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TW201332440A - Composition for pest control aerosol and pest control method - Google Patents

Composition for pest control aerosol and pest control method Download PDF

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Publication number
TW201332440A
TW201332440A TW101150065A TW101150065A TW201332440A TW 201332440 A TW201332440 A TW 201332440A TW 101150065 A TW101150065 A TW 101150065A TW 101150065 A TW101150065 A TW 101150065A TW 201332440 A TW201332440 A TW 201332440A
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pest
pest control
aerosol
pests
hlb value
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TW101150065A
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Masahiro Yamada
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Sumitomo Chemical Co
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • General Health & Medical Sciences (AREA)
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  • Agricultural Chemicals And Associated Chemicals (AREA)
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Abstract

Provided are a composition for a pest control aerosol and a pest control method each of which has an excellent pest control effect. Specifically provided are: a composition for a pest control aerosol, containing an ester compound represented by the following formula (1), a saturated hydrocarbon solvent, a silicone compound and a propellant; and a pest control method including spraying an effective amount of a composition for a pest control aerosol which contains an ester compound represented by the following formula (1), a saturated hydrocarbon solvent, a silicone compound and a propellant onto a pest or a habitat of the pest.

Description

有害生物防除氣溶膠用組成物及有害生物防除方法 Pesticide-preventing aerosol composition and pest control method

本發明是關於一種有害生物防除組成物及有害生物防除方法。 The present invention relates to a pest control composition and a pest control method.

已知一種含有下述式(1)表示的酯化合物,飽和烴溶媒及驅動劑的有害動物防除氣溶膠用組成物有防除有害生物效果(例如參照專利文獻1)。 A composition for a pest-preventing aerosol containing an ester compound represented by the following formula (1), a saturated hydrocarbon solvent and a driving agent is known to have a pest control effect (see, for example, Patent Document 1).

[引證案列表] [List of cited cases] [專利文獻] [Patent Literature]

專利文獻1:JP-A-2008-273944 Patent Document 1: JP-A-2008-273944

本發明之目的是提供一種有害生物防除氣溶膠用組成物及一種有害生物防除的方法,其各有優異的防除有害生物效果。 SUMMARY OF THE INVENTION An object of the present invention is to provide a pest-preventing aerosol composition and a pest control method each having excellent pest control effects.

本發明者為了要找出具有優異的有害生物防除效果 的氣溶膠用組成物的目的,而已進行精心及密集研究。結果發現一種有優異的有害生物防除效果的有害生物防除氣溶膠用組成物,係含有下述式(1)表示的酯化合物,飽和烴溶媒,聚矽氧化合物及驅動劑。這個發現導至本發明的完成。 The inventors have found an excellent pest control effect in order to find out Aerosols have been carefully and intensively studied for the purpose of the composition. As a result, it has been found that a pest-preventing aerosol composition having an excellent pest control effect contains an ester compound represented by the following formula (1), a saturated hydrocarbon solvent, a polyoxo compound, and a driver. This finding leads to the completion of the present invention.

具體而言,本發明的構成如下。 Specifically, the constitution of the present invention is as follows.

[1]一種有害生物防除氣溶膠用組成物,係含有式(1)表示的酯化合物,飽和烴溶媒,聚矽氧化合物及驅動劑。 [1] A composition for pest control of an aerosol comprising an ester compound represented by the formula (1), a saturated hydrocarbon solvent, a polyoxo compound, and a driving agent.

[2]如項[1]所述的有害生物防除氣溶膠用組成物,其中該式(1)表示的酯化合物的含量在0.001至3重量%,該飽合烴類溶媒的含量在10至90重量%,該聚矽氧化合物的含量在0.01至3重量%,及該驅動劑的含量在4至90重量%。 [2] The composition for pest control of an aerosol according to [1], wherein the content of the ester compound represented by the formula (1) is from 0.001 to 3% by weight, and the content of the saturated hydrocarbon solvent is from 10 to 90% by weight, the polydecane oxide is contained in an amount of 0.01 to 3% by weight, and the driving agent is contained in an amount of 4 to 90% by weight.

[3]如項[1]或項[2]所述的有害生物防除氣溶膠用組成物,其中該聚矽氧化合物是聚醚-改質聚矽氧。 [3] The composition for pest control of an aerosol according to [1], wherein the polyxanthene oxide is a polyether-modified polyoxane.

[4]如項[3]所述的有害生物防除氣溶膠用組成物,其中該聚醚-改質聚矽氧有HLB值1至15。 [4] The composition for pest control of an aerosol according to [3], wherein the polyether-modified polyfluorene has an HLB value of 1 to 15.

[5]一種有害生物防除氣溶膠,係含有如項[1]至[4]中任一項所述的有害生物防除氣溶膠用組成物。 [5] A pest-preventing aerosol composition according to any one of [1] to [4].

[6]一種有害生物防除方法,係包括將有效量的有害生物防除氣溶膠用組成物噴灑於有害生物或有害生物的棲息處,該組成物含有式(1)表示的酯化合物,飽和烴溶媒,聚矽氧化合物 及驅動劑。 [6] A pest control method comprising spraying an effective amount of a pest control aerosol composition onto a habitat of a pest or a pest, the composition containing an ester compound represented by the formula (1), a saturated hydrocarbon solvent Polyoxyl And the driver.

根據本發明的有害生物防除氣溶膠用組成物有優異的防除有害生物的效果。 The composition for pest control of an aerosol according to the present invention has an excellent pest control effect.

根據本發明的有害生物防除氣溶膠用組成物含有式(1)表示的酯化合物(有時稱為“本酯化合物”),飽和烴溶媒,聚矽氧化合物及驅動劑。 The composition for pest control of an aerosol according to the present invention contains an ester compound (sometimes referred to as "the present ester compound") represented by the formula (1), a saturated hydrocarbon solvent, a polyoxo compound and a driving agent.

本酯化合物可以依照例如在JP-A-2004-2363所述的方法製造。 The present ester compound can be produced in accordance with, for example, the method described in JP-A-2004-2363.

本酯化合物有衍生自在環丙烷環上的兩個不對稱碳原子及環丙烷環中經取代的取代基中的雙鍵的異構物。在本發明中,可使用任意比率的活性異構物的酯化合物。 The present ester compound has an isomer derived from two asymmetric carbon atoms on a cyclopropane ring and a double bond in a substituted substituent in a cyclopropane ring. In the present invention, an ester compound of any ratio of active isomers can be used.

本酯化合物的例包括:(1R)-3-(2-氰基-1-丙烯基)-2,2-二甲基環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯,(1R)-反-3-(2-氰基-1-丙烯基)-2,2-二甲基環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯,(1R)-順-3-(2-氰基-1-丙烯基)-2,2-二甲基環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯,(1R)-反-3-((E)-2-氰基-1-丙烯基)-2,2-二甲基環丙烷羧酸[2,3,5,6-四氟-4-(甲氧基甲基)苯基]甲酯,及(1R)-反-3-((Z)-2-氰基-1-丙烯基)-2,2-二甲基環丙烷羧酸[2,3,5,6-四 氟-4-(甲氧基甲基)苯基]甲酯。 Examples of the ester compound include: (1R)-3-(2-cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid [2,3,5,6-tetrafluoro-4- (methoxymethyl)phenyl]methyl ester, (1R)-trans-3-(2-cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid [2,3,5 ,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ester, (1R)-cis-3-(2-cyano-1-propenyl)-2,2-dimethylcyclopropane Carboxylic acid [2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ester, (1R)-trans-3-((E)-2-cyano-1-propene (2,3,5,6-tetrafluoro-4-(methoxymethyl)phenyl]methyl ester, and (1R)-trans-3- ((Z)-2-cyano-1-propenyl)-2,2-dimethylcyclopropanecarboxylic acid [2,3,5,6-four Fluoro-4-(methoxymethyl)phenyl]methyl ester.

根據本發明的有害生物防除氣溶膠用組成物中的本酯化合物的含量通常是0.001至3重量%,較佳是0.01至2重量%. The content of the ester compound in the composition for pest control aerosol according to the present invention is usually 0.001 to 3% by weight, preferably 0.01 to 2% by weight.

所用的飽和烴溶媒是通常有起始沸點150℃或更高以及95%蒸餾溫度300℃或更低者。當然,也可以用有起始沸點150℃或更高以及乾燥點300℃或更低的飽和烴溶媒。飽和烴溶媒的例包括Isopar G(埃克森美孚公司(Exxon Mobil Co.)製,起始沸點160℃,乾點:176℃),Isopar L(埃克森美孚公司製,起始沸點:189℃;乾點:207℃),Isopar H(埃克森美孚公司製,起始沸點:178℃,乾點:188℃),Isopar M(埃克森美孚公司製,起始沸點:223℃,乾點:254℃,Norpar 13(埃克森美孚公司製,起始沸點:222℃,乾點:242℃),Norpar 15(埃克森美孚公司製,起始沸點:249℃,乾點:274℃),Exxsol D40(埃克森美孚公司製,起始沸點:164℃,乾點:192℃),Exxsol D60(埃克森美孚公司製,起始沸點:187℃,乾點:209℃),Exxsol D80(埃克森美孚公司製,起始沸點;208℃,乾點:243℃),Neothiozol(中央化成公司製,起始沸點225℃,乾點:247℃),IP Solvent 2028(出光興產公司製,起始沸點:213℃,95%蒸餾溫度:250℃)及煤油。 The saturated hydrocarbon solvent used is usually one having a starting point of 150 ° C or higher and a 95% distillation temperature of 300 ° C or lower. Of course, a saturated hydrocarbon solvent having a starting point of 150 ° C or higher and a drying point of 300 ° C or lower can also be used. Examples of the saturated hydrocarbon solvent include Isopar G (manufactured by Exxon Mobil Co., starting point 160 ° C, dry point: 176 ° C), Isopar L (manufactured by ExxonMobil, starting point: 189 °C; dry point: 207 ° C), Isopar H (manufactured by ExxonMobil, starting point: 178 ° C, dry point: 188 ° C), Isopar M (manufactured by ExxonMobil, starting point: 223 ° C, Dry point: 254 ° C, Norpar 13 (manufactured by ExxonMobil, starting point: 222 ° C, dry point: 242 ° C), Norpar 15 (manufactured by ExxonMobil, starting point: 249 ° C, dry point: 274 ° C), Exxsol D40 (manufactured by ExxonMobil, starting point: 164 ° C, dry point: 192 ° C), Exxsol D60 (manufactured by ExxonMobil, starting point: 187 ° C, dry point: 209 ° C ), Exxsol D80 (made by ExxonMobil, starting point; 208 ° C, dry point: 243 ° C), Neothiozol (centralized into a company, starting point 225 ° C, dry point: 247 ° C), IP Solvent 2028 ( Produced by Idemitsu Kosan Co., Ltd., starting point: 213 ° C, 95% distillation temperature: 250 ° C) and kerosene.

根據本發明的有害生物防除氣溶膠用組成物中的飽和烴溶媒的含量通常是10至90重量%,較佳是20至80重量%。 The content of the saturated hydrocarbon solvent in the composition for pest control aerosol according to the present invention is usually from 10 to 90% by weight, preferably from 20 to 80% by weight.

聚矽氧化合物的例包括各有一個矽氧烷鍵結的化合物。具體例包括二甲基聚矽氧,聚醚改質聚矽氧,胺基改質聚矽氧,醇改質聚矽氧,芳烷基改質聚矽氧;烷基芳烷基改質聚矽氧, 聚醚烷基芳烷基改質聚矽氧,胺基聚醚改質聚矽氧,環氧基聚醚改質聚矽氧,巰基改質聚矽氧,環氧基改質聚矽氧,磺酸改質聚矽氧,羧基改質聚矽氧,磷酸改質聚矽氧,銨鹽改質聚矽氧,磺基甜菜鹼改質聚矽氧,甲基丙烯酸改質聚矽氧,酚改質聚矽氧。這些化合物中,聚醚-改質聚矽氧為特佳。 Examples of polyoxyxides include compounds each having a siloxane coupling. Specific examples include dimethyl polyfluorene oxide, polyether modified polyfluorene oxide, amine modified polyfluorene oxide, alcohol modified polyfluorene oxide, aralkyl modified polyfluorene oxide; alkyl aralkyl modified polycondensation Oxygen, Polyether alkyl aralkyl modified polyfluorene oxide, amine polyether modified polyfluorene oxide, epoxy polyether modified polyfluorene oxide, fluorenyl modified polyfluorene, epoxy modified polyoxyl Sulfonic acid modified polyfluorene oxide, carboxyl modified polyfluorene oxide, phosphoric acid modified polyfluorene oxide, ammonium salt modified polyfluorene oxide, sulfobetaine modified polyfluorene oxide, methacrylic acid modified polyoxo, phenol Modification of polyoxane. Among these compounds, polyether-modified polyfluorene is particularly preferred.

聚醚改質聚矽氧的例包括聚氧乙烯-甲基聚矽氧烷共聚物,聚氧丙烯-甲基聚矽氧烷共聚物,聚(氧乙烯-氧丙烯)甲基聚矽氧烷共聚物,以及甲基聚矽氧烷-十六基甲基聚矽氧烷-聚(氧乙烯-氧丙烯)甲基聚矽氧烷共聚物。聚醚改質聚矽氧包括線型共聚(ABn)型,其中聚醚與矽氧烷交替鍵結,支鏈改質型,一端或兩端改質型,以及其混合物。至少在一支鏈有聚醚基的聚醚改質聚矽氧為特佳。聚醚基的一個例是R11-(R12)s-R13-(其中R11表示羥基或碳原子數1至10的烷氧基;R12表示碳原子數2至4的伸烷基(其中2個或更多的伸烷基成為R12而存在);R13表示碳原子數2至12的伸烷基,而s表示1至20的整數)。 Examples of polyether modified polyfluorene include polyoxyethylene-methyl polyoxyalkylene copolymer, polyoxypropylene-methyl polyoxyalkylene copolymer, poly(oxyethylene-oxypropylene)methyl polyoxyalkylene oxide. Copolymer, and methyl polyoxyalkylene-hexadecylmethyl polyoxyalkylene-poly(oxyethylene-oxypropylene) methyl polyoxyalkylene copolymer. The polyether modified polyfluorene oxygen includes a linear copolymerization (ABn) type in which a polyether is alternately bonded to a decane, a branched modified type, one or both ends modified, and a mixture thereof. It is particularly preferred that the polyether modified with polyether groups in at least one chain is modified. An example of the polyether group is R 11 -(R 12 ) s -R 13 - (wherein R 11 represents a hydroxyl group or an alkoxy group having 1 to 10 carbon atoms; and R 12 represents an alkylene group having 2 to 4 carbon atoms; (wherein 2 or more alkylene groups are present as R 12 ); R 13 represents an alkylene group having 2 to 12 carbon atoms, and s represents an integer of 1 to 20).

聚醚改質聚矽氧較佳是HLB值在1至15,平均分子量55000或更小,及在25℃的黏度在500至10000 mPa.s。聚醚改質聚矽氧較佳是在25℃有液狀。 The polyether modified polyfluorene preferably has an HLB value of 1 to 15, an average molecular weight of 55,000 or less, and a viscosity at 25 ° C of 500 to 10000 mPa. s. The polyether modified polyfluorene is preferably liquid at 25 °C.

市面上可買到的聚酯改質聚矽氧產物之例包括:信越化學公司(Shin-Etsu Chemical Co.,Ltd.)製的KF-351A(HLB值:12),K-352A(HLB值:7),KF-353(HLB值:10),KF-354L(HLB值:16),KF-355A(HLB值:12),KF-615A(HLB值:10),KF-945(HLB值:4),KF-640(HLB值:14),KF-642(HLB值:12),KF-643(HL8值:14),KF-6004(HLB值:6),KF-6020(HLB:值:4),KF-6011(HLB 值:12),KF-6012(HLB值:7),KF-6015(HLB值:5),KF-6016(HLB值:5),KF-6017(HLB值:5),X-22-4515(HLB值:5)及X-22-6191(HLB值:2);道康寧東麗公司(Dow Corning Toray Co.,Ltd.)製的SH3749(HLB值:6),SH3771M(HLB值:13),SH3772M(HLB值:6),SH3773H(HLB值:9),SH3775M(HLB值:5),SS-2802(HLB值:13),SS-2804(HLB值:13),SH8400(HLB值:7),SF8427(HLB值:9),SF8428(HLB值:0),FZ-2104(HLB值:14),FZ-2105(HLB值:11),FZ-2110(HLB值:1),FZ-2120(HLB值:6),FZ-2123(HLB值:8),FZ-2154(HLB值:6),FZ-2162(HLB值:15),FZ-2164(HLB值:8),FZ-2166(HLB值:5),FZ-2191(HLB值:5),FZ-2203(HLB值:1),F-2207(HLB值:3),FZ2208(HLB值:7),FZ77(HLB值:11),L-7001(HLB值:5)及L-7002(HLB值:8)。 Examples of commercially available polyester modified polyoxo products include: KF-351A (HLB value: 12), K-352A (HLB value) manufactured by Shin-Etsu Chemical Co., Ltd. :7), KF-353 (HLB value: 10), KF-354L (HLB value: 16), KF-355A (HLB value: 12), KF-615A (HLB value: 10), KF-945 (HLB value) : 4), KF-640 (HLB value: 14), KF-642 (HLB value: 12), KF-643 (HL8 value: 14), KF-6004 (HLB value: 6), KF-6020 (HLB: Value: 4), KF-6011 (HLB Value: 12), KF-6012 (HLB value: 7), KF-6015 (HLB value: 5), KF-6016 (HLB value: 5), KF-6017 (HLB value: 5), X-22-4515 (HLB value: 5) and X-22-6191 (HLB value: 2); SH3749 (HLB value: 6), SH3771M (HLB value: 13) manufactured by Dow Corning Toray Co., Ltd. , SH3772M (HLB value: 6), SH3773H (HLB value: 9), SH3775M (HLB value: 5), SS-2802 (HLB value: 13), SS-2804 (HLB value: 13), SH8400 (HLB value: 7), SF8427 (HLB value: 9), SF8428 (HLB value: 0), FZ-2104 (HLB value: 14), FZ-2105 (HLB value: 11), FZ-2110 (HLB value: 1), FZ -2120 (HLB value: 6), FZ-2123 (HLB value: 8), FZ-2154 (HLB value: 6), FZ-2162 (HLB value: 15), FZ-2164 (HLB value: 8), FZ -2166 (HLB value: 5), FZ-2191 (HLB value: 5), FZ-2203 (HLB value: 1), F-2207 (HLB value: 3), FZ2208 (HLB value: 7), FZ77 (HLB) Values: 11), L-7001 (HLB value: 5) and L-7002 (HLB value: 8).

在本發明中,上述的聚矽氧化合物可單獨或2種以上的聚矽氧化合物之混合物而使用。在根據本發明的有害生物防除氣溶膠用組成物中的聚矽氧化合物的含量通常是0.01至3重量%,較佳是0.1至2重量%。 In the present invention, the above polyfluorene oxide compound may be used singly or in combination of two or more kinds of polyoxo compounds. The content of the polyoxygen compound in the pest-preventing aerosol composition according to the present invention is usually from 0.01 to 3% by weight, preferably from 0.1 to 2% by weight.

驅動劑有沸點在-50至0℃的液化氣體。驅動劑的例包括液化石油氣(LPG),二甲基醚,丙烷,正丁烷及異丁烷。根據本發明的有害生物防除氣溶膠用組成物中的驅動劑的含量通常是在4至90重量%(89.898%),較佳是16至80重量%。 The driving agent has a liquefied gas having a boiling point of -50 to 0 °C. Examples of the driving agent include liquefied petroleum gas (LPG), dimethyl ether, propane, n-butane and isobutane. The content of the driving agent in the pest-preventing aerosol composition according to the present invention is usually from 4 to 90% by weight (89.898%), preferably from 16 to 80% by weight.

在根據本發明的有害生物防除氣溶膠用組成物中,相對於1重量份的飽和烴溶媒,本酯化合物的含量通常是0.00001至0.3重量份,較佳是0.0001至0.1重量份,相對於1重量份的飽和烴溶媒,聚矽氧化合物的含量,通常是0.0001至0.3重量份, 較佳是0.0005至0.1重量份,及相對於1重量份的飽和烴溶媒,驅動劑的含量通常是0.04至9重量份,較佳是0.2至4重量份。 In the pest-preventing aerosol composition according to the present invention, the content of the ester compound is usually 0.00001 to 0.3 part by weight, preferably 0.0001 to 0.1 part by weight, relative to 1 part by weight of the saturated hydrocarbon solvent. The content of the saturated hydrocarbon solvent, polyoxyxide, is usually 0.0001 to 0.3 parts by weight, It is preferably 0.0005 to 0.1 part by weight, and the content of the driver is usually 0.04 to 9 parts by weight, preferably 0.2 to 4 parts by weight, per part by weight of the saturated hydrocarbon solvent.

如有需要,在本發明的有害生物防除氣溶膠用組成物中可以添加至少1種選自另一種有害生物防除成分,驅除劑,增效劑,香料等所選的成分。 If necessary, at least one selected component selected from the group consisting of another pest control component, a repellent, a synergist, a fragrance, and the like may be added to the composition for pest control of the present invention.

其他有害生物防除成分包括:有機磷化合物例如二氯松(dichlorvos),撲滅松(fenitrothion),殺蟲畏(tetrachlorvinphos),芬殺松(fenthion),陶斯松(chlorpyrifos)及大利松(diazinon);胺基甲酸酯(carbamate)化合物例如安丹(propoxur),加保利(carbaryl),噁蟲酮(metoxadiazone)及丁基滅必蝨(fenobucarb);甲殼生成抑制劑例如祿芬隆(lufenuron),克福隆(chlorfluazuron),六伏隆(hexaflumuron),二福隆(diflubenzuron),賽滅淨(cyromazine)及1-(2,6-二氟苯甲醯基)-3-[2-氟-4-(1,1,2,3,3,3-六氟丙氧基)苯基]脲;青春激素類似物(juvenile hormone analog)例如百利普芬(pyriproxyfen),烯蟲丙酯(methoprene),烯蟲乙酯(hydroprene)及芬諾克(fenoxycarb);類尼古丁(neonicotinoid)化合物;及N-苯基吡唑化合物。 Other pest control ingredients include: organophosphorus compounds such as dichlorvos, fenitrothion, tetrachlorvinphos, fenthion, chlorpyrifos and diazinon; amines Carbamate compounds such as propoxur, carbaryl, metoxadiazone and fenobucarb; crustacean production inhibitors such as lufenuron, gram Chlorfluazuron, hexaflumuron, diflubenzuron, cyromazine and 1-(2,6-difluorobenzhydryl)-3-[2-fluoro-4 -(1,1,2,3,3,3-hexafluoropropoxy)phenyl]urea; juvenile hormone analog such as pyriproxyfen, methoprene , hydroprene and fenoxycarb; neonicotinoid-like compounds; and N-phenylpyrazole compounds.

驅除劑的例包括N,N-二乙基-間-甲苯醯胺,檸檬烯(limonene),芳樟醇(linalool),香茅醛(citronellal),薄荷醇(menthol),薄荷眮(menthone),日本扁柏油(hinokitiol),香草醇(geraniol),桉樹油(eucalyptol),因得克(indoxacarb),長松針烷-3,4-二醇(carane-3,4-diol),MGK-R-326,MGK-R-874及BAY-KBR-3023。 Examples of the repellent include N,N-diethyl-m-toluidine, limonene, linalool, citronellal, menthol, menthone, Japanese hinokitiol, geraniol, eucalyptol, indoxacarb, carane-3,4-diol, MGK-R- 326, MGK-R-874 and BAY-KBR-3023.

增效劑的例包括:5-[2-(2-丁氧基乙氧基)乙氧基甲基]-6-丙基-1,3-苯並 二噁茂,N-(2-乙基己基)二環[2,2,1]庚-5-烯基-2,3-二羧亞醯胺,八氯二丙基醚,硫氰乙酸異崁酯及N-(2-乙基己基)-1-異丙基-4-甲基二環[2,2,2]辛-5-烯基-2,3-羧亞醯胺。 Examples of synergists include: 5-[2-(2-butoxyethoxy)ethoxymethyl]-6-propyl-1,3-benzo Dioxo, N-(2-ethylhexyl)bicyclo[2,2,1]hept-5-enyl-2,3-dicarboxyarlenamide, octachlorodipropyl ether, thiocyanate Anthracene ester and N-(2-ethylhexyl)-1-isopropyl-4-methylbicyclo[2,2,2]oct-5-enyl-2,3-carboxamide.

安定劑的例包括酚-型抗氧化劑例如2,6-二-三級丁基-4-甲基酚。 Examples of the stabilizer include phenol-type antioxidants such as 2,6-di-tert-butyl-4-methylphenol.

根據本發明的有害生物防除氣溶膠用組成物可形成含有根據本發明的有害生物防除氣溶膠用組成物的氣溶膠,例如,在氣溶膠容器中裝填本酯化合物,飽和烴溶媒,聚矽氧化合物及,如有需要,另外的有害生物防除成分,驅除劑,增效劑,安定劑等,在容器上附上噴霧閥,經由柄裝填驅動劑,將容器搖動,然後在容器上附上啟動器。啟動器的例包括按鈕型啟動器及板機型啟動器。 The pest-preventing aerosol composition according to the present invention can form an aerosol containing the pest-preventing aerosol composition according to the present invention, for example, an aerosol container, a saturated hydrocarbon solvent, and a polyoxyl oxide. Compounds and, if necessary, additional pest control ingredients, repellents, synergists, stabilizers, etc., attach a spray valve to the container, load the driver through the handle, shake the container, and then attach the container to the starter Device. Examples of starters include push button type starters and trigger type starters.

根據本發明的有害生物防除氣溶膠用組成物是將用於防除有害生物的有效量的含有本發明的有害生物防除氣溶膠用組成物的有害生物防除氣溶膠,例如,噴灑有害生物,有害生物的路徑及/或有害生物的棲息處的方式施用。當氣溶膠是施用於平面的表面上時,氣溶膠的施用量通常是約0.001至1000 mg本酯化合物/1m2平面的表面面積。當氣溶膠施用於空間,氣溶膠的施用量通常是約0.001至1000 mg本酯化合物/1m3空間。 The pest-preventing aerosol composition according to the present invention is an effective amount of a pest-preventing aerosol containing the composition for pest control of the present invention to be used for controlling pests, for example, spraying harmful organisms, pests The route and/or the manner in which the pest is inhabited. When the aerosol is applied to a flat surface, the aerosol application amount is usually from about 0.001 to 1000 mg of the surface area of the ester compound / 1 m 2 plane. When the aerosol is applied to the space, the aerosol is usually applied in an amount of about 0.001 to 1000 mg of the ester compound per 1 m 3 of space.

根據本發明的有害生物防除氣溶膠用組成物可防除的有害生物的例包括節肢動物例如昆蟲及螨,包含下列有害生物。 Examples of the pests which can be prevented by the composition for pest control of the pest according to the present invention include arthropods such as insects and cockroaches, and include the following pests.

屬於麟翅目(Lepidoptera)的有害生物:螟蛾科(Pyralidae)有害生物例如二化螟蟲(Chilo suppressalis),稻縱捲葉野螟(Cnaphalocrocis medinalis)、及印度穀螟蛾(Plodia interpunctella)、 及地中海粉螟(Ephestia kuehniella);切根有害生物例如斜紋夜蛾(Spodoptera litura),黏夜蛾(Pseudaletia separate),及甘藍夜蛾(Mamestra brassicae);粉蝶科(Pieridae)有害生物例如白粉蝶(Pieris rapae);捲蛾科(Tortricidae)有害生物例如茶姬捲葉蛾(Adoxophyes orana);果蛀蛾科(Carposinidae)有害生物;萊氏蛾科(Lyonetiidae)有害生物;毒蛾科(Lymantriidae)有害生物;金翅夜蛾(Trichoplusia)有害生物;夜盜蟲(Agrotis)有害生物例如蕪菁夜蛾(Agrotis segetum)及球菜夜蛾(Agrotis ipsilon);蕃茄夜蛾品種(Helicoverpa spp.)有害生物;玉米穗蟲品種(Heliothis spp)有害生物;小菜蛾(Plutella xylostella);稻弄蝶(Parnara guttata);衣蛾(Tinea translucens);小衣蛾(Tineola bisselliella);及其他者。 A pest belonging to the family Lepidoptera: Pyralidae pests such as Chilo suppressalis, Cnaphalocrocis medinalis, and Plodia interpunctella, And Ephestia kuehniella; root-cutting pests such as Spodoptera litura, Pseudaletia separate, and Mamestra brassicae; Pieridae pests such as white butterfly ( Pieris rapae); Tortricidae pests such as Adoxophyes orana; Carposinidae pests; Lyonetiidae pests; Lymantriidae pests; Trichoplusia pests; Agrotis pests such as Agrotis segetum and Agrotis ipsilon; Helicoverpa spp. pests; corn ear worms Variety (Heliothis spp) pest; Plutella xylostella; Parnara guttata; Tinea translucens; Tineola bisselliella; and others.

屬於雙翅目(Diptera)的有害生物:家蚊屬(Culex spp.) 例如尖音庫蚊淡色亞種(Culex pipiens pallens),三斑家蚊(Culex tritaeniorhynchus)及熱帶家蚊(Culex quinquefasciatus);斑蚊品種(Aedes spp.)有害生物例如埃及斑蚊(Aedes aegypti)及白線斑蚊(Aedes albopictus);瘧蚊(anopheles)有害生物例如中華瘧蚊(Anopheles sinensis)及瘧蚊(Anopheles gambiae);搖蚊科(Chironomidae)有害生物;家蠅例如家蠅(Musca domestica),廄腐蠅(Muscina stabulans)及黃腹廁蠅(Fannia canicularis);麗蠅(blow files);肉蠅(fresh flies);花蠅科(Anthomyiidae)有害生物例如灰地種蠅(Delia platura)及蔥地種蠅(Delia antiqua);果實蠅科(Tephritidae)有害生物;潛蠅科(Agromyzidae)有害生物;果蠅科(Drosophilidae)有害生物;蛾蚋科(Psychodidae)有害生物;蚤蠅科(Phoridae)有害生物;虻科(Tabanidae)有害生物;蚋科(Simuliidae)有害生物;螫蠅屬 (Stomoxys)有害生物;蠓科(Ceratopogonidae);及其他者。 A pest belonging to the order Diptera: Culex spp. For example, Culex pipiens pallens, Culex tritaeniorhynchus and Culex quinquefasciatus; Aedes spp. pests such as Aedes aegypti and Aedes albopictus; anopheles pests such as Anopheles sinensis and Anopheles gambiae; Chironomidae pests; Musca domestica, such as Musca domestica, Muscina stabulans and Fannia canicularis; blow files; fresh flies; Anthomyiidae pests such as Delia platura and onions Delia antiqua; Tephritidae pest; Agromyzidae pest; Drosophilidae pest; Psychodidae pest; Phoridae Pests; Tabanidae pests; Simuliidae pests; (Stomoxys) pests; Ceratopogonidae; and others.

屬於蜚蠊科(Blattodae)的有害生物:德國蜚蠊 (Blattella germanica),黑褐家蠊(Periplaneta fuliginosa),美洲蜚蠊(Periplaneta americana),澳洲蜚蠊(Periplaneta australasiae);棕色家蠊(Periplaneta brunnea),東方蠊(Blatta orientalis)等;及其他者。 A pest belonging to the family Blattodae: German 蜚蠊 (Blattella germanica), Periplaneta fuliginosa, Periplaneta americana, Periplaneta australasiae, Periplaneta brunnea, Blata orientalis, and others.

屬於膜翅目(Hymenoptera)的有害生物:螞蟻例如日 本弓背蟻(Camponotus japonicus),紅棕色皺家蟻(Tetramorium tsushimae),日本毛山蟻(Lasius japonicus),華夏粗針蟻(Pachycondyla chinensis),入侵單家蟻(Monornorium intrudens),日本花園蟻(Lasius nipponensis),小黃家蟻(Monomorium pharaonis),日本山蟻(Formica japonica),光滑管琉璃蟻(Ochetellus glaber),堅硬雙針蟻(Pristomyrmex punctatus),寬節大頭家蟻(Pheidole noda)及阿根廷蟻(Linepithema humile);長腳蜂(paper wasps)例如例如中華長腳馬蜂(Poliates chinensis antennalis),尖雙紋長腳蜂(Polistes riparius),家長腳蜂(Polistes jadwigae jadwigae),黃長腳蜂(Polistes rothneyi),黃星長腳蜂(Polistes nipponensis),雙斑長腳蜂(雙斑馬蜂)(Polistes snelleni)及日本馬蜂(Polistes japonicus);胡蜂科(Vespidae)有害生物:例如中華大虎頭蜂(Vespa mandarinia),黃色胡蜂(Vespa simillima),擬大虎頭蜂(Vespa analis Fabricius),費邊胡蜂(Vespa crabro Linnaeus),姬虎頭蜂(Vespa ducalis Smith),細黃胡蜂(Vespula flaviceps Smith),帶黃胡蜂(Vespula shidai)及中長黃胡蜂(Dolichovespula media);蟻形蜂科(Ethylidae)有害生物;葉蜂科(Tenthredinidae)有害生物例如日本柄瘤蚜繭蜂(Lysiphlebus japonicus);及其他者。 A pest belonging to the order Hymenoptera: ants such as the day Camponotus japonicus, Tetramorium tsushimae, Lasius japonicus, Pachycondyla chinensis, Monornorium intrudens, Japanese garden ant Lasius nipponensis), Monomorium pharaonis, Formica japonica, Ochetellus glaber, Pristomyrmex punctatus, Pheidole noda and Argentina Ant (Linepithema humile); paper wasps such as, for example, Poliates chinensis antennalis, Polistes riparius, Polistes jadwigae jadwigae, yellow long bee ( Polistes rothneyi), Polistes nipponensis, Polistes snelleni and Polistes japonicus; Vespidae pests: eg Chinese tiger head bee (Vespa) Mandarinin), Vespa simillima, Vespa analis Fabricius, Vespa crabro Linnaeus, Vespa Ducalis Smith), Vespula flaviceps Smith with Vespula shidai and Dolichovespula media; Ethylidae pests; Tenthredinidae pests such as Japan Lysiphlebus japonicus; and others.

屬於隱翅目(Aphaniptera)的有害生物:狗蚤 (Ctenocephalides canis),貓蚤(Ctenocephalides felis),人蚤(Pulex irritans)等。 A pest belonging to Aphaniptera: shit (Ctenocephalides canis), Ctenocephalides felis, Pulex irritans, etc.

屬於蝨目(Anoplura)的有害生物:人蝨(Pediculus humanus),陰蝨(Phthirus pubis),頭蝨(Pediculus humanus capitis),體蝨(Pediculus humanus corporis);及其他者。 A pest belonging to the Anoplura: Pediculus Humanus), Phthirus pubis, Pediculus humanus capitis, Pediculus humanus corporis; and others.

屬於囓蟲目(Psocoptera)的有害生物:嚙蟲科 (Psocidae)有害生物。 A pest belonging to the genus Psocoptera: the genus (Psocidae) pests.

屬於等翅目(Isoptera)的有害生物:地底白蟻例如大 和白蟻(Reticulitermies speratus),有翅型家白蟻(Coptotermes formosanus),黃肢散白蟻(Reticulitermes flaviceps),西方散白蟻(Reticulitermes Hesperus),美黑色南方散白蟻(Reticulitermes virginicus),美黑脛散白蟻(Reticulitermes tibialis)及金色異白蟻(Heterotermes aureus);乾木白蟻例如小楹白蟻(Incisitermes minor);濕木白蟻例如內華達動白蟻(Zootermopsis nevadeneis);及其他者。 a pest belonging to the Isoptera: underground termites such as large And termites (Reticulitermies speratus), Coptotermes formosanus, Reticulitermes flaviceps, Reticulitermes Hesperus, Reticulitermes virginicus, Tanning black termites ( Reticulitermes tibialis) and Heterotermes aureus; dry wood termites such as Incisitermes minor; wet wood termites such as Zootermopsis nevadeneis; and others.

屬於半翅目(Hemiptera)的有害生物:稻蝨科 (Delphacidae)有害生物例如斑飛蝨(Laodelphax striatellus),褐飛蝨(Nilaparvata lugens),及白背飛蝨(Sogatella furcifera);角頂葉蟬科(Deltocephalidae)有害生物例如偽黑尾葉蟬(Nephotettix cincticeps)及台灣黑尾葉蟬(Nephotettix virescens);常蚜科(Aphididae)有害生物;蝽科(Pentatomidae)有害生物例如草綠椿象(Nezara antennata);大豆細緣椿象(Riptortus clavatus),大刺白星椿象(Eysarcoris lewisi),白星椿象(Eysarcoris parvus),小珀椿象(Plautia stali),茶翅椿象(Halyomorpha mista),赤條纖盲椿象(Stenotus rubrovittatus) 及條赤鬚盲椿象(Trigonotylus caelestialium);粉蝨科(Aleyrodidae)有害生物;介殼蟲總科(Coccoidea)有害生物;網蝽科(Tingidae)有害生物;木蝨科(Psyllidae);臭蟲科(Cimicidae)有害生物例如臭蟲(Cimex lectularius);及其他者。 A pest belonging to the Hemiptera: Inaba (Delphacidae) pests such as Laodelphax striatellus, Nilaparvata lugens, and Sogatella furcifera; Deltocephalidae pests such as Nephotettix cincticeps And Taiwan's Nephotettix virescens; Aphididae pests; Pentatomidae pests such as Nezara antennata; Riptortus clavatus, Eysarcoris Lewisi), Eysarcoris parvus, Plautia stali, Halyomorpha mista, Stenotus rubrovittatus And Trigonotylus caelestialium; Aleyrodidae pest; Coccoidea pest; Tingidae pest; Psyllidae; Cimicidae ) pests such as bed bugs (Cimex lectularius); and others.

屬於鞘翅目(Coleoptera)的有害生物:玉米根蟲例如毛 皮蠹(Attagenus japonicas);紅斑皮蠹(Anthrenus verbasci);西部玉米食蟲(Diabrotica virgifera virgifera)及十一星黃瓜葉甲(Diabrotica undecimpunctata howardi);金龜子科(Scarabaeidae)有害生物例如金銅金龜(Anomala cuprea)及大豆赤金龜(Anomala rufocuprea);象鼻蟲科(Curcculionidae)害蟲例如玉米象(Sitophilus zeamais),水稻水象鼻蟲(Lissorhoptrus oryzophilus),棉鈴象鼻蟲(Anthonomus grandis boheman),及綠豆象(Callosobruchus chinensis);擬步行科(Tenebrionidae)有害生物例如麵包蟲(Tenebrio molitor)及擬穀盜(Tribolium castaneum);金花蟲科(Chrysomelidae)有害生物例如稻負泥蟲(Oulema oryzae),黃條葉蚤(Phyllotreta striolata)及黃守瓜(Aulacophora femoralis);標本甲科(Anobiidae)有害生物;瓢蟲品種(Epilachna spp.)有害生物例如茄二十八星瓢蟲(Epilachna vigintioctopunctata);粉蠹科(Lyctidae)有害生物;長蠹蟲科(Bostrychidae)有害生物;標本蟲科(Ptinidae)有害生物;天牛科(Cerambycidae)有害生物;蟻型隱翅蟲(Paederus fuscipes)有害生物;及其他者。 a pest belonging to the coleoptera: corn rootworm such as hair Attengus japonicas; Anthrenus verbasci; Diabrotica virgifera virgifera and Diabrotica undecimpunctata howardi; Scarabaeidae pests such as gold-copper tortoise (Anomala cuprea) And soybean red-gold turtle (Anomala rufocuprea); Curcculionidae pests such as Sitophilus zeamais, rice water weevil (Lissorhoptrus oryzophilus), cotton boll weevil (Anthonomus grandis boheman), and mung bean ( Callosobruchus chinensis); Tenebrionidae pests such as Tenebrio molitor and Tribolium castaneum; Chrysomelidae pests such as Oulema oryzae, yellow leaves Phyllotreta striolata and Aulacophora femoralis; Anobiidae pests; Epilachna spp. pests such as Epilachna vigintioctopunctata; Lyctidae) pest; Bostrychidae pest; specimen of Ptinidae ; Cerambycidae (Cerambycidae) pests; ant type paederus (Paederus fuscipes) pests; and other persons.

屬於纓翅目(Thysanoptera)的有害生物:南黃薊馬 (Thrips palmi),西方花薊馬(Frankliniella occidentalis),花薊馬(Thrips hawaiiensis);及其他者。 A pest belonging to the order Thysanoptera: Southern Yellow Horse (Thrips palmi), Frankliniella occidentalis, Thrips hawaiiensis; and others.

屬於直翅目(Orthoptera)的有害生物:螻蛄科 (Gryllotalpidae),蝗科(Acrididae),蟋蟀科(Gryllidae)有害生物;及其他者。 A pest belonging to the Orthoptera: Aphididae (Gryllotalpidae), Acrididae, Gryllidae pest; and others.

屬於蟎目(Acarina)的有害生物:皮刺蟎科 (Dermanyssidae)害蟲例如美洲室塵蟎(Dermatophagoides farinae)及歐洲室塵蟎(Dermatophagoides pteronyssinus);粉蟎科(Acaridae)有害生物例如腐食酪蟎(Tyrophagus putrescentiae)及橢圓食粉蟎(Aleuroglyphus ovatus);食甜蟎科(Glycyphagidae)害蟲例如隱秘甘蟎(Glycyphagus privatus),家食甜蟎(Glycyphagus domesticus)及長鬚粉蹣(Glycyphagus destructor);肉食蟎科(Cheyletidae)有害生物例如馬六甲肉食蟎(Cheyletus malaccensis)及肉食蟎品種(Cheyletus fortis);細蟎科(Tarsonemidae)有害生物;嗜草蟎科(Chortoglyphidae)有害生物;禽刺蟎科(Haplochthoniidae)有害生物;葉蟎科(Tetranychidae)例如二點葉蟎(Tetranychus urticae),神澤氏葉蟎(Tetranychus kanzawai),柑桔葉蟎(Panonychus citri),及歐洲紅葉蟎(Panonychus ulmi);赤蟎科(Erythraeidae)有害生物;中氣門螨目(Mesostigmata)有害生物例如長角血蜱(Haemaphysalis longicornis);巨刺蟎科(Ornithonyssus sylviarum)有害生物;及皮刺蟎科(Dermanyssidae)有害生物例如家禽蝨子(Dermanyssus gallinae)。 A pest belonging to the Acarina: Prickly (Dermanyssidae) pests such as Dermatophagoides farinae and Dermatophagoides pteronyssinus; Acaridae pests such as Tyrophagus putrescentiae and Aleuroglyphus ovatus; Glycyphagidae pests such as Glycyphagus privatus, Glycyphagus domesticus and Glycyphagus destructor; Cheyletidae pests such as Cheyletus malaccensis And carnivorous cultivars (Cheyletus fortis); Tarsonemidae pests; Chortoglyphidae pests; Haplochthoniidae pests; Tetranychidae such as two-spotted spider mites ( Tetranychus urticae), Tetranychus kanzawai, Panonychus citri, and Panonychus ulmi; Erythraeidae pest; Mesostigmata pest For example, Haemaphysalis longicornis; Ornithonyssus sylviarum pest; Prickles mites (Dermanyssidae) pests such as poultry lice (Dermanyssus gallinae).

實施例 Example

在下面以製造例及試驗例更詳細說明本發明。但是,本發明並不限於只在下面所述。如無另外註明,這裏的「份」係指「重量份」而言。 The present invention will be described in more detail below by way of Production Examples and Test Examples. However, the invention is not limited to only the following. Unless otherwise stated, the term "parts" as used herein means "parts by weight".

製造例1 Manufacturing example 1

將本酯化合物(0.02份),有HLB值為5的聚醚改質 聚矽氧(KF-6016,PEG-9甲基醚矽靈(PEG-9 methyl ether dimethicone),信越化學公司製)(1份)及Isopar M(58.98份)裝入於氣溶膠罐(AE180WO,東洋精機公司製),將閥構件(附有孔徑0.33mm的柄的按紐閥,日本精密閥公司製)套在罐上,然後將驅動劑(液化石油氣)(40份)經由閥構件裝入於該罐。如此製成含有有害生物防除氣溶膠(100份)的氣溶膠(以下稱為「本氣溶膠(1)」)。 The ester compound (0.02 parts) was modified with a polyether having an HLB value of 5. Polyfluorene (KF-6016, PEG-9 methyl ether dimethicone, manufactured by Shin-Etsu Chemical Co., Ltd.) (1 part) and Isopar M (58.98 parts) were placed in an aerosol can (AE180WO, Toyo Seiki Co., Ltd.), a valve member (a button valve with a shank having a hole diameter of 0.33 mm, manufactured by Nippon Precision Valve Co., Ltd.) was placed on the can, and then a driving agent (liquefied petroleum gas) (40 parts) was loaded through a valve member. Enter the tank. An aerosol containing a pest-preventing aerosol (100 parts) (hereinafter referred to as "the present aerosol (1)") was prepared in this manner.

製造例2 Manufacturing Example 2

將本酯化合物(0.02份),有HLB值為5的聚醚改質聚矽氧(KF-6017,PEG-10甲基醚矽靈,信越化學公司製)(1份)及Isopar M(58.98份)裝入於氣溶膠罐(AE180WO,東洋精機公司製),將閥構件(附有孔徑0.33mm的柄的按紐閥,日本精密閥公司製)套在罐上,然後將驅動劑(液化石油氣)(40份)經由閥構件裝入於該罐。如此製成含有有害生物防除氣溶膠(100份)的氣溶膠(以下稱為「本氣溶膠(2)」)。 The ester compound (0.02 parts), a polyether having an HLB value of 5, modified polyfluorene (KF-6017, PEG-10 methyl ether oxime, manufactured by Shin-Etsu Chemical Co., Ltd.) (1 part) and Isopar M (58.98) In the aerosol canister (AE180WO, manufactured by Toyo Seiki Co., Ltd.), a valve member (a button valve with a shank having a hole diameter of 0.33 mm, manufactured by Nippon Precision Valve Co., Ltd.) was placed on the can, and then the driving agent was liquefied. Petroleum gas (40 parts) was charged into the tank via a valve member. An aerosol containing a pest-preventing aerosol (100 parts) (hereinafter referred to as "the present aerosol (2)") was prepared in this manner.

製造例3 Manufacturing Example 3

將本酯化合物(0.02份),有HLB值為12的聚醚改質聚矽氧(KF-6011,PEG-11甲基醚矽靈,信越化學公司製)(0.1份)及Isopar M(59.88份)裝入於氣溶膠罐(AE180WO,東洋精機公司製),將閥構件(附有孔徑0.33mm的柄的按紐閥,日本精密閥公司製)套在罐上,然後將驅動劑(液化石油氣)(40份)經由閥構件裝入於該罐。如此製成含有有害生物防除氣溶膠(100份)的氣溶膠(以下稱為「本氣溶膠(3)」)。 The present ester compound (0.02 parts), a polyether having an HLB value of 12, modified polyfluorene (KF-6011, PEG-11 methyl ether oxime, manufactured by Shin-Etsu Chemical Co., Ltd.) (0.1 part) and Isopar M (59.88) In the aerosol canister (AE180WO, manufactured by Toyo Seiki Co., Ltd.), a valve member (a button valve with a shank having a hole diameter of 0.33 mm, manufactured by Nippon Precision Valve Co., Ltd.) was placed on the can, and then the driving agent was liquefied. Petroleum gas (40 parts) was charged into the tank via a valve member. An aerosol containing a pest-preventing aerosol (100 parts) (hereinafter referred to as "the present aerosol (3)") was prepared in this manner.

製造例4 Manufacturing Example 4

將本酯化合物(0.02份),有HLB值為1的聚醚改質 聚矽氧(FZ-2203,八甲基環四矽氧烷,道康寧東麗公司製)(1份)及Isopar M(58.98份)裝入於氣溶膠罐(AE1280WO,東洋精機公司製),將閥構件(附有孔徑0.33mm的柄的按紐閥,日本精密閥公司製)套在罐上,然後將驅動劑(液化石油氣)(40份)經由閥構件裝入於該罐。如此製成含有有害生物防除氣溶膠(100份)的氣溶膠(以下稱為「本氣溶膠(4)」)。 The ester compound (0.02 parts), modified with a polyether having an HLB value of 1 Polyfluorene (FZ-2203, octamethylcyclotetraoxane, manufactured by Dow Corning Toray Co., Ltd.) (1 part) and Isopar M (58.98 parts) were placed in an aerosol can (AE1280WO, manufactured by Toyo Seiki Co., Ltd.). A valve member (a button valve having a shank having a hole diameter of 0.33 mm, manufactured by Nippon Precision Valve Co., Ltd.) was placed on the can, and then a driving agent (liquefied petroleum gas) (40 parts) was charged into the can via a valve member. An aerosol containing a pest-preventing aerosol (100 parts) (hereinafter referred to as "the present aerosol (4)") was prepared in this manner.

製造例5 Manufacturing Example 5

將本酯化合物(0.02份),有HLB值為15的聚醚改質聚矽氧(FZ-2162,道康寧東麗公司製)(1份)及Isopar M(58.98份)裝入於氣溶膠罐(AE1280WO,東洋精機公司製),將閥構件(附有孔徑0.33mm的柄的按紐閥,日本精密閥公司製)套在罐上,然後將驅動劑(液化石油氣)(40份)經由閥構件裝入於該罐。如此製成含有有害生物防除氣溶膠(100份)的氣溶膠(以下稱為「本氣溶膠(5)」)。 The ester compound (0.02 parts), a polyether modified polyfluorene (FZ-2162, manufactured by Dow Corning Toray) (1 part) and Isopar M (58.98 parts) having an HLB value of 15 were placed in an aerosol can. (AE1280WO, manufactured by Toyo Seiki Co., Ltd.), a valve member (a button valve with a shank having a hole diameter of 0.33 mm, manufactured by Nippon Precision Valve Co., Ltd.) was placed on a can, and then a driving agent (liquefied petroleum gas) (40 parts) was passed through A valve member is loaded into the can. An aerosol containing a pest-preventing aerosol (100 parts) (hereinafter referred to as "the present aerosol (5)") was prepared in this manner.

比較製造例1 Comparative manufacturing example 1

將本酯化合物(0.02份),二氯甲烷(5份)及除臭煤油(34.98部)混合。將所得混合物裝入於氣溶膠罐(AE1280WO,東洋精機公司製),將閥構件(附有孔徑0.33mm的柄的按紐閥,日本精密閥公司製)套在罐上,然後將驅動劑(液化石油氣)(60份)經由閥構件裝入於該罐。以這方式含有有害生物防除氣溶膠(100份)的氣溶膠(以下稱為「比較氣溶膠」)。 The present ester compound (0.02 parts), dichloromethane (5 parts) and deodorized kerosene (34.98 parts) were mixed. The obtained mixture was placed in an aerosol can (AE1280WO, manufactured by Toyo Seiki Co., Ltd.), and a valve member (a button valve with a shank having a hole diameter of 0.33 mm, manufactured by Nippon Precision Valve Co., Ltd.) was placed on the can, and then the driving agent was Liquefied petroleum gas (60 parts) was charged into the tank via a valve member. In this way, an aerosol containing an anti-aerosol (100 parts) of a pest (hereinafter referred to as "comparative aerosol") is contained.

試驗例1 Test example 1

將10隻家蠅(5雄蟲及5雌蟲)成蟲飼義於聚乙烯杯(底部直徑:10.6 cm,高部直徑:12cm,高:7cm),並將杯以16 網目尼龍網蓋住。亦提供另一個同樣的聚乙烯杯,但其中沒有放家蠅。有釋放家蠅的杯放在一邊為70cm的立方形箱的底部中央,而沒有飼義家蠅的杯則放在該箱的後部。 10 housefly (5 male and 5 female) adults were fed to a polyethylene cup (bottom diameter: 10.6 cm, high diameter: 12 cm, height: 7 cm), and the cup was 16 The mesh is covered with nylon mesh. Another identical polyethylene cup is also available, but no housefly is placed. The cup with the housefly released is placed in the center of the bottom of the 70 cm square box, while the cup without the housefly is placed at the back of the box.

將本氣溶膠及比較氣溶膠各通過該箱前側壁的中央部分的小窗噴入箱內,噴入的氣溶膠組成物的量均為300mg。噴入7分鐘後,測定擊斃率(knock-down rate)。(這試驗各氣溶膠重複2次)。 The aerosol and the comparative aerosol were each sprayed into the tank through a small window in the central portion of the front side wall of the tank, and the amount of the aerosol composition sprayed was 300 mg. After 7 minutes of spraying, the knock-down rate was measured. (This test was repeated twice for each aerosol).

結果示於第1表。 The results are shown in Table 1.

[產業上應用的可能性] [Possibility of application in industry]

根據本發明,可提供有優異有害生物防除效果的一種有害生物防除氣溶膠用組成物及有害生物防除方法。 According to the present invention, it is possible to provide a pest-preventing aerosol composition and a pest control method which have an excellent pest control effect.

Claims (6)

一種有害生物防除氣溶膠用組成物,係含有式(1)表示的酯化合物,飽和烴溶媒,聚矽氧化合物及驅動劑: A pest-preventing aerosol composition comprising an ester compound represented by the formula (1), a saturated hydrocarbon solvent, a polyoxo compound and a driving agent: 如申請專利範圍第1項所述的有害生物防除氣溶膠用組成物,其中,該式(1)表示的酯化合物的含量在0.001至3重量%,該飽合烴類溶媒的含量在10至90重量%,該聚矽氧化合物的含量在0.01至3重量%,及該驅動劑的含量在4至90重量%。 The pest-preventing aerosol composition according to the above aspect of the invention, wherein the ester compound represented by the formula (1) is contained in an amount of from 0.001 to 3% by weight, and the saturated hydrocarbon solvent is in an amount of from 10 to 10 90% by weight, the polydecane oxide is contained in an amount of 0.01 to 3% by weight, and the driving agent is contained in an amount of 4 to 90% by weight. 如申請專利範圍第1項或第2項所述的有害生物防除氣溶膠用組成物,其中,該聚矽氧化合物是聚醚改質聚矽氧。 The composition for pest control of an aerosol according to claim 1 or 2, wherein the polyxanthene oxide is a polyether modified polyoxane. 如申請專利範圍第3項所述的有害生物防除氣溶膠用組成物,其中,該聚醚改質聚矽氧有HLB值1至15。 The pest-preventing aerosol composition according to claim 3, wherein the polyether-modified polyfluorene has an HLB value of 1 to 15. 一種有害生物防除氣溶膠,係含有申請專利範圍第1項至第4項任一項所述的有害生物防除氣溶膠用組成物。 A pest-preventing aerosol composition according to any one of claims 1 to 4, wherein the pest-preventing aerosol composition according to any one of claims 1 to 4. 一種有害生物防除方法,係包括將有效量的有害生物防除氣溶膠用組成物噴灑於有害生物或該有害生物的棲息處,該有害生物防除氣溶膠用組成物含有式(1)表示的酯化合物,飽和烴溶媒,聚矽氧化合物及驅動劑: A pest control method comprising spraying an effective amount of a pest control aerosol composition onto a pest or a pest, the pest control composition containing the ester compound represented by the formula (1) , saturated hydrocarbon solvent, polyoxane and driver:
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