201132300 六、發明說明： 【發明所屬之技術領域】 本發明有關經提高對初次噴煙（puf f)時的煙霧（sm〇ke) 中的揮發性香料釋出量（the amount of release of volatile perfume)之香煙。 【先前技術】 〜溥何醇香煙（menthol cigarette)，一般係在於絲施加 ，荷醇之香料後，使用於草捲製機加工為香煙者。此種薄 啊醇香煙，—般周知，係從初:欠喷煙（puff)時起至吸煙完 畢止’在每喷煙時供給於嘴邊之薄荷量會逐漸增力”亦即， 次噴煙時)所供給於嘴邊之薄荷量，係較 薄r㈣ 此種情況’會令吸煙者感覺吸煙初期的 这(不^ °姻亦可認為是單純地藉由增加於絲所含 =:::==:__出 力，醇的課題以外，此時決前述逐漸地增 添加之薄荷醇會滲出於;=大則糊 的包裝。I由於薄荷醇具有揮發性了C污染製品 法中即右杜七士 因此在歷來的加香 月匕達到所希望的釋·elease)量之問在吸煙時未 出量以及二有:種有關以控制源自菸草成分的釋 1揭示有—Λ t 難技術。，專利文獻 r〇d)，並於各呷位你田。P位(SeCtl〇n)構成菸條(tabaco 、各耗制相異種類的料填充材之香煙結 321949 4 201132300 構。專利文獻2揭示有一種於香煙前端部配置良質的終 絲，於基端部配置廉價的菸絲之結構。專利文獻3則揭示 . 有一種將菸鹼（nicotine)含量高的菸絲配置於菸條前端 - 部，以改善吸煙初期的滿足感之技術。 又，專利文獻4揭示有一種為抑制菸絲的前端掉落而 提南如端的於絲您度之郎段式香煙（segment type cigarette)。專利文獻5揭示有一種將口感佳的於草配置 於菸條前端部’藉以較歷來的香煙提高吸煙初期的口感/ 焦油（tar)比，同時在吸煙時亦能提供均勻的口感之香煙設 計以及製造方法。 再者，專利文獻6及專利文獻7揭示有一種經節段化 之香煙。 又，專利文獻8揭示有一種變更每節段之香料的香煙。 如此，雖可看到各種用以調節吸煙初期的菸草口感之 技術，惟至今尚未出現一種能提高吸煙初期的薄荷醇感， 並且能防止儲置中薄荷醇滲出捲紙，且在儲置後仍能顯著 地維持吸煙時的薄荷醇的釋出量之香煙。 、 [先前技術文獻] [專利文獻] [專利文獻1]歐洲專利申請公開第468298號 [專利文獻2]美國專利第475938〇號 [專利文獻3]日本特開日3 6卜1()8364號公報 [專利文獻4]美國專利第473〇628號 [專利文獻5]日本特開日3 62-1_70號公報 321949 5 201132300 [專利文獻6]曰本特開平01-128777號公報 [專利文獻7]曰本特開平06-209756號公報 [專利文獻8]日本實開平03-50892號公報 【發明内容】 [發明所欲解決之課題] 本發明之目的在於提供一種能增加初次喷煙時的煙霧 中所含之揮發性香料的釋出量、儲置中亦不致於發生揮發 性香料的滲出，且在儲置後的吸煙時能維持所希望的揮發 性香料釋出量之香煙。 ' [用以解決課題之手段] 本發明人等，藉由將混合有包含於多糖 (po 1 ysacchar ide)類中之含揮發性香料之材料之於草填充 材配置於菸條的特定部位，即製得能解決上述課題之香煙。 亦即，本發明提供一種香煙，如從一個側面觀察時， 係包含菸條與濾嘴，該菸條係含有菸絲之菸草填充材以捲 紙捲包且由前端部、基端部以及中央部所構成，而前述基 端部與前述濾嘴相連接，其中，前述前端部具有含於多糖 類的凝膠（gel)中之含揮發性香料之材料，前述中央部具有 前述含揮發性香料之材料或者不含有前述含揮發性香料之 材料，前述基端部具有前述含揮發性香料之材料或者不含 有前述含揮發性香料之材料，前述中央部與前述基端部的 雙方不同時含有前述含揮發性香料之材料。 [發明之效果] 本發明可提供一種經提高初次喷煙時的煙霧中所含之 6 321949 201132300 揮發性香料的釋出量，儲置中亦不發生揮發性香料的渗 出，且在儲置後的吸煙時仍能維持所希望的揮發性香料釋 ‘ 出量之香煙。 ~ 【實施方式】 本發明之香煙的特徵之一，係將混合有含於多糖類中 之含有揮發性香料之含香料的材料之菸草填充材配置於菸 條的特定部位者。 本發明中所使用之含香料之材料，包括其製造方法， 係記載於國際公開W0 2009/142159中。亦即，揮發性香料 而言，可採用各種香料，例如，可採用1 -薄荷醇。 多糖類而s ’較佳為卡拉膠（Carrageenan)、ϊ复脂 (agar)、結蘭膠（gellan gum)、羅望子膠（Tamarind gum)、 車前子膠（Psyllium seed gum)或筠篛葡甘露聚糖（Konjac glucomannan)的單成分系，或者經組合2種以上選自卡拉 膠、刺槐豆膠（Locust bean gum)、瓜爾膠（Guar gum)、瓊 月曰、結蘭膠、羅望子膠、三仙膠（Xanthan gum)、他拉膠（Tara gum)、碎弱葡甘露聚糖、澱粉、黃槐膠（Cassia gum)以及 車則子膠所成組群中的成分之複合系者。又，當進行此種 之乳化時’較佳為併用卵填脂（Leei thiη)等一般所用之乳 化劑。 &於本發明中所用之多糖類僅在水溶液中以30至90 C加熱即可使其凝膠（gel)化 ，故不需要用以使多糖類凝膠 化之凝膠反應劑。 使香料與多糖類在水溶液中經混練•乳化所調製之含 7 321949 201132300 揮發性香料之枒 並乾燥，則可作成’如在適當的支標台上鑄塑（casting) 料片裁成與於絲同=h:et)。可將此㈣ 由以片狀含揮 *王又勺尺寸而添加於終絲中。又，藉 煙中使用。。香料之材料捲包於草填充材，亦可於香 製：3揮U生香料之材料’可依包含下述步驟之方法而調 之二)將/糖類與水混合，並加熱以調製多糖類的水溶液 以進行混 練^繼化劑 、、田卢為^步驟中’將多糖類與水加以混合並加熱。加敎 皿度為30至90t，較佳為6〇至啊。 …加熱 接著，於⑼的步驟令，對上述 添加香料與乳化劑以進行混練·乳類广液中 有此種載持 時，發生更高的芳香科之吸煙物品，即可在吸煙 =發性香科之材料中的揮發性香料含有 18重夏似上，更佳為㈣以上，特佳為70%以上。為 香料：科本條 ，於條係使用捲紙 於條的㈣料包含祕的著火端之區域，#_=部 321949 201132300 係包含與濾嘴相接之端之區域，而菸條的中央部係存在於 前端部與基端部之間之區域。另外，此等區域可為不相同 的區域之間以物理方式所分割，或可為不以物理方式分割 而構成一體的菸條。 於條全長為49至70mm，更具體而言，為53mm、57mm、 68mm 等。 又，前端部佔有菸條全長的0. 018至2. 25%，基端部 佔有菸條全長的0. 018至2. 25%。較佳為前端部佔有菸條 全長的8. 8至35. 1%，基端部佔有菸條全長的8.8至 35. 1%。更佳為前端部佔有菸條全長的17. 5%，基端部佔有 菸條全長的17. 5%。 本發明之含揮發性香料之材料，必存在於菸條的前端 部，按任意之方式存在於中央部及基端部，惟不會存在於 菸條的全區域（前端部+中央部+基端部）。 再者，本發明之含揮發性香料之材料，可經捲包於構 成菸條之捲紙的内部或外側，亦可經混合於同樣構成菸條 之菸草填充材中。亦即，本發明中「具有含揮發性香料之 材料」之表現方式，包含含揮發性香料之材料配置於捲紙 的内侧或外側之情形，以及調配於菸草填充材中之態樣。 本發明之菸草填充材，可為含有前述之含揮發性香料 之材料與一般的菸絲之第1菸草填充材，或不含有含揮發 性香料之材料之由一般的於草填充材（於絲等）所構成之第 2菸草填充材。 第1菸草填充材及第2菸草填充材，可再含有將菸草 321949 201132300 葉加以磨碎之菸草粉，或者菸草葉萃取物等的菸草葉成 分。又，第1於草填充材及第2於草填充材，除於草葉或 者菸草葉成分之外，尚可含有其他菸草材料、香味料及/ 濕潤劑。於草葉的種類而言，可例舉：白肋如㈣）種於 草、黃色種菸草、東洋種菸草等。 _於本!X明之香煙中，不會有中央部與基端部的雙方均 3有含揮發性香料之材料的射彡，惟可於*含有含揮發性 ㈣之材料之中央部及/或基端部中，添加有與含揮發性香 枓之材料中所含之揮發性香料同樣的揮發性香料。然而， 本發明之較佳態樣為如下述的a)至c)。 a)前端部具有含揮發性香料之材料，惟中央部 之揮=香料之材料中所含之揮發性香料 =w端部及巾央部时含揮發性香料之㈣ 的揮發性香料之香煙。 彳中所；之揮發性香料同樣 條：=:材之材^ 填充村所構成。亦即，如材及第2终草 材料之第1养草填右 w文°周配有含揮發性香料之 的香煙。U填充材的配置，則可製得前述的a)至〇 321949 /0 201132300 特佳為上述c)中，第1菸草填充材係經配置於前端部 及基端部，而第2菸草填充材係經配置於中央部之香煙。 再者，最佳為第1菸草填充材係經配置於前端部及基 端部，第2菸草填充材係經配置於中央部，而前端部佔有 菸條全長之17. 5%，基端部佔有菸條全長之17. 5%之香煙。 如將香煙作成此種構成，則能意外地更增加初次喷煙時的 煙霧中所含之揮發性香料的釋出量。 另一方面，如含揮發性香料之材料係經捲包於捲紙内 部或外側時，則菸條中所含菸草填充材即全部由第2菸草 填充材所構成。此時，如適當改變片狀的含揮發性香料之 材料的配置，則可製得前述的a)至c)的香煙。 菸條全體中所含之含揮發性香料之材料的量，為1至 300mg(0. 16 至 50%)，較佳為 6 至 100mg(l 至 17%)。另一 方面，菸條全體中所含之揮發性香料的量，為0. 75至225mg (0. 125 至 37. 5%)，較佳為 4. 5 至 75mg(0. 75 至 12. 5%)。 又，含揮發性香料之材料所含之區域的每單位長度之揮發 性香料的含量，為0. 037至24mg/mm，較佳為0. 225至7. 5mg /mm ° 再者，本發明之香煙，即使中央部及基端部不含有揮 發性香料之情形，在含有含揮發性香料之材料之前端部燃 盡後仍然能品嚐到揮發性香料。此乃由於含有含揮發性香 料之材料之前端部在吸煙時所發出之較為多量的揮發性香 料，會被中央部及基端部的菸草填充材所吸附之故。 採用本發明之一種態樣之香煙，係將含有菸絲，及經 11 321949 201132300 裁成為祕_餘度的尺寸之 】於草填充材，及第2於草填充=香料之材料之第 將第1於草填充材配置於前端部，且=自動搂製機上， 置於中央部及基蠕部’或者將第2終草填充材配 =央部，且將第2 #草填充材配置置於前端部及 於草填充材配置於前端部及基端部，/〜部，或者將第1 配置於中央部後使用播紙進行 將，2於草填充材 利用接頭紙（tippin ^稭以製作菸條並將此 採用本發㈣連接，即可製造。 填裝於自祕Μ ㈣’係將第2料填充材 料㈣含揮發性香料之材 另字°亥片狀·的含揮於<]生悉料：？ Μ料能 僅配置於於條的前端 3輝么11香料之材料此 央部，或者心配番。卩或者此配置於菸條的前端部及中 於於條前端部及基端部之方式捲製菸條 並將此利祕頭^㈣嘴連接，即可製造。 2將2 *草填充材填裝於自動捲製機上，採用 二㈣-後，將片狀之含揮發性香料之材料僅 if而部’或者捲包於前端部及中央部，或者捲包於 一一種以製作於條，並將此利用接頭 、我而與濾1%連接，即可製造。 1次’在參考圖面之下，將本發明更詳細加以說明。 π圖至第8圖’係包含於條10及遽嘴3G之香煙。 山 '條10具有包含前端l〇a之前端部1〇1，包含基 Γη 1 1之^及位於前端部與基端部之間之中央部 土而1〇b貝]與渡嘴30相接。終條10係利用捲紙（未 321949 12 201132300 圖示)而將終草填充材加以捲包者，藉由接頭紙(未圖示) 而與濾嘴30相連接，並經加工為香煙。 第1圖，表示經將第i终草填充材21配置於终條1〇 的前端部101 + ’並將第2料填充材22配置於中央部 102及基端部103中之本發明之香煙。在此，帛丨於草填 充材21含絲（未圖示）及含揮發性香料之材料2ΐι，而 含揮發性香料之材料211均句地分散於第丨料填充材21 之中。 、 第2圖，表示不含有含揮發性香料之材料之第2菸草 填充材22配置於終條1〇之全區域，且該於條1〇的前端部 101捲包片狀的含揮發性香料之材料211之本發明的香 煙。在此，含揮發性香料之材料211存在於捲紙（未圖示） 的内側或外側。 第3圖，表示將第丨菸草填充材配置於前端部及中央 部，並將第2菸草填充材配置於基端部之本發明之香煙。 第4圖，表示第2菸草填充材22配置於菸條1〇的全 區域，且該菸條10的前端部101及中央部102捲包片狀的 含揮發性香料之材料211之本發明之香煙。 第5圖，表示將第1菸草填充材配置於前端部及基端 部，並將第2菸草填充材配置於中央部之本發明之香煙。 第6圖，表示第2菸草填充材22配置於菸條1〇的全 區域，且該菸條10的前端部1〇1及基端部1〇3捲包片狀的 含揮發性香料之材料211之本發明之香煙。 再者，於第1圖至第8圖之任一情形，菸條1〇中所含 321949 201132300 揮發性香料的總量為一定者。 其次，將本發明之香煙特性，利用下述實施例及比較 例加以驗證。 [實施例] 實施例1 [含揮發性香料之材料之調製] 作為多糖類，而選擇由微生物所代5射生成之多糖類之 結蘭膠（美國CP Kelco克爾科凝膠），與從樹木的種子所萃 取之具有木糖葡聚糖（xyloglucan)構造之羅望子膠（三榮 f畢斯托布D-2032)以1 : 1的重量比混合之複合 糸，選擇作為香 牧。 含揮發性香料、4之卜薄荷醇，並依照下述之操作以調製 於結 闌膠1 ru 狀 期 於的恆還/及羅望子膠h0g中添加100ml的水’ 中。對此添加机水糟内加熱以使上述多糖類充分溶解於水 5%水溶液1 6ιηι §之卜薄荷醇，及作為乳化劑之卵磷脂的 化。將此乳化漿；逛藉由均質機（homogenize!*)使其充分乳 ，並利用40¾料於適當的支標台上鑄塑（CaSting)成片 。此時，含^的空氣強制循環式乾燥機使其乾燥1星 持為乳化狀熊 *眭香料之材料至乾燥為止混合物仍然維 依照後述之 香料之材料且古々定步驟測定之結果，發現所得含揮發性 如下述表1之組成。 32)949 201132300 [表l ] 之材j斗之 材料名 ------- 比例（質量％) 薄荷醇 ------- 74.9 結蘭膠 7.49 羅望子膠 — - 7.49 卵磷脂 0. 15 水 10. 0 [試樣香煙之製作] 對-般的摻合絲丨咖，按依照上述步驟所調製之含 揮發性香料之材料2img之比例進行混合，以調製第}菸草 填充材（含揮發性香料之材料比例為17重量％)。將此第玉 於草填充材及第2終草填充材（上述一般的摻合絲）填裝於 自動捲製機上。_，按第丨料填储能配置於前端部 (長度為10mm(於條全長的17.5%)、第2香煙填充劑能配置 於中央。卩及基端部（合計長度為47mm(終條全長的825%)) 之方式而以捲紙加以捲包。接著，藉由接頭紙而與遽嘴 (27mm)相連接，以製作香煙（第1圖）。 使用所得香煙以進行吸煙，依照後述之測定步驟並按 每次喷煙時測定煙中所含之料量^ χ，就經製作後儲置 J個月後的香煙’亦實施同樣的定量。 f薄荷醇量之測定步驟；| 將別述之含揮發性香料之材料令的薄荷醇量，及香煙 321949 15 201132300 的煙霧中所含之薄荷醇量的測定步驟表示如下。 (1)成分萃取 (1_1)含揮發性香料之材料片材中的成分萃取 將依照前述之步驟所調製之含揮發性香料之材料片 使用剪刀裁碎為煙絲長度10mm，煙絲寬度Imm程度並 秤量約〇· lg後’置入血清瓶中。於此血清瓶中添加作為萃 取溶劑之曱醇（HPLC(高效液相色譜）用、Wako(和光）黎J ) 使用橡皮栓將此血清瓶加以阻塞、再採用封口膜（paraf i 1 、 (註冊商標）加以密封。將此置入振動機（shaker)中以 200rpm振動40分鐘，一度靜置12小時以上後，再使用振 動機振動40分鐘。將此靜置5分鐘後，使用巴士特吸量管 (Pasteur pipette)將上清液裝進褐色廣口小航（vial) 中。在此，由於卒取液之》辰度局’故在進行分析之前，加 以稀釋10倍。 (1-2)煙霧中成分之萃取 採用掛10支之線型吸煙機（linear smoking machine) (AM410、Ceruiean製），依照吸煙容量35ml/2秒鐘，吸引 間隔60秒鐘的吸煙條件，實施煙霧捕集。將香煙的燃燒長 度訂為從點火部前端49mm，其間按7次之吸煙次數，於法 蘭絨濾布（Cambridge filter)上（Bolgwaldt 社製，Φ 44mm)，進行每次喷煙之煙霧捕集（由於可能存在不需要8 次以上的吸煙之香煙，在本項試驗時，訂為7次）。 將捕集有每次噴煙之煙霧之複數濾片置入血清瓶廣口 小瓶中，使用10ml的2-丙醇以萃取20分鐘。使用巴士特 16 321949 201132300 吸量管將所得每次喷煙的上清液裝進廣口小瓶中。在此， 所萃取之成分，主要為薄荷醇、水以及菸鹼。 - (2)利用氣相色谱法（GC-FID(Gas Chromatography-Flame . ionization detector))之測定 將依照前述之步驟所裝進廣口小瓶之萃取溶液供給於 GC-FID(Agilent社製），並與絕對檢量線（abs〇lute calibration)5點同時進行分析，從峰值（peak value)之 面積值以求出含揮發性香料之材料片中及煙霧中的薄荷醇 量（mg/ml)。為檢量線製作之用的試樣，係適當改變初次儲 備溶液（primary stock s〇luti〇n)(50mg/ml 薄荷醇）以調 製5點份的檢量線1至5溶液〇· img至1〇mg/ml溶液。再 者，GC測疋時的洗滌溶劑，係為含揮發性香料之材料中薄 荷醇而言，使用曱醇，為煙霧中薄荷醇而言，則使用2_丙 醇。 (3)結果及檢討 (3-1)檢量線之製作 將從測定數據所得薄荷醇的檢量線表示於第9圖中。 在此，將檢量線範圍作成至L Gmg/ml為止的範圍，並依通 過原點之條件就5點份的測定值以進行線型近似（1丨口6 shape approximation)之結果發現，測定值與近似值（檢量 線）之間顯不有南度的相關性係(^2=〇. 999664)。亦即，該 檢篁線，係對薄荷醇的定量能以高度的信賴性使用者。 (3-2)薄荷醇之定量 採用依照前述之步驟所得檢量線，以（2)中所測定之試 17 321949 201132300 樣中的薄荷醇的分析值為依據，將含揮發性香料之材料中 之薄荷醇及煙霧中之薄荷醇定量。將煙霧中薄荷醇的定量 結果表示於第ίο圖及第η圖中。 (分析裝置測定條件） 裝置：GC[Agilent 6890N][Agilent 5973 inert] GC方法（導入試樣液1 # i) 裝置 導入口；無分割，加熱器；20CTC，壓力；5.5psi，總 流量；50ml/分鐘，對分割通風孔的沖洗氣流量（fJurgegas flow) ; 40ml/分鐘 管柱（column) ; Agilent DB_WAX[3〇mx53〇/zinxl，〇〇〇 β m ]，固定流量，出口；真空201132300 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to the amount of release of volatile perfume in the smoke (sm〇ke) when the first puff (puf f) is increased. Cigarettes. [Prior Art] ~ menthol cigarettes are generally applied to silk, and are used in the grass rolling machine to process cigarettes. Such thin alcoholic cigarettes, as is well known, are from the beginning: from the time of puffing to the end of smoking, the amount of mint supplied to the mouth will gradually increase when each cigarette is smoked. The amount of mint supplied to the mouth is thinner (four). This situation will make the smoker feel the beginning of smoking (not ^ ° marriage can be thought of simply by adding to the silk =::: ==: __Export, in addition to the topic of alcohol, at this time, the menthol added gradually added will leak out; = the packaging of the large paste. I. Because menthol has a volatile C pollution, the product is right Du Qi. Therefore, the amount of the desired ele elease in the history of the fragrant scent has not been produced at the time of smoking, and the second is: the kind of control related to the control of tobacco-derived ingredients reveals that Λ t difficult technology. Patent document r〇d), and each field of your field. The P-site (SeCtl〇n) constitutes a tobacco rod (tabaco, cigarettes of various materials and materials) 321949 4 201132300. Patent Document 2 discloses There is a structure in which a fine end wire is disposed at the tip end portion of the cigarette, and a cheap cut tobacco is disposed at the base end portion. 3 discloses that there is a technique in which a shredded tobacco having a high nicotine content is disposed at the front end portion of the tobacco rod to improve satisfaction at the initial stage of smoking. Further, Patent Document 4 discloses a method for suppressing the fall of the leading end of the shredded tobacco. In the case of the South Korean version of the segment type cigarette, Patent Document 5 discloses that the grass with the good taste is disposed at the front end of the tobacco rod. In addition, Patent Document 6 and Patent Document 7 disclose a segmented cigarette. Further, Patent Document 8 discloses a cigarette. Change the cigarettes of the spices in each section. Thus, although various techniques for regulating the taste of tobacco in the early stage of smoking can be seen, there has not been a menthol sensation which can improve the initial stage of smoking, and can prevent the menthol from oozing during storage. Cigarette which is rolled up and can still maintain the release amount of menthol at the time of smoking after being stored. [Prior Art Document] [Patent Document] [Patent Document 1] Europe Japanese Patent Laid-Open No. 468 298 [Patent Document 2] US Pat. No. 475,938, [ [Patent Document 3] Japanese Patent Laid-Open No. Hei. Japanese Patent Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. JP-A 03-50892 SUMMARY OF INVENTION [Problem to be Solved by the Invention] An object of the present invention is to provide an increase in the amount of volatile flavor contained in smoke during initial smoking, and in storage. A cigarette in which the exudation of volatile flavors occurs and the desired volatile flavor release amount is maintained during smoking after storage. [Means for Solving the Problem] The present inventors have placed a grass-filled material in a specific portion of a tobacco rod by mixing a material containing a volatile flavor contained in a polysaccharide (po 1 ysaccharide). That is, a cigarette that can solve the above problems can be obtained. That is, the present invention provides a cigarette comprising, if viewed from one side, a tobacco rod and a filter, the tobacco filler containing tobacco shreds wrapped in a roll of paper and having a front end portion, a base end portion and a central portion The base end portion is connected to the filter, wherein the front end portion has a volatile flavor-containing material contained in a polysaccharide gel, and the central portion has the volatile flavor-containing material. The material or the material containing no volatile flavor, the base end portion having the volatile fragrance-containing material or the volatile fragrance-free material, and the central portion and the base end portion are different from each other A material for volatile fragrances. [Effects of the Invention] The present invention can provide a release amount of the volatile flavor of 6 321949 201132300 contained in the smoke at the time of initial smoking, and no leakage of volatile flavors during storage, and storage After the smoking, the cigarettes of the desired volatile flavor release can still be maintained. [Embodiment] One of the characteristics of the cigarette of the present invention is that a tobacco filler containing a volatile flavor-containing material contained in the polysaccharide is placed in a specific portion of the tobacco rod. The perfume-containing material used in the present invention, including the method for producing the same, is described in International Publication WO 2009/142159. That is, for the volatile flavor, various flavors can be employed, for example, 1-menthol can be used. The polysaccharide and s 'is preferably Carrageenan, agar, gellan gum, Tamarind gum, Psyllium seed gum or scorpion A single component of mannan (Konjac glucomannan), or a combination of two or more selected from the group consisting of carrageenan, Locust bean gum, Guar gum, Qiongyue, langolin, tamarind A compound of ingredients in a group of gums, Xanthan gum, Tara gum, minced glucomannan, starch, Cassia gum, and car sap. Further, when such emulsification is carried out, it is preferred to use a emulsifier generally used such as egg fat (Leei thiη). <The polysaccharide used in the present invention can be gelled by heating at 30 to 90 C in an aqueous solution, so that a gel reagent for gelling the polysaccharide is not required. After the fragrance and the polysaccharide are kneaded and emulsified in an aqueous solution, and the scent containing 7 321949 201132300 volatile fragrance is dried and dried, it can be made as 'casting the material on the appropriate scale table. Silk with =h:et). This (4) can be added to the final filament by the size of the flakes. Also, use it in smoke. . The material of the spice is wrapped in the grass filling material, and can also be used in the scent: 3 layers of U-flavor material can be adjusted according to the method comprising the following steps: mixing / sugar with water, and heating to prepare polysaccharides The aqueous solution is mixed and heated by mixing the polysaccharide with water in a step of mixing the compound. The twisting degree is 30 to 90 tons, preferably 6 inches. ...heating, in the step of (9), adding the fragrance and the emulsifier to the above-mentioned mixing and emulsification, and when there is such a carrier in the milk wide liquid, a higher smoking article of the fragrant family occurs, and the smoking is possible. The volatile flavor in the material of the family has 18 weights of summer, more preferably (four) or more, and particularly preferably 70% or more. For the spice: the section of the strip, the strip of paper used in the strip (4) contains the secret end of the fire, #_=部321949 201132300 is the area containing the end of the filter, and the central part of the rod There is a region between the front end portion and the base end portion. In addition, the regions may be physically separated between regions that are not identical, or may be smoked cigarettes that are not physically separated. The total length of the strip is 49 to 70 mm, and more specifically, 53 mm, 57 mm, 68 mm, and the like. 018至2. 25%。 The front end portion of the total length of the tobacco rod is 0. 018 to 2. 25%.至至3. 1%。 The apex portion of the length of the tobacco rod occupies 8.8 to 35.1% of the total length of the tobacco rod. More preferably, the front end portion accounts for 17.5% of the total length of the tobacco rod, and the base end portion accounts for 17.5% of the total length of the tobacco rod. The volatile fragrance-containing material of the present invention must exist in the front end portion of the tobacco rod, and exists in the central portion and the base end portion in any manner, but does not exist in the entire region of the tobacco rod (front end portion + central portion + base) Ends). Further, the volatile flavor-containing material of the present invention may be wrapped inside or outside the roll paper constituting the tobacco rod, or may be mixed in the tobacco filler material which also constitutes the tobacco rod. That is, the "material having a volatile fragrance" in the present invention is expressed in such a manner that the material containing the volatile fragrance is disposed on the inner side or the outer side of the roll paper, and the aspect in which it is formulated in the tobacco filler. The tobacco filler of the present invention may be a first tobacco filler containing the above-mentioned volatile flavor-containing material and general cut tobacco, or a general filler for grass fillers (such as silk). ) The second tobacco filler material. The first tobacco filler and the second tobacco filler may further contain tobacco leaf components such as tobacco powder obtained by grinding tobacco leaves 321949 201132300, or tobacco leaf extract. Further, the first grass filling material and the second grass filling material may contain other tobacco materials, flavoring materials, and/or humectants in addition to the grass leaves or tobacco leaf components. In the case of the type of the grass leaf, the white ribs such as (4) are planted in grass, yellow type tobacco, and Toyo species tobacco. _ In this! X Mingzhi cigarette, there is no central and base end of both sides of the material containing volatile fragrance, but can contain * in the central part of the material containing volatile (four) and / or The base end portion is added with the same volatile flavor as the volatile flavor contained in the volatile citron-containing material. However, preferred aspects of the invention are a) to c) as described below. a) The front end portion has a material containing a volatile fragrance, but the volatile flavor contained in the material of the central portion of the fragrance = the end of the cigarette and the volatile flavor of the cigarette containing the volatile fragrance (4). In the middle of the sputum; the same as the volatile flavors: =: material of the material ^ filled the village. That is, the first plant of the material and the second grass material is filled with a cigarette containing volatile flavors. In the configuration of the U filler, the above a) to 〇321949 /0 201132300 can be obtained. In the above c), the first tobacco filler is disposed at the front end portion and the base end portion, and the second tobacco filler material is disposed. It is a cigarette that is placed in the center. The 5%, the base end portion of the first tobacco filler is disposed at the center portion and the second tobacco filler is disposed at the center portion, and the front end portion accounts for 17.5% of the total length of the tobacco rod. 5% of the cigarettes occupying the full length of the cigarette. If the cigarette is constructed in such a manner, the amount of volatile flavor contained in the smoke at the time of the first puff can be unexpectedly increased. On the other hand, if the material containing the volatile flavor is wrapped around the inside or the outside of the roll paper, the tobacco filler contained in the tobacco rod is entirely composed of the second tobacco filler. At this time, the cigarettes of the aforementioned a) to c) can be obtained by appropriately changing the arrangement of the flake-form volatile flavor-containing material. The amount of the volatile flavor-containing material contained in the entire tobacco rod is from 1 to 300 mg (0.11 to 50%), preferably from 6 to 100 mg (from 1 to 17%). 5至75之间。 (0. 75至1. 5至75mg。 The amount of the volatile flavor in the whole of the tobacco rod is 0. 75 to 225mg (0. 125 to 37. 5%), preferably 4. 5 to 75mg (0. 75 to 12. 5 %). 225至7. 5mg /mm的 Furthermore, the present invention, the content of the volatile flavor per unit length of the region containing the volatile flavor is 0. 037 to 24 mg / mm, preferably 0. 225 to 7. 5 mg / mm ° Cigarettes, even if the central portion and the base portion do not contain volatile flavors, can still taste volatile flavors after the ends are burned before containing the volatile flavor-containing material. This is because a relatively large amount of volatile flavors emitted by the ends of the material containing volatile flavors during smoking are adsorbed by the central and base tobacco fillers. A cigarette according to one aspect of the present invention will contain tobacco shreds, and the size of the grass-filled material will be cut into the size of the secret of the shovel, and the second will be the first The grass filling material is placed at the front end portion, and is placed on the automatic tanning machine, placed in the center portion and the base creeping portion' or the second final grass filling material is allocated to the central portion, and the second #草草材材置置The tip end portion and the grass filling material are disposed at the front end portion and the base end portion, and the portion is placed on the center portion, and then the paper is used, and the grass filler is used to make the tobacco. This article can be manufactured by connecting this (4). Filled in the secret (4) 'The second material filling material (4) The material containing volatile flavors is different from the word · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · · Raw materials:? The material can be placed only at the front end of the strip. The material of the spice is 11 or the heart of the material. 卩 or this is disposed at the front end of the rod and at the front end and the base of the strip. The method is to roll the cigarette rod and connect the head of the secret head ^ (4) to make it. 2 Fill the 2 * grass filling material On the automatic rolling machine, after using two (four)-, the sheet-like material containing volatile flavors is only if or 'wrapped in the front end and the central part, or wrapped in one type to be made in the strip, and This can be manufactured by connecting the joint to me with 1% of the filter. The present invention will be described in more detail below the reference plane. The π map to the eighth figure is included in the strip 10 and the grin. 3G cigarette. The mountain 'strip 10 has a front end 1〇1 including the front end l〇a, and includes a base Γ 1 1 and a central portion between the front end portion and the base end portion and 1 〇 b shell The nozzles 30 are connected to each other. The final strip 10 is wrapped with a roll of paper (not shown in 321949 12 201132300), and is connected to the filter 30 by a joint paper (not shown). In the first embodiment, the first material filler 21 is placed in the distal end portion 101 + ' of the final strip 1 , and the second material filler 22 is placed in the central portion 102 and the proximal end portion 103 . The cigarette of the present invention. Here, the grass filling material 21 contains silk (not shown) and a volatile flavor-containing material 2ΐι, and the volatile flavor-containing material 21 1 is uniformly dispersed in the second filling material 21. The second drawing shows that the second tobacco filler 22 which does not contain the volatile flavor-containing material is disposed in the entire area of the final strip 1 The tip end portion 101 of the crucible is wrapped with a sheet-like volatile flavor-containing material 211 of the cigarette of the present invention. Here, the volatile flavor-containing material 211 is present inside or outside the roll paper (not shown). The figure shows the cigarette of the present invention in which the second tobacco filler is disposed at the distal end portion and the central portion, and the second tobacco filler is placed at the proximal end portion. Fig. 4 shows the second tobacco filler 22 disposed on the tobacco rod A cigarette of the present invention in which the front end portion 101 and the central portion 102 of the tobacco rod 10 are wrapped with a sheet-like volatile flavor-containing material 211. Fig. 5 shows the cigarette of the present invention in which the first tobacco filler is placed at the distal end portion and the proximal end portion, and the second tobacco filler is placed at the central portion. Fig. 6 is a view showing the second tobacco filler 22 disposed in the entire area of the tobacco rod 1 , and the front end portion 1〇1 and the base end portion 1〇3 of the tobacco rod 10 are wrapped in a sheet-like volatile flavor-containing material. 211 of the cigarette of the invention. Furthermore, in any of the first to eighth figures, the total amount of the volatile fragrance contained in the tobacco strip 1 32 321949 201132300 is a certain one. Next, the characteristics of the cigarette of the present invention were verified by the following examples and comparative examples. [Examples] Example 1 [Preparation of a material containing a volatile fragrance] As a polysaccharide, a polysaccharide obtained by substituting a microorganism by a microorganism (a CP Kelco gel) and a tree from a tree were selected. The tamarind gum (Sanrong f Bistobu D-2032) with the xyloglucan structure extracted by the seeds was mixed with a 1:1 weight ratio and selected as the fragrant animal. The volatile flavor, 4 menthol, was added, and 100 ml of water was added to the constant/and tamarind gum h0g prepared in the gelatin 1 ru period according to the procedure described below. To this, the machine water was heated to sufficiently dissolve the above polysaccharide in a water 5% aqueous solution of 1 6 ηηι § menthol, and as an emulsifier lecithin. The emulsified pulp was placed in a fully homogenized machine (homogenize!*) to be fully milked and cast into pieces on a suitable sizing table (CaSting). At this time, the air forced circulation dryer containing ^ is dried to a emulsified bear * 眭 spice material until the mixture is still in accordance with the materials of the spices described later and the results of the ancient determination steps are found. The volatility is as shown in Table 1 below. 32)949 201132300 [Table l] Material name of the material j------- Proportion (% by mass) Menthol ------- 74.9 Aralia gum 7.49 Tamarind gum - - 7.49 Lecithin 0 15 Water 10. 0 [Preparation of sample cigarettes] For the blended silk crepe, mix the ratio of 2 img of the volatile flavor-containing material prepared according to the above steps to prepare the tobacco filler ( The proportion of the material containing the volatile fragrance was 17% by weight). This jade was filled with a grass filling material and a second final grass filling material (the above-mentioned general blending yarn) on an automatic reeling machine. _, can be placed in the front end portion according to the first material (length is 10mm (17.5% of the total length of the strip), and the second cigarette filler can be placed in the center. The base and the base end (the total length is 47mm (the total length of the strip) The paper is wrapped in roll paper by the method of 85%)). Then, it is connected to the mouth (27 mm) by the tip paper to make a cigarette (Fig. 1). The obtained cigarette is used for smoking, according to the following. In the measurement step, the amount of the material contained in the smoke is measured every time the cigarette is smoked, and the same amount is also applied to the cigarette after the storage for J months. The measuring step of the amount of menthol; The steps for determining the amount of menthol in the volatile flavor-containing material and the amount of menthol contained in the smoke of cigarette 321949 15 201132300 are as follows: (1) Ingredient extraction (1_1) Material sheet containing volatile flavor In the component extraction, the volatile flavor-containing material sheet prepared according to the foregoing steps is cut into the length of the cut tobacco by 10 mm, the width of the cut tobacco is 1 mm, and the amount is about 〇· lg and then placed in the serum bottle. Adding sterol as an extraction solvent (HPLC (efficient For liquid chromatography), Wako (Wako) was used to block the serum bottle with a rubber stopper, and then sealed with a parafilm (paraf i 1 , (registered trademark). This was placed in a shaker. After shaking at 200 rpm for 40 minutes, it was allowed to stand for 12 hours or more, and then vibrated for 40 minutes using a vibrating machine. After standing for 5 minutes, the supernatant was filled into a brown wide-mouth snail using a Pasteur pipette. (vial). Here, due to the "Creek Bureau" of the stroke liquid, it is diluted 10 times before the analysis. (1-2) The extraction of the components in the smoke is carried out by a linear smoking machine (linear smoking) Machine) (AM410, manufactured by Ceruiean), according to the smoking capacity of 35ml / 2 seconds, smoking conditions of 60 seconds of smoking, smoke collection. The burning length of the cigarette is set to 49mm from the front end of the ignition, during which 7 times The number of cigarettes smoked on a Cambridge filter (made by Bolgwaldt, Φ 44mm) for each smoke smog capture (since there may be cigarettes that do not require more than 8 cigarettes in this test) When, set it to 7 times.) A plurality of filters containing the smoke of each puff are placed in a vial of a serum vial and extracted with 10 ml of 2-propanol for 20 minutes. The supernatant of each puff is obtained using a pipette 16 321949 201132300 pipette. The liquid is filled into a wide-mouth vial. Here, the extracted components are mainly menthol, water and nicotine. - (2) Gas chromatography (GC-FID (Gas Chromatography-Flame. ionization detector)) The measurement solution was supplied to a GC-FID (manufactured by Agilent) in accordance with the above-described steps, and was analyzed simultaneously with an absolute calibration line (abs〇lute calibration) at 5 points from the peak value. The area value is used to determine the amount of menthol (mg/ml) in the flakes containing the volatile flavour and in the smoke. For the sample prepared for the calibration line, the primary stock solution (primary stock s〇luti〇n) (50 mg/ml menthol) is appropriately changed to prepare a 5 point calibration curve 1 to 5 solution 〇· img to 1 〇 mg / ml solution. Further, the washing solvent for GC measurement is based on the use of sterols for the melamine in the volatile flavor-containing material and 2-propanol for the menthol in the smog. (3) Results and review (3-1) Preparation of the calibration curve The calibration curve of menthol obtained from the measurement data is shown in Fig. 9. Here, the range of the calibration curve is set to a range of L Gmg/ml, and the measured value is obtained by performing a linear approximation (1 port 6 shape approximation) based on the condition of the origin. There is no correlation between the approximation (measurement line) and the south (^2=〇. 999664). That is, the inspection line is a highly reliable user who can quantify menthol. (3-2) Quantitative determination of menthol by using the calibration curve obtained according to the above procedure, based on the analysis value of menthol in the sample of 17 321949 201132300 measured in (2), in the material containing volatile fragrance Quantitative determination of menthol in menthol and smoke. The quantitative results of menthol in the smoke are shown in Fig. ί and Fig. (Analytical device measurement conditions) Device: GC [Agilent 6890N] [Agilent 5973 inert] GC method (introduction of sample solution 1 # i) Device inlet; no division, heater; 20 CTC, pressure; 5.5 psi, total flow; 50 ml /min, flushing gas flow to the split vent (fJurgegas flow); 40ml/min column; Agilent DB_WAX[3〇mx53〇/zinxl, 〇〇〇β m ], fixed flow, outlet; vacuum
He(氦氣）流：壓力；5. 5psi ’流量；7 3ml/分鐘，平 均速度，5 2cm/秒鐘 烘箱（oven) [表2] 溫度梯度 溫度rc) 保持時間（分鐘） 初期條件 — 60 0 5°C /min 170 10 10°C /min 200 5 [實施例2] 調製一種對一般的摻合絲1〇2mg，按與實施例丨同樣 所調製之含揮發性香料之材料1〇511^的比例混合之第1终 321949 201132300 卓填充材（含揮發財料之㈣比例9 3重㈣ 作-種該第1於草填充材經配置於前端部（長’製 全長的π.5%))及基端部（長度腕（㈣全^咖（终條 17. 5%))，第2菸草填充材(上述一般的摻合 中央部（長度37mm(終條全長的64 9%))之終條。〜ι己置於 然後;，採用該終條，按與實施例1同樣步驟以製作巷 煙，並將該香煙儲置1個月後進行吸煙，且將每次噴煙時 煙霧中所含之薄荷醇量按與實施例！同樣步驟加以定、 [比較例1 ] * 製作-種第2终草填充材經配置於全區域 著’按能對所製作之於條的前端部(長度 亭全条： 17.5%)全區域之方式，使用 · …、王長的 的薄荷醇。 使用左射益咖增）以添加14mg 然後’採用贿條，按與實補1同樣步驟以製作為 比較之用的香煙’並使用所得香煙以進行吸煙，且每次 喷煙時煙料所含之薄荷醇量按與實_丨同樣步驟加二 又’就製作後經儲置1個月後的香煙，亦實施同樣 的疋f。 [比較例2] -周裝種經對-般的摻合絲57恤，按與實施例1同 樣的步，所调製之含揮發性香料之材料21呢的比例混合 之第1於草填充材（含揮發性香料之材料比例3. 5重量％)。 使用捲紙而將該第1於草填充材捲包以製作-種第i於草 填充材為經配置於全區域之菸條。 321949 19 201132300 採用雜條，按與實施例丨同樣 吸煙，且胳香煙儲置1個月後進行 ιΜΓΓ時煙射所含之薄料量按與實施例 1冋樣步驟加以定量。 [比較例3] 調製 樣的步驟所二Γ的摻合絲陶，按與實施例" 之m 性香料之材料21mg的比例混名 之，1於草填充材（含揮發性香料之材料比例η重量％)。 it者^製Γ—種該第1於草填充材為經配置於基端部（長肩 條全長的17.5%))，而第2料填充材（上述一期 :夕絲)為經配置於前端部及中央部(合計長度4崎 條王長的82. 5%))之於條。 、:後#用5玄私條，按與實施例工同樣步驟以製作比 較之用的香煙（第8圖），並將該香煙儲置丨個月後進行吸 煙，且將每次喷㈣煙霧中所含之薄荷醇量按與實施例！ 同樣步驟加以定量。 [薄荷醇定量結果之檢討] ⑴因儲置所引起之煙霧巾薄荷醇量的變化之檢討 二Θ第10圖，係將實施例1剛製作後的香煙的煙霧中薄荷 知里的里值（圖中系列黑色三角形），及將此儲置1個月 後的煙霧中薄荷醇量的定量值（圖中系列黑色圆形），和比 較例1剛製作後的香煙的煙霧中薄荷醇量的定量值（圖中 尔列白色二角形），及將此儲置丨個月後的煙霧中薄荷醇量 的疋畺值（圖申系列白色圓形），分別按每次喷煙時所標繪 321949 20 201132300 之圖表。 由此可知剛製作後的比較例1的香煙雖在吸煙初期 (第卜2次嗔煙時）之煙霧中薄荷醇量較多，惟將此香煙儲 置1個月後，則從吸煙初期至終期為止煙霧中薄荷醇量已 有減少之情形。 y另一方面，實施例1的香煙，則由於既使儲置丨個月 後含揮發性香料之材料仍能抑制薄荷醇的揮散，故從吸煙 初期至終期為止，特別能維持吸煙初期的煙霧中薄荷醇量 為南的程度β (2)因第1菸草填充材的配置方式之不同所引起之煙霧中 薄荷醇的變化之檢討 第11圖，係將就製作後儲置1個月後的香煙、實施例 1、2以及比較例2、3的香煙之煙霧中薄荷醇量，分別按 每次噴煙時所標繪之圖表。在此，系列□為實施例丨的定 i值（與第1 〇圖的系列黑色圓形相同）、系列黑色三角形為 貫施例2的定量值、系列〇為比較例2的定量值、系列◊ 為比較例3的定量值、而系列白色三角形為實施例2的預 測值。 第1菸草填充材為經配置菸條全區域之比較例2的香 煙，及，第1菸草填充材為經配置於基端部（從菸條的基端 10mm的區域）之比較例3的香煙，雖均隨著喷煙次數而有 逐漸性增加煙霧中的薄荷醇量，惟卻未能顯著地增加作為 本發明之一種目的之吸煙初期的煙霧中之薄荷醇量。 另一方面，第1終草填充材為經配置於前端部（從終條 321949 201132300 前端1_的區域）及基端部（從於條基端腕的區域）之實 也例2的香煙’如依照當初的預測，係估計初次喷煙時的 煙霧中薄荷醇量為G. 〇5呢程度，惟不料，吸煙初期（第卜 人喷煙附近）的煙射溥荷醇量顯著地乡，特別是初次喷 煙時的薄荷醇量顯著地多。 【圖式簡單說明】 第1圖係僅於前端部配置有第1终草填充材的本發明 之香煙的模式圖。 第2圖係僅於前端部捲包含揮發性香料之材料的本發 明之香煙的模式圖。 、第3圖係於前端部及中央部配置有第ι於草填充材， 並於基端部配置有第2於草填充材的本發明之香煙的模式 圖。 第4圖係於前端部及中央部捲包含揮發性香料之材料 的本發明之香煙的模式圖。 、第5圖係於前端部及基端部配置有第丨菸草填充材， 並於中央4配置有第2 &草填充材的本發明之香煙的模式 圖。 第6圖係於前端部及基端部捲包含揮發性香料之材料 的本發明之香煙的模式圖。 第7圖係於菸條的全區域配置有第丨菸草填充材之比 較例的香煙之模式圖。 第8圖係於基端部配置有第丨菸草填充材，並於前端 部及中央雜置有第2料填充材之比_的香煙之模式 321949 22 201132300 第9圖係用於薄荷醇量的定量之檢量線的圖表。 第10圖係將就剛製作後及儲置1個月後的香煙之煙霧 中薄荷醇量，按每次噴煙所測定之圖表。 第11圖係將經變更第1菸草填充材之配置所製作之各 種香煙及比較例之香煙在儲置丨個月後，就各香煙的煙霧 中之薄荷醇量，經每次喷煙所測定之圖表。 【主要元件符號說明】 1〇 终條 基端 22 第2菸草填充材 101 前端部 103 基端部 10a 前端 21 第1菸草填充材 30 濾嘴 102 中央部 211含揮發㈣料之#_ 321949He (helium) flow: pressure; 5. 5 psi 'flow; 7 3 ml / min, average speed, 5 2 cm / sec oven (oven) [Table 2] Temperature gradient temperature rc) Retention time (minutes) Initial conditions - 60 0 5 ° C / min 170 10 10 ° C / min 200 5 [Example 2] A general blended yarn of 1 〇 2 mg was prepared, and the volatile flavor-containing material prepared in the same manner as in Example 〇1 511 The ratio of the ratio of the first to the end of 321949 201132300 Zhuo filler (containing the volatile material (four) ratio 9 3 weight (four) - the first 1 in the grass filling material is placed in the front end (long length of the full length of π.5% )) and the base end (length wrist ((4) full ^ coffee (final strip 17.5%)), the second tobacco filler (the above-mentioned general blending center (length 37mm (64 9% of the final length)) The end of the strip. ~ ι has been placed then;, using the final strip, in the same steps as in Example 1 to make the lane smoke, and the cigarette is stored for 1 month after smoking, and will be in the smoke every time The amount of menthol contained is determined in the same manner as in the example! [Comparative Example 1] * Production - The second type of final grass filling material is placed in the entire area. For the front part of the strip (length pavilion: 17.5%), the whole area, use ..., Wang Chang's menthol. Use left shot Yi coffee increase to add 14mg and then 'use bribes, press and The same step is used to make a cigarette for comparison' and the obtained cigarette is used for smoking, and the amount of menthol contained in the tobacco is increased by two in the same step as the actual one. The same 疋f was also applied to the cigarettes stored for one month. [Comparative Example 2] - Weekly preparation of the same type of blended silk 57 shirt, in the same manner as in Example 1, prepared The proportion of the material containing the volatile fragrance 21 is the first to the grass filler (the proportion of the material containing the volatile fragrance is 3.5% by weight). The first straw filler is wrapped by a roll paper to make - The i-th grass filling material is a tobacco rod that is disposed in the whole area. 321949 19 201132300 The same type of cigarette is used, and the cigarette is stored in the same manner as the example, and the cigarette is contained in the cigarette after being stored for 1 month. The amount of the material was quantified according to the procedure of Example 1. [Comparative Example 3] The mixing of the steps of the preparation of the sample Silk pottery, mixed with the ratio of 21mg of the material of the embodiment of the "sex fragrance", 1 in the grass filler (ratio of the volatile flavor-containing material η wt%). The grass filling material is disposed at the base end portion (17.5% of the total length of the long shoulder strip), and the second material filler (the first stage: the first silk thread) is disposed at the front end portion and the center portion (total length 4 82.5% of the head of the king is). ,: After #5 玄私条, according to the same steps as the implementation of the routine to make a comparison of cigarettes (Figure 8), and the cigarettes are stored for a month after smoking, and each spray (four) smoke The amount of menthol contained in the sample is as in the examples! The same steps are taken to quantify. [Review of Quantitative Results of Menthol] (1) Review of changes in the amount of menthol caused by storage. Figure 10 is the value of Mint Zhili in the smoke of the cigarette immediately after Example 1. The middle series of black triangles), and the quantitative value of the amount of menthol in the smoke after storage for one month (the series of black circles in the figure), and the amount of menthol in the smoke of the cigarette immediately after the preparation of Comparative Example 1 The value (in the figure, the white dihedral), and the enthalpy of the amount of menthol in the smoke after storage for a month (the white series of the Tushen series), respectively, plotted at the time of each smog 321949 20 201132300 chart. From this, it can be seen that the cigarette of Comparative Example 1 immediately after the production has a large amount of menthol in the smoke at the beginning of smoking (the second time of smoking), but after the cigarette is stored for one month, it is from the beginning of smoking to the beginning of smoking. The amount of menthol in the smoke has decreased since the end. y On the other hand, the cigarette of the first embodiment can maintain the smoke of the early stage of smoking from the initial stage to the end of smoking because the material containing the volatile flavor after the storage is still suppressed. The degree of menthol in the south is β (2) The review of the change of menthol in the smoke caused by the difference in the arrangement of the first tobacco filler is shown in Figure 11 and will be stored for one month after production. The amount of menthol in the smoke of cigarettes, cigarettes of Examples 1, 2 and Comparative Examples 2 and 3, respectively, is plotted on the chart when each time the cigarette is smoked. Here, the series □ is the fixed i value of the embodiment ( (the same as the series black circle of the first drawing), the series black triangle is the quantitative value of the second embodiment, and the series 〇 is the quantitative value of the comparative example 2, and the series ◊ is the quantitative value of Comparative Example 3, and the series white triangle is the predicted value of Example 2. The first tobacco filler is a cigarette of Comparative Example 2 in which the entire tobacco rod is disposed, and the first tobacco filler is a cigarette of Comparative Example 3 disposed at the base end portion (a region of 10 mm from the base end of the tobacco rod). Although the amount of menthol in the smog gradually increases with the number of spurts, the amount of menthol in the smoke at the beginning of smoking which is one of the objects of the present invention is not significantly increased. On the other hand, the first final grass filling material is a cigarette that is disposed in the front end portion (the region from the front end of the final strip 321949 201132300) and the base end portion (the region from the base end wrist). According to the original prediction, it is estimated that the amount of menthol in the smoke at the time of the initial puff is G. 〇5, but unexpectedly, the amount of smoke in the early stage of smoking (near the smoke of the first person) is significant. In particular, the amount of menthol in the first puff is remarkably large. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic view showing a cigarette of the present invention in which only a first final grass filler is disposed at a distal end portion. Fig. 2 is a schematic view showing the cigarette of the present invention in which only the material containing the volatile fragrance is wound at the leading end portion. Fig. 3 is a schematic view showing the cigarette of the present invention in which the first imaginal grass filler is placed at the distal end portion and the central portion, and the second grass filler is placed at the proximal end portion. Fig. 4 is a schematic view showing the cigarette of the present invention in which a material containing a volatile fragrance is wound at the front end portion and the center portion. Fig. 5 is a schematic view showing the cigarette of the present invention in which the second tobacco substrate is placed at the distal end portion and the proximal end portion, and the second & grass filler is placed in the center 4. Fig. 6 is a schematic view showing a cigarette of the present invention in which a material containing a volatile fragrance is wound around a front end portion and a base end portion. Fig. 7 is a schematic view showing a cigarette of a comparative example of a second tobacco filler in the entire area of the tobacco rod. Fig. 8 is a pattern of cigarettes in which the second tobacco filler is disposed at the base end portion and the second filler material is mixed at the front end portion and the center. 321949 22 201132300 Fig. 9 is for the amount of menthol. A chart of quantitative calibration lines. Figure 10 is a graph of the amount of menthol in the smoke of cigarettes immediately after production and after storage for one month, as measured by each puff. Fig. 11 is a graph showing the amount of menthol in the smoke of each cigarette after the storage of the cigarettes of the first tobacco filler and the cigarette of the comparative example, after each month of storage, by each puff Chart. [Main component symbol description] 1〇 Final strip base end 22 Second tobacco filler 101 Front end portion 103 Base end portion 10a Front end 21 First tobacco filler 30 Filter 102 Central portion 211 contains volatile (four) material #_ 321949