201133892 六、發明說明： 【發明所屬之技術領域】 本發明是關於一種利用奈米管技術所製造的陣列串接式太陽 能電池模組’尤其是關於一種利用區塊化陽極區與陰極區之串/並 聯的太陽能電池模組。 【先前技術】 面對日益升向的能源危機與環境污染問題，使得各式各樣的 再生能源產業開始蓬勃發展，例如，太陽能、風能與生質能等。 其中’太1%能電池被認為是最具發展潛力的再生能源，亦因此， 其全球市場也正以驚人的速度進行成長。在目前已知的數種太陽 月&電池當中，第一代太陽能電池是以石夕(別)為主要材質的單/複晶石夕 太陽能電池，其可達到12-20%的光電轉換效率，為目前太陽能電 池市場之主要佔有者，其主要用途為應用在可攜式電子產品之電 源以及建構太陽能發電模組上。第一代太陽能電池的基本構造為 P/N型半導體的組合，當照光時，電子被激發而產生電子與電洞的 分流，在受到内電位的影響下，分別被；^型與p型半導體所吸引 而聚集在元件的兩端，再經由外電路導出形成電流。其優點為具 有相當高的光電轉換效率，但缺點為製程條件嚴格以及製造成本 高昂。 第一代太％能電池為無機半導體薄膜(thin fiim)大陽能電池， 其包含非晶矽(a-Si，amorphous silicon)太陽能電池以及化合物半導 體薄膜電池’例如：碲化鎘(CdTe)、砷化鎵(GaAs)與硒化銅銦鎵 (CIGS’copper indium gallium seienide)。雖然薄膜電池的光電轉換效 土多較矽晶太陽能電池為低，但是材料成本也相對低廉，其為目 前成本最低的商業化太陽能電池，多用於消費性電子產品中。此 類薄膜太1%能電池的優點為光谱吸收範圍廣，且且有較好的軌穩 定性，但是材料巾所·的重金觸環境會有嚴^傷害，因^ 仍須積極尋歸代方式。其中，CIGS _场能電池是由銅銦鎵 石西所組成的一二五族化合物半導體材料加以構成，其是利用共蒸 201133892 鍍技術來製備-吸收層薄膜’膜厚只需< 3哗，因此在製造成本 上較石夕晶太陽能電池為低，並可達成接近2G%的光賴換效率。 目則最丈矚目的應屬第三代新型太陽能電池，其宗旨為導入 新，材料與鑛技術來製備低成本以及高效率的太陽能電池，希 望藉由新結構的引進，而達成增加光電轉率 分為有機導”分子或是新穎奈米材二、二J結構要； =利用有機兩分子作為光能轉換媒介之高分子太陽能電池，其 轉才、效，從開始的1%町，已提昇至5〜你，高分子太陽能電池 土有質、可撓曲特性、製程環保、低製作成本及高應用性等 立點，疋屬於第二代新興太陽能電池中極具潛力的一種。另一種 斤型太陽也電池則為寬能隙半導體奈米結構的引進，結合光合作 透明導電玻璃為基材，於其上披覆一層具奈米結構 性氧彳b辞或—氧化鈦轉體賴作為王作電極，由於此多 具有A表面積’可在表面附著—層絲材料，藉以使光 狄光能’可將電子迅速地傳遞至半導體薄膜並導出 丄Β。目刖最向的能量轉換效率可達到12〇/0，雖然效率不及 但具有低成本與製程簡易的優點’並可進行大 -減撓ί1電池元件的製備’此種突破性的發展已受到研究 =:業界_度魏’未來將發展成騎—代太陽能電池技術 I王流。 處理法(An〇dizati〇n)技術的提昇，奈米管二氧化鈦 究在丄Χίίϊϊ發曰趨成熟，這也促使奈米管太陽能電池的研 章^妊^重視。由於NT-Ti〇2薄膜製程簡便的特性， ίίίΞΓΛ能電池未來成桃續式捲對捲(偷，大面積 粒太ί能7太陽能電池與傳統奈米 产收集效*; (2)電子與電洞在奈米管内分 二ϋ;⑶電解液封裝於奈米管中不易滲漏，元件壽 極處理法製賴易，可降低太陽能電池的製程 成本，u❿極具有可撓曲特性。NT_太陽能電池元件共由^ 201133892 個主要成分(Ti/Ti〇2陽極、電解質以及Pt/TCO陰極)所組成，因此 元件包含了 Ti/Ti〇2、Ti/電解質、TiCV電解質、:pt/電解質等界面。 【發明内容】 本發明之一實施樣態可提供一種陣列串接式太陽能電池模組 的結構，包含：一透明基板；一透明導電薄膜，形成在該透明基 板上，其中該透明導電薄膜被區塊化成複數個分隔區域，並且將 於其上形成有該透明導電薄膜的該透明基板作為一太陽能電池模 組的陰極；一或多個導電基板，於其表面上形成一或多個區域的 ，子傳輸層，其中該電子傳輸層之一或多個區域與該複數個分隔 區域相匹配，該電子傳輸層係由複數根半導體奈米管所構成，並 士將於其上形成有該電子傳輸層的該導電基板作為社陽能電池 模組的陽極；一觸媒層，形成在該陰極上；一光敏染料，附著在 導體奈米管的管壁上；以及—電洞傳輸層，設置在該陰極盘 該IW極之間。 〃 明之另—實施樣態可提供—種_串接式太陽能電池模 垃方法，包含下列步驟：將一電洞傳輸層設置在一陣列串 ^陽能電賴組的陽極與陰極之間；將該雜與該陰極接合 使該太陽能電池漁具有三日総構造；錢在該太陽 月b電池模組的外部表面覆蓋一矽膠層。 該透明導電薄膜區塊化成複數個分隔區域，其中將於 值私麻ta/夕個導電基板的表面上形成-或多麵域的電子 模έ且又另—實施樣態可提供—種陣列串接式太陽能電池 方法，包含下列步驟：在—透明基板上形成-透明導 =，ϋΐ子傳輸層之一或多個區域與該複數個分隔區域 於並上^^雜聽由魏根半導縣米管賴成，並且將 的該導電細乍為該太陽能電池模組 媒染料附著於該半導體奈米管的管壁上；使一觸 、θ 陰極上，將—電卿輸層設置在該陰極與該陽極之 201133892 間；以及將該陽極與該陰極接合在一起。 依照本發明’吾人可依輸出電壓與電流值的需求而製造出具 有串聯形式或並聯形式的串接式染料敏化太陽能電池模組。 本發明之其他實施樣態以及優點可從以下與用以例示本發明 原理範例之隨附圖式相結合的詳細說明而更顯明白。 【實施方式】 以下將藉由乾例方式來說明本發明之實施例，而這些實施例 僅為示例性而非限制性。一' 春第一實施例 圖1顯示依照本發明之第一實施例之串接式染料敏化太陽能 電池模組100的橫剖面圖。染料敏化太陽能電池模組1〇〇為一種 串聯式染料敏化太陽能電池模組。染料敏化太陽能電池模組100 包含β :透明基板110、透明導電薄膜氧化層12〇、輔助電極13〇、 陰/陽極接合材140、電洞傳輸層150、電子傳輸層16〇、以及導電 ^板170。電洞傳輸層150可含有峨離子，而電洞傳輸層15〇的型 恶可包括：液態、膠態、或固態。導電基板17〇的材質可為銦(Ιη)、 鋅(Ζη)、錫(Sn)、鈦⑼、或鎢(w)。陰/陽極接合材14〇可為一種 • 可塑性分子膜，例如熱縮膜、熱固性膜、熱塑性膜、紫外光固化 膜、或矽膠膜。 在導電基板170上形成電子傳輸層160,並將於其上形成有電 子，輸層160的導電基板17〇作為染料敏化太陽能電池模組丨〇〇 的陽極，於其中，電子傳輸層160係由複數根半導體奈米管所構 成，在使光敏染料(未圖示)附著在這些半導體奈米管的管壁上之 後，即可使其成為電子的供應來源以及傳輸途徑。此光敏染料可 士有機金屬染料、無機光敏染料、或有機光敏染料。吾人可藉由 、包ί、旋轉塗佈法、或壓注法，使光敏染料附著在這些半導體 ，米管的管壁上。例如，適合作為陽極之電子傳輸層16〇的材料 可為二氧化矽(Si〇2)、三氧化二銦(ιη2〇3)、三氧化鎢(w〇3)、二氧 201133892 形輸锡(Sn〇2) °舉例來說，一種 處理法、化學氣相沉法吉水熱法、陽極 附著半後再使光敏染料 為:藉由旋轉塗佈法二另=電 體奈米管附著在導電基板170的表面上，然後再=== 奈夕f管上，此時，導電基板i7G可為金屬或非金屬 :!=奈此二使這些奈米管的管内附著倾 膠·凝膠法、水熱法、陽極處理法、化學氣相沉積法、 或物理—積法，將透明導電細氧化層⑽形成於透明基板 110上，並將於其上形成有透明導電薄膜氧化層12〇的透明基板 110作為朵料敏化太陽能電池模組1〇〇的陰極。一般而言，透明基 板110以及透明導電薄膜氧化層120可為透明或半透明之材料: 舉例來說，適合作為透明導電薄膜氧化層（或稱為透明導電薄 膜)120的材料可為銦錫氧化物(IT〇，細腦血⑽㈣、鋁辞氧化 物(AZ0 ’ Al-Zn oxides)、錄錫氧化物(ΑΤΟ，antimony doped tin oxides)、或氟錫氧化物(FTO ’ fluorine doped tin oxides);以及透明 基板110可為透明玻璃基板、透明塑膠基板等等的透明基板。例 如，此塑膠基板可由聚萘二甲酸乙二醇酯(PEN，p〇ly(ethyleiie naphthalate))或聚對苯二曱酸乙二酉旨（PET ，poly(ethylene terephthalate))所製成。 在染料敏化太陽能電池模組100中，光線可由透明基板110 以及透明導電薄膜氧化層120，透過電洞傳輸層150，而照射至陽 極電子傳輸層160,光敏染料在吸收光能之後可將電子迅速傳遞至 電子傳輸層160,然後經由電子傳輸層160再傳遞至導電基板 170，之後透過外部電路(無圖示）’而快速傳至由低阻值的辅助電 極(導電性或抗蝕性金屬）130提昇電子傳導性之透明導電薄膜氧化 層120，最後回到電洞傳輸層150，以完成此太陽能電池模組的電 201133892 .子傳輸迴路。 而二口二,，也,100之陰極部分的俯視圖’· ,^ . 之a_a線的橫剖面圖。如圖2a盘2b所千 稍助冤極130。此陰極部分的形成方疰盔·—、头 射透明導電薄膜氧化層12G，然彳_化= i 12〇上幵ΐ冓準矛121方式(，稱為到槽法〕’在透明導電薄膜氧化201133892 VI. Description of the Invention: [Technical Field] The present invention relates to an array tandem solar cell module manufactured by using a nanotube technology, in particular, a string utilizing a segmented anode region and a cathode region / Parallel solar cell modules. [Prior Art] Faced with the rising energy crisis and environmental pollution problems, various renewable energy industries have begun to flourish, such as solar energy, wind energy and biomass energy. Among them, 'too 1% energy battery is considered to be the most promising renewable energy source, and as a result, its global market is growing at an alarming rate. Among the several known solar moon & batteries, the first generation solar cells are single/double crystal solar cells based on Shi Xi (others), which can achieve 12-20% photoelectric conversion efficiency. It is the main occupant of the current solar cell market, and its main use is applied to the power supply of portable electronic products and the construction of solar power generation modules. The basic structure of the first generation solar cell is a combination of P/N type semiconductors. When illuminating, electrons are excited to generate a shunt of electrons and holes, and under the influence of the internal potential, respectively, the type and the p-type semiconductor Attracted and gathered at both ends of the component, and then derived through an external circuit to form a current. The advantage is that it has a relatively high photoelectric conversion efficiency, but the disadvantages are strict process conditions and high manufacturing costs. The first generation of solar cells is an inorganic semiconductor thin film (thin fiim) solar cell, which comprises an amorphous silicon (a-Si) solar cell and a compound semiconductor thin film battery [eg, cadmium telluride (CdTe), Gallium arsenide (GaAs) and copper indium gallium selenide (CIGS'copper indium gallium seienide). Although the photoelectric conversion effect of thin film batteries is much lower than that of twinned solar cells, the material cost is relatively low. It is the lowest cost commercial solar cell and is mostly used in consumer electronics. The advantage of such a film is that the 1% energy battery has a wide spectrum absorption range and good track stability, but the heavy gold touch environment of the material towel will be severely damaged, because it still needs to actively find the way of returning . Among them, the CIGS _ field energy battery is composed of a group of two-five-group compound semiconductor materials composed of copper indium gallium, which is prepared by co-evaporating 201133892 plating technology to absorb the film thickness of the film. Therefore, the manufacturing cost is lower than that of the Shi Xijing solar cell, and a light conversion efficiency of approximately 2 G% can be achieved. The goal is to be the third generation of new solar cells. Its purpose is to introduce new, materials and mining technologies to produce low-cost and high-efficiency solar cells. It is hoped that the introduction of new structures will increase the photoelectric conversion rate. Divided into organic guide molecules or novel nano-materials, two or two J structures; = polymer solar cells using organic two molecules as light energy conversion media, their transformation and effectiveness, from the beginning of 1%, has been upgraded To 5~ you, the polymer solar cell has the characteristics of quality, flexibility, environmental protection, low production cost and high applicability. It belongs to the second generation of emerging solar cells with great potential. The solar cell is also the introduction of a wide-gap semiconductor nanostructure. It is combined with a photosynthetic transparent conductive glass as a substrate, and is coated with a layer of nano-structured oxygen oxime b or titanium oxide. As the electrode, since this has a surface area of 'A can be attached to the surface layer material, so that the light can't transfer electrons to the semiconductor film and export it. See the most energy. The conversion efficiency can reach 12〇/0, although the efficiency is not good, but it has the advantages of low cost and simple process. It can be used for large-and-reduced ί1 battery element preparation. This breakthrough development has been studied =: Industry _ Wei 'The future will develop into a ride-generation solar cell technology I Wang Liu. The improvement of the processing method (An〇dizati〇n), the nano tube titanium dioxide research in 丄Χίίϊϊ 曰 mature, which also promotes the solar tube of the nano tube The research chapter ^Pregnant ^ attaches importance. Due to the simple and convenient characteristics of the NT-Ti〇2 film process, ίίίΞΓΛ can be made into a peach-shaped continuous roll-to-roll (stealing, large-area grain too light 7 solar cells and traditional nano-product collection effect* (2) Electrons and holes are divided into two layers in the nanotube; (3) The electrolyte is not easily leaked in the nanotubes, and the device is processed by the Sole-pole method, which can reduce the process cost of the solar cell, and the U-pole is flexible. The characteristics of the NT_ solar cell components are composed of ^201133892 main components (Ti/Ti〇2 anode, electrolyte and Pt/TCO cathode), so the components contain Ti/Ti〇2, Ti/electrolyte, TiCV electrolyte, :pt/electrolyte interface SUMMARY OF THE INVENTION An embodiment of the present invention provides a structure of an array tandem solar cell module, comprising: a transparent substrate; a transparent conductive film formed on the transparent substrate, wherein the transparent conductive film is region Blocking into a plurality of partition regions, and the transparent substrate on which the transparent conductive film is formed as a cathode of a solar cell module; one or more conductive substrates forming one or more regions on a surface thereof, a sub-transport layer, wherein one or more regions of the electron transport layer are matched with the plurality of partition regions, the electron transport layer is composed of a plurality of semiconductor nanotubes, and the electron transport is formed thereon The conductive substrate of the layer serves as an anode of the solar cell module; a catalyst layer is formed on the cathode; a photosensitive dye is attached to the tube wall of the conductor nanotube; and the hole transport layer is disposed at The cathode disk is between the IW poles. 〃 之 — 实施 实施 实施 实施 实施 实施 实施 实施 实施 _ _ _ 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串 串The hybrid bonding with the cathode causes the solar cell fish to have a three-day structure; the money covers a silicone layer on the outer surface of the solar moon b battery module. The transparent conductive film is divided into a plurality of divided regions, wherein an electronic mode of a multi-faceted domain is formed on a surface of the conductive substrate or a plurality of regions, and another embodiment can provide an array string The method of solar cell connection comprises the steps of: forming a transparent guide on a transparent substrate, and one or more regions of the transfer layer of the die and the plurality of separate regions are connected to each other by Weigen, a semi-conducting county The rice tube is laminated, and the conductive fine enamel is attached to the wall of the semiconductor nanotube by the solar cell module dye; at the touch, the θ cathode, the electro-transmission layer is disposed at the cathode Between the anode and the anode 201133892; and bonding the anode to the cathode. According to the present invention, a series-connected dye-sensitized solar cell module having a series or parallel connection can be manufactured according to the demand of output voltage and current value. Other embodiments and advantages of the invention will be apparent from the description of the appended claims. The embodiments of the present invention are described by way of example only, and are not intended to be limiting. A 'Spring First Embodiment Fig. 1 shows a cross-sectional view of a tandem dye-sensitized solar cell module 100 in accordance with a first embodiment of the present invention. The dye-sensitized solar cell module 1 is a tandem dye-sensitized solar cell module. The dye-sensitized solar cell module 100 includes β: a transparent substrate 110, a transparent conductive thin film oxide layer 12A, an auxiliary electrode 13A, an anode/anode bonding material 140, a hole transport layer 150, an electron transport layer 16A, and a conductive ^ Plate 170. The hole transport layer 150 may contain barium ions, and the type of the hole transport layer 15 may include liquid, colloidal, or solid state. The material of the conductive substrate 17A may be indium (?n), zinc (?n), tin (Sn), titanium (9), or tungsten (w). The anion/anode bonding material 14 can be a plastic film such as a heat shrinkable film, a thermosetting film, a thermoplastic film, an ultraviolet curing film, or a silicone film. An electron transport layer 160 is formed on the conductive substrate 170, and an electron is formed thereon, and the conductive substrate 17 of the transport layer 160 is used as an anode of the dye-sensitized solar cell module, wherein the electron transport layer 160 is It is composed of a plurality of semiconductor nanotubes, and after a photosensitive dye (not shown) is attached to the wall of these semiconductor nanotubes, it can be used as a source of electron supply and a transmission route. The photosensitive dye is an organometallic dye, an inorganic photosensitive dye, or an organic photosensitive dye. The photosensitive dye can be attached to the walls of these semiconductor tubes by means of, or by spin coating, or by injection. For example, a material suitable for the electron transport layer 16A of the anode may be cerium oxide (Si〇2), indium oxynitride (ITO 2 〇 3), tungsten trioxide (w 〇 3 ), and dioxin 201133892 shaped tin ( Sn〇2) ° For example, a treatment method, chemical vapor deposition method, and anodic adhesion method, and then the photosensitive dye is: by spin coating method, the electric tube is attached to the conductive substrate. On the surface of 170, and then === on the N-f tube, at this time, the conductive substrate i7G can be metal or non-metal: !=2, so that the tube of these nanotubes is attached to the gel, gel method, water Thermal method, anodizing method, chemical vapor deposition method, or physical-product method, a transparent conductive fine oxide layer (10) is formed on the transparent substrate 110, and a transparent substrate on which a transparent conductive thin film oxide layer 12 is formed is formed 110 as a cathode of a sensitized solar cell module. In general, the transparent substrate 110 and the transparent conductive thin film oxide layer 120 may be transparent or translucent: for example, a material suitable as a transparent conductive thin film oxide layer (or transparent conductive film) 120 may be indium tin oxide. (IT〇, cerebral blood (10) (four), aluminum oxide (AZ0 'Al-Zn oxides), tin oxide (ΑΤΟ, antimony doped tin oxides), or fluorine tin oxide (FTO 'fluorine doped tin oxides); And the transparent substrate 110 can be a transparent substrate of a transparent glass substrate, a transparent plastic substrate, etc. For example, the plastic substrate can be made of polyethylene naphthalate (PEN, p〇ly (ethyleiie naphthalate)) or poly(p-benzoene). In the dye-sensitized solar cell module 100, light can be transmitted through the transparent substrate 110 and the transparent conductive thin film oxide layer 120 through the hole transport layer 150. Irradiation to the anode electron transport layer 160, the photosensitive dye can transfer electrons to the electron transport layer 160 after absorbing the light energy, and then pass through the electron transport layer 160 to the conductive substrate 170, and then pass through The circuit (not shown) is quickly transferred to the transparent conductive thin film oxide layer 120 which is lifted by the low-resistance auxiliary electrode (conductive or resistive metal) 130, and finally returned to the hole transport layer 150. To complete the solar cell module's electricity 201133892. Sub-transmission loop. And two, two, also, 100 cathode section of the top view of the 'a, a. a. a cross-sectional view of the line. Figure 2a disk 2b thousand冤 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 130 Oxidation in a transparent conductive film
可形成陣列_的透明導電薄膜氧化層⑽13 塊，複數個分隔區域，接著，细網印、電鍍 2；電鑛、電泳、療鍍、刷鑛、刷塗、或旋轉塗佈等方式，將 辅助電極m職在太陽能電池漁1〇〇之陰極的邊緣U ΐί利方式來製作此陰極部分，即，利用掩蔽法，具i 來說’。人可先綱真空膠帶或模具，將透明基板UG上之不 望明導電薄膜氧化層120的區域予以遮蔽，然後再形成透 明¥電薄膜氧化層12G’接著移除真空膠帶或模具，即可產生 有透明導電薄膜氧化層12G的區域以及不形成有透明導電薄$ ^層12G的區域’接著，棚網印、電鑛、無電解電鑛、電泳、 瘵巧、刷鑛、刷塗、或旋轉塗佈等方式，將輔助電極13〇形成在 太陽能電池模組100之陰極的邊緣。然後，藉由溶膠_凝膠法、水 熱法、陽極處理法、化學氣相沉積、物理氣相沉積、蒸鍍、或化 學浸鍍等方式，在染料敏化太陽能電池模組1〇〇的陰極上形成觸 媒層(未圖示），以促進電化學反應，此觸媒層的材質可為入11(金）、 Pd(叙）、Pt(銘）、或碳(C)。此觸媒層可具有島狀或顆粒狀的顯微結 構。輔助電極130可為導電性或抗蝕性金屬，例如銅、金、鉑、 銀、銘、鎳、鈦、始、錫、銦、或鋅。 圖3a顯示圖1之太陽能電池模組1〇〇之陽極部分的俯視圖； 而圖3b顯示沿著圖3a之b-b線的橫剖面圖。如圖如與孙所示， 太陽能電池模組100的陽極部分包含電子傳輸層160以及導電基 板170。此陽極部分為：製備數量可與陰極部分之分隔區域數量相 201133892 電基板170’而在這些導電基板的表面上已形成可 刀隔區域相匹配的電子傳輸層160之區域。最後， 4G *使陰極無極接合在—起，並在 的電洞傳輸層i50’俾能完成串接式染料敏化 太陽此電賴組1GG的封裝而使其具有三0騰構造(即，利用三 3進行封裝)，如圖i所示。電洞傳輸層15〇的設置方：並 ^而加以選擇’包含注人法、塗佈法、或鍍膜法。在太陽能^ 池模組100的外部表面可覆蓋一石夕膠層(未圖示），以保護此$陽】 =也模組。料，吾人亦可制髓方絲職太陽能電池模组 100，即使用熱壓方式將太陽能電池模組1〇〇的陽極與陰極接合 —起〇 圖4為圖1之串接式染料敏化太陽能電池模組1〇〇的實體照 片，其總面積為24 cm2、總作用面積為8.5 cm2。圖5為圖4之I 陽能電池模組經封裝過後的效率圖表。如圖5所示，依照本發明 之第一實施例的串接式染料敏化太陽能電池模組丨⑻可獲得5X〇2 %=光電轉換效率⑻、7.35 v的開路電壓(F〇c)、9·21 ^的短路 ，流(/SC)、以及0.63的填充率(FF)。依照本發明之第一實施例的太 陽能電池模組100可獲得較高的電壓。 第二實施例 。圖6顯示依照本發明之第二實施例之串接式染料敏化太陽能 電池模組200的橫剖面圖。染料敏化太陽能電池模組2〇〇為一種 並聯式染料敏化太陽能電池模組。染料敏化太陽能電池模組2〇〇 包含：透明基板210、透明導電薄膜氧化層220、辅助電極230、 陰/陽極接合材240、電洞傳輸層250、電子傳輸層260、以及導電 基板270。透明基板210、透明導電薄膜氧化層220、輔助電極230、 陰/1¼極接合材240、電洞傳輸層250、電子傳輸層260、以及導電 基板270與第一實施例所定義者相同。將於其上形成有電子傳輸 層260的導電基板270作為染料敏化太陽能電池模組2〇〇的陽極， 201133892 並且將於其上形成有透明導電薄膜氧化層220的透明基板 為染料敏化太陽能電池模組200的陰極。 乍 圖7a顯示顯示圖6之太陽能電池模組2〇〇之陰極部 圖；而圖7b顯示沿著圖7a之c_c線的橫剖面圖。如圖.％蛊几 不，太陽能電池模組200的陰極部分包含透明基板21〇、透明^ 薄膜氧化層220、以及輔助電極230。此陰極部分的形 在透明基板210上先形成透明導電薄膜氧化層(或稱為透明The transparent conductive thin film oxide layer (10) of the array_ can be formed into 13 blocks, a plurality of separated regions, followed by fine screen printing, electroplating 2; electro ore, electrophoresis, electroplating, brushing, brushing, or spin coating, etc. The electrode m is used to make the cathode portion at the edge of the cathode of the solar cell fishing, that is, using the masking method, i. A vacuum tape or a mold can be used to shield the area of the undesired conductive thin film oxide layer 120 on the transparent substrate UG, and then the transparent oxide film 12G' is formed, and then the vacuum tape or the mold is removed, thereby generating a region having a transparent conductive film oxide layer 12G and a region where the transparent conductive thin film layer 12G is not formed 'Next, shed screen printing, electric ore, electroless ore, electrophoresis, smart, brushing, brushing, or rotating The auxiliary electrode 13 is formed on the edge of the cathode of the solar cell module 100 by coating or the like. Then, by a sol-gel method, a hydrothermal method, an anodizing method, a chemical vapor deposition, a physical vapor deposition, an evaporation method, or a chemical immersion plating, the dye-sensitized solar cell module is used. A catalyst layer (not shown) is formed on the cathode to promote an electrochemical reaction. The material of the catalyst layer may be 11 (gold), Pd (former), Pt (inscription), or carbon (C). This catalyst layer may have an island or granular microstructure. The auxiliary electrode 130 may be a conductive or resistive metal such as copper, gold, platinum, silver, indium, nickel, titanium, tin, indium, or zinc. Fig. 3a shows a plan view of the anode portion of the solar cell module 1 of Fig. 1; and Fig. 3b shows a cross-sectional view taken along line b-b of Fig. 3a. As shown in the figure, the anode portion of the solar cell module 100 includes an electron transport layer 160 and a conductive substrate 170. The anode portion is a region in which the number of the partition regions of the cathode portion can be made to be 201133892, and the electron transport layer 160 is formed on the surface of the conductive substrate to match the electron-transporting layer 160. Finally, 4G* causes the cathode to be infinitely bonded, and in the hole transport layer i50', the tandem dye-sensitized solar cell can be packaged to have a 30-ton structure (ie, utilize 3 3 for packaging), as shown in Figure i. The setting of the hole transport layer 15 is: and is selected to include the injection method, the coating method, or the coating method. The outer surface of the solar cell module 100 may be covered with a layer of stone (not shown) to protect the solar cell. In addition, we can also make the core solar cell module 100, that is, use the hot pressing method to join the anode and cathode of the solar cell module 1—. Figure 4 is the tandem dye-sensitized solar energy of Figure 1. The physical picture of the battery module has a total area of 24 cm2 and a total effective area of 8.5 cm2. FIG. 5 is a graph showing the efficiency of the I solar battery module of FIG. 4 after being packaged. As shown in FIG. 5, the tandem dye-sensitized solar cell module (8) according to the first embodiment of the present invention can obtain 5X〇2%=photoelectric conversion efficiency (8), open circuit voltage (F〇c) of 7.35 v, Short circuit of 9·21 ^, flow (/SC), and fill rate (FF) of 0.63. The solar battery module 100 according to the first embodiment of the present invention can obtain a higher voltage. Second embodiment. Figure 6 is a cross-sectional view showing a tandem dye-sensitized solar cell module 200 in accordance with a second embodiment of the present invention. The dye-sensitized solar cell module 2 is a parallel dye-sensitized solar cell module. The dye-sensitized solar cell module 2A includes a transparent substrate 210, a transparent conductive thin film oxide layer 220, an auxiliary electrode 230, an anion/anode bonding material 240, a hole transport layer 250, an electron transport layer 260, and a conductive substrate 270. The transparent substrate 210, the transparent conductive film oxide layer 220, the auxiliary electrode 230, the negative electrode bonding material 240, the hole transport layer 250, the electron transport layer 260, and the conductive substrate 270 are the same as those defined in the first embodiment. The conductive substrate 270 on which the electron transport layer 260 is formed is used as the anode of the dye-sensitized solar cell module 2, 201133892, and the transparent substrate on which the transparent conductive thin film oxide layer 220 is formed is dye-sensitized solar energy The cathode of the battery module 200. Figure 7a shows a cathode portion of the solar cell module 2 of Figure 6; and Figure 7b shows a cross-sectional view taken along line c-c of Figure 7a. As shown in the figure, the cathode portion of the solar cell module 200 includes a transparent substrate 21, a transparent film oxide layer 220, and an auxiliary electrode 230. The shape of the cathode portion is first formed on the transparent substrate 210 to form a transparent conductive film oxide layer (or referred to as transparent
If 用化學侧、雷射雕刻或刮除等方式(統稱為刮槽 法），在透明導電溥膜氧化層22〇上形成溝渠221，以在單 ^ 基板210上獲得呈現Ν個分隔區域(其可形成Ν個陣列圖 明導電薄膜氧化層220，即，透明導電薄膜被區塊化成複數個)分^ 區域，然後，利用網印、電鑛、無電解電鑛、電泳、蒗鍍、刷纪、 =、或旋轉塗佈等方式，將辅助電極23G形成在太陽能模 ^ 200之陰極的邊緣。又，吾人亦可利用掩蔽法來製作此陰極 分，即，吾人可先利用真空膠帶或模具，將透明基板21〇上 期望形成透明導電薄膜氧化層22G的區域予以遮蔽，然後再 透明導電薄膜氧化層22G，接著移除真空料或模具，即可產^ 成有透明導電薄膜氧化層22〇的區域以及 $ ，化層220的區域，接著，利用網印、電鍍、無電有解^導= 蒸巧、刷鍍、刷塗、或旋轉塗佈等方式，將輔職極23〇形成在 太私能電池模，組2〇〇之陰極的邊緣。然後，藉由溶膠_凝膠法、水 熱法、陽極處理法、化學氣相沉積、物理氣相沉積、蒸鑛、或化 方式’在染料敏化太陽能電池模組獅的陰極上形成觸 媒層(未圖示），以促進電化學反應，此_層的材f可為Au(金 g 顯示? 6之太陽能電池模組施之陽極部分的俯視圖，· 而，b,，、、員不沿著圖如之d-d線的橫剖面圖。如圖如與訃所示， 太陽能電池模組2〇〇的陽極部分包含電子傳輸層施以及導電基 板270 °此_陽極部分為：製備可與陰極部分相職的單片導電基板 270在此單片導電基板的表面上已形成複數個可與N個陣列圖案 11 201133892 相匹配的電子傳輸層26G之區域。最後，在染料敏化太陽能電池 模組200之陰極與陽極之間的介面上設置陰/陽極接合材24〇而使 陰極與陽極接合在-起’並在陰極與陽極之間設置含有挑離子的 電洞傳輸層250 ’俾能完成串接式染料敏化太陽能電池模組2〇〇 的封，而使其具有三明治構造(即，利用三明治法進行封裝），如圖 6所示。電洞傳輸層250的設置方式可依其型態而加以選擇，包含 注入=、塗佈法、或鍍膜法。在太陽能電池模組200的外部表面 可覆蓋-石夕膠層(未圖示），以保護此太陽能電池模組。此外，吾人 亦可使用熱壓方式來封裝太陽能電池模組2〇〇,即使用熱壓方式將 太陽能電池模組200的陽極與陰極接合在一起。 圖9為圖6之串接式染料敏化太陽能電池模組2〇〇的實體照鲁 片，其總面積為30 cm2、總作用面積為12 cm2。圖1〇為圖9之& 封裝過後之太陽能電池模組與一對比太陽能電池模組的比較效率 圖表，其中⑻線段是透明導電薄膜氧化層22〇經切除後(即，經區 ，化)之效率曲線(其顯示圖9之太陽能電池模組的效率），而⑼線 ，是透明導電薄膜氧化層22〇未經切除(即，未經區塊化)之效率曲 其顯不對比太陽能電池模組的效率）。如圖忉之作)線段所示， 巧式染料敏化太陽能電池餘勘之透明導電細氧化層22〇 ^未經切除時，可獲得光電轉換效率（々）：41〇 %、開路電壓(厂〇c): ·72 V、短路電流密度ς/sc): 10 2〇 M cm-2以及填充率(FF) : 〇 56。 鲁 如，10之(a)線段所示’相對於透明導電薄膜氧化層22〇未經切除 料敏化太陽能電池模組，透明導電薄膜氧化層22〇經切除之 敏化太陽能電池模組可獲得光電轉換效率（??）： 5 〇4%、開路 =0^c) : 0.72V、短路電流密度(Jsc) : 1217 以及填充率 ★ 2/058。依照本發明之第二實施例的太陽能電池模組2〇〇可增 :電子於透明導電薄膜氧化層220的傳導效率，進而增加太陽能 電池模組的輸出電流量。 、:上^述，依照本發明，將太陽能電池模組的陰極區塊化成 ^固为隔區域，並且在太陽能電池模組之一或多個陽極上形成 57 ^陰極之複數個分隔區域相匹配之一或多個區域的電子傳輸 12 201133892 層’然後個陰/雜接合材將陰極與陽極接合在，並在陰極 巧陽極之·置電洞傳輸層’俾能製造具有串聯或並聯形式 陽能雷池槿細。 然本發明已參考較佳實施例及®式詳加說明，但熟習本項 =者可_在不_本發明之·與齡的航下，可進行各 二改、變化以及*效替代，然*這些修改、變化以及等效替代 仍洛入本發明所附的申請專利範圍内。 【圖式簡單說明】If a chemical side, laser engraving or scraping (collectively referred to as a squeegee method), a trench 221 is formed on the transparent conductive ruthenium oxide layer 22 , to obtain a single separation region on the single substrate 210 (the An array of patterned conductive film oxide layers 220 may be formed, that is, the transparent conductive film is divided into a plurality of sub-regions, and then, using screen printing, electro-mine, electroless ore, electrophoresis, ruthenium plating, and brushing The auxiliary electrode 23G is formed at the edge of the cathode of the solar module 200 by means of, =, or spin coating. Moreover, the cathode portion can also be formed by the masking method. That is, the vacuum substrate or the mold can be used to shield the transparent substrate 21 from the region where the transparent conductive film oxide layer 22G is desired to be formed, and then the transparent conductive film is oxidized. The layer 22G, followed by removing the vacuum material or the mold, can produce a region having a transparent conductive film oxide layer 22 and a region of the layer 220, and then using screen printing, electroplating, no electricity, and evaporation = steaming Ingeniously, brush plating, brushing, or spin coating, etc., the auxiliary pole 23 〇 is formed in the too private battery module, the edge of the cathode of the group 2 。. Then, by means of sol-gel method, hydrothermal method, anodizing method, chemical vapor deposition, physical vapor deposition, steaming, or chemical method, a catalyst is formed on the cathode of the dye-sensitized solar cell module lion. a layer (not shown) to promote the electrochemical reaction, the material f of the layer can be a top view of the anode portion of the solar cell module of the gold display, and the b,,, A cross-sectional view along the dd line of the figure. As shown in Fig. 讣, the anode portion of the solar cell module 2 includes an electron transport layer and a conductive substrate 270 °. The anode portion is: prepared with a cathode The partially-oriented monolithic conductive substrate 270 has formed a plurality of regions on the surface of the monolithic conductive substrate that can be matched with the N array patterns 11 201133892. Finally, the dye-sensitized solar cell module An anode/anode bonding material 24 is disposed on the interface between the cathode and the anode of 200, and the cathode and the anode are bonded to each other, and a hole transport layer 250 containing a picking ion is disposed between the cathode and the anode. Dye-sensitized solar power The module of the pool module has a sandwich structure (ie, packaged by a sandwich method), as shown in Fig. 6. The arrangement of the hole transport layer 250 can be selected according to its type, including injection. =, coating method, or coating method. The outer surface of the solar cell module 200 can be covered with a layer of stone (not shown) to protect the solar cell module. In addition, we can also use the hot pressing method to The solar cell module 2 is packaged, that is, the anode and the cathode of the solar cell module 200 are bonded together by heat pressing. FIG. 9 is a physical photograph of the tandem dye-sensitized solar cell module 2 of FIG. The total area is 30 cm2 and the total area is 12 cm2. Figure 1 is a comparison of the efficiency of the packaged solar cell module and a comparative solar cell module in Fig. 9, where the (8) line segment is transparent. The efficiency curve of the conductive thin film oxide layer 22 after being cut (ie, by region) (which shows the efficiency of the solar cell module of FIG. 9), and the line (9) of the transparent conductive thin film oxide layer 22 is not removed ( That is, without lumping) The rate is not comparable to the efficiency of the solar module. As shown in the line), the transparent conductive fine oxide layer 22〇^ of the smart dye-sensitized solar cell can be obtained without photoelectric removal, and the photoelectric conversion efficiency (々): 41〇%, open circuit voltage (factory) 〇c): · 72 V, short-circuit current density ς/sc): 10 2 〇 M cm-2 and fill rate (FF): 〇56. Lu Ru, 10 (a) line segment shown in relation to the transparent conductive film oxide layer 22 〇 uncut material sensitized solar cell module, transparent conductive film oxide layer 22 切除 之 之 sensitized solar cell module can be obtained Photoelectric conversion efficiency (??): 5 〇 4%, open circuit = 0^c): 0.72V, short-circuit current density (Jsc): 1217 and fill rate ★ 2/058. The solar cell module 2 according to the second embodiment of the present invention can increase the conduction efficiency of electrons in the transparent conductive film oxide layer 220, thereby increasing the output current of the solar cell module. According to the present invention, the cathode block of the solar cell module is formed into a spacer region, and a plurality of separation regions of 57 ^ cathode are formed on one or more anodes of the solar cell module to match Electron transport in one or more regions 12 201133892 Layer 'then an anion/heterojunction joining the cathode to the anode and a hole-transfer layer on the cathode anode to enable the fabrication of solar energy in series or parallel The mine pool is fine. However, the present invention has been described in detail with reference to the preferred embodiment and the formula, but it is possible to carry out the second modification, the change, and the *effect alternative under the voyage of the present invention. *These modifications, variations, and equivalents are still within the scope of the appended claims. [Simple description of the map]
表示，本發明之隨附圖式中，相同的元件以相同的元件符號加以 雷外Ξ /顯不依照本發日月之第一實施例之串接式染料敏化太陽能 電池模組的橫剖面圖； 團2a顯示圖丨之太陽能電池模組之陰極 圖办顯示沿著圖2a^_a線的橫剖面圖；^視圖 圖3a顯示圖1之太陽能電池模組之陽極部分的 圖3b顯示沿著圖3au_b線的橫剖面圖；的于· ’ 圖4為圖1之串接式染料敏化太陽能電池模組的實體照片； 圖5為圖4之太陽能電池模組經封裝過後的效率圖表； 電池才 發明之第二實施例之串接式染料敏化太陽能 _ 7a顯示顯示圖6之太陽能電池模組之陰極部分的俯視圖； 圖7b顯示沿著圖7a之c-c線的橫剖面圖； 圖a顯不圖6之太]^能電池模組之陽極部分的俯視圖； 圖8b顯示沿著圖8a之d-d線的橫剖面圖； 及圖為圖6之串接式染料敏化太陽能電池模組的實體照片； 圖10為圖9之太陽能電池模組經封裝過後的效率圖表。 13 201133892 【主要元件符號說明】 100染料敏化太陽能電池模組 110透明基板 120透明導電薄膜氧化層 121溝渠 130辅助電極 140陰/陽極接合材 150電洞傳輸層 160電子傳輸層 170導電基板 200染料敏化太陽能電池模組 210透明基板 220透明導電薄膜氧化層 221溝渠 230辅助電極 240陰/陽極接合材 250電洞傳輸層 260電子傳輸層 270導電基板BRIEF DESCRIPTION OF THE DRAWINGS In the accompanying drawings, the same elements are labeled with the same element symbols and are not in accordance with the cross section of the tandem dye-sensitized solar cell module according to the first embodiment of the present invention. Figure 2a shows a cross-sectional view of the solar cell module of the solar cell module shown in Fig. 2a^-a; Fig. 3a shows the anode portion of the solar cell module of Fig. 1 Figure 3 is a cross-sectional view of the line au-b; Figure 4 is a physical photograph of the tandem dye-sensitized solar cell module of Figure 1; Figure 5 is a graph of the efficiency of the solar cell module of Figure 4 after being packaged; The tandem dye-sensitized solar energy of the second embodiment of the invention is shown in Fig. 7b showing a top view of the cathode portion of the solar cell module of Fig. 6; Fig. 7b is a cross-sectional view taken along line cc of Fig. 7a; Figure 6b shows a cross-sectional view along the dd line of Figure 8a; and Figure 8 shows the entity of the tandem dye-sensitized solar cell module of Figure 6; Photo; Figure 10 is the solar cell module of Figure 9 sealed Efficiency after the chart. 13 201133892 [Description of main components] 100 dye-sensitized solar cell module 110 transparent substrate 120 transparent conductive film oxide layer 121 trench 130 auxiliary electrode 140 cathode/anode bonding material 150 hole transport layer 160 electron transport layer 170 conductive substrate 200 dye Sensitized solar cell module 210 transparent substrate 220 transparent conductive film oxide layer 221 trench 230 auxiliary electrode 240 cathode/anode bonding material 250 hole transport layer 260 electron transport layer 270 conductive substrate