TW201124486A

TW201124486A - Conductive coating composition and coated member

Info

Publication number: TW201124486A
Application number: TW99128645A
Authority: TW
Inventors: Tadayuki Isaji; Shigeru Mitsui; Masashi Abe; Tomonori Furukawa
Original assignee: Nissan Chemical Ind Ltd
Priority date: 2009-08-26
Filing date: 2010-08-26
Publication date: 2011-07-16
Also published as: JPWO2011024830A1; WO2011024830A1

Abstract

Disclosed are: a conductive coating composition comprising an aqueous dispersion of an intrinsically conductive polymer, a thickening agent (e.g., a heteropolysaccharide), inorganic microparticles (e.g., silica), a binder (e.g., a polyvinyl alcohol resin) and a polyol (e.g., ethylene glycol); and a member having a conductive coating film formed from the conductive coating composition. The conductive coating composition is applicable to various printing modes, and can be used for various use applications including transparent electrode materials, transparent antistatic agents, ultraviolet ray absorbers, heat ray absorbers, electromagnetic wave absorbers, sensors, electrolytes for electrolytic capacitors, and electrodes for secondary batteries.

Description

201124486 六、發明說明：【發明所屬之技術領域】本發明係有關使用固有導電性高分子之水分散液的導電性塗覆組成物及被覆自該導電性塗覆組成物形成之被膜的被覆構件。【先前技術】聚苯胺、聚噻吩、聚吡咯等芳香族系之導電性高分子因具有優良安定性及導電率，而被期待運用，但此等導電性高分子不溶於任何溶劑成形性差，因此其應用領域受限〇又，最近爲了使透明性塑料防靜電及於塑料基板上形成透明電極而需求，無損基材之透明性下具有高透明性、高硬度之固有導電性高分子膜。近年來曾報告，藉由將微粒子狀導電性高分子分散於水及以芳香族溶劑爲首之有機溶劑，可提升成形性（參考專利文獻1 :特開平7-90060號公報、專利文獻2 :特表平2-5009 1 8號公報、專利文獻3 :特表2004-532292號公報、專利文獻4 :特表2004-5 3 2298號公報、專利文獻5 :國際公開第2006/087969號報告）。上述導電性高分子附加摻雜劑之固有導電性高分子分散液一般係以水性膠體分散液，或有機溶劑之分散液狀使用，但作爲塗覆劑等用時，所得被膜之硬度及對基材之密合性等會有問題，因此導電性高分子之應用領域將受限。 -5- 201124486 解決此等問題之方法曾提案，導電性高分子添加黏合劑成份用之高分子材料形成塗膜的方法（參考專利文獻6 :特開2002-06073 6號公報）、及添加矽烷偶合劑形成塗膜後形成保護膜的方法（參考專利文獻7:特開 2005-3 1 3 3 42 號公報）等。但此等會因塗覆液組成複雜，而使製作塗膜之步驟繁雜等問題。又，因上述固有導電性高分子之分散液的黏度太低，故有無法適應使用網版印刷等印刷方式形成電極之問題，此問題將成爲限制應用領域之重要理由。解決該問題之方法曾提案，導電性高分子添加增黏劑之方法（參考專利文獻8:特表2002-500408號公報、專利文獻9:特開2008-300063號公報），但要求進一步改良。因此本發明者們曾報告，複合固有導電性高分子之水分散液及各種黏合劑，可得溶劑組成及製膜方法簡便之塗覆組成物，及使用其可得高透明性、高硬度之固有導電性高分子膜（參考專利文獻10 :特開2007-324 1 43號公報 )，但此等特性仍有改良餘地。先前技術文獻專利文獻專利文獻1 :特開平7-90060號公報專利文獻2:特表平2-500918號公報 201124486 專利文獻3:特表2004-532292號公報專利文獻4 :特表2004-532298號公報專利文獻5 :國際公開第2006/087969號報告專利文獻6:特開2002-060736號公報專利文獻7:特開2005-313342號公報專利文獻8:特表2002-500408號公報專利文獻9 :特開2 0 0 8 - 3 0 0 0 6 3號公報專利文獻10:特開2007-324143號公報【發明內容】發明之槪要發明所欲解決之課題有鑑於該類事情，本發明之目的爲，提供適用於各種印刷方式之導電性塗覆組成物。解決課題之方法爲了達成上述目的經本發明者們專心檢討後發現，固有導電性高分子之水分散液中添加增黏劑、無機微粒子、黏合劑及多元醇，可得適用於各種印刷方式之導電性塗覆組成物，而完成本發明。即，本發明係提供， 1 · 一種導電性塗覆組成物，其特徵爲含有固有導電性高分子之水分散液、增黏劑、無機微粒子、黏合劑及多元醇； 201124486 2. 如1之導電性塗覆組成物，其中前述固有導電性高分子爲，被摻雜之聚苯胺、被摻雜之聚噻吩，此等之混合物或此等之共聚物； 3. 如1之導電性塗覆組成物，其中前述固有導電性高分子爲，至少含有苯胺單位； 4. 如1之導電性塗覆組成物，其中增黏劑爲，雜多糖類、聚環氧乙烷、聚乙烯基吡咯烷酮及明膠類所成群中選出之至少1種； 5. 如4之導電性塗覆組成物，其中增黏劑爲，胍爾豆膠及其衍生物所成群中選出之至少1種； 6. 如5之導電性塗覆組成物，其中增黏劑爲羥基丙基胍爾豆膠或羧基甲基羥基丙基胍爾豆膠； 7. 如1之導電性塗覆組成物，其中前述無機微粒子爲二氧化矽； 8. 如7之導電性塗覆組成物，其中前述無機微粒子爲活性矽酸； 9. 如1之導電性塗覆組成物，其中前述黏合劑爲丙烯酸樹脂、聚酯樹脂、胺基甲酸乙酯樹脂、環氧樹脂、聚乙烯醇樹脂、三聚氰胺樹脂、纖維素、纖維素衍生物、聚醯亞胺樹脂、苯酚樹脂、有機矽化合物、脲醛樹脂、二烯丙基酞酸酯樹脂及丁醛樹脂所成群中選出之至少1種； 10·如1之導電性塗覆組成物，其中前述多元醇爲乙二醇； 11·—種被覆構件，其特徵爲具有基材，及形成於該 -8- 201124486 基材上之被膜，前述被膜係自如1至10中任何1項之導電性塗覆組成物形成； 12.如11之被覆構件，其中前述基材爲塑料 '橡膠、玻璃、金屬、陶瓷或紙。發明之效果本發明可提供製造步驟簡便，且適用於網版印刷等印刷方式之導電性塗覆組成物。該導電性塗覆組成物可使用網版印刷法、輥複製法、定量分料法等各種塗佈法塗佈於基材上，而賦予具有高透明性之被膜，因此使用該組成物可於無損透明基材之透明性下製作具有導電性或防靜電性之被膜的構件。該類本發明之導電性塗覆組成物可使用於透明電極材料、透明防靜電劑、紫外線吸收劑、熱線吸收劑、電磁波吸收劑、傳感器、電解電容器用電解質、蓄電池用電極等各種用途。實施發明之形態下面將更詳細說明本發明。本發明之導電性塗覆組成物爲，含有固有導電性高分子之水分散液、增黏劑、無機微粒子、黏合劑及多元醇之物。 (A)固有導電性高分子 -9- 201124486 固有導電性高分子係指，一般業界稱爲Intrinsically Conductive Polymers (ICPs)之高分子，又使用慘雜劑藉由摻雜可形成聚自由基陽離子之鹽或聚自由基陰離子之鹽的狀態，而發揮其本身導電性之高分子。本發明可使用的固有導電性高分子無特別限定，例如可爲藉由摻雜劑摻雜苯胺、吡咯、噻吩、乙炔或此等衍生物之聚合物等已知的各種高分子之物。前述固有導電性高分子特佳爲，被摻雜之聚苯胺、被摻雜之聚噻吩，此等之混合物或此等之共聚物。又此等高分子可單獨使用、或2 種以上混合使用，但較佳爲使用其部分至少含有苯胺單位之高分子。又，摻雜劑如，聚苯乙烯磺酸、甲烷磺酸、烷基苯磺酸、樟腦磺酸等磺酸化合物、乙酸等羧酸化合物、鹽酸或溴化氫酸等鹵化氫等。 (B )增黏劑增黏劑無特別限定，但本發明較佳爲使用雜多糖類、聚環氧乙烷、聚乙烯基吡咯烷酮及明膠類所成群中選出之至少1種。雜多糖類如，胍爾豆膠（guar gum)及其衍生物、咕噸膠、增黏膠（Cerayonia Siliqua Gum)、瓊脂糖、透明質酸、木葡聚糖等。[Technical Field] The present invention relates to a conductive coating composition using an aqueous dispersion of an intrinsically conductive polymer and a coated member coated with a film formed of the conductive coating composition . [Prior Art] A conductive polymer such as polyaniline, polythiophene or polypyrrole is expected to be used because of its excellent stability and electrical conductivity. However, these conductive polymers are insoluble in any solvent and have poor moldability. However, in recent years, in order to prevent the transparent plastic from being static-proof and to form a transparent electrode on a plastic substrate, it is required to have an intrinsic conductive polymer film having high transparency and high hardness without impairing the transparency of the substrate. In recent years, it has been reported that the microparticle-like conductive polymer is dispersed in water and an organic solvent such as an aromatic solvent, and the moldability can be improved (refer to Japanese Laid-Open Patent Publication No. Hei 7-90060, Patent Document 2: Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. 2004-532292, Patent Document 4: Japanese Patent Publication No. 2004-5332, Patent Document 5: International Publication No. 2006/087969 . The conductive polymer dispersion of the conductive polymer-added dopant is generally used in the form of an aqueous colloidal dispersion or a dispersion of an organic solvent. However, when used as a coating agent or the like, the hardness and the base of the obtained film are obtained. There is a problem in the adhesion of the material, and the application field of the conductive polymer will be limited. -5- 201124486 A method for solving such a problem has been proposed, and a method for forming a coating film by using a polymer material for a conductive polymer-added binder component (refer to Patent Document 6: JP-A-2002-06073 No. 6), and adding decane A method of forming a protective film after forming a coating film by a coupling agent (refer to Patent Document 7: JP-A-2005-3 1 3 3 42). However, such a problem is complicated by the composition of the coating liquid, which complicates the steps of producing a coating film. Further, since the viscosity of the dispersion of the intrinsically conductive polymer is too low, there is a problem that the electrode cannot be formed by a printing method such as screen printing, and this problem is an important reason for limiting the application field. In order to solve this problem, a method of adding a tackifier to a conductive polymer has been proposed (refer to Patent Document 8: JP-A-2002-500408, JP-A-2002-300063), but further improvement is required. Therefore, the present inventors have reported that an aqueous dispersion of a composite intrinsically conductive polymer and various binders can provide a coating composition which is simple in solvent composition and film formation method, and can be used for high transparency and high hardness. Intrinsic conductive polymer film (refer to Japanese Laid-Open Patent Publication No. Hei. No. 2007-324 1 43), but there is still room for improvement in these characteristics. CITATION LIST PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT PATENT DOCUMENT [Patent Document 5: International Publication No. 2006/087969] Patent Document 6: JP-A-2002-060736 Patent Document 7: JP-A-2005-313342 Patent Document 8: JP-A-2002-500408 Patent Document 9: JP-A-2007-324143 DISCLOSURE OF THE INVENTION PROBLEMS TO BE SOLVED BY THE INVENTION In view of such matters, the object of the present invention is In order to provide a conductive coating composition suitable for various printing methods. In order to achieve the above-mentioned object, the present inventors have intensively reviewed and found that a thickener, an inorganic fine particle, a binder, and a polyhydric alcohol are added to an aqueous dispersion of an intrinsically conductive polymer, and it is possible to obtain a conductive material suitable for various printing methods. The composition is coated, and the present invention is completed. That is, the present invention provides, 1 that a conductive coating composition characterized by an aqueous dispersion containing an intrinsically conductive polymer, a tackifier, inorganic fine particles, a binder, and a polyol; 201124486 2. a conductive coating composition, wherein the intrinsically conductive polymer is a doped polyaniline, a doped polythiophene, a mixture of these or a copolymer thereof; 3. a conductive coating such as a composition, wherein the intrinsically conductive polymer is at least an aniline unit; 4. The conductive coating composition according to 1, wherein the tackifier is a heteropolysaccharide, a polyethylene oxide, a polyvinylpyrrolidone, and At least one selected from the group consisting of gelatins; 5. The conductive coating composition of 4, wherein the tackifier is at least one selected from the group consisting of guar gum and its derivatives; The conductive coating composition of 5, wherein the tackifier is hydroxypropyl guar gum or carboxymethyl hydroxypropyl guar gum; 7. The conductive coating composition of 1, wherein the inorganic microparticles Is cerium oxide; 8. Conductive coating composition such as 7 Wherein the inorganic fine particles are active citric acid; 9. The conductive coating composition according to 1, wherein the adhesive is acrylic resin, polyester resin, urethane resin, epoxy resin, polyvinyl alcohol resin, melamine At least one selected from the group consisting of a resin, a cellulose, a cellulose derivative, a polyimide resin, a phenol resin, an organic hydrazine compound, a urea resin, a diallyl phthalate resin, and a butyral resin; The conductive coating composition according to 1, wherein the polyol is ethylene glycol; 11-coated member characterized by having a substrate and a film formed on the substrate of -8-201124486, the film system The conductive coating composition of any one of 1 to 10 is formed; 12. The coated member according to 11, wherein the aforementioned substrate is a plastic 'rubber, glass, metal, ceramic or paper. EFFECT OF THE INVENTION The present invention can provide a conductive coating composition which is easy to manufacture and which is suitable for use in a printing method such as screen printing. The conductive coating composition can be applied to a substrate by various coating methods such as a screen printing method, a roll replication method, or a quantitative separation method, and a film having high transparency can be provided. Therefore, the composition can be used. A member having a film having electrical conductivity or antistatic property is produced without impairing the transparency of the transparent substrate. The conductive coating composition of the present invention can be used for various purposes such as a transparent electrode material, a transparent antistatic agent, an ultraviolet absorber, a heat ray absorbent, an electromagnetic wave absorber, a sensor, an electrolyte for an electrolytic capacitor, and an electrode for a battery. Mode for Carrying Out the Invention The present invention will be described in more detail below. The conductive coating composition of the present invention is an aqueous dispersion containing an intrinsically conductive polymer, a tackifier, inorganic fine particles, a binder, and a polyol. (A) Intrinsically Conductive Polymer-9- 201124486 Intrinsically conductive polymer refers to a polymer commonly known as Intrinsically Conductive Polymers (ICPs) in the industry, and is also used to form polyradical cations by doping with a dopant. A polymer which exhibits its own conductivity by the state of a salt of a salt or a polyradical anion. The intrinsically conductive polymer which can be used in the present invention is not particularly limited, and for example, various known polymers such as aniline, pyrrole, thiophene, acetylene or a polymer of such derivatives may be doped with a dopant. The above-mentioned intrinsically conductive high molecular weight is particularly preferably a polyaniline doped, a polythiophene doped, a mixture thereof or a copolymer of the above. Further, these polymers may be used singly or in combination of two or more kinds, but it is preferred to use a polymer in which at least an aniline unit is contained. Further, the dopant may be a sulfonic acid compound such as polystyrenesulfonic acid, methanesulfonic acid, alkylbenzenesulfonic acid or camphorsulfonic acid, a carboxylic acid compound such as acetic acid, or a hydrogen halide such as hydrochloric acid or hydrogen bromide. (B) tackifier The tackifier is not particularly limited, but the present invention preferably uses at least one selected from the group consisting of heteropolysaccharides, polyethylene oxide, polyvinylpyrrolidone and gelatin. Heteropolysaccharides such as guar gum and its derivatives, strontium gum, chelating gum (Cerayonia Siliqua Gum), agarose, hyaluronic acid, xyloglucan, and the like.

胍爾豆膠衍生物如，羥基丙基胍爾豆膠、羧基甲基羥基丙基胍爾豆膠、陽離子改性胍爾豆膠等。此等可自市售品取得，其具體例如，美普洛 HPG 81 1 1、美普洛 HPG -10- 201124486 8600、美普洛班得 9806、JAGUAR HP-8、JAGUAR HP-105、 JAGUAR HP-120 ( 均爲三晶（股）製）等。雜多糖類之分子量無特別限定，但較佳爲數平均分子量1萬至5,000萬之物，又以10萬至2,000萬之物爲佳〇又本發明之平均分子量爲，使用凝膠滲透色譜法之測定値。聚環氧乙烷無特別限定，但較佳爲數平均分子量 1，000至100萬之物，又以5,〇〇〇至50萬之物爲佳。聚乙烯基吡咯烷酮無特別限定，但較佳爲數平均分子量1,000至100萬之物，又以10,000至50萬之物爲佳。明膠類如，可使用酞化明膠、琥珀化明膠、偏苯三甲明膠、均苯四甲明膠、酯化明膠、醯胺化明膠、甲醯化明膠等。本發明之導電性塗覆組成物中，固有導電性高分子之水分散液與增黏劑之添加比率無特別限定，各自固體成份之質量比較佳爲固有導電性高分子：增黏劑=99.9: 0.1至 0·1至 99.9，更佳爲 99.1: 1: 99。 (C )無機微粒子無機微粒子如，氧化物' 碳化物、金屬、合金、有機金屬化合物，此等之複合物等，其具體例如，矽、鋁、銦、錫、鈦、鉻等各種元素之化合物，或碳等。其中較佳爲矽之氧化物，特佳爲二氧化矽。 -11 - 201124486 又，使用透過型電子顯微鏡觀察無機微粒子之粒徑（直徑），較佳爲l〇〇nm以下，更佳爲l〇nm以下。其下限無特別限定’可爲1 n m程度。考量該粒徑時》無機微粒子較佳爲粒徑1至1 0 n m，特佳爲2至5 n m之粒徑非常小的低聚物之活性矽酸。本發明之導電性塗覆組成物所含的固有導電性高分子之水分散液與無機微粒子的添加比率較佳爲，各自固體成份之質量比爲固有導電性高分子：無機微粒子= 99: 1至1 :99，更佳爲 90: 10 至 10: 90。 (D )黏合劑黏合劑無特別限定，可適當選擇使用已知之黏合劑，但考量進一步提高所得薄膜之強度時，較佳爲丙烯酸樹脂、聚酯樹脂、胺基甲酸乙酯樹脂、環氧樹脂、聚乙烯醇樹脂、三聚氰胺樹脂、纖維素、纖維素衍生物、聚醯亞胺樹脂、苯酚樹脂、有機矽化合物、脲醛樹脂、二烯丙基酞酸酯樹脂、丁醛樹脂等。此等可單獨使用或2種以上組合使用。 (1 )丙烯酸樹脂丙烯酸樹脂如，使用已知之方法將下述（甲基）丙烯酸基單體單獨或2種以上之混合物自由基聚合而得之物。又，以單體添加時可於形成被膜時進行聚合。 (甲基）丙烯酸基單體之具體例如，三氟乙基丙烯酸 -12- 201124486 醋'二氣甲基丙烯酸酯、苯基縮水甘油基丙烯酸酯、乙基（甲基）丙烯酸酯、四氫呋喃基丙烯酸酯、丙烯嗎咐、新戊四醇（甲基）丙烯酸酯、丨，6-己二醇二（ )丙稀酸醋' 三羥甲基丙烷（甲基）丙烯酸酯、雙三基丙院四（甲基）丙烯酸酯、季戊四醇四（甲基）丙醋、季戊四醇三（甲基）丙烯酸酯、季戊四醇（甲基嫌酸醋、乙二醇二（甲基）丙烯酸酯、二乙二醇二（ )丙稀酸酯、三乙二醇二（甲基）丙烯酸酯、四乙二 (甲基）丙燒酸酯、九乙二醇二（甲基）丙烯酸酯、一醇—（甲基）丙烯酸酯、三丙二醇二（甲基）丙烯、四丙一醇二（甲基）丙烯酸酯、九丙二醇二（甲基 μ酸酯、聚丙二醇二（甲基）丙烯酸酯 '羥基三甲基新戊二醇二（甲基）丙烯酸酯、雙酚Α二（甲基）酸醋、2 -乙基-2-丁基-丙二醇二（甲基）丙烯酸酯、壬二醇二（甲基）丙烯酸酯、2,2 -雙[4-(甲基丙烯氧乙氧基）苯基]丙烷、3 -苯氧基-2 -丙醯基丙烯酸酯、雙（3·丙烯氧基-2_羥基丙基）己基醚、三羥甲基丙 (甲基）丙烯酸酯、甘油三（甲基）丙烯酸酯、三（基乙基）三聚異氰酸酯（甲基）丙烯酸酯、季戊四醇甲基）丙烯酸酯、二季戊四醇六（甲基）丙烯酸酯、基丙基（甲基）丙烯酸酯、異丁基（甲基）丙烯酸酯丁基（甲基）丙烯酸酯、2-乙基己基（甲基）丙烯酸 2_乙基己基卡必醇丙烯酸酯、ω -羧基聚己內酯單丙酯、丙烯酸二聚物、月桂基（甲基）丙烯酸酯' 2 -甲羥基醯基甲基羥甲烯酸 )丙甲基醇二聚乙酸酯 )丙乙酸丙烯 1,9- 基二 1,6-院三 2-羥五（ 2-羥 ' t- 酯、烯酸氧基 -13- 201124486 乙基丙烯酸酯、丁氧基乙基丙烯酸酯、乙氧基乙氧基乙基丙烯酸酯、甲氧基三乙二醇丙烯酸酯、硬脂醯（甲基）丙烯酸酯、環己基（甲基）丙烯酸酯、四氫糠基（甲基）丙烯酸酯、異冰片基（甲基）丙烯酸酯、二環戊烯基丙烯酸酯、苄基丙烯酸酯、苯基縮水甘油醚環氧丙烯酸酯、苯氧基乙基（甲基）丙烯酸酯、苯氧基（聚）乙二醇丙烯酸酯、壬基苯酚乙氧基化丙烯酸酯、丙烯醯氧基乙基酞酸、三溴苯基丙烯酸酯、三溴苯酚乙氧基化（甲基）丙烯酸酯、甲基甲基丙烯酸酯、三溴苯基甲基丙烯酸酯、甲基丙烯醯氧基乙基馬來酸、甲基丙烯醯氧基乙基六氫酞酸、甲基丙烯醯氧基乙基酞酸、聚乙二醇（甲基）丙烯酸酯、聚丙二醇（甲基）丙烯酸酯、/3-羧基乙基丙烯酸酯、N-羥甲基丙烯醯胺、N-甲氧基甲基丙烯醯胺、N-乙氧基甲基丙烯醯胺、N-n-丁氧基甲基丙烯醯胺、t-丁基丙烯醯胺磺酸、硬脂酸乙烯酯、N-甲基丙烯醯胺、N-二甲基丙烯醯胺、N-二甲基胺基乙基（甲基）丙烯酸酯、N-二甲基胺基丙基丙烯醯胺、縮水甘油基（甲基）丙烯酸酯、n_ 丁基（甲基）丙烯酸酯 '乙基（甲基）丙烯酸酯、甲基丙烯酸烯丙酯、十六烷基甲基丙烯酸酯、十五烷基（甲基）丙烯酸酯、甲氧基聚乙二醇（甲基）丙烯酸酯、二乙基胺基乙基（甲基）丙烯酸酯、甲基丙烯醯氧基乙基琥珀酸、己二醇二丙烯酸醋、新戊二醇二丙烯酸酯、羥基三甲基乙酸酯新戊酯、季戊四醇二丙烯酸酯單硬脂酸酯、甘醇二丙烯酸酯、2-羥基乙基甲基丙烯醯基磷酸酯、雙酚A乙二醇加成物丙烯酸 -14- 201124486 酯、雙酚F乙二醇加成物丙烯酸酯、三環癸烷甲醇二丙烯酸酯、三羥基乙基三聚異氰酸酯二丙烯酸酯、2 -羥基-丙烯氧基-3-甲基丙烯氧基丙烷、三羥甲基丙烷乙二醇加成物三丙烯酸酯、三羥甲基丙烷丙二醇加成物三丙烯酸酯、三丙烯醯氧基乙基磷酸酯、三羥基乙基三聚異氰酸酯三丙烯酸酯、改性e-己內酯三丙烯酸酯、三羥甲基丙烷乙氧基三丙烯酸酯、甘油丙二醇加成物三丙烯酸酯、季戊四醇乙二醇加成物四丙烯酸酯、雙三羥甲基丙烷四丙烯酸酯、二季戊四醇六（五）丙烯酸酯、二季戊四醇單羥基五丙烯酸酯、環氧丙烯酸酯等。 (2 )聚酯樹脂聚酯樹脂如，二羧酸成份與二元醇成份聚縮合而得之樹脂。構成成份之二羧酸及二元醇成份例示如下所述。二羧酸之具體例如，對苯二甲酸、間苯二甲酸、酞酸、2,6-萘二羧酸、4,4’-聯苯二羧酸、1，4-環己烷二羧酸、己二酸、癸二酸、苯基茚滿二羧酸、二聚物酸等，此等可單獨或2種以上組合使用。二元醇成份之具體例如，乙二醇、1，4 - 丁二醇、新戊二醇、二乙二醇、二丙二醇、1,6-己二醇、1,4-環己烷二甲醇、二甲苯二醇、二羥甲基丙酸、甘油、三羥甲基丙烷、聚乙二醇、聚四甲醚二醇、雙酚A之環氧化物加成物、氫化雙酚A之環氧化物加成物等，此等可單獨或2種以上組合使用。 -15- 201124486 上述聚酯樹脂之具體例如，聚對苯二甲酸乙二醇酯、聚萘二甲酸乙二醇酯等。 (3 )胺基甲酸乙酯樹脂胺基甲酸乙酯樹脂如，聚異氰酸酯與含活性氫之化合物加聚反應而得之物。聚異氰酸酯之具體例如，伸甲基二苯基二異氰酸酯（ MDI )、伸乙基二異氰酸酯、四伸甲基二異氰酸酯、六伸甲基二異氰酸酯HDI、十一伸甲基二異氰酸酯、1，6,11-十二烷三異氰酸酯、2,2,4-三甲基六伸甲基二異氰酸酯、賴胺酸二異氰酸酯（2,6-二異氰酸根合甲基己酸酯）'雙（ 2-異氰酸根合乙基）富馬酸酯、雙（2-異氰酸根合乙基）碳酸酯、2-異氰酸根合乙基-2，6-二異氰酸根合六己酸酯、異佛爾酮二異氰酸酯（IPDI)、二環己基甲烷-4,4’-二異氰酸酯（氫化MDI)、環伸己基二異氰酸酯、甲基環伸己基二異氰酸酯、雙（2-異氰酸根合乙基）-4環己烯-1，2-二羧酸酯、2,5-及2,6-降莰烷二異氰酸酯、m-及p-伸二甲苯基二異氰酸酯、α,α,α'α’-四甲基伸二甲苯基二異氰酸酯等。又如聚異氰酸酯之改性物，可使用改性MDI (胺基甲酸乙酯改性MDI )、碳二醯亞胺改性MDI、三氫二價碳基磷酸酯改性MDI、胺基甲酸乙酯改性TDI、縮二脲改性 H DI、三聚異氰酸酯改性H D I、三聚異氰酸酯改性I p D I等聚異氰酸酯之改性物等。 -16- 201124486 上述聚異氰酸酯及其改性物可單獨或2種以上組合使用。含活性氫之化合物的具體例如，乙二醇、二乙二醇、 1.3- 丙二醇' 1,4-丁二醇、丨，5·戊二醇、丨，6-己二醇等2價醇；丙二醇、新戊二醇、3_甲基- I，5-戊二醇、2，2_一乙基· 1，3-丙二醇、1,2-、1,3-或2,3-丁二醇等具有支鍵之二醇； 1.4- 雙（經基甲基）環己院、m -或P -二甲苯一醇等具有環狀基之二醇；雙酚A等2價酚；甘油、三經甲基丙院、季戊四醇、山梨糖醇等多價醇；蔗糖、甲基葡糖甘等糖類及其衍生物；伸乙基二胺、六伸甲基二胺等脂鏈式二胺； 4,4，-二胺基- 3,3，-二甲基二環己基甲院、二胺基環己院' 異佛爾嗣二胺等脂環式一·3女，一乙基甲本一女寺方香族一胺；伸二甲苯基二胺、α,α,α’，α’-四甲基伸二甲苯基二胺等芳香族二胺；哌嗪等雜環二胺；二伸乙基三胺、三伸乙基四胺等多官能胺；聚酯多元醇、聚醚多元醇等高分子多元醇；琥珀酸、戊二酸、馬來酸、富馬酸、己二酸、壬二酸、癸二酸、六氫酞酸等脂肪族聚殘酸；酞酸、間苯二甲酸、對苯二甲酸、四溴酞酸、四氯酞酸、偏苯三酸、均苯四酸等芳香族聚羧酸；馬來酸酐、酞酸酐等聚羧酸酐 ;對苯二甲酸二甲酯等聚羧酸酯；r-丁內酯、己內酯、r -戊內酯等內酯單體、具有2個以上活性氫原子之化合物附加環氧化物之構造物等。此等可單獨或2種以上組合使用。 -17- 201124486 (4 )環氧樹脂環氧樹脂之具體例如，雙酚A型、雙酹F型、氫化雙酚A型、雙酚AF型、苯酚酚醛清漆型等各種液狀環氧樹脂及其衍生物、多價醇與環氧氯丙烷衍生而得之液狀環氧樹脂及其衍生物、縮水甘油基胺型、乙內醯脲型、胺基苯酚型、苯胺型、甲苯胺型等各種縮水甘油基型液狀環氧樹脂及其衍生物等。此等可單獨或2種以上組合使用。 (5 )聚乙烯醇樹脂聚乙烯醇樹脂可使用藉由乙酸乙烯酯等乙烯酯系單體自由基聚合而得之聚乙烯酯系聚合物的鹼化而得之物。聚乙烯酯系聚合物之具體例如，甲酸乙烯酯、乙酸乙烯酯、丙酸乙烯酯、甘油單戊酸乙烯酯、月桂酸乙烯酯、硬脂酸乙烯酯、苯甲酸乙烯酯、三甲基乙酸乙烯酯及烷烴羧酸乙烯酯等乙烯酯類之聚合物等，此等可單獨或2種以上組合使用。又’聚乙烯酯系聚合物可爲，上述乙烯酯單體類與可共聚合之共聚用單體共聚合而得的共聚物。共聚用單體之具體例如，乙烯、丙烯、丁烯、異丁稀等稀烴類；（甲基）丙烯酸及其鹽；（甲基）丙烯酸甲醋、（甲基）丙烯酸乙酯、（甲基）丙烯酸η-丙酯、（甲基）丙嫌酸i-丙酯、（甲基）丙烯酸η-丁酯、（甲基）丙燦酸i-丁酯、（甲基）丙烯酸t-丁酯、（甲基）丙烯酸 2-乙基己醋、（甲基）丙烯酸十二烷酯、（甲基）丙烯酸 -18 - 201124486 十六烷酯等（甲基）丙烯酸酯類；丙烯醯胺、羥基烷基丙烯醯胺、N-甲基丙烯醯胺、N-乙基丙烯醯胺、N，N-二甲基丙烯醯胺、二丙酮丙烯醯胺、丙烯醯胺丙烷磺酸及其鹽、丙烯醯胺丙基二甲基胺及其鹽或其4級鹽、N-羥甲基丙烯醯胺及其衍生物等丙烯醯胺衍生物；甲基丙烯醯胺、N-甲基甲基丙烯醯胺、N-乙基甲基丙烯醯胺、甲基丙烯醯胺丙烷磺酸及其鹽、甲基丙烯醯胺丙基二甲基胺及其鹽或其4 級鹽、N-羥甲基甲基丙烯醯胺及其衍生物等甲基丙烯醯胺衍生物；甲基乙烯醚、乙基乙烯醚、η-丙基乙烯醚、i-丙基乙烯醚、η-丁基乙烯醚、i-丁基乙烯醚、t-丁基乙烯醚、十二烷基乙烯醚、硬脂醯乙烯醚等乙烯醚類；（甲基）丙烯腈等腈類；氯乙烯、偏氯乙烯、氟乙烯 '偏氟乙烯等鹵乙烯：乙酸烯丙酯、氯丙烯等烯丙基化合物；馬來酸及其鹽或其酯；乙烯基三甲氧矽烷等乙烯基矽烷基化合物；乙酸異丙烯酯等。 (6 )三聚氰胺樹脂三聚氰胺樹脂之具體例如，甲基化三聚氰胺樹脂、丁基化三聚氰胺樹脂、甲基丁基混合型三聚氰胺樹脂等，此等可單獨或2種以上組合使用。 (7)纖維素及纖維素衍生物纖維素及纖維素衍生物之具體例如’纖維素、羥基丙基纖維素、三乙醯纖維素、二乙醯纖維素、乙醯纖維素、 -19- 201124486 纖維素乙酸酯丙酸酯、纖維素乙酸酯丁酸酯、纖維素乙酸酯酞酸酯、纖維素乙酸酯偏苯三酸酯、硝酸纖維素等。此等可單獨或2種以上組合使用。 (8 )聚醯亞胺樹脂聚醯亞胺樹脂之具體例如，四羧酸及/或其酸酐中選出之1種或2種以上，與脂肪族二胺及/或芳香族二胺中選出之1種或2種以上脫水縮合而得的聚醯亞胺。 (9 )有機矽化合物有機矽化合物如，下述式（I)及/或式（II)所示之矽化合物及其加水分解物、聚矽氧烷漆、聚矽氧烷醇酸漆、聚矽氧烷環氧漆、聚矽氧烷丙烯酸漆、聚矽氧烷聚酯漆等改性聚矽氧烷漆等，此等可單獨或2種以上組合使用〇 (R〇 a (R3) bS i (OR2) 4-(a+b) ( I ) (式中，R1及R3相互獨立爲碳數1至8之烷基、碳數2 至20之鏈烯基、碳數6至10之芳基、碳數7至20之芳烷基、碳數2至10之醯基、鹵基、環氧丙氧基、環氧基、胺基、苯基、巯基、甲基丙烯氧基及氰基所成群中選出之有機基’ R2爲碳數1至8之院基、碳數2至10之酿基及苯基所成群中選出之有機基，a及b爲0或1)。 { (OX) 3-aS i (R4) } 2Y (II) (式中’R4爲碳數1至5之1價有機基，χ爲碳數1至4 -20- 201124486 之烷基或碳數2至4之醯基，Y爲碳數2至20之2價有機基，a爲0或1 )。上述式（1)中，R1及R3之碳數1至8之烷基之具體例如，甲基、乙基、η-丙基、異丙基、η-丁基、異丁基、sec-丁基、tert-丁基 '戊基、己基、辛基、環戊基、環己基等。R1及R3之碳數2至20的鏈烯基之具體例如，乙烯基、烯丙基、丁烯基、己烯基、辛烯基等。R1及R3 之碳數6至10的芳基之具體例如，苯基、甲苯基、二甲苯基、萘基等。R1及R3之碳數7至20的芳烷基之具體例如，苄基、苯乙基、苯基丙基、萘基甲基等。R1及R3 之碳數2至10的醯基之具體如，乙醯基等。又，R2之碳數1至8的烷基之具體例如，甲基、乙基、η-丙基、異丙基、η -丁基、異丁基、sec -丁基、tert -丁基、戊基、己基、辛基、環戊基、環己基等。R2之碳數2至10的醯基之具體例如，乙醯基等。式（I )所示之有機矽化合物的具體例如，甲基矽酸酯、乙基砂酸醋、η-丙基砂酸酯、iso-丙基砂酸醋、η-丁基矽酸酯、四乙酸基矽烷、甲基三甲氧基矽烷、甲基三丙氧基矽烷、甲基三乙酸基矽烷、甲基三丁氧基矽烷、甲基三戊氧基矽烷、甲基三苯氧基矽烷、甲基三苄氧基矽院、甲基三苯乙氧基矽烷、環氧丙氧基甲基三甲氧基矽烷、環氧丙氧基甲基三乙氧基矽烷、環氧丙氧基乙基三甲氧基矽烷、環氧丙氧基乙基三乙氧基矽烷、yS-環氧丙氧基乙基三甲氧基矽烷、/3-環氧丙氧基乙基三乙氧基砂完 -21 - 201124486 、α-環氧丙氧基丙基三甲氧基矽烷、α-環氧丙氧基三乙氧基矽烷、/5-環氧丙氧基丙基三甲氧基砂院、, 氧丙氧基丙基三乙氧基砂院、環氧丙氧基丙基二基矽烷、r-環氧丙氧基丙基三乙氧基矽烷、了-環氧基丙基三丙氧基矽烷、r-環氧丙氧基丙基三丁氧基、r-環氧丙氧基丙基三苯氧基矽烷、α-環氧丙氧基三甲氧基矽烷、α-環氧丙氧基丁基三乙氧基矽烷、，氧丙氧基丁基三甲氧基矽烷、/3-環氧丙氧基丁基三基矽烷、τ-環氧丙氧基丁基三甲氧基矽烷、環氧基丁基三乙氧基矽烷、環氧丙氧基丁基三甲氧基 ' (5 -環氧丙氧基丁基三乙氧基矽烷、（3,4-環氧環己甲基三甲氧基矽烷、（3,4-環氧環己基）甲基三乙氧烷、沒-(3,4-環氧環己基）乙基三甲氧基矽烷、/ 3,4_環氧環己基）乙基三乙氧基矽烷、/3-(3,4-環氧基）乙基三丙氧基矽烷、0-(3,4-環氧環己基）乙基氧基矽烷、/3-(3,4-環氧環己基）乙基三苯氧基矽 r-(3,4-環氧環己基）丙基三甲氧基矽烷、r-(3 氧環己基）丙基三乙氧基矽烷、（5-(3,4-環氧環己基基三甲氧基矽烷、5-( 3，4-環氧基環己基）丁基三乙矽烷、環氧丙氧基甲基甲基二甲氧基矽烷、環氧丙氧基甲基二乙氧基矽烷、α-環氧丙氧基乙基甲基二甲矽烷、α-環氧丙氧基乙基甲基二乙氧基矽烷、/S-環氧基乙基甲基二甲氧基矽烷、/3-環氧丙氧基乙基乙甲氧基矽烷、α-環氧丙氧基丙基甲基二甲氧基矽烷丙基 3 -環甲氧丙氧矽烷丁基 5 -環乙氧丙氧矽烷基）基矽 ?-( 環己三丁烷、 4-環 )丁氧基基甲氧基氧丙基二 -22- 201124486 環氧丙氧基丙基甲基二乙氧基矽烷、環氧丙氧甲基二甲氧基5夕院、/3-環氧丙氧基丙基乙基二甲烷、r-環氧丙氧基丙基甲基二甲氧基矽烷、r-環基丙基甲基二乙氧基砂院、7_環氧丙氧基丙基甲氧基矽烷、r-環氧丙氧基丙基甲基二丁氧基矽烷氧丙氧基丙基甲基二苯氧基矽烷、r-環氧丙氧基基二甲氧基矽烷、r-環氧丙氧基丙基乙基二乙氧、r-環氧丙氧基丙基乙烯基甲氧基矽烷、r-環氧丙基乙烯基乙氧基矽烷、r·環氧丙氧基丙基乙烯甲氧基矽烷、r-環氧丙氧基丙基乙烯基苯基乙氧、乙基三甲氧基矽烷、乙基三乙氧基矽烷、乙烯基基矽烷、乙烯基三乙酸基矽烷、乙烯基三甲氧基乙烷、苯基三甲氧基矽烷、苯基三乙氧基矽烷、苯基基矽烷、r-氯丙基三甲氧基矽烷、r-氯丙基三乙烷、r -氯丙基三乙酸基矽烷、3,3,3-三氟丙基三甲烷、r-甲基丙烯氧基丙基三甲氧基矽烷、r-锍基甲氧基矽烷、r-毓基丙基三乙氧基矽烷、；S-氰基乙氧基矽烷、氯甲基三甲氧基矽烷、氯甲基三乙氧、n-( 胺基乙基）-r -胺基丙基三甲氧基矽烷 yS-胺基乙基）-r-胺基丙基甲基二甲氧基矽烷、‘ 丙基甲基三甲氧基矽烷、n-( /3-胺基乙基）- r-基二乙氧基砂院、N-( yS-胺基乙基）-γ-胺基丙二乙氧基矽烷、二甲基二甲氧基矽烷、苯基甲基二矽烷、二甲基二乙氧基矽烷、苯基甲基二乙氧基基丙基氧基砍氧丙氧基二丙 xm 、7 - ^ 丙基乙基矽烷丙氧基基苯基基矽烷三甲氧氧基矽三乙酸氧基砂氧基石夕丙基三乙基三基矽烷、N-( r -胺基胺基丙基甲基甲氧基矽烷、 -23- 201124486 r-氯丙基甲基二甲氧基矽烷、r-氯丙基甲基二乙氧基矽烷、二甲基二乙酸基矽烷、7 -甲基丙烯氧基丙基甲基二甲氧基矽烷、τ-甲基丙烯氧基丙基甲基二乙氧基矽烷、 τ-锍基丙基甲基二甲氧基矽烷、τ-锍基丙基甲基二乙氧基矽烷 '甲基乙烯基二甲氧基矽烷、甲基乙烯基二乙氧基矽烷等。上述式（II)中，R4之碳數1至5的1價有機基之具體例如，甲基、乙基、η-丙基、異丙基、η-丁基、異丁基、sec-丁基、tert-丁基、戊基等烷基、乙烯基、烯丙基、丁烯基等鏈烯基、乙醯基等醯基等。X之碳數1至4的烷基之具體例如，甲基、乙基、η-丙基、異丙基、η-丁基、異丁基、sec-丁基、tert-丁基。X之碳數2至4的醯基之具體例如，乙醯基等。Y之碳數2至20的2價有機基之具體例如，伸甲基、伸乙基、伸丙基、伸丁基等伸烷基、亞乙基、亞丙基等亞烷基等。式（Π)所表示之有機矽化合物的具體例如，伸甲基雙甲基二甲氧基矽烷、伸乙基雙乙基二甲氧基矽烷、伸丙基雙乙基二乙氧基矽烷、伸丁基雙甲基二乙氧基矽烷等。上述式（I)及式（II)所表示之有機矽化合物及其加水分解物可各自單獨使用，或混合兩者使用。單獨使用、兩者倂用均可組合2種以上式（I )及式（11 )之化合物使用。式（I )及式（II )所表示的有機矽化合物之加水分解步驟係藉由，將鹽酸水溶液、硫酸水溶液或乙酸水溶液 -24 - 201124486 等酸性水溶液加入有機矽化合物中攪拌進行。 (10)二烯丙基酞酸酯樹脂二烯丙基酞酸樹脂之具體例如，二烯丙基酞酸烯丙基間苯二甲酸酯、二烯丙基對苯二甲酸酯等。 (11 ) 丁醛樹脂丁醛樹脂之具體例如，聚乙烯基丁醛等。本發明之導電性塗覆組成物所含的固有導電性之水分散液與黏合劑成份的添加比率較佳爲，各自份之質量比下固有導電性高分子：黏合劑=99 : 1至，更佳爲9 0 : 1 0至1 0 : 9 0。 C E )多元醇多元醇無特別限定，例如乙二醇、1，2 -丙二醇丙二醇、丙三醇等，但就提升導電性之效果較佳爲〇多元醇之添加量相對於本發明之導電性塗覆組佳爲0.01至30.0質量％ ’更佳爲1至15質量％。本發明之導電性塗覆組成物的2 5 °c之黏度，使用印刷方式時相對於基板之塗佈性等較佳爲 lOOPa· s，更佳爲 1 至 30Pa. s。本發明之導電性塗覆組成物的調整製法無特別可藉由任意方法適當混合固有導電性高分子之水分酯、二高分子固體成 1 ： 99 ' 1,3- 乙二醇成物較就考量 0.5至限定，散液、 -25- 201124486 增黏劑、無機微粒子、黏合劑及多元醇。又，本發明之目的爲，提升導電性塗覆組成物之分散液及保存安定性時.，組成物中可添加0.1至10質量％之表面活性劑、酸、鹼等。表面活性劑無特別限定，可廣泛使用陰離子系、陽離子系、非離子系等表面活性劑，可自己知之表面活性劑中適當選擇。酸如，鹽酸、硝酸、原磷酸等無機酸；草酸、乳酸、酒石酸、蘋果酸、檸檬酸、乙醇酸、氫丙烯酸、α-氧基丁酸、丙三醇酸、酒石酸等脂肪族含氧酸；苯基膦酸、1-羥基亞乙基-1，1-二膦酸等膦酸化合物等。鹼如，氨；鹼金屬氫氧化物；乙基胺、二乙基胺、Π-丙基胺、異丙基胺、二異丙基胺、二丙基胺、η-丁基胺、異丁基胺 '二異丁基胺、三乙基胺、苄基胺、辛基胺、十二烷基胺、硬脂醯胺等烷基或芳烷基胺類；單乙醇胺、三乙醇胺等烷醇胺；脈氫氧化物、四甲基銨氫氧化物、四乙基銨氫氧化物等4級敍氫氧化物；碳酸銨、碳酸脈等有機鹼等。將本發明之導電性塗覆組成物塗佈於基板上。乾燥後可形成薄膜。自此可得具有透明導電性被膜或透明防靜電被膜之被覆構件。可使用之基材如，塑料、橡膠、玻璃、金屬、陶瓷、紙等各種物。本發明之導電性塗覆組成物的塗佈法可自，如棒塗法 -26- 201124486 、逆塗法、照相凹版印刷法、微照相凹版印刷法、網版印刷法、浸漬法、旋塗法、噴霧法、輥複製法、分配器法等已知之方法中適當選擇。自本發明之導電性塗覆組成物形成的被膜厚度可因應用途適當設定無一槪規定，較佳爲0.05至10 # m，更佳爲 0. 1 至 5 # m。上述被膜之表面電阻値爲10°至1014Ω/□，因此具有極佳之導電性能。又表面電阻値可藉由表面電阻率測定裝置（例如海雷斯UP (三菱化學（股）製）、洛雷斯IP (三菱化學（股 )製等）測定。自本發明之導電性塗覆組成物形成的被膜，例如可於其上方層合防反射膜而賦予防反射機能。防反射膜較佳爲折射率低於導電性被膜，此等之折射率差較佳爲0.05以上，更佳爲0.1至0.5，最佳爲0.15至 0.5。該折射率差未達0.05之値時，將無法得到防反射膜之相乘效果，反而會降低防反射效果。防反射膜之厚度無特別限制，較佳爲50至3 00nm。厚度未達5Onm時會降低相對於下層之導電性被膜的密合性，又厚度超過300nm時會發生光干擾而降低防反射效果。爲了得到更高防反射能而設置複數防反射膜時，其總厚度可爲50至3 00nm。構成防反射膜之材料無特別限定，例如有機矽化合物及其加水分解物；氟烯烴系聚合物、含氟丙烯酸系聚合物 -27- 201124486 等氟系樹脂；’具有低折射率之微粒子狀的氟化鎂、氟化鋰、氟化鈉、或具有空隙之微粒子與有機或無機黏合劑混合而得之低折射率塗覆組成物等。又，可以真空蒸鍍或濺鍍法等方法使氟化鎂、二氧化矽等無機化合物成膜爲防反射膜。另外自本發明之導電性塗覆組成物形成的被膜上，可交互層合高折射率層與低折射率層形成防反射膜用的多層防反射膜而賦予防反射機能。此時之高折射率層較佳爲鈦、鉬、锆、鈮及釔所成群中選出之至少1種的氧化物之層，低折射率層較佳爲二氧化矽、氧化鋁、氟化鎂、氟化鋰及氟化鈉所成群中選出之至少1種之層。此等高折射率層及低折射率層可以真空蒸鑛或濺鍍法、離子鍍金法等乾式鍍金法製膜。【實施方式】實施例下面將舉實施例及比較例更具體說明本發明，但本發明非限定下述實施例。又各物性之測定法及測定條件如下述。 [1] Tt 値使用分光濁度計器TC-H3DPK-MKII (東京電色（有 )製）測定。 -28- 201124486 [2] Haze 使用分光濁度計器TC-H3DPK-MKII (東京電色（有 )製）測定。 [3] 表面電阻値使用 Loresta IP TCP-T2 5 0 (三菱化學（股）製）測定。 [4] 鉛筆硬度使用鉛筆硬度計（No. 55 3 -M FILM HARDNESS TESTER BY MEANS OF PENCILS >安田精機製作所（股 )製）以Jis-K 5 600-5 -4記載之方法測定。 [5] 橫切試驗使用橫切導向裝置（CCI-1，可提庫（股）製）以 J IS-K5 600記載之方法試驗，並記載殘存之格子數。 [6]黏度使用E型黏度計（VISCOMETER TV-20，東機產業（股）製）以測定範圍U，回轉數0.5 rpm測定。 [製造例1 ]調製固有導電性高分子之水分散液將N -甲基吡咯烷酮60.0g加入含有被摻雜之聚苯胺的 -29- 201124486 固有導電性高分子之水性膠體分散液6903-116-000 ( ORMECON公司製）200〇g中’得水分散液（固體成份濃度1.7質量％，25 °C之黏度51 mPa· s’導電率380 S/cm [製造例2] 使用蒸發器將被摻雜之聚3,4_伸乙基二氧基噻吩的水性膠體分散液 Baytron ΡΗ5〇0 ( Η· C. Starck公司製） 100.〇g減壓蒸餾濃縮爲68.〇g’得水分散液（固體成份濃度1.7質量％ )。 [製造例3] 以水163.6g稀釋矽酸鈉溶液（Si02: 27.5質量％， Na20: 8.4質量％) 36.4g，使所得稀釋液之pH爲11.6。 25 °C下使該稀釋物通過（每1小時空間速度7)塡充氫型強酸性陽離子交換樹脂（有機製IR-120B) 250mL之管柱 (管柱徑45mm )，得活性矽酸2 1 5 · 8 g。所得活性矽酸之 pH爲2.7，固體成份濃度爲4.2質量％，透過型電子顯微鏡觀察之結果爲粒徑2至5nm。 [實施例1] 於製造例1所得的水分散液18.8g中混合水8.2g，製造例3所得的活性矽酸（固體成份濃度4.2質量％ ) 1 1.9g、紫外線硬化型聚乙烯醇樹脂組成物（0-106，中京 -30- 201124486 油脂（股）製，固體成份濃度20_4質量％ ) 2.5g、乙二醇4.2g、η-丙醇4.2g及羥基丙基胍爾豆膠（JAGUAR HP-105 ，三昌（股）製）〇.3g 後攪拌 1 小時，得導電性塗覆組成物。所得的導電性塗覆組成物之分散狀態良好’ 25 °C 之黏度爲〇.9Pa · s。使用0.001英寸（25.4ym)之塗佈機將該導電性塗覆組成物塗佈於玻璃板上，以1 〇〇 °C乾燥1 〇分鐘後’形成導電性被膜。所得的導電性被膜爲，Tt値92%、Haze 値0.3、表面電阻値420 Ω /□、鉛筆硬度Η、橫切試驗結果爲1 〇〇。 [實施例2 ] 於製造例2所得的水分散液47.9g中混合製造例3所得的活性矽酸（固體成份濃度4·2質量％ ) 28.4g、紫外線硬化型聚乙烯醇樹脂組成物（〇· 1 06，中京油脂（股）製，固體成份濃度19.1%) 5_9g、乙二醇10.0g' η-丙醇 10.〇g及羥基丙基胍爾豆膠（JAGUAR HP-105，三昌（股 )製）〇. 8 g後攪拌1小時，得導電性塗覆組成物。所得的導電性塗覆組成物之分散狀態良好，25 °C之黏度爲1 .2Pa • s ° 使用0.001英寸（25.4# m)之塗佈機將該導電性塗覆組成物塗佈於玻璃板上，以l〇〇°C乾燥10分鐘，形成導電性被膜。所得的導電性被膜爲，Tt値86%、Haze値 0.1、表面電阻値220 Ω/□、鉛筆硬度Η '橫切試驗結果 -31 - 201124486 爲 1 00。 [實施例3] 於製造例1所得的水分散液18.8g中混合水8.2g、製造例3所得的活性矽酸（固體成份濃度4.2質量％ ) 1 1.9g、紫外線硬化型聚乙烯醇樹脂組成物（0-106，中京油脂（股）製，固體成份濃度20.4質量％ ) 2.5g、1,2-丙二醇4.28、11-丙醇4.28及羥基丙基胍爾豆膠（*^01；八11 HP-105，三昌（股）製）0.3g後攪拌1小時，得導電性塗覆組成物。所得的導電性塗覆組成物之分散狀態良好， 25T：之黏度爲0.9Pa· s。使用0.001英寸（25.4；c/m)之塗佈機將該導電性塗覆組成物塗佈於玻璃板上，以l〇〇°C乾燥1〇分鐘，形成導電性被膜。所得的導電性被膜爲，Tt値93%、Haze値〇 . 1、表面電阻値7 5 0 Ω / □、鉛筆硬度Η B、橫切試驗結果爲 1 00。 [實施例4] 於製造例1所得的水分散液18.8g中混合水8_2g、製造例3所得的活性矽酸（固體成份濃度4.2質量％ ) 1 1.9g、紫外線硬化型聚乙烯醇樹脂組成物（〇-1〇6，中京油脂（股）製，固體成份濃度20.4質量％ ) 2.5g、1，3-丙二醇4.2g' η-丙醇4.2g及羥基丙基胍爾豆膠（JAGUAR HP-105，三昌（股）製）0.3g後攪拌1小時’得導電性 -32- 201124486 塗覆組成物。所得的導電性塗覆組成物之分散狀態良好， 25°C之黏度爲0.9Pa. s。使用0.001英寸（25.4// m )之塗佈機將該導電性塗覆組成物塗佈於玻璃板上，以1 00°C乾燥1 〇分鐘，形成導電性被膜。所得的導電性被膜爲，Tt値93%、Haze値〇 ·4、表面電阻値6 8 0 Ω / □、鉛筆硬度Η B、橫切試驗結果爲 1 00。 [比較例1 ] 於製造例1所得的水分散液1 8.8 g中混合水2 0 · 1 g、紫外線硬化型聚乙烯醇樹脂組成物（Ο-1 06，中京油脂（股）製，固體成份濃度20.4質量％) 2.5g、乙二醇4.2g 、η-丙醇4.2g及羥基丙基胍爾豆膠（JAGUAR HP-105’ 三昌（股）製）〇. 3 g後攪拌1小時，得導電性塗覆組成物。所得的導電性塗覆組成物之分散狀態良好，2 5 °C之黏度爲 0.9 P a · s。使用0.001英寸（25.4"m)之塗佈機將該導電性塗覆組成物塗佈於玻璃板上’以1 〇〇°C乾燥1 〇分鐘’形成導電性被膜。所得的導電性被膜爲，Tt値93%、Haze値 0.1 '表面電阻値400 Ω /□、鉛筆硬度未達HB ’無法得到充分硬度。橫切試驗結果爲1〇〇。 [比較例2 ] 於製造例1所得的水分散液〗8.8g中混合水1 〇.6g、 -33- 201124486 製造例3所得的活性矽酸（固體成份濃度4.2質量％ ) 11.9g、乙二醇4.2g、η-丙醇4.2g及羥基丙基胍爾豆膠（ JAGUAR HP-105，三昌（股）製）〇.3g後攪泮1小時，得導電性塗覆組成物。所得的導電性塗覆組成物之分散狀態良好，25°C之黏度爲〇.8Pa · s。使用0.001英寸（25.4;/m)之塗佈機將該導電性塗覆組成物塗佈於玻璃板上，以1 〇〇°C乾燥1 〇分鐘，形成導電性被膜。所得的導電性被膜爲，Tt値93%、Haze値 0.2、表面電阻値380Ω/□、鉛筆硬度未達HB，無法得到充分硬度。橫切試驗結果爲1〇〇。 [比較例3] 於製造例1所得的水分散液18.8g中混合水12.4g、製造例3所得的活性矽酸（固體成份濃度4.2質量％ ) 11.9g、紫外線硬化型聚乙烯醇樹脂組成物（0-106，中京油脂（股）製，固體成份濃度20.4質量％ ) 2· 5g、丙醇 4.2g及羥基丙基胍爾豆膠（JAGUAR HP-105，三昌（股 )製）〇.3g後攪拌1小時，得導電性塗覆組成物。所得的導電性塗覆組成物之分散狀態良好，25°C之黏度爲〇.8Pa • s ° 使用0.001英寸（25·4#π〇之塗佈機將該導電性塗覆組成物塗佈於玻璃板上，以1 00°C乾燥1 〇分鐘，得導電性被膜。所得的導電性被膜爲，Tt値92%、Haze値〇 · 9、表面電阻値1 2，0 0 0 Ω / □，無法得到充分之低電阻値 -34- 201124486 。鉛筆硬度Η、橫切試驗結果爲1 〇〇。 -35-A guar gum derivative such as hydroxypropyl guar gum, carboxymethylhydroxypropyl guar gum, cationically modified guar gum or the like. These can be obtained from commercial products, such as, for example, Meproo HPG 81 1 1 , Meprox HPG -10- 201124486 8600, Meproxant 9806, JAGUAR HP-8, JAGUAR HP-105, JAGUAR HP -120 (all are three crystals) and so on. The molecular weight of the heteropolysaccharide is not particularly limited, but is preferably a number average molecular weight of 10,000 to 50 million, and preferably 100,000 to 20,000,000, and the average molecular weight of the present invention is gel permeation chromatography. The measurement is 値. The polyethylene oxide is not particularly limited, but is preferably a number average molecular weight of 1,000 to 1,000,000, and preferably 5, 〇〇〇 to 500,000. The polyvinylpyrrolidone is not particularly limited, but is preferably a number average molecular weight of 1,000 to 1,000,000, and preferably 10,000 to 500,000. For the gelatin type, for example, bismuth gelatin, amber gelatin, trimellis gelatin, phthalic acid gelatin, esterified gelatin, guanidine gelatin, formazan gelatin or the like can be used. In the conductive coating composition of the present invention, the addition ratio of the aqueous dispersion of the intrinsically conductive polymer to the tackifier is not particularly limited, and the quality of each solid component is preferably an intrinsically conductive polymer: tackifier = 99 . 9: 0. 1 to 0·1 to 99. 9, better is 99. 1: 1: 99. (C) inorganic fine particles inorganic fine particles such as oxides, carbides, metals, alloys, organometallic compounds, composites thereof, etc., and specific examples thereof include compounds of various elements such as ruthenium, aluminum, indium, tin, titanium, and chromium. , or carbon, etc. Among them, an oxide of cerium is preferred, and cerium oxide is particularly preferred. -11 - 201124486 Further, the particle diameter (diameter) of the inorganic fine particles is observed by a transmission electron microscope, and is preferably 10 nm or less, more preferably 10 nm or less. The lower limit is not particularly limited, and may be about 1 n m. When the particle diameter is considered, the inorganic fine particles are preferably active citric acid having a particle diameter of 1 to 10 nm, particularly preferably 2 to 5 n m of a very small particle size. The addition ratio of the aqueous dispersion of the intrinsically conductive polymer contained in the conductive coating composition of the present invention to the inorganic fine particles is preferably such that the mass ratio of the respective solid components is an intrinsically conductive polymer: inorganic fine particles = 99:1 To 1:99, more preferably 90: 10 to 10: 90. (D) The binder adhesive is not particularly limited, and a known binder can be appropriately selected. However, when the strength of the obtained film is further increased, an acrylic resin, a polyester resin, a urethane resin, or an epoxy resin is preferable. Polyvinyl alcohol resin, melamine resin, cellulose, cellulose derivative, polyimide resin, phenol resin, organic hydrazine compound, urea-formaldehyde resin, diallyl phthalate resin, butyral resin, and the like. These may be used singly or in combination of two or more. (1) Acrylic resin The acrylic resin is obtained by radically polymerizing the following (meth)acrylic acid monomer alone or a mixture of two or more thereof by a known method. Further, when the monomer is added, the polymerization can be carried out when the film is formed. Specific examples of the (meth)acrylic monomer are, for example, trifluoroethylacrylic acid-12- 201124486 vinegar 'di-gas methacrylate, phenyl glycidyl acrylate, ethyl (meth) acrylate, tetrahydrofuran acrylate Ester, propylene oxime, neopentyl alcohol (meth) acrylate, hydrazine, 6-hexanediol di( ) acrylate vinegar 'trimethylolpropane (meth) acrylate, double tri-propyl propylene (meth) acrylate, pentaerythritol tetra (methyl) propyl vinegar, pentaerythritol tri (meth) acrylate, pentaerythritol (methyl vinegar, ethylene glycol di (meth) acrylate, diethylene glycol bis ( ) acrylate, triethylene glycol di(meth) acrylate, tetraethylene di(methyl) propionate, octaethylene glycol di(meth) acrylate, mono ol - (meth) acrylate Ester, tripropylene glycol di(meth) propylene, tetrapropanol di(meth) acrylate, nona propylene glycol bis (methyl acrylate, polypropylene glycol di(meth) acrylate 'hydroxy trimethyl neopentyl Alcohol di(meth)acrylate, bisphenol quinone di(meth) vinegar, 2-ethyl-2 -butyl-propylene glycol di(meth)acrylate, decanediol di(meth)acrylate, 2,2-bis[4-(methacryloxyethoxy)phenyl]propane, 3-phenoxy Benzyl-2-propenyl acrylate, bis(3·propenyloxy-2-hydroxypropyl)hexyl ether, trimethylolpropane (meth) acrylate, tris(meth)acrylate, tri Base ethyl) trimeric isocyanate (meth) acrylate, pentaerythritol methyl acrylate, dipentaerythritol hexa (meth) acrylate, propyl (meth) acrylate, isobutyl (meth) acrylate Butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate 2 - ethylhexyl carbitol acrylate, ω - carboxy polycaprolactone monopropyl ester, acrylic acid dimer, lauryl (A Acrylate '2-hydroxyl-hydroxymethyl hydroxymethane acid) propyl methyl alcohol dipolyacetate) propionic acid propylene 1,9-yl 2,6-houset 3- 2-hydroxy-5 (2- Hydroxy't-ester, enoateoxy-13- 201124486 Ethyl acrylate, butoxyethyl acrylate, ethoxyethoxyethyl acrylate, A Triethylene glycol acrylate, stearic acid (meth) acrylate, cyclohexyl (meth) acrylate, tetrahydrofurfuryl (meth) acrylate, isobornyl (meth) acrylate, bicyclo Pentenyl acrylate, benzyl acrylate, phenyl glycidyl ether epoxy acrylate, phenoxyethyl (meth) acrylate, phenoxy (poly) ethylene glycol acrylate, nonyl phenol ethoxylate Alkyl acrylate, acryloxyethyl phthalate, tribromophenyl acrylate, tribromophenol ethoxylated (meth) acrylate, methyl methacrylate, tribromophenyl methacrylate , methacrylic acid methoxyethyl maleic acid, methacryloxyethyl hexahydrophthalic acid, methacryloxyethyl phthalic acid, polyethylene glycol (meth) acrylate, polypropylene glycol (Meth) acrylate, /3-carboxyethyl acrylate, N-methylol acrylamide, N-methoxymethyl acrylamide, N-ethoxymethyl propylene amide, Nn-butyl Oxymethacrylamide, t-butyl acrylamide, vinyl stearate, N-methyl acrylamide, N-Dimethyl acrylamide, N-dimethylaminoethyl (meth) acrylate, N-dimethylaminopropyl acrylamide, glycidyl (meth) acrylate, n_ (meth) acrylate 'ethyl (meth) acrylate, allyl methacrylate, cetyl methacrylate, pentadecyl (meth) acrylate, methoxy polyethylene Alcohol (meth) acrylate, diethylaminoethyl (meth) acrylate, methacryloxyethyl succinic acid, hexanediol diacrylate vinegar, neopentyl glycol diacrylate, hydroxy three Methyl acetate neopentyl ester, pentaerythritol diacrylate monostearate, glycol diacrylate, 2-hydroxyethyl methacryl decyl phosphate, bisphenol A ethylene glycol adduct acrylic acid-14 - 201124486 Ester, bisphenol F ethylene glycol adduct acrylate, tricyclodecane methanol diacrylate, trihydroxyethyl trimeric isocyanate diacrylate, 2-hydroxy-propenyloxy-3-methylpropene oxide Propane, trimethylolpropane ethylene glycol adduct triacrylate, trimethylolpropane propylene glycol adduct Triacrylate, tripropylene methoxyethyl phosphate, trihydroxyethyl trimer isocyanate, modified e-caprolactone triacrylate, trimethylolpropane ethoxy triacrylate, glycerol propylene glycol Adducts triacrylate, pentaerythritol ethylene glycol adduct tetraacrylate, ditrimethylolpropane tetraacrylate, dipentaerythritol hexa(penta) acrylate, dipentaerythritol monohydroxypentaacrylate, epoxy acrylate, etc. . (2) Polyester resin A polyester resin such as a resin obtained by polycondensation of a dicarboxylic acid component and a glycol component. The components of the dicarboxylic acid and the diol which are constituent components are exemplified as follows. Specific examples of the dicarboxylic acid, for example, terephthalic acid, isophthalic acid, decanoic acid, 2,6-naphthalene dicarboxylic acid, 4,4'-biphenyldicarboxylic acid, 1,4-cyclohexanedicarboxylic acid And adipic acid, sebacic acid, phenyl indane dicarboxylic acid, dimer acid, etc., and these may be used individually or in combination of 2 or more types. Specific examples of the glycol component are, for example, ethylene glycol, 1,4-butanediol, neopentyl glycol, diethylene glycol, dipropylene glycol, 1,6-hexanediol, 1,4-cyclohexanedimethanol. , xylene glycol, dimethylolpropionic acid, glycerin, trimethylolpropane, polyethylene glycol, polytetramethylene glycol, epoxide addition of bisphenol A, hydrogenated bisphenol A ring An oxide adduct or the like may be used alone or in combination of two or more. -15- 201124486 Specific examples of the above polyester resin include polyethylene terephthalate, polyethylene naphthalate, and the like. (3) Ethyl urethane resin A urethane resin such as a polyisocyanate and an active hydrogen-containing compound are subjected to addition polymerization. Specific examples of the polyisocyanate are, for example, methyl diphenyl diisocyanate (MDI ), ethyl diisocyanate, tetramethyl methyl diisocyanate, hexamethylene diisocyanate HDI, eleven methyl diisocyanate, 1,6 , 11-dodecane triisocyanate, 2,2,4-trimethylhexamethylene diisocyanate, lysine diisocyanate (2,6-diisocyanatomethyl hexanoate) 'double ( 2 -isocyanatoethyl)fumarate, bis(2-isocyanatoethyl)carbonate, 2-isocyanatoethyl-2,6-diisocyanatohexahexanoate, Isophorone diisocyanate (IPDI), dicyclohexylmethane-4,4'-diisocyanate (hydrogenated MDI), cyclohexyl diisocyanate, methylcyclohexyl diisocyanate, bis(2-isocyanatoethyl) -4 cyclohexene-1,2-dicarboxylate, 2,5- and 2,6-norbornane diisocyanate, m- and p-xylylene diisocyanate, α,α,α'α '-Tetramethylxylylene diisocyanate. Another example is a modified polyisocyanate, which can be modified MDI (ethyl urethane modified MDI), carbodiimide modified MDI, trihydrodivalent carbon phosphate modified MDI, urethane A modification of a polyisocyanate such as an ester-modified TDI, a biuret-modified HDI, a trimer isocyanate-modified HDI, a trimer isocyanate-modified IpDI, or the like. -16- 201124486 The above polyisocyanate and its modified product may be used singly or in combination of two or more kinds. Specific examples of the active hydrogen-containing compound are, for example, ethylene glycol, diethylene glycol, 1. a 3-valent alcohol such as 3-propanediol 1,4-butanediol, hydrazine, 5·pentanediol, hydrazine or 6-hexanediol; propylene glycol, neopentyl glycol, 3-methyl-I, 5-pentane a glycol having a bond such as an alcohol, 2,2-ethyl-1,3-propanediol, 1,2-, 1,3- or 2,3-butanediol; a diol having a cyclic group such as 4-bis(transmethyl)cyclohexyl, m- or P-xylene monool; a divalent phenol such as bisphenol A; glycerin, trimethyl ketone, pentaerythritol, Polyvalent alcohols such as sorbitol; sugars and derivatives thereof such as sucrose and methyl glucomannan; aliphatic chain diamines such as ethyldiamine and hexamethylenediamine; 4,4,-diamino group- 3,3,-Dimethyldicyclohexylamine, diamine-based cyclohexyl', alicyclic diamine, and other alicyclic one-three females, one ethyl-ethyl-one-a-temperate An aromatic diamine such as xylylenediamine, α,α,α',α'-tetramethylxylylenediamine; a heterocyclic diamine such as piperazine; diethylidene triamine; Polyfunctional amines such as amines; polymer polyols such as polyester polyols and polyether polyols; succinic acid, glutaric acid, maleic acid, fumaric acid, adipic acid, sebacic acid, sebacic acid, hexahydrogen An aliphatic polycarboxylic acid such as citric acid; an aromatic polycarboxylic acid such as citric acid, isophthalic acid, terephthalic acid, tetrabromodecanoic acid, tetrachlorodecanoic acid, trimellitic acid or pyromellitic acid; Polycarboxylic anhydride such as acid anhydride or phthalic anhydride; terephthalic acid II Polycarboxylate esters and the like; R- butyrolactone, caprolactone, r - valerolactone lactone monomer, a compound having two or more active hydrogen atoms in the structure of the additional epoxides and the like. These may be used alone or in combination of two or more. -17- 201124486 (4) Specific examples of epoxy resin epoxy resin, such as bisphenol A type, double 酹 F type, hydrogenated bisphenol A type, bisphenol AF type, phenol novolak type, etc. a liquid epoxy resin and a derivative thereof derived from a derivative, a polyvalent alcohol and epichlorohydrin, a glycidylamine type, an intramethylene urea type, an aminophenol type, an aniline type, a toluidine type, etc. Various glycidyl type liquid epoxy resins and derivatives thereof. These may be used alone or in combination of two or more. (5) Polyvinyl alcohol resin The polyvinyl alcohol resin can be obtained by alkalization of a polyvinyl ester polymer obtained by radical polymerization of a vinyl ester monomer such as vinyl acetate. Specific examples of the polyvinyl ester-based polymer are, for example, vinyl formate, vinyl acetate, vinyl propionate, vinyl glyceryl monovalerate, vinyl laurate, vinyl stearate, vinyl benzoate, trimethylacetic acid A polymer of a vinyl ester such as a vinyl ester or an alkane carboxylic acid vinyl ester, etc., may be used alone or in combination of two or more. Further, the polyvinyl ester polymer may be a copolymer obtained by copolymerizing the above vinyl ester monomer with a copolymerizable comonomer. Specific examples of the comonomer are, for example, a rare hydrocarbon such as ethylene, propylene, butylene or isobutylene; (meth)acrylic acid and a salt thereof; methyl ketone (meth)acrylate, ethyl (meth)acrylate, (a) Base η-propyl acrylate, i-propyl (methyl) propyl acrylate, η-butyl (meth) acrylate, i-butyl (meth) acrylate, t-butyl (meth) acrylate Ester, 2-ethylhexyl methacrylate, dodecyl (meth)acrylate, (meth)acrylates such as -18 - 201124486 hexadecyl ester; acrylamide, Hydroxyalkyl acrylamide, N-methyl acrylamide, N-ethyl acrylamide, N,N-dimethyl decylamine, diacetone acrylamide, acrylamide propylene sulfonic acid and salts thereof, Acrylamide derivative such as acrylamide propylamine dimethylamine and its salt or its grade 4 salt, N-methylol acrylamide and its derivatives; methacrylamide, N-methyl methacrylate Indamine, N-ethylmethacrylamide, methacrylamide sulfonic acid and its salt, methacrylamidamine dimethylamine and its salt or its class 4 salt, N-methylol Methyl acrylamide derivatives such as acrylamide and its derivatives; methyl vinyl ether, ethyl vinyl ether, η-propyl vinyl ether, i-propyl vinyl ether, η-butyl vinyl ether, i- Vinyl ethers such as butyl vinyl ether, t-butyl vinyl ether, lauryl vinyl ether, stearic acid vinyl ether; nitriles such as (methyl) acrylonitrile; vinyl chloride, vinylidene chloride, vinyl fluoride A vinyl halide such as vinyl fluoride: an allyl compound such as allyl acetate or chloropropene; a maleic acid or a salt thereof or an ester thereof; a vinyl sulfonyl compound such as vinyltrimethoxy hydride; an isopropyl acetate; (6) Melamine resin Specific examples of the melamine resin include methylated melamine resin, butylated melamine resin, and methylbutyl mixed melamine resin. These may be used alone or in combination of two or more. (7) Cellulose and Cellulose Derivatives Specific examples of cellulose and cellulose derivatives such as 'cellulose, hydroxypropyl cellulose, triacetyl cellulose, diethyl cellulose, ethyl cellulose, -19- 201124486 Cellulose acetate propionate, cellulose acetate butyrate, cellulose acetate phthalate, cellulose acetate trimellitate, nitrocellulose, and the like. These may be used alone or in combination of two or more. (8) Specific examples of the polyimine resin, for example, one or more selected from the group consisting of tetracarboxylic acid and/or an acid anhydride thereof, and selected from aliphatic diamines and/or aromatic diamines One or more kinds of polyimine obtained by dehydration condensation. (9) an organic hydrazine compound organic hydrazine compound, such as a hydrazine compound represented by the following formula (I) and/or formula (II), and a hydrolyzate thereof, a polyoxyalkylene lacquer, a polyoxy oxyalkyl alcohol varnish, and a poly Modified polyoxyalkylene varnish, such as a decyl oxide varnish, a polyoxy siloxane lacquer, a polyoxy siloxane lacquer, etc., these may be used alone or in combination of two or more (R〇a (R3) bS i (OR2) 4-(a+b) ( I ) (wherein R1 and R3 are each independently an alkyl group having 1 to 8 carbon atoms, an alkenyl group having 2 to 20 carbon atoms, and a carbon number of 6 to 10 Base, aralkyl group having 7 to 20 carbon atoms, mercapto group having 2 to 10 carbon atoms, halo group, glycidoxy group, epoxy group, amine group, phenyl group, mercapto group, methacryloxy group and cyano group The organic group selected in the group 'R2 is a compound having a carbon number of 1 to 8, a carbon number of 2 to 10, and an organic group selected from the group of phenyl groups, and a and b are 0 or 1). (OX) 3-aS i (R4) } 2Y (II) (wherein R4 is a monovalent organic group having 1 to 5 carbon atoms, and hydrazine is an alkyl group having a carbon number of 1 to 4 -20 to 201124486 or a carbon number of 2 To a fluorenyl group of 4, Y is a divalent organic group having 2 to 20 carbon atoms, and a is 0 or 1). In the above formula (1), an alkyl group having 1 to 8 carbon atoms of R1 and R3 For example, methyl, ethyl, η-propyl, isopropyl, η-butyl, isobutyl, sec-butyl, tert-butyl 'pentyl, hexyl, octyl, cyclopentyl, cyclohexyl Specific examples of the alkenyl group having 2 to 20 carbon atoms of R1 and R3 are, for example, a vinyl group, an allyl group, a butenyl group, a hexenyl group, an octenyl group, etc. The carbon number of R1 and R3 is 6 to 10 Specific examples thereof include a phenyl group, a tolyl group, a xylyl group, a naphthyl group, etc. Specific examples of the aralkyl group having 7 to 20 carbon atoms of R1 and R3 are, for example, a benzyl group, a phenethyl group, a phenylpropyl group, a naphthyl group. Methyl group, etc. The specific group of the fluorenyl group having 2 to 10 carbon atoms of R1 and R3 is, for example, an ethyl group, etc. Further, specific examples of the alkyl group having 1 to 8 carbon atoms of R2 are, for example, methyl group, ethyl group, η-propyl group. Base, isopropyl, η-butyl, isobutyl, sec-butyl, tert-butyl, pentyl, hexyl, octyl, cyclopentyl, cyclohexyl, etc. R2 has a carbon number of 2 to 10 Specific examples of the group include, for example, an ethyl group, etc. Specific examples of the organic phosphonium compound represented by the formula (I) include, for example, methyl phthalate, ethyl oleate, η-propyl sulphate, and iso-propyl succinic acid. Vinegar, η-butyl phthalate, tetraacetic acid decane, methyl trimethoate Decane, methyltripropoxydecane, methyltriacetoxydecane, methyltributoxydecane, methyltripentyloxydecane, methyltriphenyloxydecane, methyltribenzyloxyfluorene, Methyltriphenylethoxydecane, glycidoxymethyltrimethoxydecane, glycidoxymethyltriethoxydecane, glycidoxyethyltrimethoxydecane, propylene oxide Ethyl triethoxy decane, yS-glycidoxyethyl trimethoxy decane, /3-glycidoxyethyl triethoxy sulphide - 21 - 201124486 , α-glycidoxy Propyltrimethoxydecane, α-glycidoxytriethoxydecane,/5-glycidoxypropyltrimethoxylate, oxypropoxypropyltriethoxy sand , glycidoxypropyl diyl decane, r-glycidoxypropyl triethoxy decane, epoxy-propyl tripropoxy decane, r-glycidoxypropyl three Butoxy, r-glycidoxypropyltriphenoxydecane, α-glycidoxytrimethoxydecane, α-glycidoxybutyltriethoxydecane, oxypropylene oxide Butyl trimethoxy decane, /3-epoxy propylene Butyl trimethyl decane, τ-glycidoxybutyl trimethoxy decane, epoxy butyl triethoxy decane, glycidoxybutyl trimethoxy ' (5-glycidoxy Butyl triethoxy decane, (3,4-epoxycyclohexylmethyltrimethoxydecane, (3,4-epoxycyclohexyl)methyltriethoxylate, no-(3,4-ring) Oxycyclohexyl)ethyltrimethoxydecane, /3,4-epoxycyclohexyl)ethyltriethoxydecane, /3-(3,4-epoxy)ethyltripropoxydecane, 0 -(3,4-epoxycyclohexyl)ethyloxydecane, /3-(3,4-epoxycyclohexyl)ethyltriphenoxypurine-(3,4-epoxycyclohexyl)propane Trimethoxy decane, r-(3 oxocyclohexyl)propyltriethoxy decane, (5-(3,4-epoxycyclohexyltrimethoxydecane, 5-(3,4-epoxy) Cyclohexyl)butyltriethoxysilane, glycidoxymethylmethyldimethoxydecane, glycidoxymethyldiethoxydecane, α-glycidoxyethylmethyldimethyl Decane, α-glycidoxyethylmethyldiethoxydecane, /S-epoxyethylmethyldimethoxydecane, /3-glycidoxyethylethyl Oxydecane, α-glycidoxypropylmethyldimethoxydecylpropyl 3-cyclomethoxypropoxydecylbutyl 5-cycloethoxypropoxyalkylene)ylindole-(cyclohexyl) Butane, 4-cyclo)butoxymethoxymethoxypropyl di-22- 201124486 Glycidoxypropylmethyldiethoxydecane, glycidoxymethyldimethoxy-5 , /3-glycidoxypropylethyldimethane, r-glycidoxypropylmethyldimethoxydecane, r-cyclopropylmethyldiethoxylate, 7_ Glycidoxypropylmethoxydecane, r-glycidoxypropylmethyldibutoxydecyloxypropoxypropylmethyldiphenoxydecane, r-glycidoxy Dimethoxydecane, r-glycidoxypropylethyldiethoxy, r-glycidoxypropylvinylmethoxydecane, r-epoxypropylvinylethoxydecane, r·glycidoxypropylvinylmethoxydecane, r-glycidoxypropylvinylphenylethoxy, ethyltrimethoxydecane, ethyltriethoxydecane, vinyl decane , vinyl triacetoxy decane, vinyl trimethoxy ethane Phenyltrimethoxydecane, phenyltriethoxydecane, phenyldecane, r-chloropropyltrimethoxydecane, r-chloropropyltriethane, r-chloropropyltriacetoxydecane, 3,3,3-trifluoropropyltrimethane, r-methylpropoxypropyltrimethoxydecane, r-fluorenylmethoxydecane, r-mercaptopropyltriethoxydecane, S - cyanoethoxy decane, chloromethyltrimethoxy decane, chloromethyltriethoxy, n-(aminoethyl)-r-aminopropyltrimethoxydecane yS-aminoethyl)- R-Aminopropylmethyldimethoxydecane, 'propylmethyltrimethoxydecane, n-(/3-aminoethyl)-r-yldiethoxylate, N-(yS -aminoethyl)-γ-aminopropyldiethoxydecane, dimethyldimethoxydecane, phenylmethyldioxane, dimethyldiethoxydecane, phenylmethyldiethoxy Propyl propyloxy oxypropyloxydipropyl xm, 7 - propylethyl decyl propoxy phenyl decyl trimethoxy oxy ruthenium triacetate Baseline, N-(r-aminoaminopropylmethylmethoxydecane, -23 - 201124486 r-Chloropropylmethyldimethoxydecane, r-chloropropylmethyldiethoxydecane, dimethyldiacetoxydecane, 7-methacryloxypropylmethyldimethoxy Baseline, τ-methacryloxypropylmethyldiethoxydecane, τ-mercaptopropylmethyldimethoxydecane, τ-mercaptopropylmethyldiethoxydecane 'methyl Vinyl dimethoxy decane, methyl vinyl diethoxy decane, and the like. In the above formula (II), specific examples of the monovalent organic group having 1 to 5 carbon atoms of R4 are, for example, methyl, ethyl, η-propyl, isopropyl, η-butyl, isobutyl, sec-butyl. An alkyl group such as a tert-butyl group or a pentyl group; an alkenyl group such as a vinyl group, a vinyl group, an allyl group or a butenyl group; or an anthracenyl group such as an ethenyl group. Specific examples of the alkyl group having 1 to 4 carbon atoms of X are, for example, methyl, ethyl, η-propyl, isopropyl, η-butyl, isobutyl, sec-butyl, tert-butyl. Specific examples of the fluorenyl group having a carbon number of 2 to 4 of X are, for example, an ethyl group. Specific examples of the divalent organic group having 2 to 20 carbon atoms of Y include, for example, an alkylene group such as a methyl group, an ethyl group, a propyl group or a butyl group, and an alkylene group such as an alkyl group or an ethylene group. Specific examples of the organic hydrazine compound represented by the formula (Π) include methyl dimethyl dimethoxy decane, ethyl bis dimethyl dimethoxy decane, and propyl bis diethyl dimethoxy decane. Butyl butyl dimethyl diethoxy decane and the like. The organic hydrazine compound represented by the above formula (I) and formula (II) and the hydrolyzate thereof may be used singly or in combination. The compound of the above formula (I) and formula (11) can be used in combination of either of them alone or in combination. The hydrolysis step of the organic hydrazine compound represented by the formula (I) and the formula (II) is carried out by adding an acidic aqueous solution such as an aqueous hydrochloric acid solution, an aqueous sulfuric acid solution or an aqueous acetic acid solution of -24 - 201124486 to the organic hydrazine compound and stirring. (10) Diallyl phthalate resin Specific examples of the diallyl phthalic acid resin include diallyl allylic isophthalate, diallyl terephthalate and the like. (11) Butyraldehyde Resin Specific examples of the butyral resin are, for example, polyvinyl butyral and the like. The addition ratio of the intrinsically conductive aqueous dispersion to the binder component contained in the conductive coating composition of the present invention is preferably such that the mass ratio of the respective parts is intrinsically conductive polymer: binder = 99:1 to More preferably, it is 9 0 : 1 0 to 1 0 : 9 0. The CE polyol polyol is not particularly limited, and examples thereof include ethylene glycol, 1,2-propylene glycol propylene glycol, glycerin, etc., but the effect of improving conductivity is preferably that the amount of the hydrazine polyol added is relative to the conductivity of the present invention. The coating group is preferably 0. 01 to 30. 0% by mass is more preferably 1 to 15% by mass. The viscosity of the conductive coating composition of the present invention at 25 ° C is preferably 100 Pa·s, more preferably 1 to 30 Pa, with respect to the coating property with respect to the substrate when using a printing method. s. The method for adjusting the conductive coating composition of the present invention is not particularly suitable for mixing the moisture ester of the intrinsically conductive polymer and the two polymer solids into a 1:99 '1,3-ethylene glycol composition by any method. Consider 0. 5 to limited, liquid, -25- 201124486 tackifiers, inorganic microparticles, binders and polyols. Further, the object of the present invention is to improve the dispersion of the conductive coating composition and to preserve stability. , the composition can be added 0. 1 to 10% by mass of a surfactant, an acid, a base or the like. The surfactant is not particularly limited, and surfactants such as anionic, cationic, and nonionic surfactants can be widely used, and can be appropriately selected from known surfactants. Acids such as hydrochloric acids, nitric acid, orthophosphoric acid, etc.; oxalic acid, lactic acid, tartaric acid, malic acid, citric acid, glycolic acid, hydrogen acrylic acid, α-oxybutyric acid, glycerol acid, tartaric acid, etc. a phosphonic acid compound such as phenylphosphonic acid or 1-hydroxyethylidene-1,1-diphosphonic acid. Base such as ammonia; alkali metal hydroxide; ethylamine, diethylamine, hydrazine-propylamine, isopropylamine, diisopropylamine, dipropylamine, η-butylamine, isobutylene An alkyl or aralkylamine such as a diamine, a triethylamine, a benzylamine, an octylamine, a dodecylamine or a stearylamine; an alkanol such as monoethanolamine or triethanolamine. Amine; a fourth-order hydrogen hydroxide such as a hydroxide, a tetramethylammonium hydroxide or a tetraethylammonium hydroxide; an organic base such as ammonium carbonate or a carbonic acid pulse. The conductive coating composition of the present invention is applied onto a substrate. A film can be formed after drying. From this, a coated member having a transparent conductive film or a transparent antistatic film can be obtained. Substrates such as plastic, rubber, glass, metal, ceramics, paper, and the like can be used. The coating method of the conductive coating composition of the present invention can be applied, for example, by bar coating method -26-201124486, reverse coating method, gravure printing method, micro gravure printing method, screen printing method, dipping method, spin coating Suitable methods such as a method, a spray method, a roll copy method, and a dispenser method are appropriately selected. The thickness of the film formed from the conductive coating composition of the present invention can be appropriately set according to the application, and is preferably set to 0. 05 to 10 # m, more preferably 0. 1 to 5 # m. The above film has a surface resistance 値 of 10° to 1014 Ω/□, and thus has excellent electrical conductivity. Further, the surface resistance 测定 can be measured by a surface resistivity measuring device (for example, Hayes UP (manufactured by Mitsubishi Chemical Corporation), Lorez IP (manufactured by Mitsubishi Chemical Corporation, etc.). Conductive coating from the present invention. The film formed of the composition may have an antireflection film laminated thereon, for example, to provide an antireflection function. The antireflection film preferably has a refractive index lower than that of the conductive film, and the refractive index difference is preferably 0. 05 or more, more preferably 0. 1 to 0. 5, the best is 0. 15 to 0. 5. The refractive index difference is less than 0. At 05, the synergistic effect of the anti-reflection film will not be obtained, but the anti-reflection effect will be reduced. The thickness of the antireflection film is not particularly limited, and is preferably from 50 to 300 nm. When the thickness is less than 5 Onm, the adhesion to the conductive film of the lower layer is lowered, and when the thickness exceeds 300 nm, light interference occurs to lower the antireflection effect. When a plurality of anti-reflection films are provided for higher anti-reflection energy, the total thickness thereof may be 50 to 300 nm. The material constituting the antireflection film is not particularly limited, and examples thereof include an organic hydrazine compound and a hydrolyzate thereof; a fluoroolefin polymer; a fluorine-based resin such as a fluorine-containing acrylic polymer -27-201124486; and a microparticle having a low refractive index. A low refractive index coating composition obtained by mixing magnesium fluoride, lithium fluoride, sodium fluoride, or fine particles having voids with an organic or inorganic binder. Further, an inorganic compound such as magnesium fluoride or cerium oxide can be formed into an antireflection film by a method such as vacuum vapor deposition or sputtering. Further, on the film formed of the conductive coating composition of the present invention, the high refractive index layer and the low refractive index layer are alternately laminated to form a multilayer antireflection film for an antireflection film to impart an antireflection function. The high refractive index layer at this time is preferably a layer of at least one oxide selected from the group consisting of titanium, molybdenum, zirconium, hafnium and tantalum, and the low refractive index layer is preferably ceria, alumina, and fluorinated. At least one layer selected from the group consisting of magnesium, lithium fluoride, and sodium fluoride. These high refractive index layers and low refractive index layers can be formed by dry gold plating such as vacuum distillation, sputtering or ion plating. [Embodiment] Hereinafter, the present invention will be specifically described by way of Examples and Comparative Examples, but the present invention is not limited to the following examples. Further, the measurement methods and measurement conditions of each physical property are as follows. [1] Tt 値 Measured using a spectrophotometer TC-H3DPK-MKII (manufactured by Tokyo Electric Co., Ltd.). -28- 201124486 [2] Haze was measured using a spectrophotometer TC-H3DPK-MKII (manufactured by Tokyo Electric Co., Ltd.). [3] Surface resistance 测 Measured using Loresta IP TCP-T2 5 0 (Mitsubishi Chemical Co., Ltd.). [4] Pencil hardness using a pencil hardness tester (No. 55 3 -M FILM HARDNESS TESTER BY MEANS OF PENCILS > Yasuda Seiki Seisakusho Co., Ltd.) was measured by the method described in Jis-K 5 600-5 -4. [5] Cross-cut test The cross-cutting guide (CCI-1, manufactured by Kiesi Co., Ltd.) was tested by the method described in J IS-K5 600, and the number of remaining lattices was recorded. [6] Viscosity The E-type viscometer (VISCOMETER TV-20, manufactured by Toki Sangyo Co., Ltd.) was used to measure the range U and the number of revolutions was 0. 5 rpm measurement. [Production Example 1] Preparation of an aqueous dispersion of an intrinsically conductive polymer: N-methylpyrrolidone 60. 0 g of an aqueous colloidal dispersion of 690-201124486 inherently conductive polymer containing doped polyaniline 6903-116-000 (manufactured by ORMECON Co., Ltd.) in an aqueous dispersion (solid content concentration of 1. 7 mass%, viscosity at 25 ° C 51 mPa·s' conductivity 380 S/cm [Production Example 2] An aqueous colloidal dispersion of doped poly 3,4_ethylidenethiophene using an evaporator Baytron ΡΗ5〇0 ( Η· C. Starck company) 100. 〇g distillation under reduced pressure to 68. 〇g' obtained aqueous dispersion (solid content concentration 1. 7 mass%). [Manufacturing Example 3] with water 163. 6g diluted sodium citrate solution (Si02: 27. 5 mass%, Na20: 8. 4% by mass) 36. 4g, the pH of the resulting dilution is 11. 6. The dilution was passed at 25 ° C (space velocity per hour 7) 塡 hydrogen-filled strong acid cation exchange resin (with mechanism IR-120B) 250 mL column (column diameter 45 mm) to obtain active tannic acid 2 1 5 · 8 g. The pH of the obtained active citric acid is 2. 7, the solid concentration is 4. 2% by mass, as a result of transmission electron microscopy, the particle diameter was 2 to 5 nm. [Example 1] The aqueous dispersion obtained in Production Example 1 was 18. 8g mixed water 8. 2 g, the active citric acid obtained in Production Example 3 (solid concentration of 4. 2% by mass) 1 1. 9g, ultraviolet curable polyvinyl alcohol resin composition (0-106, Zhongjing -30- 201124486 grease (stock) system, solid concentration 20_4% by mass) 5g, ethylene glycol 4. 2g, η-propanol 4. 2g and hydroxypropyl guar gum (JAGUAR HP-105, Sanchang (share) system) 〇. After stirring for 3 hours at 3 g, a conductive coating composition was obtained. The obtained conductive coating composition has a good dispersion state of '25 ° C viscosity 〇. 9Pa · s. Use 0. 001 inches (25. The conductive coating composition was applied to a glass plate by a coater of 4 μm), and dried at 1 〇 C ° C for 1 minute to form a conductive film. The obtained conductive film is Tt 値 92%, Haze 値 0. 3. Surface resistance 値420 Ω /□, pencil hardness Η, cross-cut test result is 1 〇〇. [Example 2] The aqueous dispersion obtained in Production Example 2 47. The active citric acid obtained in Production Example 3 was mixed in 9 g (solid content concentration: 4.2% by mass). 4g, ultraviolet curable polyvinyl alcohol resin composition (〇·1 06, Zhongjing Grease), solid concentration 19. 1%) 5_9g, ethylene glycol 10. 0g' η-propanol 10. 〇g and hydroxypropyl guar gum (JAGUAR HP-105, Sanchang (share) system) 〇. After 8 g, the mixture was stirred for 1 hour to obtain a conductive coating composition. The obtained conductive coating composition was in a good dispersion state, and had a viscosity of 1 at 25 °C. 2Pa • s ° Use 0. 001 inches (25. The coating composition of 4# m) was applied onto a glass plate and dried at 10 ° C for 10 minutes to form a conductive film. The obtained conductive film is Tt 値 86%, Haze 値 0. 1. Surface resistance 値220 Ω/□, pencil hardness Η 'Cross-cut test result -31 - 201124486 is 1 00. [Example 3] The aqueous dispersion obtained in Production Example 1 was 18. 8g mixed water 8. 2 g, the active citric acid obtained in Production Example 3 (solid concentration of 4. 2% by mass) 1 1. 9g, UV-curable polyvinyl alcohol resin composition (0-106, made by Zhongjing Grease), with a solid concentration of 20. 4% by mass) 2. 5g, 1,2-propanediol 4. 28, 11-propanol 4. 28 and hydroxypropyl guar gum (*^01; eight 11 HP-105, Sanchang (share) system) 0. After stirring for 3 hours at 3 g, a conductive coating composition was obtained. The obtained conductive coating composition has a good dispersion state, and the viscosity of 25T: is 0. 9Pa·s. Use 0. 001 inches (25. The coater of 4; c/m) was applied onto a glass plate, and dried at 1 ° C for 1 minute to form a conductive film. The obtained conductive film was Tt 値 93% and Haze 値〇 . 1. Surface resistance 値7 5 0 Ω / □, pencil hardness Η B, cross-cut test result is 1 00. [Example 4] The aqueous dispersion obtained in Production Example 1 was 18. 8g of mixed water in 8g, active citric acid obtained in the production example 3 (solid concentration of 4. 2% by mass) 1 1. 9g, UV-curable polyvinyl alcohol resin composition (〇-1〇6, made by Zhongjing Grease), with a solid concentration of 20. 4% by mass) 2. 5g, 1,3-propanediol 4. 2g' η-propanol 4. 2g and hydroxypropyl guar gum (JAGUAR HP-105, manufactured by Sanchang Co., Ltd.) 0. After stirring for 3 hours, 3 g was obtained. Conductivity -32 - 201124486 Coating composition. The obtained conductive coating composition has a good dispersion state, and the viscosity at 25 ° C is 0. 9Pa. s. Use 0. 001 inches (25. The coating composition of 4/m) was applied onto a glass plate, and dried at 100 ° C for 1 minute to form a conductive film. The obtained conductive film was Tt 値 93%, Haze 〇 4 · 4 , surface resistance 値 6 80 Ω / □, pencil hardness Η B, and the cross-cut test result was 100. [Comparative Example 1] The aqueous dispersion 1 obtained in Production Example 1 8. 8 g mixed water 2 0 · 1 g, UV-curable polyvinyl alcohol resin composition (Ο-1 06, made by Zhongjing Oil & Fat Co., Ltd., solid concentration 20. 4% by mass) 2. 5g, ethylene glycol 4. 2g, η-propanol 4. 2g and hydroxypropyl guar gum (JAGUAR HP-105' Sanchang (share) system) 〇. After stirring for 3 hours, 3 g was obtained to obtain a conductive coating composition. The obtained conductive coating composition was in a good dispersion state, and the viscosity at 25 ° C was 0. 9 P a · s. Use 0. 001 inches (25. In the coater of 4 "m), the conductive coating composition was applied onto a glass plate and dried at 1 ° C for 1 minute to form a conductive film. The obtained conductive film was Tt 値 93%, Haze 値 0. 1 'The surface resistance 値400 Ω /□, the pencil hardness is not up to HB', and sufficient hardness is not obtained. The cross-cut test result was 1〇〇. [Comparative Example 2] The aqueous dispersion obtained in Production Example 1 was 8. 8g mixed water 1 〇. 6g, -33- 201124486 The active citric acid obtained in Production Example 3 (solid component concentration 4. 2% by mass) 11. 9g, ethylene glycol 4. 2g, η-propanol 4. 2g and hydroxypropyl guar gum (JAGUAR HP-105, manufactured by Sanchang Co., Ltd.) 〇. After 3 g of the mixture was stirred for 1 hour, a conductive coating composition was obtained. The obtained conductive coating composition has a good dispersion state, and the viscosity at 25 ° C is 〇. 8Pa · s. Use 0. 001 inches (25. The coating composition of 4;/m) was applied onto a glass plate and dried at 1 ° C for 1 minute to form a conductive film. The obtained conductive film was Tt 値 93%, Haze 値 0. 2. The surface resistance is 値380Ω/□, the pencil hardness is less than HB, and sufficient hardness cannot be obtained. The cross-cut test result was 1〇〇. [Comparative Example 3] The aqueous dispersion obtained in Production Example 1 was 18. 8g mixed water 12. 4 g, the active citric acid obtained in Production Example 3 (solid component concentration 4. 2% by mass) 11. 9g, UV-curable polyvinyl alcohol resin composition (0-106, made by Zhongjing Grease), with a solid concentration of 20. 4% by mass) 2·5g, propanol 4. 2g and hydroxypropyl guar gum (JAGUAR HP-105, Sanchang (share) system) 〇. After stirring for 3 hours at 3 g, a conductive coating composition was obtained. The obtained conductive coating composition has a good dispersion state, and the viscosity at 25 ° C is 〇. 8Pa • s ° Use 0. The conductive coating composition was applied to a glass plate at 001 inch (25·4 #π〇), and dried at 100 ° C for 1 minute to obtain a conductive film. The obtained conductive film was Tt値92%, Haze値〇·9, surface resistance 値1 2,0 0 0 Ω / □, sufficient low resistance 値-34- 201124486 could not be obtained. Pencil hardness Η, cross-cut test result is 1 〇〇. 35-

Claims

201124486 VII. Patent application scope: 1. A conductive coating composition characterized by an aqueous dispersion containing an intrinsically conductive polymer, an adhesion promoter, inorganic fine particles, a binder, and a polyhydric alcohol. 2. The conductive coating composition of claim 1, wherein the intrinsically conductive polymer is a doped polyaniline, a doped polythiophene, a mixture thereof, or a copolymer thereof . 3. The conductive coating composition according to claim 1, wherein the intrinsically conductive polymer contains at least an aniline unit. 4. The conductive coating composition according to the invention of claim 4, wherein the tackifier is at least one selected from the group consisting of a heteropolysaccharide, a polyethylene oxide, a polyvinylpyrrolidone, and a gelatin. 5. The conductive coating composition of claim 4, wherein the tackifier is at least one selected from the group consisting of guar gum and a derivative thereof. 6. The conductive coating composition of claim 5, wherein the tackifier is hydroxypropyl guar gum or carboxymethylhydroxypropyl guar gum. 7. The conductive coating composition of claim 1, wherein the inorganic fine particles are cerium oxide. 8. The conductive coating composition of claim 7, wherein the inorganic fine particles are active citric acid. 9. The conductive coating composition of claim 1, wherein the binder is an acrylic resin, a polyester resin, a urethane tree-36-201124486 grease, an epoxy resin, a polyvinyl alcohol resin, At least one selected from the group consisting of melamine resin, cellulose, cellulose derivative, polyimide resin, phenol resin, organic hydrazine compound, urea resin, diallyl phthalate resin, and butyral resin. 10. The conductive coating composition of claim 1, wherein the polyol is ethylene glycol. A coated member characterized by comprising a substrate, and a film formed on the substrate, and the film is as claimed in any of claims 1 to 1 of the patent application! The conductive coating composition of the item is formed. 12. The coated member of claim 11, wherein the substrate is plastic, rubber, glass, metal, ceramic or paper. -37- 201124486 Four designated representatives: (1) The representative representative of the case is: None (2) The symbol of the representative figure is simple: No 201124486 If there is a chemical formula in the case, please disclose the chemical formula that best shows the characteristics of the invention: no