TW357109B - Method of preparing iron oxide catalysts and the use of catalysts prepared therefrom - Google Patents
Method of preparing iron oxide catalysts and the use of catalysts prepared therefromInfo
- Publication number
- TW357109B TW357109B TW085100834A TW85100834A TW357109B TW 357109 B TW357109 B TW 357109B TW 085100834 A TW085100834 A TW 085100834A TW 85100834 A TW85100834 A TW 85100834A TW 357109 B TW357109 B TW 357109B
- Authority
- TW
- Taiwan
- Prior art keywords
- iron oxide
- predoped
- catalysts
- mixture
- preparing iron
- Prior art date
Links
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 title abstract 18
- 239000003054 catalyst Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 abstract 6
- 229910052797 bismuth Inorganic materials 0.000 abstract 2
- 229910052793 cadmium Inorganic materials 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 2
- 229910052802 copper Inorganic materials 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 229910052750 molybdenum Inorganic materials 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 229910052718 tin Inorganic materials 0.000 abstract 2
- 229910052721 tungsten Inorganic materials 0.000 abstract 2
- 229910052720 vanadium Inorganic materials 0.000 abstract 2
- 229910052725 zinc Inorganic materials 0.000 abstract 2
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 229910052788 barium Inorganic materials 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 238000006356 dehydrogenation reaction Methods 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- 229910052741 iridium Inorganic materials 0.000 abstract 1
- 229910052746 lanthanum Inorganic materials 0.000 abstract 1
- 229910052745 lead Inorganic materials 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- -1 rare earths Inorganic materials 0.000 abstract 1
- 229910052702 rhenium Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 229920006395 saturated elastomer Polymers 0.000 abstract 1
- 229910052706 scandium Inorganic materials 0.000 abstract 1
- 229910052709 silver Inorganic materials 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- 229910052713 technetium Inorganic materials 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052727 yttrium Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3332—Catalytic processes with metal oxides or metal sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US35594994A | 1994-12-14 | 1994-12-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW357109B true TW357109B (en) | 1999-05-01 |
Family
ID=23399451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW085100834A TW357109B (en) | 1994-12-14 | 1996-01-24 | Method of preparing iron oxide catalysts and the use of catalysts prepared therefrom |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5962757A (zh) |
| EP (1) | EP0956157B1 (zh) |
| JP (1) | JP4259612B2 (zh) |
| KR (1) | KR100373572B1 (zh) |
| CN (1) | CN1099908C (zh) |
| AU (1) | AU698764B2 (zh) |
| CA (1) | CA2207564C (zh) |
| DE (1) | DE69533409T2 (zh) |
| ES (1) | ES2222468T3 (zh) |
| TW (1) | TW357109B (zh) |
| WO (1) | WO1996018458A1 (zh) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1293531B1 (it) * | 1997-08-01 | 1999-03-01 | Sud Chemie Mt S R L Ex Monteca | Catalizzatori per la deidrogenazione dell'etilbenzene a stirene |
| NO306541B1 (no) * | 1998-03-13 | 1999-11-22 | Norsk Hydro As | Katalysator |
| DE19814080A1 (de) * | 1998-03-30 | 1999-10-07 | Basf Ag | Katalysator zur Dehydrierung von Kohlenwasserstoffen, insbesondere zur Dehydrierung von Ethylbenzol zu Styrol, sowie Verfahren zu seiner Herstellung |
| US6242379B1 (en) | 1998-04-01 | 2001-06-05 | United Catalysts Inc. | Dehydrogenation catalysts |
| US6756339B1 (en) | 1998-04-01 | 2004-06-29 | Sud-Chemie Inc. | Dehydrogenation catalysts |
| US6121498A (en) * | 1998-04-30 | 2000-09-19 | Eastman Chemical Company | Method for producing acetaldehyde from acetic acid |
| US7271126B2 (en) * | 2002-05-15 | 2007-09-18 | Sud-Chemie Inc. | Catalyst for the dehydrogenation of ethyl benzene to STYRENE prepared with a high purity iron precursor |
| US20040194664A1 (en) | 2002-08-05 | 2004-10-07 | Elementis Pigments, Inc. | Low sulfur red iron oxide useful as a catalyst or catalyst component and a process for making low sulfur red iron oxide |
| US20050187191A1 (en) * | 2004-02-20 | 2005-08-25 | Kucera Louis S. | Methods and compositions for the treatment of respiratory syncytial virus |
| DE102004039603A1 (de) * | 2004-08-13 | 2006-02-23 | Basf Ag | Katalysator enthaltend Eisenoxid(e), Alkalimetallverbindung(en) und Ceroxid(e) |
| TW200631934A (en) * | 2004-11-18 | 2006-09-16 | Shell Int Research | An improved process for the manufacture of an alkenyl aromatic compound under low steam-to-oil process conditions |
| EP1827683A1 (en) * | 2004-11-18 | 2007-09-05 | Shell Oil Company | A high activity and high stability iron oxide based dehydrogenation catalyst having a low concentration of titanium and the manufacture and use thereof |
| US20080020175A1 (en) * | 2006-03-02 | 2008-01-24 | Fred Ratel | Nanostructured Indium-Doped Iron Oxide |
| BRPI0806589A2 (pt) * | 2007-01-18 | 2014-05-13 | Shell Int Research | Catalisador, sua preparação e uso. |
| CA2674953A1 (en) * | 2007-01-18 | 2008-07-24 | Shell Internationale Research Maatschappij B.V. | Iron oxide catalyst, its preparation and use in dehydrogenation reactions |
| EP2152412A2 (en) * | 2007-05-03 | 2010-02-17 | Shell Internationale Research Maatschappij B.V. | A catalyst, its preparation and use |
| EP2158036A2 (en) | 2007-05-03 | 2010-03-03 | Shell Internationale Research Maatschappij B.V. | A catalyst, its preparation and use |
| KR100888133B1 (ko) | 2007-10-02 | 2009-03-13 | 에스케이에너지 주식회사 | 4종의 금속성분으로 구성된 다성분계 비스무스몰리브데이트 촉매 제조방법 및 상기촉매를 이용하여1,3-부타디엔을 제조하는 방법 |
| CN101422735B (zh) * | 2007-11-01 | 2010-12-15 | 中国石油天然气股份有限公司 | 一种乙苯脱氢制苯乙烯的催化剂及其制备方法 |
| EP2288583A1 (en) * | 2008-04-09 | 2011-03-02 | Shell Internationale Research Maatschappij B.V. | A method of improving a dehydrogenation process |
| US20100022816A1 (en) * | 2008-07-22 | 2010-01-28 | Fina Technology, Inc. | Dehydrogenation of Methylbutenes to Isoprene |
| US20110245568A1 (en) * | 2008-07-22 | 2011-10-06 | Fina Technology, Inc. | Dehydrogenation Reactions of N-Butene to Butadiene |
| US8524969B2 (en) * | 2008-07-22 | 2013-09-03 | Fina Technology, Inc. | Dehydrogenation reactions of hydrocarbons to alkenes |
| JP5638746B2 (ja) * | 2008-08-20 | 2014-12-10 | 堺化学工業株式会社 | 有機物を熱分解するための触媒と方法と、そのような触媒を製造する方法 |
| JP5422320B2 (ja) * | 2008-09-22 | 2014-02-19 | 地方独立行政法人東京都立産業技術研究センター | 揮発性有機化合物分解用触媒と揮発性有機化合物の分解方法 |
| US20110105818A1 (en) * | 2009-10-31 | 2011-05-05 | Fina Technology, Inc. | Dehydrogenation Catalyst with a Water Gas Shift Co-Catalyst |
| US20110105316A1 (en) * | 2009-10-31 | 2011-05-05 | Fina Technology, Inc. | Mixed Metal Oxide Ingredients for Bulk Metal Oxide Catalysts |
| EP2604590A4 (en) * | 2010-08-12 | 2015-12-16 | Mitsui Chemicals Inc | METHOD FOR PRODUCING UNSATURATED HYDROCARBONS AND DEHYDRATION CATALYST USED IN THIS PROCESS |
| US20150223569A1 (en) * | 2011-05-10 | 2015-08-13 | Edward Arthur Cox | Shoe Lace Apparatus and Locking Mechanism |
| CN102950005A (zh) * | 2011-08-24 | 2013-03-06 | 中国石油化工股份有限公司 | 一种用于甲基乙苯脱氢制备甲基苯乙烯的催化剂及制备方法 |
| CN104105544B (zh) * | 2011-12-22 | 2017-08-08 | 巴斯夫欧洲公司 | 用于烃脱氢的催化剂 |
| CN103693861A (zh) * | 2013-12-11 | 2014-04-02 | 中国科学院合肥物质科学研究院 | Ge掺杂的α相三氧化二铁纳米片阵列薄膜的制备方法 |
| CN105289626B (zh) * | 2014-07-24 | 2017-12-15 | 中国石油化工股份有限公司 | 苯乙烯催化剂和苯乙烯的制备方法 |
| CN105478130B (zh) * | 2014-09-25 | 2018-06-08 | 中国石油化工股份有限公司 | 用于乙苯脱氢制苯乙烯的催化剂 |
| CN106582685B (zh) * | 2015-10-16 | 2019-04-12 | 中国石油化工股份有限公司 | 低温乙苯脱氢催化剂及其制备方法 |
| CN106582683B (zh) * | 2015-10-16 | 2019-08-06 | 中国石油化工股份有限公司 | 低水比乙苯的脱氢催化剂 |
| KR101716170B1 (ko) * | 2015-11-10 | 2017-03-14 | 희성촉매 주식회사 | 안정화 활성금속 복합체를 이용한 직쇄형 경질탄화수소류 탈수소화 촉매 제조방법 |
| MX380006B (es) | 2015-12-11 | 2025-03-11 | Clariant Catalysts Japan Kk | Catalizador de deshidrogenación de compuesto alquilaromático y proceso para producir el mismo, y proceso de deshidrogenación utilizando el mismo. |
| CN107159204A (zh) * | 2017-06-14 | 2017-09-15 | 江苏金洲粮油食品有限公司 | 一种乙苯制苯乙烯的脱氢反应催化剂及其制备方法 |
| CN110681393A (zh) * | 2018-07-06 | 2020-01-14 | 中国石油化工股份有限公司 | 低水比乙苯脱氢催化剂及制备方法和应用 |
| CN110681389A (zh) * | 2018-07-06 | 2020-01-14 | 中国石油化工股份有限公司 | 低钾含量的低水比乙苯脱氢催化剂 |
| CN110681390B (zh) * | 2018-07-06 | 2022-10-11 | 中国石油化工股份有限公司 | 低水比乙苯脱氢催化剂及其制备方法和应用 |
| CN110681391A (zh) * | 2018-07-06 | 2020-01-14 | 中国石油化工股份有限公司 | 低水比乙苯脱氢催化剂及制备方法 |
| CN110681392A (zh) * | 2018-07-06 | 2020-01-14 | 中国石油化工股份有限公司 | 低水比乙苯脱氢催化剂及其制备方法 |
| CA3050795A1 (en) * | 2018-08-03 | 2020-02-03 | Nova Chemicals Corporation | Oxidative dehydrogenation catalysts |
| CN112237921A (zh) * | 2019-07-16 | 2021-01-19 | 中国石油化工股份有限公司 | 低水比高空速乙苯脱氢催化剂及其制备方法 |
| CN112237922A (zh) * | 2019-07-19 | 2021-01-19 | 中国石油化工股份有限公司 | 超低水比乙苯脱氢催化剂及其制备方法 |
| CN112619635B (zh) * | 2019-09-24 | 2023-04-11 | 中国石油化工股份有限公司 | 一种双金属氧化物催化剂及其制备方法和应用 |
Family Cites Families (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3291756A (en) * | 1964-01-09 | 1966-12-13 | Baugh Chemical Company | Catalytic dehydrogenation |
| US3993591A (en) * | 1972-06-21 | 1976-11-23 | Phillips Petroleum Company | Oxidative dehydrogenation process |
| US3870764A (en) * | 1972-06-21 | 1975-03-11 | Phillips Petroleum Co | Oxidative dehydrogenation process |
| US4098723A (en) * | 1977-01-27 | 1978-07-04 | Shell Oil Company | Catalyst for dehydrogenation |
| CA1108114A (en) * | 1977-04-14 | 1981-09-01 | Gregor H. Riesser | Dehydrogenation catalyst |
| IN148558B (zh) * | 1977-04-14 | 1981-04-04 | Shell Int Research | |
| US4565899A (en) * | 1984-12-14 | 1986-01-21 | Mobil Oil Corporation | Iron oxide catalysts containing copper and zinc compounds and process for para-ethyltoluene dehydrogenation |
| US4684619A (en) * | 1985-02-20 | 1987-08-04 | The Dow Chemical Company | Process for making a dehydrogenation catalyst having improved moisture stability |
| FR2617060A1 (fr) * | 1987-06-29 | 1988-12-30 | Shell Int Research | Catalyseur de deshydrogenation, application a la preparation de styrene et styrene ainsi obtenu |
| US4804799A (en) * | 1987-08-28 | 1989-02-14 | The Dow Chemical Company | Dehydrogenation catalyst |
| US5023225A (en) * | 1989-07-21 | 1991-06-11 | United Catalysts Inc. | Dehydrogenation catalyst and process for its preparation |
| IT1248656B (it) * | 1990-05-29 | 1995-01-26 | Mini Ricerca Scient Tecnolog | Processo per la produzione del precursore di un catalizzatore precipitato per la sintesi dell`ammoniaca. |
| US5399541A (en) * | 1991-05-14 | 1995-03-21 | Nippon Shokubai Co., Ltd. | Catalyst for treating wastewater |
| US5171914A (en) * | 1991-08-30 | 1992-12-15 | Shell Oil Company | Dehydrogenation catalyst and process |
| US5376613A (en) * | 1993-05-04 | 1994-12-27 | The Dow Chemical Company | Dehydrogenation catalyst and process for preparing same |
| US5461179A (en) * | 1993-07-07 | 1995-10-24 | Raytheon Engineers & Constructors, Inc. | Regeneration and stabilization of dehydrogenation catalysts |
-
1995
- 1995-12-13 DE DE69533409T patent/DE69533409T2/de not_active Expired - Lifetime
- 1995-12-13 KR KR1019970703996A patent/KR100373572B1/ko not_active Expired - Fee Related
- 1995-12-13 WO PCT/EP1995/005038 patent/WO1996018458A1/en not_active Ceased
- 1995-12-13 CA CA002207564A patent/CA2207564C/en not_active Expired - Fee Related
- 1995-12-13 EP EP95942181A patent/EP0956157B1/en not_active Expired - Lifetime
- 1995-12-13 ES ES95942181T patent/ES2222468T3/es not_active Expired - Lifetime
- 1995-12-13 AU AU43462/96A patent/AU698764B2/en not_active Ceased
- 1995-12-13 CN CN95196766A patent/CN1099908C/zh not_active Expired - Lifetime
- 1995-12-13 JP JP51828796A patent/JP4259612B2/ja not_active Expired - Lifetime
-
1996
- 1996-01-24 TW TW085100834A patent/TW357109B/zh not_active IP Right Cessation
-
1997
- 1997-04-17 US US08/839,841 patent/US5962757A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2222468T3 (es) | 2005-02-01 |
| JP4259612B2 (ja) | 2009-04-30 |
| CN1099908C (zh) | 2003-01-29 |
| AU698764B2 (en) | 1998-11-05 |
| US5962757A (en) | 1999-10-05 |
| CA2207564C (en) | 2007-05-01 |
| EP0956157A1 (en) | 1999-11-17 |
| JP2000507148A (ja) | 2000-06-13 |
| WO1996018458A1 (en) | 1996-06-20 |
| EP0956157B1 (en) | 2004-08-18 |
| AU4346296A (en) | 1996-07-03 |
| CN1244138A (zh) | 2000-02-09 |
| KR100373572B1 (ko) | 2003-04-21 |
| CA2207564A1 (en) | 1996-06-20 |
| DE69533409T2 (de) | 2005-09-01 |
| DE69533409D1 (de) | 2004-09-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Annulment or lapse of patent due to non-payment of fees |