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TW202406862A - Thermal management of variable thickness glass ribbon - Google Patents

Thermal management of variable thickness glass ribbon Download PDF

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Publication number
TW202406862A
TW202406862A TW112114395A TW112114395A TW202406862A TW 202406862 A TW202406862 A TW 202406862A TW 112114395 A TW112114395 A TW 112114395A TW 112114395 A TW112114395 A TW 112114395A TW 202406862 A TW202406862 A TW 202406862A
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Taiwan
Prior art keywords
glass ribbon
thickness
processing equipment
glass
thicker
Prior art date
Application number
TW112114395A
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Chinese (zh)
Inventor
泰勒M 柏恩斯
史蒂芬馬歇爾 埃弗索爾
尼爾斯保羅 弗紐
史蒂芬瑞 霍華德
洪瑞祥
雅各 伊莫爾曼
安力歐瑪利歐 波盧門柏
大衛 普薩達皮內達
羅希特 萊
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美商康寧公司
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Publication of TW202406862A publication Critical patent/TW202406862A/en

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B25/00Annealing glass products
    • C03B25/04Annealing glass products in a continuous way
    • C03B25/06Annealing glass products in a continuous way with horizontal displacement of the glass products
    • C03B25/08Annealing glass products in a continuous way with horizontal displacement of the glass products of glass sheets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B29/00Reheating glass products for softening or fusing their surfaces; Fire-polishing; Fusing of margins
    • C03B29/04Reheating glass products for softening or fusing their surfaces; Fire-polishing; Fusing of margins in a continuous way
    • C03B29/06Reheating glass products for softening or fusing their surfaces; Fire-polishing; Fusing of margins in a continuous way with horizontal displacement of the products
    • C03B29/08Glass sheets

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)

Abstract

A glass ribbon processing apparatus to produce a glass ribbon having a first portion with a first thickness immediately adjacent to a second portion with a second thickness, the apparatus comprising a water wick contacting the first portion of the glass ribbon to cool the first portion as the glass ribbon travels passed the water wick, wherein the first thickness is greater than the second thickness.

Description

可變厚度玻璃帶之熱管理Thermal management of variable thickness glass ribbons

相關申請案之交叉引用Cross-references to related applications

本申請案依專利法主張2022年4月20日申請的美國臨時申請案第63/332773號的優先權權益,本文依賴於該美國臨時申請案的內容並且該美國臨時申請案的內容以全文引用的方式併入本文中。This application claims the priority rights and interests of the US Provisional Application No. 63/332773 filed on April 20, 2022 in accordance with the patent law. This article relies on the content of the US Provisional Application and the content of the US Provisional Application is cited in full. are incorporated into this article.

本揭示案係關於提供對連續玻璃帶內的精確區域的優先冷卻或加熱的裝置及方法。所揭示的裝置及方法可以提供對玻璃帶溫度的控制以確保厚區域與薄區域之間的溫度差異保持在零或接近零。必須以這種方式控制溫度以避免熱誘發的形狀(翹曲)及殘餘應力。可以在黏彈性區域之前及之後應用這些揭示的裝置及方法。The present disclosure relates to devices and methods that provide preferential cooling or heating of precise areas within a continuous ribbon of glass. The disclosed apparatus and methods can provide control of the temperature of the glass ribbon to ensure that the temperature difference between thick and thin areas remains at or near zero. Temperature must be controlled in this way to avoid thermally induced shape (warpage) and residual stresses. The disclosed devices and methods can be applied before and after the viscoelastic zone.

某些智慧手機及行動裝置的後蓋或電子部件的任何玻璃體或外殼設計具有不均勻的厚度,不均勻的厚度在相機區域比其他部分更厚,這允許改進相機鏡頭設計(參見,例如,U.S. PG Pub.2019/0364179 A1)。例如,玻璃厚度在較厚部分可以是1.5至3.0 mm,而在其他地方可以小於0.8 mm。為了製造裝置後蓋或外殼的較厚區段,可以對相對較厚的玻璃板進行研磨、研光及拋光,以限定較厚區域及較薄區域。在這種情況下,為了製造在較厚區域具有1.6 mm厚度及在其他地方具有0.6 mm標稱厚度的玻璃製品,可使用具有1.9 mm厚度的玻璃板。亦即,將自較厚分移除0.3 mm的材料,並且自較薄部分移除1.3 mm的材料。這種方法玻璃利用率低、耗時長、成本高、效率低,並且不環保。Any glass or housing design of the back cover or electronic components of some smartphones and mobile devices has an uneven thickness that is thicker in the camera area than other parts, which allows for improvements in camera lens design (see, for example, U.S. PG Pub.2019/0364179 A1). For example, the glass thickness can be 1.5 to 3.0 mm in thicker parts and less than 0.8 mm in other places. To create thicker sections of a device back cover or housing, relatively thick glass sheets can be ground, polished, and polished to define thicker and thinner areas. In this case, in order to produce a glass article with a thickness of 1.6 mm in thicker areas and a nominal thickness of 0.6 mm elsewhere, a glass plate with a thickness of 1.9 mm can be used. That is, 0.3 mm of material will be removed from the thicker section, and 1.3 mm of material will be removed from the thinner section. This method has low glass utilization, is time-consuming, high-cost, low-efficiency, and not environmentally friendly.

在形成具有不均勻厚度的玻璃製品的替代方法中,可將兩個玻璃基板熔合在一起(參見,例如,U.S. PG Pub.2017/0210111A1)。例如,一塊25 mm x 25 mm x1.0 mm的玻璃片可以藉由在高溫下黏合或壓合在一起而熔合成一塊更大的70 mm x 150 mm x 0.6 mm的玻璃片。這種方法提高了玻璃的利用率,但耗能大,會導致熔化界面處形成氣泡,而且成本高且耗時長。In an alternative method of forming a glass article with uneven thickness, two glass substrates can be fused together (see, eg, U.S. PG Pub. 2017/0210111 A1). For example, a 25 mm x 25 mm x 1.0 mm piece of glass can be fused into a larger 70 mm x 150 mm x 0.6 mm piece of glass by bonding or pressing them together at high temperatures. This method improves the utilization of glass, but consumes a lot of energy, can lead to the formation of bubbles at the melting interface, and is costly and time-consuming.

當研磨製程不符合成本效益並且產生太多浪費時,並且當將兩個玻璃片熔合在一起不是可行的選擇時,另一種解決方案是限定具有所需厚度差異的連續玻璃帶。生產具有厚度變化的玻璃帶可能要求在較厚部分與較薄部分之間產生顯著的溫度差異。因此,為了製造這種具有低應力及翹曲的玻璃帶,要求能夠以不同於基礎帶(或玻璃帶的較薄部分)的冷卻速率的規定速率優先冷卻較厚部分。還可能要求優先加熱基礎帶(或薄區域)以減慢其相對於厚部分的正常冷卻速率。When the grinding process is not cost-effective and creates too much waste, and when fusing two pieces of glass together is not a viable option, another solution is to define a continuous glass ribbon with the desired thickness difference. Producing glass ribbons with varying thicknesses may require significant temperature differences between thicker and thinner sections. Therefore, in order to produce such a glass ribbon with low stress and warpage, it is required to be able to preferentially cool the thicker portion at a prescribed rate different from the cooling rate of the base ribbon (or the thinner portion of the glass ribbon). There may also be a requirement to preferentially heat the base strip (or thin areas) to slow down its normal cooling rate relative to thicker sections.

本揭示案提供了針對這項技術挑戰的解決方案。This disclosure provides a solution to this technical challenge.

為了克服上文所描述的問題,本揭示案的實施例提供了設備及方法,其藉由管理自厚至薄及自上至下的溫度梯度,來藉由以比冷卻較薄部分更高的速率冷卻玻璃帶的較厚部分來最小化可變厚度玻璃板中的應力及翹曲。冷卻可以經由對流及/或輻射並且自玻璃帶的頂部及/或底部執行。可選地,局部加熱可以與優先冷卻一起使用以控制玻璃內所需的溫度參數。To overcome the problems described above, embodiments of the present disclosure provide apparatus and methods that manage thick-to-thin and top-to-bottom temperature gradients by cooling thinner portions at a higher temperature than Rate cooling of thicker portions of the glass ribbon minimizes stress and warpage in variable thickness glass sheets. Cooling can be performed via convection and/or radiation and from the top and/or bottom of the glass ribbon. Optionally, localized heating can be used with preferential cooling to control desired temperature parameters within the glass.

所描述的實施例可以應用於在退火爐及/或受控冷卻設備(controlled cooling apparatus, CCA)中行進的熱玻璃帶。CCA是改良型退火爐,或輥底式退火爐,或生產玻璃帶的輥道窯。本揭示案提供了對生產具有可變厚度的玻璃帶必須克服的熱管理挑戰的解決方案。The described embodiments may be applied to hot glass ribbons traveling in lehrs and/or controlled cooling apparatus (CCA). CCA is an improved annealing furnace, or roller hearth annealing furnace, or roller kiln for producing glass ribbons. The present disclosure provides a solution to the thermal management challenges that must be overcome to produce glass ribbons of variable thickness.

沒有當前所描述的熱管理方法,在具有可變厚度的玻璃帶中產生的應力將太高。這將要求對板進行刻劃,自板上切下高應力部分,或提供額外的精加工製程來生產所需尺寸、形狀及厚度的玻璃。減少玻璃帶中應力的替代方法是顯著增加退火爐長度或添加退火步驟。這兩種方法都涉及顯著的成本及空間要求。Without the currently described thermal management methods, the stresses generated in glass ribbons with variable thicknesses would be too high. This would require scoring the plate, cutting out highly stressed sections from the plate, or providing additional finishing processes to produce the glass of the required size, shape and thickness. Alternative methods of reducing stress in the glass ribbon are to significantly increase the annealing furnace length or to add an annealing step. Both methods involve significant cost and space requirements.

根據本揭示案的一個實施例,一種玻璃帶處理設備生產具有第一厚度的第一部分緊鄰具有第二厚度的第二部分的玻璃帶,該設備包含接觸玻璃帶的第一部分的水芯,以當玻璃帶行進經過水芯時冷卻第一部分,其中第一厚度大於第二厚度。其中第一部分以第一速率冷卻並且第二部分以第二速率冷卻,其中第一速率大於第二速率。According to one embodiment of the present disclosure, a glass ribbon processing apparatus produces a glass ribbon having a first portion of a first thickness adjacent a second portion of a second thickness, the apparatus including a water core contacting the first portion of the glass ribbon to when The glass ribbon cools the first portion as it travels through the water core, wherein the first thickness is greater than the second thickness. wherein the first portion is cooled at a first rate and the second portion is cooled at a second rate, wherein the first rate is greater than the second rate.

在一個實施例中,第一部分及第二部分沿玻璃帶的長度縱向定向。In one embodiment, the first and second portions are oriented longitudinally along the length of the glass ribbon.

玻璃帶處理設備可以進一步包括位於水芯上游的加熱器。The glass ribbon processing equipment may further include a heater located upstream of the water core.

在一個實施例中,水芯是織物條帶並且固定在玻璃帶上方的一端。In one embodiment, the water core is a fabric strip and is fixed at one end above the glass strip.

在一個實施例中,水芯是圓形的並且繞軸旋轉,並且當玻璃帶在水平方向上行進時水芯在玻璃帶下方。In one embodiment, the water core is circular and rotates about an axis and is below the glass ribbon as it travels in a horizontal direction.

在一個實施例中,水芯附接至實質上平面的板上。In one embodiment, the water core is attached to a substantially planar plate.

根據另一個實施例,玻璃帶處理設備生產具有可變厚度的玻璃帶,該設備包含霧化器以在玻璃帶的較厚部分上噴射冷卻液及/或冷卻空氣,以當玻璃帶行進經過霧化器時冷卻玻璃帶的較厚部分。According to another embodiment, a glass ribbon processing apparatus produces a glass ribbon having a variable thickness, the apparatus including an atomizer to spray coolant and/or cooling air over thicker portions of the glass ribbon to spray the fog as the glass ribbon travels through the fog. Cool the thicker part of the glass ribbon when using the vaporizer.

根據另一個實施例,玻璃帶處理設備生產具有可變厚度的玻璃帶,該設備包含加熱器以當玻璃帶行進經過加熱器時加熱玻璃帶的較薄部分。在一個實施例中,加熱器是橫跨玻璃帶的寬度對稱定位的兩個加熱器。在一個實施例中,加熱器是兩個加熱器,一個位於玻璃帶上方,一個位於玻璃帶下方。According to another embodiment, a glass ribbon processing apparatus produces a glass ribbon having a variable thickness, the apparatus including a heater to heat the thinner portions of the glass ribbon as it travels past the heater. In one embodiment, the heaters are two heaters positioned symmetrically across the width of the glass ribbon. In one embodiment, the heaters are two heaters, one above and one below the glass ribbon.

根據另一個實施例,玻璃帶處理設備生產具有可變厚度的玻璃帶,該設備包含氣桿以當玻璃帶行進經過氣桿時迫使空氣到達玻璃帶的一部分上。在一個實施例中,氣桿在玻璃帶下方。在一個實施例中,氣桿支撐玻璃帶。在一個實施例中,氣桿迫使冷卻空氣到達玻璃帶的較厚部分。在一個實施例中,空氣包括蒸汽並且經迫使注入至玻璃帶的較薄部分上。According to another embodiment, a glass ribbon processing apparatus that produces glass ribbons of variable thickness includes air rods to force air onto a portion of the glass ribbon as it travels past the air rods. In one embodiment, the gas rod is below the glass ribbon. In one embodiment, air rods support the glass ribbon. In one embodiment, air rods force cooling air to thicker portions of the glass ribbon. In one embodiment, the air includes steam and is forced onto the thinner portions of the glass ribbon.

根據一個實施例,玻璃帶處理設備生產包括第一厚度及第二厚度的玻璃帶,該設備包含:輥,當玻璃帶行進經過輥時支撐玻璃帶;以及噴嘴,該噴嘴用以迫使冷卻空氣注入到達輥接觸玻璃帶的一部分上,其中第一厚度大於第二厚度。在一個實施例中,輥接觸玻璃帶的部分對應於第一厚度。According to one embodiment, a glass ribbon processing apparatus produces a glass ribbon including a first thickness and a second thickness, the apparatus including: a roller to support the glass ribbon as it travels past the roller; and a nozzle to force cooling air to be injected The arrival roller contacts a portion of the glass ribbon where the first thickness is greater than the second thickness. In one embodiment, the portion of the roller that contacts the glass ribbon corresponds to the first thickness.

藉由以下參照附圖對本發明的較佳實施例的詳細描述,本發明的上述及其他特徵、要素、特徵、步驟及優點將變得更加明顯。The above and other features, elements, characteristics, steps and advantages of the present invention will become more apparent from the following detailed description of the preferred embodiments of the present invention with reference to the accompanying drawings.

包括較薄部分及較厚部分的玻璃帶幾何形狀藉由本揭示案中所描述的裝置及方法成為可能。拉製玻璃帶幾何形狀可以包括一定寬度,其中一部分寬度比其他部分厚。例如,較厚部分可以在玻璃帶的中心。視情況,可以有一個以上的較厚部分橫跨玻璃帶的寬度間隔開。幾何形狀通常是為特定產品設計的。Glass ribbon geometries including thinner portions and thicker portions are made possible by the apparatus and methods described in this disclosure. Drawn glass ribbon geometries can include a certain width, with some portions being thicker than others. For example, the thicker portion can be in the center of the glass ribbon. Depending on the situation, there may be more than one thicker section spaced across the width of the glass ribbon. Geometric shapes are usually designed for a specific product.

退火爐及/或CCA內部的習知熱管理導致較厚部分在整個受控冷卻區段始終比較薄的基礎玻璃更熱。在條帶冷卻過程中,較厚部分與較薄部分之間存在的這種持續的熱梯度,雖然藉由控制退火爐進行了合理的良好管理,但在成型產品中造成了高應力及翹曲。這導致迫切需要與退火爐一起使用的優先熱管理工具,以降低熱梯度並減少由此產生的應力。Conventional thermal management within the lehr and/or CCA results in the thicker section being consistently hotter than the thinner base glass throughout the controlled cooling section. This constant thermal gradient between thicker and thinner parts during strip cooling, although reasonably well managed by controlling the annealing furnace, causes high stresses and warpage in the molded product . This leads to an urgent need for priority thermal management tools used with annealing furnaces to reduce thermal gradients and reduce the resulting stresses.

一個重要的因素是經由優先熱工具提供額外的冷卻,使得玻璃帶在較厚及較薄的部分中達成幾乎相同的溫度,以保持自厚至薄的溫度差異(ΔT或DT)接近零。玻璃帶的較厚部分的優先冷卻可以與較薄部分的優先加熱相結合。較薄部分的加熱可以藉由局部加熱工具或藉由保持整個退火爐溫度高於較薄部分的溫度來實現(而冷卻工具優先冷卻較薄部分)。An important factor is to provide additional cooling via preferential thermal tools so that the glass ribbon reaches nearly the same temperature in thicker and thinner sections to keep the thick-to-thin temperature difference (ΔT or DT) close to zero. Preferential cooling of thicker parts of the glass ribbon can be combined with preferential heating of thinner parts. Heating of thinner parts can be achieved by locally heating tools or by keeping the entire annealing furnace at a higher temperature than the thinner parts (while cooling tools preferentially cool the thinner parts).

冷卻流、應力及翹曲資料表明,隨著較厚部分被冷卻,使得較厚部分與較薄部分之間的溫度差異減小,玻璃帶中的應力亦下降。自資料中可以看出,可以根據特定應用及預期結果來最佳化冷卻裝置的功能。Cooling flow, stress and warpage data show that as the thicker section is cooled, the temperature difference between the thicker and thinner sections decreases and the stress in the glass ribbon also decreases. As can be seen from the data, the functionality of the cooling unit can be optimized based on the specific application and expected results.

可以使用包括強制通風(對流)、輻射及傳導的技術的任何組合來提供冷卻。冷卻系統設計包括以下考慮因素,包括發射率、理想氣體定律及熱空氣的膨脹、熱空氣自製造廠房中的排出以及人員安全。Cooling may be provided using any combination of techniques including forced air (convection), radiation and conduction. Cooling system design includes considerations including emissivity, the ideal gas law and expansion of hot air, exhaust of hot air from the manufacturing plant, and personnel safety.

可以提供任何類型的冷卻(對流、輻射、傳導及組合)、加熱,或加熱/冷卻,使得提供處理的每個裝置可以獨立地移動及定位以與玻璃帶的任何部分對準。任何裝置皆可以置放在玻璃帶的中心以覆蓋更寬更厚的部分,或者裝置可以向玻璃帶的邊緣展開以覆蓋更窄的邊緣條帶配置。任何裝置皆可以獨立地位於上方、下方、側面,或者在不使用時相對於玻璃帶停放在一邊,並且可以手動或藉由自動機電定位系統置放到位。任選地,加熱及/或冷卻的任何數目的裝置的任何數目的位置可以藉由自動化定位及預編程,使得玻璃帶製程的不同配置可以是可重複的。Any type of cooling (convective, radiative, conductive, and combinations), heating, or heating/cooling can be provided such that each device providing the treatment can be independently moved and positioned to align with any portion of the glass ribbon. Any device can be placed in the center of the glass ribbon to cover wider and thicker sections, or the devices can be spread out towards the edges of the glass ribbon to cover narrower edge strip configurations. Any device can be positioned independently above, below, to the side, or parked aside relative to the glazing strip when not in use, and can be placed into position manually or by an automatic electromechanical positioning system. Optionally, any number of positions of any number of devices for heating and/or cooling can be positioned and preprogrammed by automation so that different configurations of the glass ribbon process can be repeatable.

如第1A圖所示,水芯10可以用於優先冷卻行進中的玻璃帶20的較厚區域。如第1A圖所示,在玻璃帶20自左至右移動的情況下,水芯10可以懸掛在懸置在玻璃帶輸送系統上方的台架30上,並且與玻璃帶20接觸置放,並且當玻璃帶20行進時被拖動。因此,較厚區域可以在玻璃帶20與水芯10接觸的部分中作為連續條帶冷卻。As shown in Figure 1A, the water core 10 can be used to preferentially cool thicker areas of the traveling glass ribbon 20. As shown in Figure 1A, when the glass ribbon 20 moves from left to right, the water core 10 can be suspended on the stand 30 suspended above the glass ribbon conveying system and placed in contact with the glass ribbon 20, and The glass strip 20 is dragged as it travels. Thus, thicker areas can be cooled as a continuous strip in the portion of the glass ribbon 20 in contact with the water core 10 .

或者,如第1B圖所示,玻璃帶可以包括間歇性重複的較厚區域,而不是玻璃帶寬度的連續條帶或部分。例如,第1B圖展示了包括間歇性重複的較厚區域28的玻璃帶25。如圖所示,較厚區域28可以經成形為實質矩形,但是其他形狀亦是可能的。第1B圖亦展示了玻璃帶20上方的冷卻歧管40,用於僅冷卻較厚部分28。Alternatively, as shown in Figure 1B, the glass ribbon may include intermittently repeating thicker regions rather than continuous strips or portions of the width of the glass ribbon. For example, Figure 1B illustrates a glass ribbon 25 that includes intermittently repeating thicker regions 28. As shown, thicker region 28 may be shaped as a substantially rectangular shape, although other shapes are possible. Figure 1B also shows a cooling manifold 40 above the glass ribbon 20 for cooling only the thicker portion 28.

冷卻歧管40可以是實質上平面的並且包括將歧管40連接至水源的水連接配件42、自水連接配件42引導水的水通道44,以及吸收經由水通道44引導至其的水的芯50。水歧管40位於玻璃帶20上方的位置,使得當玻璃帶20行進經過歧管40時玻璃帶20的較厚區域28接觸芯50。歧管40與玻璃帶20相距一定距離,使得較厚區域28可以接觸芯50但較薄區域不接觸。因此,歧管40可以在不冷卻玻璃帶20的較薄區域的情況下冷卻較厚區域28。The cooling manifold 40 may be substantially planar and include a water connection fitting 42 connecting the manifold 40 to a water source, a water channel 44 that directs water from the water connection fitting 42 , and a core that absorbs water directed thereto via the water channel 44 50. The water manifold 40 is positioned above the glass ribbon 20 such that the thicker region 28 of the glass ribbon 20 contacts the core 50 as the glass ribbon 20 travels through the manifold 40 . The manifold 40 is spaced apart from the glass ribbon 20 such that the thicker areas 28 contact the core 50 but the thinner areas do not. Therefore, manifold 40 can cool thicker regions 28 without cooling thinner regions of glass ribbon 20 .

芯材料允許水精確地沉積至正經冷卻的玻璃帶的表面上。水流速經由閥控制及調整,使得蒸發率與水流速相匹配。這確保了最大程度的散熱,而沒有過多的水不受控制地遞送至玻璃帶。例如,藉由以第1A圖所示的方式拖動水芯10,自較厚至較薄的溫度差異(ΔT或DT)減小了約8℃。期望在不冷卻玻璃帶的較薄部分或不向玻璃帶增加應力的情況下儘可能多地減小這個溫度差異。The core material allows precise deposition of water onto the surface of the glass ribbon being cooled. The water flow rate is controlled and adjusted through a valve so that the evaporation rate matches the water flow rate. This ensures maximum heat dissipation without uncontrolled delivery of excess water to the glass ribbon. For example, by dragging the water core 10 in the manner shown in Figure 1A, the temperature difference (ΔT or DT) from thicker to thinner is reduced by approximately 8°C. It is desirable to reduce this temperature difference as much as possible without cooling the thinner portions of the glass ribbon or adding stress to the glass ribbon.

水芯可以由適用於溫度及被冷卻材料的任何吸水材料製成。例如,水芯可以由編織的二氧化矽紗線製成。芯的長度、寬度、厚度、材料皆可以調整,以滿足玻璃帶產品的冷卻需求。The water core can be made of any absorbent material suitable for the temperature and material being cooled. For example, the water core can be made from woven silica yarn. The length, width, thickness and material of the core can be adjusted to meet the cooling needs of the glass ribbon product.

第2圖圖示了根據另一個實施例的使用芯吸輪來冷卻玻璃帶中的較厚區域,該芯吸輪作為第1A圖中所示的水芯10的替代裝置。芯吸輪是用水芯材料包裹的穿孔液體分配輪。雖然任何數目都是可能的,但第2圖的頂部部分展示了兩個芯吸輪的佈置,這些輪用於冷卻連續玻璃帶的較厚中心條帶。芯吸輪的工作原理與使用水芯10的浸透布將水精確地沉積至正經冷卻的玻璃帶的表面上的原理相同。芯吸輪相比水芯10具有一些優點。特別地,芯吸輪可以經部署以冷卻玻璃帶的底側,因為它不依賴重力來保持芯吸材料濕潤並與玻璃帶接觸。與水芯10一樣,經由芯吸輪供應的水流速經節流,使得流速與蒸發率相匹配,以在最大控制下實現最佳冷卻效果。玻璃帶的較厚部分比較薄部分溫度更高。如前所述,期望儘可能將DT減少至0 oC而不會過度冷卻較厚部分。 Figure 2 illustrates the use of a wicking wheel as an alternative to the water core 10 shown in Figure 1A to cool thicker areas in the glass ribbon according to another embodiment. Wicking wheels are perforated liquid distribution wheels wrapped with water core material. While any number is possible, the top portion of Figure 2 shows an arrangement of two wicking wheels used to cool the thicker center strip of continuous glass ribbon. The wicking wheel works on the same principle as using the soaked cloth of the water core 10 to deposit water precisely onto the surface of the glass ribbon being cooled. Wicking wheels have several advantages over water cores 10. In particular, the wicking wheel can be deployed to cool the underside of the glass ribbon because it does not rely on gravity to keep the wicking material wet and in contact with the glass ribbon. As with the water core 10, the water flow rate supplied via the wicking wheel is throttled so that the flow rate matches the evaporation rate for optimal cooling with maximum control. Thicker parts of the glass ribbon are hotter than thinner parts. As mentioned before, it is desirable to reduce DT to 0 o C as much as possible without overcooling the thicker sections.

第2圖的上部部分展示了芯吸輪可以由框架支撐並相對於玻璃帶保持就位。每個芯吸輪可以圍繞由兼作供水管道的軸限定的旋轉軸自由旋轉。供水裝置可以附接至軸一端的旋轉接頭上。第2圖的下部部分是框架及芯吸輪的側視圖,展示了附接至供水裝置的旋轉接頭、將水傳送至芯吸輪的管道以及兩個軸承。The upper portion of Figure 2 shows that the wicking wheel can be supported by the frame and held in place relative to the glass ribbon. Each wicking wheel is free to rotate about an axis of rotation defined by a shaft that doubles as a water supply pipe. The water supply can be attached to a swivel at one end of the shaft. The lower part of Figure 2 is a side view of the frame and wicking wheel, showing the swivel attached to the water supply, the pipe that delivers the water to the wicking wheel, and the two bearings.

第3圖至第5圖展示了根據本揭示案的另一個實施例的冷卻玻璃帶中的較厚區域的霧化裝置。霧化裝置將霧化液體引導至玻璃帶上。液體可以是水、與水的混合物或任何其他合適的流體。Figures 3 to 5 illustrate an atomization device for cooling a thicker area in a glass ribbon according to another embodiment of the present disclosure. The atomizing device directs the atomized liquid onto the glass strip. The liquid may be water, a mixture with water, or any other suitable fluid.

第3圖是在自左至右的方向上行進的玻璃帶上噴射空氣及/或液體的霧化裝置的側視圖。第4圖是向霧化裝置上游看的另一視圖。第5圖是霧化裝置噴射自透射角度的影像。如圖所示,霧化裝置可以包括支撐霧化噴霧器的框架或台架。雖然展示了三個霧化噴霧器,但是任何數目皆是可能的。框架可以包括調整霧化噴霧器距玻璃帶的高度或距離的機構。每個霧化噴霧器皆可以由帶有隔熱罩的空氣淨化外殼包圍。Figure 3 is a side view of an atomizing device that sprays air and/or liquid on a glass ribbon traveling in the direction from left to right. Figure 4 is another view looking upstream of the atomizing device. Figure 5 is an image of the spray from the atomizer device from the transmission angle. As shown, the atomizing device may include a frame or stand that supports the atomizing sprayer. Although three atomizing sprayers are shown, any number is possible. The frame may include a mechanism to adjust the height or distance of the atomizing sprayer from the glass strip. Each atomizing sprayer can be surrounded by an air purifying enclosure with a heat shield.

每個霧化噴霧器亦可以包括用於開啟及關閉霧化噴霧器的致動空氣的耦接件、用於霧化空氣的耦接件、用於液體(亦即,水或其他冷卻劑)的耦接件、用於調整液體流速的機構,以及噴嘴。霧化空氣可以一直持續,但只有在需要時才引入液體噴霧。使用致動空氣允許閥控製冷卻液體定位於噴嘴處,這使得液體噴霧的時間更加精確並減少滴落。如第5圖所示,噴嘴可以更換為噴射冷卻空氣或液體。噴嘴可以扇形或其他合適的幾何形狀輸出空氣及/或液體。可選地,每個霧化噴霧器可以經調整以與另一個霧化噴霧器不同,使得輸出模式不同,或者一個噴射空氣而另一個噴射液體。可選地,霧化裝置可以在玻璃帶進入CCA之前位於玻璃帶上方。 條件 薄 T(C) 厚 T(C) DT (C) 條帶處的壓力(MPa) 橫跨寬度的翹曲* (mm) 基準 660 700 +40 6.7 <0.1 mm 條件2 620 640 +20 4.2 ~5 mm 條件1 620 620 0 3.75 ~3.5 mm 條件3 620 600 -20 6.25 <0.3mm Each atomizing sprayer may also include a coupling for turning the atomizing sprayer's actuation air on and off, a coupling for atomizing air, a coupling for liquid (ie, water or other coolant) Adapters, mechanisms for adjusting the liquid flow rate, and nozzles. The atomizing air can be continued all the time, but the liquid spray is only introduced when needed. The use of actuated air allows the valve to control the positioning of the cooling liquid at the nozzle, which allows for more precise timing of the liquid spray and reduces dripping. As shown in Figure 5, the nozzle can be replaced to spray cooling air or liquid. The nozzle can output air and/or liquid in a fan shape or other suitable geometry. Optionally, each atomizing sprayer can be adjusted to be different from the other atomizing sprayer so that the output pattern is different, or one sprays air while the other sprays liquid. Optionally, an atomizing device can be located above the glass ribbon before it enters the CCA. condition Thin T(C) Thick T(C) DT(C) Pressure at the strip (MPa) Warp across width* (mm) benchmark 660 700 +40 6.7 <0.1 mm Condition 2 620 640 +20 4.2 ~5 mm Condition 1 620 620 0 3.75 ~3.5 mm Condition 3 620 600 -20 6.25 <0.3mm

表1Table 1

表1包括在進入CCA之前在玻璃帶上獲取的經驗資料,其展示玻璃熱學對應力及翹曲*的影響。基準條件是沒有冷卻,而條件1至3各自具有不同位準的冷卻,皆以相同的行進速率。翹曲*是彎曲或整體翹曲,而不是窗簾翹曲,它是由機械來源引起的。表1包括資料獲取條件、玻璃帶較薄部分的溫度、玻璃帶較厚部分的溫度、較薄部分與較厚部分之間的溫度差異(所有溫度以攝氏度為單位),在較厚玻璃條上測得的應力(以兆帕為單位),以及橫跨玻璃帶寬度的翹曲*(以毫米為單位)。Table 1 includes empirical data obtained on glass ribbons prior to entering CCA, which demonstrates the effects of glass thermals on stress and warpage*. The base condition is no cooling, while conditions 1 through 3 each have different levels of cooling, all at the same travel rate. Warping* is bending or overall warping, not curtain warping, which is caused by mechanical sources. Table 1 includes the data acquisition conditions, the temperature of the thinner part of the glass ribbon, the temperature of the thicker part of the glass ribbon, the temperature difference between the thinner part and the thicker part (all temperatures are in degrees Celsius), on the thicker glass strip Measured stress (in MPa), and warpage* (in mm) across the width of the glass ribbon.

經驗條件包括在玻璃帶進入CCA之前具有位於玻璃帶頂面(A側)上方的三個連續霧化噴霧器的霧化裝置。冷卻設置如第5圖所示,其中三個霧化噴霧器在CCA入口前的玻璃帶較厚條帶上方連續排列,位於圖片右側。較厚的條帶為80 mm寬,玻璃帶的較薄部分約為2.0 mm厚,並且較厚的條帶與較薄部分之間的厚度差約為0.35 mm。預CCA熱資料是使用熱像儀捕獲的。表1展示了噴霧冷卻對DT、應力及翹曲的影響。如表1所示,噴水冷卻對於冷卻較厚條帶及將DT自+40℃降低至-20℃(亦即,60℃的效應)非常有效。Empirical conditions include an atomizing device with three continuous atomizing sprayers located above the top surface (A-side) of the glass ribbon before it enters the CCA. The cooling setup is shown in Figure 5, with three atomizing sprayers arranged in a row above a thicker strip of glass ribbon in front of the CCA entrance, on the right side of the picture. The thicker strip is 80 mm wide, the thinner part of the glass strip is approximately 2.0 mm thick, and the thickness difference between the thicker strip and the thinner part is approximately 0.35 mm. Pre-CCA thermal data was captured using a thermal imaging camera. Table 1 shows the effect of spray cooling on DT, stress and warpage. As shown in Table 1, water spray cooling is very effective in cooling thicker strips and reducing DT from +40°C to -20°C (ie, the effect of 60°C).

如表1所示,在條件1(Cond 1)及條件2 (Cond 2)中提供的噴霧冷卻降低了較厚條帶的應力。然而,條件3(Cond 3)提供了與基準條件(Baseline)相似的應力。最佳冷卻位準將取決於條帶的幾何形狀及熱參數。例如,外推至0.8 mm的更高厚度增量,CCA入口處的自厚至薄DT可能約為80℃,而沒有條帶的任何優先冷卻。在這種情況下,DT為60至100℃的冷卻條件可能會提供最小的應力。As shown in Table 1, the spray cooling provided in Condition 1 (Cond 1) and Condition 2 (Cond 2) reduced stress in the thicker strips. However, Cond 3 provides similar stresses to Baseline. The optimal cooling level will depend on the strip geometry and thermal parameters. For example, extrapolating to higher thickness increments of 0.8 mm, the thick-to-thin DT at the entrance to the CCA might be around 80°C without any preferential cooling of the strip. In this case, cooling conditions with a DT of 60 to 100°C may provide minimal stress.

注意,具有最低應力的條件1及2都導致翹曲增加。可以藉由在保持玻璃帶被限制在平坦表面上的同時施加冷卻來避免翹曲增加,例如使用真空輸送機。Note that conditions 1 and 2 with the lowest stress both result in increased warpage. Increased warpage can be avoided by applying cooling while keeping the glass ribbon constrained to a flat surface, such as using a vacuum conveyor.

第6圖展示了用噴水實驗冷卻的較厚區域的應力雙折射量測(條件與表1的一樣)。雙流體霧化噴霧器用於選擇性地冷卻玻璃帶的較厚部分。雙流體霧化噴霧器的優點包括精確控制水及空氣流速、能夠循環開/關以進行非連續冷卻,以及能夠調諧水滴大小以減少萊頓弗羅斯特(Leidenfrost)效應並改善散熱。扇形噴射圖案的噴嘴用於促進橫跨貼片的均勻冷卻速率。Figure 6 shows the stress birefringence measurement of a thicker area experimentally cooled by water spray (conditions are the same as in Table 1). A two-fluid atomizing sprayer is used to selectively cool thicker portions of the glass ribbon. Advantages of dual-fluid atomizing sprayers include precise control of water and air flow rates, the ability to cycle on/off for discontinuous cooling, and the ability to tune droplet size to reduce the Leidenfrost effect and improve heat dissipation. A fan spray pattern of nozzles is used to promote a uniform cooling rate across the patch.

第6圖中所示的左側影像是沒有冷卻的玻璃帶,基準條件具有6.7 MPa的應力。第6圖中所示的右側影像是在較厚部分上噴射冷卻的玻璃帶。右側影像來自表1中的條件2,其應力為3.75 MPa。The left image shown in Figure 6 is of the uncooled glass ribbon, with a baseline condition of 6.7 MPa stress. The image on the right shown in Figure 6 is of a glass ribbon spray cooled over a thicker section. The image on the right is from Condition 2 in Table 1, which has a stress of 3.75 MPa.

第6圖的雙折射資料展示了玻璃帶的不同部分的光學特性差異,並代表了應力差異。雙折射: S1-S2 = 延遲/(厚度*SOC) S1-S2 = 面內主應力之差 延遲單位:mm SOC(應力光學係數)~ 3 nm/MPa-mm The birefringence data in Figure 6 illustrates the differences in optical properties of different parts of the glass ribbon and represents stress differences. Birefringence: S1-S2 = delay/(thickness*SOC) S1-S2 = Difference of in-plane principal stresses Delay unit: mm SOC (stress optical coefficient) ~ 3 nm/MPa-mm

在本揭示案的另一個實施例中,第7圖展示了可以用於優先加熱玻璃帶的部分以降低較厚部分與較薄部分之間的熱梯度的加熱器。所示加熱器在玻璃帶進入CCA之前位於玻璃帶上方,但任何合適的位置皆是可能的,包括玻璃帶下方。在這個實例中,有兩組加熱器,每組具有兩個加熱元件,對稱地置放在玻璃帶的每一側並遠離較厚的中心條帶區域以主要向玻璃帶的外部較薄部分提供優先加熱。In another embodiment of the present disclosure, Figure 7 illustrates a heater that can be used to preferentially heat portions of a glass ribbon to reduce the thermal gradient between thicker portions and thinner portions. The heater is shown positioned above the glass ribbon before it enters the CCA, but any suitable location is possible, including below the glass ribbon. In this example, there are two sets of heaters, each with two heating elements, placed symmetrically on each side of the glass ribbon and away from the thicker central strip area to provide primarily to the outer, thinner portions of the glass ribbon. Prioritize heating.

第8圖展示了在實際試驗中相對於具有80 mm寬的較厚中心條帶的330 mm寬玻璃帶定位的四個加熱器的佈置及相對間距。在第8圖中,玻璃帶在黏性轉向VT與CCA之間自右向左移動,其中在黏性轉向VT處,玻璃帶自豎直移動轉向水平移動。Figure 8 shows the arrangement and relative spacing of four heaters positioned relative to a 330 mm wide glass strip with a thicker center strip of 80 mm width in a real trial. In Figure 8, the glass ribbon moves from right to left between the viscous turning VT and CCA, where at the viscous turning VT, the glass ribbon moves from vertical to horizontal movement.

分析估計及數值模型化證明加熱器的有效性,並且展示了這種優先加熱方法相對於沒有這種加熱器的設備設置的優勢。為了評估加熱器的有效性,第9圖展示了加熱器面溫度與玻璃帶溫度之間的關係,其中1.3 mm厚的玻璃帶經過12”長的加熱器。該圖中展示了兩種情況:玻璃帶在850℃或750℃下進入加熱器,兩者均有約1400 lbs/hr的玻璃流,速度約為0.14 m/s。玻璃帶的總寬度為330 mm,並且較厚的中心條帶的寬度為80 mm。較薄部分的厚度為1.3 mm,並且較厚的中心條帶的厚度為2.9 mm,因此厚度增量為1.6 mm。假設加熱器的面溫度工作上限為900℃,從這一分析關係可以預計,對於離開加熱器的850℃情況,基礎帶溫度可能會增加約8℃,而對於750℃情況,則可能增加約22℃,其中第9圖展示兩種情況下曲線越過900℃時基礎溫度升高。自這一分析估計中得出的結論是,加熱器面與基礎帶之間的較高溫度增量會導致較大的溫度升高。因此,加熱器可以置放在更下游或考慮更高的工作溫度,以最大限度地提高加熱效率。Analytical estimates and numerical modeling demonstrate the effectiveness of the heater and demonstrate the advantages of this preferential heating approach over a device setup without such a heater. To evaluate the effectiveness of the heater, Figure 9 shows the relationship between heater face temperature and glass ribbon temperature, where a 1.3 mm thick glass ribbon passes through a 12” long heater. Two situations are shown in this graph: The glass ribbon enters the heater at 850°C or 750°C, both with a glass flow of approximately 1400 lbs/hr and a velocity of approximately 0.14 m/s. The total width of the glass ribbon is 330 mm, with a thicker center strip The width is 80 mm. The thickness of the thinner part is 1.3 mm, and the thickness of the thicker center strip is 2.9 mm, so the thickness increment is 1.6 mm. Assuming that the upper face temperature operating limit of the heater is 900°C, from this An analytical relationship can predict that for the 850°C case leaving the heater, the base band temperature may increase by about 8°C, and for the 750°C case, it may increase by about 22°C, with Figure 9 showing the curves crossing 900 in both cases. The base temperature rises when Go further downstream or consider higher operating temperatures to maximize heating efficiency.

為了證明相對於沒有額外局部加熱的習知退火爐的熱管理優勢,第10圖是數值模型化圖,比較了有和沒有額外局部加熱器的預CCA區段中的玻璃帶熱歷史。第10圖繪製了玻璃溫度與玻璃距VT的距離的模型資料。模型中考慮的加熱器配置如第8圖所示。同樣,考慮兩個初始條件:玻璃帶的起始溫度為850℃或750℃。繪製的實線是用加熱器照射的玻璃的溫度,其面溫度保持在900℃。虛線表示設備設置,其中有Zircar板,一種用於保持熱量的低膨脹高強度增強二氧化矽基質複合材料,作為主要熱管理工具的退火爐的兩個模組部分(M2及M3)。圖中的凸點展示了兩組加熱器的玻璃帶溫度升高,並且它們的幅度在比例關係預測的範圍內,亦即,在850℃情況下連續兩組加熱器的溫度大約5℃及10℃,而在750℃情況下兩組加熱器的溫度都在15℃左右。如第10圖中的子表所示,在850℃情況下,當玻璃帶到達CCA入口時,添加兩組加熱器使玻璃帶溫度增加8℃(自684℃至676℃),而在750℃情況下增加20℃(自637℃至617℃)。To demonstrate the thermal management advantages over a conventional annealing furnace without additional local heating, Figure 10 is a numerical modeling plot comparing the thermal history of the glass ribbon in the pre-CCA section with and without additional local heaters. Figure 10 plots model data for glass temperature versus distance of the glass from VT. The heater configuration considered in the model is shown in Figure 8. Again, consider two initial conditions: the starting temperature of the glass ribbon is 850°C or 750°C. The solid line drawn is the temperature of the glass irradiated with a heater, and its surface temperature is maintained at 900°C. The dashed line represents the equipment setup, which includes Zircar plates, a low-expansion high-strength reinforced silica matrix composite used to retain heat, and the two modular sections (M2 and M3) of the annealing furnace as the primary thermal management tool. The bumps in the figure show the temperature rise of the glass ribbon for both sets of heaters, and their amplitudes are within the range predicted by the proportional relationship, that is, at 850°C, the temperatures of the two consecutive sets of heaters are approximately 5°C and 10°C. ℃, while at 750 ℃, the temperatures of both sets of heaters are around 15 ℃. As shown in the sub-table in Figure 10, at 850°C, when the glass ribbon reaches the CCA inlet, adding two sets of heaters increases the glass ribbon temperature by 8°C (from 684°C to 676°C), while at 750°C In this case, increase by 20℃ (from 637℃ to 617℃).

第11圖是模型化資料,進一步比較了預CCA加熱器與標準設備設置的自厚至薄的熱梯度降低。與關於圖10所描述的相同的條件適用於第11圖。這裡,如第11圖中的子表所示,對於CCA入口處850℃的情況,添加兩組加熱器將自厚至薄的DT降低約30℃(141℃至113℃),而與標準設備設置相比,降低約40℃(196℃至157℃)。自分析估計及數值模型化,證明預CCA區域中的基礎帶加熱器可以作為有效的優先熱管理工具實施,有助於降低自厚至薄的DT。Figure 11 is modeled data that further compares the thermal gradient reduction from thick to thin between a pre-CCA heater and a standard equipment setup. The same conditions as described with respect to Figure 10 apply to Figure 11. Here, as shown in the sub-table in Figure 11, for the case of 850°C at the CCA inlet, adding two sets of heaters reduces the DT from thick to thin by about 30°C (141°C to 113°C) compared to the standard equipment Compared with the setting, it is about 40℃ lower (196℃ to 157℃). Self-analytical estimation and numerical modeling demonstrate that baseband heaters in the pre-CCA region can be implemented as an effective priority thermal management tool, helping to reduce thick-to-thin DT.

第12圖表示包括熱反射器(Zircar隧道及輻射原理)的退火爐的一部分。在第12圖中,玻璃帶在黏性轉向後自右至左移動。實驗表明,退火爐模組M2及M3上的兩個Zircar板可以將CCA入口處的玻璃帶溫度提高約25℃。藉由將Zircar板單獨置放在較薄部分上方並確保較厚部分保持輻射至冷得多的表面(<200℃至300℃)或對流冷卻,使用兩個以上的Zircar板或類似的熱反射器可以幫助將自厚至薄的DT減少25℃或更多。Figure 12 shows a part of an annealing furnace including a heat reflector (Zircar tunnel and radiation principle). In Figure 12, the glass ribbon moves from right to left after a viscous turn. Experiments show that the two Zircar plates on the annealing furnace modules M2 and M3 can increase the temperature of the glass strip at the CCA entrance by about 25°C. Use two or more Zircar panels or similar heat reflectors by placing the Zircar panels individually over the thinner sections and ensuring that the thicker sections remain radiant to a much cooler surface (<200°C to 300°C) or convection cooling The device can help reduce DT from thick to thin by 25°C or more.

第13圖及第14圖展示了使用「氣桿」的情況,氣桿使用強制空氣來冷卻玻璃帶的較厚部分。第13圖展示了在玻璃帶上方具有氣桿的配置,而第14圖展示了在玻璃帶下方具有三個氣桿的配置。藉由使用對流,強制空氣允許自玻璃帶的較厚部分集中移除熱量,而不自較薄部分移除熱量,從而減少自厚至薄的DT。強制空氣可以包括作為加濕手段的蒸汽注入,其增加空氣的熱容量並因此增加氣桿的有效性以降低較厚部分的溫度。Figures 13 and 14 show the use of "air rods" which use forced air to cool the thicker parts of the glass ribbon. Figure 13 shows a configuration with air bars above the glass ribbon, while Figure 14 shows a configuration with three air bars below the glass ribbon. By using convection, forced air allows concentrated heat removal from thicker parts of the glass ribbon without removing heat from thinner parts, thereby reducing thick-to-thin DT. Forced air may include steam injection as a means of humidification, which increases the heat capacity of the air and therefore increases the effectiveness of the air rods in reducing the temperature of thicker sections.

時間 條件 DR FR 0 FR1 FR2 # 重量 表設置 熱設置 01h41m C10 1.04 28 M1上有1個SiC桿 Zircar板,無冷卻工具 02h57m C11 1.04 28 M1上有1個SiC桿 無Zircar板 03h49m C12 1.04 28 M1上有1個SiC桿 Zircar,帶水芯 05h08m C13 1.04 28 M1上有1個SiC桿 Zircar,A側帶氣桿 05h42m C14 1.04 28 M1上有1個SiC桿 Zircar,中間不帶任何裝置 06h48m Q15 1.04 28 M1上有1個SiC桿 Zircar,B側帶空氣冷卻- 中度 - 無Zircar板 07h20m C16 1.04 28 M1上有1個SiC桿 Zircar,B側帶空氣冷卻- 高度 - 無Zircar板 07h58m C17 1.04 28 M1上有1個SiC桿 Zircar,B側帶空氣冷卻- 高度 - Zircar板 表2 time condition DR FR 0 FR1 FR2 #weight table settings Thermal settings 01h41m C10 1.04 shallow shallow shallow 28 There is 1 SiC rod on the M1 Zircar plate, no cooling tool 02h57m C11 1.04 shallow shallow shallow 28 There is 1 SiC rod on the M1 No Zircar board 03h49m C12 1.04 shallow shallow shallow 28 There is 1 SiC rod on the M1 Zircar, with water core 05h08m C13 1.04 shallow shallow shallow 28 There is 1 SiC rod on the M1 Zircar, A side with aerobar 05h42m C14 1.04 shallow shallow shallow 28 There is 1 SiC rod on the M1 Zircar without any device in between 06h48m Q15 1.04 shallow shallow shallow 28 There is 1 SiC rod on the M1 Zircar, B side with air cooling - medium - without Zircar plate 07h20m C16 1.04 shallow shallow shallow 28 There is 1 SiC rod on the M1 Zircar, B side with air cooling - height - without Zircar plate 07h58m C17 1.04 shallow shallow shallow 28 There is 1 SiC rod on the M1 Zircar, B side with air cooling - height - Zircar plate Table 2

表2列舉了用於熱測試的熱設置條件,其結果展示在第15圖及第16圖的圖表中。第15圖及第16圖展示了較厚部分的最大光學延遲及B側部件尺寸翹曲(PSW)。A側及B側冷卻均將自厚至薄的DT及較厚部分的應力降低了高達25%。藉由A側冷卻,與Zircar板的基準情況相比,翹曲位準保持不變。另一方面,B側冷卻情況C15及C16的翹曲增加,這是由於玻璃帶上方沒有使用Zircar板,因此玻璃帶較冷。條件C17的翹曲相對較低,其在玻璃帶上方同時具有B側冷卻和Zircar板,但仍略高於基準條件及A側冷卻情況。Table 2 lists the thermal setup conditions used for thermal testing, the results of which are shown in the graphs in Figures 15 and 16. Figures 15 and 16 show the maximum optical retardation and B-side part size warpage (PSW) of the thicker part. Both A-side and B-side cooling reduce the stress in DT and thicker parts from thick to thin by up to 25%. With A-side cooling, the warpage level remains unchanged compared to the baseline case of Zircar plates. On the other hand, the warpage of C15 and C16 increases in the B-side cooling cases. This is due to the fact that no Zircar plate is used above the glass ribbon, so the glass ribbon is cooler. Warpage is relatively low for condition C17, which has both B-side cooling and Zircar plates above the glass ribbon, but is still slightly higher than the baseline condition and the A-side cooling case.

結果與預期一致,亦即,在整平輥FR1及FR2之前對較厚部分施加較慢的冷卻速率可以減少應力而不增加翹曲。The results are as expected, i.e., applying a slower cooling rate to the thicker portion before the leveling rollers FR1 and FR2 reduces stress without increasing warpage.

第17圖表示在氣桿上方行進的玻璃帶的側視圖。氣桿為玻璃帶提供支撐並且氣流使得空氣可以在氣桿與玻璃帶之間逸出。氣桿的寬度可以改變,以提供更多或更少的面積供氣流離開氣桿。Figure 17 shows a side view of the glass ribbon traveling over the gas mast. The air rods provide support for the glass ribbon and the air flow allows air to escape between the air rods and the glass ribbon. The width of the air rod can be changed to provide more or less area for airflow to exit the air rod.

第18圖表示三個氣桿的俯視圖。灰色區域對應於璃帶的較厚部分,而粉色區域對應於較薄部分。可以冷卻灰色區域以降低溫度並增加對應於較厚部分的區域中的傳導熱傳遞速率。粉色區域可以塗有熱障塗層(例如,氧化鋯)以增加較薄部分的溫度並降低玻璃帶與對應於玻璃帶的較薄部分的區域中的氣桿之間的熱傳遞速率。可選地,可以在粉色區域使用過熱蒸汽(在~900℃下),代替室溫壓縮空氣與氣桿一起使用使玻璃漂浮以提高溫度並降低與玻璃帶的較薄部分對應的區域的傳熱率。Figure 18 shows a top view of three air rods. The gray areas correspond to thicker parts of the glass ribbon, while the pink areas correspond to thinner parts. The gray areas can be cooled to lower the temperature and increase the rate of conductive heat transfer in the areas corresponding to the thicker sections. The pink area may be coated with a thermal barrier coating (e.g., zirconia) to increase the temperature of the thinner portion and reduce the rate of heat transfer between the glass ribbon and the air rod in the area corresponding to the thinner portion of the glass ribbon. Optionally, superheated steam (at ~900°C) can be used in the pink area instead of room temperature compressed air in conjunction with air rods to float the glass to increase the temperature and reduce heat transfer in the areas corresponding to the thinner parts of the glass ribbon Rate.

第19圖表示一個實施例,其中玻璃帶的較厚部分與較薄部分之間的溫度差異在黏性轉向之前的輥壓成型階段減小。在這個實施例中,強制空氣在玻璃帶的較厚部分橫穿的部分處自噴嘴被引導至成形輥。引導至輥的較厚部分的強制空氣降低了輥的表面溫度並且使自玻璃帶的較厚部分移除的熱能的量最大化。引導較厚部分的壓縮空氣直接自與空氣集中的位置相對應的玻璃帶中帶走熱量。強制空氣可以與蒸汽注入相輔相成,以增加熱容量及強制空氣移除熱量的有效性。Figure 19 shows an embodiment in which the temperature difference between the thicker and thinner portions of the glass ribbon is reduced during the roll forming stage prior to viscosity turn. In this embodiment, forced air is directed from the nozzle to the forming roll at the portion across which the thicker portion of the glass ribbon crosses. The forced air directed to the thicker portion of the roll reduces the surface temperature of the roll and maximizes the amount of thermal energy removed from the thicker portion of the glass ribbon. Compressed air directed over thicker sections removes heat directly from the glass ribbon corresponding to the location where the air is concentrated. Forced air can be complemented with steam injection to increase heat capacity and the effectiveness of forced air in removing heat.

應當理解,前述描述僅是對本發明的說明。在不偏離本發明的情況下,本發明所屬領域中具有通常知識者可以想出各種替換及修改。因此,本發明意欲涵蓋落入所附申請專利範圍內的所有此類替代、修改及變化。It should be understood that the foregoing description is merely illustrative of the invention. Various substitutions and modifications may be devised by those skilled in the art without departing from the invention. Accordingly, the present invention is intended to cover all such alternatives, modifications, and variations falling within the scope of the appended claims.

10:水芯 20:玻璃帶 28:較厚區域 30:台架 40:冷卻歧管 42:自水連接配件 44:水通道 50:芯 10:water core 20:Glass ribbon 28:Thick area 30:Bench 40: Cooling manifold 42: Self-water connection accessories 44:Water channel 50:Core

第1A圖展示了冷卻玻璃帶的較厚區域的水芯。Figure 1A shows the water core cooling the thicker areas of the glass ribbon.

第1B圖展示了包括水芯的歧管,水芯用以冷卻玻璃帶的間歇性較厚區域。Figure 1B shows a manifold including a water core used to cool intermittent thicker areas of the glass ribbon.

第2圖展示了冷卻玻璃帶的較厚部分的芯吸輪。Figure 2 shows the wicking wheel cooling the thicker part of the glass ribbon.

第3圖至第5圖展示了冷卻玻璃帶的較厚區域的霧化裝置。Figures 3 to 5 show atomization devices that cool thicker areas of the glass ribbon.

第6圖展示了用噴水實驗冷卻的較厚部分的應力雙折射量測。Figure 6 shows the stress birefringence measurement of a thicker section experimentally cooled with water spray.

第7圖展示了用於優先加熱玻璃帶的部分的加熱器。Figure 7 shows a heater for preferentially heating portions of the glass ribbon.

第8圖展示了相對於玻璃帶定位的四個加熱器的佈置及相對間距。Figure 8 shows the arrangement and relative spacing of the four heaters positioned relative to the glass ribbon.

第9圖是展示了加熱器面溫度與經過加熱器的帶的玻璃帶溫度的關係的曲線圖。Figure 9 is a graph showing the relationship between the heater surface temperature and the glass ribbon temperature of the ribbon passing through the heater.

第10圖繪製了玻璃溫度與玻璃距黏性轉向的距離的模型資料。Figure 10 plots model data for glass temperature versus distance of the glass from the viscous turn.

第11圖是將預CCA加熱器的自厚至薄熱梯度降低與標準設備設置進行比較的模型資料圖。Figure 11 is a model data plot comparing the thick-to-thin thermal gradient reduction of a pre-CCA heater with a standard equipment setup.

第12圖表示包括熱反射器的退火爐的一部分。Figure 12 shows a part of an annealing furnace including a heat reflector.

第13圖及第14圖展示了氣桿的使用,氣桿使用強制空氣來冷卻玻璃帶的較厚部分。Figures 13 and 14 illustrate the use of air rods, which use forced air to cool thicker portions of the glass ribbon.

第15圖及第16圖展示了較厚部分及B側部分尺寸翹曲的光學延遲測試資料。Figures 15 and 16 show the optical delay test data of the dimensional warpage of the thicker part and the B-side part.

第17圖表示在氣桿上方行進的玻璃帶的側視圖。Figure 17 shows a side view of the glass ribbon traveling over the gas mast.

第18圖表示三個氣桿的俯視圖。Figure 18 shows a top view of three air rods.

第19圖表示一個實施例,其中玻璃帶的較厚部分與較薄部分之間的溫度差異在黏性轉向之前的輥壓成形階段減小。Figure 19 illustrates an embodiment in which the temperature difference between the thicker and thinner portions of the glass ribbon is reduced during the roll forming stage prior to viscosity turn.

國內寄存資訊(請依寄存機構、日期、號碼順序註記) 無 國外寄存資訊(請依寄存國家、機構、日期、號碼順序註記) 無 Domestic storage information (please note in order of storage institution, date and number) without Overseas storage information (please note in order of storage country, institution, date, and number) without

20:玻璃帶 20:Glass ribbon

28:較厚區域 28:Thick area

40:冷卻歧管 40: Cooling manifold

42:自水連接配件 42: Self-water connection accessories

44:水通道 44:Water channel

50:芯 50:Core

Claims (20)

一種玻璃帶處理設備,用於生產一第一厚度的一第一部分與一第二厚度的一第二部分緊鄰的一玻璃帶,該設備包含一水芯,該水芯接觸該玻璃帶的該第一部分以當該玻璃帶行進經過該水芯時冷卻該第一部分,其中該第一厚度大於該第二厚度。A glass ribbon processing apparatus for producing a glass ribbon having a first portion of a first thickness adjacent to a second portion of a second thickness, the apparatus including a water core contacting the third portion of the glass ribbon A portion to cool the first portion as the glass ribbon travels through the water core, wherein the first thickness is greater than the second thickness. 如請求項1所述之玻璃帶處理設備,其中該第一部分以一第一速率冷卻並且該第二部分以一第二速率冷卻,其中該第一速率大於該第二速率。The glass ribbon processing equipment of claim 1, wherein the first part is cooled at a first rate and the second part is cooled at a second rate, wherein the first rate is greater than the second rate. 如請求項1所述之玻璃帶處理設備,其中該第一部分及該第二部分沿該玻璃帶的一長度縱向定向。The glass ribbon processing equipment of claim 1, wherein the first part and the second part are oriented longitudinally along a length of the glass ribbon. 如請求項1所述之玻璃帶處理設備,進一步包含位於該水芯上游的一加熱器。The glass ribbon processing equipment of claim 1 further includes a heater located upstream of the water core. 如請求項1所述之玻璃帶處理設備,其中該水芯是一織物條帶。The glass ribbon processing equipment of claim 1, wherein the water core is a fabric strip. 如請求項5所述之玻璃帶處理設備,其中該水芯的一端固定在該玻璃帶上方。The glass ribbon processing equipment as claimed in claim 5, wherein one end of the water core is fixed above the glass ribbon. 如請求項1所述之玻璃帶處理設備,其中該水芯為圓形,並且繞一軸旋轉。The glass ribbon processing equipment as described in claim 1, wherein the water core is circular and rotates around an axis. 如請求項7所述之玻璃帶處理設備,其中當該玻璃帶沿一水平方向行進時,該水芯位於該玻璃帶下方。The glass ribbon processing equipment as claimed in claim 7, wherein when the glass ribbon travels in a horizontal direction, the water core is located below the glass ribbon. 如請求項1所述之玻璃帶處理設備,其中該水芯附接至一實質上平面的板上。The glass ribbon processing equipment of claim 1, wherein the water core is attached to a substantially planar plate. 一種用於生產具有可變厚度的一玻璃帶的玻璃帶處理設備,該設備包含一霧化器以當該玻璃帶行進經過該霧化器時將一冷卻液及/或冷卻空氣噴射在該玻璃帶的一較厚部分上以冷卻該較厚部分。A glass ribbon processing equipment for producing a glass ribbon with variable thickness, the apparatus includes an atomizer to spray a cooling liquid and/or cooling air on the glass as the glass ribbon travels through the atomizer on a thicker part of the belt to cool the thicker part. 一種用於生產具有可變厚度的一玻璃帶的玻璃帶處理設備,該設備包含一加熱器以當該玻璃帶行進經過加該熱器時加熱該玻璃帶的一較薄部分。A glass ribbon processing apparatus for producing a glass ribbon of variable thickness, the apparatus includes a heater to heat a thinner portion of the glass ribbon as the glass ribbon travels past the heater. 如請求項11所述之玻璃帶處理設備,其中該加熱器為橫跨該玻璃帶的一寬度對稱定位的兩個加熱器。The glass ribbon processing equipment of claim 11, wherein the heater is two heaters positioned symmetrically across a width of the glass ribbon. 如請求項11所述之玻璃帶處理設備,其中該加熱器為兩個加熱器,一個位於該玻璃帶上方,一個位於該玻璃帶下方。The glass ribbon processing equipment of claim 11, wherein the heater is two heaters, one located above the glass ribbon and one located below the glass ribbon. 一種用於生產具有可變厚度的一玻璃帶的玻璃帶處理設備,該設備包含一氣桿以當該玻璃帶行進經過該氣桿時迫使空氣到達該玻璃帶的一部分上。A glass ribbon processing apparatus for producing a glass ribbon having a variable thickness includes an air rod to force air onto a portion of the glass ribbon as the glass ribbon travels past the air rod. 如請求項14所述之玻璃帶處理設備,其中該氣桿位於該玻璃帶下方。The glass ribbon processing equipment as claimed in claim 14, wherein the air rod is located below the glass ribbon. 如請求項15所述之玻璃帶處理設備,其中該氣桿支撐該玻璃帶。The glass ribbon processing equipment of claim 15, wherein the air rod supports the glass ribbon. 如請求項14所述之玻璃帶處理設備,其中該氣桿迫使冷卻空氣到達該玻璃帶的一較厚部分。The glass ribbon processing apparatus of claim 14, wherein the air rod forces cooling air to reach a thicker portion of the glass ribbon. 如請求項14所述之玻璃帶處理設備,其中該空氣包括蒸汽並且經迫使至該玻璃帶的一較薄部分上。The glass ribbon processing apparatus of claim 14, wherein the air includes steam and is forced onto a thinner portion of the glass ribbon. 一種玻璃帶處理設備,用於生產包括一第一厚度及一第二厚度的一玻璃帶,該設備包含: 一輥,當該玻璃帶行進經過該輥時支撐該玻璃帶;以及 一噴嘴,該噴嘴迫使冷卻空氣至接觸該玻璃帶的該輥的一部分上,其中該第一厚度大於該第二厚度。 A glass ribbon processing equipment for producing a glass ribbon including a first thickness and a second thickness, the equipment includes: a roller to support the glass ribbon as it travels past the roller; and A nozzle forcing cooling air onto a portion of the roll contacting the glass ribbon, wherein the first thickness is greater than the second thickness. 如請求項19所述之玻璃帶處理設備,其中該輥與該玻璃帶接觸的該部分對應於該第一厚度。The glass ribbon processing equipment of claim 19, wherein the portion of the roller in contact with the glass ribbon corresponds to the first thickness.
TW112114395A 2022-04-20 2023-04-18 Thermal management of variable thickness glass ribbon TW202406862A (en)

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US8397536B2 (en) * 2010-05-26 2013-03-19 Corning Incorporated Apparatus and method for controlling thickness of a flowing ribbon of molten glass
US9682882B2 (en) * 2014-07-17 2017-06-20 Corning Incorporated Methods for producing a glass ribbon
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