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TW201833049A - Glass support substrate and laminate using same - Google Patents

Glass support substrate and laminate using same Download PDF

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Publication number
TW201833049A
TW201833049A TW106140335A TW106140335A TW201833049A TW 201833049 A TW201833049 A TW 201833049A TW 106140335 A TW106140335 A TW 106140335A TW 106140335 A TW106140335 A TW 106140335A TW 201833049 A TW201833049 A TW 201833049A
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glass substrate
less
supporting
supporting glass
substrate
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TW106140335A
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Chinese (zh)
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TWI755449B (en
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鈴木良太
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日商日本電氣硝子股份有限公司
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Publication of TWI755449B publication Critical patent/TWI755449B/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/683Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere for supporting or gripping
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/12Mountings, e.g. non-detachable insulating substrates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00Details of semiconductor or other solid state devices
    • H01L23/12Mountings, e.g. non-detachable insulating substrates
    • H01L23/14Mountings, e.g. non-detachable insulating substrates characterised by the material or its electrical properties
    • H01L23/15Ceramic or glass substrates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/10Bump connectors; Manufacturing methods related thereto
    • H01L2224/12Structure, shape, material or disposition of the bump connectors prior to the connecting process
    • H01L2224/12105Bump connectors formed on an encapsulation of the semiconductor or solid-state body, e.g. bumps on chip-scale packages
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/93Batch processes
    • H01L2224/95Batch processes at chip-level, i.e. with connecting carried out on a plurality of singulated devices, i.e. on diced chips
    • H01L2224/96Batch processes at chip-level, i.e. with connecting carried out on a plurality of singulated devices, i.e. on diced chips the devices being encapsulated in a common layer, e.g. neo-wafer or pseudo-wafer, said common layer being separable into individual assemblies after connecting

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Power Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Glass Compositions (AREA)

Abstract

The glass support substrate according to the present invention is for supporting a substrate to be processed, and is characterized by containing, as a glass composition, in mass%, 45-70% of SiO2, more than 10.5 but not more than 35% of Al2O3, 0-20% of B2O3, 5-25% of Na2O, 0-10% of K2O, 1-10% of MgO, and 0-5% of ZnO, and having a crack resistance of 500 gf or more.

Description

支撐玻璃基板及使用其的積層體Supporting glass substrate and laminated body using the same

本發明是有關於一種用以支撐加工基板的支撐玻璃基板及使用其的積層體,具體而言,是有關於一種在半導體封裝體(半導體裝置)的製造步驟中用於加工基板的支撐的支撐玻璃基板及使用其的積層體。The present invention relates to a supporting glass substrate for supporting a processed substrate and a laminated body using the same, and more particularly to a support for processing a substrate in a manufacturing step of a semiconductor package (semiconductor device) A glass substrate and a laminate using the same.

對行動電話、筆記型個人電腦、個人數位助理(Personal Data Assistance,PDA)等可攜式電子機器要求小型化及輕量化。伴隨於此,該些電子機器中使用的半導體晶片(chip)的安裝空間亦受到嚴格限制,從而半導體晶片的高密度安裝成為課題。因此,近年來,藉由三維安裝技術,即,將半導體晶片彼此積層而將各半導體晶片間進行配線連接,來實現半導體封裝體的高密度安裝。Portable electronic devices such as mobile phones, notebook personal computers, and personal digital assistants (PDAs) require miniaturization and weight reduction. Along with this, the mounting space of semiconductor chips used in these electronic devices is also severely restricted, and high-density mounting of semiconductor wafers has become a problem. Therefore, in recent years, high-density mounting of a semiconductor package has been achieved by three-dimensional mounting technology, that is, by stacking semiconductor wafers and wiring the semiconductor wafers.

另外,現有的晶圓級封裝體(Wafer Level Package,WLP)是藉由以晶圓的狀態形成凸塊後,利用切割加以單片化而製作。然而,現有的WLP中難以增加接腳數,除此之外是以半導體晶片的背面露出的狀態安裝,故有半導體晶片容易產生缺損等問題。In addition, a conventional Wafer Level Package (WLP) is produced by forming a bump in a state of a wafer and then dicing it by dicing. However, in the conventional WLP, it is difficult to increase the number of pins, and in addition, since the back surface of the semiconductor wafer is exposed, the semiconductor wafer is likely to be defective.

因此,作為新的WLP,提出一種扇出(fan out)型WLP。扇出型WLP能夠增加接腳數,且藉由保護半導體晶片的端部,可防止半導體晶片的缺損等。Therefore, as a new WLP, a fan out type WLP is proposed. The fan-out type WLP can increase the number of pins, and by protecting the ends of the semiconductor wafer, it is possible to prevent the semiconductor wafer from being damaged or the like.

扇出型WLP的製造步驟中例如包括:於將多個半導體晶片排列於支撐玻璃基板上後,利用樹脂的密封材進行成形而形成加工基板後,在加工基板的一表面進行配線的步驟;以及形成焊料凸塊的步驟等。The manufacturing process of the fan-out type WLP includes, after arranging a plurality of semiconductor wafers on a supporting glass substrate, forming a processed substrate by a resin sealing material, and then performing wiring on one surface of the processed substrate; A step of forming a solder bump or the like.

[發明所欲解決之課題] 且說,包括加工基板與支撐玻璃基板的積層體於扇出型WLP的製造步驟中在支撐玻璃基板側與搬送輸送機接觸的狀態下沿水平方向搬送。另外,於由機器臂等握持支撐玻璃基板的端緣部的狀態下進行搬送。[Problems to be Solved by the Invention] In the manufacturing process of the fan-out type WLP, the laminated body including the processed substrate and the supporting glass substrate is conveyed in the horizontal direction while the supporting glass substrate side is in contact with the conveying conveyor. In addition, the conveyance is performed in a state where the end edge portion of the supporting glass substrate is held by the robot arm or the like.

但是,支撐玻璃基板在積層體的搬送時容易受到來自搬送輸送機或機器臂的機械性衝擊。而且,若支撐玻璃基板受到機械性衝擊,則有時支撐玻璃基板產生裂紋,且以所述裂紋為起點支撐玻璃基板發生破損。However, the supporting glass substrate is easily subjected to mechanical impact from the conveying conveyor or the robot arm during conveyance of the laminated body. Further, when the supporting glass substrate is mechanically impacted, cracks may occur in the supporting glass substrate, and the glass substrate may be damaged by the crack as a starting point.

本發明是鑒於所述情況而成者,其技術性課題在於創造一種於扇出型WLP的製造步驟中在積層體的搬送時不易產生裂紋的支撐玻璃基板。 [解決課題之手段]The present invention has been made in view of the above circumstances, and a technical object is to create a supporting glass substrate which is less likely to cause cracks during the conveyance of the laminated body in the manufacturing process of the fan-out type WLP. [Means for solving the problem]

本發明者反覆進行了各種實驗,結果發現,選擇鹼性矽酸鋁玻璃作為支撐玻璃基板,並且嚴密地限制該鹼性矽酸鋁玻璃的玻璃組成範圍,並提高裂紋阻力,藉此可解決所述技術性課題,從而提出本發明。即,本發明的支撐玻璃基板用以支撐加工基板,且所述支撐玻璃基板的特徵在於:作為玻璃組成,以質量%計含有45%~70%的SiO2 、超過10.5%~35%的Al2 O3 、0%~20%的B2 O3 、5%~25%的Na2 O、0%~10%的K2 O、1%~10%的MgO、以及0%~5%的ZnO,且裂紋阻力為500 gf以上。此處,所謂「裂紋阻力」是指裂紋產生率為50%的負荷。「裂紋產生率」是指以如下方式測定而得的值。首先,於保持為濕度30%、溫度25℃的恒溫恒濕槽內,將設定為規定負荷的維氏壓頭朝玻璃表面(光學研磨面)打入15秒,於所述15秒後對自壓痕的四角產生的裂紋的數量進行計數(設為一個壓痕最大為4)。如此,將壓頭打入20次,於求出總裂紋產生數後,藉由(總裂紋產生數/80)×100的式子求出。裂紋阻力的測定裝置例如可使用未來科技(Future Tech)公司製造的幕太維氏(multi Vickers)硬度計FLC-50VX。The inventors of the present invention conducted various experiments and found that basic aluminum silicate glass was selected as the supporting glass substrate, and the glass composition range of the basic aluminum silicate glass was strictly restricted, and the crack resistance was improved, thereby solving the problem. The present invention has been made in view of the technical problems. That is, the supporting glass substrate of the present invention is for supporting a processed substrate, and the supporting glass substrate is characterized in that, as a glass composition, 45% to 70% of SiO 2 and more than 10.5% to 35% of Al are contained by mass%. 2 O 3 , 0% to 20% B 2 O 3 , 5% to 25% Na 2 O, 0% to 10% K 2 O, 1% to 10% MgO, and 0% to 5% ZnO, and the crack resistance is 500 gf or more. Here, the "crack resistance" means a load having a crack generation rate of 50%. The "crack generation rate" refers to a value measured as follows. First, in a constant temperature and humidity chamber maintained at a humidity of 30% and a temperature of 25 ° C, a Vickers indenter set to a predetermined load was driven into the glass surface (optical polishing surface) for 15 seconds, and after 15 seconds, The number of cracks generated at the four corners of the indentation was counted (set to an indentation of up to 4). In this way, the indenter was driven 20 times, and after the total number of cracks was found, it was obtained by the equation (the total number of generated cracks / 80) × 100. As the measuring device for the crack resistance, for example, a multi Vickers hardness meter FLC-50VX manufactured by Future Tech Co., Ltd. can be used.

第二,本發明的支撐玻璃基板較佳為作為玻璃組成,以質量%計含有50%~67%的SiO2 、19.7%~33%的Al2 O3 、0%~15%的B2 O3 、5%~20%的Na2 O、0%~3%的K2 O、1%~5.5%的MgO、以及0%~3%的ZnO,且裂紋阻力為700 gf以上。Secondly, the supporting glass substrate of the present invention preferably has a glass composition containing 50% to 67% of SiO 2 , 19.7% to 33% of Al 2 O 3 , and 0% to 15% of B 2 O by mass%. 3 , 5% to 20% of Na 2 O, 0% to 3% of K 2 O, 1% to 5.5% of MgO, and 0% to 3% of ZnO, and the crack resistance is 700 gf or more.

第三,本發明的支撐玻璃基板較佳為在20℃~220℃的溫度範圍內的平均線熱膨脹係數為40×10-7 /℃以上且120×10-7 /℃以下。據此,於在加工基板內對半導體晶片與密封材的比例進行變更的情況下,容易使加工基板與支撐玻璃基板的線熱膨脹係數嚴密地匹配。而且,若兩者的線熱膨脹係數相匹配,則於加工處理時容易抑制加工基板的尺寸變化(尤其是翹曲變形)。結果能夠在加工基板的一表面進行高密度配線,且亦可準確地形成焊料凸塊。此處,「在20℃~220℃的溫度範圍內的平均線熱膨脹係數」可利用膨脹計(dilatometer)進行測定。Third, the supporting glass substrate of the present invention preferably has an average linear thermal expansion coefficient in a temperature range of from 20 ° C to 220 ° C of 40 × 10 -7 / ° C or more and 120 × 10 -7 / ° C or less. Accordingly, when the ratio of the semiconductor wafer to the sealing material is changed in the processed substrate, the linear thermal expansion coefficient of the processed substrate and the supporting glass substrate is easily matched. Further, if the linear thermal expansion coefficients of the two are matched, it is easy to suppress dimensional change (especially warpage deformation) of the processed substrate during the processing. As a result, high-density wiring can be performed on one surface of the processed substrate, and solder bumps can be accurately formed. Here, the "average linear thermal expansion coefficient in a temperature range of 20 ° C to 220 ° C" can be measured by a dilatometer.

第四,本發明的支撐玻璃基板較佳為在20℃~260℃的溫度範圍內的平均線熱膨脹係數為40×10-7 /℃以上且120×10-7 /℃以下。此處,「在20℃~260℃的溫度範圍內的平均線熱膨脹係數」可利用膨脹計進行測定。Fourth, the supporting glass substrate of the present invention preferably has an average linear thermal expansion coefficient in a temperature range of from 20 ° C to 260 ° C of 40 × 10 -7 / ° C or more and 120 × 10 -7 / ° C or less. Here, the "average linear thermal expansion coefficient in a temperature range of 20 ° C to 260 ° C" can be measured by a dilatometer.

第五,本發明的支撐玻璃基板較佳為在30℃~380℃的溫度範圍內的平均線熱膨脹係數為42×10-7 /℃以上且125×10-7 /℃以下。此處,「在30℃~380℃的溫度範圍內的平均線熱膨脹係數」可利用膨脹計進行測定。Fifth, the supporting glass substrate of the present invention preferably has an average linear thermal expansion coefficient in a temperature range of from 30 ° C to 380 ° C of 42 × 10 -7 / ° C or more and 125 × 10 -7 / ° C or less. Here, the "average linear thermal expansion coefficient in a temperature range of 30 ° C to 380 ° C" can be measured by a dilatometer.

第六,本發明的支撐玻璃基板較佳為具有直徑100 mm~500 mm的晶圓形狀或大致圓板形狀,板厚小於2.0 mm,整體板厚偏差(Total Thickness Variation,TTV)為5 μm以下,且翹曲量為60 μm以下。此處,「翹曲量」是指支撐玻璃基板整體中的最高位點與最小平方焦點面之間的最大距離的絕對值、和最低位點與最小平方焦點面的絕對值的合計,例如可藉由神鋼(KOBELCO)科研公司製造的彎曲/翹曲(Bow/Warp)測定裝置SBW-331M/Ld進行測定。Sixth, the supporting glass substrate of the present invention preferably has a wafer shape or a substantially circular plate shape with a diameter of 100 mm to 500 mm, a plate thickness of less than 2.0 mm, and a total thickness variation (TTV) of 5 μm or less. And the amount of warpage is 60 μm or less. Here, the "warpage amount" refers to the sum of the absolute value of the maximum distance between the highest point and the least squared focal plane in the entire supporting glass substrate, and the absolute value of the lowest point and the least squared focal plane, for example, The measurement was carried out by a Bow/Warp measuring device SBW-331M/Ld manufactured by KOBELCO Research Co., Ltd.

第七,本發明的積層體較佳為至少包括加工基板及用以支撐加工基板的支撐玻璃基板,且支撐玻璃基板為所述支撐玻璃基板。Seventh, the laminated body of the present invention preferably includes at least a processed substrate and a supporting glass substrate for supporting the processed substrate, and the supporting glass substrate is the supporting glass substrate.

第八,本發明的積層體較佳為加工基板至少包括利用密封材進行了成形的半導體晶片。Eighth, the laminated body of the present invention preferably has a processed substrate including at least a semiconductor wafer formed by a sealing material.

第九,本發明的半導體封裝體的製造方法較佳為包括:準備至少包括加工基板及用以支撐加工基板的支撐玻璃基板的積層體的步驟;以及對加工基板進行加工處理的步驟,並且支撐玻璃基板為所述支撐玻璃基板。Ninth, the manufacturing method of the semiconductor package of the present invention preferably includes: a step of preparing a laminate including at least a processed substrate and a supporting glass substrate for supporting the processed substrate; and a step of processing the processed substrate, and supporting The glass substrate is the supporting glass substrate.

第十,本發明的半導體封裝體的製造方法較佳為加工處理包括在加工基板的一表面進行配線的步驟。Tenth, in the method of manufacturing the semiconductor package of the present invention, it is preferable that the processing includes the step of wiring on one surface of the processed substrate.

第十一,本發明的半導體封裝體的製造方法較佳為加工處理包括在加工基板的一表面形成焊料凸塊的步驟。Eleventh, in the method of fabricating the semiconductor package of the present invention, the processing includes the step of forming solder bumps on a surface of the processed substrate.

第十二,本發明的半導體封裝體較佳為利用所述半導體封裝體的製造方法製作。Twelfth, the semiconductor package of the present invention is preferably produced by the method of manufacturing the semiconductor package.

第十三,本發明的電子機器較佳為包括半導體封裝體,且半導體封裝體為所述半導體封裝體。Thirteenth, the electronic device of the present invention preferably includes a semiconductor package, and the semiconductor package is the semiconductor package.

本發明的支撐玻璃基板的特徵在於:作為玻璃組成,以質量%計含有45%~70%的SiO2 、超過10.5%~35%的Al2 O3 、0%~20%的B2 O3 、5%~25%的Na2 O、0%~10%的K2 O、1%~10%的MgO、以及0%~5%的ZnO。以下表示如所述般限定各成分的含量的理由。再者,各成分的含量的說明中,%表達是表示質量%。The supporting glass substrate of the present invention is characterized in that it contains 45% to 70% of SiO 2 , more than 10.5% to 35% of Al 2 O 3 , and 0% to 20% of B 2 O 3 as a glass composition. 5% to 25% of Na 2 O, 0% to 10% of K 2 O, 1% to 10% of MgO, and 0% to 5% of ZnO. The reason for limiting the content of each component as described above is shown below. In addition, in the description of the content of each component, the % expression means the mass %.

SiO2 是形成玻璃的骨架的主成分。若SiO2 的含量過少,則楊氏模量、耐酸性容易下降。但是,若SiO2 的含量過多,則高溫黏度增高,熔融性、成形性容易下降,除此之外白矽石(cristobalite)等的失透結晶容易析出,液相溫度容易上升。因此,SiO2 的下限範圍為45%以上,較佳為47%以上、尤其是49%以上,上限範圍為70%以下,較佳為68%以下、66%以下、尤其是65%以下,於使熔融性優先的情況下,為64%以下、63%以下、尤其是62%以下。SiO 2 is a main component of the skeleton forming the glass. When the content of SiO 2 is too small, the Young's modulus and acid resistance are liable to lower. However, when the content of SiO 2 is too large, the high-temperature viscosity is increased, and the meltability and moldability are liable to be lowered. In addition, devitrified crystals such as cristobalite are easily precipitated, and the liquidus temperature is likely to rise. Therefore, the lower limit range of SiO 2 is 45% or more, preferably 47% or more, particularly 49% or more, and the upper limit is 70% or less, preferably 68% or less, 66% or less, and especially 65% or less. When the meltability is prioritized, it is 64% or less, 63% or less, and particularly 62% or less.

Al2 O3 是提高裂紋阻力的成分。且是抑制分相、失透的成分。但是,若Al2 O3 的含量過多,則高溫黏度增高,熔融性與成形性容易下降。因此,Al2 O3 的下限範圍超過10.5%,較佳為11%以上、13%以上、15%以上、17%以上、尤其是19.7%以上,上限範圍為35%以下,較佳為30%以下,於使熔融性、成形性優先的情況下,為25%以下、尤其是20%以下。Al 2 O 3 is a component that increases the crack resistance. It is a component that inhibits phase separation and devitrification. However, when the content of Al 2 O 3 is too large, the high-temperature viscosity is increased, and the meltability and moldability are liable to lower. Therefore, the lower limit range of Al 2 O 3 is more than 10.5%, preferably 11% or more, 13% or more, 15% or more, 17% or more, especially 19.7% or more, and the upper limit is 35% or less, preferably 30%. Hereinafter, when the meltability and moldability are prioritized, it is 25% or less, particularly 20% or less.

B2 O3 是提高熔融性、耐失透性的成分,且為改善裂紋阻力的成分。但是,若B2 O3 的含量過多,則楊氏模量、耐酸性容易下降。因此,B2 O3 的下限範圍為0%以上,較佳為1%以上、2%以上、3%以上、尤其是4%以上,上限範圍為20%以下,較佳為15%以下、13%以下、11%以下、尤其是9%以下。B 2 O 3 is a component which improves meltability and devitrification resistance, and is a component which improves crack resistance. However, when the content of B 2 O 3 is too large, the Young's modulus and acid resistance are liable to lower. Therefore, the lower limit range of B 2 O 3 is 0% or more, preferably 1% or more, 2% or more, 3% or more, especially 4% or more, and the upper limit is 20% or less, preferably 15% or less, 13 % or less, 11% or less, especially 9% or less.

Na2 O是用以調整線熱膨脹係數的重要的成分,且是有助於玻璃原料的初期的熔融的成分。但是,若Na2 O的含量過多,則有線熱膨脹係數不合理地增高之虞。因此,Na2 O的下限範圍為5%以上,較佳為6%以上、7%以上、8%以上、尤其是9%以上,上限範圍為25%以下,較佳為23%以下、21%以下、尤其是18%以下。Na 2 O is an important component for adjusting the linear thermal expansion coefficient, and is a component which contributes to the initial melting of the glass raw material. However, if the content of Na 2 O is too large, the coefficient of linear thermal expansion is unreasonably increased. Therefore, the lower limit of Na 2 O is 5% or more, preferably 6% or more, 7% or more, 8% or more, and especially 9% or more, and the upper limit is 25% or less, preferably 23% or less, 21%. The following, especially 18% or less.

K2 O是用以調整線熱膨脹係數的成分,且是有助於玻璃原料的初期的熔融的成分。但是,若K2 O的含量過多,則有線熱膨脹係數不合理地增高之虞。因此,K2 O的含量為0%~10%,較佳為0%~6%、0%~5%、0.1%~1.9%、尤其是0.2%~小於1%。K 2 O is a component for adjusting the linear thermal expansion coefficient and is a component which contributes to the initial melting of the glass raw material. However, if the content of K 2 O is too large, the coefficient of linear thermal expansion is unreasonably increased. Therefore, the content of K 2 O is from 0% to 10%, preferably from 0% to 6%, from 0% to 5%, from 0.1% to 1.9%, especially from 0.2% to less than 1%.

MgO是提高裂紋阻力的成分。另外是降低高溫黏性而提高熔融性的成分,且為鹼土類金屬氧化物中顯著提高楊氏模量的成分。但是,若MgO的含量變多,則耐失透性容易下降。因此,MgO的含量為1%~10%,較佳為1%~6%、1%~5.5%、2%~5%、尤其是3%~小於4%。MgO is a component that increases the crack resistance. Further, it is a component which lowers the high-temperature viscosity and improves the meltability, and is a component which significantly increases the Young's modulus in the alkaline earth metal oxide. However, when the content of MgO is increased, the devitrification resistance is liable to lower. Therefore, the content of MgO is from 1% to 10%, preferably from 1% to 6%, from 1% to 5.5%, from 2% to 5%, especially from 3% to less than 4%.

質量比(Al2 O3 +B2 O3 +MgO)/(Na2 O+K2 O)較佳為1.3以上、1.5以上、2.0以上、2.5以上、尤其是3.0以上。若質量比(Al2 O3 +B2 O3 +MgO)/(Na2 O+K2 O)過小,則裂紋阻力下降,或者容易受到損傷,支撐玻璃基板容易因裂紋發生破損。The mass ratio (Al 2 O 3 + B 2 O 3 + MgO) / (Na 2 O + K 2 O) is preferably 1.3 or more, 1.5 or more, 2.0 or more, 2.5 or more, and particularly preferably 3.0 or more. When the mass ratio (Al 2 O 3 + B 2 O 3 + MgO) / (Na 2 O + K 2 O) is too small, the crack resistance is lowered or is easily damaged, and the supporting glass substrate is liable to be broken by cracks.

ZnO是降低高溫黏性而顯著提高熔融性、成形性的成分,且是提高耐候性的成分。但是,若ZnO的含量過多,則玻璃容易失透。因此,ZnO的含量為0%~5%,較佳為0%~4%、0.1%~2%、尤其是0.3%~1.5%。ZnO is a component that lowers high-temperature viscosity and remarkably improves meltability and formability, and is a component that improves weather resistance. However, if the content of ZnO is too large, the glass is easily devitrified. Therefore, the content of ZnO is from 0% to 5%, preferably from 0% to 4%, from 0.1% to 2%, especially from 0.3% to 1.5%.

除所述成分以外,亦可導入其他成分作為任意成分。再者,自的確享有本發明的效果的觀點考慮,所述成分以外的其他成分的含量較佳為以合計量計為25%以下、20%以下、15%以下、10%以下、尤其是5%以下。In addition to the above components, other components may be introduced as optional components. In addition, the content of the other components other than the component is preferably 25% or less, 20% or less, 15% or less, 10% or less, and especially 5 in terms of the total effect of the present invention. %the following.

Li2 O是降低高溫黏性而顯著提高熔融性、成形性的成分。且是提高楊氏模量的成分。但是,若Li2 O的含量過多,則玻璃容易失透。因此,Li2 O的含量較佳為0%~7%、0%~3%、0%~1%、尤其是0.01%~0.1%。Li 2 O is a component which lowers high-temperature viscosity and remarkably improves meltability and formability. It is a component that increases the Young's modulus. However, if the content of Li 2 O is too large, the glass is easily devitrified. Therefore, the content of Li 2 O is preferably 0% to 7%, 0% to 3%, 0% to 1%, particularly 0.01% to 0.1%.

CaO是降低高溫黏性而顯著提高熔融性、成形性的成分。且是鹼土類金屬氧化物中因導入原料相對廉價故使原料成本低廉化的成分。但是,若CaO的含量過多,則玻璃容易失透。因此,CaO的含量較佳為0%~10%、1%~8%、3%~8%、2%~6%、尤其是2%~5%。CaO is a component which lowers high-temperature viscosity and remarkably improves meltability and formability. Further, in the alkaline earth metal oxide, since the raw material to be introduced is relatively inexpensive, the raw material cost is reduced. However, if the content of CaO is too large, the glass is easily devitrified. Therefore, the content of CaO is preferably 0% to 10%, 1% to 8%, 3% to 8%, 2% to 6%, particularly 2% to 5%.

SrO是抑制分相的成分,且是提高耐失透性的成分。但是,若SrO的含量過多,則玻璃容易失透。因此,SrO的含量較佳為0%~20%、0%~15%、0%~9%、0%~5%、0%~4%、0%~3%、0%~2%、尤其是0%~小於1%。再者,於使耐失透性的提高優先的情況下,SrO的較佳的下限範圍為0.1%以上、1%以上、2%以上、4%以上、尤其是7%以上。SrO is a component that suppresses phase separation and is a component that improves resistance to devitrification. However, if the content of SrO is too large, the glass is easily devitrified. Therefore, the content of SrO is preferably 0% to 20%, 0% to 15%, 0% to 9%, 0% to 5%, 0% to 4%, 0% to 3%, 0% to 2%, Especially 0% to less than 1%. Further, in the case where the improvement of the devitrification resistance is prioritized, the preferred lower limit range of SrO is 0.1% or more, 1% or more, 2% or more, 4% or more, and particularly 7% or more.

BaO是提高耐失透性的成分。但是,若BaO的含量過多,則玻璃容易失透。因此,BaO的含量較佳為0%~20%、0%~14%、0%~9%、0%~5%、0%~4%、0%~3%、0%~2%、尤其是0%~小於1%。再者,於使耐失透性的提高優先的情況下,BaO的較佳的下限範圍為0.1%以上、1%以上、尤其是3%以上。BaO is a component that improves resistance to devitrification. However, if the content of BaO is too large, the glass is easily devitrified. Therefore, the content of BaO is preferably 0% to 20%, 0% to 14%, 0% to 9%, 0% to 5%, 0% to 4%, 0% to 3%, 0% to 2%, Especially 0% to less than 1%. Further, in the case where the improvement in devitrification resistance is prioritized, a preferred lower limit range of BaO is 0.1% or more, 1% or more, and particularly 3% or more.

Fe2 O3 是可作為雜質成分或澄清劑成分導入的成分。但是,若Fe2 O3 的含量過多,則有紫外線透過率下降之虞。即,若Fe2 O3 的含量過多,則有時難以經由樹脂層、剝離層來適當地進行加工基板與支撐玻璃基板的黏結與脫附。因此,Fe2 O3 的含量較佳為0.05%以下、0.03%以下、0.001%~0.02%、尤其是0.005%~0.01%。再者,本發明中提及的「Fe2 O3 」包含2價氧化鐵與3價氧化鐵,2價氧化鐵換算為Fe2 O3 ,而進行處理。關於其他氧化物,同樣地以表述的氧化物為基準而進行處理。Fe 2 O 3 is a component which can be introduced as an impurity component or a clarifier component. However, if the content of Fe 2 O 3 is too large, there is a possibility that the ultraviolet transmittance is lowered. In other words, when the content of Fe 2 O 3 is too large, it may be difficult to appropriately bond and debond the processed substrate and the supporting glass substrate via the resin layer or the release layer. Therefore, the content of Fe 2 O 3 is preferably 0.05% or less, 0.03% or less, 0.001% to 0.02%, particularly 0.005% to 0.01%. Further, the "Fe 2 O 3 " mentioned in the present invention contains divalent iron oxide and trivalent iron oxide, and the divalent iron oxide is converted into Fe 2 O 3 to be treated. The other oxides were treated in the same manner based on the oxides described.

作為澄清劑,As2 O3 有效地發揮作用,就環境的觀點而言,較佳為極力減少該些成分。As2 O3 的含量較佳為1%以下、0.5%以下、尤其是0.1%以下,理想的是實質不含有。此處,所謂「實質不含有As2 O3 」是指玻璃組成中的As2 O3 的含量小於0.05%的情況。As a clarifying agent, As 2 O 3 functions effectively, and from the viewpoint of the environment, it is preferred to reduce these components as much as possible. The content of As 2 O 3 is preferably 1% or less, 0.5% or less, or particularly 0.1% or less, and is preferably substantially not contained. Here, "substantially does not contain As 2 O 3 " means that the content of As 2 O 3 in the glass composition is less than 0.05%.

Sb2 O3 是在低溫區域具有良好的澄清作用的成分。Sb2 O3 的含量較佳為0%~1%、0.001%~1%、0.01%~0.9%、尤其是0.05%~0.7%。若Sb2 O3 的含量過多,則玻璃容易著色。Sb 2 O 3 is a component having a good clarifying effect in a low temperature region. The content of Sb 2 O 3 is preferably from 0% to 1%, from 0.001% to 1%, from 0.01% to 0.9%, especially from 0.05% to 0.7%. When the content of Sb 2 O 3 is too large, the glass is easily colored.

SnO2 是在高溫區域具有良好的澄清作用的成分,且是使高溫黏性下降的成分。SnO2 的含量較佳為0%~1%、0.001%~1%、0.01%~0.9%、尤其是0.05%~0.7%。若SnO2 的含量過多,則SnO2 的失透結晶容易析出。再者,若SnO2 的含量過少,則難以享有所述效果。SnO 2 is a component which has a good clarifying action in a high temperature region, and is a component which lowers the viscosity at a high temperature. The content of SnO 2 is preferably 0% to 1%, 0.001% to 1%, 0.01% to 0.9%, particularly 0.05% to 0.7%. When the content of SnO 2 is too large, devitrified crystals of SnO 2 are easily precipitated. Further, if the content of SnO 2 is too small, it is difficult to enjoy the above effect.

SO3 是具有澄清作用的成分。SO3 的含量較佳為0%~1%、0.001%~1%、0.01%~0.5%、尤其是0.05%~0.3%。若SO3 的含量過多,則容易產生SO2 再沸(reboil)。SO 3 is a component having a clarifying effect. The content of SO 3 is preferably from 0% to 1%, from 0.001% to 1%, from 0.01% to 0.5%, especially from 0.05% to 0.3%. When the content of SO 3 is too large, SO 2 is easily reboiled.

進而,只要不損害玻璃特性,亦可分別導入F、C、或Al、Si等金屬粉末至1%左右作為澄清劑。而且,CeO2 等亦可導入1%左右,但需要留意紫外線透過率的下降。Further, as long as the glass characteristics are not impaired, F, C, or a metal powder such as Al or Si may be introduced to about 1% as a clarifying agent. Further, CeO 2 or the like may be introduced at about 1%, but it is necessary to pay attention to the decrease in the ultraviolet transmittance.

Cl是促進玻璃的熔融的成分。若向玻璃組成中導入Cl,則可實現熔融溫度的低溫化、澄清作用的促進,結果,容易達成熔融成本的低廉化、玻璃製造爐的長壽命化。但是,若Cl的含量過多,則有使玻璃製造爐周圍的金屬零件腐蝕之虞。因此,Cl的含量較佳為3%以下、1%以下、0.5%以下、尤其是0.1%以下。Cl is a component that promotes melting of the glass. When Cl is introduced into the glass composition, the melting temperature can be lowered and the clarification effect can be promoted. As a result, it is easy to achieve a reduction in the melting cost and a long life of the glass furnace. However, if the content of Cl is too large, there is a possibility that the metal parts around the glass manufacturing furnace are corroded. Therefore, the content of Cl is preferably 3% or less, 1% or less, 0.5% or less, and especially 0.1% or less.

P2 O5 是可抑制失透結晶的析出的成分。但是,若大量導入P2 O5 ,則玻璃容易分相。因此,P2 O5 的含量較佳為0%~15%、0%~2.5%、0%~1.5%、0%~0.5%、尤其是0.1%~0.3%。P 2 O 5 is a component which can suppress precipitation of devitrified crystals. However, if P 2 O 5 is introduced in a large amount, the glass is easily separated into phases. Therefore, the content of P 2 O 5 is preferably 0% to 15%, 0% to 2.5%, 0% to 1.5%, 0% to 0.5%, particularly preferably 0.1% to 0.3%.

TiO2 是降低高溫黏性並提高熔融性的成分,且是抑制曝曬作用(solarization)的成分。但是,若大量導入TiO2 ,則玻璃著色,透過率容易下降。因此,TiO2 的含量較佳為0%~5%、0%~3%、0%~1%、尤其是0%~0.02%。TiO 2 is a component that lowers high-temperature viscosity and improves meltability, and is a component that suppresses solarization. However, when TiO 2 is introduced in a large amount, the glass is colored, and the transmittance is liable to lower. Therefore, the content of TiO 2 is preferably 0% to 5%, 0% to 3%, 0% to 1%, particularly 0% to 0.02%.

ZrO2 是改善耐化學品性、楊氏模量的成分。但是,若大量導入ZrO2 ,則玻璃容易失透,而且導入原料為難熔解性,因而有未熔解的結晶性異物混入至製品基板之虞。因此,ZrO2 的含量較佳為0%~10%、0%~7%、0%~5%、0.001%~3%、0.01%~1%、尤其是0.1%~0.5%。ZrO 2 is a component that improves chemical resistance and Young's modulus. However, when ZrO 2 is introduced in a large amount, the glass is easily devitrified, and the introduced raw material is insoluble, so that unmelted crystalline foreign matter is mixed into the product substrate. Therefore, the content of ZrO 2 is preferably 0% to 10%, 0% to 7%, 0% to 5%, 0.001% to 3%, 0.01% to 1%, particularly preferably 0.1% to 0.5%.

Y2 O3 、Nb2 O5 、La2 O3 中具有提高應變點、楊氏模量等的作用。但是,若該些成分的含量分別為5%,尤其多於1%,則有原料成本、製品成本高漲之虞。Y 2 O 3 , Nb 2 O 5 , and La 2 O 3 have an effect of increasing the strain point, Young's modulus, and the like. However, if the content of these components is 5%, especially more than 1%, there is a problem that the raw material cost and the product cost are high.

本發明的支撐玻璃基板較佳為具有以下特性。The supporting glass substrate of the present invention preferably has the following characteristics.

裂紋阻力為500 gf以上,較佳為600 gf以上、700 gf以上、800 gf以上、900 gf以上、尤其是1000 gf以上。若裂紋阻力低,則於扇出型WLP的製造步驟中,由於來自搬送輸送機或機器臂的機械性衝擊,支撐玻璃基板產生裂紋,以所述裂紋為起點,支撐玻璃基板容易發生破損。The crack resistance is 500 gf or more, preferably 600 gf or more, 700 gf or more, 800 gf or more, 900 gf or more, and especially 1000 gf or more. When the crack resistance is low, in the manufacturing process of the fan-out type WLP, cracks are caused in the supporting glass substrate due to mechanical impact from the conveying conveyor or the machine arm, and the supporting glass substrate is likely to be broken by the crack as a starting point.

20℃~220℃的溫度範圍內的平均線熱膨脹係數較佳為40×10-7 /℃以上且120×10-7 /℃以下,更佳為超過50×10-7 /℃以上且110×10-7 /℃以下,進而佳為60×10-7 /℃以上且100×10-7 /℃以下,尤佳為70×10-7 /℃以上且95×10-7 /℃以下。若20℃~220℃的溫度範圍內的平均線熱膨脹係數為所述範圍外,則加工基板與支撐玻璃基板的線熱膨脹係數難以匹配。而且,若兩者的線熱膨脹係數不匹配,則加工處理時容易產生加工基板的尺寸變化(尤其是翹曲變形)。The average linear thermal expansion coefficient in the temperature range of 20 ° C to 220 ° C is preferably 40 × 10 -7 / ° C or more and 120 × 10 -7 / ° C or less, more preferably more than 50 × 10 -7 / ° C or more and 110 × 10 -7 / ° C or less, further preferably 60 × 10 -7 / ° C or more and 100 × 10 -7 / ° C or less, particularly preferably 70 × 10 -7 / ° C or more and 95 × 10 -7 / ° C or less. When the average linear thermal expansion coefficient in the temperature range of 20 ° C to 220 ° C is outside the above range, the linear thermal expansion coefficient of the processed substrate and the supporting glass substrate is difficult to match. Further, if the linear thermal expansion coefficients of the two do not match, dimensional changes (especially warpage deformation) of the processed substrate are likely to occur during the processing.

20℃~260℃的溫度範圍內的平均線熱膨脹係數較佳為40×10-7 /℃以上且120×10-7 /℃以下,更佳為超過50×10-7 /℃且110×10-7 /℃以下,進而佳為60×10-7 /℃以上且100×10-7 /℃以下,尤佳為70×10-7 /℃以上且95×10-7 /℃以下。若20℃~260℃的溫度範圍內的平均線熱膨脹係數為所述範圍外,則加工基板與支撐玻璃基板的線熱膨脹係數難以匹配。而且,若兩者的線熱膨脹係數不匹配,則加工處理時容易產生加工基板的尺寸變化(尤其是翹曲變形)。The average linear thermal expansion coefficient in the temperature range of 20 ° C to 260 ° C is preferably 40 × 10 -7 / ° C or more and 120 × 10 -7 / ° C or less, more preferably more than 50 × 10 -7 / ° C and 110 × 10 -7 / ° C or less, further preferably 60 × 10 -7 / ° C or more and 100 × 10 -7 / ° C or less, particularly preferably 70 × 10 -7 / ° C or more and 95 × 10 -7 / ° C or less. When the average linear thermal expansion coefficient in the temperature range of 20 ° C to 260 ° C is outside the above range, the linear thermal expansion coefficient of the processed substrate and the supporting glass substrate is difficult to match. Further, if the linear thermal expansion coefficients of the two do not match, dimensional changes (especially warpage deformation) of the processed substrate are likely to occur during the processing.

30℃~380℃的溫度範圍內的平均線熱膨脹係數較佳為42×10-7 /℃以上且125×10-7 /℃以下,更佳為超過50×10-7 /℃且110×10-7 /℃以下,進而佳為60×10-7 /℃以上且100×10-7 /℃以下,尤佳為70×10-7 /℃以上且95×10-7 /℃以下。若30℃~380℃的溫度範圍內的平均線熱膨脹係數為所述範圍外,則加工基板與支撐玻璃基板的線熱膨脹係數難以匹配。而且,若兩者的線熱膨脹係數不匹配,則加工處理時容易產生加工基板的尺寸變化(尤其是翹曲變形)。The average linear thermal expansion coefficient in the temperature range of 30 ° C to 380 ° C is preferably 42 × 10 -7 / ° C or more and 125 × 10 -7 / ° C or less, more preferably more than 50 × 10 -7 / ° C and 110 × 10 -7 / ° C or less, further preferably 60 × 10 -7 / ° C or more and 100 × 10 -7 / ° C or less, particularly preferably 70 × 10 -7 / ° C or more and 95 × 10 -7 / ° C or less. When the average linear thermal expansion coefficient in the temperature range of 30 ° C to 380 ° C is outside the above range, the linear thermal expansion coefficient of the processed substrate and the supporting glass substrate is difficult to match. Further, if the linear thermal expansion coefficients of the two do not match, dimensional changes (especially warpage deformation) of the processed substrate are likely to occur during the processing.

102.5 dPa·s下的溫度較佳為1680℃以下、1620℃以下、1580℃以下、1550℃以下、1520℃以下、尤其是1500℃以下。若102.5 dPa·s下的溫度變高,則熔融性下降,玻璃基板的製造成本高漲。此處,「102.5 dPa·s下的溫度」能夠利用鉑球提拉法測定。再者,102.5 dPa·s下的溫度相當於熔融溫度,該溫度越低,熔融性越提高。The temperature at 10 2.5 dPa·s is preferably 1680 ° C or lower, 1620 ° C or lower, 1580 ° C or lower, 1550 ° C or lower, 1520 ° C or lower, or particularly 1500 ° C or lower. When the temperature at 10 2.5 dPa·s becomes high, the meltability is lowered, and the production cost of the glass substrate is high. Here, "the temperature at 10 2.5 dPa·s" can be measured by a platinum ball pulling method. Further, the temperature at 10 2.5 dPa·s corresponds to the melting temperature, and the lower the temperature, the higher the meltability.

液相溫度較佳為小於1300℃、1200℃以下、1100℃以下、1050℃以下、1000℃以下、尤其是950℃以下。液相溫度下的黏度較佳為10000 dPa·s以上、30000 dPa·s以上、60000 dPa·s以上、100000 dPa·s以上、200000 dPa·s以上、300000 dPa·s以上、500000 dPa·s以上、800000 dPa·s以上、尤其是1000000 dPa·s以上。如此,由於成形時失透結晶難以析出,因此容易利用下拉法、尤其是溢流下拉法將玻璃基板成形。此處,「液相溫度」能夠藉由將通過標準篩30目(500 μm)而殘留於50目(300 μm)的玻璃粉末裝入鉑舟後,於溫度梯度爐中保持24小時,並測定結晶析出的溫度而算出。「液相溫度下的黏度」能夠利用鉑球提拉法測定。再者,液相溫度下的黏度為成形性的指標,液相溫度下的黏度越高,成形性越提高。The liquidus temperature is preferably less than 1300 ° C, 1200 ° C or less, 1100 ° C or less, 1050 ° C or less, 1000 ° C or less, and especially 950 ° C or less. The viscosity at the liquidus temperature is preferably 10,000 dPa·s or more, 30,000 dPa·s or more, 60,000 dPa·s or more, 100,000 dPa·s or more, 200,000 dPa·s or more, 300,000 dPa·s or more, and 500,000 dPa·s or more. , 800,000 dPa·s or more, especially 1,000,000 dPa·s or more. As described above, since the devitrified crystal is hardly precipitated during molding, it is easy to form the glass substrate by a down-draw method, in particular, an overflow down-draw method. Here, the "liquidus temperature" can be filled in a platinum boat by charging a glass powder remaining at 50 mesh (300 μm) through a standard sieve of 30 mesh (500 μm), and maintained in a temperature gradient furnace for 24 hours. The temperature at which the crystal was precipitated was calculated. The "viscosity at the liquidus temperature" can be measured by a platinum ball pulling method. Further, the viscosity at the liquidus temperature is an index of formability, and the higher the viscosity at the liquidus temperature, the more the formability is improved.

本發明的支撐玻璃基板中,楊氏模量較佳為65 GPa以上、68 GPa以上、70 GPa以上、72 GPa以上、73 GPa以上、尤其是74 GPa以上。若楊氏模量過低,則難以維持積層體的剛性,且容易產生加工基板的變形、翹曲、破損等。此處,「楊氏模量」是指利用彎曲共振法而測定的值。In the supporting glass substrate of the present invention, the Young's modulus is preferably 65 GPa or more, 68 GPa or more, 70 GPa or more, 72 GPa or more, 73 GPa or more, and particularly 74 GPa or more. When the Young's modulus is too low, it is difficult to maintain the rigidity of the laminated body, and deformation, warpage, breakage, and the like of the processed substrate are likely to occur. Here, "Young's modulus" means a value measured by a bending resonance method.

本發明的支撐玻璃基板較佳為具有以下形狀。The support glass substrate of the present invention preferably has the following shape.

本發明的支撐玻璃基板較佳為大致圓板狀或晶圓狀,其直徑較佳為100 mm以上且500 mm以下、尤其是150 mm以上且450 mm以下。如此,容易適用於扇出型WLP的製造步驟。亦可視需要加工成除此以外的形狀、例如矩形等形狀。The supporting glass substrate of the present invention is preferably substantially disk-shaped or wafer-shaped, and its diameter is preferably 100 mm or more and 500 mm or less, particularly 150 mm or more and 450 mm or less. Thus, it is easy to apply to the manufacturing process of the fan-out type WLP. It is also possible to process into a shape other than this, for example, a shape such as a rectangle.

正圓度較佳為1 mm以下、0.1 mm以下、0.05 mm以下、尤其是0.03 mm以下。正圓度越小,越容易適用於扇出型WLP的製造步驟。再者,「正圓度」是除了凹口部以外從晶圓的外形的最大值減去最小值所得的值。The roundness is preferably 1 mm or less, 0.1 mm or less, 0.05 mm or less, or particularly 0.03 mm or less. The smaller the roundness, the easier it is to apply to the manufacturing steps of the fan-out type WLP. In addition, the "roundness" is a value obtained by subtracting the minimum value from the maximum value of the outer shape of the wafer other than the notch portion.

板厚較佳為小於2.0 mm、1.5 mm以下、1.2 mm以下、1.1 mm以下、1.0 mm以下、尤其是0.9 mm以下。板厚越薄,積層體的質量越變輕,故操作性提高。另一方面,若板厚過薄,則支撐玻璃基板本身的強度下降,變得難以發揮作為支撐基板的功能。因此,板厚較佳為0.1 mm以上、0.2 mm以上、0.3 mm以上、0.4 mm以上、0.5 mm以上、0.6 mm以上、尤其是超過0.7 mm。The plate thickness is preferably less than 2.0 mm, less than 1.5 mm, less than 1.2 mm, less than 1.1 mm, less than 1.0 mm, especially less than 0.9 mm. The thinner the plate thickness, the lighter the quality of the laminate, and the operability is improved. On the other hand, when the thickness is too small, the strength of the supporting glass substrate itself is lowered, and it becomes difficult to exhibit the function as a supporting substrate. Therefore, the sheet thickness is preferably 0.1 mm or more, 0.2 mm or more, 0.3 mm or more, 0.4 mm or more, 0.5 mm or more, 0.6 mm or more, and particularly more than 0.7 mm.

整體板厚偏差(TTV)較佳為5 μm以下、4 μm以下、3 μm以下、2 μm以下、1μm以下、尤其是0.1 μm~小於1 μm。另外,算術平均粗糙度Ra較佳為20 nm以下、10 nm以下、5 nm以下、2 nm以下、1 nm以下、尤其是0.5 nm以下。表面精度越高,越可容易提高加工處理的精度。因尤其可提高配線精度,故可進行高密度的配線。另外,支撐玻璃基板的強度提高,支撐玻璃基板及積層體不易破損。進而,可增加支撐玻璃基板的再利用次數。再者,「算術平均粗糙度Ra」可藉由觸針式表面粗糙度計或原子力顯微鏡(atomic force microscope,AFM)進行測定。The overall thickness deviation (TTV) is preferably 5 μm or less, 4 μm or less, 3 μm or less, 2 μm or less, 1 μm or less, and particularly preferably 0.1 μm to less than 1 μm. Further, the arithmetic mean roughness Ra is preferably 20 nm or less, 10 nm or less, 5 nm or less, 2 nm or less, 1 nm or less, or particularly 0.5 nm or less. The higher the surface precision, the easier it is to improve the processing accuracy. Since wiring accuracy can be improved in particular, high-density wiring can be performed. Further, the strength of the supporting glass substrate is improved, and the supporting glass substrate and the laminated body are less likely to be damaged. Further, the number of reuse of the supporting glass substrate can be increased. Further, the "arithmetic average roughness Ra" can be measured by a stylus type surface roughness meter or an atomic force microscope (AFM).

本發明的支撐玻璃基板較佳為在利用溢流下拉法成形後,對表面進行研磨而成。如此,容易將整體板厚偏差(TTV)限制在小於2.0 μm、1.5 μm以下、1.0 μm以下、尤其是0.1 μm~小於1.0 μm。The support glass substrate of the present invention is preferably formed by grinding a surface after being formed by an overflow down-draw method. Thus, it is easy to limit the overall thickness deviation (TTV) to less than 2.0 μm, 1.5 μm or less, 1.0 μm or less, and particularly preferably 0.1 μm to less than 1.0 μm.

翹曲量較佳為60 μm以下、55 μm以下、50 μm以下、1 μm~45 μm、尤其是5 μm~40 μm。翹曲量越小,越容易提高加工處理的精度。因尤其可提高配線精度,故可進行高密度的配線。The amount of warpage is preferably 60 μm or less, 55 μm or less, 50 μm or less, 1 μm to 45 μm, or particularly 5 μm to 40 μm. The smaller the amount of warpage, the easier it is to improve the accuracy of the processing. Since wiring accuracy can be improved in particular, high-density wiring can be performed.

本發明的支撐玻璃基板較佳為具有凹口部(凹口形狀的對準部),凹口部的深度更佳為於平面視時為大致圓形狀或大致V槽形狀。藉此,使定位銷等定位構件抵接於支撐玻璃基板的凹口部,容易對支撐玻璃基板進行位置固定。結果,支撐玻璃基板與加工基板的對準變得容易。尤其,若亦於加工基板上形成凹口部且使定位構件抵接,則積層體整體的對準變得容易。再者,凹口部由於抵接有定位構件,因此容易產生裂紋,但本發明的支撐玻璃基板由於裂紋阻力高,因此於具有凹口部的情況下尤其有效。The supporting glass substrate of the present invention preferably has a notch portion (an aligning portion having a notch shape), and the depth of the notch portion is preferably a substantially circular shape or a substantially V-groove shape in plan view. Thereby, the positioning member such as the positioning pin is brought into contact with the notch portion of the supporting glass substrate, and the supporting glass substrate is easily fixed in position. As a result, alignment of the supporting glass substrate with the processed substrate becomes easy. In particular, if a notch portion is formed on the processed substrate and the positioning member is brought into contact with each other, alignment of the entire laminated body becomes easy. Further, since the notch portion is in contact with the positioning member, cracks are likely to occur. However, since the supporting glass substrate of the present invention has high crack resistance, it is particularly effective when it has a notch portion.

若將定位構件抵接於支撐玻璃基板的凹口部,則應力容易集中於凹口部,以凹口部為起點,支撐玻璃基板容易發生破損。尤其,於支撐玻璃基板因外力而發生彎曲時,所述傾向變得顯著。因此,本發明的支撐玻璃基板較佳為凹口部的表面與端面交差的端緣區域的全部或一部分被倒角。藉此,可有效地避免以凹口部為起點的破損。When the positioning member is brought into contact with the notch portion of the supporting glass substrate, the stress tends to concentrate on the notch portion, and the supporting glass substrate is likely to be broken by using the notch portion as a starting point. In particular, when the supporting glass substrate is bent by an external force, the tendency becomes remarkable. Therefore, in the support glass substrate of the present invention, it is preferable that all or a part of the edge region where the surface of the notch portion intersects the end surface is chamfered. Thereby, damage from the notch portion as a starting point can be effectively avoided.

本發明的支撐玻璃基板的凹口部的表面與端面交差的端緣區域的全部或一部分被倒角,較佳為凹口部的表面與端面交差的端緣區域的50%以上被倒角,更佳為凹口部的表面與端面交差的端緣區域的90%以上被倒角,進而佳為凹口部的表面與端面交差的端緣區域全部被倒角。凹口部中被倒角的區域越大,越能夠減少以凹口部為起點的破損的概率。All or a part of the edge region of the notch portion of the supporting glass substrate of the present invention which intersects the end surface is chamfered, and it is preferable that 50% or more of the edge region where the surface of the notch portion intersects the end surface is chamfered. More preferably, 90% or more of the edge region where the surface of the notch portion intersects the end surface is chamfered, and it is preferable that the edge region where the surface of the notch portion intersects the end surface is chamfered. The larger the area of the notch that is chamfered, the more the probability of breakage starting from the notch can be reduced.

凹口部的表面方向的倒角寬度較佳為50 μm~900 μm、200 μm~800 μm、300 μm~700 μm、400 μm~650 μm、尤其是500 μm~600 μm。若凹口部的表面方向的倒角寬度過小,則以凹口部為起點,支撐玻璃基板容易發生破損。另一方面,若凹口部的表面方向的倒角寬度過大,則倒角效率下降,支撐玻璃基板的製造成本容易高漲。The chamfer width in the surface direction of the notch portion is preferably 50 μm to 900 μm, 200 μm to 800 μm, 300 μm to 700 μm, 400 μm to 650 μm, or particularly 500 μm to 600 μm. When the chamfer width in the surface direction of the notch portion is too small, the support glass substrate is likely to be damaged by using the notch portion as a starting point. On the other hand, if the chamfer width in the surface direction of the notch portion is too large, the chamfering efficiency is lowered, and the manufacturing cost of supporting the glass substrate is likely to increase.

凹口部的板厚方向的倒角寬度較佳為板厚的5%~80%、20%~75%、30%~70%、35%~65%、尤其是40%~60%。若凹口部的板厚方向的倒角寬度過小,則以凹口部為起點,支撐玻璃基板容易發生破損。另一方面,若凹口部的板厚方向的倒角寬度過大,則外力容易集中於凹口部的端面,以凹口部的端面為起點,支撐玻璃基板容易發生破損。The chamfer width in the thickness direction of the notch portion is preferably 5% to 80%, 20% to 75%, 30% to 70%, 35% to 65%, particularly 40% to 60% of the sheet thickness. When the chamfer width in the thickness direction of the notch portion is too small, the support glass substrate is likely to be broken by using the notch portion as a starting point. On the other hand, when the chamfer width in the thickness direction of the notch portion is too large, the external force tends to concentrate on the end surface of the notch portion, and the end surface of the notch portion serves as a starting point, and the supporting glass substrate is likely to be damaged.

本發明的支撐玻璃基板較佳為於表面形成(做標記(marking))有二維碼的資訊識別部(標記)。如此,可管理、認識支撐玻璃基板的生產資訊等(例如、玻璃基板的尺寸、線熱膨脹係數、批次、整體板厚偏差、製造者名、販賣者名)。再者,資訊辨別部通常形成於支撐玻璃基板的周邊區域,且以文字、記號等的形式由人的眼睛等來識別。或者,有時支撐玻璃基板的資訊辨別部亦藉由電荷耦合元件(Charge Coupled Device,CCD)相機等光學元件來自動地辨別。The support glass substrate of the present invention preferably has an information recognition portion (marker) formed on the surface (marking) with a two-dimensional code. In this way, it is possible to manage and recognize the production information and the like for supporting the glass substrate (for example, the size of the glass substrate, the linear thermal expansion coefficient, the batch, the overall thickness deviation, the manufacturer name, and the name of the vendor). Further, the information discriminating unit is usually formed in a peripheral region of the supporting glass substrate, and is recognized by a human eye or the like in the form of a character, a symbol, or the like. Alternatively, the information discriminating portion that supports the glass substrate may be automatically discriminated by an optical element such as a charge coupled device (CCD) camera.

資訊識別部可利用各種方法形成,但本發明中較佳為照射脈波雷射,對所述照射區域的玻璃進行剝蝕而形成資訊識別部,即藉由雷射剝蝕而形成資訊識別部。如此,可於照射區域的玻璃中不蓄積過剩量的熱而產生剝蝕。結果,不僅可減少厚度方向的裂紋的長度,而且可減少自點延伸的表面方向的裂紋的長度。再者,本發明的支撐玻璃基板具有如下優點:由於裂紋阻力高,因此於藉由雷射剝蝕形成資訊識別部(尤其是點)時,不易產生裂紋。The information recognition unit can be formed by various methods. However, in the present invention, it is preferable to irradiate a pulse laser to ablate the glass in the irradiation area to form an information recognition unit, that is, to form an information recognition unit by laser ablation. In this way, excessive amount of heat can be accumulated in the glass in the irradiation region to cause ablation. As a result, not only the length of the crack in the thickness direction but also the length of the crack in the surface direction from the point extension can be reduced. Further, the supporting glass substrate of the present invention has an advantage that cracks are less likely to occur when the information recognition portion (particularly, a dot) is formed by laser ablation because of high crack resistance.

資訊識別部較佳為包含多個點。點的外徑尺寸較佳為0.05 mm~0.20 mm、0.07 mm~0.13 mm、尤其是0.09 mm~0.11 mm。若點的外徑尺寸過小,則資訊識別部的視認性容易下降。另一方面,若點的外徑尺寸過大,則容易確保支撐玻璃基板的強度。The information recognition unit preferably includes a plurality of points. The outer diameter of the dots is preferably from 0.05 mm to 0.20 mm, from 0.07 mm to 0.13 mm, especially from 0.09 mm to 0.11 mm. If the outer diameter of the dot is too small, the visibility of the information recognition portion is liable to decrease. On the other hand, if the outer diameter of the dot is too large, it is easy to ensure the strength of the supporting glass substrate.

彼此相互鄰接的點的中心間距離較佳為0.06 mm~0.25 mm。若彼此相互鄰接的點的中心間距離過小,則容易確保支撐玻璃基板的強度。另一方面,若彼此相互鄰接的點的中心間距離過大,則資訊識別部的視認性容易下降。The distance between the centers of the points adjacent to each other is preferably from 0.06 mm to 0.25 mm. If the distance between the centers of the points adjacent to each other is too small, it is easy to ensure the strength of the supporting glass substrate. On the other hand, if the distance between the centers of the points adjacent to each other is too large, the visibility of the information recognition unit is likely to be lowered.

點的形狀較佳為環狀的槽。如此,若使點為環狀的槽,則由所述環狀的槽包圍的區域(相較於槽更靠內側的區域)不會藉由雷射被去除而殘存,因此能夠盡可能地防止設置有資訊識別部的區域的強度下降。另外,若為環狀的槽,只要外徑尺寸不發生變化,則即便減小槽的寬度尺寸,視認性亦不會下降那麼大程度。因此,若不改變槽的外徑尺寸而減小寬度尺寸,則相應地可大量獲取相較於槽更靠內側的區域的體積,藉此可確保視認性且確保所需的強度。The shape of the dots is preferably an annular groove. As described above, when the dot is an annular groove, the region surrounded by the annular groove (the region closer to the inner side than the groove) is not removed by the laser, and thus can be prevented as much as possible. The intensity of the area in which the information recognition unit is provided is lowered. Further, in the case of the annular groove, as long as the outer diameter does not change, the visibility does not decrease as much as the width of the groove is reduced. Therefore, if the width dimension is reduced without changing the outer diameter dimension of the groove, the volume of the region closer to the inner side than the groove can be obtained in a large amount, thereby ensuring visibility and ensuring the required strength.

形成點的槽的深度尺寸較佳為2 μm~30 μm。若槽的深度尺寸過小,則資訊識別部的視認性容易下降。另一方面,若槽的深度尺寸過大,則容易確保支撐玻璃基板的強度。The depth of the groove forming the dots is preferably from 2 μm to 30 μm. If the depth dimension of the groove is too small, the visibility of the information recognition unit is liable to decrease. On the other hand, if the depth dimension of the groove is too large, it is easy to ensure the strength of the supporting glass substrate.

本發明的支撐玻璃基板較佳為利用下拉法、尤其是溢流下拉法進行成形而成。溢流下拉法為如下方法,即,使熔融玻璃從耐熱性的流槽狀結構物的兩側溢出,使溢出的熔融玻璃一邊在流槽狀結構物的下頂端合流,一邊向下方延伸成形而製造玻璃基板。溢流下拉法中,應成為玻璃基板的表面的面不與流槽狀耐火物接觸,而以自由表面的狀態成形。因此,藉由少量的研磨,可將整體板厚偏差(TTV)減少至小於2.0 μm、尤其是小於1.0 μm。結果可使玻璃基板的製造成本低廉化。The supporting glass substrate of the present invention is preferably formed by a down-draw method, in particular, an overflow down-draw method. The overflow down-draw method is a method in which molten glass is allowed to overflow from both sides of the heat-resistant flow-like structure, and the overflowed molten glass is formed to extend downward while being joined at the lower end of the flow-like structure. A glass substrate is produced. In the overflow down-draw method, the surface which should be the surface of the glass substrate is not in contact with the flow-like refractory, but is formed in a state of a free surface. Therefore, the overall thickness deviation (TTV) can be reduced to less than 2.0 μm, especially less than 1.0 μm, by a small amount of grinding. As a result, the manufacturing cost of the glass substrate can be reduced.

本發明的支撐玻璃基板較佳為不進行離子交換處理,且較佳為表面不具有壓縮應力層。若進行離子交換處理,則支撐玻璃基板的製造成本高漲,但若不進行離子交換處理,則可使支撐玻璃基板的製造成本下降。進而,若進行離子交換處理,則難以減少支撐玻璃基板的整體板厚偏差(TTV),但若不進行離子交換處理,則容易消除所述不良情況。再者,本發明的支撐玻璃基板不排除進行離子交換處理而在表面形成壓縮應力層的形態。若僅著眼於提高機械性強度的觀點,則較佳為進行離子交換處理並在表面形成壓縮應力層。The supporting glass substrate of the present invention is preferably not subjected to ion exchange treatment, and preferably has no compressive stress layer on its surface. When the ion exchange treatment is performed, the manufacturing cost of the supporting glass substrate is increased. However, if the ion exchange treatment is not performed, the manufacturing cost of the supporting glass substrate can be lowered. Further, when the ion exchange treatment is performed, it is difficult to reduce the total thickness variation (TTV) of the supporting glass substrate. However, if the ion exchange treatment is not performed, the above-described problem is easily eliminated. Further, the supporting glass substrate of the present invention does not exclude a form in which a compressive stress layer is formed on the surface by performing ion exchange treatment. From the viewpoint of merely improving the mechanical strength, it is preferred to carry out an ion exchange treatment to form a compressive stress layer on the surface.

本發明的積層體至少包括加工基板及用以支撐加工基板的支撐玻璃基板,且所述積層體的特徵在於:支撐玻璃基板為所述支撐玻璃基板。本發明的積層體較佳為於加工基板與支撐玻璃基板之間具有接著層。接著層較佳為樹脂,且較佳為例如熱硬化性樹脂、光硬化性樹脂(尤其是紫外線硬化樹脂)等。另外,較佳為具有可耐受扇出型WLP的製造步驟中的熱處理的耐熱性。藉此,於扇出型WLP的製造步驟中接著層難以熔解,可提高加工處理的精度。再者,因容易將加工基板與支撐玻璃基板固定,故亦可將紫外線硬化型膠帶用作接著層。The laminated body of the present invention includes at least a processed substrate and a supporting glass substrate for supporting the processed substrate, and the laminated body is characterized in that the supporting glass substrate is the supporting glass substrate. The laminate of the present invention preferably has an adhesive layer between the processed substrate and the supporting glass substrate. The layer is preferably a resin, and is preferably, for example, a thermosetting resin, a photocurable resin (especially an ultraviolet curable resin), or the like. Further, it is preferable to have heat resistance of heat treatment in a manufacturing step capable of withstanding a fan-out type WLP. Thereby, in the manufacturing process of the fan-out type WLP, it is difficult to melt the subsequent layer, and the precision of the processing can be improved. Further, since the processed substrate and the supporting glass substrate are easily fixed, an ultraviolet curable adhesive tape can also be used as the adhesive layer.

本發明的積層體較佳為進而於加工基板與支撐玻璃基板之間,更具體而言於加工基板與接著層之間具有剝離層,或者於支撐玻璃基板與接著層之間具有剝離層。如此對加工基板進行規定的加工處理後,容易將加工基板自支撐玻璃基板剝離。自生產性的觀點考慮,加工基板的剝離較佳為藉由雷射光等照射光而進行。作為雷射光源,可使用釔鋁石榴石(Yttrium Aluminium Garnet,YAG)雷射(波長1064 nm)、半導體雷射(波長780 nm~1300 nm)等紅外光雷射光源。另外,於剝離層中可使用藉由照射紅外線雷射而分解的樹脂。另外,亦可將效率優良地吸收紅外線並轉換為熱的物質添加到樹脂中。例如,亦可將碳黑、石墨粉、微粒子金屬粉末、染料、顏料等添加到樹脂中。The laminate of the present invention is preferably further provided between the processed substrate and the supporting glass substrate, more specifically, a peeling layer between the processed substrate and the adhesive layer, or a peeling layer between the supporting glass substrate and the adhesive layer. After the predetermined processing of the processed substrate as described above, the processed substrate is easily peeled off from the supporting glass substrate. From the viewpoint of productivity, peeling of the processed substrate is preferably performed by irradiation of light such as laser light. As the laser light source, an infrared laser light source such as a Yttrium Aluminium Garnet (YAG) laser (wavelength 1064 nm) or a semiconductor laser (wavelength 780 nm to 1300 nm) can be used. Further, a resin which is decomposed by irradiation of an infrared laser can be used in the release layer. Further, a substance which absorbs infrared rays with high efficiency and converts it into heat can also be added to the resin. For example, carbon black, graphite powder, fine metal powder, dye, pigment, or the like may be added to the resin.

剝離層包括藉由雷射光等照射光而產生「層內剝離」或「界面剝離」的材料。即包括以下材料:若照射一定強度的光,則原子或分子中的原子間或分子間的結合力消失或減少,發生剝蝕(ablation)等,從而產生剝離的材料。再者,有藉由照射光的照射,剝離層中所含有的成分成為氣體被放出而導致分離的情況、與剝離層吸收光成為氣體並放出其蒸氣而導致分離的情況。The release layer includes a material that causes "in-layer peeling" or "interfacial peeling" by irradiation of light such as laser light. That is, the following materials are included: when a certain intensity of light is irradiated, the bonding force between atoms or molecules in an atom or a molecule disappears or decreases, and ablation or the like occurs to cause a peeled material. In addition, when the irradiation light is irradiated, the components contained in the release layer are released when the gas is released, and the separation layer absorbs light to form a gas and discharges the vapor to cause separation.

本發明的積層體中,支撐玻璃基板較佳為比加工基板大。藉此於對加工基板與支撐玻璃基板進行支撐時兩者的中心位置稍有分離的情況下,加工基板的邊緣部亦難以超出支撐玻璃基板。In the laminate of the present invention, the supporting glass substrate is preferably larger than the processed substrate. Therefore, when the center position of both of the processed substrate and the supporting glass substrate is slightly separated, the edge portion of the processed substrate is hard to exceed the supporting glass substrate.

本發明的半導體封裝體的製造方法的特徵在於包括:準備至少包括加工基板及用以支撐加工基板的支撐玻璃基板的積層體的步驟;以及對加工基板進行加工處理的步驟;並且支撐玻璃基板為所述支撐玻璃基板。A method of manufacturing a semiconductor package of the present invention includes the steps of: preparing a layered body including at least a processed substrate and a supporting glass substrate for supporting the processed substrate; and a step of processing the processed substrate; and supporting the glass substrate The supporting glass substrate.

本發明的半導體封裝體的製造方法較佳為進而包括搬送積層體的步驟。藉此,可提高加工處理的處理效率。再者,「搬送積層體的步驟」與「對加工基板進行加工處理的步驟」無須分開進行,亦可同時進行。The method of manufacturing a semiconductor package of the present invention preferably further includes the step of transporting the laminate. Thereby, the processing efficiency of the processing can be improved. In addition, the "step of transporting the laminated body" and the "step of processing the processed substrate" need not be performed separately, and may be performed simultaneously.

本發明的半導體封裝體的製造方法中,加工處理較佳為在加工基板的一表面進行配線的處理或在加工基板的一表面形成焊料凸塊的處理。本發明的半導體封裝體的製造方法中,在該些處理時加工基板尺寸不易變化,因而可適當地進行該些步驟。In the method of manufacturing a semiconductor package of the present invention, the processing is preferably a process of performing wiring on one surface of the processed substrate or a process of forming solder bumps on one surface of the processed substrate. In the method of manufacturing a semiconductor package of the present invention, the size of the processed substrate is not easily changed during the processes, and thus the steps can be appropriately performed.

除所述以外,作為加工處理亦可為以下處理中的任一個:對加工基板的一表面(通常與支撐玻璃基板為相反側的表面)以機械方式進行研磨的處理、對加工基板的一表面(通常與支撐玻璃基板為相反側的表面)進行乾式蝕刻的處理、對加工基板的一表面(通常與支撐玻璃基板為相反側的表面)進行濕式蝕刻的處理。再者,本發明的半導體封裝體的製造方法中,在加工基板上不易產生翹曲,並且可維持積層體的剛性。結果,可適當進行所述加工處理。In addition to the above, the processing may be any one of the following processes: mechanically polishing one surface of the processed substrate (usually a surface opposite to the supporting glass substrate), and processing a surface of the substrate (Normally, the surface on the opposite side to the supporting glass substrate) is subjected to dry etching treatment, and one surface of the processed substrate (usually a surface opposite to the supporting glass substrate) is subjected to wet etching. Further, in the method of manufacturing a semiconductor package of the present invention, warpage is less likely to occur on the processed substrate, and the rigidity of the laminated body can be maintained. As a result, the processing can be appropriately performed.

一邊參照圖式一邊對本發明進一步進行說明。The invention will be further described with reference to the drawings.

圖1為表示本發明的積層體1的一例的概念立體圖。圖1中,積層體1包括支撐玻璃基板10及加工基板11。支撐玻璃基板10為了防止加工基板11的尺寸變化,而貼附於加工基板11。支撐玻璃基板10與加工基板11之間配置有剝離層12與接著層13。剝離層12與支撐玻璃基板10接觸,接著層13與加工基板11接觸。Fig. 1 is a conceptual perspective view showing an example of a laminated body 1 of the present invention. In FIG. 1, the laminated body 1 includes a supporting glass substrate 10 and a processed substrate 11. The supporting glass substrate 10 is attached to the processed substrate 11 in order to prevent dimensional changes of the processed substrate 11. A peeling layer 12 and an adhesive layer 13 are disposed between the supporting glass substrate 10 and the processed substrate 11. The peeling layer 12 is in contact with the supporting glass substrate 10, and then the layer 13 is in contact with the processed substrate 11.

即,積層體1以支撐玻璃基板10、剝離層12、接著層13、加工基板11的順序積層配置。支撐玻璃基板10的形狀根據加工基板11而決定,圖1中,支撐玻璃基板10及加工基板11的形狀均為大致圓板形狀。剝離層12例如可使用藉由照射雷射而分解的樹脂。另外,亦可向樹脂中添加效率優良地吸收雷射光並轉換成熱的物質。例如為碳黑、石墨粉、微粒子金屬粉末、染料、顏料等。剝離層12藉由電漿化學氣相沈積法(Chemical vapor deposition,CVD)、溶膠-凝膠法的旋塗等而形成。接著層13包括樹脂,例如藉由各種印刷法、噴墨法、旋塗法、輥塗法等塗佈形成。另外,亦能夠使用紫外線硬化型膠帶。接著層13在藉由剝離層12從加工基板11剝離支撐玻璃基板10後,藉由溶劑等加以溶解去除。紫外線硬化型膠帶在照射紫外線後,可藉由剝離用膠帶而去除。In other words, the laminated body 1 is laminated in the order of supporting the glass substrate 10, the peeling layer 12, the adhesive layer 13, and the processed substrate 11. The shape of the supporting glass substrate 10 is determined according to the processed substrate 11. In Fig. 1, the shapes of the supporting glass substrate 10 and the processed substrate 11 are substantially disk-shaped. As the peeling layer 12, for example, a resin which is decomposed by irradiation with a laser can be used. Further, a substance which absorbs laser light with high efficiency and converts it into heat can be added to the resin. For example, carbon black, graphite powder, fine metal powder, dye, pigment, and the like. The peeling layer 12 is formed by plasma chemical vapor deposition (CVD), spin coating of a sol-gel method, or the like. Next, the layer 13 includes a resin, which is formed, for example, by various printing methods, an inkjet method, a spin coating method, a roll coating method, or the like. In addition, an ultraviolet curable tape can also be used. Next, the layer 13 is peeled off from the processed substrate 11 by the peeling layer 12, and then dissolved and removed by a solvent or the like. The ultraviolet curable tape can be removed by peeling off the tape after being irradiated with ultraviolet rays.

圖2(a)~圖2(g)是表示扇出型WLP的製造步驟的概念剖面圖。圖2(a)表示在支撐構件20的一表面形成接著層21的狀態。亦可視需要在支撐構件20與接著層21之間形成剝離層。繼而,如圖2(b)所示,於接著層21之上貼附多個半導體晶片22。此時,使半導體晶片22的主動側的面與接著層21接觸。繼而,如圖2(c)所示,利用樹脂的密封材23對半導體晶片22進行成形。密封材23使用壓縮成形後的尺寸變化、將配線成形時的尺寸變化少的材料。接著,如圖2(d)、圖2(e)所示,將半導體晶片22經成形的加工基板24自支撐構件20分離後,經由接著層25而與支撐玻璃基板26接著固定。此時,將加工基板24的表面內的與埋入半導體晶片22側的表面為相反側的表面配置於支撐玻璃基板26側。如此可獲得積層體27。再者,亦可視需要於接著層25與支撐玻璃基板26之間形成剝離層。進而搬送所獲得的積層體27後,如圖2(f)所示,於加工基板24的埋入半導體晶片22側的表面形成配線28後,形成多個焊料凸塊29。最後,在加工基板24從支撐玻璃基板26分離後,將加工基板24切斷為每個半導體晶片22,並用於之後的封裝步驟(圖2(g))。2(a) to 2(g) are conceptual cross-sectional views showing a manufacturing procedure of the fan-out type WLP. FIG. 2(a) shows a state in which the adhesion layer 21 is formed on one surface of the support member 20. A peeling layer may also be formed between the support member 20 and the adhesive layer 21 as needed. Then, as shown in FIG. 2(b), a plurality of semiconductor wafers 22 are attached on the adhesive layer 21. At this time, the surface on the active side of the semiconductor wafer 22 is brought into contact with the adhesive layer 21. Then, as shown in FIG. 2(c), the semiconductor wafer 22 is molded by the resin sealing material 23. The sealing material 23 is a material which has a dimensional change after compression molding and a small dimensional change when the wiring is formed. Next, as shown in FIGS. 2(d) and 2(e), the processed substrate 24 on which the semiconductor wafer 22 is formed is separated from the support member 20, and then fixed to the support glass substrate 26 via the adhesive layer 25. At this time, the surface on the surface of the processed substrate 24 opposite to the surface buried on the side of the semiconductor wafer 22 is disposed on the side of the supporting glass substrate 26. The laminate 27 can be obtained in this way. Further, a peeling layer may be formed between the adhesive layer 25 and the supporting glass substrate 26 as needed. After the obtained laminated body 27 is conveyed, as shown in FIG. 2(f), after the wiring 28 is formed on the surface of the processed substrate 24 on the semiconductor wafer 22 side, a plurality of solder bumps 29 are formed. Finally, after the processed substrate 24 is separated from the supporting glass substrate 26, the processed substrate 24 is cut into each of the semiconductor wafers 22 and used for the subsequent packaging step (Fig. 2(g)).

圖3(a)、圖3(b)為表示本發明的支撐玻璃基板的一例的上方概念圖。如圖3(a)所示,支撐玻璃基板31的外形為大致正圓的晶圓狀。另外,支撐玻璃基板31的外形包含凹口部32以及佔凹口部32以外的外形區域的外形部33。凹口部32具有凹口形狀、即具有凹陷的形狀。凹口形狀的深部34於平面視時為帶圓弧的大致圓形狀,凹口部32與外形部33的邊界亦為帶圓弧的大致圓形狀。如圖3(b)所示,支撐玻璃基板35的外形為大致正圓的晶圓狀。另外,支撐玻璃基板35的外形包含凹口部36以及佔凹口部36以外的外形區域的外形部37。支撐玻璃基板35的凹口部36具有凹口形狀,凹口形狀的深部38成為大致V槽形狀。3(a) and 3(b) are upper conceptual views showing an example of a supporting glass substrate of the present invention. As shown in FIG. 3(a), the outer shape of the supporting glass substrate 31 is a substantially circular wafer shape. Further, the outer shape of the supporting glass substrate 31 includes a notch portion 32 and an outer shape portion 33 that occupies an outer shape region other than the notch portion 32. The notch portion 32 has a notch shape, that is, a shape having a depression. The deep portion 34 of the notch shape has a substantially circular shape with an arc when viewed in plan, and the boundary between the notch portion 32 and the outer shape portion 33 is also a substantially circular shape with an arc. As shown in FIG. 3(b), the outer shape of the supporting glass substrate 35 is a substantially circular wafer shape. Further, the outer shape of the supporting glass substrate 35 includes a notch portion 36 and an outer shape portion 37 that occupies an outer shape region other than the notch portion 36. The notch portion 36 that supports the glass substrate 35 has a notch shape, and the deep portion 38 of the notch shape has a substantially V-groove shape.

圖4為圖3(a)的A-A'方向的剖面概念圖。如圖4所示,於支撐玻璃基板31的表面39、表面40與端面41交差的端緣區域具有倒角面42、倒角面43。支撐玻璃基板31的表面39、表面40的方向的倒角寬度X例如為50 μm~900 μm,支撐玻璃基板31的板厚方向的倒角寬度Y+Y'例如為板厚t的20%~80%。而且,端面41與倒角面42、倒角面43於分別連續地帶有圓弧的狀態下連結,表面39、表面40與倒角面42、倒角面43於分別連續地帶有圓弧的狀態下連結。 [實施例1]Fig. 4 is a conceptual cross-sectional view taken along line A-A' of Fig. 3(a). As shown in FIG. 4, the edge region of the surface 39 supporting the glass substrate 31 and the surface 40 intersecting the end surface 41 has a chamfered surface 42 and a chamfered surface 43. The chamfer width X in the direction of the surface 39 and the surface 40 of the supporting glass substrate 31 is, for example, 50 μm to 900 μm, and the chamfer width Y+Y' of the thickness direction of the supporting glass substrate 31 is, for example, 20% of the sheet thickness t. 80%. Further, the end surface 41, the chamfered surface 42 and the chamfered surface 43 are connected in a state in which the arc is continuously continuous, and the surface 39, the surface 40, the chamfered surface 42, and the chamfered surface 43 are continuously arc-shaped. Under the link. [Example 1]

以下基於實施例對本發明進行說明。再者,以下的實施例僅為例示。本發明並不受以下實施例的任何限定。The invention will now be described based on examples. Furthermore, the following examples are merely illustrative. The invention is not limited by the following examples.

表1、表2表示本發明的實施例(試樣No.1~試樣No.23)。另外,表3表示本發明的比較例(試料No.24~試料No.38)。Tables 1 and 2 show examples (sample No. 1 to sample No. 23) of the present invention. In addition, Table 3 shows a comparative example (sample No. 24 to sample No. 38) of the present invention.

[表1] [Table 1]

[表2] [Table 2]

[表3] [table 3]

首先,將以成為表中的玻璃組成的方式調合玻璃原料所得的玻璃配料放入至鉑坩堝中,以1600℃熔融4小時。當玻璃配料熔解時,使用鉑攪拌器進行攪拌,而進行均質化。然後,使熔融玻璃向碳板上流出,而成形為板狀後,從比緩冷點高20℃左右的溫度開始,以3℃/min緩冷至常溫為止。對所獲得的各試樣,評價裂紋阻力、20℃~200℃的溫度範圍內的平均線熱膨脹係數α20 200 ,20℃~220℃的溫度範圍內的平均線熱膨脹係數α20 220 ,20℃~260℃的溫度範圍內的平均線熱膨脹係數α20 260 ,30℃~380℃的溫度範圍內的平均線熱膨脹係數α30 380 ,密度,應變點Ps,緩冷點Ta,軟化點Ts,高溫黏度104.0 dPa·s下的溫度,高溫黏度103.0 dPa·s下的溫度,高溫黏度102.5 dPa·s下的溫度,液相溫度TL,液相溫度TL下的黏度η、楊氏模量、剛性係數及帕桑比。First, the glass batch obtained by blending the glass raw material in the form of a glass composition in the table was placed in a platinum crucible and melted at 1600 ° C for 4 hours. When the glass batch was melted, it was stirred using a platinum stirrer for homogenization. Then, the molten glass was allowed to flow out onto the carbon plate, and after being formed into a plate shape, it was slowly cooled to a normal temperature at 3 ° C/min from a temperature higher than the slow cooling point by about 20 ° C. Each sample obtained, evaluated crack resistance, thermal expansion coefficient of the mean line within a temperature range of 20 ℃ ~ 200 ℃ of α 20 ~ 200, the thermal expansion coefficient of the mean line within a temperature range of 20 ℃ ~ 220 ℃ of α 20 ~ 220, thermal average linear expansion coefficient within a temperature range of 20 ℃ ~ 260 ℃ of α 20 ~ 260, the thermal expansion coefficient of average linear in the temperature range 30 ℃ ~ 380 ℃ of α 30 ~ 380, density, strain point Ps of, annealing point Ta, softening Point Ts, temperature at a high temperature viscosity of 10 4.0 dPa·s, temperature at a high temperature viscosity of 10 3.0 dPa·s, temperature at a high temperature viscosity of 10 2.5 dPa·s, liquidus temperature TL, viscosity at liquidus temperature TL, Young's modulus, stiffness coefficient and Pasang ratio.

裂紋阻力是指裂紋產生率為50%的負荷,裂紋產生率以如下方式測定。首先,於保持為濕度30%、溫度25℃的恒溫恒濕槽內,將設定為規定負荷的維氏壓頭朝玻璃表面(光學研磨面)打入15秒,於所述15秒後對自壓痕的四角產生的裂紋的數量進行計數(設為一個壓痕最大為4)。如此,將壓頭打入20次,於求出總裂紋產生數後,藉由(總裂紋產生數/80)×100的式子求出。The crack resistance refers to a load at which the crack generation rate is 50%, and the crack generation rate is measured as follows. First, in a constant temperature and humidity chamber maintained at a humidity of 30% and a temperature of 25 ° C, a Vickers indenter set to a predetermined load was driven into the glass surface (optical polishing surface) for 15 seconds, and after 15 seconds, The number of cracks generated at the four corners of the indentation was counted (set to an indentation of up to 4). In this way, the indenter was driven 20 times, and after the total number of cracks was found, it was obtained by the equation (the total number of generated cracks / 80) × 100.

所述溫度範圍內的平均線熱膨脹係數為利用膨脹計進行測定而得的值。The average linear thermal expansion coefficient in the temperature range is a value measured by a dilatometer.

密度為藉由周知的阿基米德(Archimedes)法進行測定而得的值。The density is a value measured by a well-known Archimedes method.

應變點Ps、徐冷點Ta、軟化點Ts為基於美國試驗材料學會(American Society for Testing Material,ASTM)C336的方法進行測定而得的值。The strain point Ps, the cold point Ta, and the softening point Ts are values measured based on the method of the American Society for Testing Material (ASTM) C336.

高溫黏度104.0 dPa·s、高溫黏度103.0 dPa·s及高溫黏度102.5 dPa·s下的溫度為藉由鉑球提拉法進行測定而得的值。The temperature at a high temperature viscosity of 10 4.0 dPa·s, a high temperature viscosity of 10 3.0 dPa·s, and a high temperature viscosity of 10 2.5 dPa·s is a value measured by a platinum ball pulling method.

液相溫度TL為將通過標準篩30目(500 μm)而殘留於50目(300 μm)的玻璃粉末裝入鉑舟,於溫度梯度爐中保持24小時後,藉由顯微鏡觀察而對結晶析出的溫度進行測定而得的值。液相溫度TL下的黏度η為利用鉑球提拉法對液相溫度TL下的玻璃的黏度進行測定所得的值。The liquidus temperature TL is a glass boat which is left at 50 mesh (300 μm) through a standard sieve of 30 mesh (500 μm), and is placed in a platinum boat. After being kept in a temperature gradient furnace for 24 hours, the crystal is precipitated by microscopic observation. The temperature is measured. The viscosity η at the liquidus temperature TL is a value obtained by measuring the viscosity of the glass at the liquidus temperature TL by a platinum ball pulling method.

楊氏模量、剛性係數、帕桑比是指藉由共振法進行測定而得的值。The Young's modulus, the rigidity coefficient, and the Pasang ratio are values obtained by the resonance method.

根據表1、表2明確般,試樣No.1~試樣No.23的裂紋阻力為600 gf以上,因此認為於扇出型WLP的製造步驟中在積層體的搬送時不易產生裂紋。另一方面,試樣No.24~試樣No.38的裂紋阻力為494 gf以下,因此認為於扇出型WLP的製造步驟中在積層體的搬送時容易產生裂紋。 [實施例2]As is clear from Tables 1 and 2, the crack resistance of the sample No. 1 to the sample No. 23 is 600 gf or more. Therefore, it is considered that cracking is less likely to occur during the conveyance of the laminated body in the manufacturing process of the fan-out type WLP. On the other hand, since the crack resistance of the sample No. 24 to the sample No. 38 is 494 gf or less, it is considered that cracks are likely to occur during the conveyance of the laminated body in the manufacturing process of the fan-out type WLP. [Embodiment 2]

首先,以成為表1、表2中記載的試樣No.1~試樣No.23中記載的玻璃組成的方式調合玻璃原料後,供給至玻璃熔融爐中以1600℃~1700℃熔融,然後將熔融玻璃供給至溢流下拉成形裝置,分別成形為板厚0.8 mm。對於所獲得的玻璃基板,對兩表面進行機械研磨,將整體板厚偏差(TTV)減少至小於1 μm。在將所獲得的玻璃基板加工為f300 mm×0.8 mm厚後,藉由研磨裝置對其兩表面進行研磨處理。具體而言,以外徑不同的一對研磨墊夾持玻璃基板的兩表面,一邊使玻璃基板與一對研磨墊一同旋轉,一邊對玻璃基板的兩表面進行研磨處理。研磨處理時,有時以玻璃基板的一部分超出研磨墊的方式進行控制。再者,研磨墊為胺基甲酸酯製,研磨處理時所使用的研磨漿料的平均粒徑為2.5 μm,研磨速度為15 m/min。對所獲得的各研磨處理完畢的玻璃基板,藉由神鋼(KOBELCO)科研公司製造的彎曲/翹曲(Bow/Warp)測定裝置SBW-331ML/d測定整體板厚偏差(TTV)與翹曲量。結果,整體板厚偏差(TTV)分別為0.85 μm以下,翹曲量分別為35 μm以下。First, the glass raw material is blended so as to have the glass composition described in Sample No. 1 to Sample No. 23 described in Tables 1 and 2, and then supplied to a glass melting furnace to be melted at 1600 ° C to 1700 ° C, and then melted. The molten glass was supplied to an overflow down-draw forming apparatus, and each formed into a plate thickness of 0.8 mm. For the obtained glass substrate, both surfaces were mechanically ground to reduce the overall thickness deviation (TTV) to less than 1 μm. After the obtained glass substrate was processed to have a thickness of f300 mm × 0.8 mm, both surfaces thereof were subjected to a grinding treatment by a polishing apparatus. Specifically, the both surfaces of the glass substrate are sandwiched between a pair of polishing pads having different outer diameters, and both surfaces of the glass substrate are polished while rotating the glass substrate together with the pair of polishing pads. At the time of the polishing treatment, a part of the glass substrate may be controlled so as to extend beyond the polishing pad. Further, the polishing pad was made of urethane, and the polishing slurry used in the polishing treatment had an average particle diameter of 2.5 μm and a polishing rate of 15 m/min. The total thickness deviation (TTV) and the amount of warpage were measured by the Bow/Warp measuring device SBW-331ML/d manufactured by Kobelco Scientific Research Co., Ltd. for each of the obtained polished glass substrates. . As a result, the overall thickness deviation (TTV) was 0.85 μm or less, and the warpage amount was 35 μm or less.

1、27‧‧‧積層體1, 27‧‧ ‧ laminated body

10、26、31、35‧‧‧支撐玻璃基板10, 26, 31, 35‧‧‧Support glass substrate

11、24‧‧‧加工基板11, 24‧‧‧Processing substrate

12‧‧‧剝離層12‧‧‧ peeling layer

13、21、25‧‧‧接著層13, 21, 25‧‧‧ the next layer

20‧‧‧支撐構件20‧‧‧Support members

22‧‧‧半導體晶片22‧‧‧Semiconductor wafer

23‧‧‧密封材23‧‧‧ Sealing material

28‧‧‧配線28‧‧‧Wiring

29‧‧‧焊料凸塊29‧‧‧ solder bumps

32、36‧‧‧凹口部32, 36‧‧‧ Notch

33、37‧‧‧外形部33, 37‧‧‧ shape parts

34、38‧‧‧凹口部的深部34, 38‧‧‧Deep part of the notch

39、40‧‧‧支撐玻璃基板的表面39, 40‧‧‧ Supporting the surface of the glass substrate

41‧‧‧支撐玻璃基板的端面41‧‧‧ Supporting the end face of the glass substrate

42、43‧‧‧支撐玻璃基板的倒角面42, 43‧‧‧ Supporting the chamfered surface of the glass substrate

X、Y+Y'‧‧‧倒角寬度X, Y+Y'‧‧‧Chamfer width

t‧‧‧板厚T‧‧‧ plate thickness

圖1是表示本發明的積層體的一例的概念立體圖。 圖2(a)~圖2(g)是表示扇出型WLP的製造步驟的概念剖面圖。 圖3(a)、圖3(b)為表示本發明的支撐玻璃基板的一例的上方概念圖。 圖4為圖3(a)的A-A'方向的剖面概念圖。Fig. 1 is a conceptual perspective view showing an example of a laminated body of the present invention. 2(a) to 2(g) are conceptual cross-sectional views showing a manufacturing procedure of the fan-out type WLP. 3(a) and 3(b) are upper conceptual views showing an example of a supporting glass substrate of the present invention. Fig. 4 is a conceptual cross-sectional view taken along line A-A' of Fig. 3(a).

Claims (13)

一種支撐玻璃基板,其用以支撐加工基板,且所述支撐玻璃基板的特徵在於: 作為玻璃組成,以質量%計含有45%~70%的SiO2 、超過10.5%~35%的Al2 O3 、0%~20%的B2 O3 、5%~25%的Na2 O、0%~10%的K2 O、1%~10%的MgO、以及0%~5%的ZnO,且裂紋阻力為500 gf以上。A supporting glass substrate for supporting a processed substrate, wherein the supporting glass substrate is characterized in that: as a glass composition, 45% to 70% of SiO 2 and more than 10.5% to 35% of Al 2 O are contained by mass% 3 , 0% to 20% B 2 O 3 , 5% to 25% Na 2 O, 0% to 10% K 2 O, 1% to 10% MgO, and 0% to 5% ZnO, And the crack resistance is 500 gf or more. 如申請專利範圍第1項所述的支撐玻璃基板,其中作為玻璃組成,以質量%計含有50%~67%的SiO2 、19.7%~33%的Al2 O3 、0%~15%的B2 O3 、5%~20%的Na2 O、0%~3%的K2 O、1%~5.5%的MgO、以及0%~3%的ZnO,且裂紋阻力為700 gf以上。The supporting glass substrate according to claim 1, wherein the glass composition contains 50% to 67% of SiO 2 and 19.7% to 33% of Al 2 O 3 and 0% to 15% by mass%. B 2 O 3 , 5% to 20% Na 2 O, 0% to 3% K 2 O, 1% to 5.5% MgO, and 0% to 3% ZnO, and the crack resistance is 700 gf or more. 如申請專利範圍第1項或第2項所述的支撐玻璃基板,其中在20℃~220℃的溫度範圍內的平均線熱膨脹係數為40×10-7 /℃以上且120×10-7 /℃以下。The supporting glass substrate according to claim 1 or 2, wherein an average linear thermal expansion coefficient in a temperature range of 20 ° C to 220 ° C is 40 × 10 -7 / ° C or more and 120 × 10 -7 / Below °C. 如申請專利範圍第1項至第3項中任一項所述的支撐玻璃基板,其中在20℃~260℃的溫度範圍內的平均線熱膨脹係數為40×10-7 /℃以上且120×10-7 /℃以下。The supporting glass substrate according to any one of claims 1 to 3, wherein an average linear thermal expansion coefficient in a temperature range of from 20 ° C to 260 ° C is 40 × 10 -7 / ° C or more and 120 × 10 -7 / °C or less. 如申請專利範圍第1項至第4項中任一項所述的支撐玻璃基板,其中在30℃~380℃的溫度範圍內的平均線熱膨脹係數為42×10-7 /℃以上且125×10-7 /℃以下。The supporting glass substrate according to any one of claims 1 to 4, wherein an average linear thermal expansion coefficient in a temperature range of 30 ° C to 380 ° C is 42 × 10 -7 / ° C or more and 125 × 10 -7 / °C or less. 如申請專利範圍第1項至第5項中任一項所述的支撐玻璃基板,其具有直徑100 mm~500 mm的晶圓形狀或大致圓板形狀,板厚小於2.0 mm,整體板厚偏差(TTV)為5 μm以下,且翹曲量為60 μm以下。The supporting glass substrate according to any one of claims 1 to 5, which has a wafer shape or a substantially circular plate shape having a diameter of 100 mm to 500 mm, a plate thickness of less than 2.0 mm, and an overall thickness deviation (TTV) is 5 μm or less, and the amount of warpage is 60 μm or less. 一種積層體,其至少包括加工基板及用以支撐加工基板的支撐玻璃基板,且所述積層體的特徵在於:所述支撐玻璃基板為如申請專利範圍第1項至第6項中任一項所述的支撐玻璃基板。A laminated body comprising at least a processing substrate and a supporting glass substrate for supporting the processing substrate, and the laminated body is characterized in that the supporting glass substrate is any one of items 1 to 6 of the patent application scope The supporting glass substrate. 如申請專利範圍第7項所述的積層體,其中所述加工基板至少包括利用密封材進行了成形的半導體晶片。The laminated body according to claim 7, wherein the processed substrate includes at least a semiconductor wafer formed by a sealing material. 一種半導體封裝體的製造方法,其特徵在於包括:準備至少包括加工基板及用以支撐加工基板的支撐玻璃基板的積層體的步驟;以及 對所述加工基板進行加工處理的步驟;並且所述支撐玻璃基板為如申請專利範圍第1項至第6項中任一項所述的支撐玻璃基板。A method of manufacturing a semiconductor package, comprising: preparing a layer including at least a processed substrate and a supporting glass substrate for supporting the processed substrate; and a step of processing the processed substrate; and the supporting The glass substrate is a supporting glass substrate as described in any one of claims 1 to 6. 如申請專利範圍第9項所述的半導體封裝體的製造方法,其中所述加工處理包括在所述加工基板的一表面進行配線的步驟。The method of manufacturing a semiconductor package according to claim 9, wherein the processing includes a step of wiring on a surface of the processed substrate. 如申請專利範圍第9項或第10項所述的半導體封裝體的製造方法,其中所述加工處理包括在所述加工基板的一表面形成焊料凸塊的步驟。The method of manufacturing a semiconductor package according to claim 9 or claim 10, wherein the processing includes the step of forming a solder bump on a surface of the processed substrate. 一種半導體封裝體,其特徵在於利用如申請專利範圍第9項至第11項中任一項所述的半導體封裝體的製造方法製作。A semiconductor package produced by the method of manufacturing a semiconductor package according to any one of claims 9 to 11. 一種電子機器,其包括半導體封裝體,且所述電子機器的特徵在於: 所述半導體封裝體為如申請專利範圍第12項所述的半導體封裝體。An electronic device comprising a semiconductor package, and the electronic device is characterized in that: the semiconductor package is the semiconductor package according to claim 12 of the patent application.
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