201029941 六、發明說明： 【^明戶斤屬名頁3 技術領域 本發明係有關一種可適用於如減壓脫泡裝置之玻璃製 造裝置的熔融玻璃搬送設備元件，以及包含該熔融玻璃搬 送設備元件之玻璃製造裝置。 【先前技術J 發明背景 在如減壓脫泡裝置之玻璃製造裝置中，熔融玻璃之導 管的構成材料被要求具耐熱性以及對熔融玻璃具優異耐蝕 性。作為滿足此要求之材料，目前係使用銘或銘合金(參照 專利文獻1)。在鉑或鉑合金製之熔融玻璃之導管周圍，係 以包圍該導管的方式配置有隔熱磚。 由於構成導管之鉑或鉑合金與配置在該導管周圍之隔 熱碑係具有不同的熱膨脹係數，因此，加熱時之熱膨脹量 的差，及冷卻時之收縮量的差會成為問題。 為了吸收此種加熱時之熱膨脹量的差、或是冷卻時之 收縮量的差，而於兩者間填充如可澆鑄之水泥般之不定形 陶竟材料，俾以在發生溫度變化時，兩者可稍微相對移動。 先行技術文獻 專利文獻 專利文獻1:日本特開第2002-87826號公報 t發明内容3 發明概要 3 201029941 發明欲解決之課題 、 然而，本案發明人發現到，依熔融玻璃之導管的配置 而定，光靠填充不定形陶瓷材料有時會有無法完全吸收加 熱時之熱膨脹量的差、或是冷卻時之收縮量的差的情況。 第1圖係顯示減壓脫泡裝置之一構成例的截面圖。在 第1圖所示之減壓脫泡裝置100中，減壓脫泡槽130係以 其長轴朝水平方向配向的方式而收納配置於減壓殼體120 内。減壓脫泡槽130—端之下面安裝有上昇管140,另一端 之下面則安裝有下降管150。在減壓殼體120内，減壓脫泡 槽130、上昇管140以及下降管150之周圍係配設有隔熱材 160。 上昇管140係經由導管170、180及190而與熔融玻璃 上游側之結構物（未圖示，例如玻璃溶解槽)相連接。下降管 150係經由導管200、220及240而與下游侧之結構物（未圖 示，例如浮浴之板玻璃成形裝置)相連接。若更具體說明， 則具有垂直方向之中心軸的上昇管140係經由在水平方向 上具有中心軸的導管170、在垂直方向上具有中心軸的導管 180以及在水平方向上具有中心轴的導管19〇而與上流侧 之結構物相連接。另一方面，在垂直方向上具有中心轴之 下降管150係經由在水平方向上具有中心軸之導管2〇〇、在 垂直方向上具有中心轴之導管220以及在水平方向上具有 中心軸之導管240而與下流側之結構物相連接。又，上昇 管 140、下降管 150、導管 17〇、180、190、200、220 及 240 係鉑或鉑合金製的管。 201029941 儘管未圖示，隔熱磚係以包圍前述鉑或鉑合金製管的 方式配置，且該鉑或鉑合金製管與隔熱碑之間係填充有不 定形陶竟材料。 如此之結構中，僅單獨有在垂直方向上具有中心轴之 管（140、150、180及220)，或僅單獨有在水平方向上具有 中心軸之管（170、190、200及240)時，翻或翻合金製管與 隔熱磚在加熱時之熱膨脹量的差或冷卻時之收縮量的差係 A 可被填充於兩者間之不定形陶瓷材料所吸收。然而，在垂 〇 直方向上具有中心軸之管且在水平方向上具有中心軸之管 的接合部（上昇管140與導管170之接合部、下降管150與 導管200之接合部、導管170與導管180之接合部、導管 18〇與導管190之接合部、導管200與導管220之接合部以 及導管220與導管240之接合部）中，會有加熱時之熱膨脹 量的差、或冷卻時之收縮量的差無法被不定形之陶瓷材料 所吸收而在該接合部發生龜裂之虞。一旦在接合部產生龜 φ 裂’則會有因該龜裂所洩漏之熔融玻璃侵蝕配置於周圍之 隔熱磚的問題。也因此，會有因修復施工所導致之生產性 降低以及設備壽命縮短等的問題。 本發明為了解決上述習知技術的問題點，目的在於提 供—種熔融玻璃搬送設備元件及含有該熔融玻璃搬送設備 元件之玻璃製造裝置，該熔融玻璃搬送設備元件具有陶瓷 結構體，其可防止因在垂直方向上具有中心轴之導管與在 水平方向上具有中心轴之導管之接合部因加熱時之熱膨脹 或冷卻時之收縮而發生龜裂，且即使有熔融玻璃因某些原 5 201029941 因而洩漏的情況，亦難以被侵蝕。 用以解決課題之手段 提供一種熔融玻璃搬送設 本發明為了達成上述目的 備元件，包含： 熔融玻璃用導管結構體，俜 盥笛2道其描 有至少各1條第1導管 ，、第導5，該第1導管在垂直方向上具有中心軸而該第2 導管係與該第1導料通且財平方向上具有巾心軸，且 該第1導管及該第2導管係由麵或翻合金所構成；及 陶变結構體，係配置於前述第j導管及前述第 之周圍； 其特徵在於： 前述陶瓷結構體以相對於整體組成之質量％計係含有 75wt%以上之氧化鍅，且前述氧化锆中，立方晶氧化锆之 比例佔80wt%以上； 前述陶瓷結構體之平均開氣孔率為5~60% ; 前述陶瓷結構體於20~100(TC下之線膨脹係數為 8χ10-6〜12xl〇-Vc。 又，本發明提供一種玻璃製造裝置，其特徵在於包含 本發明之熔融玻璃搬送設備元件。 發明效果 在本發明之熔融玻璃搬送設備元件中，由於鉑或I白合 金製之熔融玻璃導管與配置在該導管周圍之陶瓷結構體的 線膨脹係數大約一致，因而加熱時之熱膨脹量或冷部時之 收縮量的差極小。因此，可防止在垂直方向上具有中心轴 201029941 •之導管與在水平方向上具有中心軸之導管之接合部因加熱 時之熱膨脹或冷卻時之收縮而發生龜裂。更且，即使是溶 融玻璃因某些原因而洩漏的情況下，本發明中之陶瓷結構 體亦難以被侵蝕。 又，以往，防止因加熱時之熱膨脹或冷卻時之收縮而 在導管接合部發生龜裂，以及防止熔融玻璃之洩漏所導致 之陶瓷結構體的侵儀，兩者是難以兼顧的。 然而，含有本發明之熔融玻璃搬送設備元件的坡璃製 \较置由於防止了因加熱時之熱膨脹或冷卻時之收縮而在 導營接合部發生龜裂產生，以及即使是熔融玻璃因某些原 匈而洩漏，陶瓷結構體亦難以被侵蝕，因而具優異可靠性， V長期且安定地製造玻璃。 $式簡單說明 第1圖係顯示減壓脫泡裝置之一構成例的截面圖。 ^ 第2圖係顯示本發明之熔融玻璃搬送設備元件之—構 戍例的截面圖。 第3圖係用於試驗例1之試驗體的截面圖。 第4圖係顯示第3及5圖上部之給電部6附近的立體 第5圖係用於比較例1之試驗體的截面圖。 第6圖係實施在試驗例2中之浸潰試驗的說明圖β t貧施方式】 木發明之實施型態 以下’參照圖面而就本發明進行說明。 7 201029941201029941 VI. Description of the Invention: [^ 明明家名名页3 TECHNICAL FIELD The present invention relates to a molten glass conveying apparatus component applicable to a glass manufacturing apparatus such as a vacuum degassing apparatus, and a component of the molten glass conveying apparatus. Glass manufacturing equipment. [Prior Art J BACKGROUND OF THE INVENTION In a glass manufacturing apparatus such as a vacuum degassing apparatus, a constituent material of a guide glass of molten glass is required to have heat resistance and excellent corrosion resistance to molten glass. As a material that satisfies this requirement, Ming or Ming alloy is currently used (refer to Patent Document 1). Insulating bricks are disposed around the conduit of the molten glass made of platinum or platinum alloy so as to surround the conduit. Since the platinum or platinum alloy constituting the conduit has a different thermal expansion coefficient from the thermal barrier system disposed around the conduit, the difference in the amount of thermal expansion during heating and the difference in the amount of shrinkage during cooling become a problem. In order to absorb the difference in the amount of thermal expansion during heating or the difference in the amount of shrinkage during cooling, a cement-like amorphous ceramic material is filled between the two, so that when temperature changes occur, The person can move relatively slightly. In the prior art, the inventors of the present invention have found that depending on the arrangement of the conduit of the molten glass, When the amorphous ceramic material is filled by light, there is a case where the difference in the amount of thermal expansion during heating or the difference in the amount of shrinkage during cooling may not be completely absorbed. Fig. 1 is a cross-sectional view showing a configuration example of a vacuum degassing apparatus. In the vacuum degassing apparatus 100 shown in Fig. 1, the vacuum degassing tank 130 is housed in the decompression housing 120 so that the long axis thereof is aligned in the horizontal direction. A riser pipe 140 is attached to the lower side of the vacuum degassing tank 130, and a down pipe 150 is attached to the lower side of the other end. In the decompression housing 120, a heat insulating material 160 is disposed around the vacuum degassing tank 130, the riser tube 140, and the down tube 150. The riser pipe 140 is connected to a structure (not shown, for example, a glass dissolution tank) on the upstream side of the molten glass via the conduits 170, 180, and 190. The downcomer 150 is connected to the downstream side structure (not shown, for example, a float bath glass forming apparatus) via the ducts 200, 220, and 240. More specifically, the riser 140 having the central axis in the vertical direction is via a duct 170 having a central axis in the horizontal direction, a duct 180 having a central axis in the vertical direction, and a duct 19 having a central axis in the horizontal direction. It is connected to the structure on the upstream side. On the other hand, the down tube 150 having the central axis in the vertical direction is via a catheter 2 having a central axis in the horizontal direction, a catheter 220 having a central axis in the vertical direction, and a catheter having a central axis in the horizontal direction. 240 is connected to the structure on the downstream side. Further, the riser pipe 140, the down pipe 150, the pipes 17A, 180, 190, 200, 220 and 240 are pipes made of platinum or platinum alloy. 201029941 Although not shown, the insulating brick is disposed so as to surround the above-mentioned platinum or platinum alloy tube, and the platinum or platinum alloy tube and the heat insulating monument are filled with an amorphous ceramic material. In such a structure, only the tubes (140, 150, 180, and 220) having the central axis in the vertical direction alone or only the tubes (170, 190, 200, and 240) having the central axis in the horizontal direction are separately provided. The difference between the amount of thermal expansion of the turned or turned alloy tube and the insulating brick during heating or the amount of shrinkage during cooling can be absorbed by the amorphous ceramic material filled between the two. However, the joint portion of the tube having the central axis in the vertical direction and the tube having the central axis in the horizontal direction (the joint portion of the riser tube 140 and the duct 170, the joint portion of the down tube 150 and the duct 200, the duct 170 and the duct) In the joint portion of 180, the joint portion between the duct 18A and the duct 190, the joint portion between the duct 200 and the duct 220, and the joint portion between the duct 220 and the duct 240, there is a difference in the amount of thermal expansion during heating or contraction during cooling. The difference in the amount cannot be absorbed by the amorphous ceramic material and cracks occur at the joint portion. When the turtle φ is cracked at the joint portion, there is a problem that the molten glass leaked by the crack erodes the heat insulating brick disposed around it. As a result, there are problems such as reduced productivity due to repair work and shortened equipment life. In order to solve the problems of the above-described conventional techniques, the present invention has an object of providing a molten glass conveying apparatus element and a glass manufacturing apparatus including the molten glass conveying apparatus element, wherein the molten glass conveying apparatus element has a ceramic structure, which prevents the cause The joint between the duct having the central axis in the vertical direction and the duct having the central shaft in the horizontal direction is cracked due to contraction during thermal expansion or cooling upon heating, and even if there is molten glass due to some original 5 201029941 The situation is also difficult to be eroded. Provided is a means for solving the problem. The present invention provides a component for the above-mentioned purpose, comprising: a duct structure for molten glass, wherein at least one first conduit is drawn, and the fifth guide is used. The first conduit has a central axis in a vertical direction, and the second conduit is connected to the first guide and has a scarf core in a horizontal direction, and the first conduit and the second conduit are surface-turned or alloyed. And the ceramic structure is disposed in the periphery of the j-th conduit and the first portion, wherein the ceramic structure contains 75 wt% or more of cerium oxide based on the mass% of the entire composition, and the foregoing In the zirconia, the proportion of the cubic zirconia accounts for 80% by weight or more; the average open porosity of the ceramic structure is 5 to 60%; and the ceramic structure is 20 to 100 (the linear expansion coefficient of the TC is 8 χ 10-6) Further, the present invention provides a glass manufacturing apparatus comprising the molten glass conveying apparatus element of the present invention. Advantageous Effects of Invention In the molten glass conveying apparatus component of the present invention, platinum or I is white The molten glass conduit is approximately the same as the linear expansion coefficient of the ceramic structure disposed around the conduit, so that the difference in the amount of thermal expansion during heating or the amount of shrinkage in the cold portion is extremely small. Therefore, it is possible to prevent the central axis from being vertically. 201029941 • The joint between the duct and the duct having the central axis in the horizontal direction is cracked due to thermal expansion during cooling or contraction during cooling. Moreover, even if the molten glass leaks for some reason, In the prior art, it is difficult to be eroded by the ceramic structure. Further, in the prior art, cracking of the ceramic structure due to cracking at the joint portion of the conduit due to shrinkage during thermal expansion or cooling during heating and prevention of leakage of molten glass are prevented. However, it is difficult to achieve both of them. However, the slope glass containing the element of the molten glass conveying apparatus of the present invention is prevented from being cracked at the joint portion of the camp due to thermal expansion during heating or shrinkage during cooling. And even if the molten glass leaks due to some original Hungarian, the ceramic structure is hard to be eroded, and thus has excellent reliability, V length And the glass is made in a stable manner. Fig. 1 is a cross-sectional view showing a configuration example of a vacuum degassing apparatus. ^ Fig. 2 is a cross-sectional view showing an example of a structure of the molten glass conveying apparatus of the present invention. Fig. 3 is a cross-sectional view of the test body used in Test Example 1. Fig. 4 is a perspective view showing the vicinity of the power supply unit 6 in the upper portion of Figs. 3 and 5, and a cross-sectional view of the test body used in Comparative Example 1. Fig. 6 is an explanatory diagram of the impregnation test carried out in Test Example 2, and the present invention is described below with reference to the drawings. 7 201029941
220以及240 ，啊不枣發明之熔融玻璃搬送設備元件之一構 °又’第2圖係相當於第1圖中之導管200、 的部分擴大圖。 於第2圖所示之熔融玻璃搬送設備元件中，熔融玻璃 用導管結構體1 呈現：相對於在垂直方向上具有中心轴之 第導管（以下，稱為「垂直管」）ia，連通有在水平方向上 具有中心軸之2條第2導管（以下，稱為「水平管」）化及 另 1 b的結構。 本發明中之熔融玻璃搬送設備元件只要具有至少各1 條垂直管與連通於垂直管之水平管即可’而非限定於圖示 之態様。舉例而言，可為相對於1條垂直管連通1條水平 管者。再者，亦可為：相對於1條垂直管，1條水平管係連 通於其一端側，且該水平管之另一端侧更與另一條垂直管 相連通者(相當於第1圖中之導管150、200以及220之組 合的結構等）；或者，此種結構更與1條以上之垂直管或水 平管或是其兩者相連通者(相當於第1圖中之導管150、 200、220以及240之組合的結構等）。 再者，本發明中之垂直管並非是嚴格要求其中心軸恰 在垂直方向上，其中心轴亦可是相對於垂直方向呈傾斜 者。有關水平管亦同，並非是嚴格要求其中心軸恰在水平 方向上，其中心軸亦可相對於水平方向呈某種程度傾斜 者。要言之，本發明中之垂直管以及水平管係意圖表示其 等之相對關係，在令其中_導管為垂直管時，與其成交又 關係之導管則為水平管者。 201029941 又’倘若考量前述陶瓷結構體之設置作業性，在垂直 管與水平管之接合部分中，該垂直管與該水平管所呈角度 宜在90±1〇。的範圍内。 在本發明中，由於第1導管與第2導管係用於作為熔 融玻璃之導管，因此要求其構成材料具耐熱性且對於熔融 玻璃具有優異耐蝕性。為此，第1導管與第2導管係由鉑 或是鉑合金(如鉑_金合金、鉑-铑合金及鉑_銥合金)所構成。220 and 240, the one of the molten glass conveying equipment elements of the invention is not shown in the figure, and the second drawing corresponds to a partially enlarged view of the duct 200 in Fig. 1. In the molten glass conveying apparatus element shown in FIG. 2, the duct structure 1 for molten glass exhibits a communication with a duct (hereinafter referred to as a "vertical pipe") ia having a central axis in the vertical direction. Two second ducts (hereinafter referred to as "horizontal tubes") having a central axis and a structure of the other 1 b are provided in the horizontal direction. The molten glass conveying apparatus element in the present invention may have at least one vertical pipe and a horizontal pipe that communicates with the vertical pipe, and is not limited to the illustrated state. For example, it can be one horizontal pipe connected to one vertical pipe. Furthermore, it is also possible that one horizontal pipe is connected to one end side with respect to one vertical pipe, and the other end side of the horizontal pipe is more connected with another vertical pipe (corresponding to FIG. 1) The structure of the combination of the conduits 150, 200, and 220, etc.); or, the structure is more connected to more than one vertical tube or horizontal tube or both (corresponding to the conduits 150, 200 in FIG. 1 , The structure of the combination of 220 and 240, etc.). Further, the vertical pipe of the present invention is not strictly required to have its central axis just in the vertical direction, and its central axis may be inclined with respect to the vertical direction. The same is true for horizontal pipes. It is not strictly required that the central axis is just in the horizontal direction, and the central axis may be inclined to some extent with respect to the horizontal direction. In other words, the vertical pipe and the horizontal pipe system in the present invention are intended to indicate their relative relationship. When the pipe is a vertical pipe, the pipe which is related to the transaction is a horizontal pipe. 201029941 Further, if the installation workability of the ceramic structure is considered, the angle between the vertical pipe and the horizontal pipe should be 90 ± 1 在 in the joint portion between the vertical pipe and the horizontal pipe. In the range. In the present invention, since the first duct and the second duct are used as a duct for melting glass, the constituent material is required to have heat resistance and excellent corrosion resistance to molten glass. Therefore, the first conduit and the second conduit are made of platinum or a platinum alloy (e.g., a platinum-gold alloy, a platinum-rhodium alloy, and a platinum-ruthenium alloy).
構成第1導管與第2導管之鉑或鉑合金宜為使如Preferably, the platinum or platinum alloy constituting the first conduit and the second conduit is such as
Al2〇3、Zr〇2、或ία之金屬氧化物粒子分散在鉑或鉑合 金中而構成之強化鉑。相對於鉑合金（1〇〇質量％)，此等金 屬氧化物粒子之含有量為Q〜G 5質量％，且以q Μ 量％為佳。 . 刀、散於鉑或鉑合金之金屬氧化物粒子 :礙位移或結晶粒成長之效果’機械強度因此提 :料:二Γ方面，與—般之翻或鈾合金相較，強化始 ==低，在垂直管與水平管之接合部中，與配 熱時之熱膨脹量的差或冷卻時之 部容易產生龜裂。為此t伸縮來吸收，因而於該接合 一乎不二:::=r合金與前述陶 生熱膨脹差的切發明。‘、，、膨脹或冷輕之收縮而產 有陶=;:二’第1導管1'與第2導管1b的周圍配置 本發明中之陶究結構體2以相對於整體組成之質量％ 9 201029941 §十係含有75wt%以上之氧化錯，且，在氧化錯中，立方晶 · 氧化錯之比例佔80wt%以上。換言之，本發明係使用立方 晶氧化鍅（為完全安定化之氧化鍅)作為主體，來作為配置於 第1導管與第2導管周圍之隔熱碑。 藉由使立方晶氧化鍅作為主體，在第1導管及第2導 管與配置在其等周圍之陶瓷結構體中，加熱時之熱膨脹量 或冷卻時之收縮量會變得約略相等。其結果，加熱時之熱 膨脹量或冷卻時之收縮量的差變得極小，可防止垂直管與 水平管之接合部因加熱時之熱膨脹或冷卻時之收縮而發生 ® 龜裂。 如以下所示，為完全安定化之氧化鍅的立方晶氧化鍅 於20~10〇〇c下具有與構成該導管之鉑或鉑合金極相近之 線膨脹係數，故而可防止在前述接合部發生龜裂。 銘及銘合金之線膨脹係數：9.5χ1〇-6Λ：〜11Χ1〇-6/1、 立方晶氧化锆之線膨脹係數：8.5xl〇-6/t：~1〇5xl〇-Vc。 又如立方晶氧化錯般之氧化錯對於耐熱性、溶融玻 璃之雜性、以及對於腐錄氣體之雜料甚為優異， 〇 故適於作為配置在第1導管與第2導管(紐融玻璃之導管） 周圍的隔熱碑。 為了達到上述效果，陶瓷結構體於20~1〇〇(rc下之線 膨脹係數為 8xlG.6~12xlG-6A：，且宜為 9xlG·6〜11χ1〇-6/ C ’ 更宜為 9.5x1〇-6~i〇.5x1(TVc。 然而’麵或鉑合金之線膨脹係數會因組成而或多或少 有所差異，宜因應第1導管與第2導管所使之鉑或鉑合金 10 201029941 佳 的線膨脹係數來選擇料結構趙之線膨脹絲。具體而 言姻結構體於20400(^下之線膨脹係數宜為構成第^ 導管與第2導管之合金於2(M⑻叱下之線膨服係 數的删以内，且以鳩以内為更佳，且以偷x内又更The metal oxide particles of Al2〇3, Zr〇2, or ία are dispersed in platinum or a platinum alloy to form a reinforcing platinum. The content of these metal oxide particles is preferably from 5 to 5 % by mass based on the platinum alloy (1% by mass), and is preferably q Μ % by weight. Knife, metal oxide particles scattered in platinum or platinum alloy: the effect of displacement or crystal grain growth 'Mechanical strength is therefore raised: material: in terms of diterpene, compared with the general turning or uranium alloy, the strengthening begins == Low, in the joint portion between the vertical pipe and the horizontal pipe, the difference in the amount of thermal expansion at the time of heat distribution or the portion at the time of cooling is likely to cause cracks. For this reason, t is stretched and absorbed, so that the joint is almost the same: the::=r alloy is inferior to the heat expansion of the ceramic. ',,, expansion or cold light contraction produces pottery =;: two '1st conduit 1' and the second conduit 1b are arranged around the second structure 1b of the present invention with a mass % relative to the overall composition 9 201029941 § Ten series contain 75 wt% or more of oxidization error, and in the oxidation error, the proportion of cubic crystal oxidation error accounts for 80% by weight or more. In other words, in the present invention, cubic yttrium oxide (which is a completely stabilized cerium oxide) is used as a heat insulating monument disposed around the first conduit and the second conduit. By using cubic cerium oxide as a main component, the amount of thermal expansion during heating or the amount of shrinkage during cooling in the first and second conduits and the ceramic structure disposed around the first conduit and the second conduit become approximately equal. As a result, the difference in the amount of thermal expansion during heating or the amount of shrinkage during cooling becomes extremely small, and it is possible to prevent the joint portion between the vertical pipe and the horizontal pipe from being cracked due to thermal expansion during heating or shrinkage during cooling. As shown below, the cubic cerium oxide which is completely stabilized cerium oxide has a linear expansion coefficient close to that of the platinum or platinum alloy constituting the catheter at 20 to 10 〇〇c, so that it can be prevented from occurring at the joint portion. Cracked. Linear expansion coefficient of Ming and Ming alloy: 9.5χ1〇-6Λ: ~11Χ1〇-6/1, linear expansion coefficient of cubic zirconia: 8.5xl〇-6/t:~1〇5xl〇-Vc. Oxidation error, such as cubic oxidation, is excellent for heat resistance, miscibility of molten glass, and miscellaneous materials for rotting gas, so it is suitable as a first conduit and a second conduit (neutral glass). The conduit is insulated around the monument. In order to achieve the above effect, the ceramic structure is 20~1〇〇 (the linear expansion coefficient of rc is 8xlG.6~12xlG-6A: and preferably 9xlG·6~11χ1〇-6/ C ' is more suitable for 9.5x1 〇-6~i〇.5x1(TVc. However, the coefficient of linear expansion of 'face or platinum alloy will vary more or less depending on the composition. It should be made of platinum or platinum alloy 10 according to the first conduit and the second conduit. 201029941 Good linear expansion coefficient to select the material structure Zhao Zhixian expansion wire. Specifically, the linear expansion coefficient of the marriage structure is 20400 (^ is the alloy of the second conduit and the second conduit is 2 (M(8) The coefficient of the line expansion factor is deleted, and it is better to use the inside of the line, and it is better to steal the inside of x.
❹ 為了達成上述之線膨脹係數，陶竞結構體所含之氧化 錯需為75㈣以上，且須使立方晶氧化錯於其中所伯之比 例在獅％以上。陶究結構體所含之氡化錯中，立方曰氧 化錯之比例宜佔85wt%以上，且更宜為9〇_以上。日日 f發明之喊結構體2含有安㈣，該安定化劑係為 了使乳化結成為立方晶氧化錯(安定化之氧化錯）以作為氧 化結除外之殘餘部份而添加者。再者，殘餘部份可包含不 可避免之不純物等。此外，只要不影響本發明，於本發明 之陶究結構體2中，可含有氧化錯與安定劑以外之並他成 分合計至8她左右。作為上述其他成分，舉例而言，可列 舉如為提高燒結性而添加之ΜΑ或Mg〇，且可含有此等 成分至合計5wt%左右。 _作為钱劑，係有氧化紀、氧化飾、氧化鎮、氧化約、 氧化铒等，但由對於㈣玻璃具優異耐紐優異、容易取 得及於高溫下長時間亦保持安定等理由來看，宜為氧化纪 與氧化飾。 含有選自氧化釔與氧化鈽所構成群組中之至少一者作 為安定劑時，兩者之總含有率宜為6wt%以上，且更宜為 8wt%以上，尤宜為1〇wt%以上。 11 201029941 然而，倘若安定劑之添加量過多，將有難以燒結及原 料費提高等問題。為此，兩者之總含有率宜為25wt%以下， 且更宜為20wt%以下。 陶瓷結構體中之氧化锆含量雖因安定劑之添加量而有 所差異，但為使線膨脹係數在預定範圍内而為75wt%以 上，且宜為80wt%以上，更宜為85wt%以上。另一方面， 由於兼顧到安定劑之添加量，陶瓷結構體中之氧化锆含有 量之上限為94wt%左右。 本發明之陶瓷結構體的平均開氣孔率為5~60%。雖然 本發明之陶瓷結構體對於熔融玻璃具有優異之耐蝕性，倘 若平均開氣孔率超過60%，對於熔融玻璃之耐蝕性將降 低。另一方面，倘若平均開氣孔率未滿5%，陶瓷結構體之 财熱衝擊性將降低。再者，由於熱容量會增加，#或翻合 金製之第1導管la及第2導管lb與陶瓷結構體2之間， 容易在加熱時之熱膨脹或冷卻時之收縮的時間點產生不一 致，而有垂直管之第1導管la與水平管之第2導管lb的 接合部會有發生龜裂的疑慮。此外，加熱或冷卻所需時間 亦變長。 本發明之陶瓷結構體的平均開氣孔率宜為25〜60%， 更宜為30〜50%，特宜為35~45%。 然而，一旦提高平均氣孔率，陶瓷結構體内部會產生 源自導管之熱難以傳導的部位，而妨礙部分陶瓷結構體之 熱膨脹，並造成導管之一部分負擔的情況。因此，在不造 成導管負擔之情況，或進一步提高耐蝕性的情況下，陶瓷 201029941 • 結構體之平均開氣孔率宜為5〜35%，更宜為8~30%，特宜 為 10~25%。 陶瓷結構體之平均開氣孔率可藉由利用阿基米得法或 水銀孔隙計(Porosimeter)之測定方式來求得。 本發明之陶究結構體可因應部位而具#不同的開氣孔 率。舉例而言，藉由使面對第j導管與第2導管之部位比 其他部位之職孔率為低，可提高對於熔融玻璃之耐健。 在第2射，第1導管la及第2導管lb與陶莞結構 Φ 體2之間設有間隙3。 >上所述，在本發明巾，加_之_脹量或冷卻時 之收縮量’在第1導管1a及第2導管化與配置在其等周 園之陶兗結構體2上約略相等。然而，由於構成第ι導管 U與第2導管11?之翻或麵合金與構成喊結構體2之氧化 錄的熱傳導性不同，依加熱條件或冷卻條件而定，在加熱 時之熱膨脹或冷卻時之收縮的時間點上，兩者之間會發生' 不-致的情況’而在垂直管之第i導管u與水平管之第2 ’導管lb的接合部會有發生龜裂的疑慮。 藉由在第1導管U及第2導管lb與陶曼結構體2之 間設置間隙3,可吸收兩者在加_之_脹、或冷卻時之 收縮的時間點之間的不—致，進而防止接合部發生龜裂。 又，在本發明中，由於加熱時之熱膨腸量或冷卻時之 收縮量，在第1導管1a及第2導管lb與配置在其等周圍 之陶€結構體2上約略相等，因而不需於間隙3填充不定 13 201029941 在以第1導管la與第2導管lb之最大徑為r(mm)時， 間隙3之寬度d宜為0.5mm以上' 0·02χ r (mm)以下。間隙 3之寬度d未滿〇.5mm時，會有無法充分吸收加熱時之熱 膨脹或冷卻時之收縮之時間點不一致的疑慮。另一方面， 在間隙3之寬度d大於0.02xr(mm)時，會有膨脹後兩者之 間殘留過大間隙，而使第1導管la與第2導管lb因通過 内部之熔融玻璃而變形等問題。 又，前述最大徑r宜為60mm以上。其理由在於，最 大徑r為60mm以上時，該導管之剛性變得難以確保，而 可發揮本發明之效果(防止在接合部之龜裂的產生），甚為理 想的緣故。 又，雖然前述最大徑r係因應該等導管所使用之部位 而有所不同，但在第1圖所示之上昇管14〇、下降管15〇 以及連接於此等之導管170、180、190、200、220或240 之情況下’ 一般為120~400mm。 間隙3之寬度d(mm)更宜為l~3mm，尤宜為 1.5~2.5mm。 由於立方晶氧化鍅為高價的材料，由成本面來看，配 置在第1導管與第2導管周圍之陶瓷結構體以止於所需之 最小限度為佳。具體而言，宜配置前述陶瓷結構體（以下， 亦有稱為「第1陶瓷結構體」的情況)後，於其外侧配置一 般之隔熱碑作為第2陶瓷結構體。在此情況下，作為第2 陶瓷結構體，可使用主體係選自於由鋁、鎂、鍅及矽所構 成群組中之至少一種的隔熱磚。 201029941 用作第2陶瓷結構體之隔熱碑的具體例， ^ 化石夕/氧化銘質隔熱碑、氧化錯質隔熱磚及°彳舉如氧 _ 錢質隔執確 等。市售品則可列舉有sp_15(曰之丸 … LBK3000(Is〇lite工業社製）等。 ”社製）及❹ In order to achieve the above-mentioned coefficient of linear expansion, the Otto structure contained in the Tao Jing structure should be 75 (four) or more, and the cubic oxidation should be erroneous in the proportion of the above. Among the enthalpy errors contained in the ceramic structure, the proportion of cubic oxidization error should preferably be more than 85 wt%, and more preferably 9 〇 _ or more. The shrine structure 2 of the invention f contains an (4), and the stabilizer is added to make the emulsified junction a cubic oxidization error (stabilized oxidative error) as a residual portion other than the oxidized junction. Furthermore, the residual portion may contain unavoidable impurities and the like. Further, as long as the present invention is not impaired, the ceramic structure 2 of the present invention may contain a total of other components than the oxidative error and the stabilizer. As the other components, for example, ruthenium or Mg 添加 added to improve the sinterability may be mentioned, and these components may be contained in an amount of about 5 wt% in total. _ As a money agent, there are oxidized period, oxidized decoration, oxidized town, oxidized about, yttrium oxide, etc., but it is considered to be excellent for the excellent resistance to (N) glass, easy to obtain, and stable for a long time at high temperatures. It should be oxidized and oxidized. When at least one selected from the group consisting of cerium oxide and cerium oxide is used as a stabilizer, the total content of the two is preferably 6% by weight or more, and more preferably 8% by weight or more, and particularly preferably 1% by weight or more. . 11 201029941 However, if the amount of stabilizer added is too large, there will be problems such as difficulty in sintering and increase in raw material costs. For this reason, the total content of both is preferably 25 wt% or less, and more preferably 20 wt% or less. The zirconia content in the ceramic structure differs depending on the amount of the stabilizer added, and is 75 wt% or more, and more preferably 80 wt% or more, more preferably 85 wt% or more, in order to make the coefficient of linear expansion within a predetermined range. On the other hand, since the addition amount of the stabilizer is also taken into consideration, the upper limit of the zirconia content in the ceramic structure is about 94% by weight. The ceramic structure of the present invention has an average open porosity of 5 to 60%. Although the ceramic structure of the present invention has excellent corrosion resistance to molten glass, if the average open porosity exceeds 60%, the corrosion resistance to molten glass is lowered. On the other hand, if the average open porosity is less than 5%, the thermal shock resistance of the ceramic structure will be lowered. Further, since the heat capacity is increased, the first pipe la and the second pipe lb made of the alloy and the ceramic structure 2 are easily inconsistent with each other at the time of thermal expansion at the time of heating or contraction at the time of cooling. There is a fear that cracks may occur in the joint portion between the first pipe 1a of the vertical pipe and the second pipe 1b of the horizontal pipe. In addition, the time required for heating or cooling is also prolonged. The ceramic structure of the present invention preferably has an average open porosity of from 25 to 60%, more preferably from 30 to 50%, particularly preferably from 35 to 45%. However, once the average porosity is increased, a portion of the ceramic structure which is hard to conduct from the heat of the conduit is generated, which hinders thermal expansion of a part of the ceramic structure and causes a part of the conduit to be burdened. Therefore, in the case of not causing the burden on the catheter, or further improving the corrosion resistance, the ceramic 201029941 • the average open porosity of the structure should be 5 to 35%, more preferably 8 to 30%, particularly preferably 10 to 25 %. The average open porosity of the ceramic structure can be determined by a measurement using an Archimedes method or a mercury porosimeter. The ceramic structure of the present invention has a different open porosity depending on the location. For example, by making the position of the portion facing the j-th conduit and the second catheter lower than that of other portions, the durability against molten glass can be improved. In the second shot, a gap 3 is provided between the first duct 1a and the second duct 1b and the pottery structure Φ body 2. > As described above, in the towel of the present invention, the amount of shrinkage during the expansion or cooling is approximately equal to that of the first conduit 1a and the second conduit and the ceramic structure 2 disposed on the circumference of the napkin. . However, since the thermal conductivity of the turned-to-face alloy constituting the first illuminating duct U and the second duct 11 is different from the oxidizing recording constituting the shouting structure 2, depending on heating conditions or cooling conditions, during thermal expansion or cooling during heating At the time of contraction, a 'no-in case' occurs between the two, and there is a fear that cracks may occur in the joint portion between the i-th conduit u of the vertical pipe and the second 'catheter lb of the horizontal pipe. By providing the gap 3 between the first duct U and the second duct 1b and the Tauman structure 2, it is possible to absorb the inconsistency between the time when the two are contracted during expansion or cooling. Further, cracking of the joint portion is prevented. Further, in the present invention, the amount of thermal swell at the time of heating or the amount of contraction during cooling is approximately equal to the first catheter 1a and the second catheter lb and the ceramic structure 2 disposed around it, and thus When the maximum diameter of the first conduit la and the second conduit lb is r (mm), the width d of the gap 3 is preferably 0.5 mm or more '0·02 χ r (mm) or less. When the width d of the gap 3 is less than 55 mm, there is a concern that the time point at which the thermal expansion at the time of heating or the contraction at the time of cooling is not sufficiently absorbed may be inconsistent. On the other hand, when the width d of the gap 3 is larger than 0.02 xr (mm), an excessive gap remains between the two after expansion, and the first duct 1a and the second duct 1b are deformed by the molten glass passing through the inside. problem. Further, the maximum diameter r is preferably 60 mm or more. The reason is that when the maximum diameter r is 60 mm or more, the rigidity of the catheter is difficult to secure, and the effect of the present invention (prevention of occurrence of cracks in the joint portion) is particularly desirable. Further, although the maximum diameter r is different depending on the portion to be used for the catheter, the riser 14〇, the downcomer 15〇, and the conduits 170, 180, and 190 connected thereto are shown in Fig. 1 . In the case of 200, 220 or 240, it is generally 120~400mm. The width d (mm) of the gap 3 is preferably from 1 to 3 mm, particularly preferably from 1.5 to 2.5 mm. Since cubic cerium oxide is a high-priced material, it is preferable from the viewpoint of cost that the ceramic structure disposed around the first conduit and the second conduit is preferably the minimum required. Specifically, it is preferable to arrange the ceramic structure (hereinafter also referred to as "the first ceramic structure"), and then arrange a general heat insulating monument as the second ceramic structure on the outer side. In this case, as the second ceramic structure, a heat insulating brick whose main system is selected from at least one of a group consisting of aluminum, magnesium, lanthanum and cerium may be used. 201029941 As a specific example of the thermal insulation monument of the second ceramic structure, ^ Fossil eve / oxidized inscription heat insulation monument, oxidized error insulation brick and ° 彳 如 如 氧 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Commercially available products include sp_15 (曰之丸... LBK3000 (made by Is〇lite Industrial Co., Ltd.), etc.)
在第1陶竟結構體之外侧配置第2陶究結構 1陶兗結構體之厚度宜為15贿以上，若第i陶奸構體 之厚度未滿15職，第i喊結構體在加熱時之熱膨:量或 冷卻時之收縮量會被第2陶瓷結構體所妨礙，因而在第^ 導管及第2導管她置在其之陶£結構體之間，加熱 時之熱膨脹量或冷卻時之收縮量的差會變大，而容易在第\ 導管與第2導管之接合部發生龜裂。 另一方面，在以第1導管la與第2導管比之最大徑 為r(mm)時，由成本面、施工容易度等理由來看第工陶 瓷結構體之厚度宜為0.3xr(mm)以下。 第1陶瓷結構體之厚度更宜為15~120mm，且尤宜為 30~80mm。 本發明之玻璃製造裝置係使用本發明之炼融玻璃搬送 設備元件作為熔融玻璃之流路的至少一部份。作為本發明 之玻璃製造裝置的一例’可列舉如使用本發明之熔融玻璃 搬送設備元件之減壓脫泡裝置作為溶融玻璃之流路的至少 一部份。在第1圖所示之減壓脫泡裝置為本發明之玻璃製 造裝置的情況下，則包含本發明之熔融玻璃搬送設備元件 來作為上昇管140、導管170、180及190所構成之組合的 至少一部份，或是作為下降管150、導管200、220及240 15 201029941 所構成之組合的至少一部份，或者是作為上述兩者。 本發明之玻璃製造裝置只要使用本發明之熔融玻璃搬 送設備元件作為熔融玻璃之流路的至少一部份即可，而未 特別限定，亦可為包含上流侧之玻璃溶解槽或下流侧之板 玻璃成形裝置(例如浮浴)者。 實施例 以下，將藉本發明之實施例作更進一步詳細說明，但 本發明並非偈限於該等實施例作解釋。 (試驗例1) 第3圖係試驗例1所用試驗體之截面圖。在試驗例1 中，將陶瓷結構體2配置於強化鉑製之中空管lc周圍，且 在該陶瓷結構體2周圍配置有第2陶瓷結構體4的狀態下 通電加熱該中空管lc，藉此評估該中空管lc有無發生變形 或破裂發生。 作為中空管lc，使用於外徑60mm、長度300mm、厚 度0.5mm之強化鉑（鉑-铑合金(鉑90質量％、铑10質量％) 中分散有Zr02粒子0.16質量％者。使用於20~l〇〇〇°C下之 線膨脹係數為10.3xl(T6/°C)製之中空管。在中空管lc之― 端起算200mm之位置上，藉由TIG(tungsten inert gas ;鹤 惰性氣體)熔接以固定寬度15mm、厚度1.2mm之凸緣5。 再者，如第4圖所示，在中空管lc之上端則熔接有通電加 熱用之給電部6。 雖第4圖中未顯示，但中空管lc之下端亦熔接有通電 加熱用之給電部6 »又，凸緣5以及給電部6為強化鉑（銘_ 201029941 10質量％)中分散有ZK)2粒子0.16 铑合金(鉑90質量％、錯 質量％者）。 + d 結制2仙氧化錯製 成. '氧化錯中，於氧化錯與氧聽之總量，添加有 87 /%之氧化紀作為安定劑；氧化狀含有率為 —在氧化財，立方晶氧化錯所佔比例為9細％ ; 二’陶是結構體2為内徑X外徑X長度=61_50_<In the outer side of the first ceramic structure, the second ceramic structure is arranged. The thickness of the ceramic structure is preferably 15 bribes. If the thickness of the i-th medicinal structure is less than 15 jobs, the i-th structure is heated. Thermal expansion: the amount of shrinkage during cooling or cooling is hindered by the second ceramic structure, so that between the second conduit and the second conduit, the amount of thermal expansion or heating during heating The difference in the amount of shrinkage is increased, and it is easy to cause cracking at the joint portion between the first conduit and the second conduit. On the other hand, when the maximum diameter of the first conduit la and the second conduit is r (mm), the thickness of the ceramic-ceramic structure is preferably 0.3 x r (mm) from the viewpoints of cost surface, ease of construction, and the like. the following. The thickness of the first ceramic structure is preferably 15 to 120 mm, and particularly preferably 30 to 80 mm. The glass manufacturing apparatus of the present invention uses the smelting glass conveying apparatus element of the present invention as at least a part of the flow path of the molten glass. As an example of the glass manufacturing apparatus of the present invention, a vacuum degassing apparatus using the molten glass conveying apparatus element of the present invention is used as at least a part of the flow path of the molten glass. In the case where the vacuum degassing apparatus shown in Fig. 1 is the glass manufacturing apparatus of the present invention, the molten glass conveying apparatus element of the present invention is included as a combination of the riser 140 and the conduits 170, 180, and 190. At least a portion, or at least a portion of a combination of downcomers 150, conduits 200, 220, and 240 15 201029941, or both. In the glass manufacturing apparatus of the present invention, the molten glass conveying device element of the present invention may be used as at least a part of the flow path of the molten glass, and is not particularly limited, and may be a glass dissolving tank or a downstream side plate including the upstream side. A glass forming device (such as a float bath). EXAMPLES Hereinafter, the examples of the present invention will be described in further detail, but the present invention is not construed as being limited to the examples. (Test Example 1) Fig. 3 is a cross-sectional view of the test body used in Test Example 1. In the test example 1, the ceramic structure 2 is placed around the hollow tube lc made of reinforced platinum, and the hollow tube lc is electrically heated while the second ceramic structure 4 is placed around the ceramic structure 2, Thereby, it is evaluated whether or not the hollow tube lc is deformed or broken. The hollow tube lc is used in a reinforcing platinum (platinum-rhodium alloy (platinum 90% by mass, 铑10% by mass) having a diameter of 60 mm, a length of 300 mm, and a thickness of 0.5 mm, and 0.16 mass% of Zr02 particles are dispersed in the hollow tube lc. a hollow tube made of a linear expansion coefficient of 10.3xl (T6/°C) at ~l〇〇〇°C. At the position of 200mm from the end of the hollow tube lc, by TIG (tungsten inert gas; The inert gas is welded to fix the flange 5 having a width of 15 mm and a thickness of 1.2 mm. Further, as shown in Fig. 4, the power supply portion 6 for electric heating is welded to the upper end of the hollow tube lc. Not shown, but the lower end of the hollow tube lc is also welded to the power supply unit 6 for electric heating. Further, the flange 5 and the power supply unit 6 are made of reinforced platinum (Ming_201029941 10% by mass) dispersed in ZK) 2 particles 0.16 铑Alloy (platinum 90% by mass, wrong mass%). + d is made into 2 oxidized and wrongly made. 'Oxidation error, the total amount of oxidation and oxygen is added, 87/% of the oxidized period is added as a stabilizer; the oxidation content is - in the oxidation, cubic The proportion of oxidization error is 9% by volume; the second 'Tao is the structure 2 is the inner diameter X outer diameter X length = 61_50_<
=:之中空圓筒形(將朝縱方向切割成二之半圓筒形狀 1予=裝施4)，其於之線雜雜為Μ X 。又’就陶瓷結構體2之平均氣孔率而言，已針對 約8%與約40%之2種推耔4毯 構體2之職有^:^^巾”^喊結 再者’如第3圖所示，雖然陶統構體2呈現被2個 給電部6挾持之狀態，但陶竞結構艘2之下端側係與給電 部6呈機械式固定（未圖示）。 在陶究結構體2之外側，配置有市售之氧化石夕/氧化鋁 質隔熱碑(S!M5(日之丸窯業社製))作為第2喊結構體心 以金屬製之框材繫緊第2喊結構體4周圍所成之物 作為試驗體。 -邊藉由配置在凸緣5附近之熱電對(未圖示)控制溫 度，同時實施溫錢環試驗(使將電部6來通電加熱中: 管1c，以及將該中空管lc予以冷卻，反覆進行兩者)、、。又二 以昇溫速度200°C/小時進行加熱後，在14〇〇<t下保持3 時，其後，自然放冷至200。〇為止，如此反覆進行2〇次^ 17 201029941 又’在溫度循環試驗過程中，中空管le與陶找構體2在 轴方向的膨脹與㈣除了已與給電部6作機械式固定之下 端側及設有凸緣5之部位外，均呈可自由脹縮的情況。 在/凰度擴環試驗後，將試驗體予以解體並確認中空管 lc之狀n，在±述2種平均氣孔率之喊結構體的情況 下s未確為到中空f lc之變形或破裂。然而，在平均氣 孔率約娜之喊結構體中，於凸緣5之錢部正下方之 #伤係可見圓弧狀敵紋。再者配置在中空管&周圍之=: The hollow cylindrical shape (will be cut in the longitudinal direction into a half-cylindrical shape 1 to = 4), and the line miscellaneous is Μ X . In addition, as far as the average porosity of the ceramic structure 2 is concerned, there are two types of push-pull 4 blanket body 2 for about 8% and about 40%. ^:^^ towel "^ shouting and then" In the figure 3, although the ceramic structure 2 is in a state of being held by the two power supply units 6, the lower end side of the Taojing structure ship 2 is mechanically fixed to the power supply unit 6 (not shown). On the other side of the body 2, a commercially available oxidized stone oxide/alumina heat-insulating monument (S!M5 (made by Nippon Maru Co., Ltd.)) is placed as the second shouting structure. The metal frame is fastened to the second. The object formed around the structure 4 is used as a test body. - The temperature is controlled by a thermoelectric pair (not shown) disposed in the vicinity of the flange 5, and a temperature ring test is performed (the electric portion 6 is energized and heated). The tube 1c is cooled and the hollow tube lc is cooled, and both of them are repeatedly turned on. After heating at a temperature increase rate of 200 ° C / hour, the temperature is maintained at 4 ° < t, and thereafter Naturally let cool to 200. So far, so repeated 2 times ^ 17 201029941 And 'in the temperature cycle test process, the hollow tube le and the ceramic body 2 expansion in the axial direction and (4) in addition to Both the lower end side of the mechanical fixing portion and the portion provided with the flange 5 are freely expandable and contractible. After the / diagonal expansion test, the test body is disassembled and the hollow tube lc is confirmed. In the case of the shunt structure of the two kinds of average porosity, s is not confirmed to be deformed or broken to the hollow f lc. However, in the average porosity of the screaming structure, at the flange 5 The #伤系 directly below the money department can see the arc-shaped enemies. It is placed around the hollow tube &
上述2種平均氣孔率之喊結構體的情況，外觀幾乎都未 有變化a此，倘若平均氣孔率為5〜3外，則自導管至陶 竞結構體内部之熱傳導變得特別容易，因而可防止對導管 造成負擔。 (比較例1)In the case of the above-mentioned two kinds of average porosity ratio structures, the appearance is almost unchanged. If the average porosity is 5 to 3, heat conduction from the inside of the duct to the interior of the Tao Jing structure becomes particularly easy. Prevent the burden on the catheter. (Comparative Example 1)
第5圖係比較例丨中所使用之試驗體的截面圖。比較 例1所使用之試驗體中，係在中空管lc周圍設置約3〇賴 之間隙3來配置試驗例丨_作為第2喊結構體$使用之 市售氧化碎/氧化紹質隔熱碑(sp_15(日之丸窯業社製)），以 取代在中空管lc周圍配置陶瓷結構體2的方式，接著，於 該間隙3中填充以水混合攪拌中空粒子之鋁灰泥所成之物 至無間隙’而形成不㈣之陶竟材料之層，除此之外，以 與試驗例1相同之順序實施溫度循環試驗。 在溫度循環試驗後，於將試徐體予以解艘並碟削 管k之狀態’結果，在中空管以接有凸緣5的部名 生微細的破裂。此外，配置在中空管11圍之紹灰泥為 18 201029941 如同固化後破裂般，分裂成數個碎片。 (試驗例2) 使用與試驗例i之陶究結構體2相同的材料， 均氣孔率為8%與33%與54%之3種試驗樣品(形狀= 形（直徑20mm、高度90mm))。如第6 ® _ 5 0圖所不，將此試驗 品1〇實施浸潰試驗，即’在大氣中浸潰於已裝入銘 2〇内之熔融玻璃3_酸玻璃）中。此時，祕玻Fig. 5 is a cross-sectional view of a test body used in a comparative example. In the test body used in Comparative Example 1, a gap of 3 was placed around the hollow tube lc to arrange a test example. As a second shattering structure, the commercially available oxidized ash/oxidized heat insulation was used. In place of the ceramic structure 2 disposed around the hollow tube lc, the gap 3 is filled with aluminum stucco which is mixed with water and agitated hollow particles. A temperature cycle test was carried out in the same manner as in Test Example 1 except that the layer of the ceramic material was not formed to have no gaps. After the temperature cycle test, the test piece was unwrapped and the tube k was cut. As a result, the hollow tube was finely broken by the name of the portion to which the flange 5 was attached. In addition, the stucco disposed around the hollow tube 11 is 18 201029941. When it is broken after solidification, it is split into several pieces. (Test Example 2) Three kinds of test samples (shape = shape (diameter: 20 mm, height: 90 mm)) having the same porosity and having a porosity of 8% and 33% and 54% were used as the material of the ceramic structure of the test example i. This test article was subjected to an impregnation test, i.e., "immersed in the atmosphere in molten glass 3 - acid glass which has been filled in the inside", as shown in Fig. 6 ® _ 5 0. At this time, secret glass
溫度為Μ50Χ：，試驗樣品1〇之浸潰時間為觸*時。^ 持時間結束後，將試驗樣品10取出並ό _ 、” 目‘、、、放冷。其後，將 試驗樣品以縱向切斷並確認截面之肤能 β t。無蝓疋任一試驗 樣品，玻璃皆未侵人至㈣，而確保了耐紐性，並維持 初期之形狀。然而，在平均氣孔率為54%之試驗樣品中，、 3«侵入外周部之-部份’ _部㈣曼表面可見剝離。因 此’平均氣孔率為5~35%時，耐餘性特別提高。 (比較例2) 使試驗例1中作為第2陶瓷結構體4使用之市售氧化 石夕/氧化銘f隔熱碍(叫5(日之丸黧業社製))亦以同様之順 序浸潰於熔融玻璃内。隔熱磚係因侵蝕而完全崩壞，而無 法觀察截面狀態。 (應用例1) 在第1圖所示之減壓脫泡裝置中，將上昇管14〇、導 管170、180及190所構成之組合、以及下降管15〇及導管 200、220、240所構成之組合作為本發明之熔融玻璃搬送設 備元件而構成之。 19 201029941 在強化鉑製(使0.16質量％iZr〇2粒子分散於鉑—铑合 金(鉑90質量％、铑1〇質量％)者。於20〜1000¾下之線膨 脹係數為10.3χ10·6Λ：。）之上昇管14〇、下降管150、導管 170、180、190、200、220及240(截面形狀：圓形、外徑： 180mm)周圍，將以立方晶氧化锆作為主體之第i陶瓷結構 體(相對於整體組成，氧化锆含有比例為88wt%，且在氧化 锆中’立方晶氧化锆所佔比例為95wt%，更含有12wt%之 氧化釔作為安定劑，平均開氣孔率為12%或35%，於 20~1000°C下之線膨脹係數為9.8xlO_6/°C，厚度為45mm) 與管之間隔開1.5mm之間隙來配置。 在第1陶瓷結構體之外侧，配置作為第2陶瓷結構體 之氧化矽/氧化鋁質隔熱磚。 在第1圖所示之減壓脫泡裝置之上流側配置熔解槽， 並在下流側配置浮浴，以製造板玻璃。每一垂直管與水平 管之接合部均未發生龜裂，而可安定地製造玻璃。 產業上之可利用性 含有本發明之熔融玻璃搬送設備元件的玻璃製造裝置 具有可防止導管接合部因加熱時之熱膨脹或冷卻時之收縮 而發生龜裂’此外’即使發生熔融玻璃洩漏的狀況，陶瓷 結構體難以被侵蝕，可靠度甚優異，而可長期且安定地製 造玻璃等優點，因此在產業上極為有用。 又，於此援引已於2008年12月11日提申之日本專利 申請案第2008-315710號之說明書、申請專利範圍、圖式 以及摘要之全部内容’並納入作為本發明說明書之揭示内 201029941 一 容。 r：圖式簡單說明3 第1圖係顯示減壓脫泡裝置之一構成例的截面圖。 第2圖係顯示本發明之熔融玻璃搬送設備元件之一構 成例的截面圖。 第3圖係用於試驗例1之試驗體的截面圖。 第4圖係顯示第3及5圖上部之給電部6附近的立體 圖。 m ¥ 第5圖係用於比較例1之試驗體的截面圖。 . 第6圖係實施在試驗例2中之浸潰試驗的說明圖。 【主要元件符號說明】 1 熔融玻璃搬送設備元件 120 減壓殼體 la 第1導管(垂直管） 130 減壓脫泡槽 lb 第2導管(水平管） 140 上昇管 lc 中空管 150 下降管 2 陶瓷結構體 160 隔熱材 3 間隙 170 導管 4 第2陶瓷結構體 180 導管 5 凸緣 190 導管 6 給電部 200 導管 10 試驗樣品 220 導管 20 坩鍋 240 導管 30 炼融玻璃 d 寬度 100 減壓脫泡裝置 21The temperature is Μ50Χ: when the test sample has a immersion time of 1 为. ^ After the end of the holding time, the test sample 10 is taken out and ό _, "目目", ,, and let cool. Thereafter, the test sample is cut longitudinally and the skin energy of the cross section is confirmed. The glass is not invaded to (4), and the weather resistance is ensured and the initial shape is maintained. However, in the test sample with an average porosity of 54%, 3« invades the outer part of the part - part (4) When the average porosity is 5 to 35%, the durability is particularly improved. (Comparative Example 2) Commercially available oxidized oxide used as the second ceramic structure 4 in Test Example 1 f. Insulation (called 5 (made by Nippon Maru Co., Ltd.)) was also immersed in the molten glass in the order of the same. The heat-insulating bricks completely collapsed due to erosion, and the cross-sectional state could not be observed. In the vacuum degassing apparatus shown in Fig. 1, a combination of the riser 14A, the conduits 170, 180, and 190, and the combination of the downcomer 15 and the conduits 200, 220, and 240 are used as the present invention. The invention relates to a molten glass conveying device component. 19 201029941 In strengthening platinum (making 0.16 mass% iZr 2 particles are dispersed in a platinum-rhodium alloy (platinum 90% by mass, 铑1〇% by mass). The linear expansion coefficient at 20~10003⁄4 is 10.3χ10·6Λ:)) riser 14〇, downcomer 150, conduit 170, 180, 190, 200, 220, and 240 (cross-sectional shape: circular, outer diameter: 180 mm), the i-th ceramic structure with cubic zirconia as the main body (relative to the overall composition, the proportion of zirconia is 88wt%, and the proportion of 'cubic zirconia in zirconia is 95wt%, and further contains 12wt% cerium oxide as stabilizer. The average open porosity is 12% or 35%, at 20~1000°C. The linear expansion coefficient is 9.8×10 −6 /° C. and the thickness is 45 mm. The gap is 1.5 mm apart from the tube. On the outer side of the first ceramic structure, the cerium oxide/alumina spacer as the second ceramic structure is disposed. The hot brick is disposed on the flow side of the vacuum degassing apparatus shown in Fig. 1, and the floating bath is disposed on the downstream side to manufacture the plate glass. The joint between each vertical tube and the horizontal tube is not cracked. , and glass can be stably produced. Industrial applicability contains the molten glass of the present invention The glass manufacturing apparatus of the conveyance equipment element is capable of preventing cracking of the duct joint portion due to thermal expansion during heating or shrinkage during cooling. In addition, even if molten glass leaks, the ceramic structure is hard to be eroded, and the reliability is excellent. However, it is extremely useful in the industry for the long-term and stable manufacture of glass, and the specification of the Japanese Patent Application No. 2008-315710, filed on December 11, 2008, The entire contents of the drawings and abstracts are incorporated herein by reference as the disclosure of the disclosure of the specification. r: Simple description of the drawings 3 Fig. 1 is a cross-sectional view showing a configuration example of a vacuum degassing apparatus. Fig. 2 is a cross-sectional view showing a configuration example of one of the elements of the molten glass conveying apparatus of the present invention. Fig. 3 is a cross-sectional view of the test body used in Test Example 1. Fig. 4 is a perspective view showing the vicinity of the power supply unit 6 in the upper part of Figs. 3 and 5. m ¥ Fig. 5 is a cross-sectional view of the test body used in Comparative Example 1. Fig. 6 is an explanatory view of the impregnation test carried out in Test Example 2. [Description of main component symbols] 1 Molten glass conveying equipment component 120 Decompression housing la 1st conduit (vertical pipe) 130 Vacuum degassing tank lb 2nd pipe (horizontal pipe) 140 Upright pipe lc Hollow pipe 150 Down pipe 2 Ceramic structure 160 Thermal insulation material 3 Gap 170 Conduit 4 Second ceramic structure 180 Catheter 5 Flange 190 Conduit 6 Power supply part 200 Catheter 10 Test sample 220 Catheter 20 Crucible 240 Catheter 30 Smelting glass d Width 100 Decompression decompression Device 21