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TW202532661A - Method for manufacturing hot-rolled steel sheet for non-oriented electromagnetic steel sheet and method for manufacturing non-oriented electromagnetic steel sheet - Google Patents

Method for manufacturing hot-rolled steel sheet for non-oriented electromagnetic steel sheet and method for manufacturing non-oriented electromagnetic steel sheet

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Publication number
TW202532661A
TW202532661A TW113150638A TW113150638A TW202532661A TW 202532661 A TW202532661 A TW 202532661A TW 113150638 A TW113150638 A TW 113150638A TW 113150638 A TW113150638 A TW 113150638A TW 202532661 A TW202532661 A TW 202532661A
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hot
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steel sheet
steel
rolled
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TW113150638A
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Chinese (zh)
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丸山茂宏
齋藤勇人
大久保智幸
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日商杰富意鋼鐵股份有限公司
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Publication of TW202532661A publication Critical patent/TW202532661A/en

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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/12Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of articles with special electromagnetic properties
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/60Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Electromagnetism (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacturing Of Steel Electrode Plates (AREA)
  • Soft Magnetic Materials (AREA)

Abstract

Proposed is a method for producing a hot-rolled steel sheet for a non-oriented electromagnetic steel sheet, the hot-rolled steel sheet being excellent in magnetic characteristics. In the method, a thin slab is hot-rolled. This production method comprises: casting molten steel containing, in mass%, C: ≤ 0.010%, Si: 2.50-5.00%, Mn: 0.10-3.00%, P: ≤ 0.100%, S: 0.0010-0.0050%, Al: ≤ 2.00%, N: ≤ 0.0080%, Cu: ≤ 1.00%, Mo: ≤ 0.050%, Zn: ≤ 0.010%, and Ti: ≤ 0.010%, with the balance being Fe and unavoidable impurities, into a steel slab having a prescribed thickness; subsequently heating the steel slab in a tunnel furnace, with the surface temperature of the steel slab at the exit of the tunnel furnace, the heating time in the tunnel furnace, and the cooling rate of the steel slab from the exit of the tunnel furnace to the entrance of the hot-rolling mill being within predetermined ranges; and subjecting the steel slab to hot-rolling, with the entrance temperature, exit temperature, strain rate during the first pass of the hot-rolling, and coil winding temperature for the hot-rolling mill being within predetermined ranges.

Description

無方向性電磁鋼板用熱軋鋼板的製造方法及無方向性電磁鋼板的製造方法Method for manufacturing hot-rolled steel sheet for non-oriented electromagnetic steel sheet and method for manufacturing non-oriented electromagnetic steel sheet

本發明是有關於一種無方向性電磁鋼板用熱軋鋼板的製造方法及無方向性電磁鋼板的製造方法。The present invention relates to a method for manufacturing a hot-rolled steel plate for non-oriented electromagnetic steel and a method for manufacturing non-oriented electromagnetic steel.

無方向性電磁鋼板是用於馬達或發電機的鐵芯的材料。近年來,就CO 2排放量削減的觀點而言,強烈要求電氣機器的高效率化。因此,對於作為鐵芯材料的無方向性電磁鋼板要求進一步的低鐵損化。 Non-oriented electromagnetic steel sheets are used as the core material for motors and generators. In recent years, there has been a strong demand for higher efficiency in electrical equipment to reduce CO2 emissions. Consequently, there is a demand for further reduction in the iron loss of non-oriented electromagnetic steel sheets used as core materials.

對於無方向性電磁鋼板的低鐵損化,有效的是添加Si、Al、Mn等合金元素來增加比電阻,或者將板厚減薄。但是,高合金化及薄板化會導致冷軋製中的軋製負荷增加。因此,存在容易於冷軋製中產生鋼板的斷裂的課題。若將供於冷軋製的熱軋鋼板薄板化,則可降低冷軋製的軋製負荷。於該情況下,存在熱軋製中的軋製負荷增加,形狀控制變困難的課題。Effective methods for reducing the iron loss of non-oriented electromagnetic steel sheets include increasing the specific resistivity by adding alloying elements such as Si, Al, and Mn, or reducing the sheet thickness. However, high alloying and thinning increase the rolling load during cold rolling, making the steel more susceptible to cracking during cold rolling. Thinning the hot-rolled steel sheets used for cold rolling can reduce the cold rolling load. However, this increases the rolling load during hot rolling, making shape control more difficult.

因此,提出了使用較先前更薄的鋼坯(以下,亦稱為薄板坯)來製造無方向性電磁鋼板的方法。於該方法中,使用被稱作薄板坯連鑄機的連續鑄造機製造薄板坯,繼而將該薄板坯供於軋製。藉由將鋼坯的厚度減薄,可降低熱軋製與冷軋製此兩者中的軋製負荷。另外,於使用薄板坯的方法中,亦大多情況下通常藉由將連續鑄造機(薄板坯連鑄機)與熱軋製機直接連結而省略板坯再加熱。於該情況下,可大幅度降低能源成本。Therefore, a method has been proposed for producing non-oriented electromagnetic steel using thinner steel billets (hereinafter referred to as thin slabs) than previously used. In this method, thin slabs are produced using a continuous casting machine called a thin slab mill, which is then rolled. Reducing the thickness of the billet reduces the rolling load during both hot and cold rolling. Furthermore, in many cases, the thin slab method eliminates the need for slab reheating by directly connecting the continuous casting machine (thin slab mill) to the hot rolling mill. This significantly reduces energy costs.

作為使用薄板坯的無方向性電磁鋼板的製造方法,例如可列舉專利文獻1所揭示的方法。於專利文獻1中揭示了如下技術,即,於對厚度為50 mm以上且200 mm以下的鋼坯進行保溫後,實施熱軋製而製成板厚0.4 mm以上且2.0 mm以下的熱軋鋼板的技術。 [現有技術文獻] [專利文獻] An example of a method for producing non-oriented electromagnetic steel using thin slabs is the method disclosed in Patent Document 1. Patent Document 1 discloses a technique for producing hot-rolled steel sheets having a thickness of 0.4 mm to 2.0 mm by holding a slab having a thickness of 50 mm to 200 mm at room temperature. [Prior Art Document] [Patent Document]

專利文獻1:國際公開第2023/095637號說明書Patent Document 1: International Publication No. 2023/095637

[發明所欲解決之課題] 然而,所述各先前技術中存在如以下般的必須解決的課題。 即,於專利文獻1中揭示的方法中,於將鋼坯維持為高溫的狀態下供於熱軋製。因此,存在於熱軋製之前鋼中的析出物無法充分地析出、粗大化,而於熱軋製中微細地析出的情況。而且,存在該微細析出物使鋼組織微細化,使所製造的無方向性電磁鋼板的鐵損增加的問題。 [Problems to be Solved by the Invention] However, each of the aforementioned prior arts presents the following issues that must be addressed. In the method disclosed in Patent Document 1, the steel slab is hot-rolled while being maintained at a high temperature. Consequently, precipitates in the steel prior to hot-rolling may not fully precipitate and coarsen, but instead precipitate finely during hot-rolling. Furthermore, these fine precipitates refine the steel structure, increasing the iron loss of the resulting non-oriented electromagnetic steel sheet.

因此,為解決先前技術所存在的所述課題,本發明具體而言目的在於獲得如下的熱軋鋼板,即,於對薄板坯進行保溫處理並維持在高溫的狀態下,進行熱軋製時抑制了析出物的微細析出的熱軋鋼板。另外,目的在於使用該熱軋鋼板來製造抑制了鐵損增加的無方向性電磁鋼板。 [解決課題之手段] To address the aforementioned issues with the prior art, the present invention specifically aims to provide a hot-rolled steel sheet in which the formation of fine precipitates is suppressed during hot rolling by subjecting a thin slab to a heat-insulating treatment and maintaining it at a high temperature. Furthermore, the present invention aims to use this hot-rolled steel sheet to produce a non-oriented electromagnetic steel sheet with suppressed iron loss. [Means for Solving the Problem]

發明者等人進行了努力研究,結果發現,藉由控制S含量,使熱軋製步驟的諸條件處於適當的範圍,可抑制析出物的微細析出,可抑制使用薄板坯所製造的無方向性電磁鋼板的鐵損的增加。The inventors conducted extensive research and discovered that by controlling the S content and keeping the hot rolling conditions within an appropriate range, the fine precipitation of precipitates can be suppressed, thereby suppressing the increase in iron loss in non-oriented electromagnetic steel sheets produced using thin slabs.

即,有利地解決所述課題的本發明的無方向性電磁鋼板用熱軋鋼板的製造方法包括:保溫步驟,將熔鋼鑄造成厚度30 mm以上且180 mm以下的範圍的鋼坯,繼而於隧道爐中對所述鋼坯進行保溫;以及熱軋製步驟,對所述鋼坯實施熱軋製,所述熔鋼具有如下成分組成,所述成分組成以質量%計含有:C:0.010%以下、Si:2.50%以上且5.00%以下、Mn:0.10%以上且3.00%以下、P:0.100%以下、S:0.0010%以上且0.0050%以下、Al:2.00%以下、N:0.0080%以下、Cu:1.00%以下、Mo:0.050%以下、Zn:0.010%以下、及Ti:0.010%以下,任意選擇地更含有選自以下群組中的至少一群組的元素:A群組為選自Sn:0.20%以下及Sb:0.20%以下中的至少一種;B群組為選自Mg:0.0001%以上且0.10%以下及稀土金屬(rare earth metals,REM):0.0001%以上且0.10%以下中的至少一種;C群組為B:0.002%以上且0.01%以下;D群組為Ni:0.01%以上且1.0%以下;E群組為Cr:0.1%以上且5.0%以下;F群組為選自V:0.001%以上且0.050%以下、Nb:0.001%以上且0.005%以下、Ta:0.0001%以上且0.0020%以下、W:0.001%以上且0.050%以下及Pb:0.0001%以上且0.0020%以下中的至少一種;G群組為Co:0.001%以上且0.100%以下;H群組為選自Ga:0.0005%以上且0.0300%以下及Ge:0.0005%以上且0.0300%以下中的至少一種;及I群組為As:0.001%以上且0.020%以下,剩餘部分包含Fe及不可避免的雜質,所述無方向性電磁鋼板用熱軋鋼板的製造方法的特徵在於,於所述保溫步驟中,將所述隧道爐的入口側處的鋼坯的表面溫度設為850℃以上,將所述隧道爐的出口側處的鋼坯的表面溫度設為1050℃以上且1200℃以下的範圍,將所述隧道爐中的保溫時間設為8 min以上,於所述熱軋製步驟中,於如下條件,即,將自所述隧道爐的出口側至熱軋製機入口側處的鋼坯的冷卻速度設為4℃/s以下、將熱軋製機的入口側溫度設為950℃以上、將熱軋製機的出口側溫度設為800℃以上、將熱軋製的第一道次中的應變速度設為1.5/s以上、線圈捲繞溫度滿足500℃以上的條件下進行。That is, the method for producing a hot-rolled steel plate for non-oriented electromagnetic steel of the present invention, which advantageously solves the above-mentioned problem, comprises: a heat-holding step of casting molten steel into a steel billet having a thickness in the range of 30 mm to 180 mm, and then heat-holding the steel billet in a tunnel furnace; and a hot-rolling step of hot-rolling the steel billet, wherein the molten steel has the following composition, which contains, in mass%, C: 0.010% or less, Si: 2.50% or more and 5.00% or less, Mn: 0.10% or more and 3.00% or less, P: 0.100% or less, S: 0.0010% or more and 0.0050% or less, Al: 2. 00% or less, N: 0.0080% or less, Cu: 1.00% or less, Mo: 0.050% or less, Zn: 0.010% or less, and Ti: 0.010% or less, and optionally further containing at least one element selected from the following groups: Group A is at least one element selected from Sn: 0.20% or less and Sb: 0.20% or less; Group B is at least one element selected from Mg: 0.0001% or more and 0.10% or less and rare earth metals ( Metals (REM): at least one selected from 0.0001% to 0.10%; Group C: B: 0.002% to 0.01%; Group D: Ni: 0.01% to 1.0%; Group E: Cr: 0.1% to 5.0%; Group F: at least one selected from V: 0.001% to 0.050%, Nb: 0.001% to 0.005%, Ta: 0.0001% to 0.0020%, W: 0.001% to 0.050% and Pb: 0.0001% to 0.0020%; Group G: Co: 0.00 1% or more and 0.100% or less; H group is at least one selected from Ga: 0.0005% or more and 0.0300% or less and Ge: 0.0005% or more and 0.0300% or less; and I group is As: 0.001% or more and 0.020% or less, and the remainder contains Fe and inevitable impurities. The manufacturing method of the hot-rolled steel plate for non-oriented electromagnetic steel plate is characterized in that, in the holding step, the surface temperature of the steel billet at the entrance side of the tunnel furnace is set to 850°C or more, the surface temperature of the steel billet at the exit side of the tunnel furnace is set to a range of 1050°C or more and 1200°C or less, and the holding time in the tunnel furnace is set to 8 min or more, and in the hot rolling step, the cooling rate of the steel billet from the outlet side of the tunnel furnace to the inlet side of the hot rolling mill is set to 4°C/s or less, the inlet side temperature of the hot rolling mill is set to 950°C or more, the outlet side temperature of the hot rolling mill is set to 800°C or more, the strain rate in the first pass of hot rolling is set to 1.5/s or more, and the coil winding temperature is met under the conditions of 500°C or more.

再者,本發明的無方向性電磁鋼板用熱軋鋼板的製造方法中更佳的實施形態為將所述熔鋼自電爐或轉爐中出鋼。Furthermore, in a more preferred embodiment of the method for producing a hot-rolled steel plate for non-oriented electromagnetic steel of the present invention, the molten steel is tapped from an electric furnace or a converter.

另外,有利地解決所述課題的本發明的無方向性電磁鋼板的製造方法的特徵在於包括:熱軋鋼板製造步驟,利用所述任一種無方向性電磁鋼板用熱軋鋼板的製造方法製造熱軋鋼板;熱軋板退火步驟,對所述熱軋鋼板實施退火而製成熱軋退火板;冷軋步驟,對所述熱軋退火板實施冷軋製而製成冷軋鋼板;以及精退火步驟,對所述冷軋鋼板實施精退火。 [發明的效果] Furthermore, the method for manufacturing a non-oriented electromagnetic steel sheet of the present invention, which advantageously solves the aforementioned problem, is characterized by comprising: a hot-rolled steel sheet manufacturing step of manufacturing a hot-rolled steel sheet using any of the aforementioned methods for manufacturing a hot-rolled steel sheet for non-oriented electromagnetic steel; a hot-rolled steel sheet annealing step of annealing the hot-rolled steel sheet to produce a hot-rolled annealed steel sheet; a cold-rolling step of cold-rolling the hot-rolled annealed steel sheet to produce a cold-rolled steel sheet; and a finish annealing step of finish annealing the cold-rolled steel sheet. [Effects of the Invention]

藉由本發明,可獲得如下的熱軋鋼板,即,於對薄板坯進行保溫處理並維持在高溫的狀態下,進行熱軋製時抑制了析出物的微細析出的熱軋鋼板。使用該熱軋鋼板,可製造具有良好的磁特性的無方向性電磁鋼板。The present invention provides a hot-rolled steel sheet obtained by hot-rolling a thin slab while maintaining it at a high temperature through a heat treatment process, thereby suppressing the formation of fine precipitates. This hot-rolled steel sheet can be used to produce non-oriented electromagnetic steel sheets with excellent magnetic properties.

於對本發明的實施形態進行說明時,首先對成為開發本發明的契機的實驗進行說明。於以下的說明中,只要未特別提及,則表示化學組成的「%」設為質量基準。 <實驗1> 發明者等人著眼於在鋼中微細地析出並使鐵損增加的MnS的控制,進行了鐵損的測定。將含有C:0.002%、Si:3.00%、Mn:0.50%、P:0.01%、Al:0.50%、N:0.0020%、Cu:0.01%、Mo:0.010%、Zn:0.001%、Ti:0.002%、剩餘部分為Fe及不可避免的雜質的鋼組成設為基礎。將向該些中使S於0.0001%~0.0070%的範圍內變化添加而熔煉的熔鋼鑄造成60 mm厚的鋼坯。繼而於隧道爐中對鋼坯進行1100℃的保溫。然後,於將熱軋製的入口側溫度設為960℃、將熱軋製的第一道次中的應變速度設為5.0/s、線圈捲繞溫度為520℃的條件下製成板厚1.6 mm的熱軋鋼板。繼而,於環境溫度980℃下實施30 s鐘的熱軋板退火。之後,進行冷軋製而製成板厚0.30 mm的冷軋鋼板,最後,於以vol%比計為H 2:N 2=25:75的乾燥環境下,於溫度960℃下實施10 s鐘的精退火。自由此獲得的鋼板的軋製方向與板寬方向切出寬度:30 mm×長度:280 mm的愛波斯坦(Epstein)樣品,並利用愛波斯坦試驗器測定鐵損W 10/400Before describing the embodiments of the present invention, we will first describe the experiments that led to its development. In the following description, "%" representing chemical compositions is based on mass unless otherwise specified. <Experiment 1> The inventors focused on controlling MnS, which precipitates finely in steel and increases steel losses, and measured steel losses. A basic steel composition was used: 0.002% C, 3.00% Si, 0.50% Mn, 0.01% P, 0.50% Al, 0.0020% N, 0.01% Cu, 0.010% Mo, 0.001% Zn, 0.002% Ti, with the remainder being Fe and unavoidable impurities. The molten steel, to which S was added in varying amounts ranging from 0.0001% to 0.0070%, was cast into 60 mm thick ingots. The ingots were then held at 1100°C in a tunnel furnace. They were then hot-rolled into 1.6 mm thick plates at a 960°C inlet temperature, a 5.0/s strain rate in the first hot-rolling pass, and a 520°C coiling temperature. The plates were then annealed at an ambient temperature of 980°C for 30 seconds. Afterwards, the steel was cold-rolled to produce 0.30 mm thick cold-rolled steel plates. Finally, a finish annealing process was performed at 960°C for 10 seconds in a dry atmosphere with a vol% H₂ : N₂ ratio of 25:75. Epstein specimens measuring 30 mm wide by 280 mm long were cut from the resulting steel plates in both the rolling and width directions, and the steel loss (W 10/400) was measured using an Epstein tester.

圖1中示出鋼板中的S含量與鐵損W 10/400的關係。根據圖1明確,藉由將S含量控制為0.0010%~0.0050%的範圍內而鐵損減少。另外,利用光學顯微鏡觀察到的鋼板的結晶粒徑於鐵損減少的範圍內粗大化。 Figure 1 shows the relationship between the S content in steel sheets and the iron loss (W 10/400) . As shown in Figure 1, iron loss is reduced by controlling the S content within the range of 0.0010% to 0.0050%. Furthermore, the grain size of the steel sheets observed with an optical microscope coarsens within the range where iron loss is reduced.

根據所述實驗結果,發明者等人推斷S於所述範圍內時抑制了由析出物引起的晶粒生長性降低的影響。具體而言,於S未滿0.0010%的情況下,由於析出的MnS的個數少,因此TiN或TiC等析出溫度低於MnS的析出物無法以MnS為核進行析出。因此,該些析出物微細地分散,晶粒生長性降低。於S超過0.0050%的情況下,MnS的個數增加,使晶粒生長性降低。Based on these experimental results, the inventors speculate that when the S content is within the stated range, the effects of precipitates on grain growth degradation are suppressed. Specifically, when the S content is less than 0.0010%, the number of precipitated MnS is small. Therefore, precipitates such as TiN and TiC, which have a lower precipitation temperature than MnS, cannot precipitate using MnS as nuclei. As a result, these precipitates are finely dispersed, reducing grain growth. When the S content exceeds 0.0050%, the number of MnS increases, reducing grain growth.

<實驗2> 鑒於所述結果,藉由對熱軋製步驟中的條件進行控制,使析出物粗大地析出,降低微細的析出物,因此對必要的條件進行了研究。將含有C:0.002%、Si:3.00%、Mn:0.50%、P:0.01%、Al:0.50%、N:0.0020%、Cu:0.01%、Mo:0.010%、Zn:0.001%、Ti:0.002%、S:0.0020%、剩餘部分為Fe及不可避免的雜質的鋼組成設為基礎。然後,將熔煉的熔鋼鑄造成60 mm厚的鋼坯。繼而於隧道爐中對鋼坯進行1100℃的保溫。然後,於使熱軋製的入口側溫度於875℃~1025℃的範圍內變化、將熱軋製的第一道次中的應變速度設為5.0/s、線圈捲繞溫度為520℃的條件下製成板厚1.6 mm的熱軋鋼板。對所獲得的熱軋鋼板實施與實驗1同樣的程序並測定了鐵損。 <Experiment 2> Based on the above results, we investigated the necessary conditions for controlling the hot rolling process to achieve coarse precipitates and reduce fine precipitates. A steel composition containing 0.002% C, 3.00% Si, 0.50% Mn, 0.01% P, 0.50% Al, 0.0020% N, 0.01% Cu, 0.010% Mo, 0.001% Zn, 0.002% Ti, 0.0020% S, with the remainder being Fe and unavoidable impurities, was used as a base. The molten steel was then cast into 60 mm thick billets. The billets were then held at 1100°C in a tunnel furnace. Next, hot-rolled steel plates with a thickness of 1.6 mm were produced under the following conditions: the hot-rolling inlet temperature was varied between 875°C and 1025°C, the strain rate in the first hot-rolling pass was set to 5.0/s, and the coil winding temperature was set to 520°C. The resulting hot-rolled steel plates were subjected to the same procedures as in Experiment 1, and the steel loss was measured.

圖2中示出熱軋製的入口側溫度與鐵損W 10/400的關係。根據圖2,若熱軋製的入口側溫度低於950℃,則鐵損增加。發明者等人推斷這是因為於軋製時導入應變,因此析出物析出的驅動力大,若鋼板的溫度低則TiN或TiC等析出物與MnS同時析出,並微細地分散。另外,推斷若鋼板的溫度低,則析出物的晶粒生長亦被抑制,析出物變微細。 Figure 2 shows the relationship between the hot rolling inlet temperature and the steel loss (W 10/400) . Figure 2 shows that steel loss increases when the hot rolling inlet temperature is below 950°C. The inventors speculate that this is because the strain introduced during rolling increases the driving force for precipitate formation. Low steel plate temperatures cause precipitates such as TiN and TiC to precipitate simultaneously with MnS and become finely dispersed. Furthermore, it is speculated that low steel plate temperatures also suppress precipitate grain growth, resulting in finer precipitates.

<實驗3> 接下來,對熱軋製的第一道次中的應變速度對析出物的形態造成的影響進行研究。將含有C:0.002%、Si:3.00%、Mn:0.50%、P:0.01%、Al:0.50%、N:0.0020%、Cu:0.01%、Mo:0.010%、Zn:0.001%、Ti:0.002%、S:0.0020%、剩餘部分為Fe及不可避免的雜質的鋼組成設為基礎。然後,將熔煉的熔鋼鑄造成60 mm厚的鋼坯。繼而於隧道爐中在1100℃下對鋼坯進行保溫。然後,於將熱軋製的入口側溫度設為960℃、使熱軋製的第一道次中的應變速度於0.2/s~4.2/s的範圍內變化、線圈捲繞溫度為520℃的條件下製成板厚1.6 mm的熱軋鋼板。對所獲得的熱軋鋼板實施與實驗1同樣的程序並測定了鐵損。 <Experiment 3> Next, we investigated the effect of strain rate on the morphology of precipitates during the first pass of hot rolling. A steel composition containing 0.002% C, 3.00% Si, 0.50% Mn, 0.01% P, 0.50% Al, 0.0020% N, 0.01% Cu, 0.010% Mo, 0.001% Zn, 0.002% Ti, 0.0020% S, with the remainder being Fe and unavoidable impurities, was used as a base. The molten steel was then cast into 60 mm thick billets. These billets were then held at 1100°C in a tunnel furnace. Next, hot-rolled steel sheets with a thickness of 1.6 mm were produced at a hot-rolling inlet temperature of 960°C, a strain rate in the first hot-rolling pass varying from 0.2/s to 4.2/s, and a coil winding temperature of 520°C. The same procedures as in Experiment 1 were applied to the resulting hot-rolled steel sheets, and steel loss was measured.

圖3中示出熱軋製的第一道次中的應變速度與鐵損W 10/400的關係。根據圖3,若使熱軋製的第一道次中的應變速度未滿1.5/s,則鐵損增加。發明者等人推斷,於應變速度低的情況下,析出的驅動力變小,因此於熱軋製的第一道次中MnS不充分地析出,於軋製溫度低的後級道次中析出,因此TiN或TiC等微細析出物無法於MnS的周圍析出。 Figure 3 shows the relationship between the strain rate in the first pass of hot rolling and the steel loss (W 10/400 ). Figure 3 shows that if the strain rate in the first pass of hot rolling is less than 1.5/s, the steel loss increases. The inventors speculate that at low strain rates, the driving force for precipitation decreases, resulting in insufficient precipitation of MnS in the first pass of hot rolling. Precipitation occurs in later passes at lower rolling temperatures, preventing fine precipitates such as TiN and TiC from precipitating around the MnS.

根據所述實驗1~實驗3的結果可知,即便於使用薄板坯連鑄機的情況下,藉由將S含量設為0.0010%以上且0.0050%以下,將熱軋製的入口側溫度設為950℃以上,且將熱軋製的第一道次中的應變速度設為1.5/s,亦可抑制鐵損增加。本發明是基於所述見解的發明。以下,對用於實施本發明的形態進行具體說明。再者,本發明並不限定於該實施形態。The results of Experiments 1 to 3 demonstrate that even when using a thin slab continuous casting machine, by setting the S content to 0.0010% to 0.0050%, setting the hot rolling inlet temperature to 950°C or higher, and setting the strain rate in the first hot rolling pass to 1.5/s, the increase in steel loss can be suppressed. The present invention is based on this finding. The following describes a specific embodiment of the present invention. However, the present invention is not limited to this embodiment.

<成分組成> 對本實施形態中的熔鋼的成分組成的限定理由進行說明。再者,所鑄造的薄板坯亦具有與熔鋼同等的成分組成。 <Composition> The following explains the reasons for limiting the composition of the molten steel in this embodiment. The cast thin slab also has the same composition as the molten steel.

C:0.010%以下 C是於製品板中引起磁時效而形成碳化物從而使鐵損劣化的有害元素。因此,於本實施形態中,為了抑制所述磁時效,將C含量設為0.010%以下。較佳為C含量為0.005%以下。再者,下限並無特別規定,但就抑制脫碳成本的觀點而言,C含量的下限較佳為設為0.0001%左右。 C: 0.010% or less C is a harmful element that causes magnetic aging in the finished steel sheet, forming carbides and degrading the steel. Therefore, in this embodiment, to suppress magnetic aging, the C content is set to 0.010% or less. A C content of 0.005% or less is preferred. While there is no specific lower limit, from the perspective of reducing decarburization costs, the lower limit of the C content is preferably set to approximately 0.0001%.

Si:2.50%以上且5.00%以下 為了提高鋼板的電阻、充分降低鐵損而需要添加2.50%以上的Si。因此,於本實施形態中Si含量設為2.50%以上。另一方面,若Si含量設為超過5.00%,則軋製變困難。因此,Si含量設為5.00%以下。再者,就製造性的觀點而言,Si含量較佳為4.00%以下。 Si: 2.50% or more and 5.00% or less To increase the electrical resistance of the steel sheet and sufficiently reduce iron loss, it is necessary to add 2.50% or more of Si. Therefore, in this embodiment, the Si content is set to 2.50% or more. On the other hand, if the Si content exceeds 5.00%, rolling becomes difficult. Therefore, the Si content is set to 5.00% or less. Furthermore, from the perspective of manufacturability, the Si content is preferably 4.00% or less.

Mn:0.10%以上且3.00%以下 Mn與Si、Al同樣地具有提高鋼板的電阻、降低鐵損的效果。因此,於本實施形態中Mn含量設為0.10%以上。另一方面,若Mn含量超過3.00%,則Mn碳化物析出,鐵損反而惡化。因此,Mn含量設為3.00%以下。較佳為0.20%以上且1.00%以下的範圍。 Mn: 0.10% or more to 3.00% or less Mn, like Si and Al, increases the electrical resistance of the steel sheet and reduces steel damage. Therefore, in this embodiment, the Mn content is set to 0.10% or more. On the other hand, if the Mn content exceeds 3.00%, Mn carbides precipitate, worsening steel damage. Therefore, the Mn content is set to 3.00% or less. A range of 0.20% or more to 1.00% is preferred.

P:0.100%以下 P具有提高鋼的強度的效果,可用於強度調整。另一方面,若P含量超過0.100%,則鋼會脆化,導致製造性降低。因此,P含量設為0.100%以下。再者,下限並無特別規定,但就抑制脫P成本的觀點而言,較佳為將P含量設為0.001%以上。另外,就提高P的添加效果的觀點而言,更佳為設為0.005%以上,進而佳為設為0.010%以上。 P: 0.100% or less P increases the strength of steel and is used for strength adjustment. However, if the P content exceeds 0.100%, the steel becomes brittle, reducing manufacturability. Therefore, the P content is kept to 0.100% or less. While there is no specific lower limit, a P content of 0.001% or more is preferred to reduce P removal costs. Furthermore, to enhance the effectiveness of P addition, a P content of 0.005% or more is more preferred, and 0.010% or more is even more preferred.

S:0.0010%以上且0.0050%以下 S於鋼中主要以MnS的形式存在,可與TiC或TiN等單獨析出時會對磁特性造成不良影響的析出物複合析出而實現無害化。因此,於本實施形態中S含量設為0.0010%以上。另一方面,若S含量超過0.0050%,則MnS的析出量增加,阻礙晶粒生長,增加鐵損。因此,S含量設為0.0050%以下。較佳為S含量為0.0010%以上且0.0040%以下。 S: 0.0010% or more and 0.0050% or less S exists primarily in the form of MnS in steel. It can be detoxified by complex precipitation with precipitates such as TiC and TiN, which would adversely affect magnetic properties if precipitated alone. Therefore, in this embodiment, the S content is set to 0.0010% or more. On the other hand, if the S content exceeds 0.0050%, the amount of MnS precipitation increases, hindering grain growth and increasing iron damage. Therefore, the S content is set to 0.0050% or less. A S content of 0.0010% or more and 0.0040% or less is preferred.

Al:2.00%以下 Al與Si同樣地具有提高鋼板的電阻、降低鐵損的效果。然而,若Al含量超過2.00%,則軋製變困難。因此,Al含量設為2.00%以下。就使鑄造性良好的觀點而言,較佳為將Al含量設為1.50%以下。另一方面,對Al含量的下限並未限定,但就鐵損與製造性的平衡的觀點而言,Al含量較佳為0.20%以上,更佳為0.30%以上,進而佳為0.50%以上。 Al: 2.00% or less Like Si, Al has the effect of increasing the electrical resistance of steel sheets and reducing iron loss. However, if the Al content exceeds 2.00%, rolling becomes difficult. Therefore, the Al content is set to 2.00% or less. To ensure good castability, the Al content is preferably set to 1.50% or less. While there is no specific lower limit for the Al content, from the perspective of balancing iron loss and manufacturability, the Al content is preferably 0.20% or more, more preferably 0.30% or more, and even more preferably 0.50% or more.

N:0.0080%以下 N是形成微細的氮化物而阻礙晶粒生長、使鐵損增加的有害元素,因此較佳為儘量降低。特別是若N含量超過0.0080%,則所述不良影響變顯著,因此N含量設為0.0080%以下。較佳為0.0030%以下。另一方面,就鐵損的觀點而言,N含量越低越好,因此N含量的下限並無限定,可為0%。但是,N是作為雜質而不可避免地混入至鋼中的元素,過度的降低會導致製造成本的增加。因此,就成本的觀點而言,較佳為將N含量設為0.0001%以上,更佳為設為0.0005%以上。 N: 0.0080% or less N is a harmful element that forms fine nitrides, inhibiting grain growth and increasing steel loss, so it is best to minimize its content. In particular, if the N content exceeds 0.0080%, these adverse effects become significant. Therefore, the N content should be kept to 0.0080% or less. A content of 0.0030% or less is preferred. On the other hand, from the perspective of steel loss, the lower the N content, the better. Therefore, the lower limit of the N content is not specific and can be 0%. However, N is an element that inevitably enters the steel as an impurity, and excessive reduction in N content can lead to increased manufacturing costs. Therefore, from a cost perspective, the N content is preferably kept to 0.0001% or more, and more preferably to 0.0005% or more.

Cu:1.00%以下 Cu是具有提高鋼板的磁通密度的效果的元素。但是,若Cu含量超過1.00%,則會引起熱脆性,成為表面缺陷的原因。因此,於添加Cu的情況下,將Cu含量設為1.00%以下。就磁特性與成本的平衡的觀點而言,Cu含量較佳為設為0.1%以下。另一方面,對Cu含量的下限並未限定,但就提高Cu的添加效果的觀點而言,較佳為將Cu含量設為0.01%以上。 Cu: 1.00% or less Cu is an element that increases the magnetic flux density of steel sheets. However, if the Cu content exceeds 1.00%, it can cause hot brittleness and surface defects. Therefore, when adding Cu, the Cu content should be kept to 1.00% or less. From the perspective of balancing magnetic properties and cost, the Cu content is preferably set to 0.1% or less. While there is no lower limit for the Cu content, a Cu content of 0.01% or more is preferred to maximize the effect of Cu addition.

Mo:0.050%以下 Mo與C反應而於晶界形成碳化物,具有提高強度的效果。但是,若Mo含量超過0.050%,則有鐵損增加的傾向,因此於添加Mo的情況下,將Mo含量設為0.050%以下。另一方面,對Mo含量的下限並未限定,但就強度的觀點而言,較佳為將Mo含量設為0.010%以上。 Mo: 0.050% or less Mo reacts with carbon to form carbides at grain boundaries, which improves strength. However, if the Mo content exceeds 0.050%, iron losses tend to increase. Therefore, when adding Mo, the Mo content should be kept to 0.050% or less. While there is no lower limit for the Mo content, a Mo content of 0.010% or more is preferred from the perspective of strength.

Zn:0.010%以下 Zn與S反應而形成粗大的硫化物,具有抑制MnS等微細的硫化物的析出、降低鐵損的效果。但是,若超過0.010%,則所述硫化物的量增加,反而阻礙晶粒生長而使鐵損增加。因此,Zn含量設為0.010%以下。另一方面,對Zn含量的下限並未限定,但就鐵損降低的觀點而言,較佳為將Zn含量設為0.001%以上。 Zn: 0.010% or less Zn reacts with sulfur to form coarse sulfides, which inhibit the precipitation of fine sulfides such as MnS and reduce steel damage. However, if the content exceeds 0.010%, the amount of these sulfides increases, hindering grain growth and increasing steel damage. Therefore, the Zn content is set to 0.010% or less. While there is no lower limit for the Zn content, a Zn content of 0.001% or more is preferred from the perspective of reducing steel damage.

Ti:0.010%以下 Ti與C或N反應而於晶界形成碳化物及氮化物,因此與Mo同樣地具有提高強度的效果。但是,若Ti含量超過0.010%,則所述碳化物及氮化物的量增加,反而阻礙晶粒生長而使鐵損增加。因此,Ti含量設為0.010%以下。另一方面,對Ti含量的下限並未限定,但就強度的觀點而言,較佳為將Ti含量設為0.002%以上。 Ti: 0.010% or less Ti reacts with carbon or nitrogen to form carbides and nitrides at grain boundaries, thus increasing strength, similar to Mo. However, if the Ti content exceeds 0.010%, the amount of these carbides and nitrides increases, hindering grain growth and increasing steel loss. Therefore, the Ti content is kept to 0.010% or less. While there is no lower limit for the Ti content, a Ti content of 0.002% or more is preferred from the perspective of strength.

於本實施形態中,所述熔鋼具有如下成分組成,所述成分組成含有C:0.010%以下、Si:2.50%以上且5.00%以下、Mn:0.10%以上且3.00%以下、P:0.100%以下、S:0.0010%以上且0.0050%以下、Al:2.00%以下、N:0.0080%以下、Cu:1.00%以下、Mo:0.050%以下、Zn:0.010%以下、及Ti:0.010%以下,剩餘部分包含Fe及不可避免的雜質。In the present embodiment, the molten steel has a composition comprising C: 0.010% or less, Si: 2.50% to 5.00%, Mn: 0.10% to 3.00%, P: 0.100% or less, S: 0.0010% to 0.0050%, Al: 2.00% or less, N: 0.0080% or less, Cu: 1.00% or less, Mo: 0.050% or less, Zn: 0.010% or less, and Ti: 0.010% or less, with the remainder consisting of Fe and inevitable impurities.

於本實施形態中,所述熔鋼的成分組成亦可任意選擇地更含有選自下述A群組~I群組中的至少一群組的元素。In this embodiment, the composition of the molten steel may optionally further contain elements from at least one group selected from the following Groups A to I.

A群組為選自Sn:0.20%以下及Sb:0.20%以下中的至少一種 Sn:0.20%以下 Sn是具有抑制表層的氮化或氧化、降低鐵損的效果的元素。但是,即便添加超過0.20%,則效果亦會飽和,因此於添加Sn的情況下,較佳為將Sn含量設為0.20%以下,更佳為設為0.10%以下。另一方面,就提高所述效果的觀點而言,較佳為將Sn含量設為0.005%以上。 Group A is at least one selected from Sn: 0.20% or less and Sb: 0.20% or less. Sn: 0.20% or less Sn is an element that inhibits nitridation or oxidation of the surface layer and reduces steel damage. However, even if added in amounts exceeding 0.20%, the effect is saturated. Therefore, when adding Sn, it is preferably kept to 0.20% or less, more preferably 0.10% or less. On the other hand, to enhance the aforementioned effect, a Sn content of 0.005% or more is preferred.

Sb:0.20%以下 Sb是具有抑制表層的氮化、氧化、降低鐵損的效果的元素。但是,即便添加超過0.20%,則效果亦會飽和,因此於添加Sb的情況下,較佳為將Sb含量設為0.20%以下,更佳為設為0.10%以下。另一方面,就提高所述效果的觀點而言,較佳為將Sb含量設為0.005%以上。 Sb: 0.20% or less Sb is an element that inhibits nitridation and oxidation of the surface layer and reduces steel damage. However, even if added in amounts exceeding 0.20%, these effects are saturated. Therefore, when adding Sb, the Sb content is preferably kept to 0.20% or less, more preferably 0.10% or less. On the other hand, to enhance these effects, an Sb content of 0.005% or more is preferred.

B群組為選自Mg:0.0001%以上且0.10%以下及REM:0.0001%以上且0.10%以下中的至少一種 Mg:0.0001%以上且0.10%以下 Mg是以硫化物的形式對S進行固定,有助於鐵損降低的元素。為了獲得此種效果,Mg含量設為0.0001%以上即可。另一方面,若Mg超過0.10%,則效果會飽和,徒然地導致成本上升,因此將上限設為0.10%。因此,Mg較佳為於0.0001%以上且0.10%以下的範圍內含有。 Group B is at least one element selected from Mg: 0.0001% to 0.10% and REM: 0.0001% to 0.10% Mg: 0.0001% to 0.10% Mg is an element that helps reduce iron losses by fixing sulfur in the form of sulfides. To achieve this effect, the Mg content should be 0.0001% or higher. On the other hand, if the Mg content exceeds 0.10%, the effect is saturated, resulting in unnecessary cost increases. Therefore, the upper limit is set to 0.10%. Therefore, the Mg content is preferably within the range of 0.0001% to 0.10%.

REM:0.0001%以上且0.10%以下 REM(稀土金屬元素)是以硫化物的形式對S進行固定,有助於鐵損降低的元素群組。為了獲得此種效果,REM含量設為0.0001%以上即可。另一方面,若REM含量超過0.10%,則效果會飽和,徒然地導致成本上升,因此將上限設為0.10%。因此,REM含量較佳為0.0001%以上且0.10%以下的範圍。所謂REM是Sc、Y及鑭系元素17元素的總稱。 REM: 0.0001% or more and 0.10% or less REM (rare earth metals) are a group of elements that help reduce iron losses by fixing sulfur in the form of sulfides. To achieve this effect, the REM content should be at least 0.0001%. On the other hand, if the REM content exceeds 0.10%, the effect is saturated, resulting in unnecessary cost increases. Therefore, the upper limit is set at 0.10%. Therefore, the REM content is preferably within the range of 0.0001% or more and 0.10% or less. REM is a general term for Sc, Y, and the 17 elements of the lanthanide series.

C群組為B:0.002%以上且0.01%以下 B於鋼中形成微細的碳化物,具有提高鋼板強度的效果。為了獲得此種效果,只要將B含量設為0.002%以上即可。另一方面,若B含量超過0.01%,則過度地形成碳化物而鐵損劣化,因此將上限設為0.01%。因此,B含量較佳為0.002%以上且0.01%以下的範圍。 Group C: B: 0.002% or more to 0.01% or less B forms fine carbides in steel, increasing the strength of the steel sheet. To achieve this effect, a B content of 0.002% or more is sufficient. On the other hand, if the B content exceeds 0.01%, excessive carbides form, causing steel damage and deterioration. Therefore, the upper limit is set at 0.01%. Therefore, the B content is preferably within the range of 0.002% or more to 0.01% or less.

D群組為Ni:0.01%以上且1.0%以下 Ni是提高鋼的韌性的元素,可適宜添加。為了獲得此種效果,只要將Ni含量設為0.01%以上即可。但是,若Ni含量超過1.0%,則效果會飽和,因此將Ni含量的上限設為1.0%。因此,Ni含量較佳為0.01%以上且1.0%以下的範圍。 D Group: Ni: 0.01% or more to 1.0% or less Nitride is an element that improves the toughness of steel and can be added as needed. To achieve this effect, the Ni content only needs to be at least 0.01%. However, if the Ni content exceeds 1.0%, the effect is saturated, so the upper limit of the Ni content is set at 1.0%. Therefore, the Ni content is preferably within the range of 0.01% or more to 1.0%.

E群組為Cr:0.1%以上且5.0%以下 Cr具有提高鋼的固有電阻、降低鐵損的效果。為了獲得此種效果,只要將Cr含量設為0.1%以上即可。另一方面,若Cr含量超過5.0%,則伴隨飽和磁通密度的降低,磁通密度顯著降低,因此將上限設為5.0%。因此,Cr含量較佳為0.1%以上且5.0%以下的範圍。 Group E: Cr: 0.1% or more to 5.0% or less Cr increases the intrinsic resistivity of steel and reduces iron loss. To achieve this effect, a Cr content of 0.1% or more is sufficient. On the other hand, a Cr content exceeding 5.0% significantly reduces the saturated magnetic flux density, leading to a significant decrease in magnetic flux density. Therefore, the upper limit is set at 5.0%. Therefore, the Cr content is preferably within the range of 0.1% to 5.0%.

F群組為選自V:0.001%以上且0.050%以下、Nb:0.001%以上且0.005%以下、Ta:0.0001%以上且0.0020%以下、W:0.001%以上且0.050%以下及Pb:0.0001%以上且0.0020%以下中的至少一種 V:0.001%以上且0.050%以下 V是具有提高鋼板的強度的效果的元素,可適宜添加。為了獲得此種效果,V含量設為0.001%以上即可。但是,若V含量超過0.050%,則於鋼板中微細的析出物析出而使鐵損增加,因此將V含量的上限設為0.050%。 The F group is at least one element selected from V: 0.001% to 0.050%, Nb: 0.001% to 0.005%, Ta: 0.0001% to 0.0020%, W: 0.001% to 0.050%, and Pb: 0.0001% to 0.0020%. V: 0.001% to 0.050%. V is an element that increases the strength of the steel sheet and can be added as appropriate. To achieve this effect, the V content should be 0.001% or more. However, if the V content exceeds 0.050%, fine precipitates will form in the steel sheet, increasing iron losses. Therefore, the upper limit of the V content is set to 0.050%.

Nb:0.001%以上且0.005%以下 Nb是具有提高鋼板的強度的效果的元素,可適宜添加。為了獲得此種效果,Nb含量設為0.001%以上即可。但是,若Nb含量超過0.005%,則於鋼板中微細的析出物析出而使鐵損增加,因此將Nb含量的上限設為0.005%。 Nb: 0.001% or more and 0.005% or less Nb is an element that increases the strength of steel sheets and can be added as needed. To achieve this effect, the Nb content should be at least 0.001%. However, if the Nb content exceeds 0.005%, fine precipitates will form in the steel sheet, increasing iron losses. Therefore, the upper limit of the Nb content is set at 0.005%.

Ta:0.0001%以上且0.0020%以下 Ta是具有提高鋼板的強度的效果的元素,可適宜添加。為了獲得此種效果,Ta含量設為0.0001%以上即可。但是,若Ta含量超過0.0020%,則於鋼板中微細的析出物析出而使鐵損增加,因此將Ta含量的上限設為0.0020%。 Ta: 0.0001% or more and 0.0020% or less Ta is an element that increases the strength of steel sheets and can be added as needed. To achieve this effect, the Ta content should be at least 0.0001%. However, if the Ta content exceeds 0.0020%, fine precipitates will form in the steel sheet, increasing iron losses. Therefore, the upper limit of the Ta content is set at 0.0020%.

W:0.001%以上且0.050%以下 W是具有提高鋼板的強度的效果的元素,可適宜添加。為了獲得此種效果,W含量設為0.001%以上即可。但是,若W含量超過0.050%,則於鋼板中微細的析出物析出而使鐵損增加,因此將W含量的上限設為0.050%。 W: 0.001% or more and 0.050% or less W is an element that increases the strength of steel sheets and can be added as needed. To achieve this effect, the W content should be at least 0.001%. However, if the W content exceeds 0.050%, fine precipitates will form in the steel sheet, increasing iron losses. Therefore, the upper limit of the W content is set at 0.050%.

Pb:0.0001%以上且0.0020%以下 Pb是具有提高鋼板的強度的效果的元素,可適宜添加。為了獲得此種效果,Pb含量設為0.0001%以上即可。但是,若Pb含量超過0.0020%,則於鋼板中微細的析出物析出而使鐵損增加,因此將Pb含量的上限設為0.0020%。 Pb: 0.0001% or more and 0.0020% or less Pb is an element that increases the strength of steel sheets and can be added as needed. To achieve this effect, the Pb content should be at least 0.0001%. However, if the Pb content exceeds 0.0020%, fine precipitates will form in the steel sheet, increasing iron losses. Therefore, the upper limit of the Pb content is set at 0.0020%.

G群組為Co:0.001%以上且0.100%以下 Co是具有提高鋼板的磁通密度的效果的元素,可適宜添加。為了獲得此種效果,Co含量設為0.001%以上即可。但是,若大量添加Co,則合金成本增加,因此將Co含量的上限設為0.100%。 Group G: Co: 0.001% or more to 0.100% or less Co is an element that increases the magnetic flux density of steel sheets and can be added as needed. To achieve this effect, the Co content should be at least 0.001%. However, adding large amounts of Co increases alloy costs, so the upper limit is set at 0.100%.

H群組為選自Ga:0.0005%以上且0.0300%以下及Ge:0.0005%以上且0.0300%以下中的至少一種 Ga:0.0005%以上且0.0300%以下 Ga是具有改善鋼板的織構、提高磁通密度的效果的元素,可適宜添加。為了獲得此種效果,Ga含量設為0.0005%以上即可。但是,若大量添加Ga,則不僅效果會飽和,而且合金成本增加,因此將Ga含量的上限設為0.0300%。 Group H is at least one selected from Ga: 0.0005% to 0.0300% and Ge: 0.0005% to 0.0300% Ga: 0.0005% to 0.0300% Ga is an element that improves the steel sheet's texture and increases magnetic flux density, and can be added as appropriate. To achieve these effects, the Ga content should be at least 0.0005%. However, adding large amounts of Ga not only diminishes the effect but also increases alloy costs. Therefore, the upper limit of the Ga content is set at 0.0300%.

Ge:0.0005%以上且0.0300%以下 Ge是具有改善鋼板的織構、提高磁通密度的效果的元素,可適宜添加。為了獲得此種效果,Ge含量設為0.0005%以上即可。但是,若大量添加Ge,則不僅效果會飽和,而且合金成本增加,因此將Ge含量的上限設為0.0300%。 Ge: 0.0005% or more to 0.0300% or less Ge is an element that improves the steel sheet's structure and increases magnetic flux density, making it a suitable addition. To achieve these effects, the Ge content should be at least 0.0005%. However, adding large amounts of Ge diminishes the effect and increases alloy costs, so the upper limit of the Ge content is set at 0.0300%.

I群組為As:0.001%以上且0.020%以下 As是具有提高鋼板的強度的效果的元素,可適宜添加。為了獲得此種效果,As含量設為0.001%以上即可。但是,若As含量超過0.020%,則於冷軋製中斷裂的風險增高。因此,將As含量的上限設為0.020%。 Group I: As: 0.001% or more and 0.020% or less As is an element that increases the strength of steel sheets and can be added appropriately. To achieve this effect, the As content should be at least 0.001%. However, if the As content exceeds 0.020%, the risk of cracking during cold rolling increases. Therefore, the upper limit of the As content is set at 0.020%.

再者,作為不可避免的雜質,例如包含O(氧)等,容許包含0.0050%左右。所述元素中低於有效地作用的適合範圍的含量不會對製品的磁特性產生影響,因此作為不可避免的雜質被容許。Furthermore, unavoidable impurities such as O (oxygen) are permitted up to 0.0050%. Contents below the effective range for these elements do not affect the magnetic properties of the product and are therefore permitted as unavoidable impurities.

[無方向性電磁鋼板用熱軋鋼板的製造條件] 接下來,對使用具有所述成分組成的熔鋼來製造無方向性電磁鋼板用熱軋鋼板時的製造條件進行說明。 [Manufacturing Conditions for Hot-Rolled Steel Sheets for Non-Oriented Electromagnetic Steel] Next, we will explain the manufacturing conditions for hot-rolled steel sheets for non-oriented electromagnetic steel sheets using molten steel having the aforementioned composition.

本實施形態的無方向性電磁鋼板用熱軋鋼板的製造方法包括:保溫步驟,將具有所述成分組成的熔鋼鑄造成厚度30 mm以上且180 mm以下的範圍的鋼坯,繼而於隧道爐中進行保溫;以及熱軋製步驟,實施熱軋製。而且,於保溫步驟中,將隧道爐的入口側處的鋼坯的表面溫度設為850℃以上,將隧道爐的出口側處的鋼坯的表面溫度設為1050℃以上且1200℃以下的範圍。將隧道爐中的保溫時間設為8 min以上,將自隧道爐的出口側至熱軋製機入口側處的鋼坯的冷卻速度設為4℃/s以下。於熱軋製步驟中,於如下條件,即,將熱軋製機的入口側溫度設為950℃以上、將熱軋製機的出口側溫度設為800℃以上、將熱軋製的第一道次中的應變速度設為1.5/s以上、線圈捲繞溫度滿足500℃以上的條件下製造熱軋鋼板。The method for producing hot-rolled steel for non-oriented electromagnetic steel according to this embodiment includes: a holding step of casting molten steel having the aforementioned composition into a billet having a thickness ranging from 30 mm to 180 mm, followed by holding the billet in a tunnel furnace; and a hot rolling step of hot rolling. During the holding step, the billet surface temperature at the tunnel furnace entrance is set to 850°C or higher, and the billet surface temperature at the tunnel furnace exit is set to 1050°C to 1200°C or lower. The holding time in the tunnel furnace is set to 8 minutes or longer, and the cooling rate of the billet from the tunnel furnace exit to the hot rolling mill entrance is set to 4°C/s or lower. In the hot rolling step, the hot rolled steel sheet is manufactured under the following conditions: the inlet side temperature of the hot rolling machine is set to 950°C or higher, the outlet side temperature of the hot rolling machine is set to 800°C or higher, the strain rate in the first pass of hot rolling is set to 1.5/s or higher, and the coil winding temperature is met under the conditions of 500°C or higher.

[熔鋼熔煉步驟] 對熔鋼的成分調整方法並未特別限定,可利用任意的方法進行。例如,於熔鋼的成分調整時可使用轉爐、電爐、真空脫氣裝置、及其他裝置與方法。較佳為將熔鋼自轉爐或電爐出鋼。例如,若將還原鐵或廢料於電爐中熔解並熔煉,則有助於CO 2排放量的削減,因此較佳。 [Molten Steel Melting Step] The method for adjusting the composition of the molten steel is not particularly limited and may be performed using any method. For example, a rotary furnace, electric furnace, vacuum degassing equipment, or other equipment and methods may be used to adjust the composition of the molten steel. It is preferred to tap the molten steel from a rotary furnace or electric furnace. For example, melting and smelting reduced iron or scrap in an electric furnace is preferred because it contributes to reducing CO2 emissions.

[連續鑄造步驟] 繼而,對成分調整後的熔鋼進行連續鑄造來製造鋼坯。進行連續鑄造的方法並無特別限定,可按照常規方法來進行。 [Continuous Casting Step] The molten steel, after adjusting its composition, is then continuously cast to produce a steel billet. The continuous casting method is not particularly limited and can be performed using conventional methods.

鋼坯的厚度:30 mm以上且180 mm以下 於所述連續鑄造步驟中,製造厚度為30 mm以上且180 mm以下的鋼坯。若鋼坯的厚度未滿30 mm,則相對於板坯體積而言的表面積變大,鋼坯的冷卻速度變快。藉此,於熱軋製步驟中無法確保鋼坯的溫度。因此,將鋼坯的厚度設為30 mm以上。另一方面,若鋼坯的厚度超過180 mm,則熱軋製步驟中的軋製負荷增大。藉此,增加鋼帶的斷裂風險。因此,鋼坯的厚度設為180 mm以下。 Billet Thickness: 30 mm or more and 180 mm or less In the continuous casting step, billets with a thickness of 30 mm or more and 180 mm or less are produced. If the billet thickness is less than 30 mm, the surface area relative to the slab volume increases, resulting in a faster cooling rate. Consequently, the billet temperature cannot be maintained during the hot rolling step. Therefore, the billet thickness is set to 30 mm or more. On the other hand, if the billet thickness exceeds 180 mm, the rolling load during the hot rolling step increases, thereby increasing the risk of steel strip fracture. Therefore, the billet thickness is set to 180 mm or less.

[搬運步驟] 接下來,將於所述連續鑄造步驟中製造的鋼坯搬運至用於保溫處理的隧道爐。於搬運步驟中,重要的是於將鋼坯的表面溫度維持為850℃以上的狀態下搬運至隧道爐的入口側。換言之,於本實施形態中自於連續鑄造步驟中製造至到達爐的期間鋼坯的表面溫度不會未滿850℃地進行搬運。若鋼坯的表面溫度未滿850℃,則該鋼坯的再加熱所需的能量增大,無法獲得節能的效果。因此,將隧道爐的入口側處的鋼坯的表面溫度設為850℃以上。較佳為900℃以上。未對上限進行限定,但當考慮到於連續鑄造中以完全凝固的方式進行冷卻時,鋼坯的表面溫度的上限較佳為1200℃左右。 [Transportation Step] Next, the steel slabs produced in the continuous casting step are transported to a tunnel furnace for heat preservation. During this transport step, it is crucial to maintain the surface temperature of the steel slabs at or above 850°C during transport to the tunnel furnace entrance. In other words, in this embodiment, the surface temperature of the steel slabs does not drop below 850°C from the time they are produced in the continuous casting step until they reach the furnace. If the surface temperature of the steel slabs falls below 850°C, the energy required for reheating increases, preventing the energy savings from being achieved. Therefore, the surface temperature of the steel slabs at the tunnel furnace entrance is maintained at or above 850°C, preferably at or above 900°C. There is no upper limit, but considering that cooling is performed during continuous casting to achieve complete solidification, the upper limit of the billet surface temperature is preferably around 1200°C.

於搬運步驟中,亦可於切斷鋼坯後搬運至隧道爐。但是,就抑制板坯的溫度降低的觀點而言,較佳為不切斷鋼坯而直接搬運至隧道爐。In the transfer step, the slab can be cut and then transferred to the tunnel furnace. However, from the perspective of suppressing the temperature drop of the slab, it is more preferable to transfer the slab directly to the tunnel furnace without cutting it.

[保溫步驟] 接下來,於所述隧道爐的出口側,以成為鋼坯的表面溫度為1050℃以上且1200℃以下、保溫時間為8 min以上的條件的方式進行保溫處理。藉由進行保溫處理,促進MnS或AlN等析出物的析出與粗大化。藉此,於製造無方向性電磁鋼板時使阻礙熱軋板退火步驟及精退火步驟中的晶粒生長性的微細的析出物無害化。 [Hot-Standing Step] Next, a hot-holding treatment is performed at the exit of the tunnel furnace, maintaining the billet surface temperature at 1050°C to 1200°C for at least 8 minutes. This hot-holding treatment promotes the precipitation and coarsening of precipitates such as MnS and AlN. This degrades the fine precipitates that hinder grain growth during the hot-rolled and finish annealing steps during the production of non-oriented electromagnetic steel sheets.

隧道爐出口側處的鋼坯的表面溫度:1050℃以上且1200℃以下 若所述鋼坯的溫度未滿1050℃,則不會充分地產生析出物的粗大化。因此,析出物於微細的狀態下殘存於板坯上,阻礙熱軋板退火及精退火中的晶粒生長。藉此,使製品的鐵損增加。因此,將隧道爐出口側處的鋼坯的表面溫度、即保溫溫度設為1050℃以上,較佳為設為1100℃以上。另一方面,若保溫溫度高於1200℃,則不會進行析出物的析出。因此,於保溫處理後的熱軋製中析出物微細析出。其結果,熱軋板退火步驟及精退火步驟中的晶粒生長性受到阻礙,製品的鐵損增加。因此,將保溫溫度設為1200℃以下,較佳為設為1150℃以下。 Surface temperature of the steel slab at the tunnel furnace exit: 1050°C or higher and 1200°C or lower If the slab temperature is lower than 1050°C, the precipitates will not coarsen sufficiently. Consequently, fine precipitates remain on the slab, hindering grain growth during hot-rolled annealing and finish annealing. This increases iron loss in the product. Therefore, the surface temperature of the steel slab at the tunnel furnace exit, or the holding temperature, is set to 1050°C or higher, preferably 1100°C or higher. On the other hand, if the holding temperature is higher than 1200°C, precipitates will not form. Consequently, fine precipitates form during hot rolling after the holding treatment. As a result, grain growth is hindered during the hot rolled sheet annealing and finish annealing steps, increasing iron loss in the product. Therefore, the holding temperature should be set below 1200°C, preferably below 1150°C.

保溫時間:8 min以上 若隧道爐中的保溫時間未滿8 min,則不會充分地進行析出物的析出與粗大化。因此,熱軋板退火及精退火中的晶粒生長性受到阻礙,製品的鐵損增加。因此,保溫時間設為8 min以上。另一方面,對保溫時間的上限並無特別限定,但若超過30 min,則不僅效果會飽和,而且隧道爐的爐長變長,藉此設備費增大。因此,保溫時間較佳為設為30 min以下,進而佳為設為15 min以下。 Holding Time: 8 minutes or longer If the holding time in the tunnel furnace is less than 8 minutes, precipitation and coarsening of precipitates will not proceed sufficiently. Consequently, grain growth during hot-rolled plate annealing and finish annealing is impaired, increasing iron loss in the product. Therefore, the holding time should be set to 8 minutes or longer. While there is no specific upper limit for the holding time, if it exceeds 30 minutes, the effect will be saturated and the tunnel furnace will be longer, increasing equipment costs. Therefore, the holding time is preferably set to 30 minutes or less, and more preferably 15 minutes or less.

保溫處理中的加熱方法並無特別限定,例如可使用感應加熱、煤氣爐、電爐等任意的方法。其中,於使用煤氣爐的情況下,藉由燃燒氣體而於鋼板的表面生成大量鱗皮(scale)。因此,於後述的熱軋製步驟中,當清除鱗皮時會激烈地噴射水,因此鋼坯的冷卻速度變快。因此,就將鋼坯的溫度保持為高溫的觀點而言,較佳為使用作為利用電能的加熱方法的感應加熱或電爐。The heating method used in the heat treatment is not particularly limited; for example, any method can be used, such as induction heating, a gas furnace, or an electric furnace. However, when using a gas furnace, the combustion of gas forms a large amount of scale on the surface of the steel plate. Consequently, during the hot rolling step described later, water is sprayed vigorously to remove the scale, accelerating the cooling rate of the steel slab. Therefore, from the perspective of maintaining a high temperature, induction heating or an electric furnace, which utilize electrical energy, are preferred.

[熱軋製步驟] 繼而,實施熱軋製步驟,所述熱軋製步驟是將所述鋼坯搬運至熱軋製機,實施熱軋製並捲繞於線圈來製成熱軋鋼板。於本實施形態中,於滿足下述(1)~(5)的條件下實施熱軋製步驟,以MnS為核使TiC或TiN等微細析出物複合析出的情況對於鐵損降低而言是重要的。 (1)自隧道爐出口側至熱軋製機入口側處的鋼坯的冷卻速度:4℃/s以下 (2)熱軋製機入口側處的鋼坯的表面溫度:950℃以上 (3)熱軋製的第一道次中的應變速度:1.5/s以上 (4)熱軋製機出口側處的鋼板的溫度:800℃以上 (5)線圈捲繞溫度:500℃以上 [Hot rolling step] Next, a hot rolling step is performed, in which the steel billet is transferred to a hot rolling mill, hot rolled, and wound around a coil to produce a hot rolled steel plate. In this embodiment, the hot rolling step is performed under the following conditions (1) to (5). It is important to reduce the iron loss by complex precipitation of fine precipitates such as TiC and TiN with MnS as the core. (1) Cooling rate of the steel billet from the tunnel furnace outlet to the hot rolling mill inlet: 4°C/s or less (2) Surface temperature of the steel billet at the hot rolling mill inlet: 950°C or higher (3) Strain rate in the first pass of hot rolling: 1.5/s or higher (4) Temperature of the steel plate at the hot rolling mill outlet: 800°C or higher (5) Coil winding temperature: 500°C or higher

鋼坯的冷卻速度:4℃/s以下 經過所述保溫步驟後的鋼坯與空氣中的氧反應而於表面生成鱗皮。當於殘留有鱗皮的狀態下供於熱軋製時,將鱗皮捲入而形成表面缺陷。因此,鋼坯離開隧道爐後,利用高壓水進行除鱗。藉此,可去除表面的鱗皮,並對鋼坯進行冷卻。此時,若冷卻速度大於4℃/s,則鋼坯的承受高壓水的部位局部急遽地被冷卻。藉此,大大低於MnS析出的溫度,TiC或TiN等微細析出物會析出,製品的鐵損增加。因此,冷卻速度設為4℃/s以下。另一方面,就鱗皮去除的觀點而言,較佳為冷卻速度快。因此,鋼坯的冷卻速度較佳為設為2℃/s以上。 Billet Cooling Rate: 4°C/s or less After the holding step, the billet reacts with oxygen in the air, forming scale on the surface. When hot rolling is performed with scale remaining, the scale is entangled, causing surface defects. Therefore, after leaving the tunnel furnace, the billet is descaled using high-pressure water. This removes the surface scale and allows the billet to cool. However, if the cooling rate exceeds 4°C/s, the areas of the billet exposed to the high-pressure water will cool rapidly. This significantly reduces the temperature below which MnS precipitates, causing fine precipitates such as TiC and TiN to form, increasing iron loss in the product. Therefore, the cooling rate is set to 4°C/s or less. On the other hand, from the perspective of scale removal, a faster cooling rate is preferred. Therefore, the cooling rate of the steel slab is preferably set to 2°C/s or higher.

熱軋製機入口側處的鋼坯的表面溫度:950℃以上 若熱軋製機入口側處的鋼坯的表面溫度、即入口側溫度未滿950℃,則析出的驅動力變大。因此,TiC或TiN等微細析出物與MnS同時析出,無法以MnS為核進行複合析出。因此,將熱軋製機的入口側溫度設為950℃以上。另一方面,對熱軋製機的入口側溫度的上限並無特別限定,越接近隧道爐出口側處的鋼坯的表面溫度越可抑制TiC或TiN的析出,因此較佳。 Billet Surface Temperature at the Hot Rolling Mill Inlet: 950°C or Higher If the billet surface temperature at the hot rolling mill inlet, i.e., the inlet-side temperature, is less than 950°C, the precipitation driving force increases. Consequently, fine precipitates such as TiC and TiN precipitate simultaneously with MnS, preventing complex precipitation with MnS as the nucleus. Therefore, the hot rolling mill inlet-side temperature is set to 950°C or higher. While there is no specific upper limit for the hot rolling mill inlet-side temperature, a billet surface temperature closer to the tunnel furnace outlet is preferred because it suppresses TiC and TiN precipitation.

熱軋製的第一道次中的應變速度:1.5/s以上 於熱軋製的第一道次中的應變速度未滿1.5/s的情況下,位錯恢復的速度超過作為析出的驅動力的位錯導入的速度。因此,於熱軋製的期間不會充分地進行MnS的析出。因此,熱軋製的第一道次中的應變速度設為1.5/s以上。另一方面,對熱軋製的第一道次中的應變速度的上限並無特別限定,但若應變速度過快,則甚至會析出TiC或TiN等微細析出物。因此,熱軋製的第一道次中的應變速度較佳為4.0/s以下。此處,根據下述的數式1的(1)式、(2)式計算應變速度。 Strain rate in the first pass of hot rolling: 1.5/s or more If the strain rate in the first pass of hot rolling is less than 1.5/s, the rate of dislocation recovery exceeds the rate of dislocation introduction, which is the driving force for precipitation. Therefore, MnS precipitation does not proceed sufficiently during hot rolling. Therefore, the strain rate in the first pass of hot rolling is set to 1.5/s or more. On the other hand, there is no particular upper limit for the strain rate in the first pass of hot rolling, but if the strain rate is too high, fine precipitates such as TiC and TiN may precipitate. Therefore, the strain rate in the first pass of hot rolling is preferably 4.0/s or less. Here, the strain rate is calculated according to equations (1) and (2) of the following formula 1.

[數1] [Number 1]

此處,ε(帶圈點)表示熱軋製第一道次中的應變速度(1/s),h 0表示熱軋製前的鋼坯的厚度(m),h 1表示熱軋製第一道次後的被軋製材料的厚度(m),t c表示熱軋製第一道次的軋製所需的時間(s),R表示熱軋製第一道次的輥徑(m),ν 0表示被軋製材料的通板速度(m/min)。 Here, ε (circled point) represents the strain rate in the first hot rolling pass (1/s), h0 represents the thickness of the steel billet before hot rolling (m), h1 represents the thickness of the rolled material after the first hot rolling pass (m), tc represents the rolling time required for the first hot rolling pass (s), R represents the roll diameter in the first hot rolling pass (m), and ν0 represents the sheet feed speed of the rolled material (m/min).

熱軋製機出口側處的鋼板的溫度:800℃以上 若熱軋製機出口側處的熱軋鋼板的溫度未滿800℃,則析出的驅動力變大。藉此,TiC或TiN等微細析出物與MnS同時析出,無法以MnS為核進行複合析出。因此,將熱軋製機出口側處的熱軋鋼板的溫度設為800℃以上。另一方面,對熱軋製機出口側處的熱軋鋼板的溫度的上限並無特別限定,越接近熱軋製機入口側的被軋製材料的溫度越可抑制TiC或TiN的析出,因此較佳。 Steel Sheet Temperature at the Hot Rolling Mill Exit: 800°C or Higher If the hot-rolled steel sheet temperature at the hot-rolling mill exit is less than 800°C, the precipitation driving force increases. This causes fine precipitates such as TiC and TiN to precipitate simultaneously with MnS, preventing complex precipitation with MnS as the nucleus. Therefore, the hot-rolled steel sheet temperature at the hot-rolling mill exit is set to 800°C or higher. While there is no specific upper limit for the hot-rolled steel sheet temperature at the hot-rolling mill exit, a temperature closer to the rolled material temperature at the hot-rolling mill entrance is preferred, as precipitation of TiC and TiN is more suppressed.

再者,所述熱軋製中的道次數並無特別限定,可設為1以上的任意的道次數。Furthermore, the number of passes in the hot rolling is not particularly limited and can be set to any number of passes greater than 1.

再者,熱軋製的精軋製中的出口側板厚、即最終獲得的熱軋鋼板的板厚並無特別限定,可為任意的厚度。但是,若出口側板厚未滿0.4 mm,則鋼板的全長過長,有生產性降低之虞。因此,就生產性的觀點而言,較佳為將精軋製中的出口側板厚設為0.4 mm以上。另一方面,若出口側板厚超過2.0 mm,則有冷軋製的負荷變過大之虞。因此,就降低冷軋製的負荷的觀點而言,較佳為將精軋製中的出口側板厚設為2.0 mm以下。Furthermore, the thickness of the exit side of the hot-rolled steel plate during the hot-rolled finishing process, that is, the thickness of the final hot-rolled steel plate, is not particularly limited and can be any thickness. However, if the exit side thickness is less than 0.4 mm, the total length of the steel plate will be too long, which may reduce productivity. Therefore, from the perspective of productivity, it is preferable to set the exit side thickness during finishing to 0.4 mm or more. On the other hand, if the exit side thickness exceeds 2.0 mm, there is a risk that the load during cold rolling will become too large. Therefore, from the perspective of reducing the load during cold rolling, it is preferable to set the exit side thickness during finishing to 2.0 mm or less.

線圈的捲繞溫度:500℃以上 若線圈的捲繞溫度未滿500℃,則對於TiC或TiN而言的析出的驅動力變小。藉此,無法於線圈的狀態下時效析出。因此,於下一步驟以後微細地析出,使鐵損增加。因此,線圈的捲繞溫度設為500℃以上。另一方面,對線圈的捲繞溫度的上限並無特別限定,但若於高溫下捲繞則有線圈變形之虞。因此,線圈的捲繞溫度較佳為設為550℃以下的溫度。 Coil Winding Temperature: 500°C or Higher If the coil winding temperature is below 500°C, the precipitation driving force for TiC and TiN decreases. Consequently, aging precipitation cannot occur in the coiled state. Consequently, fine precipitation occurs after the next step, increasing iron loss. Therefore, the coil winding temperature should be set above 500°C. While there is no specific upper limit for the coil winding temperature, winding at high temperatures may cause coil deformation. Therefore, the coil winding temperature is preferably set below 550°C.

[無方向性電磁鋼板的製造條件] 本實施形態中的無方向性電磁鋼板的製造方法包括:熱軋鋼板製造步驟,利用所述製造方法製造熱軋鋼板;熱軋板退火步驟,對所述熱軋鋼板實施熱軋板退火而製成熱軋退火板;冷軋步驟,對熱軋退火板實施冷軋製而製成冷軋鋼板;以及精退火步驟,對冷軋鋼板實施精退火。實施所述熱軋板退火、冷軋製、及精退火的精退火的各步驟並無特別限定,可按照常規方法來進行。 [Non-Oriented Electromagnetic Steel Sheet Manufacturing Conditions] The non-oriented electromagnetic steel sheet manufacturing method in this embodiment includes: a hot-rolled steel sheet manufacturing step, in which a hot-rolled steel sheet is manufactured using the manufacturing method; a hot-rolled steel sheet annealing step, in which the hot-rolled steel sheet is subjected to hot-rolled steel sheet annealing to produce a hot-rolled annealed steel sheet; a cold-rolling step, in which the hot-rolled annealed steel sheet is cold-rolled to produce a cold-rolled steel sheet; and a finish annealing step, in which the cold-rolled steel sheet is subjected to finish annealing. The hot-rolled steel sheet annealing, cold-rolling, and finish annealing steps are not particularly limited and can be performed according to conventional methods.

亦較佳為於熱軋板退火之後且於冷軋製之前進行酸洗。另外,較佳為於精退火之後,於所獲得的無方向性電磁鋼板的表面形成絕緣塗層。對酸洗及絕緣塗層的形成亦無特別限定,可按照常規方法來進行。 [實施例] It is also preferred to perform pickling after annealing the hot-rolled sheet and before cold rolling. Furthermore, it is preferred to form an insulating coating on the surface of the resulting non-oriented electromagnetic steel sheet after finish annealing. The pickling and insulating coating formation are not particularly limited and can be performed according to conventional methods. [Examples]

<實施例1> 利用連續鑄造法製造具有表1所示的成分組成的厚度60 mm的鋼坯。於不切斷該鋼坯的情況下,在將鋼坯的表面溫度維持為850℃以上的狀態下搬運至隧道式電爐中,於該電爐中進行保溫處理。隧道爐出口側處的鋼坯的表面溫度設為1100℃左右,保溫時間設為10 min。 繼而,利用高水壓去除鋼坯表層的鱗皮後,實施5道次的熱軋製,並捲繞於線圈而製成熱軋鋼板。於所述熱軋製步驟中,自隧道爐出口側至熱軋製機的冷卻速度設為3℃/s,熱軋製機入口側處的鋼坯的表面溫度設為1000℃。將熱軋製第一道次的應變速度設為3.0/s,將熱軋製機出口側處的鋼板的溫度設為900℃,將線圈捲繞溫度設為520℃。 <Example 1> A 60 mm thick steel slab with the composition shown in Table 1 was produced using a continuous casting method. Without cutting, the slab was transferred to a tunnel-type electric furnace while maintaining a surface temperature above 850°C, where it was held at a high temperature. The surface temperature of the slab at the tunnel furnace exit was set at approximately 1100°C, and the holding time was set for 10 minutes. The slab was then descaled using high-pressure water, followed by five passes of hot rolling and wound around a coil to produce hot-rolled steel plate. During the hot rolling process, the cooling rate from the tunnel furnace exit to the hot rolling mill was set at 3°C/s, and the surface temperature of the steel billet at the hot rolling mill entrance was set at 1000°C. The strain rate during the first hot rolling pass was set at 3.0°C/s, the temperature of the steel plate at the hot rolling mill exit was set at 900°C, and the coil winding temperature was set at 520°C.

對於所獲得的熱軋鋼板實施1000℃、30秒鐘的熱軋板退火而製成熱軋退火板。繼而,對熱軋退火板實施冷軋製而製成板厚0.30 mm的冷軋鋼板。之後,對冷軋鋼板實施1000℃、10秒鐘的精退火而獲得無方向性電磁鋼板。The resulting hot-rolled steel sheet was annealed at 1000°C for 30 seconds to produce a hot-rolled annealed sheet. The hot-rolled annealed sheet was then cold-rolled to produce a 0.30 mm thick cold-rolled steel sheet. The cold-rolled steel sheet was then finish-annealed at 1000°C for 10 seconds to produce a non-oriented electromagnetic steel sheet.

自所獲得的無方向性電磁鋼板的軋製方向與板寬方向切出寬度:30 mm×長度:280 mm的愛波斯坦樣品,並利用愛波斯坦試驗器測定鐵損W 10/400。於板厚0.30 mm時,若鐵損W 10/400為13.50 W/kg以下則良好。 Epstein samples measuring 30 mm wide and 280 mm long were cut from the resulting non-oriented electromagnetic steel sheet in both the rolling and width directions. The steel loss W10 /400 was measured using an Epstein tester. For a sheet thickness of 0.30 mm, a W10 /400 of 13.50 W/kg or less was considered acceptable.

如根據表1所示的結果可知般,於滿足本發明的條件的成分組成中,可獲得具有良好的鐵損的無方向性電磁鋼板。再者,試驗No.7、試驗No.13、試驗No.19及試驗No.23於製造時斷裂,因此無法評價。於成分組成的一欄中「-」表示未添加該成分或作為不可避免的雜質的含量。As shown in Table 1, non-oriented electromagnetic steel sheets with excellent iron loss can be obtained with a composition that meets the requirements of the present invention. Tests No. 7, No. 13, No. 19, and No. 23 fractured during production and could not be evaluated. "-" in the composition column indicates that the component was not added or was present as an unavoidable impurity.

[表1] No. 成分組成(mass%) W 10/400(W/kg) 備註 C Si Mn P S Al N Cu Mo Zn Ti 其他 1 0.0001 3.06 0.51 0.010 0.0035 0.49 0.0028 0.01 0.011 0.001 0.003 - 13.23 發明例 2 0.010 3.05 0.49 0.001 0.0035 0.50 0.0028 0.01 0.011 0.001 0.002 - 13.42 發明例 3 0.011 2.90 0.50 0.010 0.0031 0.50 0.0032 0.01 0.010 0.001 0.003 - 13.55 比較例 4 0.002 2.42 0.50 0.009 0.0033 0.49 0.0026 0.01 0.011 0.001 0.003 - 13.55 比較例 5 0.002 2.51 0.50 0.009 0.0026 0.49 0.0032 0.01 0.010 0.001 0.002 - 13.45 發明例 6 0.002 4.85 0.50 0.009 0.0033 0.50 0.0001 0.01 0.010 0.001 0.003 - 13.12 發明例 7 0.002 5.04 0.50 0.010 0.0033 0.49 0.0031 0.01 0.011 0.001 0.003 - - 比較例 8 0.002 2.99 0.09 0.011 0.0032 0.50 0.0025 0.01 0.010 0.001 0.002 - 13.64 比較例 9 0.002 3.01 0.10 0.011 0.0033 0.50 0.0025 0.01 0.010 0.001 0.003 - 13.42 發明例 10 0.002 3.05 2.96 0.011 0.0034 0.51 0.0030 0.01 0.010 0.001 0.002 - 13.46 發明例 11 0.002 2.98 3.01 0.011 0.0034 0.49 0.0030 0.01 0.011 0.001 0.002 - 13.56 比較例 12 0.002 2.90 0.50 0.095 0.0027 0.50 0.0033 0.01 0.011 0.001 0.003 - 13.35 發明例 13 0.002 3.08 0.49 0.106 0.0032 0.49 0.0026 0.01 0.010 0.001 0.003 - - 比較例 14 0.002 2.99 0.50 0.011 0.0009 0.50 0.0033 0.01 0.010 0.001 0.002 - 13.74 比較例 15 0.002 3.07 0.50 0.009 0.0011 0.50 0.0030 0.01 0.011 0.001 0.002 - 13.42 發明例 16 0.002 3.10 0.49 0.009 0.0049 0.51 0.0025 0.01 0.010 0.001 0.003 - 13.45 發明例 17 0.002 3.08 0.50 0.009 0.0053 0.20 0.0035 0.01 0.011 0.001 0.003 - 13.67 比較例 18 0.002 3.06 0.50 0.010 0.0035 1.99 0.0027 0.01 0.011 0.001 0.003 - 13.23 發明例 19 0.002 3.05 0.49 0.010 0.0032 2.01 0.0031 0.01 0.011 0.001 0.003 - - 比較例 20 0.002 3.03 0.51 0.011 0.0033 0.50 0.0078 0.01 0.010 0.001 0.003 - 13.45 發明例 21 0.002 3.05 0.51 0.010 0.0029 0.51 0.0082 0.01 0.011 0.001 0.002 - 13.74 比較例 22 0.002 3.09 0.51 0.010 0.0030 0.49 0.0025 0.98 0.010 0.001 0.002 - 13.44 發明例 23 0.002 3.00 0.50 0.009 0.0027 0.50 0.0033 1.05 0.010 0.001 0.003 - - 比較例 24 0.002 2.94 0.51 0.010 0.0031 0.50 0.0035 0.01 0.045 0.001 0.002 - 13.34 發明例 25 0.002 2.94 0.49 0.009 0.0029 0.30 0.0033 0.01 0.053 0.001 0.002 - 13.61 比較例 26 0.002 2.94 0.49 0.010 0.0031 0.50 0.0032 0.01 0.010 0.010 0.002 - 13.49 發明例 27 0.002 2.92 0.50 0.011 0.0033 0.50 0.0027 0.01 0.011 0.013 0.003 - 13.56 比較例 28 0.002 2.95 0.49 0.010 0.0033 0.50 0.0031 0.01 0.010 0.001 0.009 - 13.48 發明例 29 0.002 3.04 0.51 0.011 0.0027 0.50 0.0028 0.01 0.010 0.001 0.012 - 13.59 比較例 30 0.002 2.99 0.50 0.011 0.0027 0.50 0.0032 0.01 0.010 0.001 0.002 Sn:0.19 13.35 發明例 31 0.002 3.10 0.51 0.009 0.0034 0.50 0.0030 0.01 0.011 0.001 0.003 Sn:0.21 13.46 發明例 32 0.002 2.98 0.50 0.009 0.0033 0.50 0.0029 0.01 0.011 0.001 0.002 Sb:0.19 13.31 發明例 33 0.002 3.02 0.49 0.010 0.0031 0.50 0.0027 0.01 0.010 0.001 0.002 Sb:0.21 13.45 發明例 34 0.002 3.10 0.49 0.01 0.0032 0.50 0.0025 0.01 0.010 0.001 0.002 Mg:0.01、REM:0.01、B:0.005、Ni:0.1、Cr:0.5、V:0.01、Nb:0.002、Ta:0.001、W:0.03、Pb:0.001、Co:0.05、Ga:0.01、Ge:0.01、As:0.01 13.42 發明例 [Table 1] No. Ingredient composition (mass%) W 10/400 (W/kg) Remarks C Si Mn P S Al N Cu Mo Zn Ti other 1 0.0001 3.06 0.51 0.010 0.0035 0.49 0.0028 0.01 0.011 0.001 0.003 - 13.23 Invention Example 2 0.010 3.05 0.49 0.001 0.0035 0.50 0.0028 0.01 0.011 0.001 0.002 - 13.42 Invention Example 3 0.011 2.90 0.50 0.010 0.0031 0.50 0.0032 0.01 0.010 0.001 0.003 - 13.55 Comparative example 4 0.002 2.42 0.50 0.009 0.0033 0.49 0.0026 0.01 0.011 0.001 0.003 - 13.55 Comparative example 5 0.002 2.51 0.50 0.009 0.0026 0.49 0.0032 0.01 0.010 0.001 0.002 - 13.45 Invention Example 6 0.002 4.85 0.50 0.009 0.0033 0.50 0.0001 0.01 0.010 0.001 0.003 - 13.12 Invention Example 7 0.002 5.04 0.50 0.010 0.0033 0.49 0.0031 0.01 0.011 0.001 0.003 - - Comparative example 8 0.002 2.99 0.09 0.011 0.0032 0.50 0.0025 0.01 0.010 0.001 0.002 - 13.64 Comparative example 9 0.002 3.01 0.10 0.011 0.0033 0.50 0.0025 0.01 0.010 0.001 0.003 - 13.42 Invention Example 10 0.002 3.05 2.96 0.011 0.0034 0.51 0.0030 0.01 0.010 0.001 0.002 - 13.46 Invention Example 11 0.002 2.98 3.01 0.011 0.0034 0.49 0.0030 0.01 0.011 0.001 0.002 - 13.56 Comparative example 12 0.002 2.90 0.50 0.095 0.0027 0.50 0.0033 0.01 0.011 0.001 0.003 - 13.35 Invention Example 13 0.002 3.08 0.49 0.106 0.0032 0.49 0.0026 0.01 0.010 0.001 0.003 - - Comparative example 14 0.002 2.99 0.50 0.011 0.0009 0.50 0.0033 0.01 0.010 0.001 0.002 - 13.74 Comparative example 15 0.002 3.07 0.50 0.009 0.0011 0.50 0.0030 0.01 0.011 0.001 0.002 - 13.42 Invention Example 16 0.002 3.10 0.49 0.009 0.0049 0.51 0.0025 0.01 0.010 0.001 0.003 - 13.45 Invention Example 17 0.002 3.08 0.50 0.009 0.0053 0.20 0.0035 0.01 0.011 0.001 0.003 - 13.67 Comparative example 18 0.002 3.06 0.50 0.010 0.0035 1.99 0.0027 0.01 0.011 0.001 0.003 - 13.23 Invention Example 19 0.002 3.05 0.49 0.010 0.0032 2.01 0.0031 0.01 0.011 0.001 0.003 - - Comparative example 20 0.002 3.03 0.51 0.011 0.0033 0.50 0.0078 0.01 0.010 0.001 0.003 - 13.45 Invention Example twenty one 0.002 3.05 0.51 0.010 0.0029 0.51 0.0082 0.01 0.011 0.001 0.002 - 13.74 Comparative example twenty two 0.002 3.09 0.51 0.010 0.0030 0.49 0.0025 0.98 0.010 0.001 0.002 - 13.44 Invention Example twenty three 0.002 3.00 0.50 0.009 0.0027 0.50 0.0033 1.05 0.010 0.001 0.003 - - Comparative example twenty four 0.002 2.94 0.51 0.010 0.0031 0.50 0.0035 0.01 0.045 0.001 0.002 - 13.34 Invention Example 25 0.002 2.94 0.49 0.009 0.0029 0.30 0.0033 0.01 0.053 0.001 0.002 - 13.61 Comparative example 26 0.002 2.94 0.49 0.010 0.0031 0.50 0.0032 0.01 0.010 0.010 0.002 - 13.49 Invention Example 27 0.002 2.92 0.50 0.011 0.0033 0.50 0.0027 0.01 0.011 0.013 0.003 - 13.56 Comparative example 28 0.002 2.95 0.49 0.010 0.0033 0.50 0.0031 0.01 0.010 0.001 0.009 - 13.48 Invention Example 29 0.002 3.04 0.51 0.011 0.0027 0.50 0.0028 0.01 0.010 0.001 0.012 - 13.59 Comparative example 30 0.002 2.99 0.50 0.011 0.0027 0.50 0.0032 0.01 0.010 0.001 0.002 Sn: 0.19 13.35 Invention Example 31 0.002 3.10 0.51 0.009 0.0034 0.50 0.0030 0.01 0.011 0.001 0.003 Sn: 0.21 13.46 Invention Example 32 0.002 2.98 0.50 0.009 0.0033 0.50 0.0029 0.01 0.011 0.001 0.002 Sb:0.19 13.31 Invention Example 33 0.002 3.02 0.49 0.010 0.0031 0.50 0.0027 0.01 0.010 0.001 0.002 Sb:0.21 13.45 Invention Example 34 0.002 3.10 0.49 0.01 0.0032 0.50 0.0025 0.01 0.010 0.001 0.002 Mg: 0.01, REM: 0.01, B: 0.005, Ni: 0.1, Cr: 0.5, V: 0.01, Nb: 0.002, Ta: 0.001, W: 0.03, Pb: 0.001, Co: 0.05, Ga: 0.01, Ge: 0.01, As: 0.01 13.42 Invention Example

<實施例2> 將具有如下成分組成,即,含有C:0.002%、Si:3.00%、Mn:0.50%、P:0.01%、S:0.0030%、Al:0.50%、N:0.0020%、Cu:0.01%、Mo:0.010%、Zn:0.001%、Ti:0.002%且剩餘部分包含Fe及不可避免的雜質的成分組成的鋼熔煉,連續鑄造鋼坯,並於表2所示的條件下製造無方向性電磁鋼板用熱軋鋼板。 <Example 2> Steel having a composition comprising 0.002% C, 3.00% Si, 0.50% Mn, 0.01% P, 0.0030% S, 0.50% Al, 0.0020% N, 0.01% Cu, 0.010% Mo, 0.001% Zn, and 0.002% Ti, with the remainder consisting of Fe and inevitable impurities, was melted and continuously cast into steel slabs. Hot-rolled steel sheets for non-oriented electromagnetic steel were produced under the conditions shown in Table 2.

對於所獲得的熱軋鋼板實施1000℃、30秒鐘的熱軋板退火而製成熱軋退火板。繼而,對熱軋退火板實施冷軋製而製成板厚0.30 mm的冷軋鋼板。之後,對冷軋鋼板實施1000℃、10秒鐘的精退火而獲得無方向性電磁鋼板。The resulting hot-rolled steel sheet was annealed at 1000°C for 30 seconds to produce a hot-rolled annealed sheet. The hot-rolled annealed sheet was then cold-rolled to produce a 0.30 mm thick cold-rolled steel sheet. The cold-rolled steel sheet was then finish-annealed at 1000°C for 10 seconds to produce a non-oriented electromagnetic steel sheet.

自所獲得的無方向性電磁鋼板的軋製方向與板寬方向切出寬度:30 mm×長度:280 mm的愛波斯坦樣品,並利用愛波斯坦試驗器測定鐵損W 10/400。於板厚0.30 mm時,若鐵損W 10/400為13.50 W/kg以下則良好。 Epstein samples measuring 30 mm wide and 280 mm long were cut from the resulting non-oriented electromagnetic steel sheet in both the rolling and width directions. The steel loss W10 /400 was measured using an Epstein tester. For a sheet thickness of 0.30 mm, a W10 /400 of 13.50 W/kg or less was considered acceptable.

如根據表2所示的結果可知般,於滿足本發明的條件的製造條件中,可獲得具有良好的鐵損的無方向性電磁鋼板。As can be seen from the results shown in Table 2, under manufacturing conditions that meet the requirements of the present invention, a non-oriented electromagnetic steel sheet with good iron loss can be obtained.

[表2] No. 板坯厚度 隧道爐 熱軋製 W 10/400 備註 入口側溫度 出口側溫度 保溫時間 冷卻速度 入口側溫度 出口側溫度 應變速度 捲繞溫度 mm min ℃/s 1/s W/kg 35 60 903 1093 10 2.7 990 836 3.4 527 13.21 發明例 36 25 908 1086 11 2.6 980 836 3.0 540 13.64 比較例 37 30 916 1097 11 2.1 988 833 3.0 526 13.45 發明例 38 175 912 1102 10 2.7 984 832 3.1 533 13.42 發明例 39 60 842 1109 9 2.3 976 830 3.0 520 13.67 比較例 40 60 855 1108 10 2.3 981 847 3.3 521 13.49 發明例 41 60 900 1035 10 2.5 970 846 2.6 527 13.56 比較例 42 60 894 1052 11 2.5 984 849 3.2 528 13.41 發明例 43 60 897 1193 10 2.2 986 839 3.2 533 13.38 發明例 44 60 896 1211 10 2.8 987 846 3.3 520 13.52 比較例 45 60 891 1115 7 2.4 983 835 3.4 534 13.59 比較例 46 60 919 1105 8 2.2 978 837 3.2 530 13.47 發明例 47 60 900 1117 9 4.3 984 832 2.8 526 13.61 比較例 48 60 908 1086 10 3.9 988 844 3.1 538 13.45 發明例 49 60 899 1088 11 2.5 934 848 2.9 530 13.56 比較例 50 60 897 1105 11 2.5 955 838 2.8 527 13.49 發明例 51 60 911 1097 10 2.7 980 786 3.2 523 13.58 比較例 52 60 912 1120 11 2.2 978 805 2.7 536 13.42 發明例 53 60 910 1089 10 2.4 980 839 1.4 520 13.55 比較例 54 60 894 1115 9 2.5 984 836 1.6 534 13.45 發明例 55 60 907 1092 11 2.9 988 836 3.5 492 13.57 比較例 56 60 899 1094 9 2.2 974 844 2.6 503 13.41 發明例 [Table 2] No. Slab thickness Tunnel furnace Hot rolling W 10/400 Remarks Inlet temperature Outlet temperature Keep warm time Cooling speed Inlet temperature Outlet temperature strain speed Winding temperature mm min ℃/s 1/s W/kg 35 60 903 1093 10 2.7 990 836 3.4 527 13.21 Invention Example 36 25 908 1086 11 2.6 980 836 3.0 540 13.64 Comparative example 37 30 916 1097 11 2.1 988 833 3.0 526 13.45 Invention Example 38 175 912 1102 10 2.7 984 832 3.1 533 13.42 Invention Example 39 60 842 1109 9 2.3 976 830 3.0 520 13.67 Comparative example 40 60 855 1108 10 2.3 981 847 3.3 521 13.49 Invention Example 41 60 900 1035 10 2.5 970 846 2.6 527 13.56 Comparative example 42 60 894 1052 11 2.5 984 849 3.2 528 13.41 Invention Example 43 60 897 1193 10 2.2 986 839 3.2 533 13.38 Invention Example 44 60 896 1211 10 2.8 987 846 3.3 520 13.52 Comparative example 45 60 891 1115 7 2.4 983 835 3.4 534 13.59 Comparative example 46 60 919 1105 8 2.2 978 837 3.2 530 13.47 Invention Example 47 60 900 1117 9 4.3 984 832 2.8 526 13.61 Comparative example 48 60 908 1086 10 3.9 988 844 3.1 538 13.45 Invention Example 49 60 899 1088 11 2.5 934 848 2.9 530 13.56 Comparative example 50 60 897 1105 11 2.5 955 838 2.8 527 13.49 Invention Example 51 60 911 1097 10 2.7 980 786 3.2 523 13.58 Comparative example 52 60 912 1120 11 2.2 978 805 2.7 536 13.42 Invention Example 53 60 910 1089 10 2.4 980 839 1.4 520 13.55 Comparative example 54 60 894 1115 9 2.5 984 836 1.6 534 13.45 Invention Example 55 60 907 1092 11 2.9 988 836 3.5 492 13.57 Comparative example 56 60 899 1094 9 2.2 974 844 2.6 503 13.41 Invention Example

圖1是表示實驗1中的無方向性電磁鋼板的S含量與鐵損W 10/400的關係的曲線圖。 圖2是表示實驗2中的無方向性電磁鋼板用熱軋製中的鋼坯向熱軋製機的入口側溫度與鐵損W 10/400的關係的曲線圖。 圖3是表示實驗3中的無方向性電磁鋼板用熱軋製中的第一道次中的應變速度與鐵損W 10/400的關係的曲線圖。 Figure 1 is a graph showing the relationship between the S content and the steel loss W10 /400 in the non-oriented electromagnetic steel sheet in Experiment 1. Figure 2 is a graph showing the relationship between the steel billet inlet temperature to the hot rolling mill and the steel loss W10 /400 in hot rolling of the non-oriented electromagnetic steel sheet in Experiment 2. Figure 3 is a graph showing the relationship between the strain rate in the first pass and the steel loss W10 /400 in hot rolling of the non-oriented electromagnetic steel sheet in Experiment 3.

Claims (3)

一種無方向性電磁鋼板用熱軋鋼板的製造方法,包括: 保溫步驟,將熔鋼鑄造成厚度30 mm以上且180 mm以下的範圍的鋼坯,繼而於隧道爐中對所述鋼坯進行保溫;以及熱軋製步驟,對所述鋼坯實施熱軋製,所述熔鋼具有如下成分組成,所述成分組成以質量%計含有: C:0.010%以下、 Si:2.50%以上且5.00%以下、 Mn:0.10%以上且3.00%以下、 P:0.100%以下、 S:0.0010%以上且0.0050%以下、 Al:2.00%以下、 N:0.0080%以下、 Cu:1.00%以下、 Mo:0.050%以下、 Zn:0.010%以下、及 Ti:0.010%以下, 任意選擇地更含有選自以下群組中的至少一群組的元素: A群組為選自Sn:0.20%以下及Sb:0.20%以下中的至少一種; B群組為選自Mg:0.0001%以上且0.10%以下及稀土金屬:0.0001%以上且0.10%以下中的至少一種; C群組為B:0.002%以上且0.01%以下; D群組為Ni:0.01%以上且1.0%以下; E群組為Cr:0.1%以上且5.0%以下; F群組為選自V:0.001%以上且0.050%以下、Nb:0.001%以上且0.005%以下、Ta:0.0001%以上且0.0020%以下、W:0.001%以上且0.050%以下及Pb:0.0001%以上且0.0020%以下中的至少一種; G群組為Co:0.001%以上且0.100%以下; H群組為選自Ga:0.0005%以上且0.0300%以下及Ge:0.0005%以上且0.0300%以下中的至少一種;及 I群組為As:0.001%以上且0.020%以下, 剩餘部分包含Fe及不可避免的雜質, 所述無方向性電磁鋼板用熱軋鋼板的製造方法中, 於所述保溫步驟中,將所述隧道爐的入口側處的鋼坯的表面溫度設為850℃以上,將所述隧道爐的出口側處的鋼坯的表面溫度設為1050℃以上且1200℃以下的範圍,將所述隧道爐中的保溫時間設為8 min以上, 於所述熱軋製步驟中,於如下條件,即,將自所述隧道爐的出口側至熱軋製機入口側處的鋼坯的冷卻速度設為4℃/s以下、將熱軋製機的入口側溫度設為950℃以上、將熱軋製機的出口側溫度設為800℃以上、將熱軋製的第一道次中的應變速度設為1.5/s以上、線圈捲繞溫度滿足500℃以上的條件下進行。 A method for manufacturing a hot-rolled steel plate for use as a non-oriented electromagnetic steel plate comprises: a heat-holding step of casting molten steel into a steel billet having a thickness ranging from 30 mm to 180 mm, and then heat-holding the steel billet in a tunnel furnace; and a hot-rolling step of hot-rolling the steel billet, wherein the molten steel has the following composition, which comprises, by mass%, the following: C: 0.010% or less, Si: 2.50% or more and 5.00% or less, Mn: 0.10% or more and 3.00% or less, P: 0.100% or less, S: 0.0010% or more and 0.0050% or less, Al: 2.00% or less, N: 0.0080% or less, Cu: 1.00% or less, Mo: 0.050% or less, Zn: 0.010% or less, and Ti: 0.010% or less, optionally further containing at least one element selected from the following groups: Group A: at least one element selected from Sn: 0.20% or less and Sb: 0.20% or less; Group B: at least one element selected from Mg: 0.0001% or more and 0.10% or less and rare earth metals: 0.0001% or more and 0.10% or less; Group C: B: 0.002% or more and 0.01% or less; Group D: Ni: 0.01% or more and 1.0% or less; Group E: Cr: 0.1% or more and 5.0% or less; The F group is at least one selected from V: 0.001% to 0.050%, Nb: 0.001% to 0.005%, Ta: 0.0001% to 0.0020%, W: 0.001% to 0.050%, and Pb: 0.0001% to 0.0020%. The G group is Co: 0.001% to 0.100%. The H group is at least one selected from Ga: 0.0005% to 0.0300%, and Ge: 0.0005% to 0.0300%. The I group is As: 0.001% to 0.020%. The remainder consists of Fe and unavoidable impurities. In the method for manufacturing hot-rolled steel sheets for non-oriented electromagnetic steel, During the holding step, the surface temperature of the steel slab at the inlet side of the tunnel furnace is set to 850°C or higher, and the surface temperature of the steel slab at the outlet side of the tunnel furnace is set to a range of 1050°C or higher and 1200°C or lower. The holding time in the tunnel furnace is set to 8 minutes or longer. The hot rolling step is carried out under the following conditions: the cooling rate of the steel billet from the exit of the tunnel furnace to the entrance of the hot rolling mill is set to 4°C/s or less, the temperature at the entrance of the hot rolling mill is set to 950°C or above, the temperature at the exit of the hot rolling mill is set to 800°C or above, the strain rate in the first pass of hot rolling is set to 1.5/s or above, and the coil winding temperature is set to 500°C or above. 如請求項1所述的無方向性電磁鋼板用熱軋鋼板的製造方法,其中將所述熔鋼自電爐或轉爐中出鋼。The method for producing a hot-rolled steel plate for non-oriented electromagnetic steel according to claim 1, wherein the molten steel is tapped from an electric furnace or a converter. 一種無方向性電磁鋼板的製造方法,包括:熱軋鋼板製造步驟,利用如請求項1或2所述的無方向性電磁鋼板用熱軋鋼板的製造方法製造熱軋鋼板;熱軋板退火步驟,對所述熱軋鋼板實施退火而製成熱軋退火板;冷軋步驟,對所述熱軋退火板實施冷軋製而製成冷軋鋼板;以及精退火步驟,對所述冷軋鋼板實施精退火。A method for manufacturing a non-oriented electromagnetic steel sheet comprises: a hot-rolled steel sheet manufacturing step of manufacturing a hot-rolled steel sheet using the method for manufacturing a hot-rolled steel sheet for a non-oriented electromagnetic steel sheet as claimed in claim 1 or 2; a hot-rolled steel sheet annealing step of annealing the hot-rolled steel sheet to produce a hot-rolled annealed steel sheet; a cold-rolling step of cold-rolling the hot-rolled annealed steel sheet to produce a cold-rolled steel sheet; and a finish annealing step of finish annealing the cold-rolled steel sheet.
TW113150638A 2024-02-01 2024-12-25 Method for manufacturing hot-rolled steel sheet for non-oriented electromagnetic steel sheet and method for manufacturing non-oriented electromagnetic steel sheet TW202532661A (en)

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