TW201344881A - Semiconductor integrated structure - Google Patents
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- TW201344881A TW201344881A TW101113468A TW101113468A TW201344881A TW 201344881 A TW201344881 A TW 201344881A TW 101113468 A TW101113468 A TW 101113468A TW 101113468 A TW101113468 A TW 101113468A TW 201344881 A TW201344881 A TW 201344881A
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- 239000004065 semiconductor Substances 0.000 title description 6
- 229910052751 metal Inorganic materials 0.000 claims abstract description 53
- 239000002184 metal Substances 0.000 claims abstract description 53
- 239000000758 substrate Substances 0.000 claims abstract description 43
- 238000002955 isolation Methods 0.000 claims description 10
- 239000010410 layer Substances 0.000 description 199
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- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 4
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- 229910004298 SiO 2 Inorganic materials 0.000 description 3
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- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
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- 229910000449 hafnium oxide Inorganic materials 0.000 description 2
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 2
- 229910052451 lead zirconate titanate Inorganic materials 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- KJXBRHIPHIVJCS-UHFFFAOYSA-N oxo(oxoalumanyloxy)lanthanum Chemical compound O=[Al]O[La]=O KJXBRHIPHIVJCS-UHFFFAOYSA-N 0.000 description 2
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- 239000010703 silicon Substances 0.000 description 2
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910004129 HfSiO Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910020684 PbZr Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 1
- LEVVHYCKPQWKOP-UHFFFAOYSA-N [Si].[Ge] Chemical compound [Si].[Ge] LEVVHYCKPQWKOP-UHFFFAOYSA-N 0.000 description 1
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- KQHQLIAOAVMAOW-UHFFFAOYSA-N hafnium(4+) oxygen(2-) zirconium(4+) Chemical compound [O--].[O--].[O--].[O--].[Zr+4].[Hf+4] KQHQLIAOAVMAOW-UHFFFAOYSA-N 0.000 description 1
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(iv) oxide Chemical compound O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 1
- HFGPZNIAWCZYJU-UHFFFAOYSA-N lead zirconate titanate Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Zr+4].[Pb+2] HFGPZNIAWCZYJU-UHFFFAOYSA-N 0.000 description 1
- 238000001459 lithography Methods 0.000 description 1
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- 150000004706 metal oxides Chemical class 0.000 description 1
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
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- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910003468 tantalcarbide Inorganic materials 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- MAKDTFFYCIMFQP-UHFFFAOYSA-N titanium tungsten Chemical compound [Ti].[W] MAKDTFFYCIMFQP-UHFFFAOYSA-N 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- -1 yttrium oxide tetraethoxy decane Chemical compound 0.000 description 1
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
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- Semiconductor Integrated Circuits (AREA)
Abstract
Description
本發明係關於一種半導體的整合結構,特別是一種半導體的整合結構,其結構能同時整合金屬閘極之電晶體以及電阻。The present invention relates to an integrated structure of a semiconductor, and more particularly to an integrated structure of a semiconductor, the structure of which can simultaneously integrate a transistor of a metal gate and a resistor.
在半導體產業中,為了提升電晶體的操作效率,現已有利用金屬作為電晶體控制閘極之方式。金屬閘極具有低的電阻與無空乏效應等優點,可以改善傳統閘極使用高電阻的多晶矽材料所造成的操作效能不佳等缺點。金屬閘極可概分為前閘極(gate first)製程與後閘極(gate last)製程,其中後閘極製程又因符合金屬材料的熱預算,以及可提供較寬的材料選擇等原因,逐漸地取代了前閘極製程。In the semiconductor industry, in order to improve the operational efficiency of the transistor, there has been a way of using metal as a transistor to control the gate. The metal gate has the advantages of low resistance and no depletion effect, and can improve the shortcomings such as poor operation performance caused by the use of high-resistance polysilicon material in the conventional gate. The metal gate can be roughly divided into a gate first process and a gate last process, wherein the back gate process is in accordance with the thermal budget of the metal material and provides a wider material selection. Gradually replaced the front gate process.
另外,在積體電路中,常需要加入電阻等其它電路元件的設置,來做穩壓或濾雜訊等功能。而電阻其主體一般來說亦係利用多晶矽、摻雜區或金屬氧化物來製作。In addition, in the integrated circuit, it is often necessary to add settings of other circuit components such as resistors to perform functions such as voltage stabilization or noise filtering. The main body of the resistor is generally made of polycrystalline germanium, doped regions or metal oxides.
由於積體電路製程的高複雜度以及各式元件產品的高精密性,因此在追求良率的不斷提昇時,除了嘗試改良製程技術之外,對製程整合的需求亦是相當重要的一環,以減少製程步驟並同時提升生產效率。因此,業界仍然需要一種可成功整合電阻以及具有金屬閘極之電晶體之製作方法。Due to the high complexity of the integrated circuit process and the high precision of various component products, in addition to trying to improve the process technology, the demand for process integration is also an important part in the pursuit of improvement in yield. Reduce process steps while increasing productivity. Therefore, there is still a need in the industry for a method of fabricating a transistor that successfully integrates a resistor and has a metal gate.
根據本發明之一實施例,本發明提供了一種整合結構,包含一基底、一內層介電層、一電晶體以及一電阻。基底上定義有一電阻區以及一主動區。內層介電層直接覆蓋在該基底上。電晶體設置於內層介電層中的主動區,且電晶體包含有一金屬閘極。電阻設置在內層介電層上的電阻區中,且電阻直接接觸內層介電層。According to an embodiment of the invention, the present invention provides an integrated structure comprising a substrate, an inner dielectric layer, a transistor, and a resistor. A resistive region and an active region are defined on the substrate. The inner dielectric layer directly covers the substrate. The transistor is disposed in the active region in the inner dielectric layer, and the transistor includes a metal gate. A resistor is disposed in the resistive region on the inner dielectric layer and the resistor directly contacts the inner dielectric layer.
根據本發明另一實施例,本發明提供了一種整合結構,包含一基底、一內層介電層、一電晶體、一電阻、一虛擬電阻以及一接觸插栓。基底定義有一電阻區以及一主動區。內層介電層直接覆蓋在基底上。電晶體設置於內層介電層中的主動區,且電晶體包含有一金屬閘極。電阻設置在內層介電層上的電阻區中,且直接接觸內層介電層。虛擬電阻設置在內層介電層中的電阻區中,虛擬電阻中設置有至少一金屬層。接觸插栓穿過電阻並直接接觸在虛擬電阻中的金屬層。According to another embodiment of the present invention, the present invention provides an integrated structure including a substrate, an inner dielectric layer, a transistor, a resistor, a dummy resistor, and a contact plug. The substrate defines a resistive region and an active region. The inner dielectric layer directly covers the substrate. The transistor is disposed in the active region in the inner dielectric layer, and the transistor includes a metal gate. The resistor is disposed in the resistive region on the inner dielectric layer and directly contacts the inner dielectric layer. The dummy resistor is disposed in the resistive region in the inner dielectric layer, and at least one metal layer is disposed in the dummy resistor. The contact plug passes through the resistor and directly contacts the metal layer in the dummy resistor.
根據本發明又一實施例,本發明提供了一種整合結構。整合結構包含一基底、一內層介電層、一電晶體以及一電阻。基底定義有一電阻區以及一主動區。內層介電層直接覆蓋在基底上。一電晶體設置於內層介電層中的主動區,且電晶體包含有一金屬閘極。電阻設置於內層介電層中的電阻區中,其中電阻包含一U型金屬層。According to still another embodiment of the present invention, the present invention provides an integrated structure. The integrated structure includes a substrate, an inner dielectric layer, a transistor, and a resistor. The substrate defines a resistive region and an active region. The inner dielectric layer directly covers the substrate. A transistor is disposed in the active region of the inner dielectric layer, and the transistor includes a metal gate. The resistor is disposed in a resistive region in the inner dielectric layer, wherein the resistor comprises a U-shaped metal layer.
本發明的整合結構係和傳統的金屬閘極電晶體的製程一起製作,故可省略多道步驟,並能節省製作成本。The integrated structure of the present invention is fabricated together with the process of a conventional metal gate transistor, so that multiple steps can be omitted and manufacturing costs can be saved.
為使熟習本發明所屬技術領域之一般技藝者能更進一步了解本發明,下文特列舉本發明之數個較佳實施例,並配合所附圖式,詳細說明本發明的構成內容及所欲達成之功效。The present invention will be further understood by those skilled in the art to which the present invention pertains. The effect.
請參考第1圖至第6圖,所繪示為本發明第一實施例中形成電阻的步驟示意圖。如第1圖所示,首先提供一基底300。基底300可以是矽基底(silicon substrate)、磊晶矽(epitaxial silicon substrate)、矽鍺半導體基底(silicon germanium substrate)、碳化矽基底(silicon carbide substrate)或矽覆絕緣(silicon-on-insulator,SOI)基底等,但不以上述為限。基底300上定義有一主動區400,後續用以形成電晶體,以及一電阻區500,後續用以形成電阻。基底300中具有複數個淺溝渠隔離(shallow trench isolation,STI)302,其中部份的淺溝渠隔離302會包圍主動區400,而部份的淺溝渠隔離302則會形成在電阻區500中。然後,進行多道的半導體製程,以在主動區400中形成一電晶體402,以及在電阻區500中同時形成一虛擬電阻502。於本發明之一實施例中,電晶體402具有一介質層404、一犧牲層406、一蓋層408、一側壁子410以及一源極/汲極區412;而虛擬電阻502同樣具有一介質層504、一犧牲層506、一蓋層508、一側壁子510。於本發明較佳實施例中,介質層404與介質層504例如是二氧化矽(SiO2),犧牲層406與犧牲層506例如是多晶矽,蓋層408與蓋層508例如是氮化矽(SiN),側壁子410與側壁子510例如是氮化矽等材料之單層或多層結構,源極/汲極區412則是以適當的摻質形成在基底300中。值得注意的是,本實施例的電晶體402的各元件材質並不限於前述,且本實施例的電晶體402亦可能包含其他結構,例如金屬矽化物層(salicide)、或是其他一層或多層之保護膜等,其為本領域具有通常知識者熟知,在此不加以贅述。在形成了電晶體402與虛擬電阻502後,接著在基底300上形成一接觸洞蝕刻停止層(contact etch stop layer,CESL) 304覆蓋在電晶體402以及虛擬電阻502上。Please refer to FIG. 1 to FIG. 6 , which are schematic diagrams showing the steps of forming a resistor in the first embodiment of the present invention. As shown in Fig. 1, a substrate 300 is first provided. The substrate 300 may be a silicon substrate, an epitaxial silicon substrate, a silicon germanium substrate, a silicon carbide substrate, or a silicon-on-insulator (SOI). Base, etc., but not limited to the above. An active region 400 is defined on the substrate 300 for subsequent formation of a transistor and a resistive region 500 for subsequent formation of a resistor. The substrate 300 has a plurality of shallow trench isolation (STI) 302, wherein a portion of the shallow trench isolation 302 surrounds the active region 400, and a portion of the shallow trench isolation 302 is formed in the resistive region 500. Then, a plurality of semiconductor processes are performed to form a transistor 402 in the active region 400, and a dummy resistor 502 is simultaneously formed in the resistance region 500. In one embodiment of the invention, the transistor 402 has a dielectric layer 404, a sacrificial layer 406, a cap layer 408, a sidewall sub-410, and a source/drain region 412; and the dummy resistor 502 also has a dielectric. A layer 504, a sacrificial layer 506, a cap layer 508, and a sidewall spacer 510. In a preferred embodiment of the present invention, dielectric layer 404 and dielectric layer 504 are, for example, hafnium oxide (SiO 2 ), sacrificial layer 406 and sacrificial layer 506 are, for example, polysilicon, and cap layer 408 and cap layer 508 are, for example, tantalum nitride ( SiN), the sidewall spacer 410 and the sidewall spacer 510 are, for example, a single layer or a multilayer structure of a material such as tantalum nitride, and the source/drain region 412 is formed in the substrate 300 with a suitable dopant. It should be noted that the material of each element of the transistor 402 of the present embodiment is not limited to the foregoing, and the transistor 402 of the embodiment may also include other structures, such as a salicide layer or other layers or layers. The protective film or the like is well known to those skilled in the art and will not be described herein. After the transistor 402 and the dummy resistor 502 are formed, a contact etch stop layer (CESL) 304 is then formed over the substrate 300 over the transistor 402 and the dummy resistor 502.
如第2圖所示,在接觸洞蝕刻停止層304上形成一內層介電層(inter-layer dielectric,ILD)306。於一實施例中,內層介電層306例如是氧化矽(SiO2)、摻雜氧化矽四乙氧基矽烷(TEOS)、電漿增強式四乙氧基矽烷(PETEOS)或是其他低介電常數的介電層。接著進行一平坦化製程,例如一化學機械平坦化(chemical mechanical polish,CMP)製程或者一回蝕刻製程或兩者的組合,以依序移除部份的內層介電層306、部份的接觸洞蝕刻停止層304,部份的側壁子410、部份的側壁子510,並完全移除蓋層408、蓋層508,直到暴露出電晶體402中之犧牲層406以及虛擬電阻502中之犧牲層506。然後,進行一乾蝕刻製程及/或溼蝕刻製程,以移除電晶體402中之犧牲層406以及虛擬電阻502中之犧牲層506,以分別在主動區400形成第一溝渠414以及在電阻區500中形成一第二溝渠514。於本發明另一實施例中,亦可選擇性地再移除介質層404與介質層504。As shown in FIG. 2, an inter-layer dielectric (ILD) 306 is formed on the contact hole etch stop layer 304. In one embodiment, the inner dielectric layer 306 is, for example, yttrium oxide (SiO 2 ), doped yttrium oxide tetraethoxy decane (TEOS), plasma enhanced tetraethoxy decane (PETEOS), or other low Dielectric layer of dielectric constant. Then, a planarization process, such as a chemical mechanical polish (CMP) process or an etch process or a combination of the two, is performed to sequentially remove portions of the inner dielectric layer 306 and portions. The contact hole etch stop layer 304, a portion of the sidewall spacer 410, a portion of the sidewall spacer 510, and completely remove the cap layer 408 and the cap layer 508 until the sacrificial layer 406 in the transistor 402 and the dummy resistor 502 are exposed. Sacrificial layer 506. Then, a dry etching process and/or a wet etching process is performed to remove the sacrificial layer 406 in the transistor 402 and the sacrificial layer 506 in the dummy resistor 502 to form the first trench 414 and the resistive region 500 in the active region 400, respectively. A second trench 514 is formed in the middle. In another embodiment of the invention, the dielectric layer 404 and the dielectric layer 504 may also be selectively removed.
如第3圖所示,在基底300上全面形成一高介電常數層308以及金屬層310。高介電常數層308以及金屬層310會依序填入在第一溝渠414以及第二溝渠514中,並完全填滿第一溝渠414與第二溝渠514。於本發明較佳實施例中,高介電常數層308例如是氧化鉿(hafnium oxide,HfO2)、矽酸鉿氧化合物(hafnium silicon oxide,HfSiO4)、矽酸鉿氮氧化合物(hafnium silicon oxynitride,HfSiON)、氧化鋁(aluminum oxide,Al2O3)、氧化鑭(lanthanum oxide,La2O3)、鋁酸鑭(lanthanum aluminum oxide,LaAlO)、氧化鉭(tantalum oxide,Ta2O5)、氧化鋯(zirconium oxide,ZrO2)、矽酸鋯氧化合物(zirconium silicon oxide,ZrSiO4)、鋯酸鉿(hafnium zirconium oxide,HfZrO)、鍶鉍鉭氧化物(strontium bismuth tantalate,SrBi2Ta2O9,SBT)、鋯鈦酸鉛(lead zirconate titanate,PbZrxTi1-xO3,PZT)或鈦酸鋇鍶(barium strontium titanate,BaxSr1-xTiO3,BST)等。金屬層310例如是鋁(Al)、鈦(Ti)、鉭(Ta)、鎢(W)、鈮(Nb)、鉬(Mo)、銅(Cu)、氮化鈦(TiN)、碳化鈦(TiC)、氮化鉭(TaN)、鈦鎢(Ti/W)或鈦與氮化鈦(Ti/TiN)等單一或複合金屬層。於本發明其他實施例中,亦可依照電晶體402的電性需求,在高介電常數層308與金屬層310之間選擇性地形成一層或多層的阻障層(圖未示)或是至少一功函數金屬層(圖未示)。最後,進行一平坦化製程,以移除第一溝渠414與第二溝渠514以外的高介電常數層308以及金屬層310,使得金屬層310的頂面與內層介電層306齊高,此時第一溝渠414以及第二溝渠514表面分別形成有U型的高介電常數層308。As shown in FIG. 3, a high dielectric constant layer 308 and a metal layer 310 are integrally formed on the substrate 300. The high dielectric constant layer 308 and the metal layer 310 are sequentially filled in the first trench 414 and the second trench 514, and completely fill the first trench 414 and the second trench 514. In a preferred embodiment of the present invention, the high dielectric constant layer 308 is, for example, hafnium oxide (HfO 2 ), hafnium silicon oxide (HfSiO 4 ), hafnium silicon (hafnium silicon). Oxynitride, HfSiON), aluminum oxide (Al 2 O 3 ), lanthanum oxide (La 2 O 3 ), lanthanum aluminum oxide (LaAlO), tantalum oxide (Ta 2 O 5 ) Zirconium oxide (ZrO 2 ), zirconium silicon oxide (ZrSiO 4 ), hafnium zirconium oxide (HfZrO), strontium bismuth tantalate (SrBi 2 Ta) 2 O 9 , SBT), lead zirconate titanate (PbZr x Ti 1-x O 3 , PZT) or barium strontium titanate (BaxSr 1-x TiO 3 , BST). The metal layer 310 is, for example, aluminum (Al), titanium (Ti), tantalum (Ta), tungsten (W), niobium (Nb), molybdenum (Mo), copper (Cu), titanium nitride (TiN), titanium carbide ( TiC), tantalum nitride (TaN), titanium tungsten (Ti/W) or a single or composite metal layer such as titanium and titanium nitride (Ti/TiN). In other embodiments of the present invention, one or more barrier layers (not shown) may be selectively formed between the high dielectric constant layer 308 and the metal layer 310 according to the electrical requirements of the transistor 402. At least one work function metal layer (not shown). Finally, a planarization process is performed to remove the high dielectric constant layer 308 and the metal layer 310 outside the first trench 414 and the second trench 514 such that the top surface of the metal layer 310 is aligned with the inner dielectric layer 306. At this time, a U-shaped high dielectric constant layer 308 is formed on the surfaces of the first trench 414 and the second trench 514, respectively.
如第4圖所示,在基底300上形成一第一介電層312覆蓋並直接接觸內層介電層306上,再依序形成一導電層314以及一第二介電層316。於本發明較佳實施例中,第一介電層312例如是摻雜有氮或氧或無摻雜的碳化矽,其厚度大致為200埃至300埃;導電層314例如是任何導電材料例如是氮化鈦,其厚度大致為20埃至60埃;第二介電層316例如是氮化矽,其厚度大致上為300埃至600埃。As shown in FIG. 4, a first dielectric layer 312 is formed on the substrate 300 to cover and directly contact the inner dielectric layer 306, and a conductive layer 314 and a second dielectric layer 316 are sequentially formed. In a preferred embodiment of the present invention, the first dielectric layer 312 is, for example, niobium or oxygen doped or undoped tantalum carbide having a thickness of approximately 200 angstroms to 300 angstroms; and the conductive layer 314 is, for example, any conductive material such as It is titanium nitride having a thickness of approximately 20 angstroms to 60 angstroms; and the second dielectric layer 316 is, for example, tantalum nitride having a thickness of approximately 300 angstroms to 600 angstroms.
如第5圖所示,進行一蝕刻製程,以移除位於電阻區500以外之第二介電層316以及導電層314。舉例來說,可以先形成一圖案化光阻層(圖未示),並以此圖案化光阻層為遮罩進行一蝕刻製程,使得第二介電層316與導電層314垂直切齊。As shown in FIG. 5, an etching process is performed to remove the second dielectric layer 316 and the conductive layer 314 outside the resistance region 500. For example, a patterned photoresist layer (not shown) may be formed first, and the photoresist layer is patterned to perform an etching process for the mask such that the second dielectric layer 316 is vertically aligned with the conductive layer 314.
如第6圖所示,於基底300上全面形成一層間介電層318,並可選擇性地進行一平坦化製程。最後,在層間介電層318、第二介電層316中形成複數個接觸插栓320,其中至少兩個接觸插栓320會直接接觸導電層314,至少兩個接觸插栓320會接觸源極/汲極區412。如此一來,即可在內層介電層306上形成一電阻結構321a。如第6圖所示,電阻結構321a是直接設置虛擬電阻502上,也就是設置在內層介電層306上。電阻結構321a具有導電層314,且上下具有「第一介電層312-導電層314-第二介電層316」的三明治結構,其中第二介電層316與導電層314垂直切齊。As shown in FIG. 6, an interlayer dielectric layer 318 is formed on the substrate 300, and a planarization process can be selectively performed. Finally, a plurality of contact plugs 320 are formed in the interlayer dielectric layer 318 and the second dielectric layer 316, wherein at least two contact plugs 320 directly contact the conductive layer 314, and at least two contact plugs 320 contact the source. / bungee zone 412. In this way, a resistive structure 321a can be formed on the inner dielectric layer 306. As shown in FIG. 6, the resistor structure 321a is directly disposed on the dummy resistor 502, that is, on the inner dielectric layer 306. The resistive structure 321a has a conductive layer 314 and has a sandwich structure of "first dielectric layer 312 - conductive layer 314 - second dielectric layer 316" above and below, wherein the second dielectric layer 316 is vertically aligned with the conductive layer 314.
於其他實施例中,視產品設計亦可調整電阻結構321a的位置。請參考第7圖,所繪示為本發明第二實施例中形成整合結構的步驟示意圖。如第7圖所示,半導體的整合結構包含有電晶體402以及電阻結構321a。電晶體402設置在主動區400中的內層介電層306中。電阻結構321a設置在電阻區500中,且直接設置在內層介電層306上,但並不會直接設置在虛擬電阻502上,也就是說,電阻結構321a與淺溝渠隔離302之間具有內層介電層306,較佳者,僅具有內層介電層306。In other embodiments, the position of the resistive structure 321a can also be adjusted depending on the product design. Please refer to FIG. 7, which is a schematic diagram showing the steps of forming an integrated structure in the second embodiment of the present invention. As shown in FIG. 7, the integrated structure of the semiconductor includes a transistor 402 and a resistor structure 321a. The transistor 402 is disposed in the inner dielectric layer 306 in the active region 400. The resistor structure 321a is disposed in the resistor region 500 and disposed directly on the inner dielectric layer 306, but is not directly disposed on the dummy resistor 502, that is, the resistor structure 321a and the shallow trench isolation 302 have an inner portion. Layer dielectric layer 306, preferably, has only inner dielectric layer 306.
請參考第8圖至第14圖,所繪示為本發明第三實施例中形成整合結構的步驟示意圖。在形成了如第1圖的結構之後,如第8圖所示,在基底300上形成一圖案化光阻層322。圖案化光阻層322的開口會位於電阻區500中,且開口的寬度小於犧牲層506的寬度。Please refer to FIG. 8 to FIG. 14 , which are schematic diagrams showing the steps of forming an integrated structure in the third embodiment of the present invention. After the structure as shown in FIG. 1 is formed, as shown in FIG. 8, a patterned photoresist layer 322 is formed on the substrate 300. The opening of the patterned photoresist layer 322 will be located in the resistive region 500, and the width of the opening is less than the width of the sacrificial layer 506.
接著如第9圖所示,以圖案化光阻層322為遮罩,進行一蝕刻製程,以移除暴露的接觸洞蝕刻停止層304、蓋層508、犧牲層506以及介質層504,直到暴露出基底300中的淺溝渠隔離302,而在犧牲電阻502中形成了一第三溝渠324。值得注意的是,第三溝渠324兩邊的側壁還分別具有犧牲層506及介質層504。Next, as shown in FIG. 9, with the patterned photoresist layer 322 as a mask, an etching process is performed to remove the exposed contact hole etch stop layer 304, the cap layer 508, the sacrificial layer 506, and the dielectric layer 504 until exposed. A shallow trench isolation 302 in the substrate 300 is exited, and a third trench 324 is formed in the sacrificial resistor 502. It should be noted that the sidewalls on both sides of the third trench 324 further have a sacrificial layer 506 and a dielectric layer 504, respectively.
在去除圖案化光阻層322之後,如第10圖所示,在基底300上全面形成一內層介電層306。內層介電層306會覆蓋在接觸洞蝕刻停止層304上,並會完全填滿第三溝渠324。於一實施例中,內層介電層306例如是氧化矽、摻雜氧化矽四乙氧基矽烷、電漿增強式四乙氧基矽烷或是其他低介電常數的介電層。接著進行一平坦化製程,例如一化學機械平坦化製程或者一回蝕刻製程或兩者的組合,以依序移除部份的內層介電層306、部份的接觸洞蝕刻停止層304,部份的側壁子410、部份的側壁子510,並完全移除蓋層408、蓋層508,直到暴露出電晶體402中犧牲層406以及虛擬電阻502中犧牲層506。After the patterned photoresist layer 322 is removed, as shown in FIG. 10, an inner dielectric layer 306 is entirely formed on the substrate 300. The inner dielectric layer 306 overlies the contact hole etch stop layer 304 and completely fills the third trench 324. In one embodiment, the inner dielectric layer 306 is, for example, hafnium oxide, doped yttria tetraethoxy decane, plasma enhanced tetraethoxy decane, or other low dielectric constant dielectric layer. Then, a planarization process, such as a chemical mechanical planarization process or an etching process or a combination of the two, is performed to sequentially remove a portion of the inner dielectric layer 306 and a portion of the contact hole etch stop layer 304. A portion of the sidewalls 410, a portion of the sidewalls 510, and the cap layer 408 and the cap layer 508 are completely removed until the sacrificial layer 406 in the transistor 402 and the sacrificial layer 506 in the dummy resistor 502 are exposed.
如第11圖所示,進行一乾蝕刻及/或溼蝕刻製程,以將犧牲層406與犧牲層506完全移除。最後,填入高介電常數層308以及金屬層310,並進行平坦化製程使金屬層310的頂面與內層介電層306齊高。如第12圖所示,在基底300上形成一第一介電層312覆蓋並直接接觸內層介電層306上,再依序形成一導電層314以及一第二介電層316。然後,如第13圖所示,利用一圖案化遮罩(圖未示)來進行一蝕刻製程,以移除位於電阻區500以外之第二介電層316以及導電層314,使得第二介電層316與導電層314垂直切齊。As shown in FIG. 11, a dry etching and/or wet etching process is performed to completely remove the sacrificial layer 406 and the sacrificial layer 506. Finally, the high dielectric constant layer 308 and the metal layer 310 are filled, and a planarization process is performed to make the top surface of the metal layer 310 and the inner dielectric layer 306 high. As shown in FIG. 12, a first dielectric layer 312 is formed on the substrate 300 to cover and directly contact the inner dielectric layer 306, and a conductive layer 314 and a second dielectric layer 316 are sequentially formed. Then, as shown in FIG. 13, an etching process (not shown) is performed to remove the second dielectric layer 316 and the conductive layer 314 outside the resistance region 500, so that the second dielectric layer Electrical layer 316 is vertically aligned with conductive layer 314.
如第14圖所示,於基底300上全面形成一層間介電層318,並可選擇性地進行一平坦化製程。最後,形成複數個接觸插栓320,其中至少兩個接觸插栓320會穿過層間介電層318、第二介電層316、導電層314、第一介電層312,並分別接觸(landing)在電阻區500中的金屬層310,另外至少兩個接觸插栓320會接觸源極/汲極區412。如此一來,即可在內層介電層306上形成一電阻結構321b。如第13圖所示,電阻結構321b是直接設置在內層介電層306上。電阻結構321b具有導電層314,且其上下具有「第一介電層312-導電層314-第二介電層316」的三明治結構。本實施例的特點在於,接觸插栓320會接觸在虛擬電阻502中的金屬層310上。由於導電層314的厚度較薄,較不易將接觸插栓320對準在導電層314上。因此,本實施例藉由將接觸插栓320接觸至金屬層310上,一方面可以增加對準的精確度,另一方面可以增加電阻的阻值。As shown in FIG. 14, an interlayer dielectric layer 318 is entirely formed on the substrate 300, and a planarization process can be selectively performed. Finally, a plurality of contact plugs 320 are formed, wherein at least two contact plugs 320 pass through the interlayer dielectric layer 318, the second dielectric layer 316, the conductive layer 314, the first dielectric layer 312, and are respectively contacted. In the metal layer 310 in the resistive region 500, at least two contact plugs 320 will contact the source/drain regions 412. As a result, a resistive structure 321b can be formed on the inner dielectric layer 306. As shown in FIG. 13, the resistor structure 321b is directly disposed on the inner dielectric layer 306. The resistor structure 321b has a conductive layer 314 and has a sandwich structure of "first dielectric layer 312 - conductive layer 314 - second dielectric layer 316" above and below. A feature of this embodiment is that the contact plug 320 contacts the metal layer 310 in the dummy resistor 502. Since the thickness of the conductive layer 314 is thin, it is difficult to align the contact plug 320 on the conductive layer 314. Therefore, in this embodiment, by contacting the contact plug 320 to the metal layer 310, on the one hand, the accuracy of the alignment can be increased, and on the other hand, the resistance of the resistor can be increased.
請參考第15圖至第19圖,所繪示為本發明第四實施例中形成電阻的步驟示意圖。在經過如第1圖至第3圖的步驟後,請參考第15圖,在基底300上全面形成一層間介電層325,例如是一氧化矽(SiO2)或摻雜氧化矽四乙氧基矽烷(TEOS)層或與前述的第一介電層312具有相同材質,厚度大體上為200埃至400埃。Please refer to FIG. 15 to FIG. 19, which are schematic diagrams showing the steps of forming a resistor in the fourth embodiment of the present invention. After passing through the steps of FIGS. 1 to 3, referring to FIG. 15, an interlayer dielectric layer 325 is formed on the substrate 300, for example, cerium oxide (SiO 2 ) or doped cerium oxide tetraethoxy. The ruthenium (TEOS) layer or the same material as the first dielectric layer 312 described above has a thickness of substantially 200 angstroms to 400 angstroms.
接著如第16圖所示,進行一微影與蝕刻製程,以移除電阻區500中的層間介電層325,而形成圖案化層間介電層327。圖案化層間介電層327會至少暴露出下方的金屬層310。Next, as shown in FIG. 16, a lithography and etching process is performed to remove the interlayer dielectric layer 325 in the resistive region 500 to form a patterned interlayer dielectric layer 327. The patterned interlayer dielectric layer 327 exposes at least the underlying metal layer 310.
如第17圖所示,進行一溼蝕刻及/或乾蝕刻製程,以部份移除電阻區500中的金屬層310,而在電阻區500中形成了一第四溝渠326。於本發明較佳實施例中,金屬層310會被蝕刻至一均勻厚度,例如是20至60埃,而形成一U形的結構。值得注意的是,由於殘留有部份厚度的金屬層310,因此金屬層310下方的阻障層(圖未示)、功函數金屬層(圖未示)與高介電常數層308較佳地不會被移除,此外,本實施例之另一實施態樣亦可以幾乎移除金屬層310而留下阻障層(圖未示)、功函數金屬層(圖未示)與高介電常數層308。As shown in FIG. 17, a wet etching and/or dry etching process is performed to partially remove the metal layer 310 in the resistive region 500, and a fourth trench 326 is formed in the resistive region 500. In a preferred embodiment of the invention, the metal layer 310 is etched to a uniform thickness, for example 20 to 60 angstroms, to form a U-shaped structure. It is noted that the barrier layer (not shown), the work function metal layer (not shown) and the high dielectric constant layer 308 under the metal layer 310 are preferably formed because a metal layer 310 having a partial thickness remains. It is not removed. In addition, another embodiment of the embodiment can also remove the metal layer 310 to leave a barrier layer (not shown), a work function metal layer (not shown), and a high dielectric. Constant layer 308.
如第18圖所示,在基底300上全面形成一第二層間介電層328。第二層間介電層328會覆蓋在金屬層310上並完全填滿電阻區500中的第四溝渠326。最後,如第19圖所示,形成複數個接觸插栓320,其中至少兩個接觸插栓320會穿過第四層間介電層328,並接觸在電阻區500中的金屬層310或阻障層(圖未示)或功函數金屬層上。如此一來,同樣也可在電阻區500中形成一電阻結構321c,電阻結構321c具有「高介電常數層308-金屬層310-第四層間介電層328」的三明治結構,且金屬層310會具有U形的剖面。As shown in FIG. 18, a second interlayer dielectric layer 328 is formed over the substrate 300. The second interlayer dielectric layer 328 overlies the metal layer 310 and completely fills the fourth trench 326 in the resistive region 500. Finally, as shown in FIG. 19, a plurality of contact plugs 320 are formed, wherein at least two contact plugs 320 pass through the fourth interlayer dielectric layer 328 and contact the metal layer 310 or the barrier in the resistance region 500. Layer (not shown) or work function metal layer. In this way, a resistor structure 321c can also be formed in the resistor region 500. The resistor structure 321c has a sandwich structure of "high dielectric constant layer 308 - metal layer 310 - fourth interlayer dielectric layer 328", and the metal layer 310 Will have a U-shaped profile.
本發明提供了不同的整合結構以及其製作方法,其可以整合傳統的金屬閘極電晶體製程以及電阻製程,故可省略多道步驟,並能節省製作成本。The invention provides different integrated structures and a manufacturing method thereof, which can integrate the traditional metal gate transistor process and the resistance process, so that multiple steps can be omitted and the manufacturing cost can be saved.
以上所述僅為本發明之較佳實施例,凡依本發明申請專利範圍所做之均等變化與修飾,皆應屬本發明之涵蓋範圍。The above are only the preferred embodiments of the present invention, and all changes and modifications made to the scope of the present invention should be within the scope of the present invention.
300...基底300. . . Base
302...淺溝渠隔離302. . . Shallow trench isolation
304...接觸洞蝕刻停止層304. . . Contact hole etch stop layer
306...內層介電層306. . . Inner dielectric layer
308...高介電常數層308. . . High dielectric constant layer
310...金屬層310. . . Metal layer
312...第一介電層312. . . First dielectric layer
314...導電層314. . . Conductive layer
316...第二介電層316. . . Second dielectric layer
318...層間介電層318. . . Interlayer dielectric layer
320...接觸插栓320. . . Contact plug
321a...電阻結構321a. . . Resistance structure
321b...電阻結構321b. . . Resistance structure
321c...電阻結構321c. . . Resistance structure
322...圖案化光阻層322. . . Patterned photoresist layer
324...第三溝渠324. . . Third ditches
325...層間介電層325. . . Interlayer dielectric layer
326...第四溝渠326. . . Fourth ditches
327...圖案化層間介電層327. . . Patterned interlayer dielectric layer
328...第二層間介電層328. . . Second interlayer dielectric layer
400...主動區400. . . Active zone
500...電阻區500. . . Resistance zone
402...電晶體402. . . Transistor
502...虛擬電阻502. . . Virtual resistor
404,504...介質層404,504. . . Dielectric layer
406,506...犧牲層406,506. . . Sacrificial layer
408,508...蓋層408,508. . . Cover
410,510...側壁子410,510. . . Side wall
412...源極/汲極區412. . . Source/bungee area
414...第一溝渠414. . . First ditches
514...第二溝渠514. . . Second ditches
第1圖至第6圖繪示了本發明第一實施例中形成電阻的步驟示意圖。1 to 6 are schematic views showing the steps of forming a resistor in the first embodiment of the present invention.
第7圖繪示了本發明第二實施例中形成電阻的步驟示意圖。Fig. 7 is a view showing the steps of forming a resistor in the second embodiment of the present invention.
第8圖至第14圖繪示了本發明第三實施例中形成電阻的步驟示意圖。8 to 14 are views showing the steps of forming a resistor in the third embodiment of the present invention.
第15圖至第19圖繪示了本發明第四實施例中形成電阻的步驟示意圖。15 to 19 are views showing the steps of forming a resistor in the fourth embodiment of the present invention.
300...基底300. . . Base
302...淺溝渠隔離302. . . Shallow trench isolation
304...接觸洞蝕刻停止層304. . . Contact hole etch stop layer
306...內層介電層306. . . Inner dielectric layer
308...高介電常數層308. . . High dielectric constant layer
310...金屬層310. . . Metal layer
312...第一介電層312. . . First dielectric layer
314...導電層314. . . Conductive layer
316...第二介電層316. . . Second dielectric layer
318...層間介電層318. . . Interlayer dielectric layer
320...接觸插栓320. . . Contact plug
321a...電阻結構321a. . . Resistance structure
400...主動區400. . . Active zone
500...電阻區500. . . Resistance zone
402...電晶體402. . . Transistor
502...虛擬電阻502. . . Virtual resistor
404,504...介質層404,504. . . Dielectric layer
406,506...犧牲層406,506. . . Sacrificial layer
408,508...蓋層408,508. . . Cover
410,510...側壁子410,510. . . Side wall
412...源極/汲極區412. . . Source/bungee area
Claims (20)
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|---|---|---|---|
| TW101113468A TW201344881A (en) | 2012-04-16 | 2012-04-16 | Semiconductor integrated structure |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| TW101113468A TW201344881A (en) | 2012-04-16 | 2012-04-16 | Semiconductor integrated structure |
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| Publication Number | Publication Date |
|---|---|
| TW201344881A true TW201344881A (en) | 2013-11-01 |
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| Application Number | Title | Priority Date | Filing Date |
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| TW101113468A TW201344881A (en) | 2012-04-16 | 2012-04-16 | Semiconductor integrated structure |
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2012
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