面之注意事項再填寫本萸 裝· - α 本紙張纽適用中HU家轉(CNS)从跋(2似297公着) 27 A7政年47曰雙 _Β7 _ 五、發明説明(24 ) (讀先閱讀背面之注f項再填寫本買)Mneq: Shovel equivalent = Mn + (Ni + Cr + Cu + Mo) / 2 (%) Final path distortion speed (s · 1) £-(v / ^ / if xA,) x (l / Vr) x / n {l / (l—r)} h: the thickness of the end plate entering the end plate h2: the thickness of the end plate exiting the end r: (h, -h2) / h1 R: roll diameter v; the exit side velocity of the last passage △ T: Processing temperature (processing temperature at the exit end of the last track) First entry temperature (processing temperature at the entry end of the first track) Αγ3: 901-325C% + 33Si%-92Mneq Then, set the average cooling rate of the outflow table to 5 Above ° C / second, and it is better to coil according to the above-mentioned metal parameter: A and the winding temperature (CT) can satisfy the condition of formula (3). 9 ^ 1ogA ^ 18 (1) AT &gt; 2lXlogA- 178 (2) CT ^ 6XlogA + 312 ........ (3) This paper adopts China National Standard (CNS) A4 specification (210X297 mm) (Please read the note on the back of the page before filling in this page.) Order ο. 23 The Central Ministry of Economic Affairs rubs out Λ Negative Workers Consumer Cooperatives Co., Ltd. Yinben A7 B7 V. Invention Talk (20) In the above formula (1), such as If logA is less than 9, it is sufficient from the viewpoint of the generation of residual r and the refinement of the micro-vision structure, which will cause the dynamic deformation to offset σ dyn and the work hardening performance of 1 to 5%. For another example, if iOgA exceeds 18, the equipment to be achieved needs to be more disguised as magic ”and in (2), if the condition of (2) cannot be satisfied, the remaining 7 is excessively stable, although the remaining on the way of deformation can be carried out. However, 'r metamorphosis' cannot fully deform in the low distortion range, which will cause dynamic deformation resistance to adyn, work hardening performance of 1 to 5%, and the like. As shown in formula (2), the lower limit of ΔΤ can be alleviated by reducing iOgA. And since the equipment should be enlarged, the upper limit of the 'ΔT' of the reduction of the residual Vostian iron's integral rate and the coarsening of the micro-vision structure should be set at 300 ° C. Moreover, if the winding temperature does not satisfy the relationship of formula (3), it will have an adverse effect on ensuring the residual amount, or the residual r is too stable when the residual T is obtained, or the residual r is still deformed during the deformation. , But can not be fully deformed in the low distortion range, will cause dynamic deformation resistance adyn, 1 ~ 5% work hardenability .. «can deteriorate. Moreover, the limit of the bypass temperature can be relaxed by increasing 10 gA. In addition, when the duty factor of the Asada loose iron is 23%, each ct can be 35 (TC). However, in order to suppress the excessive production of Asada loose iron, it is desirable to make CTg 25 ° C better β. Second, the cold rolling of the present invention The steel plate is delivered to the cold-rolled copper plate at a rolling rate of 40% or more after the hot-rolled and wire-taken projects, and the cold-rolled steel plate is then annealed. The annealing is performed as shown in Figure 7 The annealing ring is most suitable for annealing. When the final product is annealed in this continuous annealing process, it is annealed at 0_1X (Ac3-Ac 丨) + Ac, above ° C and above Ac3 + 50 ° C for 10 seconds to 3 minutes. Then, once at 1 ~ 10 ° C / sec &gt; This paper size applies Chinese National Standard (CNS) A4 specification (210 × 297 mm)-* \ p, &quot; \ o · ^ ------ tr ------ (Please read the note on the back first and then fill in the note) 24. Consumers 'Cooperatives' Seal of the Ministry of Economic Affairs, China ’s Ladder and Quasi-Staff Bureau A7-_B7_ V. Description of the invention (21) However, the speed is cooled down to The primary cooling stop temperature Tq in the range of 550 ~ 720 ° C, followed by cooling to the secondary cooling stop temperature Te at a secondary cooling rate of 10 ~ 200 ° C / s And keep in Toa for 15 seconds to 20 minutes and then cool to room temperature. ”The annealing temperature is less than the temperature determined by the chemical composition of the steel, Ac 丨 and Ac3 (as published by Maruzen; WC Leslie" Copper and Iron Materials Science "p273). In the case of O.lXiAc ^ -AcO + Ac / C, the amount of Wastfield iron obtained at the annealing temperature is too small to stably retain the remaining Wastfield iron in the final steel sheet, so 0.1 X (Ac3 — Ac 丨) + Ac / C is the lower limit. In addition, if the annealing temperature exceeds Ac3 + 50 ° C, any steel properties will not be improved, which will cause cost increase. Therefore, Ac3 + 5 (TC is the upper limit of the annealing temperature. At this temperature The annealing time is at least 10 seconds for the equalization of the temperature of the steel plate and the guarantee of the amount of iron in Wastian. However, if the above effect is more than 3 minutes, the effect will be saturated and the cost will increase. The iron in the field is transformed into fat iron, which makes C concentrated in the unreformed gray iron. It is very important to stabilize the iron in the iron field in Tuvos. If its cooling rate is less than It / s, it will take a large production line for production. Poor sex, so the lower limit is 1 ° C / s If the cooling rate exceeds 10 ° C / sec, it will not be able to fully promote the metamorphosis of the target iron. Finally, it is difficult to ensure the residual Vostian iron in the steel plate. Therefore, the upper limit is 10 ° C / sec. When the temperature is less than 550 ° C, the boron iron is generated during the cooling, which will waste the stability of Vostian Iron and discard C. In the end, a sufficient amount of residual Vostian iron cannot be obtained. Furthermore, if the above cooling is only carried out to more than At 720 ° C, it can not fully promote the iron metamorphosis of the fertilizer. In order to avoid the occurrence of cooling during the secondary cooling following the rapid cooling (please note the precautions on the back of Min Jing before filling out this page) d. .Tr This paper is again applicable to the Chinese national standard (CNS> A4 specifications ( 210X297 mm) -25-Printed on A7 B7 by Shellfish Consumer Cooperative of Central Bureau of the Ministry of Economic Affairs -------------V. Description of invention (22) Polymorphic iron and carbon iron compounds Precipitation, the minimum cooling rate must also be maintained above i0r / s, but if it exceeds 200r / s, it will cause difficulties in equipment capabilities. The cooling temperature of the secondary cooling is less than 15 ° At time c, almost all of the Vastfield iron remaining before cooling was transformed into Asada loose iron, so that it is impossible to ensure the residual Vastfield iron β and the cooling stop soil degree exceeds 450 ° C, and the dynamic deformation resistance finally obtained adyn will be reduced immediately. In order to stabilize the remaining Vosstian iron in the steel plate at room temperature, it is more appropriate to change the carbon concentration of Vostian to further improve the carbon concentration of Vostian iron. When it is lower than the temperature maintained for the toughening iron metamorphosis treatment, it should be heated to this temperature. If the heating speed is maintained at 5 ° c / sec ~ 50 ° c / sec, the fan garden will not cause the final characteristics of the copper plate to deteriorate. On the contrary, if the secondary cooling stop temperature is higher than the toughened iron processing temperature, such as Forced cooling to a toughened iron processing temperature at a cooling rate of 5 ° C / sec to 20CTC / sec, even if directly transported to a heating zone with a target temperature set in advance, the final characteristics of the steel plate will not be degraded β In addition, when the steel sheet is maintained at less than 150 ° C or when it is maintained at more than 50 ° C, sufficient residual Vostian iron cannot be ensured. Therefore, the holding temperature range is from 15 to 500eC. This Time, if the holding time of 15 (TC ~ 500t is not caught for 15 seconds, it is impossible to obtain the final required amount of residual Wastfield iron due to inadequate metamorphic iron metamorphosis. If it exceeds 20 minutes, it will be toughened. After the metamorphosis of iron, carbon iron compounds will be precipitated or wave iron metamorphism will be generated, resulting in the waste of C ′ required to generate the residual Vosstian iron, and the required amount of residual Vosstian iron cannot be obtained, so it takes 15 seconds to 20 minutes. For holding time, and to maintain toughening iron metamorphosis for 15 〇 ° c ~ 500 ° C, regardless of whether it is isothermally maintained, or within this temperature range, this paper ΛΑ is suitable for CNS (consideration) • ^ 1-1-1 II— 11 ^ -1 * ^ 1 H— — ^ 1 —Λιν— II (please read the note f on the reverse side before filling out this page) Order -Γ ·. 26 A7 B7 Zhongji Department of the Central Government Zhun Λzhengong Cooperative Cooperative Yin ¾ 5. Description of the invention (23) The temperature is intentionally changed without deteriorating the final characteristics of the steel sheet. The preferred cooling conditions after annealing according to the present invention are m〇1x (Ac3_ ACD + Ac / C above A (: After annealing at a temperature below 3 + 50 ° C for 10 seconds to 3 minutes, it is cooled to 55 to 72 ° at a cooling temperature of 1 to 10 ° C / second. 〇Second cooling start temperature Tq in the range, followed by cooling at a secondary cooling rate of 10 ~ 200 / second to the temperature determined by the annealing temperature T0 of the surface material composition: Tem-100 ° C or more and Tem or less The temperature Te is reached at the end of the secondary cooling, and then maintained at a temperature of Te_50 ° C and 500 ° C below Toa for μ seconds to 20 minutes and cooled to room temperature. This is the method of expressing the quenching end overflow degree of the continuous annealing cycle shown in the eighth circle as a function of the component annealing temperature To, and annealing below a certain limit value, and the over-aging temperature To The relationship between the end of quenching temperature Te is regulated by β. Here, Tem is the starting temperature of the Asada loose iron metamorphosis remaining at the quenching start temperature Tq. That is, Tem is a value that removes the influence of the C concentration in Vostian iron. (T1) The difference between the values (T2) indicating the effect of C concentration: Tem = T1-T2. Here T1 is the temperature calculated based on the concentration of solid solution elements other than C, and T2 is the temperature calculated from the concentration of c in the self-residual Vostian iron at the time Tq determined by the composition of the steel plate and the annealing temperature. And 'Ceq_ is the carbon equivalent remaining in Vosstian iron at the annealing temperature To. So T1 is, T1 = 561-33 X {Mn% + (Ni + Cr + Cu + Mo) / 2} 'and T2 is, Ac, = 723-0.7 X Μη%-16.9 XNi% + 29.1 X Si% + 16.9XCr%, and {Please read the notes on the back before filling out this outfit.-Α This paper is suitable for HU home transfer (CNS) Congba (2 similar to 297 books) 27 A7 Political Year 47 双双 _Β7 _ V. Description of the invention (24) (Read the note f on the back before filling in this purchase)

Ac3= 910- 203 X(C%)1/2— 15.2 XNi% + 44.7 X Si% + 104 XV% + 31.5 XMo% -30 XΜη% - llXCr% -20XCu% + 70XP% +40XA1% + 400 ΧΉ% 以及退火溫度To所予以表示、 當 Ceq· = (Ac3 — Aq) X C / (To — Aq) + (Μη + Si/4 + / Ni/7+Cr+Cu+1.5Mo)/6、 /' , ? 如超過0.6時,以 T2=474X(Ac3-AcDXC/CTo-Aq)、 如0.6以下時,以丁2=474父(入(;3-八&lt;:1)父〇/{3父(入&lt;:3-入(:1) XC +〔(Mn+ Si/4 + Ni/7+Cr+Cu + 1.5Mo)/2-0.85)〕XCTo-Aq)}加 以表示。 經濟部智慧財產局貝工消費合作社印製 即,Te如未滿(Tem- 100)°C時,由於幾乎所有沃斯田 鐵均會變態為麻田散鐵,故無法獲得所需董之殘留沃斯田 鐵。又,Te如超過Tem則所得鋼板呈軟質致無法獲得由靜 態強度(TS)所期待之動態強度,故以Tem為Te之上限。且 、Toa為50(TC以上時,即會產生波來鐵乃至碳鐵化合物, 而浪费生產殘留沃斯田鐵所不可欠少之C,致無法獲得所 需量之殘留沃斯田鐵。另,Toa如未滿Te—50°C時,則需 要附加冷卻設施或連續退火爐之爐溫與鋼板之溫度差所起 因材質上之參差不齊會趨大,故以此溫度為下限。 藉採用如上述鋼板組成及製造方法即可生產;鋼板之 微視組織含有肥粒鐵及/或變韌鐵,是一種以其中任一為 主相與含有饉精分率3〜50%殘留沃斯田鐵之第3相複合之 28 本紙張又度適用中國國家梂率(CNS ) A4規格(210X297公釐) «濟部中央梯率局貝工消费合作社印装 A 7 B7 五、發明説明(25) 組織,且其施加等效畸變〇%以上10%以下予先變形後, 於5X 102〜5X 103(l/s)畸變速度範圍予以變形時之3〜10 %等效畸變範圍之變形應力平均值&lt;7dyn(MPa),可滿足其 施加予先變形前在5X10·4〜5xl(T3(l/s)畸變速度範团測 得靜態拉力試驗之最大應力TS(MPa)所表示算式crdyng 0.766 XTS + 250,及畸變1〜5%之加工硬化指數可滿足 0.080以上之具高動態變形抵狁之高強度鋼板》又,本發 明之鋼板亦可施加退火,調質軋制、電鍍等處理以製成目 的產品。 實施例 次即依據實施例說明本發明》 〈實施例1&gt; 將表1所示15種鋼材加熱至1050〜1250°C,以表2所示 製造條件進行熱軋、冷卻、繞取製成熱軋鋼板《其中可滿 足本發明成份條件及製造條件之鋼板,即如表3及表4所示 含有由殘留沃斯田鐵中固溶〔C〕舆鋼材平均Mn eq所決 定Μ值為70以上250以下之«積分率3〜50%初期殘留沃斯 田鐵’並具有(初期殘留沃斯田鐵體積分率一5%予先變形 後殘留沃斯田鐵髏積分率)/初期殘留沃斯田鐵艘積分率 20.3之適度安定性,且均能顯示CTdyn鑫0.766XTS + 250 、1〜5%之加工硬化指數go.〇80、1〜5%之加工硬化指 數X降伏強度240之卓越耐衝撞安全性,及兼具成形性舆 點焊性乃是至為明顯。 本紙張歧逍用中S國家標率(CNS ) A4^ ( 210X297公釐)~ : -- {請先《讀背面之注f項再填寫本頁) :裝 訂 d 29Ac3 = 910- 203 X (C%) 1 / 2— 15.2 XNi% + 44.7 X Si% + 104 XV% + 31.5 XMo% -30 XΜη%-llXCr% -20XCu% + 70XP% + 40XA1% + 400 χΉ% And expressed by the annealing temperature To, when Ceq · = (Ac3 — Aq) XC / (To — Aq) + (Μη + Si / 4 + / Ni / 7 + Cr + Cu + 1.5Mo) / 6, / ', If it exceeds 0.6, take T2 = 474X (Ac3-AcDXC / CTo-Aq), if it is below 0.6, take D2 = 474 father (into (; 3-eight &lt;: 1) father 0 / {3 father ( <&Lt;: 3-in (: 1) XC + [(Mn + Si / 4 + Ni / 7 + Cr + Cu + 1.5Mo) /2-0.85)] XCTo-Aq)}. Printed by the Shellfish Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs, that is, if Te is less than (Tem- 100) ° C, almost all Vostian iron will be transformed into Asada loose iron, so it is not possible to obtain the required residue of Vostian. iron. In addition, if Te exceeds Tem, the resulting steel sheet becomes soft and the dynamic strength expected from the static strength (TS) cannot be obtained. Therefore, Tem is the upper limit of Te. Moreover, when Toa is above 50 ° C, boron iron and even carbon iron compounds will be generated, and waste C, which is indispensable for the production of residual Vosted iron, will not be able to obtain the required amount of residual Vosted iron. In addition, If Toa is less than Te-50 ° C, additional cooling facilities or the temperature difference between the temperature of the steel plate and the steel plate of the continuous annealing furnace will be caused by the unevenness of the material, so this temperature is the lower limit. The above steel plate composition and manufacturing method can be produced; the microscopic structure of the steel plate contains ferrous iron and / or toughened iron, which is a kind of main phase and contains 3 to 50% residual Vostian iron. The third phase of the composite 28 paper is again applicable to China's National Standard (CNS) A4 specification (210X297 mm) «Printed by the Central Industry and Technology Bureau of the Ministry of Economic Affairs of the Bayer Consumer Cooperative A 7 B7 5. Invention Description (25) Organization , And its equivalent distortion of 0% to 10% is pre-deformed, and the deformation stress in the range of 5X 102 to 5X 103 (l / s) is 3 to 10% of the equivalent distortion range when deforming. 7dyn (MPa), which can meet the 5X10 · 4 ~ 5xl (T3 (l / s) The maximum stress TS (MPa) in the static tensile test measured by the speed fan group is calculated by the formula crdyng 0.766 XTS + 250, and the work hardening index of distortion of 1 to 5% can meet the high strength steel plate with high dynamic deformation resistance of more than 0.080 " In addition, the steel sheet of the present invention may be subjected to annealing, quenching and rolling, electroplating, etc. to produce the target product. The examples are to explain the present invention based on the examples. <Example 1> The 15 types of steel materials shown in Table 1 are heated. To 1050 ~ 1250 ° C, hot rolled, cooled, and coiled under the manufacturing conditions shown in Table 2 to produce hot rolled steel sheets. "Steels that can meet the composition and manufacturing conditions of the present invention are shown in Tables 3 and 4. Contains «integral rate 3 ~ 50% initial residual Vostian iron 'with an M value of 70 or more and 250 or less determined by the solid solution [C] of the steel in the residual Vostian iron. The score is 5% to the residual Vostian Iron Skeleton integral rate after the first deformation.) / The initial residual Vostian Iron Boat integral rate is 20.3, which is moderately stable, and both can display CTdyn Xin 0.766XTS + 250 and 1 ~ 5%. Work hardening index go.〇80, 1 ~ 5% work hard Chemical index X drop strength 240 excellent impact resistance safety, and both formability and spot weldability are even more obvious. This paper is not used in the national standard rate (CNS) A4 ^ (210X297 mm) ~: -(Please read “Note f on the back side before filling out this page): Binding d 29

AA

7 B 26) κ—\ 明 説 明 發 ΤΪ 钟 &gt;#5»9岑· *1: Mn+NHCHCuf Mo 經濟部中央揉率局貝工消费合作社印製7 B 26) κ— \ 明明明 发 ΤΪ 钟 &gt;# 5 »9cen. * 1: Mn + NHCHCuf Mo Printed by Shellfish Consumer Cooperative, Central Rubbing Bureau, Ministry of Economic Affairs

Di M·* c G v〇 00 σ\ u U) N) 窟 ρ 3 P U: s Ui o b: Ο b: ρ p p o s ρ 5ί ρ P 0: p *»* VA ρ cs P Ο cf* ·» 今 時 Η* δ 〇 O N) 8 N) 'S to 8 N) 在 N«* is: tax* N—A b: 班 h — '8 tmmt ** h-· Ο 's k o o ’% o 1 1 P § § 〇 〇 Lh 1 KJt Ο ο s p D» o 白 u! o o d 0 1 ο 1 0 1 p fo o 兰 to p § p b ηί 〇 1 〇 S 〇 1 0 1 Ρ δ P 1 0 1 0 1 p 1-— ο 1 0 1 0 1 0 1 o S O § ΟΛ 1 1 1 ο S 1 1 1 o δ ο ο § I 1 1 1 1 〇 § 1 o § ο 1 o § 0 1 0 1 i ο .1 O S 0 1 0 1 P 1 0 1 -¾ 2 LA ks κ&gt; •8 to s K&gt; s to s N) f〇 *—* 2 y: (Μ* i5 ii N·» Wm* h I p Ρ o 9 O 1 Ο δ 菩 〇 d Ο &lt; i 00 0 1 Ρ o o o i '»—· k—« 盎 h«* s — N»* t—k ο % !β k·^ S — η-* to 〇 is ji 〇 't Ο s 1 o Id ο o y o o Kj 00 o S — 〇 δ iO δ NJ δ to s NJ s 态 8 宕 3^ &gt;&lt;»* s y 1 o 洽 P « o 冶 〇 ! 21 s〇 g 豸 pm* 8 1 Dl υί ο Di KJ\ P^* m m s o° 00 宏 s u&gt; 1 3 一 2S VI 1 i 1 s N&gt; 23 笤 i 00 1 1 s d 00 g Si ►-* 8S U&gt; 8S s S 00 Di o i i i i Ϊ 澹 § | t £ $ 潘 I I § Ϊ £ ± 串 潘 重 t 举 1 $ 潘 t 率 £ £ t £ ir t Ά 生 m ^一1-^0·^^^ --------—ο 裝--(請先閲讀背面之注$項再填寫本頁) 訂 0_ 本紙張尺度適用中國國家梂準(CNS ) A4规格(210X297公釐) 30Di M · * c G v〇00 σ \ u U) N) Cave ρ 3 PU: s Ui ob: Ο b: ρ ppos ρ 5ί ρ P 0: p * »* VA ρ cs P 〇 cf * ·» Now Η * δ 〇ON) 8 N) 'S to 8 N) In N «* is: tax * N—A b: class h —' 8 tmmt ** h- · 〇 'skoo'% o 1 1 P § § 〇〇Lh 1 KJt 〇 ο sp D »o White u! Ood 0 1 ο 1 0 1 p fo o blue to p § pb ηί 〇1 〇S 〇1 0 1 ρ δ P 1 0 1 0 1 p 1-— ο 1 0 1 0 1 0 1 o SO § ΟΛ 1 1 1 ο S 1 1 1 o δ ο ο § I 1 1 1 1 〇§ 1 o § ο 1 o § 0 1 0 1 i ο .1 OS 0 1 0 1 P 1 0 1 -¾ 2 LA ks κ &gt; • 8 to s K &gt; s to s N) f〇 * — * 2 y: (Μ * i5 ii N · »Wm * h I p ρ o 9 O 1 Ο δ 〇〇d 〇 &lt; i 00 0 1 Ρ oooi '»— · k—« Ang h «* s — N» * t—k ο%! Β k · ^ S — η- * to 〇is ji 〇 't Ο s 1 o Id ο oyoo Kj 00 o S — 〇δ iO δ NJ δ to s NJ s State 8 Dang 3 ^ &gt; &lt; »* sy 1 o PP« o ye o! 21 s〇g 豸 pm * 8 1 Dl υί ο Di KJ \ P ^ * mmso ° 00 macro s u &gt; 1 3 one 2S VI 1 i 1 s N &gt; 23 笤 i 00 1 1 sd 00 g Si ►- * 8S U &gt; 8S s S 00 Di oiiii Ϊ | § | t £ $ Pan II § ± £ ± string pan weight t lift 1 $ Pan t rate £ £ t £ ir t Ά 生 m ^ 一 1- ^ 0 · ^^^ --------— ο equipment-(Please read the note on the back before filling this page) Order 0_ This paper size applies to China National Standard (CNS) A4 (210X297 mm) 30

7 7 A B 五、發明説明( 經濟部中央揉準局負工消费合作社印装 T捧&gt;却长卑潘^0导。 *1 : 7500°〜7000°150°\孝 t—* U&gt; fo o 00 -0 〇\ Ϊ-Λ u&gt; r〇 1 薄 i 00 o oo DJ GO i o i u% oo δ 00 δ -4 8 00 S \〇 °i 系 y; 呂 绽 u 绽 徊1 N—^ 1 8 oo 8 00 8 s Ui 8 8 i 8 1 S i § § § |l N&gt; 1—* k) »M·^ N&gt; I: ίο ί〇 io S) 5o IO k&gt; N) to *4^ μ-* s: *—* bo oo H-* OO 诹 η 8 g S ΰ o s 8 Η-» 8 s &gt;m4 s N-* S s — δ &gt;—* H-* \m 1 UJ s {3 D; Cj cyi 1 1 »—* 3 ►»* δ HM* u&gt; Si 5*2t 孓5 s b; δ H·* &gt;—» bR s 〇 〇 〇 〇 〇 〇 〇 X 〇 〇 〇 〇 〇 〇 〇 柰S 丰鳥 1—* 8 s b? S δ S u&gt; δ ?°1 杀 丰 朞 普 § u&gt; s u&gt; Di U&gt; 8 U) o Ul u&gt; bi O to δ u&gt; s s&gt; u&gt; J 1 背 柰 丰 〇 〇 〇 〇 〇 X X X 〇 〇 〇 〇 〇 〇 〇 柰3 &gt; 2雉素丰 —J——:----of- (請先閲讀背面之注意Ϋ項再填寫本買) 訂 Ο 本紙張尺度適用中國國家揉準(CNS ) A4规格(210X297公釐) 31 五、發明説明(28) T 捧^钋 $54:4&amp;9岑。 i5 &quot; .7 7 AB V. Description of the invention (printed by the Central Government Bureau of the Ministry of Economic Affairs of the Ministry of Economic Affairs and Consumer Cooperatives) T &gt; but Changbei Pan ^ 0 guide. * 1: 7500 ° ~ 7000 ° 150 ° \ filial t— * U &gt; fo o 00 -0 〇 \ Ϊ-Λ u &gt; r〇1 thin i 00 o oo DJ GO ioiu% oo δ 00 δ -4 8 00 S \ 〇 ° i is y; oo 8 00 8 s Ui 8 8 i 8 1 S i § § § | l N &gt; 1— * k) »M · ^ N &gt; I: ίο ί〇io S) 5o IO k &gt; N) to * 4 ^ μ -* s: * — * bo oo H- * OO 诹 η 8 g S ΰ os 8 Η- »8 s &gt; m4 s N- * S s — δ &gt; — * H- * \ m 1 UJ s { 3 D; Cj cyi 1 1 »— * 3 ►» * δ HM * u &gt; Si 5 * 2t 孓 5 sb; δ H · * &gt; — »bR s 〇〇〇〇〇〇〇〇〇〇〇〇〇〇〇 〇〇 柰 S 丰 鸟 1— * 8 sb? S δ S u &gt; δ? ° 1 Killing period § u &gt; s u &gt; Di U &gt; 8 U) o Ul u &gt; bi O to δ u &gt; s s &gt; u &gt; J 1 Back 柰 丰 〇〇〇〇〇〇XXX 〇〇〇〇〇〇〇〇〇 柰 3 &gt; 2 雉 Su Feng —J ——: ---- of- (Please read the note on the back first) Then fill out this buy) order Ο This paper applies China National rub scale quasi (CNS) A4 size (210X297 mm) 31 V. invention is described in (28) T ^ holding polonium $ 54: 4 &amp; 9 Cen. i5 &quot;.

A B 經濟部中央揉準局員工消费合作社印製 5: Cj n3 s 00 On Lft u&gt; NJ I 1 1 m 1 | | I I I I I I I I I I i I I I N y* OJ OJ 加工纽織 m* &lt;=&gt; (〇 l/l bo Kl 等董圓直 徑 at δ 容 冶 s gg s 00 s ss a % I 5; 1 to Lh 1 1 yi δ; 5; N&gt; to &lt;&gt; K&gt; OS 等量圓直 後 〇 1 i 〇 S 00 1 1 O 糸 o 〇 〇 o δ o o o 對主相粒 徑比 1 tmm* o 1 1 b Η N-« K-M Kj Ν«· 1—· Mo* y C?JML % 4* m » 皤 OJ Ο Ln 〇 〇 tsj — v〇 〇〇 1 Ο u» 私 o\ o 〇 〇\ Ul 〇s ij% fai m » 田 » 1 3 ο 糸 I 〇 o fe o h 1 • 〇 '8 〇 S 2 〇\ o 2 w o P o {V(0&gt;V(5)J /V(0) I 1 1 1 1 1 1 1 1 1 w w bs 1 U&gt; Ui &lt; 等量8直 程μπι 田 痒 Ο ο 〇 o o 〇 〇 〇 〇 〇 C/i 9s o M o «積率 % 梟 军 % 1 GO 00 •V ·〇 00 W 〇ΰ 1 CO 1 W S 1 85 5 1 « 6 Μ* s 5 s S s ΰί 1·^ IS 2 〇 1 〇 〇 〇 1 1 X 〇 〇 〇 〇 〇 〇 〇 1 — J_1_Γ— ι_------ίτ—— —---ϋ(請先閎讀背面之注$項再填窝本頁) 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) 五、發明説明(29) *1 : σφη-(0.766χτ8+250) A7 B7Printed by the Consumer Cooperative of the Central Bureau of the Ministry of Economic Affairs of the AB 5: Cj n3 s 00 On Lft u &gt; NJ I 1 1 m 1 | | IIIIIIIIII i IIIN y * OJ OJ Processing Button Weaving m * &lt; = &gt; (〇l / l bo Kl and other circular diameters at δ Rongye s gg s 00 s ss a% I 5; 1 to Lh 1 1 yi δ; 5; N &gt; to &lt; &gt; K &gt; 〇S 00 1 1 O 糸 o 〇〇o δ ooo to particle size ratio of main phase 1 tmm * o 1 1 b Η N- «KM Kj Ν« · 1— · Mo * y C? JML% 4 * m »皤OJ Ο Ln 〇〇tsj — v〇〇〇1 〇 u »Private o \ o 〇〇 \ Ul 〇s ij% fai m» Tian »1 3 ο 糸 I 〇o fe oh 1 • 〇'8 〇S 2 〇 \ o 2 wo P o {V (0 &gt; V (5) J / V (0) I 1 1 1 1 1 1 1 1 1 1 ww bs 1 U &gt; Ui &lt; equal 8 direct travel μπι Tian Tian 〇 ο 〇 oo 〇〇〇〇〇〇〇C / i 9s o M o «Production rate% 枭 军% 1 GO 00 • V · 00 00 W 〇ΰ 1 CO 1 WS 1 85 5 1« 6 Μ * s 5 s S s ΰί 1 · ^ IS 2 〇1 〇 〇〇1 1 〇〇〇〇〇〇〇〇〇1 — J_1_Γ— ι _------ ίτ—— —--- ϋ (Please read the note on the back before filling in this page) The paper size Applicable to China National Standard (CNS) A4 specification (210X297mm) V. Description of invention (29) * 1: σφη- (0.766χτ8 + 250) A7 B7

經濟部智慧財產局員工消費合作社印製 Η-* u\ &gt;—* OJ c Η-* f* ο VC όο --4 ON t-Λ u&gt; ΪΟ 辣瀹 3ί U) Η-* § 2 o S Di VI 名 a u% £ KJi a 认 § i 00 ο δ «-Λ 1^ 奉 m 钵 ^l·· ϊ m 尝 1 S I s I KJi 8 Φ s b5 cn iji S 8 b3 〇 Ln g &gt;g 1 Ui δ b3 Ο ΰ 迖 Μ 冶 UJ OJ N«A u&gt; ^ W ρ Η** i ο § p § ρ s ΙΟ b g ρ i P 画 ρ ►—* ρ 8 p S p i ρ § ρ — «μΛ Ο § 备次 ίο b2 κ bR b3 〇\ VX % ON 茬 S ΟΟ s s 00 S5 S es Η·* Η-* 8 s Si ο — 8 o κ·* 1 H-* 00 « t-n y; 1 s η-* § g Ο ΰ 罗X • H 次Ξ η 3* -1« ih ϋ· ο 相 Sh 钵 ϋ· 濘 3* 4» 钵 ϋ· η 蚪 i4- n 蚪 S' Ί* 3* 侔 ϋ· η Η« 5h 钵 〇* 4β a* 钵 O a* -i« 3· ϋ- η a· Ί* Sh 钵 ϋ· n a* -1« a* n ϋ- n 5h +» ϋ· r a* 5h 钵 ϋ- η a* 相 η ϋ· η Ί* a* η is- 8!f g *¥ m 1 S U\ KJ&gt; iy» kj% U\ U&gt; u* Ul 次 ^t 斜 斜 瞄由 系£ Ο s Ui g SS Ο § Η»* 3 Η** 00 s 00 ΟΟ $ Q 貧 1 5 ϊ Μ S Ί η-^ 1 Ui k) »-«* 1 u&gt; ζ〇 念 U) UJ δ u bo Lfi U) * f m 掛 掛 B 麻 路 掛 振 斟 齡 i S n·» s ο υ; y Oj L; ΝΜ* H-A N-* a: L*j On 1—&gt; ίέ: s 0* ---------ό-------於------cr(請先閏讀背面之注$項再填窝本賈) 本紙張尺度適用中國國家橾準(CNS ) Α4规格(210X297公釐) 33 A7 B7 五、發明説明( &lt;實施例2&gt; 將表5所示25種鋼材在Αγ3以上完成熱軋及冷卻後予以 繞取,並經酸洗再冷軋。然後自鋼材成份求出ACl、八(:3之 各溫度並進行如表6所示退火條件之加熱、冷卻、保持處 理,復又冷卻至室溫。其可符合本發明製造條件及成份條 件之各鋼材,乃如表7及表8所示,顯然可表示殘留沃斯田 鐵中固溶〔C〕與鋼材平均Mn eq所珠定之Μ值為70以上250 以下,均為adyng0.766xTS + 250、及畸變1〜5%之加 工硬化指數值呈40以上之卓越耐衝撞安全性。 **\! V '' ------IT------ (請先聞讀背面之注f項再填寫本頁) 經濟部中央橾準局貞工消费合作社印裝 本紙張尺度適用中國國家標準(CNS ) A4规格(210X297公釐) 34Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs Η- * u \ &gt; — * OJ c Η- * f * ο VC όο --4 ON t-Λ u &gt; ONΟ 瀹 瀹 3ί U) Η- * § 2 o S Di VI name au% £ KJi a Recognition § i 00 ο δ «-Λ 1 ^ Bong m bowl ^ l · · m taste 1 SI s I KJi 8 Φ s b5 cn iji S 8 b3 〇Ln g &gt; g 1 Ui δ b3 Ο 迖 迖 Μ UJ OJ N «A u &gt; ^ W ρ Η ** i ο § p § ρ s ΙΟ bg ρ i P Picture ρ ►— * ρ 8 p S pi ρ § ρ —« μΛ Ο § Preparation times ο b2 κ bR b3 〇 \ VX% ON S S ΟΟ ss 00 S5 S es Η · * Η- * 8 s Si ο — 8 o κ · * 1 H- * 00 «tn y; 1 s η -* § g Ο ΰ Luo X • H times Ξ η 3 * -1 «ih ϋ · ο phase Sh bowl ϋ · muddy 3 * 4» bowl ϋ · η 蚪 i4- n 蚪 S 'Ί * 3 * 侔 ϋ · η Η 5h bowl 0 * 4β a * bowl O a * -i «3 · ϋ- η a · Ί * Sh bowlϋ na * -1« a * n ϋ- n 5h + »ϋ · ra * 5h bowl ϋ- η a * phase η ϋ · η Ί * a * η is- 8! fg * ¥ m 1 SU \ KJ &gt; iy »kj% U \ U &gt; u * Ul times ^ t oblique oblique sighting system £ Ο s Ui g SS Ο § Η »* 3 Η ** 00 s 00 ΟΟ $ Q Lean 1 5 ϊ Μ S Ί η- ^ 1 Ui k) »-« * 1 u &gt; ζ〇 念 U) UJ δ u bo Lfi U) * fm Hanging B Bing Road Vibrating Age i S n · »s ο υ; y Oj L; NM * HA N- * a: L * j On 1— &gt; ίhand: s 0 * --------- ό ------- Yu ------ cr (Please read the note on the back of the page before filling in the nest) This paper size is applicable to China National Standards (CNS) A4 specifications (210X297 mm) 33 A7 B7 V. Description of the invention (& lt Example 2 &gt; The 25 kinds of steel materials shown in Table 5 were wound after hot rolling and cooling at Aγ3 or higher, and were pickled and then cold rolled. Then calculate the temperature of ACl, VIII (: 3) from the steel composition and perform the heating, cooling, and holding treatments as shown in Table 6 for annealing, and then cool to room temperature. It can meet the manufacturing conditions and composition conditions of the present invention. Each steel, as shown in Tables 7 and 8, can clearly indicate that the M value determined by the solid solution [C] in the residual Vosstian iron and the average Mn eq of the steel is 70 or more and 250 or less, both of which are adyng0.766xTS + 250, and The work hardening index value of distortion of 1 to 5% is superior to 40. ** \! V '' ------ IT ------ (Please read the note f on the back first (Fill in this page again.) The printed paper size of the Zhengong Consumer Cooperative of the Central Bureau of Standards and Commerce of the Ministry of Economic Affairs applies to the Chinese National Standard (CNS) A4 (210X297 mm).

AA

7 B 五、發明説明(31) 經濟部中央標準局負工消费合作社印製 ί · *1: Mn+NH〇fQHM&gt; a u&gt; — ΰ to 00 Η·* 5; 痒瀹 Ρ p f3 Ρ P ρ p ί3 p E3 s LA o s ρ p N-* ρ ρ 5ί ο 1¾ P ρ p Ej P KJ p ίο ρ Ε3 ρ ?3 ο ο y ρ Ε3 Ο 泫 η 1 s m i — ζ — u&gt; o ·—* δ y M* — 宕 N-« )&amp; o o § *^Λ i Ν&gt; 8 y — ί—· y w — p — N·* M»· b··* )&amp; — to 's MM s P d 8 Ρ C: Ο i § 〇 p ρ o 由 o 〇 y | o g •M* 0 1 o o o 0 1 0 1 Ο § Ρ 8 M p ί3 ο ο UJ § ο p § u&gt; 1 Ρ 1 ο 1 ο 1 Ο 由 ro ο ο ο 〇 0 1 1 0 1 Ρ § 0 1 0 1 O % o § 0 1 0 1 ο 1 1 1 1 1 ο 1 o S o s ο § Ρ § ο § ο § ο 'S LA 1 cn 〇 1 ο t o 's ο s 1 1 1 o s o s o s ο ο S P g N·^ Η·* ο •S 1 1 1 1 1 ο S ο .¾ ο 耷 匕 〇 § P § 1 o § i 1 i i i 1 1 1 ο 1 O i i 1 o § i ο 1 Ρ § 1 ο 1 ο § Ρ § 2 *—&gt;· NMk b! k k ic u&gt; b: O is s IB* ►—* Ν» δ P»* c: 台 »—* is N«* MBA S Κ) S bl ίίί b{ No* k 1 S u: c: § g δ b: Q S g&gt; S 1 〇 o •8 ο to % ρ 1 d δ &lt; P 0 1 w o s S — ta* |M* )S to g »-* u&gt; y »mm* s s i ο Ν«* Ν-* s * s p D! o S δ Ul s u δ KJ% o hi δ ij» δ u% s Lh Ο fe P 或 2 δ Ul ο o in P § ο fci δ *Μ* ο δ: S § o y K) tarn* N»« )£ N-* S to 茗 ε to y tmm* δ δ 1 »·» s ! g •xj «a* »^&gt; i «•4 c a SO s s CJ kM« I 萏 茜 — 00 N-* 私 ss NBA 窆 1 s 溶 s 00 s 00 So 00 s 8S 00 3 Lh 1 I 00 00 S S δ 落 S5 i d **4 s KJ\ oo 茗 1 00 N^» δ 2 οο 25 00 §; I I 宝 | 1 1 1 i I 1 1 s J3 s it S £ 寰 1 ¥; £ sr 潘 童 潘 畫 t £ 1 £ » £ 奮 i Ά 1 t &amp; 1 举 £ 重 £ 宭 t £ 1 * 欲 &gt;认童卜0=·»奔今 --------—〇·裝—(請先閲讀背面之注意事項再填寫本頁) 訂 本紙浪尺度逋用中國國家梂準(CNS ) Α4规格(210X297公釐) 35 A7 B7 五、發明説明(岣 經濟部中央橾準局貝工消費合作社印褽 OJ bi U&gt; L»J N&gt; OJ ►-* NJ 8 VO 00 1—* I W g g § g ON 00 〇\ oo ON OO g § § g g § g g 若 IS: \ ίο S g s g g 1: δ S S s o bo s s S s s δ s S η § i 1 00 8 1 00 s OO 8 o oo o 00 o 00 8 S 1 00 o 3 i 9〇 8 〇 i 00 8 1 00 δ 00 8 Η抹 气ί 9&amp; &gt;r S 8 8 S s s s S s s s S s s 8 s s s I—^ s 8 s 8 S Ul Ln Crt ΐ-Λ KJt u% &lt;-r* OO 00 U\ Ut i-ft OO oo ί-Λ U\ 〇°? 〇 卺 〇 〇 实 o 1 | 卺 〇 实 o δ o § I 1 85 〇 s o a o a O On § ON § ON § o s 实 o 〇\ 00 o 〇°s 1—» 8 1—ft 8 8 h-A S »—k 8 μ-» 8 1—» 8 &gt;—* s — s 8 1—» 8 s 8 s h&gt;* s UJ o OJ o 8 — 8 N-* 8 § N-k 8 8 8 ΙΟ r?片 UJ 8 〇 〇 u&gt; 8 U&gt; 8 CO 8 OJ 8 8 b! 〇 bi 〇 KjJ 运 bi o i g u&gt; 8 OJ 8 U) 8 § bi 〇 bi O 〇 o bi 〇 bl 〇 u&gt; 认 o ^ $ 。。5 U\ to iJt M LA UJ to f3 »—k Ul fo JjTJ UJ N&gt; N«* S) t-Λ U» H-k t3 会 00 Ul oo V/l K fo Lft ?3 U\ W 〇0§ ο b\ o 55 〇 〇 Ut K&gt; 〇 In Ό o δ o U) 〇 s o s o δ o In U\ o is o Ιλ O In ►—* o o i/l ON 〇 £ o £ o o s o iji U&gt; o Pit 4衲 冢 U\ 淫 Lh s § 茬 § f3 o u&gt; S 1—* H-* 象 U) 8 o Cj H-* o: g s; H-* H-* 匀 ►-* u&gt; 00 〇os d K) u&gt; UJ % 岑 ►«* U3 Ϊ3 OJ bi SO v〇 UJ to 00 00 ΪΟ oo u&gt; H-* 00 % u&gt; iu i i i i § u&gt; s bi O u&gt; 8 i i u&gt; K&gt; o ΰ o i i i u&gt; 8 i i i bi o o 〇〇 〇 〇; o 〇〇 〇 i i o oo 〇 § OO o 00 〇 oo o OO 〇 oo o i Di 〇 s 00 〇 oo o oo 〇 oo o o OO 〇 i 桊 孝1 (請先閱讀背面之注意事項再填寫本頁)7 B V. Description of the invention (31) Printed by the Consumers ’Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs * 1: Mn + NH〇fQHM &gt; a u &gt; — ΰ to 00 Η · * 5; itchy p p f3 ρ P ρ p ί3 p E3 s LA os ρ p N- * ρ ρ 5ί ο 1¾ P ρ p Ej P KJ p ίο ρ Ε3 ρ? 3 ο ο y ρ Ε3 Ο 泫 η 1 smi — ζ — u &gt; o · — * δ y M * — NN- «) &amp; oo § * ^ Λ i Ν &gt; 8 y — ί— · yw — p — N · * M» · b ·· *) &amp; — to 's MM s P d 8 Ρ C: 〇 i § 〇p ρ o by o 〇y | og • M * 0 1 ooo 0 1 0 〇 § ρ 8 M p ί3 ο ο UJ § ο p § u &gt; 1 ρ 1 ο 1 ο 1 〇 By ro ο ο ο 〇0 1 1 0 1 Ρ § 0 1 0 1 O% o § 0 1 0 1 ο 1 1 1 1 1 ο 1 o S os ο § ρ § ο § ο § ο 'S LA 1 cn 〇1 ο to 's ο s 1 1 1 ososos ο ο SP g N · ^ Η · * ο • S 1 1 1 1 1 ο S ο .¾ ο 耷 dagger § P § 1 o § i 1 iii 1 1 1 ο 1 O ii 1 o § i ο 1 Ρ § 1 ο 1 ο § ρ § 2 * — &gt; · NMk b! Kk ic u &gt; b: O is s IB * ►— * Ν »δ P» * c: Desk » -* Is N «* MBA S Κ) S bl ίίb {No * k 1 S u: c: § g δ b: QS g &gt; S 1 〇o • 8 ο to% ρ 1 d δ &lt; P 0 1 wos S — ta * | M *) S to g »-* u &gt; y» mm * ssi ο Ν «* Ν- * s * sp D! o S δ Ul su δ KJ% o hi δ ij» δ u% s Lh Ο fe P or 2 δ Ul ο o in P § ο fci δ * Μ * ο δ: S § oy K) tarn * N »«) £ N- * S to 茗 ε to y tmm * δ δ 1 » · »S! G • xj« a * »^ &gt; i« • 4 ca SO ss CJ kM «I 萏 茜 — 00 N- * Private ss NBA 窆 1 s solvent s 00 s 00 So 00 s 8S 00 3 Lh 1 I 00 00 SS δ drop S5 id ** 4 s KJ \ oo 茗 1 00 N ^ »δ 2 οο 25 00 §; II treasure | 1 1 1 i I 1 1 s J3 s it S £ 11 ¥; £ sr Pan Tongpan painting t £ 1 £ »£ Fen i Ά 1 t &amp; 1 lift £ heavy £ 宭 t £ 1 * desire &gt; recognize children 0 = ·» Benjin --------— · Packing— (Please read the precautions on the back before filling in this page) The size of the paper is in accordance with China National Standard (CNS) A4 specification (210X297 mm) 35 A7 B7 V. Description of the invention ("Central Standards of the Ministry of Economic Affairs") Local Shellfish Consumer Cooperatives India OJ bi U &gt; L »J N &gt; OJ ►- * NJ 8 VO 00 1— * IW gg § g ON 00 〇 \ oo ON OO g § § gg § gg If IS: \ ίο S gsgg 1: δ SS so bo ss S ss δ s S η i 1 00 8 1 00 s OO 8 o oo o 00 o 00 8 S 1 00 o 3 i 9〇8 〇i 00 8 1 00 δ 00 8 Η Wiping Gas 9 & &gt; r S 8 8 S sss S sss S ss 8 sss I— ^ s 8 s 8 S Ul Ln Crt ΐ-Λ KJt u% &lt; -r * OO 00 U \ Ut i-ft OO oo ί-Λ U \ 〇 °? 〇 卺 〇〇 real o 1 | 卺 〇 real o δ o § I 1 85 〇soaoa O On § ON § ON § os real o 〇 \ 00 o 〇 ° s 1— »8 1—ft 8 8 hA S »—k 8 μ-» 8 1— »8 &gt; — * s — s 8 1—» 8 s 8 s h &gt; * s UJ o OJ o 8 — 8 N- * 8 § Nk 8 8 8 ΙΟ r? UJ 8 〇〇u &gt; 8 U &gt; 8 CO 8 OJ 8 8 b! 〇bi 〇KjJ bi o i g u &gt; 8 OJ 8 U) 8 § bi 〇 bi O 〇 o bi 〇 bl 〇 u &gt; Recognize o ^ $. . 5 U \ to iJt M LA UJ to f3 »—k Ul fo JjTJ UJ N &gt; N« * S) t-Λ U »Hk t3 will 00 Ul oo V / l K fo Lft? 3 U \ W 〇0§ ο b \ o 55 〇〇Ut K &gt; 〇In Ό o δ o U) 〇soso δ o In U \ o is o Ιλ O In ►— * ooi / l ON 〇 £ o £ ooso iji U &gt; o Pit 4 U \ L Lh s § stub § f3 o u &gt; S 1— * H- * like U) 8 o Cj H- * o: gs; H- * H- * uniform ►- * u &gt; 00 〇os d K) u &gt; UJ% cen ► «* U3 Ϊ3 OJ bi SO v〇UJ to 00 00 ΪΟ oo u &gt; H- * 00% u &gt; iu iiii § u &gt; s bi O u &gt; 8 ii u &gt; K &gt; o ΰ oiii u &gt; 8 iii bi oo 〇〇〇〇〇; o 〇〇〇〇iio oo 〇§ OO o 00 〇oo o OO 〇oo oi Di 〇s 00 〇oo o oo oo oo OO 〇 桊 孝 1 (Please read the back first (Notes for filling in this page)

本紙張尺度適用中國國家標準(CNS ) A4规格(210 X297公釐) 36 五 3 /V明 •乱明發This paper size applies the Chinese National Standard (CNS) A4 specification (210 X297 mm) 36 5 3 / V Ming • Luan Mingfa

A B M濟部中央橾準局貝工消費合作社印装 δ UJ a ro NJ oo o; I m 穿 ϋ I I i i I i m I I I i i i 1« i i I I I I i i I I I 1 黎 Ην 金 V/l ίο 2 t u% NO Os bo V/l υ* δ P' os ON bo Οι U 〇·&gt; bo Vi U yi U u% v〇 00 Ul Ιλ C/l £ 56 鴒 _ 思 a s y 或 象 a K !S 名 ts 亡 a d b! S s C/l Kj% s 亡 盎 a s 巋 雜 I s 1 i: ΝΪ ·«» to bs 1 N&gt; oo 1 K&gt; ON Μ bU Ol u s 00 ΰ to NJ •心 to 00 K) 00 K&gt; &lt;Ts N) 00 鴒 W 苗 Η » e 田 » ο 1 § 〇 &amp; o δ 00 1 o 隹 1 o δ Οθ o 〇 § o o o bi S 00 s o o u&gt; Ut o O s s VO t Ϊ W fe 1 bi u» u&gt; c 00 1 k·^ fe 1 — PM* v〇 bi &gt;!* N·^ § δ s N·» 〇 &gt;—» s N»* Co 〇 § o 〇 〇\ -J 00 Ο 00 〇 00 M* NJ -J f3 OO Ό ? g » * C/l 蟪 〇 1-Λ Ui σ\ Ο 〇 04 U&gt; Oi 00 00 UJ OJ u&gt; UJ -J 00 Ϊ-Λ K&gt; Lfi 溪 ή I P 1 p o la o 5¾ § p M-&gt; 1 o Ο 〇 'Q o bi o s o s o P 容 o 芑 P a o o S5 o 汝 o o o 1 i5 bo 1 u&gt; bs bs W ν〇 i M K) 5: 6 to &lt;&gt; fai U&gt; u&gt; ro be UJ tax* OJ k&gt; s&gt; In 1 5; Β 5 S § 〇\ 〇 to ON o κ&gt; N»* VI 厶 私 ON 私 u&gt; KJt o N-* S 1» S 09 w C0 00 ω w ¢30 ? -¾ 00 OJ φ 09 00 W 00 W 09 C0 ω w w CO 00 09 1 i JO Ό is K 1 fo 一 G bwA « 8 s m* N·* s K c&gt; I I X X X X X X X X X 〇 〇 〇 X 〇 〇 〇 〇 〇 〇 〇 〇 0 〇 〇 〇 1 (请先閱讀背面之注$項再填寫本頁) ·-〇裝· 訂 %&gt; 本紙張尺度逍用中國國家揉準(CNS ) A4规格(210X297公釐) 37 五、發明説明(34) A7 B7Printed by the ABM Central Consumers ’Bureau of the Ministry of Economic Affairs of the People ’s Republic of China. UJ a ro NJ oo o; I m wear II ii I im III iii 1« ii IIII ii III 1 黎 Ην 金 V / l ίο 2 tu% NO Os bo V / l υ * δ P 'os ON bo 〇ι U 〇 &gt; bo Vi U yi U u% v〇00 Ul Ιλ C / l £ 56 鸰 _ Think asy or like a K! S name ts dead adb! S s C / l Kj% s is as mixed I s 1 i: ΝΪ · «» to bs 1 N &gt; oo 1 K &gt; ON Μ bU Ol us 00 ΰ to NJ • heart to 00 K) 00 K &gt; &lt; Ts N) 00 鸰 W Miao Η »e 田» ο 1 § 〇 &amp; o δ 00 1 o 隹 1 o δ Οθ o 〇§ ooo bi S 00 soo u &gt; Ut o O ss VO t Ϊ W fe 1 bi u »u &gt; c 00 1 k · ^ fe 1 — PM * v〇bi &gt;! * N · ^ § δ s N ·» 〇 &gt; — »s N» * Co 〇§ o 〇〇 \ -J 00 〇 00 〇00 M * NJ -J f3 OO Ό? G »* C / l 蟪 〇1-Λ Ui σ \ 〇 〇04 U &gt; Oi 00 00 UJ OJ u &gt; UJ -J 00 Ϊ-Λ K &gt; Lfi Creek价 IP 1 po la o 5¾ § p M- &gt; 1 o Ο 〇'Q o bi ososo P 容 o 芑 P aoo S5 o 汝 o oo 1 i5 bo 1 u &gt; bs bs W ν〇i MK) 5: 6 to &lt; &gt; fai U &gt; u &gt; ro be UJ tax * OJ k &gt; s &gt; In 1 5; Β 5 S § 〇 \ 〇to ON o κ &gt; N »* VI 厶 Private ON private u &gt; KJt o N- * S 1» S 09 w C0 00 ω w ¢ 30? -¾ 00 OJ φ 09 00 W 00 W 09 C0 ω ww CO 00 09 1 i JO Ό is K 1 fo a G bwA «8 sm * N · * s K c &gt; IIXXXXXXXXX 〇〇〇X 〇〇〇〇〇〇〇〇〇〇〇〇1 (Please read the note on the back before filling out (This page) · -〇 Binding · Order% &gt; This paper size is in accordance with China National Standard (CNS) A4 (210X297 mm) 37 V. Description of the invention (34) A7 B7

經濟部智慧財產局員工消费合作社印製 τί$3έΒ岑· *1 :Q&lt;ib®-(0.766XTS+250). UJ ㈡ u&gt; y K ΰ 00 5; Cn SO 5: s v〇 Ul Μ » 爸 § m* \〇 Μ CJ K) a «•j i S v〇 00 Μ a u&gt; m ? is- % m g s g ft ¢5 «*4 3 u&gt; 1 6 备 § 85 U% η 奈 6: N&gt; 6 Ui fcS K&gt; i K Ν·* κ « δ 0.142 1 0.164 1 0.132 0.086 1 i 1 0.141 ! I 1 0.144 1 1 0.126 | I 0.112 | 1 0.118 1 1 0.122 ] 1 0.0® 1 1 0.116 | | 0.122 | | 0.103 | 1 0.112 | 1 0.116 | I 0.112 | I 0.105 | 1 0.095 | 1 0.095 1 1 0.107 | ,0.117 1 1-5% 值 a 5ί ss U) 00 bs )£ « s a K δ P S i i § ΝΜ» ο P si 1 1 P 3 g P 2ί 1 1 δ 1 1 1 o b\ P m·* i 〇 •s % § o id 1 1 1 20152 24344 27168 26815 i 1 i 21090 23086 1 23345 1 I 24064* | 2704« 21665 I | 22440 Ί 23424 22295 22746 1 22473 | I I 25172 1 22855 ι 24768 TSXT.E1 MPs^%_ 〇 Π it n a* Π Ϊ 5a· η 蛘 3* n a* w O b- ο 5Α- O 輙 o a* &amp; i s ο a* ¥ $ 〇 * η η ah 掬 $ 〇 » W HI a* » ϋ· 〇 a* 輙 ah » 〇 * a· 钵 ϋ* O a* 卡 » 辠 m 钵 ϋ- n a· » o ¥ ϋ- 5 ¥ a* 钵 $ 〇 a· ¥ ϋ- η 3* ¥ » 予先變形 逢 1 I Ch u» ij% Ln LTl Ui U% Vi KJ% tmrn* KJ\ OJ 〇» Ul (•Λ 予先變形等 效 蚌 并 蚌 Hr 补 私 蚌 BH4 S UI § iS 00 o I S ^*4 δ i 器 hn* 00 N〇« Ul δ i ί Μ Q t 1 % 1 to lh s S: U 00 g u ΰ K U is 〇〇 •Ο bo bo -if &gt; I 7 I M » » » » m » » m » » » B » » » » (請先閱讀背面之注$項再填寫本買) 本紙張尺度逋用中國阃家揉準(CNS)A4规格(210X297公釐) -38 - 經濟部中央橾準局負工消费合作杜印製 A7 _B7 五、發明説明(35 ) 其微視组織乃藉下述方法加以評償》 肥粒鐵,變軔鐵,麻田散鐵及殘餘組織之識別,分佈 位置之觀察及平均結晶粒徑(平均等量圓直徑)與占空因素 之測定,係藉侵蝕溶劑及特開昭59-219473所開示溶劑予 以腐蝕鋼板之輾壓方向斷面,並以倍率1〇〇〇倍光學顯微銳 照片加以進行。 殘留沃斯田鐵之平均等董圓直徑則由特願平3-351209 所開示溶劑腐蝕其輾壓方向斷面,以倍率1000倍光學顯微 鏡照片加以求出之。並以同一照片觀察其分佈位置。 殘留沃斯田鐵體積分率(Vr :單位%)乃以Μ〇-Κα 線之X線解析依據下式予以算出。 V 7 =(2/3) { 100/(0.7 X a (211)/ r (220)+ 1)} +(1 /3) { 100/(0.78 X a (211)/ r (311)+ 1) } 但 ’ α(211)、r(220)、α(2ΐι)、7(311)表示面強度 ο 殘留r之C濃度(Cr :單位%)則以Cu-Κα線之X線解 析自沃斯田鐵之(200)面,(220)面,(311)面之反射角求出 晶格定數(單位A : Angstrom)、再依據下式算出。 C7* =(晶格定數一3.572)/0,033 特性評檟則藉下述方法加以評價。 拉力試驗係使用JIS 5號(棵麻距離50mm、平行部幅度 25mm)於畸變速度〇.〇〇 l/s加以實施,以求出拉力強度(TS) 、降伏強度(YS)、總延長率(T.E1)、加工硬化指數(畴變i %〜5%之11值)、並計算丫3父加工硬化指數、降伏比(丫11 本紙張尺度適用中國國家棣準(CNS ) A4规格(210X297公釐) —l·!'----9------tr---------ο. {請先閱讀背面之注$項再球寫本I ) 39 A7 B7 五、發明説明(36 ) =YS/TSX 100)、TSXT.E1。 凸緣延伸性則將20mm沖孔自其無變形之面以30度圓 錐衝頭加以擠宽,並求出其裂痕貫透板厚時之孔徑(d)與 初期孔徑(do,20mm)之擴孔比(d/do)。 點焊性乃將藉具鋼板板厚平方根5倍之尖端徑電極以 產生塵埃電流0.9倍電流予以接合之點焊試片,使用鋼鑿 加以破斷時,如產生所謂剝離破斷即評償為不適合。 如上述,本發明乃可以低成本穩定地提供以往未曾有 之具卓越衝撞安全性與成形性之汽車用高強度熱軋鋼板及 冷軋鋼板,且格外擴寬該高強度鋼板之用途及使用條件。 ίI-----ο! (請先聞讀背面之注f項再填寫本頁) 訂 鋰濟部中央揉準局負工消费合作社印裝 本紙伕尺度適用中國國家梯準(CNS ) A4规格(210X297公釐) 40Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs τί $ 3έcen. * 1: Q &lt; ib®- (0.766XTS + 250). UJ ㈡ u &gt; y K ΰ 00 5; Cn SO 5: sv〇Ul Μ »Dad § m * \ 〇Μ CJ K) a «• ji S v0000 Μ a u &gt; m? Is-% mgsg ft ¢ 5« * 4 3 u &gt; 1 6 § 85 U% η Nye 6: N &gt; 6 Ui fcS K &gt; i K Ν · * κ «δ 0.142 1 0.164 1 0.132 0.086 1 i 1 0.141! I 1 0.144 1 1 0.126 | I 0.112 | 1 0.118 1 1 0.122] 1 0.0® 1 1 0.116 | | 0.122 | | 0.103 | 1 0.112 | 1 0.116 | I 0.112 | I 0.105 | 1 0.095 | 1 0.095 1 1 0.107 |, 0.117 1 1-5% value a 5ί ss U) 00 bs) £ «sa K δ PS ii § ΝΜ» ο P si 1 1 P 3 g P 2ί 1 1 δ 1 1 1 ob \ P m · * i 〇 · s% § o id 1 1 1 20152 24344 27168 26815 i 1 i 21090 23086 1 23345 1 I 24064 * | 2704 « 21665 I | 22440 Ί 23424 22295 22746 1 22473 | II 25172 1 22855 ι 24768 TSXT.E1 MPs ^% _ 〇Π it na * Π Ϊ 5a · η 蛘 3 * na * w O b- ο 5Α- O 輙 oa * &amp; is ο a * ¥ $ 〇 * η η ah 掬 $ 〇 »W HI a *» ϋ · 〇a * 輙 ah »〇 * a · ϋ O * O a * card» 辠 m ϋ-na · »o ¥ ϋ-5 ¥ a * 钵$ 〇a · ¥ ϋ- η 3 * ¥ »Pre-transformation 1 I Ch u» ij% Ln LTl Ui U% Vi KJ% tmrn * KJ \ OJ 〇 »Ul (• Λ pre-transformation equivalent mussel and mussel Hr Buddy Clam BH4 S UI § iS 00 o IS ^ * 4 δ i hn * 00 N〇 «Ul δ i ί Μ Q t 1% 1 to lh s S: U 00 gu ΰ KU is 〇〇 • 〇 bo bo -if &gt; I 7 IM »(Please read the note on the back and fill in this purchase first) Please use the Chinese standard (CNS) ) A4 size (210X297 mm) -38-DuPont A7 _B7, Duty Printing and Consumer Cooperation of the Central Bureau of Standards, Ministry of Economic Affairs V. Description of the invention (35) The micro-vision organization is evaluated by the following methods: The identification, transformation, and observation of the scattered iron and the residual tissues of Asahi, Asada, and the measurement of the average crystal grain size (average circle diameter) and the measurement of the duty factor are based on erosion solvents and JP-A-59-219473. The solvent was developed to cross-section the steel sheet in the rolling direction, and a photomicrograph was taken at a magnification of 1,000 times. The average diameter of the Dong circle of the residual Vostian iron was calculated from the cross section of the rolling direction by the solvent disclosed in Japanese Patent Application No. 3-351209, and the photo was taken with a magnification of 1000 times. And observe the distribution location with the same photo. The residual Vosstian iron volume fraction (Vr: unit%) was calculated from the X-ray analysis of the Mo-Kα line according to the following formula. V 7 = (2/3) {100 / (0.7 X a (211) / r (220) + 1)} + (1/3) {100 / (0.78 X a (211) / r (311) +1 )} But 'α (211), r (220), α (2ΐι), 7 (311) represent the surface strength ο the concentration of C (Cr: unit%) of the residual r is analyzed by the X-ray of the Cu-Kα line. Calculate the lattice constant (unit A: Angstrom) of the reflection angles of the (200) plane, (220) plane, and (311) plane of Staine Iron, and then calculate it according to the following formula. C7 * = (lattice number 3.572) / 0,033 The characteristic evaluation is evaluated by the following method. The tensile test was performed using JIS No. 5 (distance between 50mm and 25mm in parallel) at a distortion rate of 0.001 / s to determine the tensile strength (TS), yield strength (YS), and total elongation ( T.E1), work hardening index (11% to 5% of domain change), and calculate the Y3 parent work hardening index, reduction ratio (11) This paper size applies to China National Standard (CNS) A4 specifications (210X297 Mm) —l ·! '---- 9 ------ tr --------- ο. {Please read the note on the back before writing the ball I) 39 A7 B7 V. Invention description (36) = YS / TSX 100), TSXT.E1. For flange elongation, the 20mm punched hole is extruded from its non-deformed surface with a 30-degree conical punch, and the expansion of the hole diameter (d) and the initial hole diameter (do, 20mm) when the crack penetrates through the thickness of the plate is calculated. Hole ratio (d / do). Spot weldability is a spot welding test piece that is joined by a tip diameter electrode that is 5 times the square root of the steel plate to generate 0.9 times the dust current. When a steel chisel is used to break, if the so-called peeling break occurs, the compensation is Not suitable. As described above, the present invention can stably provide a high-strength hot-rolled steel sheet and a cold-rolled steel sheet for automobiles with excellent collision safety and formability that have not previously been achieved at a low cost, and widen the use and use conditions of the high-strength steel sheet. ίI ----- ο! (Please read the note f on the back before filling out this page) Order the printed paper on the paper of the Ministry of Economic Affairs, Central Bureau of Standards and Commerce, Consumer Cooperatives, and apply the Chinese National Standard (CNS) A4 specification (210X297 mm) 40

Claims (1)

A8 B8 C8 D8A8 B8 C8 D8 六、申請專利範圍 第86117962號專利申請案 經濟部智慧財產局貝工消费合作社印製 修正本 修正曰期88年6月 種具有高動態變形抵抗之高強变鋼板,其特徵在於 :其最後所獲鋼板之微視组織乃含有肥粒鐵及/或變 物鐵’為一種以其中任一為主相舆含有饉積分率3〜5〇 %殘留沃斯田鐵之第3相複合之組織,且其經等效畸變 0%以上10%以下予先變形後再於5X 1〇2〜5 X 1〇3 (1/S) _變速度範团下變形時之3〜10%等政畸變範圍之變形 應力平均值σ dyn(MPa),係可滿足其施加予先變形前 在5X 10·4〜5X 1〇·3 (Ι/s)畸變速度範圍下測得之靜態 拉力試驗之最大應力TS(MPa)所表示算式σ dyn毳 0.766XTS + 250,並且萁畸變1〜5%之加工硬化指數 可滿足0.080以上。 2. 如申請專利範圍第1項之具有高動態變形抵抗之高強度 鋼板,其特徵在於: 上述鋼板之降伏強度X畸變1〜5%之加工硬化指 數之值能滿足40以上》 3. —種具有高動態變形抵抗之高強度鋼板,其特徵在於 :其最後所獲鋼板之撤視組織含有肥粒鐵及/或變韌 鐵、為一種以其中任一為主相舆含有饉積分率3〜50% 殘留沃斯田鐵之第3相複合之组織,且其經等效畸變〇 %以上10%以下予先變形後再於5X102〜5X103 (i/s) 畸變速度範圍下變形時之3〜10%等效畸變範圍之變形 應力平均值σ dyn,係可滿足其施加予先變形前在5X 10·4〜5 X 10·3(1 / s)畸變速度範圍下測得之餘態拉力 試驗之最大應力TS(MPa)所表示算式σ dyng 0.766Χ 1. 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 41 ----------------------------線 (請先閱讀背面之注意事項再填寫本頁) A8B8C8D8 項之具有高動態變形 /、、申請專利範圍 TS+ 250,並且上述殘留沃斯田鐵中固溶〔c〕與钢材 之平均Μη當董{Mn eq=Mn+(Ni+Cr+Cu+Mo)/2 }所決定之值(M)M=678-428X〔C〕一33Mneq 為 70 以上250以下’復又其予先變形前之殘留沃斯田鐵艟積 分率舆其經舆等效畸變5%予先變形後之殘留沃斯田鐵 艘積分率之差,為施加予先變形前之殘留沃斯田鐵艘 ,積分率30%以上,且畸變1〜5%之加工硬化指數可達 0.080以上。 如申請專利範圍第1〜3項之任一項之具有高動態變形 抵抗之高強度鋼板,其特徵在於: 上述殘留沃斯田鐵k平均結晶粒徑為5/zm以下, 及該殘留沃斯田鐵之平均結晶粒徑舆主相之肥粒鐵或 變韌鐵之平均結晶粒徑之比為〇.6以下,且主相之平均 粒徑為10仁m以下,最好為6仏mf下《» 5. 如申請專利範園第i〜3項之任一 抵抗之高強度鋼板,其特徵在於 上述鋼板之麻田散鐵艘積分_為3〜30%,該麻田 散鐵之平均結晶粒徑為1〇 M m以下,最好為5 β m以下 〇 6. 如申請專利範圍第1〜3項之任一項之具有高動態變形 抵抗之高強度鋼板,其特徵在於: 上述鋼板之肥粒鐵髏積分率為40%以上。 7. 如申請專利範圍第1〜3項之任一項之具有高動態變形 抵抗之高強度鋼板,其特徵在於: * 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) --------------------訂i!-------線 (婧先《讀背面之注$項再填寫本頁) 經濟部智慧財產局員工消费合作社印製 42 A8B8C8D8 經濟部智慧財產局貝工消费合作杜印製 六、申請專利範圍 上述鋼板之降伏比為85%以下,拉力強度X總延 伸率之值為20000以上。 8. 如申請專利範圍第i〜3項之任一項之具有高動態變形 抵抗之高強度鋼板,其特徵在於: 上述鋼板以重量計,含有C: 0.03%以上0.3%以 下,Si與A1之一方或雙方合計0.5%以上3.0%以下、及 ! .因應所需含有Mn、Ni、Cr、Cu、Mo之一種或兩種以 'ΐΙ 上合計0.5%以上3.5%以下,且其餘為以Fe為主成份 〇 9. 如申請專利範圍第8項之具有高動態變形抵抗之高強度 鋼板,其特徵在於:’ 上述鋼板以重董計,依須含有Nb、Ti、V、PiB 之一種或兩種以上,其中&gt;^、14、¥之_種或兩種以 上合計為0.3%以下,p為0.3%以下,B為0.01%以下 〇 10. 如申請專利範圍第8項之具有高動態變形抵抗之高強度 鋼板’其特徵在於: 上述鋼板以重量計,依需更含有Ca: 0.0005 %以 上 0.01% 以下、REM : 0.005% 以上0.05%以下。 11,如申請專利範团第9項之具有高動態變形抵抗之高強度 鋼板’其特徵在於: 上述鋼板以重量計,依需更含有Ca : 0.0005%以 上0.01 %以下、REM : 0.005% 以上0.05% 以下。 12. —種具有高動態變形抵抗之高強度熱軋鋼板製造方法 本紙張尺度適用中國國家棵準(CNS)A4規格(210 X 297公爱) 43 --------------------訂 i·!-------線 (锖先《讀背面之注$項再滇寫本頁) A8B8C8D8 經濟部智慧財產局貝工消费合作杜印製 六、申請專利範圍 :係將含有C : 0.03%以上0.3%以下,Si舆A1之一方 或雙方合計0.5 %以上3.0%以下,及依須含有Mn、Ni 、Cr、Cu、Mo之一種或兩種以上合計'0.5%以上3.5% 以下、更依需含有Nb、Ti、V、P、B、Ca、REM之一 種或兩種以上,且Nb、Ti、V之一種或兩種以上合計0.3 , % 以下,P 0.3% 以下,B 0.01% 以下,Ca 0.0005% 以 / ' ’‘ /· 上0.01%以下,REM : 0.005以上0.05%以下,並其餘 '1 以Fe為主成份之連續鑄造扁鋼胚,以其鑄造原樣直送 熱軋工程,或經冷卻再加熱後予以熱軋,即以Ar3~50 °C〜Ar3+120°C之加工溫度完成熱軋,再繼該熱軋在 冷卻過程經過平均冷卻k度5°C /秒以上冷卻後,以500 °C以下溫度加以繞取熱軋鋼板為特徵,而該熱軋鋼板 之微視組織乃含有肥粒鐵及/或變軔鐵,是一種以其 中任一為主相舆含有髋積分率3〜50%殘留沃斯田鐵之 第3相複合之组織,且其經等效畸變0%以上10%以下 予先變形後再於5X 102〜5X 103(l/s)畸變速度範圍 變形時之3〜10%等效畸變範圍上變形應力平均值 σ dyn(MPa),係可滿足其施加予先變形前在5X10-4〜 5Xl0_3(l/s)畸變速度範圍下測得之靜態拉力試驗之 最大應力TS(MPa)所表示算式σ dyn 2 0.766 X TS + 250 ,並且其畸變1〜5%之加工硬化指數可滿足0.080以上 〇 13.如申請專利範圍第12項之具有高動態變形抵抗之高強 度熱軋鋼板製造方法; 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公爱) 44 -------------0^--------訂ί!-------線ο· (請先閲讀背面之注項再填寫本頁&gt; A8B8C8D8 六、申請專利範圍 係在上述熱軋加工溫度為Ar3-50°C〜Ar3 + 120°C 之溫度範圍,進行其金屬參數:A可滿足下列(1)式及(2) 式之熱軋,而上述金屬參數:A可如下述表示之, Α= ε *Xexp { (75282- 42745 X Ce,)/ C 1.978 X (FT + 273)〕} 但、FT :加工溫度(°C) I 丨' Ceq :碳當量=C + Mneq/6(%) Mneq:鏟當量=Mn+(Ni+Cr+Cu+Mo)/2(%) e ^最後徑道畸變迷度(s·1) ε = (v / yfRxh^ )x (l / Vr )x lw{l /(l— r)} h:最後徑道進乂端板厚 h2 :最後徑道出口端板厚 r : (h!~ h^/h, R :軋輥直徑 v:最後徑道出口側速度 △ T:加工溫度(最後徑道出口端加工溫度)一加 工進入端溫度(第1徑道進入端加工溫度) Ar3 : 901- 325C%+ 33Si%-92Mneq 然後將流出台之平均冷卻速度設於5°C/秒以上, 並以上述金屬參數:A與繞取溫度(CT)之關係可滿足(3) 式之條件加以繞取者。 logA^ 18 (1) △ T221 XlogA-178 (2) CT^6XlogA+312 ........(3) 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) (請先《讀背面之注意事項再填寫本頁) .0^ —----訂----------線 經濟部智慧財產局員工消費合作社印製 45 經濟部智慧財產局貝工消费合作社印製 A8 B8 C8 D8 六、申請專利範圍 —種具有高動態變形抵抗之高強度冷軋鋼板製造方法 :係將含有C : 0,03%以上0.3%以下、Si舆A1之一方 或雙方合計0.5%以上3%以下,及依須含有Mn、Ni、 Cr、Cu、Mo之一種或兩種以上合計0.5%以上3.5%以 下、更依需含有Nb、Ti、V、P、B、Ca、REM之一種 , 或兩種以上,且Nb、Ti、V之一種或兩種以上合計0.3 / /ι %以下 ’ P 0.3% 以下,B 0.01%以下,Ca 0.0005%以 上0.01%以下,REM : 0.005以上0.05%以下,並其餘 以Fe為主成份之連續鑄造扁鋼胚,以其鑄造原樣直送 熱軋工程,或經冷卻再加熱後予以熱軋,且將熱軋後 繞取之熱軋鋼板施以酸’洗冷軋,復經連續退火工程加 以退火製成最後產品時,在0.1X(Ac3 — AcJ + Ac丨。C以 上Ac3+50°C以下溫度退火10秒〜3分鐘後,以1〜,10eC /秒之一次冷卻速度冷卻至550〜720°C範圍之一次冷 卻停止溫度,並繼之以10〜200°C/秒之二次冷卻速度 冷卻至15〇〜45〇°C之二次冷奸停止溫度後,在15〇〜5〇0 t温度保持15秒〜20分鐘再予冷卻至室 該冷軋鋼板之微視組織乃含有肥粒鐵及/或變軔鐵, 是一種以其中任一為主相與含有饉積分率3〜50%殘留 沃斯田鐵之第3相複合之組織,且其經等效畸變0%以 上10%以下、予先變形後再於5X102〜5X 103 (Ι/s)畸 變速度範園變形時之3〜10%等效畸變範圍之變形應 〆 力平均值adyn(MPa)、可滿足其施加予先變形前在5X 10·4〜5X 10_3(l/s)畸變速度範圍測得之靜態拉力試驗 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公釐) 46 --------------------訂 i --------線 (請先閱讀背面之注f項再凑寫本買) A8B8C8D8 經濟部智慧財產局貝工消费合作社印製 六、申請專利範圍 之最大應力TS(MPa)所表示算式σ dyn 2 0.766 X TS + 250、並其畸變1〜5%之加工硬化指數可滿足0.080以 上0 15.如申碲專利範園第14項之具有高動態變形抵抗之高強 度冷軋鋼板製造方法;在上述連續退火工程加以退火 製成產品時,於0.1X(A卩3 — Ac丨)+Ac丨。C以上Ac3+50 eC以下溫度退火10秒〜3分鐘後,以1〜10eC/秒之一 次冷卻速度冷卻至550〜720 eC範園之二次冷卻開始溫 度Tq,繼之以1〇〜200°d/秒之二次冷卻速度冷卻至 由鋼材成份舆退火溫度To所決定之溫度Tem — 100eC以 上Tem以下之二次冷卻终了溫度Te後,於Te — 50°C以 上500eC以下溫度Toa保持15秒〜20分鐘再予冷卻至室 溫為特徵,而該冷軋鋼板之微視组織乃含有肥粒鐵及 /或變韌鐵,是一種以其中任一為主相舆含有髖積分 率3〜50%殘留沃斯田鐵之第3相複合之組織,且其經 等效畸變0%以上10%以下予先變形後再以5X 102〜5 X103 (Ι/s)畸變速度範面變形時之3〜10%等效畸變 範圍之變形應力平均值σ dyn(MPa)、可滿足其施加予 先變形前在5X 10·4〜5X l〇-3(l/s)畸變速度範团測得 之靜態拉力試驗之最大應力TS(MPa)所表示算式σ dyn 2 0.766 XTS + 250、並其畸變1〜5%之加工硬化►指數 可滿足0.080以上。 本紙張尺度適用中國國家標準(CNS)A4規格(210 X 297公龙) 47 ------------ο--------tr---------^ό, (請先《讀背面之注$項再填寫本頁)Sixth, the scope of application for patent No. 86117962 Patent application printed by the Intellectual Property Bureau of the Ministry of Economic Affairs Shellfish Consumer Cooperative Co., Ltd. Amendment This amendment dated June 88 is a high-strength variable steel plate with high dynamic deformation resistance, which is characterized by: The microscopic structure of the steel plate is a third-phase composite structure containing ferrous grain iron and / or altered iron as one of the main phases containing 馑 integral rate of 3 ~ 50% residual Vostian iron. And it is deformed by the equivalent distortion of 0% to 10% before it is deformed and then deformed at 5X 10-2 ~ 5 X 103 (1 / S) _3 ~ 10% of the political distortion range when deforming under the change speed range The average deformation stress σ dyn (MPa) is the maximum stress TS that can meet the static tensile test measured in the range of 5X 10 · 4 ~ 5X 10.3 · (1 / s) distortion speed before it is applied to the first deformation. (MPa) The expression σ dyn 毳 0.766XTS + 250, and the work hardening index of 1 to 5% distortion can satisfy 0.080 or more. 2. For example, the high-strength steel plate with high dynamic deformation resistance in item 1 of the scope of the patent application is characterized in that the value of the work hardening index of the above-mentioned steel plate's yield strength X distortion 1 ~ 5% can satisfy more than 40 "3. The high-strength steel plate with high dynamic deformation resistance is characterized in that the retraction structure of the finally obtained steel plate contains ferrous iron and / or toughened iron, and it is a kind of which contains 为主 integral rate of 3 ~ 50% of the third-phase composite structure of Wastian Iron, and its equivalent distortion of 0% to 10% is deformed first and then deformed in the range of 5X102 ~ 5X103 (i / s) distortion speed. The average deformation stress σ dyn of the equivalent distortion range of ~ 10% can satisfy the residual tensile force measured under the distortion speed range of 5X 10 · 4 ~ 5 X 10 · 3 (1 / s) before the pre-deformation is applied. The expression of the maximum stress TS (MPa) in the test is σ dyng 0.766 × 1. This paper size is in accordance with China National Standard (CNS) A4 (210 X 297 mm) 41 ------------- --------------- Line (Please read the precautions on the back before filling this page) A8B8C8D8 item has high dynamic deformation /, The scope of patent application is TS + 250, and the average solution η of the solid solution [c] and the steel in the above-mentioned residual Vostian iron is determined by the value {M eq = Mn + (Ni + Cr + Cu + Mo) / 2} (M) M = 678-428X [C] A 33Mneq is 70 or more and 250 or less, and its residual Vostian iron 艟 integral rate before its pre-deformation is equal to its residual distortion of 5% after pre-deformation. The difference of the integral rate is the residual Vostian iron ship before the pre-deformation. The integral rate is more than 30%, and the work hardening index of distortion of 1 ~ 5% can be more than 0.080. For example, a high-strength steel sheet with high dynamic deformation resistance according to any one of the scope of application for patents 1 to 3, characterized in that: the average grain size of the residual Vostian iron k is 5 / zm or less, and the residual Voss The ratio of the average grain size of Tiantie to the average grain size of ferrous grains or toughened iron in the main phase is 0.6 or less, and the average grain size of the main phase is 10 kernels or less, preferably 6 仏 mf The next "» 5. If the patent application for any of the high-strength steel plates of i ~ 3, it is characterized by the fact that the points of the above-mentioned steel plates of Asada scattered iron are 3 ~ 30%, and the average crystal grains of the Asada scattered iron The diameter is 10 M m or less, preferably 5 β m or less. 6. A high-strength steel sheet with high dynamic deformation resistance, such as any one of claims 1 to 3, is characterized by: Grain Iron Skeleton points rate is above 40%. 7. If the high-strength steel sheet with high dynamic deformation resistance is in any of the items 1 to 3 of the scope of patent application, it is characterized by: * This paper size is applicable to China National Standard (CNS) A4 (210 X 297 mm) -------------------- Order i! ------- line (Jing first "read the note on the back and then fill in this page) Intellectual Property of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperatives 42 A8B8C8D8 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives, Du printed 6. Scope of Patent Application The above-mentioned steel sheet has a reduction ratio of 85% or less and a tensile strength X total elongation of more than 20,000. 8. The high-strength steel plate with high dynamic deformation resistance according to any of the items i to 3 of the scope of the patent application, characterized in that the above steel plate contains, by weight, C: 0.03% or more and 0.3% or less, and Si and A1. Either one or both parties should be 0.5% to 3.0% in total, and one or both of them should contain Mn, Ni, Cr, Cu, Mo as required, and the total amount should be 0.5% to 3.5%, and the rest shall be Fe. Principal component 09. For example, the high-strength steel plate with high dynamic deformation resistance in item 8 of the scope of patent application is characterized by: 'The above-mentioned steel plate is based on heavy directors and must contain one or two of Nb, Ti, V, and PiB as required Above, among them, ^, 14, and ¥, or two or more of them are 0.3% or less in total, p is 0.3% or less, and B is 0.01% or less. 10. As the patent application scope No. 8 has a high dynamic deformation resistance The high-strength steel sheet is characterized in that the above-mentioned steel sheet further contains Ca: 0.0005% or more and 0.01% or less, and REM: 0.005% or more and 0.05% or less as needed. 11. The high-strength steel plate with high dynamic deformation resistance according to item 9 of the patent application group is characterized in that the above steel plate further contains Ca: 0.0005% or more and 0.01% or less, and REM: 0.005% or more and 0.05 by weight. % the following. 12. —A method for manufacturing high-strength hot-rolled steel plate with high dynamic deformation resistance The paper size is applicable to China National Standard (CNS) A4 (210 X 297 public love) 43 ------------ -------- Order i ·! ------- line (I first read the note on the back of the page and then write this page in Yunnan) A8B8C8D8 Shellfish consumer cooperation of Intellectual Property Bureau of the Ministry of Economic Affairs Scope of patent application: it will contain C: 0.03% or more and 0.3% or less, one or both of Si and A1 total 0.5% or more and 3.0% or less, and one or both of Mn, Ni, Cr, Cu, Mo The above total is 0.5% or more and 3.5% or less, and one or two or more of Nb, Ti, V, P, B, Ca, and REM are contained as required, and one or two or more of Nb, Ti, and V are 0.3 or more in total. Below, P 0.3% or less, B 0.01% or less, Ca 0.0005% to / '' '/ · up to 0.01%, REM: 0.005 to 0.05%, and the remaining' 1 continuous casting flat steel blanks with Fe as the main component Directly send the hot-rolling project as it is, or heat-roll after cooling and heating, that is, complete hot-rolling at the processing temperature of Ar3 ~ 50 ° C ~ Ar3 + 120 ° C, and then continue the hot rolling during the cooling process. After the average cooling is above 5 ° C / sec, the hot-rolled steel sheet is characterized by being coiled at a temperature of 500 ° C or less, and the microstructure of the hot-rolled steel sheet contains ferrous iron and / or modified iron. It is a third-phase composite tissue with any of the main phases containing hip score of 3 ~ 50% residual Vostian iron, and its equivalent distortion is 0% to 10% before being deformed before 5X 102 ~ 5X 103 (l / s) Distortion speed range 3 ~ 10% of the equivalent distortion range during deformation. The mean deformation stress σ dyn (MPa) can satisfy 5X10-4 ~ 5Xl0_3 before it is deformed. (l / s) The maximum stress TS (MPa) in the static tensile test measured under the distortion speed range is expressed by the formula σ dyn 2 0.766 X TS + 250, and the work hardening index of its distortion of 1 ~ 5% can satisfy 0.080 or more. 13. The manufacturing method of high-strength hot-rolled steel sheet with high dynamic deformation resistance, such as item 12 of the scope of patent application; This paper size applies Chinese National Standard (CNS) A4 specification (210 X 297 public love) 44 ------ ------- 0 ^ -------- Order ί! ------- line ο · (Please read the note on the back before filling out this page> A8B8C8D8 VI. Application The scope of the patent is to carry out its metal parameters in the temperature range of the above hot rolling processing temperature from Ar3-50 ° C to Ar3 + 120 ° C: A can meet the following hot rolling of formulas (1) and (2), and the above Metal parameters: A can be expressed as follows: Α = ε * Xexp {(75282- 42745 X Ce,) / C 1.978 X (FT + 273)]}, but FT: processing temperature (° C) I 丨 'Ceq: Carbon equivalent = C + Mneq / 6 (%) Mneq: Shovel equivalent = Mn + (Ni + Cr + Cu + Mo) / 2 (%) e ^ Last path distortion distortion degree (s · 1) ε = (v / yfRxh ^) x (l / Vr) x lw {l / (l— r)} h: the thickness of the end diameter of the final path into the end h2: the thickness of the end diameter of the last path of the exit r: (h! ~ h ^ / h, R : Roller diameter v: Speed at the exit side of the last track △ T: Processing temperature (processing temperature at the exit side of the last track)-Processing entry temperature (processing temperature at the entrance end of the first track) Ar3: 901- 325C% + 33Si%- 92Mneq will then set the average cooling rate of the outflow station at 5 ° C / sec or more, and take the condition that the relationship between the above-mentioned metal parameter: A and the winding temperature (CT) can satisfy the formula (3). logA ^ 18 (1) △ T221 XlogA-178 (2) CT ^ 6XlogA + 312 ........ (3) This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) ( Please read "Notes on the back before filling this page) .0 ^ —---- Order ---------- Printed by the Consumers’ Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 45 Printed by the Industrial and Consumer Cooperatives A8 B8 C8 D8 6. Scope of patent application-a method for manufacturing high-strength cold-rolled steel plates with high dynamic deformation resistance: It will contain one of C: 0,03% or more and 0.3% or less, Siyu A1 or Both parties add 0.5% to 3% in total, and one or two or more kinds of Mn, Ni, Cr, Cu, Mo are required to contain 0.5% to 3.5% in total, and Nb, Ti, V, P, B, and One of Ca, REM, or two or more, and one or two or more of Nb, Ti, and V total 0.3% / /%% or less' P 0.3% or less, B 0.01% or less, Ca 0.0005% or more and 0.01% or less, REM : Above 0.005 and below 0.05%, and the remaining continuous cast flat steel slabs with Fe as the main component are directly sent to the hot rolling project as they are, or they are hot rolled after cooling and heating , And the hot-rolled steel sheet wound after hot rolling is subjected to acid 'washing and cold rolling, and then annealed by continuous annealing process to make the final product, at 0.1X (Ac3 — AcJ + Ac 丨. C above Ac3 + 50 ° After annealing at a temperature below C for 10 seconds to 3 minutes, it is cooled to a primary cooling stop temperature in the range of 550 to 720 ° C at a cooling rate of 1 to 10eC / second, and then twice to 10 to 200 ° C / second. After the cooling rate is cooled to the secondary rapture stop temperature of 15 ~ 45 ° C, it is held at a temperature of 150 ~ 500 t for 15 seconds ~ 20 minutes and then cooled to the room. The microscopic structure of the cold-rolled steel sheet contains Fertilized iron and / or dysprosium iron is a structure in which any one of the main phases is combined with the third phase containing 3 to 50% residual Vostian iron, and the equivalent distortion is more than 0% Below 10%, the deformation should be performed at a distortion speed of 5X102 ~ 5X 103 (Ι / s) before the deformation of Fanyuan's 3 ~ 10% equivalent distortion range. The average deformation force should be adyn (MPa), which can meet its application. Static tensile test measured in the range of 5X 10 · 4 ~ 5X 10_3 (l / s) distortion speed before pre-deformation. The paper size is applicable to China National Standard (CNS) A4. (210 X 297 mm) 46 -------------------- Order i -------- line (please read the note f on the back before making up (Buy and buy) A8B8C8D8 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Shellfish Consumer Cooperatives. 6. The expression of the maximum stress TS (MPa) in the scope of patent application. Σ dyn 2 0.766 X TS + 250, and its distortion of 1 to 5% of the work hardening index Can meet above 0.080 0 15. The method for manufacturing high-strength cold-rolled steel plate with high dynamic deformation resistance as described in item 14 of the patented tellurium patent garden; when the product is annealed in the continuous annealing process described above, the product is produced at 0.1X (A 卩 3 — Ac 丨) + Ac 丨. After annealing at a temperature above C and below Ac3 + 50 eC for 10 seconds to 3 minutes, it is cooled to a secondary cooling start temperature Tq of 550 to 720 eC at a primary cooling rate of 1 to 10 eC / s, followed by 10 to 200 °. The secondary cooling rate of d / s is cooled to a temperature determined by the annealing temperature To of the steel composition Tem — 100eC or more and Tem or less. After the secondary cooling temperature Te, the temperature is maintained at Te — 50 ° C or more and 500eC or less for 15 seconds. It is characterized by cooling to room temperature in ~ 20 minutes, and the microscopic structure of the cold-rolled steel sheet contains ferrous iron and / or toughened iron. It is a kind of which contains a hip score of 3 ~ 50% of the third phase composite structure of Wastfield Iron, and its equivalent distortion of 0% to 10% is first deformed, and then deformed at 5X 102 ~ 5 X103 (Ι / s) distortion rate. The average deformation stress σ dyn (MPa) in the range of 3 ~ 10% equivalent distortion can meet the deformation stress measured at 5X 10 · 4 ~ 5X l0-3 (l / s) before applying the first deformation. Work hardening with the expression σ dyn 2 0.766 XTS + 250 with distortion of 1 ~ 5% by the maximum stress TS (MPa) in static tensile test 0.080 or more. This paper size applies to China National Standard (CNS) A4 (210 X 297 male dragon) 47 ------------ ο -------- tr -------- -^ ό, (Please read the Note $ on the back side before filling out this page)
TW086117962A 1996-11-28 1997-11-28 High strength steels having high impact energy absorption properties and a method for producing the same TW384313B (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP33138096A JPH10158735A (en) 1996-11-28 1996-11-28 Hot-rolled high-strength thin steel sheet for automobiles having excellent collision resistance and formability, and a method for producing the same
JP2829697 1997-01-29
JP22300597A JPH1161326A (en) 1997-08-06 1997-08-06 High-strength steel sheet for automobiles excellent in collision safety and formability and manufacturing method thereof
JP25888797A JP3530355B2 (en) 1997-09-24 1997-09-24 High-strength hot-rolled steel sheet with high dynamic deformation resistance for impact absorption at the time of collision and manufacturing method thereof
JP25883497A JP3530353B2 (en) 1997-09-24 1997-09-24 High-strength cold-rolled steel sheet with high dynamic deformation resistance for impact absorption at the time of collision and manufacturing method thereof

Publications (1)

Publication Number Publication Date
TW384313B true TW384313B (en) 2000-03-11

Family

ID=27521028

Family Applications (1)

Application Number Title Priority Date Filing Date
TW086117962A TW384313B (en) 1996-11-28 1997-11-28 High strength steels having high impact energy absorption properties and a method for producing the same

Country Status (7)

Country Link
EP (2) EP2314730B1 (en)
KR (1) KR100318213B1 (en)
CN (1) CN1078623C (en)
AU (1) AU711873B2 (en)
CA (1) CA2273334C (en)
TW (1) TW384313B (en)
WO (1) WO1998023785A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI450975B (en) * 2011-04-11 2014-09-01 China Steel Corp Process for making cementite grains in pearlite of steel cylindrical or spherical
TWI494237B (en) * 2011-05-12 2015-08-01 Jfe Steel Corp Collision energy absorbing member excellent in impact energy absorbing ability and manufacturing method thereof

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0974677B2 (en) * 1997-01-29 2015-09-23 Nippon Steel & Sumitomo Metal Corporation A method for producing high strength steels having excellent formability and high impact energy absorption properties
JP3039862B1 (en) * 1998-11-10 2000-05-08 川崎製鉄株式会社 Hot-rolled steel sheet for processing with ultra-fine grains
JP4369545B2 (en) 1998-11-30 2009-11-25 新日本製鐵株式会社 Ferritic sheet steel with excellent strain rate dependency and automobile using the same
JP4524850B2 (en) 2000-04-27 2010-08-18 Jfeスチール株式会社 High-tensile cold-rolled steel sheet with excellent ductility and strain age hardening characteristics and method for producing high-tensile cold-rolled steel sheet
FR2830260B1 (en) * 2001-10-03 2007-02-23 Kobe Steel Ltd DOUBLE-PHASE STEEL SHEET WITH EXCELLENT EDGE FORMABILITY BY STRETCHING AND METHOD OF MANUFACTURING THE SAME
JP3840436B2 (en) * 2002-07-12 2006-11-01 株式会社神戸製鋼所 High strength steel plate with excellent workability
JP3764411B2 (en) * 2002-08-20 2006-04-05 株式会社神戸製鋼所 Composite steel sheet with excellent bake hardenability
ATE316157T1 (en) * 2002-09-11 2006-02-15 Thyssenkrupp Steel Ag FERRITIC/MARTENSITIC STEEL WITH HIGH STRENGTH AND VERY FINE STRUCTURE
DE102004025717B9 (en) * 2004-05-26 2011-05-26 Voestalpine Stahl Gmbh High-strength multiphase steel with improved properties
JP4555694B2 (en) * 2005-01-18 2010-10-06 新日本製鐵株式会社 Bake-hardening hot-rolled steel sheet excellent in workability and method for producing the same
DE102005003551B4 (en) * 2005-01-26 2015-01-22 Volkswagen Ag Method for hot forming and hardening a steel sheet
JP4716359B2 (en) * 2005-03-30 2011-07-06 株式会社神戸製鋼所 High strength cold-rolled steel sheet excellent in uniform elongation and method for producing the same
JP5165236B2 (en) * 2006-12-27 2013-03-21 新日鐵住金ステンレス株式会社 Stainless steel plate for structural members with excellent shock absorption characteristics
BR112012024642B1 (en) * 2010-03-29 2018-02-06 Arcelormittal Investigación Y Desarollo Sl STEEL PRODUCT BETTER RESISTANCE TO ATMOSPHERIC CORROSION IN A SALINE ENVIRONMENT AND USE OF A STEEL PRODUCT
WO2011135700A1 (en) * 2010-04-28 2011-11-03 住友金属工業株式会社 Hot rolled dual phase steel sheet having excellent dynamic strength, and method for producing same
BR112013011409A2 (en) * 2010-11-10 2016-08-02 Posco cold rolled / hot rolled high tensile steelmaking process having 590 mpa grade tensile strength, superior functionality and low mechanical property deviation
CN102286696B (en) * 2011-09-02 2013-01-02 北京科技大学 Preparation method of extra-deep drawing dual-phase steel with high plastic strain ratio
CN104755792B (en) * 2012-11-08 2016-08-17 杰富意钢铁株式会社 Impact absorbing member
MX366537B (en) * 2013-04-15 2019-07-12 Jfe Steel Corp High strength hot rolled steel sheet and method for producing same.
CN103481847B (en) * 2013-09-26 2015-09-30 无锡阳工机械制造有限公司 A kind of composite material for automobile buffer beam
CN104789894A (en) * 2015-04-04 2015-07-22 王文姣 Heat treatment method of high-strength automobile bumper and high-strength automobile bumper
ES2818195T5 (en) 2015-12-15 2023-11-30 Tata Steel Ijmuiden Bv High Strength Hot Dip Galvanized Steel Strip
CN105568145B (en) * 2015-12-24 2017-07-18 北京科技大学 A kind of strong dual phase sheet steel of automobile cold-rolled superelevation with decay resistance and preparation method thereof
CN108179364B (en) * 2017-12-28 2019-05-31 钢铁研究总院 A kind of structural alloy steel and preparation method thereof with high impact absorption energy
KR102164078B1 (en) * 2018-12-18 2020-10-13 주식회사 포스코 High strength hot-rolled steel sheet having excellentworkability, and method for manufacturing the same
EP3936628A4 (en) 2019-03-06 2022-10-26 Nippon Steel Corporation Hot rolled steel sheet
CN113383096B (en) 2019-03-06 2022-10-04 日本制铁株式会社 hot rolled steel plate
CN114585759B (en) * 2019-10-11 2023-04-07 杰富意钢铁株式会社 High-strength steel sheet, impact absorbing member, and method for producing high-strength steel sheet
EP4043593B1 (en) * 2019-10-11 2024-05-08 JFE Steel Corporation High strength steel sheet, impact absorbing member, and method for manufacturing high strength steel sheet
WO2021182395A1 (en) 2020-03-11 2021-09-16 日本製鉄株式会社 Hot-rolled steel sheet
CN112795833B (en) * 2020-11-19 2021-12-28 唐山钢铁集团有限责任公司 Production method of 1300 MPa-grade medium-nickel dual-phase steel continuous casting billet
EP4438746A1 (en) 2023-03-27 2024-10-02 Primetals Technologies Austria GmbH Method for directly producing a trip steel strip in a casting-rolling composite installation and a trip steel strip produced by the method
CN117548603B (en) * 2023-10-26 2024-08-06 武汉理工大学 High-performance forging process based on aluminum alloy components

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59219473A (en) 1983-05-26 1984-12-10 Nippon Steel Corp Color etching solution and etching method
EP0295500B2 (en) * 1987-06-03 2003-09-10 Nippon Steel Corporation Hot rolled steel sheet with a high strength and a distinguished formability
JP2952624B2 (en) * 1991-05-30 1999-09-27 新日本製鐵株式会社 High yield ratio type hot rolled high strength steel sheet excellent in formability and spot weldability and its manufacturing method and high yield ratio type hot rolled high strength steel sheet excellent in formability and its manufacturing method
JP3169293B2 (en) * 1993-06-30 2001-05-21 川崎製鉄株式会社 Automotive thin steel sheet excellent in impact resistance and method for producing the same
US5470529A (en) 1994-03-08 1995-11-28 Sumitomo Metal Industries, Ltd. High tensile strength steel sheet having improved formability
JPH07252592A (en) * 1994-03-15 1995-10-03 Nippon Steel Corp Hot rolled high strength steel sheet with excellent formability, low temperature toughness and fatigue characteristics
TW363082B (en) * 1994-04-26 1999-07-01 Nippon Steel Corp Steel sheet having high strength and being suited to deep drawing and process for producing the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI450975B (en) * 2011-04-11 2014-09-01 China Steel Corp Process for making cementite grains in pearlite of steel cylindrical or spherical
TWI494237B (en) * 2011-05-12 2015-08-01 Jfe Steel Corp Collision energy absorbing member excellent in impact energy absorbing ability and manufacturing method thereof

Also Published As

Publication number Publication date
CN1078623C (en) 2002-01-30
AU5067998A (en) 1998-06-22
EP0952235A4 (en) 2003-05-21
KR20000057266A (en) 2000-09-15
EP2314730B1 (en) 2012-03-21
EP0952235B2 (en) 2015-09-30
EP0952235B1 (en) 2011-10-12
EP0952235A1 (en) 1999-10-27
CN1241219A (en) 2000-01-12
EP2314730A1 (en) 2011-04-27
KR100318213B1 (en) 2001-12-22
WO1998023785A1 (en) 1998-06-04
CA2273334C (en) 2006-03-28
AU711873B2 (en) 1999-10-21
CA2273334A1 (en) 1998-06-04

Similar Documents

Publication Publication Date Title
TW384313B (en) High strength steels having high impact energy absorption properties and a method for producing the same
TW426742B (en) Dual-phase type high strength steel sheets having high impact energy absorption properties and a method of producing the same
JP7336144B2 (en) Hot stamping steels, hot stamping processes and hot stamped components
US11920207B2 (en) Cold rolled steel sheet and a method of manufacturing thereof
TWI495734B (en) Method for manufacturing high strength galvanized steel sheet excellent in formability
CN103582714B (en) Vehicle collision energy absorbing member excellent in energy absorbing performance and manufacturing method thereof
JP6182522B2 (en) Hot rolled steel sheet and related manufacturing method
TWI362423B (en) High tensile-strength galvanized steel sheet and process for manufacturing high tensile-strength galvanized steel sheet
JPWO2007015541A1 (en) Hot-rolled steel sheet, cold-rolled steel sheet and methods for producing them
JP3619357B2 (en) High strength steel sheet having high dynamic deformation resistance and manufacturing method thereof
JP6984319B2 (en) Nickel-containing steel sheet for low temperature with excellent toughness and its manufacturing method
CN107557673B (en) High-elongation high-strength hot-rolled pickled steel plate and manufacturing method thereof
CN109207849B (en) High-strength high-plasticity 1000 MPa-grade hot rolled steel plate and preparation method thereof
CN101855379A (en) Fire-resistant steel material excellent in reheat embrittlement resistance and low-temperature toughness of welded heat-affected zone, and manufacturing method thereof
CN108431280A (en) High-yield-ratio high-strength cold-rolled steel sheet and manufacturing method thereof
US20140363694A1 (en) Low density high strength steel and method for producing said steel
CN113215501A (en) Hot-rolled ultra-high strength steel strip product
CN109898017A (en) Cold-rolled dual-phase steel with excellent 1000 MPa-level cold bending performance and production method thereof
JP2004027249A (en) High-strength hot-rolled steel sheet and manufacturing method thereof
JP4577100B2 (en) High tensile hot dip galvanized steel sheet and manufacturing method
CN116179953B (en) A high plastic toughness phosphorus-containing hot-rolled weathering steel plate and a manufacturing method thereof
JP4325508B2 (en) High tensile hot dip galvanized steel sheet and manufacturing method
CN107109579A (en) The high strength galvanized steel plate hot rolled steel plate and its manufacture method having excellent surface quality
JP2009068039A (en) High-strength alloyed-galvanized steel sheet excellent in energy-absorbing characteristics, and production method therefor
CN111465710A (en) High yield ratio type high strength steel sheet and method for manufacturing same

Legal Events

Date Code Title Description
GD4A Issue of patent certificate for granted invention patent