TW202105016A - Optical laminate and method for manufacturing same - Google Patents
Optical laminate and method for manufacturing same Download PDFInfo
- Publication number
- TW202105016A TW202105016A TW109123640A TW109123640A TW202105016A TW 202105016 A TW202105016 A TW 202105016A TW 109123640 A TW109123640 A TW 109123640A TW 109123640 A TW109123640 A TW 109123640A TW 202105016 A TW202105016 A TW 202105016A
- Authority
- TW
- Taiwan
- Prior art keywords
- front panel
- flexible front
- optical
- optical member
- optical laminate
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
- G09F9/30—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
- G09F9/301—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements flexible foldable or roll-able electronic displays, e.g. thin LCD, OLED
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/0004—Cutting, tearing or severing, e.g. bursting; Cutter details
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/20—Displays, e.g. liquid crystal displays, plasma displays
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Engineering & Computer Science (AREA)
- Theoretical Computer Science (AREA)
- Polarising Elements (AREA)
- Electroluminescent Light Sources (AREA)
- Laminated Bodies (AREA)
Abstract
Description
本發明是有關於一種光學積層體及其製造方法。The present invention relates to an optical laminate and a manufacturing method thereof.
近年來,廣泛使用將液晶顯示裝置(液晶顯示器(Liquid Crystal Display,LCD))等各種顯示裝置以及觸控面板等結合使用的輸入裝置。例如,於智慧型電話或平板電腦(tablet)等移動設備設置有觸控面板。In recent years, input devices combining various display devices such as liquid crystal display devices (Liquid Crystal Display (LCD)) and touch panels have been widely used. For example, mobile devices such as smart phones or tablets are provided with touch panels.
如此種顯示裝置、輸入裝置等般的顯示器裝置為了保護顯示器面板免受刮擦(scratch)或外部衝擊的影響,而於顯示器面板上包括玻璃製的前面板,以便保護顯示器,通常,如觸控面板、偏光板等般的光學構件是以如下形態、即、使用黏著劑以小於前面板的尺寸進行積層的形態存在。In order to protect the display panel from scratches or external impact, display devices such as such display devices and input devices include a glass front panel on the display panel to protect the display, usually, such as touch Optical members such as panels and polarizing plates exist in a form in which an adhesive is used to be laminated with a size smaller than the front plate.
另一方面,柔性顯示器(flexible display)作為下一代顯示裝置而快速顯露頭角,所述柔性顯示器是使用如塑膠等般具有柔軟性的材料來代替現有的沒有柔軟性的玻璃,且即便如紙般進行彎折亦可原樣維持顯示性能。On the other hand, flexible displays are rapidly emerging as the next-generation display devices. The flexible displays use flexible materials such as plastic to replace the existing glass that has no flexibility and is even paper-like. The display performance can be maintained as it is by bending.
為了應用於此種柔性顯示器,嘗試有將玻璃製前面板變更為可撓性前面板,但於以小於可撓性前面板的尺寸使用黏著劑積層光學構件的形態的情況下,可撓性前面板的露出部於彎曲時誘發損傷而有時產生彎曲性能多少會降低的問題,另外,因可撓性前面板與光學構件的尺寸的偏差量的非顯示部區域而產生畫面比多少會損失的問題。In order to apply to such a flexible display, attempts have been made to change the glass front panel to a flexible front panel. However, in the case of a form in which an adhesive layered optical member is used in a size smaller than the flexible front panel, the flexible front panel The exposed part of the panel induces damage during bending, which sometimes causes a problem that the bending performance is somewhat reduced. In addition, the non-display area due to the deviation of the size of the flexible front panel and the optical member may cause the screen ratio to be somewhat lost. problem.
大韓民國公開專利第2015-0092777號是有關於一種顯示裝置以及顯示裝置的製造方法,且揭示有與如下顯示裝置相關的內容,所述顯示裝置包括:顯示面板,包含下部基板、配置於所述下部基板上的開關元件、配置於所述開關元件上的發光結構物、配置於所述發光結構物上的密封部、顯示區域以及包圍所述顯示區域的周邊區域;接著構件,配置於所述顯示面板上;透明構件,配置於所述接著構件上;遮光構件,於所述周邊區域中配置於所述透明構件的底面上;相位延遲層,配置於所述顯示面板與所述接著構件之間;以及線偏光層,配置於所述接著構件與所述透明構件之間且與所述遮光構件部分重疊。Korean Patent Publication No. 2015-0092777 relates to a display device and a manufacturing method of the display device, and discloses content related to the following display device. The display device includes: a display panel, including a lower substrate, arranged in the lower portion The switching element on the substrate, the light-emitting structure arranged on the switching element, the sealing portion arranged on the light-emitting structure, the display area, and the peripheral area surrounding the display area; and then the component is arranged on the display On the panel; transparent member arranged on the bonding member; shading member arranged on the bottom surface of the transparent member in the peripheral area; phase retardation layer arranged between the display panel and the bonding member And a linear polarizing layer, which is disposed between the adhesive member and the transparent member and partially overlaps the light-shielding member.
但是,實際情況為:如所述文獻般的現有技術中,依然具有大的非顯示部區域而產生畫面比的損失,且針對彎曲性能無法提出代替方案。 [現有技術文獻] [專利文獻]However, the actual situation is that the prior art like the document still has a large non-display area and causes a loss of screen ratio, and it is impossible to propose an alternative to the bending performance. [Prior Art Literature] [Patent Literature]
[專利文獻1]大韓民國公開專利第2015-0092777號(2015.08.17.)[Patent Document 1] Korean Patent Publication No. 2015-0092777 (2015.08.17.)
[發明所欲解決之課題] 本發明欲提供一種光學積層體,其藉由縮小不需要的遮蔽區域來提高畫面比、且彎曲性能優異。[The problem to be solved by the invention] The present invention intends to provide an optical laminated body, which improves the screen ratio by reducing the unnecessary shielding area and has excellent bending performance.
進而,本發明欲提供一種光學積層體的製造方法,其能夠縮小不需要的遮蔽區域、且可抑制彎曲評價時的裂紋產生。 [解決課題之手段]Furthermore, the present invention intends to provide a method of manufacturing an optical laminate that can reduce unnecessary shielding areas and can suppress the occurrence of cracks during bending evaluation. [Means to solve the problem]
本發明提供一種光學積層體,包括:可撓性前面板、以及存在於所述可撓性前面板的下部的至少一個以上的光學構件,並且所述光學構件的相向端部中,所述光學構件的最後退的端部位於自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。The present invention provides an optical laminate, including: a flexible front panel, and at least one optical member existing in a lower portion of the flexible front panel, and in the opposing ends of the optical member, the optical The last retracted end of the member is located at a position where the distance to the inside from the end of the flexible front panel is less than 2.0 mm.
進而,本發明提供一種光學積層體的製造方法,包括:提供至少一個以上的光學構件的階段;於所述光學構件上提供可撓性前面板的階段;將所述光學構件與所述可撓性前面板黏合的階段;以及將經黏合的所述光學構件與所述可撓性前面板以單元為單位切斷一次以上的階段,並且以所述光學構件的相向端部中、所述光學構件的最後退的端部位於自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置的方式進行切斷。 [發明的效果]Furthermore, the present invention provides a method of manufacturing an optical laminate, including: a stage of providing at least one optical member; a stage of providing a flexible front panel on the optical member; and combining the optical member with the flexible The stage of bonding the optical front panel; and the stage of cutting the bonded optical member and the flexible front panel more than once in units of units, and the optical member is at the opposing end of the optical member. The last retracted end of the member is cut so that the distance inward from the end of the flexible front panel is less than 2.0 mm. [Effects of the invention]
本發明的光學積層體具有畫面比廣、彎曲性能優異的優點。 進而,本發明的光學積層體的製造方法具有可縮小非顯示區域、且可抑制彎曲評價時的裂紋產生的優點。The optical laminate of the present invention has the advantages of wide screen ratio and excellent bending performance. Furthermore, the manufacturing method of the optical laminated body of this invention has the advantage of being able to reduce a non-display area, and can suppress the generation of cracks at the time of bending evaluation.
以下,更詳細地說明本發明。 於本發明中,所謂某構件位於其他構件「上」,不僅包括某構件與其他構件直接相接的情況,而且亦包括在兩構件之間介隔存在又一構件的情況。於本發明中,所謂某部分「包括」某構成要素,只要並無特別說明,則並非是指排除其他構成要素,而是指可進而包括其他構成要素。Hereinafter, the present invention will be explained in more detail. In the present invention, the so-called "above" a certain component is not only a case where a certain component is directly connected to another component, but also a case where another component is interposed between the two components. In the present invention, the so-called "including" a certain component in a certain part, unless otherwise specified, does not mean that other components are excluded, but it means that other components may be further included.
[可撓性前面板] 更具體地說明本發明的可撓性前面板。[Flexible front panel] More specifically, the flexible front panel of the present invention will be explained.
可撓性前面板為具有可撓性的前面板,「可撓性前面板」可與「柔性前面板」混用。所述可撓性前面板可於柔性透明基材的至少單面包括硬塗層而成。所述可撓性前面板並非如已有的玻璃(glass)般為剛性(rigid)或硬性(stiff),而是包括具有柔性特性的透明基材、以及所述透明基材的至少單面的硬塗層,藉此發揮如下作用:保護將該些設為構成要素的圖像顯示裝置的其他構成要素免受外部衝擊或周圍的溫濕度變化的影響。The flexible front panel is a flexible front panel, and the "flexible front panel" can be mixed with the "flexible front panel". The flexible front panel may include a hard coating on at least one side of the flexible transparent substrate. The flexible front panel is not rigid or stiff like existing glass, but includes a transparent substrate with flexible characteristics and at least one-sided transparent substrate The hard coat layer thereby plays a role of protecting the other components of the image display device, which are the components, from external impact or changes in ambient temperature and humidity.
所述可撓性前面板的硬塗層的厚度並無特別限定,例如可為2 μm至100 μm。於所述硬塗層的厚度小於2 μm時,難以確保充分的耐衝擊性,於超過100 μm時,耐彎曲性降低,有時產生因硬化收縮而產生捲曲的問題。The thickness of the hard coat layer of the flexible front panel is not particularly limited, and may be, for example, 2 μm to 100 μm. When the thickness of the hard coat layer is less than 2 μm, it is difficult to ensure sufficient impact resistance, and when it exceeds 100 μm, the bending resistance is reduced, and the problem of curling due to hardening shrinkage may occur.
所述硬塗層可藉由硬塗組成物的硬化而形成,所述硬塗組成物包含照射光或熱能而形成交聯結構的反應性材料。The hard coat layer may be formed by hardening a hard coat composition containing a reactive material that forms a cross-linked structure by irradiating light or thermal energy.
所述硬塗層可藉由硬塗組成物的硬化而形成,所述硬塗組成物同時包含光硬化型(甲基)丙烯酸酯單體或寡聚物、以及光硬化型環氧單體或寡聚物,但並不限定於此。The hard coat layer may be formed by hardening a hard coat composition, the hard coat composition containing both a photo-curing (meth)acrylate monomer or oligomer, and a photo-curing epoxy monomer or The oligomer is not limited to this.
另外,所述可撓性前面板可包含聚醯亞胺、聚醯亞胺醯胺、聚對苯二甲酸乙二酯膜材質,該情況下,雖柔軟但硬度優異而較佳,但並不限定於此。In addition, the flexible front panel may include polyimide, polyimide amide, and polyethylene terephthalate film materials. In this case, although it is soft, it has excellent hardness and is preferable, but it is not Limited to this.
所述可撓性前面板可如所述般直接製造,亦可購入市售的膜等來應用。The flexible front panel can be directly manufactured as described above, or commercially available films can also be purchased for application.
於本發明的一實施形態中,所述可撓性前面板的厚度可為5 μm至200 μm、較佳為20 μm至100 μm、更佳為30 μm至80 μm,該情況下,具有可藉由適當的厚度來維持硬度以及可確保彎曲性的優點,因此較佳。In an embodiment of the present invention, the thickness of the flexible front panel may be 5 μm to 200 μm, preferably 20 μm to 100 μm, and more preferably 30 μm to 80 μm. In this case, the thickness of the flexible front panel may be 5 μm to 200 μm. It is better to maintain the hardness and ensure the flexibility with the proper thickness.
[光學構件的端部] 本發明的光學積層體包括存在於所述可撓性前面板的下部的、至少一個以上的光學構件,此時,所述光學構件的相向端部中,所述光學構件的最後退的端部位於自所述可撓性前面板的端部起向內側的距離小於2.0 mm、較佳為1.2 mm以下、更佳為1.0 mm以下、最佳為0.03 mm以下的位置。[End of optical member] The optical laminate of the present invention includes at least one optical member existing in the lower portion of the flexible front panel. In this case, among the opposing ends of the optical member, the most retracted end of the optical member It is located at a position where the distance to the inside from the end of the flexible front panel is less than 2.0 mm, preferably 1.2 mm or less, more preferably 1.0 mm or less, and most preferably 0.03 mm or less.
於本發明中,所謂「端部」,是指可撓性前面板、光學構件的末端部,所謂「相向端部」,是指彼此相對的「兩端部」。具體而言,積層體中所包括的光學構件的位置關係取決於積層體的端部的位置。例如,於如圖2般在與積層方向正交的方向進行切斷時,若詳細地觀看所述端部,則可如圖8的(a)~圖9的(c)般進行表示。具體而言,於自經切斷的可撓性前面板的端部起將與積層方向正交的虛擬線設為基準線並以虛線進行表示時,剩餘的光學構件的端部的位置以距所述虛線的距離(以箭頭表示)離開。如此,藉由測定經切斷的可撓性前面板的端部與其他光學構件的端部的位置間的沿面方向的方向上的距離,可求出可撓性前面板的端部與光學構件的端部的距離。In the present invention, the "end portion" refers to the end portion of the flexible front panel and the optical member, and the "opposing end portion" refers to the "end portions" facing each other. Specifically, the positional relationship of the optical members included in the laminated body depends on the position of the end of the laminated body. For example, when cutting in the direction orthogonal to the stacking direction as shown in FIG. 2, if the end portion is viewed in detail, it can be shown as shown in FIGS. 8( a) to 9 (c ). Specifically, when the imaginary line orthogonal to the stacking direction is set as the reference line from the end of the cut flexible front panel and is indicated by a broken line, the position of the end of the remaining optical member is separated from The distance of the dashed line (indicated by the arrow) leaves. In this way, by measuring the distance in the direction along the plane direction between the end of the cut flexible front panel and the end of the other optical member, the end of the flexible front panel and the optical member can be determined The distance between the ends.
另外,所謂本發明的光學構件的端部位於自可撓性前面板的端部起向內側的距離小於2.0 mm的位置,結果是指於所述光學構件的端部自所述可撓性前面板的端部起在所述範圍內後退時,所述光學構件的端部與所述可撓性前面板的端部的距離最大為小於2.0 mm。In addition, the so-called end of the optical member of the present invention is located at a position where the distance inward from the end of the flexible front panel is less than 2.0 mm, and the result means that the end of the optical member is from the front of the flexible front panel. When the end of the panel retreats within the range, the distance between the end of the optical member and the end of the flexible front panel is less than 2.0 mm at most.
此時,更具體而言,所述距離是指包含所述可撓性前面板的端部的面、與包含欲測定距離的各光學構件的端部的面之間的最短的長度。 於本發明的一實施形態中,所述光學構件的最突出的端部以及最後退的端部可位於自所述可撓性前面板的端部起向外側的距離為0.2 mm以下的位置至自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。At this time, more specifically, the distance refers to the shortest length between the surface including the end of the flexible front panel and the surface including the end of each optical member whose distance is to be measured. In one embodiment of the present invention, the most protruding end and the most retracted end of the optical member may be located at a distance of 0.2 mm or less to the outside from the end of the flexible front panel. The position where the distance to the inside from the end of the flexible front panel is less than 2.0 mm.
所謂本發明的光學構件的端部位於自可撓性前面板的端部起向外側的距離為0.2 mm以下的位置,是指於所述光學構件的端部自所述可撓性前面板的端部起在所述範圍內突出時,所述光學構件的端部與所述可撓性前面板的端部的距離最大為0.2 mm。The so-called end of the optical member of the present invention is located at a distance of 0.2 mm or less from the end of the flexible front panel to the outside, which means that the end of the optical member is separated from the flexible front panel. When the end portion protrudes within the range, the distance between the end portion of the optical member and the end portion of the flexible front panel is at most 0.2 mm.
另外,於本發明中,所謂「光學構件」,是指所述光學積層體中所包括的「所有光學構件」,例如,於本發明的光學積層體包括可撓性前面板、以及其下部的包含偏光板、觸控感測器、基材此三層的光學構件時,所述偏光板、觸控感測器、基材的任一者均是:各端部的所有相向端部中,最後退的端部存在於自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。In addition, in the present invention, the "optical member" refers to "all optical members" included in the optical laminate. For example, the optical laminate in the present invention includes a flexible front panel and a lower part thereof. When a three-layer optical member including a polarizing plate, a touch sensor, and a base material is included, any one of the polarizing plate, touch sensor, and base material is: among all opposing ends of each end, The last retracted end exists at a position where the distance to the inside from the end of the flexible front panel is less than 2.0 mm.
於本發明的光學積層體包括可撓性前面板、以及其下部的包含偏光板、觸控感測器、基材此三層的光學構件時,較佳為所述偏光板、觸控感測器、基材的任一者均是:各端部的所有相向端部中,可使最後退的端部存在於自所述可撓性前面板的端部起向外側的距離為0.2 mm以下的位置至自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。 於本發明的光學積層體包括可撓性前面板、以及其下部的包含偏光板、觸控感測器、基材此三層的光學構件時,更佳為所述偏光板、觸控感測器、基材的任一者均是:各端部的所有相向端部中,可使最後退的端部存在於自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。When the optical laminate of the present invention includes a flexible front panel, and an optical member comprising three layers of a polarizing plate, a touch sensor, and a substrate under the flexible front panel, the polarizing plate and the touch sensor are preferably used. Either of the device and the base material: among all the opposing ends of each end, the last retreat can exist at a distance of 0.2 mm or less from the end of the flexible front panel to the outside From the position of the flexible front panel to a position where the distance to the inside from the end of the flexible front panel is less than 2.0 mm. When the optical laminate of the present invention includes a flexible front panel, and a lower part of the optical member including three layers of a polarizing plate, a touch sensor, and a substrate, it is more preferably the polarizing plate, touch sensor Any one of the device and the base material is: among all the opposite ends of each end, the end that can be retreated last exists in the distance from the end of the flexible front panel to the inner side of less than 2.0 mm position.
構成所述光學構件的面的所有相向端部中,最突出的端部以及最後退的端部亦可位於自所述可撓性前面板起向外側的距離為0.2 mm以下、較佳為0.15 mm以下、更佳為0.02 mm以下的位置至自所述可撓性前面板起向內側的距離小於2.0 mm、1.2 mm以下、較佳為1.0 mm以下、更佳為0.03 mm以下的位置,但並不限定於此。其中,較佳為相對於彎曲方向而平行的所有相向端部均滿足所述條件。Among all the opposing ends of the surface constituting the optical member, the most protruding end and the last retracted end may also be located at a distance of 0.2 mm or less to the outside from the flexible front panel, preferably 0.15 mm or less, more preferably 0.02 mm or less, to a position where the distance to the inside from the flexible front panel is less than 2.0 mm, 1.2 mm or less, preferably 1.0 mm or less, more preferably 0.03 mm or less, but It is not limited to this. Among them, it is preferable that all facing ends that are parallel to the bending direction satisfy the above-mentioned condition.
本發明的光學積層體由於所述光學構件的端部位於自所述可撓性前面板的端部起的所述範圍內,因此具有可減少非顯示區域、且可擴大畫面比的優點。In the optical laminate of the present invention, since the end of the optical member is located within the range from the end of the flexible front panel, it has the advantages of reducing the non-display area and expanding the screen ratio.
另外,於彎曲評價時,可抑制端部產生裂紋的現象,具有彎曲性優異的優點。In addition, in the bending evaluation, the phenomenon of cracks at the end can be suppressed, which has the advantage of excellent bendability.
即,本發明的光學積層體可具有以所述可撓性前面板的端部為基準而小於2.0 mm的凹陷部。另外,本發明的光學積層體可具有以所述可撓性前面板的端部為基準而為0.2 mm以下的突出部。That is, the optical laminate of the present invention may have a recessed portion less than 2.0 mm based on the end of the flexible front panel. In addition, the optical laminate of the present invention may have a protruding part of 0.2 mm or less based on the end of the flexible front panel.
本發明的光學積層體可進而包括透明基材,此時,所述透明基材的端部位於自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。另外,所述透明基材的端部可位於自所述可撓性前面板的端部起向外側的距離為0.2 mm以下的位置至自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。The optical layered body of the present invention may further include a transparent substrate. In this case, the end of the transparent substrate is located at a position where the distance inward from the end of the flexible front panel is less than 2.0 mm. In addition, the end of the transparent base material may be located at a distance of 0.2 mm or less from the end of the flexible front panel to the outside to a position at the inside from the end of the flexible front panel. Locations where the distance is less than 2.0 mm.
於所述透明基材為兩個以上時,所述透明基材的最後退的端部位於自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。所述透明基材可為柔性透明基材,可應用後述的內容。When there are two or more transparent substrates, the most retracted end of the transparent substrate is located at a position where the distance to the inside from the end of the flexible front panel is less than 2.0 mm. The transparent substrate may be a flexible transparent substrate, and the content described later may be applied.
所述透明基材亦可包括於後述的各光學構件中,亦可包括於與所述光學構件不同的光學積層體中。The transparent substrate may be included in each optical member described later, or may be included in an optical laminate different from the optical member.
更佳為於所述透明基材為兩個以上時,所述透明基材的最突出的端部以及最後退的端部可位於自所述可撓性前面板的端部起向外側的距離為0.2 mm以下的位置至自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。More preferably, when there are two or more transparent substrates, the most protruding end and the last retracted end of the transparent substrate may be located at a distance from the end of the flexible front panel to the outside From a position below 0.2 mm to a position where the distance to the inside from the end of the flexible front panel is less than 2.0 mm.
[透明基材] 透明基材可指可見光線的透過率為70%以上或80%以上的基材。所述透明基材若為具有透明性的高分子膜,則均可使用。具體而言,可為由如下高分子形成的膜:具有如降冰片烯或多環降冰片烯系單量體般的包含環烯烴的單量體的單元的環烯烴系衍生物、纖維素(二乙醯基纖維素、三乙醯基纖維素、乙醯基纖維素丁酸酯、異丁基酯纖維素、丙醯基纖維素、丁醯基纖維素、乙醯基丙醯基纖維素)乙烯-乙酸乙烯基酯共聚物、聚環烯烴、聚酯、聚苯乙烯、聚醯胺、聚醚醯亞胺、聚丙烯酸、聚醯亞胺、聚醯胺醯亞胺、聚醚碸、聚碸、聚乙烯、聚丙烯、聚甲基戊烯、聚氯乙烯、聚偏二氯乙烯、聚乙烯基醇、聚乙烯縮醛、聚醚酮、聚醚醚酮、聚甲基丙烯酸甲酯、聚對苯二甲酸乙二酯、聚對苯二甲酸丁二酯、聚萘二甲酸乙二酯、聚碳酸酯、聚胺基甲酸酯、環氧等,可使用未延伸膜、單軸延伸膜或雙軸延伸膜。[Transparent substrate] The transparent substrate may refer to a substrate with a visible light transmittance of 70% or more or 80% or more. If the transparent substrate is a polymer film with transparency, it can be used. Specifically, it may be a film formed from a polymer such as a cycloolefin derivative, cellulose ( Diacetyl cellulose, triacetyl cellulose, acetyl cellulose butyrate, isobutyl cellulose, propionyl cellulose, butyryl cellulose, acetyl propyl cellulose) ethylene -Vinyl acetate copolymer, polycyclic olefin, polyester, polystyrene, polyamide, polyetherimide, polyacrylic acid, polyimide, polyimide imine, polyether ether, polyetherimide , Polyethylene, polypropylene, polymethylpentene, polyvinyl chloride, polyvinylidene chloride, polyvinyl alcohol, polyvinyl acetal, polyether ketone, polyether ether ketone, polymethyl methacrylate, poly Ethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polycarbonate, polyurethane, epoxy, etc., unstretched film, uniaxially stretched film can be used Or biaxially stretched film.
該些高分子可分別單獨使用,或將兩種以上混合使用。於所述記載的透明基材中,較佳為可使用透明性以及耐熱性優異的聚醯胺膜、聚醯胺醯亞胺膜或聚醯亞胺膜、聚酯系膜、烯烴系膜、丙烯酸膜、纖維素系膜。於高分子膜中,分散有二氧化矽等無機粒子、有機微粒子、橡膠粒子等的膜亦較佳。進而,亦可含有如顏料或染料般的著色劑、螢光增白劑、分散劑、塑化劑、熱穩定劑、光穩定劑、紅外線吸收劑、紫外線吸收劑、抗靜電劑、抗氧化劑、潤滑劑等調配劑。所述基材的厚度可為5 μm至200 μm、較佳為20 μm至100 μm。These polymers can be used individually or in combination of two or more. Among the transparent substrates described above, it is preferable to use a polyamide film, a polyimide film or a polyimide film, a polyester film, an olefin film, which are excellent in transparency and heat resistance, Acrylic film, cellulose film. In the polymer film, a film in which inorganic particles such as silicon dioxide, organic fine particles, rubber particles, etc. are dispersed is also preferable. Furthermore, it may also contain coloring agents such as pigments or dyes, fluorescent whitening agents, dispersants, plasticizers, heat stabilizers, light stabilizers, infrared absorbers, ultraviolet absorbers, antistatic agents, antioxidants, Blending agents such as lubricants. The thickness of the substrate may be 5 μm to 200 μm, preferably 20 μm to 100 μm.
[非顯示區域] 於本發明的又一實施形態中,所述光學積層體包括定義為所述光學積層體的周邊的非顯示區域,所述非顯示區域的寬度可為15 mm以下、較佳為10 mm以下、更佳為6 mm以下。所述非顯示區域的寬度通常為0.5 mm以上。[Non-display area] In another embodiment of the present invention, the optical laminate includes a non-display area defined as the periphery of the optical laminate, and the width of the non-display area may be 15 mm or less, preferably 10 mm or less, More preferably, it is 6 mm or less. The width of the non-display area is usually 0.5 mm or more.
於本發明中,所述「非顯示區域」是指由顯示裝置主體的邊框部覆蓋的部分(圖3),是指視認不到圖像的區域。另外,所述「非顯示區域」可與「遮蔽區域」混用。In the present invention, the “non-display area” refers to a portion covered by the frame portion of the display device main body (FIG. 3 ), and refers to an area where no image can be seen. In addition, the "non-display area" can be mixed with the "masked area".
本發明的光學積層體於最外輪廓部包括所述可撓性前面板,此時,位於所述可撓性前面板的下部的各種光學構件、基材等中,最後退的光學構件的端部位於自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。The optical laminate of the present invention includes the flexible front panel in the outermost contour portion. In this case, among the various optical members, base materials, etc. located at the lower portion of the flexible front panel, the end of the optical member that is retracted last The part is located at a position where the distance to the inside from the end of the flexible front panel is less than 2.0 mm.
更佳為位於所述可撓性前面板的下部的各種光學構件、基材等中,最突出的端部以及最後退的光學構件的端部可位於自所述可撓性前面板的端部起向外側的距離為0.2 mm以下的位置至自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置。More preferably, among the various optical members, substrates, etc. located at the lower portion of the flexible front panel, the most protruding end and the end of the last retracted optical member may be located from the end of the flexible front panel The position where the distance from the outside is 0.2 mm or less to the position where the distance from the end of the flexible front panel to the inside is less than 2.0 mm.
通常,顯示區域的外輪廓是由非顯示區域包圍。於非顯示區域廣時,畫面比有時會減小,但本發明的光學積層體中,非顯示區域的寬度與先前相比變窄,於相向的兩邊中減少至小於2.0 mm,且不需要的遮蔽區域縮小,藉此具有改善縱橫比(aspect ratio)的優點。Usually, the outer contour of the display area is surrounded by the non-display area. When the non-display area is wide, the screen ratio sometimes decreases. However, in the optical laminate of the present invention, the width of the non-display area is narrower than before, and it is reduced to less than 2.0 mm on the opposite sides, and there is no need The masked area of the SR is reduced, which has the advantage of improving the aspect ratio.
於本發明中,所謂「縱橫比」,是指「顯示區域/(顯示區域+非顯示區域)」,所謂「畫面比」,是指顯示區域的橫與縱的比例。即,顯示區域越大,縱橫比越大,非顯示區域越小,縱橫比越大。In the present invention, the "aspect ratio" refers to the "display area/(display area + non-display area)", and the "screen ratio" refers to the ratio between the horizontal and vertical of the display area. That is, the larger the display area, the larger the aspect ratio, and the smaller the non-display area, the larger the aspect ratio.
另外,本發明的光學積層體於彎曲評價時可抑制端部產生裂紋的現象,具有彎曲耐久性優異的優點。In addition, the optical layered body of the present invention can suppress the occurrence of cracks at the ends during bending evaluation, and has an advantage of excellent bending durability.
[光學構件] 本發明的光學積層體包括所述可撓性前面板以及存在於所述可撓性前面板的下部的至少一個以上的光學構件。[Optical components] The optical laminate of the present invention includes the flexible front panel and at least one or more optical members present in the lower portion of the flexible front panel.
所述光學構件位於顯示面板的上部,可為偏光板、觸控感測器,並且可分別提供顯示面板的保護、視認性提高、使用者輸入功能等。 具體而言,所述光學構件可包括選自由偏光板以及觸控感測器所組成的群組中的一個以上。The optical member is located on the upper part of the display panel, and can be a polarizer or a touch sensor, and can provide protection of the display panel, improved visibility, user input functions, etc., respectively. Specifically, the optical member may include more than one selected from the group consisting of a polarizer and a touch sensor.
所述光學構件可為根據要求功能而包括至少一個以上的所述偏光板、觸控感測器的積層體,作為其積層順序的例子,可自視認側起按照可撓性前面板、偏光板、觸控感測器、或可撓性前面板、觸控感測器、偏光板的順序進行積層。此時,若偏光板存在於觸控感測器的視認側,則難以視認到觸控感測器的圖案,可改善顯示映像的視認性,因此更佳。於由所述積層體構成時,各構件可使用接著劑層等進行積層。另外,可出於遮蔽的目的,而於所述可撓性前面板、偏光板、觸控感測器中的一個層的至少單面形成遮光圖案,以便視認不到顯示面板的配線等。The optical member may be a laminate including at least one of the polarizing plate and the touch sensor according to the required function. As an example of the order of the laminate, the flexible front panel and the polarizing plate may be arranged from the visible side. , Touch sensor, or flexible front panel, touch sensor, and polarizer in the order of stacking. At this time, if the polarizing plate is on the visibility side of the touch sensor, it is difficult to see the pattern of the touch sensor, and the visibility of the displayed image can be improved, so it is better. When it is comprised by the said laminated body, each member can be laminated|stacked using an adhesive layer etc.. In addition, for the purpose of shielding, a light shielding pattern may be formed on at least one side of one layer of the flexible front panel, the polarizing plate, and the touch sensor, so that the wiring of the display panel and the like are not visible.
[偏光板] 偏光板可為單獨的偏光層、或包括偏光層以及其至少單面所附著的透明基材的結構,且根據穿過所述偏光板而出射的光的偏光狀態,被區分為直線偏光板、圓偏光板等。以下,於本說明中,並無特別限定,對吸收反射光而提高視認性時可使用的圓偏光板進行具體描述。[Polarizer] The polarizing plate may be a single polarizing layer or a structure including a polarizing layer and a transparent substrate attached to at least one side thereof, and is divided into linear polarizing plates according to the polarization state of the light emitted through the polarizing plate, Circular polarizer, etc. Hereinafter, in this description, there is no particular limitation, and a circular polarizing plate that can be used when absorbing reflected light to improve visibility will be specifically described.
圓偏光板為於直線偏光板積層λ/4相位差板而具有僅使右側或左側的圓偏光成分透過的功能的功能層。例如,可出於如下目的來使用:將外部光轉換為右側圓偏光,遮斷由有機電致發光(electroluminescence,EL)面板反射而成為左側圓偏光的外部光,從而僅使有機EL的發光成分透過,藉此抑制反射光的影響而容易看到影像。為了達成圓偏光的功能,直線偏光板的吸收軸與λ/4相位差板的延遲相位軸理論上必須為45°,但於實用時為45°±10°。直線偏光板與λ/4相位差板未必需要鄰接地積層,只要吸收軸與延遲相位軸的關係滿足所述範圍即可。較佳為於全波長中達成完全圓偏光,但於實用上未必需要如此,因此本發明的圓偏光板亦可包括橢圓偏光板。亦較佳為進一步靠近直線偏光板的視認側地積層λ/4相位差膜而將出射光設為圓偏光,藉此提高佩戴有偏光太陽鏡的狀態下的視認性。The circular polarizing plate is a functional layer having a function of laminating a λ/4 phase difference plate on a linear polarizing plate to transmit only the circularly polarized light component on the right side or the left side. For example, it can be used for the following purposes: to convert external light into right circularly polarized light, block the external light reflected by the organic electroluminescence (EL) panel and become the left circularly polarized light, so that only the light-emitting components of organic EL Through this, the influence of reflected light is suppressed and the image can be easily seen. In order to achieve the function of circular polarization, the absorption axis of the linear polarizer and the retardation phase axis of the λ/4 retardation plate must theoretically be 45°, but in practice they are 45°±10°. The linear polarizing plate and the λ/4 retardation plate do not necessarily need to be laminated adjacently, as long as the relationship between the absorption axis and the retardation phase axis satisfies the above-mentioned range. It is preferable to achieve complete circular polarization in the full wavelength, but this is not necessarily required in practice. Therefore, the circular polarization plate of the present invention may also include an elliptical polarization plate. It is also preferable to laminate a λ/4 retardation film closer to the visibility side of the linear polarizing plate to make the emitted light circularly polarized, thereby improving the visibility in the state of wearing polarized sunglasses.
直線偏光板為具有如下功能的功能層:使在透過軸方向上振動的光通過,但遮斷與其垂直的振動成分的偏光。所述直線偏光板可為單獨的直線偏光層、或包括線形偏光層以及其至少單面所附著的保護膜的結構。作為保護膜,可使用作為所述透明基材而列舉者。所述直線偏光板的厚度可為200 μm以下,較佳為可為0.5 μm至100 μm。若厚度超過200 μm,則柔軟性有時會降低。The linear polarizer is a functional layer that has a function of passing light that vibrates in the direction of the transmission axis, but blocking the polarization of the vibration component perpendicular to it. The linear polarizing plate may be a single linear polarizing layer, or a structure including a linear polarizing layer and a protective film attached to at least one side of the linear polarizing layer. As the protective film, those exemplified as the transparent substrate can be used. The thickness of the linear polarizer may be 200 μm or less, preferably 0.5 μm to 100 μm. If the thickness exceeds 200 μm, flexibility may decrease.
所述直線偏光層可為將聚乙烯基醇(Polyvinyl Alcohol,PVA)系膜染色、延伸而製造的膜型偏光層。藉由使碘等二色性染料吸附於藉由延伸而配向的PVA系膜或者於吸附於PVA系膜的狀態下進行延伸,二色性色素配向而發揮偏光性能。於所述膜型偏光層的製造中,亦可包括此外的膨潤、基於硼酸的交聯、基於水溶液的清洗、乾燥等步驟。延伸與染色的步驟可對PVA系膜單獨進行,亦可於與如聚對苯二甲酸乙二酯般的其他膜積層的狀態下進行。作為所使用的PVA系膜,厚度較佳為10 μm至100 μm,延伸倍率較佳為2倍至10倍。The linear polarizing layer may be a film-type polarizing layer manufactured by dyeing and stretching a polyvinyl alcohol (PVA) film. By adsorbing a dichroic dye such as iodine to the PVA-based film aligned by stretching or stretching while being adsorbed on the PVA-based film, the dichroic dye is aligned to exhibit polarization performance. In the production of the film-type polarizing layer, other steps such as swelling, cross-linking based on boric acid, washing based on aqueous solution, and drying may also be included. The steps of stretching and dyeing may be performed on the PVA-based film alone, or may be performed in the state of being laminated with other films such as polyethylene terephthalate. As the PVA-based film used, the thickness is preferably 10 μm to 100 μm, and the stretching ratio is preferably 2 times to 10 times.
另外,作為所述偏光層的其他例,亦可為塗佈液晶偏光組成物而形成的液晶塗佈型偏光層。所述液晶偏光組成物可包含液晶性化合物以及二色性色素化合物。作為所述液晶性化合物,只要具有顯示出液晶狀態的性質即可,尤其是具有如層列相等般高次配向狀態的化合物可發揮高偏光性能,因此較佳。另外,亦較佳為具有聚合性官能基。所述二色性色素化合物為與所述液晶化合物一起配向而顯示出二色性的色素,二色性色素自身可具有液晶性,可具有聚合性官能基。液晶偏光組成物中的一種化合物具有聚合性官能基,所述液晶偏光組成物可進而包含起始劑、溶媒、分散劑、調平劑、穩定劑、界面活性劑、交聯劑、矽烷偶合劑等。所述液晶塗佈型偏光層可藉由在配向膜塗佈液晶偏光組成物而形成液晶偏光層來製造。液晶塗佈型偏光層與膜型偏光層相比,可將厚度形成得薄。所述液晶塗佈型偏光層的厚度可為0.5 μm至10 μm、較佳為1 μm至5 μm。In addition, as another example of the above-mentioned polarizing layer, a liquid crystal coating type polarizing layer formed by applying a liquid crystal polarizing composition may also be used. The liquid crystal polarizing composition may include a liquid crystal compound and a dichroic dye compound. As the liquid crystal compound, it is sufficient as long as it has the property of exhibiting a liquid crystal state. In particular, a compound having a high-order alignment state such as a smectic order can exhibit high polarization performance, and therefore is preferable. In addition, it is also preferable to have a polymerizable functional group. The dichroic dye compound is a dye that is aligned with the liquid crystal compound to exhibit dichroism, and the dichroic dye itself may have liquid crystallinity and may have a polymerizable functional group. A compound in the liquid crystal polarizing composition has a polymerizable functional group, and the liquid crystal polarizing composition may further include an initiator, a solvent, a dispersant, a leveling agent, a stabilizer, a surfactant, a crosslinking agent, and a silane coupling agent Wait. The liquid crystal coating type polarizing layer can be manufactured by coating a liquid crystal polarizing composition on an alignment film to form a liquid crystal polarizing layer. The liquid crystal coating type polarizing layer can be made thinner than the film type polarizing layer. The thickness of the liquid crystal coating type polarizing layer may be 0.5 μm to 10 μm, preferably 1 μm to 5 μm.
所述配向膜例如可藉由在基材上塗佈配向膜形成組成物並利用摩擦、偏光照射等賦予配向性來製造。所述配向膜形成組成物包含配向劑,此外亦可包含溶劑、交聯劑、起始劑、分散劑、調平劑、矽烷偶合劑等。作為所述配向劑,例如可使用聚乙烯基醇、聚丙烯酸酯類、聚醯胺酸類、聚醯亞胺類。於應用光配向時,較佳為使用包含肉桂酸酯基的配向劑。作為所述配向劑而使用的高分子的重量平均分子量可為10,000至1,000,000左右。所述配向膜的厚度較佳為5 nm至10,000 nm,尤其是若為10 nm至500 nm,則充分顯現出配向限制力,因此較佳。所述液晶偏光層可自基材剝離、轉印後積層,亦可直接積層所述基材。所述基材亦較佳為作為保護膜或相位差板、可撓性前面板的透明基材發揮作用。The alignment film can be produced by, for example, coating an alignment film forming composition on a substrate and imparting alignment properties by rubbing, polarized light irradiation, or the like. The alignment film forming composition includes an alignment agent, and may also include a solvent, a crosslinking agent, an initiator, a dispersant, a leveling agent, a silane coupling agent, and the like. As the alignment agent, for example, polyvinyl alcohol, polyacrylates, polyamides, and polyimines can be used. When applying optical alignment, it is preferable to use an alignment agent containing a cinnamate group. The weight average molecular weight of the polymer used as the alignment agent may be about 10,000 to 1,000,000. The thickness of the alignment film is preferably 5 nm to 10,000 nm, especially if it is 10 nm to 500 nm, the alignment restriction force is fully exhibited, so it is preferable. The liquid crystal polarizing layer can be peeled from the substrate and laminated after transfer, or the substrate can be laminated directly. The substrate also preferably functions as a transparent substrate for a protective film, a retardation plate, or a flexible front panel.
所述保護膜只要為透明高分子膜即可,可使用所述透明基材中所使用的材料、添加劑。所述透明基材可應用所述內容。 所述λ/4相位差板為於與入射光的行進方向正交的方向(膜的面內方向)上提供λ/4的相位差的膜。所述λ/4相位差板可為將纖維素系膜、烯烴系膜、聚碳酸酯系膜等高分子膜延伸而製造的延伸型相位差板。視需要可包含相位差調整劑、塑化劑、紫外線吸收劑、紅外線吸收劑、如顏料以及染料般的著色劑、螢光增白劑、分散劑、熱穩定劑、光穩定劑、抗靜電劑、抗氧化劑、潤滑劑、溶劑等。所述延伸型相位差板的厚度可為200 μm以下、較佳為1 μm至100 μm。若厚度超過200 μm,則柔軟性有時會降低。The protective film may be a transparent polymer film, and materials and additives used for the transparent substrate can be used. The content can be applied to the transparent substrate. The λ/4 retardation plate is a film that provides a λ/4 retardation in a direction (in-plane direction of the film) orthogonal to the traveling direction of incident light. The λ/4 retardation plate may be a stretched retardation plate manufactured by stretching a polymer film such as a cellulose-based film, an olefin-based film, or a polycarbonate-based film. If necessary, it may contain retardation adjusters, plasticizers, ultraviolet absorbers, infrared absorbers, coloring agents such as pigments and dyes, fluorescent whitening agents, dispersants, heat stabilizers, light stabilizers, and antistatic agents , Antioxidants, lubricants, solvents, etc. The thickness of the extended phase difference plate may be 200 μm or less, preferably 1 μm to 100 μm. If the thickness exceeds 200 μm, flexibility may decrease.
另外,作為所述λ/4相位差板的其他例,亦可為塗佈液晶組成物而形成的液晶塗佈型相位差板。所述液晶組成物包含液晶性化合物,所述液晶性化合物具有顯示出向列型、膽固醇型、層列型等液晶狀態的性質。包含液晶組成物中的液晶性化合物的一種化合物具有聚合性官能基。另外,所述液晶塗佈型相位差板可進而包含起始劑、溶媒、分散劑、調平劑、穩定劑、界面活性劑、交聯劑、矽烷偶合劑等。所述液晶塗佈型相位差板可與所述液晶偏光層中的記載同樣地藉由在配向膜塗佈液晶組成物並進行硬化而形成液晶相位差層來製造。液晶塗佈型相位差板與延伸型相位差板相比,可將厚度形成得薄。所述液晶相位差層的厚度可為0.5 μm至10 μm、較佳為1 μm至5 μm。所述液晶塗佈型相位差板可自基材剝離、轉印後積層,亦可直接積層所述基材。所述基材亦較佳為作為保護膜或相位差板、可撓性前面板的透明基材發揮作用。In addition, as another example of the λ/4 retardation plate, a liquid crystal coating type retardation plate formed by coating a liquid crystal composition may also be used. The liquid crystal composition includes a liquid crystal compound having the property of showing a liquid crystal state such as a nematic type, a cholesteric type, and a smectic type. One compound including the liquid crystal compound in the liquid crystal composition has a polymerizable functional group. In addition, the liquid crystal coating type retardation plate may further include a starter, a solvent, a dispersant, a leveling agent, a stabilizer, a surfactant, a crosslinking agent, a silane coupling agent, and the like. The liquid crystal coating type retardation plate can be manufactured by forming a liquid crystal retardation layer by applying a liquid crystal composition to an alignment film and curing the same as described in the liquid crystal polarizing layer. The liquid crystal coating type retardation plate can be made thinner than the extension type retardation plate. The thickness of the liquid crystal retardation layer may be 0.5 μm to 10 μm, preferably 1 μm to 5 μm. The liquid crystal coating type retardation plate can be peeled from the substrate and laminated after transfer, or the substrate can be laminated directly. The substrate also preferably functions as a transparent substrate for a protective film, a retardation plate, or a flexible front panel.
通常,越為短波長雙折射越大、越為長波長越顯示出小的雙折射的材料多。該情況下,由於無法在整個可見光區域達成λ/4的相位差,因此大多情況為以面內相位差為100 nm至180 nm、較佳為130 nm至150 nm的方式進行設計,以便相對於視感度高的560 nm附近的波長而為λ/4。與通常情況相反,使用逆分散λ/4相位差板可進一步提高視認性,因此較佳,所述逆分散λ/4相位差板使用有具有相反的雙折射率的波長分散特性的材料。作為此種材料,於為延伸型相位差板時,亦較佳為使用日本公開專利第2007-232873號公報等中所記載的材料,於為液晶塗佈型相位差板時,亦較佳為使用日本公開專利第2010-30979號公報中所記載的材料。Generally, the shorter the wavelength, the greater the birefringence, and the longer the wavelength, the greater the birefringence. In this case, since the phase difference of λ/4 cannot be achieved in the entire visible light region, in most cases, the in-plane phase difference is designed to be 100 nm to 180 nm, preferably 130 nm to 150 nm, in order to compare The wavelength near 560 nm, which has a high visual sensitivity, is λ/4. Contrary to the usual situation, the use of the reverse dispersion λ/4 retardation plate can further improve the visibility. Therefore, it is preferable that the reverse dispersion λ/4 retardation plate uses a material with opposite birefringence and wavelength dispersion characteristics. As such a material, when it is an extension type retardation plate, it is also preferable to use the material described in Japanese Laid-Open Patent No. 2007-232873, etc., and when it is a liquid crystal coating type retardation plate, it is also preferably The materials described in Japanese Laid-open Patent No. 2010-30979 were used.
另外,作為其他方法,亦已知有與λ/2相位差板結合而獲得寬頻帶λ/4相位差板的技術(日本公開專利特開平10-90521號公報)。λ/2相位差板亦可利用與λ/4相位差板相同的材料、方法來製造。延伸型相位差板與液晶塗佈型相位差板的組合是任意的,就可使厚度薄的方面而言,較佳為均使用液晶塗佈型相位差板。In addition, as another method, a technique of combining with a λ/2 phase difference plate to obtain a wide-band λ/4 phase difference plate is also known (Japanese Laid-Open Patent Publication No. 10-90521). The λ/2 retardation plate can also be manufactured using the same material and method as the λ/4 retardation plate. The combination of the extension type retardation plate and the liquid crystal coating type retardation plate is arbitrary, and it is preferable to use both of the liquid crystal coating type retardation plates in terms of making the thickness thin.
關於所述圓偏光板,為了提高傾斜方向上的視認性,亦已知有積層正C板的方法(日本公開專利第2014-224837號公報)。正C板可為液晶塗佈型相位差板,亦可為延伸型相位差板。厚度方向上的相位差可為-200 nm至-20 nm、較佳為-140 nm至-40 nm。Regarding the circularly polarizing plate, in order to improve the visibility in the oblique direction, a method of laminating positive C plates is also known (Japanese Laid-open Patent No. 2014-224837). The positive C plate can be a liquid crystal coating type retardation plate or an extended type retardation plate. The phase difference in the thickness direction may be -200 nm to -20 nm, preferably -140 nm to -40 nm.
[觸控感測器] 觸控感測器作為輸入部件而使用。作為觸控感測器,提出有電阻膜方式、表面彈性波方式、紅外線方式、電磁感應方式、靜電電容方式等各種形態,可為任意方式,特佳為靜電電容方式。靜電電容方式觸控感測器中,被區分為活性區域以及位於所述活性區域的外輪廓地帶的非活性區域。活性區域為與顯示面板中顯示畫面的區域(顯示部)對應的區域,為感知使用者的觸控的區域,非活性區域為與顯示裝置中不顯示畫面的區域(非顯示部)對應的區域。觸控感測器可包括:基板,具有柔軟特性;感知圖案,形成於所述基板的活性區域;以及各感測線,形成於所述基板的非活性區域且用於經由所述感知圖案以及墊部而與外部的驅動電路連結。作為具有柔軟特性的基板,可使用與所述可撓性前面板的透明基材相同的材料。另一方面,韌性(toughness)是根據藉由高分子材料的拉伸實驗而獲得的應力(MPa)-變形度(%)曲線(Stress-strain curve)而由破壞點之前的曲線的下部面積定義,就抑制觸控感測器的裂縫的方面而言,觸控感測器基板較佳為具有2,000 MPa%以上的韌性。更佳為韌性可為2,000 MPa%至30,000 MPa%。[Touch Sensor] The touch sensor is used as an input component. As a touch sensor, various forms such as a resistive film method, a surface elastic wave method, an infrared method, an electromagnetic induction method, and an electrostatic capacitance method have been proposed. Any method may be used, and an electrostatic capacitance method is particularly preferred. In the capacitive touch sensor, it is divided into an active area and an inactive area located in the outer contour zone of the active area. The active area is the area corresponding to the area (display part) where the screen is displayed on the display panel, and is the area that perceives the user's touch, and the inactive area is the area corresponding to the area where the screen is not displayed (non-display part) in the display device . The touch sensor may include: a substrate with soft characteristics; a sensing pattern formed on the active area of the substrate; and each sensing line formed on the inactive area of the substrate and used to pass through the sensing pattern and the pad Part and connected with an external drive circuit. As the substrate with flexible properties, the same material as the transparent base material of the flexible front panel can be used. On the other hand, toughness is defined by the area of the lower part of the curve before the failure point based on the stress-strain curve obtained by the tensile test of polymer materials. In terms of suppressing cracks in the touch sensor, the touch sensor substrate preferably has a toughness of 2,000 MPa% or more. More preferably, the toughness may be 2,000 MPa% to 30,000 MPa%.
所述感知圖案可包括形成於第一方向上的第一圖案以及形成於第二方向上的第二圖案。第一圖案以及第二圖案配置於彼此不同的方向上。為了第一圖案以及第二圖案感知形成於同一層的經觸控的地點,而必須將各圖案電性連結。第一圖案為各單位圖案藉由擬合而彼此連結的形態,但第二圖案為各單位圖案彼此分離為島形態的結構,因此,為了將第二圖案電性連結,需要另外的橋電極。所述感知圖案可應用眾所周知的透明電極原材料。例如,可列舉:銦錫氧化物(Indium Tin Oxide,ITO)、銦鋅氧化物(Indium Zinc Oxide,IZO)、鋅氧化物(ZnO)、銦鋅錫氧化物(Indium Zinc Tin Oxide,IZTO)、鎘錫氧化物(Cadmium Tin Oxide,CTO)、PEDOT(聚(3,4-伸乙基二氧基噻吩)(poly(3,4-ethylenedioxythiophene)))、碳奈米管(Carbon Nanotube,CNT)、石墨烯、金屬線等,該些可單獨使用,或者將兩種以上混合使用。較佳為可使用ITO。金屬線中所使用的金屬並無特別限定,例如可列舉:銀、金、鋁、銅、鐵、鎳、鈦、碲、鉻等。該些可單獨使用,或者將兩種以上混合使用。The sensing pattern may include a first pattern formed in a first direction and a second pattern formed in a second direction. The first pattern and the second pattern are arranged in different directions. In order for the first pattern and the second pattern to sense the touched location formed on the same layer, the patterns must be electrically connected. The first pattern is a form in which the unit patterns are connected to each other by fitting, but the second pattern is a structure in which the unit patterns are separated from each other into an island form. Therefore, in order to electrically connect the second patterns, another bridge electrode is required. The sensing pattern can use well-known transparent electrode raw materials. For example, indium tin oxide (Indium Tin Oxide, ITO), indium zinc oxide (Indium Zinc Oxide, IZO), zinc oxide (ZnO), indium zinc tin oxide (Indium Zinc Tin Oxide, IZTO), Cadmium Tin Oxide (CTO), PEDOT (poly(3,4-ethylenedioxythiophene)), Carbon Nanotube (CNT) , Graphene, metal wire, etc., these can be used alone or in a mixture of two or more. Preferably, ITO can be used. The metal used in the metal wire is not particularly limited, and examples thereof include silver, gold, aluminum, copper, iron, nickel, titanium, tellurium, and chromium. These can be used alone or in combination of two or more.
橋電極可於感知圖案的上部介隔絕緣層而形成於所述絕緣層的上部,亦可於基板上形成橋電極,並於其上形成絕緣層以及感知圖案。所述橋電極亦可由與感知圖案相同的原材料形成,亦可由鉬、銀、鋁、銅、鈀、金、鉑、鋅、錫、鈦、或該些中的兩種以上的合金等金屬形成。由於第一圖案以及第二圖案必須電性絕緣,因此於感知圖案以及橋電極之間形成絕緣層。絕緣層亦可僅形成於第一圖案的擬合與橋電極之間,亦可以覆蓋感知圖案的層的結構形成。於後者的情況下,橋電極可經由形成於絕緣層的接觸孔來連結第二圖案。作為用於適當地補償形成有所述感知圖案的圖案區域與未形成圖案的非圖案區域之間的透過率的差、尤其是因該部分的折射率的差而誘發的光透過率的差的手段,可於基板與電極之間進而包括光學調節層,所述光學調節層可於基板上塗佈包含光硬化性有機黏合劑的光硬化組成物來形成。所述光硬化性組成物可進而包含無機粒子。藉由所述無機粒子,可增加光學調節層的折射率。The bridge electrode can be formed on the upper part of the insulating layer by insulating the edge layer on the upper part of the sensing pattern, or the bridge electrode can be formed on the substrate, and the insulating layer and the sensing pattern can be formed thereon. The bridge electrode may also be formed of the same material as the sensing pattern, or may be formed of metals such as molybdenum, silver, aluminum, copper, palladium, gold, platinum, zinc, tin, titanium, or an alloy of two or more of these. Since the first pattern and the second pattern must be electrically insulated, an insulating layer is formed between the sensing pattern and the bridge electrode. The insulating layer can also be formed only between the fitting of the first pattern and the bridge electrode, or it can be formed with a structure covering the sensing pattern. In the latter case, the bridge electrode may be connected to the second pattern via a contact hole formed in the insulating layer. As a means for appropriately compensating for the difference in transmittance between the patterned area where the sensing pattern is formed and the non-patterned area where no pattern is formed, especially the difference in light transmittance induced by the difference in the refractive index of this part The method may further include an optical adjustment layer between the substrate and the electrode, and the optical adjustment layer may be formed by coating a photocuring composition containing a photocuring organic adhesive on the substrate. The photocurable composition may further include inorganic particles. With the inorganic particles, the refractive index of the optical adjustment layer can be increased.
所述光硬化性有機黏合劑例如可包含丙烯酸酯系單量體、苯乙烯系單量體、羧酸系單量體等各單量體的共聚物。所述光硬化性有機黏合劑例如可為包含含有環氧基的重複單元、丙烯酸酯重複單元、羧酸重複單元等彼此不同的各重複單元的共聚物。The photocurable organic binder may include, for example, copolymers of monomers such as acrylic monomers, styrene monomers, and carboxylic acid monomers. The photocurable organic binder may be, for example, a copolymer containing repeating units that are different from each other, such as an epoxy group-containing repeating unit, an acrylate repeating unit, a carboxylic acid repeating unit, and the like.
所述無機粒子例如可包含氧化鋯粒子、二氧化鈦粒子、氧化鋁粒子等。所述光硬化組成物亦可進而包含光聚合起始劑、聚合性單量體、硬化輔助劑等各添加劑。The inorganic particles may include zirconia particles, titania particles, alumina particles, and the like, for example. The photocurable composition may further include various additives such as a photopolymerization initiator, a polymerizable monomer, and a curing auxiliary agent.
[接著劑層] 於構成作為所述光學構件的各層(可撓性前面板、圓偏光板、觸控感測器)以及構成各層的膜構件(直線偏光板、λ/4相位差板等)、或光學構件的積層體時,可使用接著劑。作為接著劑,可使用水系接著劑、有機溶劑系接著劑、無溶劑接著劑、固體接著劑、水系溶劑揮發型接著劑、濕氣硬化型接著劑、熱硬化型接著劑、厭氧硬化型接著劑、活性能量線硬化型接著劑、硬化劑混合接著劑、熱熔型接著劑、感壓型接著劑(黏著劑)、再濕型接著劑、黏著劑等通用的物質。其中,經常使用水系溶劑揮發型接著劑、活性能量線硬化型接著劑、黏著劑。接著劑層的厚度可根據所要求的接著力等來適宜調節,可為0.01 μm至500 μm、較佳為0.1 μm至300 μm,所述柔性圖像顯示裝置用的積層體可存在多個,各自的厚度或種類可相同,亦可不同。[Adhesive layer] It is used to constitute each layer (flexible front panel, circular polarizer, touch sensor) as the optical member and the film member (linear polarizer, λ/4 phase difference plate, etc.) constituting each layer, or optical member In the case of a laminate, an adhesive can be used. As the adhesive, water-based adhesives, organic solvent-based adhesives, solvent-free adhesives, solid adhesives, water-based solvent volatile adhesives, moisture curing adhesives, thermosetting adhesives, and anaerobic curing adhesives can be used. General-purpose substances such as adhesives, active energy ray hardening adhesives, hardening mixed adhesives, hot-melt adhesives, pressure-sensitive adhesives (adhesives), rewetting adhesives, and adhesives. Among them, water-based solvent volatile adhesives, active energy ray hardening type adhesives, and adhesives are often used. The thickness of the adhesive layer can be appropriately adjusted according to the required adhesive force, etc., and can be 0.01 μm to 500 μm, preferably 0.1 μm to 300 μm. There may be multiple laminates for the flexible image display device. The respective thicknesses or types may be the same or different.
作為所述水系溶劑揮發型接著劑,可使用聚乙烯基醇系聚合物、澱粉等水溶性聚合物、乙烯-乙酸乙烯基酯乳液、苯乙烯-丁二烯系乳液等水分散狀態的高分子樹脂聚合物。除了調配水、所述樹脂聚合物以外,亦可調配交聯劑、矽烷系化合物、離子性化合物、交聯觸媒、抗氧化劑、染料、顏料、無機填料、有機溶劑等。於利用所述水系溶劑揮發型接著劑進行接著時,可藉由將所述水系溶劑揮發型接著劑注入至被接著層之間並貼合被接著層後、使其乾燥來賦予接著性。使用所述水系溶劑揮發型接著劑時的接著層的厚度可為0.01 μm至10 μm、較佳為0.1 μm 至1 μm。於使用多層所述水系溶劑揮發型接著劑時,各層的厚度或種類可相同,亦可不同。As the water-based solvent volatile adhesive, water-dispersed polymers such as polyvinyl alcohol-based polymers, starch and other water-soluble polymers, ethylene-vinyl acetate emulsions, styrene-butadiene-based emulsions, and the like can be used. Resin polymer. In addition to mixing water and the resin polymer, crosslinking agents, silane-based compounds, ionic compounds, crosslinking catalysts, antioxidants, dyes, pigments, inorganic fillers, organic solvents, etc. can also be formulated. When the water-based solvent volatile adhesive is used for bonding, the water-based solvent volatile adhesive can be provided by injecting the water-based solvent volatile adhesive between the layers to be bonded, bonding the bonded layers, and then drying them. The thickness of the adhesive layer when the water-based solvent volatile adhesive is used may be 0.01 μm to 10 μm, preferably 0.1 μm to 1 μm. When multiple layers of the water-based solvent volatile adhesive are used, the thickness or type of each layer may be the same or different.
所述活性能量線硬化型接著劑可藉由活性能量線硬化組成物的硬化來形成,所述活性能量線硬化組成物包含照射活性能量線而形成接著劑層的反應物質。所述活性能量線硬化組成物可含有如硬塗組成物般的自由基聚合性化合物以及陽離子聚合性化合物的至少一種聚合物。所述自由基聚合性化合物與硬塗組成物相同,可使用與硬塗組成物相同的種類。作為接著層中所使用的自由基聚合性化合物,較佳為具有丙烯醯基的化合物。為了降低接著劑組成物的黏度,亦較佳為包含單官能的化合物。The active energy ray curable adhesive can be formed by curing an active energy ray curable composition that includes a reactive substance that forms an adhesive layer by irradiating an active energy ray. The active energy ray hardening composition may contain at least one polymer of a radical polymerizable compound and a cationic polymerizable compound like a hard coat composition. The radically polymerizable compound is the same as the hard coat composition, and the same kind as the hard coat composition can be used. The radically polymerizable compound used in the adhesive layer is preferably a compound having an acryl group. In order to reduce the viscosity of the adhesive composition, it is also preferable to include a monofunctional compound.
所述陽離子聚合性化合物與硬塗組成物相同,可使用與硬塗組成物相同的種類。作為活性能量線硬化組成物中所使用的陽離子聚合性化合物,特佳為環氧化合物。為了降低接著劑組成物的黏度,亦較佳為包含單官能的化合物作為反應稀釋劑。The cationically polymerizable compound is the same as the hard coat composition, and the same kind as the hard coat composition can be used. As the cationic polymerizable compound used in the active energy ray hardening composition, an epoxy compound is particularly preferred. In order to reduce the viscosity of the adhesive composition, it is also preferable to include a monofunctional compound as a reactive diluent.
活性能量線組成物亦可進而包含聚合起始劑。聚合起始劑可應用所述內容。The active energy ray composition may further include a polymerization initiator. The polymerization initiator can be applied to the content.
所述活性能量線硬化組成物亦可進而包含離子捕捉劑、抗氧化劑、鏈轉移劑、密接賦予劑、熱塑性樹脂、填充劑、流動黏度調節劑、塑化劑、消泡劑、添加劑、溶劑。於利用所述活性能量線硬化型接著劑進行接著時,可藉由如下方式進行接著:將所述活性能量線硬化組成物塗佈於被接著層中的一個或全部後,進行貼合,並介隔一個被接著層或兩個被接著層照射活性能量線使其硬化。使用所述活性能量線硬化型接著劑時的接著層的厚度可為0.01 μm至20 μm、較佳為0.1 μm至10 μm。於使用多層所述活性能量線硬化型接著劑時,各層的厚度或種類可相同,亦可彼此不同。The active energy ray hardening composition may further include ion scavengers, antioxidants, chain transfer agents, adhesion imparting agents, thermoplastic resins, fillers, flow viscosity modifiers, plasticizers, defoamers, additives, and solvents. When the active energy ray hardening adhesive is used for bonding, the bonding can be performed by applying the active energy ray hardening composition to one or all of the layers to be bonded, and then bonding, and It is hardened by irradiating active energy rays through one adhesive layer or two adhesive layers. The thickness of the adhesive layer when the active energy ray hardening adhesive is used may be 0.01 μm to 20 μm, preferably 0.1 μm to 10 μm. When multiple layers of the active energy ray-curable adhesive are used, the thickness or type of each layer may be the same or different from each other.
作為所述黏著劑,亦可使用根據樹脂聚合物而分類為丙烯酸系黏著劑、胺基甲酸酯系接著劑、橡膠接著劑、矽酮接著劑等的任一者。黏著劑除了調配樹脂聚合物以外,亦可調配交聯劑、矽烷系化合物、離子性化合物、交聯觸媒、抗氧化劑、黏著賦予劑、塑化劑、染料、顏料、無機填料等。將構成所述黏著劑的各成分溶解、分散於溶劑中,獲得黏著劑組成物,將該黏著劑組成物塗佈於基板後,使其乾燥,形成接著層。黏著層可直接形成,亦可另行轉印形成於基材的層。為了於接著前覆蓋黏著面,亦較佳為使用脫模膜。使用所述黏著劑時的接著層的厚度可為1 μm至500 μm、較佳為2 μm至300 μm。於使用多層所述黏著劑時,各層的厚度或種類可相同,亦可不同。As the adhesive, any one classified into acrylic adhesives, urethane adhesives, rubber adhesives, silicone adhesives, etc. according to the resin polymer may also be used. In addition to blending resin polymers, the adhesive can also be blended with cross-linking agents, silane-based compounds, ionic compounds, cross-linking catalysts, antioxidants, adhesion-imparting agents, plasticizers, dyes, pigments, inorganic fillers, etc. Each component constituting the adhesive is dissolved and dispersed in a solvent to obtain an adhesive composition, and the adhesive composition is applied to a substrate and dried to form an adhesive layer. The adhesive layer may be directly formed, or a layer formed on the substrate may be transferred separately. In order to cover the adhesive surface before bonding, it is also preferable to use a release film. The thickness of the adhesive layer when the adhesive is used may be 1 μm to 500 μm, preferably 2 μm to 300 μm. When multiple layers of the adhesive are used, the thickness or type of each layer may be the same or different.
[遮光圖案] 遮光圖案可作為所述柔性圖像顯示裝置的邊框或殼體的至少一部分來應用。於包含遮光圖案時,配置於所述柔性圖像顯示裝置的邊緣部的配線被遮蓋而難以視認到,因此可提高圖像的視認性。所述遮光圖案可為單層或多層的形態。遮光圖案的顏色並無特別限制,有黑色、白色、金屬色等各種顏色。遮光圖案可由用於體現顏色的顏料、與丙烯酸系樹脂、酯系樹脂、環氧樹酯、聚胺基甲酸酯、矽酮等高分子形成,可單獨使用,或者以兩種以上的混合物來使用。所述遮光圖案可藉由印刷、微影、噴墨等各種方法來形成。遮光圖案的厚度可為1 μm至100 μm,較佳為可為2 μm至50 μm。另外,亦較佳為賦予在遮光圖案的厚度方向上傾斜等的形狀。[Shading Pattern] The light-shielding pattern can be applied as at least a part of the frame or housing of the flexible image display device. When the light-shielding pattern is included, the wiring arranged at the edge of the flexible image display device is covered and is difficult to see. Therefore, the visibility of the image can be improved. The light-shielding pattern may be in the form of a single layer or multiple layers. The color of the shading pattern is not particularly limited, and there are various colors such as black, white, and metallic. The light-shielding pattern can be formed by pigments used to express colors, and polymers such as acrylic resins, ester resins, epoxy resins, polyurethanes, silicones, etc., and can be used alone or in a mixture of two or more. use. The light-shielding pattern can be formed by various methods such as printing, photolithography, and inkjet. The thickness of the light-shielding pattern may be 1 μm to 100 μm, and preferably may be 2 μm to 50 μm. In addition, it is also preferable to give a shape such as an inclination in the thickness direction of the light-shielding pattern.
[光學積層體的製造方法] 本發明的其他態樣是有關於一種光學積層體的製造方法,其包括:提供至少一個以上的光學構件的階段;於所述光學構件上提供可撓性前面板的階段;將所述光學構件與所述可撓性前面板黏合的階段;以及將經黏合的所述光學構件與所述可撓性前面板以單元為單位切斷一次以上的階段,並且以所述光學構件的相向端部中、所述光學構件的最後退的端部位於自所述可撓性前面板的端部起向內側的距離小於2.0 mm的位置的方式進行切斷。[Method of manufacturing optical laminate] Another aspect of the present invention relates to a manufacturing method of an optical laminate, which includes: a stage of providing at least one optical member; a stage of providing a flexible front panel on the optical member; The stage of bonding with the flexible front panel; and the stage of cutting the bonded optical member and the flexible front panel more than once per unit, and the opposing ends of the optical member In the middle, the most retracted end of the optical member is cut so that the distance inward from the end of the flexible front panel is less than 2.0 mm.
針對所述可撓性前面板、光學構件的內容可應用所述內容。The content can be applied to the content of the flexible front panel and the optical member.
若為於所述光學構件上提供可撓性前面板並進行黏合的、本領域的通常的使用方法,則於本發明中並無特別限定。If it is a general use method in this field in which a flexible front panel is provided on the optical member and bonded, it is not particularly limited in the present invention.
例如,可於所述光學構件上經由黏著構件來黏合所述可撓性前面板,但並不限定於此。For example, the flexible front panel can be bonded to the optical member via an adhesive member, but it is not limited to this.
於本發明的又一實施形態中,所述光學構件可為偏光層或觸控感測器,但並不限定於此。In another embodiment of the present invention, the optical member may be a polarizing layer or a touch sensor, but it is not limited thereto.
經過將所述光學構件與所述可撓性前面板黏合的階段而黏合的所述光學構件與所述可撓性前面板是以單元為單位一起被切斷一次以上。The optical member and the flexible front panel bonded through the stage of bonding the optical member and the flexible front panel are cut together more than once in a unit.
所述切斷亦可視需要進行兩次以上,但並不限定於此。具體而言,所述切斷可使用最小能量來進行切斷,以使剖面的變形最小化,於為包括多個光學構件的光學積層體時,可針對各光學構件而使用最小的能量來進行多次切斷。The cutting may be performed more than twice as necessary, but it is not limited to this. Specifically, the cutting can be performed using the minimum energy to minimize the deformation of the cross section. In the case of an optical laminate including a plurality of optical members, the cutting can be performed using the minimum energy for each optical member. Cut off several times.
參考圖1以及圖4,於為現有的光學積層體時,由於經過將前面板與光學構件分別單獨切斷後加以黏合的過程,因此多少會產生由非顯示區域所致的畫面比縮小的問題,且於彎曲時多少會產生端部產生裂紋的問題。1 and 4, in the case of a conventional optical laminate, since the front panel and the optical member are separately cut and bonded together, there is a problem of reduced screen ratio due to the non-display area. In addition, the problem of cracks at the end may occur somewhat when bent.
但是,參考圖2以及圖5,本發明的光學積層體的製造方法由於是一起切斷經黏合的所述光學構件與所述可撓性前面板,因此可減少非顯示區域,因此畫面比優異,且於彎曲時可減少與可撓性前面板一起積層的光學構件的剖面偏差區域中所顯現出的應力的偏差,因此於彎曲時抑制端部產生裂紋的問題,具有彎曲耐久性亦優異的優點。However, referring to FIGS. 2 and 5, the method of manufacturing the optical laminate of the present invention cuts the bonded optical member and the flexible front panel together, so that the non-display area can be reduced, and the screen ratio is excellent. , And can reduce the deviation of the stress that appears in the cross-sectional deviation area of the optical member laminated with the flexible front panel during bending. Therefore, the problem of cracks at the end can be suppressed during bending, and the bending durability is also excellent. advantage.
具體而言,經切斷的所述光學構件的相向端部中,所述光學構件的最後退的端部存在於自所述可撓性前面板的端部起向內側的後退距離小於2.0 mm的位置。Specifically, among the cut opposing ends of the optical member, the most retracted end of the optical member exists at a receding distance of less than 2.0 mm inward from the end of the flexible front panel s position.
較佳為所述經切斷的所述光學構件的相向端部中,可使所述光學構件的最突出的端部以及所述光學構件的最後退的端部存在於自所述可撓性前面板的端部起向外側的距離為0.2 mm以下的位置至自所述可撓性前面板的端部起向內側的後退距離小於2.0 mm的位置。It is preferable that among the opposing ends of the cut optical member, the most protruding end of the optical member and the most retracted end of the optical member may exist in the flexible The position where the distance from the end of the front panel to the outside is 0.2 mm or less to the position where the distance to the inside from the end of the flexible front panel is less than 2.0 mm.
本發明的光學積層體的製造方法為將經切斷的所述光學構件的端部形成於距所述可撓性前面板的端部近的位置般的製造方法,因此具有彎曲性能優異的優點。The manufacturing method of the optical laminate of the present invention is a manufacturing method of forming the cut end of the optical member at a position close to the end of the flexible front panel, and therefore has the advantage of excellent bending performance .
光學構件的端部的位置與可撓性前面板的端部的位置之間的距離例如可根據用於使雷射光聚集的透鏡的焦點距離、或雷射的輸出、或切斷速度等來調整。透鏡的焦點距離例如可設為10 mm~100 mm。The distance between the position of the end of the optical member and the position of the end of the flexible front panel can be adjusted according to, for example, the focal length of the lens for condensing laser light, the output of the laser, or the cutting speed, etc. . The focal length of the lens can be set to, for example, 10 mm to 100 mm.
於本發明的又一實施形態中,所述光學構件可為兩個以上。In another embodiment of the present invention, the number of the optical members may be two or more.
於所述光學構件包含基材、且包含偏光層及/或觸控感測器時,所述偏光層及/或觸控感測器可更靠近所述可撓性前面板而存在。When the optical member includes a substrate and includes a polarizing layer and/or a touch sensor, the polarizing layer and/or the touch sensor may exist closer to the flexible front panel.
於本發明的又一實施形態中,可進而包括在所述兩個以上的光學構件之間形成黏著構件的階段。其中,所述形成黏著構件的階段較佳為包括於將經黏合的所述光學構件與所述可撓性前面板以單元為單位加以黏合的階段之前。In another embodiment of the present invention, it may further include a step of forming an adhesive member between the two or more optical members. Wherein, the step of forming the adhesive member is preferably included before the step of bonding the bonded optical member and the flexible front panel on a unit basis.
藉由本發明的光學積層體的製造方法而製造的光學積層體由於包括將可撓性前面板與光學構件同時切斷的階段,因此畫面比優異,且於彎曲時可減少與可撓性前面板一起積層的光學構件的剖面偏差區域中所顯現出的應力的偏差,因此可抑制端部產生裂紋的現象,因此具有彎曲耐久性優異的優點。Since the optical laminate manufactured by the method of manufacturing the optical laminate of the present invention includes the stage of simultaneously cutting the flexible front panel and the optical member, it has an excellent screen ratio and can be reduced with the flexible front panel when bent. Since the deviation of the stress that appears in the cross-sectional deviation area of the optical members laminated together can suppress the phenomenon of cracks at the end portion, it has the advantage of excellent bending durability.
[雷射光的波長範圍] 於切斷步驟中,自雷射裝置出射的雷射光的波長為9 μm以上且11 μm以下的波長。尤其是9.3 μm附近(9.1 μm至9.7 μm)以及10.6 μm附近(10.1 μm~11 μm)的波長的雷射光在使用CO2 氣體雷射裝備作為雷射裝備時可穩定地進行輸出。因此,於採用此種波長的雷射光時,可特別良好地進行本發明的製造方法。[Wavelength range of laser light] In the cutting step, the wavelength of the laser light emitted from the laser device is a wavelength of 9 μm or more and 11 μm or less. In particular, laser light with wavelengths around 9.3 μm (9.1 μm to 9.7 μm) and 10.6 μm (10.1 μm to 11 μm) can be output stably when CO 2 gas laser equipment is used as the laser equipment. Therefore, when laser light of such a wavelength is used, the manufacturing method of the present invention can be performed particularly well.
切斷速度較佳為100 mm/s至500 mm/s的範圍,輸出較佳為設為最大輸出的10%至30%,該情況下,由於切斷膜時剖面整齊而較佳。照射次數較佳為進行1次至2次,為了切斷膜,可視需要進行多次。The cutting speed is preferably in the range of 100 mm/s to 500 mm/s, and the output is preferably set to 10% to 30% of the maximum output. In this case, it is preferable because the section is neat when the film is cut. The number of times of irradiation is preferably 1 to 2 times. In order to cut the film, it may be carried out as many times as necessary.
[圖像顯示裝置] 圖像顯示裝置並無特別限定,可由所述光學積層體與有機EL顯示面板構成,且可相對於有機EL顯示面板將光學積層體配置於視認側,並構成為能夠彎曲。所述光學積層體包括可撓性前面板、以及存在於所述可撓性前面板的下部的一個以上的光學構件,具體而言,所述光學構件可包括所述可撓性前面板、偏光板、觸控感測器。可撓性前面板、偏光板、觸控感測器的積層順序可應用所述內容,但並不限定於此。[Image display device] The image display device is not particularly limited, and may be composed of the optical laminate and the organic EL display panel, and the optical laminate may be arranged on the visible side with respect to the organic EL display panel and configured to be flexible. The optical laminate includes a flexible front panel, and one or more optical members existing in a lower portion of the flexible front panel. Specifically, the optical member may include the flexible front panel, a polarized light Board, touch sensor. The stacking sequence of the flexible front panel, the polarizing plate, and the touch sensor can be applied to the content described above, but is not limited to this.
以下,列舉實施例來進行詳細說明,以便具體說明本說明書。但是,本說明書的實施例可以其他各種形態來變形,且並不解釋為本說明書的範圍限定於以下詳細描述的實施例。本說明書的實施例是針對本領域中具有普通知識的人員而提供,以便更完全地說明本說明書。另外,以下,只要並未特別記載,則表示含量的「%」以及「份」為重量基準。Hereinafter, examples are listed for detailed description, so as to specifically describe the specification. However, the embodiments of this specification can be modified in various other forms, and it is not construed that the scope of this specification is limited to the embodiments described in detail below. The embodiments of this specification are provided for persons with ordinary knowledge in the field, so as to more fully explain this specification. In addition, in the following, unless otherwise stated, the "%" and "parts" indicating the content are based on weight.
<實施例中使用的構件(使用構件)> 可撓性前面板(以下,簡稱為WIN) 於基材膜的兩面形成有硬塗層的膜:厚度70 μm、彈性係數3457 MPa 基材膜:厚度50 μm、聚醯亞胺系(PI)樹脂膜 硬塗層:厚度10 μm、由包含末端具有多官能丙烯酸基的樹枝狀聚合物(dendrimer)化合物的組成物形成的層<Members used in Examples (Members used)> Flexible front panel (hereinafter referred to as WIN) A film with hard coats formed on both sides of the base film: thickness 70 μm, coefficient of elasticity 3457 MPa Substrate film: thickness 50 μm, polyimide-based (PI) resin film Hard coat layer: 10 μm thick, layer formed of a composition containing a dendrimer compound having a polyfunctional acrylic group at the end
偏光板(以下,簡稱為POL)
按照三乙醯纖維素(Triacetyl Cellulose,TAC)/偏光層/相位差膜的順序積層而成的積層體,厚度44.5 μm
TAC:厚度25 μm、彈性係數3,282 MPa、柯尼卡美能達(Konica Minolta)(股)
偏光層:厚度2.5 μm、彈性係數937 MPa
相位差膜:厚度17 μm
相位差膜的積層結構:外塗層(丙烯酸系樹脂組成物的硬化層、厚度1 μm、彈性係數4,510 MPa)/黏著劑層(厚度5 μm、彈性係數0.11 MPa)/由液晶化合物硬化而成的層以及配向膜構成的λ/4相位差板(厚度3 μm、彈性係數1,624 MPa)/黏著劑層(厚度5 μm、彈性係數0.11 MPa)/由液晶化合物硬化而成的層以及配向膜構成的正C板(厚度3 μm、彈性係數2,039 MPa)Polarizing plate (hereinafter referred to as POL)
A laminate formed in the order of Triacetyl Cellulose (TAC) / polarizing layer / retardation film, thickness 44.5 μm
TAC: thickness 25 μm, coefficient of elasticity 3,282 MPa, Konica Minolta (shares)
Polarizing layer: thickness 2.5 μm, elastic coefficient 937 MPa
Retardation film: thickness 17 μm
Laminated structure of retardation film: outer coating (hardened layer of acrylic resin composition, thickness 1 μm, elastic coefficient 4,510 MPa)/adhesive layer (thickness 5 μm, elastic coefficient 0.11 MPa)/cured by liquid crystal compound Λ/4 retardation plate (
觸控感測器(以下,簡稱為TS)
觸控感測器:厚度33 μm、層結構:觸控感測器圖案(作為ITO與丙烯酸系樹脂組成物的硬化層的積層體、厚度7 μm、彈性係數4,510 MPa)/接著劑層(厚度3 μm、彈性係數12,309 MPa)/環狀烯烴系樹脂膜(厚度23 μm、彈性係數1,785 MPa)Touch sensor (hereinafter referred to as TS)
Touch sensor: thickness 33 μm, layer structure: touch sensor pattern (a laminate of ITO and acrylic resin composition hardened layer, thickness 7 μm, coefficient of elasticity 4,510 MPa)/adhesive layer (
黏著構件(光學透明黏著劑(Optically Clear Adhesive)(以下,簡稱為OCA)) 使用丙烯酸系黏著劑層,將厚度設為25 μm,並藉由下述製造方法來製造。 以重量基準計,將84重量份的丙烯酸2-乙基己酯、15重量份的丙烯酸異冰片基酯、1重量份的丙烯酸羥基丙酯、以及作為聚合起始劑的0.02重量份的1-羥基環己基苯基酮混合。對混合液照射紫外線來使單體聚合。Adhesive member (Optically Clear Adhesive (hereinafter referred to as OCA)) The acrylic adhesive layer was used, and the thickness was set to 25 μm, and it was manufactured by the following manufacturing method. On a weight basis, 84 parts by weight of 2-ethylhexyl acrylate, 15 parts by weight of isobornyl acrylate, 1 part by weight of hydroxypropyl acrylate, and 0.02 parts by weight of 1- Hydroxycyclohexyl phenyl ketone mixed. The mixed liquid is irradiated with ultraviolet rays to polymerize the monomers.
其後,於所述混合物中加入作為聚合起始劑的0.4重量份的1-羥基環己基苯基酮、0.3重量份的丙烯酸月桂基酯、0.05重量份的聚乙二醇(200)二丙烯酸酯、0.05重量份的(3-縮水甘油基氧基丙基)三甲氧基矽烷,製造黏著劑組成物。Thereafter, 0.4 parts by weight of 1-hydroxycyclohexyl phenyl ketone, 0.3 parts by weight of lauryl acrylate, and 0.05 parts by weight of polyethylene glycol (200) diacrylic acid were added to the mixture as a polymerization initiator. Ester, 0.05 parts by weight of (3-glycidyloxypropyl)trimethoxysilane to produce an adhesive composition.
將黏著劑組成物塗敷於表面經矽酮處理的聚對苯二甲酸乙二酯膜(脫模膜)。將塗敷的厚度設為25 μm。準備其他脫模膜,積層於塗敷上。對具有脫模膜/接著劑組成物的塗敷層/脫模膜的結構的積層體照射紫外線。於紫外線照射步驟中,以累計光量為1500 mJ/cm2 的方式對積層體照射300 nm~400 nm的紫外線(於365 nm下發光強度極大)。如此,製作包含(甲基)丙烯酸系黏著劑層的黏著劑片。The adhesive composition is applied to a polyethylene terephthalate film (release film) treated with silicone on the surface. The thickness of the coating was set to 25 μm. Prepare other release films and layer them on the coating. The layered body having the structure of the release film/coating layer of the adhesive composition/release film is irradiated with ultraviolet rays. In the ultraviolet irradiation step, the laminated body is irradiated with ultraviolet rays of 300 nm to 400 nm (the luminous intensity is extremely high at 365 nm) with a cumulative light amount of 1500 mJ/cm 2. In this way, an adhesive sheet containing a (meth)acrylic adhesive layer was produced.
聚醯亞胺系樹脂膜(以下,簡稱為PI) 聚醯亞胺系樹脂膜(PI)、厚度38 μm、彈性係數4,865 MPa、科隆(Kolon)(股)(韓國)Polyimide resin film (hereinafter referred to as PI) Polyimide resin film (PI), thickness 38 μm, coefficient of elasticity 4,865 MPa, Kolon (share) (Korea)
遮光圖案用油墨(著色層形成用組成物)
[油墨成分]
乙炔黑 15重量%
聚酯 75重量%
戊二酸二甲酯 2.5重量%
琥珀酸 2重量%
異佛爾酮 5.5重量%
[硬化劑]
脂肪族聚異氰酸酯 75重量%
乙酸乙酯 25重量%
[溶劑]
異佛爾酮 100重量%
[製造方法]
於油墨成分100重量份中加入硬化劑10重量份、溶媒10重量份並混合,藉此獲得著色層形成用組成物(黑色)。Ink for shading pattern (composition for forming colored layer)
[Ink composition]
Acetylene black 15% by weight
Polyester 75% by weight
Dimethyl glutarate 2.5% by weight
Succinic acid 2% by weight
Isophorone 5.5% by weight
[hardener]
Aliphatic polyisocyanate 75% by weight
Ethyl acetate 25% by weight
[Solvent]
單元形態(單元形狀(cell shape)) 具有橫與縱的形態的長方向的四邊形形態Cell shape (cell shape) A quadrilateral shape with a horizontal and vertical shape in the longitudinal direction
實施例1 於可撓性前面板的單面,利用網版印刷工法,以乾燥後的厚度為3 μm的方式使用邊框(bezel)(遮光圖案)用油墨形成遮光圖案(非顯示區域)。Example 1 On one side of the flexible front panel, a screen printing method is used to form a light-shielding pattern (non-display area) with a bezel (light-shielding pattern) ink with a thickness of 3 μm after drying.
以與可撓性前面板(厚度70 μm)的邊框(遮光圖案)面相接的方式使用OCA(厚度25 μm),並使用接合機依次接合POL(厚度70 μm)、TS、PI基材,製造光學積層體。The OCA (thickness 25 μm) is used so that it is in contact with the frame (light-shielding pattern) surface of the flexible front panel (thickness 70 μm), and the POL (thickness 70 μm), TS, and PI substrates are sequentially bonded using a bonding machine. Manufacture of optical laminates.
對於所述光學積層體,以邊框(遮光圖案)的框為基準,使用LP泰科(LPTech)公司製造的CO2 雷射切斷機(60 W輸出)(以下,雷射切斷機),將入射波長設為9.3 μm,自可撓性前面板的另一面(未形成邊框的面)利用焦點距離38 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出30%、照射次數1次的條件下進行切斷,製造具有如表1般的剖面形狀的光學積層體(單元形態)。For the optical laminate, using the frame of the frame (light-shielding pattern) as a reference, a CO 2 laser cutting machine (60 W output) manufactured by LP Tech (LPTech) (hereinafter, laser cutting machine) is used, Set the incident wavelength to 9.3 μm, use a lens with a focal distance of 38 mm to focus the laser light from the other side of the flexible front panel (the side where no frame is formed), and at a speed of 400 mm/s, an output of 30%, and the number of exposures Cutting was performed under the conditions of one pass, and an optical laminate (cell form) having a cross-sectional shape as shown in Table 1 was produced.
實施例2 藉由與實施例1相同的方法製造光學積層體後,使用雷射切斷機,利用焦點距離42 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出15%、照射次數1次的條件下進行1次切斷後,利用焦點距離38 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出30%、照射次數1次的條件下進行2次切斷,製造具有如表1般的剖面形狀的光學積層體(單元形態)。Example 2 After manufacturing the optical laminate by the same method as in Example 1, a laser cutter was used to focus the laser light with a lens with a focal length of 42 mm, at a speed of 400 mm/s, an output of 15%, and the number of irradiations once. After cutting once under the conditions of, the laser light is collected by a lens with a focal distance of 38 mm, and the laser is cut twice at a speed of 400 mm/s, an output of 30%, and the number of times of irradiation. Optical laminate with general cross-sectional shape (cell form).
實施例3
除了不含TS層,藉由與實施例1相同的方法製造光學積層體,使用雷射切斷機,利用焦點距離42 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出10%、照射次數1次的條件下進行1次切斷後,利用焦點距離38 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出30%、照射次數1次的條件下進行2次切斷,製造具有如表1般的剖面形狀的光學積層體(單元形態)。Example 3
Except that the TS layer is not included, the optical laminate is manufactured by the same method as in Example 1, using a laser cutter, using a lens with a focal distance of 42 mm to focus the laser light, and at a speed of 400 mm/s and an output of 10% , After cutting once under the condition of 1 shot, use a lens with a focal distance of 38 mm to focus the laser light, and perform 2 cuts at a speed of 400 mm/s,
實施例4
除了不含POL層,藉由與實施例1相同的方法製造光學積層體,使用雷射切斷機,利用焦點距離42 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出10%、照射次數1次的條件下進行1次切斷後,利用焦點距離38 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出30%、照射次數1次的條件下進行2次切斷,製造具有如表1般的剖面形狀的光學積層體(單元形態)。Example 4
Except that the POL layer is not included, an optical laminate is manufactured by the same method as in Example 1. A laser cutter is used to condense the laser light with a lens with a focal distance of 42 mm, and at a speed of 400 mm/s and an output of 10% , After cutting once under the condition of 1 shot, use a lens with a focal distance of 38 mm to focus the laser light, and perform 2 cuts at a speed of 400 mm/s,
實施例5 藉由與實施例1相同的方法製造光學積層體後,使用雷射切斷機,利用焦點距離42 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出15%、照射次數1次的條件下進行1次切斷後,利用焦點距離38 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出15%、照射次數1次的條件下進行2次切斷,製造具有如表1般的剖面形狀的光學積層體(單元形態)。Example 5 After manufacturing the optical laminate by the same method as in Example 1, a laser cutter was used to focus the laser light with a lens with a focal length of 42 mm, at a speed of 400 mm/s, an output of 15%, and the number of irradiations once. After cutting once under the conditions of, use a lens with a focal distance of 38 mm to focus the laser light, and perform cutting twice under the conditions of a speed of 400 mm/s, an output of 15%, and the number of times of irradiation. Optical laminate with general cross-sectional shape (cell form).
實施例6 藉由與實施例1相同的方法製造光學積層體後,使用雷射切斷機,利用焦點距離42 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出15%、照射次數1次的條件下進行1次切斷後,利用焦點距離38 mm的透鏡使雷射光聚集,且於速度400 mm/s、輸出25%、照射次數1次的條件下進行2次切斷,製造具有如表1般的剖面形狀的光學積層體(單元形態)。Example 6 After manufacturing the optical laminate by the same method as in Example 1, a laser cutter was used to focus the laser light with a lens with a focal length of 42 mm, at a speed of 400 mm/s, an output of 15%, and the number of irradiations once. After cutting once under the conditions of, use a lens with a focal distance of 38 mm to focus the laser light, and perform cutting twice under the conditions of a speed of 400 mm/s, an output of 25%, and the number of times of irradiation. Optical laminate with general cross-sectional shape (cell form).
比較例1 藉由與實施例1相同的方法製作形成有邊框(遮光圖案)的可撓性前面板後,藉由與實施例1相同的方法進行切斷,並以單元形態進行準備。Comparative example 1 After fabricating a flexible front panel with a frame (light-shielding pattern) formed by the same method as in Example 1, it was cut by the same method as in Example 1, and prepared in a unit form.
製作按照OCA以及POL/TS/PI的順序使用OCA進行接合而成的光學積層體,以各邊比可撓性前面板小約4 mm的方式,藉由與實施例1相同的方法進行切斷。An optical laminate was produced by bonding OCA in the order of OCA and POL/TS/PI. The sides were cut by the same method as in Example 1 so that each side was about 4 mm smaller than the flexible front panel. .
對可撓性前面板單元與經切割的光學積層體以中心以及垂直度一致的方式進行接合,製造具有如表1般的剖面形狀的光學積層體(單元形態)。The flexible front panel unit and the cut optical laminate were joined so that the center and the verticality were aligned to produce an optical laminate (unit form) having a cross-sectional shape as shown in Table 1.
比較例2 藉由與實施例1相同的方法製作形成有邊框(遮光圖案)的可撓性前面板後,使用OCA與POL接合。Comparative example 2 After fabricating a flexible front panel with a frame (light-shielding pattern) formed by the same method as in Example 1, OCA and POL were used for bonding.
對於可撓性前面板以及POL光學積層體,藉由與實施例1相同的方法進行切斷,並以單元形態進行準備。The flexible front panel and the POL optical laminate were cut by the same method as in Example 1, and prepared in a unit form.
製作接合有OCA以及PI基材的光學積層體,以各邊比可撓性前面板小4 mm的方式,藉由與實施例1相同的方法進行切斷。An optical laminate in which OCA and PI substrates were joined was produced, and the sides were cut by the same method as in Example 1 so that each side was 4 mm smaller than the flexible front panel.
對可撓性前面板與光學積層體以中心以及垂直度一致的方式進行接合,製造具有如表1般的剖面形狀的光學積層體(單元形態)。The flexible front panel and the optical laminate were joined so that the center and the perpendicularity were aligned, and an optical laminate (cell form) having a cross-sectional shape as shown in Table 1 was produced.
比較例3 對於可撓性前面板以及TS光學積層體,藉由與實施例1相同的方法進行切斷,並以單元形態進行準備,除此以外,與比較例1同樣地製造具有如表1般的剖面形狀的光學積層體(單元形態)。Comparative example 3 The flexible front panel and the TS optical laminate were cut by the same method as in Example 1 and prepared in the form of a unit, except that the same as in Comparative Example 1 was produced with a cross-section as shown in Table 1. Shaped optical laminate (cell form).
實驗例 關於實施例與比較例中所製作的樣品,使用光學顯微鏡確認端部距離偏差,並藉由以下方法進行對此的彎曲評價。Experimental example Regarding the samples produced in the Examples and Comparative Examples, the end distance deviation was confirmed using an optical microscope, and the bending evaluation was performed by the following method.
關於各實施例以及比較例中所獲得的光學積層體,使用彎曲評價裝置(科學城(Science Town)公司製造,STS-VRT-500)確認對於彎曲的耐久性,進行評價試驗。With respect to the optical laminates obtained in the respective Examples and Comparative Examples, a bending evaluation device (manufactured by Science Town Co., Ltd., STS-VRT-500) was used to confirm the durability against bending, and an evaluation test was performed.
圖6是示意性地表示本評價試驗方法的圖。如圖6般,以間隙C為5.0 mm(2.5 R)的方式配置能夠單獨移動的兩平台201、平台202,且以寬度方向的中心位於間隙C的中心的方式,利用膠帶固定並配置實施例以及比較例的光學積層體(圖7的(a)、圖7的(b))。此時,於前表面成為可撓性前面板時為內折(IN FOLDING),於後表面成為可撓性前面板時為外折(OUT FOLDING)。例如,圖7的(a)以及圖7的(b)可理解為分別按照所述基準並利用膠帶固定並配置圖4以及圖5的光學積層體而成者。而且,使兩平台201、平台202以位置P1以及位置P2為旋轉軸的中心向上方旋轉90度,對與平台的間隙C對應的光學積層體100的區域施加彎曲力。其後,使兩平台201、平台202返回到原來的場所。結束以上一系列的操作,將彎曲力的施加次數判定為1次。累計彎曲力的施加次數,確認與平台201、平台202的間隙C對應的光學積層體的與可撓性前面板的端部尺寸的偏差區域中有無氣泡或裂縫的產生(圖7的(a)、圖7的(b)的X),於產生氣泡或裂縫的時刻中斷彎曲的評價,按照以下基準進行評價,並將評價結果示於表1中。平台201、平台202的移動速度、彎曲力的施加程度於任一對於光學積層體的評價試驗中均是設為相同的條件。Fig. 6 is a diagram schematically showing this evaluation test method. As shown in Figure 6, the two
此時,彎曲性的評價基準為如下所述。 ◎:20萬次以上 〇:15萬次以上且小於20萬次 △:10萬次以上且小於15萬次 ×:5萬次以上且小於10萬次 ××:小於5萬次At this time, the evaluation criteria of flexibility are as follows. ◎: More than 200,000 times 〇: 150,000 times or more but less than 200,000 times △: more than 100,000 times and less than 150,000 times ×: More than 50,000 times but less than 100,000 times ××: Less than 50,000 times
[表1]
參考上表1,可確認到可撓性前面板與下部光學構件的端部間的距離(偏差)對彎曲性能產生影響,得知於本發明的光學積層體中,端部間的距離越小,越顯現出優異的彎曲性能。With reference to Table 1 above, it can be confirmed that the distance (deviation) between the flexible front panel and the end of the lower optical member has an effect on the bending performance. It is found that in the optical laminate of the present invention, the distance between the ends is smaller , The more it shows excellent bending performance.
100:光學積層體
10:可撓性前面板
20:光學構件
21:偏光板(POL)
22:觸控感測器(TS)
23:基材(PI)
30:黏著構件
40:非顯示區域
X:裂紋、氣泡或裂縫的產生位置
201、202:平台
300:顯示區域
301:非顯示區域
302:非顯示區域的寬度
(A)、(B)、(C):端部間的距離
C:間隙
P1、P2:位置100: Optical laminate
10: Flexible front panel
20: Optical components
21: Polarizing plate (POL)
22: Touch Sensor (TS)
23: Substrate (PI)
30: Adhesive components
40: Non-display area
X: The location of cracks, bubbles or
圖1是例示現有的光學積層體以及基於其的畫面比的圖式。 圖2是例示本發明的光學積層體的結構的圖式。 圖3是例示顯示區域、非顯示區域以及非顯示區域的寬度的圖式。 圖4是例示使現有的光學積層體彎曲後的情況的圖式。 圖5是例示使本發明的光學積層體彎曲後的情況的圖式。 圖6是例示實驗例的彎曲實驗方法的圖式。 圖7的(a)是例示現有的光學積層體(比較例)的內折(IN-FOLDING)、外折(OUT-FOLDING)的彎曲實驗方法以及由彎曲所致的主要裂紋的產生位置的圖式。圖7的(b)是例示本發明的光學積層體(實驗例)的內折(IN-FOLDING)、外折(OUT-FOLDING)的彎曲實驗方法以及由彎曲所致的主要裂紋的產生位置的圖式。 圖8的(a)至圖8的(e)是例示實施例的光學積層體的結構以及偏差部的圖式。 圖9的(a)至圖9的(c)是例示比較例的光學積層體的結構以及偏差部的圖式。FIG. 1 is a diagram illustrating a conventional optical laminate and a screen ratio based on it. Fig. 2 is a diagram illustrating the structure of the optical laminate of the present invention. FIG. 3 is a diagram illustrating the width of the display area, the non-display area, and the non-display area. Fig. 4 is a diagram illustrating a state after bending a conventional optical laminate. Fig. 5 is a diagram illustrating a state after bending the optical laminate of the present invention. Fig. 6 is a diagram illustrating a bending test method of an experimental example. FIG. 7(a) is a diagram illustrating the bending test method of in-folding (IN-FOLDING) and out-folding (OUT-FOLDING) of a conventional optical laminate (comparative example) and the location of the main cracks caused by bending formula. Fig. 7(b) illustrates the bending test method of in-folding (IN-FOLDING) and outward-folding (OUT-FOLDING) of the optical laminate (experimental example) of the present invention, and the location of the main cracks caused by bending figure. 8(a) to 8(e) are diagrams illustrating the structure of the optical layered body and the deviation portion of the embodiment. 9(a) to 9(c) are diagrams illustrating the structure of the optical laminate of the comparative example and the deviation portion.
10:可撓性前面板 10: Flexible front panel
20:光學構件 20: Optical components
30:黏著構件 30: Adhesive components
40:非顯示區域 40: Non-display area
100:光學積層體 100: Optical laminate
Claims (4)
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| KR20190090873 | 2019-07-26 |
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| JP (1) | JPWO2021020054A1 (en) |
| KR (1) | KR20210012896A (en) |
| CN (1) | CN114144823B (en) |
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| JP3586983B2 (en) * | 1996-08-06 | 2004-11-10 | 富士通株式会社 | Gas discharge display |
| JP4132426B2 (en) * | 1999-06-25 | 2008-08-13 | 大日本印刷株式会社 | In-page layout processing device for saddle-stitched magazines |
| JP5159385B2 (en) * | 2008-03-21 | 2013-03-06 | 三菱電機株式会社 | Liquid crystal display |
| JP5268761B2 (en) * | 2008-05-26 | 2013-08-21 | 三菱電機株式会社 | Display device and manufacturing method thereof |
| JP2011186404A (en) * | 2010-03-11 | 2011-09-22 | Hitachi Displays Ltd | Liquid crystal display device |
| JP5912306B2 (en) * | 2010-08-23 | 2016-04-27 | ユー・ディー・シー アイルランド リミテッド | Organic electroluminescent substrate and organic electroluminescent device |
| TW201413512A (en) * | 2012-09-19 | 2014-04-01 | Dongguan Masstop Liquid Crystal Display Co Ltd | Touch display device and touch panel |
| KR102235720B1 (en) * | 2013-12-17 | 2021-04-05 | 삼성디스플레이 주식회사 | Curved display apparatus |
| US9321677B2 (en) * | 2014-01-29 | 2016-04-26 | Corning Incorporated | Bendable glass stack assemblies, articles and methods of making the same |
| KR20150092777A (en) | 2014-02-05 | 2015-08-17 | 삼성디스플레이 주식회사 | Display device and method of manufacturing a display device |
| KR102337671B1 (en) * | 2015-01-15 | 2021-12-09 | 삼성디스플레이 주식회사 | Organic light emitting diode display |
| WO2016122173A1 (en) * | 2015-01-27 | 2016-08-04 | 엘지이노텍 주식회사 | Touch window |
| JP6706475B2 (en) * | 2015-09-30 | 2020-06-10 | 日鉄ケミカル&マテリアル株式会社 | Long polyimide laminate film and method for producing the same, and method for producing polyimide film with functional layer |
| CN113540198B (en) * | 2015-10-13 | 2024-05-31 | 康宁股份有限公司 | Flexible electronic device module, product and manufacturing method thereof |
| US9913392B2 (en) * | 2016-04-13 | 2018-03-06 | Motorola Mobility Llc | Flexible display stack-up and method for arranging |
| KR101995977B1 (en) * | 2016-11-28 | 2019-07-04 | 삼성디스플레이 주식회사 | Flexible display apparatus |
| JP6880714B2 (en) * | 2016-12-26 | 2021-06-02 | 大日本印刷株式会社 | Decorative member, display device using it, and manufacturing method of decorative member |
| KR102672832B1 (en) * | 2016-12-30 | 2024-06-05 | 엘지디스플레이 주식회사 | Foldable display device |
| WO2018134974A1 (en) * | 2017-01-20 | 2018-07-26 | 住友化学株式会社 | Resin film, laminate, optical member, gas barrier material and touch sensor substrate |
| JP2018190347A (en) * | 2017-05-11 | 2018-11-29 | 株式会社ジャパンディスプレイ | Display device |
| KR102689816B1 (en) * | 2017-06-27 | 2024-07-29 | 스미또모 가가꾸 가부시키가이샤 | optical film |
| KR20240034853A (en) * | 2017-07-31 | 2024-03-14 | 닛토덴코 가부시키가이샤 | Layered body for flexible image display device, and flexible image display device |
| WO2019065401A1 (en) * | 2017-09-27 | 2019-04-04 | 日本ゼオン株式会社 | Laminated optical film and touch panel |
| JP6495525B1 (en) * | 2018-05-08 | 2019-04-03 | 住友化学株式会社 | Laminated body and method for producing the same |
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