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TW202449235A - Electroplating equipment and electroplating system - Google Patents

Electroplating equipment and electroplating system Download PDF

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TW202449235A
TW202449235A TW113118464A TW113118464A TW202449235A TW 202449235 A TW202449235 A TW 202449235A TW 113118464 A TW113118464 A TW 113118464A TW 113118464 A TW113118464 A TW 113118464A TW 202449235 A TW202449235 A TW 202449235A
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plating
electroplating
liquid
anode
tank
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TW113118464A
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汪若飛
楊宏超
王堅
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大陸商盛美半導體設備(上海)股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/002Cell separation, e.g. membranes, diaphragms
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/10Electrodes, e.g. composition, counter electrode
    • C25D17/12Shape or form
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/04Removal of gases or vapours ; Gas or pressure control
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D21/00Processes for servicing or operating cells for electrolytic coating
    • C25D21/12Process control or regulation
    • C25D21/14Controlled addition of electrolyte components
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/48Electroplating: Baths therefor from solutions of gold
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/08Electroplating with moving electrolyte e.g. jet electroplating
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/12Semiconductors

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Automation & Control Theory (AREA)
  • Electroplating Methods And Accessories (AREA)

Abstract

An electroplating apparatus and an electroplating system. The electroplating apparatus comprises: an electroplating bath used for accommodating an electroplating solution and a substrate; a non-soluble anode provided inside the electroplating bath and located below the substrate; an anode solution inlet used for supplying the electroplating solution into the electroplating bath; and an anode solution outlet used for discharging the electroplating solution from the electroplating bath. The anode solution inlet is higher than the non-soluble anode and the anode solution outlet, such that the electroplating solution flows in a first direction away from the substrate between the anode solution inlet and the anode solution outlet during electroplating; the flow velocity of the electroplating solution in the electroplating bath is set such that the electroplating solution applies an acting force toward the first direction to bubbles generated on the surface of the non-soluble anode; and the acting force is greater than the buoyancy of the bubbles, such that the bubbles are away from the substrate, thereby overcoming the problem of the quality of the substrate being affected due to the non-soluble anode generating more bubbles during electroplating of the substrate.

Description

電鍍裝置及電鍍系統Electroplating equipment and electroplating system

本發明涉及半導體電鍍設備領域,進一步地涉及一種電鍍裝置及電鍍系統。The present invention relates to the field of semiconductor electroplating equipment, and further relates to an electroplating device and an electroplating system.

基板電鍍製程是指在晶片製造過程中,將電鍍液中的金屬離子電鍍到基板表面形成金屬互連的製程。The substrate plating process refers to the process of electroplating metal ions in the plating solution onto the substrate surface to form metal interconnects during the chip manufacturing process.

用於執行基板電鍍製程的電鍍設備一般具有可溶性陽極,可溶性陽極可以通過自身的溶解來補充電鍍液中消耗的金屬離子,有利於維持電鍍液中的金屬離子濃度。但是,可溶性陽極也有其自身缺陷。The electroplating equipment used to perform the substrate electroplating process generally has a soluble anode, which can replenish the metal ions consumed in the electroplating solution by dissolving itself, which is beneficial to maintaining the metal ion concentration in the electroplating solution. However, the soluble anode also has its own defects.

以對基板執行銅電鍍製程採用的可溶性的銅陽極為例,在實踐中發現,在進行基板電鍍製程時,存在以下缺陷:Taking the soluble copper anode used in the copper electroplating process on the substrate as an example, it is found in practice that the following defects exist during the substrate electroplating process:

1.隨著銅陽極的消耗,銅陽極與作為陰極的基板之間距離發生變化,易導致銅的非均勻沉積。圖1和圖2分別為電鍍前後銅陽極215的狀態示意圖。如圖1和圖2所示,在電鍍的過程中,因為銅陽極215不斷消耗,造成銅陽極215與作為陰極的基板100之間的距離不斷變大,即銅陽極215與基板100之間的距離由電鍍前的距離d1增加為電鍍後的距離d2,且銅陽極215表面形狀一直在變化,這些均會造成基板100和銅陽極215之間的電場分佈不均勻,進而致使基板100表面銅的非均勻沉積。1. As the copper anode is consumed, the distance between the copper anode and the substrate serving as the cathode changes, which can easily lead to non-uniform deposition of copper. FIG1 and FIG2 are schematic diagrams of the copper anode 215 before and after electroplating, respectively. As shown in FIG. 1 and FIG. 2 , during the electroplating process, the copper anode 215 is continuously consumed, causing the distance between the copper anode 215 and the substrate 100 serving as the cathode to continuously increase, that is, the distance between the copper anode 215 and the substrate 100 increases from the distance d1 before electroplating to the distance d2 after electroplating, and the surface shape of the copper anode 215 is constantly changing, all of which will cause uneven distribution of the electric field between the substrate 100 and the copper anode 215, thereby causing uneven deposition of copper on the surface of the substrate 100.

2.電鍍銅製程一般採用含磷的銅陽極,但是含磷的銅陽極消耗時,其表面會生產一層黑色的陽極泥(主要成分是磷化銅Cu 3P 2),產生的陽極泥要定期維護,過多的陽極泥會堵塞管道和離子膜。 2. The electroplating copper process generally uses phosphorus-containing copper anodes. However, when the phosphorus-containing copper anode is consumed, a layer of black anodic mud (the main component is copper phosphide Cu 3 P 2 ) will be produced on its surface. The produced anodic mud needs to be maintained regularly. Too much anodic mud will clog the pipes and ion membranes.

3.需要定期停產停線補充或更換消耗的陽極。3. It is necessary to stop production and production line regularly to replenish or replace consumed anodes.

鑒於上述使用可溶性陽極進行電鍍時存在的缺陷,現有技術提出了利用非可溶性陽極代替可溶性陽極的技術方案。In view of the above-mentioned defects when using soluble anodes for electroplating, the prior art proposes a technical solution of using non-soluble anodes to replace soluble anodes.

在基板電鍍期間,非可溶性陽極不隨電鍍反應的進程而消耗,使得非可溶性陽極表面形狀保持不變,且非可溶性陽極與基板之間的距離保持不變,因此,使用非可溶性陽極能夠保持陽極與陰極之間的電場均勻分佈,有利於獲得良好的電鍍均勻性。During the electroplating of the substrate, the insoluble anode is not consumed as the electroplating reaction progresses, so that the surface shape of the insoluble anode remains unchanged, and the distance between the insoluble anode and the substrate remains unchanged. Therefore, the use of the insoluble anode can maintain a uniform distribution of the electric field between the anode and the cathode, which is conducive to obtaining good electroplating uniformity.

但在使用非可溶性陽極電鍍基板期間,作為陰極的基板表面發生還原反應,將電鍍液中的金屬離子還原成固態金屬;非可溶性陽極表面發生氧化反應,將電鍍液中的水電解生成氧氣,從而導致非可溶性陽極表面產生氣泡。以電鍍銅為例,使用非可溶性陽極將發生如下反應:However, when using a non-soluble anode to electroplate a substrate, a reduction reaction occurs on the surface of the substrate, which is the cathode, reducing the metal ions in the electroplating solution to solid metal; an oxidation reaction occurs on the surface of the non-soluble anode, electrolyzing the water in the electroplating solution to generate oxygen, which causes bubbles to form on the surface of the non-soluble anode. Taking copper electroplating as an example, the following reactions will occur when using a non-soluble anode:

陰極:Cu 2++2e=Cu; Cathode: Cu 2+ +2e=Cu;

陽極:2H 2O-4e=O 2+4H +Anode: 2H 2 O-4e=O 2 +4H + ;

總反應:2CuSO 4+2H 2O=2Cu+O 2+2H 2SO 4Overall reaction: 2CuSO 4 +2H 2 O=2Cu+O 2 +2H 2 SO 4 .

在實際應用中,若非可溶性陽極表面產生的氣泡附著於基板表面會導致鍍層上形成凹孔,影響基板品質,這在一定程度上阻礙了非可溶性陽極在基板電鍍領域的應用。In practical applications, if the bubbles generated on the surface of the non-soluble anode adhere to the surface of the substrate, it will cause pits to form on the coating, affecting the quality of the substrate. This, to a certain extent, hinders the application of non-soluble anodes in the field of substrate electroplating.

綜上所述,如何克服非可溶性陽極在基板電鍍期間產生的氣泡對基板品質的影響,是本領域技術人員迫切需要解決的技術問題。In summary, how to overcome the influence of bubbles generated by non-soluble anodes during substrate electroplating on substrate quality is a technical problem that technicians in this field urgently need to solve.

針對上述技術問題,本發明的目的在於克服非可溶性陽極在基板電鍍期間會產生大量氣泡,影響基板品質的問題,為了實現上述目的,本發明提供了一種電鍍裝置及電鍍系統。In view of the above technical problems, the purpose of the present invention is to overcome the problem that a large number of bubbles will be generated by the non-soluble anode during the electroplating of the substrate, which affects the quality of the substrate. In order to achieve the above purpose, the present invention provides a plating device and a plating system.

在一些實施方式中,該電鍍裝置,用於將金屬電鍍到基板上基板,包括:鍍槽,用於容納電鍍液和所述基板;非可溶性陽極,配置於所述鍍槽內部且位於所述基板下方;陽極液入口,用於向所述鍍槽內供應電鍍液;陽極液出口,用於從所述鍍槽排放電鍍液;其中,所述陽極液入口高於所述非可溶性陽極和所述陽極液出口,以使在進行電鍍作業時所述電鍍液在所述陽極液入口和所述陽極出液口之間沿遠離所述基板的第一方向流動,且所述電鍍槽內的電鍍液流速被配置為,使電鍍液對所述非可溶性陽極表面產生的氣泡施加朝向所述第一方向的作用力,且所述作用力大於所述氣泡的浮力,以使所述氣泡遠離所述基板。In some embodiments, the electroplating device is used to electroplate metal onto a substrate, comprising: a plating tank for containing a plating solution and the substrate; an insoluble anode disposed inside the plating tank and below the substrate; an anodic liquid inlet for supplying the plating solution into the plating tank; and an anodic liquid outlet for discharging the plating solution from the plating tank; wherein the anodic liquid inlet is higher than the insoluble anode and the substrate. The anodic liquid outlet is configured so that the plating liquid flows between the anodic liquid inlet and the anodic liquid outlet along a first direction away from the substrate during the electroplating operation, and the flow rate of the plating liquid in the plating tank is configured so that the plating liquid exerts a force in the first direction on the bubbles generated on the surface of the insoluble anode, and the force is greater than the buoyancy of the bubbles, so that the bubbles are away from the substrate.

進一步地,所述鍍槽的底部呈錐形或半球形,所述陽極液出口位於所述鍍槽底部中心。Furthermore, the bottom of the plating tank is conical or hemispherical, and the anodic liquid outlet is located at the center of the bottom of the plating tank.

進一步地,還包括導流板元件,配置於所述非可溶性陽極與所述陽極液出口之間。Furthermore, it also includes a guide plate element, which is arranged between the insoluble anode and the anode liquid outlet.

進一步地,所述導流板元件包括若干間隔排布的導流板,至少兩相鄰所述導流板的間隔沿所述第一方向逐漸減小,以形成所述電鍍液的流動通道。Furthermore, the guide plate element includes a plurality of guide plates arranged at intervals, and the interval between at least two adjacent guide plates gradually decreases along the first direction to form a flow channel for the electroplating solution.

進一步地,還包括離子膜,設置在所述鍍槽的內部,所述離子膜將所述鍍槽的內部沿豎直分隔為陰極區和陽極區,所述陽極液入口和所述陽極液出口均位於所述陽極區,所述基板位於所述陰極區。Furthermore, it also includes an ion membrane, which is arranged inside the plating tank. The ion membrane vertically divides the inside of the plating tank into a cathode area and an anode area. The anode liquid inlet and the anode liquid outlet are both located in the anode area, and the substrate is located in the cathode area.

進一步地,多個所述陽極液入口設置在所述鍍槽的側壁上,且所述陽極液入口間隔分佈於所述鍍槽的同一水準高度。Furthermore, a plurality of the anodic liquid inlets are arranged on the side wall of the plating tank, and the anodic liquid inlets are spaced and distributed at the same level of the plating tank.

進一步地,該電鍍裝置還包括:電鍍液供給管路、電鍍液排放管路和液泵,所述電鍍液供給管路與所述陽極液入口相連,用於將電鍍液通過所述陽極液入口供應至所述鍍槽內;所述電鍍液排放管路與所述陽極液出口相連,用於將電鍍液通過所述陽極液出口排放出去;所述液泵裝設於所述電鍍液供給管路和/或電鍍液排放管路,用於調節所述鍍槽內的電鍍液流速。Furthermore, the electroplating device also includes: a plating liquid supply pipeline, a plating liquid discharge pipeline and a liquid pump, wherein the plating liquid supply pipeline is connected to the anodic liquid inlet and is used to supply the plating liquid to the plating tank through the anodic liquid inlet; the plating liquid discharge pipeline is connected to the anodic liquid outlet and is used to discharge the plating liquid through the anodic liquid outlet; the liquid pump is installed in the plating liquid supply pipeline and/or the plating liquid discharge pipeline and is used to adjust the flow rate of the plating liquid in the plating tank.

進一步地,該電鍍裝置還包括:電源,用於為所述非可溶性陽極和所述基板供電。Furthermore, the electroplating device also includes: a power source for supplying power to the insoluble anode and the substrate.

進一步地,該電鍍裝置還包括:供液裝置,用於為所述電鍍裝置提供電鍍液。Furthermore, the electroplating device also includes: a liquid supply device, which is used to provide electroplating liquid to the electroplating device.

在一些實施方式中,該電鍍系統,包括上述的電鍍裝置,還包括:供液裝置,用於為所述電鍍裝置提供電鍍液。In some embodiments, the electroplating system includes the above-mentioned electroplating device and further includes: a liquid supply device for providing plating liquid to the electroplating device.

進一步地,該電鍍系統中供液裝置還包括:溶解槽,用於向所述鍍槽供應電鍍液;粉末計量添加裝置,用於向所述溶解槽供應金屬粉末;電流計量裝置,用於檢測電源的輸出電量;控制器,被配置為當所述電流計量裝置檢測到所述電源的輸出電量每增加預設安培小時時,控制所述粉末計量添加裝置添加預定量的所述金屬粉末。Furthermore, the liquid supply device in the electroplating system also includes: a dissolving tank for supplying plating liquid to the plating tank; a powder metering and adding device for supplying metal powder to the dissolving tank; a current metering device for detecting the output power of the power source; and a controller configured to control the powder metering and adding device to add a predetermined amount of the metal powder when the current metering device detects that the output power of the power source increases by a preset ampere-hour.

進一步地,該電鍍系統還包括:緩衝槽,連接於所述鍍槽與所述溶解槽之間,用於暫存及混合所述溶解槽和所述鍍槽之間迴圈流動的電鍍液。Furthermore, the electroplating system also includes: a buffer tank connected between the plating tank and the dissolving tank, used to temporarily store and mix the electroplating solution circulating between the dissolving tank and the plating tank.

進一步地,所述溶解槽內包括攪拌裝置和/或溫度控制裝置。Furthermore, the dissolving tank includes a stirring device and/or a temperature control device.

與現有技術相比,本發明具有以下有益效果:Compared with the prior art, the present invention has the following beneficial effects:

1、在非可溶性陽極上方製造向下的電鍍液流向,使電鍍液對氣泡產生遠離基板的作用力,以使氣泡難以靠近或附著於基板表面,避免基板鍍層形成凹孔;1. Create a downward plating solution flow above the insoluble anode so that the plating solution exerts a force on the bubbles to move away from the substrate, making it difficult for the bubbles to approach or adhere to the substrate surface, thus avoiding the formation of concave holes in the substrate coating;

2、設置多個陽極液入口,且將陽極液出口設計在不溶性陽極下方,配合導流板和鍍槽的錐形或球形底部,可使流經非可溶性陽極表面的電鍍液流速基本一致,使非可溶性陽極表面各處與電鍍液的反應速度基本一致,使電鍍液對非可溶性陽極表面各處氣泡的作用力基本一致;2. Multiple anodic liquid inlets are provided, and the anodic liquid outlet is designed below the insoluble anode. In combination with the guide plate and the conical or spherical bottom of the plating tank, the flow rate of the plating liquid flowing through the surface of the insoluble anode can be basically consistent, the reaction rate of the insoluble anode surface and the plating liquid at various locations can be basically consistent, and the force of the plating liquid on the bubbles at various locations on the surface of the insoluble anode can be basically consistent;

3、通過離子膜將鍍槽內分隔為陽極區和陰極區,一方面,可用於阻止電鍍期間陰極區的添加劑進入陽極,被氧化分解掉;另一方面,可用於防止陽極液入口輸入到陽極區內1微米以下的固態顆粒進入陰極區,黏附到基板表面,影響良率;3. The ion membrane is used to separate the plating tank into the anode area and the cathode area. On the one hand, it can be used to prevent the additives in the cathode area from entering the anode during electroplating and being oxidized and decomposed; on the other hand, it can be used to prevent solid particles below 1 micron that are input into the anode area through the anode liquid inlet from entering the cathode area and adhering to the substrate surface, affecting the yield;

4、通過使用不溶性陽極,基板電鍍期間陽極不會被消耗,其形狀和位置能夠保持不變,能提供穩定均勻的電場分佈,電鍍的均勻性得到保證。且相比較磷銅陽極,不溶性陽極表面不會發生陽極鈍化,能允許更高的陽極電流密度,且維護成本較低。4. By using insoluble anodes, the anode will not be consumed during the substrate electroplating, and its shape and position can remain unchanged, providing a stable and uniform electric field distribution, and the uniformity of electroplating is guaranteed. Compared with phosphorus copper anodes, the surface of insoluble anodes will not passivate, allowing higher anode current density and lower maintenance costs.

為了更清楚地說明本發明實施例或現有技術中的技術方案,下面將對照圖式說明本發明的具體實施方式。顯而易見地,下面描述中的圖式僅僅是本發明的一些實施例,對於本領域普通技術人員來講,在不付出創造性勞動的前提下,還可以根據這些圖式獲得其他的圖式,並獲得其他的實施方式。In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the specific implementation of the present invention will be described below with reference to the drawings. Obviously, the drawings described below are only some embodiments of the present invention, and for ordinary technicians in this field, other drawings and other implementations can be obtained based on these drawings without creative labor.

為使圖面簡潔,各圖中只示意性地表示出了與發明相關的部分,它們並不代表其作為產品的實際結構。另外,以使圖面簡潔便於理解,在有些圖中具有相同結構或功能的部件,僅示意性地繪示了其中的一個,或僅標出了其中的一個。在本文中,“一個”不僅表示“僅此一個”,也可以表示“多於一個”的情形。In order to simplify the drawings, only the parts related to the invention are schematically shown in each figure, and they do not represent the actual structure of the product. In addition, in order to simplify the drawings and facilitate understanding, in some figures, only one of the parts with the same structure or function is schematically drawn or marked. In this article, "one" not only means "only one", but also means "more than one".

在本文中,需要說明的是,除非另有明確的規定和限定,術語“安裝”、“相連”、“連接”應做廣義理解,例如,可以是固定連接,也可以是可拆卸連接,或一體地連接;可以是機械連接,也可以是電連接;可以是直接相連,也可以通過中間媒介間接相連,可以是兩個元件內部的連通。對於本領域的普通技術人員而言,可以具體情況理解上述術語在本發明中的具體含義。In this article, it should be noted that, unless otherwise clearly specified and limited, the terms "installation", "connection" and "connection" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium, or it can be a connection between two components. For ordinary technicians in this field, the specific meanings of the above terms in the present invention can be understood according to specific circumstances.

另外,在本申請的描述中,術語“第一”、“第二”等僅用於區分描述,而不能理解為指示或暗示相對重要性。In addition, in the description of the present application, the terms "first", "second", etc. are only used to distinguish the descriptions and cannot be understood as indicating or implying relative importance.

如圖3所示,本實施例公開了一種電鍍裝置21,該電鍍裝置21用於基板電鍍工藝,即將金屬電鍍到基板100上。As shown in FIG. 3 , the present embodiment discloses a plating device 21, which is used for a substrate plating process, that is, plating metal onto a substrate 100.

如圖3所示,該電鍍裝置21配置為對基板100進行電鍍,具有用於容納電鍍液和基板100的鍍槽210,鍍槽210內部設置有非可溶性陽極213,被鍍基板100可固定於非可溶性陽極213上方。圖3中虛線表示電鍍液的液位。陽極液入口216用於向鍍槽210供應電鍍液;陽極液出口217用於排出鍍槽210中的電鍍液。電鍍裝置21還配置有電源260(如圖5所示),用於為非可溶性陽極213和被鍍基板100供電。需要說明的是,在本申請中,金屬離子指電鍍到基板上的金屬的離子。As shown in FIG3 , the electroplating device 21 is configured to electroplate the substrate 100, and has a plating tank 210 for containing the plating solution and the substrate 100, and a non-soluble anode 213 is arranged inside the plating tank 210, and the substrate 100 to be plated can be fixed above the non-soluble anode 213. The dotted line in FIG3 represents the liquid level of the plating solution. The anode liquid inlet 216 is used to supply the plating solution to the plating tank 210; the anode liquid outlet 217 is used to discharge the plating solution in the plating tank 210. The electroplating device 21 is also configured with a power supply 260 (as shown in FIG5 ) for supplying power to the non-soluble anode 213 and the substrate 100 to be plated. It should be noted that, in the present application, metal ions refer to ions of metal plated onto a substrate.

其中,非可溶性陽極213為網狀或板狀結構。若選用板狀結構的非可溶性陽極213,可在非可溶性陽極213表面設置若干上下導通的通孔,或在非可溶性陽極213邊緣與鍍槽210內壁之間預設間隙,以便電鍍液從上述通孔或間隙向非可溶性陽極213下方的陽極液出口217流動。此外,非可溶性陽極213可選用鈦為基材,在其表面塗覆銥、鉭、鉑金等貴金屬塗層,也可選用鉛、碳、鉑、石墨、鎳、不銹鋼、鉛合金和鑄造的磁性氧化鐵等材質。The insoluble anode 213 is a mesh or plate structure. If a plate-shaped insoluble anode 213 is used, a plurality of through holes that are connected up and down can be set on the surface of the insoluble anode 213, or a gap can be preset between the edge of the insoluble anode 213 and the inner wall of the plating tank 210, so that the plating solution can flow from the above-mentioned through holes or gaps to the anode liquid outlet 217 below the insoluble anode 213. In addition, the insoluble anode 213 may use titanium as a substrate, and a precious metal coating such as iridium, tantalum, platinum, etc. may be coated on its surface. Alternatively, materials such as lead, carbon, platinum, graphite, nickel, stainless steel, lead alloy, and cast magnetic iron oxide may be used.

在本實施例中,為解決採用非可溶性陽極213時,在電鍍裝置21執行基板電鍍過程中,非可溶性陽極213表面處電鍍液中的水電解產生大量氣泡,影響基板品質的問題。陽極液入口216被構造為高於非可溶性陽極213和陽極液出口217。在圖3所示示例中,陽極液入口216設置在鍍槽210側壁,且高於非可溶性陽極213;陽極液出口217設置在鍍槽210底部,且位於非可溶性陽極213下方。由於陽極液入口216位於陽極液出口217和非可溶性陽極213上方,因此,在進行電鍍作業時,電鍍液在陽極液入口216和陽極液出口217之間沿遠離基板100的第一方向d流動,進而可以通過電鍍液的流向阻止非可溶性陽極213表面產生的氣泡向上浮動。此外,鍍槽210內的電鍍液流速被配置為:使電鍍液對氣泡施加朝向第一方向d的作用力,且上述作用力大於上述氣泡的浮力,以使上述氣泡遠離基板100,從而避免氣泡上浮並附著於基板100表面,導致鍍層上形成凹孔,影響基板品質。In this embodiment, in order to solve the problem that when the insoluble anode 213 is used, during the electroplating process of the substrate in the electroplating device 21, the water in the electroplating solution at the surface of the insoluble anode 213 is electrolyzed to generate a large number of bubbles, which affects the quality of the substrate. The anodic liquid inlet 216 is constructed to be higher than the insoluble anode 213 and the anodic liquid outlet 217. In the example shown in FIG. 3, the anodic liquid inlet 216 is arranged on the side wall of the plating tank 210 and is higher than the insoluble anode 213; the anodic liquid outlet 217 is arranged at the bottom of the plating tank 210 and is located below the insoluble anode 213. Since the anodic liquid inlet 216 is located above the anodic liquid outlet 217 and the insoluble anode 213, during the electroplating operation, the electroplating liquid flows between the anodic liquid inlet 216 and the anodic liquid outlet 217 along the first direction d away from the substrate 100, thereby preventing the bubbles generated on the surface of the insoluble anode 213 from floating upwards through the flow direction of the electroplating liquid. In addition, the flow rate of the electroplating liquid in the plating tank 210 is configured such that the electroplating liquid exerts a force on the bubbles in the first direction d, and the force is greater than the buoyancy of the bubbles, so that the bubbles are away from the substrate 100, thereby preventing the bubbles from floating up and adhering to the surface of the substrate 100, resulting in the formation of concave holes on the coating, which affects the quality of the substrate.

在一具體示例中,電鍍裝置21還包括電鍍液供給管路2160和電鍍液排放管路2170。如圖3所示,電鍍液供給管路2160與陽極液入口216相連,用於為鍍槽210內供應電鍍液;電鍍液排放管路2170與陽極液出口217相連,用於從鍍槽210排放電鍍液。且上述電鍍液供給管路2160和電鍍液排放管路2170中至少一個管路上裝設有用於調節鍍槽210內電鍍液流速的液泵219,在圖3所示示例中,液泵219設置在電鍍液供給管路2160上。In a specific example, the electroplating device 21 further includes a plating solution supply pipeline 2160 and a plating solution discharge pipeline 2170. As shown in FIG3 , the plating solution supply pipeline 2160 is connected to the anodic solution inlet 216 for supplying plating solution to the plating tank 210; the plating solution discharge pipeline 2170 is connected to the anodic solution outlet 217 for discharging the plating solution from the plating tank 210. At least one of the above-mentioned plating solution supply pipeline 2160 and the plating solution discharge pipeline 2170 is equipped with a liquid pump 219 for adjusting the flow rate of the plating solution in the plating tank 210. In the example shown in FIG3 , the liquid pump 219 is arranged on the plating solution supply pipeline 2160.

以陽極液出口217沿電鍍液流動方向的橫截面直徑為300mm為例,為使電鍍液對氣泡施加遠離基板100的作用力大於氣泡的上浮力,可通過液泵219將陽極液出口217處的電鍍液流速配置為0.01m/s至0.02m/s。Taking the cross-sectional diameter of the anodic liquid outlet 217 along the flow direction of the plating liquid as 300 mm as an example, in order to make the force exerted by the plating liquid on the bubbles away from the substrate 100 greater than the buoyancy of the bubbles, the plating liquid flow rate at the anodic liquid outlet 217 can be configured to 0.01 m/s to 0.02 m/s through the liquid pump 219.

此外,為使流經非可溶性陽極213表面的電鍍液流速較為均勻,可以將鍍槽210底部設計為錐形或半球形,陽極液出口217設置在鍍槽210底部中心且位於非可溶性陽極213的中心線上;也可以在非可溶性陽極213與陽極液出口217之間設置導流板元件218;還可以進一步在鍍槽210側壁的同一水準高度上均勻設置多個陽極液入口216,多根電鍍液供給管路2160分別與多個陽極液入口216一一對應連接,或同一電鍍液供給管路2160分為多個支路分別與多個陽極液入口216一一對應連接,以向多個陽極液入口216同步供給電鍍液,從而改善非可溶性陽極213表面的電鍍液流速的均勻性,這樣不僅有利於非可溶性陽極213表面各處電鍍液的反應速度一致,使被鍍基板100具有良好的電鍍均勻性,還有利於電鍍液對非可溶性陽極213表面各處氣泡的作用力一致,更好地抑制氣泡上浮,進而避免氣泡對基板品質的影響。In addition, in order to make the flow rate of the plating liquid flowing through the surface of the insoluble anode 213 more uniform, the bottom of the plating tank 210 can be designed to be conical or hemispherical, and the anodic liquid outlet 217 is set at the center of the bottom of the plating tank 210 and on the center line of the insoluble anode 213; a guide plate element 218 can also be set between the insoluble anode 213 and the anodic liquid outlet 217; and multiple anodic liquid inlets 216 can be evenly set at the same level of the side wall of the plating tank 210, and multiple plating liquid supply pipelines 2160 are respectively connected to the multiple anodic liquid inlets 216 in a one-to-one correspondence. , or the same plating liquid supply pipeline 2160 is divided into multiple branches and connected to multiple anode liquid inlets 216 one by one, so as to synchronously supply plating liquid to multiple anode liquid inlets 216, thereby improving the uniformity of the plating liquid flow rate on the surface of the insoluble anode 213. This is not only beneficial to the uniform reaction speed of the plating liquid at various locations on the surface of the insoluble anode 213, so that the plated substrate 100 has good plating uniformity, but also beneficial to the consistent force of the plating liquid on the bubbles at various locations on the surface of the insoluble anode 213, so as to better inhibit the floating of bubbles, thereby avoiding the influence of bubbles on the quality of the substrate.

如圖3和圖4所示,導流板元件218可被構造為位於非可溶性陽極213與陽極液出口217之間的若干導流板2180,各導流板2180間隔並排設置且每個導流板2180的兩端固定於鍍槽210側壁,且至少兩相鄰導流板2180的間隔沿第一方向d逐漸減小。相鄰導流板2180之間形成電鍍液的流動通道,用於調節電鍍液在鍍槽210側壁與中心線附近的流速,從而避免鍍槽210側壁附近的電鍍液流速較慢,鍍槽210中心線附近的電鍍液流速較快,進而改善非可溶性陽極213表面的電鍍液流速的均勻性。此外,導流板元件218也可被構造為表面開設有若干通孔的板件,各通孔的軸線方向可指向陽極液出口217,以形成電鍍液的流動通道,用於調節電鍍液在鍍槽210側壁與中心線附近的流速。As shown in Figures 3 and 4, the guide plate element 218 can be constructed as a plurality of guide plates 2180 located between the insoluble anode 213 and the anode liquid outlet 217, the guide plates 2180 are arranged side by side at intervals and the two ends of each guide plate 2180 are fixed to the side walls of the plating tank 210, and the interval between at least two adjacent guide plates 2180 gradually decreases along the first direction d. A flow channel of the plating solution is formed between adjacent guide plates 2180, which is used to adjust the flow rate of the plating solution near the side wall and the center line of the plating tank 210, so as to avoid the plating solution flow rate being slow near the side wall of the plating tank 210 and being fast near the center line of the plating tank 210, thereby improving the uniformity of the plating solution flow rate on the surface of the insoluble anode 213. In addition, the guide plate element 218 can also be constructed as a plate with a plurality of through holes on the surface, and the axial direction of each through hole can point to the anode liquid outlet 217 to form a flow channel of the plating solution, which is used to adjust the flow rate of the plating solution near the side wall and the center line of the plating tank 210.

另外,在本實施例中,如圖3所示,鍍槽210內還可以配置離子膜214,且離子膜214優選為呈水準設置,同時也允許存在較小的角度誤差,即允許離子膜214與水平面存在較小的夾角。離子膜214將鍍槽210內部沿豎直方向分隔為陰極區211和陽極區212,基板100位於陰極區211,陽極液入口216和陽極液出口217均位於陽極區212,因此,如圖5所示,陽極區212電鍍液在鍍槽210和溶解槽220之間迴圈過程中,可以通過離子膜214隔離電鍍液中的顆粒,例如隔離直徑大於1微米的固態顆粒進入陰極區211,進而黏附到基板100表面,影響基板良率。In addition, in this embodiment, as shown in FIG. 3 , an ion film 214 may be further disposed in the plating tank 210 , and the ion film 214 is preferably disposed horizontally, and a smaller angle error is allowed, that is, a smaller angle between the ion film 214 and the horizontal plane is allowed. The ion film 214 divides the interior of the plating tank 210 into a cathode region 211 and an anode region 212 in the vertical direction. The substrate 100 is located in the cathode region 211. The anode liquid inlet 216 and the anode liquid outlet 217 are both located in the anode region 212. Therefore, as shown in FIG. 5 , during the circulation process of the plating liquid in the anode region 212 between the plating tank 210 and the dissolution tank 220, the particles in the plating liquid can be isolated by the ion film 214. For example, solid particles with a diameter greater than 1 micron can be isolated from entering the cathode region 211 and then adhering to the surface of the substrate 100, affecting the substrate yield.

如圖5所示,在一些實施例中還公開了一種電鍍系統200,該電鍍系統200包括前文所述的電鍍裝置21,還包括供液裝置22。供液裝置22用於為電鍍裝置21提供電鍍液。As shown in FIG5 , in some embodiments, an electroplating system 200 is also disclosed, and the electroplating system 200 includes the electroplating device 21 described above, and further includes a liquid supply device 22. The liquid supply device 22 is used to provide the electroplating device 21 with a plating liquid.

在基板100電鍍期間,電鍍液中的金屬離子將在基板100表面發生還原反應形成金屬鍍層,這會導致鍍槽210內的電鍍液金屬離子濃度降低。During the electroplating of the substrate 100, the metal ions in the electroplating solution will undergo a reduction reaction on the surface of the substrate 100 to form a metal coating, which will cause the metal ion concentration of the electroplating solution in the plating tank 210 to decrease.

為解決上述技術問題,在圖5所示的實施例中,供液裝置22配置有溶解槽220、輸送管路230、粉末計量添加裝置240、電流計量裝置270和控制器290。參見圖5,溶解槽220通過輸送管路230與鍍槽210相連,用以供應電鍍液;粉末計量添加裝置240與溶解槽220相連,用於向溶解槽220供應金屬粉末,以向電鍍液中補充金屬離子;電流計量裝置270與電鍍裝置21配置的電源260相連,用於檢測電源260的輸出電量,例如,電流計量裝置270可選用安時計,安時計是應用電流對時間積分的原理測量電量的一種儀錶;控制器290分別與電流計量裝置270和粉末計量添加裝置240電連接,用以根據電流計量裝置270檢測的輸出電量,控制粉末計量添加裝置240向溶解槽220中定量添加金屬粉末。In order to solve the above technical problems, in the embodiment shown in FIG5 , the liquid supply device 22 is equipped with a dissolving tank 220, a conveying pipeline 230, a powder metering and adding device 240, a current metering device 270 and a controller 290. Referring to FIG5 , the dissolving tank 220 is connected to the plating tank 210 through the conveying pipeline 230 to supply the plating solution; the powder metering and adding device 240 is connected to the dissolving tank 220 to supply metal powder to the dissolving tank 220 to replenish metal ions in the plating solution; the current metering device 270 is connected to the power supply 260 configured in the plating device 21 to detect the output power of the power supply 260, For example, the current metering device 270 may be an ampere-hour meter, which is an instrument that measures electrical quantity by the principle of integrating current over time. The controller 290 is electrically connected to the current metering device 270 and the powder metering and adding device 240, respectively, to control the powder metering and adding device 240 to quantitatively add metal powder to the dissolution tank 220 according to the output electrical quantity detected by the current metering device 270.

由於根據金屬離子的消耗與安培小時成正比的理論,可以計算出電源260輸出預設安培小時對應的粉末計量添加裝置240所需添加的金屬粉末的預定量,因此,在本申請中,控制器290通過在電流計量裝置270測量的電源260輸出電量每增加預設安培小時時,控制粉末計量添加裝置240添加預定量的金屬粉末的方式,向電鍍液中補充金屬離子,從而維持電鍍液中金屬離子濃度的穩定。Since the theory that the consumption of metal ions is proportional to ampere-hours can be used to calculate the predetermined amount of metal powder that the powder metering and adding device 240 needs to add corresponding to the preset ampere-hour output of the power source 260, in the present application, the controller 290 replenishes metal ions into the plating solution by controlling the powder metering and adding device 240 to add a predetermined amount of metal powder every time the output power of the power source 260 measured by the current metering device 270 increases by the preset ampere-hour, thereby maintaining the stability of the metal ion concentration in the plating solution.

其中,金屬粉末可選用氧化銅粉末,溶解槽220中的電鍍液可以含有硫酸、鹽酸、硫酸銅以及水等成分,且氧化銅粉末可與硫酸或鹽酸發生反應,以溶解在溶解槽220中,形成銅離子。The metal powder may be copper oxide powder, and the plating solution in the dissolution tank 220 may contain components such as sulfuric acid, hydrochloric acid, copper sulfate, and water. The copper oxide powder may react with sulfuric acid or hydrochloric acid to dissolve in the dissolution tank 220 to form copper ions.

具體地,在本示例中,粉末計量添加裝置240包括收納金屬粉末的料斗241,該料斗241具有用於將金屬粉末向料斗內投入的投入口242、和定量排出金屬粉末的排放口243,排放口243裝設於溶解槽220上方且排放口243處設置有電驅動控制結構(圖中未示出),例如由電機驅動的螺旋輸料杆。Specifically, in this example, the powder metering and adding device 240 includes a hopper 241 for storing metal powder, the hopper 241 having an input port 242 for inputting the metal powder into the hopper, and a discharge port 243 for quantitatively discharging the metal powder, the discharge port 243 is installed above the dissolution tank 220 and an electric drive control structure (not shown in the figure) is provided at the discharge port 243, such as a screw feed rod driven by a motor.

具體地,在本示例中,電源260通過陰極線路261與被鍍基板100連接,通過陽極線路262與非可溶性陽極213連接,用於為非可溶性陽極213和被鍍基板100供電。Specifically, in this example, the power source 260 is connected to the substrate 100 to be plated via the cathode line 261 and is connected to the insoluble anode 213 via the anode line 262 , so as to supply power to the insoluble anode 213 and the substrate 100 to be plated.

需要說明的是,鍍槽210可通過輸送管路230與溶解槽220雙向連接,由一路輸送管路230將溶解槽220內的電鍍液輸送至鍍槽210,由另一路輸送管路230將鍍槽210內的電鍍液回收至溶解槽220,補充金屬離子後重新輸送至鍍槽210,依此實現電鍍液的雙向迴圈流動。此外,鍍槽210也可通過輸送管路230與溶解槽220單向連接,由一路輸送管路230將溶解槽220內的電鍍液輸送至鍍槽210,由另一路輸送管路230將鍍槽210內的電鍍液排放至除溶解槽220以外的其它回收裝置,溶解槽220內的電鍍液也由其它裝置補充,以實現電鍍液的單向流動。It should be noted that the plating tank 210 can be bidirectionally connected to the dissolving tank 220 via a delivery pipeline 230. The plating solution in the dissolving tank 220 is delivered to the plating tank 210 by one delivery pipeline 230, and the plating solution in the plating tank 210 is recovered to the dissolving tank 220 by another delivery pipeline 230, and is re-delivered to the plating tank 210 after replenishing metal ions, thereby realizing a bidirectional circulation flow of the plating solution. In addition, the plating tank 210 can also be unidirectionally connected to the dissolution tank 220 via a delivery pipeline 230. One delivery pipeline 230 delivers the plating liquid in the dissolution tank 220 to the plating tank 210, and another delivery pipeline 230 discharges the plating liquid in the plating tank 210 to other recovery devices other than the dissolution tank 220. The plating liquid in the dissolution tank 220 is also replenished by other devices to achieve unidirectional flow of the plating liquid.

優選地,在本示例中,供液裝置還包括緩衝槽250,緩衝槽250連接於鍍槽210與溶解槽220之間,用於暫存及混合溶解槽220和鍍槽210之間迴圈流動的電鍍液。Preferably, in this example, the liquid supply device further includes a buffer tank 250, which is connected between the plating tank 210 and the dissolving tank 220 and is used to temporarily store and mix the plating solution circulating between the dissolving tank 220 and the plating tank 210.

參見圖5,在本示例中,輸送管路230用於使電鍍液在鍍槽210、緩衝槽250以及溶解槽220之間沿圖5中箭頭所示方向迴圈流動。具體地,輸送管路230包括第一輸入管路231、第一輸出管路232、第二輸入管路233和第二輸出管路234。第一輸入管路231和第一輸出管路232連接於溶解槽220和緩衝槽250之間,且第一輸入管路231上配置有液泵235;第二輸入管路233和第二輸出管路234連接於緩衝槽250和鍍槽210之間,且第二輸入管路233上配置有液泵238。其中,第一輸入管路231用於將溶解槽220內的電鍍液輸送到緩衝槽250;第一輸出管路232用於將緩衝槽250內的電鍍液輸送回溶解槽220;第二輸入管路233用於將緩衝槽250內的電鍍液輸送到鍍槽210;第二輸出管路234用於將鍍槽210內的電鍍液輸送回緩衝槽250。需要說明的是,第二輸入管路233相當於圖3所示實施例中的電鍍液供給管路2160,第二輸出管路234相當於圖3所示實施例中的電鍍液排放管路2170,液泵238相當於圖3所示實施例的液泵219。Referring to FIG5 , in this example, the delivery pipeline 230 is used to make the electroplating solution circulate between the plating tank 210, the buffer tank 250 and the dissolving tank 220 in the direction indicated by the arrow in FIG5 . Specifically, the delivery pipeline 230 includes a first input pipeline 231, a first output pipeline 232, a second input pipeline 233 and a second output pipeline 234. The first input pipeline 231 and the first output pipeline 232 are connected between the dissolving tank 220 and the buffer tank 250, and a liquid pump 235 is disposed on the first input pipeline 231; the second input pipeline 233 and the second output pipeline 234 are connected between the buffer tank 250 and the plating tank 210, and a liquid pump 238 is disposed on the second input pipeline 233. The first input pipeline 231 is used to transport the plating solution in the dissolving tank 220 to the buffer tank 250; the first output pipeline 232 is used to transport the plating solution in the buffer tank 250 back to the dissolving tank 220; the second input pipeline 233 is used to transport the plating solution in the buffer tank 250 to the plating tank 210; the second output pipeline 234 is used to transport the plating solution in the plating tank 210 back to the buffer tank 250. It should be noted that the second input pipeline 233 is equivalent to the plating solution supply pipeline 2160 in the embodiment shown in FIG. 3, the second output pipeline 234 is equivalent to the plating solution discharge pipeline 2170 in the embodiment shown in FIG. 3, and the liquid pump 238 is equivalent to the liquid pump 219 in the embodiment shown in FIG. 3.

為避免溶解槽220內未溶解的金屬粉末等雜質輸送到鍍槽210內,可於第一輸入管路231裝設多級過濾裝置236。In order to prevent impurities such as undissolved metal powder in the dissolving tank 220 from being transported into the plating tank 210 , a multi-stage filtering device 236 may be installed in the first input pipeline 231 .

優選地,電鍍系統200還包括濃度分析裝置280,用於監測電鍍液中的金屬離子濃度。濃度分析裝置280可以如圖5所示設置在緩衝槽250中。可以理解的是,在其他實施方式中,濃度分析裝置280可以設置其它槽體內,例如設置在鍍槽210或溶解槽220內;還可以設置在輸送管路230上,例如設置在第二輸入管路233或第二輸出管路234上。Preferably, the electroplating system 200 further includes a concentration analysis device 280 for monitoring the metal ion concentration in the electroplating solution. The concentration analysis device 280 can be disposed in the buffer tank 250 as shown in FIG5 . It is understood that in other embodiments, the concentration analysis device 280 can be disposed in other tanks, such as in the plating tank 210 or the dissolution tank 220; and can also be disposed on the transport pipeline 230, such as on the second input pipeline 233 or the second output pipeline 234.

此外,為使金屬粉末充分溶解,溶解槽220內可附加裝設攪拌裝置221;為監控電鍍液溫度,溶解槽220內可附加裝設溫控裝置222。In addition, in order to fully dissolve the metal powder, a stirring device 221 may be additionally installed in the dissolution tank 220; in order to monitor the temperature of the electroplating solution, a temperature control device 222 may be additionally installed in the dissolution tank 220.

該電鍍系統200在進行電鍍作業時,既可以使非可溶性陽極213表面產生的氣泡遠離基板100,避免氣泡上浮並附著於基板100表面,導致鍍層上形成凹孔,影響基板品質;也可以通過離子膜214隔離電鍍液中的雜質顆粒,避免雜質顆粒進入陰極區211黏附到基板100表面,影響基板良率;還可以準確調控鍍槽210內電鍍液的金屬離子濃度,以提高對基板100電鍍效率的可控性。When the electroplating system 200 is performing the electroplating operation, it can keep the bubbles generated on the surface of the insoluble anode 213 away from the substrate 100, preventing the bubbles from floating up and adhering to the surface of the substrate 100, resulting in the formation of pits on the coating, which affects the quality of the substrate; it can also isolate the impurity particles in the plating solution through the ion film 214, preventing the impurity particles from entering the cathode area 211 and adhering to the surface of the substrate 100, which affects the substrate yield; it can also accurately adjust the metal ion concentration of the plating solution in the plating tank 210 to improve the controllability of the electroplating efficiency of the substrate 100.

應當說明的是,上述實施例均可根據需要自由組合。以上僅是本發明的優選實施方式,對於本技術領域的普通技術人員來說,在不脫離本發明原理的前提下,還可以做出若干改進和潤飾,這些改進和潤飾也應視為本發明的保護範圍。It should be noted that the above embodiments can be freely combined as needed. The above are only preferred embodiments of the present invention. For ordinary technicians in this technical field, they can make some improvements and modifications without departing from the principle of the present invention. These improvements and modifications should also be regarded as the protection scope of the present invention.

100:基板 200:電鍍系統 21:電鍍裝置 210:鍍槽 211:陰極區 212:陽極區 213:非可溶性陽極 214:離子膜 215:銅陽極 216:陽極液入口 2160:電鍍液供給管路 217:陽極液出口 2170:電鍍液排放管路 218:導流板元件 2180:導流板 219,235,238:液泵 22:供液裝置 220:溶解槽 221:攪拌裝置 222:溫控裝置 230:輸送管路 231:第一輸入管路 232:第一輸出管路 233:第二輸入管路 234:第二輸出管路 236:多級過濾裝置 240:粉末計量添加裝置 241:料斗 242:投入口 243:排放口 250:緩衝槽 260:電源 261:陰極線路 262:陽極線路 270:電流計量裝置 280:濃度分析裝置 290:控制器 d:第一方向 d1,d2:距離 100: substrate 200: electroplating system 21: electroplating device 210: plating tank 211: cathode zone 212: anode zone 213: insoluble anode 214: ion membrane 215: copper anode 216: anode liquid inlet 2160: electroplating liquid supply pipeline 217: anode liquid outlet 2170: electroplating liquid discharge pipeline 218: guide plate element 2180: guide plate 219,235,238: liquid pump 22: liquid supply device 220: dissolution tank 221: stirring device 222: temperature control device 230: transport pipeline 231: first input pipeline 232: first output pipeline 233: second input pipeline 234: second output pipeline 236: multi-stage filtering device 240: powder metering and adding device 241: hopper 242: input port 243: discharge port 250: buffer tank 260: power supply 261: cathode line 262: anode line 270: current metering device 280: concentration analysis device 290: controller d: first direction d1, d2: distance

為讓本揭露之上述和其他目的、特徵、優點與實施例能更明顯易懂,所附圖式之說明如下: 圖1是基板電鍍製程中銅陽極初始狀態示意圖。 圖2是基板電鍍製程中銅陽極進行一段時間電鍍製程後的狀態示意圖。 圖3是本發明電鍍裝置一種實施例的示意圖。 圖4是本發明一實施例的電鍍裝置中的導流板元件的立體結構示意圖。 圖5是本發明電鍍系統一種實施例的示意圖。 In order to make the above and other purposes, features, advantages and embodiments of the present disclosure more clearly understandable, the attached drawings are described as follows: FIG. 1 is a schematic diagram of the initial state of the copper anode in the substrate electroplating process. FIG. 2 is a schematic diagram of the state of the copper anode after a period of electroplating in the substrate electroplating process. FIG. 3 is a schematic diagram of an embodiment of the electroplating device of the present invention. FIG. 4 is a schematic diagram of the three-dimensional structure of the guide plate element in the electroplating device of an embodiment of the present invention. FIG. 5 is a schematic diagram of an embodiment of the electroplating system of the present invention.

100:基板 100: Substrate

21:電鍍裝置 21: Electroplating device

210:鍍槽 210: Plated groove

211:陰極區 211:Cathode zone

212:陽極區 212: Anode area

213:非可溶性陽極 213: Insoluble anode

214:離子膜 214: Ionic membrane

216:陽極液入口 216: Anodic fluid inlet

2160:電鍍液供給管路 2160: Plating liquid supply pipeline

217:陽極液出口 217: Anode liquid outlet

2170:電鍍液排放管路 2170: Plating liquid discharge pipeline

218:導流板元件 218: deflector element

219:液泵 219: Liquid pump

260:電源 260: Power supply

d:第一方向 d: First direction

Claims (12)

一種電鍍裝置,用於將金屬電鍍到基板上,包括: 鍍槽,用於容納電鍍液和所述基板; 非可溶性陽極,配置於所述鍍槽內部且位於所述基板下方; 陽極液入口,用於向所述鍍槽內供應電鍍液; 陽極液出口,用於從所述鍍槽排放電鍍液; 其中,所述陽極液入口高於所述非可溶性陽極和所述陽極液出口,以使在進行電鍍作業時所述電鍍液在所述陽極液入口和所述陽極液出口之間沿遠離所述基板的第一方向流動,且所述電鍍槽內的電鍍液流速被配置為,使電鍍液對所述非可溶性陽極表面產生的氣泡施加朝向所述第一方向的作用力,且所述作用力大於所述氣泡的浮力,以使所述氣泡遠離所述基板。 A plating device for plating metal onto a substrate, comprising: a plating tank for containing a plating solution and the substrate; a non-soluble anode disposed inside the plating tank and below the substrate; an anode liquid inlet for supplying the plating solution into the plating tank; an anode liquid outlet for discharging the plating solution from the plating tank; The anodic liquid inlet is higher than the insoluble anode and the anodic liquid outlet, so that the plating liquid flows between the anodic liquid inlet and the anodic liquid outlet in a first direction away from the substrate during the electroplating operation, and the flow rate of the plating liquid in the plating tank is configured so that the plating liquid exerts a force on the bubbles generated on the surface of the insoluble anode in the first direction, and the force is greater than the buoyancy of the bubbles, so that the bubbles are away from the substrate. 如請求項1所述之電鍍裝置,其中所述鍍槽的底部呈錐形或半球形,所述陽極液出口位於所述底部的中心。An electroplating device as described in claim 1, wherein the bottom of the plating tank is conical or hemispherical, and the anodic liquid outlet is located at the center of the bottom. 如請求項1所述之電鍍裝置,還包括導流板元件,配置於所述非可溶性陽極與所述陽極液出口之間。The electroplating device as described in claim 1 also includes a guide plate element arranged between the non-soluble anode and the anode liquid outlet. 如請求項3所述之電鍍裝置,其中所述導流板元件包括若干間隔排布的導流板,至少兩相鄰所述導流板的間隔沿所述第一方向逐漸減小,以形成所述電鍍液的流動通道。The electroplating device as described in claim 3, wherein the guide plate element includes a plurality of guide plates arranged at intervals, and the interval between at least two adjacent guide plates gradually decreases along the first direction to form a flow channel for the electroplating liquid. 如請求項1所述之電鍍裝置,還包括離子膜,設置在所述鍍槽的內部,所述離子膜將所述鍍槽的內部沿豎直方向分隔為陰極區和陽極區,所述陽極液入口和所述陽極液出口均位於所述陽極區,所述基板位於所述陰極區。The electroplating device as described in claim 1 also includes an ion membrane arranged inside the plating tank, and the ion membrane divides the inside of the plating tank into a cathode region and an anode region along the vertical direction. The anode liquid inlet and the anode liquid outlet are both located in the anode region, and the substrate is located in the cathode region. 如請求項1所述之電鍍裝置,其中多個所述陽極液入口設置在所述鍍槽的側壁上,且所述多個陽極液入口間隔分佈於所述鍍槽的同一水準高度。The electroplating device as described in claim 1, wherein the plurality of anodic liquid inlets are arranged on the side wall of the plating tank, and the plurality of anodic liquid inlets are spaced apart and distributed at the same horizontal height of the plating tank. 如請求項1所述之電鍍裝置,還包括: 電鍍液供給管路、電鍍液排放管路和液泵,所述電鍍液供給管路與所述陽極液入口相連,用於將電鍍液通過所述陽極液入口供應至所述鍍槽內;所述電鍍液排放管路與所述陽極液出口相連,用於將電鍍液通過所述陽極液出口排放出去;所述液泵裝設於所述電鍍液供給管路和/或電鍍液排放管路,用於調節所述鍍槽內的電鍍液流速。 The electroplating device as described in claim 1 further comprises: a plating liquid supply pipeline, a plating liquid discharge pipeline and a liquid pump, wherein the plating liquid supply pipeline is connected to the anodic liquid inlet and is used to supply the plating liquid into the plating tank through the anodic liquid inlet; the plating liquid discharge pipeline is connected to the anodic liquid outlet and is used to discharge the plating liquid through the anodic liquid outlet; the liquid pump is installed in the plating liquid supply pipeline and/or the plating liquid discharge pipeline and is used to adjust the flow rate of the plating liquid in the plating tank. 如請求項1所述之電鍍裝置,還包括: 電源,用於為所述非可溶性陽極和所述基板供電。 The electroplating device as described in claim 1 also includes: A power source for supplying power to the non-soluble anode and the substrate. 一種電鍍系統,包括請求項1至8任一項所述之電鍍裝置,還包括: 供液裝置,用於為所述電鍍裝置提供電鍍液。 A plating system, comprising the plating device described in any one of claims 1 to 8, and further comprising: A liquid supply device for providing plating liquid to the plating device. 如請求項9所述之電鍍系統,其中所述供液裝置包括: 溶解槽,用於向所述鍍槽供應電鍍液; 粉末計量添加裝置,用於向所述溶解槽供應金屬粉末; 電流計量裝置,用於檢測電源的輸出電量; 控制器,被配置為當所述電流計量裝置檢測到所述電源的輸出電量每增加預設安培小時時,控制所述粉末計量添加裝置添加預定量的所述金屬粉末。 The electroplating system as described in claim 9, wherein the liquid supply device comprises: a dissolving tank for supplying electroplating liquid to the plating tank; a powder metering device for supplying metal powder to the dissolving tank; a current metering device for detecting the output power of the power source; a controller configured to control the powder metering device to add a predetermined amount of the metal powder when the current metering device detects that the output power of the power source increases by a preset ampere-hour. 如請求項10所述之電鍍系統,還包括: 緩衝槽,連接於所述鍍槽與所述溶解槽之間,用於暫存及混合所述溶解槽和所述鍍槽之間迴圈流動的電鍍液。 The electroplating system as described in claim 10 further includes: A buffer tank connected between the plating tank and the dissolving tank for temporarily storing and mixing the electroplating solution circulating between the dissolving tank and the plating tank. 如請求項10所述之電鍍系統,其中所述溶解槽內包括攪拌裝置和/或溫度控制裝置。An electroplating system as described in claim 10, wherein the dissolution tank includes a stirring device and/or a temperature control device.
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