TW202522062A - Blazed grating formation by staircase etch - Google Patents
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Abstract
Description
本揭露案的實施例大體而言係關於光波導。更特定言之,本文所述的實施例提供了用於形成具有閃耀光柵的波導的技術。Embodiments of the present disclosure generally relate to optical waveguides. More particularly, embodiments described herein provide techniques for forming a waveguide having a flared grating.
虛擬實境通常被認為是電腦產生的模擬環境,其中使用者具有表觀實體存在。虛擬實境體驗可以以3D形式產生,並使用頭戴式顯示器(head-mounted display, HMD),例如眼鏡或其他可穿戴顯示設備觀看,該等其他可穿戴顯示設備具有近眼顯示面板作為透鏡來顯示替代實際環境的虛擬實境環境。Virtual reality is generally considered to be a computer-generated simulated environment in which the user has an apparent physical presence. The virtual reality experience can be generated in 3D and viewed using a head-mounted display (HMD), such as glasses, or other wearable display devices that have near-eye display panels as lenses to display the virtual reality environment in place of the real environment.
然而,擴增實境使得能夠實現如此的體驗,在該體驗中使用者仍然可以經由眼鏡或其他HMD設備的顯示透鏡看到周圍的環境,亦可以看到作為環境的部分被產生以顯示並出現的虛擬對象的圖像。擴增實境可包括任何類型的輸入,諸如音訊及觸覺輸入,以及加強或擴增使用者體驗的環境的虛擬圖像、圖形及視訊。作為一種新興技術,擴增實境面臨許多挑戰及設計約束。However, augmented reality enables an experience in which the user can still see the surrounding environment through the display lenses of glasses or other HMD devices, and can also see images of virtual objects that are generated for display and appear as part of the environment. Augmented reality can include any type of input, such as audio and tactile input, as well as virtual images, graphics, and video that enhance or expand the user's experience of the environment. As an emerging technology, augmented reality faces many challenges and design constraints.
在AR波導中需要閃耀光柵來實現目標階的高繞射效率。然而,使用傳統的圖案化很難製造閃耀刻面。目前,尚無可擴展的工業解決方案來形成用於AR波導的閃耀光柵。Blazed gratings are needed in AR waveguides to achieve high diffraction efficiency of the target order. However, blazed facets are difficult to fabricate using conventional patterning. Currently, there is no scalable industrial solution to form blazed gratings for AR waveguides.
因此,需要改進的用於形成閃耀光柵結構的系統和方法。Therefore, there is a need for improved systems and methods for forming glare grating structures.
本文的實施例總體上針對形成諸如閃耀光柵的光學元件結構的方法。Embodiments herein are generally directed to methods of forming optical component structures such as glare gratings.
在實施例中,提供了一種形成光學元件結構的方法。該方法包括:在元件層或基板上方設置的圖案化的硬遮罩上沉積光阻劑層;曝光該光阻劑層以產生複數個光阻劑區段;蝕刻該元件層或該基板以產生至少一個台階,該至少一個台階形成閃耀光柵;水平地修整該複數個光阻劑區段;以及移除該複數個光阻劑區段和該圖案化的硬遮罩。In an embodiment, a method for forming an optical element structure is provided. The method includes: depositing a photoresist layer on a patterned hard mask disposed above an element layer or a substrate; exposing the photoresist layer to produce a plurality of photoresist segments; etching the element layer or the substrate to produce at least one step, the at least one step forming a flare grating; horizontally trimming the plurality of photoresist segments; and removing the plurality of photoresist segments and the patterned hard mask.
在另一個實施例中,提供了一種形成光學元件結構的方法。該方法包括:在具有設置在元件層或基板上方的複數個硬遮罩區段的圖案化的硬遮罩上沉積光阻劑層;曝光該光阻劑層以產生複數個光阻劑區段;以及蝕刻該元件層或該基板以產生閃耀光柵的第一台階。該方法亦包括:水平地修整該複數個光阻劑區段;以及重複蝕刻該元件層或該基板;以及水平地修整該複數個光阻劑區段以產生該閃耀光柵的第二台階。該方法可進一步包括:重複蝕刻該元件層並水平地修整該複數個光阻劑區段以產生該閃耀光柵的第三台階,以及移除該複數個光阻劑區段和該圖案化的硬遮罩。In another embodiment, a method of forming an optical device structure is provided. The method includes: depositing a photoresist layer on a patterned hard mask having a plurality of hard mask segments disposed above a device layer or a substrate; exposing the photoresist layer to produce a plurality of photoresist segments; and etching the device layer or the substrate to produce a first step of a flare grating. The method also includes: horizontally trimming the plurality of photoresist segments; and repeatedly etching the device layer or the substrate; and horizontally trimming the plurality of photoresist segments to produce a second step of the flare grating. The method may further include repeatedly etching the device layer and horizontally trimming the plurality of photoresist segments to produce a third step of the blaze grating, and removing the plurality of photoresist segments and the patterned hard mask.
在另外的實施例中,提供了一種形成光學元件結構的方法。該方法包括:在元件層或基板上方設置的圖案化的硬遮罩上沉積光阻劑層;圖案化該光阻劑層以產生複數個光阻劑區段;蝕刻該元件層或該基板以便以第一線寬產生閃耀光柵的第一台階;以及水平地修整該複數個光阻劑區段。該方法亦包括:重複蝕刻該元件層或該基板並水平地修整該複數個光阻劑區段以便以第二線寬產生該閃耀光柵的第二台階;以及移除該複數個光阻劑區段和該圖案化的硬遮罩。在一個態樣中,該第二台階的該第二線寬非均勻地大於該第一台階的該第一線寬。In another embodiment, a method of forming an optical device structure is provided. The method includes: depositing a photoresist layer on a patterned hard mask disposed above a device layer or a substrate; patterning the photoresist layer to produce a plurality of photoresist segments; etching the device layer or the substrate to produce a first step of a flare grating with a first line width; and horizontally trimming the plurality of photoresist segments. The method also includes: repeatedly etching the device layer or the substrate and horizontally trimming the plurality of photoresist segments to produce a second step of the flare grating with a second line width; and removing the plurality of photoresist segments and the patterned hard mask. In one aspect, the second line width of the second stage is non-uniformly larger than the first line width of the first stage.
本文的實施例總體上針對形成具有閃耀光柵的波導結構的方法。該等方法包括將設置在具有圖案化的硬遮罩和偏移圖案化光阻劑的基板上方的元件層暴露於蝕刻劑。Embodiments herein are generally directed to methods of forming a waveguide structure having a blazed grating. The methods include exposing a device layer disposed over a substrate having a patterned hard mask and an offset patterned photoresist to an etchant.
第1A圖是光學元件100的正視圖。應當理解的是,下面描述的光學元件100是示例性光學元件。在可以與本文所述的其他實施例結合的一個實施例中,光學元件100是波導組合器,諸如擴增實境波導組合器。在可以與本文所述的其他實施例結合的另一實施例中,光學元件100是平坦的光學元件,諸如超穎表面。光學元件100包括設置在基板101中(如第1B圖所示)或該基板上(如第1C圖所示)的複數個元件結構。如第1C圖所示,元件結構形成在基板101上形成的元件層103中。元件結構可以是具有亞微米尺寸,例如奈米大小的尺寸,諸如小於1 μm的臨界尺寸的奈米結構。光學元件100包括由複數個光柵106(如第1B圖和第1C圖中所圖示)定義的輸入耦合區域102A、波導區域102B、和輸出耦合區域102C。FIG. 1A is a front view of the optical element 100. It should be understood that the optical element 100 described below is an exemplary optical element. In one embodiment that may be combined with other embodiments described herein, the optical element 100 is a waveguide combiner, such as an augmented reality waveguide combiner. In another embodiment that may be combined with other embodiments described herein, the optical element 100 is a flat optical element, such as a super-surface. The optical element 100 includes a plurality of element structures disposed in a substrate 101 (as shown in FIG. 1B) or on the substrate (as shown in FIG. 1C). As shown in FIG. 1C, the element structure is formed in an element layer 103 formed on the substrate 101. The element structure may be a nanostructure having a submicron size, such as a nano-size size, such as a critical size of less than 1 μm. The optical element 100 includes an input coupling region 102A, a waveguide region 102B, and an output coupling region 102C defined by a plurality of gratings 106 (as illustrated in FIGS. 1B and 1C ).
輸入耦合區域102A接收來自微顯示器的具有一強度的入射光束(虛擬圖像)。該複數個光柵106中的每個光柵將入射束分成複數種模式。零階模式(T0)射束在光學元件100中被折射回來或丟失。正一階模式(T1)射束穿過光學元件100,跨波導區域102B經歷全內反射(total-internal-reflection, TIR)以到達輸出耦合區域102C並輸出以供顯示。負一階模式(T-1)射束在光學元件100中在與T1射束相反的方向上傳播。在繞射階中,僅T1射束經由輸出耦合區域102C輸出到顯示器,而其他模式由於不同的方向性而丟失。因此,至關重要的是提高T1射束強度並降低其他階射束強度以實更高的元件光學效率。一種用於增加T1射束的強度並降低其他階射束的強度的方法是控制複數個光柵106中的每個光柵的形狀。該複數個光柵106中的每個光柵的閃耀形狀提供提高的光學效率。The input coupling region 102A receives an incident light beam (virtual image) with an intensity from the microdisplay. Each of the plurality of gratings 106 divides the incident beam into a plurality of modes. The zero-order mode (T0) beam is refracted back or lost in the optical element 100. The positive first-order mode (T1) beam passes through the optical element 100, undergoes total internal reflection (TIR) across the waveguide region 102B to reach the output coupling region 102C and is output for display. The negative first-order mode (T-1) beam propagates in the optical element 100 in the opposite direction to the T1 beam. In the diffraction order, only the T1 beam is output to the display via the output coupling region 102C, while other modes are lost due to different directivities. Therefore, it is crucial to increase the T1 beam intensity and reduce the intensity of other order beams to achieve higher element optical efficiency. One method for increasing the intensity of the T1 beam and reducing the intensity of other order beams is to control the shape of each of the plurality of gratings 106. The blaze shape of each of the plurality of gratings 106 provides improved optical efficiency.
第1B圖和第1C圖是根據某些實施例的複數個閃耀光柵106的示意性剖視圖。在可以與本文所述的其他實施例組合的一個實施例中,該複數個閃耀光柵106對應於光學元件100的輸入耦合區域102A。本文所述的方法200形成複數個閃耀光柵106。根據可與本文所述的其他實施例組合的一個實施例的波導組合器,可包括閃耀光柵106。閃耀光柵106中的每個閃耀光柵包括閃耀表面108、頂表面109、側壁112、深度h、和線寬d。閃耀表面108具有複數個台階110。在可以與本文所述的其他實施例結合的一個實施例中,閃耀表面108包括至少3個台階110,諸如大於16個台階110,例如32個台階110。閃耀表面108具有閃耀角γ和閃耀線寬d2。閃耀角γ是閃耀表面108與同基板101平行的表面之間的角度以及在基板101的表面法線與閃耀表面108的刻面法線f之間的角度。深度h對應於側壁112的高度,並且線寬d對應於相鄰閃耀光柵106的側壁112之間的距離。閃耀線寬d2對應於線寬d與每個閃耀光柵106的頂表面109的寬度之間的差。FIG. 1B and FIG. 1C are schematic cross-sectional views of a plurality of blazed gratings 106 according to certain embodiments. In one embodiment that can be combined with other embodiments described herein, the plurality of blazed gratings 106 correspond to the input coupling region 102A of the optical element 100. The method 200 described herein forms a plurality of blazed gratings 106. A waveguide combiner according to one embodiment that can be combined with other embodiments described herein may include blazed gratings 106. Each of the blazed gratings 106 includes a blazed surface 108, a top surface 109, a sidewall 112, a depth h, and a line width d. The blazed surface 108 has a plurality of steps 110. In one embodiment that may be combined with other embodiments described herein, the blaze surface 108 includes at least 3 steps 110, such as greater than 16 steps 110, for example 32 steps 110. The blaze surface 108 has a blaze angle γ and a blaze line width d2. The blaze angle γ is the angle between the blaze surface 108 and a surface parallel to the substrate 101 and the angle between the surface normal of the substrate 101 and the facet normal f of the blaze surface 108. The depth h corresponds to the height of the sidewall 112, and the line width d corresponds to the distance between the sidewalls 112 of adjacent blaze gratings 106. The blaze line width d2 corresponds to the difference between the line width d and the width of the top surface 109 of each blaze grating 106.
在可以與本文所述的其他實施例組合的一個實施例中,兩個或更多個閃耀光柵106的閃耀角γ是不同的。在可以與本文所述的其他實施例組合的另一實施例中,該兩個或更多個閃耀光柵106的閃耀角γ是相同的。在可以與本文所述的其他實施例結合的一個實施例中,兩個或更多個閃耀光柵106的深度h是不同的。在可以與本文所述的其他實施例組合的另一實施例中,兩個或更多個閃耀光柵106的深度h是相同的。在可以與本文所述的其他實施例組合的一個實施例中,兩個或更多個閃耀光柵106的線寬d是不同的。在可以與本文所述的其他實施例組合的另一實施例中,一或多個閃耀光柵106的線寬d是相同的。In one embodiment that can be combined with other embodiments described herein, the blaze angles γ of two or more blaze gratings 106 are different. In another embodiment that can be combined with other embodiments described herein, the blaze angles γ of the two or more blaze gratings 106 are the same. In one embodiment that can be combined with other embodiments described herein, the depths h of two or more blaze gratings 106 are different. In another embodiment that can be combined with other embodiments described herein, the depths h of two or more blaze gratings 106 are the same. In one embodiment that can be combined with other embodiments described herein, the line widths d of two or more blaze gratings 106 are different. In another embodiment that can be combined with other embodiments described herein, the line widths d of one or more blaze gratings 106 are the same.
第2圖是用於形成如第3A圖至第3I圖所示的光學元件結構300的複數個閃耀光柵106的方法200的流程圖。在一個實施例中,光學元件結構300對應於光學元件100的輸入耦合區域102A,並且包括在基板302中蝕刻的複數個閃耀光柵,該複數個閃耀光柵類似於第1B圖中所示的在基板101中形成的閃耀光柵106。FIG2 is a flow chart of a method 200 for forming a plurality of blazed gratings 106 of an optical device structure 300 as shown in FIGS. 3A to 3I. In one embodiment, the optical device structure 300 corresponds to the input coupling region 102A of the optical device 100 and includes a plurality of blazed gratings etched in a substrate 302, the plurality of blazed gratings being similar to the blazed gratings 106 formed in the substrate 101 shown in FIG. 1B.
基板302可以是本領域中使用的任何基板,並且取決於基板302作為用於波導的基板的用途,可以對所選波長的光不透明或透明。基板選擇可包括任何合適材料的基板,包括但不限於非晶形介電質、非-非晶形介電質、結晶介電質、聚合物或其組合。在一些實施例中,基板302包括但不限於含矽材料、含矽和氧的化合物、含鍺材料、含銦和磷化物的化合物、含鎵和砷的化合物、含鎵和氮的化合物、含碳材料、含矽和碳的化合物、含矽、碳和氧的化合物、含矽和氮的化合物、含矽、氧和氮的化合物、含鈮和氧的化合物、及含鋰、鈮和氧的化合物、含鋁和氧的化合物、含銦、錫和氧的化合物、含鈦和氧的化合物、含鑭和氧的化合物、含釓和氧的化合物、含鋅和氧的化合物、含釔和氧的化合物、含鎢和氧的化合物、含鉀和氧的化合物、含磷和氧的化合物、含鋇和氧的化合物、含鈉和氧的化合物,或其組合。在可以與本文所述的其他實施例組合的其他實施例中,基板302包含氧化物,該氧化物包括含釓、矽、鈉、鋇、鉀、鎢、磷、鋅、鈣、鈦、鉭、鈮、鑭、鋯、鋰或釔的材料中的一或多者。基板302的示例性材料包括矽(Si)、一氧化矽(SiO)、二氧化矽(SiO 2)、碳化矽(SiC)、熔融矽石、金剛石、石英鍺(Ge)、矽鍺(SiGe)、磷化銦(InP)、砷化鎵(GaAs)、氮化鎵(GaN)、藍寶石、藍寶石(Al 2O 3)、鈮酸鋰(LiNbO 3)、氧化銦錫(indium tin oxide, ITO)、氧化鑭(La 2O 3)、氧化釓(Gd 2O 5)、氧化鋅(ZnO)、氧化釔(Y 2O 3)、氧化鎢(WO 3)、氧化鈦(TiO 2)、氧化鋯(ZrO 3)、氧化鈉(Na 2O)、氧化鈮(Nb 2O 5)、氧化鋇(BaO)、氧化鉀(K 2O)、五氧化二磷(P 2O 5)、氧化鈣(CaO),或其組合。 Substrate 302 may be any substrate used in the art and may be opaque or transparent to selected wavelengths of light depending on the use of substrate 302 as a substrate for a waveguide. Substrate selection may include substrates of any suitable material, including but not limited to amorphous dielectrics, non-amorphous dielectrics, crystalline dielectrics, polymers, or combinations thereof. In some embodiments, the substrate 302 includes, but is not limited to, a silicon-containing material, a silicon and oxygen-containing compound, a germanium-containing material, an indium and phosphide-containing compound, a gallium and arsenic-containing compound, a gallium and nitrogen-containing compound, a carbon-containing material, a silicon and carbon-containing compound, a silicon, carbon and oxygen-containing compound, a silicon and nitrogen-containing compound, a silicon, oxygen and nitrogen-containing compound, a niobium and oxygen-containing compound, and a lithium, niobium and oxygen-containing compound, an aluminum and oxygen-containing compound, an indium, tin and oxygen-containing compound, a titanium and oxygen-containing compound, a lumen and oxygen-containing compound, a gadolinium and oxygen-containing compound, a zinc and oxygen-containing compound, a yttrium and oxygen-containing compound, a tungsten and oxygen-containing compound, a potassium and oxygen-containing compound, a phosphorus and oxygen-containing compound, a barium and oxygen-containing compound, a sodium and oxygen-containing compound, or a combination thereof. In other embodiments that may be combined with other embodiments described herein, the substrate 302 includes an oxide including one or more of a material containing gabbard, silicon, sodium, barium, potassium, tungsten, phosphorus, zinc, calcium, titanium, tantalum, niobium, lumber, zirconium, lithium, or yttrium. Exemplary materials of the substrate 302 include silicon (Si), silicon monoxide (SiO), silicon dioxide (SiO 2 ), silicon carbide (SiC), fused silica, diamond, quartz germanium (Ge), silicon germanium (SiGe), indium phosphide (InP), gallium arsenide (GaAs), gallium nitride (GaN), sapphire, sapphire (Al 2 O 3 ), lithium niobate (LiNbO 3 ), indium tin oxide (ITO), chromium oxide (La 2 O 3 ), gadolinium oxide (Gd 2 O 5 ), zinc oxide (ZnO), yttrium oxide (Y 2 O 3 ), tungsten oxide (WO 3 ), titanium oxide (TiO 2 ), zirconium oxide (ZrO 3 ), sodium oxide (Na 2 O), niobium oxide (Nb 2 O 5 ), barium oxide (BaO), potassium oxide (K 2 O), phosphorus pentoxide (P 2 O 5 ), calcium oxide (CaO), or a combination thereof.
在另一個實施例中,該複數個閃耀光柵被蝕刻在形成於基板302上方的元件層(未圖示)中,類似於第1C圖中所示的在形成於基板101上方的元件層103中形成的閃耀光柵106。在此類實施例中,元件層103和基板101包含不同的材料。元件層103包含但不限於矽、鋁、鋯、錫、鉭、鋯、鋇、鈦、鉿、鋰、鑭、鎘、鈮的一或多種氧化物、碳化物或氮化物,或其組合。元件層103的示例性材料包括碳化矽、氧碳化矽、氧化鈦、二氧化鈦、氧化矽、二氧化矽、氧化釩、氧化鋁、鋁摻雜的氧化鋅、氧化銦錫、氧化錫、氧化鋅、氧化鉭、五氧化二鉭、氮化矽、氮化鈦、氧化鋯、二氧化鋯、氧化鈮、錫酸鎘、氧氮化矽、鈦酸鋇、類金剛石碳、氧化鉿、鈮酸鋰、碳氮化矽、銀、硒化鎘、碲化汞、硒化鋅、銀銦鎵硫、銀銦硫、磷化銦、磷化鎵、硫化鉛、硒化鉛、硫化鋅、硫化鉬、硫化鎢,或其組合。In another embodiment, the plurality of blazed gratings are etched in a device layer (not shown) formed above the substrate 302, similar to the blazed gratings 106 formed in the device layer 103 formed above the substrate 101 shown in FIG. 1C. In such embodiments, the device layer 103 and the substrate 101 comprise different materials. The device layer 103 comprises, but is not limited to, one or more oxides, carbides, or nitrides of silicon, aluminum, zirconium, tin, tantalum, zirconium, barium, titanium, tantalum, lithium, tantalum, cadmium, niobium, or combinations thereof. Exemplary materials for the device layer 103 include silicon carbide, silicon oxycarbide, titanium oxide, titanium dioxide, silicon oxide, silicon dioxide, vanadium oxide, aluminum oxide, aluminum-doped zinc oxide, indium tin oxide, tin oxide, zinc oxide, tantalum oxide, tantalum pentoxide, silicon nitride, titanium nitride, zirconium oxide, tantalum dioxide, and tantalum pentoxide. Zirconium, niobium oxide, cadmium stannate, silicon oxynitride, barium titanate, diamond-like carbon, niobium oxide, lithium niobate, silicon carbonitride, silver, cadmium selenide, mercury telluride, zinc selenide, silver indium gallium sulfide, silver indium sulfide, indium phosphide, gallium phosphide, lead sulfide, lead selenide, zinc sulfide, molybdenum sulfide, tungsten sulfide, or a combination thereof.
在實施例中,在執行方法200之前,可以在基板101上沉積元件層103,以形成第1C圖所示的閃耀光柵106。可以使用任何適合的用於沉積元件層103的方法。合適的薄膜沉積方法的實例包括物理氣相沉積(physical vapor deposition, PVD)製程(例如,離子束濺射、磁控濺射、電子束蒸發)、化學氣相沉積(chemical vapor deposition, CVD)製程、電漿增強化學氣相沉積(plasma enhanced chemical vapor deposition, PECVD)製程、原子層沉積(atomic layer deposition, ALD)製程、噴墨打印製程、或三維(3D)打印製程。In an embodiment, before performing the method 200, a device layer 103 may be deposited on the substrate 101 to form the blazed grating 106 shown in FIG. 1C. Any suitable method for depositing the device layer 103 may be used. Examples of suitable thin film deposition methods include a physical vapor deposition (PVD) process (e.g., ion beam sputtering, magnetron sputtering, electron beam evaporation), a chemical vapor deposition (CVD) process, a plasma enhanced chemical vapor deposition (PECVD) process, an atomic layer deposition (ALD) process, an inkjet printing process, or a three-dimensional (3D) printing process.
如第3A圖所示,在操作201之前,在基板302(或第1C圖的元件層103(若存在))上設置並圖案化硬遮罩306。該圖案化的硬遮罩306包括複數個硬遮罩區段,諸如彼此分離的第一硬遮罩區段306a、第二硬遮罩區段306b、和第三硬遮罩區段306c。圖案化的硬遮罩306的各區段之間的間隔(例如,距離)將確定所產生的每個閃耀光柵結構的階梯表面108的最大寬度。基板302(或第1C圖的元件層103(若存在))的各部分繼而藉由圖案化的硬遮罩306的各區段之間的間隔而暴露。第3B圖是操作201處的基板302的示意性剖視圖。在操作201中,如第3B圖所示,光阻劑層308沉積或以其他方式設置在硬遮罩區段306和基板302的暴露部分(或第1C圖的元件層103(若存在))上方。光阻劑層308的材料是基於基板302蝕刻化學性質(在基板302經蝕刻以形成如第1B圖所示的閃耀光柵結構的實施例中)或元件層103蝕刻化學性質(在元件層103經蝕刻以形成如第1C圖所示的閃耀光柵結構的實施例中)而選擇的。As shown in FIG. 3A , prior to operation 201 , a hard mask 306 is disposed and patterned on a substrate 302 (or the device layer 103 of FIG. 1C (if present)). The patterned hard mask 306 includes a plurality of hard mask segments, such as a first hard mask segment 306a, a second hard mask segment 306b, and a third hard mask segment 306c that are separated from each other. The spacing (e.g., distance) between the segments of the patterned hard mask 306 will determine the maximum width of the step surface 108 of each glare grating structure produced. Portions of the substrate 302 (or the device layer 103 of FIG. 1C (if present)) are then exposed by the spacing between the segments of the patterned hard mask 306. FIG. 3B is a schematic cross-sectional view of a substrate 302 at operation 201. In operation 201, as shown in FIG. 3B, a photoresist layer 308 is deposited or otherwise disposed over the hard mask segments 306 and the exposed portions of the substrate 302 (or the device layer 103 of FIG. 1C, if present). The material of the photoresist layer 308 is selected based on the substrate 302 etch chemistry (in embodiments where the substrate 302 is etched to form a blazed grating structure as shown in FIG. 1B) or the device layer 103 etch chemistry (in embodiments where the device layer 103 is etched to form a blazed grating structure as shown in FIG. 1C).
在操作202中並且如第3C圖所示,藉由微影製程(諸如光微影或數位微影術)或藉由雷射燒蝕製程對光阻劑層308進行圖案化,以形成複數個光阻劑區段310。在實施例中,該複數個光阻劑區段310包括形成在圖案化的硬遮罩306和基板302(或第1C圖的元件層103(若存在))上方的第一光阻劑區段310a、第二光阻劑區段310b、和第三光阻劑區段310c。儘管僅圖示了三個光阻劑區段310a至310c和三個硬遮罩區段306a至306c,但是可以蝕刻整個光阻劑層308和硬遮罩306,使得取決於用於光學元件結構300的預定設計,在基板302(或第1C圖的元件層103(若存在))中形成所需數量的閃耀光柵106。In operation 202 and as shown in FIG. 3C , the photoresist layer 308 is patterned by a lithography process (such as photolithography or digital lithography) or by a laser ablation process to form a plurality of photoresist sections 310. In an embodiment, the plurality of photoresist sections 310 include a first photoresist section 310a, a second photoresist section 310b, and a third photoresist section 310c formed over the patterned hard mask 306 and the substrate 302 (or the device layer 103 of FIG. 1C if present). Although only three photoresist segments 310a to 310c and three hard mask segments 306a to 306c are illustrated, the entire photoresist layer 308 and hard mask 306 can be etched so that a desired number of glare gratings 106 are formed in the substrate 302 (or the device layer 103 of FIG. 1C if present), depending on the intended design for the optical device structure 300.
該複數個光阻劑區段310從硬遮罩區段306偏移,使得光阻劑區段310直接接觸並覆蓋基板302的一部分(或第1C圖的元件層103(若存在)),與此同時暴露各個硬遮罩區段306a、306b、和306c的一部分。進一步,光阻劑區段310不延伸至後續硬遮罩區段(例如,從第一硬遮罩區段306a至第二硬遮罩區段306b)。相反,每個光阻劑區段310都在與相鄰的後續硬遮罩區段306一距離處結束。The plurality of photoresist sections 310 are offset from the hard mask section 306 so that the photoresist section 310 directly contacts and covers a portion of the substrate 302 (or the device layer 103 of FIG. 1C if present), while exposing a portion of each hard mask section 306a, 306b, and 306c. Further, the photoresist section 310 does not extend to a subsequent hard mask section (e.g., from the first hard mask section 306a to the second hard mask section 306b). Instead, each photoresist section 310 ends at a distance from an adjacent subsequent hard mask section 306.
在操作203處,電漿蝕刻劑304接觸基板302,如第3D圖所示。使基板302暴露於與基板302接觸的電漿蝕刻劑304(諸如自由基和離子束)。將基板302(或第1C圖的元件層103(若存在))暴露於電漿蝕刻劑304可以包括蝕刻製程,諸如離子蝕刻和反應性離子蝕刻(reactive ion etching, RIE)。電漿蝕刻劑304將至少一個台階330的複數個深度324(如第3F圖至第3I圖所示)中的第一深度320蝕刻到在圖案化的硬遮罩區段306a至306c與複數個光阻劑區段310之間暴露的基板302(或第1C圖的元件層103(若存在))的各部分中。在操作203之後,除了第一深度320之外,該至少一個台階330亦包括前導側壁344的初始前導側壁部分342(如第3D圖所示)、尾接側壁352、以及從初始前導側壁部分342到尾接側壁352的第一線寬362。第一線寬362由在每個光阻劑區段310的第一側312所限定的前緣平面334與由每個硬遮罩區段306中與基板302(或第1C圖的元件層103(若存在))接觸的暴露側314所限定的後緣平面336之間的距離332控制。距離332對應於第一線寬362,因為電漿蝕刻劑304在距離332之外不接觸基板302(或第1C圖的元件層103(若存在))。At operation 203, a plasma etchant 304 contacts the substrate 302, as shown in FIG. 3D. The substrate 302 is exposed to the plasma etchant 304 (such as free radicals and ion beams) in contact with the substrate 302. Exposing the substrate 302 (or the device layer 103 of FIG. 1C, if present) to the plasma etchant 304 may include an etching process such as ion etching and reactive ion etching (RIE). The plasma etchant 304 etches a first depth 320 of a plurality of depths 324 (as shown in FIGS. 3F to 3I ) of the at least one step 330 into portions of the substrate 302 (or the device layer 103 of FIG. 1C , if present) exposed between the patterned hard mask sections 306 a to 306 c and the plurality of photoresist sections 310. After operation 203, in addition to the first depth 320, the at least one step 330 also includes an initial leading sidewall portion 342 of the leading sidewall 344 (as shown in FIG. 3D ), a trailing sidewall 352, and a first line width 362 from the initial leading sidewall portion 342 to the trailing sidewall 352. The first line width 362 is controlled by a distance 332 between a leading edge plane 334 defined by a first side 312 of each photoresist segment 310 and a trailing edge plane 336 defined by an exposed side 314 in each hard mask segment 306 that contacts the substrate 302 (or the device layer 103 of FIG. 1C if present). The distance 332 corresponds to the first line width 362 because the plasma etchant 304 does not contact the substrate 302 (or the device layer 103 of FIG. 1C if present) outside the distance 332.
在操作204處,藉由各向同性離子蝕刻製程對光阻劑區段310a、310b和310c進行修整,該各向同性離子蝕刻製程使光阻劑區段豎直和水平地凹陷。此操作將距第一線寬362(由第3D圖所示的初始前導側壁部分342至尾接側壁部分352限定)的距離增加到第3F圖所示的前導側壁344至後緣平面334之間的距離332。At operation 204, the photoresist sections 310a, 310b, and 310c are trimmed by an isotropic ion etching process that recesses the photoresist sections vertically and horizontally. This operation increases the distance from the first line width 362 (defined by the initial leading sidewall portion 342 to the trailing sidewall portion 352 shown in FIG. 3D) to the distance 332 between the leading sidewall 344 and the trailing edge plane 334 shown in FIG. 3F.
在可選的操作205處,可重複操作203和204以將至少一個台階330的複數個深度324中的至少一個第二深度322蝕刻到基板302(或第1C圖的元件層103(若存在))中。如第3E圖所示,修整每個光阻劑區段310以減小每個光阻劑區段310的寬度,使得每個光阻劑區段310的第一側312沿著基板302偏移,從而增加距離332。At optional operation 205, operations 203 and 204 may be repeated to etch at least one second depth 322 of the plurality of depths 324 of at least one step 330 into the substrate 302 (or the device layer 103 of FIG. 1C if present). As shown in FIG. 3E, each photoresist section 310 is trimmed to reduce the width of each photoresist section 310 so that the first side 312 of each photoresist section 310 is offset along the substrate 302, thereby increasing the distance 332.
如第3F圖所示,除了第二深度322之外,台階330包括第二前導側壁部分346和從第二前導側壁部分346至尾接側壁部分352的第二線寬364。第二線寬364由藉由可選操作204增加的前緣平面334與後緣平面336之間的距離332控制。由於距離332隨著操作204的每次迭代而增加,因此第二線寬364比第一線寬362更長。距離332對應於第二線寬364,因為電漿蝕刻劑304在距離332之外不接觸基板302(或第1C圖的元件層103(若存在))。如第3E圖所示,在各種實施例中,修整後各光阻劑區段310之間的距離332的增加是均勻的,並且等於第一線寬362的兩倍,例如,第二線寬364為第一線寬362的長度的兩倍,使得至少一個台階330中的每個台階都是對稱的。或者,第二線寬364可非均勻地增加超過第一線寬362,例如非均勻地大於該第一線寬。例如,第二線寬364可以增加第一線寬362的1.5倍,從而產生非對稱階梯光柵或閃耀光柵。類似地,後續線寬可能會對稱或非對稱地增大。As shown in FIG. 3F , in addition to the second depth 322, the step 330 includes a second leading sidewall portion 346 and a second line width 364 from the second leading sidewall portion 346 to the trailing sidewall portion 352. The second line width 364 is controlled by the distance 332 between the leading edge plane 334 and the trailing edge plane 336 increased by the optional operation 204. Since the distance 332 increases with each iteration of the operation 204, the second line width 364 is longer than the first line width 362. The distance 332 corresponds to the second line width 364 because the plasma etchant 304 does not contact the substrate 302 (or the device layer 103 of FIG. 1C if present) outside the distance 332. As shown in FIG. 3E , in various embodiments, the increase in the distance 332 between the photoresist segments 310 after trimming is uniform and equal to twice the first line width 362, for example, the second line width 364 is twice the length of the first line width 362, so that each step in the at least one step 330 is symmetrical. Alternatively, the second line width 364 may be increased non-uniformly beyond the first line width 362, for example, non-uniformly greater than the first line width. For example, the second line width 364 may be increased by 1.5 times the first line width 362, thereby producing an asymmetric step grating or a flare grating. Similarly, subsequent line widths may be increased symmetrically or asymmetrically.
如第3G圖和第3H圖所示,可選的操作205包括在蝕刻至少一個台階330的每個第二深度322之後重複可選的操作204。例如,在可選的操作204處,修整光阻劑區段310,從而進一步增加距離332。在可選的操作203處,創建複數個深度324中的第三深度326,以及第三前導側壁部分348和從第三前導側壁部分348至尾接側壁352的第三線寬366。第三線寬366由前緣平面334與後緣平面336之間的距離控制,並藉由後續可選的操作202增加。距離332對應於第三線寬366,因為電漿蝕刻劑304在距離332之外不接觸基板302(或第1C圖的元件層103(若存在))。As shown in FIGS. 3G and 3H , optional operation 205 includes repeating optional operation 204 after etching each second depth 322 of at least one step 330. For example, at optional operation 204, the photoresist section 310 is trimmed to further increase the distance 332. At optional operation 203, a third depth 326 of the plurality of depths 324 is created, as well as a third leading sidewall portion 348 and a third line width 366 from the third leading sidewall portion 348 to the trailing sidewall 352. The third line width 366 is controlled by the distance between the leading edge plane 334 and the trailing edge plane 336, and is increased by subsequent optional operation 202. The distance 332 corresponds to the third line width 366 because the plasma etchant 304 does not contact the substrate 302 (or the device layer 103 of FIG. 1C if present) beyond the distance 332 .
第3F圖是光學元件結構300的示意性剖視圖。重複操作203和操作204,直到形成光學元件結構300,此時至少一個台階330具有複數個深度324,包括第一深度320和與台階深度相對應的至少一個第二深度322。減小第一深度320和每個第二深度322將導致至少一個台階330的更光滑的前導側壁344。FIG. 3F is a schematic cross-sectional view of the optical element structure 300. Operations 203 and 204 are repeated until the optical element structure 300 is formed, at which time at least one step 330 has a plurality of depths 324, including a first depth 320 and at least one second depth 322 corresponding to the step depth. Reducing the first depth 320 and each second depth 322 will result in a smoother leading sidewall 344 of the at least one step 330.
第3I圖是方法200的操作206之後的光學元件結構300的示意性剖視圖。在一個實施例中,圖案化的硬遮罩306和至少一個光阻劑層308包含非透明材料,該等非透明材料在形成光學元件結構300之後在操作206處移除,如第3I圖所示。例如,圖案化的硬遮罩306和至少一個光阻劑層308包括反射材料,諸如Cr或銀(Ag)。在另一個實施例中,圖案化的硬遮罩306和光阻劑層308包括透明材料,使得圖案化的硬遮罩306和至少一個光阻劑層308在形成光學元件結構300之後保留。FIG. 3I is a schematic cross-sectional view of the optical element structure 300 after operation 206 of the method 200. In one embodiment, the patterned hard mask 306 and the at least one photoresist layer 308 include non-transparent materials, which are removed at operation 206 after forming the optical element structure 300, as shown in FIG. 3I. For example, the patterned hard mask 306 and the at least one photoresist layer 308 include reflective materials, such as Cr or silver (Ag). In another embodiment, the patterned hard mask 306 and the photoresist layer 308 include transparent materials, so that the patterned hard mask 306 and the at least one photoresist layer 308 remain after forming the optical element structure 300.
在操作206之後,至少一個步驟330保留並且形成閃耀光柵106的結構。儘管第3I圖中僅圖示了三個台階,但是可以重複可選的操作204以產生所需量的台階,諸如5個、諸如10個、諸如25個。隨著台階數量的增加,值得注意的是,每個台階(例如,362、364)的線寬可能會減小,從而為每個閃耀光柵106產生更光滑的前導側壁部分(例如,342、344)或閃耀表面108。After operation 206, at least one step 330 is performed to retain and form the structure of the blazed grating 106. Although only three steps are illustrated in FIG. 3I, the optional operation 204 may be repeated to produce a desired number of steps, such as 5, such as 10, such as 25. As the number of steps increases, it is noted that the line width of each step (e.g., 362, 364) may be reduced, thereby producing a smoother leading sidewall portion (e.g., 342, 344) or blazed surface 108 for each blazed grating 106.
本揭露案的優點提供了一種用於使用標準微影和蝕刻製程形成用於AR波導的閃耀光柵的可擴展方法。例如,方法200可以藉由以下方式使得能夠形成複數個閃耀光柵106:蝕刻複數個階梯台階來以形成各個閃耀光柵106的閃耀表面108,該閃耀表面繼而各自近似於連續的閃耀輪廓。為了提高繞射效率,AR波導中通常需要閃耀光柵。An advantage of the present disclosure is that a scalable method for forming a blazed grating for an AR waveguide using standard lithography and etching processes is provided. For example, the method 200 can enable forming a plurality of blazed gratings 106 by etching a plurality of step steps to form a blazed surface 108 of each blazed grating 106, which in turn each approximates a continuous blazed profile. Blazed gratings are often required in AR waveguides to improve diffraction efficiency.
當介紹本揭露的要素或其示例性態樣或實施例時,冠詞「一(a)」、「一(an)」、「該」和「所述」旨在表示存在一或多個要素。When introducing elements of the present disclosure or exemplary aspects or embodiments thereof, the articles "a," "an," "the," and "said" are intended to mean that there are one or more of the elements.
術語「包含」、「包括」和「具有」旨在是包括性的,並且意謂除了所列出的要素之外,亦可以有另外的要素。The terms “comprising,” “including,” and “having” are intended to be inclusive and mean that there may be additional elements other than the listed elements.
本文使用術語「耦合」來指兩個物體之間的直接或間接耦合。例如,若物體A實體地觸碰物體B並且物體B觸碰物體C,則物體A和C仍可被視為彼此耦合—即使物體A和C沒有直接彼此實體觸碰。例如,即使第一物體從未與第二物體直接實體接觸,第一物體亦可能與第二物體耦合。The term "coupled" is used herein to refer to direct or indirect coupling between two objects. For example, if object A physically touches object B and object B touches object C, then objects A and C may still be considered coupled to each other—even if objects A and C are not directly physically touching each other. For example, a first object may be coupled to a second object even if the first object has never been in direct physical contact with the second object.
儘管前面針對本揭示案的實施例,但是在不脫離本揭示案的基本範疇的情況下可以設計本揭示案的其他和進一步實施例,並且本揭示案的範疇由所附申請專利範圍確定。While the foregoing is directed to embodiments of the present disclosure, other and further embodiments of the present disclosure may be devised without departing from the basic scope of the present disclosure, and the scope of the present disclosure is determined by the appended claims.
100:光學元件 101:基板 102A:輸入耦合區域 102B:波導區域 102C:輸出耦合區域 103:元件層 106:光柵 108:表面 109:頂表面 110:台階 112:側壁 200:方法 201:操作 202:操作 203:操作 204:操作 205:操作 206:操作 300:光學元件結構 302:基板 304:電漿蝕刻劑 306:硬遮罩 306a-306c:硬遮罩區段 308:光阻劑層 310:光阻劑區段 310a-310c:光阻劑區段 312:第一側 314:側面 320:第一深度 322:第二深度 324:深度 326:第三深度 330:台階 332:距離 334:邊緣平面 336:邊緣平面 342:初始前導側壁部分 344:前導側壁 346:第二前導側壁部分 348:第三前導側壁部分 352:側壁 362:第一線寬 364:第二線寬 366:第三線寬 100: optical element 101: substrate 102A: input coupling region 102B: waveguide region 102C: output coupling region 103: element layer 106: grating 108: surface 109: top surface 110: step 112: sidewall 200: method 201: operation 202: operation 203: operation 204: operation 205: operation 206: operation 300: optical element structure 302: substrate 304: plasma etchant 306: hard mask 306a-306c: hard mask segment 308: photoresist layer 310: photoresist segment 310a-310c: photoresist section 312: first side 314: side 320: first depth 322: second depth 324: depth 326: third depth 330: step 332: distance 334: edge plane 336: edge plane 342: initial leading sidewall portion 344: leading sidewall 346: second leading sidewall portion 348: third leading sidewall portion 352: sidewall 362: first line width 364: second line width 366: third line width
為了能夠詳細理解本揭示案的上述特徵,可以參考實施例對以上簡要概述的本揭示案進行更特別的描述,實施例中的一些實施例在附圖中圖示。然而,應當注意的是,附圖僅圖示了本揭露案的示例性實施例,並且因此不應被視為是對其範疇的限制,並且本揭露案可以允許其他同等有效的實施例。In order to understand the above features of the present disclosure in detail, the present disclosure briefly summarized above will be described in more detail with reference to the embodiments, some of which are illustrated in the accompanying drawings. However, it should be noted that the accompanying drawings illustrate only exemplary embodiments of the present disclosure and therefore should not be considered as limiting the scope thereof, and the present disclosure may allow other equally effective embodiments.
第1A圖是根據某些實施例的光學元件的透視正視圖。FIG. 1A is a perspective front view of an optical element according to certain embodiments.
第1B圖和第1C圖是根據某些實施例的複數個元件結構的示意性剖視圖。1B and 1C are schematic cross-sectional views of multiple component structures according to certain embodiments.
第2圖是根據某些實施例的用於形成光學元件結構的方法的流程圖。FIG. 2 is a flow chart of a method for forming an optical element structure according to certain embodiments.
第3A圖至第3I圖是根據某些實施例,經歷用於形成第2圖的波導結構的方法的波導結構的示意性剖視圖。3A to 3I are schematic cross-sectional views of a waveguide structure undergoing a method for forming the waveguide structure of FIG. 2 according to certain embodiments.
為了促進理解,在可能的情況下,使用相同的附圖標記來表示附圖中共用的元件。預期一個實施例的元件和特徵可以有益地結合到其他實施例中,而無需進一步敘述。To facilitate understanding, identical reference numerals have been used, where possible, to designate common elements among the figures. It is contemplated that elements and features of one embodiment may be beneficially incorporated in other embodiments without further recitation.
200:方法 200:Methods
201:操作 201: Operation
202:操作 202: Operation
203:操作 203: Operation
204:操作 204: Operation
205:操作 205: Operation
206:操作 206: Operation
Claims (20)
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| US202363596108P | 2023-11-03 | 2023-11-03 | |
| US63/596,108 | 2023-11-03 |
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| TW202522062A true TW202522062A (en) | 2025-06-01 |
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| US6475704B1 (en) * | 1997-09-12 | 2002-11-05 | Canon Kabushiki Kaisha | Method for forming fine structure |
| JP2000098116A (en) * | 1998-09-18 | 2000-04-07 | Canon Inc | Method of producing element or mold for element production |
| JP2001074924A (en) * | 1999-09-03 | 2001-03-23 | Canon Inc | Manufacturing method of diffractive optical element |
| JP5864920B2 (en) * | 2010-12-20 | 2016-02-17 | キヤノン株式会社 | Manufacturing method of diffraction grating |
| CN102540298B (en) * | 2012-02-01 | 2013-10-16 | 中国科学技术大学 | Soft X-ray double-frequency gratings and manufacture method thereof |
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