經濟部中央橾準局員工消費合作社印裝 ό!6δ72 Α7 ___Β7 五、發明説明（1 ) 發明部份及背景 本發明係有熔接及相互黏合難以熔化之樹脂物件之方 法。 依據先行技藝之熔接或黏合方法之一，一段電線置於 二樹脂物件之表面部份之間。然後供應電流通過該線，以 融合或熔接二部份一起。然而，經注意到支鍵樹脂分子由 於其立體網構造，分子量相當高。且知道一些樹脂之分子 量極高，故難以迅速及強固熔接一起。克服此問題所提出 之一改進使用一^雙層'結構於樹脂物件上，其中，難以 融合之心層覆蓋以容易融合之表面層。 然而，該^雙層'物件需使用複雜及特殊設計之模子 製造，此極昂貴。而且，需嚴格控制模鑄率及溫度，因而 降低效率共升高生產成本。此雙層|樹脂物件之機械強 度，化學抵抗力，耐熱，及氣候抵抗力亦未盡滿意。 發明概要 故此，本發明之一目的在提供一種用以融合熔接難以 熔化之樹脂物件之方法，該方法設計使此等物件能在有限 之時間內以所需之融合強度相互熔接，可廉價生產具有改 良品質之最後產物。 難以熔化及熔接之樹脂爲：支鏈之聚乙嫌或類似物； 支鍵之聚氯化或聚氟化乙烯；含氟塑膠：聚二個烯丙基酞 酸酯：聚醯亞胺樹脂：Bakelite (―註冊商標）；環氧樹 脂：酚樹脂；胍胺樹脂；二甲苯樹脂：呋喃樹脂；醇酸樹 本紙張尺度適用中國國家標隼（CNS ) A4規格（210X297公釐）_ 4 _ —7 ； 裝 ""訂 ~~ 1111 I 線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消費合作社印製 A7 ________B7 _ 五、發明説明（2 ) 脂：聚氨基甲酸乙酯樹脂；聚馬來酸酯樹脂；蜜胺樹脂； 尿素樹脂；液晶樹脂；及超高聚合物樹脂。 據本發明，此處所提出之方法確使用一融合加速劑， 此破壞或消除融合阻滯劑，俾可熔接難以熔化之樹脂物件 。融合阻滯劑可爲一分子結構本身或其組成部份。例如， 每一樹脂分子中所含之一芳族環或圓形團使分子僵硬，故 稱爲 '"融合阻滯劑# 。阻礙熔接之極高分子量在此亦稱爲 ’融合阻滯劑'。分子間之交聯以及van der Waals鍵 ，諸如分子氫鍵間鍵同樣產生阻滯或阻礙融合之作用。融 合加速劑由水解，醇解，氨解，橫貫酯化作用，氧化，自 由根反應，或類似之化學反應而使此等融合阻滯劑在高溫 上不能作用。樹脂分子之有效大小由於阻滯劑及加速劑間 之此種反應而減小，從而方便熔接，及達成所需之結合強 度。 詳細言之，由本發明之方法消除去交聯或分子間鍵， 或撕裂樹脂分子本身爲較小之分子。 較宜之融合加速劑爲： 無機之氫氧化物類，諸如氫氧化鈉，氫氧化鉀，氫氧 化鋁，及氫氧化鋇； 硫酸及硫酸鹽類，諸如硫酸鋅，硫酸鋁，硫酸胺，硫 酸鈉，及硫酸羥胺： 氯酸及氯化物類，諸如氯化胺及氯化胍： 醋酸及醋酸鹽類，諸如醋酸錳，酸鉛，及醋酸鈷； 羧酸類，其分子式爲： 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 5 T---.------裝------、玎------ii (請先閱讀背面之注意事項再填寫本頁) A7 316872 ___B7_ 五、發明説明（3 ) R — (CO〇H) n，其中 R = H ，Ci—Cis ，η =1 — 4，及此等羧酸之鹽； 擴酸，其分子式爲： R — （S03H)n，其中，R^H'Ca—Cis - η =1 — 4，及此等磺酸之鹽； 磷酸及其鹽； _ 磷酸之酸性酯及其鹽； 硼酸及其鹽； 吡啶及其鹽； 二鉻酸吡啶； 吡啶衍生物，包括4二甲胺吡啶及4吡咯吡啶，此衍 生物或其鹽之一水溶液，一懸乳液，或一微胞懸浮液； 胺，其分子式爲：R_(NH2)n，其中，R = H， C 1 — C 18 * η = 1 — 4 ； 尿素及胍； 氨基醇，其分子式爲：（HO)»— R—(NH2)n ’其中，R = H，Ci_C18 ，m=l — 4，n = l — 4 ，及此等氨基醇之鹽； 醇類，其分子式爲：R — (0H) „，其中，R = H * C ! - C 18 ，n = 16，及此等醇之衍生物： 重氯酸鹽類，諸如重氯酸氨，重氯酸鉀*及重氯酸鋰Printed and printed by the Staff Consumer Cooperative of the Central Department of Economic Affairs of the Ministry of Economic Affairs ό! 6δ72 Α7 ___ Β7 5. Description of the invention (1) Part and background of the invention The present invention is a method of welding and bonding resin objects that are difficult to melt. According to one of the prior art welding or bonding methods, a length of wire is placed between the surface portions of the two resin objects. Then supply current through the wire to fuse or fuse the two parts together. However, it is noted that the branched resin molecule has a relatively high molecular weight due to its three-dimensional network structure. And it is known that some resins have extremely high molecular weight, so it is difficult to weld them together quickly and strongly. One improvement proposed to overcome this problem is to use a double layer structure on the resin object, in which the hard-to-fuse core layer is covered with a surface layer that is easy to fuse. However, the double-layer object needs to be manufactured using a complicated and specially designed mold, which is extremely expensive. Moreover, it is necessary to strictly control the mold casting rate and temperature, thus reducing the efficiency and increasing the production cost. The mechanical strength, chemical resistance, heat resistance, and weather resistance of this double layer | resin object are also not satisfactory. SUMMARY OF THE INVENTION Therefore, an object of the present invention is to provide a method for fusing and welding resin objects that are difficult to melt. The method is designed so that these objects can be welded to each other with a desired fusion strength within a limited time, which can be produced inexpensively. The final product of improved quality. Resins that are difficult to melt and fuse are: branched polyethylene or the like; branched polychlorinated or polyvinyl fluoride; fluoroplastics: polydiallyl phthalate: polyimide resin: Bakelite (―registered trademark); epoxy resins: phenol resins; guanamine resins; xylene resins: furan resins; alkyd tree-based paper standards are applicable to China National Standard Falcon (CNS) A4 specifications (210X297 mm) _ 4 _ — 7; Install " " order ~~ 1111 I line (please read the notes on the back before filling in this page) A7 ________B7 _ printed by the Beigong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economy V. Invention description (2) Fat: poly Urethane resin; polymaleate resin; melamine resin; urea resin; liquid crystal resin; and ultra-high polymer resin. According to the present invention, the method proposed here does use a fusion accelerator, which destroys or eliminates the fusion retarder, so that resin objects that are difficult to melt can be welded. The fusion blocker can be a molecular structure itself or a component thereof. For example, one aromatic ring or circular group contained in each resin molecule makes the molecule stiff, so it is called '" fusion blocker #'. The extremely high molecular weights that impede fusion are also referred to herein as 'fusion inhibitors'. Intermolecular cross-links and van der Waals bonds, such as molecular hydrogen bond bonds, also have the effect of blocking or impeding fusion. Fusion accelerators are not effective at high temperatures due to hydrolysis, alcoholysis, aminolysis, transesterification, oxidation, free radical reaction, or similar chemical reactions. The effective size of the resin molecule is reduced by this reaction between the retarder and the accelerator, thereby facilitating fusion bonding and achieving the desired bonding strength. In detail, the method of the present invention eliminates decrosslinking or intermolecular bonds, or tears the resin molecule itself into smaller molecules. Preferred fusion accelerators are: inorganic hydroxides, such as sodium hydroxide, potassium hydroxide, aluminum hydroxide, and barium hydroxide; sulfuric acid and sulfates, such as zinc sulfate, aluminum sulfate, ammonium sulfate, and sulfuric acid Sodium and hydroxylamine sulfate: chloric acid and chlorides, such as amine chloride and guanidine chloride: acetic acid and acetates, such as manganese acetate, lead acid, and cobalt acetate; carboxylic acids, the molecular formula is: This paper size is applicable China National Standard (CNS) A4 specification (210X297mm) 5 T ---.------ installed ------, 玎 ------ ii (Please read the notes on the back first (Fill in this page) A7 316872 ___B7_ V. Description of the invention (3) R — (CO〇H) n, where R = H, Ci—Cis, η = 1—4, and the salts of these carboxylic acids; acid expansion, which The molecular formula is: R — (S03H) n, where R ^ H'Ca—Cis-η = 1 — 4, and the salts of these sulfonic acids; phosphoric acid and its salts; _ phosphoric acid acid esters and its salts; boric acid and Pyridine and its salts; pyridine dichromate; pyridine derivatives, including 4 dimethylamine pyridine and 4 pyrrolidine, an aqueous solution of this derivative or one of its salts, a suspension , Or a microcell suspension; amine, its molecular formula is: R_ (NH2) n, where R = H, C 1 — C 18 * η = 1 — 4; urea and guanidine; amino alcohol, its molecular formula is: ( HO) »— R— (NH2) n 'where R = H, Ci_C18, m = l — 4, n = l — 4, and the salts of these amino alcohols; alcohols, the molecular formula is: R — (0H ) ", Where R = H * C!-C 18, n = 16, and derivatives of these alcohols: dichlorates, such as ammonia dichlorate, potassium dichlorate * and lithium dichlorate
I 硝酸及硝酸鹽類，諸如硝酸鉍，硝酸鋇，硝酸鉀，硝 酸鈣，硝酸鋁，硝酸氨，硝酸鈷，硝酸鈉，硝酸鐵，硝酸 本紙張尺度適用中國國家標準（CNS ) A4規格（2丨Ο X 297公釐） J— - I I I I I I 訂— I I I 線 (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 經濟部中央標準局員工消費合作社印製 A7 ____B7_ 五、發明説明（4 ) 鉛，硝酸鎳，及硝酸胍： 硝化物類，包括，硝基石蠟，具有分子式：R_ ( N 0 2 ) η ’其中 ’RsH'Ci— C18 » η = 1 - 4 ； 硝化甘油；及苦味酸； 醌類包含：P醌二肟：及P，P，-二苯醒二肟； 烷基過醋酸類，具有分子式：R-（COOOH)n ，其中，RsH'Ci— Ci8 ，n = l- 4;及此等酸之 鹽； 過醋酸及其鹽類； 過氧化氫（成水溶液之形狀）：及 各種有機過氧化物，諸如過氧化酮，過氧化氫，二烷 基過氧化物，二醯基過氧化物，過氧酯類，過氧二碳酸鹽 類，過氧單碳酸鹽類，烷基過氧化物類，及過氧縮酮類， ，其普通之例爲： 2. 5二甲基2. 5雙重（t 丁基過氧）己垸： 2. 5二甲基2 _ 5雙重（t 丁基過氧）己炔_3; 二枯基過氧化物； 二t 丁基過氧化物； t 丁基過氧化氫；及 t 丁基三甲基甲矽烷基過氧化物》 上列過氧化物之每一分子可包含一或二圑一 〇 — 〇 — 。此等過氧化物之任何混合物可用於此處所提之方法中。 構成有機過氧化物之烷基團可包含：任何圓形副團’ 任何支鏈部份，雙或三鍵，芳族副團，任一鹵素，酯副團 本紙張尺度適用中國國家標準（〇奶）八4規格（2丨0'乂297公釐）_7_ ~裝 II I 訂 I I I I 線 (請先閣讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作杜印製 316872 at B7 p— — — 五、發明説明（5 ) ，磷酸鹽或磷化物團，醚或硫醚鍵，氨團，氮或亞硝基團 ，羥基團，硫赶團，硫醯或亞硫醯團，羧或醯基團，肟團 ，醯胺或醯亞胺團，氰或異氰團，胍團，環氧樹脂團，或 任何其他異種元素。過氧化物在熔接期間中分解時應無異 味。爲此，過氧化物之任何分解產物應無味，或應具有低 蒸氣壓力，俾在熔接過程中不會發出任何可感量之蒸氣， 或分解之產物形成無味或不揮發之複合物或類似物。如此 ，構成有機過氧化物之烷基團宜爲：甲基，乙基，丙基及 其異構物，丁基及其異構物，戊基及有異構物，己基及其 異構物，環己基，己醯基，三甲環己基及其異構物，環十 二基及相似之脂族團，苯基，枯基，某基及相似之芬族團 ，聚烷基過氧化物，聚苯乙烯過氧化物，聚丙烯或聚甲基 丙烯過氧化物，醯基過氧化物聚合物或含有過氧化物團之 類似聚合物，此等單體之共聚物，及其任何混合物。可使 用此等過氧化物之任何或任一混合物，而無需任何適當之 添加劑，諸如：二甲丙烯酸乙烯乙二醇；三引丙烯酸三羥 甲丙烷；三烯丙基氰尿酸酯，異氰尿酸酯或類似之氰連酸 酯；硫碘：醌二肟或類似之二肟；胍：N，Ν’苯二馬來 醯亞胺；亞磷；氫醌；咪唑；苯睡唑•·硫化秋蘭姆··胺； 硫脲；氧化鋅；及環氧樹脂化合物。 可與難以熔化之樹脂之分解產物熔混且可與融合加速 劑之攜帶體及其分解產物熔混之其他添加劑包括： 苯醯過氧化物； 鉛，鈣，或鋇之過氧化物； 本紙張尺度適用中國國家標準（CNS ) Α4規格（210 X 297公釐） 。 J. .t.ΐτ (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標隼局員工消費合作社印製 A7 __B7五、發明説明（6 ) 過碘酸鹽，諸如過碘酸鈉： 過錳酸鹽，諸如過錳酸鈉； 過硼酸鹽，諸如過硼酸鈉； 過硫酸鹽，諸如過硫酸鉀，鈉，或鈉； 高聚合物氧化劑，諸如聚吡啶二鉻酸酯； 二氧化物，諸如二氧化錳或鉛； 三氧化鉻，鉻酸鹽，及二鉻酸鹽； 四氧化物，諸如四氧化餓或釕，及其鹽類； 五氧化物，諸如五氧化釩； 磷酸酯，亞磷酸酯，及硫代磷酸酯，諸如二硫代磷酸 烷酯，中，磷酸鹽具有程式：Ri ，R2 . R 3- P Ο 4 ，其中> R 2 ，及R3各爲Ci8H或Cl 羧酸酯，由Ri — (COO — R2)n表示，其中， Ri及尺2爲烷基，各具有1 — 18碳原子，及n = l — 4 ； 由（Rt— COO) n_R2所表示之其他羧酸酯，其 中，Ri及112爲11或烷基，各具有1 — 18碳原子，及 η = 1 — 4 ; 由Ri— ( C0NH — R2) η所表示之羧酸醯胺，其 中，Ri及112爲1^或烷基，各具有1 一 1 8碳原子，及 η = 1 — 4 ； 由（Ri_CONH) R2所表示之其他羧酸酿胺 ，其中，Ri及R2爲11或烷基，各具有1 — 1 8碳原子 ，及 η = 1 — 4 ; 本紙張尺度適用中國國家標準（CNS ) Α4規格（210X297公釐） ~ 一 9 - J.---.-------^------iT------^ (請先閲讀背面之注意事項再填寫本頁) A7 _______B7_ 五、發明説明（7 ) 由（Ri— CO — N — (R3 ) — C0-R2 所表示 之醯亞胺，其中’Ri ，R2 ，及R3爲Η或烷基，各具 有1 — 18碳原子，及η = 1— 4 ; 其他化合物，其分子式爲Ri，R2- C (CN) — Ν = N- C (CN) - R3. R4 ，其中，Ri ，r2 , R 3 ，及R4各爲H或烷基，具有i — i 8碳原子； 偶氮二異丁睛及偶氮二碳醯胺； 碳酸乙酯； 無機化合物或元素，諸如銨礬，砸砂，紅磷，及硫； 及 黏著劑及表面活化劑。 經濟部中央標準局員工消費合作社印製 構成作爲上列之其他添加劑鹽之陽離子可選自以下所 組之群中：鋇，鋰，銨，鈉.鋁，鈷，錳，鐵，鎳，胍， 鋅’鉀’鈣，鉻，鎘，鉑，氫（即質子），鎂，鈦，釩， 銅，羥胺，及類似物。構成作爲該等另外添加劑之有機化 合物之烷基'R 〃可包含：任何圓形副團，任何支鏈部份 ’雙或三鍵，芳族副團，任何齒素，磷酸鹽或磷化物團， 醚或硫代醚鍵，氨基，硝基或亞硝基，羥基，硫赶團，磺 醯基或亞磺醯基，羧基或醯基，肟團，醯胺或亞醯胺團， 氰或異氰團，胍醯團，環氧樹脂團，或任何其他異種元素 。具有—N =—鍵之化合物中之烷基R 1及R 2可與其他 團R3及R4相同，故此種化合物爲圓形結構。 融合加速劑可依以下之方式施加於塑膠物件中，以方 便其熔接。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） 10 經濟部中央標準局貝工消费合作社印製 A 7 __B7______ 五、發明説明（8 ) 在實施此處所提方法之一第一較宜模式中’欲熔接之 塑膠物件之表面先塗以融合加速劑。 在一第二模式中，浸有加速劑之一帶，或保持加速劑 於膠囊狀態中之一管先固定於物件之表面上。 在一第三模式中，在熔接之前或同時，一注射器壓進 加速劑於二物件表面之間。 在一第四模式中，融合加速劑先包含或埋置於一加熱 線之絕緣覆層中。 在一第五模式中，加熱線之絕緣覆層先覆蓋以加速劑 之一表面層。在施加融合加速劑之前，如需要，加速劑可 在水，任何適當之碳氫化物溶劑，酒精，酯或醚，任何適 當之砂酮油或脂中稀釋或乳化。 在本方法之一第六模式中，浸有加速劑之一帶，或裝 有加速劑於膠囊狀態中之一管先固定於用以熔化物件表面 之加熱線之外表面上。 在第二及第六模式中所用之帶或管可由在帶或管模鑄 時，直接散佈加速劑或分佈其微膠囊於帶或管之材料中來 製造》或且，可在帶及管之本身中構製若干管腔，以接受 及保持加速劑。 在使用時，以所述方式加於塑膠物件中之融合加速劑 由於在高溫度上氫解，醇解，銨解，橫貫酯化作用，氧化 ，或根反應，破壞之物件之融合阻滯元素或結構。結果， 樹脂分子之有效分子量降低，以方便熔接，並大爲提高熔 接強度》 本紙乐尺度適用中國國家標準（CNS ) A4規格（2丨0X297公釐）_ ^ T---·------裝------'玎-------^ (請先閱讀背面之注意事項再填寫本頁) 316872 A7 B7 五、發明説明（9 ) 在最宜方式之一中，上列過氧化物包含於欲熔接之塑 膠物件之一中*俾過氧化物分解，以產生原子根。此等根 取走另一塑膠物件之氫原子，從而減少其分子量，且因而 使熔接成爲可能。此一去氫作用產生新化學鍵於塑膠物件 之表面間，從而提高熔接強度。如構成塑膠物件之樹脂設 計含有不飽和化學鍵，則其間會發生交聯，進一步提高熔 接強度。 附圖簡述 圖1爲E F接頭構件之斷面圖，其中應用此處所提之 方法之一實施例； 圖2亦爲E F接頭構件之斷面圖，此等在另一實施例 中熔接； 圖3顯示樹脂所製之一毛細管，其設計爲融合加速劑 在本發明之方法中供應於構件中； 圖4爲圖3所示之毛細管，裝於E F接頭中，顯示電 流尙未供應通過加熱線； 圖5亦爲毛細管之斷面圖，顯示電流供應後之狀態； 圖6爲用於本發明之又另一實施例中之長加熱元件之 透視圖：及 圖7爲用以熔接E F接頭之長加熱元件之斷面圖。 較宜實施例 第一實施例 -12 - -Γ--.------#------tr------^ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） A7 A7 經濟部中央標準局員工消費合作社印製 水 ( 作 爲 融 合 加 速 劑 ) 丁 醇 ( 同 上 ) 丁 基 胺 ( 同 上 ) 2 5 二 甲 基 2 5 雙 重（ 0 t 丁 基 過 氧 ) 己 院 ( 同 上） 4 二 甲 基 氨 基 吡 淀 ( 同 上） 0 過 硼 酸 鈉 ( 同 上 ) 0 氰 尿 酸 三 烯 丙 酯 ( 同 上 ) 0 5份 _____B7 五、發明説明（10) 揉合以下成份，以產生一塗覆樹脂複合物（*份量 =重量份量）： 聚乙烯 1 0 0份 2份 2份 2份 —段加熱線（例如鎳备）塗以此樹脂複合物，俾具有 預定厚度之一覆套。該塗覆線置於一對塑膠物件之間，此 等物件原由樹脂，諸如難以熔化之、交聯〃聚乙烯製造。 供應電流通過該線，以相互融合熔接二物件。 圖1顯示第一實施例之一例。參考編號1標示一對插 座部份之一，此爲一電融合接頭（即EF接頭） 具有。此E F接頭〃爲交聯聚乙烯所製。一加熱元件 2埋置於插座部份1之內周表面中。一段電線3 (諸如鎳 線）由一絕緣覆套4覆蓋，此覆套爲含有融合加速劑之樹 脂所製。該段電線3經摺回並捲繞成套筒形，然後埋置於 插座部份之內表面中。線3之二端伸出接頭插座部份1 ， 俾用作一對端銷。 T · 1^111 I —1T— I I —-^ (請先閱讀背面之注意事項再填寫本頁) 私纸張尺度適用中國國家標準（CNS)A4規格（ 210X297公釐）_ _ ^^6872 at B7 五、發明説明（11) 此一 EF接頭'A 〃可由注入模鑄法製造。一定量之 熔化樹脂（例如聚乙烯）（具有交聯劑於其中）注進於一 模子之模穴中，模穴中先置加熱元件2。另一方面，一管 (例如欲連接於接頭'A 〃之插座部份上之一氣管6 )由 擠出熔化之樹脂（此亦含有交聯劑）通過一模子製成。 氣管6之一端插進接頭〃之插座部份1中，供應 適當強度之電流於延伸通過加熱元件2之電線3中經一特 定之時間。結果，覆蓋於線3上且含有融合加速劑之絕緣 覆套先熔化，然後使氣管6及E F接頭之表面部份 熔化。如此，圖1虛線所包圍之區域融合，樹脂物件6及 之接觸部份相互熔接。 經濟部中央標準局員工消費合作社印製 (請先閱讀背面之注意事項再填寫本頁) 有多種其他方式用以施加融合加速劑於EF接頭 "及氣管6上。例如，一加速劑塗層可構製於套管形加熱 元件2之外及內周面上。或且，一帶，諸如由與絕緣覆套 4相同之樹脂所製之一膠帶可先繞於元件2之周表面上或 氣管6之末端之外周面上。該膠帶無需爲此一融合加速所 製，但應爲普通樹脂所製，而具有一面無黏著劑且塗有融 合加速層。而且融合加速複合物可塗於或另外施加於E F 接頭'之內周面及氣管6之外周面二者上或任一上。 在熔接期間中或之前，可使用注射器注射定量之融合加速 複合物於接觸區域中。由注射器之針所刺穿之一針孔由融 化及其後固化之樹脂封住。觀察孔通常構製通過E F接頭 之壁，俾可目視檢查融合及熔接過程。在此情形，注射器 可方便通過此觀察孔注射。 本紙張尺度適用中國國家標準（CNS)A4規格（210X297公釐）-14 - 經濟部中央標率扃員工消費合作社印裝 A7 B7 五、發明説明（12 ) 在另一實例中，捲繞之裸電線3埋置於E F接頭’A 〃之內周面中，如顯示於圖2，融合加速複合物亦可塗於 或另外施加於EF接頭*A〃之內周面及氣管6之內周面 二者或任一上。或且，含有或塗有融合加速劑之膠帶可捲 繞於接頭內周面及管外周面二者或任—上。在本例中亦可 使用注射器，其方式如上述β 第二實施例 圖3至5概要顯示一第二實施例，其中，使用圖3所 示之一串膠襄。一樹脂毛細管1 〇以液密之方式保持定量 之2. 5二甲基2. 5雙重（t 丁基過氧）己烷（即融合 加速劑）1 2，沿該管之各均勻間隔處具有一串收縮及融 合之壁部份1 3。如此沿該管10之縱長上形成一串"^膠 囊'，且該管與塗有Nichrome (商標）之線1 4 一起捲 繞於一管1 7上》此管爲難以融合之樹脂所製，並具有管 1 0及線1 4繞於其上，此管插進接頭 〃之插座1 5 中，其方式顯示於圖4 »接頭〃亦爲難以熔化之樹脂 所製。 在熔接該等構件時，Nichrom線加熱構件至高溫度， 俾加速劑1 2分解並沸騰。結果，毛細管1 〇膨脹，如顯 示於圖5，且接頭'C"，管17，及線14間所存在之 空隙或罅峰爲膨脹之管所填塞。其後，管i 〇之此等膠囊 由於高溫而破壞，因而，加速劑1 2之分解產物及氣體分 散於欲熔接之構件之接觸表面上。由管1 〇在1 3處收縮 本紙張尺度適用中國國家標準（CNS)A4規格（ 210X297公釐）_ _ —j 1,1 I I I ~~^~~ ^~訂 I I I —.^. (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明（l3 ) 所形成之膠囊具有優點，即即使在接頭之儲存或使 用之期間中，一或一些膠襄破裂，該融合加速劑之漏失亦 甚少，不致對熔接有不利之影響，從而提高連接之可靠性 e 第三實施例 以下成份揉合一起，以產生一塗覆樹脂複合物（|份量# =重量份量）： 2. 5二甲基2.5雙重（t 100份 丁基過氧）己烷（融合加速劑） 胍（同上） 5份 醌（同上） 5份 —定量之沸石（此爲一多孔性礦物粉）浸以此液體複 合物，及如此製備之一塊段插進欲融合熔接之一接頭中。 第四實施例 以下成份揉合一起，以產生一塗覆樹脂複合物（+份量' =重量份量）： 一碳氫化物脂及一矽酮脂之混合物 100份 2. 5二甲基2.5雙重（t 20份 丁基過氧）己烷（融合加速劑） 三羥甲基丙烷（同上） 1份 一段鎳線塗以此複合物，然後插進一接頭中。 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） I.--:------^------1T------^ (請先閲讀背面之注意事項再填寫本頁) -16 - A7 B7 s^〇872 五、發明説明（14 ) 第五實施例 使用2. 5二甲基2. 5雙重（t 丁基過氧）己烷（ 作爲P T 〃稀釋片）塗覆一段加熱鎳線。該段鎳線置 於一對難以熔解之交聯樹脂物件之間，饋送電流通過該線 ，以熔接二者一起。 第六實施例 塗有樹脂之一電線在本實施例中浸以過氧化物，置於 欲熔接之樹脂物件之間。當受加熱時，過氧化物分解並與 樹脂物件起化學反應，從而方便其熔接。 此一樹脂覆蓋材可由一 ''適當#之樹脂或橡膠在大氣 內或氧氣內加熱及熔化揉合，以產生所需之量之過氧化物 及/或過氧化氫。適當之樹脂或橡膠在其分子中具有一不 飽和鍵，諸如一雙鍵，尤其是與一烯丙基共軛之雙鍵，或 具有丙烯或甲基丙烯基。此一樹脂或橡膠通常選自以下所 組之群中：丁二烯樹脂；苯乙烯丁二烯橡膠；丁二烯橡膠 :異戊間二烯橡膠；EPM;EPDM;腈丁二烯橡膠； 氯丁二烯橡膠：丁基橡膠：聚乙烯橡膠；聚異丁烯；香豆 酮樹脂；不飽和聚酯樹脂；呋喃樹脂；石油樹脂，尤其是 環戊二烯基礎者；多羥聚烯羥；馬來樹脂；富馬樹脂；聚 甲丙烯酸醇等。應明瞭如所選之樹脂或橡膠中含有足量之 此等過氧化物或過氧化氫，則無需在大氣或氧氣中加熱及 揉合。亦可由紫外線束照射此原料樹脂或橡膠，或添加含 本紙張尺度適用中國國家標準（CNS ) A4規格（210X297公釐） —4· n n Ίί I I I - - I I (請讀背面之注意事項再填寫本頁) 訂 經濟部中央標準局員工消費合作社印製 經濟部中央標準局員工消費合作社印製 S16872_^_ 五、發明説明（15) 有此過氧化物或過氧化氫之適當之量之化合物於此樹脂或 橡膠中。 該不飽和團可存在於樹脂分子之主鍵或分枝中。上述 之樹脂或橡膠可分子中含有不飽和團之適當之任何化合物 混合。此等化合物包含：油酸酯：硬脂酸脂；月桂酸酯： 聚二丙烯酸乙二醇等。 如需要，可由加進適當之如下物質於樹脂材料中，而 使過氧化氫離子穩定至所需之程度：任何烷基胺；甲基丙 烯酸，其金屬鹽，更宜爲其鎳複合物；2甲基丙烯醯磷酸 乙酯，其金靥鹽，更宜爲其鎳複合物；或二2甲基丙烯氧 磷酸乙酯，其金靥鹽，或更宜爲其鎳複合物。 如上述，含有不飽和鍵之樹脂在空氣中或在氧氣中加 熱，以提供塗有包含過氧化物之材料之一線。 可使用一適當之擠出機，以製造長元件2，其心線先 塗以絕緣覆套3 b。該擠出機用以塗覆一覆蓋樹脂複合物 4於覆套3 b上（先製備），其方式顯示於圖6。 圖7顯示黏合管6之末端於一接頭''D" 之方式。一控制器（未顯示）用以在一初階段中加熱該加 熱元件2之線3至華氏約2 0 0 — 3 0 0度》維持此等構 件於此溫度上數十秒，以熔化樹脂覆蓋物4以及與該覆蓋 物接觸之樹脂物件6及之表面。在此初階段之期間 中，過氧化物及樹脂之複合物4之不飽和鍵各中斷爲根， 此導致樹脂物件表面發生脫氫，在化學上重新結合其分子 。在最後階段，控制器加熱該加熱線2之線3至華氏 —Μ ·1 I I I I 裝1τ— I I ,1 線 {請先閲讀背面之注意事項再填寫本頁) 本紙張尺度適用中國國家標準（CNS ) Α4規格（2丨0Χ297公釐） -18 - 經濟部中央標準局員工消費合作社印製 A7 ___B7_ 五、發明説明（l6 ) 3 0 0 — 3 5 0度，亦保持於此溫度上數十秒。由於此最 後階段之作用，熔化之樹脂分子在其不飽和鍵處進行一些 聚合作用，產生新交聯，從而使熔接強度提高。 在一些情形，樹脂覆蓋物中僅有過氧化物之存在即由 於與之化學反應，足以使難於熔化之樹脂物件融合黏接。 然而，不飽和鍵之共存則較佳，因爲此等產生額外之過氧 化物，此不獨使相鄰構件間之反應更爲可靠，且導致相鄰 樹脂分子間有利之交聯，以提高熔接強度。 電線之樹脂覆蓋物4之表面氧化不足以確保上述之化 學作用（即根反應，脫氫，聚合化，及化學重新結合）。 難以在商業之規模上有效執行此假設之表面處童。爲此， 在本方法中，大量之樹脂塗覆材料接受氧化作用。 過氧化物或過氧化氫及樹脂分子間有化學鍵，故任何 可偵知之有味之危險副產物不會放出至外面，在使用過氧 化氫之情形，僅有小量無毒之水及/或其蒸汽放出外面。 總而言之，加於難以熔化之樹脂物件間所置之樹脂構 件上之融合加速劑破壞其中所含之融合阻滯劑，從而使其 可在短時間中強固熔接。 由於此改良之融合熔接，現可廉價製造改良品質之最 後熔接產物，不能由熔接製造之任何產物現可容易製成》 本紙張尺度適用中國國家標準（CNS ) A4規格（210 X 29"7公釐） —·— I I I I 裝 I I I I 訂 I I I ~~ 線 (請先閲讀背面之注意事項再填寫本頁)I Nitric acid and nitrates, such as bismuth nitrate, barium nitrate, potassium nitrate, calcium nitrate, aluminum nitrate, ammonium nitrate, cobalt nitrate, sodium nitrate, ferric nitrate, nitric acid. The paper standard is applicable to China National Standard (CNS) A4 specification (2丨 Ο X 297mm) J—-IIIIII Order—III line (please read the precautions on the back and then fill out this page) Printed by the Ministry of Economy Central Standards Bureau employee consumer cooperatives Printed by the Ministry of Economic Affairs Central Standards Bureau employee consumer cooperatives A7 ____B7_ 5. Description of the invention (4) Lead, nickel nitrate, and guanidine nitrate: nitrates, including, nitro paraffin, with the molecular formula: R_ (N 0 2) η 'where' RsH'Ci— C18 »η = 1-4 Nitroglycerin; and picric acid; quinones include: P quinone dioxime: and P, P,-diphenyl oxime dioxime; alkyl peracetic acid, with the molecular formula: R- (COOOH) n, where, RsH'Ci — Ci8, n = l-4; and salts of these acids; peracetic acid and its salts; hydrogen peroxide (in the shape of an aqueous solution): and various organic peroxides, such as ketone peroxide, hydrogen peroxide, and two Alkyl peroxide, diacyl peroxide, peroxy Esters, peroxydicarbonates, peroxymonocarbonates, alkyl peroxides, and peroxyketals, the common examples are: 2. 5 dimethyl 2. 5 dual (t Butyl peroxy) hexane: 2. 5 dimethyl 2_5 double (t butyl peroxy) hexyne_3; dicumyl peroxide; di t butyl peroxide; t butyl peroxide Hydrogen; and t-butyltrimethylsilyl peroxide. Each molecule of the peroxide listed above may contain one or two dioxins. Any mixture of these peroxides can be used in the method mentioned here. The alkyl group constituting the organic peroxide may include: any round side group 'any branched part, double or triple bond, aromatic side group, any halogen, ester side group. The paper size is in accordance with Chinese national standards (〇 Milk) 8 4 specifications (2 丨 0 '297 mm) _7_ ~ Install II I to order IIII line (please read the notes on the back of the cabinet before filling in this page) Employee consumption cooperation of Central Standard Falconry Bureau of the Ministry of Economic Affairs Du Printed 316872 at B7 p — — V. Description of the invention (5), phosphate or phosphide group, ether or thioether bond, ammonia group, nitrogen or nitroso group, hydroxyl group, sulfur chalcogenide group, sulfide or sulfite Group, carboxyl or amide group, oxime group, amide or amide group, cyanide or isocyanide group, guanidine group, epoxy group, or any other heterogeneous element. Peroxide should be deodorized when decomposed during welding. For this reason, any decomposition products of peroxides should be odorless, or should have a low vapor pressure, so that no sensible vapors are emitted during the welding process, or the decomposition products form odorless or non-volatile compounds or the like . Thus, the alkyl group constituting the organic peroxide is preferably: methyl, ethyl, propyl and its isomers, butyl and its isomers, pentyl and isomers, hexyl and its isomers , Cyclohexyl, hexyl, trimethylcyclohexyl and its isomers, cyclododecyl and similar aliphatic groups, phenyl, cumyl, a certain group and similar Finn groups, polyalkyl peroxides, Polystyrene peroxide, polypropylene or polymethacrylic peroxide, amide-based peroxide polymers or similar polymers containing peroxide groups, copolymers of these monomers, and any mixtures thereof. Any or any mixture of these peroxides can be used without any suitable additives such as: ethylene glycol dimethacrylate; trimethylolpropane triacrylate; triallyl cyanurate, isocyanide Uric acid ester or similar cyanate ester; sulfur iodide: quinone dioxime or similar dioxime; guanidine: N, N 'benzenedimaleimide; phosphorous; hydroquinone; imidazole; benzazole Sulphur thiuram · amine; thiourea; zinc oxide; and epoxy resin compounds. Other additives that can be melt-mixed with decomposition products of resins that are difficult to melt and that can be melt-mixed with carriers of fusion accelerators and their decomposition products include: benzoyl peroxide; lead, calcium, or barium peroxide; this paper The scale is applicable to China National Standard (CNS) Α4 specification (210 X 297 mm). J. .t.lτ (Please read the precautions on the back before filling in this page) A7 __B7 printed by the Employee Consumer Cooperative of the Central Standard Falcon Bureau of the Ministry of Economic Affairs 5. Description of the invention (6) Periodate, such as sodium periodate: Permanganate, such as sodium permanganate; perborate, such as sodium perborate; persulfate, such as potassium persulfate, sodium, or sodium; high polymer oxidant, such as polypyridine dichromate; dioxide , Such as manganese dioxide or lead; chromium trioxide, chromate, and dichromate; tetraoxides, such as tetroxide or ruthenium, and their salts; pentoxides, such as vanadium pentoxide; phosphate esters, Phosphite, and phosphorothioate, such as alkyl dithiophosphate, in which the phosphate has the formula: Ri, R2. R3-P Ο 4, wherein > R2, and R3 are each Ci8H or Cl carboxyl Acid ester, represented by Ri — (COO — R2) n, where Ri and Chi 2 are alkyl groups, each having 1-18 carbon atoms, and n = 1 — 4; others represented by (Rt—COO) n_R2 Carboxylic acid esters, wherein Ri and 112 are 11 or alkyl groups, each having 1 to 18 carbon atoms, and η = 1 to 4; by Ri— (C0NH — R 2) Carboxamide amides represented by η, where Ri and 112 are 1 ^ or alkyl, each having 1 to 18 carbon atoms, and η = 1 to 4; other carboxylic acids represented by (Ri_CONH) R2 Ammonia, where Ri and R2 are 11 or alkyl, each with 1 to 18 carbon atoms, and η = 1 to 4; this paper scale is applicable to the Chinese National Standard (CNS) Α4 specification (210X297 mm) ~ 1 9 -J .---.------- ^ ------ iT ------ ^ (Please read the precautions on the back before filling in this page) A7 _______B7_ V. Description of invention (7 ) The amide imine represented by (Ri— CO — N — (R3) — C0-R2, where 'Ri, R2, and R3 are Η or alkyl, each having 1-18 carbon atoms, and η = 1— 4; other compounds, whose molecular formula is Ri, R2-C (CN)-Ν = N-C (CN)-R3. R4, wherein Ri, r2, R3, and R4 are each H or alkyl, with i — I 8 carbon atoms; azobisisobutyronitrile and azodicarbonamide; ethyl carbonate; inorganic compounds or elements, such as ammonium alum, sand, red phosphorus, and sulfur; and adhesives and surfactants. Printed composition of the employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs The cations of the other additive salts listed above can be selected from the group consisting of: barium, lithium, ammonium, sodium. Aluminum, cobalt, manganese, iron, nickel, guanidine, zinc 'potassium' calcium, chromium, cadmium, platinum, Hydrogen (ie protons), magnesium, titanium, vanadium, copper, hydroxylamine, and the like. The alkyl group 'R 〃 constituting the organic compound as these additional additives may contain: any round side group, any branched part' double or triple bond, aromatic side group, any dentine, phosphate or phosphide group , Ether or thioether bond, amino, nitro or nitroso, hydroxyl, thiol group, sulfonyl or sulfenyl group, carboxyl or acetyl group, oxime group, amide or amide group, cyano or Isocyanide, guanidine, epoxy, or any other foreign element. The alkyl groups R 1 and R 2 in the compound having a —N = — bond can be the same as the other groups R3 and R4, so this compound has a circular structure. The fusion accelerator can be applied to plastic objects in the following manner to facilitate their fusion. This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 10 Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A 7 __B7______ 5. Description of the invention (8) The first of the methods mentioned here is implemented In the preferred mode, the surface of the plastic object to be welded is first coated with a fusion accelerator. In a second mode, a tube impregnated with an accelerator, or a tube holding the accelerator in a capsule state, is first fixed to the surface of the object. In a third mode, before or at the same time, a syringe presses the accelerator between the surfaces of the two objects. In a fourth mode, the fusion accelerator is first contained or buried in the insulating coating of a heating wire. In a fifth mode, the insulating coating of the heating wire is first covered with a surface layer of accelerator. Prior to application of the fusion accelerator, the accelerator may be diluted or emulsified in water, any suitable hydrocarbon solvent, alcohol, ester or ether, any suitable acetone oil or fat, if necessary. In a sixth mode of this method, a tube impregnated with an accelerator, or a tube filled with an accelerator in a capsule state is first fixed to the outer surface of the heating wire used to melt the surface of the object. The belt or tube used in the second and sixth modes can be manufactured by directly dispersing the accelerator or distributing its microcapsules in the material of the belt or tube during the molding of the belt or tube "or, Construct a number of lumens in itself to receive and maintain the accelerator. In use, the fusion accelerator added to the plastic object in the above-described manner due to hydrogenolysis, alcoholysis, ammonium hydrolysis, transesterification, oxidation, or root reaction at high temperatures, will fuse the fusion-blocking elements of the object或 结构。 Or structure. As a result, the effective molecular weight of the resin molecule is reduced to facilitate welding and greatly improve the welding strength. "The standard of this paper is applicable to the Chinese National Standard (CNS) A4 specification (2 丨 0X297mm) _ ^ T --- · ---- -装 ------ '玎 ------- ^ (Please read the precautions on the back before filling in this page) 316872 A7 B7 V. Description of the invention (9) In one of the most suitable ways, The peroxides listed above are included in one of the plastic objects to be welded * as the peroxide decomposes to create atomic roots. These roots take away the hydrogen atoms of another plastic object, thereby reducing its molecular weight, and thus making welding possible. This dehydrogenation creates new chemical bonds between the surfaces of the plastic objects, thereby improving the welding strength. If the resin design of the plastic object contains unsaturated chemical bonds, cross-linking will occur between them, further improving the welding strength. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a cross-sectional view of an EF joint member, in which an embodiment of the method mentioned herein is applied; FIG. 2 is also a cross-sectional view of an EF joint member, which is welded in another embodiment; Fig. 3 shows a capillary made of resin, which is designed to be supplied with a fusion accelerator in the component of the method of the present invention; Fig. 4 is the capillary shown in Fig. 3, installed in the EF connector, showing that the current is not supplied by heating Figure 5 is also a cross-sectional view of the capillary, showing the state after current supply; Figure 6 is a perspective view of a long heating element used in yet another embodiment of the present invention: and Figure 7 is used to weld EF connector Cross-sectional view of the long heating element. Preferred Embodiment First Embodiment-12--Γ --.------ # ------ tr ------ ^ (Please read the precautions on the back before filling this page) The size of the paper printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs applies the Chinese National Standard (CNS) A4 (210X297 mm) A7 A7 The Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy prints water (as a fusion accelerator) butanol (same as above) ) Butylamine (same as above) 2 5 dimethyl 2 5 double (0 t butyl peroxygen) Heyuan (same as above) 4 dimethylaminopyridin (same as above) 0 Sodium perborate (as above) 0 Triene cyanurate Propyl ester (same as above) 0 5 parts _____B7 5. Description of the invention (10) Knead the following ingredients to produce a coated resin composite (* parts = parts by weight): Polyethylene 10 0 parts 2 parts 2 parts 2 parts -A section of heating wire (such as nickel preparation) coated with this resin compound, so as to have a covering of a predetermined thickness. The coating line is placed between a pair of plastic objects that were originally made of resin, such as hard-to-melt, cross-linked polyethylene. Supply current through the line to fuse the two objects together. FIG. 1 shows an example of the first embodiment. Reference number 1 indicates one of a pair of socket parts. This is an electric fusion connector (ie EF connector). This EF connector is made of cross-linked polyethylene. A heating element 2 is embedded in the inner peripheral surface of the socket part 1. A piece of wire 3 (such as nickel wire) is covered by an insulating sheath 4 made of resin containing a fusion accelerator. This section of electric wire 3 is folded back and wound into a sleeve shape, and then buried in the inner surface of the socket part. The second end of the wire 3 extends out of the connector socket part 1 to serve as a pair of end pins. T · 1 ^ 111 I —1T— II —- ^ (Please read the precautions on the back before filling in this page) The private paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) _ _ ^^ 6872 at B7 5. Description of the invention (11) This EF joint 'A 〃 can be manufactured by injection molding. A certain amount of molten resin (such as polyethylene) (with a cross-linking agent in it) is injected into the cavity of a mold in which the heating element 2 is placed first. On the other hand, a tube (for example, a gas tube 6 to be connected to the socket part of the connector 'A' ') is made by extruding molten resin (this also contains a cross-linking agent) through a die. One end of the air pipe 6 is inserted into the socket part 1 of the connector, and a current of an appropriate strength is supplied to the electric wire 3 extending through the heating element 2 for a specific time. As a result, the insulating sheath covering the wire 3 and containing the fusion accelerator melts first, and then melts the surface part of the air pipe 6 and the EF connector. In this way, the area surrounded by the dotted line in FIG. 1 merges, and the resin object 6 and the contact portion are welded to each other. Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before filling out this page). There are many other ways to apply fusion accelerator to the EF connector " and the trachea 6. For example, an accelerator coating may be constructed on the outer surface and the inner peripheral surface of the sleeve-shaped heating element 2. Or, a tape, such as an adhesive tape made of the same resin as the insulating cover 4, may be wound on the peripheral surface of the element 2 or the outer peripheral surface of the end of the air tube 6 first. This tape does not need to be made for this fusion acceleration, but it should be made of ordinary resin, with one side without adhesive and coated with a fusion acceleration layer. Furthermore, the fusion accelerating compound may be applied to or additionally applied to either or both of the inner peripheral surface of the EF connector 'and the outer peripheral surface of the trachea 6. During or before welding, a syringe can be used to inject a quantitative fusion acceleration compound into the contact area. One of the pinholes pierced by the needle of the syringe is sealed by the melted and subsequently cured resin. The observation hole is usually constructed through the wall of the EF connector, so that the fusion and welding process can be visually checked. In this case, the syringe can be easily injected through this observation hole. This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) -14-Printed by the Ministry of Economic Affairs, Central Standard Staff Consumer Cooperative A7 B7 V. Description of the invention (12) In another example, the winding is naked The electric wire 3 is embedded in the inner peripheral surface of the EF connector 'A 〃, as shown in FIG. 2, the fusion acceleration compound can also be applied or applied to the inner peripheral surface of the EF connector * A 〃 and the inner peripheral surface of the trachea 6 Either or both. Or, the tape containing or coated with the fusion accelerator can be wound on either or both of the inner circumferential surface of the joint and the outer circumferential surface of the pipe. In this example, a syringe can also be used in the same manner as the above-mentioned second embodiment. FIGS. 3 to 5 schematically show a second embodiment, in which a string of glue shown in FIG. 3 is used. A resin capillary 1 〇 The amount of 2.5 dimethyl 2.5 double (t butyl peroxy) hexane (that is, fusion accelerator) 1 2 is maintained in a liquid-tight manner, with uniform intervals along the tube A series of contracted and fused wall parts 1 3. In this way, a series of " ^ capsules " are formed along the longitudinal length of the tube 10, and the tube is wound on a tube 17 together with a line 14 coated with Nichrome (trademark). This tube is made of resin that is difficult to fuse It has a tube 10 and a wire 14 wrapped around it. This tube is inserted into the socket 15 of the connector 〃. The way is shown in Figure 4. The connector 〃 is also made of resin that is difficult to melt. When welding these components, the Nichrom wire heats the components to a high temperature, so that the accelerator 12 decomposes and boils. As a result, the capillary tube 10 expands, as shown in FIG. 5, and the gap or peak existing between the joint 'C ", the tube 17, and the line 14 is filled with the expanded tube. Thereafter, the capsules of the tube i 〇 were destroyed due to high temperature, so that the decomposition products and gas of the accelerator 12 were dispersed on the contact surface of the member to be welded. By shrinking the tube 1 〇 at 13 places, the paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) _ _ —j 1,1 III ~~ ^ ~~ ^ ~ 定 III —. ^. (Please first Read the precautions on the back and then fill out this page) A7 B7 printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. The description of the invention (l3) The capsules formed have the advantage that even during the storage or use period of the joint, Some glue ruptures, and the leakage of the fusion accelerator is also very small, so as not to have an adverse effect on the welding, thereby improving the reliability of the connection. E. Part ## parts by weight): 2.5 dimethyl 2.5 double (t 100 parts butyl peroxy) hexane (fusion accelerator) guanidine (same as above) 5 parts quinone (same as above) 5 parts-quantitative zeolite (this is A porous mineral powder) is impregnated with this liquid compound, and a block prepared in this way is inserted into a joint to be welded. In the fourth embodiment, the following ingredients are kneaded together to produce a coating resin compound (+ parts' = parts by weight): a mixture of a hydrocarbon resin and a silicone resin 100 parts 2.5 dimethyl 2.5 double ( t 20 parts of butylperoxy) hexane (fusion accelerator) trimethylolpropane (same as above) 1 part of a piece of nickel wire coated with this compound, and then inserted into a joint. This paper scale is applicable to China National Standard (CNS) A4 specification (210X297mm) I .--: ------ ^ ------ 1T ------ ^ (Please read the notes on the back first Please fill in this page again) -16-A7 B7 s ^ 〇872 5. Description of the invention (14) The fifth embodiment uses 2.5 dimethyl 2.5 double (t butyl peroxy) hexane (as PT 〃 Diluted tablets) coated with a piece of heated nickel wire. This piece of nickel wire is placed between a pair of cross-linked resin objects that are difficult to melt, and a current is fed through the wire to fuse the two together. Sixth embodiment A wire coated with resin is impregnated with peroxide in this embodiment and placed between resin objects to be welded. When heated, the peroxide decomposes and reacts with the resin object to facilitate its fusion. This resin covering material can be heated and melted by a suitable resin or rubber in the atmosphere or oxygen to produce the required amount of peroxide and / or hydrogen peroxide. Suitable resins or rubbers have an unsaturated bond in their molecules, such as a double bond, especially a double bond conjugated to an allyl group, or have a propylene or methacryl group. This resin or rubber is usually selected from the group consisting of: butadiene resin; styrene butadiene rubber; butadiene rubber: isoprene rubber; EPM; EPDM; nitrile butadiene rubber; chlorine Butadiene rubber: butyl rubber: polyethylene rubber; polyisobutylene; coumarone resin; unsaturated polyester resin; furan resin; petroleum resin, especially those based on cyclopentadiene; polyhydroxypolyene hydroxy; Malay Resin; Fumar resin; polymethacrylate etc. It should be understood that if the selected resin or rubber contains sufficient amounts of these peroxides or hydrogen peroxide, there is no need to heat and knead in the atmosphere or oxygen. This raw resin or rubber can also be irradiated by ultraviolet beam, or added with paper size applicable to China National Standard (CNS) A4 specification (210X297mm) —4 · nn Ίί III--II (Please read the notes on the back and fill in this Page) Printed by the Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperative Printed by the Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperative Printed S16872 _ ^ _ V. Description of Invention (15) Compounds with the appropriate amount of this peroxide or hydrogen peroxide are here In resin or rubber. The unsaturated group may exist in the main bond or branch of the resin molecule. The above-mentioned resin or rubber may be mixed with any suitable compound containing unsaturated groups in the molecule. These compounds include: oleate: stearate; laurate: polyethylene diacrylate, etc. If necessary, the following materials can be added to the resin material to stabilize the hydrogen peroxide ion to the desired level: any alkylamine; methacrylic acid, its metal salt, and more preferably its nickel complex; 2 Ethyl methacrylic acid ethyl phosphate, its gold-tallow salt, is more preferably its nickel complex; or dimethacrylic acid ethyl phosphate, its gold-tallow salt, or more preferably its nickel complex. As described above, the resin containing unsaturated bonds is heated in air or in oxygen to provide a thread coated with a material containing peroxide. An appropriate extruder can be used to manufacture the long element 2 whose core wire is first coated with an insulating sheath 3 b. The extruder is used to coat a covering resin compound 4 on the cover 3 b (prepared first), the method of which is shown in FIG. 6. Fig. 7 shows the way in which the end of the adhesive tube 6 is connected to a joint "D". A controller (not shown) is used to heat the wire 3 of the heating element 2 to approximately 200-300 degrees Fahrenheit in an initial stage. Maintain these components at this temperature for tens of seconds, covered with molten resin The object 4 and the resin object 6 and the surface in contact with the cover. During this initial period, the unsaturated bonds of the composite of peroxide and resin 4 are each broken into roots, which results in dehydrogenation of the surface of the resin object and chemically recombines its molecules. In the final stage, the controller heats the heating wire 2 to 3 degrees Fahrenheit-Μ · 1 IIII installed 1τ-II, 1 line (please read the precautions on the back before filling this page) This paper size is applicable to the Chinese National Standard (CNS ) Α4 specifications (2 丨 0Χ297mm) -18-A7 ___B7_ printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Invention description (l6) 3 0 0 — 3 5 0 degrees, also kept at this temperature for tens of seconds . Due to the effect of this last stage, the molten resin molecules undergo some polymerization at their unsaturated bonds, creating new cross-links, thereby increasing the weld strength. In some cases, the presence of only peroxide in the resin coating is due to the chemical reaction with it, which is sufficient to fuse the resin objects that are difficult to melt. However, the coexistence of unsaturated bonds is preferable because these generate additional peroxides, which not only makes the reaction between adjacent members more reliable, but also leads to favorable cross-linking between adjacent resin molecules to improve the welding strength . The oxidation of the surface of the resin coating 4 of the wire is insufficient to ensure the above-mentioned chemical effects (ie, root reaction, dehydrogenation, polymerization, and chemical recombination). It is difficult to effectively implement this hypothesis on a commercial scale. For this reason, in this method, a large amount of resin coating material receives oxidation. There is a chemical bond between peroxide or hydrogen peroxide and resin molecules, so any detectable odorous dangerous by-products will not be released to the outside. In the case of using hydrogen peroxide, only a small amount of non-toxic water and / or The steam escaped outside. All in all, the fusion accelerator added to the resin member placed between the resin objects that are difficult to melt destroys the fusion retarder contained therein, so that it can be strongly welded in a short time. Due to this improved fusion welding, it is now possible to manufacture final welded products of improved quality at a low cost, and any products that cannot be manufactured by welding can now be easily made. " Ali) — · — IIII Pack IIII Order III ~~ line (please read the precautions on the back before filling this page)