TW201603058A - Dynamo-electric machine permanent magnet, method for manufacturing dynamo-electric machine permanent magnet, dynamo-electric machine, and method for manufacturing dynamo-electric machine - Google Patents
Dynamo-electric machine permanent magnet, method for manufacturing dynamo-electric machine permanent magnet, dynamo-electric machine, and method for manufacturing dynamo-electric machine Download PDFInfo
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
- H01F1/04—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
- H01F1/047—Alloys characterised by their composition
- H01F1/053—Alloys characterised by their composition containing rare earth metals
- H01F1/055—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5
- H01F1/057—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
- H01F1/04—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys
- H01F1/06—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder
- H01F1/08—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F41/00—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties
- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F7/00—Magnets
- H01F7/02—Permanent magnets [PM]
-
- H—ELECTRICITY
- H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
- H02K—DYNAMO-ELECTRIC MACHINES
- H02K15/00—Processes or apparatus specially adapted for manufacturing, assembling, maintaining or repairing of dynamo-electric machines
- H02K15/02—Processes or apparatus specially adapted for manufacturing, assembling, maintaining or repairing of dynamo-electric machines of stator or rotor bodies
- H02K15/03—Processes or apparatus specially adapted for manufacturing, assembling, maintaining or repairing of dynamo-electric machines of stator or rotor bodies having permanent magnets
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Hard Magnetic Materials (AREA)
- Manufacturing Cores, Coils, And Magnets (AREA)
- Permanent Field Magnets Of Synchronous Machinery (AREA)
Abstract
Description
本發明係關於一種旋轉電機用永久磁石及旋轉電機用永久磁石之製造方法、以及使用旋轉電機用永久磁石之旋轉電機及旋轉電機之製造方法。 The present invention relates to a method for producing a permanent magnet for a rotating electrical machine and a permanent magnet for a rotating electrical machine, and a method for manufacturing a rotating electrical machine and a rotating electrical machine using a permanent magnet for a rotating electrical machine.
近年來,工作機械、車輛、航空機、風力原動機等中已普遍使用將自引擎等傳遞之機械運動能轉換為電能之發電機、或相反地將電能轉換為機械運動能之馬達(電動機)等旋轉電機。此處,作為旋轉電機之一的表面磁石型旋轉電機係於轉子表面貼附有磁石之旋轉電機,能夠以相對較為簡易之構成實現高輸出化、高效率化。 In recent years, a machine that converts mechanical motion energy transmitted from an engine or the like into electric energy or a motor (electric motor) that converts electrical energy into mechanical motion energy has been widely used in work machines, vehicles, aircrafts, wind power motives, and the like. Motor. Here, the surface magnet type rotating electric machine which is one of the rotating electric machines is a rotating electric machine to which a magnet is attached to the surface of the rotor, and it is possible to achieve high output and high efficiency with a relatively simple configuration.
例如,於日本專利特開2009-27846號公報,已揭示於轉子周圍配置有複數個扇型永久磁石之表面磁石型馬達。 For example, Japanese Laid-Open Patent Publication No. 2009-27846 discloses a surface magnet type motor in which a plurality of fan-shaped permanent magnets are disposed around a rotor.
[專利文獻1]日本專利特開2009-27846號公報(第5頁、圖1) [Patent Document 1] Japanese Patent Laid-Open Publication No. 2009-27846 (page 5, Fig. 1)
此處,如圖10所示,先前之表面磁石型旋轉電機係藉由於轉子101之表面貼附扇型之複數個永久磁石102而構成。又,旋轉電機亦尋求低轉矩脈動(torque ripple)化,因此重要的是抑制永久磁石102相對 於設計位置之位置偏差。例如,為將轉矩脈動設為0.5%以下,必須將永久磁石102相對於設計位置之位置偏差抑制為5μm以下。然而,先前之將永久磁石貼附於轉子表面之構成則難以進行永久磁石對於轉子之準確定位。 Here, as shown in FIG. 10, the prior surface magnet type rotating electrical machine is constructed by attaching a plurality of permanent magnets 102 of a fan shape to the surface of the rotor 101. Moreover, the rotating electric machine also seeks low torque ripple, so it is important to suppress the relative magnet 102 relative to each other. Positional deviation at the design location. For example, in order to set the torque ripple to 0.5% or less, it is necessary to suppress the positional deviation of the permanent magnet 102 with respect to the design position to 5 μm or less. However, the previous configuration of attaching a permanent magnet to the surface of the rotor makes it difficult to accurately position the permanent magnet for the rotor.
又,一般而言,轉子101與永久磁石102使用黏著劑固定,但僅藉由黏著劑將永久磁石102對於轉子101適當固定並非易事。例如,若使用較多黏著劑,則溢出之黏著劑將對馬達造成不良影響。另一方面,若黏著劑較少,則亦存在永久磁石102自高速旋轉之轉子101脫離,或產生永久磁石102之位置偏移之可能性。 Further, in general, the rotor 101 and the permanent magnet 102 are fixed using an adhesive, but it is not easy to properly fix the permanent magnet 102 to the rotor 101 only by the adhesive. For example, if more adhesive is used, the spilled adhesive will adversely affect the motor. On the other hand, if the amount of the adhesive is small, there is a possibility that the permanent magnet 102 is detached from the rotor 101 which is rotated at a high speed, or the position of the permanent magnet 102 is displaced.
本發明係為解決上述先前之問題點而完成者,其目的在於提供一種旋轉電機用永久磁石及旋轉電機用永久磁石之製造方法、以及使用旋轉電機用永久磁石之旋轉電機及旋轉電機之製造方法,其等可對於表面磁石型旋轉電機之轉子,準確且牢固地固定於預先設計之位置,並可實現表面磁石型旋轉電機之高輸出化、高效率化、低轉矩脈衝化。 The present invention has been made to solve the above problems, and an object of the present invention is to provide a permanent magnet for a rotating electrical machine, a method for manufacturing a permanent magnet for a rotating electrical machine, and a method for manufacturing a rotating electrical machine and a rotating electrical machine using a permanent magnet for a rotating electrical machine. The rotor of the surface magnet type rotating electric machine can be accurately and firmly fixed to a pre-designed position, and can realize high output, high efficiency, and low torque pulse of the surface magnet type rotating electric machine.
用於達成上述目的之本發明之旋轉電機用永久磁石之特徵在於:其係配置於表面磁石型旋轉電機之轉子表面的永久磁石,且於與上述轉子表面接觸之面,形成有與形成於上述轉子表面之卡合部卡合之被卡合部。 A permanent magnet for a rotating electrical machine according to the present invention for achieving the above object is characterized in that it is disposed on a permanent magnet of a surface of a surface of a magnet-type rotating electrical machine, and is formed on the surface in contact with the surface of the rotor. The engaged portion of the engaging portion of the rotor surface is engaged with the engaging portion.
又,本發明之旋轉電機用永久磁石之特徵在於藉由如下步驟而製造:將磁石原料粉碎為磁石粉末;生成將上述粉碎後之磁石粉末與黏合劑混合而成之混合物;將上述混合物成形為具有上述被卡合部之成形體;及藉由對上述成形體以沿一軸向加壓之狀態保持為燒成溫度而進行燒結。 Further, the permanent magnet for a rotating electrical machine according to the present invention is characterized in that the magnet raw material is pulverized into a magnet powder; a mixture obtained by mixing the pulverized magnet powder and a binder is formed; and the mixture is formed into The molded body having the above-mentioned engaged portion; and sintering is performed by holding the molded body at a firing temperature in a state of being pressed in one axial direction.
又,本發明之旋轉電機用永久磁石之特徵在於:於將上述成形 體燒結之步驟中係以沿配置於上述轉子表面時成為與轉子之軸向相同方向之方向對上述成形體加壓之狀態進行燒結。 Further, the permanent magnet for a rotating electrical machine of the present invention is characterized in that the above-mentioned forming In the step of sintering the body, the formed body is pressed in a direction in which it is placed in the same direction as the axial direction of the rotor when disposed on the surface of the rotor.
又,本發明之旋轉電機用永久磁石之特徵在於:上述黏合劑包含熱塑性樹脂;藉由對利用成形上述成形體之步驟而產生之上述混合物之殘留物進行加熱,而將該殘留物再利用為用於成形上述成形體之上述混合物。 Further, in the permanent magnet for a rotating electrical machine according to the present invention, the binder comprises a thermoplastic resin, and the residue of the mixture produced by the step of molding the molded body is heated to reuse the residue. The above mixture for forming the above shaped body.
又,本發明之旋轉電機用永久磁石之特徵在於形成有複數個上述被卡合部。 Further, the permanent magnet for a rotating electrical machine according to the present invention is characterized in that a plurality of the engaged portions are formed.
又,本發明之旋轉電機之特徵在於:於轉子表面配置永久磁石;且上述永久磁石係於與上述轉子表面接觸之面,形成有與形成於上述轉子表面之卡合部卡合之被卡合部。 Further, the rotary electric machine according to the present invention is characterized in that a permanent magnet is disposed on a surface of the rotor; and the permanent magnet is formed on a surface in contact with the surface of the rotor, and is engaged with a engaging portion formed on a surface of the rotor. unit.
又,本發明之旋轉電機用永久磁石之製造方法之特徵在於:其係配置於表面磁石型旋轉電機之轉子表面之永久磁石的製造方法,具有如下步驟:將磁石原料粉碎為磁石粉末;生成將上述粉碎後之磁石粉末與黏合劑混合而成之混合物;將上述混合物成形為成形體;及藉由對上述成形體以沿一軸向加壓之狀態保持為燒成溫度而進行燒結;且對於上述成形體,於與上述轉子表面接觸之面,形成與形成於上述轉子表面之卡合部卡合之被卡合部。 Moreover, the method for producing a permanent magnet for a rotating electrical machine according to the present invention is characterized in that it is a method for producing a permanent magnet disposed on a surface of a rotor of a surface magnet-type rotating electrical machine, and has the following steps: pulverizing a magnet raw material into a magnet powder; a mixture of the pulverized magnet powder and a binder; forming the mixture into a molded body; and sintering by maintaining the firing temperature in a state of being pressed in one axial direction; and The molded body has an engaged portion that engages with an engaging portion formed on the surface of the rotor on a surface in contact with the surface of the rotor.
又,本發明之旋轉電機用永久磁石之製造方法之特徵在於:於:於將上述成形體燒結之步驟中係以沿配置於上述轉子表面時成為與轉子之軸向相同方向之方向對上述成形體加壓之狀態進行燒結。 Further, in the method of producing a permanent magnet for a rotating electrical machine according to the present invention, in the step of sintering the formed body, the forming is performed in the same direction as the axial direction of the rotor when disposed on the surface of the rotor. Sintering is performed in a state of body pressurization.
又,本發明之旋轉電機用永久磁石之製造方法之特徵在於形成有複數個上述被卡合部。 Moreover, the method of manufacturing a permanent magnet for a rotating electrical machine according to the present invention is characterized in that a plurality of the engaged portions are formed.
又,本發明之旋轉電機用永久磁石之製造方法之特徵在於:上述黏合劑包含熱塑性樹脂;且藉由對利用成形上述成形體之步驟所產生之上述混合物之殘留物進行加熱,而將該殘留物再利用為用於成形 上述成形體之上述混合物。 Moreover, the method for producing a permanent magnet for a rotating electrical machine according to the present invention is characterized in that the binder comprises a thermoplastic resin; and the residue of the mixture produced by the step of molding the molded body is heated to leave the residue. Reuse for forming The above mixture of the above shaped bodies.
又,本發明之旋轉電機之製造方法之特徵在於:其係藉由於轉子表面配置永久磁石而製造之旋轉電機的製造方法,且上述永久磁石係藉由如下步驟而製造:將磁石原料粉碎為磁石粉末;生成將上述粉碎後之磁石粉末與黏合劑混合而成之混合物;將上述混合物成形為成形體;及藉由對上述成形體以沿一軸向加壓之狀態保持為燒成溫度而進行燒結;且對於上述成形體,於與上述轉子表面接觸之面,形成與形成於上述轉子表面之卡合部卡合之被卡合部。 Moreover, the manufacturing method of the rotary electric machine according to the present invention is characterized in that the permanent magnet is manufactured by the following steps: the magnet material is pulverized into a magnet by a permanent magnet disposed on the surface of the rotor. a powder; a mixture obtained by mixing the pulverized magnet powder and a binder; forming the mixture into a molded body; and maintaining the firing temperature in a state of being pressed in one axial direction Sintering; and the formed body is formed with an engaged portion that engages with an engaging portion formed on the surface of the rotor on a surface in contact with the surface of the rotor.
根據具有上述構成之本發明之旋轉電機用永久磁石,由於在與旋轉電機之轉子表面接觸之面,形成與形成於轉子表面之卡合部卡合之被卡合部,故藉由使卡合部與被卡合部卡合,可將永久磁石對於轉子準確地定位於預先設計之位置。又,由於可增大永久磁石與轉子之接觸面積,故可將永久磁石對於轉子牢固地固定。其結果為,即便於轉子高速旋轉之情形時,亦可防止產生永久磁石相對於轉子之位置偏移。 According to the permanent magnet for a rotating electrical machine according to the present invention having the above configuration, since the engaged portion that engages with the engaging portion formed on the surface of the rotor is formed on the surface in contact with the surface of the rotor of the rotating electrical machine, the engaging portion is engaged. The portion is engaged with the engaged portion to accurately position the permanent magnet to the pre-designed position of the rotor. Moreover, since the contact area between the permanent magnet and the rotor can be increased, the permanent magnet can be firmly fixed to the rotor. As a result, even when the rotor is rotated at a high speed, the positional deviation of the permanent magnet with respect to the rotor can be prevented.
又,根據本發明之旋轉電機用永久磁石,由於藉由成形將磁石粉末與黏合劑混合而成之混合物而形成成形體,故與使用先前之壓粉成形等之情形相比,配向後磁石粒子亦不會旋動,且亦可提高配向度。又,於對磁石粉末與黏合劑之混合物進行磁場配向之情形時,由於可利用電流匝數,故可確保進行磁場配向時之磁場強度較大,且由於可於靜磁場實施長時間之磁場施加,故可實現偏差較少之較高之配向度。進而,可實現偏差較少之高配向關係到因燒結引起之收縮偏差的減少。即,可確保燒結後之製品形狀之均一性。其結果為,可減輕燒結後對外形加工之負擔。而且,與先前之壓粉成形相比,可容易地成形被卡合部,且由於成形之被卡合部於之後之製造步驟中不會產生 較大程度之變形,故可適當地進行卡合部與被卡合部之卡合。 Further, according to the permanent magnet for a rotating electrical machine of the present invention, since the molded body is formed by mixing a mixture of the magnet powder and the binder by molding, the post-aligning magnet particles are used as compared with the case of using the previous powder molding or the like. It will not be rotated and the alignment will be improved. Further, when the magnetic field is aligned with the mixture of the magnet powder and the binder, since the number of current turns can be utilized, the magnetic field strength at the time of the magnetic field alignment can be ensured to be large, and the magnetic field can be applied for a long time in the static magnetic field. Therefore, a higher degree of alignment with less deviation can be achieved. Further, it is possible to achieve a high alignment with less variation and a reduction in shrinkage deviation due to sintering. That is, the uniformity of the shape of the product after sintering can be ensured. As a result, the burden on the outer shape processing after sintering can be alleviated. Moreover, the engaged portion can be easily formed as compared with the prior powder forming, and since the formed engaged portion does not occur in the subsequent manufacturing steps Since the deformation is largely performed, the engagement between the engaging portion and the engaged portion can be appropriately performed.
又,根據本發明之旋轉電機用永久磁石,由於以沿成為與轉子之軸向相同方向之方向對成形體加壓之狀態進行燒結,故而因燒結引起之收縮變得均勻,藉此可防止產生燒結後之翹曲或凹陷等變形。其結果為,即便於永久磁石具有形成有被卡合部之複雜形狀之情形時,亦可精度良好地製造永久磁石。 Further, since the permanent magnet for a rotating electrical machine according to the present invention is sintered in a state in which the molded body is pressed in the same direction as the axial direction of the rotor, the shrinkage due to sintering is uniform, thereby preventing generation of the permanent magnet. Deformation such as warpage or depression after sintering. As a result, even when the permanent magnet has a complicated shape in which the engaged portion is formed, the permanent magnet can be manufactured with high precision.
又,根據本發明之旋轉電機用永久磁石,即便將磁石粉末與黏合劑之混合物加工成形狀複雜之成形體之情形時,亦由於可將因加工所產生之殘留物部分再生為混合物之一部分,故可防止良率之降低。 Further, according to the permanent magnet for a rotating electrical machine of the present invention, even when a mixture of a magnet powder and a binder is processed into a molded body having a complicated shape, a part of the residue generated by the processing can be regenerated into a part of the mixture. Therefore, the yield can be prevented from decreasing.
又,根據本發明之旋轉電機用永久磁石,藉由設置複數個被卡合部,可將永久磁石對於轉子牢固地固定。其結果為,即便於轉子高速旋轉之情形時,亦可防止產生永久磁石相對於轉子之位置偏移。 Further, according to the permanent magnet for a rotating electrical machine of the present invention, the permanent magnet can be firmly fixed to the rotor by providing a plurality of engaged portions. As a result, even when the rotor is rotated at a high speed, the positional deviation of the permanent magnet with respect to the rotor can be prevented.
又,根據本發明之旋轉電機,與先前相比,可實現旋轉電機之高轉矩化、小型化、低轉矩脈動化、及高效率化。 Further, according to the rotary electric machine of the present invention, it is possible to achieve higher torque, smaller size, lower torque ripple, and higher efficiency of the rotary electric machine than before.
又,根據本發明之旋轉電機用永久磁石之製造方法,由於在與旋轉電機之轉子表面接觸之面,形成與形成於轉子表面之卡合部卡合之被卡合部,故藉由使卡合部與被卡合部卡合,可將永久磁石對於轉子準確地定位於預先設計之位置。又,由於可增大永久磁石與轉子之接觸面積,故可將永久磁石對於轉子牢固地固定。其結果為,即便於轉子高速旋轉之情形時,亦可防止產生永久磁石相對於轉子之位置偏移。 Further, according to the method of manufacturing a permanent magnet for a rotating electrical machine according to the present invention, since the engaged portion that engages with the engaging portion formed on the surface of the rotor is formed on the surface in contact with the surface of the rotor of the rotating electrical machine, the card is engaged. The engagement of the hinge with the engaged portion allows the permanent magnet to accurately position the rotor at a pre-designed position. Moreover, since the contact area between the permanent magnet and the rotor can be increased, the permanent magnet can be firmly fixed to the rotor. As a result, even when the rotor is rotated at a high speed, the positional deviation of the permanent magnet with respect to the rotor can be prevented.
又,由於藉由成形將磁石粉末與黏合劑混合而成之混合物而形成成形體,故與使用先前之壓粉成形等之情形相比,配向後磁石粒子亦不會旋動,且亦可提高配向度。又,於對磁石粉末與黏合劑之混合物進行磁場配向之情形時,由於可利用電流匝數,故可確保進行磁場配向時之磁場強度較大,且由於可於靜磁場實施長時間之磁場施加, 從而可實現偏差較少之較高之配向度。進而,可實現偏差較少之高配向關係到因燒結引起之收縮偏差的減少。即,可確保燒結後之製品形狀之均一性。其結果為,可減輕燒結後之對外形加工之負擔。而且,與先前之壓粉成形相比,可容易地成形被卡合部,且由於成形之被卡合部於之後之製造步驟中不會產生較大程度之變形,故可適當地進行卡合部與被卡合部之卡合。 Further, since the molded body is formed by mixing a mixture of the magnet powder and the binder by molding, the magnet particles after the alignment are not rotated and can be improved as compared with the case of using the previous powder molding or the like. Orientation. Further, when the magnetic field is aligned with the mixture of the magnet powder and the binder, since the number of current turns can be utilized, the magnetic field strength at the time of the magnetic field alignment can be ensured to be large, and the magnetic field can be applied for a long time in the static magnetic field. , Thereby, a higher degree of alignment with less deviation can be achieved. Further, it is possible to achieve a high alignment with less variation and a reduction in shrinkage deviation due to sintering. That is, the uniformity of the shape of the product after sintering can be ensured. As a result, the burden on the profile processing after sintering can be alleviated. Further, the engaged portion can be easily formed as compared with the prior art powder forming, and since the formed engaged portion does not undergo a large degree of deformation in the subsequent manufacturing step, the engagement can be appropriately performed. The part is engaged with the engaged part.
又,根據本發明之旋轉電機用永久磁石之製造方法,由於以沿成為與轉子之軸向相同方向之方向對成形體加壓之狀態進行燒結,故而因燒結引起之收縮變得均勻,藉此可防止產生燒結後之翹曲或凹陷等變形。其結果為,即便於永久磁石具有形成有被卡合部之複雜形狀之情形時,亦可精度良好地製造永久磁石。 Further, according to the method for producing a permanent magnet for a rotating electrical machine according to the present invention, since the molded body is pressed in a direction in which the molded body is pressed in the same direction as the axial direction of the rotor, the shrinkage due to sintering becomes uniform. It can prevent deformation such as warpage or depression after sintering. As a result, even when the permanent magnet has a complicated shape in which the engaged portion is formed, the permanent magnet can be manufactured with high precision.
又,根據本發明之旋轉電機用永久磁石之製造方法,藉由設置複數個被卡合部,可將永久磁石對於轉子牢固地固定。其結果為,即便於轉子高速旋轉之情形時,亦可防止產生永久磁石相對於轉子之位置偏移。 Further, according to the method of manufacturing a permanent magnet for a rotating electrical machine according to the present invention, the permanent magnet can be firmly fixed to the rotor by providing a plurality of engaged portions. As a result, even when the rotor is rotated at a high speed, the positional deviation of the permanent magnet with respect to the rotor can be prevented.
又,根據本發明之旋轉電機用永久磁石之製造方法,即便於將磁石粉末與黏合劑之混合物加工成形狀複雜之成形體之情形時,亦由於可將因加工所產生之殘留物部分再生為混合物之一部分,故可防止良率之降低。 Further, according to the method for producing a permanent magnet for a rotating electrical machine according to the present invention, even when a mixture of a magnet powder and a binder is processed into a molded body having a complicated shape, the residue due to the processing can be partially regenerated into One part of the mixture prevents the yield from falling.
進而,根據本發明之旋轉電機之製造方法,與先前相比,可實現所製造之旋轉電機之高轉矩化、小型化、低轉矩脈動化、及高效率化。 Further, according to the method for manufacturing a rotating electrical machine of the present invention, it is possible to achieve higher torque, smaller size, lower torque ripple, and higher efficiency of the manufactured rotating electrical machine than before.
1‧‧‧永久磁石 1‧‧‧ permanent magnet
2‧‧‧轉子 2‧‧‧Rotor
3‧‧‧卡合部 3‧‧‧Clock Department
4‧‧‧被卡合部 4‧‧‧Be jammed
10‧‧‧磁石粉末 10‧‧‧Magnetic powder
11‧‧‧珠磨機 11‧‧‧Bead mill
12‧‧‧化合物 12‧‧‧ compounds
13‧‧‧支持基材 13‧‧‧Support substrate
14‧‧‧胚片 14‧‧ ‧Mason
15‧‧‧模具 15‧‧‧Mold
22‧‧‧塗敷輥軸 22‧‧‧Applicator roller
25‧‧‧螺線管 25‧‧‧ Solenoid
26‧‧‧加熱板 26‧‧‧heating plate
27‧‧‧箭頭符號 27‧‧‧ arrow symbol
31‧‧‧成形體 31‧‧‧Formed body
32‧‧‧燒結體 32‧‧‧Sintered body
42‧‧‧軸 42‧‧‧Axis
43‧‧‧定子 43‧‧‧ Stator
45‧‧‧SPM馬達 45‧‧‧SPM motor
101‧‧‧轉子 101‧‧‧Rotor
102‧‧‧永久磁石 102‧‧‧ permanent magnet
圖1係表示本發明之永久磁石之整體圖。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a general view showing a permanent magnet of the present invention.
圖2係表示將永久磁石固定於轉子之狀態之圖。 Fig. 2 is a view showing a state in which a permanent magnet is fixed to a rotor.
圖3係對形成於永久磁石之被卡合部之其他形狀進行表示之圖。 Fig. 3 is a view showing another shape of the engaged portion formed in the permanent magnet.
圖4係對形成於永久磁石之被卡合部之其他形狀進行表示之圖。 Fig. 4 is a view showing another shape of the engaged portion formed in the permanent magnet.
圖5係表示本發明之永久磁石之製造步驟之說明圖。 Fig. 5 is an explanatory view showing a manufacturing step of the permanent magnet of the present invention.
圖6係表示本發明之永久磁石之製造步驟中之尤其胚片之加熱步驟及磁場配向步驟之說明圖。 Fig. 6 is an explanatory view showing, in particular, a heating step and a magnetic field aligning step of the green sheet in the manufacturing process of the permanent magnet of the present invention.
圖7係對成形體之成形步驟進行說明之圖。 Fig. 7 is a view for explaining a molding step of a molded body.
圖8係對本發明之永久磁石之製造步驟中之尤其焙燒步驟之升溫態樣進行說明之圖。 Fig. 8 is a view for explaining a heating state of a particularly baking step in the manufacturing process of the permanent magnet of the present invention.
圖9係表示本發明之SPM馬達之製造步驟之說明圖。 Fig. 9 is an explanatory view showing a manufacturing procedure of the SPM motor of the present invention.
圖10係對先前技術之問題點進行說明之圖。 Fig. 10 is a diagram for explaining problems of the prior art.
以下,關於針對本發明之旋轉電機用永久磁石及旋轉電機用永久磁石之製造方法而具體化之一實施形態,於下文中一面參照圖式,一面進行詳細說明。 In the following, an embodiment of the permanent magnet for a rotating electrical machine and a permanent magnet for a rotating electrical machine according to the present invention will be described in detail below with reference to the drawings.
[永久磁石之構成] [Composition of permanent magnets]
首先,對相當於本發明之旋轉電機用永久磁石之永久磁石1之構成進行說明。圖1係表示本發明之永久磁石1之整體圖。再者,如圖1所示,本發明之永久磁石1係具有段形狀之永久磁石。又,如圖2所示,於表面磁石型之旋轉電機(馬達或發電機)之轉子2之表面配置複數個,而構成表面磁石型之旋轉電機。圖2係表示配置有永久磁石1之SPM馬達之轉子2之圖。再者,於以下實施例中,雖對將永久磁石1設為扇型之永久磁石之例進行說明,但永久磁石1之形狀可根據成為配置對象之轉子2之形狀或配置個數等進行適當變更。例如,亦可設為扇型形狀、環形狀、弓型形狀、正方體形狀。 First, the configuration of the permanent magnet 1 corresponding to the permanent magnet for a rotating electrical machine according to the present invention will be described. Figure 1 is a general view showing a permanent magnet 1 of the present invention. Further, as shown in Fig. 1, the permanent magnet 1 of the present invention has a segment-shaped permanent magnet. Further, as shown in FIG. 2, a plurality of surfaces of the rotor 2 of a surface magnet type rotary electric machine (motor or generator) are arranged to form a surface magnet type rotary electric machine. 2 is a view showing the rotor 2 of the SPM motor in which the permanent magnet 1 is disposed. In the following embodiments, an example in which the permanent magnet 1 is a fan-shaped permanent magnet will be described. However, the shape of the permanent magnet 1 can be appropriately determined according to the shape or arrangement number of the rotor 2 to be placed. change. For example, it may be a fan shape, a ring shape, a bow shape, or a square shape.
又,本發明之永久磁石1包含Nd-Fe-B系磁石。再者,各成分之含量係設為:Nd:27~40wt%、B:0.8~2wt%、Fe(電解鐵):60~70wt%。又,為提高磁性特性,亦可含有少量Dy、Tb、Co、Cu、 Al、Si、Ga、Nb、V、Pr、Mo、Zr、Ta、Ti、W、Ag、Bi、Zn、Mg等其他元素。 Further, the permanent magnet 1 of the present invention contains a Nd-Fe-B based magnet. Further, the content of each component is: Nd: 27 to 40% by weight, B: 0.8 to 2% by weight, and Fe (electrolytic iron): 60 to 70% by weight. Moreover, in order to improve magnetic properties, a small amount of Dy, Tb, Co, Cu, or Other elements such as Al, Si, Ga, Nb, V, Pr, Mo, Zr, Ta, Ti, W, Ag, Bi, Zn, Mg, and the like.
又,永久磁石1相對於轉子2之配置個數係與形成於轉子2周圍之極數相應之數量,例如於將極數設為8極之情形時,如圖2所示,將8個永久磁石1相對於轉子2以等間隔配置。又,於永久磁石1之與轉子2之表面接觸之面,形成與形成於轉子2表面之卡合部3卡合之被卡合部4。 Further, the number of the permanent magnets 1 relative to the rotor 2 is equal to the number of poles formed around the rotor 2, for example, when the number of poles is set to 8 poles, as shown in FIG. 2, 8 permanent The magnets 1 are arranged at equal intervals with respect to the rotor 2. Further, on the surface of the permanent magnet 1 that is in contact with the surface of the rotor 2, the engaged portion 4 that engages with the engaging portion 3 formed on the surface of the rotor 2 is formed.
此處,於圖1及圖2所示之例中,將形成於永久磁石1之被卡合部4設為分別形成於轉子2之圓周方向之兩端部之凸狀之腳狀構件,將形成於轉子2之卡合部3設為供該腳狀構件插入之插入孔。而且,以於永久磁石1之被卡合部4卡合於轉子2之卡合部3之狀態下,永久磁石1相對於轉子2位於預先設計之設計位置之方式構成。即,如圖2所示,分別以卡合部3與被卡合部4卡合之方式配置8個永久磁石1,並利用接著劑等將永久磁石1與轉子2固定,藉此可將永久磁石1對於轉子2準確地定位於設計位置並固定。又,藉由形成卡合部3與被卡合部4,永久磁石1與轉子2抵接之面之面積變大,故於使用接著劑固定之情形時,可將永久磁石1對於轉子2更牢固地固定。 Here, in the example shown in FIG. 1 and FIG. 2, the engaged portion 4 formed in the permanent magnet 1 is a convex-shaped leg member formed at both end portions of the rotor 2 in the circumferential direction, and The engaging portion 3 formed in the rotor 2 is an insertion hole into which the leg member is inserted. Further, in a state in which the engaged portion 4 of the permanent magnet 1 is engaged with the engaging portion 3 of the rotor 2, the permanent magnet 1 is configured to be positioned at a predetermined design position with respect to the rotor 2. In other words, as shown in FIG. 2, eight permanent magnets 1 are placed so that the engaging portion 3 and the engaged portion 4 are engaged with each other, and the permanent magnet 1 and the rotor 2 are fixed by an adhesive or the like, whereby the permanent magnet 1 can be permanently fixed. The magnet 1 is accurately positioned at the design position and fixed to the rotor 2. Further, since the area where the permanent magnet 1 abuts against the rotor 2 is increased by forming the engaging portion 3 and the engaged portion 4, the permanent magnet 1 can be made to the rotor 2 when the adhesive is fixed. Securely fixed.
再者,於圖2所示之例中,將形成於永久磁石1之被卡合部4設為對於一永久磁石1形成於2處之構成,但亦可將被卡合部4設為僅形成於一處,或形成於3處以上之構成。又,亦可設為並非對配置於轉子2之所有永久磁石1形成被卡合部4,而僅於一部分永久磁石1形成之構成。又,於圖2所示之例中,將卡合部3設為凹形狀,將被卡合部4設為凸形狀,但亦可將卡合部3設為凸形狀,將被卡合部4設為凹形狀。 Further, in the example shown in FIG. 2, the engaged portion 4 formed in the permanent magnet 1 is formed in two places for one permanent magnet 1, but the engaged portion 4 may be set only It is formed in one place or formed in three or more places. Further, it is also possible to form a configuration in which only the permanent magnet 1 is formed by forming the engaged portion 4 for all of the permanent magnets 1 disposed in the rotor 2. Moreover, in the example shown in FIG. 2, the engaging portion 3 is formed in a concave shape, and the engaged portion 4 is formed in a convex shape. However, the engaging portion 3 may be formed in a convex shape and the engaged portion may be engaged. 4 is set to a concave shape.
又,卡合部3與被卡合部4之大小或形狀可進行適當變更。 Moreover, the size or shape of the engaging portion 3 and the engaged portion 4 can be appropriately changed.
例如,如圖3所示,卡合部3與被卡合部4之形狀亦可設為對於抵接面連續形成之凹凸形狀。又,亦可設為如圖4所示之楔型形狀。再 者,若設為如圖4所示之楔型形狀,則無需使用接著劑便可將永久磁石1與轉子2固定。又,如下所述,若使用胚成形體成形永久磁石1,則亦可容易地成形為如圖3或圖4所示之複雜之形狀。進而,若採用加壓燒結進行燒結,則因燒結引起之成形體收縮變得均勻,因此,燒結後之永久磁石不會產生翹曲或凹陷等變形,燒結後之永久磁石之尺寸精度提高。因此,無需進行燒結後之永久磁石之形狀修正加工,便可使卡合部3與被卡合部4適當地卡合。 For example, as shown in FIG. 3, the shape of the engaging portion 3 and the engaged portion 4 may be a concavo-convex shape continuously formed on the abutting surface. Further, it may be a wedge shape as shown in FIG. again If the wedge shape is as shown in FIG. 4, the permanent magnet 1 and the rotor 2 can be fixed without using an adhesive. Further, as described below, when the permanent magnet 1 is formed using the blank molded body, it can be easily formed into a complicated shape as shown in Fig. 3 or Fig. 4 . Further, when sintering is performed by pressure sintering, the shrinkage of the molded body due to sintering becomes uniform. Therefore, the permanent magnet after sintering does not undergo warpage or deformation such as depression, and the dimensional accuracy of the permanent magnet after sintering is improved. Therefore, the shape correcting process of the permanent magnet after sintering is not required, and the engaging portion 3 and the engaged portion 4 can be appropriately engaged.
進而,永久磁石1係如下所述藉由對成形將磁石粉末與黏合劑混合而成之混合物之成形體(胚成形體)進行燒結而形成。再者,亦可設為如下構成:並非使混合物直接成形為最終製品形狀(例如圖1所示之扇型),而暫時成形為除最終製品形狀以外之形狀(例如片形狀、塊形狀等),其後進行沖孔加工、切削加工、變形加工等,而成為最終製品形狀。又,尤其若設為使混合物暫時成為片形狀後加工成最終製品形狀之構成,則由於以連續步驟進行生產,故而可提高生產性,且亦可提高成形精度。於將混合物設為片形狀之情形時,例如設為具有0.05mm~10mm(例如1mm)之厚度之薄膜狀之片材構件。再者,即便於設為片形狀之情形時,只要積層複數片,便亦可製造大型之永久磁石1。 Further, the permanent magnet 1 is formed by sintering a molded body (embryo molded body) obtained by molding a mixture of a magnet powder and a binder as follows. Further, it is also possible to adopt a configuration in which the mixture is not directly molded into a final product shape (for example, a fan shape as shown in FIG. 1), and is temporarily formed into a shape other than the final product shape (for example, a sheet shape, a block shape, etc.). Then, punching, cutting, deformation processing, and the like are performed to form a final product shape. Further, in particular, when the mixture is temporarily formed into a sheet shape and processed into a final product shape, the production is carried out in a continuous step, so that productivity can be improved and the molding precision can be improved. In the case where the mixture is in the form of a sheet, for example, a film member having a film thickness of 0.05 mm to 10 mm (for example, 1 mm) is used. Further, even in the case of a sheet shape, a large permanent magnet 1 can be produced by laminating a plurality of sheets.
另一方面,於本發明中,特別於製造永久磁石1之情形時,混合於磁石粉末中之黏合劑使用樹脂、長鏈烴、脂肪酸酯或其等之混合物等。 On the other hand, in the present invention, particularly in the case of producing the permanent magnet 1, the binder mixed in the magnet powder is a resin, a long-chain hydrocarbon, a fatty acid ester or the like, or the like.
進而,於對黏合劑使用樹脂之情形時,較佳為使用構造中不含氧原子且具有解聚性之電漿。又,如下所述,為了對將磁石粉末與黏合劑之混合物成形為所期望形狀(例如扇型)時所產生之混合物之殘留物再利用,以及為了於加熱混合物而使其軟化之狀態下進行磁場配向,使用熱塑性樹脂。具體而言,選自以下之通式(1)所示之聚合物 中之1種或2種以上之聚合物或包含共聚物之聚合物(polymer)符合條件。 Further, in the case where a resin is used for the binder, it is preferred to use a plasma which does not contain oxygen atoms in the structure and which has depolymerization property. Further, as described below, in order to reuse the residue of the mixture generated when the mixture of the magnet powder and the binder is formed into a desired shape (for example, a fan shape), and to soften the mixture in order to heat the mixture, The magnetic field is aligned and a thermoplastic resin is used. Specifically, a polymer selected from the following formula (1) One or more of the polymers or polymers containing the copolymers are eligible.
(其中,R1及R2表示氫原子、低級烷基、苯基或乙烯基) (wherein R1 and R2 represent a hydrogen atom, a lower alkyl group, a phenyl group or a vinyl group)
作為符合上述條件之聚合物,例如有:異丁烯之聚合物,即聚異丁烯(PIB);異戊二烯之聚合物,即聚異戊二烯(異戊二烯橡膠,IR);1,3-丁二烯之聚合物,即聚丁二烯(丁二烯橡膠,BR);苯乙烯之聚合物,即聚苯乙烯;苯乙烯與異戊二烯之共聚物,即苯乙烯-異戊二烯嵌段共聚物(SIS);異丁烯與異戊二烯之共聚物,即丁基橡膠(IIR);苯乙烯與丁二烯之共聚物,即苯乙烯-丁二烯嵌段共聚物(SBS);2-甲基-1-戊烯之聚合物,即2-甲基-1-戊烯聚合樹脂;2-甲基-1-丁烯之聚合物,即2-甲基-1-丁烯聚合樹脂;α-甲基苯乙烯之聚合物,即α-甲基苯乙烯聚合樹脂等。再者,為賦予柔軟性,較理想為對α-甲基苯乙烯聚合樹脂添加低分子量之聚異丁烯。又,作為黏合劑所使用之樹脂,亦可設為包含少量含氧原子之單體之聚合物或共聚物(例如,聚甲基丙烯酸丁酯(poly butyl methacrylate)或聚甲基丙烯酸甲酯(Polymethyl methacrylate)等)的構成。進而,不符合上述通式(1)之單體可一部分共聚。即便於該情形時,亦可達成本案發明之目的。 As the polymer satisfying the above conditions, for example, a polymer of isobutylene, that is, polyisobutylene (PIB); a polymer of isoprene, that is, polyisoprene (isoprene rubber, IR); 1, 3 - a polymer of butadiene, ie polybutadiene (butadiene rubber, BR); a polymer of styrene, ie polystyrene; a copolymer of styrene and isoprene, ie styrene-isoprene Diene block copolymer (SIS); copolymer of isobutylene and isoprene, ie butyl rubber (IIR); copolymer of styrene and butadiene, ie styrene-butadiene block copolymer ( SBS); a polymer of 2-methyl-1-pentene, ie a polymer of 2-methyl-1-pentene; a polymer of 2-methyl-1-butene, ie 2-methyl-1- Butylene polymer resin; a polymer of α-methyl styrene, that is, an α-methyl styrene polymer resin or the like. Further, in order to impart flexibility, it is preferred to add a low molecular weight polyisobutylene to the α-methylstyrene polymer resin. Further, the resin used as the binder may be a polymer or copolymer containing a small amount of a monomer having an oxygen atom (for example, polybutyl methacrylate or polymethyl methacrylate ( Composition of Polymethyl methacrylate). Further, a monomer which does not satisfy the above formula (1) may be partially copolymerized. That is, in the case of this situation, the object of the present invention can also be achieved.
再者,作為黏合劑所使用之樹脂,為適當地進行磁場配向,較理想為使用於250℃以下軟化之熱塑性樹脂,更具體而言,較理想為使用玻璃轉移點或流動起始溫度為250℃以下之熱塑性樹脂。 Further, the resin used as the binder is preferably a thermoplastic resin which is softened at 250 ° C or lower for the purpose of appropriately performing magnetic field alignment. More specifically, it is preferred to use a glass transition point or a flow initiation temperature of 250. A thermoplastic resin below °C.
另一方面,於對黏合劑使用長鏈烴之情形時,較佳為使用於室 溫為固體且於室溫以上為液體之長鏈飽和烴(長鏈烷烴)。具體而言,較佳為使用碳數為18以上之長鏈飽和烴。而且,如下所述,於將磁石粉末與黏合劑之混合物進行磁場配向時,於將混合物以長鏈烴之玻璃轉移點或流動起始溫度以上加熱而使其軟化之狀態下,進行磁場配向。 On the other hand, in the case of using long-chain hydrocarbons for the binder, it is preferably used in the chamber. A long-chain saturated hydrocarbon (long-chain alkane) which is solid at room temperature and above a room temperature. Specifically, it is preferred to use a long-chain saturated hydrocarbon having a carbon number of 18 or more. Further, as described below, when the mixture of the magnet powder and the binder is subjected to magnetic field alignment, the mixture is subjected to magnetic field alignment in a state where the mixture is heated and softened by a glass transition point or a flow initiation temperature of the long-chain hydrocarbon.
又,於對黏合劑使用脂肪酸酯之情形亦同樣,較佳為使用於室溫為固體且於室溫以上為液體之硬脂酸甲酯(Stearic Acid Methyl Ester),或山崳酸甲酯(Docosanoic Acid Methyl Ester)。而且,如下所述,於將磁石粉末與黏合劑之混合物進行磁場配向時,於將混合物以脂肪酸甲酯之流動起始溫度以上加熱而使其軟化之狀態下,進行磁場配向。 Further, in the case where a fatty acid ester is used for the binder, it is preferably used as a solid at room temperature and liquid at room temperature or higher (Stearic Acid Methyl Ester), or methyl behenate. (Docosanoic Acid Methyl Ester). Further, as described below, when the mixture of the magnet powder and the binder is subjected to magnetic field alignment, the mixture is subjected to magnetic field alignment while heating and softening the mixture at a temperature above the flow initiation temperature of the fatty acid methyl ester.
藉由使用滿足上述條件之黏合劑作為磁石粉末中所混合之黏合劑,可降低磁石內含有之碳量及氧量。具體而言,將燒結後殘存於磁石之碳量設為2000ppm以下,更佳為1000ppm以下。又,將燒結後殘存於磁石之氧量設為5000ppm以下,更佳為2000ppm以下。 By using a binder satisfying the above conditions as a binder mixed in the magnet powder, the amount of carbon and the amount of oxygen contained in the magnet can be reduced. Specifically, the amount of carbon remaining in the magnet after sintering is 2,000 ppm or less, more preferably 1,000 ppm or less. Moreover, the amount of oxygen remaining in the magnet after sintering is 5,000 ppm or less, more preferably 2,000 ppm or less.
又,為於成形漿料或加熱熔融之化合物時提高成形體之厚度精度,將黏合劑之添加量設為將磁石粒子間之空隙適當填充之量。例如,將黏合劑相對於磁石粉末與黏合劑之合計量之比率設為1wt%~40wt%,更佳為2wt%~30wt%,進而較佳為3wt%~20wt%。 Further, in order to increase the thickness precision of the molded body when molding the slurry or heating the molten compound, the amount of the binder added is an amount that appropriately fills the gap between the magnet particles. For example, the ratio of the binder to the total amount of the magnet powder and the binder is from 1 wt% to 40 wt%, more preferably from 2 wt% to 30 wt%, still more preferably from 3 wt% to 20 wt%.
[永久磁石之製造方法] [Method of manufacturing permanent magnet]
接下來,利用圖5對本發明之永久磁石1之製造方法進行說明。圖5係表示本實施形態之永久磁石1之製造步驟之說明圖。 Next, a method of manufacturing the permanent magnet 1 of the present invention will be described with reference to Fig. 5 . Fig. 5 is an explanatory view showing a manufacturing procedure of the permanent magnet 1 of the embodiment.
首先,製造包含特定分率之Nd-Fe-B(例如Nd:32.7wt%;Fe(電解鐵):65.96wt%;B:1.34wt%)之錠(ingot)。其後,藉由搗碎機或破碎機(crusher)等將錠粗粉碎成200μm左右之大小。或者,將錠熔解,以鑄片(Strip Casting)法製作薄片(flake),以氫粉碎法將其粗粉 化。藉此,可獲得粗粉碎磁石粉末10。 First, an ingot containing a specific fraction of Nd-Fe-B (for example, Nd: 32.7 wt%; Fe (electrolytic iron): 65.96 wt%; B: 1.34 wt%) is produced. Thereafter, the ingot is coarsely pulverized to a size of about 200 μm by a masher, a crusher or the like. Alternatively, the ingot is melted, and a flake is produced by a strip casting method, and the powder is pulverized by hydrogen pulverization. Chemical. Thereby, the coarsely pulverized magnet powder 10 can be obtained.
其次,藉由利用珠磨機11之濕式法或使用噴射磨機之乾式法等將粗粉碎磁石粉末10微粉化。例如,於使用利用珠磨機11之濕式法之微粉碎中,於溶劑中,將粗粉碎磁石粉末10微粉碎成特定範圍之粒徑(例如0.1μm~5.0μm),並使磁石粉末分散於溶劑中。其後,以真空乾燥等使濕式粉碎後之溶劑中所含之磁石粉末乾燥,並取出經乾燥之磁石粉末。又,粉碎所使用之溶劑之種類並無特別限定,可使用:異丙醇、乙醇、甲醇等醇類,乙酸乙酯等酯類,戊烷、己烷等低級烴類,苯、甲苯、二甲苯等芳香族類,酮類,或其等之混合物等。再者,較佳為,使用溶劑中不包含氧原子之溶劑。 Next, the coarsely pulverized magnet powder 10 is micronized by a wet method using a bead mill 11 or a dry method using a jet mill. For example, in the fine pulverization using the wet method using the bead mill 11, the coarsely pulverized magnet powder 10 is finely pulverized into a specific range of particle diameter (for example, 0.1 μm to 5.0 μm) in a solvent, and the magnet powder is dispersed. In the solvent. Thereafter, the magnet powder contained in the solvent after the wet pulverization is dried by vacuum drying or the like, and the dried magnet powder is taken out. Further, the type of the solvent to be used for the pulverization is not particularly limited, and examples thereof include alcohols such as isopropyl alcohol, ethanol, and methanol, esters such as ethyl acetate, and lower hydrocarbons such as pentane and hexane, and benzene, toluene, and An aromatic compound such as toluene, a ketone, or a mixture thereof or the like. Further, it is preferred to use a solvent which does not contain an oxygen atom in the solvent.
另一方面,於使用利用噴射磨機之乾式法之微粉碎中,於(a)包含含氧量實質上為0%之氮氣、氬氣(Ar)、氦氣(He)等惰性氣體之氛圍中,或於(b)包含含氧量為0.0001~0.5%之氮氣、氬氣(Ar)、氦氣(He)等惰性氣體之氛圍中,藉由噴射磨機將經粗粉碎之磁石粉末微粉碎,使其成為具有特定範圍之粒徑(例如,0.7μm~5.0μm)之平均粒徑之微粉末。再者,所謂氧濃度實質上為0%係指並非限定於氧濃度完全為0%之情形,亦可含有於細粉末表面極少量地形成氧化覆膜之程度之量之氧。 On the other hand, in the fine pulverization using a dry method using a jet mill, (a) an atmosphere containing an inert gas such as nitrogen gas, argon gas (Ar) or helium gas (He) having an oxygen content of substantially 0%. Or, in (b) an atmosphere containing an inert gas such as nitrogen gas, argon gas (Ar) or helium gas (He) having an oxygen content of 0.0001 to 0.5%, the coarsely pulverized magnet powder is micro-pulverized by a jet mill. The pulverization is carried out to obtain a fine powder having an average particle diameter of a specific range of particle diameters (for example, 0.7 μm to 5.0 μm). In addition, the fact that the oxygen concentration is substantially 0% means that the oxygen concentration is not limited to 0%, and oxygen may be contained in an amount such that an oxide film is formed on the surface of the fine powder in a very small amount.
其次,將經珠磨機11等微粉碎之磁石粉末成型為所期望形狀。再者,磁石粉末之成形係藉由成形將磁石粉末與黏合劑混合之混合物而進行。於以下之實施例中,於將混合物暫時成形為製品形狀以外之形狀之狀態下,施加磁場而進行磁場配向,其後,進行打孔加工、切削加工、變形加工等,藉此成為製品形狀(例如圖1所示之扇型)。尤其於以下之實施例中,於將混合物暫時成形為片形狀之胚成形體(以下,稱為胚片)後,成為製品形狀。又,於將混合物尤其成形為片形狀之情形時,有利用例如熱熔型塗敷或漿料塗敷等之成形,熱熔型塗 敷係於加熱磁石粉末與黏合劑混合而成之化合物後使之成形為片形狀,漿料塗敷係藉由將包含磁石粉末、黏合劑、及有機溶劑之漿料塗敷於基材上而成形為片狀。 Next, the magnet powder finely pulverized by the bead mill 11 or the like is molded into a desired shape. Further, the formation of the magnet powder is carried out by forming a mixture of the magnet powder and the binder. In the following embodiments, the magnetic field is aligned by applying a magnetic field in a state in which the mixture is temporarily molded into a shape other than the shape of the product, and thereafter, punching, cutting, deformation processing, or the like is performed, thereby forming a product shape ( For example, the fan type shown in Fig. 1). In particular, in the following examples, the mixture was temporarily formed into a sheet-shaped embryo molded body (hereinafter referred to as a green sheet), and then formed into a product shape. Further, in the case where the mixture is particularly formed into a sheet shape, there is a forming by, for example, hot-melt coating or slurry coating, and hot-melt coating Applying a compound obtained by mixing a heated magnet powder and a binder to form a sheet shape, and applying the slurry to a substrate by applying a slurry containing a magnet powder, a binder, and an organic solvent. Formed into a sheet.
以下,特別對使用熱熔塗敷之胚片成形進行說明。 Hereinafter, the formation of the green sheet using hot melt coating will be specifically described.
首先,藉由於經珠磨機11等微粉碎之磁石粉末中混合黏合劑,製作包含磁石粉末與黏合劑之黏土狀之混合物(化合物)12。此處,作為黏合劑,如上所述,使用樹脂、長鏈烴、脂肪酸酯或其等之混合物等。例如,於使用樹脂之情形時,較佳為使用構造中不含氧原子且包含具有解聚性之聚合物之熱塑性樹脂,另一方面,於使用長鏈烴之情形時,較佳為使用於室溫為固體且於室溫以上為液體之長鏈飽和烴(長鏈烷烴)。又,於使用脂肪酸酯之情形時,較佳為使用硬脂酸甲酯或山崳酸甲酯等。又,黏合劑之添加量係如上所述般,設為添加後之化合物12中之黏合劑相對於磁石粉末與黏合劑之合計量之比率為1wt%~40wt%,更佳為2wt%~30wt%,進而較佳為3wt%~20wt%。 First, a clay-like mixture (compound) 12 containing a magnet powder and a binder is produced by mixing a binder with a magnet powder finely pulverized by a bead mill 11 or the like. Here, as the binder, as described above, a resin, a long-chain hydrocarbon, a fatty acid ester or a mixture thereof or the like is used. For example, in the case of using a resin, it is preferred to use a thermoplastic resin which does not contain oxygen atoms in the structure and which contains a polymer having depolymerization property, and on the other hand, in the case of using a long-chain hydrocarbon, it is preferably used in the case of using a resin. A long-chain saturated hydrocarbon (long-chain alkane) which is solid at room temperature and liquid above room temperature. Further, in the case of using a fatty acid ester, methyl stearate or methyl behenate or the like is preferably used. Further, the amount of the binder added is as described above, and the ratio of the binder in the compound 12 after the addition to the total amount of the magnet powder and the binder is from 1% by weight to 40% by weight, more preferably from 2% by weight to 30% by weight. %, further preferably from 3 wt% to 20 wt%.
又,為提高於之後進行之磁場配向步驟中之配向度,亦可於上述化合物12添加有助於配向之添加劑。作為有助於配向之添加劑,使用例如烴系之添加劑,尤其較理想為使用具有極性(具體而言,酸解離常數pKa為未達41之)之添加劑。又,添加劑之添加量依存於磁石粉末之粒徑,磁石粉末之粒徑越小,則越需要增加添加量。作為具體之添加量,設為相對於磁石粉末為0.1份~10份,更佳為1份~8份。而且,添加至磁石粉末之添加劑附著於磁石粒子之表面,於下述之磁場配向處理中,具有輔助磁石粒子旋動之作用。其結果為,當施加磁場時可容易地進行配向,可將磁石粒子之易磁化軸向統一成同一方向(即,提高配向度)。尤其於在磁石粉末中添加黏合劑之情形時,由於粒子表面存在黏合劑,故配向時之摩擦力增加,粒子之配向性降低, 因此,添加添加劑之效果變得更大。 Further, in order to increase the degree of alignment in the magnetic field alignment step to be performed later, an additive which contributes to alignment may be added to the above compound 12. As the additive which contributes to the alignment, for example, a hydrocarbon-based additive is used, and it is particularly preferable to use an additive having a polarity (specifically, an acid dissociation constant pKa of less than 41). Further, the amount of the additive to be added depends on the particle diameter of the magnet powder, and the smaller the particle diameter of the magnet powder, the more the amount of addition is required. The specific addition amount is 0.1 parts to 10 parts, more preferably 1 part to 8 parts, per part of the magnet powder. Further, the additive added to the magnet powder adheres to the surface of the magnet particles, and has an effect of assisting the rotation of the magnet particles in the magnetic field alignment treatment described below. As a result, the alignment can be easily performed when a magnetic field is applied, and the easy magnetization axes of the magnet particles can be unified in the same direction (that is, the alignment degree is improved). In particular, when a binder is added to the magnet powder, since the binder is present on the surface of the particle, the frictional force at the time of alignment increases, and the orientation of the particles decreases. Therefore, the effect of adding an additive becomes larger.
再者,黏合劑之添加係於包含氮氣、Ar氣體、He氣體等惰性氣體之氛圍下進行。再者,磁石粉末與黏合劑之混合係藉由例如將磁石粉末與黏合劑分別投入至攪拌機並利用攪拌機攪拌而進行。又,為促進混練性,亦可進行加熱攪拌。又,磁石粉末與黏合劑之混合較理想為在包含氮氣、Ar氣體、He氣體等惰性氣體之氛圍下進行。又,尤其於將磁石粉末以濕式法粉碎之情形時,亦可設為如下構成:無需自粉碎所使用之溶劑取出磁石粉末,而將黏合劑添加至溶劑中,並進行混練,其後,使溶劑揮發,而獲得下述之化合物12。 Further, the addition of the binder is carried out in an atmosphere containing an inert gas such as nitrogen, Ar gas or He gas. Further, the mixing of the magnet powder and the binder is carried out by, for example, feeding the magnet powder and the binder to a stirrer and stirring it with a stirrer. Further, in order to promote kneading, heating and stirring may be performed. Further, the mixing of the magnet powder and the binder is preferably carried out in an atmosphere containing an inert gas such as nitrogen gas, Ar gas or He gas. Further, in particular, when the magnet powder is pulverized by a wet method, the magnet powder may be taken out from the solvent used for the pulverization, and the binder may be added to the solvent and kneaded. Thereafter, The solvent was volatilized to obtain the following compound 12.
繼而,藉由將化合物12成形為片狀,而製成胚片。尤其在熱熔塗敷中,藉由加熱化合物12而使化合物12熔融,使之成為液體狀後,塗敷於間隔件等支持基材13上。其後,進行散熱使其凝固,藉此於支持基材13上形成長條片狀之胚片14。再者,將化合物12加熱熔融時之溫度根據所使用之黏合劑之種類或量而不同,但設為50~300℃。惟必須設為較所使用之黏合劑之流動起始溫度更高之溫度。再者,於採用漿料塗敷之情形時,使磁石粉末與黏合劑(進而亦可包含有助於配向之添加劑)分散於大量之溶劑中,將漿料塗敷於間隔件等之支持基材13上。其後,進行乾燥使溶劑揮發,藉此於支持基材13上形成長條片狀之胚片14。 Then, the embryonic sheet was prepared by forming the compound 12 into a sheet shape. In particular, in the hot melt coating, the compound 12 is melted by heating the compound 12 to form a liquid, and then applied to a support substrate 13 such as a separator. Thereafter, heat is radiated to solidify, whereby a long sheet-like lamella 14 is formed on the support substrate 13. Further, the temperature at which the compound 12 is heated and melted differs depending on the type or amount of the binder to be used, but is set to 50 to 300 °C. However, it must be set to a temperature higher than the flow initiation temperature of the binder used. Further, in the case of coating with a slurry, the magnet powder and the binder (which may further contain an additive which contributes to alignment) are dispersed in a large amount of solvent, and the slurry is applied to a support base such as a spacer. On the material 13. Thereafter, drying is carried out to volatilize the solvent, whereby a long sheet-like green sheet 14 is formed on the support substrate 13.
此處,熔融之化合物12之塗敷方式較佳為使用狹縫式模具(Slot die)方式或砑光輥方式等厚度控制性優異之方式。尤其為實現較高之厚度精度,尤其較理想為使用厚度控制性優異之(即,可於基材表面塗敷高精度之厚度之層的方式)壓模方式或刮刀方式。例如,於狹縫式模具方式中,藉由齒輪泵將加熱而成為流體狀之化合物12擠出,並插入至模具,藉此進行塗敷。又,於砑光輥方式中,對已加熱之2根輥之間隙送入固定量之化合物12,一面使輥旋轉,一面於支持基材13 上塗敷因輥之熱而熔融之化合物12。又,作為支持基材13,例如使用聚矽氧處理聚酯膜。進而,較佳為使用消泡劑,或藉由進行加熱真空消泡等,充分地進行消泡處理以不使展開層中殘留有氣泡。又,亦可設為如下構成:不將化合物12塗敷於支持基材13上,而將藉由擠出成型或射出成形而熔融之化合物12成型為片狀,並擠出至支持基材13上,藉此於支持基材13上成形胚片14。 Here, the method of applying the molten compound 12 is preferably a method in which thickness controllability such as a slit die method or a calender roll method is excellent. In particular, in order to achieve high thickness precision, it is particularly preferable to use a stamper method or a doctor blade method which is excellent in thickness controllability (that is, a layer which can apply a layer of high precision to the surface of the substrate). For example, in the slit die method, the compound 12 heated to be fluid is extruded by a gear pump and inserted into a mold to perform coating. Further, in the calender roll method, a fixed amount of the compound 12 is fed into the gap between the two heated rolls, and the roll is rotated while supporting the substrate 13 The compound 12 which is melted by the heat of the roll is applied. Further, as the support substrate 13, for example, a polyester film is treated with polyfluorene. Further, it is preferred to use an antifoaming agent or to perform defoaming treatment by heating vacuum defoaming or the like so as not to leave air bubbles in the developed layer. Further, the compound 12 may be formed into a sheet shape by extrusion molding or injection molding without applying the compound 12 to the support substrate 13, and extruded to the support substrate 13 . Thereby, the green sheet 14 is formed on the support substrate 13.
又,於利用狹縫式模具方式之胚片14之形成步驟中,較理想為實際測量塗敷後之胚片之片厚度,基於實測值,對模具15與支持基材13間之間隙進行反饋控制。又,較理想為極力降低供給至模具15之液體狀之化合物12之量的變動(例如,抑制為±0.1%以下之變動),進而亦極力抑制塗敷速度之變動(例如,抑制為±0.1%以下之變動)。藉此,可進一步提高胚片14之厚度精度。再者,將所要形成之胚片14之厚度精度設為相對於設計值(例如1mm)±10%以內,更佳為±3%以內,進而較佳為±1%以內。再者,於另一砑光輥方式中,藉由同樣基於實測值控制軋光條件,可控制對支持基材13轉印化合物12之膜厚。 Further, in the step of forming the green sheet 14 by the slit mold method, it is preferable to actually measure the sheet thickness of the coated green sheet, and feedback the gap between the mold 15 and the support substrate 13 based on the measured value. control. Further, it is preferable to reduce the fluctuation of the amount of the liquid compound 12 supplied to the mold 15 as much as possible (for example, to suppress the variation of ±0.1% or less), and to suppress the fluctuation of the coating speed as much as possible (for example, the suppression is ±0.1). % change below). Thereby, the thickness precision of the green sheet 14 can be further improved. Further, the thickness accuracy of the green sheet 14 to be formed is set to within ±10% with respect to the design value (for example, 1 mm), more preferably within ±3%, and even more preferably within ±1%. Further, in another calender roll method, the film thickness of the transfer compound 12 to the support substrate 13 can be controlled by controlling the calendering conditions based on the measured values as well.
再者,較理想為將胚片14之設定膜厚於0.05mm~20mm之範圍內進行設定。若使厚度較0.05mm更薄,則由於必須進行多層積層,而會導致生產性降低。 Further, it is preferable to set the thickness of the green sheet 14 to a thickness of 0.05 mm to 20 mm. If the thickness is made thinner than 0.05 mm, it is necessary to carry out multilayer lamination, which leads to a decrease in productivity.
其次,進行藉由上述之熱熔塗敷而形成於支持基材13上之胚片14之磁場配向。具體而言,首先,藉由加熱與支持基材13一起被連續搬送之胚片14,而使胚片14軟化。具體而言,使胚片14軟化至胚片14之黏度成為1~1500Pa‧s,更佳為1~500Pa‧s。藉此,可適當地進行磁場配向。 Next, the magnetic field alignment of the green sheets 14 formed on the support substrate 13 by the above-described hot melt coating is performed. Specifically, first, the green sheet 14 is softened by heating the green sheet 14 which is continuously conveyed together with the support substrate 13. Specifically, the viscosity of the green sheet 14 to the green sheet 14 is 1 to 1500 Pa‧s, more preferably 1 to 500 Pa‧s. Thereby, the magnetic field alignment can be appropriately performed.
再者,加熱胚片14時之溫度及時間係根據所使用之黏合劑之種類或量而不同,但設為例如100~250℃且0.1~60分鐘。但,為使胚片14軟化,必須設為所使用之黏合劑之玻璃轉移點或流動起始溫度以 上之溫度。又,作為加熱胚片14之加熱方式,例如有利用加熱板之加熱方式或將熱媒體(聚矽氧油)用作熱源之加熱方式。其次,藉由對因加熱而軟化之胚片14之面內方向且長度方向施加磁場,而進行磁場配向。施加之磁場之強度設為5000[Oe]~15000[Oe],較佳為10000[Oe]~120000[Oe]。其結果為,胚片14所包含之磁石結晶之C軸(易磁化軸)沿一方向配向。再者,作為施加磁場之方向,亦可對胚片14之面內方向且寬度方向施加磁場。又,亦可設為對複數片胚片14同時施加磁場之構成。 Further, the temperature and time when the green sheet 14 is heated differ depending on the type or amount of the binder to be used, but it is, for example, 100 to 250 ° C and 0.1 to 60 minutes. However, in order to soften the green sheet 14, it must be set to the glass transition point or flow initiation temperature of the adhesive used. The temperature above. Further, as a heating method for heating the green sheet 14, there is, for example, a heating method using a hot plate or a heating method using a heat medium (polyoxygenated oil) as a heat source. Next, magnetic field alignment is performed by applying a magnetic field to the in-plane direction and the longitudinal direction of the green sheet 14 softened by heating. The intensity of the applied magnetic field is set to 5000 [Oe] to 15000 [Oe], preferably 10000 [Oe] to 120,000 [Oe]. As a result, the C-axis (easy magnetization axis) of the magnet crystals included in the green sheet 14 is aligned in one direction. Further, as a direction in which the magnetic field is applied, a magnetic field may be applied to the in-plane direction and the width direction of the green sheet 14. Further, it is also possible to adopt a configuration in which a magnetic field is simultaneously applied to the plurality of green sheets 14.
進而,亦可設為於對胚片14施加磁場時,與加熱步驟同時進行施加磁場之步驟的構成,亦可於進行加熱步驟之後且胚片凝固之前,進行施加磁場之步驟。又,亦可設為於藉由熱熔塗敷而經塗敷之胚片14凝固之前進行磁場配向之構成。於該情形時,無需加熱步驟。 Further, a configuration may be adopted in which a magnetic field is applied to the green sheet 14 and a step of applying a magnetic field simultaneously with the heating step, or a step of applying a magnetic field may be performed after the heating step and before the green sheet is solidified. Further, it is also possible to adopt a configuration in which magnetic field alignment is performed before the coated green sheet 14 is solidified by hot melt coating. In this case, no heating step is required.
接下來,利用圖6對胚片14之加熱步驟及磁場配向步驟進行更詳細之說明。圖6係表示胚片14之加熱步驟及磁場配向步驟之模式圖。再者,於圖6所示之例中,對與加熱步驟同時進行磁場配向步驟之例進行說明。 Next, the heating step and the magnetic field alignment step of the green sheet 14 will be described in more detail with reference to FIG. Fig. 6 is a schematic view showing a heating step and a magnetic field alignment step of the green sheet 14. Further, in the example shown in Fig. 6, an example in which the magnetic field alignment step is performed simultaneously with the heating step will be described.
如圖6所示,針對藉由上述狹縫式模具方式塗敷之胚片14之加熱及磁場配向係對由輥連續搬送之狀態之長條片狀之胚片14進行。即,將用以進行加熱及磁場配向之裝置配置於塗敷裝置(模具等)之下游側,藉由與上述塗敷步驟連續之步驟進行。 As shown in Fig. 6, the heating and the magnetic field alignment of the green sheet 14 applied by the slit die method are performed on the long sheet-shaped green sheets 14 in a state in which the rolls are continuously conveyed. That is, the apparatus for performing heating and magnetic field alignment is disposed on the downstream side of the coating apparatus (mold or the like), and is carried out by a step that is continuous with the coating step.
具體而言,於模具15或塗敷輥22之下游側,以被搬送之支持基材13及胚片14通過螺線管(solenoid)25之方式,配置螺線管25。進而,將加熱板26於螺線管25內相對於胚片14上下一對地配置。繼而,藉由上下一對地配置之加熱板26加熱胚片14,並使電流流動於螺線管25,藉此於長條片狀之胚片14之面內方向(即,平行於胚片14之片面之方向)且長度方向產生磁場。藉此,藉由加熱使被連續搬送之胚片 14軟化,並對軟化之胚片14之面內方向且長度方向(圖6之箭頭27之方向)施加磁場,從而可實現胚片14之適當且均勻之磁場配向。尤其藉由將施加磁場之方向設為面內方向,可防止胚片14之表面起毛。 Specifically, on the downstream side of the mold 15 or the application roller 22, the solenoid 25 is placed such that the supported support substrate 13 and the green sheet 14 pass through a solenoid 25. Further, the heating plate 26 is disposed in the solenoid 25 with respect to the green sheet 14 in a pair. Then, the green sheet 14 is heated by the pair of upper and lower heating plates 26, and an electric current flows through the solenoid 25, thereby being in the in-plane direction of the elongated sheet-like green sheet 14 (i.e., parallel to the green sheet). The direction of the one-sided plane of 14) and the magnetic field is generated in the longitudinal direction. Thereby, the continuously transported embryo is heated by heating The softening 14 applies a magnetic field to the in-plane direction and the longitudinal direction of the softened green sheet 14 (the direction of the arrow 27 in Fig. 6), so that proper and uniform magnetic field alignment of the green sheet 14 can be achieved. In particular, the surface of the green sheet 14 can be prevented from fluffing by setting the direction in which the magnetic field is applied to the in-plane direction.
又,於磁場配向後進行之胚片14之散熱及凝固較佳為於搬送狀態下進行。藉此,可使製作步驟更為效率化。 Further, heat dissipation and solidification of the green sheet 14 after the magnetic field alignment is preferably performed in a conveyed state. Thereby, the production steps can be made more efficient.
再者,於對胚片14之面內方向且寬度方向進行磁場配向時係以於被搬送之胚片14之左右配置一對磁場線圈以代替螺線管25之方式構成。而且,藉由使電流流動於各磁場線圈,可於長條片狀之胚片14之面內方向且寬度方向產生磁場。 Further, when the magnetic field is aligned in the in-plane direction and the width direction of the green sheet 14, a pair of magnetic field coils are disposed on the right and left sides of the transferred green sheet 14 instead of the solenoid 25. Further, by causing a current to flow through the respective field coils, a magnetic field can be generated in the in-plane direction and the width direction of the elongated sheet-like green sheet 14.
又,亦可將磁場配向設為相對於胚片14之面為垂直方向。於沿相對於胚片14之面為垂直方向進行磁場配向時,例如藉由使用磁極片之磁場施加裝置進行。再者,於將磁場配向方向設為相對於胚片14之面為垂直方向之情形時,較佳為相對於胚片14,於積層有支持基材13之相反側之面亦積層膜。藉此,可防止胚片14之表面起毛。 Further, the magnetic field alignment may be set to be perpendicular to the surface of the green sheet 14. When the magnetic field alignment is performed in the vertical direction with respect to the surface of the green sheet 14, it is performed by, for example, a magnetic field applying device using a magnetic pole piece. In the case where the direction in which the magnetic field is aligned is perpendicular to the surface of the green sheet 14, it is preferable to laminate the film on the surface opposite to the side of the support substrate 13 with respect to the green sheet 14. Thereby, the surface of the green sheet 14 can be prevented from fluffing.
又,亦可使用以熱媒體(聚矽氧油)作為熱源之加熱方式以代替利用上述加熱板26之加熱方式。 Further, instead of using the heating method of the heating plate 26, a heating method using a heat medium (polyoxygenated oil) as a heat source may be used.
此處,不採用熱熔成形,而利用一般之狹縫式模具方式或刮刀方式等,藉由漿料等流動性較高之液狀體成形胚片14之情形時,若於產生磁場梯度時搬入胚片14,則胚片14所含有之磁石粉末會被吸引至磁場較強一側,而有產生形成胚片14之漿料之偏液,即產生胚片14之厚度偏差之虞。相對於此,如本發明般藉由熱熔成形將化合物12成形為胚片14之情形時,室溫附近之黏度達到數萬~數十萬Pa‧s,並不會產生磁場梯度通過時之磁性粉末的偏移。進而,被搬送至均勻磁場中,並藉由進行加熱而產生黏合劑之黏度降低,僅藉由均勻磁場中之旋轉轉矩便可實現相同之C軸配向。 Here, in the case where the green sheet is formed by a liquid material having a high fluidity such as a slurry, a general-purpose slit mold method or a doctor blade method is not used, and a magnetic field gradient is generated. When the green sheet 14 is carried, the magnet powder contained in the green sheet 14 is attracted to the stronger magnetic field side, and the liquid phase which causes the slurry forming the green sheet 14 is generated, that is, the thickness deviation of the green sheet 14 is generated. On the other hand, when the compound 12 is formed into the green sheet 14 by hot melt forming as in the present invention, the viscosity at room temperature reaches tens of thousands to hundreds of thousands of Pa‧ s, and no magnetic field gradient is passed. The offset of the magnetic powder. Further, it is conveyed to a uniform magnetic field, and the viscosity of the adhesive is lowered by heating, and the same C-axis alignment can be realized only by the rotational torque in the uniform magnetic field.
又,於不使用熱熔成形,而利用一般之狹縫式模具方式或刮刀 方式等,將含有有機溶劑之漿料等流動性較高之液狀物成形為胚片14之情形時,若欲製成厚度超過1mm之膜,則乾燥時因漿料等所含有之有機溶劑之氣化而產生之氣泡成為問題。進而,若為抑制氣泡而將乾燥時間長時間化,則會產生磁石粉末之沈降,隨之產生相對於重力方向之磁石粉末之密度分佈偏差,從而成為燒成後之翹曲之原因。因此,自漿料之成形中,厚度之上限值實質上受到限制,故必須將胚片14以1mm以下之厚度成形,其後進行積層。但於該情形時,黏合劑彼此之黏合度不足,導致於其後之脫黏合劑步驟(焙燒處理)中產生層間剝離,此成為C軸(易磁化軸)配向性降低,即殘留磁通密度(Br)降低之原因。相對於此,如本發明般藉由熱熔成形將化合物12成形為胚片14之情形時,因不含有機溶劑,故即便製成厚度超過1mm之片材,亦消除如上述般之發泡之擔憂。而且,由於黏合劑處於充分地黏合之狀態,故不存在脫黏合劑步驟中產生層間玻璃之擔憂。 Moreover, instead of using hot melt forming, a general slit die method or a scraper is used. When a liquid material having a high fluidity such as a slurry containing an organic solvent is molded into the green sheet 14 or the like, if a film having a thickness of more than 1 mm is to be formed, the organic solvent contained in the slurry or the like during drying is required. The bubbles generated by the gasification become a problem. Further, if the drying time is prolonged in order to suppress the bubbles, sedimentation of the magnet powder occurs, and a variation in density distribution of the magnet powder with respect to the direction of gravity occurs, which causes warpage after firing. Therefore, since the upper limit of the thickness is substantially limited in the molding from the slurry, the green sheet 14 must be formed to a thickness of 1 mm or less, and then laminated. However, in this case, the adhesion of the adhesives to each other is insufficient, resulting in interlayer peeling in the subsequent debonding step (baking treatment), which results in a decrease in the alignment of the C-axis (easy magnetization axis), that is, the residual magnetic flux density. (Br) Reason for the decrease. On the other hand, when the compound 12 is formed into the green sheet 14 by hot melt forming as in the present invention, since the organic solvent is not contained, even if a sheet having a thickness of more than 1 mm is formed, the foaming as described above is eliminated. Worry. Moreover, since the adhesive is in a state of being sufficiently bonded, there is no fear that interlayer glass is generated in the debonding step.
又,於對複數片胚片14同時施加磁場之情形時,以例如於積層複數片(例如6片)胚片14之狀態下連續搬送,使積層之胚片14通過螺線管25內之方式構成。藉此,可提高生產性。 In the case where a plurality of magnetic sheets are simultaneously applied to the plurality of pieces, the plurality of sheets (for example, six pieces) of the green sheets 14 are continuously conveyed, and the laminated green sheets 14 are passed through the solenoids 25, for example. Composition. Thereby, productivity can be improved.
而且,於藉由圖6所示之方法進行胚片14之磁場配向後,進行胚片14之打孔或變形,藉此形成所期望形狀之成形體31。再者,亦可以磁場配向並非針對胚片14,而係針對進行打孔或變形後之成形體31進行之方式構成。又,磁場配向或成形體31之成形係以實現最終製品所要求之易磁化軸之方向(例如徑向配向、極各向異性配向等)。 Then, after the magnetic field alignment of the green sheet 14 is performed by the method shown in Fig. 6, the green sheet 14 is perforated or deformed, whereby the molded body 31 having a desired shape is formed. Further, the magnetic field alignment may be configured not for the green sheet 14, but also for the molded body 31 after punching or deformation. Further, the magnetic field alignment or formation of the shaped body 31 is such that the direction of the easy axis of magnetization required for the final article (e.g., radial alignment, polar anisotropic alignment, etc.) is achieved.
又,於成形成形體31時,對於配置於旋轉電機時與轉子2之表面接觸之面,形成與形成於轉子2之表面之卡合部3卡合之被卡合部4。被卡合部4例如設為分別形成於轉子2之圓周方向之兩端部之凸狀之腳狀構件。又,被卡合部4亦可與成形體31成形為一體,亦可僅將被卡合部4之部分分開成形。再者,於分開成形之情形時,藉由如圖7所示 利用接著劑、塑化劑、熱壓接等將成形之被卡合部4與成形體31相互接合,而製作成為最終製品形狀之成形體。再者,本發明之製造方法由於使用於磁石粉末中添加黏合劑之胚體成形,故與使用一般之壓粉成形之情形相比,可進行成形體彼此之適當之接合。 Further, when the molded body 31 is molded, the engaged portion 4 that engages with the engaging portion 3 formed on the surface of the rotor 2 is formed on the surface that is placed in contact with the surface of the rotor 2 when placed on the rotary electric machine. The engaged portion 4 is, for example, a convex leg-shaped member that is formed at both end portions of the rotor 2 in the circumferential direction. Further, the engaged portion 4 may be integrally formed with the molded body 31, or only the portion to be engaged by the engaging portion 4 may be separately formed. Furthermore, in the case of separate forming, as shown in FIG. The formed engaged portion 4 and the molded body 31 are joined to each other by an adhesive, a plasticizer, thermocompression bonding or the like to form a molded body having a final product shape. Further, since the production method of the present invention is used for forming an embryo body in which a binder is added to a magnet powder, it is possible to appropriately bond the molded bodies to each other as compared with the case of using a general powder molding.
又,關於因成形成形體31之步驟而產生之胚片14之殘留物部分,可作為藉由加熱至黏合劑之流動起始溫度以上而熔融之化合物12予以再利用。其結果為,再利用之殘留物部分作為胚片14之一部分再生。因此,即便於成形為複雜之形狀之情形時,亦不會使良率降低。 Further, the residue portion of the green sheet 14 which is produced by the step of molding the molded body 31 can be reused as the compound 12 which is melted by heating to a flow initiation temperature of the adhesive or more. As a result, the residue portion to be reused is partially reproduced as one of the green sheets 14. Therefore, even when formed into a complicated shape, the yield is not lowered.
繼而,將成形體31於加壓至大氣壓,或加壓至較大氣壓高或低之壓力(例如1.0Pa或1.0MPa)之非氧化性氛圍(尤其於本發明中,為氫氣氛圍或氫氣與惰性氣體之混合氣體氛圍)下,以黏合劑分解溫度保持數小時~數十小時(例如5小時),藉此進行焙燒處理。於氫氣氛圍下進行之情形時,例如將焙燒中之氫之供給量設為5L/min。藉由進行焙燒處理,可藉由解聚反應等使黏合劑等有機化合物分解為單體並使其分散而去除。即,可進行使成形體31中之碳量降低之所謂脫碳。又,焙燒處理係設為將成形體31中之碳量設為2000ppm以下,更佳為1000ppm以下之條件下進行。藉此,於其後之燒結處理中可對成形體31整體緻密地進行燒結,從而抑制殘留磁通密度或保磁力之降低。又,於將進行上述燒結處理時之加壓條件以高於大氣壓之壓力進行時,較理想為設為15MPa以下。再者,若將加壓條件設為高於大氣壓之壓力,更具體而言設為0.2MPa以上,則尤其可期待碳量降低之效果。 Then, the shaped body 31 is pressurized to atmospheric pressure, or pressurized to a high pressure or low pressure (for example, 1.0 Pa or 1.0 MPa) in a non-oxidizing atmosphere (especially in the present invention, hydrogen atmosphere or hydrogen and inertness). In the mixed gas atmosphere of the gas, the baking treatment is carried out at a binder decomposition temperature for several hours to several tens of hours (for example, five hours). In the case of performing under a hydrogen atmosphere, for example, the supply amount of hydrogen in the baking is set to 5 L/min. By performing the calcination treatment, an organic compound such as a binder can be decomposed into a monomer by a depolymerization reaction or the like and dispersed. That is, so-called decarburization which reduces the amount of carbon in the molded body 31 can be performed. In addition, the calcination treatment is carried out under the conditions that the amount of carbon in the molded body 31 is 2,000 ppm or less, more preferably 1,000 ppm or less. Thereby, the entire molded body 31 can be densely sintered in the subsequent sintering treatment, thereby suppressing a decrease in residual magnetic flux density or coercive force. Moreover, when the pressurization condition at the time of performing the said sintering process is carried out by the pressure of the atmospheric pressure, it is preferable to set it as 15 MPa or less. In addition, when the pressure condition is set to a pressure higher than atmospheric pressure, more specifically, 0.2 MPa or more, the effect of lowering the carbon amount can be expected.
再者,黏合劑分解溫度係基於黏合劑分解生成物及分解殘渣之分析結果而決定。具體而言,收集黏合劑之分解生成物,選擇不生成單體以外之分解生成物,且於殘渣之分析中亦不會檢測出因殘留之黏合劑成分之副反應而產生之生成物的溫度範圍。雖根據黏合劑之種類 而不同,但設為200℃~900℃,更佳為400℃~600℃(例如450℃)。 Further, the binder decomposition temperature is determined based on the analysis results of the binder decomposition product and the decomposition residue. Specifically, the decomposition product of the binder is collected, and the decomposition product other than the monomer is selected, and the temperature of the product due to the side reaction of the remaining binder component is not detected in the analysis of the residue. range. Depending on the type of adhesive The difference is, but it is set to 200 ° C ~ 900 ° C, more preferably 400 ° C ~ 600 ° C (for example, 450 ° C).
又,上述焙燒處理較佳為,與進行一般之磁石之燒結之情形相比,降低升溫速度。具體而言,將升溫速度設為2℃/min以下(例如1.5℃/min)。因此,於進行焙燒處理時,如圖8所示以2℃/min以下之特定昇溫速度升溫,於達到預先設定之設定溫度(黏合劑分解溫度)後,以該設定溫度保持數小時~數十小時,藉此進行焙燒處理。如上所述,藉由於焙燒處理中降低升溫速度,而不會急遽地去除成形體31中之碳,而係階段性地去除,故可提高燒結後之永久磁石之密度(即,減少永久磁石中之空隙)。而且,若將升溫速度設為2℃/min以下,則可將燒結後之永久磁石之密度設為95%以上,而可期待較高之磁石特性。 Further, it is preferable that the calcination treatment lowers the temperature increase rate as compared with the case where the general magnet is sintered. Specifically, the temperature increase rate is set to 2 ° C / min or less (for example, 1.5 ° C / min). Therefore, when the baking treatment is performed, the temperature is raised at a specific temperature increase rate of 2 ° C/min or less as shown in FIG. 8 , and after reaching a predetermined set temperature (adhesive decomposition temperature), the set temperature is maintained for several hours to several tens of times. In this case, the baking treatment is performed. As described above, by lowering the temperature increase rate in the calcination process, the carbon in the formed body 31 is not removed violently, but is removed stepwise, so that the density of the permanent magnet after sintering can be increased (i.e., the permanent magnet is reduced). The gap). In addition, when the temperature increase rate is 2 ° C / min or less, the density of the permanent magnet after sintering can be made 95% or more, and high magnet characteristics can be expected.
又,亦可藉由將經焙燒處理而被焙燒之成形體31繼而保持於真空氛圍下,而進行脫氫處理。脫氫處理係藉由使利用焙燒處理而生成之成形體31中之NdH3(活性度大),自NdH3(活性度大)→HdH2(活性度小)階段性變化,而降低通過焙燒處理被活性化之成形體31之活性度。藉此,即便將通過焙燒處理被焙燒之成形體31於其後移動至大氣中時,亦可防止Nd與氧之結合,抑制殘留磁通密度或保磁力之降低。又,亦可期待使磁石結晶之結構自NdH2等恢復至Nd2Fe14B結構之效果。 Further, the molded body 31 calcined by the calcination treatment may be further subjected to a dehydrogenation treatment by being maintained in a vacuum atmosphere. In the dehydrogenation treatment, NdH 3 (large activity) in the molded body 31 produced by the calcination treatment is gradually changed from NdH 3 (large activity) to HdH 2 (small activity), and the calcination is lowered. The activity of the activated molded body 31 is treated. Thereby, even when the molded body 31 fired by the baking process is moved to the atmosphere thereafter, the bonding of Nd and oxygen can be prevented, and the reduction of the residual magnetic flux density or the coercive force can be suppressed. Further, an effect of restoring the structure of the magnet crystal from NdH 2 or the like to the Nd 2 Fe 14 B structure can be expected.
繼而,進行將經焙燒處理而被焙燒之成形體31燒結之燒結處理。再者,作為成形體31之燒結方法,有真空中之無加壓燒結、以沿單軸向加壓之狀態進行燒結之單軸加壓燒結、以沿雙軸向加壓之狀態進行燒結之雙軸加壓燒結、以各向同性加壓狀態進行燒結之各向同性加壓燒結等。例如,使用於將成形體31配置於轉子2之表面時,以朝成為與轉子2之軸向為相同方向之方向加壓之狀態進行燒結的單軸加壓燒結。又,作為加壓燒結,例如有熱壓燒結、熱均壓加壓(HIP)燒 結、超高壓合成燒結、氣體加壓燒結、放電電漿(SPS)燒結等。但,較佳為使用可沿單軸向加壓且藉由通電燒結進行燒結之SPS燒結。再者,於利用SPS燒結進行燒結之情形時,較佳為將加熱值例如設為0.01MPa~100MPa,於數Pa以下之真空氛圍下,以10℃/分鐘上升至940℃,其後保持5分鐘。其後,進行冷卻,並再次以300℃~1000℃進行2小時熱處理。於是,燒結之結果,可製造燒結體32。 Then, a sintering treatment for sintering the molded body 31 fired by the baking treatment is performed. In addition, as a sintering method of the molded body 31, there is a uniaxial pressure sintering in which vacuum is sintered in a state of being pressed in a uniaxial direction, and sintering is performed in a state of being pressed in a biaxial direction. Biaxial pressure sintering, isotropic pressure sintering in which the sintering is performed in an isotropic state, and the like. For example, when the molded body 31 is placed on the surface of the rotor 2, uniaxial pressure sintering is performed in a state of being pressed in a direction in which the axial direction of the rotor 2 is in the same direction. Further, as the pressure sintering, there are, for example, hot press sintering and hot pressure pressurization (HIP) burning. Knot, ultra-high pressure synthetic sintering, gas pressure sintering, discharge plasma (SPS) sintering, and the like. However, it is preferred to use SPS sintering which can be pressed in a single axial direction and sintered by electric conduction sintering. Further, in the case of sintering by SPS sintering, it is preferred to set the heating value to, for example, 0.01 MPa to 100 MPa, and to increase the temperature to 10 ° C/min to 940 ° C in a vacuum atmosphere of several Pa or less, and thereafter to maintain 5 minute. Thereafter, cooling was performed, and heat treatment was again performed at 300 ° C to 1000 ° C for 2 hours. Thus, as a result of the sintering, the sintered body 32 can be produced.
其後,將燒結體32沿著C軸進行磁化。其結果為,可製造永久磁石1。再者,永久磁石1之磁化中例如使用磁化線圈、磁化軛(Magnetizing yoke)、電容器式磁化電源裝置等。再者,永久磁石1之磁化亦可如下所述設為於配置於旋轉電機之轉子2後進行之構成。 Thereafter, the sintered body 32 is magnetized along the C axis. As a result, the permanent magnet 1 can be manufactured. Further, for the magnetization of the permanent magnet 1, for example, a magnetizing coil, a magnetizing yoke, a capacitor type magnetizing power supply device, or the like is used. Further, the magnetization of the permanent magnet 1 may be configured as follows after being disposed in the rotor 2 of the rotating electrical machine.
接下來,對將利用上述製造方法製造之永久磁石1配置於轉子表面之SPM馬達之製造方法進行說明。 Next, a method of manufacturing an SPM motor in which the permanent magnet 1 manufactured by the above-described manufacturing method is disposed on the surface of the rotor will be described.
首先,如圖9所示,於轉子2之表面配置複數個永久磁石1。再者,於將永久磁石1配置於轉子2時,使形成於轉子2之卡合部3與形成於永久磁石1之被卡合部4卡合。藉此,可將永久磁石1對於轉子2準確地定位於設計位置。其後,利用接著劑等將轉子2與配置於表面之永久磁石1相互固定。 First, as shown in FIG. 9, a plurality of permanent magnets 1 are disposed on the surface of the rotor 2. Further, when the permanent magnet 1 is placed on the rotor 2, the engaging portion 3 formed in the rotor 2 is engaged with the engaged portion 4 formed in the permanent magnet 1. Thereby, the permanent magnet 1 can be accurately positioned for the rotor 2 at the design position. Thereafter, the rotor 2 and the permanent magnet 1 disposed on the surface are fixed to each other by an adhesive or the like.
其後,組裝軸42或定子43等除轉子2以外之構件。藉此,可製造SPM馬達45。 Thereafter, members other than the rotor 2 such as the shaft 42 or the stator 43 are assembled. Thereby, the SPM motor 45 can be manufactured.
如以上說明般,本實施形態之永久磁石1及永久磁石1之製造方法係將磁石原料粉碎為磁石粉末,藉由將粉碎而成之磁石粉末與黏合劑進行混合,而生成漿料12。然後,將生成之漿料12成形為片狀而製作胚片14。其後,自成形之胚片14成形成形體31,且將成形體31進行燒結,藉此製造永久磁石1,該成形體31於與轉子2之表面接觸之面形成與形成於轉子2之表面之卡合部3卡合之被卡合部4。其結果為,藉由使卡合部3與被卡合部4卡合,可將永久磁石1對於轉子2準確地定位 於預先設計之位置。又,由於可增大永久磁石1與轉子2之接觸面積,故可將永久磁石1對於轉子2牢固地固定。其結果為,即便於轉子2高速旋轉之情形時,亦可防止永久磁石1相對於轉子2之位置偏移之產生。 As described above, in the manufacturing method of the permanent magnet 1 and the permanent magnet 1 of the present embodiment, the magnet raw material is pulverized into a magnet powder, and the pulverized magnet powder and the binder are mixed to form the slurry 12. Then, the produced slurry 12 is formed into a sheet shape to produce a green sheet 14. Thereafter, the formed body 31 is molded from the formed green sheet 14, and the formed body 31 is sintered, whereby the permanent magnet 1 is formed, and the formed body 31 is formed on the surface in contact with the surface of the rotor 2 and formed on the surface of the rotor 2. The engaged portion 3 is engaged with the engaged portion 4. As a result, the permanent magnet 1 can be accurately positioned with respect to the rotor 2 by engaging the engaging portion 3 with the engaged portion 4. In a pre-designed location. Further, since the contact area between the permanent magnet 1 and the rotor 2 can be increased, the permanent magnet 1 can be firmly fixed to the rotor 2. As a result, even when the rotor 2 is rotated at a high speed, the positional deviation of the permanent magnet 1 with respect to the rotor 2 can be prevented.
又,由於藉由成形將磁石粉末與黏合劑混合而成之混合物而形成成形體,故與使用先前之壓粉成形等之情形相比,配向後磁石粒子亦不會旋動,且亦可提高配向度。又,於針對磁石粉末與黏合劑之混合物進行磁場配向時,由於可利用電流匝數,故可確保進行磁場配向時之磁場強度較大,且由於以靜磁場實施長時間之磁場施加,故可實現偏差較少之較高之配向度。進而,可實現偏差較少之較高之配向度關係到因燒結引起之收縮之偏差的減少。即,可確保燒結後之製品形狀之均勻性。其結果為,可減輕燒結後之對外形加工之負擔。而且,與先前之壓粉成形相比,可容易地成形被卡合部4,且成形之被卡合部4於其後之製造步驟中不會產生較大程度之變形,故可適當地進行卡合部3與被卡合部4之卡合。 Further, since the molded body is formed by mixing a mixture of the magnet powder and the binder by molding, the magnet particles after the alignment are not rotated and can be improved as compared with the case of using the previous powder molding or the like. Orientation. Further, when the magnetic field is aligned with the mixture of the magnet powder and the binder, since the current is used, the magnetic field strength during the magnetic field alignment can be ensured to be large, and since the magnetic field is applied for a long time by the static magnetic field, Achieve a higher degree of alignment with less deviation. Further, it is possible to achieve a higher degree of alignment with less variation and a decrease in deviation due to shrinkage due to sintering. That is, the uniformity of the shape of the product after sintering can be ensured. As a result, the burden on the profile processing after sintering can be alleviated. Moreover, the engaged portion 4 can be easily formed as compared with the prior art powder forming, and the formed engaged portion 4 does not undergo a large degree of deformation in the subsequent manufacturing steps, so that it can be appropriately performed. The engaging portion 3 is engaged with the engaged portion 4.
又,由於以朝成為與轉子2之軸向同方向之方向對成形體31加壓之狀態進行燒結,故因燒結引起之收縮變得均勻,藉此可防止產生燒結後之翹曲或凹陷等變形。其結果為,即便於永久磁石1具有形成有被卡合部4之複雜形狀之情形時,亦可精度良好地製造永久磁石1。 In addition, since the sintered body is pressed in a state in which the molded body 31 is pressed in the same direction as the axial direction of the rotor 2, the shrinkage due to sintering is uniform, thereby preventing warpage or depression after sintering. Deformation. As a result, even when the permanent magnet 1 has a complicated shape in which the engaged portion 4 is formed, the permanent magnet 1 can be manufactured with high precision.
又,即便於將磁石粉末與黏合劑之混合物加工為形狀複雜之成形體31之情形時,亦由於可將因加工而產生之殘留物部分再生為混合物之一部分,故可防止良率之降低。 Further, even when the mixture of the magnet powder and the binder is processed into the molded article 31 having a complicated shape, since the residue due to the processing can be partially regenerated into a part of the mixture, the decrease in the yield can be prevented.
又,藉由對永久磁石1設置複數個被卡合部4,可將永久磁石1對於轉子2牢固地固定。其結果為,即便於轉子2高速旋轉之情形時,亦可防止產生永久磁石1相對於轉子2之位置偏移。 Further, by providing a plurality of engaged portions 4 for the permanent magnet 1, the permanent magnet 1 can be firmly fixed to the rotor 2. As a result, even when the rotor 2 is rotated at a high speed, the positional displacement of the permanent magnet 1 with respect to the rotor 2 can be prevented.
又,本實施形態之將永久磁石1配置於表面之旋轉電機與先前相 比,可實現高轉矩化、小型化、低轉矩脈動化、及高效率化。 Further, in the present embodiment, the rotating magnet and the previous phase in which the permanent magnet 1 is disposed on the surface In comparison, high torque, miniaturization, low torque ripple, and high efficiency can be achieved.
再者,當然,本發明並非限定於上述實施例,而可在不脫離本發明之主旨之範圍內進行各種改良、變化。 It is a matter of course that the present invention is not limited to the above-described embodiments, and various modifications and changes can be made without departing from the spirit and scope of the invention.
例如,磁石粉末之粉碎條件、混練條件、成形條件、磁場配向步驟、焙燒條件、燒結條件等並非限定於上述實施例所記載之條件。例如,上述實施例中係藉由使用珠磨機之濕式粉碎而粉碎磁石原料,但亦可設為藉由使用噴射磨機之乾式粉碎進行粉碎。又,進行焙燒時之氛圍只要為非氧化性氛圍,則亦可於除氫氣氛圍以外之氛圍(例如氮氣氛圍、He氛圍或Ar氛圍等)下進行。又,亦可省略焙燒處理。於該情形時,於燒結處理之過程中進行脫碳。 For example, the pulverization conditions, the kneading conditions, the molding conditions, the magnetic field alignment step, the baking conditions, the sintering conditions, and the like of the magnet powder are not limited to the conditions described in the above examples. For example, in the above embodiment, the magnet raw material is pulverized by wet pulverization using a bead mill, but it may be pulverized by dry pulverization using a jet mill. Further, the atmosphere at the time of baking may be carried out in an atmosphere other than a hydrogen atmosphere (for example, a nitrogen atmosphere, a He atmosphere, or an Ar atmosphere) as long as it is a non-oxidizing atmosphere. Further, the baking treatment may be omitted. In this case, decarburization is carried out during the sintering process.
又,於上述實施例中,於成形磁石粉末後,在氫氣氛圍或氫氣與惰性氣體之混合氣體氛圍下進行焙燒,但亦可設為對成形前之磁石粉末進行焙燒處理,將焙燒體即磁石粉末成形為成形體,其後進行燒結,藉此製造永久磁石。若設為此種構成,則由於對粉末狀之磁石粒子進行焙燒,故與對成形後之磁石粒子進行焙燒之情形相比,可增大成為焙燒對象之磁石之表面積。即,可更確實地降低焙燒體中之碳量。但,為於焙燒處理中使黏合劑熱分解,較理想為於成形後進行焙燒處理。 Further, in the above embodiment, after the magnet powder is molded, it is calcined in a hydrogen gas atmosphere or a mixed gas atmosphere of hydrogen gas and an inert gas, but the magnet powder before molding may be calcined to form a calcined body, that is, a magnet. The powder is shaped into a shaped body, which is then sintered, thereby producing a permanent magnet. According to this configuration, since the powdery magnet particles are fired, the surface area of the magnet to be fired can be increased as compared with the case where the magnet particles after molding are fired. That is, the amount of carbon in the calcined body can be more reliably reduced. However, in order to thermally decompose the binder during the baking treatment, it is preferred to carry out the calcination treatment after the molding.
又,本發明之永久磁石除可應用於馬達以外,亦可應用於發電機或磁減速機等各種旋轉電機。又,將本發明之旋轉電機應用於磁減速機之情形時,設為具備2個轉子之雙轉子(dual-Rotor)型,可由包含磁性材料之特定數量之磁極片代替定子芯或繞線而構成定子43。 Further, the permanent magnet of the present invention can be applied to various rotating electrical machines such as a generator or a magnetic reducer in addition to the motor. Further, when the rotary electric machine of the present invention is applied to a magnetic reducer, it is a dual-rotor type having two rotors, and a stator core or a winding may be replaced by a specific number of magnetic pole pieces including a magnetic material. The stator 43 is constructed.
又,本發明中,已列舉Nd-Fe-B系磁石為例進行說明,但亦可使用其他磁石(例如釤系鈷磁石、鋁鎳鈷磁石、鐵氧體磁石等)。又,磁石之合金組成在本發明中設為Nd成分大於計量組成,但亦可設為計量組成。 Further, in the present invention, an Nd-Fe-B-based magnet has been described as an example, but other magnets (for example, lanthanum-cobalt magnet, alnico magnet, ferrite magnet, or the like) may be used. Further, in the present invention, the alloy composition of the magnet is such that the Nd component is larger than the metering composition, but may be a metering composition.
1‧‧‧永久磁石 1‧‧‧ permanent magnet
2‧‧‧轉子 2‧‧‧Rotor
3‧‧‧卡合部 3‧‧‧Clock Department
4‧‧‧被卡合部 4‧‧‧Be jammed
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| JP2014107989A JP2015226337A (en) | 2014-05-26 | 2014-05-26 | Permanent magnet for rotating electrical machine, method for manufacturing permanent magnet for rotating electrical machine, rotating electrical machine, and method for manufacturing rotating electrical machine |
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| TWI798009B (en) * | 2021-02-25 | 2023-04-01 | 日商日本電產股份有限公司 | Rotor and IPM motor including the rotor |
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| EP3518258A4 (en) * | 2016-09-23 | 2020-06-24 | Nitto Denko Corporation | Method for manufacturing sintered body for forming sintered magnet, and method for manufacturing permanent magnet using sintered body for forming sintered magnet |
| EP4254738A4 (en) * | 2020-11-25 | 2024-01-03 | Mitsubishi Electric Corporation | PERMANENT MAGNET SYNCHRONOUS MOTOR |
| WO2023026372A1 (en) * | 2021-08-24 | 2023-03-02 | 川崎重工業株式会社 | Rotor and motor |
| CN114977571A (en) * | 2022-05-31 | 2022-08-30 | 中国石油大学(华东) | Surface-mounted permanent magnet positioning structure of permanent magnet synchronous motor |
| DE102023121470A1 (en) * | 2023-08-10 | 2025-02-13 | Mimplus Technologies Gmbh & Co. Kg | Process for producing a raw magnet |
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| JP4311063B2 (en) * | 2003-03-27 | 2009-08-12 | パナソニック株式会社 | Anisotropic rare earth bonded magnet and motor |
| EP2685470A4 (en) * | 2011-06-24 | 2015-04-29 | Nitto Denko Corp | Rare earth permanent magnet and method for manufacturing rare earth permanent magnet |
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