TW201300583A - Sheet wafer growth stabilization - Google Patents
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- TW201300583A TW201300583A TW101106994A TW101106994A TW201300583A TW 201300583 A TW201300583 A TW 201300583A TW 101106994 A TW101106994 A TW 101106994A TW 101106994 A TW101106994 A TW 101106994A TW 201300583 A TW201300583 A TW 201300583A
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- 230000006641 stabilisation Effects 0.000 title description 2
- 238000011105 stabilization Methods 0.000 title description 2
- 239000012768 molten material Substances 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910002804 graphite Inorganic materials 0.000 claims description 3
- 239000010439 graphite Substances 0.000 claims description 3
- NFFIWVVINABMKP-UHFFFAOYSA-N methylidynetantalum Chemical compound [Ta]#C NFFIWVVINABMKP-UHFFFAOYSA-N 0.000 claims description 3
- 229910003468 tantalcarbide Inorganic materials 0.000 claims description 3
- 235000012431 wafers Nutrition 0.000 description 233
- 230000005499 meniscus Effects 0.000 description 19
- 238000001816 cooling Methods 0.000 description 11
- 239000007789 gas Substances 0.000 description 10
- 238000005452 bending Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 239000013078 crystal Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 241000446313 Lamella Species 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
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- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
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- 239000000758 substrate Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B15/00—Single-crystal growth by pulling from a melt, e.g. Czochralski method
- C30B15/007—Pulling on a substrate
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B15/00—Single-crystal growth by pulling from a melt, e.g. Czochralski method
- C30B15/34—Edge-defined film-fed crystal-growth using dies or slits
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10F—INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- H10F71/00—Manufacture or treatment of devices covered by this subclass
- H10F71/121—The active layers comprising only Group IV materials
- H10F71/1221—The active layers comprising only Group IV materials comprising polycrystalline silicon
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/546—Polycrystalline silicon PV cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Crystals, And After-Treatments Of Crystals (AREA)
- Liquid Deposition Of Substances Of Which Semiconductor Devices Are Composed (AREA)
Abstract
一種形成薄片型晶圓的裝置,其具有一形成內部腔室的殼體,以及一坩鍋位於內部腔室中,且坩鍋具有一頂面。該坩鍋係構成以容納一容量之熔融材料。該裝置還具有一位於內部腔室中而與坩鍋頂面間隔開的晶圓導件,該晶圓導件形成一用於讓生長中之薄片型晶圓通過的通道。A device for forming a wafer-type wafer having a housing forming an internal chamber, and a crucible being located in the internal chamber, the crucible having a top surface. The crucible is constructed to accommodate a volume of molten material. The device also has a wafer guide positioned in the interior chamber spaced from the top surface of the crucible, the wafer guide forming a passage for the growing wafer wafer to pass.
Description
本發明係有關於一種薄片型晶圓(Sheet wafers),特別是有關於一種形成薄片型晶圓的裝置及程序。 The present invention relates to a sheet wafer, and more particularly to an apparatus and program for forming a wafer wafer.
矽晶圓是各種半導體裝置的建構模組(Building blocks),該半導體裝置例如為太陽能電池(Solar cell)、積體電路及微機電系統(MEMS)裝置。舉例來說,美國麻薩諸塞州馬爾堡的長青太陽能股份有限公司(Evergreen Solar,Inc.of Marlboro,Massachusetts)以兩細線引入矽熔物的坩鍋所產生的矽薄片型晶圓來製造太陽能電池。這晶圓的類型可以被稱為“線薄片型晶圓(Filament sheet wafers)”,而在業內被稱為細帶狀(STRING RIBBONTM)晶圓。 The germanium wafer is a building block of various semiconductor devices, such as a solar cell, an integrated circuit, and a microelectromechanical system (MEMS) device. For example, Evergreen Solar, Inc. of Marlboro, Massachusetts, USA, manufactures tantalum wafers from crucibles that are introduced into a crucible with two thin wires. Solar battery. This type of wafer may be referred to as "Filament sheet wafers" and is referred to in the industry as a STRING RIBBON (TM ) wafer.
帶狀拖曳(Ribbon pulling)技術使用已經驗證過的製程來製造高品質的矽晶體(Silicon crystal),然而此製程技術所製造的薄片型晶圓會扭曲到某種程度(此項技術中亦稱為“彎曲”)。 Ribbon pulling technology uses proven processes to produce high-quality silicone crystals, but wafer-type wafers produced by this process technology are distorted to some extent (also known in the art). To "bend").
根據本發明的一實施例,一形成薄片型晶圓的裝置具有一形成內部腔室的殼體,以及一坩鍋位於該內部腔室中,且該坩鍋具有一頂面。該坩鍋係構成以容納一容量之熔融材料。該裝置還具有一位於內部腔室中而與該坩鍋頂面間隔開的晶圓導件,該晶圓導件形成一用於讓生長中之薄片型晶圓通過的通道。 In accordance with an embodiment of the invention, a device for forming a wafer wafer has a housing defining an interior chamber, and a crucible is located in the interior chamber, and the crucible has a top surface. The crucible is constructed to accommodate a volume of molten material. The apparatus also has a wafer guide positioned in the interior chamber spaced from the top surface of the crucible, the wafer guide forming a passage for the growing wafer wafer to pass.
該裝置也可以具有一位於用於控制該內部腔室中之溫度的後熱器區。該晶圓導件可以至少部分在該後熱器區中。此外,該晶圓導件可以包含由 該後熱器的至少兩個相對表面所延伸的複數個柱體。或者,抑或除此之外,該晶圓導件可以包含由該後熱器的至少兩個相對表面所延伸的一對實心構件。 The apparatus can also have an afterheater zone located to control the temperature in the internal chamber. The wafer guide can be at least partially in the afterheater zone. In addition, the wafer guide can be comprised of a plurality of cylinders extending from at least two opposing surfaces of the afterheater. Alternatively, or in addition, the wafer guide can include a pair of solid members extending from at least two opposing surfaces of the afterheater.
該坩鍋進一步可以包含其頂面上的熔融材料(例如,多結晶體矽)。該熔融材料形成一由該坩鍋延伸的薄片型晶圓,當它進入及通過該後熱器區,於此以一種受控制的方式冷卻,初期冷卻是非常迅速的。該等晶圓導件柱體被設置在熔物表面附近,但不能太近而實質影響薄片的冷卻(特別是在該迅速的初期冷卻期間)或引起額外的冷卻。該晶圓導件被設置得愈遠離彎液面(Meniscus),對於該彎液面移動的穩定化作用愈小。 The crucible may further comprise a molten material (eg, a polycrystalline crucible) on its top surface. The molten material forms a sheet wafer extending from the crucible as it enters and passes through the afterheater zone where it is cooled in a controlled manner and the initial cooling is very rapid. The wafer guide posts are disposed adjacent the surface of the melt, but not too close to substantially affect the cooling of the sheet (especially during the rapid initial cooling) or cause additional cooling. The further the wafer guide is placed away from the meniscus, the less stabilizing the movement of the meniscus is.
該內部腔室因此可視為在該坩鍋及一後平穩區之間具有一平穩區。該晶圓導件係至少部分定位於該後平穩區中。該後平穩區的位置及尺寸是根據該裝置被設計來使用的該熔融材料決定。 The internal chamber can thus be considered to have a plateau between the crucible and a rear plateau. The wafer guide is at least partially positioned in the rear plateau. The position and size of the rear plateau is determined by the molten material that the device is designed to use.
該通道被視為具有一長度、一高度及一寬度(即該寬度是相對的晶圓導件之間的間隙)。在某些實施例中,該晶圓導件包含向內延伸來改變該通道寬度的複數個晶圓導件。例如,該通道可以具有一對末端區及一中央區。因此該中央區內該通道的寬度可以小於該對末端區。此外,該高度較佳比該長度小得許多,及/或該通道可以為長形。 The channel is considered to have a length, a height, and a width (ie, the width is a gap between opposing wafer guides). In some embodiments, the wafer guide includes a plurality of wafer guides extending inwardly to change the width of the channel. For example, the channel can have a pair of end regions and a central region. Thus the width of the channel in the central zone may be less than the pair of end zones. Moreover, the height is preferably much smaller than the length, and/or the channel can be elongated.
形成該晶圓導件應使用該裝置中能夠承受預期溫度(例如超過1200℃)的材料。例如,除其他之外,該晶圓導件可以是由碳化矽及石墨的至少一種所形成。 The formation of the wafer guide should use materials in the device that can withstand the expected temperatures (eg, over 1200 ° C). For example, the wafer guide may be formed of at least one of tantalum carbide and graphite, among others.
根據本發明的另一實施例,一形成薄片型晶圓的方法及裝置,其是添加熔融材料至一熔爐中的坩鍋,且以一對細線由該熔融材料生長出一薄片 型晶圓。該方法及裝置使該生長中薄片型晶圓的至少一部分通過一定位於該熔爐的後平穩區中的晶圓導件構件。為此,此晶圓導件構件形成一具有長形的通道,用以讓該生長中薄片型晶圓通過。 According to another embodiment of the present invention, a method and apparatus for forming a wafer-type wafer is a crucible in which a molten material is added to a furnace, and a thin sheet is grown from the molten material by a pair of thin wires. Wafer. The method and apparatus pass at least a portion of the growing sheet wafer through a wafer guide member that is located in a rear plateau of the furnace. To this end, the wafer guide member forms an elongated channel for the growth of the growing wafer wafer.
在例示性實施例中,一薄片型晶圓熔爐具有一內部結構,用於限制生長中薄片型晶圓的移動於其局部彎液面(Local meniscus)。這將顯著有效地緩和或消除潛在晶圓彎曲的一來源。為此,該熔爐具有複數個晶圓導件策略地位於彎液面附近,而在彎液面的下游。當適當地定位,該等晶圓導件減少由後製程而引起的晶圓移動,例如當其持續生長時,輸送及抽出該晶圓。下述說明例示性實施例的細節。 In an exemplary embodiment, a sheet-type wafer furnace has an internal structure for limiting the movement of the growing wafer-type wafer to its local meniscus. This will significantly effectively mitigate or eliminate a source of potential wafer bowing. To this end, the furnace has a plurality of wafer guides strategically located near the meniscus and downstream of the meniscus. When properly positioned, the wafer guides reduce wafer movement caused by post-processes, such as transporting and withdrawing the wafer as it continues to grow. The details of the illustrative embodiments are described below.
第1圖係顯示根據本發明例示性實施例構成的線薄片型晶圓(Filament sheet wafer)10。該晶圓10可以類似於例如美國麻薩諸塞州馬爾堡的長青太陽能股份有限公司的線狀矽晶帶晶圓。某種程度上類似於其他線薄片型晶圓,此薄片型晶圓10大致呈矩形,且在其正面和背面具有相當大的表面面積。 Fig. 1 shows a film sheet wafer 10 constructed in accordance with an exemplary embodiment of the present invention. The wafer 10 can be similar to a linear twin ribbon wafer of Evergreen Solar Co., Ltd., for example, Marburg, Massachusetts, USA. To some extent similar to other wire sheet wafers, the wafer wafer 10 is generally rectangular in shape and has a relatively large surface area on its front and back sides.
該薄片型晶圓10的厚度會改變,且相對於其長度及寬度尺寸非常薄(以下將討論)。儘管如此,該線薄片型晶圓10可視為橫越長度及/或是寬度具有一平均厚度。例如,該薄片型晶圓10橫越寬度可以具有一介於80微米至320微米之間的厚度。某些實施例具有一介於100微米至200微米之間的平均厚度,例如170微米左右。該線薄片型晶圓10主要可以包括各種晶體類型的任一種,例如多結晶體(Multi-crystalline)、單晶質(Single crystalline)、多晶質(Polycrystalline)、微晶質(Microcrystalline)或是非晶 質材料(Amorphous,如矽)等。 The thickness of the wafer wafer 10 will vary and is very thin relative to its length and width dimensions (discussed below). Nonetheless, the wire sheet wafer 10 can be viewed as having an average thickness across the length and/or width. For example, the sheet wafer 10 may have a thickness between 80 microns and 320 microns across the width. Some embodiments have an average thickness between 100 microns and 200 microns, such as around 170 microns. The wire sheet wafer 10 may mainly include any of various crystal types, such as multi-crystalline, single crystalline, polycrystalline, microcrystalline or amorphous. Amorphous (such as 矽) and so on.
如所屬領域的技術人員所知,從一對由矽材(例如多結晶體矽或單晶矽)實質封裝的細線12(亦稱為絃)形成該線薄片型晶圓10。該矽材可以稍微延伸於該細線12之外以形成該薄片型晶圓10的邊緣。第1圖係藉由沿著該晶圓10長邊的想像虛線顯示該細線12以說明這一點。 As known to those skilled in the art, the wire-sheet wafer 10 is formed from a pair of thin wires 12 (also referred to as strings) substantially encapsulated by a coffin (e.g., polycrystalline germanium or single crystal germanium). The coffin may extend slightly beyond the thin line 12 to form an edge of the sheet wafer 10. The first figure illustrates this by displaying the thin line 12 along the imaginary dotted line on the long side of the wafer 10.
對於本討論之目的,該晶圓10平行於該等細線12的邊緣之間的距離,其被視為是該晶圓10的“寬度”。第1圖明確標出這個尺度。該等細線12因此被視為是大致垂直於主體的寬度而延伸。因此可以從第1圖的立體圖中,形成寬度的該兩邊緣(或兩側)可視為“左和右邊緣(或側)”。在一個相應的方式中,第1圖還明確顯示“長度”尺寸,其大致是垂直於寬度,亦即大致平行於該等細線12。此外,從第1圖的立體圖中形成長度的該兩邊緣或兩側可視為是“頂側(邊緣)及底側(邊緣)”。 For the purposes of this discussion, the wafer 10 is parallel to the distance between the edges of the thin lines 12, which is considered to be the "width" of the wafer 10. Figure 1 clearly identifies this scale. The thin lines 12 are thus considered to extend substantially perpendicular to the width of the body. Therefore, from the perspective view of Fig. 1, the two edges (or both sides) forming the width can be regarded as "left and right edges (or sides)". In a corresponding manner, Figure 1 also clearly shows the "length" dimension which is generally perpendicular to the width, i.e., substantially parallel to the thin lines 12. Further, the two edges or both sides forming the length from the perspective view of Fig. 1 can be regarded as "top side (edge) and bottom side (edge)".
該晶圓10的長度會有很大的變化,取決於自動化流程在何處處理及/或操作者在何處切割該生長中薄片型晶圓10。自動化流程及/或操作者較佳是以生產較小而大致長度均勻之晶圓10的方式來切割/分離該薄片型晶圓10。該晶圓10可以具有一傳統尺寸的寬度,或大於發明人已知傳統線薄片型晶圓的寬度。例如,該晶圓10的寬度可能會超過140毫米左右。在某些實施例中,該晶圓10具有一介於145毫米到165毫米之間的寬度,或者156毫米左右。 The length of the wafer 10 can vary widely depending on where the automated process is processed and/or where the operator cuts the growing wafer wafer 10. Preferably, the automated process and/or operator cuts/separates the wafer wafer 10 in a manner that produces a wafer 10 that is relatively small and substantially uniform in length. The wafer 10 can have a width of a conventional size or greater than the width of a conventional wire sheet wafer known to the inventors. For example, the width of the wafer 10 may exceed about 140 mm. In some embodiments, the wafer 10 has a width of between 145 mm and 165 mm, or about 156 mm.
形成一薄片型晶圓10的程序包含許多變數及複雜性。實際上,在該晶圓10中,這些變數有些會令人不滿意地導致晶圓10的屈曲或彎曲;一種晶圓翹曲的形式。例如,某些傳統的薄片型晶圓技術從該生長中薄片型晶 圓10以雷射分割一較小的部分以形成一個別的晶圓10(如第1圖所示)之前,抓取該生長中薄片型晶圓10。此晶圓操縱機械性移動在晶圓10從熔融材料(以下將參照第2圖及其他圖討論的彎液面,“液固介面”)的相應坩鍋延伸時,移動該生長中晶圓10的基部。這種和其他此類的機械性操縱會引起該晶圓10的彎曲。 The process of forming a wafer wafer 10 involves many variables and complexities. In fact, in the wafer 10, these variables may somewhat unsatisfactorily cause buckling or bending of the wafer 10; a form of wafer warping. For example, some conventional thin-film wafer technologies from this growing lamella The growing wafer wafer 10 is captured by the circle 10 prior to laser dividing a smaller portion to form another wafer 10 (as shown in FIG. 1). The wafer manipulation mechanical movement moves the growing wafer 10 as it extends from the corresponding crucible of the molten material (hereinafter referred to as the meniscus, "liquid-solid interface" discussed in FIG. 2 and other figures). The base. This and other such mechanical manipulations can cause bending of the wafer 10.
如果彎曲度的總量太大,在製造中和製造後會較容易斷裂,使得該晶圓10通常具有很小的市場價值。例如當使用於一太陽能電池,程序通常是網版印刷銀或某些其他金屬在該線薄片型晶圓10的正面和背面上(在後面進行更詳細的討論)。許多傳統的網版印刷程序要求大致平坦的晶圓10,否則,該網版印刷程序可能毀壞該非常薄及易碎的晶圓10。這會顯著降低產量,從而增加成本。 If the total amount of curvature is too large, it will break more easily during and after manufacture, so that the wafer 10 generally has a small market value. For example, when used in a solar cell, the process is typically screen printing silver or some other metal on the front and back sides of the line wafer 10 (discussed in more detail later). Many conventional screen printing programs require a substantially flat wafer 10 that would otherwise destroy the very thin and fragile wafer 10. This will significantly reduce production and thus increase costs.
為了解彎曲,可以考慮一理想的線薄片型晶圓10,其是一完美的平面。如上所述,然而,該線薄片型晶圓10橫越該主體通常具有變化的厚度。因此一理想的、可變厚度線薄片型晶圓10整個主體在厚度中最厚部分的平面下面/之間。厚度中最厚部分可視為形成一“理想平面”。然而在實際上,不管該晶圓寬度,該主體可能有某些部分非期望地彎曲以引起某個邊緣(或側)延伸出該理想平面。 To understand the bend, an ideal wire sheet wafer 10 can be considered which is a perfect plane. As noted above, however, the wire sheet wafer 10 typically has a varying thickness across the body. Thus, an ideal, variable thickness line wafer wafer 10 is entirely under/between the plane of the thickest portion of the thickness. The thickest portion of the thickness can be considered to form an "ideal plane." In practice, however, regardless of the width of the wafer, the body may have portions that are undesirably curved to cause a certain edge (or side) to extend out of the ideal plane.
在例示性實施例中,該線薄片型晶圓10不具有延伸出該理想平面超過預定離面量的邊緣、面部或其他部分。例如,該晶圓10不得延伸出理想平面超過約2.5毫米。因此,晶圓製造及品管程序拒絕有任何部分延伸出該理想平面超過約2.5毫米的晶圓。例如,晶圓10具有一延伸離面約2.8毫米的邊緣,其可以被視為具有“一2.8毫米的彎曲”。 In an exemplary embodiment, the wire sheet wafer 10 does not have edges, faces or other portions that extend beyond the ideal plane beyond a predetermined amount of off-surface. For example, the wafer 10 must not extend beyond the ideal plane by more than about 2.5 millimeters. Therefore, wafer fabrication and quality control procedures reject any portion of the wafer that extends beyond the ideal plane by more than about 2.5 mm. For example, wafer 10 has an edge that extends approximately 2.8 millimeters from the face, which can be considered to have "a bend of 2.8 millimeters."
一種簡單測定彎曲是否小於最大容許量的方法,其是放置該晶圓10於一大致平坦的輸送帶上,且使該晶圓10通過約2.5毫米或小於上述理想平面(即該頂面的最高部分超過約2.5毫米)的桿或元件的底下。例如,某些程序以理想平面之上2.0毫米來進行這項檢驗。如果該晶圓10通過桿或元件的底下,其具有可接受的彎曲且可以商業化用於太陽能電池中。如果其不能通過桿的底下,是因為其具有太大的彎曲而被淘汰。預期不合格的晶圓10的該等邊緣(非面部)大多可能是離面。內部部分可以在該晶圓10的面部上,然而,還是有離面狀況而可能致使該晶圓報廢。 A method for simply determining whether a bend is less than a maximum allowable amount by placing the wafer 10 on a substantially flat conveyor belt and passing the wafer 10 through about 2.5 mm or less (i.e., the highest of the top surface) Part of the rod or element below about 2.5 mm). For example, some programs perform this test with 2.0 mm above the ideal plane. If the wafer 10 passes under the rod or element, it has acceptable curvature and can be commercialized for use in solar cells. If it can't pass under the pole, it is eliminated because it has too much bending. Most of the edges (non-faces) of the wafer 10 that are expected to fail are likely to be off-plane. The inner portion may be on the face of the wafer 10, however, there is still an off-surface condition that may cause the wafer to be scrapped.
因此彎曲是一個重要的問題。為控制彎曲,本發明人了解到生長中晶圓10的橫向移動必須仔細加以控制。為此,本發明人從源頭修改該晶圓生長熔爐以減少彎曲。 Therefore bending is an important issue. To control the bending, the inventors have learned that the lateral movement of the wafer 10 during growth must be carefully controlled. To this end, the inventors modified the wafer growth furnace from the source to reduce bending.
具體地,如所屬領域的技術人員所知,該等細線薄片型晶圓10是在高溫線薄片型晶圓生長熔爐中生長。第2圖係顯示本發明各實施例中一薄片型晶圓熔爐14。該熔爐14可以包括一形成封閉或密封內部(顯示於後圖中)的殼體16。該內部可實質上不含氧(例如防止燃燒)及包括一或更多的氣體,例如氬氣或其他惰性氣體,其可以從一外部氣體源頭提供。該內部包括一容納熔融矽的電阻加熱坩鍋18(如第3-5圖中所示),以及為大致同時生長一或更多的矽薄片型晶圓10之其他元件。儘管第2圖顯示四個薄片型晶圓10,該熔爐14可以大致同時生長更少或更多的線薄片型晶圓10。例如,該熔爐14可以生長兩寬薄片型晶圓10(亦稱為“晶體片10”)。 Specifically, as is known to those skilled in the art, the thin-line wafers 10 are grown in a high temperature wire wafer growth furnace. Fig. 2 is a view showing a sheet type wafer fusing 14 in each embodiment of the present invention. The furnace 14 can include a housing 16 that forms a closed or sealed interior (shown in the following figures). The interior may be substantially free of oxygen (e.g., to prevent combustion) and include one or more gases, such as argon or other inert gases, which may be provided from an external source of gas. The interior includes a resistance heating crucible 18 containing molten crucibles (as shown in Figures 3-5) and other elements for growing substantially one or more crucible wafers 10 simultaneously. Although FIG. 2 shows four wafer-type wafers 10, the furnace 14 can grow fewer or more wire-sheet wafers 10 substantially simultaneously. For example, the furnace 14 can grow two wide sheet wafers 10 (also referred to as "crystal sheets 10").
該殼體16可以包含一門20,以允許進行該內部及其元件的檢測,以及一或更多選擇附加的觀察窗22。該殼體16還具有一引導例如矽顆粒等原料 物質的入口(圖中未標示),使之進入該殼體16的內部至該坩鍋18。應該指出的是,前述矽原料和矽薄片型晶圓10的討論是一說明且意不在於限制本發明的所有實施例。例如,由其他材料可以形成該薄片型晶圓10,如金屬、玻璃、陶瓷或合金。 The housing 16 can include a door 20 to permit detection of the interior and its components, as well as one or more additional viewing windows 22. The housing 16 also has a material for guiding, for example, bismuth particles. The inlet of the substance (not shown) is brought into the interior of the housing 16 to the crucible 18. It should be noted that the foregoing discussion of the tantalum material and the tantalum wafer 10 is illustrative and is not meant to limit all embodiments of the present invention. For example, the sheet wafer 10 such as metal, glass, ceramic or alloy may be formed of other materials.
第3圖係顯示一具有去除部分殼體16的熔爐14之部分剖開立體圖,而第4圖係顯示一具有去除該殼體16的生長系統之剖視圖。如上所述,在該殼體16的內部中,該熔爐14包括一容納熔融材料24的坩鍋18。 3 is a partially cutaway perspective view showing a furnace 14 having a portion of the casing 16 removed, and FIG. 4 is a cross-sectional view showing a growth system having the casing 16 removed. As described above, in the interior of the housing 16, the furnace 14 includes a crucible 18 that houses a molten material 24.
在一實施例中,該坩鍋18可以具有一可支托或包含該熔融材料24(例如熔融多結晶體矽)的大致平坦的上表面。或者,該坩鍋18的其他實施例(圖中未標示)可以具有用於容納該熔融材料的牆體。該坩鍋18包含允許一或更多的細線12通過該坩鍋18的細線孔(圖中未標示)。當該等細線12通過該坩鍋18時,部分熔融矽於各自表面的彎液面(surface meniscil;即上面提到的液固介面)凝固,從而在各相對細線12之間形成該生長中薄片型晶圓10。為了促使晶圓並排生長,該坩鍋18為長形,具有一區域用於使薄片型晶圓10以並排配置的方式沿著其長度生長。然而,在其他實施例中,可以面對面的方式生長該等晶圓10。 In one embodiment, the crucible 18 can have a substantially flat upper surface that can support or contain the molten material 24 (e.g., molten polycrystalline crucible). Alternatively, other embodiments of the crucible 18 (not shown) may have walls for receiving the molten material. The crucible 18 includes a fine wire hole (not shown) that allows one or more thin wires 12 to pass through the crucible 18. When the thin wires 12 pass through the crucible 18, the surface meniscil of the respective surfaces is solidified, thereby forming the growing flakes between the respective relatively thin wires 12. Wafer 10. To facilitate wafer side-by-side growth, the crucible 18 is elongated and has an area for growing the sheet wafer 10 along its length in a side-by-side configuration. However, in other embodiments, the wafers 10 can be grown face to face.
為了至少部分控制在其內部的溫度曲線,該熔爐14具有在該殼體16中基於區域之熱需求所形成的隔熱物。例如,形成該隔熱物是基於1)含有該熔融材料24的區域(即該坩鍋18),以及2)含有產生的該生長中薄片型晶圓10的區域(後熱器28,以下將合併專利申請號13/015,047更詳細地討論)。為此,該隔熱物包括一形成含有該坩鍋18與該熔融材料24之範圍的隔熱底座26,以及一定位於該隔熱底座26(由立體圖視之)上之後熱器28。 In order to at least partially control the temperature profile inside it, the furnace 14 has an insulation formed in the housing 16 based on the heat demand of the zone. For example, the formation of the heat insulator is based on 1) a region containing the molten material 24 (ie, the crucible 18), and 2) a region containing the generated wafer-type wafer 10 (postheater 28, The combined patent application number 13/015,047 is discussed in more detail). To this end, the insulation comprises a thermally insulated base 26 forming a range containing the crucible 18 and the molten material 24, and a heat exchanger 28 located on the insulated base 26 (as viewed from a perspective view).
該後熱器28對於彎曲問題是很重要的,其為剛形成的晶圓10從非常高溫冷卻至環境溫度之所在。理想地,該後熱器28在橫越該晶圓10的X及Y方向引起冷卻的變動率基本上是不變的。為此目的,本發明人建構了該後熱器28。此外,參閱上述合併13/015,047專利申請,以了解關於該後熱器28的各種實施例的更多細節。 The afterheater 28 is important for the bending problem, which is where the wafer 10 just formed is cooled from very high temperatures to ambient temperatures. Ideally, the rate of change of the cooling caused by the afterheater 28 across the X and Y directions of the wafer 10 is substantially constant. To this end, the inventors constructed the afterheater 28. In addition, reference is made to the aforementioned incorporated patent application Serial No. 13/015,047 for further details of various embodiments of the afterheater 28.
在某些實施例中,該熔爐14還可以包含一從外部氣體來源(圖中未標示)經過一氣體冷卻岐管至氣體噴嘴30以供應氣體的氣體冷卻系統。該氣體冷卻系統可以提供氣體而進一步冷卻該生長中薄片型晶圓10且控制其厚度。舉例來說,如第3-5圖中所示,在該坩鍋18以上的範圍中,該等氣體冷卻噴嘴30可以面對該生長中薄片型晶圓10,即朝向前述提及從熔物延伸且含有該晶圓10之彎液面。 In certain embodiments, the furnace 14 may also include a gas cooling system that supplies gas from a source of external gas (not shown) through a gas-cooled manifold to the gas nozzle 30. The gas cooling system can provide a gas to further cool the growing sheet wafer 10 and control its thickness. For example, as shown in Figures 3-5, in the range above the crucible 18, the gas cooling nozzles 30 may face the growing sheet wafer 10, i.e., toward the aforementioned reference from the melt Extending and containing the meniscus of the wafer 10.
為緩和晶圓彎曲,該熔爐14具有複數個策略定位其內部中的晶圓導件32。為此,在該熔爐14的各通道中,該等晶圓導件32被定位非常接近於其相應的彎液面(即是接近當運作時會有彎液面的地方),但是不能太靠近於其相應的彎液面。如同在後面進行更詳細的討論,該等晶圓導件32被定位以減小其對在該熔爐14中溫度曲線的影響,且仍盡可能穩定化該生長中晶圓10。 To mitigate wafer bowing, the furnace 14 has a plurality of strategies for positioning the wafer guides 32 in its interior. To this end, in each channel of the furnace 14, the wafer guides 32 are positioned very close to their respective meniscus (i.e., close to where there is a meniscus when operating), but not too close On its corresponding meniscus. As discussed in more detail later, the wafer guides 32 are positioned to reduce their effect on the temperature profile in the furnace 14 and still stabilize the growing wafer 10 as much as possible.
具體地,第3-5圖均顯示根據本發明例示性實施例構成的一對晶圓導件32。這些晶圓導件32大致機械性保留該生長中晶圓10在其理想的位置,亦即從該熔融材料24延伸之彎液面的附近。換言之,該等晶圓導件32理想地補償於會移動該晶圓10之基部的後續機械性操縱(該生長中晶圓10的),故該晶圓10在彎液面上。因此該等晶圓導件32可以限制該晶圓在一 維或二維中移動,亦即垂直及/或平行於該彎液面的長度。 Specifically, Figures 3-5 each show a pair of wafer guides 32 constructed in accordance with an illustrative embodiment of the present invention. These wafer guides 32 substantially mechanically retain the growing wafer 10 in its desired position, i.e., near the meniscus from which the molten material 24 extends. In other words, the wafer guides 32 are ideally compensated for subsequent mechanical manipulations of the substrate that will move the wafer 10 (of the growing wafer 10) so that the wafer 10 is on the meniscus. Therefore, the wafer guides 32 can limit the wafer to a Move in dimension or two dimensions, that is, perpendicular and/or parallel to the length of the meniscus.
雖然第3-5圖只顯示部分時,第6A圖係顯示一晶圓導件的完整前視圖。該晶圓導件32以其端部34機械性連接於該後熱器28的內部表面,且具有一跨於其端部34之間的主體36。為了有額外的支撐結構,該晶圓導件32的某些實施例在其他區(例如該主體36中央部分的附近)固定於該後熱器28。如下所討論的,該生長中晶圓10可以接觸任何的相應導件32之表面。然而,為了減少接觸,本發明人設計該等晶圓導件32的高度相對於其長度是極小的。 While Figures 3-5 show only portions, Figure 6A shows a complete front view of a wafer guide. The wafer guide 32 is mechanically coupled at its end 34 to the interior surface of the afterheater 28 and has a body 36 that spans between its ends 34. In order to have an additional support structure, certain embodiments of the wafer guide 32 are secured to the afterheater 28 in other regions, such as in the vicinity of the central portion of the body 36. As discussed below, the growing wafer 10 can contact the surface of any of the respective leads 32. However, in order to reduce contact, the inventors have designed the height of the wafer guides 32 to be extremely small relative to their length.
該等導件32的高度可以被選擇作為通道寬度的函數,反之亦然。例如,可以預料的是,具有一較大寬度(如該晶圓10平均寬度的兩倍)及一較大高度之通道38是在具有一較小寬度及一較小高度之通道38對應的方式下操作。 The height of the guides 32 can be selected as a function of the width of the channel and vice versa. For example, it is contemplated that a channel 38 having a larger width (e.g., twice the average width of the wafer 10) and a larger height is associated with a channel 38 having a smaller width and a smaller height. Under the operation.
該等晶圓導件32應由普遍預期於晶圓熔爐14中可耐高溫之材料形成。例如,此溫度通常超過1400℃。因此,除其他之外,該等晶圓導件32可以由石墨或碳化矽形成。 The wafer guides 32 should be formed of a material that is generally expected to be resistant to high temperatures in the wafer furnace 14. For example, this temperature typically exceeds 1400 °C. Thus, among other things, the wafer guides 32 can be formed of graphite or tantalum carbide.
如其他圖示顯示,該後熱器28的兩主要內壁各支撐一晶圓導件32。因此各晶圓導件32直接相對於一相應晶圓導件32以形成一長型通道38,使得該生長中晶圓10能夠通過。此通道38能夠在其末端關閉,或在其末端開啟。在例示性實施例中,該通道38提供非常小的間隙,用以讓該晶圓10通過。例如,如果該晶圓10的最大厚度約為190微米,使得該晶圓通道38的厚度可能僅約為195微米到200微米。當然,其他實施例可以具有寬的晶圓通道38。 As shown in the other figures, the two main inner walls of the afterheater 28 each support a wafer guide 32. Thus, each wafer guide 32 is directly opposite a corresponding wafer guide 32 to form an elongated channel 38 such that the growing wafer 10 can pass. This channel 38 can be closed at its end or open at its end. In the exemplary embodiment, the channel 38 provides a very small gap for the wafer 10 to pass through. For example, if the wafer 10 has a maximum thickness of about 190 microns, the wafer channel 38 may have a thickness of only about 195 microns to 200 microns. Of course, other embodiments may have a wide wafer channel 38.
因此該通道38可以具有一尺寸均勻的寬度。於是,該通道寬度應大於該生長中晶圓10的最大預期厚度。如上所述,然而,許多薄片型晶圓10,包括第1圖所示者,橫越其寬度具有變化的厚度。因此,該等晶圓導件32可以被固定於該後熱器28,以改變該通道38橫越其長度的厚度。例如,該線薄片型晶圓10的末端可以比同一晶圓10沿其縱軸(亦即其寬度中央的附近)處還厚。因此例示性實施例可以構成該等晶圓導件32,以便該通道38在其末端寬過於其中央附近。因此,在這個範例中,該通道厚度從一端部34橫過向中央減少。 Thus the channel 38 can have a uniform width. Thus, the channel width should be greater than the maximum expected thickness of the growing wafer 10. As noted above, however, many sheet wafers 10, including those shown in Figure 1, have varying thickness across their width. Thus, the wafer guides 32 can be secured to the afterheater 28 to vary the thickness of the channel 38 across its length. For example, the end of the wire sheet wafer 10 may be thicker than the same wafer 10 along its longitudinal axis (i.e., near the center of its width). Thus, the exemplary embodiment can constitute the wafer guides 32 such that the channel 38 is wider at its end than near its center. Thus, in this example, the channel thickness decreases from one end 34 across the center.
實際上,可以在許多位置改變該通道厚度以更密切地追蹤該生長中晶圓10之變化的厚度。本發明人預期這樣變化的厚度通道38於該晶圓生長程序期間將提供改良結果。當然,基於該生長中晶圓10的預期尺寸及形狀(取決於用以形成該晶圓10的熔融材料之性質),所屬領域的技術人員將預先設定該通道38的尺寸及幾何形狀。 In fact, the channel thickness can be varied at many locations to more closely track the varying thickness of the growing wafer 10. The inventors expect that such varying thickness channels 38 will provide improved results during the wafer growth process. Of course, based on the expected size and shape of the wafer 10 in the growth (depending on the nature of the molten material used to form the wafer 10), those skilled in the art will pre-set the dimensions and geometry of the channel 38.
如上所述,該等晶圓導件32可以被應用於多通道晶圓生長熔爐14中。例如,在描述的方式中,四通道晶圓熔爐14的各通道較佳具有晶圓導件32,用於以上述方式限制該生長中晶圓10的移動。第6B圖係顯示一實施例,在其中兩通道晶圓熔爐14的各通道具有晶圓導件32,用以以所需方式減少晶圓彎曲。應該指出的是,第6B圖只顯示該後熱器28的一側。因此,該後熱器28之相應設置的一側具有相應的晶圓導件32以完成了實質限制晶圓移動的必要結構。 As described above, the wafer guides 32 can be applied to the multi-channel wafer growth furnace 14. For example, in the manner described, each channel of the four-channel wafer furnace 14 preferably has a wafer guide 32 for limiting the movement of the growing wafer 10 in the manner described above. Figure 6B shows an embodiment in which the channels of the two-channel wafer furnace 14 have wafer guides 32 to reduce wafer bowing in a desired manner. It should be noted that Figure 6B shows only one side of the afterheater 28. Accordingly, the correspondingly disposed side of the afterheater 28 has a corresponding wafer guide 32 to complete the necessary structure to substantially limit wafer movement.
許多設計限制建議一種使用晶圓導件32以減少晶圓彎曲的方法。首先,設置一塊附加材料非期望地相當接近彎液面,會作用得像是妨礙該晶 圓10適當冷卻之隔熱物。這會產生太薄且易碎的缺陷晶圓。當面對這個問題,本發明人發現減小該等晶圓導件32的尺寸能緩和冷卻問題,而仍提供相同的功能。 Many design limitations suggest a way to use wafer guides 32 to reduce wafer bowing. First, setting an additional material undesirably close to the meniscus will act as a hindrance to the crystal. Round 10 properly cooled insulation. This produces defective wafers that are too thin and fragile. In the face of this problem, the inventors have found that reducing the size of the wafer guides 32 can alleviate the cooling problem while still providing the same function.
因此,本發明人發現從該後熱器牆體延伸的複數個仔細定位的柱體/插腳/構件(後稱為“柱體40”)可以提供相應地效益(亦即該等柱體40形成一非連續的晶圓導件),而不是使用連續晶圓導件32。實際上,如果適當地定位(以下將討論),該非連續晶圓導件32可以在不顯著影響溫度曲線下實現抑制非期望的晶圓移動之效益。為此,第7圖係顯示一個實施此類型晶圓導件32的二通道晶圓熔爐14之後熱器牆體。與第6A圖一樣,該後熱器28相對應的一半與該後熱器28所顯示的部分一起作用,以形成限制非期望晶圓移動的通道38。 Accordingly, the inventors have discovered that a plurality of carefully positioned cylinders/pins/members (hereinafter referred to as "cylinders 40") extending from the afterheater wall can provide corresponding benefits (i.e., the formation of the cylinders 40) Instead of using a continuous wafer guide 32, a non-continuous wafer guide). In fact, if properly positioned (discussed below), the discontinuous wafer guide 32 can achieve the benefit of suppressing undesired wafer movement without significantly affecting the temperature profile. To this end, Figure 7 shows a heater wall after a two-channel wafer furnace 14 implementing this type of wafer guide 32. As with Figure 6A, the corresponding half of the afterheater 28 acts in conjunction with the portion of the afterheater 28 to form a channel 38 that limits undesired wafer movement.
為了更符合該晶圓10之變化的厚度,該等柱體40可以從該後熱器牆體延伸不同距離,從而有效地形成一可變厚度通道38。此外,該等柱體40可以具有不同表面面積,用以接觸該生長中薄片型晶圓10。各柱體40可以具有一相應的、直接相對安裝的柱體。或者,抑或除此之外,在各側上該等柱體40可以相互偏移。 To more closely match the varying thickness of the wafer 10, the posts 40 can extend a different distance from the afterheater wall to effectively form a variable thickness channel 38. Moreover, the pillars 40 can have different surface areas for contacting the growing wafer wafer 10. Each of the cylinders 40 can have a corresponding, directly oppositely mounted cylinder. Alternatively, or in addition, the posts 40 may be offset from each other on each side.
應該指出的是,這個討論提到在該後熱器28之各牆體上的複數晶圓導件32作為一個範例。然而,在其他實施例中,只設置一晶圓導件32在該後熱器28的一牆體上。該生長中晶圓10的物理性後續操縱僅在一方向(例如朝向該晶圓導件)中推進移動時,這種方式尤其奏效。此外,在其他實施例中,該後熱器28的一半可以具有一實心的晶圓導件,而該後熱器28的另一半可以具有一非連續晶圓導件32(如第7圖所示)。儘管其他實施例 可以在該後熱器28的同一側上具有非連續和連續的晶圓導件32。 It should be noted that this discussion refers to the plurality of wafer guides 32 on the walls of the afterheater 28 as an example. However, in other embodiments, only one wafer guide 32 is disposed on a wall of the afterheater 28. This approach is particularly effective when the physical subsequent manipulation of the growing wafer 10 is only propelled in one direction (e.g., toward the wafer guide). In addition, in other embodiments, one half of the afterheater 28 may have a solid wafer guide, and the other half of the afterheater 28 may have a discontinuous wafer guide 32 (as shown in FIG. 7). Show). Although other embodiments There may be non-continuous and continuous wafer guides 32 on the same side of the afterheater 28.
此外,某些實施例並非將該等晶圓導件32裝設至該後熱器28上。例如,該等晶圓導件32可以直接裝設於該內部腔室牆體。或者,該等晶圓導件32可以僅部分在該後熱器28中。 Moreover, some embodiments do not mount the wafer guides 32 to the afterheater 28. For example, the wafer guides 32 can be mounted directly to the interior chamber wall. Alternatively, the wafer guides 32 may be only partially in the afterheater 28.
不論其種類,如果設置太接近於彎液面,晶圓導件32仍可能對溫度曲線造成負面影響。這可能使得有人會設置該等晶圓導件32太過於遠離彎液面,以充分穩定化該晶圓10。當面臨這問題時,本發明人發現該熔爐14內一中間點,其可以最佳化穩定該晶圓10,且不致顯著影響該溫度曲線。 Regardless of the type, if the setting is too close to the meniscus, the wafer guide 32 may still have a negative impact on the temperature profile. This may cause someone to place the wafer guides 32 too far away from the meniscus to fully stabilize the wafer 10. In the face of this problem, the inventors have discovered an intermediate point within the furnace 14 that optimizes the stabilization of the wafer 10 without significantly affecting the temperature profile.
具體地,第8圖通過範例圖形化地顯示以多結晶體矽形成線薄片型晶圓10之操作晶圓熔爐14中的溫度曲線。這範例中此熔爐14以24毫米/分鐘左右的比率向上移動該晶圓10。x軸顯示晶圓相對於該彎液面頂面移動的時間,而y軸顯示在那時該熔爐14中相應位置上的溫度。 Specifically, FIG. 8 graphically shows, by way of example, a temperature profile in the operation wafer foiler 14 in which the linear wafer-type wafer 10 is formed in a polycrystalline body. In this example, the furnace 14 moves the wafer 10 upward at a rate of about 24 mm/min. The x-axis shows the time the wafer moved relative to the top surface of the meniscus, while the y-axis shows the temperature at the corresponding location in the furnace 14 at that time.
如所示,在彎液面頂部上的溫度接近1400℃。該溫度隨後即刻急劇下降至1250℃左右,其保持在大約15秒到大約16秒的平穩狀態。該熔爐14中溫度急劇下降(從大約0秒到大約3秒左右起)的區域在此被稱為“驟降區”,而該熔爐14中溫度平穩(大概從3秒至19秒左右起)的區域在此被稱為“平穩區”。在此熔爐14中的平穩區大致對應於該後熱器28(由立體圖視之)下的該熔爐內部區域。在平穩區內,帶狀晶圓及環境之間的熱流是一種由輻射熱流控制的非常微妙平衡。於是,在該熔爐14的區域上僅有些微冷卻。因此在此區域中設置該等晶圓導件32可能干擾此微妙輻射熱平衡。 As shown, the temperature on the top of the meniscus is close to 1400 °C. The temperature then drops sharply to about 1250 ° C immediately, which is maintained at a plateau of about 15 seconds to about 16 seconds. The region in the furnace 14 where the temperature drops sharply (from about 0 seconds to about 3 seconds) is referred to herein as the "sudden zone", and the temperature in the furnace 14 is stable (approximately from about 3 seconds to about 19 seconds). The area is referred to herein as the "stationary area." The plateau zone in this furnace 14 generally corresponds to the inner region of the furnace under the post-heater 28 (as viewed from a perspective view). In the plateau, the heat flow between the ribbon wafer and the environment is a very delicate balance controlled by the radiant heat flow. Thus, there is only some micro-cooling in the area of the furnace 14. Therefore, the placement of the wafer guides 32 in this region may interfere with this delicate radiant heat balance.
從大約19秒到大約60秒左右,該溫度大致呈線性下降。實際上,該 晶圓10一般線性冷卻比60秒還長許多(例如10分鐘)。為了方便起見,此圖示因此終止於60秒。這線性下降區域在此被稱為“後平穩區”。因此,為避開該平穩區,此例示性範例的該晶圓導件32是定位於後平穩區,其相符於大約19秒到大約60秒左右,或更多。為更穩定化該生長中晶圓10,且仍減少熱曲線影響,定位該等晶圓導件32盡可能接近該平穩區(例如大約相符21秒到22秒的後平穩區中)。在另一範例,該等晶圓導件32可以是定位於29秒左右的後平穩區中。此區域可為該後熱器28的基部/入口。在一熔爐14中,例如,此區域是從該坩鍋18的表面間隔約22毫米。儘管晶圓導件32應該在從彎液面的任何距離處都穩定化該生長中晶圓10,當在後平穩區的下部/早期階段時,預期該等晶圓導件32有較佳的表現。 From about 19 seconds to about 60 seconds, the temperature drops substantially linearly. In fact, the The wafer 10 is generally linearly cooled much longer than 60 seconds (e.g., 10 minutes). For the sake of convenience, this illustration thus ends in 60 seconds. This linearly falling region is referred to herein as the "post-stationary region." Thus, to avoid this plateau, the wafer guide 32 of this illustrative example is positioned in a post-stationary zone that corresponds to about 19 seconds to about 60 seconds, or more. To more stabilize the growing wafer 10 and still reduce the effects of the thermal profile, the wafer guides 32 are positioned as close as possible to the plateau (e.g., in a post-stationary region that approximately corresponds to 21 seconds to 22 seconds). In another example, the wafer guides 32 can be positioned in a rear plateau of about 29 seconds. This area may be the base/inlet of the afterheater 28. In a furnace 14, for example, this area is spaced about 22 mm from the surface of the crucible 18. Although the wafer guide 32 should stabilize the growing wafer 10 at any distance from the meniscus, it is expected that the wafer guides 32 are preferred when in the lower/early stage of the back plateau. which performed.
當然,該等晶圓導件32的特定溫度及位置僅是通過範例討論。由於所屬領域的技術人員是根據製作該晶圓10(除此之外)之材料決定設置該等晶圓導件32,該實際位置根據該坩鍋18所包含的材料而有變化。 Of course, the particular temperatures and locations of the wafer guides 32 are discussed by way of example only. Since the person skilled in the art determines the placement of the wafer guides 32 based on the material from which the wafer 10 is fabricated, the actual position varies depending on the material contained in the crucible 18.
因此例示性實施例機械性限制了該薄片型晶圓10在由該坩鍋18生長時的某些非期望的運動。在許多先前技術的薄片型晶圓生長程序中,這應該緩和了一重要的內在彎曲來源。 The exemplary embodiment thus mechanically limits some undesirable movement of the sheet wafer 10 as it is grown by the crucible 18. In many prior art wafer wafer growth procedures, this should alleviate an important source of intrinsic bending.
雖然本發明已用較佳實施例揭露如上,然其並非用以限定本發明,本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 While the invention has been described above in terms of the preferred embodiments, the invention is not intended to limit the invention, and the invention may be practiced without departing from the spirit and scope of the invention. The scope of protection of the present invention is therefore defined by the scope of the appended claims.
10‧‧‧薄片型晶圓、晶圓 10‧‧‧Sheet wafers, wafers
12‧‧‧細線 12‧‧‧ Thin line
14‧‧‧熔爐 14‧‧‧Furn
16‧‧‧殼體 16‧‧‧Shell
18‧‧‧坩鍋 18‧‧‧ 坩 pot
20‧‧‧門 20‧‧‧
22‧‧‧觀察窗 22‧‧‧ observation window
24‧‧‧熔融材料 24‧‧‧ molten material
26‧‧‧隔熱底座 26‧‧‧Insulated base
28、28a、28b‧‧‧後熱器 28, 28a, 28b‧‧‧ after heat exchanger
30‧‧‧氣體冷卻噴嘴 30‧‧‧ gas cooling nozzle
32‧‧‧晶圓導件 32‧‧‧ Wafer Guides
34‧‧‧端部 34‧‧‧End
36‧‧‧主體 36‧‧‧ Subject
38‧‧‧通道 38‧‧‧ passage
40‧‧‧柱體 40‧‧‧Cylinder
第1圖係顯示根據本發明例示性實施例構成的薄片型晶圓。 Fig. 1 shows a sheet-type wafer constructed in accordance with an exemplary embodiment of the present invention.
第2圖係顯示本發明例示性實施例中薄片型晶圓生長系統的部分立體圖。 Figure 2 is a partial perspective view showing a wafer type wafer growth system in an exemplary embodiment of the present invention.
第3圖係顯示本發明第2圖去除部分殼體之薄片型晶圓生長系統的部分剖開立體圖。 Fig. 3 is a partially cutaway perspective view showing a sheet-type wafer growth system in which a part of the casing is removed in Fig. 2 of the present invention.
第4圖係顯示本發明各實施例中一薄片型晶圓生長系統的剖視圖,其在後熱器中具有一導件系統。 Figure 4 is a cross-sectional view showing a wafer type wafer growth system in various embodiments of the present invention having a guide system in the afterheater.
第5圖係顯示熔爐的部分近視圖。 Figure 5 is a partial close up view showing the furnace.
第6A圖及第6B圖係顯示根據本發明例示性實施例晶圓導件兩用法的一種。 6A and 6B show one of two uses of a wafer guide according to an exemplary embodiment of the present invention.
第7圖係顯示根據本發明例示性實施例第二種構成的晶圓導件。 Figure 7 is a diagram showing a wafer guide of a second configuration in accordance with an exemplary embodiment of the present invention.
第8圖係顯示一樣本晶圓熔爐中的溫度曲線圖。 Figure 8 is a graph showing the temperature profile in the same wafer furnace.
10‧‧‧薄片型晶圓、晶圓 10‧‧‧Sheet wafers, wafers
12‧‧‧細線 12‧‧‧ Thin line
14‧‧‧熔爐 14‧‧‧Furn
16‧‧‧殼體 16‧‧‧Shell
18‧‧‧坩鍋 18‧‧‧ 坩 pot
20‧‧‧門 20‧‧‧
24‧‧‧熔融材料 24‧‧‧ molten material
26‧‧‧隔熱底座 26‧‧‧Insulated base
28、28a、28b‧‧‧後熱器 28, 28a, 28b‧‧‧ after heat exchanger
32‧‧‧晶圓導件 32‧‧‧ Wafer Guides
34‧‧‧端部 34‧‧‧End
Claims (15)
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| AT382299B (en) * | 1983-08-01 | 1987-02-10 | Haas Franz Waffelmasch | DEVICE FOR PRODUCING WAFFLE BLOCKS |
| JP3662404B2 (en) * | 1997-11-19 | 2005-06-22 | 芝浦メカトロニクス株式会社 | Wafer sheet stretching apparatus and pellet bonding apparatus using the same |
| US6423642B1 (en) * | 1998-03-13 | 2002-07-23 | Semitool, Inc. | Reactor for processing a semiconductor wafer |
| DE60316337T2 (en) * | 2002-10-18 | 2008-06-05 | Evergreen Solar Inc., Marlborough | METHOD AND DEVICE FOR CRYSTAL BREEDING |
| WO2010025125A1 (en) * | 2008-08-29 | 2010-03-04 | Evergreen Solar, Inc. | Single-sided textured sheet wafer and manufactoring method therefore |
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