TW201326432A - Coating and method for manufacturing the coating - Google Patents
Coating and method for manufacturing the coating Download PDFInfo
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- TW201326432A TW201326432A TW101101031A TW101101031A TW201326432A TW 201326432 A TW201326432 A TW 201326432A TW 101101031 A TW101101031 A TW 101101031A TW 101101031 A TW101101031 A TW 101101031A TW 201326432 A TW201326432 A TW 201326432A
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- layer
- coating
- metal layer
- transparent substrate
- primer layer
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- 239000011248 coating agent Substances 0.000 title claims abstract description 19
- 238000000576 coating method Methods 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 21
- 239000002184 metal Substances 0.000 claims abstract description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000758 substrate Substances 0.000 claims abstract description 19
- 239000003973 paint Substances 0.000 claims abstract 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 12
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 10
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 7
- 239000004417 polycarbonate Substances 0.000 claims description 7
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 7
- 238000007738 vacuum evaporation Methods 0.000 claims description 7
- 239000006229 carbon black Substances 0.000 claims description 6
- 229920000515 polycarbonate Polymers 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 2
- 230000008020 evaporation Effects 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 1
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011651 chromium Substances 0.000 claims 1
- 238000000151 deposition Methods 0.000 claims 1
- 229910052709 silver Inorganic materials 0.000 claims 1
- 239000004332 silver Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract 2
- 238000012797 qualification Methods 0.000 abstract 2
- 239000010410 layer Substances 0.000 description 36
- 230000000694 effects Effects 0.000 description 7
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 239000011247 coating layer Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012994 photoredox catalyst Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000005019 vapor deposition process Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/06—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain multicolour or other optical effects
- B05D5/067—Metallic effect
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/56—Three layers or more
- B05D7/57—Three layers or more the last layer being a clear coat
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/02—Pretreatment of the material to be coated
- C23C14/024—Deposition of sublayers, e.g. to promote adhesion of the coating
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/18—Metallic material, boron or silicon on other inorganic substrates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/20—Metallic material, boron or silicon on organic substrates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/584—Non-reactive treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/62—Plasma-deposition of organic layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2350/00—Pretreatment of the substrate
- B05D2350/60—Adding a layer before coating
- B05D2350/65—Adding a layer before coating metal layer
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31692—Next to addition polymer from unsaturated monomers
- Y10T428/31699—Ester, halide or nitrile of addition polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Paints Or Removers (AREA)
Abstract
Description
本發明涉及一種鍍膜件及鍍膜件的製作方法,尤其涉及一種遮光效果好且具有良好外觀的鍍膜件及其製作方法。The invention relates to a method for manufacturing a coating material and a coating material, in particular to a coating material with good shading effect and good appearance and a manufacturing method thereof.
NCVM的主要特徵係結合了傳統真空鍍膜技術的特性,採用新的鍍膜技術、新的材料,做出不同於普通真空電鍍的金屬外觀效果,起到美化工件表面之功用。籍由NCVM對按鍵、導光柱等產品的表面處理,要求字體部分和導光面的部分能夠無遮蔽,使光線順利通过,保持高通过率,字體以外部分或導光面則不要求光線通过,但同時要保證塑膠面有高金屬質感又不影響電磁波信號的傳播,保持信號暢通,但NCVM在遮光效果方面受到很大的限制,很難達到完全的遮光效果。The main features of NCVM combine the characteristics of traditional vacuum coating technology, using new coating technology, new materials, making metal appearance effects different from ordinary vacuum plating, and beautifying the surface of the workpiece. The NCVM handles the surface treatment of buttons, light guides, etc., requiring the font portion and the light guide surface to be unobstructed, allowing light to pass smoothly, maintaining a high pass rate, and the light outside the font or the light guide surface does not require light to pass. At the same time, it is necessary to ensure that the plastic surface has a high metal texture without affecting the propagation of the electromagnetic wave signal, and keep the signal unblocked, but the NCVM is greatly limited in the shading effect, and it is difficult to achieve a complete shading effect.
鑒於此,本發明提供一種遮光效果好且具有良好外觀的鍍膜件。In view of this, the present invention provides a coated member having a good light-shielding effect and a good appearance.
另,還有必要提供一所述鍍膜件的製作方法。In addition, it is also necessary to provide a method of fabricating the coated member.
一種鍍膜件,其包括一透明基材,在該透明基材上依次形成有底漆層、金屬層和面漆層,所述底漆層為丙烯酸,該丙烯酸中添加质量百分比為35%~40%的二氧化鈦白色色漿或质量百分比為2%~4%炭黑或氧化鐵的黑色色漿,所述金屬層以真空蒸鍍的方法形成,所述面漆層為丙烯酸。A coated member comprising a transparent substrate on which a primer layer, a metal layer and a topcoat layer are sequentially formed, the primer layer being acrylic acid, and the acrylic acid is added in a mass percentage of 35% to 40% % of titanium dioxide white paste or a black paste of 2% to 4% by weight of carbon black or iron oxide, the metal layer being formed by vacuum evaporation, the topcoat layer being acrylic acid.
一種製造鍍膜件的方法。A method of making a coated member.
提供一透明基材;Providing a transparent substrate;
在該透明基材一表面上形成底漆層;Forming a primer layer on a surface of the transparent substrate;
所述底漆層為丙烯酸,該丙烯酸中添加质量百分比為35%~40%的二氧化鈦白色色漿或质量百分比為2%~4%炭黑或氧化鐵的黑色色漿;The primer layer is acrylic acid, and a white color paste of 35% to 40% by mass or a black color paste of 2% to 4% of carbon black or iron oxide is added to the acrylic acid;
籍由真空蒸鍍形成金屬層;Forming a metal layer by vacuum evaporation;
在金屬層上噴塗面漆層,該面漆層為丙烯酸。A topcoat layer is sprayed onto the metal layer, the topcoat layer being acrylic.
與習知技術相比,本發明所述鍍膜件可以在保留原NCVM工藝基本步驟和參數,籍由底漆層內添加一定比例的色漿實現了保持電磁波信號的暢通,并遮光效果好,且具有良好外觀的鍍膜件。Compared with the prior art, the coated member of the present invention can retain the basic steps and parameters of the original NCVM process, and maintain a certain proportion of the color paste in the primer layer to maintain the smoothness of the electromagnetic wave signal, and the shading effect is good, and A coated part with a good appearance.
請參閱圖1,本發明的鍍膜件10包括一透明基材11,在該透明基材11上形成底漆層13,在該底漆層13上形成金屬層15,該金屬層15以真空蒸鍍的方法形成,最後,在該金屬層15形成面漆層17。Referring to FIG. 1, the coated member 10 of the present invention comprises a transparent substrate 11 on which a primer layer 13 is formed, on which a metal layer 15 is formed, which is vacuum evaporated. A plating method is formed, and finally, a topcoat layer 17 is formed on the metal layer 15.
該透明基材11由透明的材料製成,如透明的塑膠材料,本較佳實施例中選取的塑膠材料為透明的聚碳酸酯(Polycarbonate,PC)或聚甲基丙烯酸甲酯(Polymethyl Methacrylate,PMMA)。The transparent substrate 11 is made of a transparent material, such as a transparent plastic material. The plastic material selected in the preferred embodiment is a transparent polycarbonate (Polycarbonate, PC) or a polymethyl methacrylate (Polymethyl Methacrylate, PMMA).
所述底漆層13主要成分為丙烯酸,底漆層13的厚度約為10-20μm。該底漆層13中添加有白色色漿,其质量百分比為35%~40%。該白色色漿主要成份係二氧化鈦顏料,其作用係配合鍍膜層遮蔽非導光區域的光線通过。該底漆層13中或添加有黑色色漿,其质量百分比為2%~4%,該黑色色漿主要成份係氧化鐵或炭黑顏料,其作用也係配合鍍膜層遮蔽非導光區域的光線通过。The primer layer 13 is mainly composed of acrylic acid, and the primer layer 13 has a thickness of about 10 to 20 μm. A white color paste is added to the primer layer 13 in a mass percentage of 35% to 40%. The main component of the white color paste is a titanium dioxide pigment, which acts in conjunction with the coating layer to shield the light passing through the non-light-conducting region. The primer layer 13 is added with a black color paste, and the mass percentage thereof is 2% to 4%. The main component of the black color paste is iron oxide or carbon black pigment, and the function is also matched with the coating layer to shield the non-light-conducting region. Light passes through.
該金屬層15通过真空蒸鍍形成,膜層厚度200-500nm,既滿足金屬質感高光外觀,又能滿足RF檢測,不干擾電磁波信號。The metal layer 15 is formed by vacuum evaporation, and the film layer has a thickness of 200-500 nm, which satisfies both the metallic texture and the high-gloss appearance, and satisfies the RF detection without interfering with the electromagnetic wave signal.
最後,噴塗面漆層17,所述面漆層17主要成分為丙烯酸,厚度約為10-15μm,經過流平,60oC烘烤5min,再經過紫外光固化。Finally, the topcoat layer 17 is sprayed. The topcoat layer 17 is mainly composed of acrylic acid and has a thickness of about 10-15 μm. It is leveled, baked at 60 o C for 5 min, and then cured by ultraviolet light.
本發明一較佳實施方式的鍍膜件10的製作方法,其包括如下步驟:A manufacturing method of a coated member 10 according to a preferred embodiment of the present invention includes the following steps:
提供一基材11。基材11由透明或半透明的材料製成,如透明的塑膠材料,本較佳實施例中選取的塑膠材料為透明的聚碳酸酯(Polycarbonate,PC)或聚甲基丙烯酸甲酯(Polymethyl Methacrylate,PMMA)。A substrate 11 is provided. The substrate 11 is made of a transparent or translucent material, such as a transparent plastic material. The plastic material selected in the preferred embodiment is a transparent polycarbonate (Polycarbonate, PC) or a polymethyl methacrylate (Polymethyl Methacrylate). , PMMA).
前處理:基材11放入無水乙醇中進行超聲波清洗,以去除基材11表面的油污漬,清洗時間為5~10min。Pretreatment: The substrate 11 was placed in absolute ethanol for ultrasonic cleaning to remove oil stains on the surface of the substrate 11, and the cleaning time was 5 to 10 minutes.
請參閱圖1,鍍膜件10包括一透明基材11、在該透明基材11上一面底漆層13,所述底漆層13主要成分為丙烯酸,厚度約為10-20μm,並在底漆層中添加二氧化鈦的白色色5%~40%或炭黑或氧化鐵的黑色色漿质量百分比為2%~4%,經過流平,70oC烘烤10min,再經過紫外光固化步驟完成。Referring to FIG. 1, the coating member 10 includes a transparent substrate 11 and a primer layer 13 on the transparent substrate 11. The primer layer 13 is mainly composed of acrylic acid and has a thickness of about 10-20 μm and is in a primer. The white color of 5% to 40% of titanium dioxide added to the layer or the black color paste of carbon black or iron oxide is 2% to 4%, which is leveled, baked at 70 o C for 10 minutes, and then subjected to ultraviolet curing step.
金屬層15,籍由真空蒸發鍍膜形成,其步驟參數為:鍍膜真空度3×10-8Pa,採用99.9%的鋁絲其直徑1.0mm,鍍料長度8-10cm,選擇雙電極真空蒸發鍍膜,公轉和自轉比為7:6,公轉15PRM,鍍膜電壓7-9V,鍍膜電流4000-5000A,蒸發時間7分鐘。該金屬層15的厚度200-500nm,經過以上蒸鍍製程處理後的鍍膜件10,既滿足金屬質感高光外觀,又能滿足RF檢測,達到不干擾電磁波信號的目的。The metal layer 15 is formed by vacuum evaporation coating, and the step parameters are: coating vacuum degree 3×10 -8 Pa, using 99.9% aluminum wire with a diameter of 1.0 mm, a plating length of 8-10 cm, and selecting a two-electrode vacuum evaporation coating. The ratio of revolution and rotation is 7:6, the revolution is 15PRM, the coating voltage is 7-9V, the coating current is 4000-5000A, and the evaporation time is 7 minutes. The metal layer 15 has a thickness of 200-500 nm, and the coated member 10 subjected to the above vapor deposition process satisfies both the metallic high-gloss appearance and the RF detection, and does not interfere with the electromagnetic wave signal.
噴塗面漆層17,所述面漆層17主要成分為丙烯酸,厚度約為10-15μm,經過流平,60oC烘烤5min,再經過紫外光固化步驟完成。The topcoat layer 17 is sprayed. The topcoat layer 17 is mainly composed of acrylic acid and has a thickness of about 10-15 μm. It is leveled, baked at 60 o C for 5 min, and then subjected to an ultraviolet curing step.
本發明所述鍍膜件10可以在保留原NCVM工藝基本步驟和參數的前提下,又實現了保持電磁波信號的暢通的遮光效果好且具有良好外觀的鍍膜件。The coating member 10 of the invention can realize the coating member with good light shielding effect and good appearance while maintaining the smooth electromagnetic wave signal under the premise of retaining the basic steps and parameters of the original NCVM process.
實驗測試Experimental test
1.附著力測試。3M膠帶黏3分鐘沿45度方向快速拉起,無脫落。1. Adhesion test. The 3M tape is quickly pulled up in the direction of 45 degrees for 3 minutes without peeling off.
2. 目視樣品無明顯色差。2. There is no obvious color difference in the visual sample.
3.光澤度要求20oC下並達到100GΜ以上,在1W的LED白光光源照射下目視無投射通过。3. Glossiness is required to reach 100G 20 above 20 o C, and no projection is observed under the illumination of 1W LED white light source.
10...鍍膜件10. . . Coated parts
11...透明基材11. . . Transparent substrate
13...底漆層13. . . Primer layer
15...金屬層15. . . Metal layer
17...面漆層17. . . Top coat
圖1係本發明一較佳實施方式鍍膜件的剖視放大示意圖。BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic enlarged cross-sectional view showing a coated member of a preferred embodiment of the present invention.
10...鍍膜件10. . . Coated parts
11...透明基材11. . . Transparent substrate
13...底漆層13. . . Primer layer
15...金屬層15. . . Metal layer
17...面漆層17. . . Top coat
Claims (9)
提供一透明基材;
在該透明基材一表面上形成底漆層;
所述底漆層為丙烯酸,該丙烯酸中添加质量百分比為35%~40%的二氧化鈦的白色色漿或质量百分比為2%~4%炭黑或氧化鐵的黑色色漿;
通过真空蒸鍍形成金屬層;
在金屬層上噴塗面漆層,該面漆層為丙烯酸。A method of manufacturing a coated member, comprising the steps of:
Providing a transparent substrate;
Forming a primer layer on a surface of the transparent substrate;
The primer layer is acrylic acid, and a white color paste of 35% to 40% by mass of titanium dioxide or a black color paste of 2% to 4% of carbon black or iron oxide is added to the acrylic acid;
Forming a metal layer by vacuum evaporation;
A topcoat layer is sprayed onto the metal layer, the topcoat layer being acrylic.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104506610A CN103184411A (en) | 2011-12-29 | 2011-12-29 | Film-coating member and manufacturing method thereof |
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| Publication Number | Publication Date |
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| TW201326432A true TW201326432A (en) | 2013-07-01 |
| TWI573884B TWI573884B (en) | 2017-03-11 |
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| US (1) | US20130171446A1 (en) |
| CN (1) | CN103184411A (en) |
| TW (1) | TWI573884B (en) |
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| CN103818177B (en) * | 2013-12-26 | 2017-05-10 | 东莞劲胜精密组件股份有限公司 | Surface decoration processing method of electronic equipment housing |
| CN106362920B (en) * | 2016-08-29 | 2020-02-21 | 晋江国盛新材料科技有限公司 | Surface modification process of EVA shoe material |
| CN109023244A (en) * | 2018-07-18 | 2018-12-18 | 东莞华清光学科技有限公司 | A kind of cover board grey NCVM plated film preparation process |
| CN109280888A (en) * | 2018-09-06 | 2019-01-29 | 维沃移动通信有限公司 | Shell preparation method and shell |
| CN111556676B (en) * | 2020-04-02 | 2021-11-12 | 维沃移动通信(重庆)有限公司 | Shell, preparation method thereof and electronic equipment |
| CN112871603A (en) * | 2021-01-08 | 2021-06-01 | 彭卫娟 | Metal paint coating and preparation method thereof |
| CN113025968A (en) * | 2021-03-11 | 2021-06-25 | 惠州市昌霖电子科技有限公司 | Vacuum plating PVD coating process |
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| US6413588B1 (en) * | 1999-01-11 | 2002-07-02 | E. I. Du Pont De Nemours And Company | Method of producing durable layered coatings |
| DE19930665A1 (en) * | 1999-07-02 | 2001-01-11 | Basf Coatings Ag | Basecoat and its use for the production of color and / or effect basecoats and multi-layer coating |
| EP1730244B1 (en) * | 2004-03-02 | 2009-09-23 | E.I. Du Pont De Nemours And Company | Decorative laminated safety glass |
| CN101879799A (en) * | 2009-05-04 | 2010-11-10 | 富准精密工业(深圳)有限公司 | Shell and manufacturing method thereof |
| CN102111972B (en) * | 2009-12-29 | 2015-07-29 | 深圳富泰宏精密工业有限公司 | Case of electronic device |
| US20120148848A1 (en) * | 2010-12-10 | 2012-06-14 | Martin David C | Polymeric substrates having a thin metal film and fingerprint resistant clear coating deposited thereon and related methods |
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| US20130171446A1 (en) | 2013-07-04 |
| CN103184411A (en) | 2013-07-03 |
| TWI573884B (en) | 2017-03-11 |
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